National Library of Energy BETA

Sample records for infrared spectral radiance

  1. ARM - Measurement - Longwave spectral radiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    spectral radiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave spectral radiance The rate at which the spectrally resolved radiant energy in the longwave portion of the spectrum is emitted in a particular direction per unit area perpendicular to the direction of radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  2. ARM - Measurement - Shortwave spectral radiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    spectral radiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral radiance The rate at which the spectrally resolved radiant energy in the shortwave portion of the spectrum is emitted in a particular direction per unit area perpendicular to the direction of radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  3. Facility for spectral irradiance and radiance responsivity calibrations using uniform sources

    SciTech Connect (OSTI)

    Brown, Steven W.; Eppeldauer, George P.; Lykke, Keith R

    2006-11-10

    Detectors have historically been calibrated for spectral power responsivity at the National Institute of Standards and Technology by using a lamp-monochromator system to tune the wavelength of the excitation source. Silicon detectors can be calibrated in the visible spectral region with combined standard uncertainties at the 0.1% level. However,uncertainties increase dramatically when measuring an instrument's spectral irradiance or radiance responsivity. We describe what we believe to be a new laser-based facility for spectral irradiance and radiance responsivity calibrations using uniform sources (SIRCUS) that was developed to calibrate instruments directly in irradiance or radiance mode with uncertainties approaching or exceeding those available for spectral power responsivity calibrations. In SIRCUS, the emission from high-power, tunable lasers is introduced into an integrating sphere using optical fibers, producing uniform, quasi-Lambertian, high-radiant-flux sources. Reference standard irradiance detectors, calibrated directly against national primary standards for spectral power responsivity and aperture area measurement,are used to determine the irradiance at a reference plane. Knowing the measurement geometry, the source radiance can be readily determined as well. The radiometric properties of the SIRCUS source coupled with state-of-the-art transfer standard radiometers whose responsivities are directly traceable to primary national radiometric scales result in typical combined standard uncertainties in irradiance and radiance responsivity calibrations of less than 0.1%. The details of the facility and its effect on primary national radiometric scales are discussed.

  4. Initial analyses of surface spectral radiance between observations and Line-By-Line calculations

    SciTech Connect (OSTI)

    Brown, P.D.; Clough, S.A.; Miller, N.E.; Shippert, T.R.; Turner, D.D.

    1996-04-01

    The evaluation an improvement of radiative transfer calculations are essential to attain improved performance of general circulation models (GCMs) for climate change applications. A Quality Measurement Experiment (QME) is being conducted to analyze the spectral residuals between the downwelling longwave radiance measured by the University of Wisconsin Atmospheric Emitted Radiance Interferometer (AERI) and spectral radiance calculated by the Line-By-Line Radiative Transfer Model (LBLRTM). The three critical components of this study are (1) the assessment of the quality of the high resolution AERI measurements, (2) the assessment of the ability to define the atmospheric state in the radiating column, and (3) the evaluation of the capability of LBLRTM. Validations have been performed on spectral radiance data, obtained from April 1994 through July 1994, through the analysis of the spectral interval and physical process. The results are archived as a function of time, enabling the retrieval of specific data and facilitating investigations and diurnal effects, seasonal effects, and longer-term trends. While the initial focus is restricted to clear-sky analyses, efforts are under way to include the effects of clouds and aerosols. Plans are well formulated for the extension of the current approach to the shortwave. An overview of the concept of the QME is described by Miller et al. (1994), and a detailed description of this study is provided by Clough et al. (1994).

  5. Posters Residual Analysis of Surface Spectral Radiances Between...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... the future, will be taken from 915-MHz and 55-MHz radio acoustic sounding systems (RASS). ... Spectral Resolution (cm -1 ): 0.5 (wavenumber to first zero) Noise (670-1400 cm -1 ) (Wm ...

  6. Process of preparing metal parts to be heated by means of infrared radiance

    DOE Patents [OSTI]

    Mayer, Howard Robinson; Blue, Craig A.

    2009-06-09

    A method for preparing metal for heating by infrared radiance to enable uniform and consistent heating. The surface of one or more metal parts, such as aluminum or aluminum alloy parts, is treated to alter the surface finish to affect the reflectivity of the surface. The surface reflectivity is evaluated, such as by taking measurements at one or more points on the surface, to determine if a desired reflectivity has been achieved. The treating and measuring are performed until the measuring indicates that the desired reflectivity has been achieved. Once the treating has altered the surface finish to achieve the desired reflectivity, the metal part may then be exposed to infrared radiance to heat the metal part to a desired temperature, and that heating will be substantially consistent throughout by virtue of the desired reflectivity.

  7. Final Report: High Spectral Resolution Atmospheric Emitted Radiance Studies with the ARM UAV

    SciTech Connect (OSTI)

    Revercomb, Henry E.

    1999-12-31

    The active participation in the Atmospheric Radiation Measurement (ARM) Unmanned Airborne Vehicle (UAV) science team that was anticipated in the grant proposal was indefinitely delayed after the first year due to a programmatic decision to exclude the high spectral resolution observations from the existing ARM UAV program. However, this report shows that substantial progress toward the science objectives of this grant have made with the help of separate funding from NASA and other agencies. In the four year grant period (including time extensions), a new high spectral resolution instrument has been flown and has successfully demonstrated the ability to obtain measurements of the type needed in the conduct of this grant. In the near term, the third water vapor intensive observing period (WVIOP-3) in October 2000 will provide an opportunity to bring the high spectral resolution observations of upwelling radiance into the ARM program to complement the downwelling radiance observations from the existing ARM AERI instruments. We look forward to a time when the ARM-UAV program is able to extend its scope to include the capability for making these high spectral resolution measurements from a UAV platform.

  8. Posters Preliminary Analysis of Ground-Based Microwave and Infrared Radiance Observations

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    3 Posters Preliminary Analysis of Ground-Based Microwave and Infrared Radiance Observations During the Pilot Radiation OBservation Experiment E. R. Westwater, Y. Han, J. H. Churnside, and J. B. Snider National Oceanic and Atmospheric Administration Environmental Research Laboratories Environmental Technology Laboratory Boulder, Colorado Introduction During Phase Two of the Pilot Radiation OBservation Experiment (PROBE) held in Kavieng, Papua New Guinea (Renné et al. 1994), the National Oceanic

  9. Session Papers Preliminary Analysis of Ground-Based Microwave and Infrared Radiance Observations

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Session Papers Preliminary Analysis of Ground-Based Microwave and Infrared Radiance Observations During the Pilot Radiation OBservation Experiment E. R. Westwater, Y. Han, J. H. Churnside, and J. B. Snider National Oceanic and Atmospheric Administration Environmental Research Laboratories Environmental Technology Laboratory Boulder, Colorado Introduction During Phase Two of the Pilot Radiation OBservation Experiment (PROBE) held in Kavieng, Papua New Guinea (Renné et al. 1994), the National

  10. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    engineering data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): engineering data Atmospheric Sounder Spectrometer for Infrared Spectral ...

  11. Atmospheric Emitted Radiance Interferometer

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gero, Jonathan; Ermold, Brian; Gaustad, Krista; Koontz, Annette; Hackel, Denny; Garcia, Raymond

    2005-01-01

    The atmospheric emitted radiance interferometer (AERI) is a ground-based instrument that measures the downwelling infrared radiance from the Earth’s atmosphere. The observations have broad spectral content and sufficient spectral resolution to discriminate among gaseous emitters (e.g., carbon dioxide and water vapor) and suspended matter (e.g., aerosols, water droplets, and ice crystals). These upward-looking surface observations can be used to obtain vertical profiles of tropospheric temperature and water vapor, as well as measurements of trace gases (e.g., ozone, carbon monoxide, and methane) and downwelling infrared spectral signatures of clouds and aerosols. The AERI is a passive remote sounding instrument, employing a Fourier transform spectrometer operating in the spectral range 3.3–19.2 μm (520–3020 cm-1) at an unapodized resolution of 0.5 cm-1 (max optical path difference of 1 cm). The extended-range AERI (ER-AERI) deployed in dry climates, like in Alaska, have a spectral range of 3.3–25.0 μm (400–3020 cm-1) that allow measurements in the far-infrared region. Typically, the AERI averages views of the sky over a 16-second interval and operates continuously.

  12. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    1 data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): channel 1 data Atmospheric Sounder Spectrometer for Infrared Spectral Technology ...

  13. ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    summary data Title: ARM: Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST): summary data Atmospheric Sounder Spectrometer for Infrared Spectral Technology ...

  14. Infrared Spectroscopy of Explosives Residues: Measurement Techniques and Spectral Analysis

    SciTech Connect (OSTI)

    Phillips, Mark C.; Bernacki, Bruce E.

    2015-03-11

    Infrared laser spectroscopy of explosives is a promising technique for standoff and non-contact detection applications. However, the interpretation of spectra obtained in typical standoff measurement configurations presents numerous challenges. Understanding the variability in observed spectra from explosives residues and particles is crucial for design and implementation of detection algorithms with high detection confidence and low false alarm probability. We discuss a series of infrared spectroscopic techniques applied toward measuring and interpreting the reflectance spectra obtained from explosives particles and residues. These techniques utilize the high spectral radiance, broad tuning range, rapid wavelength tuning, high scan reproducibility, and low noise of an external cavity quantum cascade laser (ECQCL) system developed at Pacific Northwest National Laboratory. The ECQCL source permits measurements in configurations which would be either impractical or overly time-consuming with broadband, incoherent infrared sources, and enables a combination of rapid measurement speed and high detection sensitivity. The spectroscopic methods employed include standoff hyperspectral reflectance imaging, quantitative measurements of diffuse reflectance spectra, reflection-absorption infrared spectroscopy, microscopic imaging and spectroscopy, and nano-scale imaging and spectroscopy. Measurements of explosives particles and residues reveal important factors affecting observed reflectance spectra, including measurement geometry, substrate on which the explosives are deposited, and morphological effects such as particle shape, size, orientation, and crystal structure.

  15. Remotely Controlled, Continuous Observations of Infrared Radiance with the CSIRO/ARM Mark II Radiometer at the SGP CART Site

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Remotely Controlled, Continuous Observations of Infrared Radiance with the CSIRO/ARM Mark II Radiometer at the SGP CART Site C. M. R. Platt and R. T. Austin Department of Atmospheric Science Colorado State University Fort Collins, Colorado C. M. R. Platt and J. A. Bennett Commonwealth Scientific and Industrial Research Organization Atmospheric Research Aspendale, Victoria, Australia Abstract The Commonwealth Scientific and Industrial Research Organization/Atmospheric Radiation Measurement

  16. Use of the ARM Measurements of Spectral Zenith Radiance for Better...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Use of the ARM Measurements of Spectral Zenith ... situation, with particular emphasis on cloud optical depth and effective particle size. ...

  17. Atmospheric Sounder Spectrometer for Infrared Spectral Technology...

    Office of Scientific and Technical Information (OSTI)

    (BER) Country of Publication: United States Availability: ORNL Language: English Subject: 54 Environmental Sciences Longwave spectral brightness temperature,Longwave spectral ...

  18. Atmospheric Emitted Radiance Interferometer (AERI) Handbook

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gero, Jonathan; Hackel, Denny; Garcia, Raymond

    2005-01-01

    The atmospheric emitted radiance interferometer (AERI) is a ground-based instrument that measures the downwelling infrared radiance from the Earth’s atmosphere. The observations have broad spectral content and sufficient spectral resolution to discriminate among gaseous emitters (e.g., carbon dioxide and water vapor) and suspended matter (e.g., aerosols, water droplets, and ice crystals). These upward-looking surface observations can be used to obtain vertical profiles of tropospheric temperature and water vapor, as well as measurements of trace gases (e.g., ozone, carbon monoxide, and methane) and downwelling infrared spectral signatures of clouds and aerosols.The AERI is a passive remote sounding instrument, employing a Fourier transform spectrometer operating in the spectral range 3.3–19.2 μm (520–3020 cm-1) at an unapodized resolution of 0.5 cm-1 (max optical path difference of 1 cm). The extended-range AERI (ER-AERI) deployed in dry climates, like in Alaska, have a spectral range of 3.3–25.0 μm (400–3020 cm-1) that allow measurements in the far-infrared region. Typically, the AERI averages views of the sky over a 16-second interval and operates continuously.

  19. Contributed Review: Absolute spectral radiance calibration of fiber-optic shock-temperature pyrometers using a coiled-coil irradiance standard lamp

    SciTech Connect (OSTI)

    Fat’yanov, O. V. Asimow, P. D.

    2015-10-15

    We describe an accurate and precise calibration procedure for multichannel optical pyrometers such as the 6-channel, 3-ns temporal resolution instrument used in the Caltech experimental geophysics laboratory. We begin with a review of calibration sources for shock temperatures in the 3000-30 000 K range. High-power, coiled tungsten halogen standards of spectral irradiance appear to be the only practical alternative to NIST-traceable tungsten ribbon lamps, which are no longer available with large enough calibrated area. However, non-uniform radiance complicates the use of such coiled lamps for reliable and reproducible calibration of pyrometers that employ imaging or relay optics. Careful analysis of documented methods of shock pyrometer calibration to coiled irradiance standard lamps shows that only one technique, not directly applicable in our case, is free of major radiometric errors. We provide a detailed description of the modified Caltech pyrometer instrument and a procedure for its absolute spectral radiance calibration, accurate to ±5%. We employ a designated central area of a 0.7× demagnified image of a coiled-coil tungsten halogen lamp filament, cross-calibrated against a NIST-traceable tungsten ribbon lamp. We give the results of the cross-calibration along with descriptions of the optical arrangement, data acquisition, and processing. We describe a procedure to characterize the difference between the static and dynamic response of amplified photodetectors, allowing time-dependent photodiode correction factors for spectral radiance histories from shock experiments. We validate correct operation of the modified Caltech pyrometer with actual shock temperature experiments on single-crystal NaCl and MgO and obtain very good agreement with the literature data for these substances. We conclude with a summary of the most essential requirements for error-free calibration of a fiber-optic shock-temperature pyrometer using a high-power coiled tungsten halogen

  20. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    DOE PAGES-Beta [OSTI]

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperaturemore » and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.« less

  1. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    SciTech Connect (OSTI)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperature and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.

  2. Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    4 Atmospheric Sounder Spectrometer for Infrared Spectral Technology (ASSIST) Handbook C Flynn March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use

  3. THE INFRARED TELESCOPE FACILITY (IRTF) SPECTRAL LIBRARY: COOL STARS

    SciTech Connect (OSTI)

    Rayner, John T.; Cushing, Michael C.; Vacca, William D. E-mail: michael.cushing@gmail.com

    2009-12-01

    We present a 0.8-5 {mu}m spectral library of 210 cool stars observed at a resolving power of R {identical_to} {lambda}/{delta}{lambda} {approx} 2000 with the medium-resolution infrared spectrograph, SpeX, at the 3.0 m NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii. The stars have well-established MK spectral classifications and are mostly restricted to near-solar metallicities. The sample not only contains the F, G, K, and M spectral types with luminosity classes between I and V, but also includes some AGB, carbon, and S stars. In contrast to some other spectral libraries, the continuum shape of the spectra is measured and preserved in the data reduction process. The spectra are absolutely flux calibrated using the Two Micron All Sky Survey photometry. Potential uses of the library include studying the physics of cool stars, classifying and studying embedded young clusters and optically obscured regions of the Galaxy, evolutionary population synthesis to study unresolved stellar populations in optically obscured regions of galaxies and synthetic photometry. The library is available in digital form from the IRTF Web site.

  4. Spectral calibration in the mid-infrared: Challenges and solutions

    SciTech Connect (OSTI)

    Sloan, G. C. [Cornell University, Center for Radiophysics and Space Research, Ithaca, NY 14853-6801 (United States); Herter, T. L.; Houck, J. R. [Cornell University, Astronomy Department, Ithaca, NY 14853-6801 (United States); Charmandaris, V. [Department of Physics and ITCP, University of Crete, GR-71003, Heraklion (Greece); Sheth, K. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States); Burgdorf, M., E-mail: sloan@isc.astro.cornell.edu [HE Space Operations, Flughafenallee 24, D-28199 Bremen (Germany)

    2015-01-01

    We present spectra obtained with the Infrared Spectrograph on the Spitzer Space Telescope of 33 K giants and 20 A dwarfs to assess their suitability as spectrophotometric standard stars. The K giants confirm previous findings that the strength of the SiO absorption band at 8 ?m increases for both later optical spectral classes and redder (BV){sub 0} colors, but with considerable scatter. For K giants, the synthetic spectra underpredict the strengths of the molecular bands from SiO and OH. For these reasons, the assumed true spectra for K giants should be based on the assumption that molecular band strengths in the infrared can be predicted accurately from neither optical spectral class or color nor synthetric spectra. The OH bands in K giants grow stronger with cooler stellar temperatures, and they are stronger than predicted by synthetic spectra. As a group, A dwarfs are better behaved and more predictable than the K giants, but they are more likely to show red excesses from debris disks. No suitable A dwarfs were located in parts of the sky continuously observable from Spitzer, and with previous means of estimating the true spectra of K giants ruled out, it was necessary to use models of A dwarfs to calibrate spectra of K giants from observed spectral ratios of the two groups and then use the calibrated K giants as standards for the full database of infrared spectra from Spitzer. We also describe a lingering artifact that affects the spectra of faint blue sources at 24 ?m.

  5. Preliminary analysis of ground-based microwave and infrared radiance observations during the Pilot Radiation OBservation Experiment

    SciTech Connect (OSTI)

    Westwater, E.R.; Han, Y.; Churnside, J.H.; Snider, J.B.

    1995-04-01

    During Phase Two of the Pilot Radiation OBservation Experiment (PROBE) held in Kavieng, Papua New Guinea, the National Oceanic and Atmospheric Administration`s Environmental Technology Laboratory (ETL) operated both microwave and infrared radiometers. Phase Two lasted from January 6 to February 28, 1993. The dramatic differences in the water vapor environment between the tropics and mid-latitudes were illustrated by Westwater et al. (1994) who presented PROBE data as well as additional data that were taken during the 1991 First ISCCP Regional Experiment (FIRE) 11 experiment in Coffeyville, Kansas. We present an analysis of microwave data and a preliminary analysis of infrared data obtained during PROBE.

  6. Radiance | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Radiance Radiance Radiance rendering of daylighting and electric lighting for the retrofit of the New York Times offices in New York.<br /> Image credit: Andrew McNeil, LBNL. Radiance rendering of daylighting and electric lighting for the retrofit of the New York Times offices in New York. Image credit: Andrew McNeil, LBNL. In FY14, LBNL implemented a new method for controlling error in diffuse inter-reflection calculations. This method improves the time-quality (or accuracy) trade-off by

  7. Accurate, practical simulation of satellite infrared radiometer spectral data

    SciTech Connect (OSTI)

    Sullivan, T.J.

    1982-09-01

    This study's purpose is to determine whether a relatively simple random band model formulation of atmospheric radiation transfer in the infrared region can provide valid simulations of narrow interval satellite-borne infrared sounder system data. Detailed ozonesondes provide the pertinent atmospheric information and sets of calibrated satellite measurements provide the validation. High resolution line-by-line model calculations are included to complete the evaluation.

  8. Radiance Solar | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Radiance Solar Jump to: navigation, search Name: Radiance Solar Place: Atlanta, Georgia Zip: 30318 Product: Commercial and residential PV installer based in Atlanta. Coordinates:...

  9. A Principal Component Analysis Noise Filter Value-Added Procedure to Remove Uncorrelated Noise from Atmospheric Emitted Radiance Interferometer (AERI) Observations

    SciTech Connect (OSTI)

    C. Lo D. D. Turner R. O. Knuteson

    2006-01-31

    This technical report provide a short description of the application of the principle component analysis techniques to remove uncorrelated random noise from ground-based high spectral resolution infrared radiance observations collected by the atmospheric emitted radiance interferometers (AERIs) deployed by the Atmospheric Radiation Measurement (ARM) Program. A general overview of the technique, the input, and output datastreams of the newly generated value-added product, and the data quality checks used are provided. A more complete discussion of the theory and results is given in Turner et al. (2006).

  10. High Spectral Resolution Infrared and Raman Lidar Observations for the ARM Program: Clear and Cloudy Sky Applications

    SciTech Connect (OSTI)

    Revercomb, Henry; Tobin, David; Knuteson, Robert; Borg, Lori; Moy, Leslie

    2009-06-17

    This grant began with the development of the Atmospheric Emitted Radiance Interferometer (AERI) for ARM. The AERI has provided highly accurate and reliable observations of downwelling spectral radiance (Knuteson et al. 2004a, 2004b) for application to radiative transfer, remote sensing of boundary layer temperature and water vapor, and cloud characterization. One of the major contributions of the ARM program has been its success in improving radiation calculation capabilities for models and remote sensing that evolved from the multi-year, clear-sky spectral radiance comparisons between AERI radiances and line-by-line calculations (Turner et al. 2004). This effort also spurred us to play a central role in improving the accuracy of water vapor measurements, again helping ARM lead the way in the community (Turner et al. 2003a, Revercomb et al. 2003). In order to add high-altitude downlooking AERI-like observations over the ARM sites, we began the development of an airborne AERI instrument that has become known as the Scanning High-resolution Interferometer Sounder (Scanning-HIS). This instrument has become an integral part of the ARM Unmanned Aerospace Vehicle (ARM-UAV) program. It provides both a cross-track mapping view of the earth and an uplooking view from the 12-15 km altitude of the Scaled Composites Proteus aircraft when flown over the ARM sites for IOPs. It has successfully participated in the first two legs of the “grand tour” of the ARM sites (SGP and NSA), resulting in a very good comparison with AIRS observations in 2002 and in an especially interesting data set from the arctic during the Mixed-Phase Cloud Experiment (M-PACE) in 2004.

  11. Radiance: Synthetic Imaging System | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    tools User Interface: Desktop Application Website: radsite.lbl.govradiance Cost: Free References: Radiance1 Logo: RADIANCE RADIANCE is a highly accurate ray-tracing...

  12. Joint spatio-spectral based edge detection for multispectral infrared imagery.

    SciTech Connect (OSTI)

    Krishna, Sanjay; Hayat, Majeed M.; Bender, Steven C.; Sharma, Yagya D.; Jang, Woo-Yong; Paskalva, Biliana S.

    2010-06-01

    Image segmentation is one of the most important and difficult tasks in digital image processing. It represents a key stage of automated image analysis and interpretation. Segmentation algorithms for gray-scale images utilize basic properties of intensity values such as discontinuity and similarity. However, it is possible to enhance edge-detection capability by means of using spectral information provided by multispectral (MS) or hyperspectral (HS) imagery. In this paper we consider image segmentation algorithms for multispectral images with particular emphasis on detection of multi-color or multispectral edges. More specifically, we report on an algorithm for joint spatio-spectral (JSS) edge detection. By joint we mean simultaneous utilization of spatial and spectral characteristics of a given MS or HS image. The JSS-based edge-detection approach, termed Spectral Ratio Contrast (SRC) edge-detection algorithm, utilizes the novel concept of matching edge signatures. The edge signature represents a combination of spectral ratios calculated using bands that enhance the spectral contrast between the two materials. In conjunction with a spatial mask, the edge signature give rise to a multispectral operator that can be viewed as a three-dimensional extension of the mask. In the extended mask, the third (spectral) dimension of each hyper-pixel can be chosen independently. The SRC is verified using MS and HS imagery from a quantum-dot in a well infrared (IR) focal plane array, and the Airborne Hyperspectral Imager.

  13. Frequency Selective Surfaces as Near Infrared Electro-Magnetic Filters for Thermophotovoltaic Spectral Control

    SciTech Connect (OSTI)

    RF Kristensen; JF Beausang; DM DePoy

    2004-06-28

    Frequency selective surfaces (FSS) effectively filter electromagnetic radiation in the microwave band (1 mm to 100 mm). Interest exists in extending this technology to the near infrared (1 {micro}m to 10 {micro}m) for use as a filter of thermal radiation in thermophotovoltaic (TPV) direct energy conversion. This paper assesses the ability of FSS to meet the strict spectral performance requirements of a TPV system. Inherent parasitic absorption, which is the result of the induced currents in the FSS metallization, is identified as a significant obstacle to achieving high spectral performance.

  14. Frequency Selective Surfaces as Near Infrared Electro-Magnetic Filters for Thermophotovoltaic Spectral Control

    SciTech Connect (OSTI)

    Ryan T. Kristensen; John F. Beausang; David M. DePoy

    2003-12-01

    Frequency selective surfaces (FSS) effectively filter electromagnetic radiation in the microwave band (1mm to 100mm). Interest exists in extending this technology to the near infrared (1 {micro}m to 10 {micro}m) for use as a filter of thermal radiation in thermophotovoltaic (TPV) direct energy conversion. This paper assesses the ability of FSS to meet the strict spectral performance requirements of a TPV system. Inherent parasitic absorption, which is the result of the induced currents in the FSS metallization, is identified as a significant obstacle to achieving high spectral performance.

  15. Infrared and Raman spectra, DFT-calculations and spectral assignments of germacyclohexane

    SciTech Connect (OSTI)

    Aleksa, V. Ozerenskis, D.; Pucetaite, M.; Sablinskas, V.; Cotter, C.; Guirgis, G. A.

    2015-03-30

    Raman spectra of germacyclohexane in liquid and solid states were recorded and depolarization data obtained. Infrared absorption spectra of the vapor and liquid have been studied. The wavenumbers of the vibrational modes were derived in the harmonic and anharmonic approximation in B3LYP/ccpVTZ calculations. According to the calculations, germacyclohexane exists in the stable chair conformation, whereas a possible twist form should have more than 15 kJ·mol{sup -1} higher enthalpy of formation what makes this conformer experimentally not observable. The 27 A' and 21 A'' fundamentals were assigned on the basis of the calculations and infrared and Raman band intensities, contours of gas phase infrared spectral bands and Raman depolarization measurements. An average discrepancy of ca. 0.77 % was found between the observed and the calculated anharmonic wavenumbers for the 48 modes. Substitution of carbon atom with Ge atom in the cyclohexane ring is reasoning flattening of the ring.

  16. The Northwest Infrared (NWIR) gas-phase spectral database of industrial and environmental chemicals: Recent updates

    SciTech Connect (OSTI)

    Brauer, Carolyn S.; Johnson, Timothy J.; Blake, Thomas A.; Sharpe, Steven W.; Sams, Robert L.; Tonkyn, Russell G.

    2014-05-22

    With continuing improvements in both standoff- and point-sensing techniques, there is an ongoing need for high-quality infrared spectral databases. The Northwest Infrared Database (NWIR) contains quantitative, gas-phase infrared spectra of nearly 500 pure chemical species that can be used for a variety of applications such as atmospheric monitoring, biomass burning studies, etc. The data, recorded at 0.1 cm-1 resolution, are pressure broadened to one atmosphere (N2) in order to mimic atmospheric conditions. Each spectrum is a composite composed of multiple individual measurements. Recent updates to the database include over 60 molecules that are known or suspected biomass-burning effluents. Examples from this set of measurements will be presented and experimental details will be discussed in the context of the utility of NWIR for environmental applications.

  17. THE SPECTRAL ENERGY DISTRIBUTION OF THE CARINA NEBULA FROM FAR-INFRARED TO RADIO WAVELENGTHS

    SciTech Connect (OSTI)

    Salatino, M.; De Bernardis, P.; Masi, S. [Physics Department, Sapienza Universita di Roma, p.le Aldo Moro 2, I-00185 Roma (Italy); Polenta, G., E-mail: maria.salatino@roma1.infn.it [ASI Science Data Center, ESRIN, via G. Galilei, I-00044, Frascati (Italy)

    2012-03-20

    Multi-wavelength observations are necessary for understanding the physical properties of astrophysical sources. In this paper, we use observations in the far-infrared to radio range to derive the spectral energy distribution (SED) of the Carina nebula. To do this, we carefully subtract the irregularly varying diffuse emission from the Galactic plane, which can be of the order of 10% of the nebula flux at these wavelengths. We find that the far-infrared SED can be modeled as emission from a dust population with a single temperature T{sub d} = (34.5{sup +2.0}{sub -1.8}) K and with a spectral index of emissivity {alpha} = -1.37{sup +0.09}{sub -0.08}. We also find a total infrared luminosity of the nebula of (7.4{sup +2.5}{sub -1.4}) Multiplication-Sign 10{sup 6} L{sub Sun} and, assuming a single temperature of the dust, a mass of the dust of (9500{sup +4600}{sub -3500}) M{sub Sun }.

  18. Spectral response of localized surface plasmon in resonance with mid-infrared light

    SciTech Connect (OSTI)

    Kusa, Fumiya [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo 184-8588 (Japan); Institute of Industrial Science, the University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan); Ashihara, Satoshi, E-mail: ashihara@iis.u-tokyo.ac.jp [Institute of Industrial Science, the University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan)

    2014-10-21

    We study spectral responses of localized surface plasmons (LSPs) in gold nanorods, which resonate at mid-infrared frequencies, by transmission spectroscopy and electromagnetic field analyses. The resonance linewidth is found to be linearly proportional to the resonance frequency, indicating that the dephasing due to Drude relaxation is suppressed and that the overall dephasing is dominated by radiative damping. Owing to the reduced radiative/non-radiative damping and large geometrical length of the nanorod, near-field intensity enhancement exceeds several hundred times. Nonetheless the resonance linewidth is comparable with or larger than the bandwidth of a 100-fs pulse, and therefore the enhanced near-field as short as 100-fs can be created upon pulsed excitation. The large enhancements with appropriate bandwidths make LSPs promising for enhanced nonlinear spectroscopies, coherent controls, and strong-field light-matter interactions in the mid-infrared range.

  19. Near infrared spectral imaging of explosives using a tunable laser source

    SciTech Connect (OSTI)

    Klunder, G L; Margalith, E; Nguyen, L K

    2010-03-26

    Diffuse reflectance near infrared hyperspectral imaging is an important analytical tool for a wide variety of industries, including agriculture consumer products, chemical and pharmaceutical development and production. Using this technique as a method for the standoff detection of explosive particles is presented and discussed. The detection of the particles is based on the diffuse reflectance of light from the particle in the near infrared wavelength range where CH, NH, OH vibrational overtones and combination bands are prominent. The imaging system is a NIR focal plane array camera with a tunable OPO/laser system as the illumination source. The OPO is programmed to scan over a wide spectral range in the NIR and the camera is synchronized to record the light reflected from the target for each wavelength. The spectral resolution of this system is significantly higher than that of hyperspectral systems that incorporate filters or dispersive elements. The data acquisition is very fast and the entire hyperspectral cube can be collected in seconds. A comparison of data collected with the OPO system to data obtained with a broadband light source with LCTF filters is presented.

  20. Release Path Temperatures of Shock-Compressed Tin from Dynamic Reflectance and Radiance Measurements

    SciTech Connect (OSTI)

    La Lone, B. M.; Stevens, G. D.; Turley, W. D.; Holtkamp, D. B.; Iverson, A. J.; Hixson, R. S.; Veeser, L. R.

    2013-08-01

    Dynamic reflectance and radiance measurements were conducted for tin samples shock compressed to 35 GPa and released to 15 GPa using high explosives. We determined the reflectance of the tin samples glued to lithium fluoride windows using an integrating sphere with an internal xenon flashlamp as an illumination source. The dynamic reflectance (R) was determined at near normal incidence in four spectral bands with coverage in visible and near-infrared spectra. Uncertainties in R/R0 are < 2%, and uncertainties in absolute reflectance are < 5%. In complementary experiments, thermal radiance from the tin/glue/lithium fluoride interface was recorded with similar shock stress and spectral coverage as the reflectance measurements. The two sets of experiments were combined to obtain the temperature history of the tin surface with an uncertainty of < 2%. The stress at the interface was determined from photonic Doppler velocimetry and combined with the temperatures to obtain temperature-stress release paths for tin. We discuss the relationship between the experimental release paths and release isentropes that begin on the principal shock Hugoniot.

  1. Release path temperatures of shock-compressed tin from dynamic reflectance and radiance measurements

    SciTech Connect (OSTI)

    La Lone, B. M. Stevens, G. D.; Turley, W. D.; Holtkamp, D. B.; Iverson, A. J.; Hixson, R. S.; Veeser, L. R.

    2013-08-14

    Dynamic reflectance and radiance measurements were conducted for tin samples shock compressed to 35 GPa and released to 15 GPa using high explosives. We determined the reflectance of the tin samples glued to lithium fluoride windows using an integrating sphere with an internal xenon flashlamp as an illumination source. The dynamic reflectance (R) was determined at near normal incidence in four spectral bands with coverage in visible and near-infrared spectra. Uncertainties in R/R{sub 0} are <2%, and uncertainties in absolute reflectance are <5%. In complementary experiments, thermal radiance from the tin/glue/lithium fluoride interface was recorded with similar shock stress and spectral coverage as the reflectance measurements. The two sets of experiments were combined to obtain the temperature history of the tin surface with an uncertainty of <2%. The stress at the interface was determined from photonic Doppler velocimetry and combined with the temperatures to obtain temperature-stress release paths for tin. We discuss the relationship between the experimental release paths and release isentropes that begin on the principal shock Hugoniot.

  2. ARM - Measurement - Longwave narrowband radiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    narrowband radiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave narrowband radiance The rate at which radiant energy in the longwave portion of the spectrum is emitted in narrow wavelength bands in a particular direction per unit area perpendicular to the direction of radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  3. Final Scientific/Technical Report Grant title: Use of ARM Measurements of Spectral Zenith Radiance for Better Understanding of 3D Cloud-Radiation Processes and Aerosol-Cloud Interaction This is a collaborative project with the NASA GSFC project of Dr. A. Marshak and W. Wiscombe (PIs). This report covers BU activities from February 2011 to June 2011 and BU "no-cost extension" activities from June 2011 to June 2012. This report summarizes results that complement a final technical report submitted by the PIs in 2011.

    SciTech Connect (OSTI)

    Knyazikhin, Y

    2012-09-10

    Main results are summarized for work in these areas: spectrally-invariant approximation within atmospheric radiative transfer; spectral invariance of single scattering albedo for water droplets and ice crystals at weakly absorbing wavelengths; seasonal changes in leaf area of Amazon forests from leaf flushing and abscission; and Cloud droplet size and liquid water path retrievals from zenith radiance measurements.

  4. Atmospheric Emitted Radiance Interferometer (AERI) Archived Data at the University of Wisconsin Space Science and Engineering Center (SSEC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The AERI instrument is an advanced version of the high spectral resolution interferometer sounder (HIS) designed and fabricated at the University of Wisconsin (Revercomb et al. 1988) to measure upwelling infrared radiances from an aircraft. The AERI is a fully automated ground-based passive infrared interferometer that measures downwelling atmospheric radiance from 3.3 - 18.2 mm (550 - 3000 cm-1) at less than 10-minute temporal resolution with a spectral resolution of one wavenumber. It has been used in DOEÆs Atmospheric Radiation Measurement (ARM) program. Much of the data available here at the Cooperative Institute for Meteorological Satellite Studies (CIMSS), an institute within the University of Wisconsin’s Space Science and Engineering Center, may also be available in the ARM Archive. On this website, data and images from six different field experiments are available, along with AERIPLUS realtime data for the Madison, Wisconsin location. Realtime data includes temperature and water vapor time-height cross sections, SKEWT diagrams, convective stability indices, and displays from a rooftop Lidar instrument. The field experiments took place in Oaklahoma and Wisconsin with the AERI prototype.

  5. Atmospheric Emitted Radiance Interferometer (AERI) Archived Data at the University of Wisconsin Space Science and Engineering Center (SSEC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The AERI instrument is an advanced version of the high spectral resolution interferometer sounder (HIS) designed and fabricated at the University of Wisconsin (Revercomb et al. 1988) to measure upwelling infrared radiances from an aircraft. The AERI is a fully automated ground-based passive infrared interferometer that measures downwelling atmospheric radiance from 3.3 - 18.2 mm (550 - 3000 cm-1) at less than 10-minute temporal resolution with a spectral resolution of one wavenumber. It has been used in DOEs Atmospheric Radiation Measurement (ARM) program. Much of the data available here at the Cooperative Institute for Meteorological Satellite Studies (CIMSS), an institute within the University of Wisconsins Space Science and Engineering Center, may also be available in the ARM Archive. On this website, data and images from six different field experiments are available, along with AERIPLUS realtime data for the Madison, Wisconsin location. Realtime data includes temperature and water vapor time-height cross sections, SKEWT diagrams, convective stability indices, and displays from a rooftop Lidar instrument. The field experiments took place in Oaklahoma and Wisconsin with the AERI prototype.

  6. ARM - Measurement - Shortwave broadband radiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    broadband radiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband radiance A measure of the intrinsic radiant energy flux intensity, at wavelengths between 0.4 and 4 {mu}, emitted by a radiator in a given direction, expressed in units of energy per unit time per unit solid angle. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the

  7. ARM - Measurement - Shortwave narrowband radiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    narrowband radiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband radiance A measure of the intrinsic radiant energy flux intensity, at wavelengths between 0.4 and 4 {mu}, emitted by a radiator in a given direction, expressed in units of energy per unit time per unit solid angle. Categories Radiometric Instruments The above measurement is considered scientifically relevant for

  8. Method And Apparatus For Examining A Tissue Using The Spectral Wing Emission Therefrom Induced By Visible To Infrared Photoexcitation.

    DOE Patents [OSTI]

    Alfano, Robert R.; Demos, Stavros G.; Zhang, Gang

    2003-12-16

    Method and an apparatus for examining a tissue using the spectral wing emission therefrom induced by visible to infrared photoexcitation. In one aspect, the method is used to characterize the condition of a tissue sample and comprises the steps of (a) photoexciting the tissue sample with substantially monochromatic light having a wavelength of at least 600 nm; and (b) using the resultant far red and near infrared spectral wing emission (SW) emitted from the tissue sample to characterize the condition of the tissue sample. In one embodiment, the substantially monochromatic photoexciting light is a continuous beam of light, and the resultant steady-state far red and near infrared SW emission from the tissue sample is used to characterize the condition of the tissue sample. In another embodiment, the substantially monochromatic photoexciting light is a light pulse, and the resultant time-resolved far red and near infrared SW emission emitted from the tissue sample is used to characterize the condition of the tissue sample. In still another embodiment, the substantially monochromatic photoexciting light is a polarized light pulse, and the parallel and perpendicular components of the resultant polarized time-resolved SW emission emitted from the tissue sample are used to characterize the condition of the tissue sample.

  9. Super-radiance in the sodium resonance lines from sodium iodide arc lamps

    SciTech Connect (OSTI)

    Karabourniotis, D.; Drakakis, E.

    2010-08-09

    Super-radiance observed within the centers of the sodium resonance D lines emitted by arc lamps containing sodium iodide as additive in a high-pressure mercury plasma environment was studied by high-resolution emission spectroscopy. The spectral radiance of these self-reversed lines including super-radiance was simulated by considering a local enhancement of the source function due to the presence of an additional source of radiation near the arc wall. Causes of this hitherto unrecognized source of radiation are given.

  10. INFRARED SPECTRAL ENERGY DISTRIBUTIONS OF SEYFERT GALAXIES: SPITZER SPACE TELESCOPE OBSERVATIONS OF THE 12 {mu}m SAMPLE OF ACTIVE GALAXIES

    SciTech Connect (OSTI)

    Gallimore, J. F.; Yzaguirre, A.; Jakoboski, J.; Stevenosky, M. J.; Axon, D. J.; O'Dea, C. P.; Robinson, A.; Baum, S. A.; Buchanan, C. L.; Elitzur, M.; Elvis, M.

    2010-03-01

    The mid-infrared spectral energy distributions (SEDs) of 83 active galaxies, mostly Seyfert galaxies, selected from the extended 12 {mu}m sample are presented. The data were collected using all three instruments, Infrared Array Camera (IRAC), Infrared Spectrograph (IRS), and Multiband Imaging Photometer for Spitzer (MIPS), aboard the Spitzer Space Telescope. The IRS data were obtained in spectral mapping mode, and the photometric data from IRAC and IRS were extracted from matched, 20'' diameter circular apertures. The MIPS data were obtained in SED mode, providing very low-resolution spectroscopy (R {approx} 20) between {approx}55 and 90 {mu}m in a larger, 20'' x 30'' synthetic aperture. We further present the data from a spectral decomposition of the SEDs, including equivalent widths and fluxes of key emission lines; silicate 10 {mu}m and 18 {mu}m emission and absorption strengths; IRAC magnitudes; and mid-far-infrared spectral indices. Finally, we examine the SEDs averaged within optical classifications of activity. We find that the infrared SEDs of Seyfert 1s and Seyfert 2s with hidden broad line regions (HBLRs, as revealed by spectropolarimetry or other technique) are qualitatively similar, except that Seyfert 1s show silicate emission and HBLR Seyfert 2s show silicate absorption. The infrared SEDs of other classes within the 12 {mu}m sample, including Seyfert 1.8-1.9, non-HBLR Seyfert 2 (not yet shown to hide a type 1 nucleus), LINER, and H II galaxies, appear to be dominated by star formation, as evidenced by blue IRAC colors, strong polycyclic aromatic hydrocarbon emission, and strong far-infrared continuum emission, measured relative to mid-infrared continuum emission.

  11. Radiance Research Particle Soot/Absorption Photometer Instrument...

    Office of Scientific and Technical Information (OSTI)

    Radiance Research Particle SootAbsorption Photometer Instrument Handbook Citation Details In-Document Search Title: Radiance Research Particle SootAbsorption Photometer ...

  12. Circuit model optimization of a nano split ring resonator dimer antenna operating in infrared spectral range

    SciTech Connect (OSTI)

    Gneiding, N.; Zhuromskyy, O.; Peschel, U.; Shamonina, E.

    2014-10-28

    Metamaterials are comprised of metallic structures with a strong response to incident electromagnetic radiation, like, for example, split ring resonators. The interaction of resonator ensembles with electromagnetic waves can be simulated with finite difference or finite elements algorithms, however, above a certain ensemble size simulations become inadmissibly time or memory consuming. Alternatively a circuit description of metamaterials, a well developed modelling tool at radio and microwave frequencies, allows to significantly increase the simulated ensemble size. This approach can be extended to the IR spectral range with an appropriate set of circuit element parameters accounting for physical effects such as electron inertia and finite conductivity. The model is verified by comparing the coupling coefficients with the ones obtained from the full wave numerical simulations, and used to optimize the nano-antenna design with improved radiation characteristics.

  13. TORUS AND ACTIVE GALACTIC NUCLEUS PROPERTIES OF NEARBY SEYFERT GALAXIES: RESULTS FROM FITTING INFRARED SPECTRAL ENERGY DISTRIBUTIONS AND SPECTROSCOPY

    SciTech Connect (OSTI)

    Alonso-Herrero, Almudena; Ramos Almeida, Cristina; Mason, Rachel; Asensio Ramos, Andres; Rodriguez Espinosa, Jose Miguel; Perez-Garcia, Ana M.; Roche, Patrick F.; Levenson, Nancy A.; Elitzur, Moshe; Packham, Christopher; Young, Stuart; Diaz-Santos, Tanio

    2011-08-01

    We used the CLUMPY torus models and a Bayesian approach to fit the infrared spectral energy distributions and ground-based high angular resolution mid-infrared spectroscopy of 13 nearby Seyfert galaxies. This allowed us to put tight constraints on torus model parameters such as the viewing angle i, the radial thickness of the torus Y, the angular size of the cloud distribution {sigma}{sub torus}, and the average number of clouds along radial equatorial rays N{sub 0}. We found that the viewing angle i is not the only parameter controlling the classification of a galaxy into type 1 or type 2. In principle, type 2s could be viewed at any viewing angle i as long as there is one cloud along the line of sight. A more relevant quantity for clumpy media is the probability for an active galactic nucleus (AGN) photon to escape unabsorbed. In our sample, type 1s have relatively high escape probabilities, P{sub esc} {approx} 12%-44%, while type 2s, as expected, tend to have very low escape probabilities. Our fits also confirmed that the tori of Seyfert galaxies are compact with torus model radii in the range 1-6 pc. The scaling of the models to the data also provided the AGN bolometric luminosities L{sub bol}(AGN), which were found to be in good agreement with estimates from the literature. When we combined our sample of Seyfert galaxies with a sample of PG quasars from the literature to span a range of L{sub bol}(AGN) {approx} 10{sup 43}-10{sup 47} erg s{sup -1}, we found plausible evidence of the receding torus. That is, there is a tendency for the torus geometrical covering factor to be lower (f{sub 2} {approx} 0.1-0.3) at high AGN luminosities than at low AGN luminosities (f{sub 2} {approx} 0.9-1 at {approx}10{sup 43}-10{sup 44} erg s{sup -1}). This is because at low AGN luminosities the tori appear to have wider angular sizes (larger {sigma}{sub torus}) and more clouds along radial equatorial rays. We cannot, however, rule out the possibility that this is due to

  14. Atmospheric emitted radiance interferometer (AERI): Status and the aerosol explanation for extra window region emissions

    SciTech Connect (OSTI)

    Revercomb, H.E.; Knuteson, R.O.; Best, F.A.; Dirkx, T.P.

    1996-04-01

    High spectral resolution observations of downwelling emission from 3 to 19 microns have been made by the Atmospheric Emitted Radiance Interferometer (AERI) Prototype at the Southern Great Plains (SGP) Cloud and Radiative Testbed (CART) site for over two years. The spectral data set from AERI provides a basis for improving clear sky radiative transfer; determining the radiative impact of clouds, including the derivation of cloud radiative properties; defining the influences of aerosols in the window regions; and retrieving boundary layer state properties, including temperature, water vapor, and other trace gases. The data stream of radiometrically and spectrally calibrated radiances is routinely provided by Pacific Northwest Laboratory (PNL) to those science teams requesting it, and further information on the instrument and data characteristics is available in the ARM Science Team proceedings for 1993 and 1994 and in several conference publications. This paper describes the AERI status, calibration, field experiment wit a new AERI-01 and schedule, window region emissions, and future AERI plans.

  15. Near-infrared spectral tomography integrated with digital breast tomosynthesis: Effects of tissue scattering on optical data acquisition design

    SciTech Connect (OSTI)

    Michaelsen, Kelly; Krishnaswamy, Venkat; Pogue, Brian W.; Poplack, Steven P.; Paulsen, Keith D.

    2012-07-15

    Purpose: Design optimization and phantom validation of an integrated digital breast tomosynthesis (DBT) and near-infrared spectral tomography (NIRST) system targeting improvement in sensitivity and specificity of breast cancer detection is presented. Factors affecting instrumentation design include minimization of cost, complexity, and examination time while maintaining high fidelity NIRST measurements with sufficient information to recover accurate optical property maps. Methods: Reconstructed DBT slices from eight patients with abnormal mammograms provided anatomical information for the NIRST simulations. A limited frequency domain (FD) and extensive continuous wave (CW) NIRST system was modeled. The FD components provided tissue scattering estimations used in the reconstruction of the CW data. Scattering estimates were perturbed to study the effects on hemoglobin recovery. Breast mimicking agar phantoms with inclusions were imaged using the combined DBT/NIRST system for comparison with simulation results. Results: Patient simulations derived from DBT images show successful reconstruction of both normal and malignant lesions in the breast. They also demonstrate the importance of accurately quantifying tissue scattering. Specifically, 20% errors in optical scattering resulted in 22.6% or 35.1% error in quantification of total hemoglobin concentrations, depending on whether scattering was over- or underestimated, respectively. Limited frequency-domain optical signal sampling provided two regions scattering estimates (for fat and fibroglandular tissues) that led to hemoglobin concentrations that reduced the error in the tumor region by 31% relative to when a single estimate of optical scattering was used throughout the breast volume of interest. Acquiring frequency-domain data with six wavelengths instead of three did not significantly improve the hemoglobin concentration estimates. Simulation results were confirmed through experiments in two-region breast mimicking

  16. Enhancing mid-infrared spectral response at the LaAlO{sub 3}/SrTiO{sub 3} interface by magnetic field

    SciTech Connect (OSTI)

    Feng, Xin; Zhao, Kun Xi, Jian-Feng; Xiang, Wen-Feng; Lu, Zhi-Qing; Sun, Qi; Wu, Shi-Xiang; Ni, Hao

    2014-12-15

    Many unexpected properties have been found in the LaAlO{sub 3}/SrTiO{sub 3} heterostructure, but the interaction of the many ground states at its interface remains unclear. Here, we demonstrate an optical property of this n-type heterostructure where the mid-infrared spectral responsivity at the interface is enhanced by an external magnetic field. The field intensity ranged from 0.8 to 6 kOe at a low temperature (19 K) as measured with our spectral response measurement system. Two spectral peaks related to the spin-orbit coupling effect were also observed at wavelengths 2400 nm and 3700 nm. The intriguing phenomena relate to changes in the crystallographic structure and subband structure at the interface.

  17. Super-radiance and open quantum systems

    SciTech Connect (OSTI)

    Volya, Alexander [Department of Physics, Florida State University, Tallahassee, FL 32306-4350 (United States); Zelevinsky, Vladimir [NSCL, Michigan State University, East Lansing, MI 48824-1321 (United States); Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824-1321 (United States)

    2005-07-08

    Quantum wires, loosely bound nuclei, molecules in chemical reactions and exotic narrow pentaquark states are different examples of open quantum mesoscopic systems. The coupling with and through continuum is their common feature. We discuss general properties of quantum systems in the regime of strong continuum coupling, when the mechanism of Dicke super-radiance changes intrinsic dynamics, signatures of quantum chaos, lifetime of unstable states and reaction cross sections. The examples are shown for various areas of mesoscopic physics.

  18. MAGIC Cloud Properties from Zenith Radiance Data Final Campaign...

    Office of Scientific and Technical Information (OSTI)

    Title: MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary Cloud droplet size and optical depth are the most fundamental properties for understanding cloud ...

  19. Spectral behavior of the optical constants in the visible/near infrared of GeSbSe chalcogenide thin films grown at glancing angle

    SciTech Connect (OSTI)

    Martin-Palma, R. J.; Ryan, Joseph V.; Pantano, C. G.

    2007-04-23

    GeSbSe chalcogenide thin films were deposited using glancing angle deposition onto transparent glass substrates for the determination of the spectral behavior of the optical constants (index of refraction n and extinction coefficient k) in the visible and near infrared ranges (400-2500 nm) as a function of the deposition angle. Computational simulations based on the matrix method were employed to determine the values of the optical constants of the different films from the experimental reflectance and transmittance spectra. A significant dependence of the overall optical behavior on the deposition angle is found. Furthermore, the band gap of the GeSbSe thin films was calculated. The accurate determination of the optical constants of films grown at glancing angle will enable the development of sculptured thin film fiber-optic chemical sensors and biosensors.

  20. Design, manufacture, and calibration of infrared radiometric blackbody sources

    SciTech Connect (OSTI)

    Byrd, D.A.; Michaud, F.D.; Bender, S.C.

    1996-04-01

    A Radiometric Calibration Station (RCS) is being assembled at the Los Alamos National Laboratories (LANL) which will allow for calibration of sensors with detector arrays having spectral capability from about 0.4-15 {mu}m. The configuration of the LANL RCS. Two blackbody sources have been designed to cover the spectral range from about 3-15 {mu}m, operating at temperatures ranging from about 180-350 K within a vacuum environment. The sources are designed to present a uniform spectral radiance over a large area to the sensor unit under test. The thermal uniformity requirement of the blackbody cavities has been one of the key factors of the design, requiring less than 50 mK variation over the entire blackbody surface to attain effective emissivity values of about 0.999. Once the two units are built and verified to the level of about 100 mK at LANL, they will be sent to the National Institute of Standards and Technology (NIST), where at least a factor of two improvement will be calibrated into the blackbody control system. The physical size of these assemblies will require modifications of the existing NIST Low Background Infrared (LBIR) Facility. LANL has constructed a bolt-on addition to the LBIR facility that will allow calibration of our large aperture sources. Methodology for attaining the two blackbody sources at calibrated levels of performance equivalent to present state of the art will be explained in the following.

  1. Infrared source test

    SciTech Connect (OSTI)

    Ott, L.

    1994-11-15

    The purpose of the Infrared Source Test (IRST) is to demonstrate the ability to track a ground target with an infrared sensor from an airplane. The system is being developed within the Advance Technology Program`s Theater Missile Defense/Unmanned Aerial Vehicle (UAV) section. The IRST payload consists of an Amber Radiance 1 infrared camera system, a computer, a gimbaled mirror, and a hard disk. The processor is a custom R3000 CPU board made by Risq Modular Systems, Inc. for LLNL. The board has ethernet, SCSI, parallel I/O, and serial ports, a DMA channel, a video (frame buffer) interface, and eight MBytes of main memory. The real-time operating system VxWorks has been ported to the processor. The application code is written in C on a host SUN 4 UNIX workstation. The IRST is the result of a combined effort by physicists, electrical and mechanical engineers, and computer scientists.

  2. CIMEL Measurements of Zenith Radiances at the ARM SGP Site

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CIMEL Measurements of Zenith Radiances at the ARM SGP Site W. J. Wiscombe National Aeronautics and Space Administration Goddard Space Flight Center Climate and Radiation Branch Greenbelt, Maryland A. Marshak and K. Evans Joint Center for Earth Systems Technology University of Maryland Baltimore, Maryland Y. Knyazikhin Department of Geography Boston University Boston, Massachusetts H. W. Barker Environment Canada Downsview, Ontario, Canada C. F. Pavloski Department of Meteorology Pennsylvania

  3. Temperature dependent dielectric function in the near-infrared to vacuum-ultraviolet ultraviolet spectral range of alumina and yttria stabilized zirconia thin films

    SciTech Connect (OSTI)

    Schmidt-Grund, R. Lhmann, T.; Bntgen, T.; Franke, H.; Lorenz, M.; Grundmann, M.; Opper, D.

    2013-12-14

    The dielectric function of nano-/polycrystalline alumina and yttria stabilised zirconia thin films has been investigated in a wide spectral range from 1.0?eV to 7.5?eV and temperatures between 10?K and room temperature. In the near band-edge spectral range, we found a broad distribution of optical transitions within the band gap, the so-called Urbach absorption tail which is typical for amorphous or polycrystalline materials due to the lack of long range order in the crystal structure. The coupling properties of the electronic system to the optical phonon bath and thermal lattice vibrations strongly depend on the ratio of the spectral extent of these disorder states to the main phonon energy, which we correlate with the different crystalline structure of our samples. The films have been grown at room temperature and 650?C by pulsed laser deposition.

  4. Infrared retina

    DOE Patents [OSTI]

    Krishna, Sanjay; Hayat, Majeed M.; Tyo, J. Scott; Jang, Woo-Yong

    2011-12-06

    Exemplary embodiments provide an infrared (IR) retinal system and method for making and using the IR retinal system. The IR retinal system can include adaptive sensor elements, whose properties including, e.g., spectral response, signal-to-noise ratio, polarization, or amplitude can be tailored at pixel level by changing the applied bias voltage across the detector. "Color" imagery can be obtained from the IR retinal system by using a single focal plane array. The IR sensor elements can be spectrally, spatially and temporally adaptive using quantum-confined transitions in nanoscale quantum dots. The IR sensor elements can be used as building blocks of an infrared retina, similar to cones of human retina, and can be designed to work in the long-wave infrared portion of the electromagnetic spectrum ranging from about 8 .mu.m to about 12 .mu.m as well as the mid-wave portion ranging from about 3 .mu.m to about 5 .mu.m.

