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Sample records for miquelon nr nauru

  1. Nauru: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    "","visitedicon":"" Country Profile Name Nauru Population 9,275 GDP Unavailable Energy Consumption 0.00 Quadrillion Btu 2-letter ISO code NR 3-letter ISO code NRU Numeric ISO...

  2. TWP Nauru Site

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Nauru Site-Inactive TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists TWP Nauru Site-Inactive Location: 0° 31' 15.6" S, 166° 54' 57.60" E Altitude: 7.1 meters The Nauru facility was established in November 1998 as the second TWP climate research station. Situated in the Denigomodu district

  3. Nauru Island Effect Detection Data Set

    DOE Data Explorer

    Long, Chuck

    2010-07-15

    During Nauru99 it was noted that the island was producing small clouds that advected over the ARM site. The Nauru Island Effect Study was run for 1.5 years and the methodology developed to detect the occurrence. Nauru ACRF downwelling SW, wind direction, and air temperature data are used, along with downwelling SW data from Licor radiometers located on the southern end of the island near the airport landing strip. A statistical analysis and comparison of data from the two locations is used to detect the likely occurrence of an island influence on the Nauru ACRF site data

  4. Nauru Island Effect Detection Data Set

    DOE Data Explorer

    Long, Chuck

    During Nauru99 it was noted that the island was producing small clouds that advected over the ARM site. The Nauru Island Effect Study was run for 1.5 years and the methodology developed to detect the occurrence. Nauru ACRF downwelling SW, wind direction, and air temperature data are used, along with downwelling SW data from Licor radiometers located on the southern end of the island near the airport landing strip. A statistical analysis and comparison of data from the two locations is used to detect the likely occurrence of an island influence on the Nauru ACRF site data

  5. ARM - TWP Nauru Site-Inactive

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Site-Inactive TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical...

  6. Nauru

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

  7. ARM - PI Product - Nauru Island Effect Detection Data Set

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ProductsNauru Island Effect Detection Data Set ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Nauru Island Effect Detection Data Set During Nauru99 it was noted that the island was producing small clouds that advected over the ARM site. The Nauru Island Effect Study was run for 1.5 years and the methodology developed to detect the occurrence. Nauru ACRF downwelling SW, wind direction, and air

  8. Nauru Island Effect Detection Data Set (Dataset) | Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Nauru ACRF downwelling SW, wind direction, and air temperature data are used, along with ... fraction; Cloud optical depth; Horizontal wind; Longwave broadband downwelling ...

  9. Using ARM TWP Nauru Observations to Evaluate a Simple Thermodynamic...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Using ARM TWP Nauru Observations to Evaluate a Simple Thermodynamic Model of the Subcloud Layer Under Fair-Weather Cumulus Conditions Albrecht, Bruce University of Miami Kollias, ...

  10. The Impact of the Annual Cycle on Cloudiness at Manus and Nauru

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Impact of the Annual Cycle on Cloudiness at Manus and Nauru J. H. Mather Pacific Northwest National Laboratory Richland, Washington Introduction Convection is ubiquitous throughout the maritime continent region. The frequency of convection is modulated by a variety of phenomena including the diurnal cycle, intra-seasonal waves, and El Niño/Southern Oscillation (ENSO). While much of this region does not experience seasons to the same degree as one finds in mid-latitudes, the annual solar cycle

  11. Remote Sensing Observations from MTI Satellites and GMS Over Tropical Island of Nauru

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Remote Sensing Observations from MTI Satellites and GMS Over Tropical Island of Nauru W. M. Porch, P. Chylek, and B. Henderson Los Alamos National Laboratory Los Alamos, New Mexico Introduction The observations of island cloud trails have revealed a strong relationship between the character and frequency of occurrence of island cloud trails and the Tropical Ocean Southern Oscillation (MacFarlane et al. 2004 a, b). Island cloud trails from the U.S. Department of Energy's (DOE) Atmospheric and

  12. Cloud Classes and Radiative Heating profiles at the Manus and Nauru Atmospheric Radiation Measurement (ARM) Sites

    SciTech Connect

    Mather, James H.; McFarlane, Sally A.

    2009-10-07

    The Tropical Western Pacific (TWP) is a convective regime; however, the frequency and depth of convection is dependant on dynamical forcing which exhibits variability on a range of temporal scales and also on location within the region. Manus Island, Papua New Guinea lies in the heart of the western Pacific warm pool region and exhibits frequent deep convection much of the time while Nauru, which lies approximately 20 degrees to the East of Manus, lies in a transition zone where the frequency of convection is dependent on the phase of the El Nino/Southern Oscillation. Because of this difference in dynamical regime, the distribution of clouds and the associated radiative heating is quite different at the two sites. Individual cloud types: boundary layer cumulus, thin cirrus, stratiform convective outflow, do occur at both sites – but with different frequencies. In this study we compare cloud profiles and heating profiles for specific cloud types at these two sites using data from the Atmospheric Radiation Measurement (ARM) Climate Research Facility (ACRF). Results of this comparison indicate that, while the frequency of specific cloud types differ between the two sites as one would expect, the characteristics of individual cloud classes are remarkably similar. This information could prove to be very useful for applying tropical ARM data to the broader region.

  13. Nauru Island Effect Study

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Although these shallow cumulus clouds have little impact on the total radiation budget of ... 1999 through June 2000 by Nordeen et al. (2001), cloud plumes were seen in 50% of the ...

  14. nr | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    nr On Womens Equality Day, we celebrate NNSA's talented Women in STEM About Naval Reactors What Is the Naval Nuclear Propulsion Program? The Naval Nuclear Propulsion Program comprises the military and civilian personnel who design, build, operate, maintain, and manage the nuclear-powered ships and the many facilities that support the U.S. nuclear-powered naval fleet. The Program... Powering the Nuclear Navy Concern for the Environment Protection of People Naval Nuclear Propulsion Plants Annual

  15. nr

    National Nuclear Security Administration (NNSA)

    4%2A en Powering the Nuclear Navy http:www.nnsa.energy.govourmissionpoweringnavy

    Page...

  16. nr

    National Nuclear Security Administration (NNSA)

    %2A en Powering the Nuclear Navy http:nnsa.energy.govourmissionpoweringnavy

    Page...

  17. ARM - Field Campaign - Nauru99 Campaign

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    General guidelines: ARM-sponsored data will be shared in accordance with the basic tenets ... when and where feasible. 3). Timely release of data to the ARM Science Team and the ...

  18. Nauru'99: Scaling of Radiosondes by

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Technology Laboratory Boulder, Colorado D. Cimini University of L' Aquila L' Aquila, Italy B. M. Lesht Argonne National Laboratory Chicago, Illinois Introduction Previous ...

  19. Hanford Site - 100-NR-2 | Department of Energy

    Office of Environmental Management (EM)

    NR-2 Hanford Site - 100-NR-2 July 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Hanford Site, WA Responsible DOE Office: Office of Environmental Management Plume Name: 100-NR-2 Remediation Contractor: CHPRC PBS Number: 30 Report Last Updated: July 2014 with CY2013 data Contaminants Halogenated VOCs/SVOCs Present?: No Fuel Present? Yes Metals Present? Yes Isotopes Present? Yes Explosives Present? No Other Contaminants? No

  20. Preliminary Analysis of the Nauru Island Effect Study Data

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    to the surrounding ocean) induces convection and cloud formation (Nordeen et al. 2001). ... relatively small effect on the radiation budget in the region, it may cause the radiation ...

  1. Microsoft Word - DE-NR0000031-075.doc

    National Nuclear Security Administration (NNSA)

    ITEM NO. SUPPLIES/SERVICES QUANTITY UNIT UNIT PRICE AMOUNT NAME OF OFFEROR OR CONTRACTOR 2 183 CONTINUATION SHEET REFERENCE NO. OF DOCUMENT BEING CONTINUED PAGE OF BECHTEL MARINE PROPULSION CORPORATION (A) (B) (C) (D) (E) (F) DE-NR0000031/075 a. Clause 4., Changes, is amended by removing the name G. W. Twardowski. Therefore, page 2 of Section H is deleted in its entirety and replaced with the new page 2 attached hereto. b. Clause 26., Responsible Corporate Official, is amended by inserting

  2. Summary of TPH Monitoring Conducted at 100-NR-2 during CY 2008 and 2009

    SciTech Connect

    Fritz, Brad G.; Mendoza, Donaldo P.; young, david; Stegen, J. A.; Bunn, Amoret L.

    2009-08-12

    This report covers a variety of environmental monitoring activities that were conducted over an 18 month period to provide characterization of a TPH-diesel contamination plume in the 100-NR-2 OU

  3. The LANL C-NR counting room and fission product yields

    SciTech Connect

    Jackman, Kevin Richard

    2015-09-21

    This PowerPoint presentation focused on the following areas: LANL C-NR counting room; Fission product yields; Los Alamos Neutron wheel experiments; Recent experiments ad NCERC; and Post-detonation nuclear forensics

  4. Activation of nuclear receptor NR5A2 increases Glut4 expression and glucose metabolism in muscle cells

    SciTech Connect

    Bolado-Carrancio, A.; Riancho, J.A.; Sainz, J.; Rodrguez-Rey, J.C.

    2014-04-04

    Highlights: NR5A2 expression in C2C12 is associated with myotube differentiation. DLPC induces an increase in GLUT4 levels and glucose uptake in C2C12 myotubes. In high glucose conditions the activation of NR5A2 inhibits fatty acids oxidation. - Abstract: NR5A2 is a nuclear receptor which regulates the expression of genes involved in cholesterol metabolism, pluripotency maintenance and cell differentiation. It has been recently shown that DLPC, a NR5A2 ligand, prevents liver steatosis and improves insulin sensitivity in mouse models of insulin resistance, an effect that has been associated with changes in glucose and fatty acids metabolism in liver. Because skeletal muscle is a major tissue in clearing glucose from blood, we studied the effect of the activation of NR5A2 on muscle metabolism by using cultures of C2C12, a mouse-derived cell line widely used as a model of skeletal muscle. Treatment of C2C12 with DLPC resulted in increased levels of expression of GLUT4 and also of several genes related to glycolysis and glycogen metabolism. These changes were accompanied by an increased glucose uptake. In addition, the activation of NR5A2 produced a reduction in the oxidation of fatty acids, an effect which disappeared in low-glucose conditions. Our results suggest that NR5A2, mostly by enhancing glucose uptake, switches muscle cells into a state of glucose preference. The increased use of glucose by muscle might constitute another mechanism by which NR5A2 improves blood glucose levels and restores insulin sensitivity.

  5. 100-NR-2 Apatite Treatability Test FY09 Status: High Concentration Calcium-Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization

    SciTech Connect

    Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Szecsody, James E.; Williams, Mark D.

    2009-12-16

    100-NR-2 Apatite Treatability Test FY09 Status: High Concentration Calcium-Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization INTERIM LETTER REPORT

  6. AmeriFlux US-NR1 Niwot Ridge Forest (LTER NWT1)

    DOE Data Explorer

    Blanken, Peter [University of Colorado

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-NR1 Niwot Ridge Forest (LTER NWT1). Site Description - The Niwot Ridge AmeriFlux site is located in a subalpine forest ecosystem just below the Continental Divide near Nederland, CO. The site is located at 3050 m elevation, within 600m of the NOAA C1 long-term monitoring station, approximately 8 km east of the Continental Divide. The surrounding subalpine forest is ~97 years old and in a state of aggradation, having recovered from early twentieth century logging (Monson, et al. Global Change Biology (2002), 8 459-478).

  7. Pacific Northwest National Laboratory Apatite Investigation at the 100-NR-2 Quality Assurance Project Plan

    SciTech Connect

    Fix, N. J.

    2008-03-28

    This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by staff working on the 100-NR-2 Apatite Project. The U.S. Department of Energy, Fluor Hanford, Inc., Pacific Northwest National Laboratory, and the Washington Department of Ecology agreed that the long-term strategy for groundwater remediation at 100-N would include apatite sequestration as the primary treatment, followed by a secondary treatment. The scope of this project covers the technical support needed before, during, and after treatment of the targeted subsurface environment using a new high-concentration formulation.

  8. ARM - Education Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Nauru Airport. The kiosk at Nauru. Two children at the TWP kiosk dedication at Nauru sport ARM Climate Research Facility headwear. Beginning in 2003, ARM Education and Outreach...

  9. ARM Climate Modeling Best Estimate From Nauru (ARMBE-ATM TWPC2)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  10. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC2)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2012-05-14

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  11. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC1)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2012-05-14

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  12. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC2 V2.1)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2010-08-11

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  13. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC3)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2012-05-14

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  14. ARM Climate Modeling Best Estimate From Nauru (ARMBE-ATM TWPC2)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2010-10-05

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  15. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC1)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  16. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC3)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  17. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC2)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  18. ARM Climate Modeling Best Estimate from Nauru (ARMBE-CLDRAD TWPC2 V2.1)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  19. PNNL Apatite Investigation at 100-NR-2 Quality Assurance Project Plan

    SciTech Connect

    Fix, N. J.

    2009-04-02

    In 2004, the U.S. Department of Energy, Fluor Hanford, Inc., Pacific Northwest National Laboratory (PNNL), and the Washington Department of Ecology agreed that the long-term strategy for groundwater remediation at the 100-N Area would include apatite sequestration as the primary treatment, followed by a secondary treatment if necessary. Since then, the agencies have worked together to agree on which apatite sequestration technology has the greatest chance of reducing strontium-90 flux to the Columbia River. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by staff working on the PNNL Apatite Investigation at 100-NR-2 Project. The plan is designed to be used exclusively by project staff.

  20. Tetrahalide Complexes of the [U(NR)(2)]2+ Ion: Synthesis, Theory, and Chlorine K-Edge X-ray Absorption Spectroscopy

    SciTech Connect

    Spencer, Liam P.; Yang, Ping; Minasian, Stefan G.; Jilek, Robert E.; Batista, Enrique R.; Boland, Kevin S.; Boncella, James M.; Conradson, S. D.; Clark, David L.; Hayton, Trevor W.; Kozimor, Stosh A.; Martin, Richard L.; MacInnes, Molly M.; Olson, Angela C.; Scott, Brian L.; Shuh, D. K.; Wilkerson, Marianne P.

    2013-02-13

    Synthetic routes to salts containing uranium bisimido tetrahalide anions [U(NR)(2)X-4](2-) (X = Cl-, Br-) and non-coordinating NEt4+ and PPh4+ countercations are reported. In general, these compounds can be prepared from U(NR)(2)I-2(THF)(x) (x = 2 and R = 'Bu, Ph; x = 3 and R = Me) upon addition of excess halide. In addition to providing stable coordination complexes with Cl-, the [U(NMe)(2)](2 +) cation also reacts with Br- to form stable [NEt4](2)[U(NMe)(2)Br-4] complexes. These materials were used as a platform to compare electronic structure and bonding in [U(NR)(2)](2+) with [UO2](2+). Specifically, Cl K-edge X-ray absorption spectroscopy (XAS) and both ground-state and time-dependent hybrid density functional theory (DFT and TDDFT) were used to probe U-Cl bonding interactions in [PPh4](2)[U((NBu)-Bu-t)(2)Cl-4] and [PPh4](2)[UO2Cl4]. The DFT and XAS results show the total amount of Cl 3p character mixed with the U 5f orbitals was roughly 7-10% per U-Cl bond for both compounds, which shows that moving from oxo to imido has little effect on orbital mixing between the U 5f and equatorial Cl 3p orbitals. The results are presented in the context of recent Cl K-edge XAS and DFT studies on other hexavalent uranium chloride systems with fewer oxo or imido ligands.

  1. ARM XDC Datastreams

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... DAR Darwin, Australia ECMWF European Centre for Medium Range Forecasting FKB Black Forest, Germany GRIB GRIdded Binary MAN Manus, Papua New Guinea NAU Nauru, Republic of Nauru NIM ...

  2. ARM - 2000 ARM Science Team Meeting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Judy Curry - TBD MJ Post - Nauru99: Overview of Ship OperationsResults Stuart Mathews - Aircraft Radiation and Flux Measurements from the Nauru99 Field Program Chuck Long...

  3. Environmental contaminants activate human and polar bear (Ursus maritimus) pregnane X receptors (PXR, NR1I2) differently

    SciTech Connect

    Lille-Langøy, Roger; Goldstone, Jared V.; Rusten, Marte; Milnes, Matthew R.; Male, Rune; Stegeman, John J.; Blumberg, Bruce; Goksøyr, Anders

    2015-04-01

    Background: Many persistent organic pollutants (POPs) accumulate readily in polar bears because of their position as apex predators in Arctic food webs. The pregnane X receptor (PXR, formally NR1I2, here proposed to be named promiscuous xenobiotic receptor) is a xenobiotic sensor that is directly involved in metabolizing pathways of a wide range of environmental contaminants. Objectives: In the present study, we comparably assess the ability of 51 selected pharmaceuticals, pesticides and emerging contaminants to activate PXRs from polar bears and humans using an in vitro luciferase reporter gene assay. Results: We found that polar bear PXR is activated by a wide range of our test compounds (68%) but has a slightly more narrow ligand specificity than human PXR that was activated by 86% of the 51 test compounds. The majority of the agonists identified (70%) produces a stronger induction of the reporter gene via human PXR than via polar bear PXR, however with some notable and environmentally relevant exceptions. Conclusions: Due to the observed differences in activation of polar bear and human PXRs, exposure of each species to environmental agents is likely to induce biotransformation differently in the two species. Bioinformatics analyses and structural modeling studies suggest that amino acids that are not part of the ligand-binding domain and do not interact with the ligand can modulate receptor activation. - Highlights: • Comparative study of ligand activation of human and polar bear PXRs. • Polar bear PXR is a promiscuous ligand-activated nuclear receptor but less so than human PXR. • Environmental contaminants activate human and polar bear PXRs differently. • Expression and ligand promiscuity indicate that PXR is a xenosensor in polar bears.

  4. 100-NR-2 Apatite Treatability Test: High-Concentration Calcium-Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization

    SciTech Connect

    Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Szecsody, James E.; Williams, Mark D.

    2010-09-01

    Following an evaluation of potential strontium-90 (90Sr) treatment technologies and their applicability under 100-NR-2 hydrogeologic conditions, the U.S. Department of Energy (DOE), Fluor Hanford, Inc. (now CH2M Hill Plateau Remediation Company [CHPRC]), Pacific Northwest National Laboratory, and the Washington State Department of Ecology agreed that the long-term strategy for groundwater remediation at the 100-N Area should include apatite as the primary treatment technology. This agreement was based on results from an evaluation of remedial alternatives that identified the apatite permeable reactive barrier (PRB) technology as the approach showing the greatest promise for reducing 90Sr flux to the Columbia River at a reasonable cost. This letter report documents work completed to date on development of a high-concentration amendment formulation and initial field-scale testing of this amendment solution.

  5. ARM - Feature Stories and Releases Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    30, 2013 [Facility News, Feature Stories and Releases] Small Footprint, Big Shoes: Stepping Out at Nauru Bookmark and Share Kim Nitschke (white shirt) joined members of the Nauru Government for a walk down memory lane at the ARM Nauru site to help commemorate the site decommissioning, recognized at a closing reception on September 23, 2013. Kim Nitschke (white shirt) joined members of the Nauru Government for a walk down memory lane at the ARM Nauru site to help commemorate the site

  6. ARM Climate Modeling Best Estimate from Nauru with additional satellite product (ARMBE-CLDRAD TWPC2 V2.1a)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    2011-02-07

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  7. ARM Climate Modeling Best Estimate from Nauru with additional satellite product (ARMBE-CLDRAD TWPC2 V2.1a)

    DOE Data Explorer

    McCoy, Renata; Xie, Shaocheng

    The ARM CMBE-ATM [Xie, McCoy, Klein et al.] data file contains a best estimate of several selected atmospheric quantities from ACRF observations and NWP analysis data.

  8. The Niwot Ridge Subalpine Forest US-NR1 AmeriFlux site – Part 1: Data acquisition and site record-keeping

    DOE PAGES [OSTI]

    Burns, Sean P.; Maclean, Gordon D.; Blanken, Peter D.; Oncley, Steven P.; Semmer, Steven R.; Monson, Russell K.

    2016-09-29

    The Niwot Ridge Subalpine Forest AmeriFlux site (US-NR1) has been measuring eddy-covariance ecosystem fluxes of carbon dioxide, heat, and water vapor since 1 November 1998. Throughout this 17-year period there have been changes to the instrumentation and improvements to the data acquisition system. Here, in Part 1 of this three-part series of papers, we describe the hardware and software used for data-collection and metadata documentation. We made changes to the data acquisition system that aimed to reduce the system complexity, increase redundancy, and be as independent as possible from any network outages. Changes to facilitate these improvements were (1) switching to a PC/104-based computer runningmore » the National Center for Atmospheric Research (NCAR) In-Situ Data Acquisition Software (NIDAS) that saves the high-frequency data locally and over the network, and (2) time-tagging individual 10 Hz serial data samples using network time protocol (NTP) coupled to a GPS-based clock, providing a network-independent, accurate time base. Since making these improvements almost 2 years ago, the successful capture of high-rate data has been better than 99.98 %. We also provide philosophical concepts that shaped our design of the data system and are applicable to many different types of environmental data collection.« less

  9. Interim Report: 100-NR-2 Apatite Treatability Test: Low Concentration Calcium Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization

    SciTech Connect

    Williams, Mark D.; Fritz, Brad G.; Mendoza, Donaldo P.; Rockhold, Mark L.; Thorne, Paul D.; Xie, YuLong; Bjornstad, Bruce N.; Mackley, Rob D.; Newcomer, Darrell R.; Szecsody, James E.; Vermeul, Vincent R.

    2008-07-11

    Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100-NR-2 hydrogeologic conditions, U.S. Department of Energy, Fluor Hanford, Inc., Pacific Northwest National Laboratory, and the Washington Department of Ecology agreed that the long-term strategy for groundwater remediation at 100-N Area will include apatite sequestration as the primary treatment, followed by a secondary treatment if necessary (most likely phytoremediation). Since then, the agencies have worked together to agree on which apatite sequestration technology has the greatest chance of reducing Sr-90 flux to the river at a reasonable cost. In July 2005, aqueous injection, (i.e., the introduction of apatite-forming chemicals into the subsurface) was endorsed as the interim remedy and selected for field testing. Studies are in progress to assess the efficacy of in situ apatite formation by aqueous solution injection to address both the vadose zone and the shallow aquifer along the 300 ft of shoreline where Sr-90 concentrations are highest. This report describes the field testing of the shallow aquifer treatment.

  10. EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3

    SciTech Connect

    Wolery, T.J.

    1992-09-14

    EQ3NR is an aqueous solution speciation-solubility modeling code. It is part of the EQ3/6 software package for geochemical modeling. It computes the thermodynamic state of an aqueous solution by determining the distribution of chemical species, including simple ions, ion pairs, and complexes, using standard state thermodynamic data and various equations which describe the thermodynamic activity coefficients of these species. The input to the code describes the aqueous solution in terms of analytical data, including total (analytical) concentrations of dissolved components and such other parameters as the pH, pHCl, Eh, pe, and oxygen fugacity. The input may also include a desired electrical balancing adjustment and various constraints which impose equilibrium with special pure minerals, solid solution end-member components (of specified mole fractions), and gases (of specified fugacities). The code evaluates the degree of disequilibrium in terms of the saturation index (SI = 1og Q/K) and the thermodynamic affinity (A = {minus}2.303 RT log Q/K) for various reactions, such as mineral dissolution or oxidation-reduction in the aqueous solution itself. Individual values of Eh, pe, oxygen fugacity, and Ah (redox affinity) are computed for aqueous redox couples. Equilibrium fugacities are computed for gas species. The code is highly flexible in dealing with various parameters as either model inputs or outputs. The user can specify modification or substitution of equilibrium constants at run time by using options on the input file.

  11. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    by Clouds Bookmark and Share A new data set that identifies periods when Nauru data ... The Nauru island effect (NIE) data set currently covers the period from September 2005 to ...

  12. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The SMET systems are located at each of the TWP sites of Darwin, Australia, Los Negros Island in Manus, Papua New Guinea and Nauru Island, Republic of Nauru. The SMET is used to ...

  13. ARM - Visiting the TWP

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    InactiveVisiting the TWP TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists Visiting the TWP Nauru Island from the air. Nauru Island from the air. The Tropical Western Pacific site consists of three diverse climate research facilities in Papua New Guinea, the Republic of Nauru, and Australia. Each

  14. ARM - Site Instruments

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Nauru Site-InactiveInstruments TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists Instruments : Central Facility, Nauru Island Active Retired Active instruments are currently deployed at fixed or mobile facilities or are available through the ARM Aerial Facility. MFRSR Multifilter Rotating Shadowband

  15. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Air-Sea Temperatures Measured With Scanning Microwave and Infrared Radiometers in Nauru99 ... This paper presents further analysis and results from air-sea temperature difference ...

  16. ARM - Blog Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    October 1, 2013 [Blog, Field Notes] A Personal Note to Nauru Bookmark and Share Message from the ARM Tropical Western Pacific Site Scientist, Chuck Long: Circa 1998, Chuck Long shares his mood after helping ARM colleagues install the observation site on Nauru Island. Circa 1998, Chuck Long shares his mood after helping ARM colleagues install the observation site on Nauru Island. I first arrived on Nauru in late 1998 to help install the ARM site. Yes, I had a shovel in hand, digging the trenches

  17. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Radiation Measurement (ARM) Program. The tropical sites of Manus Island, Papua New Guinea, and the Island of Nauru are ideally located to study the tropical ocean warm pool. ...

  18. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    In a concerted effort to upgrade the TWP sites on Darwin, Australia; Nauru Island; and Manus Island, Papua New Guinea; infrastructure staff recently completed a number of notable ...

  19. Annual Energy Outlook 2015 - Appendix A

    Gasoline and Diesel Fuel Update

    ... Myanmar (Burma), Nauru, Nepal, New Caledonia, Niue, North Korea, Pakistan, Papua New Guinea, Philippines, Samoa, Singapore, Solomon Islands, Sri Lanka, Taiwan, Thailand, ...

  20. clements-99.PDF

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    New Caledonia Port Moresby Manus Nauru Midway Johnston Atoll Kwajalein Pohnpei Tarawa Truk Papua New Guinea Guam Hawaii Western Samoa American Samoa Cook Islands Tahiti Fiji Palau ...

  1. 8.5x11 ARM Brochure

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... University Japan * Nauru * Clouds and Radiation (CLARA) Study Netherlands * Papua New Guinea * Central Aerological Observatory Russia * Institute for Atmospheric Optics (IAO) ...

  2. Newsletter Southern Great Plains

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... He worked closely with teams from several laboratories to develop the measurement facilities that were ultimately deployed at Manus, Papua New Guinea; Nauru Island, Republic of ...

  3. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    data from ARM sites in Barrow, Alaska; Nauru Island; Manus Island, Papua New Guinea; and Darwin, Australia; and the Southern Great Plains (SGP) site in Lamont, Oklahoma. ...

  4. DISCLAIMER

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... currently operates a total of seven laser ceilometers at its fixed sites (in Oklahoma, Alaska, Australia, Papua New Guinea, and the Republic of Nauru) and its mobile facilities. ...

  5. Executive Summary

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    SW irradiance at the Nauru ARCS (blue), and the two top side met packages (black and red) shown in Figure 1. (J. Cole, PSU)... 2 3 Comparison of...

  6. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    data at five ARM sites: Barrow, Alaska; Lamont, Oklahoma; Darwin, Australia; Manus, Papa New Guinea; and Nauru Island. In addition to bringing ARM the MMCR, Ken is also...

  7. ARM - TWP Contacts

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Contacts TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection...

  8. ARM - TWP Science

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Science TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical...

  9. ARM - Information for Guest Scientists

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Scientists TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical...

  10. NR Pu SEIS Advisory 07272012_Clean

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Savannah R iver O perations O ffice P.O. B ox A Aiken, S C 2 9802 http://sro.srs.gov/index.html SAVANNAH R IVER O PERATIONS O FFICE AIKEN, S C 2 9802 NEWS M EDIA C ONTACTS: FOR I MMEDIATE R ELEASE Savannah R iver: B ill T aylor, ( 803) 9 52---8564 Friday, J uly 2 7, 2 012 bill.taylor@srs.gov Los A lamos: Toni C hiri, ( 505) 6 67---6691 toni.chiri@nnsa.doe.gov Carlsbad: Deb G ill, ( 575) 2 34---7270 deb.gill@wipp.ws Tennessee Ray G olden, ( 423) 7 51---8400 Valley A uthority: r rgolden@tva.gov

  11. Summary of NR Program Prometheus Efforts

    SciTech Connect

    Ashcroft, John; Eshelman, Curtis

    2007-01-30

    The Naval Reactors Program led work on the development of a reactor plant system for the Prometheus space reactor program. The work centered on a 200 kWe electric reactor plant with a 15-20 year mission applicable to nuclear electric propulsion (NEP). After a review of all reactor and energy conversion alternatives, a direct gas Brayton reactor plant was selected for further development. The work performed subsequent to this selection included preliminary nuclear reactor and reactor plant design, development of instrumentation and control techniques, modeling reactor plant operational features, development and testing of core and plant material options, and development of an overall project plan. Prior to restructuring of the program, substantial progress had been made on defining reference plant operating conditions, defining reactor mechanical, thermal and nuclear performance, understanding the capabilities and uncertainties provided by material alternatives, and planning non-nuclear and nuclear system testing. The mission requirements for the envisioned NEP missions cannot be accommodated with existing reactor technologies. Therefore concurrent design, development and testing would be needed to deliver a functional reactor system. Fuel and material performance beyond the current state of the art is needed. There is very little national infrastructure available for fast reactor nuclear testing and associated materials development and testing. Surface mission requirements may be different enough to warrant different reactor design approaches and development of a generic multi-purpose reactor requires substantial sacrifice in performance capability for each mission.

  12. Summary of NR Program Prometheus Efforts

    SciTech Connect

    J Ashcroft; C Eshelman

    2006-02-08

    The Naval Reactors Program led work on the development of a reactor plant system for the Prometheus space reactor program. The work centered on a 200 kWe electric reactor plant with a 15-20 year mission applicable to nuclear electric propulsion (NEP). After a review of all reactor and energy conversion alternatives, a direct gas Brayton reactor plant was selected for further development. The work performed subsequent to this selection included preliminary nuclear reactor and reactor plant design, development of instrumentation and control techniques, modeling reactor plant operational features, development and testing of core and plant material options, and development of an overall project plan. Prior to restructuring of the program, substantial progress had been made on defining reference plant operating conditions, defining reactor mechanical, thermal and nuclear performance, understanding the capabilities and uncertainties provided by material alternatives, and planning non-nuclear and nuclear system testing. The mission requirements for the envisioned NEP missions cannot be accommodated with existing reactor technologies. Therefore concurrent design, development and testing would be needed to deliver a functional reactor system. Fuel and material performance beyond the current state of the art is needed. There is very little national infrastructure available for fast reactor nuclear testing and associated materials development and testing. Surface mission requirements may be different enough to warrant different reactor design approaches and development of a generic multi-purpose reactor requires substantial sacrifice in performance capability for each mission.

  13. LANSCE | Lujan Center | Highlights | Neutron Reflectometry (NR...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    composites because the scattering strength is a non-monotonic function of the Z number of a material. Therefore, elements like Cu and Nb provide the necessary neutron...

  14. SCM Forcing Data Derived from NWP Analyses

    DOE Data Explorer

    Jakob, Christian

    2008-01-15

    Forcing data, suitable for use with single column models (SCMs) and cloud resolving models (CRMs), have been derived from NWP analyses for the ARM (Atmospheric Radiation Measurement) Tropical Western Pacific (TWP) sites of Manus Island and Nauru.

  15. cohn-99.PDF

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    from a 915-MHz radar wind profiler (RWP) with Radio Acoustic Sounding System (RASS). ... Measurements from the Nauru99 study conducted in the summer 1999 will provide more data ...

  16. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    students crowd around the new ARM educational kiosk to learn more about climate change. Surround by the Pacific Ocean, the Republic of Nauru is one of three sites that make...

  17. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Team Meeting Proceedings, San Antonio, Texas, March 13-17, 2000 2 Figure 1. Time series of a cloud plume near Nauru on October 27-28, 1999, Universal Time Coordinates (UTC). ...

  18. Through

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The first of these sites was established in 1996 on Manus Island, Papua New Guinea. The second TWP site was established on Nauru Island in 1998, and a third site began operating in ...

  19. DOE/SC-ARM-11-004 ARM Climate Research Facility The U.S. Department...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The TWP site is composed of facilities at Manus Island in Papua New Guinea; the island Republic of Nauru; and Darwin, Australia. Data are transmitted continuously from each site by ...

  20. ARM - Detailed Experiment Description

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    active research and is one of the main themes of research associated with the tropical western Pacific ARM sites located in Manus (Papua New Guinea), Nauru, and Darwin (Australia). ...

  1. DISCLAIMER

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... North Slope of Alaska, Barrow (NSA-C1) * Tropical Western Pacific, Manus Island, Papua New Guinea (TWP-C1) * Tropical Western Pacific, Nauru Island (TWP-C2) * Tropical Western ...

  2. Tropical Western Pacific CART Site

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Technical Contact: Douglas L. Sisterson Editor: Donna J. Holdridge CART sites in the TWP are in Manus Province in Papua New Guinea and on Nauru Island. The first site implemented ...

  3. Visiting Scientists and Researchers

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The TWP facility is composed of sites at Manus Island in Papua New Guinea, the island Republic of Nauru, and Darwin, Australia. Data are transmitted continuously from each site by ...

  4. ARM - Data Announcements Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Plains site from 1996-2007. Similar CMBE data will be available from the other ARM sites (Barrow, Alaska; Nauru Island; Manus Island, Papua New Guinea; and Darwin, Australia) soon. ...

  5. ARM TR-008

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... 3. Deployment Locations and History ARCS site C1 was installed on Manus Island, Papua New Guinea in October 1996. ARCS site C2 was installed on the island of Nauru (republic) in ...

  6. DOE/SC-ARM-TR-102 Sonde Adjust Value-Added Product Technical...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Slope of Alaska * twpsondeadjustC1.c1 - Tropical Western Pacific (TWP) Manus, Papua New Guinea * twpsondeadjustC2.c1 - TWP Nauru D Troyan, December 2011, DOESC-ARM-TR-102 6 * ...

  7. Developing El Niño The National Oceanic and Atmospheric Administratio...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The site at Manus Island (Figure 3), Papua New Guinea, is always in the "warm pool," whereas the site on the island of Nauru (Figure 4), approximately 1200 miles to the east, is in ...

  8. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... "Our greatest thanks is extended to the host countries and the people that we had the honor of working with in the Republic of Nauru, Papua New Guinea and Australia. I will truly ...

  9. clements-98.pdf

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Three sites (Figure 1) have been identified for imple- mentation in the TWP locale. The first site in Papua New Guinea (PNG) is operational, the second site on Nauru is scheduled ...

  10. ARM - Facility News Article

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... the MMCRs at the TWP Manus and Nauru sites will occur after TWP-ICE, so the associated components can be made available during the experiment should the need arise for spare parts

  11. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2004). For Manus and Nauru, an 8-month running composite fit is used for the clear-sky total downwelling shortwave (SW), with fit coefficients for the clear-sky ratio of...

  12. PowerPoint Presentation

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and (4) Coastal convection. ARM sites: D Darwin, M Manus, N Nauru). Plot color scheme: yellow is cold, blue is warm. 1 2 3 4 M M N N D D 6 December, 2005, 5:30 GMT 6...

  13. ARM - Kiosks

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    HomeroomKiosks Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Kiosks A kiosk was installed at the Nauru airport in November 2006. A kiosk was installed at the Nauru airport in November 2006. The North Slope of Alaska kiosk was installed in October 2003. The North Slope of Alaska kiosk was

  14. ARM - Traditional Knowledge

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    HomeroomTraditional Knowledge Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Traditional Knowledge An elder from Nauru is interviewed for the TWP kiosks. An elder from Nauru is interviewed for the TWP kiosks. Traditional knowledge can be defined as a cumulative body of knowledge and

  15. Research Highlight

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Tropical Radiosonde Comparisons May Improve Past and Present Humidity Data Submitter: Westwater, E. R., University of Colorado Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference: Westwater, E.R., B.B. Stankov, D.Cimini, Y. Han, J.A. Shaw, B.M. Lesht, C.N. Long, 2003, Radiosonde Humidity Soundings and Microwave Radiometers during Nauru99, Journal of Atmospheric and Oceanic Technology, Vol. 21. ARM's Nauru99 campaign provided a

  16. Research Highlight

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Modification of the Atmospheric Boundary Layer by a Small Island: Observations from Nauru Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Cloud Distributions/Characterizations Working Group(s): Radiative Processes Journal Reference: Matthews, S., J. M. Hacker, J. Cole, J. Hare, C. N. Long, and R. M. Reynolds, (2007): Modification of the atmospheric boundary layer by a small island: observations from Nauru, MWR, Vol. 135, No. 3, pages 891-905. Figure 1.

  17. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Evidence of Island Effects on Nauru Cole, H., and Miller, E., National Center for Atmospheric Research Ninth Atmospheric Radiation Measurement (ARM) Science Team Meeting Nauru Island has been selected as the second Atmospheric Radiation and Cloud Station (ARCS) for the Atmospheric Radiation Measurement (ARM) Program. The utility of this site for characterizing conditions over the Tropical Western Pacific depends directly on understanding the differences between this island site and the open

  18. ARM - Publications: Science Team Meeting Documents: An Observational

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Analysis of Cumulus Congestus at Nauru An Observational Analysis of Cumulus Congestus at Nauru Jensen, Michael Brookhaven National Laboratory Del Genio, Anthony NASA/Goddard Institute for Space Studies Cumulus congestus clouds, with moderate shortwave albedos and cloud-top temperatures near freezing, occur fairly often in the tropics. These clouds may play an important role in the evolution of the Madden-Julian oscillation and the regulation of relative humidity in the mid-troposphere.

  19. Microsoft Word - DE-NR0000031-075.doc

    National Nuclear Security Administration (NNSA)

    ... In the performance of work under this contract, the Contractor shall provide its services in a manner that promotes the natural environment, reduces greenhouse gas emissions and ...

  20. Microsoft Word - DE-NR0000031-001.rtf

    National Nuclear Security Administration (NNSA)

    SDLlCITATIDNIMDDIFICATIDN OF CONTRACT 1:.CONTRACTID CODE IPAGE OF PAGES DE-N ROOOOO31 1 I 27 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 4. REQUISmONJPURCHASE REQ. NO. I 5. PROJECT NO. (If applicable) 001 Same as Block l6C NlA 6. ISSUED BY CODE 7. ADMINISTERED BY (If other than Item 6) Code I U.S. Department of Energy Pittsburgh Naval Reactors Office P.O. Box 109 West Mifflin, PA 15122-0109 8. NAME AND ADDRESS OF CONTRACTOR (No. street, county, State end ZIP Code) J1... 9A. AMENDMENT OF

  1. NR WIPP Transportation Award Jan 9 2012f.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Environmental Management Consolidated Business Center 250 E. 5 th Street, Suite 500, Cincinnati, Ohio 45202 Media Contact: For Immediate Release Bill Taylor 803-952-8564 January 9,...

  2. NR Hanford OCMED Awd4 June 8 2012.docx

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Management Consolidated Business Center 250 E. 5 th Street, Suite 500, Cincinnati, Ohio 45202 Media Contact: June 8, 2012 Cameron Hardy 509-308-4947 Cameron.hardy@rl.gov DOE ...

  3. 2008-07-31 Draft NR Block Template

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Customer Name acquires from an identified or unidentified electricity-producing unit by contract purchase, and for which the amount received by Customer Name does not...

  4. Microsoft Word - NR WIPP CONTRACT EXTENSION MAY 3 2010.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    DOE Extends Management and Operations Contract at Waste Isolation Pilot Plant Carlsbad, NM. - The U.S. Department of Energy's Waste Isolation Pilot Plant (WIPP) today announced a...

  5. Microsoft Word - 090723NR200WGW.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    News Release Media Contact: For Immediate Release: Geoff Tyree, DOE July 23, 2009 (509) 376-4171, Geoff_Tyree@rl.gov U.S. Department of Energy Announces Start of Construction on Hanford's Largest Groundwater Treatment System Treatment system funded by American Recovery and Reinvestment Act RICHLAND, Wash. - Dr. Inés Triay, U.S. Department of Energy Assistant Secretary for Environmental Management, today announced that construction of the largest treatment system for contaminated groundwater to

  6. Microsoft Word - NR WIPP CONTRACT EXTENSION MAY 3 2010.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    DOE Extends Management and Operations Contract at Waste Isolation Pilot Plant Carlsbad, NM. - The U.S. Department of Energy's Waste Isolation Pilot Plant (WIPP) today announced a two-year extension of the Washington TRU Solutions LLC management and operations (M&O) contract. As the WIPP M&O contractor, Washington TRU Solutions is responsible for managing the National Transuranic (TRU) Waste Program, which includes retrieval, characterization, transportation, and disposal activities at

  7. NR Pu SEIS Advisory 07152010 _final_.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    SRS: Jim Giusti, (803) 952-7697 Thursday, July 15, 2010 james-r.giusti@srs.gov CBO: Deb Gill, (575) 234-7270 deg.gill@wipp.ws TVA: Terry Johnson, (423) 751-6875 twjohnson@tva.gov DOE Announces Modification of Supplemental Environmental Study on Plutonium Disposition WASHINGTON, DC -- The U.S. Department of Energy's (DOE) National Nuclear Security Administration is announcing its intent to modify the scope of the ongoing Surplus Plutonium Disposition Supplemental Environmental Impact Statement

  8. NR SRNS Contract Extension Sept 6 2012.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    September 6, 2012 Bill Taylor, 803-952-8564 bill.taylor@srs.gov DOE to Extend Savannah River Nuclear Solutions Contract at Savannah River Site to September 2016 Aiken, SC -- The Department of Energy's (DOE) Savannah River Operations Office today exercised its option to extend the current Savannah River Site Management and Operating contract with Savannah River Nuclear Solutions, LLC (SRNS) for an additional 38 months, from August 1, 2013 to September 2016. The SRNS contract was competitively

  9. NR-WFR Plan for Comment July 8 2013.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Monday, July 8, 2013 Bill Taylor - 803-952-8564 bill.taylor@srs.gov Public Comment Sought for Savannah River Site Workforce Restructuring Plan AIKEN, SC -- The Department of Energy Savannah River Site (DOE-SR) has posted a draft workforce restructuring plan for public comment. The draft workforce restructuring plan, prepared under Section 3161 of the National Defense Authorization Act, is designed to mitigate the impacts of any potential workforce reductions to contractor employees at the Site

  10. Microsoft Word - DE-NR0000031-FY11.doc

    National Nuclear Security Administration (NNSA)

    ... OR SUSPENSION OF ADVANCED, PARTIAL, OR ... and mathematics, including, but not limited to, research in economics, ... reports, and journal articles. (g) By ...

