National Library of Energy BETA

Sample records for grand marais mn

  1. City of Grand Marais, Minnesota (Utility Company) | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Grand Marais Place: Minnesota Phone Number: (218) 387-3030 or (218)387-1848 Website: www.ci.grand-marais.mn.usinde Facebook: https:www.facebook.comGrandMaraisMN Outage Hotline:...

  2. Grand Marais PUC - Commercial & Industrial Energy Efficiency...

    Energy.gov [DOE] (indexed site)

    - Rooftop and Packaged AC, Air and Water, Cooled Chillers, Air Source Heat Pumps, Ground Source Heat Pumps, Water Source Heat Pumps: Varies Motors: 15 - 2,700, varies by...

  3. Grande

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    breaks ground on key sediment control project November 5, 2009 Structures will limit flow of sediments toward Rio Grande Los Alamos, New Mexico, November 5, 2009- Crews broke...

  4. Grande

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    breaks ground on key sediment control project November 5, 2009 Structures will limit flow of sediments toward Rio Grande Los Alamos, New Mexico, November 5, 2009- Crews broke ground this week on one of two engineered structures in a Los Alamos National Laboratory environmental project to reduce the flow of sediments down two canyons toward the Rio Grande. Called "grade-control" structures, the approximately $2 million features are up to eight feet high and made of rocks packed tightly

  5. 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist Team

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Submissions | Department of Energy Race to Zero Competition Grand Winner and Grand Winner Finalist Team Submissions 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist Team Submissions Read the team submissions for the Grand Winner and Grand Winner Finalist teams from the 2015 Race to Zero Student Design Competition below. Learn more about the results of the 2015 competition. Grand Winner: Opti-MN, University of Minnesota (38.54 MB) Grand Winner Finalist: Team App,

  6. 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist...

    Energy.gov [DOE] (indexed site)

    Learn more about the results of the 2015 competition. PDF icon Grand Winner: Opti-MN, University of Minnesota PDF icon Grand Winner Finalist: Team App, Appalachian State University ...

  7. Rio Grande

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Rio Grande Rio Grande In New Mexico, the Rio Grande flows from one sediment-filled basin to another, cutting canyons between the basins and supporting a fragile ecosystem on its...

  8. Grand Challenges

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Grand Challenges Grand Challenges Our goals to live a sustainable future LANL stakeholders TA-21 cleanup activities water on LANL land Collaborate with our stakeholders and tribal...

  9. Rio Grande

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Rio Grande Rio Grande In New Mexico, the Rio Grande flows from one sediment-filled basin to another, cutting canyons between the basins and supporting a fragile ecosystem on its flood plain. August 1, 2013 river bank Banks of the Rio Grande Groundwater at LANL discharges to springs along the Rio Grande. Stream flow resulting from heavy storms and snowmelt also has the potential to reach the Rio Grande. RELATED IMAGES http://farm3.staticflickr.com/2818/9628464665_3a972e1387_t.jpg Enlarge

  10. Rio Grande

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    In New Mexico, the Rio Grande flows from one sediment-filled basin to another, cutting canyons between the basins and supporting a fragile ecosystem on its flood plain. August 1, ...

  11. Grand Challenges

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Grand Challenges Grand Challenges Our goals to live a sustainable future LANL stakeholders TA-21 cleanup activities water on LANL land Collaborate with our stakeholders and tribal governments to ensure that LANL's impact on the environment is as low as reasonably achievable Remove or stabilize pollutants from the Manhattan Project and Cold War eras Protect water resource quality and reduce water use Stormwater drainage at LANL LANL land waste workers at LANL Eliminate industrial emissions,

  12. Opti-MN Impact House Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Opti-MN Impact House Presentation Opti-MN Impact House Presentation Opti-MN was the Grand Winner of the 2015 Race to Zero Student Design Competition. View the presentation for the Opti-MN Impact House below. Read a full list of the winning teams. Opti-MN Presentation (5.74 MB) More Documents & Publications 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist Team Submissions 2016 Race to Zero Competition Winner Team Presentations 2014 Race to Zero Student Design Competition:

  13. SOFT COST GRAND CHALLENGE

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    energycenter.org California Center for Sustainable Energy Soft Cost Grand Challenge May 22, 2014 Accelerating the transition to a sustainable world powered by clean energy 2...

  14. GRAND CHALLENGE PROBLEMS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    GRAND CHALLENGE PROBLEMS Time is the biggest issue. Materials typically become critical in a matter of months, but solutions take years or decades to develop and implement. Our first two grand challenges address this discrepancy. Anticipating Which Materials May Go Critical In an ideal world, users of materials would anticipate supply-chain disruptions before they occur. They would undertake activities to manage the risks of disruption, including R&D to diversify and increase supplies or to

  15. Mountain View Grand | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Mountain View Grand Jump to: navigation, search Name Mountain View Grand Facility Mountain View Grand Sector Wind energy Facility Type Small Scale Wind Facility Status In Service...

  16. DOE - Office of Legacy Management -- Grand Junction Sites

    Office of Legacy Management (LM)

    Grand Junction Sites Grand Junction Sites gj_map Grand Junction Disposal Site Grand Junction Processing Site Grand Junction Site Contact Us

  17. Rio Grande North | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name Rio Grande North Facility Rio Grande North Sector Wind energy Facility Type Offshore Wind Facility Status Proposed Owner Baryonyx Corporation Developer Baryonyx...

  18. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January ...

  19. Nuclear Proliferation and Grand Challenges

    SciTech Connect

    McCarthy, Kathy

    2009-01-01

    Nuclear engineer Dr. Kathy McCarthy leads systems analysis. She talks about proliferation and the grand challenges of nuclear R&D. For more information about INL energy research, visit http://www.facebook.com/idahonationallaboratory.

  20. Nuclear Proliferation and Grand Challenges

    ScienceCinema

    McCarthy, Kathy

    2013-05-28

    Nuclear engineer Dr. Kathy McCarthy leads systems analysis. She talks about proliferation and the grand challenges of nuclear R&D. For more information about INL energy research, visit http://www.facebook.com/idahonationallaboratory.

  1. Tax Credits, Rebates & Savings | Department of Energy

    Energy.gov [DOE] (indexed site)

    Grand Marais PUC- Commercial & Industrial Energy Efficiency Rebate Program Southern Minnesota Municipal Power Agency (SMMPA) is a joint-action agency which generates and sells...

  2. SU(6) grand unified model

    SciTech Connect

    Dong, J.X.

    1986-03-14

    A model of grand unified theory based on SU(6) gauge group is proposed. It can accommodate two generations of ordinary fermions with V-A weak coupling and two generations of weird fermions with V+A weak coupling. In this model, a new discrete symmetry is introduced that insures existence of fermions with lower masses when SU(6) gauge symmetry is spontaneously broken. Simple Higgs fields with appropriate vacuum expectation values are chosen, so that the masses of weird fermions are heavier than those of ordinary fermions. This model also gives the same value of Weinberg angle, sin sq of Theta/sub w/ = 3/8, as in the usual SU(5) grand unified model at the grand unified scale.

  3. EA-33 Rio Grande Electric | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Rio Grande Electric EA-33 Rio Grande Electric Order authorizing Rio Grande Electric to export electric energy to Mexico EA-33 Rio Grande Electric (555.17 KB) More Documents & Publications EA-33-A and PP-33-1 Rio Grande Electric Cooperative, Inc. PP-33-1 and EA-33-A Rio Grande Electric Cooperative Inc PP-53 Rio Grande

  4. DOE Grand Junction Projects Office Edgemont LTSP

    Office of Legacy Management (LM)

    DOE Grand Junction Projects Office Edgemont LTSP June 1996 Page ii Contents Page 1.0 Introduction ......

  5. Team OptiMN

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    University of Minnesota Team OptiMN "OptiMN Impact Home" Project Summary Designed to fit on the majority of North Minneapolis infill lots, the OptiMN Impact Home is a collaborative project between the University of Minnesota and Urban Homeworks. The overarching goal was a flexible, high-performance, energy-efficient, and affordable house that can be easily built by Urban Homeworks and purchased by eligible low-income residents of North Minneapolis through the Green Homes North program.

  6. Mississippi Nuclear Profile - Grand Gulf

    Energy Information Administration (EIA) (indexed site)

    Grand Gulf" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date" 1,"1,251","9,643",88.0,"BWR","application/vnd.ms-excel","application/vnd.ms-excel" ,"1,251","9,643",88.0 "Data for 2010" "BWR = Boiling Water Reactor."

  7. Destilaria Rio Grande | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    to: navigation, search Name: Destilaria Rio Grande Place: Fronteira, Minas Gerais, Brazil Zip: 38230-000 Product: Brazil based ethanol producer. References: Destilaria Rio...

  8. Usina Serra Grande | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    navigation, search Name: Usina Serra Grande Place: Maceio, Alagoas, Brazil Product: Ethanol producer Coordinates: -9.666479, -35.734954 Show Map Loading map......

  9. EV Everywhere Grand Challenge - Charging Infrastructure Enabling...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Documents & Publications EV Everywhere Framing Workshop - Report Out & Lessons Learned EV Everywhere Framing Workshop Report Out & Lessons Learned EV Everywhere Grand ...

  10. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    9 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 9 PDF icon grandchallengesportfoliopg9.pdf More Documents & Publications ...

  11. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 8 PDF icon grandchallengesportfoliopg8.pdf More Documents & Publications ...

  12. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    6 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 6 PDF icon grandchallengesportfoliopg6.pdf More Documents & Publications ...

  13. Grand River Dam Authority | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    River Dam Authority Place: Oklahoma Phone Number: 918-256-5545 Website: www.grda.com Twitter: @okgrda Facebook: https:www.facebook.compagesGrand-River-Dam-Authority...

  14. PP-33 Rio Grande Electric Cooperative Inc

    Energy.gov [DOE]

    Presidential permit authorizing Grande Electric Cooperative Inc to construct, operate, and maintain electric transmission facilities at the U.S-Mexico border.

  15. EV Everywhere Grand Challenge - Battery Workshop Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ...2012 EV Everywhere Grand Challenge -- Battery Workshop Thursday, July 26, 2012 - ... Technologies Program 9:25-9:50 AM EV BATTERY TECHNOLOGY-CURRENT STATUS & COST ...

  16. EV Everywhere Grand Challenge Overview Presentation

    Energy.gov [DOE]

    Presentation by EERE Assistant Secretary David Danielson at the EV Everywhere Grand Challenge Kick-Off meeting held on June 21, 2012 at the Hyatt Regency, Dearborn, MI

  17. Grand Junction Office Founder Honored at the

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4 Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park Dedication and Open House The U.S. Department of Energy (DOE) Offce of Legacy Management (LM) held an open house and park dedication at the Grand Junction, Colorado, Offce to commemorate its place in the Manhattan Project and Cold War histories. The park, located in the middle of the Grand Junction Offce campus, was dedicated to Army Major (retired) Philip C. Leahy. Leahy came to Grand Junction in 1943 under secret

  18. CRAD, NNSA - Maintenance (MN) | Department of Energy

    Energy Saver

    NNSA - Maintenance (MN) CRAD, NNSA - Maintenance (MN) CRAD for Maintenance (MN). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and ...

  19. 2014 Race to Zero Student Design Competition: Grand Winner Teams...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grand Winner Teams 2014 Race to Zero Student Design Competition: Grand Winner Teams 2014 Race to Zero Student Design Competition: Grand Winner Teams, from the U.S. Department of ...

  20. EV Everywhere Grand Challenge Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2_danielson_caci.pdf (299.97 KB) More Documents & Publications EV Everywhere Grand Challenge Introduction for Electric Drive Workshop EV Everywhere Grand Challenge Overview EV Everywhere Battery Workshop: Setting the Stage for the EV Everywhere Grand Challenge

  1. Rio Grande, TX Natural Gas Pipeline Exports to Mexico (Million...

    Energy Information Administration (EIA) (indexed site)

    Grande, TX Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Rio Grande, TX ... 05312016 Referring Pages: U.S. Natural Gas Pipeline Exports by Point of Exit Rio Grande

  2. Agropecuaria e Industrial Serra Grande | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    e Industrial Serra Grande Jump to: navigation, search Name: Agropecuaria e Industrial Serra Grande Place: So Raimundo das Mangabeiras, Maranhao, Brazil Product: Privately owned...

  3. Defining the Mechanisms of Friction: A Grand Challenge in Interfacial...

    Office of Scientific and Technical Information (OSTI)

    Defining the Mechanisms of Friction: A Grand Challenge in Interfacial Mechanics. Citation Details In-Document Search Title: Defining the Mechanisms of Friction: A Grand Challenge...

  4. East Grand St Bridge Snowmelt Low Temperature Geothermal Facility...

    OpenEI (Open Energy Information) [EERE & EIA]

    East Grand St Bridge Snowmelt Low Temperature Geothermal Facility Jump to: navigation, search Name East Grand St Bridge Snowmelt Low Temperature Geothermal Facility Facility East...

  5. Rio Grande Rift Geothermal Region | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Region Data Acquisition-Manipulation At Rio Grande Rift Region (Morgan, Et Al., 2010) Ground Gravity Survey At Rio Grande Rift Region (Aiken & Ander, 1981) Magnetotellurics At...

  6. Preservationists Tour Historic Log Cabin at the Grand Junction...

    Office of Environmental Management (EM)

    Preservationists Tour Historic Log Cabin at the Grand Junction, Colorado, Office Preservationists Tour Historic Log Cabin at the Grand Junction, Colorado, Office April 19, 2016 - ...

  7. Grand Junction Office Founder Honored at the Philip C. Leahy...

    Office of Environmental Management (EM)

    Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park Dedication and Open House Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park ...

  8. Students from Grand Junction High School Triumph in Colorado...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Grand Junction High School Triumph in Colorado Science Bowl For more information contact: e:mail: Public Affairs Golden, Colo., Feb. 12, 2000 - Students from Grand Junction High ...

  9. EV Everywhere EV Everywhere Grand Challenge - Electric Drive...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop Agenda EV Everywhere EV Everywhere Grand Challenge - Electric Drive (Power ...

  10. Wintertime meteorology of the Grand Canyon region

    SciTech Connect

    Whiteman, C.D.

    1992-09-01

    The Grand Canyon region of the American Southwest is an interesting region meteorologically, but because of its isolated location, the lack of major population centers in the region, and the high cost of meteorological field experiments, it has historically received little observational attention. In recent years, however, attention has been directed to episodes of visibility degradation in many of the US National parks, and two recent field studies focused on this visibility problem have greatly increased the meteorological data available for the Grand Canyon region. The most recent and comprehensive of these studies is the Navajo Generating Station Winter Visibility Study of 1989--90. This study investigated the sources of visibility degradation in Grand Canyon National Park and the meteorological mechanisms leading to low visibility episodes. In this paper we present analyses of this rich data set to gain a better understanding of the key wintertime meteorological features of the Grand Canyon region.

  11. Grand Coulee & Hungry Horse SCADA Replacement

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Gates Replacement This project is part of the Third Powerplant overhaul at Grand Coulee Dam. The full overhaul effort involves a mechanical overhaul of units G19 - G24. The...

  12. CMI Grand Challenge Problems | Critical Materials Institute

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    CMI Grand Challenge Problems Time is the biggest issue. Materials typically become critical in a matter of months, but solutions take years or decades to develop and implement. Our first two grand challenges address this discrepancy. Anticipating Which Materials May Go Critical In an ideal world, users of materials would anticipate supply-chain disruptions before they occur. They would undertake activities to manage the risks of disruption, including R&D to diversify and increase supplies or

  13. Hydrogen Storage Grand Challenge Individual Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Individual Projects Hydrogen Storage Grand Challenge Individual Projects Hydrogen Storage Grand Challenge individual projects funded for three Centers of Excellence, led by the National Renewable Energy Laboratory, Sandia National Laboratories, and Los Alamos National Laboratory. grand_challenge_projects.pdf (68.62 KB) More Documents & Publications Hydrogen Storage Grand Challenge Centers of Excellence Learning Demonstration Teams Major DOE Biofuels Project Locations

  14. EV Everywhere Grand Challenge - Battery Workshop Agenda | Department of

    Energy Saver

    Energy Agenda EV Everywhere Grand Challenge - Battery Workshop Agenda Agenda for the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree O'Hare, Chicago, IL. agenda_b.pdf (196.97 KB) More Documents & Publications EV Everywhere Grand Challenge - Charge to the Breakout Groups EV Everywhere Grand Challenge Introduction for Electric Drive Workshop EV Everywhere Grand Challenge Kick-Off

  15. MN Office of Energy Security | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    MN Office of Energy Security Jump to: navigation, search Name: MN Office of Energy Security Place: St. Paul, MN Website: www.mnofficeofenergysecurity.c References: MN Office of...

  16. Monopoles of SU(15) grand unification

    SciTech Connect

    Pal, P.B.

    1991-03-01

    In a recently analyzed grand unified model based on the gauge group SU(15), monopoles are automatically consistent with the cosmological mass density bound. The Parker bound of monopole flux puts some constaints on the model which can be easily satisfied.

  17. Middle Rio Grande Cooperative Water Model

    Energy Science and Technology Software Center

    2005-11-01

    This is computer simulation model built in a commercial modeling product Called Studio Expert, developed by Powersim, Inc. The simulation model is built in a system dynamics environment, allowing the simulation of the interaction among multiple systems that are all changing over time. The model focuses on hydrology, ecology, demography, and economy of the Middle Rio Grande, with Water as the unifying feature.

  18. Category:Minneapolis, MN | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    16 total. SVFullServiceRestaurant Minneapolis MN Northern States Power Co (Minnesota) Excel Energy.png SVFullServiceRestauran... 89 KB SVHospital Minneapolis MN Northern States...

  19. DOE/EIS-0485 Final Environmental Impact Statement Grande Prairie...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grande Prairie Wind has applied to Western to interconnect the proposed Project to Western's 345-kilovolt (kV) Fort Thompson to Grand Island transmission line at a new switchyard. ...

  20. GreenHunter Biodiesel Refinery Grand Opening | Department of...

    Office of Environmental Management (EM)

    GreenHunter Biodiesel Refinery Grand Opening GreenHunter Biodiesel Refinery Grand Opening June 2, 2008 - 12:51pm Addthis Remarks as Prepared for (Acting) Deputy Secretary Kupfer ...

  1. Rio Grande LNG LLC- Dkt. No. 15-190-LNG

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Office of Fossil Energy gives notice of receipt of an Application filed December 23, 2015, by Rio Grande LNG, LLC (Rio Grande), seeking a long-term multi-contract authorization to export...

  2. SunShot Grand Challenge: Summit and Technology Forum

    Energy.gov [DOE]

    The SunShot Grand Challenge: Summit and Technology Forum was the first event in a series of Department of Energy Grand Challenges. This event focused on SunShot Initiative goals of achieving grid...