  5. Comparison of absolute spectral irradiance responsivity measurement techniques using wavelength-tunable lasers

    SciTech Connect (OSTI)

    Ahtee, Ville; Brown, Steven W.; Larason, Thomas C.; Lykke, Keith R.; Ikonen, Erkki; Noorma, Mart

    2007-07-10

    Independent methods for measuring the absolute spectral irradiance responsivity of detectors have been compared between the calibration facilities at two national metrology institutes, the Helsinki University of Technology (TKK), Finland, and the National Institute of Standards and Technology (NIST). The emphasis is on the comparison of two different techniques for generating a uniform irradiance at a reference plane using wavelength-tunable lasers. At TKK's Laser Scanning Facility (LSF) the irradiance is generated by raster scanning a single collimated laser beam, while at the NIST facility for Spectral Irradiance and Radiance Responsivity Calibrations with Uniform Sources (SIRCUS), lasers are introduced into integrating spheres to generate a uniform irradiance at a reference plane. The laser-based irradiance responsivity results are compared to a traditional lamp-monochromator-based irradiance responsivity calibration obtained at the NIST Spectral Comparator Facility (SCF). A narrowband filter radiometer with a24 nm bandwidth and an effective band-center wavelength of 801 nm was used as the artifact. The results of the comparison between the different facilities, reported for the first time in the near-infrared wavelength range, demonstrate agreement at the uncertainty level of less than 0.1%. This result has significant implications in radiation thermometry and in photometry as well as in radiometry.

  6. Development of two-band infrared radiometer for irradiance calibration of target simulators

    SciTech Connect (OSTI)

    Yang, Sen; Li, Chengwei

    2015-07-15

    A detector-based spectral radiometer has been developed for the calibration of target simulator. Unlike the conventional spectral irradiance calibration method based on radiance and irradiance, the new radiometer is calibrated using image-space temperature based method. The image-space temperature based method improves the reproducibility in the calibration of radiometer and reduces the uncertainties existing in the conventional calibration methods. The calibrated radiometer is then used to establish the irradiance transfer standard for the target simulator. With the designed radiometer in this paper, a highly accurate irradiance calibration for target simulators of wavelength from 2.05 to 2.55 μm and from 3.7 to 4.8 μm can be performed with an expanded uncertainty (k = 2) of calibration of 2.18%. Last but not least, the infrared radiation of the target simulator was measured by the infrared radiometer, the effectiveness and capability of which are verified through measurement of temperature and irradiance and a comparison with the thermal imaging camera.

  7. Glue Film Thickness Measurements by Spectral Reflectance

    SciTech Connect (OSTI)

    B. R. Marshall

    2010-09-20

    Spectral reflectance was used to determine the thickness of thin glue layers in a study of the effect of the glue on radiance and reflectance measurements of shocked-tin substrates attached to lithium fluoride windows. Measurements based on profilometry of the components were found to be inaccurate due to flatness variations and deformation of the tin substrate under pressure during the gluing process. The accuracy of the spectral reflectance measurements were estimated to be ±0.5 μm, which was sufficient to demonstrate a convincing correlation between glue thickness and shock-generated light.

  8. ARM: Shortwave Array Spectroradiometer-Zenith, Radiance and Transmitta...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC), Biological and Environmental Research (BER) ... Subject: 54 Environmental Sciences Shortwave spectral direct normal irradiance; Shortwave ...

  9. Spectral, mechanical, thermal, optical and solid state parameters...

    Office of Scientific and Technical Information (OSTI)

    belongs to triclinic system with the space group P-1. Functional groups in bis(hydrogenmaleate)-Co(II) tetrahydrate were identified by Fourier transform infrared spectral analysis. ...

  10. Method to analyze remotely sensed spectral data

    DOE Patents [OSTI]

    Stork, Christopher L.; Van Benthem, Mark H.

    2009-02-17

    A fast and rigorous multivariate curve resolution (MCR) algorithm is applied to remotely sensed spectral data. The algorithm is applicable in the solar-reflective spectral region, comprising the visible to the shortwave infrared (ranging from approximately 0.4 to 2.5 .mu.m), midwave infrared, and thermal emission spectral region, comprising the thermal infrared (ranging from approximately 8 to 15 .mu.m). For example, employing minimal a priori knowledge, notably non-negativity constraints on the extracted endmember profiles and a constant abundance constraint for the atmospheric upwelling component, MCR can be used to successfully compensate thermal infrared hyperspectral images for atmospheric upwelling and, thereby, transmittance effects. Further, MCR can accurately estimate the relative spectral absorption coefficients and thermal contrast distribution of a gas plume component near the minimum detectable quantity.

  11. BEO Tram Spectral Data 2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Torn, Margaret; Serbin, Shawn

    2015-06-10

    Visible to near-infrared (350-1100nm) vegetation spectral reflectance data collected on the BEO automated tram measurement platform during the 2014 growing season. The spectra were collected using a PP Systems UniSpec-DC instrument and was processed to at-surface reflectance and interpolated to 1nm.

  12. Instrillment Development Multi-Spectral Automated Rotating Shadowt)and Radiometry

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Instrillment Development Multi-Spectral Automated Rotating Shadowt)and Radiometry L. Harrison Atmospheric: Sciences Research Center State University of New York at Albany Albany, NY 12205 I am developing two related instruments for use in the Atmospheric Radiation Measurement (ARM) p,rogram; both use an automated rotating shadowband technique to make spectrally resolved measurements of the direct-normal, total horizontal, and diffuse horizontal irradiances. These parameters of the sky-radiance

  13. Infrared thermography

    SciTech Connect (OSTI)

    Roberts, C.C. Jr.

    1982-12-01

    Infrared thermography is a useful tool for the diagnosis of problems in building systems. In instances where a building owner has several large buildings, an investment in a typical $30,000 infrared system may be cost effective. In most instances, however, the rental of an infrared system or the hiring of an infrared consulting service is a cost effective alternative. As can be seen from the several applications presented here, any mechanical problem manifesting itself in an atypical temperature pattern can usually be detected. The two primary savings generated from infrared analysis of building systems are maintenance and energy.

  14. Improved ARM-SGP TOA OLR Fluxes from GOES-8 IR Radiances Based on CERES Data

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ARM-SGP TOA OLR Fluxes from GOES-8 IR Radiances Based on CERES Data D. R. Doelling and M. M. Khaiyer Analytical Services and Materials, Inc. Hampton, Virginia P. Minnis National Aeronautics and Space Administration Langley Research Center Hampton, Virginia Introduction The radiation budget at the top of the atmosphere (TOA) is a quantity of fundamental importance to the Atmospheric Radiation Measurement (ARM) Program. Thus, it is necessary to measure the radiation budget components, broadband

  15. Acceleration of Radiance for Lighting Simulation by Using Parallel Computing with OpenCL

    SciTech Connect (OSTI)

    Zuo, Wangda; McNeil, Andrew; Wetter, Michael; Lee, Eleanor

    2011-09-06

    We report on the acceleration of annual daylighting simulations for fenestration systems in the Radiance ray-tracing program. The algorithm was optimized to reduce both the redundant data input/output operations and the floating-point operations. To further accelerate the simulation speed, the calculation for matrix multiplications was implemented using parallel computing on a graphics processing unit. We used OpenCL, which is a cross-platform parallel programming language. Numerical experiments show that the combination of the above measures can speed up the annual daylighting simulations 101.7 times or 28.6 times when the sky vector has 146 or 2306 elements, respectively.

  16. Simulating the Daylight Performance of Complex Fenestration Systems Using Bidirectional Scattering Distribution Functions within Radiance

    SciTech Connect (OSTI)

    Ward, Gregory; Mistrick, Ph.D., Richard; Lee, Eleanor; McNeil, Andrew; Jonsson, Ph.D., Jacob

    2011-01-21

    We describe two methods which rely on bidirectional scattering distribution functions (BSDFs) to model the daylighting performance of complex fenestration systems (CFS), enabling greater flexibility and accuracy in evaluating arbitrary assemblies of glazing, shading, and other optically-complex coplanar window systems. Two tools within Radiance enable a) efficient annual performance evaluations of CFS, and b) accurate renderings of CFS despite the loss of spatial resolution associated with low-resolution BSDF datasets for inhomogeneous systems. Validation, accuracy, and limitations of the methods are discussed.

  17. SU-E-T-470: Beam Performance of the Radiance 330 Proton Therapy System

    SciTech Connect (OSTI)

    Nazaryan, H; Nazaryan, V; Wang, F; Flanz, J; Alexandrov, V

    2014-06-01

    Purpose: The ProTom Radiance 330 proton radiotherapy system is a fully functional, compact proton radiotherapy system that provides advanced proton delivery capabilities. It supports three-dimensional beam scanning with energy and intensity modulation. A series of measurements have been conducted to characterize the beam performance of the first installation of the system at the McLaren Proton Therapy Center in Flint, Michigan. These measurements were part of the technical commissioning of the system. Select measurements and results are presented. Methods: The Radiance 330 proton beam energy range is 70250 MeV for treatment, and up to 330 MeV for proton tomography and radiography. Its 3-D scanning capability, together with a small beam emittance and momentum spread, provides a highly efficient beam delivery. During the technical commissioning, treatment plans were created to deliver uniform maps at various energies to perform Gamma Index analysis. EBT3 Gafchromic films were irradiated using the Planned irradiation maps. Bragg Peak chamber was used to test the dynamic range during a scan in one layer for high (250 MeV) and Low (70 MeV) energies. The maximum and minimum range, range adjustment and modulation, distal dose falloff (80%20%), pencil beam spot size, spot placement accuracy were also measured. The accuracy testing included acquiring images, image registration, receiving correction vectors and applying the corrections to the robotic patient positioner. Results: Gamma Index analysis of the Treatment Planning System (TPS) data vs. Measured data showed more than 90% of points within (3%, 3mm) for the maps created by the TPS. At Isocenter Beam Size (One sigma) < 3mm at highest energy (250 MeV) in air. Beam delivery was within 0.6 mm of the intended target at the entrance and the exit of the beam, through the phantom. Conclusion: The Radiance 330 Beam Performance Measurements have confirmed that the system operates as designed with excellent clinical

  18. Acceleration of the matrix multiplication of Radiance three phase daylighting simulations with parallel computing on heterogeneous hardware of personal computer

    SciTech Connect (OSTI)

    Zuo, Wangda; McNeil, Andrew; Wetter, Michael; Lee, Eleanor S.

    2013-05-23

    Building designers are increasingly relying on complex fenestration systems to reduce energy consumed for lighting and HVAC in low energy buildings. Radiance, a lighting simulation program, has been used to conduct daylighting simulations for complex fenestration systems. Depending on the configurations, the simulation can take hours or even days using a personal computer. This paper describes how to accelerate the matrix multiplication portion of a Radiance three-phase daylight simulation by conducting parallel computing on heterogeneous hardware of a personal computer. The algorithm was optimized and the computational part was implemented in parallel using OpenCL. The speed of new approach was evaluated using various daylighting simulation cases on a multicore central processing unit and a graphics processing unit. Based on the measurements and analysis of the time usage for the Radiance daylighting simulation, further speedups can be achieved by using fast I/O devices and storing the data in a binary format.

  19. Surface contamination detection by means of near-infrared stimulation of thermal luminescence

    SciTech Connect (OSTI)

    Carrieri, Arthur H.; Roese, Erik S

    2006-02-01

    A method for remotely detecting liquid chemical contamination on terrestrial surfaces is presented. Concurrent to irradiation by an absorbing near-infrared beam, the subject soil medium liberates radiance called thermal luminescence (TL) comprising middle-infrared energies (numir) that is scanned interferometrically in beam duration tau. Cyclic states of absorption and emission by the contaminant surrogate are rendered from a sequential differential-spectrum measurement [deltaS(numir,tau)] of the scanned TL. Detection of chemical warfare agent simulant wetting soil is performed in this manner, for example, through pattern recognition of its unique, thermally dynamic, molecular vibration resonance bands on display in the deltaS(numir,tau) metric.

  20. Infrared floodlight

    DOE Patents [OSTI]

    Levin, Robert E.; English, George J.

    1986-08-05

    An infrared floodlight assembly designed particularly for security purposes and including a heat-conducting housing, a lens secured to the housing to provide a closure therefor, and a floodlight located within (and surrounded by) the housing. The floodlight combines the use of a tungsten halogen light source and dichroic hot and cold mirrors for directing substantially only infrared radiation toward the assembly's forward lens. Visible radiation is absorbed by the housing's interior wall(s) and, optionally, by a filter located between the floodlight and lens. An optional means may be used within the floodlight to reflect all forward radiation back toward the paraboloidal hot mirror or, alternatively, to reflect only visible radiation in this direction. The dichroic hot and cold mirrors preferably each comprise a glass substrate having multiple layers of titanium dioxide and silicon dioxide thereon.

  1. Instrument development for atmospheric radiation measurement (ARM): Status of the Atmospheric Emitted Radiance Interferometer - extended Resolution (AERI-X), the Solar Radiance Transmission Interferometer (SORTI), and the Absolute Solar Transmission Inferometer (ASTI)

    SciTech Connect (OSTI)

    Murcray, F.; Stephen, T.; Kosters, J.

    1996-04-01

    This paper describes three instruments currently under developemnt for the Atmospheric Radiation Measurement (ARM) Program at the University of Denver: the AERI-X (Atmospheric Emitted Radiance Interferometer-Extended Resolution) and the SORTI (Solar R adiance Transmission Interferometer), and ASTI (Absolute Solar transmission Interferometer).

  2. Multidimensional spectral load balancing

    SciTech Connect (OSTI)

    Hendrickson, B.; Leland, R.

    1993-01-01

    We describe an algorithm for the static load balancing of scientific computations that generalizes and improves upon spectral bisection. Through a novel use of multiple eigenvectors, our new spectral algorithm can divide a computation into 4 or 8 pieces at once. These multidimensional spectral partitioning algorithms generate balanced partitions that have lower communication overhead and are less expensive to compute than those produced by spectral bisection. In addition, they automatically work to minimize message contention on a hypercube or mesh architecture. These spectral partitions are further improved by a multidimensional generalization of the Kernighan-Lin graph partitioning algorithm. Results on several computational grids are given and compared with other popular methods.

  3. Relative Infrared (IR) and Terahertz (THz) Signatures of Common Explosives

    SciTech Connect (OSTI)

    Sharpe, Steven W.; Johnson, Timothy J.; Sheen, David M.; Atkinson, David A.

    2006-11-13

    Pacific Northwest National Laboratory (PNNL) has recently recorded the infrared (IR) and far-infrared (sometimes called the terahertz, THz) spectral signatures of four common explosives, in the condensed phase. The signatures of RDX, PETN, TNT and Tetryl were recorded both in the infrared and the THz domains, using Fourier transform infrared (FTIR) spectroscopy. Samples consisted of thin films and were made by depositing and subsequent evaporation of an acetone-explosive mixture. The complete spectrum spanned the range from 4,000 to 8 cm-1 at 2.0 cm-1 spectral resolution. Preliminary results in the infrared agree with those of previous workers, while the THz signatures are one order of magnitude weaker than the strongest IR bands.

  4. Enhanced Thermal Stability of W-Ni-Al2O3 Cermet-Based Spectrally...

    Office of Scientific and Technical Information (OSTI)

    Solar Absorbers with Tungsten Infrared Reflectors Citation Details In-Document Search Title: Enhanced Thermal Stability of W-Ni-Al2O3 Cermet-Based Spectrally Selective Solar ...

  5. Far-Infrared Spectral Observations of the Galaxy by COBE

    SciTech Connect (OSTI)

    Reach, W.T.; Dwek, E.; Fixsen, D.J.; Hewagama, T.; Mather, J.C.; Shafer, R.A.; Banday, A.J.; Bennett, C.L.; Cheng, E.S.; Eplee Jr., R.E.,; Leisawi tz, D.; Lubin, P.M.; Read, S.M.; Rosen, L.P.; Shuman, F.G.D.; Smoot, G.F.; Sodroski, T.J.; Wright, E.L.

    1994-10-27

    We derive Galactic continuum spectra from 5-96 cm(-1) fromCOBE/FIRAS observations. The spectra are dominated by warm dust emission,which may be fitted with a single temperature in the range 16-21 K (fornu(2) emissivity) along each line of sight. Dust heated by the attenuatedradiation field in molecular clouds gives rise tointermediate-temperature (10-14 K) emission in the inner Galaxy only. Awidespread, very cold component (4-7 K) with optical depth that isspatially correlated with the warm component is also detected. The coldcomponent is unlikely to be due to very cold dust shielded from starlightbecause it is present at high latitude. We consider hypotheses that thecold component is due to enhanced submillimeter emissivity of the dustthat gives rise to the warm component, or that it may be due to verysmall, large, or fractal particles. Lack of substantial power above theemission from warm dust places strong constraints on the amount of coldgas in the Galaxy. The microwave sky brightness due to interstellar dustis dominated by the cold component, and its angular variation could limitour ability to discern primordial fluctuations in the cosmic microwavebackground radiation.

  6. MID-INFRARED SPECTRAL INDICATORS OF STAR FORMATION AND ACTIVE...

    Office of Scientific and Technical Information (OSTI)

    and, with poorer statistics, of the neon emission lines and molecular hydrogen ... ENERGY BALANCE; GALAXIES; LUMINOSITY; NEON; PHOTOMETRY; POLYCYCLIC AROMATIC ...

  7. Multi-spectral Infrared Computed Tomography (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States) Sponsoring Org: USDOE Country of Publication: United States Language: English Word Cloud More Like ...

  8. XPS Spectral Database - JCAP

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    JCAP20130222-220.jpg XPS Spectral Database Research Why Solar Fuels Goals & Objectives Thrust 1 Thrust 2 Thrust 3 Thrust 4 Publications Research Highlights Videos Innovations User Facilities Expert Team Benchmarking Database Device Simulation Tool XPS Spectral Database Research Introduction Why Solar Fuels? Goals & Objectives Thrusts Thrust 1 Thrust 2 Thrust 3 Thrust 4 Library Publications Research Highlights Videos Resources User Facilities Expert Team Benchmarking Database Device

  9. Thermophotovoltaic Spectral Control

    SciTech Connect (OSTI)

    DM DePoy; PM Fourspring; PF Baldasaro; JF Beausang; EJ Brown; MW Dashiel; KD Rahner; TD Rahmlow; JE Lazo-Wasem; EJ Gratrix; B Wemsman

    2004-06-09

    Spectral control is a key technology for thermophotovoltaic (TPV) direct energy conversion systems because only a fraction (typically less than 25%) of the incident thermal radiation has energy exceeding the diode bandgap energy, E{sub g}, and can thus be converted to electricity. The goal for TPV spectral control in most applications is twofold: (1) Maximize TPV efficiency by minimizing transfer of low energy, below bandgap photons from the radiator to the TPV diode. (2) Maximize TPV surface power density by maximizing transfer of high energy, above bandgap photons from the radiator to the TPV diode. TPV spectral control options include: front surface filters (e.g. interference filters, plasma filters, interference/plasma tandem filters, and frequency selective surfaces), back surface reflectors, and wavelength selective radiators. System analysis shows that spectral performance dominates diode performance in any practical TPV system, and that low bandgap diodes enable both higher efficiency and power density when spectral control limitations are considered. Lockheed Martin has focused its efforts on front surface tandem filters which have achieved spectral efficiencies of {approx}83% for E{sub g} = 0.52 eV and {approx}76% for E{sub g} = 0.60 eV for a 950 C radiator temperature.

  10. Aerosol Properties from Multi-spectral and Multi-angular Aircraft 4STAR Observations: Expected Advantages and Challenges

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Flynn, Connor J.; Redemann, Jens; Schmid, Beat; Russell, P. B.; Sinyuk, Alexander

    2012-11-01

    The airborne Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) is developed to retrieve aerosol microphysical and optical properties from multi-angular and multi-spectral measurements of sky radiance and direct-beam sun transmittance. The necessarily compact design of the 4STAR may cause noticeable apparent enhancement of sky radiance at small scattering angles. We assess the sensitivity of expected 4STAR-based aerosol retrieval to such enhancement by applying the operational AERONET retrieval code and constructed synthetic 4STARlike data. Also, we assess the sensitivity of the broadband fluxes and the direct aerosol radiative forcing to uncertainties in aerosol retrievals associated with the sky radiance enhancement. Our sensitivity study results suggest that the 4STARbased aerosol retrieval has limitations in obtaining detailed information on particle size distribution and scattering phase function. However, these limitations have small impact on the retrieved bulk optical parameters, such as the asymmetry factor (up to 4%, or 0.02) and single-scattering albedo (up to 2%, or 0.02), and the calculated direct aerosol radiative forcing (up to 6%, or 2 Wm-2).

  11. Uncooled infrared photon detector and multicolor infrared detection...

    Office of Scientific and Technical Information (OSTI)

    A multicolor infrared sensor includes a stack of frequency specific optomechanical ... lattice; strain; multicolor; infrared; sensor; stack; frequency; specific; ...

  12. Studies of planetary boundary layer by infrared thermal imagery

    SciTech Connect (OSTI)

    Albina, Bogdan; Dimitriu, Dan Gheorghe Gurlui, Silviu Octavian; Cazacu, Marius Mihai; Timofte, Adrian

    2014-11-24

    The IR camera is a relatively novel device for remote sensing of atmospheric thermal processes from the Planetary Boundary Layer (PBL) based on measurements of the infrared radiation. Infrared radiation is energy radiated by the motion of atoms and molecules on the surface of aerosols, when their temperature is more than absolute zero. The IR camera measures directly the intensity of radiation emitted by aerosols which is converted by an imaging sensor into an electric signal, resulting a thermal image. Every image pixel that corresponds to a specific radiance is pre-processed to identify the brightness temperature. The thermal infrared imaging radiometer used in this study, NicAir, is a precision radiometer developed by Prata et al. The device was calibrated for the temperature range of 270–320 K and using a calibration table along with image processing software, important information about variations in temperature can be extracted from acquired IR images. The PBL is the lowest layer of the troposphere where the atmosphere interacts with the ground surfaces. The importance of PBL lies in the fact that it provides a finite but varying volume in which pollutants can disperse. The aim of this paper is to analyze the PBL altitude and thickness variations over Iasi region using the IR imaging camera as well as its behavior from day to night and thermal processes occurring in PBL.

  13. Use of the ARM Measurements of Spectral Zenith Radiance for Better Understanding of 3D Cloud-Radiation Processes & Aerosol-Cloud Interaction

    SciTech Connect (OSTI)

    Chiu, Jui-Yuan Christine

    2014-04-10

    This project focuses on cloud-radiation processes in a general three-dimensional cloud situation, with particular emphasis on cloud optical depth and effective particle size. The proposal has two main parts. Part one exploits the large number of new wavelengths offered by the Atmospheric Radiation Measurement (ARM) zenith-pointing ShortWave Spectrometer (SWS), to develop better retrievals not only of cloud optical depth but also of cloud particle size. We also take advantage of the SWS’ high sampling resolution to study the “twilight zone” around clouds where strong aerosol-cloud interactions are taking place. Part two involves continuing our cloud optical depth and cloud fraction retrieval research with ARM’s 2-channel narrow vield-of-view radiometer and sunphotometer instrument by, first, analyzing its data from the ARM Mobile Facility deployments, and second, making our algorithms part of ARM’s operational data processing.

  14. Parametric Explosion Spectral Model

    SciTech Connect (OSTI)

    Ford, S R; Walter, W R

    2012-01-19

    Small underground nuclear explosions need to be confidently detected, identified, and characterized in regions of the world where they have never before occurred. We develop a parametric model of the nuclear explosion seismic source spectrum derived from regional phases that is compatible with earthquake-based geometrical spreading and attenuation. Earthquake spectra are fit with a generalized version of the Brune spectrum, which is a three-parameter model that describes the long-period level, corner-frequency, and spectral slope at high-frequencies. Explosion spectra can be fit with similar spectral models whose parameters are then correlated with near-source geology and containment conditions. We observe a correlation of high gas-porosity (low-strength) with increased spectral slope. The relationship between the parametric equations and the geologic and containment conditions will assist in our physical understanding of the nuclear explosion source.

  15. High dynamic range measurement of spectral responsivity and linearity of a radiation thermometer using a super-continuum laser and LEDs

    SciTech Connect (OSTI)

    Yoo, Y. S.; Lee, D. H.; Park, C. W.; Park, S. N. [Korea Research Institute of Standards and Science 209 Gajeong-Ro, Yuseong-Gu, Daejon 305-340 (Korea, Republic of)] [Korea Research Institute of Standards and Science 209 Gajeong-Ro, Yuseong-Gu, Daejon 305-340 (Korea, Republic of)

    2013-09-11

    To realize the temperature scale above the freezing point of silver according to the definition of ITS-90, the dynamic range of the spectral responsivity is one of the most important factors which limit its uncertainty. When the residual spectral response at both side bands of a spectral band is not negligible, a significant uncertainty can be caused by a low dynamic range of the spectral responsivity measurement. In general, incandescent lamps are used to measure the spectral responsivity and the linearity. The dynamic range of the spectral responsivity measurement is often limited by a trade-off with the desired spectral resolution, which is less than 6 decades. Nonlinearity is another limiting fact of uncertainties of the temperature scale. Tungsten lamps have disadvantage in the nonlinearity measurements in terms of adjustability of radiance level and spectral selectivity. We report spectral responsivity measurements of which the measurable dynamic range is enhanced 50 times after replacing a QTH lamp with a super continuum laser. We also present a spectrally selected linearity measurement over a wide dynamic range using high-brightness light emitting diode arrays to observe a slight saturation of linearity.

  16. LCLS Spectral Flux Viewer

    Energy Science and Technology Software Center (OSTI)

    2005-10-25

    This application (FluxViewer) is a tool for displaying spectral flux data for the Linac Coherent Light Source (LCLS). This tool allows the user to view sliced spatial and energy distributions of the photons selected for specific energies and positions transverse to the beam axis.

  17. A new facility for the synchrotron radiation-based calibration of transfer radiation sources in the ultraviolet and vacuum ultraviolet spectral range

    SciTech Connect (OSTI)

    Thornagel, Reiner; Fliegauf, Rolf; Klein, Roman Kroth, Simone; Paustian, Wolfgang; Richter, Mathias

    2015-01-15

    The Physikalisch-Technische Bundesanstalt (PTB) has a long tradition in the calibration of radiation sources in the ultraviolet and vacuum ultraviolet spectral range, with traceability to calculable synchrotron radiation. Within this context, new instrumentation in the PTB laboratory at the Metrology Light Source (MLS) has been put into operation that opens up extended and improved calibration possibilities. A new facility for radiation source calibrations has been set up in the spectral range from 7 nm to 400 nm based on a combined normal incidence-grazing incidence monochromator. The facility can be used for the calibration of transfer sources in terms of spectral radiant intensity or mean spectral radiance, with traceability to the MLS primary source standard. We describe the design and performance of the experimental station and give examples of some commissioning results.

  18. INFRARED STUDIES OF EPSILON AURIGAE IN ECLIPSE

    SciTech Connect (OSTI)

    Stencel, Robert E.; Kloppenborg, Brian K.; Wall, Randall E.; Hopkins, Jeffrey L.; Howell, Steve B.; Hoard, D. W.; Rayner, John; Bus, Schelte; Tokunaga, Alan; Sitko, Michael L.; Bradford, Suellen; Russell, Ray W.; Lynch, David K.; Hammel, Heidi; Whitney, Barbara; Orton, Glenn; Yanamandra-Fisher, Padma; Hora, Joseph L.; Hinz, Philip; Hoffmann, William; and others

    2011-11-15

    We report here on a series of medium resolution spectro-photometric observations of the enigmatic long period eclipsing binary epsilon Aurigae, during its eclipse interval of 2009-2011, using near-infrared spectra obtained with SpeX on the Infrared Telescope Facility (IRTF), mid-infrared spectra obtained with BASS on AOES and IRTF, MIRSI on IRTF, and MIRAC4 on the MMT, along with mid-infrared photometry using MIRSI on IRTF and MIRAC4 on the MMT, plus 1995-2000 timeframe published photometry and data obtained with Denver's TNTCAM2 at WIRO. The goals of these observations included: (1) comparing eclipse depths with prior eclipse data, (2) confirming the re-appearance of CO absorption bands at and after mid-eclipse, associated with sublimation in the disk, (3) seeking evidence for any mid-infrared solid state spectral features from particles in the disk, and (4) providing evidence that the externally irradiated disk has azimuthal temperature differences. IR eclipse depths appear similar to those observed during the most recent (1983) eclipse, although evidence for post-mid-eclipse disk temperature increase is present, due to F star heated portions of the disk coming into view. Molecular CO absorption returned 57 days after nominal mid-eclipse, but was not detected at mid-eclipse plus 34 days, narrowing the association with differentially heated sub-regions in the disk. Transient He I 10830A absorption was detected at mid-eclipse, persisting for at least 90 days thereafter, providing a diagnostic for the hot central region. The lack of solid-state features in Spitzer Infrared Spectrograph, BASS, and MIRAC spectra to date suggests the dominance of large particles (micron-sized) in the disk. Based on these observations, mid-infrared studies out of eclipse can directly monitor and map the disk thermal changes, and better constrain disk opacity and thermal conductivity.

  19. Infrared microscope inspection apparatus

    DOE Patents [OSTI]

    Forman, S.E.; Caunt, J.W.

    1985-02-26

    Apparatus and system for inspecting infrared transparents, such as an array of photovoltaic modules containing silicon solar cells, includes an infrared microscope, at least three sources of infrared light placed around and having their axes intersect the center of the object field and means for sending the reflected light through the microscope. The apparatus is adapted to be mounted on an X-Y translator positioned adjacent the object surface. 4 figs.

  20. Infrared microscope inspection apparatus

    DOE Patents [OSTI]

    Forman, Steven E.; Caunt, James W.

    1985-02-26

    Apparatus and system for inspecting infrared transparents, such as an array of photovoltaic modules containing silicon solar cells, includes an infrared microscope, at least three sources of infrared light placed around and having their axes intersect the center of the object field and means for sending the reflected light through the microscope. The apparatus is adapted to be mounted on an X-Y translator positioned adjacent the object surface.

  1. Far infrared supplement: Catalog of infrared observations, second edition

    SciTech Connect (OSTI)

    Gezari, D.Y.; Schmitz, M.; Mead, J.M.

    1988-08-01

    The Far Infrared Supplement: Catalog of Infrared Observations summarizes all infrared astronomical observations at far infrared wavelengths (5 to 1000 microns) published in the scientific literature from 1965 through 1986. The Supplement list contain 25 percent of the observations in the full Catalog of Infrared Observations (CIO), and essentially eliminates most visible stars from the listings. The Supplement is thus more compact than the main catalog, and is intended for easy reference during astronomical observations. The Far Infrared Supplement (2nd Edition) includes the Index of Infrared Source Positions and the Bibliography of Infrared Astronomy for the subset of far infrared observations listed.

  2. Spectral tailoring device

    DOE Patents [OSTI]

    Brager, H.R.; Schenter, R.E.; Carter, L.L.; Karnesky, R.A.

    1987-08-05

    A spectral tailoring device for altering the neutron energy spectra and flux of neutrons in a fast reactor thereby selectively to enhance or inhibit the transmutation rate of a target metrical to form a product isotope. Neutron moderators, neutron filters, neutron absorbers and neutron reflectors may be used as spectral tailoring devices. Depending on the intended use for the device, a member from each of these four classes of materials could be used singularly, or in combination, to provide a preferred neutron energy spectra and flux of the neutrons in the region of the target material. In one embodiment of the invention, an assembly is provided for enhancing the production of isotopes, such as cobalt 60 and gadolinium 153. In another embodiment of the invention, a spectral tailoring device is disposed adjacent a target material which comprises long lived or volatile fission products and the device is used to shift the neutron energy spectra and flux of neutrons in the region of the fission products to preferentially transmute them to produce a less volatile fission product inventory. 6 figs.

  3. Invited Article: An integrated mid-infrared, far-infrared, and terahertz optical Hall effect instrument

    SciTech Connect (OSTI)

    Kühne, P. Schubert, M. Hofmann, T.; Herzinger, C. M. Woollam, J. A.

    2014-07-15

    We report on the development of the first integrated mid-infrared, far-infrared, and terahertz optical Hall effect instrument, covering an ultra wide spectral range from 3 cm{sup −1} to 7000 cm{sup −1} (0.1–210 THz or 0.4–870 meV). The instrument comprises four sub-systems, where the magneto-cryostat-transfer sub-system enables the usage of the magneto-cryostat sub-system with the mid-infrared ellipsometer sub-system, and the far-infrared/terahertz ellipsometer sub-system. Both ellipsometer sub-systems can be used as variable angle-of-incidence spectroscopic ellipsometers in reflection or transmission mode, and are equipped with multiple light sources and detectors. The ellipsometer sub-systems are operated in polarizer-sample-rotating-analyzer configuration granting access to the upper left 3 × 3 block of the normalized 4 × 4 Mueller matrix. The closed cycle magneto-cryostat sub-system provides sample temperatures between room temperature and 1.4 K and magnetic fields up to 8 T, enabling the detection of transverse and longitudinal magnetic field-induced birefringence. We discuss theoretical background and practical realization of the integrated mid-infrared, far-infrared, and terahertz optical Hall effect instrument, as well as acquisition of optical Hall effect data and the corresponding model analysis procedures. Exemplarily, epitaxial graphene grown on 6H-SiC, a tellurium doped bulk GaAs sample and an AlGaN/GaN high electron mobility transistor structure are investigated. The selected experimental datasets display the full spectral, magnetic field and temperature range of the instrument and demonstrate data analysis strategies. Effects from free charge carriers in two dimensional confinement and in a volume material, as well as quantum mechanical effects (inter-Landau-level transitions) are observed and discussed exemplarily.

  4. Design and implementation of a rapid-mixer flow cell for time-resolved infrared microspectroscopy

    SciTech Connect (OSTI)

    Marinkovic, Nebojsa S.; Adzic, Aleksandar R.; Sullivan, Michael; Kovacs, Kevin; Miller, Lisa M.; Rousseau, Denis L.; Yeh, Syun-Ru; Chance, Mark R.

    2000-11-01

    A rapid mixer for the analysis of reactions in the millisecond and submillisecond time domains by Fourier-transform infrared microspectroscopy has been constructed. The cell was tested by examination of cytochrome-c folding kinetics. The device allows collection of full infrared spectral data on millisecond and faster time scales subsequent to chemical jump reaction initiation. The data quality is sufficiently good such that spectral fitting techniques could be applied to analysis of the data. Thus, this method provides an advantage over kinetic measurements at single wavelengths using infrared laser or diode sources, particularly where band overlap exists.

  5. Transition undulator radiation as bright infrared sources

    SciTech Connect (OSTI)

    Kim, K.J.

    1995-02-01

    Undulator radiation contains, in addition to the usual component with narrow spectral features, a broad-band component in the low frequency region emitted in the near forward direction, peaked at an angle 1/{gamma}, where {gamma} is the relativistic factor. This component is referred to as the transition undulator radiation, as it is caused by the sudden change in the electron`s longitudinal velocity as it enters and leaves the undulator. The characteristic of the transition undulator radiation are analyzed and compared with the infrared radiation from the usual undulator harmonics and from bending magnets.

  6. Method of multivariate spectral analysis

    DOE Patents [OSTI]

    Keenan, Michael R.; Kotula, Paul G.

    2004-01-06

    A method of determining the properties of a sample from measured spectral data collected from the sample by performing a multivariate spectral analysis. The method can include: generating a two-dimensional matrix A containing measured spectral data; providing a weighted spectral data matrix D by performing a weighting operation on matrix A; factoring D into the product of two matrices, C and S.sup.T, by performing a constrained alternating least-squares analysis of D=CS.sup.T, where C is a concentration intensity matrix and S is a spectral shapes matrix; unweighting C and S by applying the inverse of the weighting used previously; and determining the properties of the sample by inspecting C and S. This method can be used to analyze X-ray spectral data generated by operating a Scanning Electron Microscope (SEM) with an attached Energy Dispersive Spectrometer (EDS).

  7. ARM - Field Campaign - ASSIST: Atmospheric Sounder Spectrometer for

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Spectral Technology govCampaignsASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : ASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology 2008.07.08 - 2008.07.18 Lead Scientist : Michael Howard For data sets, see below. Abstract Goals of assist were to intercompare radiance spectra and profile retrievals

  8. Application Of High-Resolution Thermal Infrared Sensors For Geothermal...

    Open Energy Information (Open El) [EERE & EIA]

    comparison to SEBASS. The land-leaving TIR radiance data were separated into brightness temperature and surface emissivity. TIR emissivity data are unique to each mineral and a...

  9. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE PAGES-Beta [OSTI]

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-02-16

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer cloud using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievals using synthetic measurements from large-eddy simulation snapshots of cumulusmore » under stratocumulus, where cloud water path is retrieved with an error of 31 g m−2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the northeast Pacific. Here, retrieved cloud water path agrees well with independent 3-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m−2.« less

  10. Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances

    DOE PAGES-Beta [OSTI]

    Fielding, M. D.; Chiu, J. C.; Hogan, R. J.; Feingold, G.; Eloranta, E.; O'Connor, E. J.; Cadeddu, M. P.

    2015-07-02

    Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a new method to simultaneously retrieve cloud and drizzle vertical profiles in drizzling boundary-layer clouds using surface-based observations of radar reflectivity, lidar attenuated backscatter, and zenith radiances under conditions when precipitation does not reach the surface. Specifically, the vertical structure of droplet size and water content of both cloud and drizzle is characterised throughout the cloud. An ensemble optimal estimation approach provides full error statistics given the uncertainty in the observations. To evaluate the new method, we first perform retrievalsmore » using synthetic measurements from large-eddy simulation snapshots of cumulus under stratocumulus, where cloud water path is retrieved with an error of 31 g m-2. The method also performs well in non-drizzling clouds where no assumption of the cloud profile is required. We then apply the method to observations of marine stratocumulus obtained during the Atmospheric Radiation Measurement MAGIC deployment in the Northeast Pacific. Here, retrieved cloud water path agrees well with independent three-channel microwave radiometer retrievals, with a root mean square difference of 10–20 g m-2.« less

  11. Covariance propagation in spectral indices

    DOE PAGES-Beta [OSTI]

    Griffin, P. J.

    2015-01-09

    In this study, the dosimetry community has a history of using spectral indices to support neutron spectrum characterization and cross section validation efforts. An important aspect to this type of analysis is the proper consideration of the contribution of the spectrum uncertainty to the total uncertainty in calculated spectral indices (SIs). This study identifies deficiencies in the traditional treatment of the SI uncertainty, provides simple bounds to the spectral component in the SI uncertainty estimates, verifies that these estimates are reflected in actual applications, details a methodology that rigorously captures the spectral contribution to the uncertainty in the SI, andmore » provides quantified examples that demonstrate the importance of the proper treatment the spectral contribution to the uncertainty in the SI.« less

  12. Covariance propagation in spectral indices

    SciTech Connect (OSTI)

    Griffin, P. J.

    2015-01-09

    In this study, the dosimetry community has a history of using spectral indices to support neutron spectrum characterization and cross section validation efforts. An important aspect to this type of analysis is the proper consideration of the contribution of the spectrum uncertainty to the total uncertainty in calculated spectral indices (SIs). This study identifies deficiencies in the traditional treatment of the SI uncertainty, provides simple bounds to the spectral component in the SI uncertainty estimates, verifies that these estimates are reflected in actual applications, details a methodology that rigorously captures the spectral contribution to the uncertainty in the SI, and provides quantified examples that demonstrate the importance of the proper treatment the spectral contribution to the uncertainty in the SI.

  13. ULTRAVIOLET RAMAN SPECTRAL SIGNATURE ACQUISITION: UV RAMAN SPECTRAL FINGERPRINTS.

    SciTech Connect (OSTI)

    SEDLACEK,III, A.J.FINFROCK,C.

    2002-09-01

    As a member of the science-support part of the ITT-lead LISA development program, BNL is tasked with the acquisition of UV Raman spectral fingerprints and associated scattering cross-sections for those chemicals-of-interest to the program's sponsor. In support of this role, the present report contains the first installment of UV Raman spectral fingerprint data on the initial subset of chemicals. Because of the unique nature associated with the acquisition of spectral fingerprints for use in spectral pattern matching algorithms (i.e., CLS, PLS, ANN) great care has been undertaken to maximize the signal-to-noise and to minimize unnecessary spectral subtractions, in an effort to provide the highest quality spectral fingerprints. This report is divided into 4 sections. The first is an Experimental section that outlines how the Raman spectra are performed. This is then followed by a section on Sample Handling. Following this, the spectral fingerprints are presented in the Results section where the data reduction process is outlined. Finally, a Photographs section is included.

  14. Variable waveband infrared imager

    DOE Patents [OSTI]

    Hunter, Scott R.

    2013-06-11

    A waveband imager includes an imaging pixel that utilizes photon tunneling with a thermally actuated bimorph structure to convert infrared radiation to visible radiation. Infrared radiation passes through a transparent substrate and is absorbed by a bimorph structure formed with a pixel plate. The absorption generates heat which deflects the bimorph structure and pixel plate towards the substrate and into an evanescent electric field generated by light propagating through the substrate. Penetration of the bimorph structure and pixel plate into the evanescent electric field allows a portion of the visible wavelengths propagating through the substrate to tunnel through the substrate, bimorph structure, and/or pixel plate as visible radiation that is proportional to the intensity of the incident infrared radiation. This converted visible radiation may be superimposed over visible wavelengths passed through the imaging pixel.

  15. Infrared Basics | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Infrared Basics Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Infrared Basics Author Protherm Published Publisher Not Provided, 2013 DOI Not Provided...

  16. Innovative Office Lighting System with Integrated Spectrally...

    Energy Savers

    Office Lighting System with Integrated Spectrally Adaptive Control Innovative Office Lighting System with Integrated Spectrally Adaptive Control Lead Performer: Philips Research ...

  17. Photon sorting in the near field using subwavelength cavity arrays in the near-infrared

    SciTech Connect (OSTI)

    Mandel, Isroel M. Lansey, Eli; Gollub, Jonah N.; Sarantos, Chris H.; Akhmechet, Roman; Golovin, Andrii B.; Crouse, David T.

    2013-12-16

    A frequency selective metasurface capable of sorting photons in the near-infrared spectral range is designed, fabricated, and characterized. The metasurface, a periodic array of dielectric cylindrical cavities in a gold film, localizes and transmits light of two spectral frequency bands into spatially separated cavities, resulting in near-field light splitting. The design and fabrication methodologies of the metasurface are discussed. The transmittance and photon sorting properties of the designed structure is simulated numerically and the measured transmission is presented.

  18. Infrared floodlight assembly

    DOE Patents [OSTI]

    Wierzbicki, Julian J.; Chakrabarti, Kirti B.

    1987-09-22

    An infrared floodlight assembly (10) including a cast aluminum outer housing (11) defining a central chamber (15) therein. A floodlight (14), having a tungsten halogen lamp as the light source, is spacedly positioned within a heat conducting member (43) within chamber (15) such that the floodlight is securedly positioned in an aligned manner relative to the assembly's filter (35) and lens (12) components. The invention also includes venting means (51) to allow air passage between the interior of the member (43) and the adjacent chamber (15), as well as engagement means (85) for engaging a rear surface of the floodlight (14) to retain it firmly against an internal flange of the member (43). A reflector (61), capable of being compressed to allow insertion or removal, is located within the heat conducting member's interior between the floodlight (14) and filter (35) to reflect infrared radiation toward the filter (35) and spaced lens (12).

  19. Pigments which reflect infrared radiation from fire

    DOE Patents [OSTI]

    Berdahl, Paul H.

    1998-01-01

    Conventional paints transmit or absorb most of the intense infrared (IR) radiation emitted by fire, causing them to contribute to the spread of fire. The present invention comprises a fire retardant paint additive that reflects the thermal IR radiation emitted by fire in the 1 to 20 micrometer (.mu.m) wavelength range. The important spectral ranges for fire control are typically about 1 to about 8 .mu.m or, for cool smoky fires, about 2 .mu.m to about 16 .mu.m. The improved inventive coatings reflect adverse electromagnetic energy and slow the spread of fire. Specific IR reflective pigments include titanium dioxide (rutile) and red iron oxide pigments with diameters of about 1 .mu.m to about 2 .mu.m and thin leafing aluminum flake pigments.

  20. Pigments which reflect infrared radiation from fire

    DOE Patents [OSTI]

    Berdahl, P.H.

    1998-09-22

    Conventional paints transmit or absorb most of the intense infrared (IR) radiation emitted by fire, causing them to contribute to the spread of fire. The present invention comprises a fire retardant paint additive that reflects the thermal IR radiation emitted by fire in the 1 to 20 micrometer ({micro}m) wavelength range. The important spectral ranges for fire control are typically about 1 to about 8 {micro}m or, for cool smoky fires, about 2 {micro}m to about 16 {micro}m. The improved inventive coatings reflect adverse electromagnetic energy and slow the spread of fire. Specific IR reflective pigments include titanium dioxide (rutile) and red iron oxide pigments with diameters of about 1 {micro}m to about 2 {micro}m and thin leafing aluminum flake pigments. 4 figs.

  1. TESTING THE HYPOTHESIS THAT METHANOL MASER RINGS TRACE CIRCUMSTELLAR DISKS: HIGH-RESOLUTION NEAR-INFRARED AND MID-INFRARED IMAGING

    SciTech Connect (OSTI)

    De Buizer, James M.; Bartkiewicz, Anna; Szymczak, Marian

    2012-08-01

    Milliarcsecond very long baseline interferometry maps of regions containing 6.7 GHz methanol maser emission have lead to the recent discovery of ring-like distributions of maser spots and the plausible hypothesis that they may be tracing circumstellar disks around forming high-mass stars. We aimed to test this hypothesis by imaging these regions in the near- and mid-infrared at high spatial resolution and compare the observed emission to the expected infrared morphologies as inferred from the geometries of the maser rings. In the near-infrared we used the Gemini North adaptive optics system of ALTAIR/NIRI, while in the mid-infrared we used the combination of the Gemini South instrument T-ReCS and super-resolution techniques. Resultant images had a resolution of {approx}150 mas in both the near-infrared and mid-infrared. We discuss the expected distribution of circumstellar material around young and massive accreting (proto)stars and what infrared emission geometries would be expected for the different maser ring orientations under the assumption that the masers are coming from within circumstellar disks. Based upon the observed infrared emission geometries for the four targets in our sample and the results of spectral energy distribution modeling of the massive young stellar objects associated with the maser rings, we do not find compelling evidence in support of the hypothesis that methanol masers rings reside in circumstellar disks.

  2. Frequency selective infrared sensors

    DOE Patents [OSTI]

    Davids, Paul; Peters, David W

    2013-05-28

    A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

  3. Frequency selective infrared sensors

    DOE Patents [OSTI]

    Davids, Paul; Peters, David W

    2014-11-25

    A frequency selective infrared (IR) photodetector having a predetermined frequency band. The exemplary frequency selective photodetector includes: a dielectric IR absorber having a first surface and a second surface substantially parallel to the first surface; an electrode electrically coupled to the first surface of the dielectric IR absorber; and a frequency selective surface plasmonic (FSSP) structure formed on the second surface of the dielectric IR absorber. The FSSP structure is designed to selectively transmit radiation in the predetermined frequency band that is incident on the FSSP structure substantially independent of the angle of incidence of the incident radiation on the FSSP structure.

  4. Infrared laser system

    DOE Patents [OSTI]

    Cantrell, Cyrus D.; Carbone, Robert J.; Cooper, Ralph

    1982-01-01

    An infrared laser system and method for isotope separation may comprise a molecular gas laser oscillator to produce a laser beam at a first wavelength, Raman spin flip means for shifting the laser to a second wavelength, a molecular gas laser amplifier to amplify said second wavelength laser beam to high power, and optical means for directing the second wavelength, high power laser beam against a desired isotope for selective excitation thereof in a mixture with other isotopes. The optical means may include a medium which shifts the second wavelength high power laser beam to a third wavelength, high power laser beam at a wavelength coincidental with a corresponding vibrational state of said isotope and which is different from vibrational states of other isotopes in the gas mixture.

  5. Infrared laser system

    DOE Patents [OSTI]

    Cantrell, Cyrus D.; Carbone, Robert J.; Cooper, Ralph S.

    1977-01-01

    An infrared laser system and method for isotope separation may comprise a molecular gas laser oscillator to produce a laser beam at a first wavelength, Raman spin flip means for shifting the laser to a second wavelength, a molecular gas laser amplifier to amplify said second wavelength laser beam to high power, and optical means for directing the second wavelength, high power laser beam against a desired isotope for selective excitation thereof in a mixture with other isotopes. The optical means may include a medium which shifts the second wavelength high power laser beam to a third wavelength, high power laser beam at a wavelength coincidental with a corresponding vibrational state of said isotope and which is different from vibrational states of other isotopes in the gas mixture.

  6. Lateral conduction infrared photodetector

    DOE Patents [OSTI]

    Kim, Jin K.; Carroll, Malcolm S.

    2011-09-20

    A photodetector for detecting infrared light in a wavelength range of 3-25 .mu.m is disclosed. The photodetector has a mesa structure formed from semiconductor layers which include a type-II superlattice formed of alternating layers of InAs and In.sub.xGa.sub.1-xSb with 0.ltoreq.x.ltoreq.0.5. Impurity doped regions are formed on sidewalls of the mesa structure to provide for a lateral conduction of photo-generated carriers which can provide an increased carrier mobility and a reduced surface recombination. An optional bias electrode can be used in the photodetector to control and vary a cut-off wavelength or a depletion width therein. The photodetector can be formed as a single-color or multi-color device, and can also be used to form a focal plane array which is compatible with conventional read-out integrated circuits.

  7. Dynamics, Spectral Geometry and Topology

    SciTech Connect (OSTI)

    Burghelea, Dan

    2011-02-10

    The paper is an informal report on joint work with Stefan Haller on Dynamics in relation with Topology and Spectral Geometry. By dynamics one means a smooth vector field on a closed smooth manifold; the elements of dynamics of concern are the rest points, instantons and closed trajectories. One discusses their counting in the case of a generic vector field which has some additional properties satisfied by a still very large class of vector fields.

  8. ARM - Facility News Article

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    July 31, 2008 [Facility News] Southern Great Plains Gets an "Assist" for Instrument Intercomparison Bookmark and Share In July, the SGP site hosted an instrument intercomparison between the AERI and the new ASSIST instrument, shown above. One instrument scientists use to obtain measurements important for climate studies is an atmospherically emitted radiance interferometer, or AERI. This sophisticated instrument measures the absolute infrared spectral radiance of the sky directly above

  9. NREL: Measurements and Characterization - Spectral Responsivity

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Spectral Responsivity Spectral responsivity (SR) measurement is an important part of the National Renewable Energy Laboratory (NREL) photovoltaic (PV) device performance assessment process. Spectral responsivity systems measure how a device responds to selected narrow (spectral) bands of irradiance. Responsivity is measured in units of amps per watt versus wavelength and reported in terms of quantum efficiency (QE) - a measure of how efficiently a device converts incoming photons to charge

  10. Solar spectral measurements and modeling

    SciTech Connect (OSTI)

    Bird, R.E.; Hulstrom, R.L.

    1981-01-01

    A newly developed spectroradiometer for routine measurement of the solar spectra is described. This instrument measures the solar spectrum between 300 and 2500 nm in less than 2.5 min, with 0.7-nm resolution in the visible and 10-nm resolution in the infrared. Many examples of global, direct, and diffuse spectra are illustrated for Bedford, Mass. and Golden, Colo. The effects of air mass, turbidity, and sun tracking on the spectrum are presented, and radiative transfer modeling capabilities and comparisons between models and between models and experiment are discussed.

  11. Probing Organic Transistors with Infrared Beams

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood,...

  12. Forward looking infrared | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    looking infrared Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Forward looking infrared Author Wikipedia Published Publisher Not Provided, 2013...

  13. Synchrotron Infrared Unveils a Mysterious Microbial Community

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Synchrotron Infrared Unveils a Mysterious Microbial Community Synchrotron Infrared Unveils a Mysterious Microbial Community Print Tuesday, 22 January 2013 00:00 A cold sulfur...

  14. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    infrared microspectroscopy at the ALS, with a diffraction-limited infrared beam diameter of less than 10 m, can overcome this hurdle. And while previous studies used...

  15. Template:SpectralImagingSensor | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    This is the 'Spectral Imaging Sensor' template. To define a new Spectral Imaging Sensor, please use the Spectral Imaging Sensor Form. Parameters Name - Full, spelled-out name...

  16. Mid-infrared tunable metamaterials

    DOE Patents [OSTI]

    Brener, Igal; Miao, Xiaoyu; Shaner, Eric A; Passmore, Brandon Scott; Jun, Young Chul

    2015-04-28

    A mid-infrared tunable metamaterial comprises an array of resonators on a semiconductor substrate having a large dependence of dielectric function on carrier concentration and a semiconductor plasma resonance that lies below the operating range, such as indium antimonide. Voltage biasing of the substrate generates a resonance shift in the metamaterial response that is tunable over a broad operating range. The mid-infrared tunable metamaterials have the potential to become the building blocks of chip based active optical devices in mid-infrared ranges, which can be used for many applications, such as thermal imaging, remote sensing, and environmental monitoring.

  17. Method for determining and displaying the spacial distribution of a spectral pattern of received light

    DOE Patents [OSTI]

    Bennett, Charles L.

    1996-01-01

    An imaging Fourier transform spectrometer (10, 210) having a Fourier transform infrared spectrometer (12) providing a series of images (40) to a focal plane array camera (38). The focal plane array camera (38) is clocked to a multiple of zero crossing occurrences as caused by a moving mirror (18) of the Fourier transform infrared spectrometer (12) and as detected by a laser detector (50) such that the frame capture rate of the focal plane array camera (38) corresponds to a multiple of the zero crossing rate of the Fourier transform infrared spectrometer (12). The images (40) are transmitted to a computer (45) for processing such that representations of the images (40) as viewed in the light of an arbitrary spectral "fingerprint" pattern can be displayed on a monitor (60) or otherwise stored and manipulated by the computer (45).

  18. Method for determining and displaying the spacial distribution of a spectral pattern of received light

    DOE Patents [OSTI]

    Bennett, C.L.

    1996-07-23

    An imaging Fourier transform spectrometer is described having a Fourier transform infrared spectrometer providing a series of images to a focal plane array camera. The focal plane array camera is clocked to a multiple of zero crossing occurrences as caused by a moving mirror of the Fourier transform infrared spectrometer and as detected by a laser detector such that the frame capture rate of the focal plane array camera corresponds to a multiple of the zero crossing rate of the Fourier transform infrared spectrometer. The images are transmitted to a computer for processing such that representations of the images as viewed in the light of an arbitrary spectral ``fingerprint`` pattern can be displayed on a monitor or otherwise stored and manipulated by the computer. 2 figs.