  11. DOE and HBCU MOU FINAL NR.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Department of Energy DOE Small Business Opportunities Working with DOE November 30 2016 DOE Small Business Opportunities Working with DOE November 30 2016 November 30, 2016 11:30AM to 1:00PM EST The Army and Navy Club of Washington, DC 901 17th Street, N.W. Washington, DC 20006 Luncheon series.... "DOE Small Business Opportunities/ Working with DOE" by John H. Hale III Director, Office of Small and Disadvantaged Business Utilization Department of Energy John is the Director of the

  12. DOE-NR CAB New Members.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    on the Citizens Advisory Board. The Savannah River Site (SRS) Citizens Advisory Board (CAB) is a community board that provides advice and recommendations, from a community...

  13. NR-CAB Meeting March 25-26 2013.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Management cleanup programs. For addition information on the SRS Citizens Advisory Board visit: http:www.srs.govgeneraloutreachsrs-cabsrs-cab.html -DOE- SR-13-01...

  14. c5nr01856k 9878..9885 ++

    Office of Scientific and Technical Information (OSTI)

    Universitat de Barcelona, Marti i Franques 1, 08028 Barcelona, Spain cDepartament de Fisica, Universitat Autonoma de Barcelona, 08193 Bellaterra (Barcelona), Spain dICN2 - ...

  15. Seasonal Variability in Clouds and Radiation at the Manus ARM Site

    SciTech Connect

    Mather, Jim H.

    2005-07-01

    The Atmospheric Radiation Measurement (ARM) program operates three climate observation stations in the tropical western Pacific region. Two of these sites, located on Manus island in Papua New Guinea and on the island republic of Nauru, have been operating for over five years. This data set provides an opportunity to examine variability in tropical cloudiness on a wide range of time scales. The focus of this study is on the annual cycle. The most obvious manifestation of the annual cycle in this region is the oscillation of monsoon convection between Asia and Australia. The impact of the annual cycle on Manus and Nauru is more subtle; however, analysis of radiation and cloud observations from the Manus and Nauru ARM sites reveals links to the annual monsoon cycle. One such link relates to the proximity of Manus to the Maritime Continent, the collection of islands separating the Pacific and Indian oceans. Convection over the large islands in the maritime continent exhibits a distinct annual cycle. Outflow from large-island convection is shown to modulate the cirrus population over Manus. During neutral or cool ENSO periods, convection over Nauru is relatively suppressed. During such periods, Nauru is shown to exhibit an annual cycle in local convective activity. During the inactive season, cirrus are often found near the tropopause over Nauru. These clouds are not formed directly by the outflow from convection. The seasonality and source of these clouds is also examined. Identifying the source of cirrus observed at Manus and Nauru is important because of the potential dependence of cirrus properties on the source of convection.

  16. Darwin : The Third DOE ARM TWP ARCS Site /

    SciTech Connect

    Clements, William E.; Jones, L. A.; Baldwin, T.; Nitschke, K.

    2002-01-01

    The United States Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) Program began operations in its Tropical Western Pacific (TWP) locale in October 1996 when the first Atmospheric Radiation and Cloud Station (ARCS) began collecting data on Manus Island in Papua New Guinea (PNG). Two years later, in November 1998, a second ARCS began operations on the island of Nauru in the Central Pacific. Now a third ARCS has begun collecting data in Darwin, Australia. The Manus, Nauru, and Darwin sites are operated through collaborative agreements with the PNG National Weather Service, The Nauru Department of Industry and Economic Development (IED), and the Australian Bureau of Meteorology's (BOM) Special Services Unit (SSU) respectively. All ARM TWP activities in the region are coordinated with the South Pacific Regional Environment Programme (SPREP) based in Apia, Samoa. The Darwin ARM site and its role in the ARM TWP Program are discussed.

  17. Research Highlight

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Case Closed on Nauru Island Effect Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Long CN and SA McFarlane. 2012. "Quantification of the impact of Nauru Island on ARM measurements." Journal of Applied Meteorology and Climatology, 51(3), 628-636. McFarlane SA, CN Long, and DM Flynn. 2005. "Impact of island-induced clouds on surface

  18. Research Highlight

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Island-Induced Cloud Plumes Influence Tropical Atmospheric Measurements, Surface Radiation Submitter: McFarlane, S. A., U.S. Department of Energy Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: McFarlane, S.A., Long, C.N., and Flynn, D., Nauru Island Effect Study, Fourteenth ARM Science Team Meeting, March 22 to 26, 2004, Albuquerque, New Mexico. Nauru Island, about 1,200 miles northeast of Papua New Guinea in the western South Pacific, is one of

  19. Tropical Western Pacific

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    govSitesTropical Western Pacific TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists Tropical Western Pacific-Inactive Manus, Papua New Guinea: 2° 3' 39.64" S, 147° 25' 31.43" E Nauru Island: 0° 31' 15.6" S, 166° 54' 57.60" E Darwin, Australia: 12° 25' 28.56" S, 130° 53'

  20. 1

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Comparison of the Daily Cycle of Lower-Tropospheric Winds Over the Open Ocean and Those Above a Small Island L. M. Hartten and W. M. Angevine Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Aeronomy Laboratory Boulder, Colorado Introduction The Nauru99 Intensive Operational Period (IOP) took place from June 16, 1999, (Day 167) to July 15, 1999, (Day 196) on and near the Republic of Nauru (0.5° S, 166.9° E).

  1. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Nauru99: Mirai Profiler Island Heating and other Observations Brown, W.O.J. (a), Parsons, D.B. (a), Cohn, S.A. (a), and Yoneyama, K. (b), National Center for Atmospheric Research (a), Japan Marine Science and Technology Center (b) Eleventh Atmospheric Radiation Measurement (ARM) Science Team Meeting Two boundary layer wind profilers on the JAMSTEC R/V Mirai made intensive observations of the boundary layer during the Nauru99 campaign. A DBS profiler was used to make standard wind profiler and

  2. ARM - Datastreams - avhrrhovmuller

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Datastreamsavhrrhovmuller Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRRHOVMULLER AVHRR: Hovmuller diagrams for Manus and Nauru Active Dates 1996.11.01 - 2002.07.01

  3. ARM - Datastreams - avhrr14gacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    gacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR14GACNAU Global Area Coverage 4-km resolution files for Nauru

  4. ARM - Datastreams - avhrr14lacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    lacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR14LACNAU AVHRR (NOAA 14), 1-km res., local area coverage of Nauru

  5. ARM - Datastreams - avhrr15gacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    gacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR15GACNAU Global Area Coverage 4-km resolution files for Nauru

  6. ARM - Datastreams - avhrr16gacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    gacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR16GACNAU Global Area Coverage 4-km resolution files for Nauru

  7. ARM - Datastreams - avhrr16lacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    lacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR16LACNAU AVHRR (NOAA 16), 1-km res., local area coverage of Nauru

  8. ARM - Datastreams - avhrr17lacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    lacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR17LACNAU AVHRR (NOAA 17), 1-km res., local area coverage of Nauru from Kwajalein, provided by Aeromet Active Dates 2002.09.15

  9. ARM - VAP Product - lbtm3minnisnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    minnisnau Documentation lbtm-minnis : XDC documentation Data Management Facility Plots (Quick Looks) ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send VAP Output : LBTM3MINNISNAU Layered Bispectral Threshold Method (LBTM) cloud products derived from GMS-5,Nauru

  10. SRS Biomass Startup NR-03 12 12 - DOE FINAL.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    AIKEN, SC 29802 NEWS MEDIA CONTACTS FOR IMMEDIATE RELEASE Amy Caver (803) 952-7213 March 12, 2012 amy.caver@srs.gov CarolAnn Hibbard, (508) 661-2264 news@ameresco.com SRS MARKS SUCCESSFUL OPERATIONAL STARTUP OF NEW BIOMASS COGENERATION FACILITY Senior DOE Officials and SC Congressional Leadership Gather to Celebrate Major Renewable Energy Project AIKEN, S.C. - (March 12) Today, Under Secretary of Energy Thomas D'Agostino joined U.S. Representative Joe Wilson (R-SC) and other senior officials

  11. http://www.bls.gov/news.release/osh.nr0.htm

    National Nuclear Security Administration (NNSA)

    industry injury and illness cases reported nationally in 2009 were of a more serious nature that involved days away from work, job transfer, or restriction--commonly referred to...

  12. N.R. 20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS...

    Office of Scientific and Technical Information (OSTI)

    20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; 14 SOLAR ENERGY; 15 GEOTHERMAL ENERGY; GEOTHERMAL POWER PLANTS; COMPUTERIZED SIMULATION; HEAT...

  13. 100-NR-2 Apatite Treatability Test: Fall 2010 Tracer Infiltration Test (White Paper)

    SciTech Connect

    Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Greenwood, William J.; Johnson, Timothy C.; Horner, Jacob A.; Strickland, Christopher E.; Szecsody, James E.; Williams, Mark D.

    2011-04-14

    The primary objectives of the tracer infiltration test were to 1) determine whether field-scale hydraulic properties for the compacted roadbed materials and underlying Hanford fm. sediments comprising the zone of water table fluctuation beneath the site are consistent with estimates based laboratory-scale measurements on core samples and 2) characterize wetting front advancement and distribution of soil moisture achieved for the selected application rate. These primary objectives were met. The test successfully demonstrated that 1) the remaining 2 to 3 ft of compacted roadbed material below the infiltration gallery does not limit infiltration rates to levels that would be expected to eliminate near surface application as a viable amendment delivery approach and 2) the combined aqueous and geophysical monitoring approaches employed at this site, with some operational adjustments based on lessons learned, provides an effective means of assessing wetting front advancement and the distribution of soil moisture achieved for a given solution application. Reasonably good agreement between predicted and observed tracer and moisture front advancement rates was observed. During the first tracer infiltration test, which used a solution application rate of 0.7 cm/hr, tracer arrivals were observed at the water table (10 to 12 ft below the bottom of the infiltration gallery) after approximately 5 days, for an advancement rate of approximately 2 ft/day. This advancement rate is generally consistent with pre-test modeling results that predicted tracer arrival at the water table after approximately 5 days (see Figure 8, bottom left panel). This agreement indicates that hydraulic property values specified in the model for the compacted roadbed materials and underlying Hanford formation sediments, which were based on laboratory-scale measurements, are reasonable estimates of actual field-scale conditions. Additional work is needed to develop a working relationship between resistivity change and the associated change in moisture content so that 4D images of moisture content change can be generated. Results from this field test will be available for any future Ca-citrate-PO4 amendment infiltration tests, which would be designed to evaluate the efficacy of using near surface application of amendments to form apatite mineral phases in the upper portion of the zone of water table fluctuation.

  14. Microsoft Word - NR DRAFT RFP WIPP M&O APR 1 2011

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    April 1, 2011 william.taylor@emcbc.doe.gov DOE Issues Draft Request for Proposals Seeking Contractor to Manage, Operate Waste Isolation Pilot Plant Cincinnati -- The U.S. Department of Energy (DOE) issued a Draft Request for Proposal (RFP) seeking a management and operations contractor to maintain the Waste Isolation Pilot Plan (WIPP) and manage the DOE National Transuranic Waste (TRU) Program in Carlsbad, New Mexico. The estimated value of the anticipated contract is from $130 to $160 million

  15. Microsoft Word - NR WIPP TECH ASSISTANCE RFQ MAY 3 2010.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    DOE Seeks Technical Assistance Contractor at New Mexico Waste Isolation Pilot Plant Cincinnati -- The Department of Energy (DOE) issued a Request for Quotation (RFQ) today for a technical assistance contract to the Carlsbad Field Office and the Waste Isolation Pilot Project (WIPP) in Carlsbad, NM. This acquisition is under a General Services Administration (GSA) Federal Supply Schedule. The Department intends to award a single task order with a three-year performance period with options that can

  16. Microsoft Word - NR WIPP TRANSPORT RFP MARCH 30 2011f2

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    March 30, 2011 william.taylor@emcbc.doe.gov DOE Seeks Trucking Services for Transuranic Waste Shipments Cincinnati -- The Department of Energy (DOE) today will issue a Request for Proposals for the continuation of carrier services to transport transuranic waste (TRU) between DOE sites and the Waste Isolation Pilot Plant (WIPP) site, near Carlsbad, New Mexico. The transportation of TRU waste is accomplished by contracted trucking carriers that ship the waste via public highways on custom designed

  17. NR-SRS TRU Waste Shipments Milestone June 4 2013.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    June 4, 2013 Bill Taylor, DOE-SR, (803) 952-8564 bill.taylor@srs.gov DT Townsend, SRNS, (803) 952-7566 Dt-lawrence.townsend@srs.gov Savannah River Site Exceeds Waste Shipment Goals AIKEN, S.C. - During the month of April, the Savannah River Site met two new milestone records towards analyzing, preparing, packaging and shipping radioactive transuranic (TRU) waste bound for a disposal site in New Mexico. The Savannah River Nuclear Solutions Solid Waste organization completed thirty-two TRU waste

  18. http://www.bls.gov/news.release/osh.nr0.htm

    National Nuclear Security Administration (NNSA)

    ... using the 2007 version of the North American Industry Classification System (NAICS 2007). ... Freedom of Information Act | Privacy & Security Statement | Disclaimers | Customer ...

  19. ARM - TWP Darwin Site - Aussie Trivia

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    InactiveTWP Darwin Site-InactiveTWP Darwin Site - Aussie Trivia TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists TWP Darwin Site - Aussie Trivia Did you know... The first beer brewed in Australia was in 1796 by John Boston, thus starting Australia's lifelong love for the amber nectar! Christmas is

  20. ARM - Datastreams - avhrr12lacnau

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    lacnau Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : AVHRR12LACNAU AVHRR (NOAA 12),1-km res., local area coverage of Nauru from Kwajalein, provided by Aeromet Active Dates 2002.04.16 - 2002.09.10

  1. ARM - Datastreams - ncepgfsnausprof

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Datastreamsncepgfsnausprof Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : NCEPGFSNAUSPROF NCEP GFS: vertical profiles of met quantities at sigma layers, at Nauru Active Dates 2001.01.01 - 2010.07.26 Measurement Categories Atmospheric State, Cloud Properties Originating Instrument National Centers for Environment Prediction Global Forecast System

  2. ARM - Datastreams - ncepgfsnauzprof

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Datastreamsncepgfsnauzprof Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : NCEPGFSNAUZPROF NCEP GFS: vertical profiles of met quantities at standard heights, at Nauru Active Dates 2001.01.01 - 2010.07.26 Measurement Categories Atmospheric State, Cloud Properties Originating Instrument National Centers for Environment Prediction Global Forecast System

  3. MS_08_15.pdf

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and Changes to the Merged Sounding VAP David Troyan and Mike Jensen, BNL Jim Mather and Sally McFarlane, PNNL Eli Mlawer and Jennifer Delamere, AER, Inc. Mark Miller, Rutger University Dave Turner, University of Wisconsin Jay Mace, University of Utah Merged Sounding Data Availability SGP: NSA: TWP Manus: TWP Nauru: TWP Darwin: 2000 - 2005 2004 - 2007 2006 2004 - 2006 2002 - 2006 Two versions of Merged Sounding exist. The original version is continuing to be run for all permanent sites; the

  4. campbell-99.PDF

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Micropulse Lidar Data Sets and Initial Observations at Nauru Island J. R. Campbell and D. L. Hlavka Science Systems and Applications Inc. National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland J. D. Spinhirne Mesoscale and Atmospheric Processes Branch National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland C. J. Flynn Pacific Northwest National Laboratory Richland, Washington Introduction Full-time atmospheric profiling

  5. Evaluation of Tropical Cirrus Cloud Properties and Dynamical Processes Derived from ECMWF Model Output and Ground Based Mea...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Tropical Cirrus Cloud Properties and Dynamical Processes Derived from ECMWF Model Output and Ground-Based Measurements Over Nauru Island J. M. Comstock and J. H. Mather Pacific Northwest National Laboratory Richland, Washington C. Jakob Bureau of Meteorology Research Centre Melbourne, Australia Introduction Identifying the mechanisms responsible for the formation of cirrus clouds is important in understanding the role of cirrus in the tropical atmosphere. Thin cirrus clouds near the tropical

  6. Microsoft Word - Gage-KS.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Intercomparisons of Cloud Observations from the AL S-band Profiler and the ETL K-band Millimeter-Wave Cloud Radar on the R/V Ronald H. Brown during Nauru99 K. S. Gage and D. A. Carter National Oceanic and Atmospheric Administration Aeronomy Laboratory Boulder, Colorado P. E. Johnston and C. R. Williams Cooperative Institute for Research in Environmental Sciences University of Colorado Boulder, Colorado M. Ryan Science Technology Corporation Boulder, Colorado D. Hazen and B. W. Orr National

  7. Research and development on ocean thermal energy conversion in Japan

    SciTech Connect

    Uehara, H.

    1982-08-01

    The study of Ocean Thermal Energy Conversion (OTEC) in Japan has been conducted under the leadership of a team of the ''Sunshine Project'', a national new energy development project promoted by the Ministry of International Trade and Industries (MITI) since 1974. At present, two experimental OTEC power plants -Nauru's OTEC plant and Imari's OTEC plant are operating. In this paper, the review of research and development activity of these two OTEC plants in Japan is made.

  8. Impact of cloud microphysics on squall line organization

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ARM Observations to Validate and Improve Cloud Micrfophysical Schemes Wojciech Grabowski (PI) Hugh Morrison, Sally McFarlane (Co-PIs) Hanna Pawlowska (Co-I) CMWG Breakout, ARM STM 2008 Two major efforts of project * Warm clouds. We will use microphysical retrievals from Nauru and SGP (including CLASIC), together with aircraft observations (RICO) to assess model simulations of shallow cumulus. * Focus is on treatment of turbulent- microphysical interactions and impact on optical properties. *

  9. In-service packet with pics.pmd

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Climate Change Into The Classroom ARM Education Program North Slope of Alaska 2002 What is ARM? What is ARM Education? The Atmospheric Radiation Measurement Program (here, "radiation" means sunlight and radiant heat) is the largest global climate change research program supported by the U.S. Department of Energy. The ARM Program has data collecting sites in three very different places in the world: the Tropical Western Pacific (Australia, Papua New Guinea, and Nauru), in the Southern

  10. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Radiative Effects of Cloud Inhomogeneity and Geometric Association over the Tropical Western Pacific Warm Pool Jensen, M.P.(a) and DelGenio, A.D.(b), Department of Applied Physics and Applied Mathematics, Columbia University, NASA GISS (a), NASA GISS (b) Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting The radiative and microphysical characteristics for several precipitating anvil systems observed by the TRMM satellite over the Manus or Nauru Island ARM sites are modelled.

  11. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Observations of Mid-level Convective Clouds During Nauru99 Jensen, M.P.(a) and Del Genio, A.D.(b), Department of Applied Physics and Applied Mathematics, Columbia University/ NASA GISS (a), NASA Goddard Institute for Space Studies Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting It has long been recognized that there is an abundance of different convective cloud types in the tropics. Tropical convective cloud populations have often been considered to be dominated by shallow

  12. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ARM Sites in the BSRN Database Hodges, G.B., University of Colorado, CIRES (a), NOAA (b) Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting A description of the four ARM sites (Billings/BRS, E13, Manus and Nauru) currently included in the Baseline Surface Radiation Network (BSRN) database. Details of the specific parameters being submitted are presented, as well as the data status for each site. An overview of the formatting process is also described

  13. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ARM Sites in the BSRN Database - Year 2002 Update Hodges, G.B., University of Colorado at Boulder CIRES and NOAA Thirteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting The current status and availability of ARM data in the Baseline Surface Radiation Network (BSRN) database is shown. The author is currently submitting data from BRS and E13 located in the Southern Great Plains Central Facility, and Manus and Nauru from the Tropical Western Pacific (TWP). These four sites comprise

  14. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    A Simulation Study of Shallow Moist Convection and Its Impact on the Atmospheric Boundary Layer Zhu, P. and Bretherton, C., University of Washington Thirteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting By comparing the simulations of a regional model (MM5) with the observations collected at the southern Great Plains (SGP) site and the tropical western Pacific (TWP) Nauru site of the Atmospheric Radiation Measurement (ARM) project, this paper evaluates the overall performance

  15. ARM - Site Instruments

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Manus Site-InactiveInstruments TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists Instruments : Central Facility, Manus I., PNG Active Retired Active instruments are currently deployed at fixed or mobile facilities or are available through the ARM Aerial Facility. MPL Micropulse Lidar Cloud Properties

  16. ARM - Site Instruments

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Darwin Site-InactiveInstruments TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists Instruments : Central Facility, Darwin, Australia Active Retired Active instruments are currently deployed at fixed or mobile facilities or are available through the ARM Aerial Facility. MFRSR Multifilter Rotating

  17. C:\DOCUME~1\d3k776\LOCALS~1\TEM

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Talking About Climate at Schools in the Tropical Western Pacific (continued on page 3) Education Climate Update ARM News from the ARM Program for students and teachers about climate change studies IN THIS ISSUE TWP Classroom Visits Elder Knowledge Student Activity Critical Thinking ? WCS Conservation Teacher's Experience Dr. Bill Porch, ARM Science Programs Specialist W WINTER 2002 hen I visit the ARM sites at Manus Island, Papua New Guinea and the Island Nation of Nauru, I am often asked to

  18. NNSA Defense Programs Announces Quarterly Awards | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Defense Programs Announces Quarterly Awards February 16, 2011 Microsoft Office document icon NR-02-1

  19. Performance of Nafion® N115, Nafion® NR-212, and Nafion® NR-211 in a 1 kW Class All Vanadium Mixed Acid Redox Flow Battery

    SciTech Connect

    Reed, David M.; Thomsen, Edwin C.; Wang, Wei; Nie, Zimin; Li, Bin; Wei, Xiaoliang; Koeppel, Brian J.; Sprenkle, Vincent L.

    2015-07-01

    Three Nafion membranes of similar composition but different thicknesses were operated in a 3-cell 1kW class all vanadium mixed acid redox flow battery. The influence of current density on the charge/discharge characteristics, coulombic and energy efficiency, capacity fade, operating temperature and pressure drop in the flow circuit will be discussed and correlated to the Nafion membrane thickness. Material costs associated with the Nafion membranes, ease of handling the membranes, and performance impacts will also be discussed.

  20. Atmospheric Radiation Measurement (ARM) Data from the Tropical Western Pacific (TWP) Site.

    DOE Data Explorer

    ARM maintains four major, permanent sites for data collection and deploys the ARM Mobile Facility to other sites as determined. The Tropical Western Pacific (TWP) site is one of the four fixed sites. It consists of three climate research facilities; the Manus facility on Los Negros Island in Manus, Papua New Guinea (established in 1996); the Nauru facility on Nauru Island, Republic of Nauru (1998); and the Darwin facility in Darwin, Northern Territory, Australia (2002). The operations are supported by government agencies in each host country. Covering the area roughly between 10 degrees N and 10 degrees S of the equator and from 130 degrees E to 167 degrees E, the TWP locale includes a region that plays a large role in the interannual variability observed in the global climate system. More than 250,000 TWP data sets from 1996 to the present reside in the ARM Archive. Begin at the TWP information page for links or access data directly from the ARM Archive at http://www.archive.arm.gov/. Users will need to register for a password, but all files are then free for viewing or downloading. The ARM Archive physically resides at the Oak Ridge National Laboratory.

  1. E&nr Ph. S. W.. Wahhgt~n. D.C. 200242174, TIkpbnc (202) 48a60uo

    Office of Legacy Management (LM)

    ... Operations Office revealed five additional colleges and universities that performed research in support of Hanford's Division of Biology and Medicine and Division of Research. ...

  2. SREL Reprint #3036

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    of East Anglia, Norwich NR4 7TJ, UK 2Molecular Biology, Ume University, SE-901 87 Ume, Sweden 3Department of Molecular Biology, John Innes Centre, Norwich NR4 7UH, UK ...

  3. Y-12 Breaks Ground for Potable Water System Upgrades Project...

    National Nuclear Security Administration (NNSA)

    Breaks Ground for Potable Water System Upgrades Project March 15, 2008 Microsoft Office document icon NR-2-08

  4. Atmospheric Radiation Measurement (ARM) Data from the Tropical Western Pacific (TWP) Site.

    DOE Data Explorer

    The Atmospheric Radiation Measurement (ARM) Program is the largest global change research program supported by the U.S. Department of Energy. The primary goal of the ARM Program is to improve the treatment of cloud and radiation physics in global climate models in order to improve the climate simulation capabilities of these models. To achieve this goal, ARM scientists and researchers around the world use continuous data obtained through the ARM Climate Research Facility. ARM maintains four major, permanent sites for data collection and deploys the ARM Mobile Facility to other sites as determined. The Tropical Western Pacific (TWP) site is one of the four fixed sites. It consists of three climate research facilities; the Manus facility on Los Negros Island in Manus, Papua New Guinea (established in 1996); the Nauru facility on Nauru Island, Republic of Nauru (1998); and the Darwin facility in Darwin, Northern Territory, Australia (2002). The operations are supported by government agencies in each host country. Covering the area roughly between 10 degrees N and 10 degrees S of the equator and from 130 degrees E to 167 degrees E, the TWP locale includes a region that plays a large role in the interannual variability observed in the global climate system. More than 250,000 TWP data sets from 1996 to the present reside in the ARM Archive. Begin at the TWP information page for links or access data directly from the ARM Archive at http://www.archive.arm.gov/. Users will need to register for a password, but all files are then free for viewing or downloading. The ARM Archive physically resides at the Oak Ridge National Laboratory.

  5. ARM - PI Product - SCM Forcing Data Derived from NWP Analyses

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ProductsSCM Forcing Data Derived from NWP Analyses ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : SCM Forcing Data Derived from NWP Analyses Forcing data, suitable for use with single column models (SCMs) and cloud resolving models (CRMs), have been derived from NWP analyses for the ARM (Atmospheric Radiation Measurement) Tropical Western Pacific (TWP) sites of Manus Island and Nauru. Data Details

  6. ARM - VAP Product - armbeatm

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Productsarmbearmbeatm Documentation Data Management Facility Plots (Quick Looks) Citation DOI: 10.5439/1095313 DOI: 10.5439/1039931 Central Facility, Lamont, OK (SGP C1) DOI: 10.5439/1039932 Central Facility, Barrow AK (NSA C1) DOI: 10.5439/1039933 Central Facility, Manus I., PNG (TWP C1) DOI: 10.5439/1039934 Central Facility, Nauru Island (TWP C2) DOI: 10.5439/1039935 Central Facility, Darwin, Australia (TWP C3) [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We

  7. ARM - VAP Product - armbecldrad

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Productsarmbearmbecldrad Documentation Data Management Facility Plots (Quick Looks) Citation DOI: 10.5439/1095314 DOI: 10.5439/1039926 Central Facility, Lamont, OK (SGP C1) DOI: 10.5439/1039927 Central Facility, Barrow AK (NSA C1) DOI: 10.5439/1039928 Central Facility, Manus I., PNG (TWP C1) DOI: 10.5439/1039929 Central Facility, Nauru Island (TWP C2) DOI: 10.5439/1039930 Central Facility, Darwin, Australia (TWP C3) [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We

  8. ARM - Campaign Instrument - lbtm-minnis

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    govInstrumentslbtm-minnis Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Minnis Cloud Products Using LBTM Algorithm (LBTM-MINNIS) Instrument Categories Cloud Properties, Satellite Observations Campaigns ARESE II IOP [ Download Data ] Southern Great Plains, 2000.02.01 - 2000.04.05 Nauru99 Campaign [ Download Data ] Tropical Western Pacific, 1999.06.16 - 1999.07.15 Primary Measurements Taken The following measurements are

  9. Microsoft PowerPoint - ARM_2008.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    MEASUREMENTS OF VERTICAL VELOCITY IN BOUNDARY LAYER CLOUDS P. Kollias 1 , B. A. Albrecht 2 and V. Ghate 2 1.McGill University, Montreal Canada 2.University of Miami, Miami Florida Fig. 1 Monthly-averaged hydrometeor (cloud+precipitation) fraction using MMCR-only observations at the Nauru (C2) ARM Tropical Western Pacific site Progress has been made in our ability to observe the vertical velocity in clouds using the ARM MMCR's (Kollias et al., 2007; Kollias and Albrecht, 2000; Kollias et al.,

  10. TWP Darwin Site

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Darwin Site-Inactive TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists TWP Darwin Site-Inactive Location: 12° 25' 28.56" S, 130° 53' 29.75" E Altitude: 29.9 meters The third TWP climate research facility was established in April 2002 in Darwin, Northern Territory, Australia. The facility is

  11. TWP Manus Site

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Manus Site-Inactive TWP Related Links Facilities and Instruments Manus Island Nauru Island Darwin, AUS ES&H Guidance Statement Operations Science Field Campaigns Year of Tropical Convection Visiting the Site TWP Fact Sheet Images Information for Guest Scientists TWP Manus Site-Inactive Location: 2° 3' 39.64" S, 147° 25' 31.43" E Altitude: 4 meters In August 1996, the first climate research facility in the Tropical Western Pacific locale was established. The Manus facility was

  12. A Model Evaluation Data Set for the Tropical ARM Sites

    DOE Data Explorer

    Jakob, Christian

    2008-01-15

    This data set has been derived from various ARM and external data sources with the main aim of providing modelers easy access to quality controlled data for model evaluation. The data set contains highly aggregated (in time) data from a number of sources at the tropical ARM sites at Manus and Nauru. It spans the years of 1999 and 2000. The data set contains information on downward surface radiation; surface meteorology, including precipitation; atmospheric water vapor and cloud liquid water content; hydrometeor cover as a function of height; and cloud cover, cloud optical thickness and cloud top pressure information provided by the International Satellite Cloud Climatology Project (ISCCP).

  13. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Evaluation of Broadband Surface Flux Closure Under Cloudy Skies at Nauru McFarlane, S.A. and Evans, K.F., University of Colorado Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting Time series of vertical profiles of cloud properties retrieved from cloud radar data at a single point are often used to characterize the statistics of clouds at a particular location. These datasets may then be used by cloud modelers to assess the ability of their model to predict cloud properties or

  14. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Fair - Weather Cumuli Climatology at the TWP ARM Site Kollias, P. and Albrecht B.A., University of Miami Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting Fair-weather cumuli are fundamental in regulating the vertical structure of water vapor and entropy in the lowest 2 km of the Earths atmosphere over vast areas of the oceans. Over two years of data from the mm-wavelength cloud radar, at the Nauru (TWP-ARM) site, are analyzed and a statistical description of the field of fair

  15. ARM - Publications: Science Team Meeting Documents

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    A Dataset of the Evaluation of Large-Scale Models Using ARM Data at Manus and Nauru Jakob, C. and May, P.T., BMRC Thirteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting The use of ARM data for model evaluation is a first necessary step in achieving one of the programs foremost goals, the improvement of parameterizations of clouds and radiation in GCMs. However, most of the data in the ARM archive is representative for time and space scales that are incompatible with the large

  16. A Model Evaluation Data Set for the Tropical ARM Sites

    DOE Data Explorer

    Jakob, Christian

    This data set has been derived from various ARM and external data sources with the main aim of providing modelers easy access to quality controlled data for model evaluation. The data set contains highly aggregated (in time) data from a number of sources at the tropical ARM sites at Manus and Nauru. It spans the years of 1999 and 2000. The data set contains information on downward surface radiation; surface meteorology, including precipitation; atmospheric water vapor and cloud liquid water content; hydrometeor cover as a function of height; and cloud cover, cloud optical thickness and cloud top pressure information provided by the International Satellite Cloud Climatology Project (ISCCP).

  17. Multiple Irradiation Capsule Experiment (MICE)-3B Irradiation Test of Space Fuel Specimens in the Advanced Test Reactor (ATR) - Close Out Documentation for Naval Reactors (NR) Information

    SciTech Connect

    M. Chen; CM Regan; D. Noe

    2006-01-09

    Few data exist for UO{sub 2} or UN within the notional design space for the Prometheus-1 reactor (low fission rate, high temperature, long duration). As such, basic testing is required to validate predictions (and in some cases determine) performance aspects of these fuels. Therefore, the MICE-3B test of UO{sub 2} pellets was designed to provide data on gas release, unrestrained swelling, and restrained swelling at the upper range of fission rates expected for a space reactor. These data would be compared with model predictions and used to determine adequacy of a space reactor design basis relative to fission gas release and swelling of UO{sub 2} fuel and to assess potential pellet-clad interactions. A primary goal of an irradiation test for UN fuel was to assess performance issues currently associated with this fuel type such as gas release, swelling and transient performance. Information learned from this effort may have enabled use of UN fuel for future applications.

  18. EXPLANATION OF SIGNIFICANT DIFFERENCES

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    EXPLANATION OF SIGNIFICANT DIFFERENCE FOR THE 100-NR-1 OPERABLE UNIT TREATMENT, STORAGE, AND DISPOSAL INTERIM ACTION RECORD OF DECISION AND 100-NR-1/100-NR-2 OPERABLE UNIT INTERIM ACTION RECORD OF DECISION January 2003 SITE NAME AND LOCATION U.S. Department of Energy 100 Areas 100-NR-1 and 100-NR-2 Operable Units, Hanford Site Benton County, Washington INTRODUCTION TO THE SITE AND STATEMENT OF PURPOSE The Washington State Department of Ecology (Ecology), U.S. Environmental Protection Agency

  19. Collaborative Research: ARM observations for the development and evaluation of models and parameterizations of cloudy boundary layers

    SciTech Connect

    Albrecht, Bruce,

    2013-07-12

    This is a collaborative project with Dr. Ping Zhu at Florida International University. It was designed to address key issues regarding the treatment of boundary layer cloud processes in climate models with UM’s research focusing on the analyses of ARM cloud radar observations from MMCR and WACR and FIU’s research focusing on numerical simulations of boundary layer clouds. This project capitalized on recent advancements in the ARM Millimeter Cloud Radar (MMCR) processing and the development of the WACR (at the SGP) to provide high temporal and spatial resolution Doppler cloud radar measurements for characterizing in-cloud turbulence, large-eddy circulations, and high resolution cloud structures of direct relevance to high resolution numerical modeling studies. The principal focus of the observational component of this collaborative study during this funding period was on stratocumulus clouds over the SGP site and fair-weather cumuli over the Nauru site. The statistical descriptions of the vertical velocity structures in continental stratocumulus clouds and in the Nauru shallow cumuli that are part of this study represents the most comprehensive observations of the vertical velocities in boundary layer clouds to date and were done in collaboration with Drs. Virendra Ghate and Pavlos Kollias.

  20. DOE national user facility in the Tropical Western Pacific.

    SciTech Connect

    Jones, L. A.; Porch, W. M.; Sisterson, Doug L.; Mather, J. H.; Long, C. N.

    2004-01-01

    In July 2003, the Department of Energy's Office of Biological and Environmental Research designated the Atmospheric Radiation Measurement sites as National User Facilities and renamed them the ARM Climate Research Facility (ACRF). As a result, the former ARM Cloud and Radiation Test bed (CART) sites are now collectively called Climate Research Sites. Part of the conditions associated with funding for ACRF is that the ARM program must attract new users. Located in Australia, and the island nations of Papua New Guinea and the Republic of Nauru, the three Tropical Western Pacific (TWP) research facilities offer unique scientific opportunities to prospective users. Although the locations of the facilities pose significant logistical challenges, particularly the two island sites, the TWP Office addresses these issues so that prospective users can focus on their research. The TWP Office oversees the operation of these sites by collaborating with the governments of Australia, Papua New Guinea, and the Republic of Nauru. Local observers are trained to effectively operate and maintain the facilities, and the state-side TWP Office offers supporting resources including daily instrument monitoring; equipment shipping, inventory tracking; customs coordination; and a readily deployable technical maintenance team at relatively minimal cost to prospective users. Satellite communications allow continuous, near-real time data from all three stations. The TWP Office also works diligently to maintain good local government and community relations with active outreach programs. This paper presents the TWP research facilities as the valuable resources they are to the scientific community.

  1. ARM Research in the Equatorial Western Pacific: A Decade and Counting

    SciTech Connect

    Long, Charles N.; McFarlane, Sally A.; Del Genio, Anthony D.; Minnis, Patrick; Ackerman, Thomas P.; Mather, James H.; Comstock, Jennifer M.; Mace, Gerald G.; Jensen, Michael; Jakob, Christian

    2013-05-22

    The tropical western Pacific (TWP) is an important climatic region. Strong solar heating, warm sea surface temperatures and the annual progression of the Intertropical Convergence Zone (ITCZ) across this region generate abundant convective systems, which through their effects on the heat and water budgets have a profound impact on global climate and precipitation. To accurately represent tropical cloud systems in models, measurements of tropical clouds, the environment in which they reside, and their impact on the radiation and water budgets are needed. Because of the remote location, ground-based datasets of cloud, atmosphere, and radiation properties from the TWP region have traditionally come primarily from short-term field experiments. While providing extremely useful information on physical processes, these datasets are limited in statistical and climatological information because of their short duration. To provide long-term measurements of the surface radiation budget in the tropics, and the atmospheric properties that affect it, the Atmospheric Radiation Measurement program established a measurement site on Manus Island, Papua New Guinea in 1996 and on the island republic of Nauru in late 1998. These sites provide unique datasets available from more than 10 years of operation in the equatorial western Pacific on Manus and Nauru. We present examples of the scientific use of these datasets including characterization of cloud properties, analysis of cloud radiative forcing, model studies of tropical clouds and processes, and validation of satellite algorithms. We also note new instrumentation recently installed at the Manus site that will expand opportunities for tropical atmospheric science.

  2. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    By combining surface imaging with nanoscale depth-sensitive neutron reflectometry (NR) and ... Inverted Organic Solar Cells with Nanoscale Structures Das, Sanjib ; Keum, Jong Kahk ...

  3. Peculiarity of two thermodynamically-stable morphologies and...

    Office of Scientific and Technical Information (OSTI)

    By combining surface imaging with nanoscale depth-sensitive neutron reflectometry (NR) and ... Language: English Subject: 14 SOLAR ENERGY nanoscale materials; solar cells Word Cloud ...

  4. Cimon, Engstrom, Mattson, Pollet, Vanni, Suyama Page 1 of 3

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2014 RAP Committee: Draft Advice re: 100-N Draft A, v.2 Cimon, Engstrom, Mattson, Pollet, Vanni, Suyama Page 1 of 3 Draft Advice re: Proposed Plan for Remediation of the 100-NR-1 and 100-NR-2 Operable Units (DOE/RL-2012-68, Draft A) Background The 100-N area is the last of the 100 Area, River Corridor, RI/FS and Proposed Plans for submittal. The 100-N area consists of two Decision Units, NR-1, which is the source unit, and NR-2, the groundwater unit. There are 234 facilities, of which 76% have

  5. LANL: AOT & LANSCE The Pulse December 2012

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Department of Physics and Astronomy, used a combination of surface enhanced Raman spectroscopy (SERS) and neutron refectometry (NR) to nondestructively characterize with ...

  6. December 2010 | National Nuclear Security Administration | (NNSA)

    National Nuclear Security Administration (NNSA)

    December 2010 December 09, 2010 Small Business Contracts Surge from the Department of Energy's Work in Oak Ridge Microsoft Office document icon NR-12

  7. LANL: AOT & LANSCE The Pulse December 2009

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Hillary Smith, Michael Jablin, and Jaroslaw Majewski (LANSCE- LC); and Joseph Hickey, Antoinette Trujillo, and James Freyer (B-9) used NR to examine living mouse fbroblast cells ...

  8. Careers & the disABLED Career Expo

    Office of Energy Efficiency and Renewable Energy (EERE)

    Location: Ronald Reagan Bldg, Washington, DCAttendees:  Terri Sosa (Science)POC:  Donna FriendWebsite: http://bit.ly/1tlHhNr

  9. Y-12 Successfully Meets and Exceeds Defense Programs Goals During...

    National Nuclear Security Administration (NNSA)

    Successfully Meets and Exceeds Defense Programs Goals During FY 2010 November 10, 2010 Microsoft Office document icon NR-11-10

  10. Dabbrook Services | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Services Jump to: navigation, search Name: Dabbrook Services Place: Great Yarmouth, United Kingdom Zip: NR31 6PT Sector: Services Product: Provides design and engineering...

  11. Econic Renewable Energy Solutions | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Econic Renewable Energy Solutions Jump to: navigation, search Name: Econic Renewable Energy Solutions Place: Norfolk, United Kingdom Zip: NR 105PQ Sector: Renewable Energy Product:...

  12. Chemical and isotopic characteristics of fluids within the Baca...

    OpenEI (Open Energy Information) [EERE & EIA]

    by conductive reheating during downward movement. Chemical modeling using the EQ3NR computer code indicates chemical stability with the mineral assemblage quartz, albite, K-mica,...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    mariapoienar@yahoo.com ; National Institute for Research and Development in Electrochemistry and Condensed Matter, Plautius Andronescu Str Nr 1, 300224 Timisoara ; Hardy,...

  14. Carbon Connections | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Connections Jump to: navigation, search Name: Carbon Connections Place: Norfolk, England, United Kingdom Zip: NR4 7TJ Sector: Carbon Product: Carbon Connections links partner...