  3. City of Grand Haven, Michigan (Utility Company) | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Grand Haven Place: Michigan Phone Number: (616) 846-6250 Website: www.ghblp.org Twitter: @ghblp Facebook: https:www.facebook.comGrandHavenBLP Outage Hotline: (616) 842-2241...

  4. Energy Secretary Steven Chu to Attend Grand Opening of Recovery...

    Energy Saver

    to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant Energy Secretary Steven Chu to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant ...

  5. Winning the Future: Grand Ronde Solar Projects Reduce Pollution...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grand Ronde Solar Projects Reduce Pollution, Cut Costs Winning the Future: Grand Ronde Solar Projects Reduce Pollution, Cut Costs October 20, 2014 - 5:00pm Addthis PV panels ...

  6. SunShot Grand Challenge Summit Breakout Sessions Announced

    Energy.gov [DOE]

    The 2014 SunShot Grand Challenge Summit is only six weeks away! SunShot is excited to announce our thought-provoking lineup of Grand Challenge Breakout Sessions.

  7. Grand Challenges | U.S. DOE Office of Science (SC)

    Office of Science (SC)

    Grand Challenges Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events Publications History Grand Challenges BES Reports Document Archives Contests Contact BES Home History Grand Challenges Print Text Size: A A A FeedbackShare Page Grand Challenge Report The Basic Energy Sciences Advisory Committee (BESAC) report, Directing Matter and Energy: Five Challenges for Science and the Imagination was the culmination of a series of BES-sponsored

  8. Grand Challenges | U.S. DOE Office of Science (SC)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Grand Challenges Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events Publications History Grand Challenges BES Reports Document Archives Contests Contact BES Home History Grand Challenges Print Text Size: A A A FeedbackShare Page Grand Challenge Report The Basic Energy Sciences Advisory Committee (BESAC) report, Directing Matter and Energy: Five Challenges for Science and the Imagination was the culmination of a series of BES-sponsored

  9. 2014 Race to Zero Student Design Competition: Grand Winner Teams |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Grand Winner Teams 2014 Race to Zero Student Design Competition: Grand Winner Teams 2014 Race to Zero Student Design Competition: Grand Winner Teams, from the U.S. Department of Energy. rtz_grand_winner_team_rosters.pdf (59.94 KB) More Documents & Publications 2014 Race to Zero Student Design Competition: Montage Builders Team Submission 2014 Race to Zero Student Design Competition: Montage Builders Profile 2014 Race to Zero Student Design Competition: Auburn

  10. PP-53 Rio Grande Electric Cooperative, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    3 Rio Grande Electric Cooperative, Inc. PP-53 Rio Grande Electric Cooperative, Inc. Presidential Permit authorizing Rio Grande Electric Cooperative, Inc.to construct, operate, and maintain electric transmission facilities at the U.S. - Mexico Border. PP-53 Rio Grande Electric Cooperative, Inc. (1.09 MB) More Documents & Publications PP-55 Roseau Electric Cooperative, Inc. PP-42 Roseau Electric Cooperative, Inc. PP-67 North Central Electric Cooperative, Inc.

  11. Winners Announced for the NNSA Grand Challenge Competition

    Energy.gov [DOE]

    Clark Atlanta University students' rocket tail component for Additive Manufacturing won the NNSA student Grand Challenge Competition.

  12. EV Everywhere Grand Challenge - Charge to the Breakout Groups | Department

    Energy Saver

    of Energy Charge to the Breakout Groups EV Everywhere Grand Challenge - Charge to the Breakout Groups Presentation given at the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree OHare, Chicago, IL. 7_howell_b.pdf (796.65 KB) More Documents & Publications EV Everywhere - Charge to Breakout Sessions EV Everywhere Grand Challenge - Battery Workshop Agenda EV Everywhere EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric

  13. Hydrogen Storage Grand Challenge Centers of Excellence | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Centers of Excellence Hydrogen Storage Grand Challenge Centers of Excellence DOE's Hydrogen Storage Grand Challenge Centers of Excellence and partners, led by NREL, SNL, and LANL grand_challenge_centers.pdf (62.21 KB) More Documents & Publications Hydrogen Storage Grand Challenge Individual Projects Final Solar and Wind H2 Report EPAct 812.doc Microsoft Word - H2 National Release 2.doc

  14. Grand Coulee-Creston_FONSI_and_MAP_27May2014

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grand Coulee-Creston Transmission Line Rebuild Project 1 Finding of No Significant Impact Grand Coulee-Creston Transmission Line Rebuild Project Finding of No Significant Impact (FONSI) Bonneville Power Administration DOE/EA-1950 May 2014 SUMMARY Bonneville Power Administration (BPA) announces its environmental findings on the Grand Coulee-Creston Transmission Line Rebuild Project. The project would rebuild nearly 28 miles of the Grand Coulee-Creston No. 1 115-kilovolt (kV) transmission line

  15. EA-0930: Facility Operations at the U.S. DOE Grand Junction Projects Office, Grand Junction, Colorado

    Office of Energy Efficiency and Renewable Energy (EERE)

    This EA evaluates the environmental impacts of the proposal to expand and upgrade the U.S. Department of Energy's Grand Junction Projects Office facilities and operations in Grand Junction, Colorado.

  16. Upper Rio Grande Simulation Model (URGSIM)

    Energy Science and Technology Software Center

    2010-08-05

    URGSIM estimates the location of surface water and groundwater resources in the upper Rio Grande Basin between the Colorado-New Mexico state line, and Caballo Reservoir from 1975 - 2045. It is a mass balance hydrology model of the Upper Rio Grande surface water, groundwater, and water demand systems which runs at a monthly timestep from 1975-1999 in calibration mode, 2000 – 2004 in validation mode, and 2005 – 2045 in scenario analysis mode.

  17. SunShot Grand Challenge | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SunShot Grand Challenge SunShot Grand Challenge Addthis SunShot Grand Challenge 1 of 28 SunShot Grand Challenge Participants gather for the plenary session at the SunShot Grand Challenge Summit and Technology Forum in Denver, Colorado. (Photo by DENNIS SCHROEDER / NREL) Date taken: 2012-06-13 07:10 Arun Majumdar, Founding Director, ARPA-E 2 of 28 Arun Majumdar, Founding Director, ARPA-E Arun Majumdar, Founding Director, ARPA-E gives the welcoming remarks. (Photo by DENNIS SCHROEDER / NREL) Date

  18. Rio Grande pipeline introduces LPG to Mexico

    SciTech Connect

    1997-06-01

    Rio Grande Pipeline, a joint venture between Mid-America Pipeline Co., Amoco Pipeline Co. and Navajo Pipeline Co., has broken new ground in the energy industry as the first LPG pipeline to cross the US-Mexico border. Plans for the project were announced in November 1995 and first deliveries started three months ago on March 21, 1997. The 8-inch, 265-mile pipeline originates near Odessa, TX, where it receives an 85-15 propane-butane mix via a connection to Mid-America Pipeline. From Odessa, product moves west through the Texas desert and crosses the Rio Grande River about 15 miles south of El Paso near Clint, TX and extends 20 miles into Mexico. Capacity of the line is 24,000 bpd and it has been averaging about 22,000 bpd since line-fill. All in all, it sounded like a reasonably feasible, routine project. But perceptions can be deceiving, or at least misleading. In other words, the project can be summarized as follows: one river, two cultures and a world of difference. The official border crossing for pipeline construction took place on Dec. 2, 1996, with a directional drill under the Rio Grande River, but in actuality, the joint venture partners were continually bridging differences in language, laws, customs and norms with Pemex and contracted workers from Mexico.

  19. Raptor Use of the Rio Grande Gorge

    SciTech Connect

    Ponton, David A.

    2015-03-20

    The Rio Grande Gorge is a 115 km long river canyon located in Southern Colorado (15 km) and Northern New Mexico (100 km). The majority of the canyon is under the administration of the Bureau of Land Management {BLM), and 77 km of the canyon south of the Colorado/New Mexico border are designated Wild River under the National Wild and Scenic Rivers Act of 1968. Visits I have made to the Rio Grande Gorge over the past 15 .years disclosed some raptor utilization. As the Snake River Birds of Prey Natural Area gained publicity, its similarity to the Rio Grande Gorge became obvious, and I was intrigued by the possibility of a high raptor nesting density in the Gorge. A survey in 1979 of 20 km of the northern end of the canyon revealed a moderately high density of red-tailed hawks and prairie falcons. With the encouragement of that partial survey, and a need to assess the impact of river-running on nesting birds of prey, I made a more comprehensive survey in 1980. The results of my surveys, along with those of a 1978 helicopter survey by the BLM, are presented in this report, as well as general characterization of the area, winter use by raptors, and an assessment of factors influencing the raptor population.

  20. SunShot Grand Challenge Summit

    Energy.gov [DOE]

    The SunShot Initiative at the U.S. Department of Energy (DOE) will host the second SunShot Grand Challenge Summit and Peer Review from May 19-22, 2014 at the Hilton Anaheim, California. The 2014 SunShot Summit brings together 800 esteemed members of the solar energy community including SunShot-funded project teams, industry leaders, innovative researchers and scientists, and local, state and federal government policymakers to review the progress made and discuss the challenges ahead to make solar energy more affordable and widespread across America.

  1. Saft America Advanced Batteries Plant Celebrates Grand Opening in

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Jacksonville | Department of Energy Saft America Advanced Batteries Plant Celebrates Grand Opening in Jacksonville Saft America Advanced Batteries Plant Celebrates Grand Opening in Jacksonville September 16, 2011 - 12:30pm Addthis Department of Energy Investment Helps Support Job Creation, U.S. Economic Competitiveness and Advanced Vehicle Industry WASHINGTON, D.C. - Today, Secretary Steven Chu joined with Saft America to announce the grand opening of the company's Jacksonville, Florida,

  2. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Signals in the Subsurface | Department of Energy SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface Grand Challenge Workshop -Imaging Subsurface.pdf (434.52 KB) More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - American Geophysical Union

  3. DOE Announces Awardees for the Industrial Energy Efficiency Grand Challenge

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Awardees for the Industrial Energy Efficiency Grand Challenge DOE Announces Awardees for the Industrial Energy Efficiency Grand Challenge May 5, 2010 - 12:00am Addthis WASHINGTON, DC - The U.S. Department of Energy announced today that 48 research and development projects across the country have been selected as award winners of the Industrial Energy Efficiency Grand Challenge. The grantees will receive a total of $13 million to fund the development of transformational

  4. Rio Grande County, Colorado: Energy Resources | Open Energy Informatio...

    OpenEI (Open Energy Information) [EERE & EIA]

    B. Places in Rio Grande County, Colorado Center, Colorado Del Norte, Colorado Monte Vista, Colorado South Fork, Colorado Retrieved from "http:en.openei.orgw...

  5. Sandia Energy - SunShot Grand Challenge: Regional Test Centers

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Challenge: Regional Test Centers Home Videos Renewable Energy Energy Events News SunShot News & Events Photovoltaic Solar SunShot Grand Challenge: Regional Test Centers Previous...

  6. EV Everywhere Grand Challenge Kick-Off | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Dearborn, MI framingworkshopagenda062112.pdf (85.02 KB) More Documents & Publications EV Everywhere Grand Challenge Overview Presentation EV Everywhere Framing Workshop - ...

  7. Grand Blanc, Michigan: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    5th congressional district.12 Registered Energy Companies in Grand Blanc, Michigan 21st century Green Solutions LLC References US Census Bureau Incorporated place and...

  8. Alpine Extensional Detachment Tectonics In The Grande Kabylie...

    OpenEI (Open Energy Information) [EERE & EIA]

    Extensional Detachment Tectonics In The Grande Kabylie Metamorphic Core Complex Of The Maghrebides (Northern Algeria) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  9. Winning the Future: Grand Ronde Solar Projects Reduce Pollution...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    coastal range, the Confederated Tribes of the Grand Ronde Community of Oregon has a strong connection to the earth and nature and a deep commitment to environmental stewardship. ...

  10. EV Everywhere Grand Challenge: Consumer Acceptance and Charging...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Agenda for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on July 30, 2012 held at the LAX Marriott, Los Angeles, CA PDF icon ...

  11. EV Everywhere Grand Challenge: Consumer Acceptance and Charging...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Attnedance list for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on July 30, 2012 held at the LAX Marriott, Los Angeles, CA PDF icon ...

  12. Statement by Energy Secretary Steven Chu on Today's Grand Opening...

    Energy Saver

    on today's grand opening of the Nordex wind turbine manufacturing facility in Jonesboro. ... to assist in the creation of a wind turbine manufacturing facility in Jonesboro, Arkansas. ...

  13. Field Studies of Geothermal Reservoirs: Rio Grande Rift, New...

    OpenEI (Open Energy Information) [EERE & EIA]

    Abstract The Rio Grande rift provides an excellent field laboratory to study the nature of geothermal systems in an extensional environment. Much of the geologic complexity...

  14. EV Everywhere Grand Challenge- Battery Status and Cost Reduction Prospects

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by technology manager David Howell at the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree O'Hare, Chicago, IL.

  15. Sierra Grande Lodge Pool & Spa Low Temperature Geothermal Facility...

    OpenEI (Open Energy Information) [EERE & EIA]

    Spa Low Temperature Geothermal Facility Facility Sierra Grande Lodge Sector Geothermal energy Type Pool and Spa Location Truth or Consequences, New Mexico Coordinates 33.1284047,...

  16. EV Everywhere Grand Challenge- Battery Workshop attendees list

    Energy.gov [DOE]

    Attendance list for the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree O'Hare, Chicago, IL.

  17. Grand Rapids Public Util Comm | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    https:www.facebook.compagesGrand-Rapids-Public-Utilities108782819203449?skwall Outage Hotline: 218-326-4806 References: EIA Form EIA-861 Final Data File for 2010 -...

  18. Grand Opening of Abengoa's Biorefinery: Nation's Third Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The nation's third commercial-scale cellulosic ethanol biorefinery celebrates its grand ... The plant will produce cellulosic ethanol from non-edible corn stalks, stems, and leaves ...

  19. EV Everywhere Grand Challenge Introduction for Electric Drive...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Presentation given by EERE Assistant Secretary David Danielson at the EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop on July 24, ...

  20. EV Everywhere Grand Challenge - Electric Drive (Power Electronics...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    - Electric Drive (Power Electronics and Electric Machines) Workshop EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop List of ...

  1. SunShot Grand Challenge Summit | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SunShot Grand Challenge Summit Online registration is now closed Online registration is now closed Limited onsite registration is available. Learn more. Read more Resources for ...

  2. Grand Junction, Colorado: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    district.12 Registered Energy Companies in Grand Junction, Colorado Ruby Canyon Engineering Inc References US Census Bureau Incorporated place and minor civil...

  3. Summary of Grand Challenge Products Selected for Award Negotiations

    SciTech Connect

    2010-04-26

    DOE provides $13 million in funding to 48 research and development projects across the country that were selected as award winners of the Industrial Energy Efficiency Grand Challenge.

  4. City of Grand Junction, Iowa (Utility Company) | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Iowa (Utility Company) Jump to: navigation, search Name: Grand Junction Municipal Utilities Place: Iowa Phone Number: (515) 738-2285 or (515) 738-2726 Facebook: https:...

  5. Data Compendium for the Logging Test Pits at the ERDA Grand Junction...

    Energy.gov [DOE] (indexed site)

    Data Compendium for the Logging Test Pits at the ERDA Grand Junction Compound (December 1975) Data Compendium for the Logging Test Pits at the ERDA Grand Junction Compound ...

  6. Microsoft Word - Mn.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    5 Structural Determination of Marine Bacteriogenic Manganese Oxides John R. Bargar, Samuel M. Webb (Stanford Synchrotron Radiation Laboratory), and Bradley M. Tebo (Oregon Health and Science University) Bacterial oxidation of Mn(II) impacts the global geochemical cycling of carbon, nitrogen, sulfur, nutrients, and contaminants in the environment. Manganese is abundant in the biosphere (~10 14 Kg of suspended and dissolved manganese in the oceans) and is second only to iron in relative

  7. Mn4+ emission in pyrochlore oxides

    DOE PAGES [OSTI]

    Du, Mao-Hua

    2015-01-01

    For the existing Mn4+ activated red phosphors have relatively low emission energies (or long emission wavelengths) and are therefore inefficient for general lighting. Density functional calculations are performed to study Mn4+ emission in rare-earth hafnate, zirconate, and stannate pyrochlore oxides (RE2Hf2O7, RE2Zr2O7, and RE2Sn2O7). We show how the different sizes of the RE3+ cation in these pyrochlores affect the local structure of the distorted MnO6 octahedron, the Mn–O hybridization, and the Mn4+ emission energy. The Mn4+ emission energies of many pyrochlores are found to be higher than those currently known for Mn4+ doped oxides and should be closer to thatmore » of Y2O3:Eu3+ (the current commercial red phosphor for fluorescent lighting). The O–Mn–O bond angle distortion in a MnO6 octahedron is shown to play an important role in weakening Mn–O hybridization and consequently increasing the Mn4+ emission energy. Our result shows that searching for materials that allow significant O–Mn–O bond angle distortion in a MnO6 octahedron is an effective approach to find new Mn4+ activated red phosphors with potential to replace the relatively expensive Y2O3:Eu3+ phosphor.« less

  8. Proposal to Control Tank Vapors Wins ORP's Grand Challenge | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Proposal to Control Tank Vapors Wins ORP's Grand Challenge Proposal to Control Tank Vapors Wins ORP's Grand Challenge October 17, 2016 - 12:50pm Addthis Mark Edgren, ORP chief of staff, left, presents Larry Shaffer and Clinton Summers with a plaque announcing their Grand Challenge-winning proposal. The two were part of a four-person team whose proposal aims to destroy organic bearing compounds and remove mercury by installing special skid-mounted treatment units to the vent pipes

  9. EV Everywhere Grand Challenge Blueprint | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EV Everywhere Grand Challenge Blueprint EV Everywhere Grand Challenge Blueprint Recognizing that vehicle electrification is an essential part of our countrys "all-of-the above" energy strategy, President Obama issued the EV Everywhere Grand Challenge to the nation in March 2012 with the bold goal to enable plug-in electric vehicles (PEVs) that are as affordable and convenient for the American family as gasoline-powered vehicles by 2022. This "Blueprint" provides an outline

  10. SUNSHOT GRAND CHALLENGE SUMMIT AND PEER REVIEW EVENT PROGRAM

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    GRAND CHALLENGE SUMMIT AND PEER REVIEW EVENT PROGRAM MAY 19-22 2014 ANAHEIM, CALIFORNIA Hilton Anaheim 3 Welcome to the SunShot Grand Challenge Summit and Peer Review 2014 Building on the success of the first SunShot Initiative Grand Challenge Summit in 2012, this year's premier gathering convenes hundreds of the best and the brightest in the solar community to review the progress made toward the SunShot goal - including 60% progress to achieving cost-competitive utility-scale solar electricity

  11. EV Everywhere Grand Challenge Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    3_davis_caci.pdf (591.63 KB) More Documents & Publications EV Everywhere Framing Workshop Report Out & Lessons Learned EV Everywhere Framing Workshop - Report Out & Lessons Learned EV Everywhere Grand Challenge - Charge to the Breakout Groups

  12. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    PDF icon Grand Challenge Workshop -Imaging Subsurface.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - ...