  19. WARM MOLECULAR GAS IN LUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Lu, N.; Zhao, Y.; Xu, C. K.; Mazzarella, J. M.; Howell, J.; Appleton, P.; Lord, S.; Schulz, B.; Gao, Y.; Armus, L.; Daz-Santos, T.; Surace, J.; Isaak, K. G.; Petric, A. O.; Charmandaris, V.; Evans, A. S.; Inami, H.; Iwasawa, K.; Leech, J.; Sanders, D. B.; and others

    2014-06-01

    We present our initial results on the CO rotational spectral line energy distribution (SLED) of the J to J1 transitions from J = 4 up to 13 from Herschel SPIRE spectroscopic observations of 65 luminous infrared galaxies (LIRGs) in the Great Observatories All-Sky LIRG Survey. The observed SLEDs change on average from one peaking at J ? 4 to a broad distribution peaking around J ? 6 to 7 as the IRAS 60-to-100?m color, C(60/100), increases. However, the ratios of a CO line luminosity to the total infrared luminosity, L {sub IR}, show the smallest variation for J around 6 or 7. This suggests that, for most LIRGs, ongoing star formation (SF) is also responsible for a warm gas component that emits CO lines primarily in the mid-J regime (5 ? J ? 10). As a result, the logarithmic ratios of the CO line luminosity summed over CO(54), (65), (76), (87) and (109) transitions to L {sub IR}, log R {sub midCO}, remain largely independent of C(60/100), and show a mean value of 4.13 (?log?R{sub midCO}{sup SF}) and a sample standard deviation of only 0.10 for the SF-dominated galaxies. Including additional galaxies from the literature, we show, albeit with a small number of cases, the possibility that galaxies, which bear powerful interstellar shocks unrelated to the current SF, and galaxies, in which an energetic active galactic nucleus contributes significantly to the bolometric luminosity, have their R {sub midCO} higher and lower than R{sub midCO}{sup SF}, respectively.

  20. A REDSHIFT SURVEY OF HERSCHEL FAR-INFRARED SELECTED STARBURSTS AND IMPLICATIONS FOR OBSCURED STAR FORMATION

    SciTech Connect (OSTI)

    Casey, C. M.; Budynkiewicz, J.; Berta, S.; Lutz, D.; Magnelli, B.; Bethermin, M.; Le Floc'h, E.; Magdis, G.; Burgarella, D.; Chapin, E.; Chapman, S. C.; Clements, D. L.; Conley, A.; Conselice, C. J.; Cooray, A.; Farrah, D.; Hatziminaoglou, E.; Ivison, R. J.; and others

    2012-12-20

    We present Keck spectroscopic observations and redshifts for a sample of 767 Herschel-SPIRE selected galaxies (HSGs) at 250, 350, and 500 {mu}m, taken with the Keck I Low Resolution Imaging Spectrometer and the Keck II DEep Imaging Multi-Object Spectrograph. The redshift distribution of these SPIRE sources from the Herschel Multitiered Extragalactic Survey peaks at z = 0.85, with 731 sources at z < 2 and a tail of sources out to z {approx} 5. We measure more significant disagreement between photometric and spectroscopic redshifts (({Delta}z/(1 + z{sub spec})) = 0.29) than is seen in non-infrared selected samples, likely due to enhanced star formation rates and dust obscuration in infrared-selected galaxies. The infrared data are used to directly measure integrated infrared luminosities and dust temperatures independent of radio or 24 {mu}m flux densities. By probing the dust spectral energy distribution (SED) at its peak, we estimate that the vast majority (72%-83%) of z < 2 Herschel-selected galaxies would drop out of traditional submillimeter surveys at 0.85-1 mm. We find that dust temperature traces infrared luminosity, due in part to the SPIRE wavelength selection biases, and partially from physical effects. As a result, we measure no significant trend in SPIRE color with redshift; if dust temperature were independent of luminosity or redshift, a trend in SPIRE color would be expected. Composite infrared SEDs are constructed as a function of infrared luminosity, showing the increase in dust temperature with luminosity, and subtle change in near-infrared and mid-infrared spectral properties. Moderate evolution in the far-infrared (FIR)/radio correlation is measured for this partially radio-selected sample, with q{sub IR}{proportional_to}(1 + z){sup -0.30{+-}0.02} at z < 2. We estimate the luminosity function and implied star formation rate density contribution of HSGs at z < 1.6 and find overall agreement with work based on 24 {mu}m extrapolations of the LIRG

  1. Spectral utilization in thermophotovoltaic devices

    SciTech Connect (OSTI)

    Clevenger, M.B.; Murray, C.S.

    1997-12-31

    Multilayer assemblies of epitaxially-grown, III-V semiconductor materials are being investigated for use in thermophotovoltaic (TPV) energy conversion applications. It has been observed that thick, highly-doped semiconductor layers within cell architectures dominate the parasitic free-carrier absorption (FCA) of devices at wavelengths above the bandgap of the semiconductor material. In this work, the wavelength-dependent, free-carrier absorption of p- and n-type InGaAs layers grown epitaxially onto semi-insulating (SI) InP substrates has been measured and related to the total absorption of long-wavelength photons in thermophotovoltaic devices. The optical responses of the TPV cells are then used in the calculation of spectral utilization factors and device efficiencies.

  2. THE DISCOVERY OF Y DWARFS USING DATA FROM THE WIDE-FIELD INFRARED SURVEY EXPLORER (WISE)

    SciTech Connect (OSTI)

    Cushing, Michael C.; Mainzer, A.; Eisenhardt, Peter R.; Kirkpatrick, J. Davy; Gelino, Christopher R.; Griffith, Roger L.; Marsh, Kenneth A.; Beichman, Charles A.; Skrutskie, Michael F.; Burgasser, Adam J.; Prato, Lisa A.; Simcoe, Robert A.; Marley, Mark S.; Freedman, Richard S.; Saumon, D.; Wright, Edward L.

    2011-12-10

    We present the discovery of seven ultracool brown dwarfs identified with the Wide-field Infrared Survey Explorer (WISE). Near-infrared spectroscopy reveals deep absorption bands of H{sub 2}O and CH{sub 4} that indicate all seven of the brown dwarfs have spectral types later than UGPS J072227.51-054031.2, the latest-type T dwarf currently known. The spectrum of WISEP J182831.08+265037.8 is distinct in that the heights of the J- and H-band peaks are approximately equal in units of f{sub {lambda}}, so we identify it as the archetypal member of the Y spectral class. The spectra of at least two of the other brown dwarfs exhibit absorption on the blue wing of the H-band peak that we tentatively ascribe to NH{sub 3}. These spectral morphological changes provide a clear transition between the T dwarfs and the Y dwarfs. In order to produce a smooth near-infrared spectral sequence across the T/Y dwarf transition, we have reclassified UGPS 0722-05 as the T9 spectral standard and tentatively assign WISEP J173835.52+273258.9 as the Y0 spectral standard. In total, six of the seven new brown dwarfs are classified as Y dwarfs: four are classified as Y0, one is classified as Y0 (pec?), and WISEP J1828+2650 is classified as >Y0. We have also compared the spectra to the model atmospheres of Marley and Saumon and infer that the brown dwarfs have effective temperatures ranging from 300 K to 500 K, making them the coldest spectroscopically confirmed brown dwarfs known to date.

  3. Hybrid least squares multivariate spectral analysis methods

    DOE Patents [OSTI]

    Haaland, David M.

    2002-01-01

    A set of hybrid least squares multivariate spectral analysis methods in which spectral shapes of components or effects not present in the original calibration step are added in a following estimation or calibration step to improve the accuracy of the estimation of the amount of the original components in the sampled mixture. The "hybrid" method herein means a combination of an initial classical least squares analysis calibration step with subsequent analysis by an inverse multivariate analysis method. A "spectral shape" herein means normally the spectral shape of a non-calibrated chemical component in the sample mixture but can also mean the spectral shapes of other sources of spectral variation, including temperature drift, shifts between spectrometers, spectrometer drift, etc. The "shape" can be continuous, discontinuous, or even discrete points illustrative of the particular effect.

  4. Hybrid least squares multivariate spectral analysis methods

    DOE Patents [OSTI]

    Haaland, David M.

    2004-03-23

    A set of hybrid least squares multivariate spectral analysis methods in which spectral shapes of components or effects not present in the original calibration step are added in a following prediction or calibration step to improve the accuracy of the estimation of the amount of the original components in the sampled mixture. The hybrid method herein means a combination of an initial calibration step with subsequent analysis by an inverse multivariate analysis method. A spectral shape herein means normally the spectral shape of a non-calibrated chemical component in the sample mixture but can also mean the spectral shapes of other sources of spectral variation, including temperature drift, shifts between spectrometers, spectrometer drift, etc. The shape can be continuous, discontinuous, or even discrete points illustrative of the particular effect.

  5. MODELING THE INFRARED EMISSION IN CYGNUS A

    SciTech Connect (OSTI)

    Privon, G. C.; Baum, S. A.; Noel-Storr, J.; O'Dea, C. P.; Axon, D. J.; Robinson, A.; Gallimore, J.

    2012-03-01

    We present new Spitzer IRS spectroscopy of Cygnus A, one of the most luminous radio sources in the local universe. Data on the inner 20'' are combined with new reductions of MIPS and IRAC photometry as well as data from the literature to form a radio through mid-infrared spectral energy distribution (SED). This SED is then modeled as a combination of torus reprocessed active galactic nucleus (AGN) radiation, dust enshrouded starburst, and a synchrotron jet. This combination of physically motivated components successfully reproduces the observed emission over almost 5 dex in frequency. The bolometric AGN luminosity is found to be 10{sup 12} L{sub Sun} (90% of L{sub IR}), with a clumpy AGN-heated dust medium extending to {approx}130 pc from the supermassive black hole. Evidence is seen for a break or cutoff in the core synchrotron emission. The associated population of relativistic electrons could in principle be responsible for some of the observed X-ray emission though the synchrotron self-Compton mechanism. The SED requires a cool dust component, consistent with dust-reprocessed radiation from ongoing star formation. Star formation contributes at least 6 Multiplication-Sign 10{sup 10} L{sub Sun} to the bolometric output of Cygnus A, corresponding to a star formation rate of {approx}10 M{sub Sun} yr{sup -1}.

  6. Design of the First Infrared Beamline at the Siam Photon Laboratory

    SciTech Connect (OSTI)

    Pattanasiriwisawa, W.; Songsiriritthigul, P.; Dumas, P.

    2010-06-23

    This report presents the optical design and optical simulations for the first infrared beamline at the Siam Photon Laboratory. The beamline collects the edge radiation and bending magnet radiation, producing from the BM4 bending magnet of the 1.2 GeV storage ring of the Siam Photon Source. The optical design is optimized for the far- to mid-infrared spectral range (4000-100 cm{sup -1}) for microspectroscopic applications. The optical performance has been examined by computer simulations.

  7. ARM - Measurement - Longwave spectral brightness temperature

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    spectral brightness temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave spectral brightness temperature A descriptive measure of radiation in terms of the temperature of a hypothetical black body emitting an identical amount of radiation at the same spectrally resolved wavelengths. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the

  8. Spectrally Enhanced Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Information Resources » Tools » Spectrally Enhanced Lighting Spectrally Enhanced Lighting Spectrally enhanced lighting (SEL) is a cost-effective, low-risk design method for achieving significant energy savings. It entails shifting the color of lamps from the warmer to the cooler (whiter) end of the color spectrum, more closely matching daylight. Studies show that, with this color shift, occupants perceive lighting to be brighter and they are able to see more clearly. Since SEL provides the

  9. Synthesis, spectral characterization, and single crystal structure...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Synthesis, spectral ... Resource Type: Journal Article Resource Relation: Journal Name: Crystallography Reports; Journal Volume: ...

  10. Development of spectral interferometry for shock characterization...

    Office of Scientific and Technical Information (OSTI)

    interferometry for shock characterization in energetic materials. Citation Details In-Document Search Title: Development of spectral interferometry for shock characterization in ...

  11. Spectral Solar Radiation Data Base at NREL

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    *In September 1991 the Solar Energy Research Institute became the National Renewable Energy Laboratory. [Description taken from http://rredc.nrel.gov/solar/old_data/spectral/

  12. A two-parameter model for the infrared/submillimeter/radio spectral...

    Office of Scientific and Technical Information (OSTI)

    Pasadena, CA 91125 (United States) Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom) Spitzer Science Center, California Institute of ...

  13. A Statistics-Based Method For The Short-Wave Infrared Spectral...

    Open Energy Information (Open El) [EERE & EIA]

    that deduces assemblages of SWIR active minerals. The effectiveness of this methodology is illustrated with a study of the Acoculco Caldera, which is a geothermal...

  14. Lattice Simulations and Infrared Conformality

    DOE PAGES-Beta [OSTI]

    Appelquist, Thomas; Fleming, George T.; Lin, Meifeng; Neil, Ethan T.; Schaich, David A

    2011-09-01

    We examine several recent lattice-simulation data sets, asking whether they are consistent with infrared conformality. We observe, in particular, that for an SU(3) gauge theory with 12 Dirac fermions in the fundamental representation, recent simulation data can be described assuming infrared conformality. Lattice simulations include a fermion mass m which is then extrapolated to zero, and we note that this data can be fit by a small-m expansion, allowing a controlled extrapolation. We also note that the conformal hypothesis does not work well for two theories that are known or expected to be confining and chirally broken, and that itmore » does work well for another theory expected to be infrared conformal.« less

  15. Electrically tunable infrared metamaterial devices

    DOE Patents [OSTI]

    Brener, Igal; Jun, Young Chul

    2015-07-21

    A wavelength-tunable, depletion-type infrared metamaterial optical device is provided. The device includes a thin, highly doped epilayer whose electrical permittivity can become negative at some infrared wavelengths. This highly-doped buried layer optically couples with a metamaterial layer. Changes in the transmission spectrum of the device can be induced via the electrical control of this optical coupling. An embodiment includes a contact layer of semiconductor material that is sufficiently doped for operation as a contact layer and that is effectively transparent to an operating range of infrared wavelengths, a thin, highly doped buried layer of epitaxially grown semiconductor material that overlies the contact layer, and a metallized layer overlying the buried layer and patterned as a resonant metamaterial.

  16. Real time infrared aerosol analyzer

    DOE Patents [OSTI]

    Johnson, Stanley A.; Reedy, Gerald T.; Kumar, Romesh

    1990-01-01

    Apparatus for analyzing aerosols in essentially real time includes a virtual impactor which separates coarse particles from fine and ultrafine particles in an aerosol sample. The coarse and ultrafine particles are captured in PTFE filters, and the fine particles impact onto an internal light reflection element. The composition and quantity of the particles on the PTFE filter and on the internal reflection element are measured by alternately passing infrared light through the filter and the internal light reflection element, and analyzing the light through infrared spectrophotometry to identify the particles in the sample.

  17. Method of photon spectral analysis

    DOE Patents [OSTI]

    Gehrke, R.J.; Putnam, M.H.; Killian, E.W.; Helmer, R.G.; Kynaston, R.L.; Goodwin, S.G.; Johnson, L.O.

    1993-04-27

    A spectroscopic method to rapidly measure the presence of plutonium in soils, filters, smears, and glass waste forms by measuring the uranium L-shell x-ray emissions associated with the decay of plutonium. In addition, the technique can simultaneously acquire spectra of samples and automatically analyze them for the amount of americium and [gamma]-ray emitting activation and fission products present. The samples are counted with a large area, thin-window, n-type germanium spectrometer which is equally efficient for the detection of low-energy x-rays (10-2,000 keV), as well as high-energy [gamma] rays (>1 MeV). A 8,192- or 16,384 channel analyzer is used to acquire the entire photon spectrum at one time. A dual-energy, time-tagged pulser, that is injected into the test input of the preamplifier to monitor the energy scale, and detector resolution. The L x-ray portion of each spectrum is analyzed by a linear-least-squares spectral fitting technique. The [gamma]-ray portion of each spectrum is analyzed by a standard Ge [gamma]-ray analysis program. This method can be applied to any analysis involving x- and [gamma]-ray analysis in one spectrum and is especially useful when interferences in the x-ray region can be identified from the [gamma]-ray analysis and accommodated during the x-ray analysis.

  18. Method of photon spectral analysis

    DOE Patents [OSTI]

    Gehrke, Robert J.; Putnam, Marie H.; Killian, E. Wayne; Helmer, Richard G.; Kynaston, Ronnie L.; Goodwin, Scott G.; Johnson, Larry O.

    1993-01-01

    A spectroscopic method to rapidly measure the presence of plutonium in soils, filters, smears, and glass waste forms by measuring the uranium L-shell x-ray emissions associated with the decay of plutonium. In addition, the technique can simultaneously acquire spectra of samples and automatically analyze them for the amount of americium and .gamma.-ray emitting activation and fission products present. The samples are counted with a large area, thin-window, n-type germanium spectrometer which is equally efficient for the detection of low-energy x-rays (10-2000 keV), as well as high-energy .gamma. rays (>1 MeV). A 8192- or 16,384 channel analyzer is used to acquire the entire photon spectrum at one time. A dual-energy, time-tagged pulser, that is injected into the test input of the preamplifier to monitor the energy scale, and detector resolution. The L x-ray portion of each spectrum is analyzed by a linear-least-squares spectral fitting technique. The .gamma.-ray portion of each spectrum is analyzed by a standard Ge .gamma.-ray analysis program. This method can be applied to any analysis involving x- and .gamma.-ray analysis in one spectrum and is especially useful when interferences in the x-ray region can be identified from the .gamma.-ray analysis and accommodated during the x-ray analysis.

  19. HERSCHEL OBSERVATIONS OF FAR-INFRARED COOLING LINES IN INTERMEDIATE REDSHIFT (ULTRA)-LUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Rigopoulou, D.; Magdis, G. E.; Thatte, N.; Hopwood, R.; Clements, D.; Swinyard, B. M.; Pearson, C.; Farrah, D.; Huang, J.-S.; Alonso-Herrero, A.; Bock, J. J.; Cooray, A.; Griffin, M. J.; Oliver, S.; Smith, A.; Wang, L.; Riechers, D.; Scott, D.; Vaccari, M.; Valtchanov, I.

    2014-01-20

    We report the first results from a spectroscopic survey of the [C II] 158?m line from a sample of intermediate redshift (0.2 infrared galaxies, (U)LIRGs (L {sub IR} > 10{sup 11.5} L {sub ?}), using the Spectral and Photometric Imaging REceiver-Fourier Transform Spectrometer on board the Herschel Space Observatory. This is the first survey of [C II] emission, an important tracer of star formation, at a redshift range where the star formation rate density of the universe increases rapidly. We detect strong [C II] 158?m line emission from over 80% of the sample. We find that the [C II] line is luminous, in the range (0.8-4) 10{sup 3} of the far-infrared continuum luminosity of our sources, and appears to arise from photodissociation regions on the surface of molecular clouds. The L{sub [C} {sub II]}/L {sub IR} ratio in our intermediate redshift (U)LIRGs is on average ?10times larger than that of local ULIRGs. Furthermore, we find that the L{sub [C} {sub II]}/L {sub IR} and L{sub [CII]}/L{sub CO(1-0)} ratios in our sample are similar to those of local normal galaxies and high-z star-forming galaxies. ULIRGs at z ? 0.5 show many similarities to the properties of local normal and high-z star-forming galaxies. Our findings strongly suggest that rapid evolution in the properties of the star-forming regions of (U)LIRGs is likely to have occurred in the last 5 billion years.

  20. Infrared emitting device and method

    DOE Patents [OSTI]

    Kurtz, Steven R.; Biefeld, Robert M.; Dawson, L. Ralph; Howard, Arnold J.; Baucom, Kevin C.

    1997-01-01

    An infrared emitting device and method. The infrared emitting device comprises a III-V compound semiconductor substrate upon which are grown a quantum-well active region having a plurality of quantum-well layers formed of a ternary alloy comprising InAsSb sandwiched between barrier layers formed of a ternary alloy having a smaller lattice constant and a larger energy bandgap than the quantum-well layers. The quantum-well layers are preferably compressively strained to increase the threshold energy for Auger recombination; and a method is provided for determining the preferred thickness for the quantum-well layers. Embodiments of the present invention are described having at least one cladding layer to increase the optical and carrier confinement in the active region, and to provide for waveguiding of the light generated within the active region. Examples have been set forth showing embodiments of the present invention as surface- and edge-emitting light emitting diodes (LEDs), an optically-pumped semiconductor laser, and an electrically-injected semiconductor diode laser. The light emission from each of the infrared emitting devices of the present invention is in the midwave infrared region of the spectrum from about 2 to 6 microns.

  1. EVIDENCE FOR INFRARED-FAINT RADIO SOURCES AS z > 1 RADIO-LOUD ACTIVE GALACTIC NUCLEI

    SciTech Connect (OSTI)

    Huynh, Minh T.; Norris, Ray P.; Siana, Brian; Middelberg, Enno

    2010-02-10

    Infrared-Faint Radio Sources (IFRSs) are a class of radio objects found in the Australia Telescope Large Area Survey which have no observable mid-infrared counterpart in the Spitzer Wide-area Infrared Extragalactic (SWIRE) survey. The extended Chandra Deep Field South now has even deeper Spitzer imaging (3.6-70 {mu}m) from a number of Legacy surveys. We report the detections of two IFRS sources in IRAC images. The non-detection of two other IFRSs allows us to constrain the source type. Detailed modeling of the spectral energy distribution of these objects shows that they are consistent with high-redshift (z {approx}> 1) active galactic nuclei.

  2. Apparatus and system for multivariate spectral analysis

    DOE Patents [OSTI]

    Keenan, Michael R.; Kotula, Paul G.

    2003-06-24

    An apparatus and system for determining the properties of a sample from measured spectral data collected from the sample by performing a method of multivariate spectral analysis. The method can include: generating a two-dimensional matrix A containing measured spectral data; providing a weighted spectral data matrix D by performing a weighting operation on matrix A; factoring D into the product of two matrices, C and S.sup.T, by performing a constrained alternating least-squares analysis of D=CS.sup.T, where C is a concentration intensity matrix and S is a spectral shapes matrix; unweighting C and S by applying the inverse of the weighting used previously; and determining the properties of the sample by inspecting C and S. This method can be used by a spectrum analyzer to process X-ray spectral data generated by a spectral analysis system that can include a Scanning Electron Microscope (SEM) with an Energy Dispersive Detector and Pulse Height Analyzer.

  3. Augmented classical least squares multivariate spectral analysis

    DOE Patents [OSTI]

    Haaland, David M.; Melgaard, David K.

    2004-02-03

    A method of multivariate spectral analysis, termed augmented classical least squares (ACLS), provides an improved CLS calibration model when unmodeled sources of spectral variation are contained in a calibration sample set. The ACLS methods use information derived from component or spectral residuals during the CLS calibration to provide an improved calibration-augmented CLS model. The ACLS methods are based on CLS so that they retain the qualitative benefits of CLS, yet they have the flexibility of PLS and other hybrid techniques in that they can define a prediction model even with unmodeled sources of spectral variation that are not explicitly included in the calibration model. The unmodeled sources of spectral variation may be unknown constituents, constituents with unknown concentrations, nonlinear responses, non-uniform and correlated errors, or other sources of spectral variation that are present in the calibration sample spectra. Also, since the various ACLS methods are based on CLS, they can incorporate the new prediction-augmented CLS (PACLS) method of updating the prediction model for new sources of spectral variation contained in the prediction sample set without having to return to the calibration process. The ACLS methods can also be applied to alternating least squares models. The ACLS methods can be applied to all types of multivariate data.

  4. Augmented Classical Least Squares Multivariate Spectral Analysis

    DOE Patents [OSTI]

    Haaland, David M.; Melgaard, David K.

    2005-07-26

    A method of multivariate spectral analysis, termed augmented classical least squares (ACLS), provides an improved CLS calibration model when unmodeled sources of spectral variation are contained in a calibration sample set. The ACLS methods use information derived from component or spectral residuals during the CLS calibration to provide an improved calibration-augmented CLS model. The ACLS methods are based on CLS so that they retain the qualitative benefits of CLS, yet they have the flexibility of PLS and other hybrid techniques in that they can define a prediction model even with unmodeled sources of spectral variation that are not explicitly included in the calibration model. The unmodeled sources of spectral variation may be unknown constituents, constituents with unknown concentrations, nonlinear responses, non-uniform and correlated errors, or other sources of spectral variation that are present in the calibration sample spectra. Also, since the various ACLS methods are based on CLS, they can incorporate the new prediction-augmented CLS (PACLS) method of updating the prediction model for new sources of spectral variation contained in the prediction sample set without having to return to the calibration process. The ACLS methods can also be applied to alternating least squares models. The ACLS methods can be applied to all types of multivariate data.

  5. Augmented Classical Least Squares Multivariate Spectral Analysis

    DOE Patents [OSTI]

    Haaland, David M.; Melgaard, David K.

    2005-01-11

    A method of multivariate spectral analysis, termed augmented classical least squares (ACLS), provides an improved CLS calibration model when unmodeled sources of spectral variation are contained in a calibration sample set. The ACLS methods use information derived from component or spectral residuals during the CLS calibration to provide an improved calibration-augmented CLS model. The ACLS methods are based on CLS so that they retain the qualitative benefits of CLS, yet they have the flexibility of PLS and other hybrid techniques in that they can define a prediction model even with unmodeled sources of spectral variation that are not explicitly included in the calibration model. The unmodeled sources of spectral variation may be unknown constituents, constituents with unknown concentrations, nonlinear responses, non-uniform and correlated errors, or other sources of spectral variation that are present in the calibration sample spectra. Also, since the various ACLS methods are based on CLS, they can incorporate the new prediction-augmented CLS (PACLS) method of updating the prediction model for new sources of spectral variation contained in the prediction sample set without having to return to the calibration process. The ACLS methods can also be applied to alternating least squares models. The ACLS methods can be applied to all types of multivariate data.

  6. Solar and Infrared Radiation Station (SIRS) Handbook

    SciTech Connect (OSTI)

    Stoffel, T

    2005-07-01

    The Solar Infrared Radiation Station (SIRS) provides continuous measurements of broadband shortwave (solar) and longwave (atmospheric or infrared) irradiances for downwelling and upwelling components. The following six irradiance measurements are collected from a network of stations to help determine the total radiative flux exchange within the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) Climate Research Facility: Direct normal shortwave (solar beam) Diffuse horizontal shortwave (sky) Global horizontal shortwave (total hemispheric) Upwelling shortwave (reflected) Downwelling longwave (atmospheric infrared) Upwelling longwave (surface infrared)

  7. Tunable Surface Plasmon Infrared Modulator - Energy Innovation...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    and Industries Infrared Modulator IR Counter Measures Photonic Circuitry Metamaterials Chemical Sensing Variable Attenuation Patents and Patent Applications ID Number...

  8. Infrared spectroscopic investigation of nuclear spin conversion...

    Office of Scientific and Technical Information (OSTI)

    relaxation processes mediated by phonons to the temperature dependence of these ... INFRARED SPECTRA; METHANE; MOLECULES; PHONONS; RELAXATION; SOLIDS; SPIN; TEMPERATURE ...

  9. Sample rotating turntable kit for infrared spectrometers

    DOE Patents [OSTI]

    Eckels, Joel Del (Livermore, CA); Klunder, Gregory L. (Oakland, CA)

    2008-03-04

    An infrared spectrometer sample rotating turntable kit has a rotatable sample cup containing the sample. The infrared spectrometer has an infrared spectrometer probe for analyzing the sample and the rotatable sample cup is adapted to receive the infrared spectrometer probe. A reflectance standard is located in the rotatable sample cup. A sleeve is positioned proximate the sample cup and adapted to receive the probe. A rotator rotates the rotatable sample cup. A battery is connected to the rotator.

  10. Far-infrared surface emissivity and climate

    SciTech Connect (OSTI)

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

  11. Far-infrared surface emissivity and climate

    DOE PAGES-Beta [OSTI]

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

  12. ARM - Measurement - Shortwave spectral diffuse downwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    diffuse downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral diffuse downwelling irradiance The rate at which spectrally resolved radiant energy at wavelengths shorter than approximately 4 {mu}m, that has been scattered in the atmosphere at least once, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above

  13. ARM - Measurement - Shortwave spectral direct normal irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    direct normal irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral direct normal irradiance The narrow spectral range of measurements coming directly from the sun whose wavelength falls within the solar range of 0.4 and 4 {mu}m. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream

  14. Multi-channel infrared thermometer

    DOE Patents [OSTI]

    Ulrickson, Michael A.

    1986-01-01

    A device for measuring the two-dimensional temperature profile of a surface comprises imaging optics for generating an image of the light radiating from the surface; an infrared detector array having a plurality of detectors; and a light pipe array positioned between the imaging optics and the detector array for sampling, transmitting, and distributing the image over the detector surfaces. The light pipe array includes one light pipe for each detector in the detector array.

  15. Multi-channel infrared thermometer

    DOE Patents [OSTI]

    Ulrickson, M.A.

    A device for measuring the two-dimensional temperature profile of a surface comprises imaging optics for generating an image of the light radiating from the surface; an infrared detector array having a plurality of detectors; and optical means positioned between the imaging optics and the detector array for sampling, transmitting, and distributing the image over the detector surfaces. The optical means may be a light pipe array having one light pipe for each detector in the detector array.

  16. Ferroelectric infrared detector and method

    DOE Patents [OSTI]

    Lashley, Jason Charles; Opeil, Cyril P.; Smith, James Lawrence

    2010-03-30

    An apparatus and method are provided for sensing infrared radiation. The apparatus includes a sensor element that is positioned in a magnetic field during operation to ensure a .lamda. shaped relationship between specific heat and temperature adjacent the Curie temperature of the ferroelectric material comprising the sensor element. The apparatus is operated by inducing a magnetic field on the ferroelectric material to reduce surface charge on the element during its operation.

  17. Spectral light separator based on deep-subwavelength resonant apertures in a metallic film

    SciTech Connect (OSTI)

    Bykalp, Yasin; Catrysse, Peter B. Shin, Wonseok; Fan, Shanhui

    2014-07-07

    We propose to funnel, select, and collect light spectrally by exploiting the unique properties of deep-subwavelength resonant apertures in a metallic film. In our approach, each aperture has an electromagnetic cross section that is much larger than its physical size while the frequency of the collected light is controlled by its height through the Fabry-Prot resonance mechanism. The electromagnetic crosstalk between apertures remains low despite physical separations in the deep-subwavelength range. The resulting device enables an extremely efficient, subwavelength way to decompose light into its spectral components without the loss of photons and spatial coregistration errors. As a specific example, we show a subwavelength-size structure with three deep-subwavelength slits in a metallic film designed to operate in the mid-wave infrared range between 3 and 5.5??m.

  18. Infrared emitting device and method

    DOE Patents [OSTI]

    Kurtz, S.R.; Biefeld, R.M.; Dawson, L.R.; Howard, A.J.; Baucom, K.C.

    1997-04-29

    The infrared emitting device comprises a III-V compound semiconductor substrate upon which are grown a quantum-well active region having a plurality of quantum-well layers formed of a ternary alloy comprising InAsSb sandwiched between barrier layers formed of a ternary alloy having a smaller lattice constant and a larger energy bandgap than the quantum-well layers. The quantum-well layers are preferably compressively strained to increase the threshold energy for Auger recombination; and a method is provided for determining the preferred thickness for the quantum-well layers. Embodiments of the present invention are described having at least one cladding layer to increase the optical and carrier confinement in the active region, and to provide for waveguiding of the light generated within the active region. Examples have been set forth showing embodiments of the present invention as surface- and edge-emitting light emitting diodes (LEDs), an optically-pumped semiconductor laser, and an electrically-injected semiconductor diode laser. The light emission from each of the infrared emitting devices of the present invention is in the midwave infrared region of the spectrum from about 2 to 6 microns. 8 figs.

  19. Methods and apparatus for mid-infrared sensing

    DOE Patents [OSTI]

    Lin, Pao Tai; Cai, Yan; Agarwal, Anuradha Murthy; Kimerling, Lionel C.

    2015-06-02

    A chip-scale, air-clad semiconductor pedestal waveguide can be used as a mid-infrared (mid-IR) sensor capable of in situ monitoring of organic solvents and other analytes. The sensor uses evanescent coupling from a silicon or germanium waveguide, which is highly transparent in the mid-IR portion of the electromagnetic spectrum, to probe the absorption spectrum of fluid surrounding the waveguide. Launching a mid-IR beam into the waveguide exposed to a particular analyte causes attenuation of the evanescent wave's spectral components due to absorption by carbon, oxygen, hydrogen, and/or nitrogen bonds in the surrounding fluid. Detecting these changes at the waveguide's output provides an indication of the type and concentration of one or more compounds in the surrounding fluid. If desired, the sensor may be integrated onto a silicon substrate with a mid-IR light source and a mid-IR detector to form a chip-based spectrometer.

  20. Three-dimensional infrared metamaterial with asymmetric transmission

    DOE PAGES-Beta [OSTI]

    Kenanakis, George; Xomalis, Aggelos; Selimis, Alexandros; Vamvakaki, Maria; Farsari, Maria; Kafesaki, Maria; Soukoulis, Costas M.; Economou, Eleftherios N.

    2015-01-14

    A novel three-dimensional (3D) metallic metamaterial structure with asymmetric transmission for linear polarization is demonstrated in the infrared spectral region. The structure was fabricated by direct laser writing and selective electroless silver coating, a straightforward, novel technique producing mechanically and chemically stable 3D photonic structures. The structure unit cell is composed of a pair of conductively coupled magnetic resonators, and the asymmetric transmission response results from interplay of electric and magnetic responses; this equips the structure with almost total opaqueness along one propagation direction versus satisfying transparency along the opposite one. It also offers easily adjustable impedance, 90° one-way puremore » optical activity and backward propagation possibility, resulting thus in unique capabilities in polarization control and isolation applications. We show also that scaling down the structure can make it capable of exhibiting its asymmetric transmission and its polarization capabilities in the optical region.« less

  1. Three-dimensional infrared metamaterial with asymmetric transmission

    SciTech Connect (OSTI)

    Kenanakis, George; Xomalis, Aggelos; Selimis, Alexandros; Vamvakaki, Maria; Farsari, Maria; Kafesaki, Maria; Soukoulis, Costas M.; Economou, Eleftherios N.

    2015-01-14

    A novel three-dimensional (3D) metallic metamaterial structure with asymmetric transmission for linear polarization is demonstrated in the infrared spectral region. The structure was fabricated by direct laser writing and selective electroless silver coating, a straightforward, novel technique producing mechanically and chemically stable 3D photonic structures. The structure unit cell is composed of a pair of conductively coupled magnetic resonators, and the asymmetric transmission response results from interplay of electric and magnetic responses; this equips the structure with almost total opaqueness along one propagation direction versus satisfying transparency along the opposite one. It also offers easily adjustable impedance, 90° one-way pure optical activity and backward propagation possibility, resulting thus in unique capabilities in polarization control and isolation applications. We show also that scaling down the structure can make it capable of exhibiting its asymmetric transmission and its polarization capabilities in the optical region.

  2. Spectral characteristics of time resolved magnonic spin Seebeck...

    Office of Scientific and Technical Information (OSTI)

    Spectral characteristics of time resolved magnonic spin Seebeck effect Citation Details In-Document Search Title: Spectral characteristics of time resolved magnonic spin Seebeck ...

  3. Webinar-Terrestrial Solar Spectral Modeling for Renewable Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Webinar-Terrestrial Solar Spectral Modeling for Renewable Energy: SMARTS Model Jump to: navigation, search Tool Summary Name: Webinar-Terrestrial Solar Spectral Modeling for...

  4. ARM: Ka ARM Zenith Radar (KAZR): filtered spectral data, moderate...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: Ka ARM Zenith Radar (KAZR): filtered spectral data, moderate sensitivity mode, cross-polarized mode Ka ARM Zenith Radar (KAZR): filtered spectral data, moderate ...

  5. IR Spectral Bands and Performance | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    2013 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for IR Spectral Bands and Performance Citation Chris Douglass. IR Spectral Bands...

  6. Solar spectral optical properties of pigments--Part II: survey...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Solar spectral optical properties of ... K (absorption) as functions ofwavelength in the solar spectral range of 300 to 2500 nm. ...

  7. A spectral filtering procedure for Eddy-resolving simulations with a spectral element ocean model

    SciTech Connect (OSTI)

    Levin, J.G.; Iskandarani, M.; Haidvogel, D.B.

    1997-10-01

    This report introduces a new filtering method designed to control the growth of nonlinear instabilities in the spectral element solution of nonlinear turbulent oceanic flow model.

  8. Solar spectral irradiance changes during cycle 24

    SciTech Connect (OSTI)

    Marchenko, S. V.; DeLand, M. T.

    2014-07-10

    We use solar spectra obtained by the Ozone Monitoring Instrument (OMI) on board the Aura satellite to detect and follow long-term (years) and short-term (weeks) changes in the solar spectral irradiance (SSI) in the 265-500 nm spectral range. During solar Cycle 24, in the relatively line-free regions the SSI changed by ∼0.6% ± 0.2% around 265 nm. These changes gradually diminish to 0.15% ± 0.20% at 500 nm. All strong spectral lines and blends, with the notable exception of the upper Balmer lines, vary in unison with the solar 'continuum'. Besides the lines with strong chromospheric components, the most involved species include Fe I blends and all prominent CH, NH, and CN spectral bands. Following the general trend seen in the solar 'continuum', the variability of spectral lines also decreases toward longer wavelengths. The long-term solar cycle SSI changes are closely, to within the quoted 0.1%-0.2% uncertainties, matched by the appropriately adjusted short-term SSI variations derived from the 27 day rotational modulation cycles. This further strengthens and broadens the prevailing notion about the general scalability of the UV SSI variability to the emissivity changes in the Mg II 280 nm doublet on timescales from weeks to years. We also detect subtle deviations from this general rule: the prominent spectral lines and blends at λ ≳ 350 nm show slightly more pronounced 27 day SSI changes when compared to the long-term (years) trends. We merge the solar data from Cycle 21 with the current Cycle 24 OMI and GOME-2 observations and provide normalized SSI variations for the 170-795 nm spectral region.

  9. Spectral Energy Distributions for Disk and Halo M Dwarfs

    SciTech Connect (OSTI)

    Leggett, S. K.; Allard, F.; Dahn, Conard; Hauschildt, P. H.; Kerr, T. H.; Rayner, J.

    2000-06-01

    We have obtained infrared (1-2.5 {mu}m) spectroscopy for 42 halo and disk dwarfs with spectral types M1-M6.5. These data are compared to synthetic spectra generated by the latest model atmospheres of Allard and Hauschildt. Photospheric parameters metallicity, effective temperature, and radius are determined for the sample.We find good agreement between observation and theory except for known problems due to incomplete molecular data for metal hydrides and H2O. The metal-poor M subdwarfs are well matched by the models, as oxide opacity sources are less important in this case. The derived effective temperatures for the sample range from 3600 to 2600 K; at these temperatures grain formation and extinction are not significant in the photosphere. The derived metallicities range from solar to 1/10 solar. The radii and effective temperatures derived agree well with recent models of low-mass stars. The spectra are available in electronic form upon request. (c) 2000 The American Astronomical Society.

  10. Information-efficient spectral imaging sensor

    DOE Patents [OSTI]

    Sweatt, William C.; Gentry, Stephen M.; Boye, Clinton A.; Grotbeck, Carter L.; Stallard, Brian R.; Descour, Michael R.

    2003-01-01

    A programmable optical filter for use in multispectral and hyperspectral imaging. The filter splits the light collected by an optical telescope into two channels for each of the pixels in a row in a scanned image, one channel to handle the positive elements of a spectral basis filter and one for the negative elements of the spectral basis filter. Each channel for each pixel disperses its light into n spectral bins, with the light in each bin being attenuated in accordance with the value of the associated positive or negative element of the spectral basis vector. The spectral basis vector is constructed so that its positive elements emphasize the presence of a target and its negative elements emphasize the presence of the constituents of the background of the imaged scene. The attenuated light in the channels is re-imaged onto separate detectors for each pixel and then the signals from the detectors are combined to give an indication of the presence or not of the target in each pixel of the scanned scene. This system provides for a very efficient optical determination of the presence of the target, as opposed to the very data intensive data manipulations that are required in conventional hyperspectral imaging systems.

  11. Infrared Debonding - Energy Innovation Portal

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Infrared Debonding Y-12 National Security Complex Contact Y12 About This Technology Publications: PDF Document Publication Fact Sheet (302 KB) PDF Document Publication Presentation (370 KB) PDF Document Publication Patent (48 KB) <p align="left">&nbsp;</p> <p><em><span style="font-size: x-small;">Y-12 worker elevates object for positioning inside the IR

  12. Passive infrared bullet detection and tracking

    DOE Patents [OSTI]

    Karr, T.J.

    1997-01-21

    An apparatus and method for passively detecting a projectile such as, for example, a bullet using a passive infrared detector. A passive infrared detector is focused onto a region in which a projectile is expected to be located. Successive images of infrared radiation in the region are recorded. Background infrared radiation present in the region is suppressed such that second successive images of infrared radiation generated by the projectile as the projectile passes through the region are produced. A projectile path calculator determines the path and other aspects of the projectile by using the second successive images of infrared radiation generated by the projectile. The present invention, in certain embodiments, also determines the origin of the path of the projectile and takes a photograph of the area surrounding the origin and/or fires at least one projectile at the area surrounding the origin of the path of the projectile. 9 figs.

  13. Passive infrared bullet detection and tracking

    DOE Patents [OSTI]

    Karr, Thomas J.

    1997-01-01

    An apparatus and method for passively detecting a projectile such as, for example, a bullet using a passive infrared detector. A passive infrared detector is focused onto a region in which a projectile is expected to be located. Successive images of infrared radiation in the region are recorded. Background infrared radiation present in the region is suppressed such that second successive images of infrared radiation generated by the projectile as the projectile passes through the region are produced. A projectile path calculator determines the path and other aspects of the projectile by using the second successive images of infrared radiation generated by the projectile. The present invention, in certain embodiments, also determines the origin of the path of the projectile and takes a photograph of the area surrounding the origin and/or fires at least one projectile at the area surrounding the origin of the path of the projectile.

  14. A spectral mimetic least-squares method

    DOE PAGES-Beta [OSTI]

    Bochev, Pavel; Gerritsma, Marc

    2014-09-01

    We present a spectral mimetic least-squares method for a model diffusion–reaction problem, which preserves key conservation properties of the continuum problem. Casting the model problem into a first-order system for two scalar and two vector variables shifts material properties from the differential equations to a pair of constitutive relations. We also use this system to motivate a new least-squares functional involving all four fields and show that its minimizer satisfies the differential equations exactly. Discretization of the four-field least-squares functional by spectral spaces compatible with the differential operators leads to a least-squares method in which the differential equations are alsomore » satisfied exactly. Additionally, the latter are reduced to purely topological relationships for the degrees of freedom that can be satisfied without reference to basis functions. Furthermore, numerical experiments confirm the spectral accuracy of the method and its local conservation.« less

  15. Classical least squares multivariate spectral analysis

    DOE Patents [OSTI]

    Haaland, David M.

    2002-01-01

    An improved classical least squares multivariate spectral analysis method that adds spectral shapes describing non-calibrated components and system effects (other than baseline corrections) present in the analyzed mixture to the prediction phase of the method. These improvements decrease or eliminate many of the restrictions to the CLS-type methods and greatly extend their capabilities, accuracy, and precision. One new application of PACLS includes the ability to accurately predict unknown sample concentrations when new unmodeled spectral components are present in the unknown samples. Other applications of PACLS include the incorporation of spectrometer drift into the quantitative multivariate model and the maintenance of a calibration on a drifting spectrometer. Finally, the ability of PACLS to transfer a multivariate model between spectrometers is demonstrated.

  16. Evolution of the spectral index after inflation

    SciTech Connect (OSTI)

    Asgari, A.A.; Abbassi, A.H. E-mail: ahabbasi@modares.ac.ir

    2014-09-01

    In this article we investigate the time evolution of the adiabatic (curvature) and isocurvature (entropy) spectral indices after inflation era for all cosmological scales with two different initial conditions. For this purpose, we first extract an explicit equation for the time evolution of the comoving curvature perturbation (which may be known as the generalized Mukhanov-Sasaki equation). It would be cleared that the evolution of adiabatic spectral index severely depends on the initial conditions moreover, as expected it is constant only for the super-Hubble scales and adiabatic initial conditions. Additionally, the adiabatic spectral index after recombination approaches a constant value for the isocurvature perturbations. Finally, we re-investigate the Sachs-Wolfe effect and show that the fudge factor  1/3 in the adiabatic ordinary Sachs-Wolfe formula must be replaced by 0.4.

  17. A spectral mimetic least-squares method

    SciTech Connect (OSTI)

    Bochev, Pavel; Gerritsma, Marc

    2014-09-01

    We present a spectral mimetic least-squares method for a model diffusionreaction problem, which preserves key conservation properties of the continuum problem. Casting the model problem into a first-order system for two scalar and two vector variables shifts material properties from the differential equations to a pair of constitutive relations. We also use this system to motivate a new least-squares functional involving all four fields and show that its minimizer satisfies the differential equations exactly. Discretization of the four-field least-squares functional by spectral spaces compatible with the differential operators leads to a least-squares method in which the differential equations are also satisfied exactly. Additionally, the latter are reduced to purely topological relationships for the degrees of freedom that can be satisfied without reference to basis functions. Furthermore, numerical experiments confirm the spectral accuracy of the method and its local conservation.

  18. Infrared systems, SPIE proceedings. Vol. 256

    SciTech Connect (OSTI)

    Sanmann, E.E.

    1980-01-01

    The seminar focused on infrared systems sensor specifications, applications of infrared thermography in the analysis of induced surface currents due to incident electromagnetic radiation on complex shapes, advanced optical ceramics for sensor windows, digital processing in calibrated infrared imagery, and calibration. Papers were presented on nearby object radiometry, homing overlay experiment radiometric error terminology, design of radiometric calibration sources and spectroradiometers, and the Lockheed sensor test facility.

  19. Infra-red signature neutron detector

    DOE Patents [OSTI]

    Bell, Zane William [Oak Ridge, TN; Boatner, Lynn Allen [Oak Ridge, TN

    2009-10-13

    A method of detecting an activator, the method including impinging with an activator a receptor material that includes a photoluminescent material that generates infrared radiation and generation a by-product of a nuclear reaction due to the activator impinging the receptor material. The method further includes generating light from the by-product via the Cherenkov effect, wherein the light activates the photoluminescent material so as to generate the infrared radiation. Identifying a characteristic of the activator based on the infrared radiation.

  20. Sensitive Multi-Species Emissions Monitoring: Infrared Laser-Based Detection of Trace-Level Contaminants.

    SciTech Connect (OSTI)

    Steill, Jeffrey D

    2015-01-01

    This report summarizes our development of spectroscopic chemical analysis techniques and spectral modeling for trace-gas measurements of highly-regulated low-concentration species present in flue gas emissions from utility coal boilers such as HCl under conditions of high humidity. Detailed spectral modeling of the spectroscopy of HCl and other important combustion and atmospheric species such as H 2 O, CO 2 , N 2 O, NO 2 , SO 2 , and CH 4 demonstrates that IR-laser spectroscopy is a sensitive multi-component analysis strategy. Experimental measurements from techniques based on IR laser spectroscopy are presented that demonstrate sub-ppm sensitivity levels to these species. Photoacoustic infrared spectroscopy is used to detect and quantify HCl at ppm levels with extremely high signal-to-noise even under conditions of high relative humidity. Additionally, cavity ring-down IR spectroscopy is used to achieve an extremely high sensitivity to combustion trace gases in this spectral region; ppm level CH 4 is one demonstrated example. The importance of spectral resolution in the sensitivity of a trace-gas measurement is examined by spectral modeling in the mid- and near-IR, and efforts to improve measurement resolution through novel instrument development are described. While previous project reports focused on benefits and complexities of the dual-etalon cavity ring-down infrared spectrometer, here details on steps taken to implement this unique and potentially revolutionary instrument are described. This report also illustrates and critiques the general strategy of IR- laser photodetection of trace gases leading to the conclusion that mid-IR laser spectroscopy techniques provide a promising basis for further instrument development and implementation that will enable cost-effective sensitive detection of multiple key contaminant species simultaneously.

  1. Near-infrared (JHK) spectroscopy of young stellar and substellar objects in orion

    SciTech Connect (OSTI)

    Ingraham, P.; Albert, L.; Doyon, R.; Artigau, E.

    2014-02-10

    We performed low-resolution (R ∼ 40) near-infrared (0.9-2.4 μm) multi-object spectroscopy of 240 isolated point sources having apparent H-band magnitudes between 9 and 18 in the central 5' × 6' of the Orion Trapezium cluster. The observations were performed over four nights at the Canada-France-Hawaii Telescope using the visiting instrument SIMON, an infrared imager and multi-object spectrograph. We present the spectra of 104 objects with accurately derived spectral types including 7 new objects having masses below the hydrogen-burning limit, and 6 objects with masses below the deuterium-burning limit. The spectral classification is performed by fitting previously classified spectral templates of dwarf stars (K4-M3) and optically classified young stellar and substellar objects (M4-L0), to the entire 0.9-2.4 μm spectral energy distribution in order to assign a spectral type and visual extinction for each object. Of the 104 objects studied, 44 have been previously classified spectroscopically using various techniques. We perform a rigorous comparison between the previous classifications and our own and find them to be in good agreement. Using the dereddened H-band magnitudes, the classified objects are used to create an Hertzsprung-Russell diagram for the cluster. We find that the previous age estimates of ∼1 Myr to be consistent with our results. Consistent with previous studies, numerous objects are observed to have luminosities several magnitudes above the 1 Myr isochrone. Numerous objects exhibiting emission features in the J band are also reported.

  2. ARM - Field Campaign - Surface spectral albedo

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    govCampaignsSurface spectral albedo ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Surface spectral albedo 2002.08.14 - 2002.08.20 Lead Scientist : Alexander Trishchenko Data Availability Analysis of the data collected during IOP is not completed yet. Preliminary results will be presented during the IRF workshop on 8-10 October, 2002. Data will be available at the following URL (

  3. Logarithmic compression methods for spectral data

    DOE Patents [OSTI]

    Dunham, Mark E.

    2003-01-01

    A method is provided for logarithmic compression, transmission, and expansion of spectral data. A log Gabor transformation is made of incoming time series data to output spectral phase and logarithmic magnitude values. The output phase and logarithmic magnitude values are compressed by selecting only magnitude values above a selected threshold and corresponding phase values to transmit compressed phase and logarithmic magnitude values. A reverse log Gabor transformation is then performed on the transmitted phase and logarithmic magnitude values to output transmitted time series data to a user.

  4. Infrared trace element detection system

    DOE Patents [OSTI]

    Bien, F.; Bernstein, L.S.; Matthew, M.W.

    1988-11-15

    An infrared trace element detection system includes an optical cell into which the sample fluid to be examined is introduced and removed. Also introduced into the optical cell is a sample beam of infrared radiation in a first wavelength band which is significantly absorbed by the trace element and a second wavelength band which is not significantly absorbed by the trace element for passage through the optical cell through the sample fluid. The output intensities of the sample beam of radiation are selectively detected in the first and second wavelength bands. The intensities of a reference beam of the radiation are similarly detected in the first and second wavelength bands. The sensed output intensity of the sample beam in one of the first and second wavelength bands is normalized with respect to the other and similarly, the intensity of the reference beam of radiation in one of the first and second wavelength bands is normalized with respect to the other. The normalized sample beam intensity and normalized reference beam intensity are then compared to provide a signal from which the amount of trace element in the sample fluid can be determined. 11 figs.

  5. The COBE Diffuse Infrared Background Experiment search for thecosmic infrared background. I. Limits and detections

    SciTech Connect (OSTI)

    Hauser, M.G.; Arendt, R.G.; Kelsall, T.; Dwek, E.; Odegard, N.; Weiland, J.L.; Freudenreich, H.T.; Reach, W.T.; Silverberg, R.F.; Moseley, S.H.; Pei, Y.C.; Lubin, P.; Mather, J.C.; Shafer, R.A.; Smoot,G.F.; Weiss, R.; Wilkinson, D.T.; Wright, E.L.

    1998-01-06

    The Diffuse Infrared Background Experiment (DIRBE) on the Cosmic Background Explorer (COBE) spacecraft was designed primarily to conduct a systematic search for an isotropic cosmic infrared background (CIB) in 10 photometric bands from 1.25 to 240 mu m. The results of that search are presented here. Conservative limits on the CIB are obtained from the minimum observed brightness in all-sky maps at each wavelength, with the faintest limits in the DIRBE spectral range being at 3.5 mu m(nu l nu<64 nW m-2 sr-1, 95 percent confidence level) and at 240 mu m (nu l nu < 28 nW m-1 sr-1, 95 percent confidence level). The bright foregrounds from interplanetary dust scattering and emission, stars, and interstellar dust emission are the principal impediments to the DIRBE measurements of the CIB. These foregrounds have been modeled and removed from the sky maps. Assessment of the random and systematic uncertainties in the residuals and tests for isotropy show that only the 140 and 240 mum data provide candidate detections of the CIB. The residuals and their uncertainties provide CIB upper limits more restrictive than the dark sky limits at wavelengths from 1.25 to 100 mu m. No plausible solar system or Galactic source of the observed 140 and 240 mu m residuals can be identified, leading to the conclusion that the CIB has been detected at levels of nu l nu = 25 +- 7 and 14 +- 3 nW m-2 sr-1 at 140 and 240 mu m, respectively. The integrated energy from 140 to 240 mu m, 10.3 nW m-2sr-1, is about twice the integrated optical light from the galaxies in the Hubble Deep Field, suggesting that star formation might have been heavily enshrouded by dust at high redshift. The detections and upper limits reported here provide new constraints on models of the history of energy-releasing processes and dust production since the decoupling of the cosmic microwave background from matter.

  6. Dynamically Responsive Infrared Window Coatings | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Dynamically Responsive Infrared Window Coatings Addthis 1 of 5 An oxygen plasma etcher is ... Kyle Alvine checks on the progress of the plasma etch. Image: Pacific Northwest National ...

  7. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    signature, allowing their evolution into the final product to be precisely monitored with infrared spectroscopy. Although other (non-synchrotron) spectroscopic tools have the...

  8. SPITZER INFRARED SPECTROGRAPH DETECTION OF MOLECULAR HYDROGEN...

    Office of Scientific and Technical Information (OSTI)

    MOLECULAR HYDROGEN ROTATIONAL EMISSION TOWARDS TRANSLUCENT CLOUDS Citation Details In-Document Search Title: SPITZER INFRARED SPECTROGRAPH DETECTION OF MOLECULAR HYDROGEN ...