  15. Eirich Named Y-12 Site Office Senior Project Director | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Eirich Named Y-12 Site Office Senior Project Director August 15, 2006 PDF icon NR-05-06

  16. Management Changes at the Y-12 Site Office Announced | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Management Changes at the Y-12 Site Office Announced January 02, 2008 Microsoft Office document icon NR-1-08

  17. NNSA Defense Programs Announces Quarterly Awards | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Defense Programs Announces Quarterly Awards February 16, 2011 Microsoft Office document icon NR-02-1

  18. NNSA, Small Business Help Shape Y-12 | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) NNSA, Small Business Help Shape Y-12 January 30, 2006 PDF icon NR-02-06.pdf

  19. Terri Slack Named Site Counsel for NNSA's Y-12 Site Office | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration | (NNSA) Terri Slack Named Site Counsel for NNSA's Y-12 Site Office January 12, 2006 PDF icon NR-01-06.pdf

  20. Y-12 Breaks Ground for Potable Water System Upgrades Project | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration | (NNSA) Breaks Ground for Potable Water System Upgrades Project March 15, 2008 Microsoft Office document icon NR-2-08

  1. Y-12 Completes Major Upgrade of Compressed Air Systems | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Major Upgrade of Compressed Air Systems September 26, 2007 Microsoft Office document icon NR-09-07

  2. Y-12 Final Site-Wide Environmental Impact Statement Approved | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration | (NNSA) Final Site-Wide Environmental Impact Statement Approved March 02, 2011 Microsoft Office document icon NR-03-2

  3. Y-12 Site Office Recognized for Contributions to Combined Federal Campaign

    National Nuclear Security Administration (NNSA)

    | National Nuclear Security Administration | (NNSA) Site Office Recognized for Contributions to Combined Federal Campaign February 14, 2006 PDF icon NR-03-06

  4. Y-12 Successfully Meets and Exceeds Defense Programs Goals During FY 2010 |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) Successfully Meets and Exceeds Defense Programs Goals During FY 2010 November 10, 2010 Microsoft Office document icon NR-11-10

  5. Microsoft PowerPoint - 3 - Marcinowski Waste Presentation.pptx

    Office of Environmental Management (EM)

    - Soot cleaning of electrical panels * Expedite mine stability * Initial ... Handled RH - Remote Handled SNF - Spent Nuclear Fuel SNF IDAHO SITE NR SNF DOECommercial ...

  6. Microsoft PowerPoint - SSAB Chairs Spring 2015 Marcinowski final...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    - Soot cleaning of electrical panels * Expedite mine stability * Initial ... Handled RH - Remote Handled SNF - Spent Nuclear Fuel SNF IDAHO SITE NR SNF DOECommercial ...

  7. Bettis and Knolls Atomic Power Laboratories | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) Bettis and Knolls Atomic Power Laboratories Bettis and Knolls Atomic Power Laboratories DE-NR0000031 Managed and Operated by Bechtel Marine Propulsion Corporation Updated to Modification 075 dated 10/10/2012 BASIC Contract (Official) Modifications (Official) Funding Mods Available Upon Request Conformed Contract (Unofficial) Basic Contract (9/18/2008) (pdf, 2307KB) NR 001 (12/8/08) (pdf, 7938KB) DE-NR0000031 (Conformed to Mod 075 dated 10/10/2011) (pdf, 12MB) NR 002

  8. Atmospheric Radiation Measurement Program facilities newsletter, May 2000.

    SciTech Connect

    Sisterson, D.L.

    2000-06-01

    This month the authors will visit an ARM CART site with a pleasant climate: the Tropical Western Pacific (TWP) CART site, along the equator in the western Pacific Ocean. The TWP locale lies between 10 degrees North latitude and 10 degrees South latitude and extends from Indonesia east-ward beyond the international date line. This area was selected because it is in and around the Pacific warm pool, the area of warm sea-surface temperatures that determine El Nino/La Nina episodes. The warm pool also adds heat and moisture to the atmosphere and thus fuels cloud formation. Understanding the way tropical clouds and water vapor affect the solar radiation budget is a focus of the ARM Program. The two current island-based CART sites in the TWP are in Manus Province in Papua New Guinea and on Nauru Island.

  9. Microsoft Word - S09799_EnhancedMR.docx

    Office of Legacy Management (LM)

    ... N001 06112012 0.00011 - .160 0 WL Manganese mgL 0840 N001 06112012 0.00011 - ... NR N mV 0405 N001 06132012 - - .3 166 WL Oxidation Reduction Potential NR N mV 0405 ...

  10. February 2011 | National Nuclear Security Administration | (NNSA)

    National Nuclear Security Administration (NNSA)

    February 2011 February 16, 2011 NNSA Defense Programs Announces Quarterly Awards Microsoft Office document icon NR-02-16.doc February 04, 2011 NNSA Y-12 National Security Complex Transfers $8M of Equipment to DoD for Reapplication Microsoft Office document icon NR-02-11

  11. Prometheus Reactor I&C Software Development Methodology, for Action

    SciTech Connect

    T. Hamilton

    2005-07-30

    The purpose of this letter is to submit the Reactor Instrumentation and Control (I&C) software life cycle, development methodology, and programming language selections and rationale for project Prometheus to NR for approval. This letter also provides the draft Reactor I&C Software Development Process Manual and Reactor Module Software Development Plan to NR for information.

  12. Plasmon-enhanced polymer photovoltaic cells based on large aspect ratio gold nanorods and the related working mechanism

    SciTech Connect

    Chen, S. F.; Cheng, F.; Mei, Y.; Kong, M.; Hao, J. Y.; Zhang, R.; Wang, L. H.; Peng, B.; Xiong, Q. H. E-mail: iamdirector@njupt.edu.cn; Huang, W. E-mail: iamdirector@njupt.edu.cn

    2014-05-26

    Two types of Au nanorods (NRs) possessing longitudinal/transverse axes of 55/11 (NR{sub 11}) and 90/18 nm (NR{sub 18}) are, respectively, incorporated into the hole extraction layer to improve optical-to-electrical conversion performances in polymer photovoltaic cells. Totally different improvement factors in short-circuit current and power conversion efficiency occur in the NR{sub 11}- and NR{sub 18}-doped cells. Optical simulations, electrical analysis, and morphology alteration accompanying with the incorporation of NRs were proceeded to investigate the reason, and analysis demonstrates that a slower damping of field around NRs{sub 18} (results in a field and absorption enhancement around the active layer) and one order higher scattering cross section in the NR{sub 18}-incorporated cell are key factors contributed to the improvement of cell performances.

  13. Nitrogen-doped and simultaneously reduced graphene oxide with superior dispersion as electrocatalysts for oxygen reduction reaction

    SciTech Connect

    Lee, Cheol-Ho; Yun, Jin-Mun; Lee, Sungho; Jo, Seong Mu; Yoo, Sung Jong; Cho, Eun Ae; Khil, Myung-Seob; Joh, Han-Ik

    2014-11-15

    Nitrogen doped graphene oxide (Nr-GO) with properties suitable for electrocatalysts is easily synthesized using phenylhydrazine as a reductant at relatively low temperature. The reducing agent removes various oxygen functional groups bonded to graphene oxide and simultaneously dope the nitrogen atoms bonded with phenyl group all over the basal planes and edge sites of the graphene. The Nr-GO exhibits remarkable electrocatalytic activities for oxygen reduction reaction compared to the commercial carbon black and graphene oxide due to the electronic modification of the graphene structure. In addition, Nr-GO shows excellent dispersibility in various solvent due to the dopant molecules.

  14. Microsoft Word - 2012 Research Day Winners.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    C-NR Marcus Weigand, MPA-CMMS Blake Sturtevant, MPA-11 Satish Karra, EES-16 Graham King, LANSCE-LC Eric Daub, EES-17T-CNLS Louise Evans, NEN-1 Benjamin Ueland, MPA-CMMS Yan...

  15. Faces of Science

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Division Office (505) 667-4457 Email C-AAC Becky Chamberlin C-NR Susan Hanson - Video C-IIAC Eva Birnbaum, (SPO-SC) Program Manager for Isotope Production - Video John Gordon - ...

  16. Scira Offshore Energy | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Kingdom Zip: NR32 1DE Sector: Wind energy Product: Developer of the Sheringham Shoals offshore wind farm. References: Scira Offshore Energy1 This article is a stub. You can...

  17. February 2012 | National Nuclear Security Administration | (NNSA)

    National Nuclear Security Administration (NNSA)

    February 2012 February 17, 2012 NNSA Names Terri Slack as Attorney of the Year File Slack release - 2.10.12.docx February 15, 2012 Nuclear disarmament with a personal touch File NR-01-12 Sofia

  18. Nuclear disarmament with a personal touch | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) Nuclear disarmament with a personal touch February 15, 2012 Team Led by Y-12 Site Office Employee Visits Russian girl Aided by U.S. Monitors File NR-01-12 Sofia

  19. Wind Power Renewables | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Wind Power Renewables Place: Norfolk, United Kingdom Zip: NR29 5BG Sector: Wind energy Product: Wind project developer Coordinates: 36.846825, -76.285069 Show Map Loading...

  20. Infrastructure Security

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    waste to return of research reactor fuel of U.S. origin. In addition, Snl supports the nrC in the development of technical bases to support various rule-making activities...

  1. Microsoft Word - Participants_Web.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Research Day 2015 i Postdoc Participants Adamska, Lyudmyla T-1 Poster 003 Ahmed, Towfiq T-4 Poster 004 Barker, Beau C-NR Poster 005 Beedle, Christopher MPA-CMMS Poster 006 Bennett, ...

  2. Long-Term Measurements of Submicrometer Aerosol

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    non-refractory submicron particulate matter (NR-PM1) including organic aerosol (OA), sulfate (SO 4 2- ), nitrate (NO 3 - ), ammonium (NH 4 + ), and chloride (Cl-). In this study,...

  3. CX-005033: Categorical Exclusion Determination

    Energy.gov [DOE]

    Oil Cleanup in 100-NR-2CX(s) Applied: B6.1Date: 01/19/2011Location(s): Hanford, WashingtonOffice(s): Environmental Management, Office of River Protection-Richland Office

  4. Pellet Zone Ltd | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Pellet Zone Ltd Jump to: navigation, search Name: Pellet Zone Ltd Place: England, United Kingdom Zip: NR19 1AE Sector: Biomass Product: UK based biomass pellet trading firm....

  5. National Nuclear Security Administration/Nevada Field Office

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... programs. NSTec also works on projects for other federal agencies, as it fulfills its national security missions. RSL Aviation Chief of Maintenance Dave Krausnick NR-16-0010 XXX

  6. -

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    - our vision is that one day they may become our employees." Scholarship recipients are given an opportunity to intern at NSTec after their first year of college. NR-15-0013 XXX

  7. Major Milestone Achieved in Nuclear Weapons Stockpile Stewardship Program

    National Nuclear Security Administration (NNSA)

    at Y-12 | National Nuclear Security Administration | (NNSA) Major Milestone Achieved in Nuclear Weapons Stockpile Stewardship Program at Y-12 April 18, 2006 PDF icon NR-04-06.pdf

  8. NNSA Y-12 National Security Complex Transfers $8M of Equipment to DoD for

    National Nuclear Security Administration (NNSA)

    Reapplication | National Nuclear Security Administration | (NNSA) NNSA Y-12 National Security Complex Transfers $8M of Equipment to DoD for Reapplication February 04, 2011 Microsoft Office document icon NR-02-11

  9. Recovery Act Helps Y-12 Exceed Cleanup Goal at Manhattan Project-Era

    National Nuclear Security Administration (NNSA)

    Building | National Nuclear Security Administration | (NNSA) Helps Y-12 Exceed Cleanup Goal at Manhattan Project-Era Building March 17, 2011 Microsoft Office document icon NR-03-17

  10. Small Business Contracts Surge from the Department of Energy's Work in Oak

    National Nuclear Security Administration (NNSA)

    Ridge | National Nuclear Security Administration | (NNSA) Business Contracts Surge from the Department of Energy's Work in Oak Ridge December 09, 2010 Microsoft Office document icon NR-12-09

  11. Research Highlight

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Atmospheric Environment, 106, DOI:10.1016j.atmosenv.2015.01.060. ONLINE. The monthly variations in average NR-PM1 mass concentration, composition and wind data for one year ...

  12. November 2010 | National Nuclear Security Administration | (NNSA...

    National Nuclear Security Administration (NNSA)

    Y-12 Successfully Meets and Exceeds Defense Programs Goals During FY 2010 Microsoft Office document icon NR-11-10.doc November 09, 2010 New Y-12 Mill Supports Non-Proliferation ...

  13. Relativistic effects for the reaction Sg + 6 CO → Sg(CO){sub 6}: Prediction of the mean bond energy, atomization energy, and existence of the first organometallic transactinide superheavy hexacarbonyl Sg(CO){sub 6}

    SciTech Connect

    Malli, Gulzari L.

    2015-02-14

    Our ab initio all-electron fully relativistic Dirac–Fock (DF) and nonrelativistic (NR) Hartree-Fock calculations predict the DF relativistic and NR energies for the reaction: Sg + 6 CO → Sg(CO){sub 6} as −7.39 and −6.96 eV, respectively, i.e., our calculated ground state total DF relativistic and NR energies for the reaction product Sg(CO){sub 6} are lower by 7.39 and 6.96 eV than the total DF and NR ground state energies of the reactants, viz., one Sg atom plus six CO molecules, respectively. Our calculated DF relativistic and NR atomization energies (Ae) are 65.23 and 64.82 eV, respectively, and so the contribution of relativistic effects to the Ae of ∼0.40 eV is marginal. The Sg–C and C–O optimized bond distances for the octahedral geometry as calculated in our DF (NR) calculations are 2.151 (2.318 Å) and 1.119 (1.114 Å), respectively. The BSSE correction calculated using the DIRAC code ∼14 kcal/mol. The relativistic DF and NR mean energies predicted by us are 118.8 and 111.9 kJ/mol, respectively, and the contribution of ∼7 kJ/mol due to relativistic effects to the mean energy of Sg(CO){sub 6} is negligible. Ours are the first calculations of the relativistic effects for the atomization energy, mean bond energy, and energy of the reaction for possible formation of Sg(CO){sub 6}, and both our relativistic DF and the NR treatments clearly predict for the first time the existence of hexacarbonyl of the transactinide superheavy element seaborgium Sg. In conclusion, relativistic effects are not significant for Sg(CO){sub 6}.

  14. Sample variance in weak lensing: How many simulations are required?

    DOE PAGES [OSTI]

    Petri, Andrea; May, Morgan; Haiman, Zoltan

    2016-03-24

    Constraining cosmology using weak gravitational lensing consists of comparing a measured feature vector of dimension Nb with its simulated counterpart. An accurate estimate of the Nb × Nb feature covariance matrix C is essential to obtain accurate parameter confidence intervals. When C is measured from a set of simulations, an important question is how large this set should be. To answer this question, we construct different ensembles of Nr realizations of the shear field, using a common randomization procedure that recycles the outputs from a smaller number Ns ≤ Nr of independent ray-tracing N-body simulations. We study parameter confidence intervalsmore » as a function of (Ns, Nr) in the range 1 ≤ Ns ≤ 200 and 1 ≤ Nr ≲ 105. Previous work [S. Dodelson and M. D. Schneider, Phys. Rev. D 88, 063537 (2013)] has shown that Gaussian noise in the feature vectors (from which the covariance is estimated) lead, at quadratic order, to an O(1/Nr) degradation of the parameter confidence intervals. Using a variety of lensing features measured in our simulations, including shear-shear power spectra and peak counts, we show that cubic and quartic covariance fluctuations lead to additional O(1/N2r) error degradation that is not negligible when Nr is only a factor of few larger than Nb. We study the large Nr limit, and find that a single, 240 Mpc/h sized 5123-particle N-body simulation (Ns = 1) can be repeatedly recycled to produce as many as Nr = few × 104 shear maps whose power spectra and high-significance peak counts can be treated as statistically independent. Lastly, a small number of simulations (Ns = 1 or 2) is sufficient to forecast parameter confidence intervals at percent accuracy.« less

  15. Nuclear and Radiochemistry

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    NR Nuclear and Radiochemistry We provide vital radiochemical and radioanalytical capabilities to a wide range of programs. Contact Us Group Leader Felicia Taw Deputy Group Leader Rich Oldenborg Group Office (505) 667-4546 The Nuclear and Radiochemistry (C-NR) Group provides vital radiochemical and radioanalytical capabilities to a wide range of programs. These programs include maintenance and stewardship of the nuclear stockpile, nuclear non-proliferation, environmental management, international

  16. DATE

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    0 SECTION A. Project Title: Test Reactor Cask Implementation. SECTION B. Project Description: This proposed action is a process and facility modification. Background / Purpose & Need The Advanced Test Reactor (ATR) uses the Naval Reactors (NR) Casks to transport test trains between the Naval Reactors Facility (NRF) Expended Core Facility and the ATR. The Naval Reactor (NR) Casks, however, are approaching the end of their design life. In 1997, Bettis initiated a contract for construction of

  17. Transcription factor COUP-TFII is indispensable for venous and lymphatic development in zebrafish and Xenopus laevis

    SciTech Connect

    Aranguren, Xabier L.; Beerens, Manu; Vandevelde, Wouter; Dewerchin, Mieke; Carmeliet, Peter; Luttun, Aernout

    2011-06-24

    Highlights: {yields} COUP-TFII deficiency in zebrafish affects arterio-venous EC specification. {yields} COUP-TFII is indispensable for lymphatic development in zebrafish. {yields} COUP-TFII knockdown in Xenopus disrupts lymphatic EC differentiation and migration. {yields} COUP-TFII's role in EC fate decisions is evolutionary conserved. -- Abstract: Transcription factors play a central role in cell fate determination. Gene targeting in mice revealed that Chicken Ovalbumin Upstream Promoter-Transcription Factor II (COUP-TFII, also known as Nuclear Receptor 2F2 or NR2F2) induces a venous phenotype in endothelial cells (ECs). More recently, NR2F2 was shown to be required for initiating the expression of Prox1, responsible for lymphatic commitment of venous ECs. Small animal models like zebrafish embryos and Xenopus laevis tadpoles have been very useful to elucidate mechanisms of (lymph) vascular development. Therefore, the role of NR2F2 in (lymph) vascular development was studied by eliminating its expression in these models. Like in mice, absence of NR2F2 in zebrafish resulted in distinct vascular defects including loss of venous marker expression, major trunk vessel fusion and vascular leakage. Both in zebrafish and Xenopus the development of the main lymphatic structures was severely hampered. NR2F2 knockdown significantly decreased prox1 expression in zebrafish ECs and the same manipulation affected lymphatic (L)EC commitment, migration and function in Xenopus tadpoles. Therefore, the role of NR2F2 in EC fate determination is evolutionary conserved.

  18. Quantifying Diurnal Cloud Radiative Effects by Cloud Type in the Tropical Western Pacific

    SciTech Connect

    Burleyson, Casey D.; Long, Charles N.; Comstock, Jennifer M.

    2015-06-01

    Cloud radiative effects are examined using long-term datasets collected at the three Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facilities in the tropical western Pacific. We quantify the surface radiation budget, cloud populations, and cloud radiative effects by partitioning the data by cloud type, time of day, and as a function of large scale modes of variability such as El Niño Southern Oscillation (ENSO) phase and wet/dry seasons at Darwin. The novel facet of our analysis is that we break aggregate cloud radiative effects down by cloud type across the diurnal cycle. The Nauru cloud populations and subsequently the surface radiation budget are strongly impacted by ENSO variability whereas the cloud populations over Manus only shift slightly in response to changes in ENSO phase. The Darwin site exhibits large seasonal monsoon related variations. We show that while deeper convective clouds have a strong conditional influence on the radiation reaching the surface, their limited frequency reduces their aggregate radiative impact. The largest source of shortwave cloud radiative effects at all three sites comes from low clouds. We use the observations to demonstrate that potential model biases in the amplitude of the diurnal cycle and mean cloud frequency would lead to larger errors in the surface energy budget compared to biases in the timing of the diurnal cycle of cloud frequency. Our results provide solid benchmarks to evaluate model simulations of cloud radiative effects in the tropics.

  19. Radiative Heating Profiles in the Convective Tropics: A Comparison of Observations and Models

    SciTech Connect

    McFarlane, Sally A.; Mather, Jim H.; Ackerman, Thomas P.

    2005-01-10

    Radiative heating is one of the principal drivers of tropical circulation. While we have good knowledge of radiative fluxes at the top-of-atmosphere and at specific surface sites, observations of atmospheric profiles of radiative heating, particular in cloudy conditions, have been largely unavailable. The Atmospheric Radiation Measurement (ARM) Program has begun a program to compute radiative heating profiles routinely at its observational sites at Nauru and Manus Island, Papua New Guinea, using observed and retrieved inputs of water vapor and condensed water phase, particle size, and mass. The accuracy of these profiles can be assessed by comparing the calculated TOA and surface fluxes with observations. We have computed radiative heating profiles every 20 minutes for several months at each of these two sites in the 1999-2000 time period, which represent a unique dataset for model comparison. Here, we compare this dataset to model output from the European Center for Medium-Range Weather Forecasting (ECMWF) analysis, the NCAR Community Atmosphere Model (CAM 3.0) and the Multi-Scale Modeling Framework (MMF). These three models, all run using observed SST for this comparison, provide an interesting range of resolution from the 4 km cloud resolving model in the MMF to the approximately 280 km grid-scale of the CAM and a contrast between forecasting and climate models. In general, the model results fail to capture the structure of the observed heating in the upper troposphere because of their failure to simulate cirrus and stratiform cloud adequately.

  20. Mineral industries of Australia, Canada, and Oceania (including a discussion of Antarctica's mineral resources). Mineral perspective

    SciTech Connect

    Kimbell, C.L.; Lyday, T.Q.; Newman, H.H.

    1985-12-01

    The Bureau of Mines report gives the mineral industry highlights of two of the world's major mineral producing countries, Australia and Canada, and seven Pacific island nations or territories--Fiji, New Caledonia, New Zealand, Papua New Guinea, Republic of Nauru, Solomon Islands, and Vanuatu. The mineral resources of Antarctica are also discussed. Because of the size of the Australian and Canadian mineral industries, summary reviews are presented for each of the States, Provinces, or Territories. The most current information available from all nations is given on major minerals or mineral-commodity production, share of world production, and reserves. Reported also are significant mining companies, locations and capacities of their main facilities, and their share of domestic production. Other information is provided on mineral-related trade with the United States, government mineral policy, energy production-consumption and trade, the mining industry labor force, and prospects for the mineral industry. Maps show the locations of selected mineral deposits, oilfields and gasfields, mines, and processing facilities including iron and steel plants, nonferrous smelters and refineries, and cement plants, as well as infrastructure pertinent to the mineral industry.

  1. Boundary Layer Cloudiness Parameterizations Using ARM Observations

    SciTech Connect

    Bruce Albrecht

    2004-09-15

    This study used DOE ARM data and facilities to: (1) study macroscopic properties of continental stratus clouds at SGP and the factors controlling these properties, (2) develop a scientific basis for understanding the processes responsible for the formation of boundary layer clouds using ARM observations in conjunction with simple parametric models and LES, and (3) evaluate cumulus cloud characteristics retrieved from the MMCR operating at TWP-Nauru. In addition we have used high resolution 94 GHz observations of boundary layer clouds and precipitation to: (1) develop techniques for using high temporal resolution Doppler velocities to study large-eddy circulations and turbulence in boundary layer clouds and estimate the limitations of using current and past MMCR data for boundary layer cloud studies, (2) evaluate the capability and limitations of the current MMCR data for estimating reflectivity, vertical velocities, and spectral under low- signal-to-noise conditions associated with weak no n-precipitating clouds, (3) develop possible sampling modes for the new MMCR processors to allow for adequate sampling of boundary layer clouds, and (4) retrieve updraft and downdraft structures under precipitating conditions.

  2. Final Technical Report ARM DOE Grant #DE-FG02-03ER63520 Parameterizations of Shortwave Radiactive Properties of Broken Clouds from Satellite and Ground-Based Measurements

    SciTech Connect

    Albrecht, Bruce, A.

    2006-06-19

    This study used DOE ARM data and facilities to: 1) study macroscopic properties of continental stratus clouds at SGP and the factors controlling these properties, 2) develop a scientific basis for understanding the pocesses responsible for the formation of boundary layer clouds using ARM observations in conjunction with simple parametric models and LES, and 3) evaluate cumulus cloud characteristics retrieved retrieved from the MMCR operating at TWP-Nauru. In addition we have used high resolution 94 GHz observations of boundary layer clouds and precipitation to: 1)develop techniques for using high temporal resolution Doppler velocities to study large-eddy circulations and turbulence in boundary layer clouds and estimate the limitations of using current and past MMCR data for boundary layer cloud studies, 2) evaluate the capability and limitation of the current MMCR data for estimating reflectivity, vertical velocities, and spectral under low-signal-to-noise conditions associated with weak non-precipitating clouds, 3) develop possible sampling modes for the new MMCR processors to allow for adequate sampling of boundary layer clouds, and 4) retrieve updraft and downdraft structures under precipitating conditions.

  3. Scattering attributes of one-dimensional semiconducting oxide nanomaterials individually probed for varying light-matter interaction angles

    SciTech Connect

    Choi, Daniel S.; Singh, Manpreet; Zhou, Hebing; Milchak, Marissa; Hahm, Jong-in

    2015-10-12

    We report the characteristic optical responses of one-dimensional semiconducting oxide nanomaterials by examining the individual nanorods (NRs) of ZnO, SnO{sub 2}, indium tin oxide, and zinc tin oxide under precisely controlled, light-matter interaction geometry. Scattering signals from a large set of NRs of the different types are evaluated spatially along the NR length while varying the NR tilt angle, incident light polarization, and analyzer rotation. Subsequently, we identify material-indiscriminate, NR tilt angle- and incident polarization-dependent scattering behaviors exhibiting continuous, intermittent, and discrete responses. The insight gained from this study can advance our fundamental understanding of the optical behaviors of the technologically useful nanomaterials and, at the same time, promote the development of highly miniaturized, photonic and bio-optical devices utilizing the spatially controllable, optical responses of the individual semiconducting oxide NRs.

  4. Enhanced photoresponse of conformal TiO{sub 2}/Ag nanorod array-based Schottky photodiodes fabricated via successive glancing angle and atomic layer deposition

    SciTech Connect

    Haider, Ali; Biyikli, Necmi; Cansizoglu, Hilal; Cansizoglu, Mehmet Fatih; Karabacak, Tansel; Okyay, Ali Kemal

    2015-01-01

    In this study, the authors demonstrate a proof of concept nanostructured photodiode fabrication method via successive glancing angle deposition (GLAD) and atomic layer deposition (ALD). The fabricated metal-semiconductor nanorod (NR) arrays offer enhanced photoresponse compared to conventional planar thin-film counterparts. Silver (Ag) metallic NR arrays were deposited on Ag-film/Si templates by utilizing GLAD. Subsequently, titanium dioxide (TiO{sub 2}) was deposited conformally on Ag NRs via ALD. Scanning electron microscopy studies confirmed the successful formation of vertically aligned Ag NRs deposited via GLAD and conformal deposition of TiO{sub 2} on Ag NRs via ALD. Following the growth of TiO{sub 2} on Ag NRs, aluminum metallic top contacts were formed to complete the fabrication of NR-based Schottky photodiodes. Nanostructured devices exhibited a photo response enhancement factor of 1.49??10{sup 2} under a reverse bias of 3 V.

  5. Polymers incorporating covalently attached organoimido polyoxometalates

    DOEpatents

    Maatta, Eric A.; Moore, Aaron R.

    2004-03-16

    New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.

  6. Strongly enhanced Raman scattering of graphene by a single gold nanorod

    SciTech Connect

    He, Yingbo; Shen, Hongming; Cheng, Yuqing; Lu, Guowei Gong, Qihuang

    2015-08-03

    Individual gold nanorods (AuNRs) and monolayer graphene hybrid system is investigated experimentally. Surface enhanced Raman scattering (SERS) signal of the graphene is observed due to a single AuNR with enhancement factor up to ∼1000-fold. The SERS intensity is strongly polarization dependent and the enhancement effect varies with the detuning between the excitation laser and the AuNR resonance. The SERS effect is highest when the resonant wavelength of the AuNRs matches well with the excitation light. By correlating the scattering and photoluminescence, it is demonstrated that the conventional background in SERS ascribes to the photon emission of metallic nanostructures.

  7. PowerPoint Presentation

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    N Proposed Plan & RI/FS Report * Submitted to Ecology June 2012 * TPA Milestone M-015-75 * TPA "Primary Document" * 45 day review (30 day extension) N Reactor Operational History *Reactor constructed from 1958-1963 *Full Production started January 1964 *Operated continuously until January 1987 *Placed in Cold Standby February 1988 *Shutdown order issued September 1991 100-K 100-N 100-NR-1 / NR-2 Operable Unit * 234 facilities * 136 waste sites * 4 RCRA designated TSD facilities * *

  8. Issue framework for potential 100-N advice (lead Issue Manager: Engstrom

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Issue framework for potential 100-N advice (lead Issue Manager: Engstrom) Background information The 100-N area is the last of the 100 Area, River Corridor, RI/FS and Proposed Plans for submittal. The 100-N area consists of two Decision Units, NR-1, which is the source unit, and NR-2, the groundwater unit. There are 234 facilities, of which 76% have been demolished, and there are 175 waste sites and four RCRA TSD sites. Of these waste sites, 18 have been cleaned up and 78 have been scheduled for

  9. The improvement in functional characteristics of eco-friendly composites made of natural rubber and cellulose

    SciTech Connect

    Araki, Kunihiro; Kaneko, Shonosuke; Matsumoto, Koki; Tanaka, Tatsuya; Arao, Yoshihiko; Nagatani, Asahiro

    2015-05-22

    We investigated the efficient use of cellulose to resolve the problem of the depletion of fossil resources. In this study, as the biomass material, the green composite based on natural rubber (NR) and the flake-shaped cellulose particles (FSCP) was produced. In order to further improvement of functional characteristics, epoxidized natural rubber (ENR) was also used instead of NR. The FSCP were produced by mechanical milling in a planetary ball mill with a grinding aid as a cellulose aggregation inhibitor. Moreover, talc and mica particles were used to compare with FSCP. NR and ENR was mixed with vulcanizing agents and then each filler was added to NR compound in an internal mixer. The vulcanizing agents are as follows: stearic acid, zinc oxide, sulfur, and vulcanization accelerator. The functionalities of the composites were evaluated by a vibration-damping experiment and a gas permeability experiment. As a result, we found that FSCP filler has effects similar to (or more than) inorganic filler in vibration-damping and O{sub 2} barrier properties. And then, vibration- damping and O{sub 2} barrier properties of the composite including FSCP was increased with use of ENR. In particular, we found that ENR-50 composite containing 50 phr FSCP has three times as high vibration-damping property as ENR-50 without FSCP.

  10. Blunt Trauma Performance of Fabric Systems Utilizing Natural Rubber Coated High Strength Fabrics

    SciTech Connect

    Ahmad, M. R.; Ahmad, W. Y. W.; Samsuri, A.; Salleh, J.; Abidin, M. H.

    2010-03-11

    The blunt trauma performance of fabric systems against 9 mm bullets is reported. Three shots were fired at each fabric system with impact velocity of 367+-9 m/s and the depth of indentation on the modeling clay backing was measured. The results showed that 18-layer and 21-layer all-neat fabric systems failed the blunt trauma test. However, fabric systems with natural rubber (NR) latex coated fabric layers gave lower blunt trauma of between 25-32 mm indentation depths. Deformations on the neat fabrics upon impact were identified as broken yarns, yarn stretching and yarn pull-out. Deflections of the neat fabrics were more localised. For the NR latex coated fabric layers, no significant deformation can be observed except for peeled-off regions of the NR latex film at the back surface of the last layer. From the study, it can be said that the NR latex coated fabric layers were effective in reducing the blunt trauma of fabric systems.

  11. Analysis of biosurfaces by neutron reflectometry: From simple to complex interfaces

    SciTech Connect

    Junghans, Ann; Watkins, Erik B.; Barker, Robert D.; Singh, Saurabh; Waltman, Mary Jo; Smith, Hillary L.; Pocivavsek, Luka; Majewski, Jaroslaw

    2015-03-01

    Because of its high sensitivity for light elements and the scattering contrast manipulation via isotopic substitutions, neutron reflectometry (NR) is an excellent tool for studying the structure of soft-condensed material. These materials include model biophysical systems as well as in situ living tissue at the solid–liquid interface. The penetrability of neutrons makes NR suitable for probing thin films with thicknesses of 5–5000 Å at various buried, for example, solid–liquid, interfaces [J. Daillant and A. Gibaud, Lect. Notes Phys. 770, 133 (2009); G. Fragneto-Cusani, J. Phys.: Condens. Matter 13, 4973 (2001); J. Penfold, Curr. Opin. Colloid Interface Sci. 7, 139 (2002)]. Over the past two decades, NR has evolved to become a key tool in the characterization of biological and biomimetic thin films. Highlighted In the current report are some of the authors' recent accomplishments in utilizing NR to study highly complex systems, including in-situ experiments. Such studies will result in a much better understanding of complex biological problems, have significant medical impact by suggesting innovative treatment, and advance the development of highly functionalized biomimetic materials.

  12. Collective electronic behaviors of laterally heterostructured armchair MoS{sub 2}-NbS{sub 2} nanoribbons

    SciTech Connect

    Wu, Nannan; Zhou, Wenzhe; Zou, Hui; Chen, Yu; Yang, Zhixiong; Xiong, Xiang; Ouyang, Fangping

    2015-08-28

    Based on density functional theory, we have investigated the electronic properties of molybdenum disulfide-niobium disulfide hybrid nanoribbons (MoS{sub 2}-NbS{sub 2} NRs). It is found that the MoS{sub 2} edge, MoS{sub 2} center, NbS{sub 2} edge, and NbS{sub 2} center have distinct contributions to the collective electronic behaviors of MoS{sub 2}-NbS{sub 2} NRs. Its behavior, metallic or semiconductor, depends on whether the central area of NR contains NbS{sub 2} chain or not. This dependence has been also revealed in the electronic structures of NbS{sub 2}-MoS{sub 2}-NbS{sub 2} NR and MoS{sub 2}-NbS{sub 2}-MoS{sub 2} NR, of which the former is semiconductor and the latter is metal. In comparison with MoS{sub 2} NR of the same width, the hybrid has a different bandgap that was caused by the coupled effects between NbS{sub 2} edge and MoS{sub 2} edge. This fact makes MoS{sub 2}-NbS{sub 2} NRs a possible candidate for nanoelectronic devices based on heterostructured transition-metal dichalcogenide.

  13. Analysis of biosurfaces by neutron reflectometry: From simple to complex interfaces

    DOE PAGES [OSTI]

    Junghans, Ann; Watkins, Erik B.; Barker, Robert D.; Singh, Saurabh; Waltman, Mary Jo; Smith, Hillary L.; Pocivavsek, Luka; Majewski, Jaroslaw

    2015-03-16

    Because of its high sensitivity for light elements and the scattering contrast manipulation via isotopic substitutions, neutron reflectometry (NR) is an excellent tool for studying the structure of soft-condensed material. These materials include model biophysical systems as well as in situ living tissue at the solid–liquid interface. The penetrability of neutrons makes NR suitable for probing thin films with thicknesses of 5–5000 Å at various buried, for example, solid–liquid, interfaces [J. Daillant and A. Gibaud, Lect. Notes Phys. 770, 133 (2009); G. Fragneto-Cusani, J. Phys.: Condens. Matter 13, 4973 (2001); J. Penfold, Curr. Opin. Colloid Interface Sci. 7, 139 (2002)].more » Over the past two decades, NR has evolved to become a key tool in the characterization of biological and biomimetic thin films. Highlighted In the current report are some of the authors' recent accomplishments in utilizing NR to study highly complex systems, including in-situ experiments. Such studies will result in a much better understanding of complex biological problems, have significant medical impact by suggesting innovative treatment, and advance the development of highly functionalized biomimetic materials.« less

  14. Acid-catalyzed dehydrogenation of amine-boranes

    DOEpatents

    Stephens, Frances Helen; Baker, Ralph Thomas

    2010-01-12

    A method of dehydrogenating an amine-borane using an acid-catalyzed reaction. The method generates hydrogen and produces a solid polymeric [R.sup.1R.sup.2B--NR.sup.3R.sup.4].sub.n product. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources.

  15. NUCLEAR REGULATOR%'-C~fiMls6N REGION I

    Office of Legacy Management (LM)

    jNrTED ST&ye I ) r P, NUCLEAR REGULATOR%'-CfiMls6N REGION I 63I PIIRK AVENUE ... Repcr; Number 43-X6691-01 U.S. NUCLEAR ZGULATORY COMMISSION 3FFiCE OF IXS? ...

  16. #iWNCD W ONTAININO Il@MQWm;

    Office of Legacy Management (LM)

    PERCENTS 17.77 g ', 10 Attention: Nr. RI ' ia God, Jr. AIJO' Div. Pm&. (Agent We have been mqueeted by We est;mate that %t wuld be ptmalble to edd &mNa&drlf 1500 man-hours rt ...

  17. The correlation study of parallel feature extractor and noise reduction approaches

    SciTech Connect

    Dewi, Deshinta Arrova; Sundararajan, Elankovan; Prabuwono, Anton Satria

    2015-05-15

    This paper presents literature reviews that show variety of techniques to develop parallel feature extractor and finding its correlation with noise reduction approaches for low light intensity images. Low light intensity images are normally displayed as darker images and low contrast. Without proper handling techniques, those images regularly become evidences of misperception of objects and textures, the incapability to section them. The visual illusions regularly clues to disorientation, user fatigue, poor detection and classification performance of humans and computer algorithms. Noise reduction approaches (NR) therefore is an essential step for other image processing steps such as edge detection, image segmentation, image compression, etc. Parallel Feature Extractor (PFE) meant to capture visual contents of images involves partitioning images into segments, detecting image overlaps if any, and controlling distributed and redistributed segments to extract the features. Working on low light intensity images make the PFE face challenges and closely depend on the quality of its pre-processing steps. Some papers have suggested many well established NR as well as PFE strategies however only few resources have suggested or mentioned the correlation between them. This paper reviews best approaches of the NR and the PFE with detailed explanation on the suggested correlation. This finding may suggest relevant strategies of the PFE development. With the help of knowledge based reasoning, computational approaches and algorithms, we present the correlation study between the NR and the PFE that can be useful for the development and enhancement of other existing PFE.

  18. Daniel Hoag Named Y-12 Site Office Deputy Manager | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Daniel Hoag Named Y-12 Site Office Deputy Manager March 23, 2011 Daniel hoag named y-12 site office deputy manager. OAK RIDGE, Tenn. -- Daniel K. Hoag has been named Deputy Manager for the National Nuclear Security Administration's Y-12 Site Office (YSO). Microsoft Office document icon NR-03-23

  19. Section 3161 Announcement: Possible Workforce Restructuring at the Y-12

    National Nuclear Security Administration (NNSA)

    National Security Complex and Its Satellite Facilities Announced | National Nuclear Security Administration | (NNSA) Section 3161 Announcement: Possible Workforce Restructuring at the Y-12 National Security Complex and Its Satellite Facilities Announced October 10, 2007 Microsoft Office document icon NR-10-07

  20. Y-12 Steam Plant Project Received National Recognition for Project

    National Nuclear Security Administration (NNSA)

    Management Excellence | National Nuclear Security Administration | (NNSA) Steam Plant Project Received National Recognition for Project Management Excellence March 23, 2011 Y-12 steam plant project receives national recognition for project management excellence. Y-12's Steam Plant Life Extension Project (SPLE) has received the Secretary of Energy's Project Management Improvement Award. Microsoft Office document icon NR-03-28

  1. DOE/NV/11718-594

    National Nuclear Security Administration (NNSA)

    ... 231 FRENCH, N.R., C.D. JORGENSEN, M.H. SMITH, and B.G. MAZA. 1971. Comparison of Some ... E.P., T.E. HUXMAN, M.E. LOIK, and S.D. SMITH. 2000. Effects of extreme high ...

  2. Title Geographic Distribution. Eumeces gilberti Rubricaudatus...

    National Nuclear Security Administration (NNSA)

    RL 10,0.3 km E ofCo.RoadDD(Sec.33,T52N.R26W).16July 1989. F. E. Blake & D. D. Smith. ... Conserv. Publ., 368 pp.). Submitted by DONALD D. SMITH, Divi- sion of Allergy & ...

  3. University of Regina researchers complete milestone in major international

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    physics project at JLab (University of Regina) | Jefferson Lab researchers complete milestone in major international physics project at JLab (University of Regina) External Link: http://www.uregina.ca/external/communications/releases/current/nr-03232012.html By jlab_admin on Fri, 2012-03-23

  4. Participants: Judith Holm, DOE-AL Markus Popa, RW-44 Betty Nolan...

    Office of Environmental Management (EM)

    Judith Holm, DOE-AL Markus Popa, RW-44 Betty Nolan, DOE-HQ-CI Dave Crose, IN-MWCSG Ray English, DOE-NR Greg Sahd, DOE-CAO-WIPP Fred Butterfield, DOE-HQ-EM-22 Audrey Adamson, UETC-...

  5. Reduced Activity of Double-Strand Break Repair Genes in Prostate Cancer Patients With Late Normal Tissue Radiation Toxicity

    SciTech Connect

    Oorschot, Bregje van; Hovingh, Suzanne E.; Moerland, Perry D.; Medema, Jan Paul; Stalpers, Lukas J.A.; Vrieling, Harry; Franken, Nicolaas A.P.

    2014-03-01

    Purpose: To investigate clinical parameters and DNA damage response as possible risk factors for radiation toxicity in the setting of prostate cancer. Methods and Materials: Clinical parameters of 61 prostate cancer patients, 34 with (overresponding, OR) and 27 without (non-responding, NR) severe late radiation toxicity were assembled. In addition, for a matched subset the DNA damage repair kinetics (γ-H2AX assay) and expression profiles of DNA repair genes were determined in ex vivo irradiated lymphocytes. Results: Examination of clinical data indicated none of the considered clinical parameters to be correlated with the susceptibility of patients to develop late radiation toxicity. Although frequencies of γ-H2AX foci induced immediately after irradiation were similar (P=.32), significantly higher numbers of γ-H2AX foci were found 24 hours after irradiation in OR compared with NR patients (P=.03). Patient-specific γ-H2AX foci decay ratios were significantly higher in NR patients than in OR patients (P<.0001). Consequently, NR patients seem to repair DNA double-strand breaks (DSBs) more efficiently than OR patients. Moreover, gene expression analysis indicated several genes of the homologous recombination pathway to be stronger induced in NR compared with OR patients (P<.05). A similar trend was observed in genes of the nonhomologous end-joining repair pathway (P=.09). This is congruent with more proficient repair of DNA DSBs in patients without late radiation toxicity. Conclusions: Both gene expression profiling and DNA DSB repair kinetics data imply that less-efficient repair of radiation-induced DSBs may contribute to the development of late normal tissue damage. Induction levels of DSB repair genes (eg, RAD51) may potentially be used to assess the risk for late radiation toxicity.