  13. EV Everywhere Grand Challenge Introduction for Electric Drive Workshop

    Energy.gov [DOE]

    Presentation given by EERE Assistant Secretary David Danielson at the EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop on July 24, 2012 held at the Doubletree O'Hare, Chicago, IL.

  14. EA-1037: Uranium Lease Management Program, Grand Junction, Colorado

    Office of Energy Efficiency and Renewable Energy (EERE)

    This EA evaluates the environmental impacts of the U.S. Department of Energy's Grand Junction Projects Office's proposal to maintain and preserve the nation's immediately accessible supply of...

  15. Evaluation of Geothermal Potential of Rio Grande Rift and Basin...

    OpenEI (Open Energy Information) [EERE & EIA]

    to: navigation, search OpenEI Reference LibraryAdd to library Report: Evaluation of Geothermal Potential of Rio Grande Rift and Basin and Range Province, New Mexico Abstract A...

  16. City of Grand Rapids- Green Power Purchasing Policy

    Energy.gov [DOE]

    In 2005, the City of Grand Rapids established a goal of purchasing 20% of its municipal power demand from renewable energy by 2008. In November 2007, the city signed a three-year agreement with a...

  17. EV Everywhere Grand Challenge - Battery Status and Cost Reduction...

    Energy.gov [DOE] (indexed site)

    Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree O'Hare, Chicago, IL. 5howellb.pdf (1.24 MB) More Documents & Publications PHEV Battery Cost Assessment ...

  18. EV Everywhere Grand Challenge - Battery Workshop attendees list...

    Energy.gov [DOE] (indexed site)

    Attendance list for the EV Everywhere Grand Challenge: Battery Workshop on July 26, 2012 held at the Doubletree OHare, Chicago, IL. companiesinattendanceb.pdf (149.45 KB) More ...

  19. 2014 SunShot Grand Challenge Summit Opening Session Photos |...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Anaheim Mayor Tom Tait with SunShot Director Minh Le Credit: SunShot Initiative Date ... SunShot Grand Challenge Summit Opening Session SunShot Director Minh Le Credit: SunShot ...

  20. Grand Forks County, North Dakota: Energy Resources | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Dakota. Its FIPS County Code is 035. It is classified as ASHRAE 169-2006 Climate Zone Number 7 Climate Zone Subtype A. Registered Energy Companies in Grand Forks County, North...

  1. Arroyo Grande, California: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    This article is a stub. You can help OpenEI by expanding it. Arroyo Grande is a city in San Luis Obispo County, California. It falls under California's 22nd congressional...

  2. Casa Grande, Arizona: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Hide Map This article is a stub. You can help OpenEI by expanding it. Casa Grande is a city in Pinal County, Arizona. It falls under Arizona's 1st congressional...

  3. Fernald Preserve Visitors Center Grand Opening and LEED Platinum

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Certification | Department of Energy Fernald Preserve Visitors Center Grand Opening and LEED Platinum Certification Fernald Preserve Visitors Center Grand Opening and LEED Platinum Certification October 16, 2008 - 4:14pm Addthis Remarks as Prepared for Acting Deputy Secretary Kupfer Thank you, Mike, for that introduction and to both you and Jane for hosting this event. You both have been instrumental in the dramatic transformation of this site. We made a commitment more than a decade ago to

  4. EV Everywhere Grand Challenge - Electric Drive (Power Electronics and

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Electric Machines) Workshop | Department of Energy - Electric Drive (Power Electronics and Electric Machines) Workshop EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop List of companies in attendance at the Electric Drive Workshop held on July 24, 2012 at the Doubletree O'Hare, Chicago, IL companies_in_attendance_ed.pdf (145.65 KB) More Documents & Publications EV Everywhere Grand Challenge Introduction for Electric Drive Workshop EV

  5. EV Everywhere Grand Challenge - Charging Infrastructure Enabling Flexible

    Energy Saver

    EV Design | Department of Energy Charging Infrastructure Enabling Flexible EV Design EV Everywhere Grand Challenge - Charging Infrastructure Enabling Flexible EV Design Presentation given at the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on July 30, 2012 held at the LAX Marriott, Los Angeles, CA 5_slezak_caci.pdf (2 MB) More Documents & Publications EV Everywhere Framing Workshop - Report Out & Lessons Learned EV Everywhere Framing

  6. EV Everywhere Grand Challenge: Consumer Acceptance and Charging

    Energy Saver

    Electric Machines) Workshop | Department of Energy - Electric Drive (Power Electronics and Electric Machines) Workshop EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop List of companies in attendance at the Electric Drive Workshop held on July 24, 2012 at the Doubletree O'Hare, Chicago, IL companies_in_attendance_ed.pdf (145.65 KB) More Documents & Publications EV Everywhere Grand Challenge Introduction for Electric Drive Workshop EV

  7. EV Everywhere Grand Challenge: Consumer Acceptance and Charging

    Energy Saver

    Infrastructure Workshop Attendence List | Department of Energy Attendence List EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop Attendence List Attnedance list for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on July 30, 2012 held at the LAX Marriott, Los Angeles, CA companies_in_attendance_caci.pdf (137.02 KB) More Documents & Publications EV Everywhere Consumer Acceptance and Charging Infrastructure

  8. Montage Builders Northern Forest, Ryerson University Selected as Grand

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Winners of First Student Design Competition for Zero Energy Ready Homes | Department of Energy Montage Builders Northern Forest, Ryerson University Selected as Grand Winners of First Student Design Competition for Zero Energy Ready Homes Montage Builders Northern Forest, Ryerson University Selected as Grand Winners of First Student Design Competition for Zero Energy Ready Homes April 29, 2014 - 2:15pm Addthis To help cut energy waste and improve U.S. energy productivity, the Energy

  9. SubTER Grand Challenge Roundtable: Imaging Geophysical and

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface The Grand Challenge SubTER Panel (Dr. Marcia McNutt, Chair) DOE Leads: Margaret Coleman, Julio Friedmann, Doug Hollett, and Harriet Kung Introduction The future of the world's energy production and deployment is closely tied to our understanding of the subsurface, as well as our capabilities in subsurface or geologic engineering. Developments over the past ten years, including the growth of natural

  10. EA-1338: Transfer of the Department of Energy Grand Junction Office to Non-DOE Ownership, Grand Junction, Colorado

    Office of Energy Efficiency and Renewable Energy (EERE)

    This EA evaluates the environmental impacts for the proposed transfer of real and personal property at the U.S. Department of Energy's Grand Junction Office to non-DOE ownership.

  11. PP-33-1 and EA-33-A Rio Grande Electric Cooperative Inc | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy -1 and EA-33-A Rio Grande Electric Cooperative Inc PP-33-1 and EA-33-A Rio Grande Electric Cooperative Inc Rescission of Presidential Permit and Electricity Export Authorization for Rio Grande Electric Cooperative to Export electricity to Mexico. PP-33-1 and EA-33-A Rio Grande Electric Cooperative Inc (52.93 KB) More Documents & Publications EA-33-A and PP-33-1 Rio Grande Electric Cooperative, Inc. PP-53 Rio Grande Electric Cooperative, Inc. PP-33 Rio Grande Electric Cooperative

  12. Magnetostructural phase transformations in Tb 1-x Mn 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    phase transformations in Tb 1-x Mn 2 Citation Details In-Document Search Title: Magnetostructural phase transformations in Tb 1-x Mn 2 Magnetism and phase transformations ...

  13. DOE - Office of Legacy Management -- Elk River Reactor - MN 01

    Office of Legacy Management (LM)

    Designated Name: Not Designated Alternate Name: None Location: Elk River , Minnesota MN.01-1 Evaluation Year: 1985 MN.01-1 Site Operations: Boiling water reactor demonstration, ...

  14. Magnetocrystalline anisotropy in UMn<mn>2mn>Ge>2mn> and related Mn-based actinide ferromagnets

    SciTech Connect

    Parker, David S.; Ghimire, Nirmal; Singleton, John; Thompson, J. D.; Bauer, Eric D.; Baumbach, Ryan; Mandrus, David; Li, Ling; Singh, David J.

    2015-05-04

    We present magnetization isotherms in pulsed magnetic fields up to 62 Tesla, supported by first principles calculations, demonstrating a huge uniaxial magnetocrystalline anisotropy energy - approximately 20 MJ/m3 - in UMn<mn>2mn>Ge>2mn>. This large anisotropy results from the extremely strong spin-orbit coupling affecting the uranium 5 f electrons, which in the calculations exhibit a substantial orbital moment exceeding 2 μB. Finally, we also find from theoretical calculations that a number of isostructural Mn-actinide compounds are expected to have similarly large anisotropy.

  15. Environmental Audit of the Grand Junction Projects Office

    SciTech Connect

    Not Available

    1991-08-01

    The Grand Junction Projects Office (GJPO) is located in Mesa County, Colorado, immediately south and west of the Grand Junction city limits. The US Atomic Energy Commission (AEC) established the Colorado Raw Materials Office at the present-day Grand Junction Projects Office in 1947, to aid in the development of a viable domestic uranium industry. Activities at the site included sampling uranium concentrate; pilot-plant milling research, including testing and processing of uranium ores; and operation of a uranium mill pilot plant from 1954 to 1958. The last shipment of uranium concentrate was sent from GJPO in January, 1975. Since that time the site has been utilized to support various DOE programs, such as the former National Uranium Resource Evaluation (NURE) Program, the Uranium Mill Tailings Remedial Action Project (UMTRAP), the Surplus Facilities Management Program (SFMP), and the Technical Measurements Center (TMC). All known contamination at GJPO is believed to be the result of the past uranium milling, analyses, and storage activities. Hazards associated with the wastes impounded at GJPO include surface and ground-water contamination and potential radon and gamma-radiation exposure. This report documents the results of the Baseline Environmental Audit conducted at Grand Junction Projects Office (GJPO) located in Grand Junction, Colorado. The Grand Junction Baseline Environmental Audit was conducted from May 28 to June 12, 1991, by the Office of Environmental Audit (EH-24). This Audit evaluated environmental programs and activities at GJPO, as well as GJPO activities at the State-Owned Temporary Repository. 4 figs., 12 tabs.

  16. EA-33-A and PP-33-1 Rio Grande Electric Cooperative, Inc. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy -A and PP-33-1 Rio Grande Electric Cooperative, Inc. EA-33-A and PP-33-1 Rio Grande Electric Cooperative, Inc. Order authorizing Rio Grande Electric Cooperative, Inc to export electric energy to Mexico EA-33-A and PP-33-1 Rio Grande Electric Cooperative, Inc. (52.93 KB) More Documents & Publications PP-33-1 and EA-33-A Rio Grande Electric Cooperative Inc PP-53 Rio Grande Electric Cooperative, Inc. EA-288 Vermont

  17. 2014 SunShot Grand Challenge Summit Opening Session Photos | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy 2014 SunShot Grand Challenge Summit Opening Session Photos 2014 SunShot Grand Challenge Summit Opening Session Photos Addthis SunShot Grand Challenge Summit Opening Session 1 of 35 SunShot Grand Challenge Summit Opening Session Anaheim Mayor Tom Tait with SunShot Director Minh Le Credit: SunShot Initiative Date taken: 2014-05-19 16:01 SunShot Grand Challenge Summit Opening Session 2 of 35 SunShot Grand Challenge Summit Opening Session SunShot Director Minh Le Credit: SunShot

  18. Magnetic coupling in ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers

    SciTech Connect

    Wang, M.; Wadley, P.; Campion, R. P.; Rushforth, A. W.; Edmonds, K. W.; Gallagher, B. L.; Charlton, T. R.; Kinane, C. J.; Langridge, S.

    2015-08-07

    We report on a study of ferromagnetic semiconductor (Ga,Mn)As/(Al,Ga,Mn)As bilayers using magnetometry and polarized neutron reflectivity (PNR). From depth-resolved characterization of the magnetic structure obtained by PNR, we concluded that the (Ga,Mn)As and (Al,Ga,Mn)As layers have in-plane and perpendicular-to-plane magnetic easy axes, respectively, with weak interlayer coupling. Therefore, the layer magnetizations align perpendicular to each other under low magnetic fields and parallel at high fields.

  19. SSL Demonstration: Bridge Lighting, Minneapolis, MN

    SciTech Connect

    2014-10-01

    DOE Solid-State Lighting GATEWAY summary brief for Phase II report on the longer-term performance of LED lighting installed in 2008 on the I-35W Bridge in Minneapolis, MN.

  20. Grand Traverse Band of Ottawa and Chippewa Indians- 2005 Project

    Energy.gov [DOE]

    The Grand Traverse Band of Ottawa and Chippewa Indians (GTB) will conduct a feasibility study to determine the cost effectiveness and other economic, environmental, cultural, and social benefits of maximizing the diversity of energy sources used at GTB facilities. This includes an assessment of energy conservation measures as well as renewable energy sources such as wind, solar, and biomass.

  1. Mesa Grande Band of Mission Indians- 2004 Project

    Energy.gov [DOE]

    The Mesa Grande Band of Mission Indians, located in northern San Diego County, will conduct a study of the feasibility of reducing air pollution generated on the reservation by an over-reliance on wood-burning stoves, kerosene heaters, and gasoline generators, and to identify the types of renewable energy systems that could be used for residential structures and well-pump systems.

  2. High Mn austenitic stainless steel

    DOEpatents

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  3. Save the Date: 2014 SunShot Grand Challenge Summit, May 19-22...

    Energy.gov [DOE] (indexed site)

    2014 SunShot Grand Challenge Summit and Peer Review SunShot Grand Challenge Summit Opening Session Energy Department Announces New Prize Challenge to Drive Down Solar Costs

  4. The emerging multi-polar world and China's grand game (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: The emerging multi-polar world and China's grand game Citation Details In-Document Search Title: The emerging multi-polar world and China's grand game You are ...

  5. Solar Community Comes Out in Full Force for SunShot Grand Challenge...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit May 22, 2014 - 9:58am Addthis ...

  6. Winning the Future: Grand Ronde Solar Projects Reduce Pollution, Cut Costs

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Grand Ronde Solar Projects Reduce Pollution, Cut Costs Winning the Future: Grand Ronde Solar Projects Reduce Pollution, Cut Costs October 20, 2014 - 5:00pm Addthis PV panels installed on Grand Ronde Tribal Housing Authority carport. Photo from GRTHA, NREL 31797 PV panels installed on Grand Ronde Tribal Housing Authority carport. Photo from GRTHA, NREL 31797 Challenge: Situated on nearly 12,000 acres in the heart of Western Oregon's scenic coastal range, the

  7. Grand Traverse Band Renewable Energy Feasibility Study in Wind, Biomass and Solar

    SciTech Connect

    Suzanne McSawby, Project Director Steve Smiley, Principle Investigator Grand Traverse Resort, Cost Sharing Partner

    2008-12-31

    Renewable Energy Feasibility Study for wind, biomass, solar on the Grand Traverse Band tribal lands from 2005 - 2008

  8. Local environment of Mn in Mn delta-doped Si layers

    SciTech Connect

    Xiao, Q.F.; Kahwaji, S.; Monchesky, T.L.; Gordon, R.A.; Crozier, E.D.

    2009-11-09

    Dilute magnetic semiconductors combine both magnetic ordering and semiconducting behaviour, leading to potential spintronic applications. Silicon containing dilute Mn impurities is a potential dilute magnetic semiconductor. We have grown Mn delta-doped films by deposition of 0.7 of a monolayer of Mn on Si(001) by molecular beam epitaxy and capping the film with Si. The magnetic properties are likely sensitive to the distribution of Mn on substitutional or interstitial sites and the formation of metallic precipitates. We have used polarization-dependent XAFS to examine the local structure. We compare to a thicker MnSi film grown on Si(111) and also examine the influence of lead on the manganese environment when used as a surfactant in the growth process.

  9. Structural, magnetic, and superconducting properties of pulsed-laser-deposition-grown La<mn>1.85mn> Sr<mn>0.15mn> CuO<mn>4mn> / La<mn>2mn>/>3mn> Ca<mn>1mn>/>3mn> MnO>3mn> superlattices on (001)-oriented LaSrAlO<mn>4mn> substrates

    SciTech Connect

    Das, S.; Sen, K.; Marozau, I.; Uribe-Laverde, M. A.; Biskup, N.; Varela, M.; Khaydukov, Y.; Soltwedel, O.; Keller, T.; Döbeli, M.; Schneider, C. W.; Bernhard, C.

    2014-03-12

    Epitaxial La<mn>1.85mn> Sr<mn>0.15mn> CuO<mn>4mn> / La<mn>2mn>/>3mn> Ca<mn>1mn>/>3mn> MnO>3mn> (LSCO/LCMO) superlattices (SL) on (001)- oriented LaSrAlO4 substrates have been grown with pulsed laser deposition (PLD) technique. Their structural, magnetic and superconducting properties have been determined with in-situ reflection high energy electron diffraction (RHEED), x-ray diffraction, specular neutron reflectometry, scanning transmission electron microscopy (STEM), electric transport, and magnetization measurements. We find that despite the large mismatch between the in-plane lattice parameters of LSCO (a = 0.3779 nm) and LCMO (a = 0.387 nm) these superlattices can be grown epitaxially and with a high crystalline quality. While the first LSCO layer remains clamped to the LSAO substrate, a sizeable strain relaxation occurs already in the first LCMO layer. The following LSCO and LCMO layers adopt a nearly balanced state in which the tensile and compressive strain effects yield alternating in-plane lattice parameters with an almost constant average value. No major defects are observed in the LSCO layers, while a significant number of vertical antiphase boundaries are found in the LCMO layers. The LSCO layers remain superconducting with a relatively high superconducting onset temperature of Tconset ≈ 36 K. The macroscopic superconducting response is also evident in the magnetization data due to a weak diamagnetic signal below 10 K for H ∥ ab and a sizeable paramagnetic shift for H ∥ c that can be explained in terms of a vortex-pinning-induced flux compression. The LCMO layers maintain a

  10. (In,Mn)As multilayer quantum dot structures

    SciTech Connect

    Bouravleuv, Alexei; Sapega, Victor; Nevedomskii, Vladimir; Khrebtov, Artem; Samsonenko, Yuriy; Cirlin, George

    2014-12-08

    (In,Mn)As multilayer quantum dots structures were grown by molecular beam epitaxy using a Mn selective doping of the central parts of quantum dots. The study of the structural and magneto-optical properties of the samples with three and five layers of (In,Mn)As quantum dots has shown that during the quantum dots assembly, the out-diffusion of Mn from the layers with (In,Mn)As quantum dots can occur resulting in the formation of the extended defects. To produce a high quality structures using the elaborated technique of selective doping, the number of (In,Mn)As quantum dot layers should not exceed three.