  9. Calibration Pad Assignments for Spectral Gamma (November 1985) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Pad Assignments for Spectral Gamma (November 1985) Calibration Pad Assignments for Spectral Gamma (November 1985) Calibration Pad Assignments for Spectral Gamma (November 1985) Calibration Pad Assignments for Spectral Gamma (November 1985) (5.3 MB) More Documents & Publications Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models (April 1984) Field Calibration Facilities for Environmental Measurement of Radium, Thorium, and Potassium (October 2013) Grade

  10. Retrieval Using Texture Features in High Resolution Multi-spectral Satellite Imagery

    SciTech Connect (OSTI)

    Newsam, S D; Kamath, C

    2004-01-22

    Texture features have long been used in remote sensing applications to represent and retrieve image regions similar to a query region. Various representations of texture have been proposed based on the Fourier power spectrum, spatial co-occurrence, wavelets, Gabor filters, etc. These representations vary in their computational complexity and their suitability for representing different region types. Much of the work done thus far has focused on panchromatic imagery at low to moderate spatial resolutions, such as images from Landsat 1-7 which have a resolution of 15-30 m/pixel, and from SPOT 1-5 which have a resolution of 2.5-20 m/pixel. However, it is not clear which texture representation works best for the new classes of high resolution panchromatic (60-100 cm/pixel) and multi-spectral (4 bands for red, green, blue, and near infra-red at 2.4-4 m/pixel) imagery. It is also not clear how the different spectral bands should be combined. In this paper, we investigate the retrieval performance of several different texture representations using multi-spectral satellite images from IKONOS. A query-by-example framework, along with a manually chosen ground truth dataset, allows different combinations of texture representations and spectral bands to be compared. We focus on the specific problem of retrieving inhabited regions from images of urban and rural scenes. Preliminary results show that (1) the use of all spectral bands improves the retrieval performance, and (2) co-occurrence, wavelet and Gabor texture features perform comparably.

  11. Compensated infrared absorption sensor for carbon dioxide and other infrared absorbing gases

    DOE Patents [OSTI]

    Owen, Thomas E.

    2005-11-29

    A gas sensor, whose chamber uses filters and choppers in either a semicircular geometry or annular geometry, and incorporates separate infrared radiation filters and optical choppers. This configuration facilitates the use of a single infrared radiation source and a single detector for infrared measurements at two wavelengths, such that measurement errors may be compensated.

  12. Staring 2-D hadamard transform spectral imager

    DOE Patents [OSTI]

    Gentry, Stephen M.; Wehlburg, Christine M.; Wehlburg, Joseph C.; Smith, Mark W.; Smith, Jody L.

    2006-02-07

    A staring imaging system inputs a 2D spatial image containing multi-frequency spectral information. This image is encoded in one dimension of the image with a cyclic Hadamarid S-matrix. The resulting image is detecting with a spatial 2D detector; and a computer applies a Hadamard transform to recover the encoded image.

  13. Gamma-ray Spectral Analysis Algorithm Library

    Energy Science and Technology Software Center (OSTI)

    1997-09-25

    The routines of the Gauss Algorithm library are used to implement special purpose products that need to analyze gamma-ray spectra from GE semiconductor detectors as a part of their function. These routines provide the ability to calibrate energy, calibrate peakwidth, search for peaks, search for regions, and fit the spectral data in a given region to locate gamma rays.

  14. Gamma-ray spectral analysis algorithm library

    Energy Science and Technology Software Center (OSTI)

    2013-05-06

    The routines of the Gauss Algorithms library are used to implement special purpose products that need to analyze gamma-ray spectra from Ge semiconductor detectors as a part of their function. These routines provide the ability to calibrate energy, calibrate peakwidth, search for peaks, search for regions, and fit the spectral data in a given region to locate gamma rays.

  15. Low-Cost Spectral Sensor Development Description.

    SciTech Connect (OSTI)

    Armijo, Kenneth Miguel; Yellowhair, Julius

    2014-11-01

    Solar spectral data for all parts of the US is limited due in part to the high cost of commercial spectrometers. Solar spectral information is necessary for accurate photovoltaic (PV) performance forecasting, especially for large utility-scale PV installations. A low-cost solar spectral sensor would address the obstacles and needs. In this report, a novel low-cost, discrete- band sensor device, comprised of five narrow-band sensors, is described. The hardware is comprised of commercial-off-the-shelf components to keep the cost low. Data processing algorithms were developed and are being refined for robustness. PV module short-circuit current ( I sc ) prediction methods were developed based on interaction-terms regression methodology and spectrum reconstruction methodology for computing I sc . The results suggest the computed spectrum using the reconstruction method agreed well with the measured spectrum from the wide-band spectrometer (RMS error of 38.2 W/m 2 -nm). Further analysis of computed I sc found a close correspondence of 0.05 A RMS error. The goal is for ubiquitous adoption of the low-cost spectral sensor in solar PV and other applications such as weather forecasting.

  16. The spectral irradiance traceability chain at PTB

    SciTech Connect (OSTI)

    Sperfeld, P.; Pape, S.; Nevas, S.

    2013-05-10

    Spectral irradiance is a fundamental radiometric unit. Its application to measurement results requires qualified traceability to basic units of the international system of units (Systeme international d'unites, SI). The Physikalisch-Technische Bundesanstalt (PTB) is amongst other national metrological institutes (NMIs) responsible for the realization, maintenance and dissemination of various radiometric and photometric units based on and traceable to national standards. The unit of spectral irradiance is realized and represented by a blackbody-radiator as the national primary standard of the PTB. Based on Planck's radiation law, the irradiance is calculated and realized for any wavelength taking into account the exact knowledge of the radiation temperature and the geometrical parameters. Using a double-monochromator-based spectroradiometer system, secondary standard lamps can be calibrated by direct comparison to the blackbody-radiator (substitution method). These secondary standard lamps are then used at the PTB to calibrate standard lamps of customers. The customers themselves use these so-called transfer standards to calibrate their working standard lamps. These working standards are then used to calibrate own spectroradiometers or sources. This rather complex calibration chain is a common procedural method that for the customers generally leads to satisfying measurement results on site. Nevertheless, the standard lamps in use have to fulfill highest requirements concerning stability and reproducibility. Only this allows achieving comparably low transfer measurement uncertainties, which occur at each calibration step. Thus, the PTB is constantly investigating the improvement and further development of transfer standards and measurement methods for various spectral regions. The realization and dissemination of the spectral irradiance using the blackbody-radiator at the PTB is accomplished with worldwide approved minimized measurement uncertainties confirmed by

  17. FY 2005 Infrared Photonics Final Report

    SciTech Connect (OSTI)

    Anheier, Norman C.; Allen, Paul J.; Ho, Nicolas; Krishnaswami, Kannan; Johnson, Bradley R.; Sundaram, S. K.; Riley, Bradley M.; Martinez, James E.; Qiao, Hong; Schultz, John F.

    2005-12-01

    Research done by the Infrared Photonics team at Pacific Northwest National Laboratory (PNNL) is focused on developing miniaturized integrated optics for mid-wave infrared (MWIR) and long-wave infrared (LWIR) sensing applications by exploiting the unique optical and material properties of chalcogenide glass. PNNL has developed thin-film deposition capabilities, direct laser writing techniques, infrared photonic device demonstration, holographic optical element design and fabrication, photonic device modeling, and advanced optical metrologyall specific to chalcogenide glass. Chalcogenide infrared photonics provides a pathway to quantum cascade laser (QCL) transmitter miniaturization. QCLs provide a viable infrared laser source for a new class of laser transmitters capable of meeting the performance requirements for a variety of national security sensing applications. The high output power, small size, and superb stability and modulation characteristics of QCLs make them amenable for integration as transmitters into ultra-sensitive, ultra-selective point sampling and remote short-range chemical sensors that are particularly useful for nuclear nonproliferation missions. During FY 2005, PNNLs Infrared Photonics research team made measurable progress exploiting the extraordinary optical and material properties of chalcogenide glass to develop miniaturized integrated optics for mid-wave infrared (MWIR) and long-wave infrared (LWIR) sensing applications. We investigated sulfur purification methods that will eventually lead to routine production of optical quality chalcogenide glass. We also discovered a glass degradation phenomenon and our investigation uncovered the underlying surface chemistry mechanism and developed mitigation actions. Key research was performed to understand and control the photomodification properties. This research was then used to demonstrate several essential infrared photonic devices, including LWIR single-mode waveguide devices and waveguide

  18. THE WIRED SURVEY. II. INFRARED EXCESSES IN THE SDSS DR7 WHITE DWARF CATALOG

    SciTech Connect (OSTI)

    Debes, John H.; Leisawitz, David T.; Hoard, D. W.; Wachter, Stefanie; Cohen, Martin

    2011-12-01

    With the launch of the Wide-field Infrared Survey Explorer (WISE), a new era of detecting planetary debris and brown dwarfs (BDs) around white dwarfs (WDs) has begun with the WISE InfraRed Excesses around Degenerates (WIRED) Survey. The WIRED Survey is sensitive to substellar objects and dusty debris around WDs out to distances exceeding 100 pc, well beyond the completeness level of local WDs. In this paper, we present a cross-correlation of the preliminary Sloan Digital Sky Survey (SDSS) Data Release 7 (DR7) WD catalog between the WISE, Two-Micron All Sky Survey (2MASS), UKIRT Infrared Deep Sky Survey (UKIDSS), and SDSS DR7 photometric catalogs. From {approx}18,000 input targets, there are WISE detections comprising 344 'naked' WDs (detection of the WD photosphere only), 1020 candidate WD+M dwarf binaries, 42 candidate WD+BD systems, 52 candidate WD+dust disk systems, and 69 targets with indeterminate infrared excess. We classified all of the detected targets through spectral energy distribution model fitting of the merged optical, near-IR, and WISE photometry. Some of these detections could be the result of contaminating sources within the large ( Almost-Equal-To 6'') WISE point-spread function; we make a preliminary estimate for the rates of contamination for our WD+BD and WD+disk candidates and provide notes for each target of interest. Each candidate presented here should be confirmed with higher angular resolution infrared imaging or infrared spectroscopy. We also present an overview of the observational characteristics of the detected WDs in the WISE photometric bands, including the relative frequencies of candidate WD+M, WD+BD, and WD+disk systems.

  19. Constraining the Ly? escape fraction with far-infrared observations of Ly? emitters

    SciTech Connect (OSTI)

    Wardlow, Julie L.; Calanog, J.; Cooray, A.; Malhotra, S.; Zheng, Z.; Rhoads, J.; Finkelstein, S.; Bock, J.; Bridge, C.; Ciardullo, R.; Gronwall, C.; Conley, A.; Farrah, D.; Gawiser, E.; Heinis, S.; Ibar, E.; Ivison, R. J.; Marsden, G.; Oliver, S. J.; Riechers, D.; and others

    2014-05-20

    We study the far-infrared properties of 498 Ly? emitters (LAEs) at z = 2.8, 3.1, and 4.5 in the Extended Chandra Deep Field-South, using 250, 350, and 500 ?m data from the Herschel Multi-tiered Extragalactic Survey and 870 ?m data from the LABOCA ECDFS Submillimeter Survey. None of the 126, 280, or 92 LAEs at z = 2.8, 3.1, and 4.5, respectively, are individually detected in the far-infrared data. We use stacking to probe the average emission to deeper flux limits, reaching 1? depths of ?0.1 to 0.4 mJy. The LAEs are also undetected at ?3? in the stacks, although a 2.5? signal is observed at 870 ?m for the z = 2.8 sources. We consider a wide range of far-infrared spectral energy distributions (SEDs), including an M82 and an Sd galaxy template, to determine upper limits on the far-infrared luminosities and far-infrared-derived star formation rates of the LAEs. These star formation rates are then combined with those inferred from the Ly? and UV emission to determine lower limits on the LAEs' Ly? escape fraction (f {sub esc}(Ly?)). For the Sd SED template, the inferred LAEs f {sub esc}(Ly?) are ? 30% (1?) at z = 2.8, 3.1, and 4.5, which are all significantly higher than the global f {sub esc}(Ly?) at these redshifts. Thus, if the LAEs f {sub esc}(Ly?) follows the global evolution, then they have warmer far-infrared SEDs than the Sd galaxy template. The average and M82 SEDs produce lower limits on the LAE f {sub esc}(Ly?) of ?10%-20% (1?), all of which are slightly higher than the global evolution of f {sub esc}(Ly?), but consistent with it at the 2?-3? level.

  20. Near-infrared line identification in type Ia supernovae during the transitional phase

    SciTech Connect (OSTI)

    Friesen, Brian; Baron, E.; Wisniewski, John P.; Miller, Timothy R.; Parrent, Jerod T.; Thomas, R. C.; Marion, G. H.

    2014-09-10

    We present near-infrared synthetic spectra of a delayed-detonation hydrodynamical model and compare them to observed spectra of four normal Type Ia supernovae ranging from day +56.5 to day +85. This is the epoch during which supernovae are believed to be undergoing the transition from the photospheric phase, where spectra are characterized by line scattering above an optically thick photosphere, to the nebular phase, where spectra consist of optically thin emission from forbidden lines. We find that most spectral features in the near-infrared can be accounted for by permitted lines of Fe II and Co II. In addition, we find that [Ni II] fits the emission feature near 1.98 μm, suggesting that a substantial mass of {sup 58}Ni exists near the center of the ejecta in these objects, arising from nuclear burning at high density.

  1. Room-temperature near-infrared silicon carbide nanocrystalline emitters based on optically aligned spin defects

    SciTech Connect (OSTI)

    Muzha, A.; Fuchs, F.; Simin, D.; Astakhov, G. V.; Tarakina, N. V.; Trupke, M.; Soltamov, V. A.; Mokhov, E. N.; Baranov, P. G.; Dyakonov, V.; and others

    2014-12-15

    Bulk silicon carbide (SiC) is a very promising material system for bio-applications and quantum sensing. However, its optical activity lies beyond the near infrared spectral window for in-vivo imaging and fiber communications due to a large forbidden energy gap. Here, we report the fabrication of SiC nanocrystals and isolation of different nanocrystal fractions ranged from 600?nm down to 60?nm in size. The structural analysis reveals further fragmentation of the smallest nanocrystals into ca. 10-nm-size clusters of high crystalline quality, separated by amorphization areas. We use neutron irradiation to create silicon vacancies, demonstrating near infrared photoluminescence. Finally, we detect room-temperature spin resonances of these silicon vacancies hosted in SiC nanocrystals. This opens intriguing perspectives to use them not only as in-vivo luminescent markers but also as magnetic field and temperature sensors, allowing for monitoring various physical, chemical, and biological processes.

  2. Second harmonic generation spectroscopy in the Reststrahl band of SiC using an infrared free-electron laser

    SciTech Connect (OSTI)

    Paarmann, Alexander Razdolski, Ilya; Melnikov, Alexey; Gewinner, Sandy; Schöllkopf, Wieland; Wolf, Martin

    2015-08-24

    The Reststrahl spectral region of silicon carbide has recently attracted much attention owing to its potential for mid-infrared nanophotonic applications based on surface phonon polaritons (SPhPs). Studies of optical phonon resonances responsible for surface polariton formation, however, have so far been limited to linear optics. In this Letter, we report the first nonlinear optical investigation of the Reststrahl region of SiC, employing an infrared free-electron laser to perform second harmonic generation (SHG) spectroscopy. We observe two distinct resonance features in the SHG spectra, one attributed to resonant enhancement of the nonlinear susceptibility χ{sup (2)} and the other due to a resonance in the Fresnel transmission. Our work clearly demonstrates high sensitivity of mid-infrared SHG to phonon-driven phenomena and opens a route to studying nonlinear effects in nanophotonic structures based on SPhPs.

  3. THREE NEW GALACTIC CENTER X-RAY SOURCES IDENTIFIED WITH NEAR-INFRARED SPECTROSCOPY

    SciTech Connect (OSTI)

    DeWitt, Curtis; Bandyopadhyay, Reba M.; Eikenberry, Stephen S.; Sarajedini, Ata; Sellgren, Kris; Blum, Robert; Olsen, Knut; Bauer, Franz E.

    2013-11-01

    We have conducted a near-infrared spectroscopic survey of 47 candidate counterparts to X-ray sources discovered by the Chandra X-Ray Observatory near the Galactic center (GC). Though a significant number of these astrometric matches are likely to be spurious, we sought out spectral characteristics of active stars and interacting binaries, such as hot, massive spectral types or emission lines, in order to corroborate the X-ray activity and certify the authenticity of the match. We present three new spectroscopic identifications, including a Be high-mass X-ray binary (HMXB) or a ? Cassiopeiae (Cas) system, a symbiotic X-ray binary, and an O-type star of unknown luminosity class. The Be HMXB/? Cas system and the symbiotic X-ray binary are the first of their classes to be spectroscopically identified in the GC region.

  4. Vacuum ultraviolet and infrared spectra of condensed methyl acetate on cold astrochemical dust analogs

    SciTech Connect (OSTI)

    Sivaraman, B.; Nair, B. G.; Mason, N. J.; Lo, J.-I.; Cheng, B.-M.; Kundu, S.; Davis, D.; Prabhudesai, V.; Krishnakumar, E.; Raja Sekhar, B. N.

    2013-12-01

    Following the recent report of the first identification of methyl acetate (CH{sub 3}COOCH{sub 3}) in the interstellar medium (ISM), we have carried out vacuum ultraviolet (VUV) and infrared (IR) spectroscopy studies on methyl acetate from 10 K until sublimation in an ultrahigh vacuum chamber simulating astrochemical conditions. We present the first VUV and IR spectra of methyl acetate relevant to ISM conditions. Spectral signatures clearly showed molecular reorientation to have started in the ice by annealing the amorphous ice formed at 10 K. An irreversible phase change from amorphous to crystalline methyl acetate ice was found to occur between 110 K and 120 K.

  5. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOE Patents [OSTI]

    Wolfe, Jesse D.

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  6. Mid infrared optical properties of Ge/Si quantum dots with different doping level

    SciTech Connect (OSTI)

    Sofronov, A. N.; Firsov, D. A.; Vorobjev, L. E.; Shalygin, V. A.; Panevin, V. Yu.; Vinnichenko, M. Ya.; Tonkikh, A. A.; Danilov, S. N.

    2013-12-04

    Optical characterization of the Ge/Si quantum dots using equilibrium and photo-induced absorption spectroscopy in the mid-infrared spectral range was performed in this work. Equilibrium absorption spectra were measured in structures with various doping levels for different light polarizations. Photo-induced absorption spectra measured in undoped structure under interband optical excitation of non-equilibrium charge carriers demonstrate the same features as doped sample in equilibrium conditions. Hole energy spectrum was determined from the analysis of experimental data.

  7. Automated eXpert Spectral Image Analysis

    Energy Science and Technology Software Center (OSTI)

    2003-11-25

    AXSIA performs automated factor analysis of hyperspectral images. In such images, a complete spectrum is collected an each point in a 1-, 2- or 3- dimensional spatial array. One of the remaining obstacles to adopting these techniques for routine use is the difficulty of reducing the vast quantities of raw spectral data to meaningful information. Multivariate factor analysis techniques have proven effective for extracting the essential information from high dimensional data sets into a limtedmore » number of factors that describe the spectral characteristics and spatial distributions of the pure components comprising the sample. AXSIA provides tools to estimate different types of factor models including Singular Value Decomposition (SVD), Principal Component Analysis (PCA), PCA with factor rotation, and Alternating Least Squares-based Multivariate Curve Resolution (MCR-ALS). As part of the analysis process, AXSIA can automatically estimate the number of pure components that comprise the data and can scale the data to account for Poisson noise. The data analysis methods are fundamentally based on eigenanalysis of the data crossproduct matrix coupled with orthogonal eigenvector rotation and constrained alternating least squares refinement. A novel method for automatically determining the number of significant components, which is based on the eigenvalues of the crossproduct matrix, has also been devised and implemented. The data can be compressed spectrally via PCA and spatially through wavelet transforms, and algorithms have been developed that perform factor analysis in the transform domain while retaining full spatial and spectral resolution in the final result. These latter innovations enable the analysis of larger-than core-memory spectrum-images. AXSIA was designed to perform automated chemical phase analysis of spectrum-images acquired by a variety of chemical imaging techniques. Successful applications include Energy Dispersive X-ray Spectroscopy, X

  8. Spectral Asymmetry Due to Magnetic Coordinates

    SciTech Connect (OSTI)

    Park, Jong-kyu; Boozer, Allen H.; Menard, Jonathan E.

    2008-05-06

    The use of magnetic coordinates is ubiquitous in toroidal plasma physics, but the distortion in Fourier spectra produced by these coordinates is not well known. A spatial symmetry of the field is not always represented by a symmetry in the Fourier spectrum when magnetic coordinates are used because of the distortion of the toroidal angle. The practical importance of spectral distortion is illustrated with a tokamak example.

  9. Fiberoptic probe and system for spectral measurements

    DOE Patents [OSTI]

    Dai, Sheng; Young, Jack P.

    1998-01-01

    A fused fiberoptic probe, a system, method and embodiments thereof for conducting spectral measurements are disclosed. The fused fiberoptic probe comprises a probe tip having a specific geometrical configuration, an exciting optical fiber and at least one collection optical fiber fused within a housing, preferrably silica. The specific geometrical configurations in which the probe tip can be shaped include a slanted probe tip with an angle greater than 0.degree., an inverted cone-shaped probe tip, and a lens head.

  10. Fiberoptic probe and system for spectral measurements

    DOE Patents [OSTI]

    Dai, S.; Young, J.P.

    1998-10-13

    A fused fiberoptic probe, a system, method and embodiments thereof for conducting spectral measurements are disclosed. The fused fiberoptic probe comprises a probe tip having a specific geometrical configuration, an exciting optical fiber and at least one collection optical fiber fused within a housing, preferably silica. The specific geometrical configurations in which the probe tip can be shaped include a slanted probe tip with an angle greater than 0{degree}, an inverted cone-shaped probe tip, and a lens head. 12 figs.

  11. Spectral Solar Radiation Data Base at NREL

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Solar Energy Research Institute (SERI)*, Electric Power Research Institute (EPRI), Florida Solar Energy Center (FSEC), and Pacific Gas and Electric Company (PG&E) cooperated to produce a spectral solar radiation data base representing a range of atmospheric conditions (or climates) that is applicable to several different types of solar collectors. Data that are included in the data base were collected at FSEC from October 1986 to April 1988, and at PG&E from April 1987 to April 1988. FSEC operated one EPRI and one SERI spectroradiometer almost daily at Cape Canaveral, which contributed nearly 2800 spectra to the data base. PG&E operated one EPRI spectroradiometer at San Ramon, Calif., as resources permitted, contributing nearly 300 spectra to the data base. SERI collected about 200 spectra in the Denver/Golden, Colo., area form November 1987 to February 1988 as part of a research project to study urban spectral solar radiation, and added these data to the data base. *In September 1991 the Solar Energy Research Institute became the National Renewable Energy Laboratory. [Description taken from http://rredc.nrel.gov/solar/old_data/spectral/

  12. Category:Near Infrared Surveys | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Infrared Surveys Retrieved from "http:en.openei.orgwindex.php?titleCategory:NearInfraredSurveys&oldid794164" Feedback Contact needs updating Image needs updating...

  13. Category:Long-Wave Infrared | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Infrared Retrieved from "http:en.openei.orgwindex.php?titleCategory:Long-WaveInfrared&oldid794161" Feedback Contact needs updating Image needs updating Reference...

  14. A NEAR-INFRARED SPECTROSCOPIC STUDY OF YOUNG FIELD ULTRACOOL DWARFS

    SciTech Connect (OSTI)

    Allers, K. N.; Liu, Michael C.

    2013-08-01

    We present a near-infrared (0.9-2.4 {mu}m) spectroscopic study of 73 field ultracool dwarfs having spectroscopic and/or kinematic evidence of youth ( Almost-Equal-To 10-300 Myr). Our sample is composed of 48 low-resolution (R Almost-Equal-To 100) spectra and 41 moderate-resolution spectra (R {approx}> 750-2000). First, we establish a method for spectral typing M5-L7 dwarfs at near-IR wavelengths that is independent of gravity. We find that both visual and index-based classification in the near-IR provides consistent spectral types with optical spectral types, though with a small systematic offset in the case of visual classification at J and K band. Second, we examine features in the spectra of {approx}10 Myr ultracool dwarfs to define a set of gravity-sensitive indices based on FeH, VO, K I, Na I, and H-band continuum shape. We then create an index-based method for classifying the gravities of M6-L5 dwarfs that provides consistent results with gravity classifications from optical spectroscopy. Our index-based classification can distinguish between young and dusty objects. Guided by the resulting classifications, we propose a set of low-gravity spectral standards for the near-IR. Finally, we estimate the ages corresponding to our gravity classifications.

  15. Characterizing Wolf-Rayet stars in the near- and mid-infrared

    SciTech Connect (OSTI)

    Faherty, Jacqueline K.; Shara, Michael M.; Zurek, David; Kanarek, Graham; Moffat, Anthony F. J.

    2014-05-01

    We present refined color-color selection criteria for identifying Wolf-Rayet (WR) stars using available mid-infrared (MIR) photometry from WISE in combination with near-infrared (NIR) photometry from the Two Micron All Sky Survey. Using a sample of spectrally classified objects, we find that WR stars are well distinguished from the field stellar population in the (W1 – W2) versus (J – K{sub s} ) color-color diagram, and further distinguished from other emission line objects such as planetary nebulae, Be, and cataclysmic variable stars using a combination of NIR and MIR color constraints. As proof of concept we applied the color constraints to a photometric sample in the Galactic plane, located WR star candidates, and present five new spectrally confirmed and classified WC (1) and WN (4) stars. Analysis of the 0.8-5.0 μm spectral data for a subset of known, bright WC and WN stars shows that emission lines (primarily He I) extend into the 3.0-5.0 μm spectral region, although their strength is greatly diminished compared to the 0.8-2.5 μm region. The WR population stands out relative to background field stars at NIR and MIR colors due to an excess continuum contribution, likely caused by free-free scattering in dense winds. Mean photometric properties of known WRs are presented and imply that reddened late-type WN and WC sources are easier to detect than earlier-type sources at larger Galactic radii. WISE W3 and W4 images of 10 WR stars show evidence of circumstellar shells linked to mass ejections from strong stellar winds.

  16. Mushroom plasmonic metamaterial infrared absorbers

    SciTech Connect (OSTI)

    Ogawa, Shinpei Fujisawa, Daisuke; Hata, Hisatoshi; Uetsuki, Mitsuharu; Misaki, Koji; Kimata, Masafumi

    2015-01-26

    There has been a considerable amount of interest in the development of various types of electromagnetic wave absorbers for use in different wavelength ranges. In particular, infrared (IR) absorbers with wavelength selectivity can be applied to advanced uncooled IR sensors, which would be capable of identifying objects through their radiation spectrum. In the present study, mushroom plasmonic metamaterial absorbers (MPMAs) for the IR wavelength region were designed and fabricated. The MPMAs consist of a periodic array of thin metal micropatches connected to a thin metal plate with narrow silicon (Si) posts. A Si post height of 200 nm was achieved by isotropic XeF{sub 2} etching of a thin Si layer sandwiched between metal plates. This fabrication procedure is relatively simple and is consistent with complementary metal oxide semiconductor technology. The absorption spectra of the fabricated MPMAs were experimentally measured. In addition, theoretical calculations of their absorption properties were conducted using rigorous coupled wave analysis. Both the calculated and measured absorbance results demonstrated that these MPMAs can realize strong selective absorption at wavelengths beyond the period of the array by varying the micropatch width. Absorbance values greater than 90% were achieved. Dual- or single-mode absorption can also be selected by varying the width of the Si posts. Pixel structures using such MPMAs could be used as high responsivity, high resolution and fast uncooled IR sensors.

  17. ARM - Field Campaign - Arctic Cloud Infrared Imaging

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    govCampaignsArctic Cloud Infrared Imaging Campaign Links Field Campaign Report ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Cloud Infrared Imaging 2012.07.16 - 2014.07.31 Lead Scientist : Joseph Shaw For data sets, see below. Abstract The 3rd-generation Infrared Cloud Imager (ICI) instrument was deployed close to the Great White facility at the North Slope of Alaska site and operated as

  18. Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    (April 1984) | Department of Energy Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models (April 1984) Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models (April 1984) Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models (April 1984) Parameter Assignments for Spectral Gamma-Ray Borehole Calibration Models (April 1984) (3.25 MB) More Documents & Publications Grade Assignments for Models Used for Calibration of Gross-Count

  19. PROBING THE UNIVERSE'S TILT WITH THE COSMIC INFRARED BACKGROUND DIPOLE

    SciTech Connect (OSTI)

    Fixsen, D. J.; Kashlinsky, A. E-mail: alexander.kashlinsky@nasa.gov

    2011-06-10

    Conventional interpretation of the observed cosmic microwave background (CMB) dipole is that all of it is produced by local peculiar motions. Alternative explanations requiring part of the dipole to be primordial have received support from measurements of large-scale bulk flows. A test of the two hypotheses is whether other cosmic dipoles produced by collapsed structures later than the last scattering coincide with the CMB dipole. One background is the cosmic infrared background (CIB) whose absolute spectrum was measured to {approx}30% by the COBE satellite. Over the 100-500 {mu}m wavelength range its spectral energy distribution can provide a probe of its alignment with the CMB. This is tested with the COBE FIRAS data set which is available for such a measurement because of its low noise and frequency resolution which are important for Galaxy subtraction. Although the FIRAS instrument noise is in principle low enough to determine the CIB dipole, the Galactic foreground is sufficiently close spectrally to keep the CIB dipole hidden. A similar analysis is performed with DIRBE, which-because of the limited frequency coverage-provides a poorer data set. We discuss strategies for measuring the CIB dipole with future instruments to probe the tilt and apply it to the Planck, Herschel, and the proposed Pixie missions. We demonstrate that a future FIRAS-like instrument with instrument noise a factor of {approx}10 lower than FIRAS would make a statistically significant measurement of the CIB dipole. We find that the Planck and Herschel data sets will not allow a robust CIB dipole measurement. The Pixie instrument promises a determination of the CIB dipole and its alignment with either the CMB dipole or the dipole galaxy acceleration vector.

  20. Dynamically Responsive Infrared Window Coatings | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Dynamically Responsive Infrared Window Coatings 1 of 5 An oxygen plasma etcher is used to ... Kyle Alvine checks on the progress of the plasma etch. Image: Pacific Northwest National ...

  1. Rapid infrared heating of a surface

    DOE Patents [OSTI]

    Sikka, Vinod K.; Blue, Craig A.; Ohriner, Evan Keith

    2002-01-01

    High energy flux infrared heaters are used to treat an object having a surface section and a base section such that a desired characteristic of the surface section is physically, chemically, or phasically changed while the base section remains unchanged.

  2. Rapid infrared heating of a surface

    DOE Patents [OSTI]

    Sikka, Vinod K.; Blue, Craig A.; Ohriner, Evan Keith

    2001-01-01

    High energy flux infrared heaters are used to treat an object having a surface section and a base section such that a desired characteristic of the surface section is physically, chemically, or phasically changed while the base section remains unchanged.

  3. Rapid infrared heating of a surface

    DOE Patents [OSTI]

    Sikka, Vinod K.; Blue, Craig A.; Ohriner, Evan Keith

    2003-12-23

    High energy flux infrared heaters are used to treat an object having a surface section and a base section such that a desired characteristic of the surface section is physically, chemically, or phasically changed while the base section remains unchanged.

  4. Uncooled infrared photon detector and multicolor infrared detection using microoptomechanical sensors

    DOE Patents [OSTI]

    Datskos, Panagiotis G.; Rajic, Solobodan; Datskou, Irene C.

    1999-01-01

    Systems and methods for infrared detection are described. An optomechanical photon detector includes a semiconductor material and is based on measurement of a photoinduced lattice strain. A multicolor infrared sensor includes a stack of frequency specific optomechanical detectors. The stack can include one, or more, of the optomechanical photon detectors that function based on the measurement of photoinduced lattice strain. The systems and methods provide advantages in that rapid, sensitive multicolor infrared imaging can be performed without the need for a cooling subsystem.

  5. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  6. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  7. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  8. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  9. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  10. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  11. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Print A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ using infrared microspectroscopy, while the state of the catalyst along the flow

  12. Infrared Mapping Helps Optimize Catalytic Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Mapping Helps Optimize Catalytic Reactions Infrared Mapping Helps Optimize Catalytic Reactions Print Wednesday, 20 August 2014 07:59 A pathway to more effective and efficient synthesis of pharmaceuticals and other flow-reactor chemical products has been opened by a study in which, for the first time, the catalytic reactivity inside a microreactor was mapped in high resolution from start to finish. The formation of different chemical products during the reactions was analyzed in situ

  13. Probing Organic Transistors with Infrared Beams

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also

  14. Posters Long-Pathlength Infrared Absorption Measurements

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    3 Posters Long-Pathlength Infrared Absorption Measurements in the 8- to 14-µm Atmospheric Window: Self-Broadening Coefficient Data T. J. Kulp (a) and J. Shinn Geophysics and Environmental Research Program Lawrence Livermore National Laboratory Livermore, California Introduction The accurate characterization of the latent infrared (IR) absorption in the atmospheric window regions continues to be an area of research interest for the global climate modeling community. In the window between 8 and

  15. THE GALACTIC CENTER IN THE FAR-INFRARED

    SciTech Connect (OSTI)

    Etxaluze, M.; Smith, Howard A.; Tolls, V.; Stark, A. A. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Gonzalez-Alfonso, E., E-mail: metxaluz@cfa.harvard.edu [CfA and Universidad de Alcala, Alcala de Henares 28801 (Spain)

    2011-10-15

    We analyze the far-infrared dust emission from the Galactic center region, including the circumnuclear disk (CND) and other structures, using Herschel PACS and SPIRE photometric observations. These Herschel data are complemented by unpublished observations by the Infrared Space Observatory Long Wavelength Spectrometer (ISO-LWS), which used parallel mode scans to obtain photometric images of the region with a larger beam than Herschel but with a complementary wavelength coverage and more frequent sampling with 10 detectors observing at 10 different wavelengths in the range from 46 {mu}m to 180 {mu}m, where the emission peaks. We also include data from the Midcourse Space Experiment at 21.3 {mu}m for completeness. We model the combined ISO-LWS continuum plus Herschel PACS and SPIRE photometric data toward the central 2 pc in Sagittarius A* (Sgr A*), a region that includes the CND. We find that the far-infrared spectral energy distribution is best represented by a continuum that is the sum of three gray body curves from dust at temperatures of 90, 44.5, and 23 K. We obtain temperature and molecular hydrogen column density maps of the region. We estimate the mass of the inner part of the CND to be {approx}5.0 x 10{sup 4} M{sub sun}, with luminosities: L{sub cavity} {approx} 2.2 x 10{sup 6} L{sub sun} and L{sub CND} {approx} 1.5 x 10{sup 6} L{sub sun} in the central 2 pc radius around Sgr A*. We find from the Herschel and ISO data that the cold component of the dust dominates the total dust mass, with a contribution of {approx}3.2 x 10{sup 4} M{sub sun}; this important cold material had escaped the notice of earlier studies that relied on shorter wavelength observations. The hotter component disagrees with some earlier estimates, but is consistent with measured gas temperatures and with models that imply shock heating or turbulent effects are at work. We find that the dust grain sizes apparently change widely across the region, perhaps in response to the temperature

  16. Spectral method for a kinetic swarming model

    DOE PAGES-Beta [OSTI]

    Gamba, Irene M.; Haack, Jeffrey R.; Motsch, Sebastien

    2015-04-28

    Here we present the first numerical method for a kinetic description of the Vicsek swarming model. The kinetic model poses a unique challenge, as there is a distribution dependent collision invariant to satisfy when computing the interaction term. We use a spectral representation linked with a discrete constrained optimization to compute these interactions. To test the numerical scheme we investigate the kinetic model at different scales and compare the solution with the microscopic and macroscopic descriptions of the Vicsek model. Lastly, we observe that the kinetic model captures key features such as vortex formation and traveling waves.

  17. ARM - Measurement - Shortwave spectral total downwelling irradiance

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    total downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral total downwelling irradiance The rate at which radiant energy, at specrally-resolved wavelengths between 0.4 and 4 {mu}m, is being emitted upwards and downwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments

  18. Mixed-Precision Spectral Deferred Correction: Preprint

    SciTech Connect (OSTI)

    Grout, Ray W. S.

    2015-09-02

    Convergence of spectral deferred correction (SDC), where low-order time integration methods are used to construct higher-order methods through iterative refinement, can be accelerated in terms of computational effort by using mixed-precision methods. Using ideas from multi-level SDC (in turn based on FAS multigrid ideas), some of the SDC correction sweeps can use function values computed in reduced precision without adversely impacting the accuracy of the final solution. This is particularly beneficial for the performance of combustion solvers such as S3D [6] which require double precision accuracy but are performance limited by the cost of data motion.

  19. THE INFRARED SPECTRUM OF URANIUM HOLLOW CATHODE LAMPS FROM 850...

    Office of Scientific and Technical Information (OSTI)

    CATHODES; ELECTRODES; ELECTROMAGNETIC RADIATION; ELEMENTS; INFRARED RADIATION; INTEGRAL TRANSFORMATIONS; MEASURING INSTRUMENTS; METALS; RADIATIONS; SPECTRA; SPECTROMETERS; ...

  20. Radiometric calibration of optical microscopy and microspectroscopy apparata over a broad spectral range using a special thin-film luminescence standard

    SciTech Connect (OSTI)

    Valenta, J. Greben, M.

    2015-04-15

    Application capabilities of optical microscopes and microspectroscopes can be considerably enhanced by a proper calibration of their spectral sensitivity. We propose and demonstrate a method of relative and absolute calibration of a microspectroscope over an extraordinary broad spectral range covered by two (parallel) detection branches in visible and near-infrared spectral regions. The key point of the absolute calibration of a relative spectral sensitivity is application of the standard sample formed by a thin layer of Si nanocrystals with stable and efficient photoluminescence. The spectral PL quantum yield and the PL spatial distribution of the standard sample must be characterized by separate experiments. The absolutely calibrated microspectroscope enables to characterize spectral photon emittance of a studied object or even its luminescence quantum yield (QY) if additional knowledge about spatial distribution of emission and about excitance is available. Capabilities of the calibrated microspectroscope are demonstrated by measuring external QY of electroluminescence from a standard poly-Si solar-cell and of photoluminescence of Er-doped Si nanocrystals.

  1. Spectral dependence of third-order nonlinear optical properties in InN

    SciTech Connect (OSTI)

    Ahn, H. Lee, M.-T.; Chang, Y.-M.

    2014-05-19

    We report on the nonlinear optical properties of InN measured in a wide near-infrared spectral range with the femtosecond Z-scan technique. The above-bandgap nonlinear absorption in InN is found to originate from the saturation of absorption by the band-state-filling and its cross-section increases drastically near the bandgap energy. With below-bandgap excitation, the nonlinear absorption undergoes a transition from saturation absorption (SA) to reverse-SA (RSA), attributed to the competition between SA of band-tail states and two-photon-related RSA. The measured large nonlinear refractive index of the order of 10{sup −10} cm{sup 2}/W indicates InN as a potential material for all-optical switching and related applications.

  2. Spectral geometry of {kappa}-Minkowski space

    SciTech Connect (OSTI)

    D'Andrea, Francesco

    2006-06-15

    After recalling Snyder's idea [Phys. Rev. 71, 38 (1947)] of using vector fields over a smooth manifold as 'coordinates on a noncommutative space', we discuss a two-dimensional toy-model whose 'dual' noncommutative coordinates form a Lie algebra: this is the well-known {kappa}-Minkowski space [Phys. Lett. B 334, 348 (1994)]. We show how to improve Snyder's idea using the tools of quantum groups and noncommutative geometry. We find a natural representation of the coordinate algebra of {kappa}-Minkowski as linear operators on an Hilbert space (a major problem in the construction of a physical theory), study its 'spectral properties', and discuss how to obtain a Dirac operator for this space. We describe two Dirac operators. The first is associated with a spectral triple. We prove that the cyclic integral of Dimitrijevic et al. [Eur. Phys. J. C 31, 129 (2003)] can be obtained as Dixmier trace associated to this triple. The second Dirac operator is equivariant for the action of the quantum Euclidean group, but it has unbounded commutators with the algebra.

  3. Hyper-spectral scanner design and analysis

    SciTech Connect (OSTI)

    Canavan, G.; Moses, J.; Smith, R.

    1996-06-01

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). An earlier project produced rough designs for key components of a compact hyper-spectral sensor for environmental and ecological measurements. Such sensors could be deployed on unmanned vehicles, aircraft, or satellites for measurements important to agriculture, the environment, and ecologies. This represents an important advance in remote sensing. Motorola invited us to propose an add-on, proof-of-principle sensor for their Comet satellite, whose primary mission is to demonstrate a channel of the IRIDIUM satellite communications system. Our project converted the preliminary designs from the previous effort into final designs for the telescope, camera, computer and interfaces that constitute the hyper-spectral scanning sensor. The work concentrated on design, fabrication, preliminary integration, and testing of the electronic circuit boards for the computer, data compression board, and interface board for the camera-computer and computer-modulator (transmitter) interfaces.

  4. Characterization of high proper motion objects from the wide-field infrared survey explorer

    SciTech Connect (OSTI)

    Luhman, K. L.; Sheppard, Scott S.

    2014-06-01

    We present an analysis of high proper motion objects that we have found in a recent study and in this work with multi-epoch astrometry from the Wide-field Infrared Survey Explorer (WISE). Using photometry and proper motions from the Two Micron All-Sky Survey and WISE, we have identified the members of this sample that are likely to be late-type, nearby, or metal-poor. We have performed optical and near-infrared spectroscopy on 41 objects, from which we measure spectral types that range from M4-T2.5. This sample includes 11 blue L dwarfs and 5 subdwarfs; the latter were also classified as such in the recent study by Kirkpatrick and coworkers. Based on their spectral types and photometry, several of our spectroscopic targets may have distances of <20 pc with the closest at ∼12 pc. The tangential velocities implied by the spectrophotometric distances and proper motions indicate that four of the five subdwarfs are probably members of the Galactic halo while several other objects, including the early-T dwarf WISE J210529.08–623558.7, may belong to the thick disk.

  5. Object detection utilizing a linear retrieval algorithm for thermal infrared imagery

    SciTech Connect (OSTI)

    Ramsey, M.S. [Arizona State Univ., Tempe, AZ (United States)

    1996-11-01

    Thermal infrared (TIR) spectroscopy and remote sensing have been proven to be extremely valuable tools for mineralogic discrimination. One technique for sub-pixel detection and data reduction, known as a spectral retrieval or unmixing algorithm, will prove useful in the analysis of data from scheduled TIR orbital instruments. This study represents the first quantitative attempt to identify the limits of the model, specifically concentrating on the TIR. The algorithm was written and applied to laboratory data, testing the effects of particle size, noise, and multiple endmembers, then adapted to operate on airborne Thermal Infrared Multispectral Scanner data of the Kelso Dunes, CA, Meteor Crater, AZ, and Medicine Lake Volcano, CA. Results indicate that linear spectral unmixmg can produce accurate endmember detection to within an average of 5%. In addition, the effects of vitrification and textural variations were modeled. The ability to predict mineral or rock abundances becomes extremely useful in tracking sediment transport, decertification, and potential hazard assessment in remote volcanic regions. 26 refs., 3 figs.

  6. Infrared spectroscopy and structure of (NO)n clusters

    DOE PAGES-Beta [OSTI]

    Hoshina, Hiromichi; Slipchenko, Mikhail; Prozument, Kirill; Verma, Deepak; Schmidt, Michael W.; Ivanic, Joseph; Vilesov, Andrey F.

    2016-01-12

    Nitrogen oxide clusters (NO)n have been studied in He droplets via infrared depletion spectroscopy and by quantum chemical calculations. The ν1 and ν5 bands of cis-ON-NO dimer have been observed at 1868.2 and 1786.5 cm–1, respectively. Furthermore, spectral bands of the trimer and tetramer have been located in the vicinity of the corresponding dimer bands in accord with computed frequencies that place NO-stretch bands of dimer, trimer, and tetramer within a few wavenumbers of each other. In addition, a new line at 1878.1 cm–1 close to the band origin of single molecules was assigned to van der Waals bound dimersmore » of (NO)2, which are stabilized due to the rapid cooling in He droplets. Spectra of larger clusters (n > 5), have broad unresolved features in the vicinity of the dimer bands. As a result, experiments and calculations indicate that trimers consist of a dimer and a loosely bound third molecule, whereas the tetramer consists of two weakly bound dimers.« less

  7. Infrared curing simulations of liquid composites molding

    SciTech Connect (OSTI)

    Nakouzi, S.; Pancrace, J.; Schmidt, F. M.; Le Maoult, Y.; Berthet, F. [Universite de Toulouse (France); INSA, UPS, Mines Albi, ISAE, ICA - Institut Clement Ader, Campus Jarlard, F-81013 Albi cedex 09 (France); Ecole des Mines Albi, Campus Jarlard, F-81013 Albi (France)

    2011-05-04

    Infrared radiation is an effective energy source to cure thermosetting polymers. Its usage is expected to reduce curing time in comparison with thermal heating and mold thermally regulated. In addition, because of the polymerization mechanism and instant on-off control of this power, an improvement in the final properties of the material is also expected. In this paper, we studied the infrared interaction with carbon (or glass) fibers reinforced epoxy matrix, where Liquid resin infusion (LRI) is used to manufacture the composite. Temperature of the composite is a key parameter that affects its mechanical properties and is controlled by the infrared emitters and the exothermic heat released from the polymerization. Radiative heat flux is computed using the in-lab developed software RAYHEAT. Then, the heat flux (or absorbed energy for glass fibers) is exported to the finite element based program COMSOLMULTIPHYSICS where heat balance equation is solved. This equation is coupled with the exothermic heat released during the curing process in order to predict the composite temperature versus time and degree of cure. Numerical simulations will be performed on planar parts (sheet shape) as well as curvilinear shapes. Experimental validations of the infrared curing carbon (glass)-epoxy composite system are presented in this paper Sheet surface temperature distribution are measured thanks to infrared camera. Kinetic parameters were estimated from differential scanning calorimeter (DSC) experimental data.

  8. BBHRP Assessment Using Ground and Satellite-based High Spectral...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Infrared Observations Revercomb, Henry University of Wisconsin-Madison DeSlover, Daniel University of Wisconsin Holz, Robert University of Wisconsin, CIMMS Knuteson, Robert...

  9. Model for spectral and chromatographic data

    DOE Patents [OSTI]

    Jarman, Kristin [Richland, WA; Willse, Alan [Richland, WA; Wahl, Karen [Richland, WA; Wahl, Jon [Richland, WA

    2002-11-26

    A method and apparatus using a spectral analysis technique are disclosed. In one form of the invention, probabilities are selected to characterize the presence (and in another form, also a quantification of a characteristic) of peaks in an indexed data set for samples that match a reference species, and other probabilities are selected for samples that do not match the reference species. An indexed data set is acquired for a sample, and a determination is made according to techniques exemplified herein as to whether the sample matches or does not match the reference species. When quantification of peak characteristics is undertaken, the model is appropriately expanded, and the analysis accounts for the characteristic model and data. Further techniques are provided to apply the methods and apparatuses to process control, cluster analysis, hypothesis testing, analysis of variance, and other procedures involving multiple comparisons of indexed data.

  10. Spectral line broadening in magnetized black holes

    SciTech Connect (OSTI)

    Frolov, Valeri P.; Shoom, Andrey A.; Tzounis, Christos E-mail: ashoom@ualberta.ca

    2014-07-01

    We consider weakly magnetized non-rotating black holes. In the presence of a regular magnetic field the motion of charged particles in the vicinity of a black hole is modified. As a result, the position of the innermost stable circular orbit (ISCO) becomes closer to the horizon. When the Lorentz force is repulsive (directed from the black hole) the ISCO radius can reach the gravitational radius. In the process of accretion charged particles (ions) of the accreting matter can be accumulated near their ISCO, while neutral particles fall down to the black hole after they reach 6M radius. The sharp spectral line Fe α, emitted by iron ions at such orbits, is broadened when the emission is registered by a distant observer. In this paper we study this broadening effect and discuss how one can extract information concerning the strength of the magnetic field from the observed spectrum.

  11. Spatially resolved spectral-imaging device

    DOE Patents [OSTI]

    Bloom, Joshua Simon; Tyson, John Anthony

    2016-02-09

    A spatially resolved spectral device comprising a dispersive array to receive an incident light comprising a principal ray. The dispersive array comprising a plurality of dichroic layers, each of the plurality of dichroic layers disposed in a path of a direction of the principal ray. Each of the plurality of dichroic layers configured to at least one of reflect or transmit a different wavelength range of the incident light. The device further comprising a detection array operatively coupled with the dispersive array. The detection array comprising a photosensitive component including a plurality of detection pixels, each of the plurality of detection pixels having a light-receiving surface disposed parallel to the direction of the principal ray to detect a respective one of the different wavelength ranges of incident light reflected from a corresponding one of the plurality of dichroic layers.

  12. Alma observations of nearby luminous infrared galaxies with various agn energetic contributions using dense gas tracers

    SciTech Connect (OSTI)

    Imanishi, Masatoshi; Nakanishi, Kouichiro

    2014-07-01

    We present the results of our ALMA Cycle 0 observations, using HCN/HCO{sup +}/HNC J = 4-3 lines, of six nearby luminous infrared galaxies with various energetic contributions from active galactic nuclei (AGNs) estimated from previous infrared spectroscopy. These lines are very effective for probing the physical properties of high-density molecular gas around the hidden energy sources in the nuclear regions of these galaxies. We find that HCN to HCO{sup +} J = 4-3 flux ratios tend to be higher in AGN-important galaxies than in starburst-dominated regions, as was seen at the J = 1-0 transition, while there is no clear difference in the HCN-to-HNC J = 4-3 flux ratios among observed sources. A galaxy with a starburst-type infrared spectral shape and very large molecular line widths shows a high HCN-to-HCO{sup +} J = 4-3 flux ratio, which could be due to turbulence-induced heating. We propose that enhanced HCN J = 4-3 emission relative to HCO{sup +} J = 4-3 could be used to detect more energetic activity than normal starbursts, including deeply buried AGNs, in dusty galaxy populations.

  13. Characterizing ultraviolet and infrared observational properties for galaxies. II. Features of attenuation law

    SciTech Connect (OSTI)

    Mao, Ye-Wei; Kong, Xu; Lin, Lin E-mail: xkong@ustc.edu.cn

    2014-07-01

    Variations in the attenuation law have a significant impact on observed spectral energy distributions for galaxies. As one important observational property for galaxies at ultraviolet and infrared wavelength bands, the correlation between infrared-to-ultraviolet luminosity ratio and ultraviolet color index (or ultraviolet spectral slope), i.e., the IRX-UV relation (or IRX-β relation), offered a widely used formula for correcting dust attenuation in galaxies, but the usability appears to be in doubt now because of considerable dispersion in this relation found by many studies. In this paper, on the basis of spectral synthesis modeling and spatially resolved measurements of four nearby spiral galaxies, we provide an interpretation of the deviation in the IRX-UV relation with variations in the attenuation law. From both theoretical and observational viewpoints, two components in the attenuation curve, the linear background and the 2175 Å bump, are suggested to be the parameters in addition to the stellar population age (addressed in the first paper of this series) in the IRX-UV function; different features in the attenuation curve are diagnosed for the galaxies in our sample. Nevertheless, it is often difficult to ascertain the attenuation law for galaxies in actual observations. Possible reasons for preventing the successful detection of the parameters in the attenuation curve are also discussed in this paper, including the degeneracy of the linear background and the 2175 Å bump in observational channels, the requirement for young and dust-rich systems to study, and the difficulty in accurate estimates of dust attenuations at different wavelength bands.

  14. Spectral output of Z-machine implosions.

    SciTech Connect (OSTI)

    Idzorek, G. C.; Chrien, Robert E.; Peterson, D. L.; Watt, R. G.; Chandler, G. A.; Fehl, D. L.; Sanford, T. W. L.

    2001-01-01

    Sandia National Laboratories Z-machine has developed into a reproducible, high power (>200 TW), high temperature (>200 eV) driver for radiation physics experiments. Imploding cylindrical wire arrays on the Z-machine produce a radiation source with a bolometric temperature of about 200 eV. By surrounding the z-pinch implosion with a vacuum hohlraum a nearly Planckian source of about 140 eV temperature is created with peak radiation powers of about 200 terawatts and integrated energy of 2 megajoules or more. In this energy rich environment we can field a dozen experiments all being driven by an identical source. In addition to 'standard' vacuum hohlraums we also use dynamic hohlraums consisting of two nested wire arrays converging onto an axially centered foam cylinder. Radiation flowing from the ends on the cylinder indicates a Planckian source temperature well over 200 eV. Only two experiments can be fielded on a dynamic hohlraum (one on each end) but the higher source temperature justifies the added complexity of the set-up. We routinely use arrays of filtered silicon photodiodes (SiD) and filtered photocathode x-ray diodes (XRD) to determine the temperature of the source. Three different techniques for unfolding spectra from the XRD and SiD detector data are being used. They are: (1) Treat each detector independently and find the Planckian temperature for a given source size and solid angle that would give the measured detector signal, (2) Use all detector signals and detector spectral responses simultaneously and find a spectrum that best fits the observed data, (3) Use all detector signals and averaged detector spectral responses and find a histogram spectrum that best fits the observed data. When used as complementary set of analysis tools these techniques generate remarkably consistent results showing nearly Planckian behavior on our vacuum hohlraum experiments.

  15. Infrared light sources with semimetal electron injection

    DOE Patents [OSTI]

    Kurtz, Steven R.; Biefeld, Robert M.; Allerman, Andrew A.

    1999-01-01

    An infrared light source is disclosed that comprises a layered semiconductor active region having a semimetal region and at least one quantum-well layer. The semimetal region, formed at an interface between a GaAsSb or GalnSb layer and an InAsSb layer, provides electrons and holes to the quantum-well layer to generate infrared light at a predetermined wavelength in the range of 2-6 .mu.m. Embodiments of the invention can be formed as electrically-activated light-emitting diodes (LEDs) or lasers, and as optically-pumped lasers. Since the active region is unipolar, multiple active regions can be stacked to form a broadband or multiple-wavelength infrared light source.

  16. HerMES: Spectral energy distributions of submillimeter galaxies at z > 4

    SciTech Connect (OSTI)

    Huang, J.-S.; Rigopoulou, D.; Magdis, G.; Rowan-Robinson, M.; Clements, D. L.; Dai, Y.; Fazio, G. G.; Bock, J. J.; Burgarella, D.; Chapman, S.; Cooray, A.; Farrah, D.; Glenn, J.; Oliver, S.; Smith, A. J.; Wang, L.; Page, M.; Symeonidis, M.; Riechers, D.; Roseboom, I.; and others

    2014-03-20

    We present a study of the infrared properties for a sample of seven spectroscopically confirmed submillimeter galaxies (SMGs) at z > 4.0. By combining ground-based near-infrared, Spitzer IRAC and MIPS, Herschel SPIRE, and ground-based submillimeter/millimeter photometry, we construct their spectral energy distributions (SEDs) and a composite model to fit the SEDs. The model includes a stellar emission component at λ{sub rest} < 3.5 μm, a hot dust component peaking at λ{sub rest} ∼ 5 μm, and cold dust component which becomes significant for λ{sub rest} > 50 μm. Six objects in the sample are detected at 250 and 350 μm. The dust temperatures for the sources in this sample are in the range of 40-80 K, and their L {sub FIR} ∼ 10{sup 13} L {sub ☉} qualifies them as hyper-luminous infrared galaxies. The mean FIR-radio index for this sample is around (q) = 2.2 indicating no radio excess in their radio emission. Most sources in the sample have 24 μm detections corresponding to a rest-frame 4.5 μm luminosity of Log{sub 10}(L {sub 4.5}/L {sub ☉}) = 11 ∼ 11.5. Their L {sub 4.5}/L {sub FIR} ratios are very similar to those of starburst-dominated SMGs at z ∼ 2. The L {sub CO} – L {sub FIR} relation for this sample is consistent with that determined for local ULIRGs and SMGs at z ∼ 2. We conclude that SMGs at z > 4 are hotter and more luminous in the FIR but otherwise very similar to those at z ∼ 2. None of these sources show any sign of the strong QSO phase being triggered.