  6. Effects of the nitro-group on the mutagenicity and toxicity of some benzamines

    SciTech Connect

    Chung, K.T.; Murdock, C.A.; Zhou, Y.

    1995-11-01

    The Ames Salmonella/microsomal assay was employed to test the mutagenicity of some benzamines and their nitro-derivatives using strains TA98 and TA100, and their nitro-reductase deficient mutants, TA98NR and TA100 NR, in the presence and absence of Aroclor 1254 induced rat S9 mix. Aniline was not mutagenic to any tester strains; whereas p-nitroaniline was directly mutagenic to TA98, but not to TA98NR. 2-Nitro-p-phenylenediamine and 4-nitro-o-phenylenediamine were strongly mutagenic to all strains with or without S9 mix, whereas p-phenylenediamine was weakly mutagenic to TA98 and TA98NR after metabolic activation. 3-Nitro-o-phenylendiamine was a weak mutagen to all strains; and o-phenylenediamine was mutagenic to TA98, TA98NR, and TA100 with activation. The addition of the nitro-group to benzamines thus converts them into direct mutagens; the position of the nitro-group is crucial for mutagenic activity. Cytoxicity of these compounds were also examined using Chinese hamster ovary cells. The oxidation potentials of these compounds were measured using PARC EGG 273 Potentiostat/Gavonostat equipped with a PC computer. Physical properties such as the energy difference between the Lowest Unoccupied Molecular Orbital and the Highest Occupied Molecular Orbital, ionization potential and dipole moment were calculated. The mutagenicity or toxicity of these compounds was not related to any of these physical properties. The effect of the nitro-group on the mutagenicity of benzamines is unclear.

  7. Cadmium amido alkoxide and alkoxide precursors for the synthesis of nanocrystalline CdE (E=S,Se, Te).

    SciTech Connect

    Boyle, Timothy J.; Avilucea, Gabriel; Bunge, Scott D.; Alam, Todd Michael; Headley, Thomas Jeffrey; Holland, Gregory P.

    2004-12-01

    The synthesis and characterization of a family of alternative precursors for the production of CdE nanoparticles (E = S, Se, and Te) is reported. The reaction of Cd(NR{sub 2}){sub 2} where NR{sub 2} = N(SiMe{sub 3}){sub 2} with n HOR led to the isolation of the following: n = 1 [Cd({mu}-OCH{sub 2}CMe{sub 3})(NR{sub 2})(py)]{sub 2} (1, py = pyridine), Cd[({mu}-OC{sub 6}H{sub 3}(Me){sub 2}-2,6){sub 2}Cd(NR{sub 2})(py)]{sub 2} (2), [Cd({mu}-OC{sub 6}H{sub 3}(CHMe{sub 2}){sub 2}-2,6)(NR{sub 2})(py)]{sub 2} (3), [Cd({mu}-OC{sub 6}H{sub 3}(CMe{sub 3}){sub 2}-2,6)(NR{sub 2})(py)]{sub 2} (4), [Cd({mu}-OC{sub 6}H{sub 2}(NH{sub 2}){sub 3}-2,4,6)(NR{sub 2})(py)]{sub 2} (5), and n = 2 [Cd({mu}-OC{sub 6}H{sub 3}(Me){sub 2}-2,6)(OC{sub 6}H{sub 3}(Me){sub 2}-2,6)(py){sub 2}]{sub 2} (6), and [Cd({mu}-OC{sub 6}H{sub 3}(CMe{sub 3}){sub 2}-2,6)(OC{sub 6}H{sub 3}(CMe{sub 3}){sub 2}-2,6)(THF)]{sub 2} (7). For all but 2, the X-ray crystal structures were solved as discrete dinuclear units bridged by alkoxide ligands and either terminal -NR{sub 2} or -OR ligands depending on the stoichiometry of the initial reaction. For 2, a trinuclear species was isolated using four {mu}-OR and two terminal -NR{sub 2} ligands. The coordination of the Cd metal center varied from 3 to 5 where the higher coordination numbers were achieved by binding Lewis basic solvents for the less sterically demanding ligands. These complexes were further characterized in solution by {sup 1}H, {sup 13}C, and {sup 113}Cd NMR along with solid-state {sup 113}Cd NMR spectroscopy. The utility of these complexes as 'alternative precursors' for the controlled preparation of nanocrystalline CdS, CdSe, and CdTe was explored. To synthesize CdE nanocrystals, select species from this family of compounds were individually heated in a coordinating solvent (trioctylphosphine oxide) and then injected with the appropriate chalcogenide stock solution. Transmission electron spectroscopy and UV-vis spectroscopy were used to characterize

  8. SU-D-18C-01: A Novel 4D-MRI Technology Based On K-Space Retrospective Sorting

    SciTech Connect

    Liu, Y; Yin, F; Cai, J

    2014-06-01

    Purpose: Current 4D-MRI techniques lack sufficient temporal/spatial resolution and consistent tumor contrast. To overcome these limitations, this study presents the development and initial evaluation of an entirely new framework of 4D-MRI based on k-space retrospective sorting. Methods: An important challenge of the proposed technique is to determine the number of repeated scans(NR) required to obtain sufficient k-space data for 4D-MRI. To do that, simulations using 29 cancer patients' respiratory profiles were performed to derive the relationship between data acquisition completeness(Cp) and NR, also relationship between NR(Cp=95%) and the following factors: total slice(NS), respiratory phase bin length(Lb), frame rate(fr), resolution(R) and image acquisition starting-phase(P0). To evaluate our technique, a computer simulation study on a 4D digital human phantom (XCAT) were conducted with regular breathing (fr=0.5Hz; R=256256). A 2D echo planer imaging(EPI) MRI sequence were assumed to acquire raw k-space data, with respiratory signal and acquisition time for each k-space data line recorded simultaneously. K-space data was re-sorted based on respiratory phases. To evaluate 4D-MRI image quality, tumor trajectories were measured and compared with the input signal. Mean relative amplitude difference(D) and cross-correlation coefficient(CC) are calculated. Finally, phase-sharing sliding window technique was applied to investigate the feasibility of generating ultra-fast 4D-MRI. Result: Cp increased with NR(Cp=100*[1-exp(-0.19*NR)], when NS=30, Lb=100%/6). NR(Cp=95%) was inversely-proportional to Lb (r=0.97), but independent of other factors. 4D-MRI on XCAT demonstrated highly accurate motion information (D=0.67%, CC=0.996) with much less artifacts than those on image-based sorting 4D-MRI. Ultra-fast 4D-MRI with an apparent temporal resolution of 10 frames/second was reconstructed using the phase-sharing sliding window technique. Conclusions: A novel 4D-MRI technology

  9. Experimental verification of epsilon-near-zero plasmon polariton modes in degenerately doped semiconductor nanolayers

    SciTech Connect

    Campione, Salvatore; Kim, Iltai; de Ceglia, Domenico; Keeler, Gordon A.; Luk, Ting S.

    2016-01-01

    Here, we investigate optical polariton modes supported by subwavelength-thick degenerately doped semiconductor nanolayers (e.g. indium tin oxide) on glass in the epsilon-near-zero (ENZ) regime. The dispersions of the radiative (R, on the left of the light line) and non-radiative (NR, on the right of the light line) ENZ polariton modes are experimentally measured and theoretically analyzed through the transfer matrix method and the complex-frequency/real-wavenumber analysis, which are in remarkable agreement. We observe directional near-perfect absorption using the Kretschmann geometry for incidence conditions close to the NR-ENZ polariton mode dispersion. Along with field enhancement, this provides us with an unexplored pathway to enhance nonlinear optical processes and to open up directions for ultrafast, tunable thermal emission.

  10. Experimental verification of epsilon-near-zero plasmon polariton modes in degenerately doped semiconductor nanolayers

    DOE PAGES [OSTI]

    Campione, Salvatore; Kim, Iltai; de Ceglia, Domenico; Keeler, Gordon A.; Luk, Ting S.

    2016-01-01

    Here, we investigate optical polariton modes supported by subwavelength-thick degenerately doped semiconductor nanolayers (e.g. indium tin oxide) on glass in the epsilon-near-zero (ENZ) regime. The dispersions of the radiative (R, on the left of the light line) and non-radiative (NR, on the right of the light line) ENZ polariton modes are experimentally measured and theoretically analyzed through the transfer matrix method and the complex-frequency/real-wavenumber analysis, which are in remarkable agreement. We observe directional near-perfect absorption using the Kretschmann geometry for incidence conditions close to the NR-ENZ polariton mode dispersion. Along with field enhancement, this provides us with an unexplored pathwaymore » to enhance nonlinear optical processes and to open up directions for ultrafast, tunable thermal emission.« less

  11. The signaling phospholipid PIP3 creates a new interaction surface on the nuclear receptor SF-1

    DOE PAGES [OSTI]

    Blind, Raymond D.; Sablin, Elena P.; Kuchenbecker, Kristopher M.; Chiu, Hsiu-Ju; Deacon, Ashley M.; Das, Debanu; Fletterick, Robert J.; Ingraham, Holly A.

    2014-10-06

    We previously reported that lipids PI(4,5)P2 (PIP2) and PI(3,4,5)P3 (PIP3) bind NR5A nuclear receptors to regulate their activity. Here, the crystal structures of PIP2 and PIP3 bound to NR5A1 (SF-1) define a new interaction surface that is organized by the solvent-exposed PIPn headgroups. We find that stabilization by the PIP3 ligand propagates a signal that increases coactivator recruitment to SF-1, consistent with our earlier work showing that PIP3 increases SF-1 activity. This newly created surface harbors a cluster of human mutations that lead to endocrine disorders, thus explaining how these puzzling mutations cripple SF-1 activity. Finally, we propose that thismore » new surface acts as a PIP3-regulated interface between SF-1 and coregulatory proteins, analogous to the function of membrane-bound phosphoinositides.« less

  12. Shippingport Station Decommissioning Project. Final project report

    SciTech Connect

    McKernan, M.L.

    1989-12-22

    The Shippingport Atomic Power Station was located on the Ohio River in Shippingport Borough (Beaver County), Pennsylvania, USA. The US Atomic Energy Commission (AEC) constructed the plant in the mid-1950s on a seven and half acre parcel of land leased from Duquesne Light Company (DLC). The purposes were to demonstrate and to develop Pressurized Water Recovery technology and to generate electricity. DLC operated the Shippingport plant under supervision of (the successor to AEC) the Department of Energy (DOE)-Naval Reactors (NR) until operations were terminated on October 1, 1982. NR concluded end-of-life testing and defueling in 1984 and transferred the Station`s responsibility to DOE Richland Operations Office (RL), Surplus Facility Management Program Office (SFMPO5) on September 5, 1984. SFMPO subsequently established the Shippingport Station Decommissioning Project and selected General Electric (GE) as the Decommissioning Operations Contractor. This report is intended to provide an overview of the Shippingport Station Decommissioning Project.

  13. Shippingport Station Decommissioning Project

    SciTech Connect

    McKernan, M.L.

    1989-12-22

    The Shippingport Atomic Power Station was located on the Ohio River in Shippingport Borough (Beaver County), Pennsylvania, USA. The US Atomic Energy Commission (AEC) constructed the plant in the mid-1950s on a seven and half acre parcel of land leased from Duquesne Light Company (DLC). The purposes were to demonstrate and to develop Pressurized Water Recovery technology and to generate electricity. DLC operated the Shippingport plant under supervision of (the successor to AEC) the Department of Energy (DOE)-Naval Reactors (NR) until operations were terminated on October 1, 1982. NR concluded end-of-life testing and defueling in 1984 and transferred the Station's responsibility to DOE Richland Operations Office (RL), Surplus Facility Management Program Office (SFMPO5) on September 5, 1984. SFMPO subsequently established the Shippingport Station Decommissioning Project and selected General Electric (GE) as the Decommissioning Operations Contractor. This report is intended to provide an overview of the Shippingport Station Decommissioning Project.

  14. Microsoft Word - Action Plan Appendix B as of 02-25-2014

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    B Listing of Treatment, Storage, and Disposal Groups/Units (sheet 1 of 19) B-1 Treatment, Storage, and Disposal Planned Action Group Number Group/Units Operable Unit (if applicable) Closure* Operating Permit D-1-1 100-D Ponds (120-D-1) 100-DR-1 X T-1-1 105-DR (122-DR-1) Sodium Fire Facility X D-1-2 1301-N/1325-N Liquid Waste Disposal Facilities 116-N-1 Crib 116-N-3 Crib 100-NR-1 X T-1-2 1324-N/1324-NA Liquid Waste Facilities 120-N-1 Pond 120-N-2 Neutralization Unit 100-NR-1 X T-1-3** 1706-KE

  15. Distinguished Student Awards Paul Asare Agyapong, NEN-3, UGS, Technical

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Distinguished Student Awards Paul Asare Agyapong, NEN-3, UGS, Technical Ty Brooks, C-IIAC, UGS, Technical Amy Jordan, EES-16, GRA, Technical Heather Hughes, IRM-CAS, GRA, Administrative Alison Tamasi, C-NR, GRA, Technical Andrea Vargas, ITPMO, GRA, Administrative Naomi Wasserman, EES-14, UGS, Technical Distinguished Mentor Awards Joysree Aubrey, IAT-DO Alina Deshpande, DSA-3 Andrew Nelson, MST-7 Robert Robey, XCP-2 Information Technology Cody Jackson, "Evaluating Cyber Security Policies

  16. Assessment Report: OAS-V-15-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1 Assessment Report: OAS-V-15-01 November 25, 2014 Assessment of Audit Coverage of Cost Allowability for Bechtel Marine Propulsion Corporation During October 1, 2012, Through September 30, 2013, Under Department of Energy Contract No. DE-NR0000031 Bechtel Marine Propulsion Corporation (BMPC) was established solely to operate the Naval Nuclear Propulsion Program, which is a joint Navy-Department of Energy program responsible for the research, design, construction, operation, and maintenance of

  17. Combined therapeutic potential of nuclear receptors with receptor tyrosine kinase inhibitors in lung cancer

    SciTech Connect

    Wairagu, Peninah M.; Park, Kwang Hwa; Kim, Jihye; Choi, Jong-Whan; Kim, Hyun-Won; Yeh, Byung-Il; Jung, Soon-Hee; Yong, Suk-Joong; Jeong, Yangsik

    2014-05-09

    Highlights: The 48 NR genes and 48 biological anti-cancer targets are profiled in paired-cells. Growth inhibition by NR ligands or TKIs is target receptor level-dependent. T0901317 with gefitinib/PHA665752 shows additive growth inhibition in lung cells. - Abstract: Cancer heterogeneity is a big hurdle in achieving complete cancer treatment, which has led to the emergence of combinational therapy. In this study, we investigated the potential use of nuclear receptor (NR) ligands for combinational therapy with other anti-cancer drugs. We first profiled all 48 NRs and 48 biological anti-cancer targets in four pairs of lung cell lines, where each pair was obtained from the same patient. Two sets of cell lines were normal and the corresponding tumor cell lines while the other two sets consisted of primary versus metastatic tumor cell lines. Analysis of the expression profile revealed 11 NRs and 15 cancer targets from the two pairs of normal versus tumor cell lines, and 9 NRs and 9 cancer targets from the primary versus metastatic tumor cell lines had distinct expression patterns in each category. Finally, the evaluation of nuclear receptor ligand T0901317 for liver X receptor (LXR) demonstrated its combined therapeutic potential with tyrosine kinase inhibitors. The combined treatment of cMET inhibitor PHA665752 or EGFR inhibitor gefitinib with T0901317 showed additive growth inhibition in both H2073 and H1993 cells. Mechanistically, the combined treatment suppressed cell cycle progression by inhibiting cyclinD1 and cyclinB expression. Taken together, this study provides insight into the potential use of NR ligands in combined therapeutics with other biological anti-cancer drugs.

  18. Long-term measurements of submicrometer aerosol chemistry at the Southern Great Plains (SGP) using an Aerosol Chemical Speciation Monitor (ACSM)

    SciTech Connect

    Parworth, Caroline; Tilp, Alison; Fast, Jerome; Mei, Fan; Shippert, Tim; Sivaraman, Chitra; Watson, Thomas; Zhang, Qi

    2015-04-01

    In this study the long-term trends of non-refractory submicrometer aerosol (NR-PM1) composition and mass concentration measured by an Aerosol Chemical Speciation Monitor (ACSM) at the Atmospheric Radiation Measurement (ARM) program's Southern Great Plains (SGP) site are discussed. NR-PM1 data was recorded at ~30 min intervals over a period of 19 months between November 2010 and June 2012. Positive Matrix Factorization (PMF) was performed on the measured organic mass spectral matrix using a rolling window technique to derive factors associated with distinct sources, evolution processes, and physiochemical properties. The rolling window approach also allows us to capture the dynamic variations of the chemical properties in the organic aerosol (OA) factors over time. Three OA factors were obtained including two oxygenated OA (OOA) factors, differing in degrees of oxidation, and a biomass burning OA (BBOA) factor. Back trajectory analyses were performed to investigate possible sources of major NR-PM1 species at the SGP site. Organics dominated NR-PM1 mass concentration for the majority of the study with the exception of winter, when ammonium nitrate increases due to transport of precursor species from surrounding urban and agricultural areas and also due to cooler temperatures. Sulfate mass concentrations have little seasonal variation with mixed regional and local sources. In the spring BBOA emissions increase and are mainly associated with local fires. Isoprene and carbon monoxide emission rates were obtained by the Model of Emissions of Gases and Aerosols from Nature (MEGAN) and the 2011 U.S. National Emissions Inventory to represent the spatial distribution of biogenic and anthropogenic sources, respectively. The combined spatial distribution of isoprene emissions and air mass trajectories suggest that biogenic emissions from the southeast contribute to SOA formation at the SGP site during the summer.

  19. On Womens Equality Day, we celebrate NNSA's talented Women in STEM |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) On Womens Equality Day, we celebrate NNSA's talented Women in STEM Friday, August 26, 2016 - 4:07pm Related Topics lanl Lawrence Livermore National Laboratory llnl Los alamos national laboratory naval reactors nr pantex Pantex Plant Sandia National Laboratories Savannah river site snl srs STEM Y-12 National Security Complex y12 Related News Former Army Ranger wins Sandia-sponsored student of the year award NNSA engineer teaches young people

  20. Reversible Electrocatalytic Production and Oxidation of Hydrogen at Low Overpotentials by a Functional Hydrogenase Mimic

    SciTech Connect

    Smith, Stuart E.; Yang, Jenny Y.; DuBois, Daniel L.; Bullock, Morris

    2012-03-26

    A new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A {Delta}G{sup o} of 0.84 kcal/mol{sup -1} for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, a characteristic most commonly associated with hydrogenase enzymes.

  1. Long-term Measurements of Submicrometer Aerosol Chemistry at the Southern Great Plains (SGP) Using an Aerosol Chemical Speciation Monitor (ACSM)

    SciTech Connect

    Parworth, Caroline; Fast, Jerome D.; Mei, Fan; Shippert, Timothy R.; Sivaraman, Chitra; Tilp, Alison; Watson, Thomas; Zhang, Qi

    2015-04-01

    In this study the long-term trends of non-refractory submicrometer aerosol (NR-PM1) composition and mass concentration measured by an Aerosol Chemical Speciation Monitor (ACSM) at the U.S. Department of Energy’s Southern Great Plains (SGP) site are discussed. Over the period of 19 months (Nov. 20, 2010 – June 2012) highly time resolved (~30 min.) NR-PM1 data was recorded. Using this dataset the value-added product (VAP) of deriving organic aerosol components (OACOMP) is introduced. With this VAP, multivariate analysis of the measured organic mass spectral matrix can be performed on long term data to return organic aerosol (OA) factors that are associated with distinct sources, evolution processes, and physiochemical properties. Three factors were obtained from this VAP including two oxygenated OA (OOA) factors, differing in degrees of oxidation, and a biomass burning OA (BBOA) factor. Back trajectory analyses were performed to investigate possible sources of major NR-PM1 species at the SGP site. Organics dominated NR-PM1 mass concentration for the majority of the study with the exception of winter, when nitrate increased due to transport of precursor species from surrounding urban and agricultural areas and also due to cooler temperatures. Sulfate mass concentrations showed little seasonal variation with mixed regional and local sources. In the spring BBOA emissions increased and were mainly associated with local fires. Isoprene and carbon monoxide emission rates were computed by the Model of Emissions of Gases and Aerosols from Nature (MEGAN) to represent the spatial distribution of biogenic and anthropogenic sources, respectively. From this model there is evidence to support that biogenic emissions from the southeast contribute to SOA formation at the SGP site during the summer.

  2. EIS-0350-S1: Supplemental Environmental Impact Statement for the Nuclear Facility Portion of the Chemistry and Metallurgy Research Building Replacement Project at Los Alamos National Laboratory, New Mexico

    Energy.gov [DOE]

    This Supplemental EIS evaluates the completion of the Chemistry and Metallurgy Research Building Replacement (CMRR) Project, which consists of constructing the nuclear facility portion (CMRR-NF) at Los Alamos National Laboratory (LANL). The CMRR Project provides the analytical chemistry and materials characterization capabilities currently or previously performed in the existing Chemistry and Metallurgy Research (CMR) Building. Because of recent detailed site geotechnical investigations, certain aspects of the CMRR-NR project have changed resulting in change to the environmental impacts.

  3. SPRU by the Numbers August 2015

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Separations Process Research Unit (SPRU) is an inactive facility located at the Naval Reactor's (NR) Knolls Atomic Power Laboratory (KAPL) in Niskayuna, New York, near Schenectady. The Mohawk River forms the northern boundary of this site. KAPL was created as a general-purpose laboratory for the former U.S. Atomic Energy Commission. Built in the late 1940s, the buildings supported the SPRU mission to research the chemical process to extract plutonium from irradiated materials. Equipment was

  4. Long-term measurements of submicrometer aerosol chemistry at the Southern Great Plains (SGP) using an Aerosol Chemical Speciation Monitor (ACSM)

    DOE PAGES [OSTI]

    Parworth, Caroline; Tilp, Alison; Fast, Jerome; Mei, Fan; Shippert, Tim; Sivaraman, Chitra; Watson, Thomas; Zhang, Qi

    2015-04-01

    In this study the long-term trends of non-refractory submicrometer aerosol (NR-PM1) composition and mass concentration measured by an Aerosol Chemical Speciation Monitor (ACSM) at the Atmospheric Radiation Measurement (ARM) program's Southern Great Plains (SGP) site are discussed. NR-PM1 data was recorded at ~30 min intervals over a period of 19 months between November 2010 and June 2012. Positive Matrix Factorization (PMF) was performed on the measured organic mass spectral matrix using a rolling window technique to derive factors associated with distinct sources, evolution processes, and physiochemical properties. The rolling window approach also allows us to capture the dynamic variations ofmore » the chemical properties in the organic aerosol (OA) factors over time. Three OA factors were obtained including two oxygenated OA (OOA) factors, differing in degrees of oxidation, and a biomass burning OA (BBOA) factor. Back trajectory analyses were performed to investigate possible sources of major NR-PM1 species at the SGP site. Organics dominated NR-PM1 mass concentration for the majority of the study with the exception of winter, when ammonium nitrate increases due to transport of precursor species from surrounding urban and agricultural areas and also due to cooler temperatures. Sulfate mass concentrations have little seasonal variation with mixed regional and local sources. In the spring BBOA emissions increase and are mainly associated with local fires. Isoprene and carbon monoxide emission rates were obtained by the Model of Emissions of Gases and Aerosols from Nature (MEGAN) and the 2011 U.S. National Emissions Inventory to represent the spatial distribution of biogenic and anthropogenic sources, respectively. The combined spatial distribution of isoprene emissions and air mass trajectories suggest that biogenic emissions from the southeast contribute to SOA formation at the SGP site during the summer.« less

  5. A unique nuclear receptor direct repeat 17 (DR17) is present within the upstream region of Schistosoma mansoni female-specific p14 gene

    SciTech Connect

    Fantappie, Marcelo Rosado Furtado, Daniel Rodrigues; Rumjanek, Franklin David; LoVerde, Philip T.

    2008-07-11

    The eggs produced by sexually mature female Schistosma mansoni are responsible for the pathogenesis of the disease. The eggshell precursor gene p14 is expressed only in the vitelline cells of sexually mature female worms in response to a yet unidentified male stimulus. Herein, we report the identification of a novel nuclear receptor response element in the upstream region of the p14 gene. This element contains the canonical hexameric DNA core motif, 5'-PuGGTCA, composed of an atypically spaced direct repeat (DR17). Schistosome nuclear receptors SmRXR1 and SmNR1 specifically bound to the p14-DR17 element as a heterodimer. SmRXR1, but not SmNR1, bound to the motif as a monomer. Introduction of mutations in the TCA core sequence completely abolished the binding by SmRXR1/SmNR1 heterodimer. This finding supports our hypothesis that the expression of Schistosoma mansonip14 gene is regulated through the nuclear receptor signaling pathway.

  6. Effects of relativity for atomization and isomerization energies of seaborgium carbonyl SgCO and seaborgium isocarbonyl SgOC: Relativity predicts SgOC to be more stable than SgCO

    SciTech Connect

    Malli, Gulzari L.

    2015-12-15

    Our ab initio all-electron fully relativistic Dirac-Fock (DF) and nonrelativistic Hartree-Fock (NR) calculations for seaborgium isocarbonyl SgOC predict atomization energy (AE) of 13.04 and 11.05 eV, respectively. However, the corresponding DF and NR atomization energies for the seaborgium carbonyl SgCO are predicted as 12.75 and 12.45 eV, respectively. This is the first such result in Chemistry where an isocarbonyl (and especially for a system of superheavy element Sg) is predicted to be more stable at the DF level of theory than the corresponding carbonyl. The predicted energy for the formation of the carbonyl SgCO at the relativistic DF and NR levels of theory is -54.90 and -50.95 kJ /mol, whereas the corresponding energy of formation of the isocarbonyl SgOC is -64.44 and -18.64 kJ/mol, respectively. Ours are the first results of relativistic effects for isomerization and atomization energies of the superheavy seaborgium isocarbonyl SgOC and its isomer SgCO.The formation of isocarbonyl SgOC, should be favored over the carbonyl isomer SgCO in the first step of the reaction Sg+CO →SgOC.

  7. Model Investigation of Temperature and Concentration Dependent Luminescence of Erbium-doped Tellurite Glasses

    SciTech Connect

    Ghoshal, S. K.; Sahar, M. R.; Rohani, M. S.; Tewari, H. S.

    2011-11-22

    Improving the up-conversion efficiency is the key issue in tellurite glasses. The quantum efficiency, radiative transition rate and lifetimes of excited states are greatly influenced by the optical properties of the host material, ligand field, multiphonon relaxation processes, impurities, temperature and concentration of erbium ions. We develop a comprehensive 4-level model to examine the radiative and nonradiative (NR) decay processes for the green ({sup 4}S{sub 3/2}{yields}{sup 4}I{sub 15/2}) and red ({sup 4}F{sub 9/2}{yields}{sup 4}I{sub 15/2}) emission over a temperature range of (10-340 K) and concentration range of (0.1-4.5 mol.%). Concentration dependent enhancement and thermal quenching of efficiency for up-conversion is investigated using the derived rate equations. These features are attributed to the NR energy transfer processes, trapped impurity effects, and thermal assisted hopping. The unusual nature of temperature and concentration dependent quenching effects for green and red emission is queries for further investigations. It is further suggested that to achieve higher infrared to visible up-converted efficiency in tellurite glasses the NR channels for energy and charge transfer by phonon and impurity mediated process has to be minimized. Our results on pump power dependent emission intensity, quantum efficiency, luminescence intensity, radiative lifetimes, and transition probabilities are in conformity with other experimental findings.

  8. Atmospheric Radiation Measurement Program Climate Research Facility Operations Quarterly Report. October 1 - December 31, 2009.

    SciTech Connect

    D. L. Sisterson

    2010-01-12

    individual instrument uptime. Thus, the average percentage of data in the Archive represents the average percentage of the time (24 hours per day, 92 days for this quarter) the instruments were operating this quarter. The Site Access Request System is a web-based database used to track visitors to the fixed and mobile sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP locale has historically had a central facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. Beginning this quarter, the SGP began a transition to a smaller footprint (150 km x 150 km) by rearranging the original and new instrumentation made available through the American Recovery and Reinvestment Act (ARRA). The central facility and 4 extended facilities will remain, but there will be up to 16 surface new characterization facilities, 4 radar facilities, and 3 profiler facilities sited in the smaller domain. This new configuration will provide observations at scales more appropriate to current and future climate models. The TWP locale has the Manus, Nauru, and Darwin sites. These sites will also have expanded measurement capabilities with the addition of new instrumentation made available through ARRA funds. It is anticipated that the new instrumentation at all the fixed sites will be in place within the next 12 months. The AMF continues its 20-month deployment in Graciosa Island, Azores, Portugal, that started May 1, 2009. The AMF will also have additional observational capabilities within the next 12 months. Users can participate in field experiments at the sites and mobile facility, or they can participate remotely. Therefore, a variety of mechanisms are provided to users to access site information. Users who have immediate (real-time) needs for data access can request a research account on the local site data systems. This access is particularly useful to users for quick decisions in executing time

  9. Atmospheric Radiation Measurement program climate research facility operations quarterly report July 1 - September 30, 2008.

    SciTech Connect

    Sisterson, D. L.

    2008-10-08

    Individual raw data streams from instrumentation at the Atmospheric Radiation Measurement (ARM) Program Climate Research Facility (ACRF) fixed and mobile sites are collected and sent to the Data Management Facility (DMF) at Pacific Northwest National Laboratory (PNNL) for processing in near real-time. Raw and processed data are then sent daily to the ACRF Archive, where they are made available to users. For each instrument, we calculate the ratio of the actual number of data records received daily at the Archive to the expected number of data records. The results are tabulated by (1) individual data stream, site, and month for the current year and (2) site and fiscal year (FY) dating back to 1998. Table 1 shows the accumulated maximum operation time (planned uptime), actual hours of operation, and variance (unplanned downtime) for the period July 1 - September 30, 2008, for the fixed sites. The AMF has been deployed to China, but the data have not yet been released. The fourth quarter comprises a total of 2,208 hours. The average exceeded our goal this quarter. The Site Access Request System is a web-based database used to track visitors to the fixed and mobile sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP site has a central facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. The TWP locale has the Manus, Nauru, and Darwin sites. HFE represents the AMF statistics for the Shouxian, China, deployment in 2008. FKB represents the AMF statistics for the Haselbach, Germany, past deployment in 2007. NIM represents the AMF statistics for the Niamey, Niger, Africa, past deployment in 2006. PYE represents just the AMF Archive statistics for the Point Reyes, California, past deployment in 2005. In addition, users who do not want to wait for data to be provided through the ACRF Archive can request a research account on the local site data system. The seven computers for the

  10. Atmospheric Radiation Measurement program climate research facility operations quarterly report January 1 - March 31, 2008.

    SciTech Connect

    Sisterson, D. L.

    2008-05-22

    Individual raw data streams from instrumentation at the Atmospheric Radiation Measurement (ARM) Program Climate Research Facility (ACRF) fixed and mobile sites are collected and sent to the Data Management Facility (DMF) at Pacific Northwest National Laboratory (PNNL) for processing in near real time. Raw and processed data are then sent daily to the ACRF Archive, where they are made available to users. For each instrument, we calculate the ratio of the actual number of data records received daily at the Archive to the expected number of data records. The results are tabulated by (1) individual data stream, site, and month for the current year and (2) site and fiscal year (FY) dating back to 1998. Table 1 shows the accumulated maximum operation time (planned uptime), actual hours of operation, and variance (unplanned downtime) for the period January 1 - March 31, 2008, for the fixed sites. The AMF is being deployed to China and is not in operation this quarter. The second quarter comprises a total of 2,184 hours. The average as well as the individual site values exceeded our goal this quarter. The Site Access Request System is a web-based database used to track visitors to the fixed and mobile sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP site has a central facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. The TWP locale has the Manus, Nauru, and Darwin sites. FKB represents the AMF statistics for the Haselbach, Germany, past deployment in 2007. NIM represents the AMF statistics for the Niamey, Niger, Africa, past deployment in 2006. PYE represents just the AMF Archive statistics for the Point Reyes, California, past deployment in 2005. In addition, users who do not want to wait for data to be provided through the ACRF Archive can request a research account on the local site data system. The seven computers for the research accounts are located at the Barrow

  11. Atmospheric Radiation Measurement program climate research facility operations quarterly report October 1 - December 31, 2006.

    SciTech Connect

    Sisterson, D. L.

    2007-03-14

    Individual raw data streams from instrumentation at the Atmospheric Radiation Measurement (ARM) Program Climate Research Facility (ACRF) fixed and mobile sites are collected and sent to the Data Management Facility (DMF) at Pacific Northwest National Laboratory (PNNL) for processing in near real time. Raw and processed data are then sent daily to the ACRF Archive, where they are made available to users. For each instrument, we calculate the ratio of the actual number of data records received daily at the Archive to the expected number of data records. The results are tabulated by (1) individual data stream, site, and month for the current year and (2) site and fiscal year dating back to 1998. Table 1 shows the accumulated maximum operation time (planned uptime), the actual hours of operation, and the variance (unplanned downtime) for the period October 1 through December 31, 2006, for the fixed and mobile sites. Although the AMF is currently up and running in Niamey, Niger, Africa, the AMF statistics are reported separately and not included in the aggregate average with the fixed sites. The first quarter comprises a total of 2,208 hours. For all fixed sites, the actual data availability (and therefore actual hours of operation) exceeded the individual (and well as aggregate average of the fixed sites) operational goal for the first quarter of fiscal year (FY) 2007. The Site Access Request System is a web-based database used to track visitors to the fixed sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP site has a Central Facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. The TWP locale has the Manus, Nauru, and Darwin sites. NIM represents the AMF statistics for the current deployment in Niamey, Niger, Africa. PYE represents the AMF statistics for the Point Reyes, California, past deployment in 2005. In addition, users who do not want to wait for data to be

  12. Atmospheric Radiation Measurement program climate research facility operations quarterly report October 1 - December 31, 2007.

    SciTech Connect

    Sisterson, D. L.

    2008-01-24

    Individual raw data streams from instrumentation at the Atmospheric Radiation Measurement (ARM) Program Climate Research Facility (ACRF) fixed and mobile sites are collected and sent to the Data Management Facility (DMF) at Pacific Northwest National Laboratory (PNNL) for processing in near real time. Raw and processed data are then sent daily to the ACRF Archive, where they are made available to users. For each instrument, we calculate the ratio of the actual number of data records received daily at the Archive to the expected number of data records. The results are tabulated by (1) individual data stream, site, and month for the current year and (2) site and fiscal year (FY) dating back to 1998. Table 1 shows the accumulated maximum operation time (planned uptime), actual hours of operation, and variance (unplanned downtime) for the period October 1 - December 31, 2007, for the fixed sites and the mobile site. The AMF has been deployed to Germany and this was the final operational quarter. The first quarter comprises a total of 2,208 hours. Although the average exceeded our goal this quarter, a series of severe weather events (i.e., widespread ice storms) disrupted utility services, which affected the SGP performance measures. Some instruments were covered in ice and power and data communication lines were down for more than 10 days in some areas of Oklahoma and Kansas, which resulted in lost data at the SGP site. The Site Access Request System is a web-based database used to track visitors to the fixed sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP site has a central facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. The TWP locale has the Manus, Nauru, and Darwin sites. The AMF completed its mission at the end of this quarter in Haselback, Germany (FKB designation). NIM represents the AMF statistics for the Niamey, Niger, Africa, past deployment in 2006. PYE

  13. A novel approach to determine post mortem interval using neutron radiography

    DOE PAGES [OSTI]

    Bilheux, Hassina Z.; Cekanova, Maria; Vass, Arpad Alexander; Nichols, Trent L.; Bilheux, Jean -Christophe; Donnell, Robert; Finocchiaro, Vincenzo

    2015-03-06

    In this study, neutron radiography (NR) is used non-destructively to measure changes in hydrogen (H) content in decaying tissues as a mean to estimate post-mortem invertal (PMI). After death, tissue undergoes sequential changes consisting of organic and inorganic phase variations, as well as a gradual reduction of tissue water content. H is the primary contributor to NR contrast in biological specimens because (1) it is the most abundant element in biological tissues and (2) its nucleus scatter thermal and cold neutrons more strongly than any other atomic nucleus. These contrast differences can be advantageous in a forensic context to determinemore » small changes in hydrogen concentrations. Dog cadavers were used as a model for human cadavers. Canine tissues and cadavers were exposed to controlled (laboratory settings) and uncontrolled (University of Tennessee Anthropology Research Facility) environmental conditions during putefraction, respectively. Neutron radiographs were supplemented with photographs and histology data to assess the decomposition stage of cadavers. Results demonstrated that the increase in neutron transmission likely corresponded to a decrease in hydrogen content in the tissue, which was correlated with the time of decay of the tissue. Tissues depleted in hydrogen are brighter in the neutron transmission radiographs of skeletal muscles, lung, and bone, under controlled conditions. Over a period of 10 days, changes in neutron transmission through lung and muscle were found to be higher than bone by 8.3%, 7.0 %, and 2.0 %, respectively. Estimation of the PMI was calculated from a natural logarithmic fitting of the NR data. Under controlled conditions, estimation of the PMI was 70% and 63.9 % accurate for bone and lung tissues, while being 1.4% accurate for muscle tissue. All results underestimated the true PMI. In conclusion, neutron radiography can be used for detection of hydrogen changes in decaying tissues to estimate PMI.« less

  14. A novel approach to determine post mortem interval using neutron radiography

    SciTech Connect

    Bilheux, Hassina Z; Cekanova, Maria; Vass, Arpad Alexander; Nichols, Trent L; Bilheux, Jean-Christophe; Donnell, Robert; Finocchiaro, Vincenzo

    2015-01-01

    In this study, neutron radiography (NR) is used non-destructively to measure changes in hydrogen (H) content in decaying tissues as a mean to estimate post-mortem invertal (PMI). After death, tissue undergoes sequential changes consisting of organic and inorganic phase variations, as well as a gradual reduction of tissue water content. H is the primary contributor to NR contrast in biological specimens because (1) it is the most abundant element in biological tissues and (2) its nucleus scatter thermal and cold neutrons more strongly than any other atomic nucleus. These contrast differences can be advantageous in a forensic context to determine small changes in hydrogen concentrations. Dog cadavers were used as a model for human cadavers. Canine tissues and cadavers were exposed to controlled (laboratory settings) and uncontrolled (University of Tennessee Anthropology Research Facility) environmental conditions during putefraction, respectively. Neutron radiographs were supplemented with photographs and histology data to assess the decomposition stage of cadavers. Results demonstrated that the increase in neutron transmission likely corresponded to a decrease in hydrogen content in the tissue, which was correlated with the time of decay of the tissue. Tissues depleted in hydrogen are brighter in the neutron transmission radiographs of skeletal muscles, lung, and bone, under controlled conditions. Over a period of 10 days, changes in neutron transmission through lung and muscle were found to be higher than bone by 8.3%, 7.0 %, and 2.0 %, respectively. Estimation of the PMI was calculated from a natural logarithmic fitting of the NR data. Under controlled conditions, estimation of the PMI was 70% and 63.9 % accurate for bone and lung tissues, while being 1.4% accurate for muscle tissue. All results underestimated the true PMI. In conclusion, neutron radiography can be used for detection of hydrogen changes in decaying tissues to estimate PMI.

  15. Computer-aided breast MR image feature analysis for prediction of tumor response to chemotherapy

    SciTech Connect

    Aghaei, Faranak; Tan, Maxine; Liu, Hong; Zheng, Bin; Hollingsworth, Alan B.; Qian, Wei

    2015-11-15

    Purpose: To identify a new clinical marker based on quantitative kinetic image features analysis and assess its feasibility to predict tumor response to neoadjuvant chemotherapy. Methods: The authors assembled a dataset involving breast MR images acquired from 68 cancer patients before undergoing neoadjuvant chemotherapy. Among them, 25 patients had complete response (CR) and 43 had partial and nonresponse (NR) to chemotherapy based on the response evaluation criteria in solid tumors. The authors developed a computer-aided detection scheme to segment breast areas and tumors depicted on the breast MR images and computed a total of 39 kinetic image features from both tumor and background parenchymal enhancement regions. The authors then applied and tested two approaches to classify between CR and NR cases. The first one analyzed each individual feature and applied a simple feature fusion method that combines classification results from multiple features. The second approach tested an attribute selected classifier that integrates an artificial neural network (ANN) with a wrapper subset evaluator, which was optimized using a leave-one-case-out validation method. Results: In the pool of 39 features, 10 yielded relatively higher classification performance with the areas under receiver operating characteristic curves (AUCs) ranging from 0.61 to 0.78 to classify between CR and NR cases. Using a feature fusion method, the maximum AUC = 0.85 ± 0.05. Using the ANN-based classifier, AUC value significantly increased to 0.96 ± 0.03 (p < 0.01). Conclusions: This study demonstrated that quantitative analysis of kinetic image features computed from breast MR images acquired prechemotherapy has potential to generate a useful clinical marker in predicting tumor response to chemotherapy.