  11. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  12. City of Grand Rapids Building Solar Roof Demonstration

    SciTech Connect

    DeClercq, Mark; Martinez, Imelda

    2012-08-31

    Grand Rapids, Michigan is striving to reduce it environmental footprint. The municipal government organization has established environmental sustainability policies with the goal of securing 100% of its energy from renewable sources by 2020. This report describes the process by which the City of Grand Rapids evaluated, selected and installed solar panels on the Water/Environmental Services Building. The solar panels are the first to be placed on a municipal building. Its new power monitoring system provides output data to assess energy efficiency and utilization. It is expected to generate enough clean solar energy to power 25 percent of the building. The benefit to the public includes the economic savings from reduced operational costs for the building; an improved environmentally sustainable area in which to live and work; and increased knowledge about the use of solar energy. It will serve as a model for future energy saving applications.

  13. EV Everywhere Grand Challenge Road to Success | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Road to Success EV Everywhere Grand Challenge Road to Success Initial progress report for EV Everywhere. The report highlights the significant cost reduction in batteries this year, which will enable increased PEV affordability for consumers. Also, the efforts on increasing the convenience of PEVs through the Workplace Charging Challenge, which calls on U.S. employers to help develop the nation's charging infrastructure. eveverywhere_road_to_success.pdf (4.01 MB) More Documents &

  14. Grande Ronde Basin Supplementation Program; Lostine River, 2000 Annual Report.

    SciTech Connect

    Onjukka, Sam T.; Harbeck, Jim

    2003-03-01

    The Northwest Power Planning Council (NPPC) identified supplementation as a high priority to achieve its goal of increasing runs of anadromous fish in the Columbia Basin. Supplementation activities in the Lostine River and associated monitoring and evaluation conducted by the Nez Perce Tribe relate directly to the needs addressed in the Columbia River Basin Fish and Wildlife Program (NPPC 1994). Measure 7.4L.1 of the Program mandates that appropriate research accompany any proposed supplementation. In addition, measure 7.3B.2 of the Program stresses the need for evaluating supplementation projects to assess their ability to increase production. Finally, Section 7.4D.3 encourages the study of hatchery rearing and release strategies to improve survival and adaptation of cultured fish. In 1997, Oregon Department of Fisheries and Wildlife (ODFW) requested a modification of Permit 1011 to allow the take of adult spring chinook salmon. In 1998, the Nez Perce Tribe also requested a permit specific to activities on Lostine River. The permit was issued in 2000. A special condition in the permits required the development of a long term management plan for the spring chinook salmon of the Grande Ronde Basin. The Nez Perce Tribe, ODFW, and the Confederated Tribes of the Umatilla Indian Reservation (CTUIR) completed a formal long range plan entitled ''Grande Ronde Basin Endemic Spring Chinook Salmon Supplementation Program''. The program proposes to increase the survival of spring chinook salmon in the Grand Ronde Basin through hatchery intervention. Adult salmon from the Lostine River, Catherine Creek, and the Upper Grande Ronde River are used for a conventional supplementation program in the basin. The Nez Perce program currently operates under the ESA Section 10 Permit 1149.

  15. Grande Ronde Basin Supplementation Program; Lostine River, 2001 Annual Report.

    SciTech Connect

    Onjukka, Sam T.; Harbeck, Jim

    2003-03-01

    The Northwest Power Planning Council (NPPC) identified supplementation as a high priority to achieve its goal of increasing runs of anadromous fish in the Columbia Basin. Supplementation activities in the Lostine River and associated monitoring and evaluation conducted by the Nez Perce Tribe relate directly to the needs addressed in the Columbia River Basin Fish and Wildlife Program (NPPC 1994). Measure 7.4L.1 of the Program mandates that appropriate research accompany any proposed supplementation. In addition, measure 7.3B.2 of the Program stresses the need for evaluating supplementation projects to assess their ability to increase production. Finally, Section 7.4D.3 encourages the study of hatchery rearing and release strategies to improve survival and adaptation of cultured fish. In 1997, Oregon Department of Fisheries and Wildlife (ODFW) requested a modification of Permit 1011 to allow the take of adult spring chinook salmon. In 1998, the Nez Perce Tribe also requested a permit specific to activities on Lostine River. The permit was issued in 2000. A special condition in the permits required the development of a long term management plan for the spring chinook salmon of the Grande Ronde Basin. The Nez Perce Tribe, ODFW, and the Confederated Tribes of the Umatilla Indian Reservation (CTUIR) completed a formal long range plan entitled ''Grande Ronde Basin Endemic Spring Chinook Salmon Supplementation Program''. The program proposes to increase the survival of spring chinook salmon in the Grand Ronde Basin through hatchery intervention. Adult salmon from the Lostine River, Catherine Creek, and the Upper Grande Ronde River are used for a conventional supplementation program in the basin. The Nez Perce program currently operates under the ESA Section 10 Permit 1149.

  16. Grand Challenge Winning Entry Proposes Efficiencies to Tank Waste Cleanup |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Winning Entry Proposes Efficiencies to Tank Waste Cleanup Grand Challenge Winning Entry Proposes Efficiencies to Tank Waste Cleanup December 29, 2015 - 12:55pm Addthis From left, Elaine Diaz, Office of River Protection (ORP) acting chief engineer; John Vienna, Pacific Northwest National Laboratory scientist; Albert Kruger, ORP glass scientist; and Kevin Smith, ORP manager. From left, Elaine Diaz, Office of River Protection (ORP) acting chief engineer; John Vienna,

  17. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE PAGES [OSTI]

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore » a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) μB and 0.81(4)μB, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 < J1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  18. Environmental assessment of facility operations at the U.S. Department of Energy Grand Junction Projects Office, Grand Junction, Colorado

    SciTech Connect

    1996-06-01

    The US Department of Energy (DOE) has prepared a sitewide environmental assessment (EA) of the proposed action to continue and expand present-day activities on the DOE Grand Junction Projects Office (GJPO) facility in Grand Junction, Colorado. Because DOE-GJPO regularly proposes and conducts many different on-site activities, DOE decided to evaluate these activities in one sitewide EA rather than in multiple, activity-specific documents. On the basis of the information and analyses presented in the EA, DOE has determined that the proposed action does not constitute a major Federal action significantly affecting the quality of the human environment, as defined by the National Environmental Policy Act (NEPA) of 1969. Therefore, preparation of an environmental impact statement is not required for facility operations, and DOE is issuing this Finding of No Significant Impact (FONSI).

  19. Magnetoelectric coupling tuned by competing anisotropies in Mn...

    Office of Scientific and Technical Information (OSTI)

    Magnetoelectric coupling tuned by competing anisotropies in Mn 1 - x Ni x TiO 3 Prev Next Title: Magnetoelectric coupling tuned by competing anisotropies in Mn 1 - x Ni x TiO ...

  20. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    SciTech Connect

    Taylor, Alice E; Berlijn, Tom; Hahn, Steven E; May, Andrew F; Williams, Travis J; Poudel, Lekhanath N; Calder, Stuart A; Fishman, Randy Scott; Stone, Matthew B; Aczel, Adam A; Cao, Huibo; Lumsden, Mark D; Christianson, Andrew D

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int

  1. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    DOE PAGES [OSTI]

    Taylor, Alice E; Berlijn, Tom; Hahn, Steven E; May, Andrew F; Williams, Travis J; Poudel, Lekhanath N; Calder, Stuart A; Fishman, Randy Scott; Stone, Matthew B; Aczel, Adam A; et al

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (Hmore » K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int« less

  2. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    DOE PAGES [OSTI]

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010]/χ[001] ≈ 3.5. A strong power-lawmore » divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.« less

  3. Reviewing the success of intentional flooding of the Grand Canyon

    SciTech Connect

    Wirth, B.D.

    1997-04-01

    A description and evaluation of the results of an intentional flooding experiment at the Grand Canyon are described. The purpose of the 7-day release of flood waters from the Glen Canyon Dam was to determine if managed floods have the ability to predictably restore the riverine environment. A summary of environmental conditions leading to the experiment is provided and flood results are listed. Initial results showed significant improvement in the size and number of the river`s beaches, creation of backwater habitat for endangered species, and no adverse impact to the trout fishery, Indian cultural sites, and other resources.

  4. Growth mode and structures of magnetic Mn clusters on graphene

    DOE PAGES [OSTI]

    Liu, Xiaojie; Wang, Cai-Zhuang

    2016-06-22

    We present a systematic study of Mn clusters on graphene by first-principles calculations. We show that the growth of Mn on graphene follows a three-dimensional (3D) mode. Both adsorption and attachment energies show that (Mn)3 and (Mn)6 on graphene are energetically favorable in the size range (Mn)1-7. Moreover, larger formation energy for Mn cluster on graphene implies the incoming Mn atoms are likely to nucleate and grow into bigger and bigger Mn clusters on graphene. The magnetic moments of (Mn)1,5,7 on graphene are enhanced by 11%, 186%, and 26% from their values at free-standing clusters, respectively. By contrast, the netmore » magnetic moment of (Mn)2,3,4,6 on graphene is reduced from that of the corresponding free-standing clusters. The origin of the magnetic moment changes can be attributed to the charge transfer within the Mn clusters and between the clusters and graphene upon adsorption.« less

  5. Monitoring of the Airport Calibration Pads at Walker Field, Grand Junction,

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Colorado, for Long-Term Radiation Variations (August 1978) | Department of Energy of the Airport Calibration Pads at Walker Field, Grand Junction, Colorado, for Long-Term Radiation Variations (August 1978) Monitoring of the Airport Calibration Pads at Walker Field, Grand Junction, Colorado, for Long-Term Radiation Variations (August 1978) Monitoring of the Airport Calibration Pads at Walker Field, Grand Junction, Colorado, for Long-Term Radiation Variations (August 1978) Monitoring of the

  6. Statement by Energy Secretary Steven Chu on Today's Grand Opening of the

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Nordex Manufacturing Facility in Jonesboro, Arkansas | Department of Energy Today's Grand Opening of the Nordex Manufacturing Facility in Jonesboro, Arkansas Statement by Energy Secretary Steven Chu on Today's Grand Opening of the Nordex Manufacturing Facility in Jonesboro, Arkansas October 29, 2010 - 12:00am Addthis WASHINGTON, D.C. - U.S. Energy Secretary Steven Chu issued the following statement on today's grand opening of the Nordex wind turbine manufacturing facility in Jonesboro. The

  7. Updated Radiation Exhibit Unveiled at Math and Science Center in Grand

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Junction, Colorado | Department of Energy Updated Radiation Exhibit Unveiled at Math and Science Center in Grand Junction, Colorado Updated Radiation Exhibit Unveiled at Math and Science Center in Grand Junction, Colorado April 26, 2016 - 4:50pm Addthis What does this project do? Goal 6. Engage the Public, Governments, and Interested Parties A newly updated radiation exhibit, created by the U.S. Department of Energy (DOE) Office of Legacy Management (LM) office in Grand Junction, Colorado,

  8. Geomorphology of plutonium in the Northern Rio Grande

    SciTech Connect

    Graf, W.L.

    1993-03-01

    Nearly all of the plutonium in the natural environment of the Northern Rio Grande is associated with soils and sediment, and river processes account for most of the mobility of these materials. A composite regional budget for plutonium based on multi-decadal averages for sediment and plutonium movement shows that 90 percent of the plutonium moving into the system is from atmospheric fallout. The remaining 10 percent is from releases at Los Alamos. Annual variation in plutonium flux and storage exceeds 100 percent. The contribution to the plutonium budget from Los Alamos is associated with relatively coarse sediment which often behaves as bedload in the Rio Grande. Infusion of these materials into the main stream were largest in 1951, 1952, 1957, and 1968. Because of the schedule of delivery of plutonium to Los Alamos for experimentation and weapons manufacturing, the latter two years are probably the most important. Although the Los Alamos contribution to the entire plutonium budget was relatively small, in these four critical years it constituted 71--86 percent of the plutonium in bedload immediately downstream from Otowi.

  9. Media Invitation: 2014 SunShot Grand Challenge Summit and Peer Review |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Media Invitation: 2014 SunShot Grand Challenge Summit and Peer Review Media Invitation: 2014 SunShot Grand Challenge Summit and Peer Review April 14, 2014 - 4:27pm Addthis Media Invitation: 2014 SunShot Grand Challenge Summit and Peer Review You're Invited: 2014 SunShot Grand Challenge Summit and Peer Review Hear from solar's brightest visionaries about what's on the horizon for the U.S. solar energy industry WASHINGTON, D.C. -- Members of the media are invited to attend

  10. 2011 Annual Planning Summary for Office of Legacy Management (LM), Grand Junction (See LM APS)

    Energy.gov [DOE]

    The ongoing and projected Environmental Assessments and Environmental Impact Statements for 2011 and 2012 within the Office of Legacy Management (LM), Grand Junction (See LM APS).

  11. EIS-0344: Grand Coulee-Bell 500 kV Transmission Line

    Energy.gov [DOE]

    This EIS analyzes DOE's proposed action for the construction and operation of the proposed Grand Coulee-Bell 500-kV Transmission Line Project.

  12. SunShot Grand Challenge Highlights Ambitious Efforts along the Entire Solar Spectrum

    Energy.gov [DOE]

    Today at the SunShot Grand Challenge Summit in Denver, Energy Secretary Steven Chu lauded progress in driving down the cost of solar.

  13. EIS-0519: Rio Grande LNG Project and Rio Bravo Pipeline Project...

    Office of Environmental Management (EM)

    LNG Project and Rio Bravo Pipeline Project; Kleberg, Kenedy, Willacy, and Cameron Counties, Texas EIS-0519: Rio Grande LNG Project and Rio Bravo Pipeline Project; Kleberg, Kenedy, ...

  14. Feasibility for Reintroducing Sockeye and Coho Salmon in the Grande Ronde Basin, 1998 Final Report.

    SciTech Connect

    Cramer, Steven P.; Witty, Kenneth L.

    1998-07-01

    A report concerning the feasibility of reintroducing Sockeye Salmon into Wallowa Lake and Coho Salmon into the Grande Ronde River Basin.

  15. Save the Date: 2014 SunShot Grand Challenge Summit, May 19-22, Anaheim, CA

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Save the Date: 2014 SunShot Grand Challenge Summit, May 19-22, Anaheim, CA Save the Date: 2014 SunShot Grand Challenge Summit, May 19-22, Anaheim, CA January 9, 2014 - 10:02am Addthis The SunShot Initiative at the U.S. Department of Energy (DOE) will host the second 2014 SunShot Grand Challenge Summit and Peer Review from May 19-22 in Anaheim, California. Building on the success of the first Grand Challenge Summit in 2012, this conference will bring together more than

  16. EV Everywhere EV Everywhere Grand Challenge- Electric Drive (Power Electronics and Electric Machines) Workshop Agenda

    Energy.gov [DOE]

    Agenda for the EV Everywhere Grand Challenge - Electric Drive Workshop on July 24, 2012 at the Doubletree O'Hare, Chicago, IL

  17. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn

    SciTech Connect

    Provino, A.; Paudyal, D.; Fornasini, ML; Dhiman, I.; Dhar, SK.; Das, A.; Mudryk, Y.; Manfrinetti, P.; Pecharsky, VK

    2013-01-29

    We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the MnCu2In and MnCu2Sn alloys. In contrast, the homologous compound MnCu4Sn, which crystallizes in the cubic MgCu4Sn-type, orders antiferromagnetically with TN = 110 K. The neutron diffraction studies show ferromagnetic spin orientation in the {1 0 1} plane in MnCu4In with a magnetic moment of 4.5 ?B/Mn at 22 K, and a corresponding value of 4.7 ?B/Mn in the antiferromagnetic MnCu4Sn with propagation vector View the MathML source. The first-principles electronic structure calculations show that the unexpected difference in both magnetic and crystal structures of MnCu4In and MnCu4Sn is due to the difference in the Mn-3d bands and exchange interactions relating to different crystal anisotropy, coordination numbers, and interatomic distances.

  18. Solid Solution Phases in the Olivine-Type LiMnPO4/MnPO4 System

    SciTech Connect

    Chen, Guoying; Richardson, Thomas J.

    2009-04-07

    Nonstoichiometry is reported in the LiMnPO{sub 4}/MnPO{sub 4} system for the first time. As lithium is removed from crystalline LiMnPO{sub 4} by chemical or electrochemical methods, the resulting two phase mixture consists of stoichiometric LiMnPO{sub 4} and a delithiated phase, Li{sub y}MnPO{sub 4}, whose lattice parameters depend upon the global extent of delithiation and on the crystalline domain size of the delithiated phase. This behavior is reproduced during electrochemical insertion of lithium. Again, no evidence for nonstoichiometry was found in the vicinity of LiMnPO{sub 4}. Attempts to create single phase solid solutions by heating mixtures of the two phases failed due to the thermal instability of Li{sub y}MnPO{sub 4}.

  19. Grande Ronde Basin Fish Habitat Enhancement Project : 2007 Annual Report.

    SciTech Connect

    McGowan, Vance R.; Morton, Winston H.

    2008-12-30

    On July 1, 1984 the Bonneville Power Administration and the Oregon Department of Fish and Wildlife entered into an intergovernmental contract to initiate fish habitat enhancement work in the Joseph Creek subbasin of the Grande Ronde River Basin in northeast Oregon. In 1985 the Upper and Middle Grande Ronde River, and Catherine Creek subbasins were included in the contract, and in 1996 the Wallowa River subbasin was added. The primary goal of 'The Grande Ronde Basin Fish Habitat Enhancement Project' is to create, protect, and restore riparian and instream habitat for anadromous salmonids, thereby maximizing opportunities for natural fish production within the basin. This project provided for implementation of Program Measure 703 (C)(1), Action Item 4.2 of the Northwest Power Planning Council's Columbia River Basin Fish and Wildlife Program (NPPC, 1987), and continues to be implemented as offsite mitigation for mainstem fishery losses caused by the Columbia River hydro-electric system. All work conducted by the Oregon Department of Fish and Wildlife and partners is on private lands and therefore requires that considerable time be spent developing rapport with landowners to gain acceptance of, and continued cooperation with this program throughout 10-15 year lease periods. Both passive and active restoration treatment techniques are used. Passive regeneration of habitat, using riparian exclosure fencing and alternate water sources are the primary method to restore degraded streams when restoration can be achieved primarily through changes in management. Active restoration techniques using plantings, bioengineering, site-specific instream structures, or whole stream channel alterations are utilized when streams are more severely degraded and not likely to recover in a reasonable timeframe. Individual projects contribute to and complement ecosystem and basin-wide watershed restoration efforts that are underway by state, federal, and tribal agencies, and coordinated by

  20. Salto Grande. [1890-MW project on Vruguay River

    SciTech Connect

    de Hoyos, R.J.