  17. Simulation framework for spatio-spectral anomalous change detection

    SciTech Connect (OSTI)

    Theiler, James P; Harvey, Neal R; Porter, Reid B; Wohlberg, Brendt E

    2009-01-01

    The authors describe the development of a simulation framework for anomalous change detection that considers both the spatial and spectral aspects of the imagery. A purely spectral framework has previously been introduced, but the extension to spatio-spectral requires attention to a variety of new issues, and requires more careful modeling of the anomalous changes. Using this extended framework, they evaluate the utility of spatial image processing operators to enhance change detection sensitivity in (simulated) remote sensing imagery.

  18. Line Focus Receiver Infrared Temperature Survey System

    Energy Science and Technology Software Center (OSTI)

    2010-06-01

    For ongoing maintenance and performance purposes, solar parabolic trough field operators desire to know that the Heat Collection Elements (HCEs) are performing properly. Measuring their temperature is one way of doing this One 30MW field can contain approximately 10,000 HCE's. This software interfaces with a GPS receiver and an infrared camera. It takes global positioning data from the GPS and uses this information to automate the infrared image capture and temperature analysis of individual solarmore » parabolic HCEs in a solar parabolic trough field With this software system an entire 30MW field can be surveyed in 2-3 days.« less

  19. Thermal tuning of infrared resonant absorbers based on hybrid gold-VO{sub 2} nanostructures

    SciTech Connect (OSTI)

    Kocer, Hasan; Butun, Serkan; Aydin, Koray; Banar, Berker; Wang, Kevin; Wu, Junqiao; Tongay, Sefaatttin

    2015-04-20

    Resonant absorbers based on plasmonic materials, metamaterials, and thin films enable spectrally selective absorption filters, where absorption is maximized at the resonance wavelength. By controlling the geometrical parameters of nano/microstructures and materials' refractive indices, resonant absorbers are designed to operate at wide range of wavelengths for applications including absorption filters, thermal emitters, thermophotovoltaic devices, and sensors. However, once resonant absorbers are fabricated, it is rather challenging to control and tune the spectral absorption response. Here, we propose and demonstrate thermally tunable infrared resonant absorbers using hybrid gold-vanadium dioxide (VO{sub 2}) nanostructure arrays. Absorption intensity is tuned from 90% to 20% and 96% to 32% using hybrid gold-VO{sub 2} nanowire and nanodisc arrays, respectively, by heating up the absorbers above the phase transition temperature of VO{sub 2} (68 °C). Phase change materials such as VO{sub 2} deliver useful means of altering optical properties as a function of temperature. Absorbers with tunable spectral response can find applications in sensor and detector applications, in which external stimulus such as heat, electrical signal, or light results in a change in the absorption spectrum and intensity.

  20. Fully automated dual-frequency three-pulse-echo 2DIR spectrometer accessing spectral range from 800 to 4000 wavenumbers

    SciTech Connect (OSTI)

    Leger, Joel D.; Nyby, Clara M.; Varner, Clyde; Tang, Jianan; Rubtsova, Natalia I.; Yue, Yuankai; Kireev, Victor V.; Burtsev, Viacheslav D.; Qasim, Layla N.; Rubtsov, Igor V.; Rubtsov, Grigory I.

    2014-08-15

    A novel dual-frequency two-dimensional infrared instrument is designed and built that permits three-pulse heterodyned echo measurements of any cross-peak within a spectral range from 800 to 4000 cm{sup −1} to be performed in a fully automated fashion. The superior sensitivity of the instrument is achieved by a combination of spectral interferometry, phase cycling, and closed-loop phase stabilization accurate to ∼70 as. The anharmonicity of smaller than 10{sup −4} cm{sup −1} was recorded for strong carbonyl stretching modes using 800 laser shot accumulations. The novel design of the phase stabilization scheme permits tuning polarizations of the mid-infrared (m-IR) pulses, thus supporting measurements of the angles between vibrational transition dipoles. The automatic frequency tuning is achieved by implementing beam direction stabilization schemes for each m-IR beam, providing better than 50 μrad beam stability, and novel scheme for setting the phase-matching geometry for the m-IR beams at the sample. The errors in the cross-peak amplitudes associated with imperfect phase matching conditions and alignment are found to be at the level of 20%. The instrument can be used by non-specialists in ultrafast spectroscopy.

  1. Spectral and morphological analysis of the remnant of supernova 1987A with ALMA and ATCA

    SciTech Connect (OSTI)

    Zanardo, Giovanna; Staveley-Smith, Lister [International Centre for Radio Astronomy Research (ICRAR), M468, University of Western Australia, Crawley, WA 6009 (Australia); Indebetouw, Remy; Chevalier, Roger A. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Matsuura, Mikako; Barlow, Michael J. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Gaensler, Bryan M. [Australian Research Council, Centre of Excellence for All-sky Astrophysics (CAASTRO) (Australia); Fransson, Claes; Lundqvist, Peter [Department of Astronomy, Oskar Klein Center, Stockholm University, AlbaNova, SE-106 91 Stockholm (Sweden); Manchester, Richard N. [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia); Baes, Maarten [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281 S9, B-9000 Gent (Belgium); Kamenetzky, Julia R. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721-0065 (United States); Laki?evi?, Maa [Institute for the Environment, Physical Sciences and Applied Mathematics, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom); Marcaide, Jon M. [Departamento de Astronoma, Universidad de Valencia, C/Dr. Moliner 50, E-46100 Burjassot (Spain); Mart-Vidal, Ivan [Department of Earth and Space Sciences, Chalmers University of Technology, Onsala Space Observatory, SE-439 92 Onsala (Sweden); Meixner, Margaret [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Ng, C.-Y. [Department of Physics, University of Hong Kong, Pokfulam Road, Hong Kong (China); Park, Sangwook, E-mail: giovanna.zanardo@gmail.com [Department of Physics, University of Texas at Arlington, 108 Science Hall, Box 19059, Arlington, TX 76019 (United States); and others

    2014-12-01

    We present a comprehensive spectral and morphological analysis of the remnant of supernova (SN) 1987A with the Australia Telescope Compact Array (ATCA) and the Atacama Large Millimeter/submillimeter Array (ALMA). The non-thermal and thermal components of the radio emission are investigated in images from 94 to 672 GHz (? 3.2 mm to 450 ?m), with the assistance of a high-resolution 44 GHz synchrotron template from the ATCA, and a dust template from ALMA observations at 672 GHz. An analysis of the emission distribution over the equatorial ring in images from 44 to 345 GHz highlights a gradual decrease of the east-to-west asymmetry ratio with frequency. We attribute this to the shorter synchrotron lifetime at high frequencies. Across the transition from radio to far infrared, both the synchrotron/dust-subtracted images and the spectral energy distribution (SED) suggest additional emission beside the main synchrotron component (S {sub ?}??{sup 0.73}) and the thermal component originating from dust grains at T ? 22 K. This excess could be due to free-free flux or emission from grains of colder dust. However, a second flat-spectrum synchrotron component appears to better fit the SED, implying that the emission could be attributed to a pulsar wind nebula (PWN). The residual emission is mainly localized west of the SN site, as the spectral analysis yields 0.4 ? ? ? 0.1 across the western regions, with ? ? 0 around the central region. If there is a PWN in the remnant interior, these data suggest that the pulsar may be offset westward from the SN position.

  2. Solar spectral irradiance changes during cycle 24 (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Title: Solar spectral irradiance changes during cycle 24 We use solar spectra obtained by the Ozone Monitoring Instrument (OMI) on board the Aura satellite to detect and follow ...

  3. ARM: Ka ARM Zenith Radar (KAZR): filtered spectral data, high...

    Office of Scientific and Technical Information (OSTI)

    Ka ARM Zenith Radar (KAZR): filtered spectral data, high sensitivity mode, co-polarized mode Authors: Dan Nelson ; Joseph Hardin ; Iosif 1 ; Bradley Isom ; Karen Johnson ; Nitin ...

  4. Solar spectral optical properties of pigments--Part I: model...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Solar spectral optical properties of ... Resource Type: Journal Article Resource Relation: Journal Name: Solar Energy Materials and ...

  5. SPECTRAL CLASSIFICATION OF THE BRIGHTEST OBJECTS IN THE GALACTIC STAR-FORMING REGION W40

    SciTech Connect (OSTI)

    Shuping, R. Y.; Vacca, William D.; Kassis, Marc; Yu, Ka Chun

    2012-10-01

    We present high signal-to-noise, moderate resolution (R Almost-Equal-To 2000) near-infrared spectra, as well as 10 {mu}m imaging, for the brightest members of the central stellar cluster in the W40 H II region, obtained using the SpeX and MIRSI instruments at NASA's Infrared Telescope Facility. Using these observations combined with archival Spitzer Space Telescope data, we have determined the spectral classifications, extinction, distances, and spectral energy distributions (SEDs) for the brightest members of the cluster. Of the eight objects observed, we identify four main-sequence (MS) OB stars (one late-O, three early-B), two Herbig Ae/Be stars, and two low-mass young stellar objects (Class II). Strong He I absorption at 1.083 {mu}m in the MS star spectra strongly suggests that at least some of these sources are in fact close binaries. Two out of the four MS stars also show significant infrared excesses typical of circumstellar disks. Extinctions and distances were determined for each MS star by fitting model stellar atmospheres to the SEDs. We estimate a distance to the cluster of between 455 and 535 pc, which agrees well with earlier (but far less precise) distance estimates. We conclude that the late-O star we identify is the dominant source of Lyman continuum luminosity needed to power the W40 H II region and is the likely source of the stellar wind that has blown a large ( Almost-Equal-To 4 pc) pinched-waist bubble observed in wide-field mid-IR images. We also suggest that 3.6 cm radio emission observed from some of the sources in the cluster is likely not due to emission from ultracompact H II regions, as suggested in other work, due to size constraints based on our derived distance to the cluster. Finally, we also present a discussion of the curious source IRS 3A, which has a very strong mid-IR excess (despite its B3 MS classification) and appears to be embedded in a dusty envelope roughly 2700 AU in size.

  6. Activities of the CLIO infrared facility

    SciTech Connect (OSTI)

    Ortega, J.M.; Berset, J.M.; Chaput, R.

    1995-12-31

    The CLIO infrared FEL is operated since 1992. It is based on a 3 GHz RF linac. The laser beam time was about 2400 h in 1994, 1600 for users and 800 for FEL physics and machine optimisation. The beam time is limited mainly by user ability to work during nights.

  7. Transmissive infrared frequency selective surfaces and infrared antennas : final report for LDRD 105749.

    SciTech Connect (OSTI)

    Wendt, Joel Robert; Hadley, G. Ronald; Samora, Sally; Loui, Hung; Cruz-Cabrera, Alvaro Augusto; Davids, Paul; Kemme, Shanalyn A.; Basilio, Lorena I.; Johnson, William Arthur; Peters, David William

    2009-09-01

    Plasmonic structures open up new opportunities in photonic devices, sometimes offering an alternate method to perform a function and sometimes offering capabilities not possible with standard optics. In this LDRD we successfully demonstrated metal coatings on optical surfaces that do not adversely affect the transmission of those surfaces at the design frequency. This technology could be applied as an RF noise blocking layer across an optical aperture or as a method to apply an electric field to an active electro-optic device without affecting optical performance. We also demonstrated thin optical absorbers using similar patterned surfaces. These infrared optical antennas show promise as a method to improve performance in mercury cadmium telluride detectors. Furthermore, these structures could be coupled with other components to lead to direct rectification of infrared radiation. This possibility leads to a new method for infrared detection and energy harvesting of infrared radiation.

  8. Radiometric characterization of a high temperature blackbody in the visible and near infrared

    SciTech Connect (OSTI)

    Taubert, R. D.; Hollandt, J.

    2013-09-11

    At the Physikalisch-Technische Bundesanstalt the radiance temperature in the range from 962 C to 3000 C is disseminated by applying a high temperature blackbody (HTBB) with a directly heated pyrolytic graphite cavity. The thermodynamic radiance temperature of the HTBB was measured in the temperature range from 1000 C to 3000 C by applying almost simultaneously absolutely calibrated silicon photodiode based filter radiometers with centre wavelengths at 476 nm, 676 nm, 800 nm, 900 nm and 1000 nm and InGaAs photodiode based filter radiometers with centre wavelengths at 1300 nm, 1550 nm and 1595 nm. The results demonstrate that, expressed in terms of irradiance, within an uncertainty of 0.1 % (k=1) in a broad wavelength range the thermodynamic radiance temperature of the HTBB is wavelength independent in the investigated temperature interval.

  9. FIRE SPECTROSCOPY OF FIVE LATE-TYPE T DWARFS DISCOVERED WITH THE WIDE-FIELD INFRARED SURVEY EXPLORER

    SciTech Connect (OSTI)

    Burgasser, Adam J.; Cushing, Michael C.; Mainzer, A.; Bauer, James M.; Kirkpatrick, J. Davy; Gelino, Christopher R.; Griffith, Roger L.; Marsh, Kenneth A.; Looper, Dagny L.; Tinney, Christopher; Simcoe, Robert A.; Bochanski, John J.; Skrutskie, Michael F.; Thompson, Maggie A.; Wright, Edward L.

    2011-07-10

    We present the discovery of five late-type T dwarfs identified with the Wide-field Infrared Survey Explorer (WISE). Low-resolution near-infrared spectroscopy obtained with the Magellan Folded-port InfraRed Echellette reveal strong H{sub 2}O and CH{sub 4} absorption in all five sources, and spectral indices and comparison to spectral templates indicate classifications ranging from T5.5 to T8.5:. The spectrum of the latest-type source, WISE J1812+2721, is an excellent match to that of the T8.5 companion brown dwarf Wolf 940B. WISE-based spectrophotometric distance estimates place these T dwarfs at 12-13 pc from the Sun, assuming they are single. Preliminary fits of the spectral data to the atmosphere models of Saumon and Marley indicate effective temperatures ranging from 600 K to 930 K, both cloudy and cloud-free atmospheres, and a broad range of ages and masses. In particular, two sources show evidence of both low surface gravity and cloudy atmospheres, tentatively supporting a trend noted in other young brown dwarfs and exoplanets. In contrast, the high proper motion T dwarf WISE J2018-7423 exhibits a suppressed K-band peak and blue spectrophotometric J - K colors indicative of an old, massive brown dwarf; however, it lacks the broadened Y-band peak seen in metal-poor counterparts. These results illustrate the broad diversity of low-temperature brown dwarfs that will be uncovered with WISE.

  10. Effects of Cosmic Infrared Background on High Energy Delayed...

    Office of Scientific and Technical Information (OSTI)

    Effects of Cosmic Infrared Background on High Energy Delayed Gamma-Rays From Gamma-Ray Bursts Citation Details In-Document Search Title: Effects of Cosmic Infrared Background on...

  11. Investigation into Spectral Parameters as they Impact CPV Module Performance

    SciTech Connect (OSTI)

    Muller, M.; Marion, B.; Kurtz, S.; Rodriguez, J.

    2011-03-01

    The CPV industry is well aware that performance of triple junction cells depends on spectral conditions but there is a lack of data quantifying this spectral dependence at the module level. This paper explores the impact of precipitable water vapor, aerosol optical depth (AOD), and optical air mass on multiple CPV module technologies on-sun in Golden, CO.

  12. Propagation of spectral functions and dilepton production at SIS energies

    SciTech Connect (OSTI)

    Wolf, Gy.; Kaempfer, B.; Zetenyi, M.

    2012-06-15

    The time evolution of vector meson spectral functions is studied within a BUU-type transport model. Applications focus on {rho} and {omega} mesons being important pieces for the interpretation of the dielectron invariant mass spectrum. Since the evolution of the spectral functions is driven by the local density, the inmedium modifications turn out to compete, in this approach, with the known vacuum contributions.

  13. Discriminating trpzip2 and trpzip4 peptides folding landscape using the two-dimensional infrared spectroscopy: A simulation study

    SciTech Connect (OSTI)

    Wu, Tianmin; Zhang, Ruiting; Li, Huanhuan; Zhuang, Wei, E-mail: wzhuang@dicp.ac.cn, E-mail: lijiangy@pku.edu.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning (China); Yang, Lijiang, E-mail: wzhuang@dicp.ac.cn, E-mail: lijiangy@pku.edu.cn [College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871 (China)] [College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871 (China)

    2014-02-07

    We analyzed, based on the theoretical spectroscopic modeling, how the differences in the folding landscapes of two ?-hairpin peptides trpzip2 and trpzip4 are reflected in their thermal unfolding infrared measurements. The isotope-edited equilibrium FTIR and two dimensional infrared spectra of the two peptides were calculated, using the nonlinear exciton propagation method, at a series of temperatures. The spectra calculations were based on the configuration distributions generated using the GB{sup OBC} implicit solvent MD simulation and the integrated tempering sampling technique. Conformational analysis revealed the different local thermal stabilities for these two peptides, which suggested the different folding landscapes. Our study further suggested that the ellipticities of the isotope peaks in the coherent IR signals are more sensitive to these local stability differences compared with other spectral features such as the peak intensities. Our technique can thus be combined with the relevant experimental measurements to achieve a better understanding of the peptide folding behaviors.

  14. Rapid infrared joining takes on the advanced materials

    SciTech Connect (OSTI)

    Blue, C.A.; Warrier, S.G.; Robson, M.T.; Lin, R.Y. . Dept. of Materials Science and Engineering)

    1993-06-01

    Applying the rapid infrared joining technique, the authors have successfully joined steels, Inconel[sup [reg sign

  15. Quantitative Analysis of Spectral Impacts on Silicon Photodiode Radiometers

    SciTech Connect (OSTI)

    Myers, D. R.

    2011-01-01

    Inexpensive broadband pyranometers with silicon photodiode detectors have a non-uniform spectral response over the spectral range of 300-1100 nm. The response region includes only about 70% to 75% of the total energy in the terrestrial solar spectral distribution from 300 nm to 4000 nm. The solar spectrum constantly changes with solar position and atmospheric conditions. Relative spectral distributions of diffuse hemispherical irradiance sky radiation and total global hemispherical irradiance are drastically different. This analysis convolves a typical photodiode response with SMARTS 2.9.5 spectral model spectra for different sites and atmospheric conditions. Differences in solar component spectra lead to differences on the order of 2% in global hemispherical and 5% or more in diffuse hemispherical irradiances from silicon radiometers. The result is that errors of more than 7% can occur in the computation of direct normal irradiance from global hemispherical irradiance and diffuse hemispherical irradiance using these radiometers.

  16. Quantitative Analysis of Spectral Impacts on Silicon Photodiode Radiometers: Preprint

    SciTech Connect (OSTI)

    Myers, D. R.

    2011-04-01

    Inexpensive broadband pyranometers with silicon photodiode detectors have a non-uniform spectral response over the spectral range of 300-1100 nm. The response region includes only about 70% to 75% of the total energy in the terrestrial solar spectral distribution from 300 nm to 4000 nm. The solar spectrum constantly changes with solar position and atmospheric conditions. Relative spectral distributions of diffuse hemispherical irradiance sky radiation and total global hemispherical irradiance are drastically different. This analysis convolves a typical photodiode response with SMARTS 2.9.5 spectral model spectra for different sites and atmospheric conditions. Differences in solar component spectra lead to differences on the order of 2% in global hemispherical and 5% or more in diffuse hemispherical irradiances from silicon radiometers. The result is that errors of more than 7% can occur in the computation of direct normal irradiance from global hemispherical irradiance and diffuse hemispherical irradiance using these radiometers.

  17. Multitemporal spectral analysis for cheatgrass (Bromus tectorum) classification.

    SciTech Connect (OSTI)

    Singh, Nagendra; Glenn, Nancy F

    2009-07-01

    Operational satellite remote sensing data can provide the temporal repeatability necessary to capture phenological differences among species. This study develops a multitemporal stacking method coupled with spectral analysis for extracting information from Landsat imagery to provide species-level information. Temporal stacking can, in an approximate mathematical sense, effectively increase the 'spectral' resolution of the system by adding spectral bands of several multitemporal images. As a demonstration, multitemporal linear spectral unmixing is used to successfully delineate cheatgrass (Bromus tectorum) from soil and surrounding vegetation (77% overall accuracy). This invasive plant is an ideal target for exploring multitemporal methods because of its phenological differences with other vegetation in early spring and, to a lesser degree, in late summer. The techniques developed in this work are directly applicable for other targets with temporally unique spectral differences.

  18. Spatio-spectral image analysis using classical and neural algorithms

    SciTech Connect (OSTI)

    Roberts, S.; Gisler, G.R.; Theiler, J.

    1996-12-31

    Remote imaging at high spatial resolution has a number of environmental, industrial, and military applications. Analysis of high-resolution multi-spectral images usually involves either spectral analysis of single pixels in a multi- or hyper-spectral image or spatial analysis of multi-pixels in a panchromatic or monochromatic image. Although insufficient for some pattern recognition applications individually, the combination of spatial and spectral analytical techniques may allow the identification of more complex signatures that might not otherwise be manifested in the individual spatial or spectral domains. We report on some preliminary investigation of unsupervised classification methodologies (using both ``classical`` and ``neural`` algorithms) to identify potentially revealing features in these images. We apply dimension-reduction preprocessing to the images, duster, and compare the clusterings obtained by different algorithms. Our classification results are analyzed both visually and with a suite of objective, quantitative measures.

  19. The {ital COBE} Diffuse Infrared Background Experiment Search for the Cosmic Infrared Background. I. Limits and Detections

    SciTech Connect (OSTI)

    Hauser, M.G.; Arendt, R.G.; Kelsall, T.; Dwek, E.; Odegard, N.; Weiland, J.L.; Freudenreich, H.T.; Reach, W.T.; Pei, Y.C.; Lubin, P.; Mather, J.C.; Shafer, R.A.; Smoot, G.F.; Weiss, R.; Wilkinson, D.T.; Wright, E.L.

    1998-11-01

    The Diffuse Infrared Background Experiment (DIRBE) on the Cosmic Background Explorer ({ital COBE}) spacecraft was designed primarily to conduct a systematic search for an isotropic cosmic infrared background (CIB) in 10 photometric bands from 1.25 to 240 {mu}m. The results of that search are presented here. Conservative limits on the CIB are obtained from the minimum observed brightness in all-sky maps at each wavelength, with the faintest limits in the DIRBE spectral range being at 3.5 {mu}m ({nu}{ital I}{sub {nu}} {lt} 64 nW m{sup {minus}2} sr{sup {minus}1}, 95{percent} confidence level) and at 240 {mu}m ({nu}{ital I}{sub {nu}} {lt} 28 nW m{sup {minus}2} sr{sup {minus}1}, 95{percent} confidence level). The bright foregrounds from interplanetary dust scattering and emission, stars, and interstellar dust emission are the principal impediments to the DIRBE measurements of the CIB. These foregrounds have been modeled and removed from the sky maps. Assessment of the random and systematic uncertainties in the residuals and tests for isotropy show that only the 140 and 240 {mu}m data provide candidate detections of the CIB. The residuals and their uncertainties provide CIB upper limits more restrictive than the dark sky limits at wavelengths from 1.25 to 100 {mu}m. No plausible solar system or Galactic source of the observed 140 and 240 {mu}m residuals can be identified, leading to the conclusion that the CIB has been detected at levels of {nu}{ital I}{sub {nu}} = 25 {plus_minus} 7 and 14 {plus_minus} 3 nW m{sup {minus}2} sr{sup {minus}1} at 140 and 240 {mu}m, respectively. The integrated energy from 140 to 240 {mu}m, 10.3 nW m{sup {minus}2} sr{sup {minus}1}, is about twice the integrated optical light from the galaxies in the Hubble Deep Field, suggesting that star formation might have been heavily enshrouded by dust at high redshift. The detections and upper limits reported here provide new constraints on models of the history of energy-releasing processes and dust

  20. Results of First Outdoor Comparison Between Absolute Cavity Pyrgeometer (ACP) and Infrared Integrating Sphere (IRIS) Radiometer at PMOD (Presentation)

    SciTech Connect (OSTI)

    Reda, I.; Grobner, J.; Wacker, S.; Stoffel, T.

    2013-03-01

    The ACP and IRIS are developed to establish a world reference for calibrating pyrgeometers with traceability to SI units. The two radiometers are unwindowed with negligible spectral dependence, and traceable to SI units through the temperature scale (ITS-90). The first outdoor comparison between the two designs was held from January 28 to February 8, 2013 at the Physikalisch-Metorologisches Observatorium Davos (PMOD). The difference between the irradiance measured by ACP and that of IRIS was within 1 W/m2. A difference of 5 W/m2 was observed between the irradiance measured by ACP&IRIS and that of the interim World Infrared Standard Group (WISG).

  1. G-Plus Report to Judel Products: Spectral Analysis and Imaging of Colored Glasses

    SciTech Connect (OSTI)

    Wang, H

    2005-06-20

    Redox state is one of the most important factors that affect color of glasses. Recently, optical properties and redox state of the glass melts have been studied at TNO by A.J. Faber [1]. Spectral measurements up to 4 {micro}m into the infrared region were taken. The focus of similar studies [2] was on the redox state of iron. In glassware production, the control of color is mainly dependent upon the experience of the operators. When the color varies due to changes in processing conditions, batching or furnace contamination, usually little can be done but to scrap the entire batch. This can result in significant down time and waste of energy to melt and refine the glass. For small glass companies, detecting out-of-specification color variation early in the melting process means savings on labor and energy costs. In larger color glass operations, early detection may provide means to correct or save the batch. Monitoring the redox state of the glass melt can be used to effectively control the quality of glass products. An in-line redox sensor has been tested in industrial environment [3]. Thermal emission spectroscopy is a non-contact, real-time sensing technique. The collection of a spectrum takes only a few seconds or less. This may allow on-line analysis of the glass melt or hot glass products. For a specific glass product, a series of spectra with different processing parameters could be collected and analyzed. The sensing system would be able to detect a deviation from the normal conditions and signal the operator a change has occurred. The primary goal of this GPLUS effort is to find a practical solution for color monitoring. In this project, we proposed to conduct initial experiments of spectral characterization of colored glasses from the designated glass industry members of the Society for Glass Science and Practices. The work plan contained three stages: (1) Obtain glass samples and use spectroscopy analysis at ORNL to measure basic spectral characteristics

  2. The near-infrared spectrum of ethynyl radical

    DOE PAGES-Beta [OSTI]

    Le, Anh T.; Hall, Gregory E.; Sears, Trevor J.

    2016-08-17

    We used transient diode laser absorption spectroscopy to measure three strong vibronic bands in the near infrared spectrum of the C2H, ethynyl, radical not previously observed in the gas phase. The radical was produced by ultraviolet excimer laser photolysis of either acetylene or (1,1,1)-trifluoropropyne in a slowly flowing sample of the precursor diluted in inert gas, and the spectral resolution was Doppler-limited. The character of the upper states was determined from the rotational and fine structure in the observed spectra and assigned by measurement of ground state rotational combination differences. The upper states include a 2Σ+ state at 6696 cm-1,more » a second 2Σ+ state at 7088 cm-1, and a 2Π state at 7110 cm-1. By comparison with published calculations [R. Tarroni and S. Carter, J. Chem. Phys 119, 12878 (2003); Mol. Phys. 102, 2167 (2004)], the vibronic character of these levels was also assigned. Moreover, the observed states contain both X 2Σ+ and A 2Π electronic characters. Several local rotational level perturbations were observed in the excited states. Kinetic measurements of the time-evolution of the ground state populations following collisional relaxation and reactive loss of the radicals formed in a hot, non-thermal, population distribution were made using some of the strong rotational lines observed. Finally, the case of C2H may be a good place to investigate the behavior at intermediate pressures of inert colliders, where the competition between relaxation and reaction can be tuned and observed to compare with master equation models, rather than deliberately suppressed to measure thermal rate constants.« less

  3. Spectral ellipsometry of a nanodiamond composite

    SciTech Connect (OSTI)

    Yastrebov, S. G. Gordeev, S. K.; Garriga, M.; Alonso, I. A.; Ivanov-Omskii, V. I.

    2006-07-15

    Optical properties of a nanodiamond composite were analyzed by methods of spectral ellipsometry in the range of photon energies 1.4-5 eV, which are characteristic of {pi}-{pi}* transitions in amorphous carbon. The nanocomposite was synthesized by molding nanodiamond powder with subsequent binding of diamond nanoparticles by pyrocarbon formed as a result of the heterogeneous chemical reaction of methane decomposition. The dispersion curves of the imaginary and real parts of the dielectric function were reconstructed. It is shown that the imaginary part of the dielectric function can be represented as the sum of two components generated by the two types of {pi}-{pi}* optical transitions. The maximum contribution of the transitions of the first and second types manifests itself at energies of 2.6 and 5.6 eV, respectively, which correspond to peaks in optical density at 2.9 and 6.11 eV. It was established that the main specific features of the normalized optical density of the nanodiamond composite almost coincide with those for poly(para-phenylenevinylene). It was found that the energy of a {sigma} + {pi} plasmon of the pyrocarbon component of the nanodiamond composite is 24.2 eV. On the basis on this value, the pyrocarbon density matrix was estimated to be 2 g/cm{sup 3}. Within the concepts of optimum filling of an elementary volume by carbon atoms in an amorphous material with such a density, the allotropic composition of the pyrocarbon matrix was restored.

  4. Research Highlight

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Trends in Downwelling Longwave Radiation over SGP Download a printable PDF Submitter: Gero, J., University of Wisconsin Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Gero P and DD Turner. 2011. "Long-term trends in downwelling spectral infrared radiance over the U.S. Southern Great Plains." Journal of Climate, 24(18),

  5. THE INFRARED COLORS OF THE SUN

    SciTech Connect (OSTI)

    Casagrande, L.; Asplund, M.; Ramirez, I.; Melendez, J.

    2012-12-10

    Solar infrared colors provide powerful constraints on the stellar effective temperature scale, but they must be measured with both accuracy and precision in order to do so. We fulfill this requirement by using line-depth ratios to derive in a model-independent way the infrared colors of the Sun, and we use the latter to test the zero point of the Casagrande et al. effective temperature scale, confirming its accuracy. Solar colors in the widely used Two Micron All Sky Survey (2MASS) JHK{sub s} and WISE W1-4 systems are provided: (V - J){sub Sun} = 1.198, (V - H){sub Sun} = 1.484, (V - K{sub s} ){sub Sun} = 1.560, (J - H){sub Sun} = 0.286, (J - K{sub s} ){sub Sun} = 0.362, (H - K{sub s} ){sub Sun} = 0.076, (V - W1){sub Sun} = 1.608, (V - W2){sub Sun} = 1.563, (V - W3){sub Sun} = 1.552, and (V - W4){sub Sun} = 1.604. A cross-check of the effective temperatures derived implementing 2MASS or WISE magnitudes in the infrared flux method confirms that the absolute calibration of the two systems agrees within the errors, possibly suggesting a 1% offset between the two, thus validating extant near- and mid-infrared absolute calibrations. While 2MASS magnitudes are usually well suited to derive T{sub eff}, we find that a number of bright, solar-like stars exhibit anomalous WISE colors. In most cases, this effect is spurious and can be attributed to lower-quality measurements, although for a couple of objects (3% {+-} 2% of the total sample) it might be real, and may hint at the presence of warm/hot debris disks.

  6. Probing Organic Transistors with Infrared Beams

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  7. Infrared Sky Imager (IRSI) Instrument Handbook

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    2 Infrared Sky Imager Instrument Handbook VR Morris April 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights.

  8. Probing Organic Transistors with Infrared Beams

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  9. Probing Organic Transistors with Infrared Beams

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However,

  10. FY2008 Calibration Systems Final Report

    SciTech Connect (OSTI)

    Cannon, Bret D.; Myers, Tanya L.; Broocks, Bryan T.

    2009-01-01

    The Calibrations project has been exploring alternative technologies for calibration of passive sensors in the infrared (IR) spectral region. In particular, we have investigated using quantum cascade lasers (QCLs) because these devices offer several advantages over conventional blackbodies such as reductions in size and weight while providing a spectral source in the IR with high output power. These devices can provide a rapid, multi-level radiance scheme to fit any nonlinear behavior as well as a spectral calibration that includes the fore-optics, which is currently not available for on-board calibration systems.

  11. AMIP Simulation with the CAM4 Spectral Element Dynamical Core

    SciTech Connect (OSTI)

    Evans, Katherine J; Lauritzen, Peter; Mishra, Saroj; Neale, Rich; Taylor, Mark; Tribbia, Joe

    2013-01-01

    We evaluate the climate produced by the Community Earth System Model, version 1, running with the new spectral-element atmospheric dynamical core option. The spectral-element method is congured to use a cubed-sphere grid, providing quasi-uniform resolution over the sphere, increased parallel scalability and removing the need for polar filters. It uses a fourth order accurate spatial discretization which locally conserves mass and moist total energy. Using the Atmosphere Model Intercomparison Project protocol, we compare the results from the spectral-element dy- namical core with those produced by the default nite-volume dynamical core and with observations.

  12. Indoor and Outdoor Spectroradiometer Intercomparison for Spectral Irradiance Measurement

    SciTech Connect (OSTI)

    Habte, A.; Andreas, A.; Ottoson, L.; Gueymard, C.; Fedor, G.; Fowler, S.; Peterson, J.; Naranen, R.; Kobashi, T.; Akiyama, A.; Takagi, S.

    2014-05-01

    This report details the global spectral irradiance intercomparison using spectroradiometers that was organized by the National Renewable Energy Laboratory's Solar Radiation Research Laboratory. The intercomparison was performed both indoors and outdoors on September 17, 2013. Five laboratories participated in the intercomparison using 10 spectroradiometers, and a coordinated measurement setup and a common platform were employed to compare spectral irradiances under both indoor and outdoor conditions. The intercomparison aimed to understand the performance of the different spectroradiometers and to share knowledge in making spectral irradiance measurements. This intercomparison was the first of its kind in the United States.

  13. Optical Strong Coupling between near-Infrared Metamaterials and Intersubband Transitions in III-Nitride Heterostructures

    SciTech Connect (OSTI)

    Benz, Alexander; Campione, Salvatore; Moseley, Michael W.; Wierer, Jonathan J.; Allerman, Andrew A.; Wendt, Joel R.; Brener, Igal

    2014-08-25

    We present the design, realization, and characterization of optical strong light–matter coupling between intersubband transitions within a semiconductor heterostructures and planar metamaterials in the near-infrared spectral range. The strong light–matter coupling entity consists of a III-nitride intersubband superlattice heterostructure, providing a two-level system with a transition energy of ~0.8 eV (λ ~1.55 μm) and a planar “dogbone” metamaterial structure. Furthermore, as the bare metamaterial resonance frequency is varied across the intersubband resonance, a clear anticrossing behavior is observed in the frequency domain. We found that this strongly coupled entity could enable the realization of electrically tunable optical filters, a new class of efficient nonlinear optical materials, or intersubband-based light-emitting diodes.

  14. Optical Strong Coupling between near-Infrared Metamaterials and Intersubband Transitions in III-Nitride Heterostructures

    DOE PAGES-Beta [OSTI]

    Benz, Alexander; Campione, Salvatore; Moseley, Michael W.; Wierer, Jonathan J.; Allerman, Andrew A.; Wendt, Joel R.; Brener, Igal

    2014-08-25

    We present the design, realization, and characterization of optical strong light–matter coupling between intersubband transitions within a semiconductor heterostructures and planar metamaterials in the near-infrared spectral range. The strong light–matter coupling entity consists of a III-nitride intersubband superlattice heterostructure, providing a two-level system with a transition energy of ~0.8 eV (λ ~1.55 μm) and a planar “dogbone” metamaterial structure. Furthermore, as the bare metamaterial resonance frequency is varied across the intersubband resonance, a clear anticrossing behavior is observed in the frequency domain. We found that this strongly coupled entity could enable the realization of electrically tunable optical filters, a newmore » class of efficient nonlinear optical materials, or intersubband-based light-emitting diodes.« less

  15. CdS/PbSe heterojunction for high temperature mid-infrared photovoltaic detector applications

    SciTech Connect (OSTI)

    Weng, Binbin E-mail: shi@ou.edu; Qiu, Jijun; Zhao, Lihua; Chang, Caleb; Shi, Zhisheng E-mail: shi@ou.edu

    2014-03-24

    n-CdS/p-PbSe heterojunction is investigated. A thin CdS film is deposited by chemical bath deposition on top of epitaxial PbSe film by molecular beam epitaxy on Silicon. Current-voltage measurements demonstrate very good junction characteristics with rectifying ratio of ∼178 and ideality factor of 1.79 at 300 K. Detectors made with such structure exhibit mid-infrared spectral photoresponse at room temperature. The peak responsivity R{sub λ} and specific detectivity D{sup *} are 0.055 A/W and 5.482 × 10{sup 8} cm·Hz{sup 1/2}/W at λ = 4.7 μm under zero-bias photovoltaic mode. Temperature-dependent photoresponse measurements show abnormal intensity variation below ∼200 K. Possible reasons for this phenomenon are also discussed.

  16. Areal-averaged and Spectrally-resolved Surface Albedo from Ground-based Transmission Data Alone: Toward an Operational Retrieval

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.; Riihimaki, Laura D.; Michalsky, Joseph; Hodges, G. B.

    2014-08-22

    We present here a simple retrieval of the areal-averaged and spectrally resolved surface albedo using only ground-based measurements of atmospheric transmission under fully overcast conditions. Our retrieval is based on a one-line equation and widely accepted assumptions regarding the weak spectral dependence of cloud optical properties in the visible and near-infrared spectral range. The feasibility of our approach for the routine determinations of albedo is demonstrated for different landscapes with various degrees of heterogeneity using three sets of measurements:(1) spectrally resolved atmospheric transmission from Multi-Filter Rotating Shadowband Radiometer (MFRSR) at wavelength 415, 500, 615, 673, and 870 nm, (2) tower-based measurements of local surface albedo at the same wavelengths, and (3) areal-averaged surface albedo at four wavelengths (470, 560, 670 and 860 nm) from collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) observations. These integrated datasets cover both long (2008-2013) and short (April-May, 2010) periods at the ARM Southern Great Plains (SGP) site and the NOAA Table Mountain site, respectively. The calculated root mean square error (RMSE), which is defined here as the root mean squared difference between the MODIS-derived surface albedo and the retrieved area-averaged albedo, is quite small (RMSE≤0.01) and comparable with that obtained previously by other investigators for the shortwave broadband albedo. Good agreement between the tower-based daily averages of surface albedo for the completely overcast and non-overcast conditions is also demonstrated. This agreement suggests that our retrieval originally developed for the overcast conditions likely will work for non-overcast conditions as well.

  17. Direct experimental determination of spectral densities of molecular complexes

    SciTech Connect (OSTI)

    Pachn, Leonardo A.; Brumer, Paul

    2014-11-07

    Determining the spectral density of a molecular system immersed in a proteomic scaffold and in contact to a solvent is a fundamental challenge in the coarse-grained description of, e.g., electron and energy transfer dynamics. Once the spectral density is characterized, all the time scales are captured and no artificial separation between fast and slow processes need to be invoked. Based on the fluorescence Stokes shift function, we utilize a simple and robust strategy to extract the spectral density of a number of molecular complexes from available experimental data. Specifically, we show that experimental data for dye molecules in several solvents, amino acid proteins in water, and some photochemical systems (e.g., rhodopsin and green fluorescence proteins), are well described by a three-parameter family of sub-Ohmic spectral densities that are characterized by a fast initial Gaussian-like decay followed by a slow algebraic-like decay rate at long times.

  18. Method and apparatus for measuring film spectral properties

    DOE Patents [OSTI]

    Forrest, Stephen R.; Burrows, Paul E.; Garbuzov, Dmitri Z.; Bulovic, Vladimir

    1999-12-21

    Film spectral properties are measured by projecting chopped monochromatic light onto a luminescent film sample deposited on a substrate, and coupling through use of immersion oil the reflection of light therefrom to a light detector.

  19. Breast tissue decomposition with spectral distortion correction: A postmortem study

    SciTech Connect (OSTI)

    Ding, Huanjun; Zhao, Bo; Baturin, Pavlo; Behroozi, Farnaz; Molloi, Sabee

    2014-10-15

    Purpose: To investigate the feasibility of an accurate measurement of water, lipid, and protein composition of breast tissue using a photon-counting spectral computed tomography (CT) with spectral distortion corrections. Methods: Thirty-eight postmortem breasts were imaged with a cadmium-zinc-telluride-based photon-counting spectral CT system at 100 kV. The energy-resolving capability of the photon-counting detector was used to separate photons into low and high energy bins with a splitting energy of 42 keV. The estimated mean glandular dose for each breast ranged from 1.8 to 2.2 mGy. Two spectral distortion correction techniques were implemented, respectively, on the raw images to correct the nonlinear detector response due to pulse pileup and charge-sharing artifacts. Dual energy decomposition was then used to characterize each breast in terms of water, lipid, and protein content. In the meantime, the breasts were chemically decomposed into their respective water, lipid, and protein components to provide a gold standard for comparison with dual energy decomposition results. Results: The accuracy of the tissue compositional measurement with spectral CT was determined by comparing to the reference standard from chemical analysis. The averaged root-mean-square error in percentage composition was reduced from 15.5% to 2.8% after spectral distortion corrections. Conclusions: The results indicate that spectral CT can be used to quantify the water, lipid, and protein content in breast tissue. The accuracy of the compositional analysis depends on the applied spectral distortion correction technique.

  20. Mass Correlation of Engine Emissions with Spectral Instruments | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Mass Correlation of Engine Emissions with Spectral Instruments Mass Correlation of Engine Emissions with Spectral Instruments 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of Minnesota, Cambustion UK 2004_deer_collings.pdf (417.32 KB) More Documents & Publications Nanoparticle Emissions from Internal Combustion Engines Chemical and Physical Characteristics of Diesel Aerosol Measurement of diesel solid nanoparticle emissions using a catalytic

  1. Spectral, mechanical, thermal, optical and solid state parameters, of

    Office of Scientific and Technical Information (OSTI)

    metal-organic bis(hydrogenmaleate)-CO(II) tetrahydrate crystal (Journal Article) | SciTech Connect Spectral, mechanical, thermal, optical and solid state parameters, of metal-organic bis(hydrogenmaleate)-CO(II) tetrahydrate crystal Citation Details In-Document Search Title: Spectral, mechanical, thermal, optical and solid state parameters, of metal-organic bis(hydrogenmaleate)-CO(II) tetrahydrate crystal Metal-organic bis(hydrogenmaleate)-Co(II) tetrahydrate single crystals have been grown

  2. Precision spectral manipulation: A demonstration using a coherent optical memory

    SciTech Connect (OSTI)

    Sparkes, B. M.; Cairns, C.; Hosseini, M.; Higginbottom, D.; Campbell, G. T.; Lam, P. K.; Buchler, B. C.

    2014-12-04

    The ability to coherently spectrally manipulate quantum information has the potential to improve qubit rates across quantum channels and find applications in optical quantum computing. Here we present experiments that use a multi-element solenoid combined with the three-level gradient echo memory scheme to perform precision spectral manipulation of optical pulses. If applied in a quantum information network, these operations would enable frequency-based multiplexing of qubits.

  3. Cloud properties derived from the High Spectral Resolution Lidar during

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    MPACE Cloud properties derived from the High Spectral Resolution Lidar during MPACE Eloranta, Edwin University of Wisconsin Category: Field Campaigns Cloud properties were derived from data acquired with University of Wisconsin High Spectral Resolution Lidar during its 6-week MPACE deployment. This poster presents statistics on: 1) the altitude and temperature distribution of optical depth and cloud phase. 2) the dependence of lidar depolarization and backscatter phase function on

  4. Methods for spectral image analysis by exploiting spatial simplicity

    DOE Patents [OSTI]

    Keenan, Michael R.

    2010-05-25

    Several full-spectrum imaging techniques have been introduced in recent years that promise to provide rapid and comprehensive chemical characterization of complex samples. One of the remaining obstacles to adopting these techniques for routine use is the difficulty of reducing the vast quantities of raw spectral data to meaningful chemical information. Multivariate factor analysis techniques, such as Principal Component Analysis and Alternating Least Squares-based Multivariate Curve Resolution, have proven effective for extracting the essential chemical information from high dimensional spectral image data sets into a limited number of components that describe the spectral characteristics and spatial distributions of the chemical species comprising the sample. There are many cases, however, in which those constraints are not effective and where alternative approaches may provide new analytical insights. For many cases of practical importance, imaged samples are "simple" in the sense that they consist of relatively discrete chemical phases. That is, at any given location, only one or a few of the chemical species comprising the entire sample have non-zero concentrations. The methods of spectral image analysis of the present invention exploit this simplicity in the spatial domain to make the resulting factor models more realistic. Therefore, more physically accurate and interpretable spectral and abundance components can be extracted from spectral images that have spatially simple structure.

  5. Methods for spectral image analysis by exploiting spatial simplicity

    DOE Patents [OSTI]

    Keenan, Michael R.

    2010-11-23

    Several full-spectrum imaging techniques have been introduced in recent years that promise to provide rapid and comprehensive chemical characterization of complex samples. One of the remaining obstacles to adopting these techniques for routine use is the difficulty of reducing the vast quantities of raw spectral data to meaningful chemical information. Multivariate factor analysis techniques, such as Principal Component Analysis and Alternating Least Squares-based Multivariate Curve Resolution, have proven effective for extracting the essential chemical information from high dimensional spectral image data sets into a limited number of components that describe the spectral characteristics and spatial distributions of the chemical species comprising the sample. There are many cases, however, in which those constraints are not effective and where alternative approaches may provide new analytical insights. For many cases of practical importance, imaged samples are "simple" in the sense that they consist of relatively discrete chemical phases. That is, at any given location, only one or a few of the chemical species comprising the entire sample have non-zero concentrations. The methods of spectral image analysis of the present invention exploit this simplicity in the spatial domain to make the resulting factor models more realistic. Therefore, more physically accurate and interpretable spectral and abundance components can be extracted from spectral images that have spatially simple structure.

  6. NGC 4102: HIGH-RESOLUTION INFRARED OBSERVATIONS OF A NUCLEAR STARBURST RING

    SciTech Connect (OSTI)

    Beck, Sara C.; Lacy, John H.; Turner, Jean L.

    2010-10-20

    The composite galaxy NGC 4102 hosts a LINER nucleus and a starburst. We mapped NGC 4102 in the 12.8 {mu}m line of [Ne II], using the echelon spectrometer TEXES on the NASA IRTF, to obtain a data cube with 1.''5 spatial, and 25 km s{sup -1} spectral, resolution. Combining near-infrared, radio, and the [Ne II] data shows that the extinction to the starburst is substantial, more than 2 mag at the K band, and that the neon abundance is less than half solar. We find that the star formation in the nuclear region is confined to a rotating ring or disk of 4.''3 ({approx}300 pc) diameter, inside the inner Lindblad resonance. This region is an intense concentration of mass, with a dynamical mass {approx}3 x 10{sup 9} M{sub sun}, and of star formation. The young stars in the ring produce the [Ne II] flux reported by Spitzer for the entire galaxy. The mysterious blue component of line emission detected in the near-infrared is also seen in [Ne II]; it is not a normal active galactic nucleus outflow.

  7. THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE WIDE-FIELD IMAGERS

    SciTech Connect (OSTI)

    Bock, J.; Battle, J.; Sullivan, I.; Arai, T.; Matsumoto, T.; Matsuura, S.; Tsumura, K.; Cooray, A.; Mitchell-Wynne, K.; Smidt, J.; Hristov, V.; Lam, A. C.; Levenson, L. R.; Mason, P.; Keating, B.; Renbarger, T.; Kim, M. G.; Lee, D. H.; Nam, U. W.; Suzuki, K.; and others

    2013-08-15

    We have developed and characterized an imaging instrument to measure the spatial properties of the diffuse near-infrared extragalactic background light (EBL) in a search for fluctuations from z > 6 galaxies during the epoch of reionization. The instrument is part of the Cosmic Infrared Background Experiment (CIBER), designed to observe the EBL above Earth's atmosphere during a suborbital sounding rocket flight. The imaging instrument incorporates a 2 Degree-Sign Multiplication-Sign 2 Degree-Sign field of view to measure fluctuations over the predicted peak of the spatial power spectrum at 10 arcmin, and 7'' Multiplication-Sign 7'' pixels, to remove lower redshift galaxies to a depth sufficient to reduce the low-redshift galaxy clustering foreground below instrumental sensitivity. The imaging instrument employs two cameras with {Delta}{lambda}/{lambda} {approx} 0.5 bandpasses centered at 1.1 {mu}m and 1.6 {mu}m to spectrally discriminate reionization extragalactic background fluctuations from local foreground fluctuations. CIBER operates at wavelengths where the electromagnetic spectrum of the reionization extragalactic background is thought to peak, and complements fluctuation measurements by AKARI and Spitzer at longer wavelengths. We have characterized the instrument in the laboratory, including measurements of the sensitivity, flat-field response, stray light performance, and noise properties. Several modifications were made to the instrument following a first flight in 2009 February. The instrument performed to specifications in three subsequent flights, and the scientific data are now being analyzed.

  8. Discovery of GeV emission from the direction of the luminous infrared galaxy NGC 2146

    SciTech Connect (OSTI)

    Tang, Qing-Wen; Wang, Xiang-Yu [School of Astronomy and Space Science, Nanjing University, Nanjing, 210093 (China); Thomas Tam, Pak-Hin, E-mail: xywang@nju.edu.cn, E-mail: phtam@phys.nthu.edu.tw [Institute of Astronomy and Department of Physics, National Tsing Hua University, Hsinchu 30013, Taiwan (China)

    2014-10-10

    Recent detections of high-energy gamma-ray emission from starburst galaxies M82 and NGC 253 suggest that starburst galaxies are huge reservoirs of cosmic rays and these cosmic rays convert a significant fraction of their energy into gamma-rays by colliding with the dense interstellar medium. In this paper, we report the search for high-energy gamma-ray emission from several nearby star-forming and starburst galaxies using the 68 month data obtained with the Fermi Large Area Telescope. We found a ?5.5? detection of gamma-ray emission above 200 MeV from a source spatially coincident with the location of the luminous infrared galaxy NGC 2146. Also taking into account the temporal and spectral properties of the gamma-ray emission, we suggest that the gamma-ray source is likely to be the counterpart of NGC 2146. The gamma-ray luminosity suggests that cosmic rays in NGC 2146 convert most of their energy into secondary pions, so NGC 2146 is a 'proton calorimeter'. It is also found that NGC 2146 obeys the quasi-linear scaling relation between gamma-ray luminosity and total infrared luminosity for star-forming galaxies, strengthening the connection between massive star formation and gamma-ray emission of star-forming galaxies. Possible TeV emission from NGC 2146 is predicted and the implications for high-energy neutrino emission from starburst galaxies are discussed.

  9. THE EARLIEST NEAR-INFRARED TIME-SERIES SPECTROSCOPY OF A TYPE Ia SUPERNOVA

    SciTech Connect (OSTI)

    Hsiao, E. Y.; Phillips, M. M.; Morrell, N.; Contreras, C.; Roth, M.; Marion, G. H.; Kirshner, R. P.; Burns, C. R.; Freedman, W. L.; Persson, S. E.; Winge, C.; Gerardy, C. L.; Hoeflich, P.; Im, M.; Jeon, Y.; Pignata, G.; Stanishev, V.; and others

    2013-04-01

    We present ten medium-resolution, high signal-to-noise ratio near-infrared (NIR) spectra of SN 2011fe from SpeX on the NASA Infrared Telescope Facility (IRTF) and Gemini Near-Infrared Spectrograph (GNIRS) on Gemini North, obtained as part of the Carnegie Supernova Project. This data set constitutes the earliest time-series NIR spectroscopy of a Type Ia supernova (SN Ia), with the first spectrum obtained at 2.58 days past the explosion and covering -14.6 to +17.3 days relative to B-band maximum. C I {lambda}1.0693 {mu}m is detected in SN 2011fe with increasing strength up to maximum light. The delay in the onset of the NIR C I line demonstrates its potential to be an effective tracer of unprocessed material. For the first time in a SN Ia, the early rapid decline of the Mg II {lambda}1.0927 {mu}m velocity was observed, and the subsequent velocity is remarkably constant. The Mg II velocity during this constant phase locates the inner edge of carbon burning and probes the conditions under which the transition from deflagration to detonation occurs. We show that the Mg II velocity does not correlate with the optical light-curve decline rate {Delta}m{sub 15}(B). The prominent break at {approx}1.5 {mu}m is the main source of concern for NIR k-correction calculations. We demonstrate here that the feature has a uniform time evolution among SNe Ia, with the flux ratio across the break strongly correlated with {Delta}m{sub 15}(B). The predictability of the strength and the onset of this feature suggests that the associated k-correction uncertainties can be minimized with improved spectral templates.

  10. Infrared spectroscopy study of irradiated PVDF

    SciTech Connect (OSTI)

    Chappa, Veronica; Grosso, Mariela del; Garcia Bermudez, Gerardo; Behar, Moni

    2007-10-26

    The effects induced by 1 MeV/amu ion irradiations were compared to those induced by 4-12 MeV/amu irradiations. Structural analysis with infrared spectroscopy (FTIR) was carried out on PVDF irradiated using C and He beams with different fluences. From these spectra it was observed, as a function of fluence, an overall destruction of the polymer, amorphization of the crystalline regions and the creation of in-chain unsaturations. The track dimensions were determined using a previously developed Monte Carlo simulation code and these results were compared to a semiempirical model.

  11. Resonator-quantum well infrared photodetectors

    SciTech Connect (OSTI)

    Choi, K. K. Sun, J.; Olver, K.; Jhabvala, M. D.; Jhabvala, C. A.; Waczynski, A.

    2013-11-11

    We applied a recent electromagnetic model to design the resonator-quantum well infrared photodetector (R-QWIP). In this design, we used an array of rings as diffractive elements to diffract normal incident light into parallel propagation and used the pixel volume as a resonator to intensify the diffracted light. With a proper pixel size, the detector resonates at certain optical wavelengths and thus yields a high quantum efficiency (QE). To test this detector concept, we fabricated a number of R-QWIPs with different quantum well materials and detector geometries. The experimental result agrees satisfactorily with the prediction, and the highest QE achieved is 71%.