  16. A novel approach to determine post mortem interval using neutron radiography

    SciTech Connect

    Bilheux, Hassina Z.; Cekanova, Maria; Vass, Arpad Alexander; Nichols, Trent L.; Bilheux, Jean -Christophe; Donnell, Robert; Finocchiaro, Vincenzo

    2015-03-06

    In this study, neutron radiography (NR) is used non-destructively to measure changes in hydrogen (H) content in decaying tissues as a mean to estimate post-mortem invertal (PMI). After death, tissue undergoes sequential changes consisting of organic and inorganic phase variations, as well as a gradual reduction of tissue water content. H is the primary contributor to NR contrast in biological specimens because (1) it is the most abundant element in biological tissues and (2) its nucleus scatter thermal and cold neutrons more strongly than any other atomic nucleus. These contrast differences can be advantageous in a forensic context to determine small changes in hydrogen concentrations. Dog cadavers were used as a model for human cadavers. Canine tissues and cadavers were exposed to controlled (laboratory settings) and uncontrolled (University of Tennessee Anthropology Research Facility) environmental conditions during putefraction, respectively. Neutron radiographs were supplemented with photographs and histology data to assess the decomposition stage of cadavers. Results demonstrated that the increase in neutron transmission likely corresponded to a decrease in hydrogen content in the tissue, which was correlated with the time of decay of the tissue. Tissues depleted in hydrogen are brighter in the neutron transmission radiographs of skeletal muscles, lung, and bone, under controlled conditions. Over a period of 10 days, changes in neutron transmission through lung and muscle were found to be higher than bone by 8.3%, 7.0 %, and 2.0 %, respectively. Estimation of the PMI was calculated from a natural logarithmic fitting of the NR data. Under controlled conditions, estimation of the PMI was 70% and 63.9 % accurate for bone and lung tissues, while being 1.4% accurate for muscle tissue. All results underestimated the true PMI. In conclusion, neutron radiography can be used for detection of hydrogen changes in decaying tissues to estimate PMI.

  17. Field dependence of the vortex core size probed by scanning tunneling microscopy

    DOE PAGES [OSTI]

    Fente, A.; Herrera, E.; Guillamón, I.; Suderow, H.; Mañas-Valero, S.; Galbiati, M.; Coronado, E.; Kogan, V. G.

    2016-07-29

    We study the spatial distribution of the density of states (DOS) at zero bias N(r) in the mixed state of single and multigap superconductors. We provide an analytic expression for N(r) based on deGennes' relationship between DOS and the order parameter that reproduces well scanning tunneling microscopy (STM) data in several superconducting materials. In the single gap superconductor β-Bi2 Pd, we find that N(r) is governed by a length scale ξH =more » $$\\sqrt{Φ0/2πH}$$ which decreases in rising fields. The vortex core size $C$ ∝ (d Δ/dr|r→0)₋1 differs from ξH by a material dependent numerical factor. The new data on the tunneling conductance and vortex lattice of the 2H-NbSe1.8S0.2 show the in-plane isotropic vortices, suggesting that substitutional scattering removes the in-plane anisotropy found in the two-gap superconductor 2H-NbSe2. We fit the tunneling conductance of 2H-NbSe1.8S0.2 to a two gap model and calculate the vortex core size $C$ for each band. We find that $C$ is field independent and has the same value for both bands. We also analyze the two-band superconductor 2H-NbSe2 and find the same result. Lastly, we conclude that, independently of the magnetic field induced variation of the order parameter values in both bands, the spatial variation of the order parameter close to the vortex core is the same for all bands.« less

  18. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE PAGES [OSTI]

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-18

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  19. Collection efficiency of the Soot-Particle Aerosol Mass Spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE PAGES [OSTI]

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-05-26

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of two. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  20. Fine golden rings: Tunable surface plasmon resonance from assembled nanorods in topological defects of liquid crystals

    DOE PAGES [OSTI]

    Lee, Elaine; Xia, Yu; Ferrier, Jr., Robert C.; Kim, Hye -Na; Gharbi, Mohamed A.; Stebe, Kathleen J.; Kamien, Randall D.; Composto, Russell J.; Yang, Shu

    2016-02-08

    Unprecedented, reversible, and dynamic control over an assembly of gold nanorods dispersed in liquid crystals (LC) is demonstrated. The LC director field is dynamically tuned at the nanoscale using microscale ring confinement through the interplay of elastic energy at different temperatures, thus fine-tuning its core replacement energy to reversibly sequester nanoscale inclusions at the microscale. As a result, this leads to shifts of 100 nm or more in the surface plasmon resonance peak, an order of magnitude greater than any previous work with AuNR composites.

  1. AMENDMENT OF SOLICITATION/MODIFICATION OF CONTRACT I~' CONTRACT

    National Nuclear Security Administration (NNSA)

    I~' CONTRACT ID CODE IPAGE OF PAGES DE-NR0000031 . 1 I 1 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 4. REQUISITION/PURCHASE REQ. NO. I 5. PROJECT NO. (If applicable) 003 Same as Block 16G . N~ 6. ISSUED BV CODE 7. ADMINISTERED BV (If other than Item 6) Code I U.S. Department of Energy Pittsburgh Naval Reactors Office P.O. Box 109 West Mifflin, PA 15122-0109 8. NAME AND ADDRESS OF CONTRACTOR (No. street, county, State and ZIP Code) (*...) 9.A. AMENDMENT OF SOLICITATION NO. Bechtel Marine

  2. Microsoft Word - FY12 Fee Des.doc

    National Nuclear Security Administration (NNSA)

    NR0000031 copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of the offer submitted; or (c) By separate letter or telegram which includes a reference to the solicitation and amendment numbers. FAILURE OF YOUR ACKNOWLEDGEMENT TO BE RECEIVED AT THE PLACE DESIGNATED FOR THE RECEIPT OF OFFERS PRIOR TO THE HOUR AND DATE SPECIFIED MAY RESULT IN REJECTION OF YOUR OFFER. If by virtue of this amendment you desire to change an offer already submitted, such change may be

  3. Microsoft Word - M002-SF30.doc

    National Nuclear Security Administration (NNSA)

    I:.CONTRACT ID CODE IPAGE OF PAGES DE-NR0000031 1 I 27 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 4. REQUISITION/PURCHASE REQ. NO. 15. PROJECT NO. (II app/icable) 002 Same as Block 16C N/A 6. ISSUED BY CODE 7. ADMINISTERED BY (If other than Item 6) Code I U.S. Department of Energy Pittsburgh Naval Reactors Office P.O. Box 109 West Mifflin, PA 15122-0109 8. NAME AND ADDRESS OF CONTRACTOR (No. slreet, county, State and ZIP Code) ..J.:l 9.A. AMENDMENT OF SOLICITATION NO. Bechtel Marine

  4. EQ3/6 A Software Package for Geochemical Modeling

    Energy Science and Technology Software Center

    2010-12-13

    EQ3/6 is a software package for modeling geochemical interactions between aqueous solution, solids, and gases, following principles of chemical thermodynamics and chemical kinetics. It is useful for interpreting aqueiou solution chemical compositions and for calculating the consequences of reaction of such solutions with minerals, other solids, and gases. It is designed to run in a command line environment. EQPT is a thermodynamic data file preprocessor. EQ3NR is a speciation-solubility code. EQ6 is a reaction pathmore » code.« less

  5. Microsoft PowerPoint - SC-0023(SamPosterArmStm09).e.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Algorithm for Deriving Particle Size Distributions for Thin Clouds From Sun and Aureole Measurements Using a Diffraction Approximation J.G. DeVore 1 , A.T. Stair 1 , S.A. Rappaport 1,2 1 Science and Engineering Applications Corporation Burlington, MA 01803 2 Department of Physics, MIT Cambridge, MA 02139 1. Diffraction Approximation Contact: J. DeVore devore@ScEAC.com 781-791-3209 March 08 - SC-0023 2. Key Theoretical Result The differential density of spherical scatterers, n(r) (#/area/µ µ µ

  6. Ecological

    Office of Legacy Management (LM)

    - Consequences of Nuclear Testing Amcl~itka isln,zd has a Iristory of disturbnnce by nroder~r matt, i,rclr~ding US. military operatio~ts on the isla~rd drrring Il'orld ll'nr % n~rterlnthrg the a~tder.qou~rd nuclear tests Nilrow nrrd Cannikin, for which preparation begntr in 1966. nlarry of the. terrestrial distarbnrrces resttlti,tg from ,taclear testing were superimposed o n scars remai~tirrg from the nrilitnry occt~pntiotz. Constrriction, road hirprouement, and the hlilrow an(/ Cnrrnikbt

  7. Fibrous composites comprising carbon nanotubes and silica

    DOEpatents

    Peng, Huisheng; Zhu, Yuntian Theodore; Peterson, Dean E.; Jia, Quanxi

    2011-10-11

    Fibrous composite comprising a plurality of carbon nanotubes; and a silica-containing moiety having one of the structures: (SiO).sub.3Si--(CH.sub.2).sub.n--NR.sub.1R.sub.2) or (SiO).sub.3Si--(CH.sub.2).sub.n--NCO; where n is from 1 to 6, and R.sub.1 and R.sub.2 are each independently H, CH.sub.3, or C.sub.2H.sub.5.

  8. Microsoft Word - BLZhuikov_09_02_2014.docx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Production o f m edical r adioisotopes i n R ussia a nd P rospective Isotope p rogram i n I nstitute o f N uclear R esearch. Dr. B oris L . Z huikov Laboratory o f R adioisotope C omplex, I NR, M oscow, R ussia Institute f or N uclear R esearch o f R ussian A cademy o f S cience ABSTRACT: Reactor and accelerator centers in Russia produce medical isotopes and develop prospective technologies. In the near future, we anticipate increased isotope production for use in nuclear medicine in Russia. T

  9. Quality Assurance Plan, N springs expedited response action

    SciTech Connect

    Jackson, G.J.

    1994-07-01

    This document is the Quality Assurance Plan (QAP) to be followed during the definitive design, construction, and operational phases for activities associated with the N Springs Expedited Response Action (ERA) for the 100-NR-2 Operable Unit (OU). Westinghouse Hanford Company (WHC) will comply with the US Department of Energy (DOE) Order 5700.6C, Quality Assurance (DOE 1989), and the US Environmental Protection Agency (EPA), EPA/530-SW-86-031, Technical Guidance Document: Construction Quality Assurance for Hazardous Waste Land Disposal Facilities (EPA 1986).

  10. Nuclear Navy Turns 50 | National Nuclear Security Administration | (NNSA)

    National Nuclear Security Administration (NNSA)

    Navy Turns 50 Nuclear Navy Turns 50 Washington, DC Crew members of the U.S.S. Enterprise, the first nuclear-powered aircraft carrier, spell out NR-50! To commemorate the 50th anniversary of the Nuclear Navy. Admiral Hyman G. Rickover formed the Nuclear Power Branch within the Navy's Bureau of Ships in August 1948. The Office of Naval Reactors is an integrated organization of DOE and the Department of Navy. The Enterprise's eight A2W nuclear reactors were developed by Bettis Laboratory, with the

  11. Evaluating the solid electrolyte interphase formed on silicon electrodes: A comparison of ex situ X-ray photoelectron spectroscopy and in situ neutron reflectometry

    DOE PAGES [OSTI]

    Doucet, Mathieu; Browning, Jim; Baldwin, J. K.; Winiarz, Jeffrey; Kaiser, Helmut; Taub, H.; Veith, Gabriel M.

    2016-04-15

    This work details the in situ characterization of the interface between a silicon electrode and an electrolyte using a linear fluorinated solvent molecule, 0.1 M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in deuterated dimethyl perfluoroglutarate (d6-PF5M2) (1.87 x 10-2 mS/cm-1). The solid electrolyte interphase (SEI) composition and thickness determined via in situ neutron reflectometry (NR) and ex situ X-ray photoelectron spectroscopy (XPS) were compared. The data show that SEI expansion and contraction (breathing) during electrochemical cycling was observed via both techniques; however, ex situ XPS suggests that the SEI thickness increases during Si lithiation and decreases during delithiation, while in situ NR suggestsmore » the opposite. The most likely cause of this discrepancy is the selective removal of SEI components (top 20 nm of the SEI) during the electrode rinse process, required to remove electrolyte residue prior to ex situ analysis, demonstrating the necessity of performing SEI characterizations in situ.« less

  12. Design, Construction, and Initial Test of High Spatial Resolution Thermometry Arrays for Detection of Surface Temperature Profiles on SRF Cavities in Super Fluid Helium

    SciTech Connect

    Ari Palczewski, Rongli Geng, Grigory Eremeev

    2011-07-01

    We designed and built two high resolution (0.6-0.55mm special resolution [1.1-1.2mm separation]) thermometry arrays prototypes out of the Allen Bradley 90-120 ohm 1/8 watt resistor to measure surface temperature profiles on SRF cavities. One array was designed to be physically flexible and conform to any location on a SRF cavity; the other was modeled after the common G-10/stycast 2850 thermometer and designed to fit on the equator of an ILC (Tesla 1.3GHz) SRF cavity. We will discuss the advantages and disadvantages of each array and their construction. In addition we will present a case study of the arrays performance on a real SRF cavity TB9NR001. TB9NR001 presented a unique opportunity to test the performance of each array as it contained a dual (4mm separation) cat eye defect which conventional methods such as OST (Oscillating Superleak second-sound Transducers) and full coverage thermometry mapping were unable to distinguish between. We will discuss the new arrays ability to distinguish between the two defects and their preheating performance.

  13. Effects of fluid shear stress on polyelectrolyte multilayers by neutron scattering studies

    SciTech Connect

    Singh, Saurabh; Junghans, Ann; Watkins, Erik; Kapoor, Yash; Toomey, Ryan; Majewski, Jaroslaw

    2015-02-17

    The structure of layer-by-layer (LbL) deposited nanofilm coatings consists of alternating polyethylenimine (PEI) and polystyrenesulfonate (PSS) films deposited on a single crystal quartz substrate. LbL-deposited nanofilms were investigated by neutron reflectomery (NR) in contact with water in the static and fluid shear stress conditions. The fluid shear stress was applied through a laminar flow of the liquid parallel to the quartz/polymer interface in a custom-built solid–liquid interface cell. The scattering length density profiles obtained from NR results of these polyelectrolyte multilayers (PEM), measured under different shear conditions, showed proportional decrease of volume fraction of water hydrating the polymers. For the highest shear rate applied (ca. 6800 s–1) the water volume fraction decreased by approximately 7%. The decrease of the volume fraction of water was homogeneous through the thickness of the film. Since there were not any significant changes in the total polymer thickness, it resulted in negative osmotic pressures in the film. The PEM films were compared with the behavior of thin films of thermoresponsive poly(N-isopropylacrylamide) (pNIPAM) deposited via spin-coating. The PEM and pNIPAM differ in their interactions with water molecules, and they showed opposite behaviors under the fluid shear stress. In both cases the polymer hydration was reversible upon the restoration of static conditions. Furthermore, a theoretical explanation is given to explain this difference in the effect of shear on hydration of polymeric thin films.

  14. Electrocatalytic Hydrogen Production by [Ni(7PPh2NH)2]2+: Removing the Distinction Between Endo- and Exo- Protonation Sites

    SciTech Connect

    Brown, Houston JS; Wiese, Stefan; Roberts, John A.; Bullock, R. Morris; Helm, Monte L.

    2015-04-03

    A new Ni(II) complex, [Ni(7PPh2NH)2]2+ (7PPh2NH = 3,6-triphenyl-1-aza-3,6-diphosphacycloheptane) has been synthesized, and its electrochemical properties are reported. The 7PPh2NH ligand features an NH, ensuring properly positioned protonated amine groups (NH+) for electrocatalysis, regardless of whether protonation occurs exo- or endo- to the metal center. The compound is an electrocatalyst for H2 production in the presence of organic acids (pKa range 1013 in CH3CN) with turnover frequencies ranging from 160770 s-1 at overpotentials between 320470 mV, as measured at the half peak potential of the catalytic wave. In stark contrast to [Ni(PR2NR'2)2]2+ and other [Ni(7PPh2NR')]2+ complexes, catalytic turnover frequencies for H2 production by [Ni(7PPh2NH)2]2+ do not show catalytic rate enhancement upon the addition of H2O. This finding supports the assertion that [Ni(7PPh2NH)2]2+ eliminates the distinction between the endo- and exo-protonation isomers. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  15. Hydrogenation-induced edge magnetization in armchair MoS{sub 2} nanoribbon and electric field effects

    SciTech Connect

    Ouyang, Fangping; Yang, Zhixiong; Wu, Nannan; Chen, Yu; Ni, Xiang; Xiong, Xiang

    2014-02-17

    We performed density functional theory study on the electronic and magnetic properties of armchair MoS{sub 2} nanoribbons (AMoS{sub 2}NR) with different edge hydrogenation. Although bare and fully passivated AMoS{sub 2}NRs are nonmagnetic semiconductors, it was found that hydrogenation in certain patterns can induce localized ferromagnetic edge state in AMoS{sub 2}NRs and make AMoS{sub 2}NRs become antiferromagnetic semiconductors or ferromagnetic semiconductors. Electric field effects on the bandgap and magnetic moment of AMoS{sub 2}NRs were investigated. Partial edge hydrogenation can change a small-sized AMoS{sub 2}NR from semiconductor to metal or semimetal under a moderate transverse electric field. Since the rate of edge hydrogenation can be controlled experimentally via the temperature, pressure and concentration of H{sub 2}, our results suggest edge hydrogenation is a useful method to engineer the band structure of AMoS{sub 2}NRs.

  16. Synergistic regulation of the mouse orphan nuclear receptor SHP gene promoter by CLOCK-BMAL1 and LRH-1

    SciTech Connect

    Oiwa, Ako; Kakizawa, Tomoko . E-mail: tkaki@hsp.md.shinshu-u.ac.jp; Miyamoto, Takahide; Yamashita, Koh; Jiang, Wei; Takeda, Teiji; Suzuki, Satoru; Hashizume, Kiyoshi

    2007-02-23

    Small heterodimer partner (SHP; NR0B2) is an orphan nuclear receptor and acts as a repressor for wide variety of nuclear hormone receptors. We demonstrated here that mouse SHP mRNA showed a circadian expression pattern in the liver. Transient transfection of the mSHP promoter demonstrated that CLOCK-BMAL1, core circadian clock components, bound to E-box (CACGTG), and stimulated the promoter activity by 4-fold. Liver receptor homologue-1 (LRH-1; NR5A2) stimulated the mSHP promoter, and CLOCK-BMAL1 synergistically enhanced the LRH-1-mediated transactivation. Interestingly, SHP did not affect the CLOCK-BMAL1-mediated promoter activity, but strongly repressed the synergistic activation of CLOCK-BMAL1 and LRH-1. Furthermore, in vitro pull-down assays revealed the existence of direct protein-protein interaction between LRH-1 and CLOCK. In summary, this study shows that CLOCK-BMAL1, LRH-1 and SHP coordinately regulate the mSHP gene to generate the circadian oscillation. The cyclic expression of mSHP may affect daily activity of other nuclear receptors and contribute to circadian liver functions.

  17. The signaling phospholipid PIP3 creates a new interaction surface on the nuclear receptor SF-1

    SciTech Connect

    Blind, Raymond D.; Sablin, Elena P.; Kuchenbecker, Kristopher M.; Chiu, Hsiu-Ju; Deacon, Ashley M.; Das, Debanu; Fletterick, Robert J.; Ingraham, Holly A.

    2014-10-06

    We previously reported that lipids PI(4,5)P2 (PIP2) and PI(3,4,5)P3 (PIP3) bind NR5A nuclear receptors to regulate their activity. Here, the crystal structures of PIP2 and PIP3 bound to NR5A1 (SF-1) define a new interaction surface that is organized by the solvent-exposed PIPn headgroups. We find that stabilization by the PIP3 ligand propagates a signal that increases coactivator recruitment to SF-1, consistent with our earlier work showing that PIP3 increases SF-1 activity. This newly created surface harbors a cluster of human mutations that lead to endocrine disorders, thus explaining how these puzzling mutations cripple SF-1 activity. Finally, we propose that this new surface acts as a PIP3-regulated interface between SF-1 and coregulatory proteins, analogous to the function of membrane-bound phosphoinositides.

  18. Method Of Signal Amplification In Multi-Chromophore Luminescence Sensors

    DOEpatents

    Levitsky, Igor A.; Krivoshlykov, Sergei G.

    2004-02-03

    A fluorescence-based method for highly sensitive and selective detection of analyte molecules is proposed. The method employs the energy transfer between two or more fluorescent chromophores in a carefully selected polymer matrix. In one preferred embodiment, signal amplification has been achieved in the fluorescent sensing of dimethyl methylphosphonate (DMMP) using two dyes, 3-aminofluoranthene (AM) and Nile Red (NR), in a hydrogen bond acidic polymer matrix. The selected polymer matrix quenches the fluorescence of both dyes and shifts dye emission and absorption spectra relative to more inert matrices. Upon DMMP sorption, the AM fluorescence shifts to the red at the same time the NR absorption shifts to the blue, resulting in better band overlap and increased energy transfer between chromophores. In another preferred embodiment, the sensitive material is incorporated into an optical fiber system enabling efficient excitation of the dye and collecting the fluorescent signal form the sensitive material on the remote end of the system. The proposed method can be applied to multichromophore luminescence sensor systems incorporating N-chromophores leading to N-fold signal amplification and improved selectivity. The method can be used in all applications where highly sensitive detection of basic gases, such as dimethyl methylphosphonate (DMMP), Sarin, Soman and other chemical warfare agents having basic properties, is required, including environmental monitoring, chemical industry and medicine.

  19. Geochemical Modeling Of Aqueous Systems

    Energy Science and Technology Software Center

    1995-09-07

    EQ3/6 is a software package for geochemical modeling of aqueous systems. This description pertains to version 7.2b. It addresses aqueous speciation, thermodynamic equilibrium, disequilibrium, and chemical kinetics. The major components of the package are EQ3NR, a speciation-solubility code, and EQ6 a reaction path code. EQ3NR is useful for analyzing groundwater chemistry data, calculating solubility limits, and determining whether certain reactions are in states of equilibrium or disequilibrium. It also initializes EQ6 calculations. EQ6 models themore » consequences of reacting an aqueous solution with a specified set of reactants (e.g., minerals or waste forms). It can also model fluid mixing and the effects of changes in temperature. Each of five supporting data files contain both standard state and activity coefficient-related data. Three support the use of the Davies or B-dot equations for the activity coefficients; the other two support the use of Pitzer''s equations. The temperature range of the thermodynamic data on the data files varies from 25 degrees C only to 0-300 degrees C.« less

  20. INDEPENDENT TECHNICAL ASSESSMENT OF MANAGEMENT OF STORMWATER AND WASTEWATER AT THE SEPARATIONS PROCESS RESEARCH UNIT (SPRU) DISPOSITION PROJECT, NEW YORK

    SciTech Connect

    Abitz, R.; Jackson, D.; Eddy-Dilek, C.

    2011-06-27

    The U.S. Department of Energy (DOE) is currently evaluating the water management procedures at the Separations Process Research Unit (SPRU). The facility has three issues related to water management that require technical assistance: (1) due to a excessive rainfall event in October, 2010, contaminated water collected in basements of G2 and H2 buildings. As a result of this event, the contractor has had to collect and dispose of water offsite; (2) The failure of a sump pump at a KAPL outfall resulted in a Notice of Violation issued by the New York State Department of Environment and Conservation (NYSDEC) and subsequent Consent Order. On-site water now requires treatment and off-site disposition; and (3) stormwater infiltration has resulted in Strontium-90 levels discharged to the storm drains that exceed NR standards. The contractor has indicated that water management at SPRU requires major staff resources (at least 50 persons). The purpose of this review is to determine if the contractor's technical approach warrants the large number of staff resources and to ensure that the technical approach is compliant and in accordance with federal, state and NR requirements.

  1. Understanding dynamic changes in live cell adhesion with neutron reflectometry

    DOE PAGES [OSTI]

    Junghans, Ann; Waltman, Mary Jo; Smith, Hillary L.; Pocivavsek, Luka; Zebda, Noureddine; Birukov, Konstantin; Viapiano, Mariano; Majewski, Jaroslaw

    2014-12-10

    In this study, neutron reflectometry (NR) was used to examine various live cells' adhesion to quartz substrates under different environmental conditions, including flow stress. To the best of our knowledge, these measurements represent the first successful visualization and quantization of the interface between live cells and a substrate with sub-nanometer resolution. In our first experiments, we examined live mouse fibroblast cells as opposed to past experiments using supported lipids, proteins, or peptide layers with no associated cells. We continued the NR studies of cell adhesion by investigating endothelial monolayers and glioblastoma cells under dynamic flow conditions. We demonstrated that neutronmore » reflectometry is a powerful tool to study the strength of cellular layer adhesion in living tissues, which is a key factor in understanding the physiology of cell interactions and conditions leading to abnormal or disease circumstances. Continuative measurements, such as investigating changes in tumor cell — surface contact of various glioblastomas, could impact advancements in tumor treatments. In principle, this can help us to identify changes that correlate with tumor invasiveness. Pursuit of these studies can have significant medical impact on the understanding of complex biological problems and their effective treatment, e.g. for the development of targeted anti-invasive therapies.« less

  2. Understanding dynamic changes in live cell adhesion with neutron reflectometry

    SciTech Connect

    Junghans, Ann; Waltman, Mary Jo; Smith, Hillary L.; Pocivavsek, Luka; Zebda, Noureddine; Birukov, Konstantin; Viapiano, Mariano; Majewski, Jaroslaw

    2014-12-10

    In this study, neutron reflectometry (NR) was used to examine various live cells' adhesion to quartz substrates under different environmental conditions, including flow stress. To the best of our knowledge, these measurements represent the first successful visualization and quantization of the interface between live cells and a substrate with sub-nanometer resolution. In our first experiments, we examined live mouse fibroblast cells as opposed to past experiments using supported lipids, proteins, or peptide layers with no associated cells. We continued the NR studies of cell adhesion by investigating endothelial monolayers and glioblastoma cells under dynamic flow conditions. We demonstrated that neutron reflectometry is a powerful tool to study the strength of cellular layer adhesion in living tissues, which is a key factor in understanding the physiology of cell interactions and conditions leading to abnormal or disease circumstances. Continuative measurements, such as investigating changes in tumor cell — surface contact of various glioblastomas, could impact advancements in tumor treatments. In principle, this can help us to identify changes that correlate with tumor invasiveness. Pursuit of these studies can have significant medical impact on the understanding of complex biological problems and their effective treatment, e.g. for the development of targeted anti-invasive therapies.

  3. Use of bark-derived pyrolysis oils ass a phenol substitute in structural panel adhesives

    SciTech Connect

    Louisiana Pacific Corp

    2004-03-01

    The main objective of this program was to pilot the world's first commercial-scale production of an acceptable phenol formaldehyde (PF) resin containing natural resin (NR) ingredients, for use as an adhesive in Oriented-Strand Board (OSB) and plywood panel products. Natural Resin products, specifically MNRP are not lignin ''fillers''. They are chemically active, natural phenolics that effectively displace significant amounts of phenol in PF resins, and which are extracted from bark-derived and wood-derived bio-oils. Other objectives included the enhancement of the economics of NR (MNRP) production by optimizing the production of certain Rapid Thermal Processing (RTP{trademark}) byproducts, particularly char and activated carbon. The options were to activate the char for use in waste-water and/or stack gas purification. The preliminary results indicate that RTP{trademark} carbon may ultimately serve as a feedstock for activated carbon synthesis, as a fuel to be used within the wood product mill, or a fuel for an electrical power generating facility. Incorporation of the char as an industrial heat source for use in mill operations was L-P's initial intention for the carbon, and was also of interest to Weyerhaeuser as they stepped into in the project.

  4. Effective detective quantum efficiency for two mammography systems: Measurement and comparison against established metrics

    SciTech Connect

    Salvagnini, Elena; Bosmans, Hilde; Marshall, Nicholas W.; Struelens, Lara

    2013-10-15

    Purpose: The aim of this paper was to illustrate the value of the new metric effective detective quantum efficiency (eDQE) in relation to more established measures in the optimization process of two digital mammography systems. The following metrics were included for comparison against eDQE: detective quantum efficiency (DQE) of the detector, signal difference to noise ratio (SdNR), and detectability index (d′) calculated using a standard nonprewhitened observer with eye filter.Methods: The two systems investigated were the Siemens MAMMOMAT Inspiration and the Hologic Selenia Dimensions. The presampling modulation transfer function (MTF) required for the eDQE was measured using two geometries: a geometry containing scattered radiation and a low scatter geometry. The eDQE, SdNR, and d′ were measured for poly(methyl methacrylate) (PMMA) thicknesses of 20, 40, 60, and 70 mm, with and without the antiscatter grid and for a selection of clinically relevant target/filter (T/F) combinations. Figures of merit (FOMs) were then formed from SdNR and d′ using the mean glandular dose as the factor to express detriment. Detector DQE was measured at energies covering the range of typical clinically used spectra.Results: The MTF measured in the presence of scattered radiation showed a large drop at low spatial frequency compared to the low scatter method and led to a corresponding reduction in eDQE. The eDQE for the Siemens system at 1 mm{sup −1} ranged between 0.15 and 0.27, depending on T/F and grid setting. For the Hologic system, eDQE at 1 mm{sup −1} varied from 0.15 to 0.32, again depending on T/F and grid setting. The eDQE results for both systems showed that the grid increased the system efficiency for PMMA thicknesses of 40 mm and above but showed only small sensitivity to T/F setting. While results of the SdNR and d′ based FOMs confirmed the eDQE grid position results, they were also more specific in terms of T/F selection. For the Siemens system at 20 mm PMMA

  5. DHA down-regulates phenobarbital-induced cytochrome P450 2B1 gene expression in rat primary hepatocytes by attenuating CAR translocation

    SciTech Connect

    Li, C.-C.; Lii, C.-K.; Liu, K.-L.; Yang, J.-J.; Chen, H.-W.

    2007-12-15

    The constitutive androstane receptor (CAR) plays an important role in regulating the expression of detoxifying enzymes, including cytochrome P450 2B (CYP 2B). Phenobarbital (PB) induction of human CYP 2B6 and mouse CYP 2b10 has been shown to be mediated by CAR. Our previous study showed that PB-induced CYP 2B1 expression in rat primary hepatocytes is down-regulated by both n-6 and n-3 polyunsaturated fatty acids (PUFAs), especially docosahexaenoic acid (DHA); however, the mechanism for this down-regulation by DHA was previously unknown. The objective of the present study was to determine whether change in CAR translocation is involved in the down-regulation by n-6 and n-3 PUFAs of PB-induced CYP 2B1 expression in rat primary hepatocytes. We used 100 {mu}M arachidonic acid, linoleic acid, eicosapentaenoic acid, and DHA to test this hypothesis. PB triggered the translocation of CAR from the cytosol into the nucleus in a dose-dependent and time-dependent manner in our hepatocyte system, and the CAR distribution in rat primary hepatocytes was significantly affected by DHA. DHA treatment decreased PB-inducible accumulation of CAR in the nuclear fraction and increased it in the cytosolic fraction in a dose-dependent manner. The down-regulation of CYP 2B1 expression by DHA occurred in a dose-dependent manner, and a similar pattern was found for the nuclear accumulation of CAR. The results of immunoprecipitation showed a CAR/RXR heterodimer bound to nuclear receptor binding site 1 (NR-1) of the PB-responsive enhancer module (PBREM) of the CYP 2B1gene. The EMSA results showed that PB-induced CAR binding to NR-1 was attenuated by DHA. Taken together, these results suggest that attenuation of CAR translocation and decreased subsequent binding to NR-1 are involved in DHA's down-regulation of PB-induced CYP 2B1 expression.

  6. NRC antitrust licensing actions, 1978--1996

    SciTech Connect

    Mayer, S.J.; Simpson, J.J.

    1997-09-01

    NUREG-0447, Antitrust Review of Nuclear Power Plants, was published in May 1978 and includes a compilation and discussion of U.S. Nuclear Regulatory Commission (NRC) proceedings and activity involving the NRC`s competitive review program through February 1978, NUREG-0447 is an update of an earlier discussion of the NRC`s antitrust review of nuclear power plants, NR-AIG-001, The US Nuclear Regulatory Commission`s Antitrust Review of Nuclear Power Plants: The Conditioning of Licenses, which reviewed the Commission`s antitrust review function from its inception in December 1970 through April 1976. This report summarizes the support provided to NRC staff in updating the compilation of the NRC`s antitrust licensing review activities for commercial nuclear power plants that have occurred since February 1978. 4 refs., 4 tabs.

  7. Hazard analysis for 300 Area N Reactor Fuel Fabrication and Storage Facilty

    SciTech Connect

    Johnson, D.J.; Brehm, J.R.

    1994-01-25

    This hazard analysis (HA) has been prepared for the 300 Area N Reactor Fuel Fabrication and Storage Facility (Facility), in compliance with the requirements of Westinghouse Hanford Company (Westinghouse Hanford) controlled manual WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual, and to the direction of WHC-IP-0690, Safety Analysis and Regulation Desk Instructions, (WHC 1992). An HA identifies potentially hazardous conditions in a facility and the associated potential accident scenarios. Unlike the Facility hazard classification documented in WHC-SD-NR-HC-004, Hazard Classification for 300 Area N Reactor Fuel Fabrication and Storage Facility, (Huang 1993), which is based on unmitigated consequences, credit is taken in an HA for administrative controls or engineered safety features planned or in place. The HA is the foundation for the accident analysis. The significant event scenarios identified by this HA will be further evaluated in a subsequent accident analysis.

  8. Seeded Growth of Monodisperse Gold Nanorods Using Bromide-Free Surfactant Mixtures

    SciTech Connect

    Ye, XC; Gao, YZ; Chen, J; Reifsnyder, DC; Zheng, C; Murray, CB

    2013-05-01

    We demonstrate for the first time that monodisperse gold nanorods (NRs) with broadly tunable dimensions and longitudinal surface plasmon resonances can be synthesized using a bromide-free surfactant mixture composed of alkyltrimethylammonium chloride and sodium oleate. It is found that uniform gold NRs can be obtained even with an iodide concentration approaching 100 mu M in the growth solution. In contrast to conventional wisdom, our results provide conclusive evidence that neither bromide as the surfactant counterion nor a high concentration of bromide ions in the growth solution is essential for gold NR formation. Correlated electron microscopy study of three-dimensional structures of gold NRs reveals a previously unprecedented octagonal prismatic structure enclosed predominantly by high index {310} crystal planes. These findings should have profound implications for a comprehensive mechanistic understanding of seeded growth of anisotropic metal nanocrystals.

  9. Biaxial Creep Specimen Fabrication

    SciTech Connect

    JL Bump; RF Luther

    2006-02-09

    This report documents the results of the weld development and abbreviated weld qualification efforts performed by Pacific Northwest National Laboratory (PNNL) for refractory metal and superalloy biaxial creep specimens. Biaxial creep specimens were to be assembled, electron beam welded, laser-seal welded, and pressurized at PNNL for both in-pile (JOYO reactor, O-arai, Japan) and out-of-pile creep testing. The objective of this test campaign was to evaluate the creep behavior of primary cladding and structural alloys under consideration for the Prometheus space reactor. PNNL successfully developed electron beam weld parameters for six of these materials prior to the termination of the Naval Reactors program effort to deliver a space reactor for Project Prometheus. These materials were FS-85, ASTAR-811C, T-111, Alloy 617, Haynes 230, and Nirnonic PE16. Early termination of the NR space program precluded the development of laser welding parameters for post-pressurization seal weldments.

  10. Ab initio investigation of electronic and vibrational contributions to linear and nonlinear dielectric properties of ice

    SciTech Connect

    Casassa, S.; Baima, J.; Mahmoud, A.; Kirtman, B.

    2014-06-14

    Electronic and vibrational contributions to the static and dynamic (hyper)polarizability tensors of ice XI and model structures of ordinary hexagonal ice have been theoretically investigated. Calculations were carried out by the finite field nuclear relaxation method for periodic systems (FF-NR) recently implemented in the CRYSTAL code, using the coupled-perturbed Kohn-Sham approach (CPKS) for evaluating the required electronic properties. The effect of structure on the static electronic polarizabilities (dielectric constants) and second-hyperpolarizabilities is minimal. On the other hand, the vibrational contributions to the polarizabilities were found to be significant. A reliable evaluation of these (ionic) contributions allows one to discriminate amongst ice phases characterized by different degrees of proton-order, primarily through differences caused by librational motions. Transverse static and dynamic vibrational (hyper)polarizabilities were found by extrapolating calculations for slabs of increasing size, in order to eliminate substantial surface contributions.

  11. Electromagnetic radiation absorbers and modulators comprising polyaniline

    DOEpatents

    Epstein, Arthur J.; Ginder, John M.; Roe, Mitchell G.; Hajiseyedjavadi, Hamid

    1992-01-01

    A composition for absorbing electromagnetic radiation, wherein said electromagnetic radiation possesses a wavelength generally in the range of from about 1000 Angstroms to about 50 meters, wherein said composition comprises a polyaniline composition of the formula ##STR1## where y can be equal to or greater than zero, and R.sup.1 and R.sup.2 are independently selected from the group containing of H, --OCH.sub.3, --CH.sub.3, --F, --Cl, --Br, --I, NR.sup.3 .sub.2, --NHCOR.sup.3, --OH, --O.sup.-, SR.sup.3, --OCOR.sup.3, --NO.sub.2, --COOH, --COOR.sup.3, --COR.sup.3, --CHO, and --CN, where R.sup.3 is a C.sub.1 to C.sub.8 alkyl, aryl or aralkyl group.

  12. Infrared photoemitting diode having reduced work function

    DOEpatents

    Hirschfeld, T.B.

    1982-05-06

    In electro-optical detectors which include as elements a photoemitting photocathode and anode, a photoemitting diode is fabricated which lowers the diode's work function, thus reducing the cooling requirement typically needed for this type of device. The work function is reduced by sandwiching between the photocathode and anode a liquid meidum of the formula NR/sub 3/ and having an electron affinity for the electrons of the photocathode, which liquid medium permits free electrons leaving the photocathode to remain as stable solvated species in the liquid medium. Thus, highly light-absorbent, and therefore thin, metallic layers can be used for detection, thereby reducing dark current at a given temperature, with a consequent reduction in cooling requirements at constant detector performance.

  13. Infrared photoemitting diode having reduced work function

    DOEpatents

    Hirschfeld, Tomas B.

    1984-01-01

    In electro-optical detectors which include as elements a photoemitting photocathode and anode, a photoemitting diode is fabricated which lowers the diode's work function, thus reducing the cooling requirement typically needed for this type of device. The work function is reduced by sandwiching between the photocathode and anode a liquid medium of the formula NR.sub.3 and having an electron affinity for the electrons of the photocathode, which liquid medium permits free electrons leaving the photocathode to remain as stable solvated species in the liquid medium. Thus, highly light-absorbent, and therefore thin, metallic layers can be used for detection, thereby reducing dark current at a given temperature, with a consequent reduction in cooling requirements at constant detector performance.

  14. Resolution of Surveillance Report No. PAD-BDW-95-004 for suspect bolts installed in the 105 KW roof addition structure

    SciTech Connect

    Frier, W.A.

    1995-04-14

    A DOE RL surveillance determined that a test report (WHC-SD-NR-TRP-020) was less than adequate. As a result, WHC removed nine of the previous in-situ tested A325 suspect bolts and contracted with Koon-Hall Testing Corporation to perform hardness and tensile testing and chemical composition analysis of the removed bolts. WHC also contracted with ADVENT Engineering, Inc., to perform an evaluation of the Koon-Hall test results and to respond to the concerns identified in the DOE RL surveillance. The Koon-Hall Laboratory test results and the assessments strongly support the conclusion that the suspect bolts are indeed the equivalent of A325 high-strength, Type-1 bolts and have been properly heat-treated.

  15. Coupling reactions of phenylacetylene with water, hydrogen sulfide and primary amines mediated by a Ru(II) phenylvinylidene complex

    SciTech Connect

    Bianchini, C.; Peruzzini, M.; Zanobini, F. [Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, Florence (Italy)] [and others

    1995-12-31

    The Ru(II) fragment [(PNP)RuCl{sub 2}] assists the reaction of phenylacetylene with water, hydrogen sulfide and primary amines to give carbonyl, {eta}{sup 1}-benzylthioaldehyde, and isonitrile complexes, respectively [PNP = CH{sub 3}CH{sub 2}CH{sub 2}N(CH{sub 2}CH{sub 2}PPh{sub 2}){sub 2}]. In all of these processes, the reaction is initiated by the 1-alkyne to vinylidene tautomerization at the Ru(II) center, followed by attack of the H{sub 2}Z molecule (Z = O, S, NR) on the vinylidene ligand. The mechanisms which account for these transformations have been completely elucidated and several of the intermediates in these reactions have been isolated and fully characterized. The scope of these reactions in view of their potential applications in organic syntheses involving thioaldehydes and optically pure isonitriles will be briefly presented.

  16. Effects of fluid shear stress on polyelectrolyte multilayers by neutron scattering studies

    DOE PAGES [OSTI]

    Singh, Saurabh; Junghans, Ann; Watkins, Erik; Kapoor, Yash; Toomey, Ryan; Majewski, Jaroslaw

    2015-02-17

    The structure of layer-by-layer (LbL) deposited nanofilm coatings consists of alternating polyethylenimine (PEI) and polystyrenesulfonate (PSS) films deposited on a single crystal quartz substrate. LbL-deposited nanofilms were investigated by neutron reflectomery (NR) in contact with water in the static and fluid shear stress conditions. The fluid shear stress was applied through a laminar flow of the liquid parallel to the quartz/polymer interface in a custom-built solid–liquid interface cell. The scattering length density profiles obtained from NR results of these polyelectrolyte multilayers (PEM), measured under different shear conditions, showed proportional decrease of volume fraction of water hydrating the polymers. For themore » highest shear rate applied (ca. 6800 s–1) the water volume fraction decreased by approximately 7%. The decrease of the volume fraction of water was homogeneous through the thickness of the film. Since there were not any significant changes in the total polymer thickness, it resulted in negative osmotic pressures in the film. The PEM films were compared with the behavior of thin films of thermoresponsive poly(N-isopropylacrylamide) (pNIPAM) deposited via spin-coating. The PEM and pNIPAM differ in their interactions with water molecules, and they showed opposite behaviors under the fluid shear stress. In both cases the polymer hydration was reversible upon the restoration of static conditions. Furthermore, a theoretical explanation is given to explain this difference in the effect of shear on hydration of polymeric thin films.« less

  17. Nuclear structure studies with ([ital e],[ital e][prime]), ([pi],[pi][prime]), and ([gamma],[pi]) reactions: Applications to [sup 10]B

    SciTech Connect

    Sato, T.; Odagawa, N.; Ohtsubo, H. ); Lee, T.H. )

    1994-02-01

    Theoretical approaches for investigating nuclear structure with ([ital e],[ital e][prime]), ([pi],[pi][prime]), and ([gamma],[pi]) reactions are presented and applied to study the shell-model description of [sup 10]B. The distorted wave impulse approximation formulated in momentum space is used to calculate the cross sections of ([pi],[pi][prime]) and ([gamma],[pi]) reactions from the [pi][ital N][r arrow][pi][ital N] and [pi][ital N][r arrow][gamma][ital N] off-shell amplitudes which are generated from the model of Nozawa, Blankleider, and Lee[1]. It is found that the nonlocal effects due to [pi][ital N] off-shell dynamics and nucleon Fermi motion are important in predicting ([gamma],[pi]) cross sections. The one-pion-exchange two-body exchange currents are included in ([ital e],[ital e][prime]) calculations. It is shown that the core polarization effects, calculated in a perturbation approach including excitations up to 6[h bar][omega], are essential in obtaining quantitative agreements with the data with no adjustable parameters. The predictions based on the shell model of Cohen and Kurath [2] and Hague and Maripuu [3] are compared in order to illustrate the use of ([ital e],[ital e][prime]), ([pi],[pi][prime]), and ([gamma],[pi]) reactions in distinguishing nuclear structure theories which are almost equivalent in describing static properties in nuclei. Predictions for future ([ital e],[ital e][prime]) and ([gamma],[pi]) experiments are also presented.