    1980-09-01

    A joint hydroelectric project, the Salto Grande Dam on the Uruguay River, serves six million people in Argentina and Uruguay. The construction day was continuous from April 1974 until the first turbine began on schedule in July 1979. Although planning began in 1890 by individual visionaries who saw the river's potential, serious efforts did not get underway for another 50 years. The project became a technical training school and has built up a recognized management team in the process. Financing became available only after the 1973 oil embargo. The benefits of regional cooperation to develop a common resource enables the two countries to provide water resources, electric power, navigable streams for commerce and recreation, a common highway, and an interconnecting railroad. The cooperative infrastructure established to meet the needs of project personnel has improved living conditions for the area. (DCK)

  1. A Leptophobic Z' And Dark Matter From Grand Unification

    SciTech Connect

    Buckley, Matthew R.; Hooper, Dan; Rosner, Jonathan L.

    2011-09-01

    We explore the phenomenology of Grand Unified Models based on the E_6 group, focusing on the Z' with suppressed couplings to leptons that can appear in such models. We find that this Z' can accommodate the W+dijets anomaly reported by the CDF collaboration. Furthermore, a viable dark matter candidate in the form of a right-handed sneutrino is also present within the fundamental 27-dimensional representation of E_6. Through its sizable couplings to the Z', the dark matter is predicted to possess an elastic scattering cross section with neutrons which can generate the signals reported by the CoGeNT and DAMA/LIBRA collaborations. To avoid being overproduced in the early universe, the dark matter must annihilate to leptons through the exchange of charged or neutral fermions which appear in the 27 of E_6, providing an excellent fit to the gamma ray spectrum observed from the Galactic Center by the Fermi Gamma Ray Space Telescope.

  2. Precision welding cuts downtime at Grand Coulee Dam

    SciTech Connect

    Light, S.; White, E.

    1997-03-01

    The three large 700-MW generators at Grand Coulee Dam--originally built and installed by Canadian General Electric in the late 1970s--are being upgraded using precision welding techniques and leading edge installation technology. These generators suffered from numerous water leaks at and around the bar water connections, resulting in a significant number of forced repair outages that were increasing in frequency. The US Bureau of Reclamation, in conjunction with the Bonneville Power Administration, decided to overhaul these machines. The design from Siemens Power Corp. provided state-of-the-art materials and included a rating increase from 700 to 805 MW, which would make these three machines the highest output single-unit hydrogenerators in the world. The upgrade was to be accomplished with only the replacement of the stator components; there would be no changes to the rotating element. The cost for all three machines is approximately $27.5 million. This project is described in this paper.

  3. Scientific Grand Challenges Workshop Series | U.S. DOE Office of Science

    Office of Science (SC)

    (SC) Scientific Grand Challenges Workshop Series Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) Community Resources Featured Content ASCR Discovery ASCR Program Documents ASCR Workshops and Conferences Workshops & Conferences Archive DOE Simulations Summit Scientific Grand Challenges Workshop Series SciDAC Conferences HPC Operations Review

  4. Investigations of element spatial correlation in Mn-promoted...

    Office of Scientific and Technical Information (OSTI)

    Investigations of element spatial correlation in Mn-promoted Co-based Fischer-Tropsch synthesis catalysts This content will become publicly available on June 4, 2017 Title: ...

  5. Spin caloritronics in graphene with Mn

    SciTech Connect

    Torres, Alberto Lima, Matheus P. Fazzio, A.; Silva, Antnio J. R. da

    2014-02-17

    We show that graphene with Mn adatoms trapped at single vacancies features spin-dependent Seebeck effect, thus enabling the use of this material for spin caloritronics. A gate potential can be used to tune its thermoelectric properties in a way it presents either a total spin polarized current, flowing in one given direction, or currents for both spins flowing in opposite directions without net charge transport. Moreover, we show that the thermal magnetoresistance can be tuned between ?100% and +100% by varying a gate potential.

  6. DOE Tour of Zero: The Depot Neighborhood by Habitat for Humanity, Grand

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Traverse Region | Department of Energy Depot Neighborhood by Habitat for Humanity, Grand Traverse Region DOE Tour of Zero: The Depot Neighborhood by Habitat for Humanity, Grand Traverse Region 1 of 22 Habitat for Humanity, Grand Traverse Region, built this 1,352-square-foot home in Traverse City, Michigan, to the performance criteria of the U.S. Department of Energy Zero Energy Ready Home (ZERH) program. 2 of 22 The builder installed a 7.43-kW solar photovoltaic electric system that should

  7. DOE Tour of Zero: The Depot Neighborhood by Habitat for Humanity, Grand

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Traverse Region | Department of Energy Depot Neighborhood by Habitat for Humanity, Grand Traverse Region DOE Tour of Zero: The Depot Neighborhood by Habitat for Humanity, Grand Traverse Region Addthis 1 of 22 Habitat for Humanity, Grand Traverse Region, built this 1,352-square-foot home in Traverse City, Michigan, to the performance criteria of the U.S. Department of Energy Zero Energy Ready Home (ZERH) program. 2 of 22 The builder installed a 7.43-kW solar photovoltaic electric system that

  8. Grand challenge problems in environmental modeling and remediation: Groundwater contaminant transport. Final project report 1998

    SciTech Connect

    1998-04-01

    The over-reaching goal of the Groundwater Grand Challenge component of the Partnership in Computational Science (PICS) was to develop and establish the massively parallel approach for the description of groundwater flow and transport and to address the problem of uncertainties in the data and its interpretation. This necessitated the development of innovative algorithms and the implementation of massively parallel computational tools to provide a suite of simulators for groundwater flow and transport in heterogeneous media. This report summarizes the activities and deliverables of the Groundwater Grand Challenge project funded through the High Performance Computing grand challenge program of the Department of Energy from 1995 through 1997.

  9. Grand Opening for Project LIBERTY: Nation's First Plant to Use Corn Waste

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    as a Feedstock | Department of Energy Grand Opening for Project LIBERTY: Nation's First Plant to Use Corn Waste as a Feedstock Grand Opening for Project LIBERTY: Nation's First Plant to Use Corn Waste as a Feedstock August 28, 2014 - 12:33pm Addthis POET-DSM's Project LIBERTY in Emmetsburg, Iowa, will celebrate its grand opening September 3, 2014, becoming the first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock. Developed through a joint venture between POET LLC

  10. Highlights from the 2014 SunShot Grand Challenge Summit | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Highlights from the 2014 SunShot Grand Challenge Summit Highlights from the 2014 SunShot Grand Challenge Summit Addthis Packed House 1 of 12 Packed House An energetic crowd of hundreds of leaders throughout the solar community gathered for the 2014 SunShot Grand Challenge Summit to work together to reduce the costs of solar energy technologies. Image: SunShot Initiative, Energy Department. Solar Tech Forum 2 of 12 Solar Tech Forum Attendees enter the SunShot Summit Technology forum --

  11. Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit May 22, 2014 - 10:13am Addthis Packed House 1 of 12 Packed House An energetic crowd of hundreds of leaders throughout the solar community gathered for the 2014 SunShot Grand Challenge Summit to work together to reduce the costs of solar energy technologies. Image: SunShot Initiative, Energy Department. Solar Tech Forum 2

  12. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect

    Liu, Xiaojie; Wang, Cai-Zhuang; Lin, Hai-Qing; Ho, Kai-Ming

    2014-08-21

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  13. Mn4+ emission in pyrochlore oxides

    SciTech Connect

    Du, Mao-Hua

    2015-01-01

    For the existing Mn4+ activated red phosphors have relatively low emission energies (or long emission wavelengths) and are therefore inefficient for general lighting. Density functional calculations are performed to study Mn4+ emission in rare-earth hafnate, zirconate, and stannate pyrochlore oxides (RE2Hf2O7, RE2Zr2O7, and RE2Sn2O7). We show how the different sizes of the RE3+ cation in these pyrochlores affect the local structure of the distorted MnO6 octahedron, the Mn–O hybridization, and the Mn4+ emission energy. The Mn4+ emission energies of many pyrochlores are found to be higher than those currently known for Mn4+ doped oxides and should be closer to that of Y2O3:Eu3+ (the current commercial red phosphor for fluorescent lighting). The O–Mn–O bond angle distortion in a MnO6 octahedron is shown to play an important role in weakening Mn–O hybridization and consequently increasing the Mn4+ emission energy. Our result shows that searching for materials that allow significant O–Mn–O bond angle distortion in a MnO6 octahedron is an effective approach to find new Mn4+ activated red phosphors with potential to replace the relatively expensive Y2O3:Eu3+ phosphor.

  14. Electrochemical behavior of β-MnO{sub 2} and MnOOH nanorods in different electrolytes

    SciTech Connect

    Chinnasamy, Revathi; Thangavelu, Rajendrakumar Ramasamy

    2015-06-24

    A manganese dioxide (β-MnO{sub 2}) and MnOOH nanoparticles has been synthesized by hydrothermal method. As prepared samples are analyzed by X-ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM). FESEM showed rod morphology within the diameter of 50–200 and length of few nanometers. These nanorods are immobilized on a Glassy Carbon Electrode (GCE) by drop cast method. The comparative electrochemical behavior of β-MnO{sub 2} and MnOOH rod modified GCE electrodes are analyzed by cyclic Voltammetry (CV) method in different electrolytes of 0.1M KCl, 0.1M Na{sub 2}SO{sub 4}, 0.1M NaOH, 0.1M PBS, 0.1M H{sub 2}SO{sub 4}. From the cyclic Voltammetry analysis found that in all the electrolytes both β-MnO{sub 2} and MnOOH modified GCE electrodes exhibit electrochemical behavior and KCl shows well redox properties as compared with others. There is also an observable difference in reduction potential value of both crystalline nanostructurers and concluded that β-MnO{sub 2} has high catalytic ability as compared with MnOOH rods.

  15. Preservationists Tour Historic Log Cabin at the Grand Junction, Colorado, Office

    Energy.gov [DOE]

    A working committee of local historic preservation specialists held their monthly meeting at the U.S. Department of Energy Office of Legacy Management (LM) Grand Junction, Colorado, Office on...

  16. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 1999 Annual Report.

    SciTech Connect

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2000-01-01

    This project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Folk John Day and Grande Ronde Rivers, for five years.

  17. EIS-0485: Interconnection of the Grande Prairie Wind Farm, Holt County, Nebraska

    Energy.gov [DOE]

    DOE’s Western Area Power Administration prepared an EIS to evaluate the environmental impacts of interconnecting the proposed Grande Prairie Wind Farm, in Holt County, near O’Neill, Nebraska, to Western’s power transmission system.

  18. Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park Dedication and Open House

    Energy.gov [DOE]

    The U.S. Department of Energy (DOE) Office of Legacy Management (LM) held an open house and park dedication at the Grand Junction, Colorado, Office to commemorate its place in the Manhattan Project...

  19. Grand Challenge Kicks Off with 34 Entries to Improve ORP Mission

    Energy.gov [DOE]

    RICHLAND, Wash. – The 2016 EM Office of River Protection (ORP) Grand Challenge submissions are in, with 34 entries ranging in subject from methods to treat waste in Hanford’s western tank farms to software for waste processing.

  20. Top 5 Reasons to Attend the SunShot Grand Challenge Solar Summit

    Office of Energy Efficiency and Renewable Energy (EERE)

    Anticipation for the SunShot Grand Challenge Summit is heating up. Register now for the event, which is taking place May 19 to May 22 in Anaheim, California.

  1. Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit

    Energy.gov [DOE]

    This week in sunny Anaheim, California, more than 800 solar industry leaders gathered for the 2014 SunShot Grand Challenge Summit. The Summit, launched by the Energy Department’s SunShot Initiative...

  2. EV Everywhere Grand Challenge Kick-off Parameters and Analysis | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy off Parameters and Analysis EV Everywhere Grand Challenge Kick-off Parameters and Analysis Presentation at the EV Everywhere Grand Challenge Kick-Off meeting held on June 21, 2012 at the Hyatt Regency, Dearborn, MI. 4-jake.pdf (464.38 KB) More Documents & Publications EV Everywhere Electric Drive Workshop: Preliminary Target-Setting Framework EV Everywhere Battery Workshop: Preliminary Target-Setting Framework EV Everywhere Consumer/Charging Workshop: Target-Setting Framework

  3. U.S. Department of Energy Grand Junction Office Listed on National Register

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Historic Places | Department of Energy U.S. Department of Energy Grand Junction Office Listed on National Register of Historic Places U.S. Department of Energy Grand Junction Office Listed on National Register of Historic Places November 2, 2016 - 12:45pm Addthis NEWS CONTACTS Laurena Davis, Navarro Historian/Public Participation Specialist DOE Legacy Management Support Contractor (970) 248-6141 laurena.davis@lm.doe.gov Terri Benson, The Business Incubator Center Marketing Manager (970)

  4. Grand Traverse Band of Ottawa & Chippewa Indians - Renewable Energy Feasibility Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Tribal Energy Program Review DOE Tribal Energy Program Review Denver, Colorado Denver, Colorado November 5 November 5 - - 8, 2007 8, 2007 Final Report Final Report December 2007 December 2007 Grand Traverse Band Grand Traverse Band * * 4,023 Members 4,023 Members * * 2,370 Acres 2,370 Acres - - Checkerboard Checkerboard * * Six Six - - County Service Area County Service Area * * EDC: 2 Casinos, Resort (424 Rooms), EDC: 2 Casinos, Resort (424 Rooms), Gas Station, etc. Gas Station, etc. * *

  5. Grand Traverse Band of Ottawa and Chippewa Indians - Renewable Energy Feasibility Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Tribal Energy Forum DOE Tribal Energy Forum October 25, 2006 October 25, 2006 Grand Traverse Band Grand Traverse Band * * 3,988 Members 3,988 Members * * 2,370 Acres 2,370 Acres - - Checkerboard Checkerboard * * Six Six - - County Service Area County Service Area * * EDC: 2 Casinos, Resort (424 Rooms), Gas EDC: 2 Casinos, Resort (424 Rooms), Gas Station, etc. Station, etc. * * Gov Gov ' ' t: Administration, Housing, Medicine t: Administration, Housing, Medicine Lodge, Strong Heart Center,

  6. Grand Traverse Band of Ottawa and Chippewa Indians - Renewable Energy Feasibility Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Renewable Energy & Energy Efficiency Feasibility Study DOE Tribal Energy Program Review Denver, Colorado November 14 - 20, 2008 November 2008 Grand Traverse Band * 3,988 Members * 2,370 Acres - Checkerboard * Six-County Service Area * EDC: 2 Casinos, Resort Hotels (600 Rooms), Gas Station, etc. * Gov't: Administration, Housing, Medicine Lodge, Strong Heart Center, Day Care, etc. Grand Traverse Resort and Spa Turtle Creek Casino Hotel (June 08) GTB Energy Vision & Plan Three Focus Areas:

  7. A GRAND DESIGN FOR GALAXY CLUSTERS: CONNECTIONS AND PREDICTIONS

    SciTech Connect

    Cavaliere, A.; Lapi, A.; Fusco-Femiano, R.

    2011-11-20

    We analyze with our entropy-based Supermodel a library of 12 galaxy clusters featuring extended X-ray observations of their intracluster plasma (ICP). The few intrinsic parameters of the model-basically, the central level and the outer slope of the entropy profile-enable us to uniformly derive not only robust snapshots of the ICP thermal state, but also the 'concentration' parameter marking the age of the host dark matter (DM) halo. We test these profiles for consistency with numerical simulations and observations. We find the central and the outer entropy correlate, so that these clusters split into two main classes defined on the basis of low (LE) or high entropy (HE) conditions prevailing throughout the ICP. We also find inverse correlations between the central/outer entropy and the halo concentration. We interpret these in terms of mapping the ICP progress on timescales around 5 Gyr toward higher concentrations, under the drive of the DM halo development. The progress proceeds from HE clusters to LE clusters, toward states of deeper entropy erosion by radiative cooling in the inner regions and of decreasing outer entropy production as the accretion peters out. We propose these radial and time features constitute a cluster Grand Design that we use here to derive a number of predictions. For HE clusters we predict sustained outer temperature profiles. For LEs we expect the outer entropy ramp to bend over; hence the temperature declines before steepening at low z; this feature goes together with an increasing turbulent support, a condition that can be directly probed with the Sunyaev-Zel'dovich effect. We finally discuss the looming out of two intermediate subsets: a wiggled HE-tilde at low z that features central temperature profiles retaining imprints of entropy discharged by active galactic nuclei or deep mergers and high-z LEs where the cosmogony/cosmology had little time to enforce a sharp outer entropy bending.

  8. High performance computing and communications grand challenges program

    SciTech Connect

    Solomon, J.E.; Barr, A.; Chandy, K.M.; Goddard, W.A., III; Kesselman, C.

    1994-10-01

    The so-called protein folding problem has numerous aspects, however it is principally concerned with the {ital de novo} prediction of three-dimensional (3D) structure from the protein primary amino acid sequence, and with the kinetics of the protein folding process. Our current project focuses on the 3D structure prediction problem which has proved to be an elusive goal of molecular biology and biochemistry. The number of local energy minima is exponential in the number of amino acids in the protein. All current methods of 3D structure prediction attempt to alleviate this problem by imposing various constraints that effectively limit the volume of conformational space which must be searched. Our Grand Challenge project consists of two elements: (1) a hierarchical methodology for 3D protein structure prediction; and (2) development of a parallel computing environment, the Protein Folding Workbench, for carrying out a variety of protein structure prediction/modeling computations. During the first three years of this project, we are focusing on the use of two proteins selected from the Brookhaven Protein Data Base (PDB) of known structure to provide validation of our prediction algorithms and their software implementation, both serial and parallel. Both proteins, protein L from {ital peptostreptococcus magnus}, and {ital streptococcal} protein G, are known to bind to IgG, and both have an {alpha} {plus} {beta} sandwich conformation. Although both proteins bind to IgG, they do so at different sites on the immunoglobin and it is of considerable biological interest to understand structurally why this is so. 12 refs., 1 fig.