  12. Defining the infrared systems for ITER

    SciTech Connect (OSTI)

    Reichle, R.; Andrew, P.; Drevon, J.-M.; Encheva, A.; Janeschitz, G.; Levesy, B.; Martin, A.; Pitcher, C. S.; Pitts, R.; Thomas, D.; Vayakis, G.; Walsh, M.; Counsell, G.; Johnson, D.; Kusama, Y.

    2010-10-15

    The International Thermonuclear Experimental Reactor will have wide angle viewing systems and a divertor thermography diagnostic, which shall provide infrared coverage of the divertor and large parts of the first wall surfaces with spatial and temporal resolution adequate for operational purposes and higher resolved details of the divertor and other areas for physics investigations. We propose specifications for each system such that they jointly respond to the requirements. Risk analysis driven priorities for future work concern mirror degradation, interfaces with other diagnostics, radiation damage to refractive optics, reflections, and the development of calibration and measurement methods for varying optical and thermal target properties.

  13. Infrared Images of Shock-Heated Tin

    SciTech Connect (OSTI)

    Craig W. McCluskey; Mark D. Wilke; William D. Turley; Gerald D. Stevens; Lynn R. Veeser; Michael Grover

    2004-09-01

    High-resolution, gated infrared images were taken of tin samples shock heated to just below the 505 K melting point. Sample surfaces were either polished or diamond-turned, with grain sizes ranging from about 0.05 to 10 mm. A high explosive in contact with a 2-mm-thick tin sample induced a peak sample stress of 18 GPa. Interferometer data from similarly-driven tin shots indicate that immediately after shock breakout the samples spall near the free (imaged) surface with a scab thickness of about 0.1 mm.

  14. First Principles Simulations of the Infrared Spectrum of Liquid Water |

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Argonne Leadership Computing Facility Infrared spectra of liquid water Infrared spectra of liquid water computed using hybrid (solid lines) and semi-local (dotted line) functionals, computed by ab-initio molecular dynamics with the Qbox code. Cui Zhang, UC-Davis. First Principles Simulations of the Infrared Spectrum of Liquid Water PI Name: Giulia Galli PI Email: gagalli@ucdavis.edu Institution: University of California-Davis Allocation Program: INCITE Allocation Hours at ALCF: 15 Million

  15. Doped carbon nanostructure field emitter arrays for infrared imaging

    DOE Patents [OSTI]

    Korsah, Kofi [Knoxville, TN; Baylor, Larry R [Farragut, TN; Caughman, John B [Oak Ridge, TN; Kisner, Roger A [Knoxville, TN; Rack, Philip D [Knoxville, TN; Ivanov, Ilia N [Knoxville, TN

    2009-10-27

    An infrared imaging device and method for making infrared detector(s) having at least one anode, at least one cathode with a substrate electrically connected to a plurality of doped carbon nanostructures; and bias circuitry for applying an electric field between the anode and the cathode such that when infrared photons are adsorbed by the nanostructures the emitted field current is modulated. The detectors can be doped with cesium to lower the work function.

  16. Infrared Thermography (IRT) Working Group | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Infrared Thermography (IRT) Working Group Infrared Thermography (IRT) Working Group Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado pvmrw13_ps3_pvmc_mcwilliams.pdf (1.52 MB) More Documents & Publications US & Japan TG 4 Activities of QA Forum Agenda for the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado Energy Auditor - Single Family 2.0: Interpreting Infrared

  17. Nanosecond Time Resolved and Steady State Infrared Studies of...

    Office of Scientific and Technical Information (OSTI)

    Nanosecond Time Resolved and Steady State Infrared Studies of Photoinduced Decomposition of TATB at Ambient and Elevated Pressures Citation Details In-Document Search Title: ...

  18. Synchrotron radiation infrared microscopic study of non-bridging...

    Office of Scientific and Technical Information (OSTI)

    Title: Synchrotron radiation infrared microscopic study of non-bridging oxygen modes associated with laser-induced breakdown of fused silica Authors: Matthews, M J ; Carr, C W ; ...

  19. NREL: Measurements and Characterization - Fourier-Transform Infrared...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Fourier-Transform Infrared and Raman Spectroscopy Image of FTIR map FTIR mapping capabilities are extremely useful for the quick, nondestructive characterization of heterogeneous ...

  20. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    because it is extremely difficult to perform spectroscopic measurements on a single monolayer of graphene. Infrared measurements can probe the dynamical properties of...

  1. Application Of Airborne Thermal Infrared Imagery To Geothermal...

    Open Energy Information (Open El) [EERE & EIA]

    Infrared Imagery To Geothermal Exploration Abstract Burlington Northern (BN) conducted TIR surveys using a fixed wing aircraft over 17 different geothermal prospects in...

  2. Near-infrared (JHK) spectroscopy of young stellar and substellar...

    Office of Scientific and Technical Information (OSTI)

    7 new objects having masses below the hydrogen-burning limit, and 6 objects with masses ... SPECTRA; HERTZSPRUNG-RUSSELL DIAGRAM; HYDROGEN BURNING; LUMINOSITY; MASS; NEAR INFRARED ...

  3. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    signatures of many-body interactions in graphene and have demonstrated the potential of graphene for novel applications in optoelectronics. Infrared View of Graphene Graphene's...

  4. Enhancement of Aluminum Alloy Forgings Using Rapid Infrared Heating...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    and industry partners, Queen City Forging Company and Infra Red Heating Technologies LLC, have developed a process for forging aluminum parts using infrared (IR) technology. ...

  5. Quantitative infrared absorption cross sections of isoprene for...

    Office of Scientific and Technical Information (OSTI)

    Quantitative infrared absorption cross sections of isoprene for atmospheric measurements ... and other oxygenated organics, yet little quantitative IR data exists for isoprene. ...

  6. Electrochemical and infrared studies of the reduction of organic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electrochemical and infrared studies of the reduction of organic carbonates Citation Details ... Publication Date: 2001-06-01 OSTI Identifier: 821009 Report ...

  7. Thermal And-Or Near Infrared At Yellowstone Region (Hellman ...

    Open Energy Information (Open El) [EERE & EIA]

    Activity Details Location Yellowstone Caldera Geothermal Region Exploration Technique Thermal And-Or Near Infrared Activity Date Usefulness useful DOE-funding Unknown...

  8. A near-infrared 64-pixel superconducting nanowire single photon...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; DETECTION; EFFICIENCY; NANOWIRES; NEAR INFRARED RADIATION; ...

  9. Nonlinear Bayesian Algorithms for Gas Plume Detection and Estimation from Hyper-spectral Thermal Image Data

    SciTech Connect (OSTI)

    Heasler, Patrick G.; Posse, Christian; Hylden, Jeff L.; Anderson, Kevin K.

    2007-06-13

    This paper presents a nonlinear Bayesian regression algorithm for the purpose of detecting and estimating gas plume content from hyper-spectral data. Remote sensing data, by its very nature, is collected under less controlled conditions than laboratory data. As a result, the physics-based model that is used to describe the relationship between the observed remotesensing spectra, and the terrestrial (or atmospheric) parameters that we desire to estimate, is typically littered with many unknown "nuisance" parameters (parameters that we are not interested in estimating, but also appear in the model). Bayesian methods are well-suited for this context as they automatically incorporate the uncertainties associated with all nuisance parameters into the error estimates of the parameters of interest. The nonlinear Bayesian regression methodology is illustrated on realistic simulated data from a three-layer model for longwave infrared (LWIR) measurements from a passive instrument. This shows that this approach should permit more accurate estimation as well as a more reasonable description of estimate uncertainty.

  10. Discrete spectral incoherent solitons in nonlinear media with noninstantaneous response

    SciTech Connect (OSTI)

    Michel, Claire; Kibler, Bertrand; Picozzi, Antonio

    2011-02-15

    We show theoretically that nonlinear optical media characterized by a finite response time may support the existence of discrete spectral incoherent solitons. The structure of the soliton consists of three incoherent spectral bands that propagate in frequency space toward the low-frequency components in a discrete fashion and with a constant velocity. Discrete spectral incoherent solitons do not exhibit a confinement in the space-time domain, but exclusively in the frequency domain. The kinetic theory describes in detail all the essential properties of discrete spectral incoherent solitons: A quantitative agreement has been obtained between simulations of the kinetic equation and the nonlinear Schroedinger equation. Discrete spectral incoherent solitons may be supported in both the normal dispersion regime or the anomalous dispersion regime. These incoherent structures find their origin in the causality condition inherent to the nonlinear response function of the material. Considering the concrete example of the Raman effect, we show that discrete incoherent solitons may be spontaneously generated through the process of supercontinuum generation in photonic crystal fibers.

  11. Germanium blocked impurity band infrared detectors

    SciTech Connect (OSTI)

    Rossington, C.S.; Haller, E.E.

    1988-08-01

    Germanium blocked impurity band (BIB) photoconductors have been fabricated and characterized for responsivity, dark current, and noise equivalent power. BIB photoconductors theoretically provide an extension of the spectral response, a reduction in sensitivity to cosmic radiation and a reduction in noise characteristics compared with conventional photoconductors. Silicon BIB detectors have been successfully developed by researchers at Rockwell International, which do indeed meet their theoretical potential. In the proper configuration, these same Si BIB detectors are capable of continuous detection of individual photons in the wavelength range from 0.4 to 28 ..mu..m. Until the BIB concept was developed, detection of individual photons was only possible with photomultiplier tubes which detected visible light. Due to the successes of the Si BIB detectors, it seemed natural to extend this concept to Ge detectors, which would then allow an extension of the spectral response over conventional Ge detectors from /approximately/100 ..mu..m to /approximately/200 ..mu..m. 8 refs., 2 figs.

  12. Application of External-Cavity Quantum Cascade Infrared Lasers to Nanosecond Time-Resolved Infrared Spectroscopy of Condensed-Phase Samples Following Pulse Radiolysis

    SciTech Connect (OSTI)

    Grills, D.C.; Cook, A.R.; Fujita, E.; George, M.W.; Miller, J.R.; Preses, J.M.; Wishart, J.F.

    2010-06-01

    Pulse radiolysis, utilizing short pulses of high-energy electrons from accelerators, is a powerful method for rapidly generating reduced or oxidized species and other free radicals in solution. Combined with fast time-resolved spectroscopic detection (typically in the ultraviolet/visible/near-infrared), it is invaluable for monitoring the reactivity of species subjected to radiolysis on timescales ranging from picoseconds to seconds. However, it is often difficult to identify the transient intermediates definitively due to a lack of structural information in the spectral bands. Time-resolved vibrational spectroscopy offers the structural specificity necessary for mechanistic investigations but has received only limited application in pulse radiolysis experiments. For example, time-resolved infrared (TRIR) spectroscopy has only been applied to a handful of gas-phase studies, limited mainly by several technical challenges. We have exploited recent developments in commercial external-cavity quantum cascade laser (EC-QCL) technology to construct a nanosecond TRIR apparatus that has allowed, for the first time, TRIR spectra to be recorded following pulse radiolysis of condensed-phase samples. Near single-shot sensitivity of DeltaOD <1 x 10(-3) has been achieved, with a response time of <20 ns. Using two continuous-wave EC-QCLs, the current apparatus covers a probe region from 1890-2084 cm(-1), and TRIR spectra are acquired on a point-by-point basis by recording transient absorption decay traces at specific IR wavelengths and combining these to generate spectral time slices. The utility of the apparatus has been demonstrated by monitoring the formation and decay of the one-electron reduced form of the CO(2) reduction catalyst, [Re(I)(bpy)(CO)(3)(CH(3)CN)](+), in acetonitrile with nanosecond time resolution following pulse radiolysis. Characteristic red-shifting of the nu(CO) IR bands confirmed that one-electron reduction of the complex took place. The availability of

  13. Zenith Radiance Retrieval of Cloud Properties

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    retrievals of cloud properties from the AMF/COPS campaign Preliminary retrievals of cloud properties from the AMF/COPS campaign Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC The cloud optical properties of interest are: The cloud optical properties of interest are: * Cloud optical depth τ - the great unknown * Radiative cloud

  14. Posters Atmospheric Emitted Radiance Interferometer Data Analysis...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Analysis Methods R. O. Knuteson, W. L. Smith, S. A. Ackerman, H. E. Revercomb, H. ... project under the direction of William L. Smith of the University of Wisconsin-Madison. ...

  15. Posters Atmospheric Emitted Radiance Interferometer: Status and...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    H. E. Revercomb, R. O. Knuteson, W. L. Smith, F. A. Best, and R. G. Dedecker University of ... and in several conference publications (Revercomb et al. 1993, 1994; Smith et al. 1993). ...

  16. Rotating shadowband radiometer development and analysis of spectral shortwave data

    SciTech Connect (OSTI)

    Michalsky, J.; Harrison, L.; Min, Q.

    1996-04-01

    Our goals in the Atmospheric Radiation Measurement (ARM) Program are improved measurements of spectral shortwave radiation and improved techniques for the retrieval of climatologically sensitive parameters. The multifilter rotating shadowband radiometer (MFRSR) that was developed during the first years of the ARM program has become a workhorse at the Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) site, and it is widely deployed in other climate programs. We have spent most of our effort this year developing techniques to retrieve column aerosol, water vapor, and ozone from direct beam spectral measurements of the MFRSR. Additionally, we have had some success in calculating shortwave surface diffuse spectral irradiance. Using the surface albedo and the global irradiance, we have calculated cloud optical depths. From cloud optical depth and liquid water measured with the microwave radiometer, we have calculated effective liquid cloud particle radii. The rest of the text will provide some detail regarding each of these efforts.

  17. Predicting the Spectral Effects of Soils on Concentrating Photovoltaic Systems

    SciTech Connect (OSTI)

    Burton, Patrick D.; King, Bruce Hardison; Riley, Daniel M.

    2014-12-15

    The soiling losses on high concentrating photovoltaic (HCPV) systems may be influenced by the spectral properties of accumulated soil. We predicted the response of an isotype cell to changes in spectral content and reduction in transmission due to soiling using measured UV/vis transmittance through soil films. Artificial soil test blends deposited on glass coupons were used to supply the transmission data, which was then used to calculate the effect on model spectra. Moreover, the wavelength transparency of the test soil was varied by incorporating red and yellow mineral pigments into graded sand. The more spectrally responsive (yellow) soils were predicted to alter the current balance between the top and middle subcells throughout a range of air masses corresponding to daily and seasonal variation.

  18. Predicting the Spectral Effects of Soils on Concentrating Photovoltaic Systems

    DOE PAGES-Beta [OSTI]

    Burton, Patrick D.; King, Bruce Hardison; Riley, Daniel M.

    2014-12-15

    The soiling losses on high concentrating photovoltaic (HCPV) systems may be influenced by the spectral properties of accumulated soil. We predicted the response of an isotype cell to changes in spectral content and reduction in transmission due to soiling using measured UV/vis transmittance through soil films. Artificial soil test blends deposited on glass coupons were used to supply the transmission data, which was then used to calculate the effect on model spectra. Moreover, the wavelength transparency of the test soil was varied by incorporating red and yellow mineral pigments into graded sand. The more spectrally responsive (yellow) soils were predictedmore » to alter the current balance between the top and middle subcells throughout a range of air masses corresponding to daily and seasonal variation.« less

  19. THE BATSE 5B GAMMA-RAY BURST SPECTRAL CATALOG

    SciTech Connect (OSTI)

    Goldstein, Adam; Preece, Robert D.; Briggs, Michael S.; Burgess, J. Michael [University of Alabama in Huntsville, 320 Sparkman Drive, Huntsville, AL 35899 (United States); Mallozzi, Robert S.; Fishman, Gerald J.; Kouveliotou, Chryssa [Space Science Office, VP62, NASA/Marshall Space Flight Center, Huntsville, AL 35812 (United States); Paciesas, William S. [Universities Space Research Association, 320 Sparkman Drive, Huntsville, AL 35805 (United States)

    2013-10-01

    We present systematic spectral analyses of gamma-ray bursts (GRBs) detected with the Burst and Transient Source Experiment (BATSE) on board the Compton Gamma-Ray Observatory during its entire nine years of operation. This catalog contains two types of spectra extracted from 2145 GRBs, and fitted with five different spectral models resulting in a compendium of over 19,000 spectra. The models were selected based on their empirical importance to the spectral shape of many GRBs, and the analysis performed was devised to be as thorough and objective as possible. We describe in detail our procedures and criteria for the analyses, and present the bulk results in the form of parameter distributions. This catalog should be considered an official product from the BATSE Science Team, and the data files containing the complete results are available from the High-Energy Astrophysics Science Archive Research Center (HEASARC)

  20. Spatial and spectral effects in subcritical system pulsed experiments

    SciTech Connect (OSTI)

    Dulla, S.; Nervo, M.; Ravetto, P.; Carta, M.

    2013-07-01

    Accurate neutronic models are needed for the interpretation of pulsed experiments in subcritical systems. In this work, the extent of spatial and spectral effects in the pulse propagation phenomena is investigated and the analysis is applied to the GUINEVERE experiment. The multigroup cross section data is generated by the Monte Carlo SERPENT code and the neutronic evolution following the source pulse is simulated by a kinetic diffusion code. The results presented show that important spatial and spectral aspects need to be properly accounted for and that a detailed energy approach may be needed to adequately capture the physical features of the system to the pulse injection. (authors)

  1. Synthesis, spectral characterization, and single crystal structure studies

    Office of Scientific and Technical Information (OSTI)

    of (2-nitro-ethene-1,1-diyl)-bis-((4-isopropyl-benzyl)sulfane) (Journal Article) | SciTech Connect Synthesis, spectral characterization, and single crystal structure studies of (2-nitro-ethene-1,1-diyl)-bis-((4-isopropyl-benzyl)sulfane) Citation Details In-Document Search Title: Synthesis, spectral characterization, and single crystal structure studies of (2-nitro-ethene-1,1-diyl)-bis-((4-isopropyl-benzyl)sulfane) The title compound (2-nitro-ethene-1,1-diyl)-bis-(4-isopropylbenzyl)sulfane)

  2. Asymmetric spectral broadening of modulated electrostatic ion-cyclotron waves

    SciTech Connect (OSTI)

    Koepke, M.E.; Alport, M.J.; Sheridan, T.E.; Amatucci, W.E.; Carroll, J.J. III

    1994-06-01

    Modulated, current-driven, electrostatic ion-cyclotron (CDEIC) waves are shown to exhibit amplitude and frequency modulation, spectral broadening, and time-averaged frequency pulling. The observed spectral broadening is asymmetric and sensitively dependent on the driving frequency. Qualitative features of the experimental data are reproduced by the forced van der Pol equation and are explainable using processes associated with driven self oscillations. These results may be relevant to ionospheric modification experiments involving the controlled modulation of the natural electrojet. 31 refs., 4 figs.

  3. SPECTRAL AMPLITUDE AND PHASE EVOLUTION IN PETAWATT LASER PULSES

    SciTech Connect (OSTI)

    Filip, C V

    2010-11-22

    The influence of the active gain medium on the spectral amplitude and phase of amplified pulses in a CPA system is studied. Results from a 10-PW example based on Nd-doped mixed glasses are presented. In conclusion, this study shows that, by using spectral shaping and gain saturation in a mixed-glass amplifier, it is possible to produce 124 fs, 1.4 kJ laser pulses. One detrimental effect, the pulse distortion due to resonant amplification medium, has been investigated and its magnitude as well as its compensation calculated.

  4. Oxidation of carbynes: Signatures in infrared spectra

    SciTech Connect (OSTI)

    Cinquanta, E. E-mail: p.rudolf@rug.nl; Manini, N.; Caramella, L.; Onida, G.; Ravagnan, L.; Milani, P.; Rudolf, P. E-mail: p.rudolf@rug.nl

    2014-06-28

    We report and solidly interpret the infrared spectrum of both pristine and oxidized carbynes embedded in a pure-carbon matrix. The spectra probe separately the effects of oxidation on sp- and on sp{sup 2}-hybridized carbon, and provide information on the stability of the different structures in an oxidizing atmosphere. The final products are mostly short end-oxidized carbynes anchored with a double bond to sp{sup 2} fragments, plus an oxidized sp{sup 2} amorphous matrix. Our results have important implications for the realization of carbyne-based nano-electronics devices and highlight the active participation of carbynes in astrochemical reactions where they act as carbon source for the promotion of more complex organic species.

  5. Tunable infrared source employing Raman mixing

    DOE Patents [OSTI]

    Byer, Robert L.; Herbst, Richard L.

    1980-01-01

    A tunable source of infrared radiation is obtained by irradiating an assemblage of Raman active gaseous atoms or molecules with a high intensity pumping beam of coherent radiation at a pump frequency .omega..sub.p to stimulate the generation of Stokes wave energy at a Stokes frequency .omega..sub.s and to stimulate the Raman resonant mode at the Raman mode frequency .omega..sub.R within the irradiated assemblage where the pump frequency .omega..sub.p minus the Stokes frequency .omega..sub.s is equal to the Raman mode frequency .omega..sub.R. The stimulated assemblage is irradiated with a tunable source of coherent radiation at a frequency .omega..sub.i to generate the output infrared radiation of the frequency .omega..sub.0 which is related to the Raman mode frequency .omega..sub.R and the input wave .omega..sub.i by the relation .omega..sub.0 =.omega..sub.i .+-..omega..sub.R. In one embodiment the interaction between the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i is collinear and the ratio of the phase velocity mismatch factor .DELTA.k to the electric field exponential gain coefficient T is within the range of 0.1 to 5. In another embodiment the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i have velocity vectors k.sub.p and k.sub.i which cross at an angle to each other to compensate for phase velocity mismatches in the medium. In another embodiment, the Stokes wave energy .omega..sub.s is generated by pump energy .omega..sub.p in a first Raman cell and .omega..sub.s, .omega..sub.i and .omega..sub.p are combined in a second Raman mixing cell to produce the output at .omega..sub.i.

  6. Apparatus and method for transient thermal infrared spectrometry

    DOE Patents [OSTI]

    McClelland, John F.; Jones, Roger W.

    1991-12-03

    A method and apparatus for enabling analysis of a material (16, 42) by applying a cooling medium (20, 54) to cool a thin surface layer portion of the material and to transiently generate a temperature differential between the thin surface layer portion and the lower portion of the material sufficient to alter the thermal infrared emission spectrum of the material from the black-body thermal infrared emission spectrum of the material. The altered thermal infrared emission spectrum of the material is detected by a spectrometer/detector (28, 50) while the altered thermal infrared emission spectrum is sufficiently free of self-absorption by the material of the emitted infrared radiation. The detection is effected prior to the temperature differential propagating into the lower portion of the material to an extent such that the altered thermal infrared emission spectrum is no longer sufficiently free of self-absorption by the material of emitted infrared radiation, so that the detected altered thermal infrared emission spectrum is indicative of the characteristics relating to the molecular composition of the material.

  7. Near-infrared spectroscopic tissue imaging for medical applications

    DOE Patents [OSTI]

    Demos, Stavros; Staggs, Michael C.

    2006-12-12

    Near infrared imaging using elastic light scattering and tissue autofluorescence are explored for medical applications. The approach involves imaging using cross-polarized elastic light scattering and tissue autofluorescence in the Near Infra-Red (NIR) coupled with image processing and inter-image operations to differentiate human tissue components.

  8. Near-infrared spectroscopic tissue imaging for medical applications

    DOE Patents [OSTI]

    Demos; Stavros , Staggs; Michael C.

    2006-03-21

    Near infrared imaging using elastic light scattering and tissue autofluorescence are explored for medical applications. The approach involves imaging using cross-polarized elastic light scattering and tissue autofluorescence in the Near Infra-Red (NIR) coupled with image processing and inter-image operations to differentiate human tissue components.

  9. Multivariate classification of infrared spectra of cell and tissue samples

    DOE Patents [OSTI]

    Haaland, David M.; Jones, Howland D. T.; Thomas, Edward V.

    1997-01-01

    Multivariate classification techniques are applied to spectra from cell and tissue samples irradiated with infrared radiation to determine if the samples are normal or abnormal (cancerous). Mid and near infrared radiation can be used for in vivo and in vitro classifications using at least different wavelengths.

  10. Retrieval of Areal-averaged Spectral Surface Albedo from Transmission Data Alone: Computationally Simple and Fast Approach

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Barnard, James C.; Flynn, Connor J.; Riihimaki, Laura D.; Michalsky, Joseph; Hodges, G. B.

    2014-10-25

    We introduce and evaluate a simple retrieval of areal-averaged surface albedo using ground-based measurements of atmospheric transmission alone at five wavelengths (415, 500, 615, 673 and 870nm), under fully overcast conditions. Our retrieval is based on a one-line semi-analytical equation and widely accepted assumptions regarding the weak spectral dependence of cloud optical properties, such as cloud optical depth and asymmetry parameter, in the visible and near-infrared spectral range. To illustrate the performance of our retrieval, we use as input measurements of spectral atmospheric transmission from Multi-Filter Rotating Shadowband Radiometer (MFRSR). These MFRSR data are collected at two well-established continental sites in the United States supported by the U.S. Department of Energys (DOEs) Atmospheric Radiation Measurement (ARM) Program and National Oceanic and Atmospheric Administration (NOAA). The areal-averaged albedos obtained from the MFRSR are compared with collocated and coincident Moderate Resolution Imaging Spectroradiometer (MODIS) white-sky albedo. In particular, these comparisons are made at four MFRSR wavelengths (500, 615, 673 and 870nm) and for four seasons (winter, spring, summer and fall) at the ARM site using multi-year (2008-2013) MFRSR and MODIS data. Good agreement, on average, for these wavelengths results in small values (?0.01) of the corresponding root mean square errors (RMSEs) for these two sites. The obtained RMSEs are comparable with those obtained previously for the shortwave albedos (MODIS-derived versus tower-measured) for these sites during growing seasons. We also demonstrate good agreement between tower-based daily-averaged surface albedos measured for nearby overcast and non-overcast days. Thus, our retrieval originally developed for overcast conditions likely can be extended for non-overcast days by interpolating between overcast retrievals.

  11. Industrial applications of accelerator-based infrared sources: Analysis using infrared microspectroscopy

    SciTech Connect (OSTI)

    Bantignies, J.L.; Fuchs, G.; Wilhelm, C.; Carr, G.L.; Dumas, P.

    1997-09-01

    Infrared Microspectroscopy, using a globar source, is now widely employed in the industrial environment, for the analysis of various materials. Since synchrotron radiation is a much brighter source, an enhancement of an order of magnitude in lateral resolution can be achieved. Thus, the combination of IR microspectroscopy and synchrotron radiation provides a powerful tool enabling sample regions only few microns size to be studied. This opens up the potential for analyzing small particles. Some examples for hair, bitumen and polymer are presented.

  12. Infrared non-destructive evaluation method and apparatus

    DOE Patents [OSTI]

    Baleine, Erwan; Erwan, James F; Lee, Ching-Pang; Stinelli, Stephanie

    2014-10-21

    A method of nondestructive evaluation and related system. The method includes arranging a test piece (14) having an internal passage (18) and an external surface (15) and a thermal calibrator (12) within a field of view (42) of an infrared sensor (44); generating a flow (16) of fluid characterized by a fluid temperature; exposing the test piece internal passage (18) and the thermal calibrator (12) to fluid from the flow (16); capturing infrared emission information of the test piece external surface (15) and of the thermal calibrator (12) simultaneously using the infrared sensor (44), wherein the test piece infrared emission information includes emission intensity information, and wherein the thermal calibrator infrared emission information includes a reference emission intensity associated with the fluid temperature; and normalizing the test piece emission intensity information against the reference emission intensity.

  13. Using digital imaging to assess spectral solar-optical properties of complex fenestration materials: A new approach in video-goniophotometry

    SciTech Connect (OSTI)

    Andersen, Marilyne; Stokes, Eleanor; Gayeski, Nicholas; Browne, Courtney

    2010-04-15

    A large variety of angularly selective fenestration systems have been developed in the past two decades and show great potential in improving visual comfort while reducing energy consumption, especially when combined with spectrally selective properties. Such systems include light-redirecting glazing, shading, film coatings, reflectors and others. To assess the potential of these systems accurately and reliably, one needs to be able to predict in detail how they modify the energy, direction and spectral make-up of solar radiation. For this assessment, spectral (wavelength-dependent) Bidirectional Transmission or Reflection Distribution Functions are used, usually referred to as BTDFs or BRDFs, or more generally BSDFs for Scattering Functions. To enable a faster, cheaper, and continuous investigation of these properties over most of the solar spectrum (400-1700 nm), an innovative goniospectrometric instrument has been created, relying on digital imaging, on light collection by an ellipsoidal half-transparent mirror, and on a filtering method in the visible range to generate spectral radiometric BSDFs. This so-called Heliodome instrument is described in this paper. It enables the performance of new fenestration technologies to be assessed in terms of lighting and solar gains management potential. The rotating table also serves as a heliodon, an architectural design tool for visualizing sunlight distribution inside a scale model and performing analyses on appropriate sun control strategies. The Heliodome's major innovations compared to other devices are to enable an analysis of both the visible and the near-infrared portions of the solar spectrum, to provide spectral as well as photometric light distribution data, and to ensure a continuous investigation of the transmitted or reflected light in a time-efficient way. (author)

  14. Wavelet Approach for Operational Gamma Spectral Peak Detection - Preliminary Assessment

    SciTech Connect (OSTI)

    ,

    2012-02-01

    Gamma spectroscopy for radionuclide identifications typically involves locating spectral peaks and matching the spectral peaks with known nuclides in the knowledge base or database. Wavelet analysis, due to its ability for fitting localized features, offers the potential for automatic detection of spectral peaks. Past studies of wavelet technologies for gamma spectra analysis essentially focused on direct fitting of raw gamma spectra. Although most of those studies demonstrated the potentials of peak detection using wavelets, they often failed to produce new benefits to operational adaptations for radiological surveys. This work presents a different approach with the operational objective being to detect only the nuclides that do not exist in the environment (anomalous nuclides). With this operational objective, the raw-count spectrum collected by a detector is first converted to a count-rate spectrum and is then followed by background subtraction prior to wavelet analysis. The experimental results suggest that this preprocess is independent of detector type and background radiation, and is capable of improving the peak detection rates using wavelets. This process broadens the doors for a practical adaptation of wavelet technologies for gamma spectral surveying devices.

  15. Demodulation circuit for AC motor current spectral analysis

    DOE Patents [OSTI]

    Hendrix, Donald E.; Smith, Stephen F.

    1990-12-18

    A motor current analysis method for the remote, noninvasive inspection of electric motor-operated systems. Synchronous amplitude demodulation and phase demodulation circuits are used singly and in combination along with a frequency analyzer to produce improved spectral analysis of load-induced frequencies present in the electric current flowing in a motor-driven system.

  16. A new scoring function for top-down spectral deconvolution

    SciTech Connect (OSTI)

    Kou, Qiang; Wu, Si; Liu, Xiaowen

    2014-12-18

    Background: Top-down mass spectrometry plays an important role in intact protein identification and characterization. Top-down mass spectra are more complex than bottom-up mass spectra because they often contain many isotopomer envelopes from highly charged ions, which may overlap with one another. As a result, spectral deconvolution, which converts a complex top-down mass spectrum into a monoisotopic mass list, is a key step in top-down spectral interpretation. Results: In this paper, we propose a new scoring function, L-score, for evaluating isotopomer envelopes. By combining L-score with MS-Deconv, a new software tool, MS-Deconv+, was developed for top-down spectral deconvolution. Experimental results showed that MS-Deconv+ outperformed existing software tools in top-down spectral deconvolution. Conclusions: L-score shows high discriminative ability in identification of isotopomer envelopes. Using L-score, MS-Deconv+ reports many correct monoisotopic masses missed by other software tools, which are valuable for proteoform identification and characterization.

  17. A new scoring function for top-down spectral deconvolution

    DOE PAGES-Beta [OSTI]

    Kou, Qiang; Wu, Si; Liu, Xiaowen

    2014-12-18

    Background: Top-down mass spectrometry plays an important role in intact protein identification and characterization. Top-down mass spectra are more complex than bottom-up mass spectra because they often contain many isotopomer envelopes from highly charged ions, which may overlap with one another. As a result, spectral deconvolution, which converts a complex top-down mass spectrum into a monoisotopic mass list, is a key step in top-down spectral interpretation. Results: In this paper, we propose a new scoring function, L-score, for evaluating isotopomer envelopes. By combining L-score with MS-Deconv, a new software tool, MS-Deconv+, was developed for top-down spectral deconvolution. Experimental results showedmore » that MS-Deconv+ outperformed existing software tools in top-down spectral deconvolution. Conclusions: L-score shows high discriminative ability in identification of isotopomer envelopes. Using L-score, MS-Deconv+ reports many correct monoisotopic masses missed by other software tools, which are valuable for proteoform identification and characterization.« less

  18. Spitzer SAGE-Spec: Near infrared spectroscopy, dust shells, and cool envelopes in extreme Large Magellanic Cloud asymptotic giant branch stars

    SciTech Connect (OSTI)

    Blum, R. D.; Srinivasan, S.; Kemper, F.; Ling, B.

    2014-11-01

    K-band spectra are presented for a sample of 39 Spitzer Infrared Spectrograph (IRS) SAGE-Spec sources in the Large Magellanic Cloud. The spectra exhibit characteristics in very good agreement with their positions in the near-infrared—Spitzer color-magnitude diagrams and their properties as deduced from the Spitzer IRS spectra. Specifically, the near-infrared spectra show strong atomic and molecular features representative of oxygen-rich and carbon-rich asymptotic giant branch stars, respectively. A small subset of stars was chosen from the luminous and red extreme ''tip'' of the color-magnitude diagram. These objects have properties consistent with dusty envelopes but also cool, carbon-rich ''stellar'' cores. Modest amounts of dust mass loss combine with the stellar spectral energy distribution to make these objects appear extreme in their near-infrared and mid-infrared colors. One object in our sample, HV 915, a known post-asymptotic giant branch star of the RV Tau type, exhibits CO 2.3 μm band head emission consistent with previous work that demonstrates that the object has a circumstellar disk.

  19. Dispersion properties and low infrared optical losses in epitaxial AlN on sapphire substrate in the visible and infrared range

    SciTech Connect (OSTI)

    Soltani, A. Stolz, A.; Gerbedoen, J.-C.; Rousseau, M.; Bourzgui, N.; De Jaeger, J.-C.; Charrier, J.; Mattalah, M.; Barkad, H. A.; Mortet, V.

    2014-04-28

    Optical waveguiding properties of a thick wurtzite aluminum nitride highly [002]-textured hetero-epitaxial film on (001) basal plane of sapphire substrate are studied. The physical properties of the film are determined by X-ray diffraction, atomic force microscopy, microRaman, and photocurrent spectroscopy. The refractive index and the thermo-optic coefficients are determined by m-lines spectroscopy using the classical prism coupling technique. The optical losses of this planar waveguide are also measured in the spectral range of 450–1553 nm. The lower value of optical losses is equal to 0.7 dB/cm at 1553 nm. The optical losses due to the surface scattering are simulated showing that the contribution is the most significant at near infrared wavelength range, whereas the optical losses are due to volume scattering and material absorption in the visible range. The good physical properties and the low optical losses obtained from this planar waveguide are encouraging to achieve a wide bandgap optical guiding platform from these aluminum nitride thin films.

  20. Damage threshold and focusability of mid-infrared free-electron laser pulses gated by a plasma mirror with nanosecond switching pulses

    SciTech Connect (OSTI)

    Wang, Xiaolong; Nakajima, Takashi; Zen, Heishun; Kii, Toshiteru; Ohgaki, Hideaki

    2013-11-04

    The presence of a pulse train structure of an oscillator-type free-electron laser (FEL) results in the immediate damage of a solid target upon focusing. We demonstrate that the laser-induced damage threshold can be significantly improved by gating the mid-infrared FEL pulses with a plasma mirror. Although the switching pulses we employ have a nanosecond duration which does not guarantee the clean wavefront of the gated FEL pulses, the high focusability is experimentally confirmed through the observation of spectral broadening by a factor of 2.1 when we tightly focus the gated FEL pulses onto the Ge plate.

  1. Negligible sample heating from synchrotron infrared beam

    SciTech Connect (OSTI)

    Martin, Michael C.; Tsvetkova, Nelly M.; Crowe, John H.; McKinney, Wayne R.

    2000-08-30

    The use of synchrotron sources for infrared (IR) spectromicroscopy provides greatly increased brightness enabling high-quality IR measurements at diffraction-limited spatial resolutions. This permits synchrotron-based IR spectromicroscopy to be applied to biological applications at spatial resolutions of the order of the size of a single mammalian cell. The question then arises, ''Does the intense synchrotron beam harm biological samples?'' Mid-IR photons are too low in energy to break bonds directly, however they could cause damage to biological molecules due to heating. In this work, we present measurements showing negligible sample heating effects from a diffraction-limited synchrotron IR source. The sample used is fully hydrated lipid bilayers composed of dipalmitoylphosphatidylcholine(DPPC), which undergoes a phase transition from a gel into a liquid-crystalline state at about 315 K during heating. Several IR-active vibrational modes clearly shift in frequency when the sample passes through the phase transition. We calibrate and then use these shifting vibrational modes as an in situ temperature sensor.

  2. Radiant energy required for infrared neural stimulation

    SciTech Connect (OSTI)

    Tan, Xiaodong; Rajguru, Suhrud; Young, Hunter; Xia, Nan; Stock, Stuart R.; Xiao, Xianghui; Richter, Claus-Peter

    2015-08-25

    Infrared neural stimulation (INS) has been proposed as an alternative method to electrical stimulation because of its spatial selective stimulation. Independent of the mechanism for INS, to translate the method into a device it is important to determine the energy for stimulation required at the target structure. Custom-designed, flat and angle polished fibers, were used to deliver the photons. By rotating the angle polished fibers, the orientation of the radiation beam in the cochlea could be changed. INS-evoked compound action potentials and single unit responses in the central nucleus of the inferior colliculus (ICC) were recorded. X-ray computed tomography was used to determine the orientation of the optical fiber. Maximum responses were observed when the radiation beam was directed towards the spiral ganglion neurons (SGNs), whereas little responses were seen when the beam was directed towards the basilar membrane. The radiant exposure required at the SGNs to evoke compound action potentials (CAPs) or ICC responses was on average 18.9 ± 12.2 or 10.3 ± 4.9 mJ/cm2, respectively. For cochlear INS it has been debated whether the radiation directly stimulates the SGNs or evokes a photoacoustic effect. The results support the view that a direct interaction between neurons and radiation dominates the response to INS.

  3. Radiant energy required for infrared neural stimulation

    DOE PAGES-Beta [OSTI]

    Tan, Xiaodong; Rajguru, Suhrud; Young, Hunter; Xia, Nan; Stock, Stuart R.; Xiao, Xianghui; Richter, Claus-Peter

    2015-08-25

    Infrared neural stimulation (INS) has been proposed as an alternative method to electrical stimulation because of its spatial selective stimulation. Independent of the mechanism for INS, to translate the method into a device it is important to determine the energy for stimulation required at the target structure. Custom-designed, flat and angle polished fibers, were used to deliver the photons. By rotating the angle polished fibers, the orientation of the radiation beam in the cochlea could be changed. INS-evoked compound action potentials and single unit responses in the central nucleus of the inferior colliculus (ICC) were recorded. X-ray computed tomography wasmore » used to determine the orientation of the optical fiber. Maximum responses were observed when the radiation beam was directed towards the spiral ganglion neurons (SGNs), whereas little responses were seen when the beam was directed towards the basilar membrane. The radiant exposure required at the SGNs to evoke compound action potentials (CAPs) or ICC responses was on average 18.9 ± 12.2 or 10.3 ± 4.9 mJ/cm2, respectively. For cochlear INS it has been debated whether the radiation directly stimulates the SGNs or evokes a photoacoustic effect. The results support the view that a direct interaction between neurons and radiation dominates the response to INS.« less

  4. Infrared Thermographic Study of Laser Ignition

    SciTech Connect (OSTI)

    Mohler, Jonathan H.; Chow, Charles T. S.

    1986-07-01

    Pyrotechnic ignition has been studied in the past by making a limited number of discrete temperature-time observations during ignition. Present-day infrared scanning techniques make it possible to record thermal profiles, during ignition, with high spacial and temporal resolution. Data thus obtained can be used with existing theory to characterize pyrotechnic materials and to develop more precise kinetic models of the ignition process. Ignition has been studied theoretically and experimentally using various thermal methods. It has been shown that the whole process can, ideally, be divided into two stages. In the first stage, the sample pellet behaves like an inert body heated by an external heat source. The second stage is governed by the chemical reaction in the heated volume produced during the first stage. High speed thermographic recording of the temperature distribution in the test sample during laser ignition makes it possible to calculate the heat content at any instant. Thus, one can actually observe laser heating and the onset of self-sustained combustion in the pellet. The experimental apparatus used to make these observations is described. The temperature distributions recorded are shown to be in good agreement with those predicted by heat transfer theory. Heat content values calculated from the observed temperature distributions are used to calculate thermal and kinetic parameters for several samples. These values are found to be in reasonable agreement with theory.

  5. Infrared thermographic study of laser ignition

    SciTech Connect (OSTI)

    Mohler, J.H.; Chow, C.T.S.

    1986-07-21

    Pyrotechnic ignition has been studied in the past by making a limited number of discrete temperature-time observations during ignition. Present-day infrared scanning techniques make it possible to record thermal profiles, during ignition, with high spacial and temporal resolution. Data thus obtained can be used with existing theory to characterize pyrotechnic materials and to develop more precise kinetic models of the ignition process. Ignition has been studied theoretically and experimentally using various thermal methods. It has been shown that the whole process can, ideally, be divided into two stages. In the first stage, the sample pellet behaves like an inert body heated by an external heat source. The second stage is governed by the chemical reaction in the heated volume produced during the first stage. High speed thermographic recording of the temperature distribution in the test sample during laser ignition makes it possible to calculate the heat content at any instant. Thus, one can actually observe laser heating and the onset of self-sustained combustion in the pellet.

  6. Star formation relations and CO spectral line energy distributions across the J-ladder and redshift

    SciTech Connect (OSTI)

    Greve, T. R.; Leonidaki, I.; Xilouris, E. M.; Wei, A.; Henkel, C.; Zhang, Z.-Y.; Van der Werf, P.; Meijerink, R.; Aalto, S.; Armus, L.; Daz-Santos, T.; Evans, A. S.; Fischer, J.; Gao, Y.; Gonzlez-Alfonso, E.; Harris, A.; Naylor, D. A.; Smith, H. A.; Spaans, M.; and others

    2014-10-20

    We present FIR [50-300 ?m]CO luminosity relations (i.e., log L{sub FIR}=?log L{sub CO}{sup ?}+?) for the full CO rotational ladder from J = 1-0 up to J = 13-12 for a sample of 62 local (z ? 0.1) (Ultra) Luminous Infrared Galaxies (LIRGs; L {sub IR[8-1000} {sub ?m]} > 10{sup 11} L {sub ?}) using data from Herschel SPIRE-FTS and ground-based telescopes. We extend our sample to high redshifts (z > 1) by including 35 submillimeter selected dusty star forming galaxies from the literature with robust CO observations, and sufficiently well-sampled FIR/submillimeter spectral energy distributions (SEDs), so that accurate FIR luminosities can be determined. The addition of luminous starbursts at high redshifts enlarge the range of the FIRCO luminosity relations toward the high-IR-luminosity end, while also significantly increasing the small amount of mid-J/high-J CO line data (J = 5-4 and higher) that was available prior to Herschel. This new data set (both in terms of IR luminosity and J-ladder) reveals linear FIRCO luminosity relations (i.e., ? ? 1) for J = 1-0 up to J = 5-4, with a nearly constant normalization (? ? 2). In the simplest physical scenario, this is expected from the (also) linear FIR(molecular line) relations recently found for the dense gas tracer lines (HCN and CS), as long as the dense gas mass fraction does not vary strongly within our (merger/starburst)-dominated sample. However, from J = 6-5 and up to the J = 13-12 transition, we find an increasingly sublinear slope and higher normalization constant with increasing J. We argue that these are caused by a warm (?100 K) and dense (>10{sup 4} cm{sup 3}) gas component whose thermal state is unlikely to be maintained by star-formation-powered far-UV radiation fields (and thus is no longer directly tied to the star formation rate). We suggest that mechanical heating (e.g., supernova-driven turbulence and shocks), and not cosmic rays, is the more likely source of energy for this component. The global CO

  7. INFRARED VIBRATIONAL PREDISSOCIATION SPECTROSCOPY OF WATER CLUSTERS BY THE CROSSED LASER MOLECULAR BEAM TECHNIQUE

    SciTech Connect (OSTI)

    Vernon, M.F.; Krajnovich, D.J.; Kwok, H.S.; Lisy, J.M.; Shen, Y.R.; Lee, Y.T.

    1981-11-01

    Water clusters formed in a molecular beam are predissociated by tunable, pulsed, infrared radiation in the frequency range 2900~3750 cm{sup -1}. The recoiling fragments are detected off axis from the molecular beam using a rotatable mass spectrometer. Arguments are presented which show that the measured frequency dependent signal at a fixed detector angle is proportional to the absorption spectrum of the clusters. It is found that the spectra of clusters containing three or more water molecules are remarkably similar to the liquid phase spectrum. Dynamical information on the predissociation process is obtained from the velocity distribution of the fragments. An upper limit to the excited vibrational state lifetime of ~1 microsecond is observed for the results reported here. The most probable dissociation process concentrates the available excess energy into the internal motions of the fragment molecules. Both the time scale and translational energy distribution are consistent with the qualitative predictions of current theoretical models for cluster predissociation. From adiabatic dissociation trajectories and Monte Carlo simulations it is seen that the strong coupling present in the water polymers probably invalidates the simpler "diatomic" picture formulations of cluster predissociation. Instead, the energy can be extensively shared among the intermolecular motions in the polymer before dissociation. Comparison between current intermolecular potentials describing liquid water and the observed frequencies is made in the normal mode approximation. The inability of any potential to predict the gross spectral features (the number of bands and their observed frequency shift from the gas phase monomer) suggests that substantial improvement in the potential energy functions are possible, but that more accurate methods of solving the vibrational wave equation are necessary before a proper explanation of the spectral fine structure is possible. The observed differences

  8. The infrared medium-deep survey. II. How to trigger radio AGNs? Hints from their environments

    SciTech Connect (OSTI)

    Karouzos, Marios; Im, Myungshin; Kim, Jae-Woo; Lee, Seong-Kook; Jeon, Yiseul; Choi, Changsu; Hong, Jueun; Hyun, Minhee; Jun, Hyunsung David; Kim, Dohyeong; Kim, Yongjung; Kim, Ji Hoon; Kim, Duho; Park, Won-Kee; Taak, Yoon Chan; Yoon, Yongmin; Chapman, Scott; Pak, Soojong; Edge, Alastair

    2014-12-10

    Activity at the centers of galaxies, during which the central supermassive black hole is accreting material, is nowadays accepted to be rather ubiquitous and most probably a phase of every galaxy's evolution. It has been suggested that galactic mergers and interactions may be the culprits behind the triggering of nuclear activity. We use near-infrared data from the new Infrared Medium-Deep Survey and the Deep eXtragalactic Survey of the VIMOS-SA22 field and radio data at 1.4 GHz from the FIRST survey and a deep Very Large Array survey to study the environments of radio active galactic nuclei (AGNs) over an area of ?25 deg{sup 2} and down to a radio flux limit of 0.1 mJy and a J-band magnitude of 23 mag AB. Radio AGNs are predominantly found in environments similar to those of control galaxies at similar redshift, J-band magnitude, and (M{sub u} M{sub r} ) rest-frame color. However, a subpopulation of radio AGNs is found in environments up to 100 times denser than their control sources. We thus preclude merging as the dominant triggering mechanism of radio AGNs. By fitting the broadband spectral energy distribution of radio AGNs in the least and most dense environments, we find that those in the least dense environments show higher radio-loudness, higher star formation efficiencies, and higher accretion rates, typical of the so-called high-excitation radio AGNs. These differences tend to disappear at z > 1. We interpret our results in terms of a different triggering mechanism for these sources that is driven by mass loss through winds of young stars created during the observed ongoing star formation.

  9. The mid-infrared appearance of the galactic mini-starburst W49A

    SciTech Connect (OSTI)

    Stock, D. J.; Peeters, E.; Choi, W. D.-Y.; Shannon, M. J.

    2014-08-20

    The massive star-forming region W49A represents one of the largest complexes of massive star formation present in the Milky Way and contains at least 50 young massive stars still enshrouded in their natal molecular cloud. We employ Spitzer/Infrared Spectrometer spectral mapping observations of the northern part of W49A to investigate the mid-infrared (MIR) spatial appearance of the polycyclic aromatic hydrocarbon (PAH) bands, PAH plateau features, atomic lines, and continuum emission. We examine the spatial variations of the MIR emission components in slices through two of the ultra-compact-H II (UC-H II) regions. We find that the PAH bands reproduce known trends, with the caveat that the 6.2 μm PAH band seems to decouple from the other ionized PAH bands in some of the UC-H II regions—an effect previously observed only in one other object: the giant star forming region N66 in the Large Magellanic Cloud. Furthermore, we compare the nature of the emission surrounding W49A to that of 'diffuse' sightlines. It is found that the surrounding emission can be explained by line of sight emission and does not represent true 'diffuse' material. Additionally, we examine the MIR appearance of star formation on various scales from UC-H II regions to starburst galaxies, including a discussion of the fraction of PAH emission in the 8 μm IRAC filter. We find that the MIR appearance of W49A is that of a starburst on large scales, yet its individual components are consistent with other galactic H II regions.

  10. NEAR-INFRARED DETECTION OF A SUPER-THIN DISK IN NGC 891

    SciTech Connect (OSTI)

    Schechtman-Rook, Andrew; Bershady, Matthew A.

    2013-08-10

    We probe the disk structure of the nearby, massive, edge-on spiral galaxy NGC 891 with subarcsecond resolution JHK{sub s}-band images covering {approx} {+-}10 kpc in radius and {+-}5 kpc in height. We measure intrinsic surface brightness (SB) profiles using realistic attenuation corrections constrained from near- and mid-infrared (Spitzer) color maps and three-dimensional Monte Carlo radiative-transfer models. In addition to the well-known thin and thick disks, a super-thin disk with 60-80 pc scale-height-comparable to the star-forming disk of the Milky Way-is visibly evident and required to fit the attenuation-corrected light distribution. Asymmetries in the super-thin disk light profile are indicative of young, hot stars producing regions of excess luminosity and bluer (attenuation-corrected) near-infrared color. To fit the inner regions of NGC 891, these disks must be truncated within {approx}3 kpc, with almost all their luminosity redistributed in a bar-like structure 50% thicker than the thin disk. There appears to be no classical bulge but rather a nuclear continuation of the super-thin disk. The super-thin, thin, thick, and bar components contribute roughly 30%, 42%, 13%, and 15% (respectively) to the total K{sub s}-band luminosity. Disk axial ratios (length/height) decrease from 30 to 3 from super-thin to thick components. Both exponential and sech{sup 2} vertical SB profiles fit the data equally well. We find that the super-thin disk is significantly brighter in the K{sub s}-band than typically assumed in integrated spectral energy distribution models of NGC 891: it appears that in these models the excess flux, likely produced by young stars in the super-thin disk, has been mistakenly attributed to the thin disk.

  11. Examination of the technical potential of near-infrared switching thermochromic windows for commercial building applications

    SciTech Connect (OSTI)

    Hoffmann, Sabine; Lee, Eleanor S.; Clavero, Cesar

    2013-12-01

    Current thermochromic windows modulate solar transmission primarily within the visible range, resulting in reduced space-conditioning energy use but also reduced daylight, thereby increasing lighting energy use compared to conventional static, near-infrared selective, low-emittance windows. To better understand the energy savings potential of improved thermochromic devices, a hypothetical near-infrared switching thermochromic glazing was defined based on guidelines provided by the material science community. EnergyPlus simulations were conducted on a prototypical large office building and a detailed analysis was performed showing the progression from switching characteristics to net window heat flow and perimeter zone loads and then to perimeter zone heating, ventilation, and air-conditioning (HVAC) and lighting energy use for a mixed hot/cold climate and a hot, humid climate in the US. When a relatively high daylight transmission is maintained when switched (Tsol = 0.10-0.50, Tvis = 0.30-0.60) and if coupled with a low-e inboard glazing layer (e = 0.04), the hypothetical thermochromic window with a low critical switching temperature range (14-20°C) achieved reductions in total site annual energy use of 14.0-21.1 kWh/m2-floor-yr or 12-14%2 for moderate- to large-area windows (WWR≥0.30) in Chicago and 9.8-18.6 kWh/m2-floor-yr or 10-17%3 for WWR≥0.45 in Houston compared to an unshaded spectrally-selective, low-e window (window E1) in south-, east-, and west-facing perimeter zones. If this hypothetical thermochromic window can be offered at costs that are competitive to conventional low-e windows and meet aesthetic requirements defined by the building industry and end users, then the technology is likely to be a viable energy-efficiency option for internal load dominated commercial buildings.

  12. Information-Efficient Spectral Imaging Sensor With Tdi

    DOE Patents [OSTI]

    Rienstra, Jeffrey L.; Gentry, Stephen M.; Sweatt, William C.

    2004-01-13

    A programmable optical filter for use in multispectral and hyperspectral imaging employing variable gain time delay and integrate arrays. A telescope focuses an image of a scene onto at least one TDI array that is covered by a multispectral filter that passes separate bandwidths of light onto the rows in the TDI array. The variable gain feature of the TDI array allows individual rows of pixels to be attenuated individually. The attenuations are functions of the magnitudes of the positive and negative components of a spectral basis vector. The spectral basis vector is constructed so that its positive elements emphasize the presence of a target and its negative elements emphasize the presence of the constituents of the background of the imaged scene. This system provides for a very efficient determination of the presence of the target, as opposed to the very data intensive data manipulations that are required in conventional hyperspectral imaging systems.

  13. Soliton communication lines based on spectrally efficient modulation formats

    SciTech Connect (OSTI)

    Yushko, O V; Redyuk, A A

    2014-06-30

    We report the results of mathematical modelling of optical-signal propagation in soliton fibre-optic communication lines (FOCLs) based on spectrally efficient signal modulation formats. We have studied the influence of spontaneous emission noise, nonlinear distortions and FOCL length on the data transmission quality. We have compared the characteristics of a received optical signal for soliton and conventional dispersion compensating FOCLs. It is shown that in the presence of strong nonlinearity long-haul soliton FOCLs provide a higher data transmission performance, as well as allow higher order modulation formats to be used as compared to conventional communication lines. In the context of a coherent data transmission, soliton FOCLs allow the use of phase modulation with many levels, thereby increasing the spectral efficiency of the communication line. (optical communication lines)

  14. Apparatus and method for transient thermal infrared emission spectrometry

    DOE Patents [OSTI]

    McClelland, John F.; Jones, Roger W.