  18. Interfacial morphology of low-voltage anodic aluminium oxide

    SciTech Connect

    Hu, Naiping; Dongcinn, Xuecheng; He, Xueying; Argekar, Sandip; Zhang, Yan; Browning, Jim; Schaefer, Dale

    2013-01-01

    X-ray reflectivity (XRR) and neutron reflectivity (NR), as well as ultra-smallangle X-ray scattering (USAXS), are used to examine the in-plane and surfacenormal structure of anodic films formed on aluminium alloy AA2024 and pure aluminium. Aluminium and alloy films up to 3500 A thick were deposited on Si wafers by electron beam evaporation of ingots. Porous anodic aluminium oxide (AAO) films are formed by polarizing at constant voltage up to 20 V noble to the open circuit potential. The voltage sweet spot (5 V) appropriate for constant-voltage anodization of such thin films was determined for both alloy and pure Al. In addition, a new concurrent voltage- and current-control protocol was developed to prepare films with larger pores (voltages higher than 5 V), but formed at a controlled current so that pore growth is slow enough to avoid stripping the aluminium substrate layer. USAXS shows that the pore size and interpore spacing are fixed in the first 10 s after initiation of anodization. Pores then grow linearly in time, at constant radius and interpore spacing. Using a combination of XRR and NR, the film density and degree of hydration of the films were determined from the ratio of scattering length densities. Assuming a chemical formula Al2O3xH2O, it was found that x varies from 0.29 for the native oxide to 1.29 for AAO grown at 20 V under concurrent voltage and current control. The average AAO film density of the porous film at the air surface is 2.45 (20) g cm3. The density of the barrier layer at the metal interface is 2.9 (4) g cm3, which indicates that this layer is also quite porous

  19. EQPT, a data file preprocessor for the EQ3/6 software package: User`s guide and related documentation (Version 7.0); Part 2

    SciTech Connect

    Daveler, S.A.; Wolery, T.J.

    1992-12-17

    EQPT is a data file preprocessor for the EQ3/6 software package. EQ3/6 currently contains five primary data files, called datao files. These files comprise alternative data sets. These data files contain both standard state and activity coefficient-related data. Three (com, sup, and nea) support the use of the Davies or B-dot equations for the activity coefficients; the other two (hmw and pit) support the use of Pitzer`s (1973, 1975) equations. The temperature range of the thermodynamic data on these data files varies from 25{degrees}C only to 0-300{degrees}C. The principal modeling codes in EQ3/6, EQ3NR and EQ6, do not read a data0 file, however. Instead, these codes read an unformatted equivalent called a data1 file. EQPT writes a datal file, using the corresponding data0 file as input. In processing a data0 file, EQPT checks the data for common errors, such as unbalanced reactions. It also conducts two kinds of data transformation. Interpolating polynomials are fit to data which are input on temperature adds. The coefficients of these polynomials are then written on the datal file in place of the original temperature grids. A second transformation pertains only to data files tied to Pitzer`s equations. The commonly reported observable Pitzer coefficient parameters are mapped into a set of primitive parameters by means of a set of conventional relations. These primitive form parameters are then written onto the datal file in place of their observable counterparts. Usage of the primitive form parameters makes it easier to evaluate Pitzer`s equations in EQ3NR and EQ6. EQPT and the other codes in the EQ3/6 package are written in FORTRAN 77 and have been developed to run under the UNIX operating system on computers ranging from workstations to supercomputers.

  20. Effect of number of stack on the thermal escape and non-radiative and radiative recombinations of photoexcited carriers in strain-balanced InGaAs/GaAsP multiple quantum-well-inserted solar cells

    SciTech Connect

    Aihara, Taketo; Fukuyama, Atsuhiko; Ikari, Tetsuo; Suzuki, Hidetoshi; Fujii, Hiromasa; Nakano, Yoshiaki; Sugiyama, Masakazu

    2015-02-28

    Three non-destructive methodologies, namely, surface photovoltage (SPV), photoluminescence, and piezoelectric photothermal (PPT) spectroscopies, were adopted to detect the thermal carrier escape from quantum well (QW) and radiative and non-radiative carrier recombinations, respectively, in strain-balanced InGaAs/GaAsP multiple-quantum-well (MQW)-inserted GaAs p-i-n solar cell structure samples. Although the optical absorbance signal intensity was proportional to the number of QW stack, the signal intensities of the SPV and PPT methods decreased at high number of stack. To explain the temperature dependency of these signal intensities, we proposed a model that considers the three carrier dynamics: the thermal escape from the QW, and the non-radiative and radiative carrier recombinations within the QW. From the fitting procedures, it was estimated that the activation energies of the thermal escape ΔE{sub barr} and non-radiative recombination ΔE{sub NR} were 68 and 29 meV, respectively, for a 30-stacked MQW sample. The estimated ΔE{sub barr} value agreed well with the difference between the first electron subband and the top of the potential barrier in the conduction band. We found that ΔE{sub barr} remained constant at approximately 70 meV even with increasing QW stack number. However, the ΔE{sub NR} value monotonically increased with the increase in the number of stack. Since this implies that non-radiative recombination becomes improbable as the number of stack increases, we found that the radiative recombination probability for electrons photoexcited within the QW increased at a large number of QW stack. Additional processes of escaping and recapturing of carriers at neighboring QW were discussed. As a result, the combination of the three non-destructive methodologies provided us new insights for optimizing the MQW components to further improve the cell performance.

  1. Alkali metal yttrium neo-pentoxide double alkoxide precursors to alkali metal yttrium oxide nanomaterials

    DOE PAGES [OSTI]

    Boyle, Timothy J.; Neville, Michael L.; Sears, Jeremiah Matthew; Cramer, Roger

    2016-03-15

    In this study, a series of alkali metal yttrium neo-pentoxide ([AY(ONep)4]) compounds were developed as precursors to alkali yttrium oxide (AYO2) nanomaterials. The reaction of yttrium amide ([Y(NR2)3] where R=Si(CH3)3) with four equivalents of H-ONep followed by addition of [A(NR2)] (A=Li, Na, K) or Ao (Ao=Rb, Cs) led to the formation of a complex series of AnY(ONep)3+n species, crystallographically identified as [Y2Li3(μ3-ONep)(μ3-HONep)(μ-ONep)5(ONep)3(HONep)2] (1), [YNa2(μ3-ONep)4(ONep)]2 (2), {[Y2K3(μ3-ONep)3(μ-ONep)4(ONep)2(ηξ-tol)2][Y4K2(μ4-O)(μ3-ONep)8(ONep)4]•ηx-tol]} (3), [Y4K2(μ4-O)(μ3-ONep)8(ONep)4] (3a), [Y2Rb3(μ4-ONep)3(μ-ONep)6] (4), and [Y2Cs4(μ6-O)(μ3-ONep)6(μ3-HONep)2(ONep)2(ηx-tol)4]•tol (5). Compounds 1–5 were investigated as single source precursors to AYOx nanomaterials following solvothermal routes (pyridine, 185 °C for 24h). The final products after thermal processing weremore » found by powder X-ray diffraction experiments to be Y2O3 with variable sized particles based on transmission electron diffraction. Energy dispersive X-ray spectroscopy studies indicated that the heavier alkali metal species were present in the isolated nanomaterials.« less

  2. Atmospheric Radiation Measurement Program Climate Research Facility Operation quarterly report July 1 - September 30, 2010.

    SciTech Connect

    Sisterson, D. L.

    2010-10-26

    individual instrument uptime. Thus, the average percentage of data in the Archive represents the average percentage of the time (24 hours per day, 92 days for this quarter) that the instruments were operating this quarter. Table 1 shows the accumulated maximum operation time (planned uptime), actual hours of operation, and variance (unplanned downtime) for the period July 1-September 30, 2010, for the fixed sites. Because the AMF operates episodically, the AMF statistics are reported separately and not included in the aggregate average with the fixed sites. This fourth quarter comprises a total of 2208 possible hours for the fixed and mobile sites. The average of the fixed sites exceeded our goal this quarter. The Site Access Request System is a web-based database used to track visitors to the fixed and mobile sites, all of which have facilities that can be visited. The NSA locale has the Barrow and Atqasuk sites. The SGP site has historically had a Central Facility, 23 extended facilities, 4 boundary facilities, and 3 intermediate facilities. Beginning in the second quarter of FY2010, the SGP began a transition to a smaller footprint (150 km x 150 km) by rearranging the original instrumentation and new instrumentation made available through the American Recovery and Reinvestment Act of 2009 (ARRA). The Central Facility and 4 extended facilities will remain, but there will be up to 12 new surface characterization facilities, 4 radar facilities, and 3 profiler facilities sited in the smaller domain. This new configuration will provide observations at scales more appropriate to current and future climate models. The transition to the smaller footprint is ongoing through this quarter. The TWP locale has the Manus, Nauru, and Darwin sites. These sites will also have expanded measurement capabilities with the addition of new instrumentation made available through ARRA funds. It is anticipated that the new instrumentation at all the fixed sites will be in place by the end of

  3. 100-N Area Strontium-90 Treatability Demonstration Project: Phytoextraction Along the 100-N Columbia River Riparian Zone – Field Treatability Study

    SciTech Connect

    Fellows, Robert J.; Fruchter, Jonathan S.; Driver, Crystal J.; Ainsworth, Calvin C.

    2010-01-11

    Strontium-90 (90Sr) is present both in the aquifer near the river and in the vadose and riparian zones of the river’s shore at 100-NR-2. Phytoextraction of 90Sr is being considered as a potential remediation system along the riparian zone of the Columbia River. Phytoextraction would employ coyote willow (Salix exigua). Past studies have shown that willow roots share uptake mechanisms for Sr with Ca, a plant macronutrient as well as no discrimination between Sr and 90Sr. Willow 90Sr concentration ratios [CR’s; (pCi 90Sr/g dry wt. of new growth tissue)/(pCi 90Sr/g soil porewater)] were consistently greater than 65 with three-quarters of the assimilated label partitioned into the above ground shoot. Insect herbivore experiments also demonstrated no significant potential for bioaccumulation or food chain transfer from their natural activities. The objectives of this field study were three-fold: (1) to demonstrate that a viable, “managed” plot of coyote willows can be established on the shoreline of the Columbia River that would survive the same microenvironment to be encountered at the 100-NR-2 shoreline; (2) to show through engineered barriers that large and small animal herbivores can be prevented from feeding on these plants; and (3) to show that once established, the plants will provide sufficient biomass annually to support the phytoextraction technology. A field treatability demonstration plot was established on the Columbia River shoreline alongside the 100-K West water intake at the end of January 2007. The plot was delimited by a 3.05 m high chain-link fence and was approximately 10 x 25 m in size. A layer of fine mesh metal small animal screening was placed around the plot at the base of the fencing to a depth of 45 cm. A total of sixty plants were placed in six slightly staggered rows with 1-m spacing between plants. The actual plot size was 0.00461 hectare (ha). At the time of planting (March 12, 2007), the plot was located about 10 m from the

  4. WE-A-17A-05: Differences in Applicator Configuration and Dwell Loading Between Standard and Image-Guided Tandem and Ring (T and R) HDR Brachytherapy

    SciTech Connect

    Damato, A; Cormack, R; Bhagwat, M; Buzurovic, I; Lee, L; Viswanathan, A

    2014-06-15

    Purpose: To investigate differences in: (i) relative location of the tandem and the ring compared to a rigid standard applicator model; and (ii) relative loading and changes in loading pattern between standard and image-guided planning. Methods: All T and R insertions performed in 2013 in our institution under CT- or MR-guidance were analyzed. Standard plans were generated using library applicator models with a fixed relationship between ring and tandem, standardized uniform dwell loading and normalization to point A. The graphic plans and the associated standard-plan dwell configurations were compared: the rings were rigidly registered, and the residual tandem shift, rotation and maximum distance between plan tandem dwell and corresponding model tandem dwell were calculated. The normalization ratio (NR = the ratio of graphic versus standard-plan total reference air kerma [TRAK]), the general loading difference (GLD = the difference between graphic and standard ratios of the tandem versus the ring TRAK), and the percent standard deviation (SD% = SD/mean) of the tandem and the ring TRAK for the graphic plan (all standard-plans SD% = 0) were calculated. Results: 71 T and R were analyzed. Residual tandem shift, rotation and maximum corresponding dwell distance were 1.2±0.8mm (0.4±0.4mm lateral, 0.9±0.8mm craniocaudal, 0.4±0.3mm anterior-posterior), 2.3±1.9deg and 3.4±2.3mm. NR was 0.86±0.11 indicating a lower overall loading of the graphic compared to the standard plans. GLD was -0.12±0.16 indicating a modest increased ring loading relative to the tandem in the graphic plans. SD% was 2.1±1.6% for tandem and 2.8±1.9% for ring, indicating small deviations from uniform loading. Conclusion: Variability in the relative locations of the tandem and the ring necessitates the independent registration of each component model for accurate digitization. Our clinical experience suggests that graphically planned T and R results on average in a lower total dose to the

  5. Electronic and magnetic properties of armchair MoS{sub 2} nanoribbons under both external strain and electric field, studied by first principles calculations

    SciTech Connect

    Hu, Ting; Dong, Jinming; Zhou, Jian; Kawazoe, Yoshiyuki

    2014-08-14

    The electronic and magnetic properties of armchair edge MoS{sub 2} nanoribbons (MoS{sub 2}-ANRs) underboth the external strain and transverse electric field (E{sub t}) have been systematically investigated by using the first-principles calculations. It is found that: (1) If no electric field is applied, an interesting structural phase transition would appear under a large tensile strain, leading to a new phase MoS{sub 2}-A'NR, and inducing a big jump peak of the band gap in the transition region. But, the band gap response to compressive strains is much different from that to tensile strain, showing no the structural phase transition. (2) Under the small tensile strains (<10%), the combined E{sub t} and tensile strain give rise to a positive superposition (resonant) effect on the band gap reduction at low E{sub t} (<3 V/nm), and oppositely a negative superposition (antiresonant) one at high E{sub t} (>4 V/nm). On the other hand, the external compressive strains have always presented the resonant effect on the band gap reduction, induced by the electric field. (3) After the structural phase transition, an external large tensile strain could greatly reduce the critical field E{sub tc} causing the band gap closure, and make the system become a ferromagnetic (FM) metal at a relative low E{sub t} (e.g., <4 V/nm), which is very helpful for its promising applications in nano-mechanical spintronics devices. (4) At high E{sub t} (>10 V/nm), the magnetic moments of both the MoS{sub 2}-ANR and MoS{sub 2}-A'NR in their FM states could be enhanced greatly by a tensile strain. Our numerical results of effectively tuning physical properties of MoS{sub 2}-ANRs by combined external strain and electric field may open their new potential applications in nanoelectronics and spintronics.

  6. Sex-related differences in murine hepatic transcriptional and proteomic responses to TCDD

    SciTech Connect

    Prokopec, Stephenie D.; Watson, John D.; Lee, Jamie; Pohjanvirta, Raimo; Boutros, Paul C.

    2015-04-15

    2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is an environmental contaminant that produces myriad toxicities in most mammals. In rodents alone, there is a huge divergence in the toxicological response across species, as well as among different strains within a species. But there are also significant differences between males and females animals of a single strain. These differences are inconsistent across model systems: the severity of toxicity is greater in female rats than males, while male mice and guinea pigs are more sensitive than females. Because the specific events that underlie this difference remain unclear, we characterized the hepatic transcriptional response of adult male and female C57BL/6 mice to 500 μg/kg TCDD at multiple time-points. The transcriptional profile diverged significantly between the sexes. Female mice demonstrated a large number of altered transcripts as early as 6 h following treatment, suggesting a large primary response. Conversely, male animals showed the greatest TCDD-mediated response 144 h following exposure, potentially implicating significant secondary responses. Nr1i3 was statistically significantly induced at all time-points in the sensitive male animals. This mRNA encodes the constitutive androstane receptor (CAR), a transcription factor involved in the regulation of xenobiotic metabolism, lipid metabolism, cell cycle and apoptosis. Surprisingly though, changes at the protein level (aside from the positive control, CYP1A1) were modest, with only FMO3 showing clear induction, and no genes with sex-differences. Thus, while male and female mice show transcriptional differences in their response to TCDD, their association with TCDD-induced toxicities remains unclear. - Highlights: • Differences exist between the toxicity phenotypes to TCDD in male and female mice. • TCDD-mediated transcriptomic differences were identified between the sexes. • Resistant female mice displayed a large, early-onset, transcriptomic response.

  7. Opposing regulation of cytochrome P450 expression by CAR and PXR in hypothyroid mice

    SciTech Connect

    Park, Young Joo; Lee, Eun Kyung; Lee, Yoon Kwang; Park, Do Joon; Jang, Hak Chul; Moore, David D.

    2012-09-01

    Clinical hypothyroidism affects various metabolic processes including drug metabolism. CYP2B and CYP3A are important cytochrome P450 drug metabolizing enzymes that are regulated by the xenobiotic receptors constitutive androstane receptor (CAR, NR1I3) and pregnane X receptor (PXR, NR1I2). We evaluated the regulation of the hepatic expression of CYPs by CAR and PXR in the hypothyroid state induced by a low-iodine diet containing 0.15% propylthiouracil. Expression of Cyp3a11 was suppressed in hypothyroid C57BL/6 wild type (WT) mice and a further decrement was observed in hypothyroid CAR{sup −/−} mice, but not in hypothyroid PXR{sup −/−} mice. In contrast, expression of Cyp2b10 was induced in both WT and PXR{sup −/−} hypothyroid mice, and this induction was abolished in CAR{sup −/−} mice and in and CAR{sup −/−} PXR{sup −/−} double knockouts. CAR mRNA expression was increased by hypothyroidism, while PXR expression remained unchanged. Carbamazepine (CBZ) is a commonly used antiepileptic that is metabolized by CYP3A isoforms. After CBZ treatment of normal chow fed mice, serum CBZ levels were highest in CAR{sup −/−} mice and lowest in WT and PXR{sup −/−} mice. Hypothyroid WT or PXR{sup −/−} mice survived chronic CBZ treatment, but all hypothyroid CAR{sup −/−} and CAR{sup −/−} PXR{sup −/−} mice died, with CAR{sup −/−}PXR{sup −/−} mice surviving longer than CAR{sup −/−} mice (12.3 ± 3.3 days vs. 6.3 ± 2.1 days, p = 0.04). All these findings suggest that hypothyroid status affects xenobiotic metabolism, with opposing responses of CAR and PXR and their CYP targets that can cancel each other out, decreasing serious metabolic derangement in response to a xenobiotic challenge. -- Highlights: ► Hypothyroid status activates CAR in mice and induces Cyp2b10 expression. ► Hypothyroid status suppresses PXR activity in mice and represses Cyp3a11 expression. ► These responses balance each other out in normal mice.

  8. Prenatal PCBs disrupt early neuroendocrine development of the rat hypothalamus

    SciTech Connect

    Dickerson, Sarah M.; Cunningham, Stephanie L.; Gore, Andrea C.

    2011-04-01

    Neonatal exposure to endocrine disrupting chemicals (EDCs) such as polychlorinated biphenyls (PCBs) can interfere with hormone-sensitive developmental processes, including brain sexual differentiation. We hypothesized that disruption of these processes by gestational PCB exposure would be detectable as early as the day after birth (postnatal day (P) 1) through alterations in hypothalamic gene and protein expression. Pregnant Sprague-Dawley rats were injected twice, once each on gestational days 16 and 18, with one of the following: DMSO vehicle; the industrial PCB mixture Aroclor 1221 (A1221); a reconstituted mixture of the three most prevalent congeners found in humans, PCB138, PCB153, and PCB180; or estradiol benzoate (EB). On P1, litter composition, anogenital distance (AGD), and body weight were assessed. Pups were euthanized for immunohistochemistry of estrogen receptor {alpha} (ER{alpha}) or TUNEL labeling of apoptotic cells or quantitative PCR of 48 selected genes in the preoptic area (POA). We found that treatment with EB or A1221 had a sex-specific effect on developmental apoptosis in the neonatal anteroventral periventricular nucleus (AVPV), a sexually dimorphic hypothalamic region involved in the regulation of reproductive neuroendocrine function. In this region, exposed females had increased numbers of apoptotic nuclei, whereas there was no effect of treatment in males. For ER{alpha}, EB treatment increased immunoreactive cell numbers and density in the medial preoptic nucleus (MPN) of both males and females, while A1221 and the PCB mixture had no effect. PCR analysis of gene expression in the POA identified nine genes that were significantly altered by prenatal EDC exposure, in a manner that varied by sex and treatment. These genes included brain-derived neurotrophic factor, GABA{sub B} receptors-1 and -2, IGF-1, kisspeptin receptor, NMDA receptor subunits NR2b and NR2c, prodynorphin, and TGF{alpha}. Collectively, these results suggest that the

  9. Recyclable catalysts methods of making and using the same

    DOEpatents

    Dioumaev, Vladimir K.; Bullock, R. Morris

    2006-02-28

    Organometallic complexes are provided, which include a catalyst containing a transition metal, a ligand and a component having the formula GAr.sup.F. Ar.sup.F is an aromatic ring system selected from phenyl, naphthalenyl, anthracenyl, fluorenyl, or indenyl. The aromatic ring system has at least a substituent selected from fluorine, hydrogen, hydrocarbyl or fluorinated hydrocarbyl, G is substituted or unsubstituted (CH.sub.2).sub.n or (CF.sub.2).sub.n, wherein n is from 1 to 30, wherein further one or more CH.sub.2 or CF.sub.2 groups are optionally replaced by NR, PR, SiR.sub.2, BR, O or S, or R is hydrocarbyl or substituted hydrocarbyl, GAr.sup.F being covalently bonded to either said transition metal or said ligand of said catalyst, thereby rendering said cationic organometallic complex liquid. The catalyst of the organometallic complex can be [CpM(CO).sub.2(NHC)L.sub.k].sup.+A.sup.-, wherein M is an atom of molybdenum or tungsten, Cp is substituted or unsubstituted cyclopentadienyl radical represented by the formula [C.sub.5Q.sup.1Q.sup.2Q.sup.3Q.sup.4Q.sup.5], wherein Q.sup.1 to Q.sup.5 are independently selected from the group consisting of H radical, GAr.sup.F C.sub.1-20 hydrocarbyl radical, substituted hydrocarbyl radical, substituted hydrocarbyl radical substituted by GAr.sup.F, halogen radical, halogen-substituted hydrocarbyl radical, --OR, --C(O)R', --CO.sub.2R', --SiR'.sub.3 and --NR'R'', wherein R' and R'' are independently selected from the group consisting of H radical, C.sub.1-20 hydrocarbyl radical, halogen radical, and halogen-substituted hydrocarbyl radical, wherein said Q.sup.1 to Q.sup.5 radicals are optionally linked to each other to form a stable bridging group, NHC is any N-heterocyclic carbene ligand, L is either any neutral electron donor ligand, wherein k is a number from 0 to 1 or L is an anionic ligand wherein k is 2, and A.sup.- is an anion. Processes using the organometallic complexes as catalysts in catalytic reactions, such as for

  10. Neutron Reflectometry and QCM-D Study of the Interaction of Cellulase Enzymes with Films of Amorphous Cellulose

    SciTech Connect

    Halbert, Candice E; Ankner, John Francis; Kent, Michael S; Jaclyn, Murton K; Browning, Jim; Cheng, Gang; Liu, Zelin; Majewski, Jaroslaw; Supratim, Datta; Michael, Jablin; Bulent, Akgun; Alan, Esker; Simmons, Blake

    2011-01-01

    Improving the efficiency of enzymatic hydrolysis of cellulose is one of the key technological hurdles to reduce the cost of producing ethanol and other transportation fuels from lignocellulosic material. A better understanding of how soluble enzymes interact with insoluble cellulose will aid in the design of more efficient enzyme systems. We report a study involving neutron reflectometry (NR) and quartz crystal microbalance with dissipation (QCM-D) of the interaction of a commercial fungal enzyme extract (T. viride), two purified endoglucanses from thermophilic bacteria (Cel9A from A. acidocaldarius and Cel5A from T. maritima), and a mesophilic fungal endoglucanase (Cel45A from H. insolens) with amorphous cellulose films. The use of amorphous cellulose is motivated by the promise of ionic liquid pretreatment as a second generation technology that disrupts the native crystalline structure of cellulose. NR reveals the profile of water through the film at nm resolution, while QCM-D provides changes in mass and film stiffness. At 20 oC and 0.3 mg/ml, the T. viride cocktail rapidly digested the entire film, beginning from the surface followed by activity throughout the bulk of the film. For similar conditions, Cel9A and Cel5A were active for only a short period of time and only at the surface of the film, with Cel9A releasing 40 from the ~ 700 film and Cel5A resulting in only a slight roughening/swelling effect at the surface. Subsequent elevation of the temperature to the Topt in each case resulted in a very limited increase in activity, corresponding to the loss of an additional 60 from the film for Cel9A and 20 from the film for Cel5A, and very weak penetration into and digestion within the bulk of the film, before the activity again ceased. The results for Cel9A and Cel5A contrast sharply with results for Cel45A where very rapid and extensive penetration and digestion within the bulk of the film was observed at 20 C. We speculate that the large differences are due

  11. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    DOE PAGES [OSTI]

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmedmore » using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.« less

  12. Color stable manganese-doped phosphors

    DOEpatents

    Lyons, Robert Joseph; Setlur, Anant Achyut; Deshpande, Anirudha Rajendra; Grigorov, Ljudmil Slavchev

    2012-08-28

    A process for preparing color stable Mn.sup.+4 doped phosphors includes providing a phosphor of formula I; A.sub.x[MF.sub.y]:Mn.sup.+4 I and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; A.sub.x[MF.sub.y]; II wherein A is Li, Na, K, Rb, Cs, NR.sub.4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7. In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof. A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor composition radiationally coupled to the light source, and which includes a color stable Mn.sup.+4 doped phosphor.

  13. Color stable manganese-doped phosphors

    DOEpatents

    Lyons, Robert Joseph; Setlur, Anant Achyut; Deshpande, Anirundha Rajendra; Grigorov, Ljudmil Slavchev

    2014-04-29

    A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor material radiationally coupled to the light source. The phosphor material includes a color-stable Mn.sup.+4 doped phosphor prepared by a process including providing a phosphor of formula I; A.sub.x[MF.sub.y]:Mn.sup.+4 I and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; A.sub.x[MF.sub.y]; II wherein A is Li, Na, K, Rb, Cs, NR.sub.4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7. In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof.

  14. Simplified treatment of exact resonance elastic scattering model in deterministic slowing down equation

    SciTech Connect

    Ono, M.; Wada, K.; Kitada, T.

    2012-07-01

    Simplified treatment of resonance elastic scattering model considering thermal motion of heavy nuclides and the energy dependence of the resonance cross section was implemented into NJOY [1]. In order to solve deterministic slowing down equation considering the effect of up-scattering without iterative calculations, scattering kernel for heavy nuclides is pre-calculated by the formula derived by Ouisloumen and Sanchez [2], and neutron spectrum in up-scattering term is expressed by NR approximation. To check the verification of the simplified treatment, the treatment is applied to U-238 for the energy range from 4 eV to 200 eV. Calculated multi-group capture cross section of U-238 is greater than that of conventional method and the increase of the capture cross sections is remarkable as the temperature becomes high. Therefore Doppler coefficient calculated in UO{sub 2} fuel pin is calculated more negative value than that on conventional method. The impact on Doppler coefficient is equivalent to the results of exact treatment of resonance elastic scattering reported in previous studies [2-7]. The agreement supports the validation of the simplified treatment and therefore this treatment is applied for other heavy nuclide to evaluate the Doppler coefficient in MOX fuel. The result shows that the impact of considering thermal agitation in resonance scattering in Doppler coefficient comes mainly from U-238 and that of other heavy nuclides such as Pu-239, 240 etc. is not comparable in MOX fuel. (authors)

  15. Peculiarity of two thermodynamically-stable morphologies and their impact on the efficiency of small molecule bulk heterojunction solar cells

    DOE PAGES [OSTI]

    Herath, Nuradhika; Das, Sanjib; Keum, Jong K.; Zhu, Jiahua; Kumar, Rajeev; Ivanov, Ilia N.; Sumpter, Bobby G.; Browning, James F.; Xiao, Kai; Gu, Gong; et al

    2015-08-28

    Structural characteristics of the active layers in organic photovoltaic (OPV) devices play a critical role in charge generation, separation and transport. Here we report on morphology and structural control of p-DTS(FBTTh2)2:PC71BM films by means of thermal annealing and 1,8-diiodooctane (DIO) solvent additive processing, and correlate it to the device performance. By combining surface imaging with nanoscale depth-sensitive neutron reflectometry (NR) and X-ray diffraction, three-dimensional morphologies of the films are reconstituted with information extending length scales from nanometers to microns. DIO promotes the formation of a well-mixed donor-acceptor vertical phase morphology with a large population of small p-DTS(FBTTh2)2 nanocrystals arranged inmore » an elongated domain network of the film, thereby enhancing the device performance. In contrast, films without DIO exhibit three-sublayer vertical phase morphology with phase separation in agglomerated domains. Our findings are supported by thermodynamic description based on the Flory-Huggins theory with quantitative evaluation of pairwise interaction parameters that explain the morphological changes resulting from thermal and solvent treatments. Our study reveals that vertical phase morphology of small-molecule based OPVs is significantly different from polymer-based systems. Lastly, the significant enhancement of morphology and information obtained from theoretical modeling may aid in developing an optimized morphology to enhance device performance for OPVs.« less

  16. Electronic and magnetic properties of zigzag silicene nanoribbons with Stone–Wales defects

    SciTech Connect

    Dong, Haixia; Fang, Dangqi; Gong, Baihua; Zhang, Yang; Zhang, Erhu; Zhang, Shengli

    2015-02-14

    The structural, electronic, and magnetic properties of zigzag silicene nanoribbons (ZSiNRs) with Stone–Wales (SW) defects were investigated using first-principles calculations. We found that two types of SW defects (named SW-Ι and SW-ΙΙ) exist in ZSiNRs. The SW defect was found to be the most stable at the edge of the ZSiNR, independently of the defect orientation, even more stable than it is in an infinite silicene sheet. In addition, the ZSiNRs can transition from semiconductor to metal or half-metal by modifying the SW defect location and concentration. For the same defect concentration, the band structures influenced by the SW-Ι defect are more distinct than those influenced by the SW-ΙΙ when the SW defect is at the edge. The present study suggests the possibility of tuning the electronic properties of ZSiNRs using the SW defects and might motivate their potential application in nanoelectronics and spintronics.

  17. Regioselectivity of radical attacks on substituted olefins. Application of the SCD model

    SciTech Connect

    Shaik, S.S. ); Canadell, E. )

    1990-02-14

    The SCD model is used to derive regiochemical trends in radical addition to olefins. Regiochemistry is discussed by appeal to two fundamental properties of the radical and the olefin. The first factor is the relative spin density in the {sup 3}{pi}{pi}* state of the olefin. Thus, radical attack is directed toward the olefinic carbon which possesses the highest spin density. The second factor is the relative bond strengths of the radical to the olefinic carbons. This factor directs the regiochemistry toward the olefinic terminus which forms the strongest bond with the radical. When the two effects join up, regioselectivity will be large, e.g., for CH{sub 2}=CHX (X = NR{sub 2}, CR, Cl, CN, Ph). When the two effects oppose one another, regioselectivity will be smaller, and regioselectivity crossovers are expected, e.g., for CF{sub 2}=CHF. The normal regiochemistry is shown to coincide with the spin density rule which makes identical predictions to the HOMO rule.

  18. Imaging dirac-mass disorder from magnetic dopant-atoms in the ferromagnetic topological insulator Crx(Bi?.?Sb?.?)??xTe?

    DOE PAGES [OSTI]

    Lee, Inhee; Kim, Chung Koo; Lee, Jinho; Billinge, Simon J. L.; Zhong, Ruidan D.; Schneeloch, John A.; Liu, Tiansheng S.; Valla, Tonica; Tranquada, John M.; Gu, Genda; et al

    2015-01-20

    To achieve and use the most exotic electronic phenomena predicted for the surface states of 3D topological insulators (TIs), it is necessary to open a Dirac-mass gap in their spectrum by breaking time-reversal symmetry. Use of magnetic dopant atoms to generate a ferromagnetic state is the most widely applied approach. However, it is unknown how the spatial arrangements of the magnetic dopant atoms influence the Dirac-mass gap at the atomic scale or, conversely, whether the ferromagnetic interactions between dopant atoms are influenced by the topological surface states. Here we image the locations of the magnetic (Cr) dopant atoms in themoreferromagnetic TI Cr?.??(Bi?.?Sb?.?)?.??Te?. Simultaneous visualization of the Dirac-mass gap ?(r) reveals its intense disorder, which we demonstrate is directly related to fluctuations in n(r), the Cr atom areal density in the termination layer. We find the relationship of surface-state Fermi wavevectors to the anisotropic structure of ?(r) not inconsistent with predictions for surface ferromagnetism mediated by those states. Moreover, despite the intense Dirac-mass disorder, the anticipated relationship ?(r)?n(r) is confirmed throughout and exhibits an electrondopant interaction energy J* = 145 meVnm. These observations reveal how magnetic dopant atoms actually generate the TI mass gap locally and that, to achieve the novel physics expected of time-reversal symmetry breaking TI materials, control of the resulting Dirac-mass gap disorder will be essential.less

  19. Density functional theory analysis of the impact of steric interaction on the function of switchable polarity solvents

    SciTech Connect

    McNally, Joshua S.; Noll, Bruce; Orme, Christopher J.; Wilson, Aaron D.

    2015-05-04

    Here, a density functional theory (DFT) analysis has been performed to explore the impact of steric interactions on the function of switchable polarity solvents (SPS) and their implications on a quantitative structure-activity relationship (QSAR) model previously proposed for SPS. An x-ray crystal structure of the N,N-dimethylcyclohexylammonium bicarbonate (Hdmcha) salt has been solved as an asymmetric unit containing two cation/anion pairs, with a hydrogen bonding interaction observed between the bicarbonate anions, as well as between the cation and anion in each pair. DFT calculations provide an optimized structure of Hdmcha that closely resembles experimental data and reproduces the cation/anion interaction with the inclusion of a dielectric field. Relaxed potential energy surface (PES) scans have been performed on Hdmcha-based computational model compounds, differing in the size of functional group bonded to the nitrogen center, to assess the steric impact of the group on the relative energy and structural properties of the compound. Results suggest that both the length and amount of branching associated with the substituent impact the energetic limitations on rotation of the group along the N-R bond and NC-R bond, and disrupt the energy minimized position of the hydrogen bonded bicarbonate group. The largest interaction resulted from functional groups that featured five bonds between the ammonium proton and a proton on a functional group with the freedom of rotation to form a pseudo-six membered ring which included both protons.

  20. Impact of membrane characteristics on the performance and cycling of the Br₂–H₂ redox flow cell

    DOE PAGES [OSTI]

    Tucker, Michael C.; Cho, Kyu Taek; Spingler, Franz B.; Weber, Adam Z.; Lin, Guangyu

    2015-03-04

    The Br₂/H₂ redox flow cell shows promise as a high-power, low-cost energy storage device. In this paper, the effect of various aspects of material selection and processing of proton exchange membranes on the operation of the Br₂/H₂ redox flow cell is determined. Membrane properties have a significant impact on the performance and efficiency of the system. In particular, there is a tradeoff between conductivity and crossover, where conductivity limits system efficiency at high current density and crossover limits efficiency at low current density. The impact of thickness, pretreatment procedure, swelling state during cell assembly, equivalent weight, membrane reinforcement, and additionmore » of a microporous separator layer on this tradeoff is assessed. NR212 (50 μm) pretreated by soaking in 70 °C water is found to be optimal for the studied operating conditions. For this case, an energy efficiency of greater than 75% is achieved for current density up to 400 mA cm⁻², with a maximum obtainable energy efficiency of 88%. A cell with this membrane was cycled continuously for 3164 h. Membrane transport properties, including conductivity and bromine and water crossover, were found to decrease moderately upon cycling but remained higher than those for the as-received membrane.« less

  1. Synthesis of labeled oxalic acid derivatives

    DOEpatents

    Martinez, Rodolfo A.; Unkefer, Clifford J.; Alvarez, Marc A.

    2004-06-22

    The present invention is directed to labeled compounds, specifically ##STR1## where each C* is selected from the group consisting of a carbon-12, i.e., .sup.12 C, or a carbon-13, i.e., .sup.13 C and at least one C* is .sup.13 C, R.sup.1 is selected from the group of C.sub.1 -C.sub.4 lower alkyl and aryl, and X is selected from the group of --NR.sup.2 R.sup.3 where R.sup.2 and R.sup.3 are each independently selected from the group of C.sub.1 -C.sub.4 lower alkyl, alkoxy and aryl, --SR.sup.4 where R.sup.4 is selected from the group of C.sub.1 -C.sub.4 lower alkyl, alkoxy and aryl, and --OR.sup.5 where R.sup.5 is selected from the group of C.sub.1 -C.sub.4 lower alkyl, alkoxy and aryl with the proviso that when R.sup.1 is methyl then R.sup.5 is other than methyl, when R.sup.1 is ethyl then R.sup.5 is other than ethyl, and when R.sup.1 is benzyl then R.sup.5 is other than benzyl.

  2. Transcriptome sequencing and differential gene expression analysis in Viola yedoensis Makino (Fam. Violaceae) responsive to cadmium (Cd) pollution

    SciTech Connect

    Gao, Jian; Luo, Mao; Zhu, Ye; He, Ying; Wang, Qin; Zhang, Chun

    2015-03-27

    Viola yedoensis Makino is an important Chinese traditional medicine plant adapted to cadmium (Cd) pollution regions. Illumina sequencing technology was used to sequence the transcriptome of V. yedoensis Makino. We sequenced Cd-treated (VIYCd) and untreated (VIYCK) samples of V. yedoensis, and obtained 100,410,834 and 83,587,676 high quality reads, respectively. After de novo assembly and quantitative assessment, 109,800 unigenes were finally generated with an average length of 661 bp. We then obtained functional annotations by aligning unigenes with public protein databases including NR, NT, SwissProt, KEGG and COG. In addition, 892 differentially expressed genes (DEGs) were investigated between the two libraries of untreated (VIYCK) and Cd-treated (VIYCd) plants. Moreover, 15 randomly selected DEGs were further validated with qRT-PCR and the results were highly accordant with the Solexa analysis. This study firstly generated a successful global analysis of the V. yedoensis transcriptome and it will provide for further studies on gene expression, genomics, and functional genomics in Violaceae. - Highlights: • A de novo assembly generated 109,800 unigenes and 5,4479 of them were annotated. • 31,285 could be classified into 26 COG categories. • 263 biosynthesis pathways were predicted and classified into five categories. • 892 DEGs were detected and 15 of them were validated by qRT-PCR.

  3. Mechanisms of degradation in adhesive joint strength: Glassy polymer thermoset bond in a humid environment

    SciTech Connect

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted for by the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.

  4. Density functional theory analysis of the impact of steric interaction on the function of switchable polarity solvents

    DOE PAGES [OSTI]

    McNally, Joshua S.; Noll, Bruce; Orme, Christopher J.; Wilson, Aaron D.