  9. Water dissociation on Mn(1×1)/Ag(100)

    DOE PAGES [OSTI]

    Arble, Chris; Tong, Xiao; Giordano, Livia; Ferrari, Anna Maria; Newberg, John T.

    2016-08-19

    In this work we utilize experimental and simulation techniques to examine the molecular level interaction of water with a MnO(1×1) thin film deposited onto Ag(100). The formation of MnO(1×1)/Ag(100) was characterized by low energy electron diffraction and scanning tunneling microscopy. Density functional theory (DFT) shows MnO(1×1) is thermodynamically more stable than MnO(2×1) by –0.4 eV per MnO. Upon exposure to 2.5 Torr water vapor at room temperature, X-ray photoemission spectroscopy results show extensive surface hydroxylation attributed to reactivity at MnO(1×1) terrace sites. DFT calculations of a water monomer on MnO(1×1)/Ag(100) show the dissociated form is energetically more favorable than molecularmore » adsorption, with a hydroxylation activation barrier 0.4 eV per H2O. Lastly, these results are discussed and contrasted with previous studies of MgO/Ag(100) which show a stark difference in behavior for water dissociation.« less

  10. Inverse spin Hall effect in Pt/(Ga,Mn)As

    SciTech Connect

    Nakayama, H.; Chen, L.; Chang, H. W.; Ohno, H.; Matsukura, F.

    2015-06-01

    We investigate dc voltages under ferromagnetic resonance in a Pt/(Ga,Mn)As bilayer structure. A part of the observed dc voltage is shown to originate from the inverse spin Hall effect. The sign of the inverse spin Hall voltage is the same as that in Py/Pt bilayer structure, even though the stacking order of ferromagnetic and nonmagnetic layers is opposite to each other. The spin mixing conductance at the Pt/(Ga,Mn)As interface is determined to be of the order of 10{sup 19 }m{sup −2}, which is about ten times greater than that of (Ga,Mn)As/p-GaAs.

  11. Environmental monitoring report on the US Department of Energy's Grand Junction Projects Office facility, Grand Junction, Colorado, for calendar year 1987

    SciTech Connect

    Not Available

    1988-05-01

    This report presents results of environmental monitoring activities conducted in 1987 at the US Department of Energy's (DOE) Grand Junction Projects Office (GJPO) Facility in Colorado. The site is included under the DOE's Defense Decontamination and Decommissioning (Defense D and D) Program.

  12. International Falls, MN Natural Gas Pipeline Imports From Canada...

    Energy Information Administration (EIA) (indexed site)

    Million Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 ...

  13. Magnetic domain tuning and the emergence of bubble domains in the bilayer manganite La<mn>2mn>->2mn>xSr<mn>1mn>+>2mn>xMn>2mn>O>7mn>(x=<mn>0.32mn>)

    SciTech Connect

    Jeong, Juyoung; Yang, Ilkyu; Yang, Jinho; Ayala-Valenzuela, Oscar E.; Wulferding, Dirk; Zhou, J. -S.; Goodenough, John B.; de Lozanne, Alex; Mitchell, J. F.; Leon, Neliza; Movshovich, Roman; Jeong, Yoon Hee; Yeom, Han Woong; Kim, Jeehoon

    2015-08-17

    Here, we report a magnetic force microscopy study of the magnetic domain evolution in the layered manganite La2–2xSr1+2xMn2O7 (with x = 0.32). This strongly correlated electron compound is known to exhibit a wide range of magnetic phases, including a recently uncovered biskyrmion phase. We observe a continuous transition from dendritic to stripelike domains, followed by the formation of magnetic bubbles due to a field- and temperature-dependent competition between in-plane and out-of-plane spin alignments. The magnetic bubble phase appears at comparable field and temperature ranges as the biskyrmion phase, suggesting a close relation between both phases. Based on our real-space images we construct a temperature-field phase diagram for this composition.

  14. Grande Ronde Basin Spring Chinook Salmon Captive Broodstock Program, 1995-2002 Summary Report.

    SciTech Connect

    Hoffnagle, Timothy; Carmichael, Richard; Noll, William

    2003-12-01

    The Grande Ronde Basin once supported large runs of chinook salmon Oncorhynchus tshawytscha and estimated peak escapements in excess of 10,000 occurred as recently as the late 1950's (U.S. Army Corps of Engineers 1975). Natural escapement declines in the Grande Ronde Basin have been severe and parallel those of other Snake River populations. Reduced productivity has primarily been attributed to increased mortality associated with downstream and upstream migration past eight dams and reservoirs in the Snake and Columbia rivers. Reduced spawner numbers, combined with human manipulation of previously important spawning and rearing habitat in the Grande Ronde Basin, have resulted in decreased spawning distribution and population fragmentation of chinook salmon in the Grande Ronde Basin (Figure 1; Table 1). Escapement of spring/summer chinook salmon in the Snake River basin included 1,799 adults in 1995, less than half of the previous record low of 3,913 adults in 1994. Catherine Creek, Grande Ronde River and Lostine River were historically three of the most productive populations in the Grande Ronde Basin (Carmichael and Boyce 1986). However, productivity of these populations has been poor for recent brood years. Escapement (based on total redd counts) in Catherine Creek and Grande Ronde and Lostine rivers dropped to alarmingly low levels in 1994 and 1995. A total of 11, 3 and 16 redds were observed in 1994 in Catherine Creek, upper Grande Ronde River and Lostine River, respectively, and 14, 6 and 11 redds were observed in those same streams in 1995. In contrast, the maximum number of redds observed in the past was 505 in Catherine Creek (1971), 304 in the Grande Ronde River (1968) and 261 in 1956 in the Lostine River (Tranquilli et al 2003). Redd counts for index count areas (a standardized portion of the total stream) have also decreased dramatically for most Grande Ronde Basin streams from 1964-2002, dropping to as low as 37 redds in the 119.5 km in the index survey

  15. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    SciTech Connect

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010][001] ≈ 3.5. A strong power-law divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.

  16. Grande Ronde Endemic Spring Chinook Salmon Supplementation Program : Facility Operation and Maintenance Facilities, Annual Report 2003.

    SciTech Connect

    McLean, Michael L.; Seeger, Ryan; Hewitt, Laurie

    2004-01-01

    Anadromous salmonid stocks have declined in both the Grande Ronde River Basin (Lower Snake River Compensation Plan (LSRCP) Status Review Symposium 1998) and in the entire Snake River Basin (Nehlsen et al. 1991), many to the point of extinction. The Grande Ronde River Basin historically supported large populations of fall and spring chinook (Oncorhynchus tshawytscha), sockeye (O. nerka), and coho (O. kisutch) salmon and steelhead trout (O. mykiss) (Nehlsen et al. 1991). The decline of chinook salmon and steelhead populations and extirpation of coho and sockeye salmon in the Grande Ronde River Basin was, in part, a result of construction and operation of hydroelectric facilities, over fishing, and loss and degradation of critical spawning and rearing habitat in the Columbia and Snake River basins (Nehlsen et al. 1991). Hatcheries were built in Oregon, Washington and Idaho under the Lower Snake River Compensation Plan (LSRCP) to compensate for losses of anadromous salmonids due to the construction and operation of the lower four Snake River dams. Lookingglass Hatchery (LGH) on Lookingglass Creek, a tributary of the Grande Ronde River, was completed under LSRCP in 1982 and has served as the main incubation and rearing site for chinook salmon programs for Grande Ronde and Imnaha rivers in Oregon. Despite these hatchery programs, natural spring chinook populations continued to decline resulting in the National Marine Fisheries Service (NMFS) listing Snake River spring/summer chinook salmon as ''threatened'' under the federal Endangered Species Act (1973) on 22 April 1992. Continuing poor escapement levels and declining population trends indicated that Grande Ronde River basin spring chinook salmon were in imminent danger of extinction. These continuing trends led fisheries co-managers in the basin to initiate the Grande Ronde Endemic Spring Chinook Salmon Supplementation Program (GRESCSSP) in order to prevent extinction and preserve options for use of endemic fish stocks

  17. Grand Challenges in Modeling, Simulation and Analysis: Extraction and Visualization of Power Systems

    SciTech Connect

    Fernandez, Steven J; Omitaomu, Olufemi A

    2010-01-01

    Threats to the national electric power grid often require the coupling of real-time state data with look-ahead or forecasting models to provide timely disruption warnings. However, successful accomplishment of this capability presents a grand challenge in modeling, simulation, and analysis. Analysis of inter-area oscillatory modes may provide a new path to anticipate power system stability and address this grand challenge. An algorithm is presented for the identification and analysis of such modes from high resolution phasor measurement data that might indicate a pathway to meet this grand challenge. The process outlined includes data collection, conditioning, extraction of the primary oscillatory frequency, and determination of participating areas of the system.

  18. UMTRA Project water sampling and analysis plan, Grand Junction, Colorado. Revision 1, Version 6

    SciTech Connect

    1995-09-01

    This water sampling and analysis plan describes the planned, routine ground water sampling activities at the Grand Junction US DOE Uranium Mill Tailings Remedial Action (UMTRA) Project site (GRJ-01) in Grand Junction, Colorado, and at the Cheney Disposal Site (GRJ-03) near Grand Junction. The plan identifies and justifies the sampling locations, analytical parameters, detection limits, and sampling frequencies for the routine monitoring stations at the sites. Regulatory basis is in the US EPA regulations in 40 CFR Part 192 (1994) and EPA ground water quality standards of 1995 (60 FR 2854). This plan summarizes results of past water sampling activities, details water sampling activities planned for the next 2 years, and projects sampling activities for the next 5 years.

  19. US Department of Energy Grand Junction Projects Office Remedial Action Project, final report of the decontamination and decommissioning of Building 36 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. Building 36 was found to be radiologically contaminated and was demolished in 1996. The soil beneath the building was remediated in accordance with identified standards and can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  20. Strong enhancement of s -wave superconductivity near a quantum critical point of Ca<mn>3mn>Ir>4mn>Sn>13mn>

    SciTech Connect

    Biswas, P. K.; Guguchia, Z.; Khasanov, R.; Chinotti, M.; Li, L.; Wang, Kefeng; Petrovic, C.; Morenzoni, E.

    2015-11-11

    We report microscopic studies by muon spin rotation/relaxation as a function of pressure of the Ca<mn>3mn>Ir>4mn>Sn>13mn> and Sr3Ir4Sn13 system displaying superconductivity and a structural phase transition associated with the formation of a charge density wave (CDW). Our findings show a strong enhancement of the superfluid density and a dramatic increase of the pairing strength above a pressure of ≈ 1.6 GPa giving direct evidence of the presence of a quantum critical point separating a superconducting phase coexisting with CDW from a pure superconducting phase. The superconducting order parameter in both phases has the same s-wave symmetry. In spite of the conventional phonon-mediated BCS character of the weakly correlated (Ca1-xSrx)3Ir4Sn13 system the dependence of the effective superfluid density on the critical temperature puts this compound in the “Uemura” plot close to unconventional superconductors. This system exemplifies that conventional BCS superconductors in the presence of competing orders or multi-band structure can also display characteristics of unconventional superconductors.

  1. Race to Zero Student Design Competition: Inspiring the Next Generation...

    Energy Saver

    Image: John De La Rosa, National Renewable Energy Laboratory. GRAND WINNER: Opti-MN Impact ... GRAND WINNER: Opti-MN Impact House - Opti-MN Opti-MN Impact House of the Opti-MN team from ...

  2. Energy Secretary Steven Chu to Attend Grand Opening of Recovery Act-Funded

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    A123 Systems Battery Plant | Department of Energy to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant Energy Secretary Steven Chu to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant September 10, 2010 - 12:00am Addthis Washington D.C. - This Monday, U.S. Energy Secretary Steven Chu will speak at the dedication ceremony for the largest lithium-ion automotive battery production facility in North America. Funded in part by $249 million from the

  3. 2014 SunShot Grand Challenge Summit Day Two Photos | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Grand Challenge Summit Day Two Photos 2014 SunShot Grand Challenge Summit Day Two Photos Addthis Day 2 Subprogram Overviews 9 1 of 39 Day 2 Subprogram Overviews 9 Photo Credit: SunShot Date taken: 2014-05-20 14:41 Day 2 Subprogram Overviews 8 2 of 39 Day 2 Subprogram Overviews 8 Photo Credit: SunShot Date taken: 2014-05-20 14:37 Day 2 Subprogram Overviews 7 3 of 39 Day 2 Subprogram Overviews 7 Photo Credit: SunShot Date taken: 2014-05-20 14:36 Day 2 Subprogram Overviews 6 4 of 39 Day 2

  4. Restoring The Azimuthal Symmetry Of Charged Particle Lateral Density In The Range Of KASCADE-Grande

    SciTech Connect

    Sima, O.; Rebel, H.; Apel, W. D.; Bekk, K.; Bozdog, H.; Daumiller, K.; Doll, P.; Engel, R.; Engler, J.; Finger, M.; Gils, H. J.; Haungs, A.; Heck, D.; Huege, T.; Isar, P. G.; Klages, H. O.; Mathes, H. J.; Mayer, H. J.; Milke, J.; Nehls, S.

    2010-11-24

    KASCADE-Grande, an extension of the former KASCADE experiment, is a multi-component Extensive Air Shower (EAS) experiment located in Karlsruhe Institute of Technology (Campus North), Germany. An important observable for analyzing the EAS is the lateral density of charged particles in the intrinsic shower plane. This observable is deduced from the basic information provided by the Grande scintillators - the energy deposit - first in the observation plane, by using a Lateral Energy Correction Function (LECF), then in the intrinsic shower plane, by applying an adequate mapping procedure. In both steps azimuthal.

  5. Energy Secretary Steven Chu to Attend Grand Opening of Recovery Act-Funded

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    A123 Systems Battery Plant | Department of Energy to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant Energy Secretary Steven Chu to Attend Grand Opening of Recovery Act-Funded A123 Systems Battery Plant September 10, 2010 - 12:00am Addthis Washington D.C. - This Monday, U.S. Energy Secretary Steven Chu will speak at the dedication ceremony for the largest lithium-ion automotive battery production facility in North America. Funded in part by $249 million from the

  6. DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Advanced Biofuels Industry | Department of Energy DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels Industry DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels Industry November 20, 2015 - 12:49pm Addthis DuPont’s cellulosic ethanol biorefinery in Nevada, Iowa, opened on October 30, 2015. | Photo courtesy of DuPont DuPont's cellulosic ethanol biorefinery in Nevada, Iowa, opened on October 30, 2015. | Photo courtesy

  7. SunShot Shoots for the Moon with First Grand Challenge Event | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Shoots for the Moon with First Grand Challenge Event SunShot Shoots for the Moon with First Grand Challenge Event May 23, 2012 - 11:40am Addthis The Energy Department's SunShot Initiative focuses on making solar electricity cost-competitive by the end of the decade. | Photo courtesy of Dennis Schroeder/NREL. The Energy Department's SunShot Initiative focuses on making solar electricity cost-competitive by the end of the decade. | Photo courtesy of Dennis Schroeder/NREL. Ramamoorthy

  8. ,"Rio Grande, TX Natural Gas Pipeline Exports to Mexico (MMcf)"

    Energy Information Administration (EIA) (indexed site)

    Grande, TX Natural Gas Pipeline Exports to Mexico (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Rio Grande, TX Natural Gas Pipeline Exports to Mexico (MMcf)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  9. Grande Ronde Basin Chinook Salmon Captive Brood and Conventional Supplementation Program, 2000 Annual Report.

    SciTech Connect

    Carmichael, Richard W.

    2003-03-01

    Endangered Species Permit Number 1011 (formerly Permit No. 973) authorizes ODFW to take listed spring chinook salmon juveniles from Catherine Creek (CC), Lostine River (LR) and Grande Ronde River (GR) for research and enhancement purposes. Modification 2 of this permit authorizes ODFW to take adults for spawning and the production and release of smolts for the Captive and Conventional broodstock programs. This report satisfies the requirement that an annual report be submitted. Herein we report on activities conducted and provide cursory data analyses for the Grande Ronde spring chinook salmon Captive and Conventional broodstock projects from 1 January-31 December 2000.

  10. Wildlife Mitigation and Restoration for Grand Coulee Dam: Blue Creek Project, Phase 1.

    SciTech Connect

    Merker, Christopher

    1993-04-01

    This report is a recommendation from the Spokane Tribe to the Northwest Power Planning Council (NPPC) for partial mitigation for the extensive wildlife and wildlife habitat losses on the Spokane Indian Reservation caused by the construction of Grand Coulee Dam. NPPC`s interim wildlife goal over the next 7 years for the Columbia hydropower system, is to protect, mitigate and enhance approximately 35% basin wide of the lost habitat units. Grand Coulee Dam had the greatest habitat losses of any Dams of the Wildlife Rule.

  11. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOEpatents

    Brager, Howard R.; Garner, Francis A.

    1987-01-01

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  12. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    DOE PAGES [OSTI]

    Lendinez, S.; Billinge, S. J. L.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amoresingle crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.less

  13. Revealing the Restructured Surface of Li[Mn2]O4

    DOE PAGES [OSTI]

    Amos, Charles D.; Roldan, Manuel A.; Varela, Maria; Goodenough, John B.; Ferreira, Paulo J.