    1991-12-24

    A method and apparatus for enabling analysis of a solid material (16, 42) by applying energy from an energy source (20, 70) top a surface region of the solid material sufficient to cause transient heating in a thin surface layer portion of the solid material (16, 42) so as to enable transient thermal emission of infrared radiation from the thin surface layer portion, and by detecting with a spectrometer/detector (28, 58) substantially only the transient thermal emission of infrared radiation from the thin surface layer portion of the solid material. The detected transient thermal emission of infrared radiation is sufficiently free of self-absorption by the solid material of emitted infrared radiation, so as to be indicative of characteristics relating to molecular composition of the solid material.

  15. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned...

  16. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dynamcs in Graphene by Infrared Spectroscopy Print Wednesday, 29 October 2008 00:00 Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high...

  17. Infrared and Raman Spectroscopy from Ab Initio Molecular Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Infrared and Raman Spectroscopy from Ab Initio Molecular Dynamics and Static Normal Mode Analysis: The C-H Region of DMSO as a Case Study Citation Details In-Document Search Title: ...

  18. Nanosecond Time Resolved and Steady State Infrared Studies of...

    Office of Scientific and Technical Information (OSTI)

    Ultrafast time-resolved infrared and steady state Fourier transform IR (FTIR) spectroscopies were used to probe TATB and its products after photoexcitation with a 5 ns pulse of 532 ...

  19. Spectral Slope of MHD Turbulence | Argonne Leadership Computing Facility

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Spectral Slope of MHD Turbulence PI Name: Andrey Beresnyak PI Email: andrey.at.astro@gmail.com Institution: Los Alamos National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 35 Million Year: 2013 Research Domain: Physics MHD turbulence has attracted attention of astronomers since mid 1960s. As most astrophysical media are ionized, plasmas are coupled to the magnetic fields. A simple one-fluid description known as magnetohydrodynamics (MHD) is broadly applicable to most

  20. The number counts and infrared backgrounds from infrared-bright galaxies

    SciTech Connect (OSTI)

    Hacking, P.B.; Soifer, B.T. California Institute of Technology, Pasadena )

    1991-02-01

    Extragalactic number counts and diffuse backgrounds at 25, 60, and 100 microns are predicted using new luminosity functions and improved spectral-energy distribution density functions derived from IRAS observations of nearby galaxies. Galaxies at redshifts z less than 3 that are like those in the local universe should produce a minimum diffuse background of 0.0085, 0.038, and 0.13 MJy/sr at 25, 60, and 100 microns, respectively. Models with significant luminosity evolution predict backgrounds about a factor of 4 greater than this minimum. 22 refs.

  1. Scalar spectral measures associated with an operator-fractal

    SciTech Connect (OSTI)

    Jorgensen, Palle E. T.; Kornelson, Keri A.; Shuman, Karen L.

    2014-02-15

    We study a spectral-theoretic model on a Hilbert space L{sup 2}(μ) where μ is a fixed Cantor measure. In addition to μ, we also consider an independent scaling operator U acting in L{sup 2}(μ). To make our model concrete, we focus on explicit formulas: We take μ to be the Bernoulli infinite-convolution measure corresponding to scale number 1/4 . We then define the unitary operator U in L{sup 2}(μ) from a scale-by-5 operation. The spectral-theoretic and geometric properties we have previously established for U are as follows: (i) U acts as an ergodic operator; (ii) the action of U is not spatial; and finally, (iii) U is fractal in the sense that it is unitarily equivalent to a countable infinite direct sum of (twisted) copies of itself. In this paper, we prove new results about the projection-valued measures and scalar spectral measures associated to U and its constituent parts. Our techniques make use of the representations of the Cuntz algebra O{sub 2} on L{sup 2}(μ)

  2. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  3. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  4. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  5. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  6. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  7. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  8. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future nanoelectronics. Using infrared spectromicroscopy at ALS Beamline 1.4, a group of researchers from

  9. Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Dirac Charge Dynamcs in Graphene by Infrared Spectroscopy Print Wednesday, 29 October 2008 00:00 Graphene-a single layer of carbon atoms arranged in a honeycomb lattice-has very high conductivity that can be tuned by applying a gate voltage. The charge carriers in graphene can travel ballistically over great distances (~1 micron) without scattering. These unusual electronic properties make graphene a promising candidate for future

  10. Design of integration-ready metasurface-based infrared absorbers

    SciTech Connect (OSTI)

    Ogando, Karim Pastoriza, Hernán

    2015-07-28

    We introduce an integration ready design of metamaterial infrared absorber, highly compatible with many kinds of fabrication processes. We present the results of an exhaustive experimental characterization, including an analysis of the effects of single meta-atom geometrical parameters and collective arrangement. We confront the results with the theoretical interpretations proposed in the literature. Based on the results, we develop a set of practical design rules for metamaterial absorbers in the infrared region.

  11. UV-TO-FIR ANALYSIS OF SPITZER/IRAC SOURCES IN THE EXTENDED GROTH STRIP. I. MULTI-WAVELENGTH PHOTOMETRY AND SPECTRAL ENERGY DISTRIBUTIONS

    SciTech Connect (OSTI)

    Barro, Guillermo; Perez-Gonzalez, P. G.; Gallego, J.; Villar, V.; Zamorano, J.; Ashby, M. L. N.; Kajisawa, M.; Yamada, T.; Miyazaki, S.

    2011-03-15

    We present an IRAC 3.6+4.5 {mu}m selected catalog in the Extended Groth Strip (EGS) containing photometry from the ultraviolet to the far-infrared and stellar parameters derived from the analysis of the multi-wavelength data. In this paper, we describe the method used to build coherent spectral energy distributions (SEDs) for all the sources. In a forthcoming companion paper, we analyze those SEDs to obtain robust estimations of stellar parameters such as photometric redshifts, stellar masses, and star formation rates. The catalog comprises 76,936 sources with [3.6] {<=} 23.75 mag (85% completeness level of the IRAC survey in the EGS) over 0.48 deg{sup 2}. For approximately 16% of this sample, we are able to deconvolve the IRAC data to obtain robust fluxes for the multiple counterparts found in ground-based optical images. Typically, the SEDs of the IRAC sources in our catalog count with more than 15 photometric data points, spanning from the ultraviolet wavelengths probed by GALEX to the far-infrared observed by Spitzer, and going through ground- and space-based optical and near-infrared data taken with 2-8 m class telescopes. Approximately 95% and 90% of all IRAC sources are detected in the deepest optical and near-infrared bands. These fractions are reduced to 85% and 70% for S/N > 5 detections in each band. Only 10% of the sources in the catalog have optical spectroscopy and redshift estimations. Almost 20% and 2% of the sources are detected by MIPS at 24 and 70 {mu}m, respectively. We also cross-correlate our catalog with public X-ray and radio catalogs. Finally, we present the Rainbow Navigator public Web interface utility, designed to browse all the data products resulting from this work, including images, spectra, photometry, and stellar parameters.

  12. ARM: Marine W-band (95 GHz) ARM Cloud Radar, filtered spectral...

    Office of Scientific and Technical Information (OSTI)

    Radar, filtered spectral data, co-polarized mode Title: ARM: Marine W-band (95 GHz) ARM Cloud Radar, filtered spectral data, co-polarized mode Marine W-band (95 GHz) ARM Cloud ...

  13. A POPULATION OF z > 2 FAR-INFRARED HERSCHEL-SPIRE-SELECTED STARBURSTS

    SciTech Connect (OSTI)

    Casey, C. M.; Berta, S.; Lutz, D.; Magnelli, B.; Bethermin, M.; Floc'h, E. le; Magdis, G.; Burgarella, D.; Chapin, E.; Chapman, S. C.; Clements, D. L.; Conley, A.; Conselice, C. J.; Farrah, D.; Hatziminaoglou, E.; Ivison, R. J.; Oliver, S. J.; and others

    2012-12-20

    We present spectroscopic observations for a sample of 36 Herschel-SPIRE 250-500 {mu}m selected galaxies (HSGs) at 2 < z < 5 from the Herschel Multi-tiered Extragalactic Survey. Redshifts are confirmed as part of a large redshift survey of Herschel-SPIRE-selected sources covering {approx}0.93 deg{sup 2} in six extragalactic legacy fields. Observations were taken with the Keck I Low Resolution Imaging Spectrometer and the Keck II DEep Imaging Multi-Object Spectrograph. Precise astrometry, needed for spectroscopic follow-up, is determined by identification of counterparts at 24 {mu}m or 1.4 GHz using a cross-identification likelihood matching method. Individual source luminosities range from log (L{sub IR}/L{sub Sun }) = 12.5-13.6 (corresponding to star formation rates (SFRs) 500-9000 M{sub Sun} yr{sup -1}, assuming a Salpeter initial mass function), constituting some of the most intrinsically luminous, distant infrared galaxies discovered thus far. We present both individual and composite rest-frame ultraviolet spectra and infrared spectral energy distributions. The selection of these HSGs is reproducible and well characterized across large areas of the sky in contrast to most z > 2 HyLIRGs in the literature, which are detected serendipitously or via tailored surveys searching only for high-z HyLIRGs; therefore, we can place lower limits on the contribution of HSGs to the cosmic star formation rate density (SFRD) at (7 {+-} 2) Multiplication-Sign 10{sup -3} M{sub Sun} yr{sup -1} h {sup 3} Mpc{sup -3} at z {approx} 2.5, which is >10% of the estimated total SFRD of the universe from optical surveys. The contribution at z {approx} 4 has a lower limit of 3 Multiplication-Sign 10{sup -3} M{sub Sun} yr{sup -1} h {sup 3} Mpc{sup -3}, {approx}>20% of the estimated total SFRD. This highlights the importance of extremely infrared-luminous galaxies with high SFRs to the buildup of stellar mass, even at the earliest epochs.

  14. Femtosecond measurements of near-infrared pulse induced mid-infrared transmission modulation of quantum cascade lasers

    SciTech Connect (OSTI)

    Cai, Hong; Liu, Sheng; Lalanne, Elaine; Guo, Dingkai; Chen, Xing; Choa, Fow-Sen; Wang, Xiaojun; Johnson, Anthony M.

    2014-05-26

    We temporally resolved the ultrafast mid-infrared transmission modulation of quantum cascade lasers (QCLs) using a near-infrared pump/mid-infrared probe technique at room temperature. Two different femtosecond wavelength pumps were used with photon energy above and below the quantum well (QW) bandgap. The shorter wavelength pump modulates the mid-infrared probe transmission through interband transition assisted mechanisms, resulting in a high transmission modulation depth and several nanoseconds recovery lifetime. In contrast, pumping with a photon energy below the QW bandgap induces a smaller transmission modulation depth but much faster (several picoseconds) recovery lifetime, attributed to intersubband transition assisted mechanisms. The latter ultrafast modulation (>60?GHz) could provide a potential way to realize fast QCL based free space optical communication.

  15. Energy efficient residential new construction: market transformation. Spectral selective glass. Final project report

    SciTech Connect (OSTI)

    Hammon, Robert

    2000-12-18

    This final report describes the following tasks associated with this project: cost and availability of spectrally selective glass (SSG); window labeling problem and field verification of glass; availability of SSG replacement glass and tempered glass; HVAC load reduction due to spectrally selective glass; and comsumer appreciation of spectrally selective glass. Also included in the report are four attachments: builder and HVAC subcontractor presentation, sample advertisements, spectrally selective glass demonstration model, and invitation to SCE Glass mini trade-show.

  16. Technical progress report: Completion of spectral rotating shadowband radiometers and analysis of atmospheric radiation measurement spectral shortwave data

    SciTech Connect (OSTI)

    Michalsky, J.; Harrison, L.

    1996-04-01

    Our goal in the Atmospheric Radiation Measurement (ARM) Program is the improvement of radiation models used in general circulation models (GCMs), especially in the shortwave, (1) by providing improved shortwave radiometric measurements for the testing of models and (2) by developing methods for retrieving climatologically sensitive parameters that serve as input to shortwave and longwave models. At the Atmospheric Sciences Research Center (ASRC) in Albany, New York, we are acquiring downwelling direct and diffuse spectral irradiance, at six wavelengths, plus downwelling broadband longwave, and upwelling and downwelling broadband shortwave irradiances that we combine with National Weather Service surface and upper air data from the Albany airport as a test data set for ARM modelers. We have also developed algorithms to improve shortwave measurements made at the Southern Great Plains (SGP) ARM site by standard thermopile instruments and by the multifilter rotating shadowband radiometer (MFRSR) based on these Albany data sets. Much time has been spent developing techniques to retrieve column aerosol, water vapor, and ozone from the direct beam spectral measurements of the MFRSR. Additionally, we have had success in calculating shortwave surface albedo and aerosol optical depth from the ratio of direct to diffuse spectral reflectance.

  17. INFRARED SPECTROSCOPY OF COMET 73P/SCHWASSMANN-WACHMANN 3 USING THE SPITZER SPACE TELESCOPE

    SciTech Connect (OSTI)

    Sitko, Michael L.; Whitney, Barbara A.; Wolff, Michael J.; Lisse, Carey M.; Kelley, Michael S.; Polomski, Elisha F.; Lynch, David K.; Russell, Ray W.; Kimes, Robin L.; Harker, David E. E-mail: bwhitney@wisc.edu E-mail: carey.lisse@jhuapl.edu E-mail: epolomsk@uwec.edu E-mail: Ray.W.Russell@aero.org E-mail: dharker@ucsd.edu

    2011-09-15

    We have used the Spitzer Space Telescope Infrared Spectrograph (IRS) to observe the 5-37 {mu}m thermal emission of comet 73P/Schwassmann-Wachmann 3 (SW3), components B and C. We obtained low spectral resolution (R {approx} 100) data over the entire wavelength interval, along with images at 16 and 22 {mu}m. These observations provided an unprecedented opportunity to study nearly pristine material from the surface and what was until recently the interior of an ecliptic comet-the cometary surface having experienced only two prior perihelion passages, and including material that was totally fresh. The spectra were modeled using a variety of mineral types including both amorphous and crystalline components. We find that the degree of silicate crystallinity, {approx}35%, is somewhat lower than most other comets with strong emission features, while its abundance of amorphous carbon is higher. Both suggest that SW3 is among the most chemically primitive solar system objects yet studied in detail, and that it formed earlier or farther from the Sun than the bulk of the comets studied so far. The similar dust compositions of the two fragments suggest that these are not mineralogically heterogeneous, but rather uniform throughout their volumes. The best-fit particle size distribution for SW3B has a form dn/da {approx} a{sup -3.5}, close to that expected for dust in collisional equilibrium, while that for SW3C has dn/da {approx} a{sup -4.0}, as seen mostly in active comets with strong directed jets, such as C/1995 O1 Hale-Bopp. The total mass of dust in the comae plus nearby tail, extrapolated from the field of view of the IRS peak-up image arrays, is (3-5) x 10{sup 8} kg for B and (7-9) x 10{sup 8} kg for C. Atomic abundances derived from the spectral models indicate a depletion of O compared to solar photospheric values, despite the inclusion of water ice and gas in the models. Atomic C may be solar or slightly sub-solar, but its abundance is complicated by the potential

  18. A monitoring campaign for Luhman 16AB. I. Detection of resolved near-infrared spectroscopic variability

    SciTech Connect (OSTI)

    Burgasser, Adam J.; Gillon, Michal; Jehin, E.; Delrez, L.; Opitom, C.; Faherty, Jacqueline K.; Radigan, Jacqueline; Triaud, Amaury H. M. J.; Plavchan, Peter

    2014-04-10

    We report resolved near-infrared spectroscopic monitoring of the nearby L dwarf/T dwarf binary WISE J104915.57531906.1AB (Luhman 16AB), as part of a broader campaign to characterize the spectral energy distribution and temporal variability of this system. A continuous 45 minute sequence of low-resolution IRTF/SpeX data spanning 0.8-2.4 ?m were obtained, concurrent with combined-light optical photometry with ESO/TRAPPIST. Our spectral observations confirm the flux reversal of this binary, and we detect a wavelength-dependent decline in the relative spectral fluxes of the two components coincident with a decline in the combined-light optical brightness of the system over the course of the observation. These data are successfully modeled as a combination of achromatic (brightness) and chromatic (color) variability in the T0.5 Luhman 16B, consistent with variations in overall cloud opacity; and no significant variability was found in L7.5 Luhman 16A, consistent with recent resolved photometric monitoring. We estimate a peak-to-peak amplitude of 13.5% at 1.25 ?m over the full light curve. Using a simple two-spot brightness temperature model for Luhman 16B, we infer an average cold covering fraction of ?30%-55%, varying by 15%-30% over a rotation period assuming a ?200-400 K difference between hot and cold regions. We interpret these variations as changes in the covering fraction of a high cloud deck and corresponding 'holes' which expose deeper, hotter cloud layers, although other physical interpretations are possible. A Rhines scale interpretation for the size of the variable features explains an apparent correlation between period and amplitude for Luhman 16B and the variable T dwarfs SIMP 0136+0933 and 2MASS J2139+0220, and predicts relatively fast winds (1-3 km s{sup 1}) for Luhman 16B consistent with light curve evolution on an advective time scale (1-3 rotation periods). The strong variability observed in this flux reversal brown dwarf pair supports the model of

  19. THE HAWAII INFRARED PARALLAX PROGRAM. I. ULTRACOOL BINARIES AND THE L/T TRANSITION

    SciTech Connect (OSTI)

    Dupuy, Trent J.; Liu, Michael C.

    2012-08-01

    We present the first results from our high-precision infrared (IR) astrometry program at the Canada-France-Hawaii Telescope. We measure parallaxes for 83 ultracool dwarfs (spectral types M6-T9) in 49 systems, with a median uncertainty of 1.1 mas (2.3%) and as good as 0.7 mas (0.8%). We provide the first parallaxes for 48 objects in 29 systems, and for another 27 objects in 17 systems, we significantly improve upon published results, with a median (best) improvement of 1.7 times (5 times). Three systems show astrometric perturbations indicative of orbital motion; two are known binaries (2MASS J0518-2828AB and 2MASS J1404-3159AB) and one is spectrally peculiar (SDSS J0805+4812). In addition, we present here a large set of Keck adaptive optics imaging that more than triples the number of binaries with L6-T5 components that have both multi-band photometry and distances. Our data enable an unprecedented look at the photometric properties of brown dwarfs as they cool through the L/T transition. Going from Almost-Equal-To L8 to Almost-Equal-To T4.5, flux in the Y and J bands increases by Almost-Equal-To 0.7 mag and Almost-Equal-To 0.5 mag, respectively (the Y- and J-band 'bumps'), while flux in the H, K, and L' bands declines monotonically. This wavelength dependence is consistent with cloud clearing over a narrow range of temperature, since condensate opacity is expected to dominate at 1.0-1.3 {mu}m. Interestingly, despite more than doubling the near-IR census of L/T transition objects, we find a conspicuous paucity of objects on the color-magnitude diagram just blueward of the late-L/early-T sequence. This 'L/T gap' occurs at (J - H){sub MKO} 0.1-0.3 mag, (J - K){sub MKO} = 0.0-0.4 mag, and implies that the last phases of cloud evolution occur rapidly. Finally, we provide a comprehensive update to the absolute magnitudes of ultracool dwarfs as a function of spectral type using a combined sample of 314 objects.

  20. NEAR-INFRARED IMAGING OF A z = 6.42 QUASAR HOST GALAXY WITH THE HUBBLE SPACE TELESCOPE WIDE FIELD CAMERA 3

    SciTech Connect (OSTI)

    Mechtley, M.; Windhorst, R. A.; Cohen, S. H.; Jansen, R. A.; Scannapieco, E.; Ryan, R. E.; Koekemoer, A. M.; Schneider, G.; Fan, X.; Hathi, N. P.; Keel, W. C.; Roettgering, H.; Schneider, D. P.; Strauss, M. A.; Yan, H. J.

    2012-09-10

    We report on deep near-infrared F125W (J) and F160W (H) Hubble Space Telescope Wide Field Camera 3 images of the z = 6.42 quasar J1148+5251 to attempt to detect rest-frame near-ultraviolet emission from the host galaxy. These observations included contemporaneous observations of a nearby star of similar near-infrared colors to measure temporal variations in the telescope and instrument point-spread function (PSF). We subtract the quasar point source using both this direct PSF and a model PSF. Using direct subtraction, we measure an upper limit for the quasar host galaxy of m{sub J} > 22.8 and m{sub H} > 23.0 AB mag (2 {sigma}). After subtracting our best model PSF, we measure a limiting surface brightness from 0.''3 to 0.''5 radius of {mu}{sub J} > 23.5 and {mu}{sub H} > 23.7 AB mag arcsec{sup -2} (2 {sigma}). We test the ability of the model subtraction method to recover the host galaxy flux by simulating host galaxies with varying integrated magnitude, effective radius, and Sersic index, and conducting the same analysis. These models indicate that the surface brightness limit ({mu}{sub J} > 23.5 AB mag arcsec{sup -2}) corresponds to an integrated upper limit of m{sub J} > 22-23 AB mag, consistent with the direct subtraction method. Combined with existing far-infrared observations, this gives an infrared excess log (IRX) > 1.0 and corresponding ultraviolet spectral slope {beta} > -1.2 {+-} 0.2. These values match those of most local luminous infrared galaxies, but are redder than those of almost all local star-forming galaxies and z {approx_equal} 6 Lyman break galaxies.

  1. Primer on Use of Multi-Spectral and Infra Red Imaging for On-Site Inspections

    SciTech Connect (OSTI)

    Henderson, J R

    2010-10-26

    . Finally, an appendix provides detail describing the magnitude and spatial extent of the surface shock expected from an underground nuclear explosion. If there is a seismic event or other data to suggest there has been a nuclear explosion in violation of the CTBT, an OSI may be conducted to determine whether a nuclear explosion has occurred and to gather information which may be useful in identifying the party responsible for conducting the explosion. The OSI must be conducted in the area where the event that triggered the inspection request occurred, and the inspected area must not exceed 1,000 square kilometers, or be more than 50 km on aside (CTBT Protocol, Part II, Paragraphs 2 and 3). One of the guiding principles for an inspection is that it be effective, minimally intrusive, timely, and cost-effective [Hawkins, Feb 1998]. In that context, MSIR is one of several technologies that can be used during an aircraft overflight to identify ground regions of high interest in a timely and cost-effective manner. This allows for an optimized inspection on the ground. The primary purpose for MSIR is to identify artifacts and anomalies that might be associated with a nuclear explosion, and to use the location of those artifacts and anomalies to reduce the search area that must be inspected from the ground. The MSIR measurements can have additional utility. The multi-spectral measurements of the ground can be used for terrain classification, which can aid in geological characterization of the Inspected Area. In conditions of where light smoke or haze is present, long-wave infrared imaging can provide better imaging of the ground than is possible with standard visible imagery.

  2. SUBARU AND GEMINI HIGH SPATIAL RESOLUTION INFRARED 18 {mu}m IMAGING OBSERVATIONS OF NEARBY LUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Imanishi, Masatoshi; Imase, Keisuke; Oi, Nagisa; Ichikawa, Kohei

    2011-05-15

    We present the results of a ground-based, high spatial resolution infrared 18 {mu}m imaging study of nearby luminous infrared galaxies (LIRGs), using the Subaru 8.2 m and Gemini-South 8.1 m telescopes. The diffraction-limited images routinely achieved with these telescopes in the Q band (17-23 {mu}m) allow us to investigate the detailed spatial distribution of infrared emission in these LIRGs. We then investigate whether the emission surface brightnesses are modest, as observed in starbursts, or are so high that luminous active galactic nuclei (AGNs; high emission surface brightness energy sources) are indicated. The sample consists of 18 luminous buried AGN candidates and starburst-classified LIRGs identified in earlier infrared spectroscopy. We find that the infrared 18 {mu}m emission from the buried AGN candidates is generally compact, and the estimated emission surface brightnesses are high, sometimes exceeding the maximum value observed in and theoretically predicted for a starburst phenomenon. The starburst-classified LIRGs usually display spatially extended 18 {mu}m emission and the estimated emission surface brightnesses are modest, within the range sustained by a starburst phenomenon. The general agreement between infrared spectroscopic and imaging energy diagnostic methods suggests that both are useful tools for understanding the hidden energy sources of the dusty LIRG population.

  3. Nonequilibrium fixed points in longitudinally expanding scalar theories: Infrared cascade, Bose condensation and a challenge for kinetic theory

    DOE PAGES-Beta [OSTI]

    Berges, J.; Schlichting, S.; Boguslavski, K.; Venugopalan, R.

    2015-11-05

    In [Phys. Rev. Lett. 114, 061601 (2015)], we reported on a new universality class for longitudinally expanding systems, encompassing strongly correlated non-Abelian plasmas and N-component self-interacting scalar field theories. Using classical-statistical methods, we showed that these systems share the same self-similar scaling properties for a wide range of momenta in a limit where particles are weakly coupled but their occupancy is high. Here we significantly expand on our previous work and delineate two further self-similar regimes. One of these occurs in the deep infrared (IR) regime of very high occupancies, where the nonequilibrium dynamics leads to the formation of amore » Bose-Einstein condensate. The universal IR scaling exponents and the spectral index characterizing the isotropic IR distributions are described by an effective theory derived from a systematic large-N expansion at next-to-leading order. Remarkably, this effective theory can be cast as a vertex-resummed kinetic theory. The other novel self-similar regime occurs close to the hard physical scale of the theory, and sets in only at later times. In this study, we argue that the important role of the infrared dynamics ensures that key features of our results for scalar and gauge theories cannot be reproduced consistently in conventional kinetic theory frameworks.« less

  4. IONIZED GAS KINEMATICS AT HIGH RESOLUTION. II. DISCOVERY OF A DOUBLE INFRARED CLUSTER IN II Zw 40

    SciTech Connect (OSTI)

    Beck, Sara; Lahad, Ohr; Turner, Jean; Lacy, John; Greathouse, Thomas

    2013-04-10

    The nearby dwarf galaxy II Zw 40 hosts an intense starburst. At the center of the starburst is a bright compact radio and infrared source, thought to be a giant dense H II region containing Almost-Equal-To 14, 000 O stars. Radio continuum images suggest that the compact source is actually a collection of several smaller emission regions. We accordingly use the kinematics of the ionized gas to probe the structure of the radio-infrared emission region. With TEXES on the NASA-IRTF we measured the 10.5 {mu}m [S IV] emission line with effective spectral resolutions, including thermal broadening, of {approx}25 and {approx}3 km s{sup -1} and spatial resolution {approx}1''. The line profile shows two distinct, spatially coextensive, emission features. The stronger feature is at galactic velocity and has FWHM 47 km s{sup -1}. The second feature is {approx}44 km s{sup -1} redward of the first and has FWHM 32 km s{sup -1}. We argue that these are two giant embedded clusters, and estimate their masses to be Almost-Equal-To 3 Multiplication-Sign 10{sup 5} M{sub Sun} and Almost-Equal-To 1.5 Multiplication-Sign 10{sup 5} M{sub Sun }. The velocity shift is unexpectedly large for such a small spatial offset. We suggest that it may arise in a previously undetected kinematic feature remaining from the violent merger that formed the galaxy.

  5. Nonequilibrium fixed points in longitudinally expanding scalar theories: Infrared cascade, Bose condensation and a challenge for kinetic theory

    SciTech Connect (OSTI)

    Berges, J.; Schlichting, S.; Boguslavski, K.; Venugopalan, R.

    2015-11-05

    In [Phys. Rev. Lett. 114, 061601 (2015)], we reported on a new universality class for longitudinally expanding systems, encompassing strongly correlated non-Abelian plasmas and N-component self-interacting scalar field theories. Using classical-statistical methods, we showed that these systems share the same self-similar scaling properties for a wide range of momenta in a limit where particles are weakly coupled but their occupancy is high. Here we significantly expand on our previous work and delineate two further self-similar regimes. One of these occurs in the deep infrared (IR) regime of very high occupancies, where the nonequilibrium dynamics leads to the formation of a Bose-Einstein condensate. The universal IR scaling exponents and the spectral index characterizing the isotropic IR distributions are described by an effective theory derived from a systematic large-N expansion at next-to-leading order. Remarkably, this effective theory can be cast as a vertex-resummed kinetic theory. The other novel self-similar regime occurs close to the hard physical scale of the theory, and sets in only at later times. In this study, we argue that the important role of the infrared dynamics ensures that key features of our results for scalar and gauge theories cannot be reproduced consistently in conventional kinetic theory frameworks.

  6. Results of Second Outdoor Comparison Between Absolute Cavity Pyrgeometer (ACP) and Infrared Integrating Sphere (IRIS) Radiometer at PMOD (Presentation)

    SciTech Connect (OSTI)

    Reda, I.; Grobner, J.; Wacker, S.

    2014-01-01

    The Absolute Cavity Pyrgeometer (ACP) and InfraRed Integrating Sphere radiometer (IRIS) are developed to establish a world reference for calibrating pyrgeometers with traceability to SI units. The two radiometers are un-windowed with negligible spectral dependence, and traceable to SI units through the temperature scale (ITS-90). The second outdoor comparison between the two designs was held from September 30 to October 11, 2013 at the Physikalisch-Metorologisches Observatorium Davos (PMOD). The difference between the irradiance measured by ACP and that of the IRIS was within 1 W/m2 (3 IRISs: PMOD + Australia + Germany). From the first and second comparisons, a difference of 4-6 W/m2 was observed between the irradiance measured by ACP&IRIS and that of the interim World Infrared Standard Group (WISG). This presentation includes results from the first and second comparison in an effort to establish the world reference for pyrgeometer calibrations, a key deliverable for the World Meteorological Organization (WMO), and the DOE-ASR.

  7. A versatile femtosecond stimulated Raman spectroscopy setup with tunable pulses in the visible to near infrared

    SciTech Connect (OSTI)

    Zhu, Liangdong; Liu, Weimin; Fang, Chong

    2014-07-28

    We demonstrate a versatile and efficient setup to perform femtosecond stimulated Raman spectroscopy (FSRS). Technical innovations are implemented to achieve the wavelength tunability for both the picosecond narrowband Raman pump pulse and femtosecond broadband Raman probe pulse. Using a simplified one-grating scheme in a home-built second harmonic bandwidth compressor followed by a two-stage noncollinear optical parametric amplifier, we tune the Raman pump pulse from ca. 480 to 750 nm. To generate the suitable Raman probe pulse in tandem, we rely on our recently demonstrated broadband up-converted multicolor array technique that readily provides tunable broadband laser sidebands across the visible to near-infrared range. This unique setup has unparalleled flexibility for conducting FSRS. We measure the ground-state Raman spectra of a cyclohexane standard using tunable pump-probe pairs at various wavelengths across the visible region. The best spectral resolution is ∼12 cm{sup −1}. By tuning the pump wavelength closer to the electronic absorption band of a photoacid pyranine in water, we observe the pre-resonantly enhanced Raman signal. The stimulated Raman gain of the 1627 cm{sup −1} mode is increased by over 15 times.

  8. Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

    SciTech Connect (OSTI)

    Grills, David C.; Farrington, Jaime A.; Layne, Bobby H.; Preses, Jack M.; Bernstein, Herbert J.; Wishart, James F.

    2015-04-27

    When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of a unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330-1051 cm⁻¹. The response time of the TRIR detection setup is ~40 ns, with a typical sensitivity of ~100 µOD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. As a result, this new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.

  9. Localization of polyhydroxybutyrate in sugarcane using Fourier-transform infrared microspectroscopy and multivariate imaging

    SciTech Connect (OSTI)

    Lupoi, Jason S.; Smith-Moritz, Andreia; Singh, Seema; McQualter, Richard; Scheller, Henrik V.; Simmons, Blake A.; Henry, Robert J.

    2015-07-10

    Background: Slow-degrading, fossil fuel-derived plastics can have deleterious effects on the environment, especially marine ecosystems. The production of bio-based, biodegradable plastics from or in plants can assist in supplanting those manufactured using fossil fuels. Polyhydroxybutyrate (PHB) is one such biodegradable polyester that has been evaluated as a possible candidate for relinquishing the use of environmentally harmful plastics. Results: PHB, possessing similar properties to polyesters produced from non-renewable sources, has been previously engineered in sugarcane, thereby creating a high-value co-product in addition to the high biomass yield. This manuscript illustrates the coupling of a Fourier-transform infrared microspectrometer, equipped with a focal plane array (FPA) detector, with multivariate imaging to successfully identify and localize PHB aggregates. Principal component analysis imaging facilitated the mining of the abundant quantity of spectral data acquired using the FPA for distinct PHB vibrational modes. PHB was measured in the chloroplasts of mesophyll and bundle sheath cells, acquiescent with previously evaluated plant samples. Conclusion: This study demonstrates the power of IR microspectroscopy to rapidly image plant sections to provide a snapshot of the chemical composition of the cell. While PHB was localized in sugarcane, this method is readily transferable to other value-added co-products in different plants.

  10. Localization of polyhydroxybutyrate in sugarcane using Fourier-transform infrared microspectroscopy and multivariate imaging

    DOE PAGES-Beta [OSTI]

    Lupoi, Jason S.; Smith-Moritz, Andreia; Singh, Seema; McQualter, Richard; Scheller, Henrik V.; Simmons, Blake A.; Henry, Robert J.

    2015-07-10

    Background: Slow-degrading, fossil fuel-derived plastics can have deleterious effects on the environment, especially marine ecosystems. The production of bio-based, biodegradable plastics from or in plants can assist in supplanting those manufactured using fossil fuels. Polyhydroxybutyrate (PHB) is one such biodegradable polyester that has been evaluated as a possible candidate for relinquishing the use of environmentally harmful plastics. Results: PHB, possessing similar properties to polyesters produced from non-renewable sources, has been previously engineered in sugarcane, thereby creating a high-value co-product in addition to the high biomass yield. This manuscript illustrates the coupling of a Fourier-transform infrared microspectrometer, equipped with a focalmore » plane array (FPA) detector, with multivariate imaging to successfully identify and localize PHB aggregates. Principal component analysis imaging facilitated the mining of the abundant quantity of spectral data acquired using the FPA for distinct PHB vibrational modes. PHB was measured in the chloroplasts of mesophyll and bundle sheath cells, acquiescent with previously evaluated plant samples. Conclusion: This study demonstrates the power of IR microspectroscopy to rapidly image plant sections to provide a snapshot of the chemical composition of the cell. While PHB was localized in sugarcane, this method is readily transferable to other value-added co-products in different plants.« less

  11. Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

    SciTech Connect (OSTI)

    Grills, David C. Farrington, Jaime A.; Layne, Bobby H.; Preses, Jack M.; Wishart, James F.; Bernstein, Herbert J.

    2015-04-15

    When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of a unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330 to 1051 cm{sup ?1}. The response time of the TRIR detection setup is ?40 ns, with a typical sensitivity of ?100 ?OD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. This new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.

  12. Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

    SciTech Connect (OSTI)

    Grills, David C.; Farrington, Jaime A.; Layne, Bobby H.; Preses, Jack M.; Bernstein, Herbert J.; Wishart, James F.

    2015-04-27

    When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of a unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330-1051 cm?. The response time of the TRIR detection setup is ~40 ns, with a typical sensitivity of ~100 OD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. As a result, this new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.

  13. Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

    DOE PAGES-Beta [OSTI]

    Grills, David C.; Farrington, Jaime A.; Layne, Bobby H.; Preses, Jack M.; Bernstein, Herbert J.; Wishart, James F.

    2015-04-27

    When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of amore » unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330-1051 cm⁻¹. The response time of the TRIR detection setup is ~40 ns, with a typical sensitivity of ~100 µOD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. As a result, this new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.« less

  14. CITIUS: An infrared-extreme ultraviolet light source for fundamental and applied ultrafast science

    SciTech Connect (OSTI)

    Grazioli, C.; Gauthier, D.; Ivanov, R.; De Ninno, G.; Elettra Sincrotrone Trieste, Trieste ; Callegari, C.; Spezzani, C.; Ciavardini, A.; Coreno, M.; Institute of Inorganic Methodologies and Plasmas , Montelibretti, Roma ; Frassetto, F.; Miotti, P.; Poletto, L.; Golob, D.; Kivimäki, A.; Mahieu, B.; Service des Photons Atomes et Molécules, Commissariat à l'Energie Atomique, Centre d'Etudes de Saclay, Bâtiment 522, 91191 Gif-sur-Yvette ; Bučar, B.; Merhar, M.; Polo, E.; Ressel, B.

    2014-02-15

    We present the main features of CITIUS, a new light source for ultrafast science, generating tunable, intense, femtosecond pulses in the spectral range from infrared to extreme ultraviolet (XUV). The XUV pulses (about 10{sup 5}-10{sup 8} photons/pulse in the range 14-80 eV) are produced by laser-induced high-order harmonic generation in gas. This radiation is monochromatized by a time-preserving monochromator, also allowing one to work with high-resolution bandwidth selection. The tunable IR-UV pulses (10{sup 12}-10{sup 15} photons/pulse in the range 0.4-5.6 eV) are generated by an optical parametric amplifier, which is driven by a fraction of the same laser pulse that generates high order harmonics. The IR-UV and XUV pulses follow different optical paths and are eventually recombined on the sample for pump-probe experiments. We also present the results of two pump-probe experiments: with the first one, we fully characterized the temporal duration of harmonic pulses in the time-preserving configuration; with the second one, we demonstrated the possibility of using CITIUS for selective investigation of the ultra-fast dynamics of different elements in a magnetic compound.

  15. A multi-wavelength view of the central kiloparsec region in the luminous infrared galaxy NGC 1614

    SciTech Connect (OSTI)

    Herrero-Illana, Rubén; Pérez-Torres, Miguel Á.; Alberdi, Antxon; Hernández-García, Lorena; Alonso-Herrero, Almudena; Colina, Luis; Efstathiou, Andreas; Miralles-Caballero, Daniel; Väisänen, Petri; Packham, Christopher C.; Rajpaul, Vinesh; Zijlstra, Albert A.

    2014-05-10

    The Luminous Infrared Galaxy NGC 1614 hosts a prominent circumnuclear ring of star formation. However, the nature of the dominant emitting mechanism in its central ∼100 pc is still under debate. We present sub-arcsecond angular resolution radio, mid-infrared, Paα, optical, and X-ray observations of NGC 1614, aimed at studying in detail both the circumnuclear ring and the nuclear region. The 8.4 GHz continuum emission traced by the Very Large Array and the Gemini/T-ReCS 8.7 μm emission, as well as the Paα line emission, show remarkable morphological similarities within the star-forming ring, suggesting that the underlying emission mechanisms are tightly related. We used a Hubble Space Telescope/NICMOS Paα map of similar resolution to our radio maps to disentangle the thermal free-free and non-thermal synchrotron radio emission, from which we obtained the intrinsic synchrotron power law for each individual region within the central kiloparsec of NGC 1614. The radio ring surrounds a relatively faint, steep-spectrum source at the very center of the galaxy, suggesting that the central source is not powered by an active galactic nucleus (AGN), but rather by a compact (r ≲ 90 pc) starburst (SB). Chandra X-ray data also show that the central kiloparsec region is dominated by SB activity, without requiring the existence of an AGN. We also used publicly available infrared data to model-fit the spectral energy distribution of both the SB ring and a putative AGN in NGC 1614. In summary, we conclude that there is no need to invoke an AGN to explain the observed bolometric properties of the galaxy.

  16. CHARACTERIZING ULTRAVIOLET AND INFRARED OBSERVATIONAL PROPERTIES FOR GALAXIES. I. INFLUENCES OF DUST ATTENUATION AND STELLAR POPULATION AGE

    SciTech Connect (OSTI)

    Mao Yewei; Kong Xu [Center for Astrophysics, University of Science and Technology of China, Hefei 230026 (China); Kennicutt, Robert C. Jr. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA (United Kingdom); Hao, Cai-Na [Tianjin Astrophysics Center, Tianjin Normal University, Tianjin 300387 (China); Zhou Xu, E-mail: owen81@mail.ustc.edu.cn, E-mail: xkong@ustc.edu.cn [National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2012-09-20

    The correlation between infrared-to-ultraviolet luminosity ratio and ultraviolet color (or ultraviolet spectral slope), i.e., the IRX-UV (or IRX-{beta}) relation, found in studies of starburst galaxies is a prevalent recipe for correcting extragalactic dust attenuation. Considerable dispersion in this relation discovered for normal galaxies, however, complicates its usability. In order to investigate the cause of the dispersion and to have a better understanding of the nature of the IRX-UV relation, in this paper, we select five nearby spiral galaxies, and perform spatially resolved studies on each of the galaxies, with a combination of ultraviolet and infrared imaging data. We measure all positions within each galaxy and divide the extracted regions into young and evolved stellar populations. By means of this approach, we attempt to discover separate effects of dust attenuation and stellar population age on the IRX-UV relation for individual galaxies. In this work, in addition to dust attenuation, stellar population age is interpreted to be another parameter in the IRX-UV function, and the diversity of star formation histories is suggested to disperse the age effects. At the same time, strong evidence shows the need for more parameters in the interpretation of observational data, such as variations in attenuation/extinction law. Fractional contributions of different components to the integrated luminosities of the galaxies suggest that the integrated measurements of these galaxies, which comprise different populations, would weaken the effect of the age parameter on IRX-UV diagrams. The dependence of the IRX-UV relation on luminosity and radial distance in galaxies presents weak trends, which offers an implication of selective effects. The two-dimensional maps of the UV color and the infrared-to-ultraviolet ratio are displayed and show a disparity in the spatial distributions between the two galaxy parameters, which offers a spatial interpretation of the scatter

  17. Laboratory determination of the infrared band strengths of pyrene frozen in water ice: Implications for the composition of interstellar ices

    SciTech Connect (OSTI)

    Hardegree-Ullman, E. E.; Gudipati, M. S.; Werner, M.; Boogert, A. C. A.; Lignell, H.; Allamandola, L. J.; Stapelfeldt, K. R. E-mail: gudipati@jpl.nasa.gov

    2014-04-01

    Broad infrared emission features (e.g., at 3.3, 6.2, 7.7, 8.6, and 11.3 ?m) from the gas phase interstellar medium have long been attributed to polycyclic aromatic hydrocarbons (PAHs). A significant portion (10%-20%) of the Milky Way's carbon reservoir is locked in PAH molecules, which makes their characterization integral to our understanding of astrochemistry. In molecular clouds and the dense envelopes and disks of young stellar objects (YSOs), PAHs are expected to be frozen in the icy mantles of dust grains where they should reveal themselves through infrared absorption. To facilitate the search for frozen interstellar PAHs, laboratory experiments were conducted to determine the positions and strengths of the bands of pyrene mixed with H{sub 2}O and D{sub 2}O ices. The D{sub 2}O mixtures are used to measure pyrene bands that are masked by the strong bands of H{sub 2}O, leading to the first laboratory determination of the band strength for the CH stretching mode of pyrene in water ice near 3.25 ?m. Our infrared band strengths were normalized to experimentally determined ultraviolet band strengths, and we find that they are generally ?50% larger than those reported by Bouwman et al. based on theoretical strengths. These improved band strengths were used to reexamine YSO spectra published by Boogert et al. to estimate the contribution of frozen PAHs to absorption in the 5-8 ?m spectral region, taking into account the strength of the 3.25 ?m CH stretching mode. It is found that frozen neutral PAHs contain 5%-9% of the cosmic carbon budget and account for 2%-9% of the unidentified absorption in the 5-8 ?m region.

  18. RESOLVED NEAR-INFRARED SPECTROSCOPY OF WISE J104915.57-531906.1AB: A FLUX-REVERSAL BINARY AT THE L DWARF/T DWARF TRANSITION

    SciTech Connect (OSTI)

    Burgasser, Adam J.; Sheppard, Scott S.; Luhman, K. L.

    2013-08-01

    We report resolved near-infrared spectroscopy and photometry of the recently identified brown dwarf binary WISE J104915.57-531906.1AB, located 2.02 {+-} 0.15 pc from the Sun. Low-resolution spectral data from Magellan/FIRE and IRTF/SpeX reveal strong H{sub 2}O and CO absorption features in the spectra of both components, while the secondary also exhibits weak CH{sub 4} absorption at 1.6 {mu}m and 2.2 {mu}m. Spectral indices and comparison to low-resolution spectral standards indicate component types of L7.5 and T0.5 {+-} 1, the former consistent with the optical classification of the primary. Both sources also have unusually red spectral energy distributions for their spectral types, which we attribute to enhanced condensate opacity (thick clouds). Relative photometry reveals a flux reversal between the J and K bands, with the T dwarf component being brighter in the 0.95-1.3 {mu}m region ({Delta}J = -0.31 {+-} 0.05). As with other L/T transition binaries, this reversal likely reflects the depletion of condensate opacity in the T dwarf, with the contrast enhanced by the thick clouds present in the photosphere of the L dwarf primary. The 1 {mu}m flux from the T dwarf most likely emerges from gaps in its cloud layer, as suggested by the significant optical variability detected from this source by Gillon et al. Component mass measurements of the WISE J1049-5319AB system through astrometric and component radial velocity monitoring may resolve the current debate as to whether the loss of photospheric condensate clouds at the L dwarf/T dwarf boundary is a slow or rapid process, a conceivable endeavor given its proximity, brightness, small separation (3.1 {+-} 0.3 AU), and reasonable orbital period (20-30 yr)

  19. Spectral, mechanical, thermal, optical and solid state parameters, of metal-organic bis(hydrogenmaleate)-CO(II) tetrahydrate crystal

    SciTech Connect (OSTI)

    Chandran, Senthilkumar; Jagan, R.; Paulraj, Rajesh; Ramasamy, P.

    2015-10-15

    Metal-organic bis(hydrogenmaleate)-Co(II) tetrahydrate single crystals have been grown by slow evaporation solution growth technique at room temperature. The crystal structure and the unit cell parameters were analyzed from the X-ray diffraction studies. Single-crystal X-ray diffraction analyses reveal that the grown crystal belongs to triclinic system with the space group P-1. Functional groups in bis(hydrogenmaleate)-Co(II) tetrahydrate were identified by Fourier transform infrared spectral analysis. The peak observed at 663 cm{sup −1} is assigned to the (Co–O) stretching vibrations. The optical transmission of the crystal was studied by UV–vis–NIR spectral analysis. The photoluminescence emission studies were carried out for the title compound in a wide wavelength range between 350 nm and 550 nm at 303 K. Mechanical strength was tested by Vickers microhardness test. The laser damage threshold value has been determined using Nd:YAG laser operating at 1064 nm. At various frequencies and temperatures the dielectric behavior of the material was investigated. Solid state parameters such as plasma energy, Penn gap, Fermi energy and electronic polarizability were evaluated. Photoconductivity measurements were carried out for the grown crystal in the presence of DC electric field at room temperature. Thermal stability and decomposition of the crystal were studied by TG–DTA. The weight loss of the title compound occurs in different steps. - Graphical abstract: Molecular structure of the bis(hydrogenmaleate)-Co(II) tetrahydrate drawn at 40% ellipsoid probability level. - Highlights: • Bis(hydrogenmaleate)-Co(II) tetrahydrate single crystal is grown by slow evaporation method. • Structural and optical properties were discussed. • The title complex crystal is thermally stable up to 91 °C. • Plasma energy, Fermi energy and electronic polarizability are evaluated. • It exhibits positive photoconductivity.

  20. Multivariate calibration techniques applied to NIRA (near infrared reflectance analysis) and FTIR (Fourier transform infrared) data

    SciTech Connect (OSTI)

    Long, C.L.

    1991-02-01

    Multivariate calibration techniques can reduce the time required for routine testing and can provide new methods of analysis. Multivariate calibration is commonly used with near infrared reflectance analysis (NIRA) and Fourier transform infrared (FTIR) spectroscopy. Two feasibility studies were performed to determine the capability of NIRA, using multivariate calibration techniques, to perform analyses on the types of samples that are routinely analyzed at this laboratory. The first study performed included a variety of samples and indicated that NIRA would be well-suited to perform analyses on selected materials properties such as water content and hydroxyl number on polyol samples, epoxy content on epoxy resins, water content of desiccants, and the amine values of various amine cure agents. A second study was performed to assess the capability of NIRA to perform quantitative analysis of hydroxyl numbers and water contents of hydroxyl-containing materials. Hydroxyl number and water content were selected for determination because these tests are frequently run on polyol materials and the hydroxyl number determination is time consuming. This study pointed out the necessity of obtaining calibration standards identical to the samples being analyzed for each type of polyol or other material being analyzed. Multivariate calibration techniques are frequently used with FTIR data to determine the composition of a large variety of complex mixtures. A literature search indicated many applications of multivariate calibration to FTIR data. Areas identified where quantitation by FTIR would provide a new capability are quantitation of components in epoxy and silicone resins, polychlorinated biphenyls (PCBs) in oils, and additives to polymers. 19 refs., 15 figs., 6 tabs.

  1. Spectral regularisation: induced gravity and the onset of inflation

    SciTech Connect (OSTI)

    Kurkov, Max A.; Sakellariadou, Mairi E-mail: mairi.sakellariadou@kcl.ac.uk

    2014-01-01

    Using spectral regularisation, we compute the Weyl anomaly and express the anomaly generating functional of the quantum effective action through a collective scalar degree of freedom of all quantum vacuum fluctuations. Such a formulation allows us to describe induced gravity on an equal footing with the anomaly-induced effective action, in a self-consistent way. We then show that requiring stability of the cosmological constant under loop quantum corrections, Sakharov's induced gravity and Starobinsky's anomaly-induced inflation are either both present or both absent, depending on the particle content of the theory.

  2. Spectral sum rules for the quark-gluon plasma

    SciTech Connect (OSTI)

    Romatschke, P.; Son, D. T.

    2009-09-15

    We derive sum rules involving the spectral density of the stress-energy tensor in N=4 super-Yang-Mills theory and pure Yang-Mills theory. The sum rules come from the hydrodynamic behavior at small momenta and the conformal (in the case of N=4 super-Yang-Mills theory) or asymptotically free (as for the pure Yang-Mills theory) behavior at large momenta. These sum rules may help constrain quark-gluon plasma transport coefficients obtained from lattice QCD.

  3. Nova-like cataclysmic variables in the infrared

    SciTech Connect (OSTI)

    Hoard, D. W.; Long, Knox S.; Howell, Steve B.; Wachter, Stefanie; Brinkworth, Carolyn S.; Knigge, Christian; Drew, J. E.; Szkody, Paula; Kafka, S.; Belle, Kunegunda; Ciardi, David R.; Froning, Cynthia S.; Van Belle, Gerard T.; Pretorius, M. L.

    2014-05-01

    Nova-like (NL) cataclysmic variables have persistently high mass transfer rates and prominent steady state accretion disks. We present an analysis of infrared observations of 12 NLs obtained from the Two Micron All Sky Survey, the Spitzer Space Telescope, and the Wide-field Infrared Survey Explorer All Sky Survey. The presence of an infrared excess at ? ? 3-5 ?m over the expectation of a theoretical steady state accretion disk is ubiquitous in our sample. The strength of the infrared excess is not correlated with orbital period, but shows a statistically significant correlation (but shallow trend) with system inclination that might be partially (but not completely) linked to the increasing view of the cooler outer accretion disk and disk rim at higher inclinations. We discuss the possible origin of the infrared excess in terms of emission from bremsstrahlung or circumbinary dust, with either mechanism facilitated by the mass outflows (e.g., disk wind/corona, accretion stream overflow, and so on) present in NLs. Our comparison of the relative advantages and disadvantages of either mechanism for explaining the observations suggests that the situation is rather ambiguous, largely circumstantial, and in need of stricter observational constraints.

  4. Suppressing spectral diffusion of emitted photons with optical pulses

    DOE PAGES-Beta [OSTI]

    Fotso, H. F.; Feiguin, A. E.; Awschalom, D. D.; Dobrovitski, V. V.

    2016-01-22

    In many quantum architectures the solid-state qubits, such as quantum dots or color centers, are interfaced via emitted photons. However, the frequency of photons emitted by solid-state systems exhibits slow uncontrollable fluctuations over time (spectral diffusion), creating a serious problem for implementation of the photon-mediated protocols. Here we show that a sequence of optical pulses applied to the solid-state emitter can stabilize the emission line at the desired frequency. We demonstrate efficiency, robustness, and feasibility of the method analytically and numerically. Taking nitrogen-vacancy center in diamond as an example, we show that only several pulses, with the width of 1more » ns, separated by few ns (which is not difficult to achieve) can suppress spectral diffusion. As a result, our method provides a simple and robust way to greatly improve the efficiency of photon-mediated entanglement and/or coupling to photonic cavities for solid-state qubits.« less

  5. Multi-Spectral Detection of Microfluidic Separation Products.

    SciTech Connect (OSTI)

    Hayden, Carl C.; Meagher, Robert

    2007-12-01

    The objectives of this project were to develop a new scientific tool for studies of chemical processes at the single molecule level, and to provide enhanced capabilities for multiplexed, ultrasensitive separations and immunoassays. We have combined microfluidic separation techniques with our newly developed technology for spectrally and temporally resolved detection of single molecules. The detection of individual molecules can reveal fluctuations in molecular conformations, which are obscured in ensemble measurements, and allows detailed studies of reaction kinetics such as ligand or antibody binding. Detection near the single molecule level also enables the use of correlation techniques to extract information, such as diffusion rates, from the fluorescence signal. The micro-fluidic technology offers unprecedented control of the chemical environment and flow conditions, and affords the unique opportunity to study biomolecules without immobilization. For analytical separations, the fluorescence lifetime and spectral resolution of the detection makes it possible to use multiple parameters for identification of separation products to improve the certainty of identification. We have successfully developed a system that can measure fluorescence spectra, lifetimes and diffusion constants of the components of mixtures separated in a microfluidic electrophoresis chip.

  6. Spectral statistics in noninteracting many-particle systems

    SciTech Connect (OSTI)

    Munoz, L.; Relano, A.; Retamosa, J. [Departamento de Fisica Atomica, Molecular y Nuclear, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Faleiro, E. [Departamento de Fisica Aplicada, E.U.I.T. Industrial, Universidad Politecnica de Madrid, E-28012 Madrid (Spain); Molina, R.A. [Max-Planck-Institut fuer Physik Komplexer Systeme, Noethnitzer Strasse 38, D-01187 Dresden (Germany)

    2006-03-15

    It is widely accepted that the statistical properties of energy level spectra provide an essential characterization of quantum chaos. Indeed, the spectral fluctuations of many different systems like quantum billiards, atoms, or atomic nuclei have been studied. However, noninteracting many-body systems have received little attention, since it is assumed that they must exhibit Poisson-like fluctuations. Apart from a heuristic argument of Bloch, there are neither systematic numerical calculations nor a rigorous derivation of this fact. Here we present a rigorous study of the spectral fluctuations of noninteracting identical particles moving freely in a mean field emphasizing the evolution with the number of particles N as well as with the energy. Our results are conclusive. For N{>=}2 the spectra of these systems exhibit Poisson fluctuations provided that we consider sufficiently high excitation energies. Nevertheless, when the mean field is chaotic there exists a critical energy scale L{sub c}; beyond this scale, the fluctuations deviate from the Poisson statistics as a reminiscence of the statistical properties of the mean field.