    2015-05-04

    Here, a density functional theory (DFT) analysis has been performed to explore the impact of steric interactions on the function of switchable polarity solvents (SPS) and their implications on a quantitative structure-activity relationship (QSAR) model previously proposed for SPS. An x-ray crystal structure of the N,N-dimethylcyclohexylammonium bicarbonate (Hdmcha) salt has been solved as an asymmetric unit containing two cation/anion pairs, with a hydrogen bonding interaction observed between the bicarbonate anions, as well as between the cation and anion in each pair. DFT calculations provide an optimized structure of Hdmcha that closely resembles experimental data and reproduces the cation/anion interaction withmore » the inclusion of a dielectric field. Relaxed potential energy surface (PES) scans have been performed on Hdmcha-based computational model compounds, differing in the size of functional group bonded to the nitrogen center, to assess the steric impact of the group on the relative energy and structural properties of the compound. Results suggest that both the length and amount of branching associated with the substituent impact the energetic limitations on rotation of the group along the N-R bond and NC-R bond, and disrupt the energy minimized position of the hydrogen bonded bicarbonate group. The largest interaction resulted from functional groups that featured five bonds between the ammonium proton and a proton on a functional group with the freedom of rotation to form a pseudo-six membered ring which included both protons.« less

  5. Functional and structural diversity in GH62 α-L-arabinofuranosidases from the thermophilic fungus Scytalidium thermophilum

    DOE PAGES [OSTI]

    Kaur, Amrit Pal; Nocek, Boguslaw P.; Xu, Xiaohui; Lowden, Michael J.; Leyva, Juan Francisco; Stogios, Peter J.; Cui, Hong; Leo, Rosa Di; Powlowski, Justin; Tsang, Adrian; et al

    2015-05-01

    The genome of the thermophilic fungus Scytalidium thermophilum (strain CBS 625.91) harbours a wide range of genes involved in carbohydrate degradation, including three genes, abf62A, abf62B and abf62C, predicted to encode glycoside hydrolase family 62 (GH62) enzymes. Transcriptome analysis showed that only abf62A and abf62C are actively expressed during growth on diverse substrates including straws from barley, alfalfa, triticale and canola. The abf62A and abf62C genes were expressed in Escherichia coli and the resulting recombinant proteins were characterized. Calcium-free crystal structures of Abf62C in apo and xylotriose bound forms were determined to 1.23 and 1.48 Å resolution respectively. Site-directed mutagenesismore » confirmed Asp55, Asp171 and Glu230 as catalytic triad residues, and revealed the critical role of non-catalytic residues Asp194, Trp229 and Tyr338 in positioning the scissile α-L-arabinofuranoside bond at the catalytic site. Further, the +2R substrate-binding site residues Tyr168 and Asn339, as well as the +2NR residue Tyr226, are involved in accommodating long-chain xylan polymers. Overall, our structural and functional analysis highlights characteristic differences between Abf62A and Abf62C, which represent divergent subgroups in the GH62 family.« less

  6. Catalysts For Hydrogenation And Hydrosilylation Methods Of Making And Using The Same

    DOEpatents

    Dioumaev, Vladimir K.; Bullock, R. Morris

    2004-05-18

    A compound is provided including an organometallic complex represented by the formula I: wherein M is an atom of molybdenum or tangsten, Cp is substituted or unsubstituted cyclopentadienyl radical represented by the formula [C.sub.5 Q.sup.1 Q.sup.2 Q.sup.3 Q.sup.4 Q.sup.5 ], wherein Q.sup.1 to Q.sup.5 are independently selected from the group consisting of H radical, C.sub.1-20 hydrocarbyl radical, substituted hydrocarbyl radical, halogen radical, halogen-substituted hydrocarbyl radical, --OR, --C(O)R', --CO.sub.2 R', --SiR'.sub.3 and --NR'R", wherein R' and R" are independently selected from the group consisting of H radical, C.sub.1-20 hydrocarbyl radical, halogen radical, and halogen-substituted hydrocarbyl radical, wherein said Q.sup.1 to Q.sup.5 radicals are optionally linked to each other to form a stable bridging group, NHC is any N-heterocyclic carbene ligand, L is either any neutral electron donor ligand, wherein k is a number from 0 to 1 or L is an anionic ligand wherein k is 2, and A.sup.- is an anion. Processes using the organometallic complex as catalyst for hydrogenation of aldehydes and ketones are provided. Processes using the organometallic complex as catalyst for the hydrosilylation of aldehydes, ketones and esters are also provided.

  7. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    SciTech Connect

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmed using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.

  8. Rigid-rotor, field-reversed configuration

    SciTech Connect

    Conti, F. Giammanco, F.; Plasma Diagnostics and Technologies Ltd., Via Giuntini 63, 56023 Navacchio ; Wessel, F. J.; Binderbauer, M. W.; Bolte, N.; Morehouse, M.; Qerushi, A.; Rahman, H. U.; Roche, T.; Slepchenkov, M.

    2014-02-15

    The radial profiles, n(r), B{sub z}(r), and E{sub r}(r), for a Flux-Coil (“inductively driven”), Field-Reversed Configuration (FC-FRC) are measured and compared to the predictions of the Rigid-Rotor Model (RRM), which is an analytic, one-dimensional, time-independent, equilibrium description for the FRC. Injectors mounted on both ends of the confinement vessel provide a pre-fill plasma. Coaxial coils mounted outside the vacuum boundaries of the annular-confinement vessel accelerate the plasma and produce the FRC. The density profile is measured by laser interferometry, the magnetic-field profile using an in-situ probe array, and the electric-field profile using an in-situ, floating-probe array. Free parameters for each profile are measured, which also allow other intrinsic-plasma parameters to be determined, using computer-fit algorithms: null radius, radial thickness, plasma temperature, rotation frequencies, the latter of which are independently verified by spectroscopy. All radial profiles agree with the RRM predictions, for the experimental configuration, parameter regime, and specified-time interval studied here.

  9. Mechanisms of degradation in adhesive joint strength: Glassy thermoset polymer bond in a humid environment

    DOE PAGES [OSTI]

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted formoreby the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.less

  10. Mechanisms of degradation in adhesive joint strength: Glassy polymer thermoset bond in a humid environment

    DOE PAGES [OSTI]

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted formore » by the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.« less

  11. Impact of membrane characteristics on the performance and cycling of the Br-2-H-2 redox flow cell

    SciTech Connect

    Tucker, MC; Cho, KT; Spingler, FB; Weber, AZ; Lin, GY

    2015-06-15

    The Br-2/H-2 redox flow cell shows promise as a high-power, low-cost energy storage device. In this paper, the effect of various aspects of material selection and processing of proton exchange membranes on the operation of the Br-2/H-2 redox flow cell is determined. Membrane properties have a significant impact on the performance and efficiency of the system. In particular, there is a tradeoff between conductivity and crossover, where conductivity limits system efficiency at high current density and crossover limits efficiency at low current density. The impact of thickness, pretreatment procedure, swelling state during cell assembly, equivalent weight, membrane reinforcement, and addition of a microporous separator layer on this tradeoff is assessed. NR212 (50 mu m) pretreated by soaking in 70 degrees C water is found to be optimal for the studied operating conditions. For this case, an energy efficiency of greater than 75% is achieved for current density up to 400 mA cm(-2), with a maximum obtainable energy efficiency of 88%. A cell with this membrane was cycled continuously for 3164 h. Membrane transport properties, including conductivity and bromine and water crossover, were found to decrease moderately upon cycling but remained higher than those for the as-received membrane. (C) 2015 Elsevier B.V. All rights reserved.

  12. Impact of membrane characteristics on the performance and cycling of the Br₂–H₂ redox flow cell

    SciTech Connect

    Tucker, Michael C.; Cho, Kyu Taek; Spingler, Franz B.; Weber, Adam Z.; Lin, Guangyu

    2015-03-04

    The Br₂/H₂ redox flow cell shows promise as a high-power, low-cost energy storage device. In this paper, the effect of various aspects of material selection and processing of proton exchange membranes on the operation of the Br₂/H₂ redox flow cell is determined. Membrane properties have a significant impact on the performance and efficiency of the system. In particular, there is a tradeoff between conductivity and crossover, where conductivity limits system efficiency at high current density and crossover limits efficiency at low current density. The impact of thickness, pretreatment procedure, swelling state during cell assembly, equivalent weight, membrane reinforcement, and addition of a microporous separator layer on this tradeoff is assessed. NR212 (50 μm) pretreated by soaking in 70 °C water is found to be optimal for the studied operating conditions. For this case, an energy efficiency of greater than 75% is achieved for current density up to 400 mA cm⁻², with a maximum obtainable energy efficiency of 88%. A cell with this membrane was cycled continuously for 3164 h. Membrane transport properties, including conductivity and bromine and water crossover, were found to decrease moderately upon cycling but remained higher than those for the as-received membrane.

  13. CHL1 is involved in human breast tumorigenesis and progression

    SciTech Connect

    He, Li-Hong; Ma, Qin; Shi, Ye-Hui; Ge, Jie; Zhao, Hong-Meng; Li, Shu-Fen; Tong, Zhong-Sheng

    2013-08-23

    Highlights: •CHL1 is down-regulation in breast cancer tissues. •Down-regulation of CHL1 is related to high grade. •Overexpression of CHL1 inhibits breast cancer cell proliferation and invasion in vitro. •CHL1 deficiency induces breast cancer cell proliferation and invasion both in vitro and in vivo. -- Abstract: Neural cell adhesion molecules (CAM) play important roles in the development and regeneration of the nervous system. The L1 family of CAMs is comprised of L1, Close Homolog of L1 (CHL1, L1CAM2), NrCAM, and Neurofascin, which are structurally related trans-membrane proteins in vertebrates. Although the L1CAM has been demonstrated play important role in carcinogenesis and progression, the function of CHL1 in human breast cancer is limited. Here, we found that CHL1 is down-regulated in human breast cancer and related to lower grade. Furthermore, overexpression of CHL1 suppresses proliferation and invasion in MDA-MB-231 cells and knockdown of CHL1 expression results in increased proliferation and invasion in MCF7 cells in vitro. Finally, CHL1 deficiency promotes tumor formation in vivo. Our results may provide a strategy for blocking breast carcinogenesis and progression.

  14. Volume generation of negative ions in high density hydrogen discharges. Revision 1

    SciTech Connect

    Hiskes, J.R.; Karo, A.M.

    1983-11-11

    An optimized tandem two-chamber negative-ion source system is discussed. In the first chamber high energy (E > 20 eV) electron collisions provide for H/sub 2/ vibrational excitation, while in the second chamber negative ions are formed by dissociative attachment. The gas density, electron density, and system scale length are varied as independent parameters. The extracted negative ion current density passes through a maximum as electron and gas densities are varied. This maximum scales inversely with system scale length, R. The optimum extracted current densities occur for electron densities near nR = 10/sup 13/ electrons cm/sup -2/ and for gas densities, N/sub 2/R, in the range 10/sup 14/ to 10/sup 15/ molecules cm/sup -2/. The extracted current densities are sensitive to the atomic concentration in the discharge. The atomic concentration is parametrized by the wall recombination coefficient, ..gamma.., and scale length, R. As ..gamma.. ranges from 0.1 to 1.0 and for system scale lengths of one centimeter, extracted current densities range from 8.0 to 80. mA cm/sup -2/.

  15. Double Retort System for Materials Compatibility Testing

    SciTech Connect

    V. Munne; EV Carelli

    2006-02-23

    With Naval Reactors (NR) approval of the Naval Reactors Prime Contractor Team (NRPCT) recommendation to develop a gas cooled reactor directly coupled to a Brayton power conversion system as the Space Nuclear Power Plant (SNPP) for Project Prometheus (References a and b) there was a need to investigate compatibility between the various materials to be used throughout the SNPP. Of particular interest was the transport of interstitial impurities from the nickel-base superalloys, which were leading candidates for most of the piping and turbine components to the refractory metal alloys planned for use in the reactor core. This kind of contamination has the potential to affect the lifetime of the core materials. This letter provides technical information regarding the assembly and operation of a double retort materials compatibility testing system and initial experimental results. The use of a double retort system to test materials compatibility through the transfer of impurities from a source to a sink material is described here. The system has independent temperature control for both materials and is far less complex than closed loops. The system is described in detail and the results of three experiments are presented.

  16. Hot Leg Piping Materials Issues

    SciTech Connect

    V. Munne

    2006-07-19

    With Naval Reactors (NR) approval of the Naval Reactors Prime Contractor Team (NRPCT) recommendation to develop a gas cooled reactor directly coupled to a Brayton power conversion system as the space nuclear power plant (SNPP) for Project Prometheus (References a and b) the reactor outlet piping was recognized to require a design that utilizes internal insulation (Reference c). The initial pipe design suggested ceramic fiber blanket as the insulation material based on requirements associated with service temperature capability within the expected range, very low thermal conductivity, and low density. Nevertheless, it was not considered to be well suited for internal insulation use because its very high surface area and proclivity for holding adsorbed gases, especially water, would make outgassing a source of contaminant gases in the He-Xe working fluid. Additionally, ceramic fiber blanket insulating materials become very friable after relatively short service periods at working temperatures and small pieces of fiber could be dislodged and contaminate the system. Consequently, alternative insulation materials were sought that would have comparable thermal properties and density but superior structural integrity and greatly reduced outgassing. This letter provides technical information regarding insulation and materials issues for the Hot Leg Piping preconceptual design developed for the Project Prometheus space nuclear power plant (SNPP).

  17. Cyclopentadienyl-Containing Low-Valent Early Transition Metal Olefin Polymerization Catalysts

    DOEpatents

    Marks, Tobin J.; Luo, Lubin; Yoon, Sung Cheol

    2004-06-08

    A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n }.sup.+ {A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 -C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 -C.sub.20 hydrocarbyl, SiR".sub.3, NR".sub.2, OR", SR", GeR".sub.3, SnR".sub.3, and C.dbd.C-containing groups (R"=C.sub.1 -C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

  18. Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts

    DOEpatents

    Marks, Tobin J.; Luo, Lubin; Yoon, Sung Cheol

    2006-10-10

    A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n}.sup.+{A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 C.sub.20 hydrocarbyl, SiR''.sub.3, NR''.sub.2, OR'', SR'', GeR''.sub.3, SnR''.sub.3, and C.dbd.C-containing groups (R''=C.sub.1 C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

  19. Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts

    DOEpatents

    Marks, Tobin J.; Luo, Lubin; Yoon, Sung Cheol

    2007-01-09

    A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n}.sup.+{A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 C.sub.20 hydrocarbyl, SiR''.sub.3, NR''.sub.2, OR'', SR'', GeR''.sub.3, SnR''.sub.3, and C.dbd.C-containing groups (R''=C.sub.1 C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

  20. Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts

    DOEpatents

    Marks, Tobin J.; Luo, Lubin; Yoon, Sung Cheol

    2003-12-30

    A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 -C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 -C.sub.20 hydrocarbyl, SiR".sub.3, NR".sub.2, OR", SR", GeR".sub.3, SnR".sub.3, and C.dbd.C containing groups (R".dbd.C.sub.1 -C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

  1. Cyclopentadienyl-containing low-valent early transition metal olefin polymerization catalysts

    DOEpatents

    Marks, Tobin J.; Luo, Lubin; Yoon, Sung Cheol

    2003-04-08

    A catalyst system useful to polymerize and co-polymerize polar and non-polar olefin monomers is formed by in situ reduction with a reducing agent of a catalyst precursor comprising {Cp*MRR'.sub.n }.sup.+ {A}.sup.- wherein Cp* is a cyclopentadienyl or substituted cyclopentadienyl moiety; M is an early transition metal; R is a C.sub.1 -C.sub.20 hydrocarbyl; R' are independently selected from hydride, C.sub.1 -C.sub.20 hydrocarbyl, SiR".sub.3, NR".sub.2, OR", SR", GeR".sub.3, and SnR".sub.3 containing groups (R"=C.sub.1 -C.sub.10 hydrocarbyl); n is an integer selected to balance the oxidation state of M; and A is a suitable non-coordinating anionic cocatalyst or precursor. This catalyst system may form stereoregular olefin polymers including syndiotactic polymers of styrene and methylmethacrylate and isotactic copolymers of polar and nonpolar olefin monomers such as methylmethacrylate and styrene.

  2. EARLY AFTERGLOWS OF GAMMA-RAY BURSTS IN A STRATIFIED MEDIUM WITH A POWER-LAW DENSITY DISTRIBUTION

    SciTech Connect

    Yi, Shuang-Xi; Dai, Zi-Gao [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Wu, Xue-Feng, E-mail: dzg@nju.edu.cn [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China)

    2013-10-20

    A long-duration gamma-ray burst (GRB) has been widely thought to arise from the collapse of a massive star, and it has been suggested that its ambient medium is a homogenous interstellar medium (ISM) or a stellar wind. There are two shocks when an ultra-relativistic fireball that has been ejected during the prompt gamma-ray emission phase sweeps up the circumburst medium: a reverse shock that propagates into the fireball, and a forward shock that propagates into the ambient medium. In this paper, we investigate the temporal evolution of the dynamics and emission of these two shocks in an environment with a general density distribution of n?R {sup k} (where R is the radius) by considering thick-shell and thin-shell cases. A GRB afterglow with one smooth onset peak at early times is understood to result from such external shocks. Thus, we can determine the medium density distribution by fitting the onset peak appearing in the light curve of an early optical afterglow. We apply our model to 19 GRBs and find that their k values are in the range of 0.4-1.4, with a typical value of k ? 1, implying that this environment is neither a homogenous ISM with k = 0 nor a typical stellar wind with k = 2. This shows that the progenitors of these GRBs might have undergone a new mass-loss evolution.

  3. Implementation of New Process Models for Tailored Polymer Composite Structures into Processing Software Packages

    SciTech Connect

    Nguyen, Ba Nghiep; Jin, Xiaoshi; Wang, Jin; Phelps, Jay; Tucker III, Charles L.; Kunc, Vlastimil; Bapanapalli, Satish K.; Smith, Mark T.

    2010-02-23

    This report describes the work conducted under the Cooperative Research and Development Agreement (CRADA) (Nr. 260) between the Pacific Northwest National Laboratory (PNNL) and Autodesk, Inc. to develop and implement process models for injection-molded long-fiber thermoplastics (LFTs) in processing software packages. The structure of this report is organized as follows. After the Introduction Section (Section 1), Section 2 summarizes the current fiber orientation models developed for injection-molded short-fiber thermoplastics (SFTs). Section 3 provides an assessment of these models to determine their capabilities and limitations, and the developments needed for injection-molded LFTs. Section 4 then focuses on the development of a new fiber orientation model for LFTs. This model is termed the anisotropic rotary diffusion - reduced strain closure (ARD-RSC) model as it explores the concept of anisotropic rotary diffusion to capture the fiber-fiber interaction in long-fiber suspensions and uses the reduced strain closure method of Wang et al. to slow down the orientation kinetics in concentrated suspensions. In contrast to fiber orientation modeling, before this project, no standard model was developed to predict the fiber length distribution in molded fiber composites. Section 5 is therefore devoted to the development of a fiber length attrition model in the mold. Sections 6 and 7 address the implementations of the models in AMI, and the conclusions drawn from this work is presented in Section 8.

  4. Peculiarity of two thermodynamically-stable morphologies and their impact on the efficiency of small molecule bulk heterojunction solar cells

    SciTech Connect

    Herath, Nuradhika; Das, Sanjib; Keum, Jong K.; Zhu, Jiahua; Kumar, Rajeev; Ivanov, Ilia N.; Sumpter, Bobby G.; Browning, James F.; Xiao, Kai; Gu, Gong; Joshi, Pooran; Smith, Sean; Lauter, Valeria

    2015-08-28

    Structural characteristics of the active layers in organic photovoltaic (OPV) devices play a critical role in charge generation, separation and transport. Here we report on morphology and structural control of p-DTS(FBTTh2)2:PC71BM films by means of thermal annealing and 1,8-diiodooctane (DIO) solvent additive processing, and correlate it to the device performance. By combining surface imaging with nanoscale depth-sensitive neutron reflectometry (NR) and X-ray diffraction, three-dimensional morphologies of the films are reconstituted with information extending length scales from nanometers to microns. DIO promotes the formation of a well-mixed donor-acceptor vertical phase morphology with a large population of small p-DTS(FBTTh2)2 nanocrystals arranged in an elongated domain network of the film, thereby enhancing the device performance. In contrast, films without DIO exhibit three-sublayer vertical phase morphology with phase separation in agglomerated domains. Our findings are supported by thermodynamic description based on the Flory-Huggins theory with quantitative evaluation of pairwise interaction parameters that explain the morphological changes resulting from thermal and solvent treatments. Our study reveals that vertical phase morphology of small-molecule based OPVs is significantly different from polymer-based systems. Lastly, the significant enhancement of morphology and information obtained from theoretical modeling may aid in developing an optimized morphology to enhance device performance for OPVs.

  5. Inclusion of cool roofs in nonresidential Title 24 prescriptiverequirements

    SciTech Connect

    Levinson, Ronnen; Akbari, Hashem; Konopacki, Steve; Bretz, Sarah

    2003-07-01

    Roofs that have high solar reflectance (high ability toreflect sunlight) and high thermal emittance (high ability to radiateheat) tend to stay cool in the sun. The same is true of low-emittanceroofs with exceptionally high solar reflectance. Substituting a cool rooffor a non-cool roof tends to decrease cooling electricity use, coolingpower demand, and cooling-equipment capacity requirements, while slightlyincreasing heating energy consumption. Cool roofs can also lower citywideambient air temperature in summer, slowing ozone formation and increasinghuman comfort.DOE-2.1E building energy simulations indicate that use of acool roofing material on a prototypical California nonresidential (NR)building with a low-sloped roof yields average annual cooling energysavings of approximately 3.2 kW h/m2 (300 kW h/1000 ft2), average annualnatural gas deficits of 5.6 MJ/m2 (4.9 therm/1000 ft2), average annualsource energy savings of 30 MJ/m2 (2.6 MBTU/1000 ft2), and average peakpower demand savings of 2.1 W/m2 (0.19 kW/1000 ft2). The 15-year netpresent value (NPV) of energy savings averages $4.90/m2 ($450/1000 ft2)with time-dependent valuation (TDV), and $4.00/m2 ($370/1000 ft2) withoutTDV. When cost savings from downsizing cooling equipment are included,the average total savings (15-year NPV+equipment savings) rises to$5.90/m2 ($550/1000 ft2) with TDV, and to $5.00/m2 ($470/1000 ft2)without TDV.Total savings range from 1.90 to 8.30 $/m2 (0.18 0.77 $/ft2)with TDV, and from 1.70 to 7.10 $/m2 (0.16 0.66 $/ft2) without TDV,across California's 16 climate zones. The typical cost premium for a coolroof is 0.00 2.20 $/m2 (0.00 0.20 $/ft2). Cool roofs with premiums up to$2.20/m2 ($0.20/ft2) are expected to be cost effective in climate zones 216; those with premiums not exceeding $1.90/m2 ($0.18/ft2) are expectedto be also cost effective in climate zone 1. Hence, this study recommendsthat the year-2005 California building energy efficiency code (Title 24,Part 6 of the California Code of

  6. Characterization of Ambient Aerosols in Mexico City during the MCMA-2003 Campaign with Aerosol Mass Spectrometry. Results from the CENICA Supersite

    SciTech Connect

    Salcedo, D.; Onasch, Timothy B.; Dzepina, K.; Canagaratna, M. R.; Zhang, Q.; Huffman, A. J.; DeCarlo, Peter; Jayne, J. T.; Mortimer, P.; Worsnop, Douglas R.; Kolb, C. E.; Johnson, Kirsten S.; Zuberi, Bilal M.; Marr, L.; Volkamer, Rainer M.; Molina, Luisa; Molina, Mario J.; Cardenas, B.; Bernabe, R.; Marquez, C.; Gaffney, Jeffrey S.; Marley, Nancy A.; Laskin, Alexander; Shutthanandan, V.; Xie, YuLong; Brune, W. H.; Lesher, R.; Shirley, T.; Jiminez, J. L.

    2006-03-24

    An Aerodyne Aerosol Mass Spectrometer (AMS) was deployed at the CENICA Supersite, while another was deployed in the Aerodyne Mobile Laboratory (AML) during the Mexico City Metropolitan Area field study (MCMA-2003) from March 29-May 4, 2003 to investigate particle concentrations, sources, and processes. This is the first of a series of papers reporting the AMS results from this campaign. The AMS provides real time information on mass concentration and composition of the non-refractory species in particulate matter less than 1 ?m (NR PM1) with high time and size resolution. For the first time, we report field results from a beam width probe, which was used to study the shape and mixing state of the particles and to quantify potential losses of irregular particles due to beam broadening inside the AMS. Data from this probe show that no significant amount of irregular particles was lost due to excessive beam broadening. A comparison of the CENICA and AML AMSs measurements is presented, being the first published intercomparison between two quadrupole AMSs. The speciation, and mass concentrations reported by the two AMSs compared well. In order to account for the refractory material in the aerosol, we also present measurements of Black Carbon (BC) using an aethalometer and an estimate of the aerosol soil component obtained from PIXE analysis of filters. Comparisons of (AMS + BC + soil) mass concentration with other collocated particle instruments (a LASAIR Optical Particle Counter, a Tapered Element Oscillating Microbalance (TEOM) and a DustTrack Aerosol Monitor) are also presented. The comparisons show that the (AMS + BC + soil) mass concentration during MCMC-2003 is a good approximation to the total PM??? mass concentration.

  7. High-performance ultraviolet detection and visible-blind photodetector based on Cu{sub 2}O/ZnO nanorods with poly-(N-vinylcarbazole) intermediate layer

    SciTech Connect

    Perng, Dung-Ching

    2015-12-14

    This study reports a high-performance hybrid ultraviolet (UV) photodetector with visible-blind sensitivity fabricated by inserting a poly-(N-vinylcarbazole) (PVK) intermediate layer between low-cost processed Cu{sub 2}O film and ZnO nanorods (NRs). The PVK layer acts as an electron-blocking/hole-transporting layer between the n-ZnO and p-Cu{sub 2}O films. The Cu{sub 2}O/PVK/ZnO NR photodetector exhibited a responsivity of 13.28 A/W at 360 nm, a high detectivity of 1.03 × 10{sup 13} Jones at a low bias of −0.1 V under a low UV light intensity of 24.9 μW/cm{sup 2}. The photo-to-dark current ratios of the photodetector with and without the PVK intermediate layer at a bias of −0.5 V are 1.34 × 10{sup 2} and 3.99, respectively. The UV-to-visible rejection ratios (R{sub 360 nm}/R{sub 450 nm}) are 350 and 1.735, respectively. Several features are demonstrated: (a) UV photo-generated holes at the ZnO NRs can effectively be transported through the PVK layer to the p-Cu{sub 2}O layer; (b) the insertion of a PVK buffer layer significantly minimizes the reverse-bias leakage current, which leads to a larger amplification of the photocurrent; and (c) the PVK buffer layer greatly improves the UV-to-visible responsivity ratio, allowing the device to achieve high UV detection sensitivity at a low bias voltage using a very low light intensity.

  8. Biodegradation of biodiesel fuels

    SciTech Connect

    Zhang, X.; Haws, R.; Wright, B.; Reese, D.; Moeller, G.; Peterson, C.

    1995-12-31

    Biodiesel fuel test substances Rape Ethyl Ester (REE), Rape Methyl Ester (RME), Neat Rape Oil (NR), Say Methyl Ester (SME), Soy Ethyl Ester (SEE), Neat Soy Oil (NS), and proportionate combinations of RME/diesel and REE/diesel were studied to test the biodegradability of the test substances in an aerobic aquatic environment using the EPA 560/6-82-003 Shake Flask Test Method. A concurrent analysis of Phillips D-2 Reference Diesel was also performed for comparison with a conventional fuel. The highest rates of percent CO{sub 2} evolution were seen in the esterified fuels, although no significant difference was noted between them. Ranges of percent CO{sub 2} evolution for esterified fuels were from 77% to 91%. The neat rape and neat soy oils exhibited 70% to 78% CO{sub 2} evolution. These rates were all significantly higher than those of the Phillips D-2 reference fuel which evolved from 7% to 26% of the organic carbon to CO{sub 2}. The test substances were examined for BOD{sub 5} and COD values as a relative measure of biodegradability. Water Accommodated Fraction (WAF) was experimentally derived and BOD{sub 5} and COD analyses were carried out with a diluted concentration at or below the WAF. The results of analysis at WAF were then converted to pure substance values. The pure substance BOD{sub 5} and COD values for test substances were then compared to a control substance, Phillips D-2 Reference fuel. No significant difference was noted for COD values between test substances and the control fuel. (p > 0.20). The D-2 control substance was significantly lower than all test substances for BCD, values at p << 0.01. RME was also significantly lower than REE (p < 0.05) and MS (p < 0.01) for BOD{sub 5} value.

  9. Functional and structural diversity in GH62 ?-L-arabinofuranosidases from the thermophilic fungus Scytalidium thermophilum

    SciTech Connect

    Kaur, Amrit Pal; Nocek, Boguslaw P.; Xu, Xiaohui; Lowden, Michael J.; Leyva, Juan Francisco; Stogios, Peter J.; Cui, Hong; Leo, Rosa Di; Powlowski, Justin; Tsang, Adrian; Savchenko, Alexei

    2015-05-01

    The genome of the thermophilic fungus Scytalidium thermophilum (strain CBS 625.91) harbours a wide range of genes involved in carbohydrate degradation, including three genes, abf62A, abf62B and abf62C, predicted to encode glycoside hydrolase family 62 (GH62) enzymes. Transcriptome analysis showed that only abf62A and abf62C are actively expressed during growth on diverse substrates including straws from barley, alfalfa, triticale and canola. The abf62A and abf62C genes were expressed in Escherichia coli and the resulting recombinant proteins were characterized. Calcium-free crystal structures of Abf62C in apo and xylotriose bound forms were determined to 1.23 and 1.48 resolution respectively. Site-directed mutagenesis confirmed Asp55, Asp171 and Glu230 as catalytic triad residues, and revealed the critical role of non-catalytic residues Asp194, Trp229 and Tyr338 in positioning the scissile ?-L-arabinofuranoside bond at the catalytic site. Further, the +2R substrate-binding site residues Tyr168 and Asn339, as well as the +2NR residue Tyr226, are involved in accommodating long-chain xylan polymers. Overall, our structural and functional analysis highlights characteristic differences between Abf62A and Abf62C, which represent divergent subgroups in the GH62 family.

  10. Imaging Dirac-mass disorder from magnetic dopant atoms in the ferromagnetic topological insulator Crx(Bi0.1Sb0.9)2-xTe3

    DOE PAGES [OSTI]

    Lee, Inhee; Kim, Chung Koo; Lee, Jinho; Billinge, Simon J. L.; Zhong, Ruidan D.; Schneeloch, John A.; Liu, Tiansheng S.; Valla, Tonica; Tranquada, John M.; Gu, Genda D.; et al

    2015-01-20

    To achieve and use the most exotic electronic phenomena predicted for the surface states of 3D topological insulators (TIs), it is necessary to open a “Dirac-mass gap” in their spectrum by breaking time-reversal symmetry. Use of magnetic dopant atoms to generate a ferromagnetic state is the most widely applied approach. However, it is unknown how the spatial arrangements of the magnetic dopant atoms influence the Dirac-mass gap at the atomic scale or, conversely, whether the ferromagnetic interactions between dopant atoms are influenced by the topological surface states. Here we image the locations of the magnetic (Cr) dopant atoms in themore » ferromagnetic TI Cr₀.₀₈(Bi₀.₁Sb₀.₉)₁.₉₂Te₃. Simultaneous visualization of the Dirac-mass gap Δ(r) reveals its intense disorder, which we demonstrate is directly related to fluctuations in n(r), the Cr atom areal density in the termination layer. We find the relationship of surface-state Fermi wavevectors to the anisotropic structure of Δ(r) not inconsistent with predictions for surface ferromagnetism mediated by those states. Moreover, despite the intense Dirac-mass disorder, the anticipated relationship Δ(r)∝n(r) is confirmed throughout and exhibits an electron–dopant interaction energy J* = 145 meV·nm². In addition, these observations reveal how magnetic dopant atoms actually generate the TI mass gap locally and that, to achieve the novel physics expected of time-reversal symmetry breaking TI materials, control of the resulting Dirac-mass gap disorder will be essential.« less

  11. Imaging Dirac-mass disorder from magnetic dopant atoms in the ferromagnetic topological insulator Crx(Bi0.1Sb0.9)2-xTe3

    SciTech Connect

    Lee, Inhee; Kim, Chung Koo; Lee, Jinho; Billinge, Simon J. L.; Zhong, Ruidan D.; Schneeloch, John A.; Liu, Tiansheng S.; Valla, Tonica; Tranquada, John M.; Gu, Genda D.; Davis, J. C. Séamus

    2015-01-20

    To achieve and use the most exotic electronic phenomena predicted for the surface states of 3D topological insulators (TIs), it is necessary to open a “Dirac-mass gap” in their spectrum by breaking time-reversal symmetry. Use of magnetic dopant atoms to generate a ferromagnetic state is the most widely applied approach. However, it is unknown how the spatial arrangements of the magnetic dopant atoms influence the Dirac-mass gap at the atomic scale or, conversely, whether the ferromagnetic interactions between dopant atoms are influenced by the topological surface states. Here we image the locations of the magnetic (Cr) dopant atoms in the ferromagnetic TI Cr₀.₀₈(Bi₀.₁Sb₀.₉)₁.₉₂Te₃. Simultaneous visualization of the Dirac-mass gap Δ(r) reveals its intense disorder, which we demonstrate is directly related to fluctuations in n(r), the Cr atom areal density in the termination layer. We find the relationship of surface-state Fermi wavevectors to the anisotropic structure of Δ(r) not inconsistent with predictions for surface ferromagnetism mediated by those states. Moreover, despite the intense Dirac-mass disorder, the anticipated relationship Δ(r)∝n(r) is confirmed throughout and exhibits an electron–dopant interaction energy J* = 145 meV·nm². In addition, these observations reveal how magnetic dopant atoms actually generate the TI mass gap locally and that, to achieve the novel physics expected of time-reversal symmetry breaking TI materials, control of the resulting Dirac-mass gap disorder will be essential.

  12. Stratified magnetically driven accretion-disk winds and their relations to jets

    SciTech Connect

    Fukumura, Keigo; Tombesi, Francesco; Kazanas, Demosthenes; Shrader, Chris; Contopoulos, Ioannis

    2014-01-10

    We explore the poloidal structure of two-dimensional magnetohydrodynamic (MHD) winds in relation to their potential association with the X-ray warm absorbers (WAs) and the highly ionized ultra-fast outflows (UFOs) in active galactic nuclei (AGNs), in a single unifying approach. We present the density n(r, ?), ionization parameter ?(r, ?), and velocity structure v(r, ?) of such ionized winds for typical values of their fluid-to-magnetic flux ratio, F, and specific angular momentum, H, for which wind solutions become super-Alfvnic. We explore the geometrical shape of winds for different values of these parameters and delineate the values that produce the widest and narrowest opening angles of these winds, quantities necessary in the determination of the statistics of AGN obscuration. We find that winds with smaller H show a poloidal geometry of narrower opening angles with their Alfvn surface at lower inclination angles and therefore they produce the highest line of sight (LoS) velocities for observers at higher latitudes with the respect to the disk plane. We further note a physical and spatial correlation between the X-ray WAs and UFOs that form along the same LoS to the observer but at different radii, r, and distinct values of n, ?, and v consistent with the latest spectroscopic data of radio-quiet Seyfert galaxies. We also show that, at least in the case of 3C 111, the winds' pressure is sufficient to contain the relativistic plasma responsible for its radio emission. Stratified MHD disk winds could therefore serve as a unique means to understand and unify the diverse AGN outflows.

  13. CHEMICAL AND PHYSICAL CONDITIONS IN MOLECULAR CLOUD CORE DC 000.4-19.5 (SL42) IN CORONA AUSTRALIS

    SciTech Connect

    Hardegree-Ullman, E.; Whittet, D. C. B.; Harju, J.; Juvela, M.; Sipilae, O.; Hotzel, S.

    2013-01-20

    Chemical reactions in starless molecular clouds are heavily dependent on interactions between gas phase material and solid phase dust and ices. We have observed the abundance and distribution of molecular gases in the cold, starless core DC 000.4-19.5 (SL42) in Corona Australis using data from the Swedish ESO Submillimeter Telescope. We present column density maps determined from measurements of C{sup 18}O (J = 2-1, 1-0) and N{sub 2}H{sup +} (J = 1-0) emission features. Herschel data of the same region allow a direct comparison to the dust component of the cloud core and provide evidence for gas phase depletion of CO at the highest extinctions. The dust color temperature in the core calculated from Herschel maps ranges from roughly 10.7 to 14.0 K. This range agrees with the previous determinations from Infrared Space Observatory and Planck observations. The column density profile of the core can be fitted with a Plummer-like density distribution approaching n(r) {approx} r {sup -2} at large distances. The core structure deviates clearly from a critical Bonnor-Ebert sphere. Instead, the core appears to be gravitationally bound and to lack thermal and turbulent support against the pressure of the surrounding low-density material: it may therefore be in the process of slow contraction. We test two chemical models and find that a steady-state depletion model agrees with the observed C{sup 18}O column density profile and the observed N(C{sup 18}O) versus A{sub V} relationship.

  14. Effect of Divalent Cation Removal on the Structure of Gram-Negative Bacterial Outer Membrane Models

    DOE PAGES [OSTI]

    Clifton, Luke A.; Skoda, Maximilian W. A.; Le Brun, Anton P.; Ciesielski, Filip; Kuzmenko, Ivan; Holt, Stephen A.; Lakey, Jeremy H.

    2014-12-09

    The Gram-negative bacterial outer membrane (GNB-OM) is asymmetric in its lipid composition with a phospholipid-rich inner leaflet and an outer leaflet predominantly composed of lipopolysaccharides (LPS). LPS are polyanionic molecules, with numerous phosphate groups present in the lipid A and core oligosaccharide regions. The repulsive forces due to accumulation of the negative charges are screened and bridged by the divalent cations (Mg2+ and Ca2+) that are known to be crucial for the integrity of the bacterial OM. Indeed, chelation of divalent cations is a well-established method to permeabilize Gram-negative bacteria such as Escherichia coli. Here, we use X-ray and neutronmore » reflectivity (XRR and NR, respectively) techniques to examine the role of calcium ions in the stability of a model GNB-OM. Using XRR we show that Ca2+ binds to the core region of the rough mutant LPS (RaLPS) films, producing more ordered structures in comparison to divalent cation free monolayers. Using recently developed solid-supported models of the GNB-OM, we study the effect of calcium removal on the asymmetry of DPPC:RaLPS bilayers. We show that without the charge screening effect of divalent cations, the LPS is forced to overcome the thermodynamically unfavorable energy barrier and flip across the hydrophobic bilayer to minimize the repulsive electrostatic forces, resulting in about 20% mixing of LPS and DPPC between the inner and outer bilayer leaflets. These results reveal for the first time the molecular details behind the well-known mechanism of outer membrane stabilization by divalent cations. This confirms the relevance of the asymmetric models for future studies of outer membrane stability and antibiotic penetration.« less

  15. Effect of Divalent Cation Removal on the Structure of Gram-Negative Bacterial Outer Membrane Models

    SciTech Connect

    Clifton, Luke A.; Skoda, Maximilian W. A.; Le Brun, Anton P.; Ciesielski, Filip; Kuzmenko, Ivan; Holt, Stephen A.; Lakey, Jeremy H.

    2014-12-09

    The Gram-negative bacterial outer membrane (GNB-OM) is asymmetric in its lipid composition with a phospholipid-rich inner leaflet and an outer leaflet predominantly composed of lipopolysaccharides (LPS). LPS are polyanionic molecules, with numerous phosphate groups present in the lipid A and core oligosaccharide regions. The repulsive forces due to accumulation of the negative charges are screened and bridged by the divalent cations (Mg2+ and Ca2+) that are known to be crucial for the integrity of the bacterial OM. Indeed, chelation of divalent cations is a well-established method to permeabilize Gram-negative bacteria such as Escherichia coli. Here, we use X-ray and neutron reflectivity (XRR and NR, respectively) techniques to examine the role of calcium ions in the stability of a model GNB-OM. Using XRR we show that Ca2+ binds to the core region of the rough mutant LPS (RaLPS) films, producing more ordered structures in comparison to divalent cation free monolayers. Using recently developed solid-supported models of the GNB-OM, we study the effect of calcium removal on the asymmetry of DPPC:RaLPS bilayers. We show that without the charge screening effect of divalent cations, the LPS is forced to overcome the thermodynamically unfavorable energy barrier and flip across the hydrophobic bilayer to minimize the repulsive electrostatic forces, resulting in about 20% mixing of LPS and DPPC between the inner and outer bilayer leaflets. These results reveal for the first time the molecular details behind the well-known mechanism of outer membrane stabilization by divalent cations. This confirms the relevance of the asymmetric models for future studies of outer membrane stability and antibiotic penetration.

  16. Transcription factor FOXA2-centered transcriptional regulation network in non-small cell lung cancer

    SciTech Connect

    Jang, Sang-Min; An, Joo-Hee; Kim, Chul-Hong; Kim, Jung-Woong Choi, Kyung-Hee

    2015-08-07

    Lung cancer is the leading cause of cancer-mediated death. Although various therapeutic approaches are used for lung cancer treatment, these mainly target the tumor suppressor p53 transcription factor, which is involved in apoptosis and cell cycle arrest. However, p53-targeted therapies have limited application in lung cancer, since p53 is found to be mutated in more than half of lung cancers. In this study, we propose tumor suppressor FOXA2 as an alternative target protein for therapies against lung cancer and reveal a possible FOXA2-centered transcriptional regulation network by identifying new target genes and binding partners of FOXA2 by using various screening techniques. The genes encoding Glu/Asp-rich carboxy-terminal domain 2 (CITED2), nuclear receptor subfamily 0, group B, member 2 (NR0B2), cell adhesion molecule 1 (CADM1) and BCL2-associated X protein (BAX) were identified as putative target genes of FOXA2. Additionally, the proteins including highly similar to heat shock protein HSP 90-beta (HSP90A), heat shock 70 kDa protein 1A variant (HSPA1A), histone deacetylase 1 (HDAC1) and HDAC3 were identified as novel interacting partners of FOXA2. Moreover, we showed that FOXA2-dependent promoter activation of BAX and p21 genes is significantly reduced via physical interactions between the identified binding partners and FOXA2. These results provide opportunities to understand the FOXA2-centered transcriptional regulation network and novel therapeutic targets to modulate this network in p53-deficient lung cancer. - Highlights: • Identification of new target genes of FOXA2. • Identifications of novel interaction proteins of FOXA2. • Construction of FOXA2-centered transcriptional regulatory network in non-small cell lung cancer.

  17. Transcriptome Analysis in Sheepgrass (Leymus chinensis). A Dominant Perennial Grass of the Eurasian Steppe

    SciTech Connect

    Chen, Shuangyan; Huang, Xin; Yang, Xiaohan; Liu, Gongshe

    2013-07-04

    BACKGROUND: Sheepgrass [Leymus chinensis (Trin.) Tzvel.] is an important perennial forage grass across the Eurasian Steppe and is known for its adaptability to various environmental conditions. However, insufficient data resources in public databases for sheepgrass limited our understanding of the mechanism of environmental adaptations, gene discovery and molecular marker development. RESULTS: The transcriptome of sheepgrass was sequenced using Roche 454 pyrosequencing technology. We assembled 952,328 high-quality reads into 87,214 unigenes, including 32,416 contigs and 54,798 singletons. There were 15,450 contigs over 500 bp in length. BLAST searches of our database against Swiss-Prot and NCBI non-redundant protein sequences (nr) databases resulted in the annotation of 54,584 (62.6%) of the unigenes. Gene Ontology (GO) analysis assigned 89,129 GO term annotations for 17,463 unigenes. We identified 11,675 core Poaceae-specific and 12,811 putative sheepgrass-specific unigenes by BLAST searches against all plant genome and transcriptome databases. A total of 2,979 specific freezing-responsive unigenes were found from this RNAseq dataset. We identified 3,818 EST-SSRs in 3,597 unigenes, and some SSRs contained unigenes that were also candidates for freezing-response genes. Characterizations of nucleotide repeats and dominant motifs of SSRs in sheepgrass were also performed. Similarity and phylogenetic analysis indicated that sheepgrass is closely related to barley and wheat. CONCLUSIONS: This research has greatly enriched sheepgrass transcriptome resources. The identified stress-related genes will help us to decipher the genetic basis of the environmental and ecological adaptations of this species and will be used to improve wheat and barley crops through hybridization or genetic transformation. The EST-SSRs reported here will be a valuable resource for future gene-phenotype studies and for the molecular breeding of sheepgrass and other Poaceae species.