    2016-03-29

    The spinel Revealing the Restructured Surface of Li[Mn2]O4 is a candidate cathode for a Li-ion battery, but its capacity fades over a charge/discharge cycle of Li1–x[Mn2]O4 (0 < x < 1) that is associated with a loss of Mn to the organic-liquid electrolyte. It is known that the disproportionation reaction 2Mn3+ = Mn2+ + Mn4+ occurs at the surface of a Mn spinel, and it is important to understand the atomic structure and composition of the surface of Revealing the Restructured Surface of Li[Mn2]O4 in order to understand how Mn loss occurs. We report a study of the surface reconstructionmore » of Revealing the Restructured Surface of Li[Mn2]O4 by aberration-corrected scanning transmission electron microscopy. The atomic structure coupled with Mn-valence and the distribution of the atomic ratio of oxygen obtained by electron energy loss spectroscopy reveals a thin, stable surface layer of Mn3O4, a subsurface region of Li1+x[Mn2]O4 with retention of bulk Li[Mn2]O4. We conclude that this observation is compatible with the disproportionation reaction coupled with oxygen deficiency and a displacement of surface Li+ from the Mn3O4 surface phase. These results provide a critical step toward understanding how Mn is lost from Li[Mn2]O4, once inside a battery.« less

  14. Structure and magnetic properties of LnMnSbO ( Ln=La and Ce)

    DOE PAGES [OSTI]

    Zhang, Qiang; Kumar, C. M. N.; Tian, Wei; Dennis, Kevin W.; Goldman, Alan I.; Vaknin, David

    2016-03-11

    Here, a neutron powder diffraction (NPD) study of LnMnSbO (Ln = La or Ce) reveals differences between the magnetic ground state of the two compounds due to the strong Ce-Mn coupling compared to La-Mn. The two compounds adopt the P4/nmm space group down to 2 K, and whereas magnetization measurements do not show obvious anomaly at high temperatures, NPD reveals a C-type antiferromagnetic (AFM) order below TN = 255K for LaMnSbO and 240 K for CeMnSbO. While the magnetic structure of LaMnSbO is preserved to base temperature, a sharp transition at TSR = 4.5K is observed in CeMnSbO due tomore » a spin-reorientation (SR) transition of the Mn2+ magnetic moments from pointing along the c axis to the ab plane. The SR transition in CeMnSbO is accompanied by a simultaneous long-range AFM ordering of the Ce moments, which indicates that the Mn SR transition is driven by the Ce-Mn coupling. The ordered moments are found to be somewhat smaller than those expected for Mn2+ (S = 5/2) in insulators, but large enough to suggest that these compounds belong to the class of local-moment antiferromagnets. The lower TN found in these two compounds compared to the As-based counterparts (TN = 317 for LaMnAsO, TN = 347K for CeMnAsO) indicates that the Mn-Pn (Pn=As or Sb) hybridization that mediates the superexchange Mn-Pn-Mn coupling is weaker for the Sb-based compounds.« less

  15. Synthesis, characterization and electrochemical performance of Al-substituted Li₂MnO₃

    DOE PAGES [OSTI]

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectronmore » spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. As a result, aluminum substitutions increased the formation of spinel phase which is responsible for cycling.« less

  16. Biofuels and Sustainable Development: An Executive Session on the Grand Challenges of the Sustainability Transition

    SciTech Connect

    Lee, Henry; Clark, William C.; Devereaux, Charan

    2008-05-20

    This report is the result of the second in a series of intense workshops and study sessions on Grand Challenges of the Sustainability Transition, organized by the Sustainability Science Program at Harvard University, hosted by Venice International University, and supported by the Italian Ministry of Environment, Land and Sea.

  17. Recovery sequences for a station blackout accident at the Grand Gulf Nuclear Station

    SciTech Connect

    Carbajo, J.J. [Martin Marietta Energy Systems, Oak Ridge, TN (United States)

    1995-12-31

    Recovery sequences for a low-pressure, short term, station blackout severe accident at the Grand Gulf power plant have been investigated using the computer code MELCOR, version 1.8.3 PN. This paper investigates the effect of reflood timing and mass flow rate on accident recovery.

  18. Grand Coulee Dam Wildlife Mitigation Program : Pygmy Rabbit Programmatic Management Plan, Douglas County, Washington.

    SciTech Connect

    Ashley, Paul

    1992-06-01

    The Northwest Power Planning Council and the Bonneville Power Administration approved the pygmy rabbit project as partial mitigation for impacts caused by the construction of Grand Coulee Dam. The focus of this project is the protection and enhancement of shrub-steppe/pygmy rabbit habitat in northeastern Washington.

  19. EV Everywhere Grand Challenge: DOE's 10-Year Vision for Plug-in Electric Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    EV Everywhere is a Clean Energy Grand Challenge to have the U.S. become the first nation in the world to produce plug-in electric vehicles that are as affordable for the average American family as today's gasoline-powered vehicles within the next 10 years.

  20. Site observational work plan for the UMTRA Project Site at Grand Junction, Colorado

    SciTech Connect

    1996-03-01

    The U.S. Department of Energy (DOE) has prepared this initial site observational work plan (SOWP) for the Uranium Mill Tailings Remedial Action (UMTRA) Project site in Grand Junction, Colorado. This SOWP is one of the first UMTRA Ground Water Project documents developed to select a compliance strategy that meets the UMTRA ground water standards (40 CFR Part 192, as amended by 60 FR 2854) for the Grand Junction site. This SOWP applies information about the Grand Junction site to the compliance strategy selection framework developed in the UMTRA Ground Water Project draft programmatic environmental impact statement (PEIS). This risk-based, decision-making framework identifies the decision logic for selecting compliance strategies that could be used to meet the ground water standards. The DOE goal is to use the observational method to implement a cost-effective site strategy that complies with the ground water standards and protects human health and the environment. Based on an evaluation of the site characterization and risk assessment data available for the preparation of this SOWP, DOE proposes that the most likely compliance strategy for the Grand Junction site is no remediation based on the application of supplemental standards. This proposed strategy is based on a conceptual site model that indicates site-related contamination is confined to a limited-use aquifer as defined in the ground water standards.

  1. EA-1950: Grand Coulee-Creston Transmission Line Rebuild; Grant and Lincoln Counties, Washington

    Energy.gov [DOE]

    Bonneville Power Administration prepared this EA to evaluate potential environmental impacts of rebuilding approximately 28 miles of the Grand Coulee-Creston No. 1 115-kilovolt (kV) transmission line between Coulee Dam in Grant County and Creston in Lincoln County, Washington.

  2. Project Reports for Grand Traverse Band of Ottawa and Chippewa Indians- 2005 Project

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Grand Traverse Band of Ottawa and Chippewa Indians (GTB) will conduct a feasibility study to determine the cost effectiveness and other economic, environmental, cultural, and social benefits of maximizing the diversity of energy sources used at GTB facilities. This includes an assessment of energy conservation measures as well as renewable energy sources such as wind, solar, and biomass.

  3. SunShot Grand Challenge Summit: Bright Outlook to Achieve SunShot Goal

    Office of Energy Efficiency and Renewable Energy (EERE)

    Last week, hundreds of solar energy leaders gathered in southern California to participate in SunShot’s biennial Grand Challenge Summit. Read a recap of the four-day event, which focused on making solar energy fully cost-competitive with traditional forms of energy by 2020.

  4. Grande Ronde Basin Chinook Salmon Captive Brood and Conventional Supplementation Programs, 1999 Annual Report.

    SciTech Connect

    Carmichael, Richard W.

    2003-03-01

    Permit Number 1011 (formerly Permit No. 973) authorized ODFW to take listed spring chinook salmon juveniles from Catherine Creek and the Lostine and Grande Ronde rivers for scientific research and enhancement purposes. Special condition 2a specified the need for an annual report prior to initiation of next year's work.

  5. Grand Opening of Abengoa’s Biorefinery: Nation’s Third Commercial-Scale Facility

    Energy.gov [DOE]

    The nation’s third commercial-scale cellulosic ethanol biorefinery celebrates its grand opening on October 17, 2014, in Hugoton, Kansas. The Abengoa Bioenergy Biomass of Kansas (ABBK) facility is the first of its kind to use a proprietary enzymatic hydrolysis process which turns cellulosic biomass into fermentable sugars that are then converted into transportation fuels.

  6. Comparative flow measurements: Grand Coulee pumping-generating plant unit P/G9. Final report

    SciTech Connect

    Heigel, L.; Lewey, A.B.; Greenwood, J.B.

    1986-10-01

    In extensive testing, two acoustic flow measurement systems compared well in accuracy and repeatability with conventional methods at a power plant at Grand Coulee Dam. Acoustic flow measurement systems offer utilities an inexpensive, real-time method for optimizing hydro plant efficiency.

  7. Stress induced anisotropy in CoFeMn soft magnetic nanocomposites...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Stress induced anisotropy in CoFeMn soft magnetic nanocomposites Citation Details In-Document Search Title: Stress induced anisotropy in CoFeMn soft magnetic ...

  8. Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance

    SciTech Connect

    Dai, Qilin; Wang, Wenyong E-mail: jtang2@uwyo.edu; Tang, Jinke E-mail: jtang2@uwyo.edu; Sabio, Erwin M.

    2014-05-05

    In this work, we demonstrate (1) a facile method to prepare Mn doped CdSe quantum dots (QDs) on Zn{sub 2}SnO{sub 4} photoanodes by pulsed laser deposition and (2) improved device performance of quantum dot sensitized solar cells of the Mn doped QDs (CdSe:Mn) compared to the undoped QDs (CdSe). The band diagram of photoanode Zn{sub 2}SnO{sub 4} and sensitizer CdSe:Mn QD is proposed based on the incident-photon-to-electron conversion efficiency (IPCE) data. Mn-modified band structure leads to absorption at longer wavelengths than the undoped CdSe QDs, which is due to the exchange splitting of the CdSe:Mn conduction band by the Mn dopant. Three-fold increase in the IPCE efficiency has also been observed for the Mn doped samples.

  9. Pulsed laser deposition of Mn doped CdSe quantum dots for improved...

    Office of Scientific and Technical Information (OSTI)

    Pulsed laser deposition of Mn doped CdSe quantum dots for improved solar cell performance Citation Details In-Document Search Title: Pulsed laser deposition of Mn doped CdSe ...

  10. Coexistence of charge-density wave and ferromagnetism in Ni2MnGa...

    Office of Scientific and Technical Information (OSTI)

    Coexistence of charge-density wave and ferromagnetism in Ni2MnGa Citation Details In-Document Search Title: Coexistence of charge-density wave and ferromagnetism in Ni2MnGa ...

  11. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

    SciTech Connect

    Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

    2014-05-07

    Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

  12. Epitaxial Growth of Intermetallic MnPt Films on Oxides and Large Exchange Bias

    DOE PAGES [OSTI]

    Liu, Zhiqi; Biegalski, Michael D.; Hsu, Shang-Lin; Shang, Shunli; Marker, Cassie; Liu, Jian; Li, Li; Fan, Lisha S.; Meyer, Tricia L.; Wong, Anthony T.; et al

    2015-11-05

    High-quality epitaxial growth of intermetallic MnPt films on oxides is achieved, with potential for multiferroic heterostructure applications. Antisite-stabilized spin-flipping induces ferromagnetism in MnPt films, although it is robustly antiferromagnetic in bulk. Moreover, highly ordered antiferromagnetic MnPt films exhibit superiorly large exchange coupling with a ferromagnetic layer.

  13. Epitaxial growth of intermetallic MnPt films on oxides and large exchange bias

    SciTech Connect

    Liu, Zhiqi; Biegalski, Michael D.; Hsu, Shang-Lin; Shang, Shunli; Marker, Cassie; Liu, Jian; Li, Li; Fan, Lisha S.; Meyer, Tricia L.; Wong, Anthony T.; Nichols, John A.; Chen, Deyang; You, Long; Chen, Zuhuang; Wang, Kai; Wang, Kevin; Ward, Thomas Z.; Gai, Zheng; Lee, Ho Nyung; Sefat, Athena S.; Lauter, Valeria; Liu, Zi-kui; Christen, Hans M.

    2015-11-05

    High-quality epitaxial growth of intermetallic MnPt films on oxides is achieved, with potential for multiferroic heterostructure applications. Antisite-stabilized spin-flipping induces ferromagnetism in MnPt films, although it is robustly antiferromagnetic in bulk. Thus, highly ordered antiferromagnetic MnPt films exhibit superiorly large exchange coupling with a ferromagnetic layer.

  14. Neutron scattering study of spin ordering and stripe pinning in superconducting La<mn>1.93mn>Sr>0.07mn>CuO>4mn>

    SciTech Connect

    Jacobsen, H.; Zaliznyak, I. A.; Savici, A. T.; Winn, B. L.; Chang, S.; Hücker, M.; Gu, G. D.; Tranquada, J. M.

    2015-11-20

    The relationships among charge order, spin fluctuations, and superconductivity in underdoped cuprates remain controversial. We use neutron scattering techniques to study these phenomena in La<mn>1.93mn>Sr>0.07mn>CuO>4mn> a superconductor with a transition temperature of Tc = 20 K. At T<< Tc, we find incommensurate spin fluctuations with a quasielastic energy spectrum and no sign of a gap within the energy range from 0.2 to 15 meV. A weak elastic magnetic component grows below ~ 10 K, consistent with results from local probes. Regarding the atomic lattice, we have discovered unexpectedly strong fluctuations of the CuO6 octahedra about Cu-O bonds, which are associated with inequivalent O sites within the CuO2 planes. Moreover, we observed a weak elastic (3 30) superlattice peak that implies a reduced lattice symmetry. The presence of inequivalent O sites rationalizes various pieces of evidence for charge stripe order in underdoped La2-xSrxCuO4. The coexistence of superconductivity with quasi-static spin-stripe order suggests the presence of intertwined orders; however, the rotation of the stripe orientation away from the Cu-O bonds might be connected with evidence for a finite gap at the nodal points of the superconducting gap function.

  15. Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}

    SciTech Connect

    Lpez, C.A.; Saleta, M.E.; Pedregosa, J.C.; Snchez, R.D.; Alonso, J.A.; and others

    2014-02-15

    We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By in-situ NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?MnO?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: Two novel Mn-containing double perovskites were obtained by solid-state reactions. Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

  16. Clarification of enhanced ferromagnetism in Be-codoped InMnP fabricated using Mn/InP:Be bilayers grown by molecular beam epitaxy

    SciTech Connect

    Shon, Yoon; Lee, Sejoon; Taek Yoon, Im; Jeon, H. C.; Lee, D. J.; Kang, T. W.; Song, J. D.; Yoon, Chong S.; Kim, D. Y.; Park, C. S.

    2011-11-07

    The p-type InMnP:Be epilayers were prepared by the sequential growth of Mn/InP:Be bilayers using molecular-beam-epitaxy and the subsequent in-situ annealing at 200-300 deg. C. In triple-axis x-ray diffraction patterns, the samples revealed a shoulder peak indicative of intrinsic InMnP. The ferromagnetic transition in InMnP:Be was observed to occur at the elevated temperature of {approx}140 K, and the ferromagnetic spin-domains clearly appeared in magnetic force microscopy images. The improved ferromagnetic properties are attributed to the increased p-d hybridation due to high p-type conductivity of InMnP:Be (p {approx} 10{sup 20 }cm{sup -3}). The results suggest that enhanced ferromagnetism can be effectively obtained from Be-codoped InMnP.

  17. Magnetic properties of α−MnO{sub 2} and Co-doped α−MnO{sub 2} nanowires

    SciTech Connect

    Stella, C. Soundararajan, N. Ramachandran, K.

    2014-04-24

    α−MnO{sub 2} and Co-doped α−MnO{sub 2} nanowires (NWs) were synthesized by hydrothermal method. The structural characterization by XRD revealed the tetragonal structure of α−MnO{sub 2}. The formation of one dimensional (1D) NWs of pure and Co-doped α−MnO{sub 2} was confirmed from SEM. From UV-Vis absorption spectra, it is found that both pure and Co-doped α−MnO{sub 2} NWs showed blue shift compared to bulk, which revealed the quantum confinement in the synthesized samples. The magnetic properties were analyzed by VSM, which suggest that pure and doped α−MnO{sub 2} exhibit ferromagnetic behavior at room temperature (RT)

  18. US Department of Energy Grand Junction Projects Office Remedial Action Project. Final report of the decontamination and decommissioning of Building 52 at the Grand Junction Projects Office Facility

    SciTech Connect

    Krabacher, J.E.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also was the remedial action contractor. Building 52 was found to be radiologically contaminated and was demolished in 1994. The soil area within the footprint of the building has been remediated in accordance with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  19. Role of t{sub 2g} electrons in Mn-Tb coupling of multiferroic TbMnO{sub 3}

    SciTech Connect

    Guo, Y. Y.; Wang, Y. L.; Liu, J.-M.; Wei, T.

    2014-08-14

    We investigate the effect of Cr-doping in polycrystalline TbMn{sub 1?x}Cr{sub x}O{sub 3} (x???6%) ceramics on the magnetism, ferroelectricity, and dielectricity. The Cr substitution gradually suppresses the ferroelectricity induced by the Mn spiral spin ordering, and results in a stronger modulation of polarization by magnetic field with increasing x. However, the transition temperature T{sub Tb} corresponding to onset of Tb magnetic ordering has barely shifted with Cr doping. In other words, although the Cr-doping obviously disrupts the Mn spiral spin ordering, the exchange field J{sub Mn-Tb} acting on the Tb moments from the Mn-spin structure is hardly impacted. Our work demonstrates that the e{sub g} electron of Mn{sup 3+} plays an important role in forming the Mn spiral spin order, but the f-d exchange interaction between the Mn 3d spins and the Tb 4f moments in multiferroic TbMnO{sub 3} almost involves only the t{sub 2g} electrons.

  20. Effect of Mn substitution on the transport properties of co-sputtered Fe{sub 3−x}Mn{sub x}Si epilayers

    SciTech Connect

    Tang, M.; Jin, C.; Bai, H. L.

    2014-11-07

    Motivated by the theoretical calculations that Fe{sub 3−x}Mn{sub x}Si can simultaneously exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical properties of Fe{sub 3−x}Mn{sub x}Si, we have investigated the effect of Mn substitution on the transport properties of epitaxial Fe{sub 3−x}Mn{sub x}Si (0≤x≤1) films systematically. The Fe{sub 3−x}Mn{sub x}Si films were epitaxially grown on MgO(001) plane with 45° rotation. The magnetization for various x shows enhanced irreversibility, implying the antiferromagnetic ordering induced by the substitution of Mn. A metal-semiconductor crossover was observed due to the enhanced disorders of interactions and the local lowering of symmetry induced by the substitution of Mn. The single-domain state in the Fe{sub 3−x}Mn{sub x}Si films leads to twofold symmetric curves of the anisotropic magnetoresistance and planar Hall resistivity.

  1. Lower Rio Grande Valley transboundary air pollution project (TAPP). Project report 1996--1997

    SciTech Connect

    Mukerjee, S.; Shadwick, D.S.; Dean, K.E.; Carmichael, L.Y.; Bowser, J.J.

    1999-04-01

    The Lower Rio Grande Valley Transboundary Air Pollution Project (TAPP) was a US-Mexico Border XXI project to find out if air pollutants were moving across the border from Mexico into the Lower Rio Grande Valley of Texas and to see what levels of air pollutants were present. Ambient measurements and meteorology were collected data for a year (March 1996-March 1997) at three fixed sites in and near Brownsville, Texas very close to the US-Mexico border on a continuous and 24-h internal basis. Overall levels of air pollution were similar to or lower than other areas in Texas and elsewhere. Based on wind sector analyses, transport of air pollution across the border did not appear to adversely impact air quality on the US side of the Valley. Southeasterly winds from the Gulf of Mexico were largely responsible for the clean air conditions.

  2. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems

    SciTech Connect

    Factorovich, Matas H.; Scherlis, Damin A.