  7. Numeric spectral radiation hydrodynamic calculations of supernova shock breakouts

    SciTech Connect (OSTI)

    Sapir, Nir; Halbertal, Dorri

    2014-12-01

    We present here an efficient numerical scheme for solving the non-relativistic one-dimensional radiation-hydrodynamics equations including inelastic Compton scattering, which is not included in most codes and is crucial for solving problems such as shock breakout. The devised code is applied to the problems of a steady-state planar radiation mediated shock (RMS) and RMS breakout from a stellar envelope. The results are in agreement with those of a previous work on shock breakout, in which Compton equilibrium between matter and radiation was assumed and the 'effective photon' approximation was used to describe the radiation spectrum. In particular, we show that the luminosity and its temporal dependence, the peak temperature at breakout, and the universal shape of the spectral fluence derived in this earlier work are all accurate. Although there is a discrepancy between the spectral calculations and the effective photon approximation due to the inaccuracy of the effective photon approximation estimate of the effective photon production rate, which grows with lower densities and higher velocities, the difference in peak temperature reaches only 30% for the most discrepant cases of fast shocks in blue supergiants. The presented model is exemplified by calculations for supernova 1987A, showing the detailed evolution of the burst spectrum. The incompatibility of the stellar envelope shock breakout model results with observed properties of X-ray flashes (XRFs) and the discrepancy between the predicted and observed rates of XRFs remain unexplained.

  8. Three new cool brown dwarfs discovered with the wide-field infrared survey explorer (WISE) and an improved spectrum of the Y0 dwarf wise J041022.71+150248.4

    SciTech Connect (OSTI)

    Cushing, Michael C.; Kirkpatrick, J. Davy; Gelino, Christopher R.; Mace, Gregory N.; Skrutskie, Michael F.; Gould, Andrew

    2014-05-01

    As part of a larger search of Wide-field Infrared Survey Explorer (WISE) data for cool brown dwarfs with effective temperatures less than 1000 K, we present the discovery of three new cool brown dwarfs with spectral types later than T7. Using low-resolution, near-infrared spectra obtained with the NASA Infrared Telescope Facility and the Hubble Space Telescope, we derive spectral types of T9.5 for WISE J094305.98+360723.5, T8 for WISE J200050.19+362950.1, and Y0: for WISE J220905.73+271143.9. The identification of WISE J220905.73+271143.9 as a Y dwarf brings the total number of spectroscopically confirmed Y dwarfs to 17. In addition, we present an improved spectrum (i.e., higher signal-to-noise ratio) of the Y0 dwarf WISE J041022.71+150248.4 that confirms the Cushing et al. classification of Y0. Spectrophotometric distance estimates place all three new brown dwarfs at distances less than 12 pc, with WISE J200050.19+362950.1 lying at a distance of only 3.9-8.0 pc. Finally, we note that brown dwarfs like WISE J200050.19+362950.1 that lie in or near the Galactic plane offer an exciting opportunity to directly measure the mass of a brown dwarf via astrometric microlensing.

  9. Hard, infrared black coating with very low outgassing

    SciTech Connect (OSTI)

    Kuzmenko, P J; Behne, D M; Casserly, T; Boardman, W; Upadhyaya, D; Boinapally, K; Gupta, M; Cao, Y

    2008-06-02

    Infrared astronomical instruments require absorptive coatings on internal surfaces to trap scattered and stray photons. This is typically accomplished with any one of a number of black paints. Although inexpensive and simple to apply, paint has several disadvantages. Painted surfaces can be fragile, prone to shedding particles, and difficult to clean. Most importantly, the vacuum performance is poor. Recently a plasma enhanced chemical vapor deposition (PECVD) process was developed to apply thick (30 {micro}m) diamond-like carbon (DLC) based protective coatings to the interior of oil pipelines. These DLC coatings show much promise as an infrared black for an ultra high vacuum environment. The coatings are very robust with excellent cryogenic adhesion. Their total infrared reflectivity of < 10% at normal incidence approaches that of black paints. We measured outgas rates of <10{sup -12} Torr liter/sec cm{sup 2}, comparable to bare stainless steel.

  10. Blocked impurity band hybrid infrared focal plane arrays for astronomy

    SciTech Connect (OSTI)

    Reynolds, D.B.; Seib, D.H.; Stetson, S.B.; Herter, T.; Rowlands, N.; Schoenwald, J.

    1989-02-01

    High-performance infrared hybrid focal plane arrays using 10 x 50 element Si:As Blocked-Impurity-Band (BIB) detectors (cut-off wavelength = 28 ..mu..m) and matching switched MOSFET multiplexers have been developed and characterized for space astronomy. Use of impurity band conduction technology provides detectors which are nuclear radiation hard and free of the many anomalies associated with conventional silicon photoconductive detectors. Emphasis in this paper is on recent advances in detector material quality which have led to significantly improved detector and hybrid characteristics. Results demonstrating increase quantum efficiency (particular at short wavelength infrared), obtained by varying the Blocked-Impurity-Band detector properties (infrared active layer thickness and arsenic doping profile), are summarized. Read noise and dark current for different temperatures have been measured and are also described. The hybrid array performance achieved clearly demonstrates that BIB detectors are well suited for use in astronomical instrumentation.

  11. Noise Reduction Efforts for the ALS Infrared Beamlines

    SciTech Connect (OSTI)

    Scarvie, Tom; Andresen, Nord; Baptiste, Ken; Byrd, John; Chin, Mike; Martin, Michael; McKinney, Wayne; Steier, Christoph

    2004-05-12

    The quality of infrared microscopy and spectroscopy data collected at synchrotron based sources is strongly dependent on signal-to-noise. We have successfully identified and suppressed several noise sources affecting Beamlines 1.4.2, 1.4.3, and 1.4.4 at the Advanced Light Source (ALS), resulting in a significant increase in the quality of FTIR spectra obtained. In this paper, we present our methods of noise source analysis, the negative effect of noise on the infrared beam quality, and the techniques used to reduce the noise. These include reducing the phase noise in the storage ring radio-frequency (RF) system, installing an active mirror feedback system, analyzing and changing physical mounts to better isolate portions of the beamline optics from low-frequency environmental noise, and modifying the input signals to the main ALS RF system. We also discuss the relationship between electron beam energy oscillations at a point of dispersion and infrared beamline noise.

  12. High speed infrared radiation thermometer, system, and method

    DOE Patents [OSTI]

    Markham, James R. (Middlefield, CT)

    2002-01-01

    The high-speed radiation thermometer has an infrared measurement wavelength band that is matched to the infrared wavelength band of near-blackbody emittance of ceramic components and ceramic thermal barrier coatings used in turbine engines. It is comprised of a long wavelength infrared detector, a signal amplifier, an analog-to-digital converter, an optical system to collect radiation from the target, an optical filter, and an integral reference signal to maintain a calibrated response. A megahertz range electronic data acquisition system is connected to the radiation detector to operate on raw data obtained. Because the thermometer operates optimally at 8 to 12 .mu.m, where emittance is near-blackbody for ceramics, interferences to measurements performed in turbine engines are minimized. The method and apparatus are optimized to enable mapping of surface temperatures on fast moving ceramic elements, and the thermometer can provide microsecond response, with inherent self-diagnostic and calibration-correction features.

  13. Apparatus for generating coherent infrared energy of selected wavelength

    DOE Patents [OSTI]

    Stevens, Charles G.

    1985-01-01

    A tunable source (11) of coherent infrared energy includes a heat pipe (12) having an intermediate region (24) at which cesium (22) is heated to vaporizing temperature and end regions (27, 28) at which the vapor is condensed and returned to the intermediate region (24) for reheating and recirculation. Optical pumping light (43) is directed along the axis of the heat pipe (12) through a first end window (17) to stimulate emission of coherent infrared energy which is transmitted out through an opposite end window (18). A porous walled tubulation (44) extends along the axis of the heat pipe (12) and defines a region (46) in which cesium vapor is further heated to a temperature sufficient to dissociate cesium dimers which would decrease efficiency by absorbing pump light (43). Efficient generation of any desired infrared wavelength is realized by varying the wavelength of the pump light (43).

  14. Antenna-coupled microcavities for enhanced infrared photo-detection

    SciTech Connect (OSTI)

    Nga Chen, Yuk; Todorov, Yanko Askenazi, Benjamin; Vasanelli, Angela; Sirtori, Carlo; Biasiol, Giorgio; Colombelli, Raffaele

    2014-01-20

    We demonstrate mid-infrared detectors embedded into an array of double-metal nano-antennas. The antennas act as microcavities that squeeze the electric field into thin semiconductor layers, thus enhancing the detector responsivity. Furthermore, thanks to the ability of the antennas to gather photons from an area larger than the device's physical dimensions, the dark current is reduced without hindering the photo-generation rate. In these devices, the background-limited performance is improved with a consequent increase of the operating temperature. Our results illustrate how the antenna-coupled microcavity concept can be applied to enhance the performances of infrared opto-electronic devices.

  15. Infrared absorption spectroscopy and chemical kinetics of free radicals

    SciTech Connect (OSTI)

    Curl, R.F.; Glass, G.P.

    1993-12-01

    This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

  16. A far-infrared spectroscopic survey of intermediate redshift (ultra) luminous infrared galaxies

    SciTech Connect (OSTI)

    Magdis, Georgios E.; Rigopoulou, D.; Hopwood, R.; Clements, D.; Huang, J.-S.; Farrah, D.; Pearson, C.; Alonso-Herrero, Almudena; Bock, J. J.; Cooray, A.; Griffin, M. J.; Oliver, S.; Perez Fournon, I.; Riechers, D.; Swinyard, B. M.; Thatte, N.; Scott, D.; Valtchanov, I.; Vaccari, M.

    2014-11-20

    We present Herschel far-IR photometry and spectroscopy as well as ground-based CO observations of an intermediate redshift (0.21 ? z ? 0.88) sample of Herschel-selected (ultra)-luminous infrared galaxies (L {sub IR} > 10{sup 11.5} L {sub ?}). With these measurements, we trace the dust continuum, far-IR atomic line emission, in particular [C II] 157.7 ?m, as well as the molecular gas of z ? 0.3 luminous and ultraluminous infrared galaxies (LIRGs and ULIRGs) and perform a detailed investigation of the interstellar medium of the population. We find that the majority of Herschel-selected intermediate redshift (U)LIRGs have L {sub C} {sub II}/L {sub FIR} ratios that are a factor of about 10 higher than that of local ULIRGs and comparable to that of local normal and high-z star-forming galaxies. Using our sample to bridge local and high-z [C II] observations, we find that the majority of galaxies at all redshifts and all luminosities follow an L {sub C} {sub II}L {sub FIR} relation with a slope of unity, from which local ULIRGs and high- z active-galactic-nucleus-dominated sources are clear outliers. We also confirm that the strong anti-correlation between the L {sub C} {sub II}/L {sub FIR} ratio and the far-IR color L {sub 60}/L {sub 100} observed in the local universe holds over a broad range of redshifts and luminosities, in the sense that warmer sources exhibit lower L {sub C} {sub II}/L {sub FIR} at any epoch. Intermediate redshift ULIRGs are also characterized by large molecular gas reservoirs and by lower star formation efficiencies compared to that of local ULIRGs. The high L {sub C} {sub II}/L {sub FIR} ratios, the moderate star formation efficiencies (L {sub IR}/L{sub CO}{sup ?} or L {sub IR}/M{sub H{sub 2}}), and the relatively low dust temperatures of our sample (which are also common characteristics of high-z star-forming galaxies with ULIRG-like luminosities) indicate that the evolution of the physical properties of (U)LIRGs between the present day and z

  17. SPECTRAL ENERGY DISTRIBUTIONS OF TYPE 1 ACTIVE GALACTIC NUCLEI IN THE COSMOS SURVEY. I. THE XMM-COSMOS SAMPLE

    SciTech Connect (OSTI)

    Elvis, M.; Hao, H.; Civano, F.; Brusa, M.; Salvato, M.; Bongiorno, A.; Cappelluti, N.; Capak, P.; Zamorani, G.; Comastri, A.; Gilli, R.; Jahnke, K.; Lusso, E.; Cisternas, M.; Mainieri, V.; Trump, J. R.; Ho, L. C.; Aussel, H.; Frayer, D.; Hasinger, G. E-mail: hhao@cfa.harvard.edu; and others

    2012-11-01

    The 'Cosmic Evolution Survey' (COSMOS) enables the study of the spectral energy distributions (SEDs) of active galactic nuclei (AGNs) because of the deep coverage and rich sampling of frequencies from X-ray to radio. Here we present an SED catalog of 413 X-ray (XMM-Newton)-selected type 1 (emission line FWHM > 2000 km s{sup -1}) AGNs with Magellan, SDSS, or VLT spectrum. The SEDs are corrected for Galactic extinction, broad emission line contributions, constrained variability, and host galaxy contribution. We present the mean SED and the dispersion SEDs after the above corrections in the rest-frame 1.4 GHz to 40 keV, and show examples of the variety of SEDs encountered. In the near-infrared to optical (rest frame {approx}8 {mu}m-4000 A), the photometry is complete for the whole sample and the mean SED is derived from detections only. Reddening and host galaxy contamination could account for a large fraction of the observed SED variety. The SEDs are all available online.

  18. High-efficiency spectral purity filter for EUV lithography

    DOE Patents [OSTI]

    Chapman, Henry N.

    2006-05-23

    An asymmetric-cut multilayer diffracts EUV light. A multilayer cut at an angle has the same properties as a blazed grating, and has been demonstrated to have near-perfect performance. Instead of having to nano-fabricate a grating structure with imperfections no greater than several tens of nanometers, a thick multilayer is grown on a substrate and then cut at an inclined angle using coarse and inexpensive methods. Effective grating periods can be produced this way that are 10 to 100 times smaller than those produced today, and the diffraction efficiency of these asymmetric multilayers is higher than conventional gratings. Besides their ease of manufacture, the use of an asymmetric multilayer as a spectral purity filter does not require that the design of an EUV optical system be modified in any way, unlike the proposed use of blazed gratings for such systems.

  19. A spectral unaveraged algorithm for free electron laser simulations

    SciTech Connect (OSTI)

    Andriyash, I.A.; Lehe, R.; Malka, V.

    2015-02-01

    We propose and discuss a numerical method to model electromagnetic emission from the oscillating relativistic charged particles and its coherent amplification. The developed technique is well suited for free electron laser simulations, but it may also be useful for a wider range of physical problems involving resonant field–particles interactions. The algorithm integrates the unaveraged coupled equations for the particles and the electromagnetic fields in a discrete spectral domain. Using this algorithm, it is possible to perform full three-dimensional or axisymmetric simulations of short-wavelength amplification. In this paper we describe the method, its implementation, and we present examples of free electron laser simulations comparing the results with the ones provided by commonly known free electron laser codes.

  20. Spectrally Enhanced Lighting Program Implementation for Energy Savings: Field Evaluation

    SciTech Connect (OSTI)

    Gordon, Kelly L.; Sullivan, Gregory P.; Armstrong, Peter R.; Richman, Eric E.; Matzke, Brett D.

    2006-08-22

    This report provides results from an evaluation PNNL conducted of a spectrally enhanced lighting demonstration project. PNNL performed field measurements and occupant surveys at three office buildings in California before and after lighting retrofits were made in August and December 2005. PNNL measured the following Overhead lighting electricity demand and consumption, Light levels in the workspace, Task lighting use, and Occupant ratings of satisfaction with the lighting. Existing lighting, which varied in each building, was replaced with lamps with correlated color temperature (CCT) of 5000 Kelvin, color rendering index (CRI) of 85, of varying wattages, and lower ballast factor electronic ballasts. The demonstrations were designed to decrease lighting power loads in the three buildings by 22-50 percent, depending on the existing installed lamps and ballasts. The project designers hypothesized that this reduction in electrical loads could be achieved by the change to higher CCT lamps without decreasing occupant satisfaction with the lighting.

  1. Spectral and temperature correction of silicon photovoltaic solar radiation detectors

    SciTech Connect (OSTI)

    Michalsky, J.J.; Perez, R.; Harrison, L. ); LeBaron, B.A. )

    1991-01-01

    Silicon photovoltaic sensors are an inexpensive alternative to standard thermopile sensors for the measurement of solar radiation. However, their temperature and spectral response render them less accurate for global horizontal irradiance and unsuitable for direct beam and diffuse horizontal irradiance unless they can be reliably corrected. A correction procedure for the rotating shadowband radiometer, which measures all three components, based on a three-way parameterization of the solar position and sky conditions is proposed. After correction, root-mean-square errors for the global and diffuse horizontal irradiance and the direct normal irradiance are about 10, 12, and 13 W/m{sup 2} in comparison with coincident, 5-minute thermopile measurements. While the numerical results are specific to the rotating shadowband instrument, the correction algorithm should apply universally.

  2. Method for detection and imaging over a broad spectral range

    DOE Patents [OSTI]

    Yefremenko, Volodymyr (Westmont, IL); Gordiyenko, Eduard (Westmont, IL); Pishko, legal representative, Olga (Kharkov, UA); Novosad, Valentyn (Chicago, IL); Pishko, deceased; Vitalii (Westmont, IL)

    2007-09-25

    A method of controlling the coordinate sensitivity in a superconducting microbolometer employs localized light, heating or magnetic field effects to form normal or mixed state regions on a superconducting film and to control the spatial location. Electron beam lithography and wet chemical etching were applied as pattern transfer processes in epitaxial Y--Ba--Cu--O films. Two different sensor designs were tested: (i) a 3 millimeter long and 40 micrometer wide stripe and (ii) a 1.25 millimeters long, and 50 micron wide meandering-like structure. Scanning the laser beam along the stripe leads to physical displacement of the sensitive area, and, therefore, may be used as a basis for imaging over a broad spectral range. Forming the superconducting film as a meandering structure provides the equivalent of a two-dimensional detector array. Advantages of this approach are simplicity of detector fabrication, and simplicity of the read-out process requiring only two electrical terminals.

  3. ARM - Recovery Act Instruments

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    (300 to 2000 nm) Connor Flynn Solar Spectrometry Solar spectral radiance and irradiance Doppler Lidar (353 nm) Rob Newsom Lidars Clear air vertical velocities and cloud...

  4. REGULATION OF THE SPECTRAL PEAK IN GAMMA-RAY BURSTS

    SciTech Connect (OSTI)

    Beloborodov, Andrei M.

    2013-02-20

    Observations indicate that the peak of a gamma-ray burst spectrum forms in the opaque region of an ultrarelativistic jet. Recent radiative transfer calculations support this picture and show that the spectral peak is inherited from initially thermal radiation, which is changed by heating into a broad photon distribution with a high-energy tail. We discuss the processes that regulate the observed position of the spectral peak E {sub pk}. The opaque jet has three radial zones: (1) the Planck zone r < R {sub P} where a blackbody spectrum is enforced; this zone ends where the Thomson optical depth decreases to {tau} Almost-Equal-To 10{sup 5}, (2) the Wien zone R {sub P} < r < R {sub W} with a Kompaneets parameter y >> 1 where radiation has a Bose-Einstein spectrum, and (3) the Comptonization zone r > R {sub W} where the radiation spectrum develops a high-energy tail. Besides the initial jet temperature, an important factor regulating E {sub pk} is internal dissipation (of bulk motions and magnetic energy) at large distances from the central engine. Dissipation in the Planck zone reduces E {sub pk}, and dissipation in the Wien zone can increase E {sub pk}. In jets with subdominant magnetic fields, the predicted E {sub pk} varies around 1 MeV up to a maximum value of about 10 MeV. If the jet carries an energetically important magnetic field, E {sub pk} can be additionally increased by dissipation of magnetic energy. This increase is suggested by observations, which show E {sub pk} up to about 20 MeV. We also consider magnetically dominated jets; then a simple model of magnetic dissipation gives E {sub pk} Almost-Equal-To 30 {Gamma}{sub W} keV where {Gamma}{sub W} is the jet Lorentz factor at the Wien radius R {sub W}.

  5. THE AKARI 2.5-5.0 ?m SPECTRAL ATLAS OF TYPE-1 ACTIVE GALACTIC NUCLEI: BLACK HOLE MASS ESTIMATOR, LINE RATIO, AND HOT DUST TEMPERATURE

    SciTech Connect (OSTI)

    Kim, Dohyeong; Im, Myungshin; Kim, Ji Hoon; Jun, Hyunsung David; Lee, Seong-Kook; Woo, Jong-Hak; Lee, Hyung Mok; Lee, Myung Gyoon; Nakagawa, Takao; Matsuhara, Hideo; Wada, Takehiko; Takagi, Toshinobu; Oyabu, Shinki; Ohyama, Youichi E-mail: mim@astro.snu.ac.kr

    2015-01-01

    We present 2.5-5.0?m spectra of 83 nearby (0.002 < z < 0.48) and bright (K < 14 mag) type-1 active galactic nuclei (AGNs) taken with the Infrared Camera on board AKARI. The 2.5-5.0?m spectral region contains emission lines such as Br? (2.63?m), Br? (4.05?m), and polycyclic aromatic hydrocarbons (3.3?m), which can be used for studying the black hole (BH) masses and star formation activity in the host galaxies of AGNs. The spectral region also suffers less dust extinction than in the ultra violet (UV) or optical wavelengths, which may provide an unobscured view of dusty AGNs. Our sample is selected from bright quasar surveys of Palomar-Green and SNUQSO, and AGNs with reverberation-mapped BH masses from Peterson etal. Using 11 AGNs with reliable detection of Brackett lines, we derive the Brackett-line-based BH mass estimators. We also find that the observed Brackett line ratios can be explained with the commonly adopted physical conditions of the broad line region. Moreover, we fit the hot and warm dust components of the dust torus by adding photometric data of SDSS, 2MASS, WISE, and ISO to the AKARI spectra, finding hot and warm dust temperatures of ?1100 K and ?220 K, respectively, rather than the commonly cited hot dust temperature of 1500 K.

  6. Measurement of directional thermal infrared emissivity of vegetation and soils

    SciTech Connect (OSTI)

    Norman, J.M. [Wisconsin Univ., Madison, WI (United States). Dept. of Soil Science; Balick, L.K. [EG and G Energy Measurements, Inc., Las Vegas, NV (United States)

    1995-10-01

    A new method has been developed for measuring directional thermal emissivity as a function of view angle for plant canopies and soils using two infrared thermometers each sensitive to a different wavelength band. By calibrating the two infrared thermometers to 0.1C consistency, canopy directional emissivity can be estimated with typical errors less than 0.005 in the 8--14 um wavelength band, depending on clarity of the sky and corrections for CO{sub 2} absorption by the atmosphere. A theoretical justification for the method is developed along with an error analysis. Laboratory measurements were used to develop corrections for CO{sub 2}, absorption and a field calibration method is used to obtain the necessary 0.1C consistency for relatively low cost infrared thermometers. The emissivity of alfalfa (LAI=2.5) and corn (LAI=3.2) was near 0.995 and independent of view angle. Individual corn leaves had an emissivity of 0.97. A wheat (LAI=3.0) canopy had an emissivity of 0.985 at nadir and 0.975 at 75 degree view angle. The canopy emissivity values tend to be higher than values in the literature, and are useful for converting infrared thermometer measurements to kinetic temperature and interpreting satellite thermal observations.

  7. Emissivity corrected infrared method for imaging anomalous structural heat flows

    DOE Patents [OSTI]

    Del Grande, Nancy K.; Durbin, Philip F.; Dolan, Kenneth W.; Perkins, Dwight E.

    1995-01-01

    A method for detecting flaws in structures using dual band infrared radiation. Heat is applied to the structure being evaluated. The structure is scanned for two different wavelengths and data obtained in the form of images. Images are used to remove clutter to form a corrected image. The existence and nature of a flaw is determined by investigating a variety of features.

  8. Galaxy Evolution Insights from Spectral Modeling of Large Data Sets from the Sloan Digital Sky Survey

    SciTech Connect (OSTI)

    Hoversten, Erik A.; /Johns Hopkins U.

    2007-10-01

    This thesis centers on the use of spectral modeling techniques on data from the Sloan Digital Sky Survey (SDSS) to gain new insights into current questions in galaxy evolution. The SDSS provides a large, uniform, high quality data set which can be exploited in a number of ways. One avenue pursued here is to use the large sample size to measure precisely the mean properties of galaxies of increasingly narrow parameter ranges. The other route taken is to look for rare objects which open up for exploration new areas in galaxy parameter space. The crux of this thesis is revisiting the classical Kennicutt method for inferring the stellar initial mass function (IMF) from the integrated light properties of galaxies. A large data set ({approx} 10{sup 5} galaxies) from the SDSS DR4 is combined with more in-depth modeling and quantitative statistical analysis to search for systematic IMF variations as a function of galaxy luminosity. Galaxy H{alpha} equivalent widths are compared to a broadband color index to constrain the IMF. It is found that for the sample as a whole the best fitting IMF power law slope above 0.5 M{sub {circle_dot}} is {Lambda} = 1.5 {+-} 0.1 with the error dominated by systematics. Galaxies brighter than around M{sub r,0.1} = -20 (including galaxies like the Milky Way which has M{sub r,0.1} {approx} -21) are well fit by a universal {Lambda} {approx} 1.4 IMF, similar to the classical Salpeter slope, and smooth, exponential star formation histories (SFH). Fainter galaxies prefer steeper IMFs and the quality of the fits reveal that for these galaxies a universal IMF with smooth SFHs is actually a poor assumption. Related projects are also pursued. A targeted photometric search is conducted for strongly lensed Lyman break galaxies (LBG) similar to MS1512-cB58. The evolution of the photometric selection technique is described as are the results of spectroscopic follow-up of the best targets. The serendipitous discovery of two interesting blue compact dwarf

  9. Facile synthesis, spectral properties and formation mechanism of sulfur nanorods in PEG-200

    SciTech Connect (OSTI)

    Xie, Xin-yuan; Li, Li-yun; Zheng, Pu-sheng; Zheng, Wen-jie; Bai, Yan; Cheng, Tian-feng; Liu, Jie

    2012-11-15

    Graphical abstract: Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of about 68 was obtained. The sulfur nanoparticles could self-assemble from spherical particles to nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift which was due to the production of nanorods. Highlights: ? A novel, facile and greener method to synthesize sulfur nanorods by the solubilizing and templating effect of PEG-200 was reported. ? S{sup 0} nanoparticles could self assemble in PEG-200 and finally form monodisperse and homogeneous rod-like structure with an average diameter of about 80 nm, the length ca. 600 nm. ? The absorption band showed a red shift and the RRS intensity enhanced continuously during the self-assembling process. ? PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. -- Abstract: The synthesis of nano-sulfur sol by dissolving sublimed sulfur in a green solvent-PEG-200 was studied. Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of 68 was obtained. The structure, morphology, size, and stability of the products were investigated by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering (DLS) measurements. The spectral properties of the products were investigated by ultraviolet-visible (UVvis) absorption and resonance Rayleigh scattering spectroscopy (RRS). The results showed that the spherical sulfur nanoparticles could self-assemble into nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift and the RRS intensity enhanced continuously. There was physical cross-linking between PEG and sulfur nanoparticles. PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal

  10. ARM Climate Research Facility Spectral Surface Albedo Value-Added Product (VAP) Report

    SciTech Connect (OSTI)

    McFarlane, S; Gaustad, K; Long, C; Mlawer, E

    2011-07-15

    This document describes the input requirements, output data products, and methodology for the Spectral Surface Albedo (SURFSPECALB) value-added product (VAP). The SURFSPECALB VAP produces a best-estimate near-continuous high spectral resolution albedo data product using measurements from multifilter radiometers (MFRs). The VAP first identifies best estimates for the MFR downwelling and upwelling shortwave irradiance values, and then calculates narrowband spectral albedo from these best-estimate irradiance values. The methodology for finding the best-estimate values is based on a simple process of screening suspect data and backfilling screened and missing data with estimated values when possible. The resulting best-estimate MFR narrowband spectral albedos are used to determine a daily surface type (snow, 100% vegetation, partial vegetation, or 0% vegetation). For non-snow surfaces, a piecewise continuous function is used to estimate a high spectral resolution albedo at 1 min temporal and 10 cm-1 spectral resolution.

  11. Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability presentation at the April 2013 peer review meeting held in Denver, Colorado. hawaii_geophysics_planetology_peer2013.pdf (439.06 KB) More Documents & Publications Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and

  12. INFRARED ECLIPSES OF THE STRONGLY IRRADIATED PLANET WASP-33b, AND OSCILLATIONS OF ITS HOST STAR

    SciTech Connect (OSTI)

    Deming, Drake; Fraine, Jonathan D.; Sada, Pedro V.; Madhusudhan, Nikku; Knutson, Heather A.; Harrington, Joseph; Blecic, Jasmina; Nymeyer, Sarah; Smith, Alexis M. S.; Jackson, Brian

    2012-08-01

    We observe two secondary eclipses of the strongly irradiated transiting planet WASP-33b, in the K{sub s} band at 2.15 {mu}m, and one secondary eclipse each at 3.6 {mu}m and 4.5 {mu}m using Warm Spitzer. This planet orbits an A5V {delta}-Scuti star that is known to exhibit low-amplitude non-radial p-mode oscillations at about 0.1% semi-amplitude. We detect stellar oscillations in all of our infrared eclipse data, and also in one night of observations at J band (1.25 {mu}m) out of eclipse. The oscillation amplitude, in all infrared bands except K{sub s} , is about the same as in the optical. However, the stellar oscillations in K{sub s} band (2.15 {mu}m) have about twice the amplitude (0.2%) as seen in the optical, possibly because the Brackett-{gamma} line falls in this bandpass. As regards the exoplanetary eclipse, we use our best-fit values for the eclipse depth, as well as the 0.9 {mu}m eclipse observed by Smith et al., to explore possible states of the exoplanetary atmosphere, based on the method of Madhusudhan and Seager. On this basis we find two possible states for the atmospheric structure of WASP-33b. One possibility is a non-inverted temperature structure in spite of the strong irradiance, but this model requires an enhanced carbon abundance (C/O > 1). The alternative model has solar composition, but an inverted temperature structure. Spectroscopy of the planet at secondary eclipse, using a spectral resolution that can resolve the water vapor band structure, should be able to break the degeneracy between these very different possible states of the exoplanetary atmosphere. However, both of those model atmospheres absorb nearly all of the stellar irradiance with minimal longitudinal re-distribution of energy, strengthening the hypothesis of Cowan and Agol that the most strongly irradiated planets circulate energy poorly. Our measurement of the central phase of the eclipse yields ecos {omega} = 0.0003 {+-} 0.00013, which we regard as being consistent with a

  13. THE NUCLEAR INFRARED EMISSION OF LOW-LUMINOSITY ACTIVE GALACTIC NUCLEI

    SciTech Connect (OSTI)

    Mason, R. E.; Lopez-Rodriguez, E.; Packham, C.; Alonso-Herrero, A.; Elitzur, M.; Aretxaga, I.; Roche, P. F.; Oi, N.

    2012-07-15

    We present high-resolution mid-infrared (MIR) imaging, nuclear spectral energy distributions (SEDs), and archival Spitzer spectra for 22 low-luminosity active galactic nuclei (LLAGNs; L{sub bol} {approx}< 10{sup 42} erg s{sup -1}). Infrared (IR) observations may advance our understanding of the accretion flows in LLAGNs, the fate of the obscuring torus at low accretion rates, and, perhaps, the star formation histories of these objects. However, while comprehensively studied in higher-luminosity Seyferts and quasars, the nuclear IR properties of LLAGNs have not yet been well determined. We separate the present LLAGN sample into three categories depending on their Eddington ratio and radio emission, finding different IR characteristics for each class. (1) At the low-luminosity, low-Eddington-ratio (log L{sub bol}/L{sub Edd} < -4.6) end of the sample, we identify 'host-dominated' galaxies with strong polycyclic aromatic hydrocarbon bands that may indicate active (circum-)nuclear star formation. (2) Some very radio-loud objects are also present at these low Eddington ratios. The IR emission in these nuclei is dominated by synchrotron radiation, and some are likely to be unobscured type 2 AGNs that genuinely lack a broad-line region. (3) At higher Eddington ratios, strong, compact nuclear sources are visible in the MIR images. The nuclear SEDs of these galaxies are diverse; some resemble typical Seyfert nuclei, while others lack a well-defined MIR 'dust bump'. Strong silicate emission is present in many of these objects. We speculate that this, together with high ratios of silicate strength to hydrogen column density, could suggest optically thin dust and low dust-to-gas ratios, in accordance with model predictions that LLAGNs do not host a Seyfert-like obscuring torus. We anticipate that detailed modeling of the new data and SEDs in terms of accretion disk, jet, radiatively inefficient accretion flow, and torus components will provide further insights into the nuclear

  14. A JOINT MODEL OF X-RAY AND INFRARED BACKGROUNDS. II. COMPTON...

    Office of Scientific and Technical Information (OSTI)

    X-RAY AND INFRARED BACKGROUNDS. II. COMPTON-THICK ACTIVE GALACTIC NUCLEUS ABUNDANCE Citation Details In-Document Search Title: A JOINT MODEL OF X-RAY AND INFRARED BACKGROUNDS. II. ...

  15. ARM: Ka-Band Scanning ARM Cloud Radar, filtered spectral data...

    Office of Scientific and Technical Information (OSTI)

    Ka-Band Scanning ARM Cloud Radar, filtered spectral data, co-polarized mode Authors: Dan Nelson ; Joseph Hardin ; Iosif 1 ; Bradley Isom ; Karen Johnson ; Nitin Bharadwaj + Show ...

  16. ARM: X-Band Scanning ARM Cloud Radar, filtered spectral data...

    Office of Scientific and Technical Information (OSTI)

    X-Band Scanning ARM Cloud Radar, filtered spectral data, co-polarized mode Authors: Dan Nelson ; Joseph Hardin ; Iosif 1 ; Bradley Isom ; Karen Johnson ; Nitin Bharadwaj + Show ...

  17. Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Spectral SP: A New Approach to Mapping Reservoir Flow and Permeability presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon hawaiigeophysicsplane...

  18. Infrared (IR) photon-sensitive spectromicroscopy in a cryogenic environment

    DOE Patents [OSTI]

    Pereverzev, Sergey

    2016-06-14

    A system designed to suppress thermal radiation background and to allow IR single-photon sensitive spectromicroscopy of small samples by using both absorption, reflection, and emission/luminescence measurements. The system in one embodiment includes: a light source; a plurality of cold mirrors configured to direct light along a beam path; a cold or warm sample holder in the beam path; windows of sample holder (or whole sample holder) are transparent in a spectral region of interest, so they do not emit thermal radiation in the same spectral region of interest; a cold monochromator or other cold spectral device configured to direct a selected fraction of light onto a cold detector; a system of cold apertures and shields positioned along the beam path to prevent unwanted thermal radiation from arriving at the cold monochromator and/or the detector; a plurality of optical, IR and microwave filters positioned along the beam path and configured to adjust a spectral composition of light incident upon the sample under investigation and/or on the detector; a refrigerator configured to maintain the detector at a temperature below 1.0K; and an enclosure configured to: thermally insulate the light source, the plurality of mirrors, the sample holder, the cold monochromator and the refrigerator.

  19. The continued optical to mid-infrared evolution of V838 Monocerotis

    SciTech Connect (OSTI)

    Loebman, S. R.; Wisniewski, J. P.; Schmidt, S. J.; Kowalski, A. F.; Barry, R. K.; Bjorkman, K. S.; Hammel, H. B.; Hawley, S. L.; Szkody, P.; Hebb, L.; Kasliwal, M. M.; Lynch, D. K.; Russell, R. W.; Sitko, M. L.

    2015-01-01

    The eruptive variable V838 Monocerotis (V838 Mon) gained notoriety in 2002 when it brightened nine magnitudes in a series of three outbursts and then rapidly evolved into an extremely cool supergiant. We present optical, near-infrared (near-IR), and mid-IR spectroscopic and photometric observations of V838 Mon obtained between 2008 and 2012 at the Apache Point Observatory 3.5 m, NASA IRTF 3 m, and Gemini South 8 m telescopes. We contemporaneously analyze the optical and IR spectroscopic properties of V838 Mon to arrive at a revised spectral type L3 supergiant and effective temperature T{sub eff}?20002200 K. Because there are no existing optical observational data for L supergiants, we speculate that V838 Mon may represent the prototype for L supergiants in this wavelength regime. We find a low level of H? emission present in the system, consistent with interaction between V838 Mon and its B3V binary; however, we cannot rule out a stellar collision as the genesis event, which could result in the observed H? activity. Based upon a two-component blackbody fit to all wavelengths of our data, we conclude that, as of 2009, a shell of ejecta surrounded V838 Mon at a radius of R=26310 AU with a temperature of T=2852 K. This result is consistent with IR interferometric observations from the same era and predictions from the Lynch et al. model of the expanding system, which provides a simple framework for understanding this complicated system.

  20. FAR-INFRARED FINE-STRUCTURE LINE DIAGNOSTICS OF ULTRALUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Farrah, D.; Petty, S. M.; Harris, K.; Lebouteiller, V.; Spoon, H. W. W.; Bernard-Salas, J.; Pearson, C.; Rigopoulou, D.; Smith, H. A.; Gonzlez-Alfonso, E.; Clements, D. L.; Efstathiou, A.; Cormier, D.; Afonso, J.; Hurley, P.; Borys, C.; Verma, A.; Cooray, A.; Salvatelli, V.

    2013-10-10

    We present Herschel observations of 6 fine-structure lines in 25 ultraluminous infrared galaxies at z < 0.27. The lines, [O III]52 ?m, [N III]57 ?m, [O I]63 ?m, [N II]122 ?m, [O I]145 ?m, and [C II]158 ?m, are mostly single Gaussians with widths <600 km s{sup 1} and luminosities of 10{sup 7}-10{sup 9} L{sub ?}. There are deficits in the [O I]63/L{sub IR}, [N II]/L{sub IR}, [O I]145/L{sub IR}, and [C II]/L{sub IR} ratios compared to lower luminosity systems. The majority of the line deficits are consistent with dustier H II regions, but part of the [C II] deficit may arise from an additional mechanism, plausibly charged dust grains. This is consistent with some of the [C II] originating from photodissociation regions or the interstellar medium (ISM). We derive relations between far-IR line luminosities and both the IR luminosity and star formation rate. We find that [N II] and both [O I] lines are good tracers of the IR luminosity and star formation rate. In contrast, [C II] is a poor tracer of the IR luminosity and star formation rate, and does not improve as a tracer of either quantity if the [C II] deficit is accounted for. The continuum luminosity densities also correlate with the IR luminosity and star formation rate. We derive ranges for the gas density and ultraviolet radiation intensity of 10{sup 1} < n < 10{sup 2.5} and 10{sup 2.2} < G{sub 0} < 10{sup 3.6}, respectively. These ranges depend on optical type, the importance of star formation, and merger stage. We do not find relationships between far-IR line properties and several other parameters: active galactic nucleus (AGN) activity, merger stage, mid-IR excitation, and SMBH mass. We conclude that these far-IR lines arise from gas heated by starlight, and that they are not strongly influenced by AGN activity.

  1. Polarization of photons scattered by electrons in any spectral distribution

    SciTech Connect (OSTI)

    Chang, Zhe; Lin, Hai-Nan; Jiang, Yunguo

    2014-01-01

    On the basis of the quantum electrodynamics, we present a generic formalism of the polarization for beamed monochromatic photons scattered by electrons in any spectral distribution. The formulae reduce to the components of the Fano matrix when electrons are at rest. We mainly investigate the polarization in three scenarios, i.e., electrons at rest, isotropic electrons with a power-law spectrum, and thermal electrons. If the incident beam is polarized, the polarization is reduced significantly by isotropic electrons at large viewing angles; the degree of polarization caused by thermal electrons is about half of that caused by power-law electrons. If the incident bean is unpolarized, soft ?-rays can lead to about 15% polarization at viewing angles around ?/4. For isotropic electrons, one remarkable feature is that the polarization as a function of the incident photon energy always peaks roughly at 1 MeV; this is valid for both the thermal and power-law cases. This feature can be used to distinguish the model of the inverse Compton scattering from that of the synchrotron radiation.

  2. Spectrally Resolved Magnetic Resonance Imaging of the XenonBiosensor

    SciTech Connect (OSTI)

    Hilty, Christian; Lowery, Thomas; Wemmer, David; Pines, Alexander

    2005-07-15

    Due to its ability to non-invasively record images, as well as elucidate molecular structure, nuclear magnetic resonance is the method of choice for applications as widespread as chemical analysis and medical diagnostics. Its detection threshold is, however, limited by the small polarization of nuclear spins in even the highest available magnetic fields. This limitation can, under certain circumstances, be alleviated by using hyper-polarized substances. Xenon biosensors make use of the sensitivity gain of hyperpolarized xenon to provide magnetic resonance detection capability for a specific low-concentration target. They consist of a cryptophane cage, which binds one xenon atom, and which has been connected via a linker to a targeting moiety such as a ligand or antibody. Recent work has shown the possibility of using the xenon biosensor to detect small amounts of a substance in a heterogeneous environment by NMR. Here, we demonstrate that magnetic resonance (MR) provides the capability to obtain spectrally and spatially resolved images of the distribution of immobilized biosensor, opening the possibility for using the xenon biosensor for targeted imaging.

  3. Systematic wavelength selection for improved multivariate spectral analysis

    DOE Patents [OSTI]

    Thomas, Edward V.; Robinson, Mark R.; Haaland, David M.

    1995-01-01

    Methods and apparatus for determining in a biological material one or more unknown values of at least one known characteristic (e.g. the concentration of an analyte such as glucose in blood or the concentration of one or more blood gas parameters) with a model based on a set of samples with known values of the known characteristics and a multivariate algorithm using several wavelength subsets. The method includes selecting multiple wavelength subsets, from the electromagnetic spectral region appropriate for determining the known characteristic, for use by an algorithm wherein the selection of wavelength subsets improves the model's fitness of the determination for the unknown values of the known characteristic. The selection process utilizes multivariate search methods that select both predictive and synergistic wavelengths within the range of wavelengths utilized. The fitness of the wavelength subsets is determined by the fitness function F=.function.(cost, performance). The method includes the steps of: (1) using one or more applications of a genetic algorithm to produce one or more count spectra, with multiple count spectra then combined to produce a combined count spectrum; (2) smoothing the count spectrum; (3) selecting a threshold count from a count spectrum to select these wavelength subsets which optimize the fitness function; and (4) eliminating a portion of the selected wavelength subsets. The determination of the unknown values can be made: (1) noninvasively and in vivo; (2) invasively and in vivo; or (3) in vitro.

  4. Magnetoelectroluminescence of organic heterostructures: Analytical theory and spectrally resolved measurements

    DOE PAGES-Beta [OSTI]

    Liu, Feilong; Kelley, Megan R.; Crooker, Scott A.; Nie, Wanyi; Mohite, Aditya D.; Ruden, P. Paul; Los Alamos National Lab.; Smith, Darryl L.; Los Alamos National Lab.

    2014-12-22

    The effect of a magnetic field on the electroluminescence of organic light emitting devices originates from the hyperfine interaction between the electron/hole polarons and the hydrogen nuclei of the host molecules. In this paper, we present an analytical theory of magnetoelectroluminescence for organic semiconductors. To be specific, we focus on bilayer heterostructure devices. In the case we are considering, light generation at the interface of the donor and acceptor layers results from the formation and recombination of exciplexes. The spin physics is described by a stochastic Liouville equation for the electron/hole spin density matrix. By finding the steady-state analytical solutionmore » using Bloch-Wangsness-Redfield theory, we explore how the singlet/triplet exciplex ratio is affected by the hyperfine interaction strength and by the external magnetic field. In order to validate the theory, spectrally resolved electroluminescence experiments on BPhen/m-MTDATA devices are analyzed. With increasing emission wavelength, the width of the magnetic field modulation curve of the electroluminescence increases while its depth decreases. Furthermore, these observations are consistent with the model.« less

  5. Spectral monodromy of non-self-adjoint operators

    SciTech Connect (OSTI)

    Phan, Quang Sang

    2014-01-15

    In the present paper, we build a combinatorial invariant, called the “spectral monodromy” from the spectrum of a single (non-self-adjoint) h-pseudodifferential operator with two degrees of freedom in the semi-classical limit. Our inspiration comes from the quantum monodromy defined for the joint spectrum of an integrable system of n commuting self-adjoint h-pseudodifferential operators, given by S. Vu Ngoc [“Quantum monodromy in integrable systems,” Commun. Math. Phys. 203(2), 465–479 (1999)]. The first simple case that we treat in this work is a normal operator. In this case, the discrete spectrum can be identified with the joint spectrum of an integrable quantum system. The second more complex case we propose is a small perturbation of a self-adjoint operator with a classical integrability property. We show that the discrete spectrum (in a small band around the real axis) also has a combinatorial monodromy. The main difficulty in this case is that we do not know the description of the spectrum everywhere, but only in a Cantor type set. In addition, we also show that the corresponding monodromy can be identified with the classical monodromy, defined by J. Duistermaat [“On global action-angle coordinates,” Commun. Pure Appl. Math. 33(6), 687–706 (1980)].

  6. Gravitational collapse of scalar fields via spectral methods

    SciTech Connect (OSTI)

    Oliveira, H. P. de; Rodrigues, E. L.; Skea, J. E. F.

    2010-11-15

    In this paper we present a new numerical code based on the Galerkin method to integrate the field equations for the spherical collapse of massive and massless scalar fields. By using a spectral decomposition in terms of the radial coordinate, the field equations were reduced to a finite set of ordinary differential equations in the space of modes associated with the Galerkin expansion of the scalar field, together with algebraic sets of equations connecting modes associated with the metric functions. The set of ordinary differential equations with respect to the null coordinate is then integrated using an eighth-order Runge-Kutta method. The numerical tests have confirmed the high accuracy and fast convergence of the code. As an application we have evaluated the whole spectrum of black hole masses which ranges from infinitesimal to large values obtained after varying the amplitude of the initial scalar field distribution. We have found strong numerical evidence that this spectrum is described by a nonextensive distribution law.

  7. Spectral and polarization properties of photospheric emission from stratified jets

    SciTech Connect (OSTI)

    Ito, Hirotaka; Nagataki, Shigehiro; Matsumoto, Jin; Lee, Shiu-Hang; Tolstov, Alexey; Mao, Jirong; Dainotti, Maria; Mizuta, Akira

    2014-07-10

    We explore the spectral and polarization properties of photospheric emissions from stratified jets in which multiple components, separated by sharp velocity shear regions, are distributed in lateral directions. Propagation of thermal photons injected at a high optical depth region are calculated until they escape from the photosphere. It is found that the presence of the lateral structure within the jet leads to the nonthermal feature of the spectra and significant polarization signal in the resulting emission. The deviation from thermal spectra, as well as the polarization degree, tends to be enhanced as the velocity gradient in the shear region increases. In particular, we show that emissions from multicomponent jet can reproduce the typical observed spectra of gamma-ray bursts irrespective of the position of the observer when a velocity shear region is closely spaced in various lateral (θ) positions. The degree of polarization associated with the emission is significant (>few percent) at a wide range of observer angles and can be higher than 30%.

  8. Non-destructive component separation using infrared radiant energy

    SciTech Connect (OSTI)

    Simandl, Ronald F.; Russell, Steven W.; Holt, Jerrid S.; Brown, John D.

    2011-03-01

    A method for separating a first component and a second component from one another at an adhesive bond interface between the first component and second component. Typically the method involves irradiating the first component with infrared radiation from a source that radiates substantially only short wavelengths until the adhesive bond is destabilized, and then separating the first component and the second component from one another. In some embodiments an assembly of components to be debonded is placed inside an enclosure and the assembly is illuminated from an IR source that is external to the enclosure. In some embodiments an assembly of components to be debonded is simultaneously irradiated by a multi-planar array of IR sources. Often the IR radiation is unidirectional. In some embodiments the IR radiation is narrow-band short wavelength infrared radiation.

  9. Near-infrared photodetector with reduced dark current

    DOE Patents [OSTI]

    Klem, John F; Kim, Jin K

    2012-10-30

    A photodetector is disclosed for the detection of near-infrared light with a wavelength in the range of about 0.9-1.7 microns. The photodetector, which can be formed as either an nBp device or a pBn device on an InP substrate, includes an InGaAs light-absorbing layer, an InAlGaAs graded layer, an InAlAs or InP barrier layer, and an InGaAs contact layer. The photodetector can detect near-infrared light with or without the use of an applied reverse-bias voltage and is useful as an individual photodetector, or to form a focal plane array.

  10. Research Highlight

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    AERI Instrument Status and Analysis Results: 1998 Submitter: Revercomb, H. E., University of Wisconsin, Madison Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Smith, W.L, W.F. Feltz, R.O. Knuteson, H.E. Revercomb, H.B. Howell, and H.M. Woolf, 1999: "The retrieval of planetary boundary layer structure using ground-based infrared spectral radiance measurements." J. Atmos. Oceanic Technol., 16(3): 323-333.> Feltz, W. F., W.L. Smith, R.O.

  11. Research Highlight

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    AERI-ER at the SHEBA Ice Station: Far Infrared H2O Continuum Submitter: Revercomb, H. E., University of Wisconsin, Madison Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Tobin, D.C., F.A. Best, P.D. Brown, S.A. Clough, R.G. Dedecker, R.G. Ellingson, R.K. Garcia, H.B. Howell, R.O. Knuteson, E.J. Mlawer, H.E. Revercomb, J.F. Short, P.F.W. van Delst, and V.P. Walden, 1999. "Downwelling spectral radiance observations at the SHEBA ice station:

  12. Low Cost Near Infrared Selective Plasmonic Smart Windows

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Guillermo Garcia, memo@heliotropetech.com Heliotrope Technologies Low Cost Near Infrared Selective Plasmonic Smart Windows 2015 Building Technologies Office Peer Review 2 Project Summary Timeline: Start date: 5/15/14 Planned end date: 5/15/16 Key Milestones 1. Met device performance milestones by optimizing material composition, Aug 2014 2. Established fabrication protocol for transition to commercial scaled samples, Oct 2014 3. Validated UV sensitivity, variable temperature operation, and cycle

  13. Tailorable infrared sensing device with strain layer superlattice structure

    DOE Patents [OSTI]

    Cheng, Li-Jen

    1987-12-08

    An infrared photodetector is formed of a heavily doped p-type Ge.sub.x Si.sub.1-x /Si superlattice in which x is pre-established during manufacture in the range 0 to 100 percent. A custom tailored photodetector that can differentiate among close wavelengths in the range of 2.7 to 50 microns is fabricated by appropriate selection of the alloy constituency value, x, to establish a specific wavelength at which photodetection cut-off will occur.

  14. Deuterium separation by infrared-induced addition reaction

    DOE Patents [OSTI]

    Marling, John B.

    1977-01-01

    A method for deuterium enrichment by the infrared-induced addition reaction of a deuterium halide with an unsaturated aliphatic compound. A gaseous mixture of a hydrogen halide feedstock and an unsaturated aliphatic compound, particularly an olefin, is irradiated to selectively vibrationally excite the deuterium halide contained therein. The excited deuterium halide preferentially reacts with the unsaturated aliphatic compound to produce a deuterated addition product which is removed from the reaction mixture.

  15. Assessing Cloud Spatial and Vertical Distribution with Infrared Cloud Analyzer

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Cloud Spatial and Vertical Distribution with Infrared Cloud Analyzer I. Genkova and C. N. Long Pacific Northwest National Laboratory Richland, Washington T. Besnard ATMOS SARL Le Mans, France D. Gillotay Institute d'Aeronomie Spatiale de Belgique Brussels, Belgium Introduction In the effort to resolve uncertainties about global climate change, the Atmospheric Radiation Measurement (ARM) Program (www.arm.gov) is improving the treatment of cloud radiative forcing and feedbacks in general

  16. Emissivity corrected infrared method for imaging anomalous structural heat flows

    DOE Patents [OSTI]

    Del Grande, N.K.; Durbin, P.F.; Dolan, K.W.; Perkins, D.E.

    1995-08-22

    A method for detecting flaws in structures using dual band infrared radiation is disclosed. Heat is applied to the structure being evaluated. The structure is scanned for two different wavelengths and data obtained in the form of images. Images are used to remove clutter to form a corrected image. The existence and nature of a flaw is determined by investigating a variety of features. 1 fig.

  17. Sensitized near infrared emission from lanthanide-exchanged zeolites

    SciTech Connect (OSTI)

    Monguzzi, A.; Macchi, G.; Meinardi, F.; Tubino, R.; Burger, M.; Calzaferri, G.

    2008-03-24

    In this work, we present an alternative approach to sensitize the near infrared emission of Er{sup 3+} ions (used in telecom applications) by exploiting the geometrical confinement occurring in porous zeolites structures. The sensitization of the Ln ion is obtained by energy transfer between a suitable organic molecule acting as an antenna and the emitting ion arranged in closed proximity, thus, avoiding the limits imposed by the coordination chemistry.

  18. THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS

    SciTech Connect (OSTI)

    Ricca, Alessandra; Bauschlicher, Charles W. Jr.; Allamandola, Louis J. E-mail: Charles.W.Bauschlicher@nasa.gov

    2013-10-10

    The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

  19. Spectral network based on component cells under the SOPHIA European project

    SciTech Connect (OSTI)

    Núñez, Rubén Antón, Ignacio; Askins, Steve; Sala, Gabriel; Domínguez, César; Voarino, Philippe; Steiner, Marc; Siefer, Gerald; Fucci, Rafaelle; Roca, Franco; Minuto, Alessandro; Morabito, Paolo

    2015-09-28

    In the frame of the European project SOPHIA, a spectral network based on component (also called isotypes) cells has been created. Among the members of this project, several spectral sensors based on component cells and collimating tubes, so-called spectroheliometers, were installed in the last years, allowing the collection of minute-resolution spectral data useful for CPV systems characterization across Europe. The use of spectroheliometers has been proved useful to establish the necessary spectral conditions to perform power rating of CPV modules and systems. If enough data in a given period of time is collected, ideally a year, it is possible to characterize spectrally the place where measurements are taken, in the same way that hours of annual irradiation can be estimated using a pyrheliometer.

  20. SPITZER OBSERVATIONS OF ABELL 1763. I. INFRARED AND OPTICAL PHOTOMETRY

    SciTech Connect (OSTI)

    Edwards, Louise O. V.; Fadda, Dario; Biviano, Andrea

    2010-02-15

    We present a photometric analysis of the galaxy cluster Abell 1763 at visible and infrared wavelengths. Included are fully reduced images in r', J, H, and K{sub s} obtained using the Palomar 200in telescope, as well as the IRAC and MIPS images from Spitzer. The cluster is covered out to approximately 3 virial radii with deep 24 {mu}m imaging (a 5{sigma} depth of 0.2 mJy). This same field of {approx}40' x 40' is covered in all four IRAC bands as well as the longer wavelength MIPS bands (70 and 160 {mu}m). The r' imaging covers {approx}0.8 deg{sup 2} down to 25.5 mag, and overlaps with most of the MIPS field of view. The J, H, and K{sub s} images cover the cluster core and roughly half of the filament galaxies, which extend toward the neighboring cluster, Abell 1770. This first, in a series of papers on Abell 1763, discusses the data reduction methods and source extraction techniques used for each data set. We present catalogs of infrared sources (with 24 and/or 70 {mu}m emission) and their corresponding emission in the optical (u', g', r', i', z'), and near- to far-IR (J, H, K{sub s} , IRAC, and MIPS 160 {mu}m). We provide the catalogs and reduced images to the community through the NASA/IPAC Infrared Science Archive.