  18. Synthesis, Protonation, and Reduction of Ruthenium–Peroxo Complexes with Pendent Nitrogen Bases

    SciTech Connect

    Tronic, Tristan A.; Kaminsky, Werner; Coggins, Michael K.; Mayer, James M.

    2012-10-15

    Cyclopentadienyl and pentamethylcyclopentadienyl ruthenium(II) complexes have been synthesized with cyclic (RPCH2NR'CH2)2 ligands, with the goal of using these [CpR"Ru(PR2NR'2)]+ complexes for catalytic O2 reduction to H2O (R = t-butyl, phenyl; R' = benzyl, phenyl; R" = methyl, H). In each compound, the Ru is coordinated to the two phosphines, positioning the amines of the ligand in the second coordination sphere where they may act as proton relays to a bound dioxygen ligand. The phosphine, amine, and cyclopentadienyl substituents have been systematically varied in order to understand the effects of each of these parameters on the properties of the complexes. These CpR"Ru(PR2NR'2)+ complexes react with O2 to form η2-peroxo complexes, which have been characterized by NMR, IR, and X-ray crystallography. The peak reduction potentials of the O2 ligated complexes have been shown by cyclic voltammetry to vary as much as 0.1 V upon varying the phosphine and amine. In the presence of acid, protonation of these complexes occurs at the pendent amine, forming a hydrogen bond between the protonated amine and the bound O2. The ruthenium–peroxo complexes decompose upon reduction, precluding catalytic O2 reduction. Finally, the irreversible reduction potentials of the protonated O2 complexes depend on the basicity of the pendent amine, giving insight into the role of the proton relay in facilitating reduction.

  19. Synthesis, structure, and coordination chemistry of a tridentate, six-electron-donor amidinate ligand

    SciTech Connect

    Kincaid, K.; Gerlach, C.P.; Giesbrecht, G.R.; Hagadorn, J.R.; Whitener, G.D.; Shafir, A.; Arnold, J.

    1999-12-06

    The coordination chemistry of ancillary amidinate ligands with a pendant pyridine functionality is described. Reaction of p-toluoyl- or p-tBu benzoyl chloride with 2-amino-ethylpyridine generates the amides 2-Py-(CH{sub 2}){sub 2}NHCO(p-RPh) (R = Me 1a tBu 1b); these amides are then converted to the amidines 2-Py-(CH{sub 2}){sub 2}NHC(p-RPh)NR{prime} (R = Me, R{prime} = Ph (2a) (L{sup Me}H); R = tBu, R{prime} = 3,5-dimethylphenyl (2b) (L{sup tBu}H)) by reaction with PCl{sub 5} followed by R{prime}NH{sub 2}. The amidines 2a,b were characterized by {sup 1}H NMR and IR spectroscopy and elemental analyses, and 2b was characterized by X-ray crystallography. Reaction of 2a or 2b with homoleptic metal-alkyls or -amides yields the mono- or bis(amidinate) complexes (L{sup Me}){sub 2}Mg (3a), (L{sup tBu})AlMe{sub 2} (4), (L{sup tBu})Zr(CH{sub 2}Ph){sub 3} (5), and (L{sup Me}){sub 2}La[N(SiMe{sub 3}){sub 2}] (6). All metal complexes were characterized by {sup 1}H NMR and IR spectroscopy, elemental analyses, and X-ray crystallography. The X-ray crystal structures of compounds 3--6 show them to be monomeric, with the pendant pyridine coordinates intramolecularly in all cases. The tridentate amidinate coordinates meridionally to the metal center except in the case of the lanthanum derivative 6, where an approximate facial geometry is observed.

  20. Reactions of isocyanide-substituted dimanganese carbonyl complexes with alkynes. Alkyne-isocyanide coupling and the synthesis of metalated n-substituted pyridines

    SciTech Connect

    Adams, R.D.; Huang, M. )

    1995-01-01

    When activated by Me[sub 3]NO in the presence of MeCN, the compounds Mn[sub 2](CO)[sub 9](CNR) (la,b; R = Me, Ph) react with MeO[sub 2]O[sub 2]CC[triple bond]CCO[sub 2]Me to yield the new compounds Mn[sub 2](CO)[sub 8][[mu]-(MeO[sub 2]C)C=C(CO[sub 2]Me)C=NR] (2a,b; R = Me, Ph) in yields of 40% and 32%, respectively. Minor products, Mn[sub 2](CO)[sub 7](CNR)[[mu]-(MeO[sub 2]C)C=C(CO[sub 2]Me)-C=O] (3a,b; R = Me, Ph) were also formed. Compound 2a was characterized crystallographically. The structure shows that the isocyanide ligand was coupled to the alkyne, and the nitrogen atom is coordinated to one of the manganese atoms to form a five-membered cyclo-mangana enimine ring. One of the carboxylate groups is coordinated to the other manganese atom. The compounds (4a), (4b), and (4c) were prepared in yields of 27%, 32%, and 31%, respectively, by treatment of 2a,b with C[sub 2]H[sub 2], and of 2a with HC[sub 2](CO[sub 2]Me) in the presence of UV irradiation. Compound 4a was characterized crystallographically. This compound contains a metalated N-methylpyridine ring formed by a 1,4-cycloaddition of the alkyne to the enimine grouping in compound 2a. One of the metal atoms was shifted to a n-bonding coordination involving four of the carbon atoms of the pyridine ring. 14 refs., 2 figs., 7 tabs.

  1. METAL ABUNDANCES, RADIAL VELOCITIES, AND OTHER PHYSICAL CHARACTERISTICS FOR THE RR LYRAE STARS IN THE KEPLER FIELD

    SciTech Connect

    Nemec, James M.; Cohen, Judith G.; Sesar, Branimir; Ripepi, Vincenzo; Derekas, Aliz; Moskalik, Pawel; Chadid, Merieme; Bruntt, Hans E-mail: jmn@isr.bc.ca E-mail: bsesar@astro.caltech.edu E-mail: derekas@konkoly.hu E-mail: chadid@marseille.fr

    2013-08-20

    Spectroscopic iron-to-hydrogen ratios, radial velocities, atmospheric parameters, and new photometric analyses are presented for 41 RR Lyrae stars (and one probable high-amplitude {delta} Sct star) located in the field-of-view of the Kepler space telescope. Thirty-seven of the RR Lyrae stars are fundamental-mode pulsators (i.e., RRab stars) of which sixteen exhibit the Blazhko effect. Four of the stars are multiperiodic RRc pulsators oscillating primarily in the first-overtone mode. Spectroscopic [Fe/H] values for the 34 stars for which we were able to derive estimates range from -2.54 {+-} 0.13 (NR Lyr) to -0.05 {+-} 0.13 dex (V784 Cyg), and for the 19 Kepler-field non-Blazhko stars studied by Nemec et al. the abundances agree will with their photometric [Fe/H] values. Four non-Blazhko RR Lyrae stars that they identified as metal-rich (KIC 6100702, V2470 Cyg, V782 Cyg and V784 Cyg) are confirmed as such, and four additional stars (V839 Cyg, KIC 5520878, KIC 8832417, KIC 3868420) are also shown here to be metal-rich. Five of the non-Blazhko RRab stars are found to be more metal-rich than [Fe/H] {approx}-0.9 dex while all of the 16 Blazhko stars are more metal-poor than this value. New P-{phi}{sub 31}{sup s}-[Fe/H] relationships are derived based on {approx}970 days of quasi-continuous high-precision Q0-Q11 long- and short-cadence Kepler photometry. With the exception of some Blazhko stars, the spectroscopic and photometric [Fe/H] values are in good agreement. Several stars with unique photometric characteristics are identified, including a Blazhko variable with the smallest known amplitude and frequency modulations (V838 Cyg)

  2. Validation of New Process Models for Large Injection-Molded Long-Fiber Thermoplastic Composite Structures

    SciTech Connect

    Nguyen, Ba Nghiep; Jin, Xiaoshi; Wang, Jin; Kunc, Vlastimil; Tucker III, Charles L.

    2012-02-23

    This report describes the work conducted under the CRADA Nr. PNNL/304 between Battelle PNNL and Autodesk whose objective is to validate the new process models developed under the previous CRADA for large injection-molded LFT composite structures. To this end, the ARD-RSC and fiber length attrition models implemented in the 2013 research version of Moldflow was used to simulate the injection molding of 600-mm x 600-mm x 3-mm plaques from 40% glass/polypropylene (Dow Chemical DLGF9411.00) and 40% glass/polyamide 6,6 (DuPont Zytel 75LG40HSL BK031) materials. The injection molding was performed by Injection Technologies, Inc. at Windsor, Ontario (under a subcontract by Oak Ridge National Laboratory, ORNL) using the mold offered by the Automotive Composite Consortium (ACC). Two fill speeds under the same back pressure were used to produce plaques under slow-fill and fast-fill conditions. Also, two gating options were used to achieve the following desired flow patterns: flows in edge-gated plaques and in center-gated plaques. After molding, ORNL performed measurements of fiber orientation and length distributions for process model validations. The structure of this report is as follows. After the Introduction (Section 1), Section 2 provides a summary of the ARD-RSC and fiber length attrition models. A summary of model implementations in the latest research version of Moldflow is given in Section 3. Section 4 provides the key processing conditions and parameters for molding of the ACC plaques. The validations of the ARD-RSC and fiber length attrition models are presented and discussed in Section 5. The conclusions will be drawn in Section 6.

  3. Improving in vitro Sertoli cell/gonocyte co-culture model for assessing male reproductive toxicity: Lessons learned from comparisons of cytotoxicity versus genomic responses to phthalates

    SciTech Connect

    Yu Xiaozhong; Hong, Sung Woo; Moreira, Estefania G.; Faustman, Elaine M.

    2009-09-15

    Gonocytes exist in the neonatal testis and represent a transient population of male germ-line stem cells. It has been shown that stem cell self-renewal and progeny production is probably controlled by the neighboring differentiated cells and extracellular matrix (ECM) in vivo known as niches. Recently, we developed an in vitro three-dimensional (3D) Sertoli cell/gonocyte co-culture (SGC) model with ECM overlay, which creates an in vivo-like niche and supports germ-line stem cell functioning within a 3D environment. In this study, we applied morphological and cytotoxicity evaluations, as well as microarray-based gene expression to examine the effects of different phthalate esters (PE) on this model. Known in vivo male developmentally toxic PEs (DTPE) and developmentally non-toxic PEs (DNTPE) were evaluated. We observed that DTPE induced significantly greater dose-dependent morphological changes, a decrease in cell viability and an increase in cytotoxicity compared to those treated with DNTPE. Moreover, the gene expression was more greatly altered by DTPE than by DNTPE and non-supervised cluster analysis allowed the discrimination of DTPE from the DNTPE. Our systems-based GO-Quant analysis showed significant alterations in the gene pathways involved in cell cycle, phosphate transport and apoptosis regulation with DTPE but not with DNTPE treatment. Disruptions of steroidogenesis related-gene expression such as Star, Cyp19a1, Hsd17b8, and Nr4a3 were observed in the DTPE group, but not in the DNTPE group. In summary, our observation on cell viability, cytotoxicity, and microarray-based gene expression analysis induced by PEs demonstrate that our in vitro 3D-SGC system mimicked in vivo responses for PEs and suggests that the 3D-SGC system might be useful in identifying developmental reproductive toxicants.

  4. Modeling hot gas flow in the low-luminosity active galactic nucleus of NGC 3115

    SciTech Connect

    Shcherbakov, Roman V.; Reynolds, Christopher S.; Wong, Ka-Wah; Irwin, Jimmy A.

    2014-02-20

    Based on the dynamical black hole (BH) mass estimates, NGC 3115 hosts the closest billion solar mass BH. Deep studies of the center revealed a very underluminous active galactic nucleus (AGN) immersed in an old massive nuclear star cluster. Recent 1 Ms Chandra X-ray visionary project observations of the NGC 3115 nucleus resolved hot tenuous gas, which fuels the AGN. In this paper we connect the processes in the nuclear star cluster with the feeding of the supermassive BH. We model the hot gas flow sustained by the injection of matter and energy from the stars and supernova explosions. We incorporate electron heat conduction as the small-scale feedback mechanism, the gravitational pull of the stellar mass, cooling, and Coulomb collisions. Fitting simulated X-ray emission to the spatially and spectrally resolved observed data, we find the best-fitting solutions with ?{sup 2}/dof = 1.00 for dof = 236 both with and without conduction. The radial modeling favors a low BH mass <1.3 10{sup 9} M {sub ?}. The best-fitting supernova rate and the best-fitting mass injection rate are consistent with their expected values. The stagnation point is at r {sub st} ? 1'', so that most of the gas, including the gas at a Bondi radius r{sub B} = 2''-4'', outflows from the region. We put an upper limit on the accretion rate at 2 10{sup 3} M {sub ?} yr{sup 1}. We find a shallow density profile n?r {sup ?} with ? ? 1 over a large dynamic range. This density profile is determined in the feeding region 0.''5-10'' as an interplay of four processes and effects: (1) the radius-dependent mass injection, (2) the effect of the galactic gravitational potential, (3) the accretion flow onset at r ? 1'', and (4) the outflow at r ? 1''. The gas temperature is close to the virial temperature T{sub v} at any radius.

  5. P3HT-b-PS Copolymers as P3HT/PCBM Interfacial Compatibilizers for High Efficiency Photovoltaics

    SciTech Connect

    Sun, Zhenzhong; Xiao, Kai; Yu, Xiang; Hong, Kunlun; Keum, Jong Kahk; Browning, Jim; Ivanov, Ilia N; Chen, Jihua; Alonzo Calderon, Jose E; Sumpter, Bobby G; Payzant, E Andrew; Rouleau, Christopher M; Geohegan, David B

    2011-01-01

    To control the donor-acceptor phase separation for more efficient organic bulk heterojunction photovoltaic cells, poly(3-hexylthiophene)-block-polystyrene (P3HT-b-PS) diblock copolymer was added to serve as a compatibilizer in a P3HT/ [6,6]-phenyl-C61-butyric acid methyl ester fullerene derivative (PCBM) blend. An addition of 5 wt% of P3HT-b-PS copolymer in the P3HT/PCBM blend improved the power-conversion efficiency from 3.3% to 4.1% due to an enhancement of both the short-circuit current density and fill factor compared to that of a pristine P3HT/PCBM solar cell. Grazing incidence x-ray scattering (GIXS), absorption spectroscopy and carrier mobility studies reveal that the crystallinity and orientation of P3HT were improved, thereby enhancing hole transport in the P3HT polymer, and leading to a better balance between the electron and hole mobilities in the P3HT/PCBM active layer. Neutron reflectometry (NR) experiments demonstrate that a distinct scattering length density profile shows the highest PCBM concentration in the middle layer region and a more compact and homogeneous layer, presumably due to an increase in miscibility of P3HT and PCBM driven by the copolymer compatibilizer, while adding 5 wt% of P3HT-b-PS copolymer in the P3HT/PCBM blend. Quantum density functional theory calculations show that the P3HT-b-PS additive tends to promote microphase segregation, with the PCBM attracted to the PS block, and the P3HT stacking onto the P3HT block, which presumably leads to improvements in long-range crystallinity , consistent with the GIXS findings. Overall, the results for P3HT-b-PS copolymer in a P3HT/PCBM blend demonstrate that tailored block copolymers can act as an effective compatibilizer in blended systems to further improve solar cell performance

  6. Amino acid modified Ni catalyst exhibits reversible H2 oxidation/production over a broad pH range at elevated temperatures

    SciTech Connect

    Dutta, Arnab; DuBois, Daniel L.; Roberts, John A.; Shaw, Wendy J.

    2014-11-18

    Hydrogenases interconvert H2 and protons at high rates and with high energy efficiencies, providing inspiration for the development of molecular catalysts. Studies designed to determine how the protein scaffold can influence a catalytically active site has led to the synthesis of amino acid derivatives, [Ni(PCy2NAmino acid2)2]2+ (CyAA), of [Ni(PR2NR'2)2]2+ complexes. It is shown that these CyAA derivatives can catalyze fully reversible H2 production/oxidation, a feature reminiscent of enzymes. The reversibility is achieved in acidic aqueous solutions, 0.25% H2/Ar, and elevated temperatures (tested up to 348 K) for the glycine (CyGly), arginine (CyArg), and arginine methyl ester (CyArgOMe) derivatives. As expected for a reversible process, the activity is dependent upon H2 and proton concentration. CyArg is significantly faster in both directions than the other two derivatives (~300 s-1 H2 production and 20 s-1 H2 oxidation; pH=1, 348 K). The significantly slower rates for CyArgOMe (35 s-1 production and 7 s-1 oxidation) compared to CyArg suggests an important role for the COOH group during catalysis. That CyArg is faster than CyGly (3 s-1 production and 4 s-1 oxidation under the same conditions) suggests that the additional structural features imparted by the guanidinium groups facilitate fast and reversible H2 addition/release. These observations demonstrate that appended, outer coordination sphere amino acids work in synergy with the active site and can play an equally important role for synthetic molecular electrocatalysts as the protein scaffold does for redox active enzymes. This work was funded by the Office of Science Early Career Research Program through the US DOE, BES (AD, WJS), and the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US DOE, BES (DLD, JASR). PNNL is operated by Battelle for the US DOE.

  7. Ortho-aminoazotoluene activates mouse constitutive androstane receptor (mCAR) and increases expression of mCAR target genes

    SciTech Connect

    Smetanina, Mariya A.; Pakharukova, Mariya Y.; Kurinna, Svitlana M.; Dong, Bingning; Hernandez, Juan P.; Moore, David D.; Merkulova, Tatyana I.

    2011-08-15

    2'-3-dimethyl-4-aminoazobenzene (ortho-aminoazotoluene, OAT) is an azo dye and a rodent carcinogen that has been evaluated by the International Agency for Research on Cancer (IARC) as a possible (class 2B) human carcinogen. Its mechanism of action remains unclear. We examined the role of the xenobiotic receptor Constitutive Androstane Receptor (CAR, NR1I3) as a mediator of the effects of OAT. We found that OAT increases mouse CAR (mCAR) transactivation in a dose-dependent manner. This effect is specific because another closely related azo dye, 3'-methyl-4-dimethyl-aminoazobenzene (3'MeDAB), did not activate mCAR. Real-time Q-PCR analysis in wild-type C57BL/6 mice revealed that OAT induces the hepatic mRNA expression of the following CAR target genes: Cyp2b10, Cyp2c29, Cyp3a11, Ugt1a1, Mrp4, Mrp2 and c-Myc. CAR-null (Car{sup -/-}) mice showed no increased expression of these genes following OAT treatment, demonstrating that CAR is required for their OAT dependent induction. The OAT-induced CAR-dependent increase of Cyp2b10 and c-Myc expression was confirmed by Western blotting. Immunohistochemistry analysis of wild-type and Car{sup -/-} livers showed that OAT did not acutely induce hepatocyte proliferation, but at much later time points showed an unexpected CAR-dependent proliferative response. These studies demonstrate that mCAR is an OAT xenosensor, and indicate that at least some of the biological effects of this compound are mediated by this nuclear receptor. - Highlights: > The azo dye and mouse carcinogen OAT is a very effective mCAR activator. > OAT increases mCAR transactivation in a dose-dependent manner. > OAT CAR-dependently increases the expression of a specific subset of CAR target genes. > OAT induces an unexpectedly deferred, but CAR-dependent hepatocyte proliferation.

  8. Investigation of the in vitro toxicological properties of the synthetic cannabimimetic drug CP-47,497-C8

    SciTech Connect

    Koller, Verena J.; Auwärter, Volker; Grummt, Tamara; Moosmann, Bjoern; Mišík, Miroslav; Knasmüller, Siegfried

    2014-06-01

    Cannabicyclohexanol (CP-47,497-C8) is a representative of a group of cannabimimetic cyclohexylphenols which is added to herbal mixtures as a cannabis substitute since 2008. Although in the beginning CP-47,497-C8 was the main ingredient of “Spice” and similar products, it was partly replaced by aminoalkylindole-type cannabinoid receptor agonists like JWH-018, JWH-073 or JWH-250, but never completely disappeared from the market. Since information on its toxicological properties is scarce, we investigated the effects of the drug in human derived cell lines. The cytotoxic effects were studied in a panel of assays (SRB, XTT, LDHe and NR tests) in a buccal derived (TR146) and a liver derived (HepG2) cell line. The strongest effects were seen in the two former assays at levels ≥ 7.5 μM indicating that the compound interferes with protein synthesis and causes membrane damage. In additional comet assays, DNA damage was detected at levels ≥ 10 μM. Experiments with lesion specific enzymes showed that these effects are not due to oxidative damage of DNA bases. The negative findings obtained in Salmonella/microsome assays and the positive results of micronucleus tests with the cell lines indicate that the compound does not cause gene mutations but acts on the chromosomal level. In contrast to other synthetic cannabinoids, no indication for estrogenic/antiestrogenic properties was seen in a luciferase assay with bone marrow derived U2-OS cells. In conclusion, our findings show that the drug has only weak cytotoxic properties. However, the induction of chromosomal damage indicates that it may cause adverse effects in users due to its impact on the stability of the genetic material. - Highlights: • We tested the toxic properties of a synthetic cannabinoid. • Acute cytotoxic effects were detected with doses ≥ 7 μM. • No hormonal effects were found. • DNA damage was detected at levels ≥ 10 μM in comet assay and micronucleus tests. • Effects in directly

  9. An in vitro investigation of endocrine disrupting effects of the mycotoxin alternariol

    SciTech Connect

    Frizzell, Caroline; Ndossi, Doreen; Kalayou, Shewit; Eriksen, Gunnar S.; Verhaegen, Steven; Srlie, Morten; Elliott, Christopher T.; Ropstad, Erik; Connolly, Lisa

    2013-08-15

    Alternariol (AOH) is a mycotoxin commonly produced by Alternaria alternata on a wide range of foods. Few studies to date have been performed to evaluate the effects of AOH on endocrine activity. The present study makes use of in vitro mammalian cellular based assays and gene expression to investigate the ability of AOH to act as an endocrine disruptor by various modes of action. Reporter gene assays (RGAs), incorporating natural steroid hormone receptors for oestrogens, androgens, progestagens and glucocorticoids were used to identify endocrine disruption at the level of nuclear receptor transcriptional activity, and the H295R steroidogenesis assay was used to assess endocrine disruption at the level of gene expression and steroid hormone production. AOH exhibited a weak oestrogenic response when tested in the oestrogen responsive RGA and binding of progesterone to the progestagen receptor was shown to be synergistically increased in the presence of AOH. H295R cells when exposed to 0.11000 ng/ml AOH, did not cause a significant change in testosterone and cortisol hormones but exposure to 1000 ng/ml (3.87 ?M) AOH resulted in a significant increase in estradiol and progesterone production. In the gene expression study following exposure to 1000 ng/ml (3.87 ?M) AOH, only one gene NR0B1 was down-regulated, whereas expression of mRNA for CYP1A1, MC2R, HSD3B2, CYP17, CYP21, CYP11B2 and CYP19 was up-regulated. Expression of the other genes investigated did not change significantly. In conclusion AOH is a weak oestrogenic mycotoxin that also has the ability to interfere with the steroidogenesis pathway. - Highlights: Alternariol was investigated for endocrine disrupting activity. Reporter gene assays and the H295R steroidogenesis assay have been used. An oestrogenic effect of alternariol was observed. This can lead to an increase in expression of the progesterone receptor. Alternariol is capable of modulating hormone production and gene expression.

  10. Evaluation of nitrogen-rich macrocyclic ligands for the chelation of therapeutic bismuth radioisotopes

    DOE PAGES [OSTI]

    Wilson, Justin J.; Ferrier, Maryline; Radchenko, Valery; Maassen, Joel R.; Engle, Jonathan W.; Batista, Enrique R.; Martin, Richard L.; Nortier, Francois M.; Fassbender, Michael E.; John, Kevin D.; et al

    2015-05-01

    The use of α-emitting isotopes for radionuclide therapy is a promising treatment strategy for small micro-metastatic disease. The radioisotope ²¹³Bi is a nuclide that has found substantial use for targeted α-therapy (TAT). The relatively unexplored aqueous chemistry of Bi³⁺, however, hinders the development of bifunctional chelating agents that can successfully deliver these Bi radioisotopes to the tumor cells. Here, a novel series of nitrogen-rich macrocyclic ligands is explored for their potential use as Bi-selective chelating agents. The ligands, 1,4,7,10-tetrakis(pyridin-2-ylmethyl)-1,4,7,10-tetraazacyclododecane (Lpy), 1,4,7,10-tetrakis(3-pyridazylmethyl)-1,4,7,10-tetraazacyclododecane (Lpyd), 1,4,7,10-tetrakis(4-pyrimidylmethyl)-1,4,7,10-tetraazacyclododecane (Lpyr), and 1,4,7,10-tetrakis(2-pyrazinylmethyl)-1,4,7,10-tetraazacyclododecane (Lpz), were prepared by a previously reported method and investigated here for their abilitiesmore » to bind Bi radioisotopes. The commercially available and commonly used ligands 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTA) and N-[(R)-2-amino-3-(p-isothiocyanato-phenyl)propyl]-trans-(S,S)- cyclohexane-1,2-diamine-N,N,N',N",N"-pentaacetic acid (CHX-A''-DTPA) were also explored for comparative purposes. Radio-thin-layer chromatography (TLC) was used to measure the binding kinetics and stabilities of the complexes formed. The long-lived isotope, ²⁰⁷Bi (t1/2 = 32 years), was used for these studies. Density functional theory (DFT) calculations were also employed to probe the ligand interactions with Bi³⁺ and the generator parent ion Ac³⁺.In contrast to DOTA and CHX-A''-DTPA, these nitrogen-rich macrocycles selectively chelate Bi³⁺ in the presence of the parent isotope Ac³⁺. Among the four tested, Lpy was found to exhibit optimal Bi³⁺-binding kinetics and complex stability. Lpy complexes Bi³⁺ more rapidly than DOTA, yet the resulting complexes are of similar stability. DFT

  11. Deep sequencing of the Camellia sinensis transcriptome revealed candidate genes for major metabolic pathways of tea-specific compounds

    SciTech Connect

    Shi, CY; Yang, H; Wei, CL; Yu, O; Zhang, ZZ; Sun, J; Wan, XC

    2011-01-01

    Tea is one of the most popular non-alcoholic beverages worldwide. However, the tea plant, Camellia sinensis, is difficult to culture in vitro, to transform, and has a large genome, rendering little genomic information available. Recent advances in large-scale RNA sequencing (RNA-seq) provide a fast, cost-effective, and reliable approach to generate large expression datasets for functional genomic analysis, which is especially suitable for non-model species with un-sequenced genomes. Using high-throughput Illumina RNA-seq, the transcriptome from poly (A){sup +} RNA of C. sinensis was analyzed at an unprecedented depth (2.59 gigabase pairs). Approximate 34.5 million reads were obtained, trimmed, and assembled into 127,094 unigenes, with an average length of 355 bp and an N50 of 506 bp, which consisted of 788 contig clusters and 126,306 singletons. This number of unigenes was 10-fold higher than existing C. sinensis sequences deposited in GenBank (as of August 2010). Sequence similarity analyses against six public databases (Uniprot, NR and COGs at NCBI, Pfam, InterPro and KEGG) found 55,088 unigenes that could be annotated with gene descriptions, conserved protein domains, or gene ontology terms. Some of the unigenes were assigned to putative metabolic pathways. Targeted searches using these annotations identified the majority of genes associated with several primary metabolic pathways and natural product pathways that are important to tea quality, such as flavonoid, theanine and caffeine biosynthesis pathways. Novel candidate genes of these secondary pathways were discovered. Comparisons with four previously prepared cDNA libraries revealed that this transcriptome dataset has both a high degree of consistency with previous EST data and an approximate 20 times increase in coverage. Thirteen unigenes related to theanine and flavonoid synthesis were validated. Their expression patterns in different organs of the tea plant were analyzed by RT-PCR and quantitative real

  12. Laser schlieren deflectometry for temperature analysis of filamentary non-thermal atmospheric pressure plasma

    SciTech Connect

    Schaefer, J.; Foest, R.; Reuter, S.; Weltmann, K.-D.; Kewitz, T.; Sperka, J.

    2012-10-15

    The heat convection generated by micro filaments of a self-organized non-thermal atmospheric pressure plasma jet in Ar is characterized by employing laser schlieren deflectometry (LSD). It is demonstrated as a proof of principle, that the spatial and temporal changes of the refractive index n in the optical beam path related to the neutral gas temperature of the plasma jet can be monitored and evaluated simultaneously. The refraction of a laser beam in a high gradient field of n(r) with cylindrical symmetry is given for a general real refraction index profile. However, the usually applied Abel approach represents an ill-posed problem and in particular for this plasma configuration. A simple analytical model is proposed in order to minimize the statistical error. Based on that, the temperature profile, specifically the absolute temperature in the filament core, the FWHM, and the frequencies of the collective filament dynamics are obtained for non-stationary conditions. For a gas temperature of 700 K inside the filament, the presented model predicts maximum deflection angles of the laser beam of 0.3 mrad which is in accordance to the experimental results obtained with LSD. Furthermore, the experimentally obtained FWHM of the temperature profile produced by the filament at the end of capillary is (1.5 {+-} 0.2) mm, which is about 10 times wider than the visual radius of the filament. The obtained maximum temperature in the effluent is (450 {+-} 30) K and is in consistence with results of other techniques. The study demonstrates that LSD represents a useful low-cost method for monitoring the spatiotemporal behaviour of microdischarges and allows to uncover their dynamic characteristics, e.g., the temperature profile even for challenging diagnostic conditions such as moving thin discharge filaments. The method is not restricted to the miniaturized and self-organized plasma studied here. Instead, it can be readily applied to other configurations that produce measurable

  13. Strategic Basis for License Application Planning for a Potential Yucca Mountain Repository

    SciTech Connect

    Newberry, C. M.; Brocoum, S. J.; Gamble, R. P.; Murray, R. C.; Cline, M.

    2002-02-26

    If Yucca Mountain, Nevada is designated as the site for development of a geologic repository for disposal of spent nuclear fuel and high-level radioactive waste, the Department of Energy (DOE) must obtain Nuclear Regulatory Commission (NRC) approval first for repository construction, then for an operating license, and, eventually, for repository closure and decommissioning. The licensing criteria defined in Code of Federal Regulations, Title 10, Part 63 (10 CFR Part 63) establish the basis for these NRC decisions. Submittal of a license application (LA) to the NRC for authorization to construct a repository at the Yucca Mountain site is, at this point, only a potential future action by the DOE. The policy process defined in the Nuclear Waste Policy Act (NWPA), as amended, for recommendation and designation of Yucca Mountain as a repository site makes it difficult to predict whether or when the site might be designated. The DOE may only submit a LA to the NRC if the site designation takes effect. In spite of this uncertainty, the DOE must take prudent and appropriate action now, and over the next several years, to prepare for development and timely submittal of a LA. This is particularly true given the need for the DOE to develop, load, and certify the operation of its electronic information system to provide access to its relevant records as part of the licensing support network (LSN) in compliance with NRC requirements six months prior to LA submittal. The DOE must also develop a LA, which is a substantially different document from those developed to support a Site Recommendation (SR) decision. The LA must satisfy NRC licensing criteria and content requirements, and address the acceptance criteria defined by the NRC in its forthcoming Yucca Mountain Review Plan (YMRP). The content of the LA must be adequate to facilitate NRC acceptance and docketing for review, and the LA and its supporting documents must provide the documented basis for the NR C findings required

  14. Advanced Test Reactor Core Modeling Update Project Annual Report for Fiscal Year 2012

    SciTech Connect

    David W. Nigg, Principal Investigator; Kevin A. Steuhm, Project Manager

    2012-09-01

    depletion HELIOS calculations for all ATR cycles since August 2009, Cycle 145A through Cycle 151B, was successfully completed during 2012. This major effort supported a decision late in the year to proceed with the phased incorporation of the HELIOS methodology into the ATR Core Safety Analysis Package (CSAP) preparation process, in parallel with the established PDQ-based methodology, beginning late in Fiscal Year 2012. Acquisition of the advanced SERPENT (VTT-Finland) and MC21 (DOE-NR) Monte Carlo stochastic neutronics simulation codes was also initiated during the year and some initial applications of SERPENT to ATRC experiment analysis were demonstrated. These two new codes will offer significant additional capability, including the possibility of full-3D Monte Carlo fuel management support capabilities for the ATR at some point in the future. Finally, a capability for rigorous sensitivity analysis and uncertainty quantification based on the TSUNAMI system has been implemented and initial computational results have been obtained. This capability will have many applications as a tool for understanding the margins of uncertainty in the new models as well as for validation experiment design and interpretation.

  15. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes

    SciTech Connect

    Guodong Du

    2004-12-19

    In this work, the first examples of group 4 metalloporphyrin 1,2-diolato complexes were synthesized through a number of strategies. In general, treatment of imido metalloporphyrin complexes, (TTP)M=NR, (M = Ti, Zr, Hf), with vicinal diols led to the formation of a series of diolato complexes. Alternatively, the chelating pinacolate complexes could be prepared by metathesis of (TTP)MCl{sub 2} (M = Ti, Hf) with disodium pinacolate. These complexes were found to undergo C-C cleavage reactions to produce organic carbonyl compounds. For titanium porphyrins, treatment of a titanium(II) alkyne adduct, (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh), with aromatic aldehydes or aryl ketones resulted in reductive coupling of the carbonyl groups to produce the corresponding diolato complexes. Aliphatic aldehydes or ketones were not reactive towards (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh). However, these carbonyl compounds could be incorporated into a diolato complex on reaction with a reactive precursor, (TTP)Ti[O(Ph){sub 2}C(Ph){sub 2}O] to provide unsymmetrical diolato complexes via cross coupling reactions. In addition, an enediolato complex (TTP)Ti(OCPhCPhO) was obtained from the reaction of (TTP)Ti({eta}{sup 2}-PhC{triple_bond}CPh) with benzoin. Titanium porphyrin diolato complexes were found to be intermediates in the (TTP)Ti=O-catalyzed cleavage reactions of vicinal diols, in which atmospheric oxygen was the oxidant. Furthermore, (TTP)Ti=O was capable of catalyzing the oxidation of benzyl alcohol and {alpha}-hydroxy ketones to benzaldehyde and {alpha}-diketones, respectively. Other high valent metalloporphyrin complexes also can catalyze the oxidative diol cleavage and the benzyl alcohol oxidation reactions with dioxygen. A comparison of Ti(IV) and Sn(IV) porphyrin chemistry was undertaken. While chelated diolato complexes were invariably obtained for titanium porphyrins on treatment with 1,2-diols, the reaction of vicinal diols with tin porphyrins gave a number of

  16. End Calorimeter Warm Tube Heater

    SciTech Connect

    Primdahl, K.; /Fermilab

    1991-08-06

    The Tevatron accelerator beam tube must pass through the End Calorimeter cryostats of the D-Zero Collider Detector. Furthermore, the End Calorimeter cryostats must be allowed to roll back forty inches without interruption of the vacuum system; hence, the Tev tube must slide through the End Calorimeter cryostat as it is rolled back. The Tev pass through the End Calorimeter can actually be thought of as a cluster of concentric tubes: Tev tube, warm (vacuum vessel) tube, IS layers of superinsulation, cold tube (argon vessel), and Inner Hadronic center support tube. M. Foley generated an ANSYS model to study the heat load. to the cryostat. during collider physics studies; that is, without operation of the heater. A sketch of the model is included in the appendix. The vacuum space and superinsulation was modeled as a thermal solid, with conductivity derived from tests performed at Fermilab. An additional estimate was done. by this author, using data supplied by NR-2. a superinsulation manufacturer. The ANSYS result and hand calculation are in close agreement. The ANSYS model was modified. by this author. to incorporate the effect of the heater. Whereas the earlier model studied steady state operation only. the revised model considers the heater-off steady state mode as the initial condition. then performs a transient analysis with a final load step for time tending towards infinity. Results show the thermal gradient as a function of time and applied voltage. It should be noted that M. Foley's model was generated for one half the warm tube. implying the tube to be symmetric. In reality. the downstream connection (relative to the collision point) attachment to the vacuum shell is via several convolutions of a 0.020-inch wall bellows; hence. a nearly adiabatic boundary condition. Accordingly. the results reported in the table reflect extrapolation of the curves to the downstream end of the tube. Using results from the ANSYS analysis, that is, tube temperature and

  17. Evaluation of Concepts for Mulitiple Application Thermal Reactor for Irradiation eXperiments (MATRIX)

    SciTech Connect

    Michael A. Pope; Hans D. Gougar; John M. Ryskamp

    2013-09-01

    The Advanced Test Reactor (ATR) is a high power density test reactor specializing in fuel and materials irradiation. For more than 45 years, the ATR has provided irradiations of materials and fuels testing along with radioisotope production. Originally operated primarily in support of the Offcie of Naval Reactors (NR), the mission has gradually expanded to cater to other customers, such as the DOE Office of Nuclear Energy (NE), private industry, and universities. Unforeseen circumstances may lead to the decommissioning of ATR, thus leaving the U.S. Government without a large-scale materials irradiation capability to meet the needs of its nuclear energy and naval reactor missions. In anticipation of this possibility, work was performed under the Laboratory Directed Research and Development (LDRD) program to investigate test reactor concepts that could satisfy the current missions of the ATR along with an expanded set of secondary missions. This work can be viewed as an update to a project from the 1990’s called the Broad Application Test Reactor (BATR). In FY 2012, a survey of anticipated customer needs was performed, followed by analysis of the original BATR concepts with fuel changed to low-enriched uranium. Departing from these original BATR designs, four concepts were identified for further analysis in FY2013. The project informally adopted the acronym MATRIX (Multiple-Application Thermal Reactor for Irradiation eXperiments). This report discusses analysis of the four MATRIX concepts along with a number of variations on these main concepts. Designs were evaluated based on their satisfaction of anticipated customer requirements and the “Cylindrical” variant was selected for further analysis of options. This downselection should be considered preliminary and the backup alternatives should include the other three main designs. The baseline Cylindrical MATRIX design is expected to be capable of higher burnup than the ATR (or longer cycle length given a

  18. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen

    SciTech Connect

    Yan, Ka King

    2013-05-02

    {sub 2}(NR{sub 2})ZrX (X = Cl, I, OTf; R = t-Bu, SiHMe{sub 2}) and lithium hydrosilazide ultimately afford hydride products Cp{sub 2}(NR{sub 2})ZrH that suggest unusual β-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp{sub 2}Zr[N(SiHMe{sub 2})t-Bu][N(SiHMe{sub 2}){sub 2}], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, γ-abstraction of a CH, and β-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride does not follow the classical four-center β- elimination mechanism. Elimination and abstraction reactions dominate the chemistry of ligands containing β- hydrogen. In contrast, Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}H and Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}Me undergo selective γ-CH bond activation to yield the azasilazirconacycle Cp{sub 2Zr}{κ{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}}, even though there are reactive β-hydrogen available for abstraction. The β-SiH groups in metallacycle provide access to new pathways for sixteen-electron zirconium alkyl compounds, in which Cp{sub 2}Zr{κ{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}} undergoes a rare σ-bond metathesis reaction with ethylene. The resulting vinyl intermediate undergoes β-hydrogen abstraction to reform ethylene and a silanimine zirconium species that reacts with ethylene to give a metallacyclopentane as the isolated product. The pendent β-SiH in metallocycle also reacts with paraformaldehyde through an uncatalyzed hydrosilylation to form an exocyclic methoxysilyl moiety, while the zirconium-carbon bond in metallocycle is surprisingly inert toward formaldehyde. Still, the Zr-C moiety in metallocycle is available for chemistry, and it interacts with the carbon monoxide and strong

  19. Final Report for Project: Impacts of stratification and non-equilibrium winds and waves on hub-height winds

    SciTech Connect

    Patton, Edward G.

    2015-07-14

    wind plant scale. Overall project conclusions include; In the presence of fast-moving swell (significant wave height Hs = 6.4 m, and phase speed cp = 18 ms-1), the atmospheric boundary layer grows more rapidly when waves propagate opposite to the winds compared to when winds and waves are aligned. Pressure drag increases by nearly a factor of 2 relative to the turbulent stress for the extreme case where waves propagate at 180° compared to the pressure gradient forcing. Net wind speed reduces by nearly 15% at hub-height for the 180°-case compared to the 0°-case, and turbulence intensities increase by nearly a factor of 2. These impacts diminish with decreasing wave age; Stratification increases hub height wind speeds and increases the vertical shear of the mean wind across the rotor plane. Fortuitously, this stability-induced enhanced shear does not influence turbulence intensity at hub height, but does increase (decrease) turbulence intensity below (above) hub height. Increased stability also increases the wave-induced pressure stress by ~ 10%; Off the East Coast of the United States during Coupled Boundary Layers Air-Sea Transfer - Low Wind (CBLAST-Low), cases with short fetch include thin stable boundary layers with depths of only a few tens of meters. In the coastal zone, the relationship between the mean wind and the surface fiction velocity (u*(V )) is significantly related to wind direction for weak winds but is not systematically related to the air sea difference of virtual potential temperature, δθv; since waves generally propagate from the south at the Air-Sea Interaction Tower (ASIT) tower, these results suggest that under weak wind conditions waves likely influence surface stress more than stratification does; and Winds and waves are frequently misaligned in the coastal zone. Stability conditions persist for long duration. Over a four year period, the Forschungsplattformen in Nord- und Ostsee Nr. 1 (FINO1) tower (a site with long fetch