    2014-02-14

    In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

  3. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect

    KAPLAN, DANIEL

    2005-09-13

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface

  4. Haze in the Grand Canyon: An evaluation of the Winter Haze Intensive Tracer Experiment

    SciTech Connect

    Not Available

    1990-10-01

    The Grand Canyon is one of the most spectacular natural sights on earth. Approximately 4 million visitors travel to Grand Canyon National Park (GCNP) each year to enjoy its majestic geological formations and intensely colored views. However, visibility in GCNP can be impaired by small increases in concentrations of fine suspended particles that scatter and absorb light; the resulting visibility degradation is perceived as haze. Sulfate particles are a major factor in visibility impairment at Grand Canyon in summer and winter. Many wintertime hazes at GCNP are believed to result from the accumulation of emissions from local sources during conditions of air stagnation, which occur more frequently in winter than in summer. In January and February 1987, the National Park Service (NPS) carried out a large-scale experiment known as the Winter Haze Intensive Tracer Experiment (WHITEX) to investigate the causes of wintertime haze in the region of GCNP and Canyonlands National Park. The overall objective of WHITEX was to assess the feasibility of attributing visibility impairment in specific geographic regions to emissions from a single point source. The experiment called for the injection of a tracer, deuterated methane (CD{sub 4}), into one of the stacks of the Navajo Generating Station (NGS), a major coal-fired power plant located 25 km from the GCNP boundary and 110 km northeast of Grand Canyon Village. A network of field stations was established in the vicinity -- mostly to the northeast of GCNP and NGS -- to measure CD{sub 4} concentrations, atmospheric aerosol and optical properties, and other chemical and physical attributes. 19 refs., 3 figs.

  5. Strobe Light Deterrent Efficacy Test and Fish Behavior Determination at Grand Coulee Dam Third Powerplant Forebay

    SciTech Connect

    Simmons, Mary Ann; Johnson, Robert L.; McKinstry, Craig A.; Simmons, Carver S.; Cook, Chris B.; Brown, Richard S.; Tano, Daniel K.; Thorsten, Susan L.; Faber, Derrek M.; Lecaire, Richard; Francis, Stephen

    2004-01-01

    This report documents the third year of a four-year study to assess the efficacy of a prototype strobe light system to elicit a negative phototactic response in kokanee salmon (Oncorhynchus nerka) and rainbow trout (O. mykiss) in the forebay to the third powerplant at Grand Coulee Dam. This work was conducted for the Bonneville Power Administration, U.S. Department of Energy, by Pacific Northwest National Laboratory (PNNL) in conjunction with the Confederated Tribes of the Colville Reservation (Colville Confederated Tribes).

  6. University of Texas Rio Grande Valley Regional High School Science Bowl |

    Office of Science (SC)

    U.S. DOE Office of Science (SC) University of Texas Rio Grande Valley Regional High School Science Bowl National Science Bowl® (NSB) NSB Home About Regional Competitions Rules, Forms, and Resources High School Regionals Middle School Regionals National Finals Volunteers Key Dates Frequently Asked Questions News Media Contact Us WDTS Home Contact Information National Science Bowl® U.S. Department of Energy SC-27/ Forrestal Building 1000 Independence Ave., SW Washington, DC 20585 E: Email Us

  7. University of Texas Rio Grande Valley Regional Middle School Science Bowl |

    Office of Science (SC)

    U.S. DOE Office of Science (SC) University of Texas Rio Grande Valley Regional Middle School Science Bowl National Science Bowl® (NSB) NSB Home About Regional Competitions Rules, Forms, and Resources High School Regionals Middle School Regionals National Finals Volunteers Key Dates Frequently Asked Questions News Media Contact Us WDTS Home Contact Information National Science Bowl® U.S. Department of Energy SC-27/ Forrestal Building 1000 Independence Ave., SW Washington, DC 20585 E: Email

  8. Grand Valley State University Checks Out Energy Savings at New Mary Idema Pew Library

    SciTech Connect

    none,

    2013-03-01

    Grand Valley State University (GVSU) partnered with the Department of Energy (DOE) to develop and implement solutions to build new, low-energy buildings that are at least 50% below Standard 90.1-2007 of the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE), the American National Standards Institute (ANSI), and the Illuminating Engineering Society of North America (IESNA) as part of DOE’s Commercial Building Partnerships (CBP) Program.

  9. Strobe Light Deterrent Efficacy Test and Fish Behavior Determination at Grand Coulee Dam Third Powerplant Forebay

    SciTech Connect

    Johnson, Robert L.; Simmons, Mary Ann; McKinstry, Craig A.; Simmons, Carver S.; Cook, Chris B.; Brown, Richard S.; Tano, Daniel K.; Thorsten, Susan L.; Faber, Derrek M.; Lecaire, Richard; Francis, Stephen

    2005-02-25

    This report documents the fourth year of a four-year study to assess the efficacy of a prototype strobe light system to elicit a negative phototactic response in kokanee salmon (Oncorhynchus nerka) and rainbow trout (O. mykiss) in the forebay to the third powerplant at Grand Coulee Dam. This work was conducted for the Bonneville Power Administration, U.S. Department of Energy, by Pacific Northwest National Laboratory (PNNL) in conjunction with the Confederated Tribes of the Colville Reservation (Colville Confederated Tribes).

  10. Habitat Evaluation Procedures (HEP) Report : Grand Coulee Dam Mitigation, 1996-1999 Technical Report.

    SciTech Connect

    Kieffer, B.; Singer, Kelly; Abrahamson, Twa-le

    1999-07-01

    The purpose of this Habitat Evaluation Procedures (HEP) study was to determine baseline habitat units and to estimate future habitat units for Bonneville Power Administration (BPA) mitigation projects on the Spokane Indian Reservation. The mitigation between BPA and the Spokane Tribe of Indians (STOI) is for wildlife habitat losses on account of the construction of Grand Coulee Dam. Analysis of the HEP survey data will assist in mitigation crediting and appropriate management of the mitigation lands.

  11. Relation between the magnetization and the electrical properties of alloy GaSb-MnSb films

    SciTech Connect

    Koplak, O. V.; Polyakov, A. A.; Davydov, A. B.; Morgunov, R. B.; Talantsev, A. D.; Kochura, A. V.; Fedorchenko, I. V.; Novodvorskii, O. A.; Parshina, L. S.; Khramova, O. D.; Shorokhova, A. V.; Aronzon, B. A.

    2015-06-15

    The influence of the charge carrier concentration on the magnetic properties of GaSb-MnSb alloys is studied. The ferromagnetism of GaSb-MnSb films is caused by the presence of MnSb granules and manifests itself in both magnetometric measurements and the presence of an anisotropic magnetoresistance and the anomalous Hall effect. Electric conduction is executed by charge carriers (holes) in a GaSb matrix. The magnetization of clusters depends on stoichiometry and the concentration of Mn{sup 2+} and Mn{sup 3+} ions, which is specified by the film growth conditions. At high film growth temperatures, ferromagnetic clusters containing Mn{sup 2+} ions mainly form. At low growth temperatures, an antiferromagnetic phase containing Mn{sup 3+} ions forms.

  12. Key wintertime meteorological features of the Grand Canyon and the Colorado Plateaus Basin

    SciTech Connect

    Whiteman, C.D.; Allwine, K.J.

    1992-06-01

    In the winter of 1989--1990 a major meteorological and air pollution experiment was conducted in the Colorado Plateaus Basin (Richards et al., 1991). The focus of the experiment, conducted by Arizona's Soft River Project, was to investigate the influence of three 750-MW coal-fired power plant units at the Navajo Generating Station near Page, Arizona, on visibility at Grand Canyon National Park. As part of the meteorological experiment, surface and upper air data were collected from multiple sites within the basin. This data set is the most comprehensive meteorological data set ever collected within the region, and the purpose of this paper is to briefly summarize the key wintertime meteorological features of the Colorado Plateaus Basin and the Grand Canyon, through which the basin drains, using analyses of the Winter Visibility Study data. Our analyses focused primarily on thermally driven circulations within the basin and the Grand Canyon, but we also investigated the surface energy budget that drives these circulations and the interactions between the thermal circulations and the overlying synoptic-scale flows.

  13. Key wintertime meteorological features of the Grand Canyon and the Colorado Plateaus Basin

    SciTech Connect

    Whiteman, C.D.; Allwine, K.J.

    1992-06-01

    In the winter of 1989--1990 a major meteorological and air pollution experiment was conducted in the Colorado Plateaus Basin (Richards et al., 1991). The focus of the experiment, conducted by Arizona`s Soft River Project, was to investigate the influence of three 750-MW coal-fired power plant units at the Navajo Generating Station near Page, Arizona, on visibility at Grand Canyon National Park. As part of the meteorological experiment, surface and upper air data were collected from multiple sites within the basin. This data set is the most comprehensive meteorological data set ever collected within the region, and the purpose of this paper is to briefly summarize the key wintertime meteorological features of the Colorado Plateaus Basin and the Grand Canyon, through which the basin drains, using analyses of the Winter Visibility Study data. Our analyses focused primarily on thermally driven circulations within the basin and the Grand Canyon, but we also investigated the surface energy budget that drives these circulations and the interactions between the thermal circulations and the overlying synoptic-scale flows.

  14. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 2000 Annual Report.

    SciTech Connect

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2001-01-01

    Fine sediment in spawning substrate has a major effect on salmon survival from egg to smolt. Basin-wide restoration plans have established targets for fine sediment levels in spawning habitat. The project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Fork John Day (NFJDR) and Grande Ronde Rivers, for five years. The project is also investigating the potential relationship between surface fine levels and overwinter sedimentation. It will provide data to assess trends in substrate conditions in monitored reaches and whether trends are consistent with efforts to improve salmon habitat conditions. The data on the magnitude of overwinter sedimentation will also be used to estimate salmon survival from egg to emergence. In Sept. 1998, 1999, and Aug. 2000, sites for monitoring overwinter sedimentation were established in salmon spawning habitat in the upper Grande Ronde River, Catherine Creek (a Grande Ronde tributary), the North Fork John Day River (NFJDR), and Granite Creek (a NFJDR tributary). Surface fine sediment levels were measured in these reaches via the grid method and visually estimated to test the relative accuracy of these two methods. In 1999 and 2000, surface fine sediment was also estimated via pebble counts at selected reaches to allow comparison of results among the methods. Overwintering substrate samples were collected in April 1999 and April-May 2000 to estimate the amount of overwinter sedimentation in clean gravels in spawning habitat. Monitoring methods and locations are described.

  15. National Uranium Resource Evaluation. Bibliographic index of Grand Junction office uranium reports

    SciTech Connect

    Johnson, J.B.

    1981-05-01

    In October 1978, Mesa College entered into subcontract with Bendix Field Engineering Corporation (BFEC) to prepare a bibliographic index of the uranium raw materials reports issued by the Grand Junction Office of the US Department of Energy (DOE). Bendix, prime contractor to the Grand Junction Office, operates the Technical Library at the DOE facility. Since the early 1950s, approximately 2700 reports have been issued by the Grand Junction Office. These reports were the results of uranium investigations conducted by federal agencies and their subcontractors. The majority of the reports cover geology, mineralogy, and metallurgy of uranium and/or thorium. No single, complete list of these reports existed. The purpose of this subcontract was to compile a comprehensive index to these reports. The Mesa College geology faculty worked with the BFEC and DOE staffs to develop the format for the index. Undergraduate geology students from Mesa compiled a master record sheet for each report. All reports issued up to January 1, 1979 were included in the bibliography. The bibliography is in preliminary, unedited form. It is being open-filed at this time, on microfiche, to make the information available to the public on a timely basis. The bibliography is divided into a master record list arranged in alpha-numeric order by report identification number, with separate indices arranged by title, author, state and county, 1/sup 0/ x 2/sup 0/ NTMS quadrangle, key words, and exploration area.

  16. Finite element analysis of the I-40 bridge over the Rio Grande

    SciTech Connect

    Farrar, C.R.; Duffey, T.A.; Goldman, P.A.; Jauregui, D.V.; Vigil, J.S.

    1996-01-01

    In the 1960s and 1970s numerous bridges were built in the US with a design similar to those on Interstate 40 (I-40) over the Rio Grande in Albuquerque, New Mexico. The Federal Highway Administration (FHWA) and the National Science Foundation (NSF) have provided funds to New Mexico State University (NMSU) through the New Mexico State Highway and Transportation Department (NMSH and TD) and The Alliance For Transportation Research (ATR) for evaluation and testing of the existing fracture-critical bridges over the Rio Grande. Because the I-40 Bridges over the Rio Grande were to be razed during the summer of 1993, the investigators were able to introduce damage into the structure in order to test various damage identification methods and to observe the changes in load paths through the structure caused by the cracking. To support this research effort, NMSU contracted Los Alamos National Laboratory (LANL) to perform experimental modal analyses, and to develop experimentally verified numerical models of the bridge. A previous report (LA-12767-MS) summarizes the results of the experimental modal analyses. This report summarizes the numerical analyses of the bridges and compares the results of these analyses to the experimental results.

  17. Grand Challenge Problems in Environmental Modeling and Remediation: Groundwater Contaminant Transport (Partnerships in Computational Science)

    SciTech Connect

    Sharpley, Robert C.

    1997-12-01

    The over-reaching goal of the Groundwater Grand Challenge component of the Partnership in Computational Science (PICS) was to develop and establish the massively parallel approach for the description of groundwater flow and transport and to address the problem of uncertainties in the data and its interpretation. This necessitated the development of innovative algorithms and the implementation of massively parallel computational tools to provide a suite of simulators for groundwater flow and transport in heterogeneous media. This report summarizes the activities and deliverables of the University of South Carolina component of the Groundwater Grand Challenge project funded through the High Performance Computing grand challenge program of the Department of Energy from 1995 through 1997. Seven institutions were primarily involved in this project: Brookhaven National Laboratory, Oak Ridge National Laboratory, Princeton University, SUNY at Stony Brook, Texas A&M University, The University of South Carolina, and the University of Texas at Austin, with contributing efforts from the Westinghouse Savannah River Technology Center. Each institution had primary responsibility for specific research components, but strong collaboration among all institutions was essential for the success of the project and in producing the final deliverables. PICS deliverables include source code for the suite of research simulators and auxiliary HPC tools, associated documentation, and test problems. These materials will be available as indicated from each institution's web page or from the Center for Computational Sciences Oak Ridge National Laboratory in January 1998.

  18. Work plan for ground water elevation data recorder/monitor well injection at Grand Junction, Colorado

    SciTech Connect

    Not Available

    1994-07-18

    The purpose of this document is to describe the work that will be performed and the procedures that will be followed during installation of ground water monitor wells and ground water elevation data recorders (data loggers) at the Grand Junction, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project site. The monitor wells and data loggers will be used to gather required time-dependent data to investigate the interaction between the shallow aquifer and the Colorado River. Data collection objectives (DCO) identify reasons for collecting data. The following are DCOs for the Grand Junction ground water elevation data recorder/monitor well installation project: long-term continuous ground water level data and periodic ground water samples will be collected to better understand the relationship between surface and ground water at the site; water level and water quality data will eventually be used in future ground water modeling to more firmly establish boundary conditions in the vicinity of the Grand Junction processing site; modeling results will be used to demonstrate and document the potential remedial alternative of natural flushing.

  19. Site observational work plan for the UMTRA project site at Grand Junction, Colorado

    SciTech Connect

    1996-01-01

    This site observational work plan (SOWP) is one of the first Uranium Mill Tailings Remedial Action (UMTRA) Ground Water Project documents developed to select a compliance strategy that meets the UMTRA ground water standards for the Grand Junction site. This SOWP applies information about the Grand Junction site to the compliance strategy selection framework developed in the UMTRA Ground Water Project draft programmatic environmental impact statement. This risk-based, decision-making framework identifies the decision logic for selecting compliance strategies that could be used to meet the ground water standards. The US Department of Energy (DOE) goal is to implement a cost-effective site strategy that complies with the ground water standards and protects human health and the environment. Based on an evaluation of the site characterization and risk assessment data available for the preparation of this SOWP, DOE proposes that the most likely compliance strategy for the Grand Junction site is no remediation with the application of supplemental standards. This proposed strategy is based on a conceptual site model that indicates site-related contamination is confined to a limited-use aquifer as defined in the ground water standards. The conceptual model demonstrates that the uranium processing-related contamination at the site has affected the unconfined alluvial aquifer, but not the deeper confined aquifer.

  20. Final report of the radiological release survey of Building 11 at the Grand Junction Office Facility

    SciTech Connect

    Johnson, R.K.; Corle, S.G.

    1997-09-01

    The U.S. Department of Energy (DOE) Grand Junction Office (GJO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore concentrates and mill tailings during vanadium refining activities of the Manhattan Engineer District, and during sampling, assaying, pilot milling, storage, and brokerage activities conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJO Remedial Action Project (GJORAP) to clean up and restore the facility lands, improvements, and underlying aquifer. WASTREN-Grand Junction is the site contractor for the facility and the remedial action contractor for GJORAP. Building 11 and the underlying soil were found not to be radiologically contaminated; therefore, the building can be released for unrestricted use. Placards have been placed at the building entrances indicating the completion of the radiological release survey and prohibiting the introduction of any radioactive materials within the building without written approvals from the GJO Facilities Operations Manager. This document was prepared in response to a DOE-GJO request for an individual final release report for each GJO building.

  1. Final audit report of remedial action construction at the UMTRA Project, Grand Junction, Colorado, processing site

    SciTech Connect

    1995-02-01

    This final audit report (FAR) for remedial action at the Grand Junction, Colorado, Uranium Mill Tailings Remedial Action (UMTRA) Project processing site consists of a summary of the radiological surveillances/ audits, the quality assurance (QA) in-process surveillances, and the QA final close-out inspection performed by the US Department of Energy (DOE) and Technical Assistance Contractor (TAC). The FAR also summarizes other surveillances performed by the US Nuclear Regulatory Commission (NRC). To summarize, a total of one finding and 127 observations were noted during DOE/TAC audit and surveillance activities. The NRC noted general site-related observations during the OSCRs. Follow-up to responses required from MK-Ferguson for the DOE/TAC finding and observations indicated that all issues related to the Grand Junction processing site were resolved and closed out to the DOE`s satisfaction. The NRC OSCRs resulted in no issues related to the Grand Junction processing site requiring a response from MK-Ferguson.

  2. Final report of the radiological release survey of Building 19 at the Grand Junction Office Facility

    SciTech Connect

    Johnson, R.K.; Corle, S.G.

    1997-09-01

    The U.S. Department of Energy (DOE) Grand Junction Office (GJO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore concentrates and mill tailings during vanadium refining activities of the Manhattan Engineer District, and during sampling, assaying, pilot milling, storage, and brokerage activities conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJO Remedial Action Project (GJORAP) to clean up and restore the facility lands, improvements, and underlying aquifer. WASTREN-Grand Junction is the site contractor for the facility and the remedial action contractor for GJORAP. Building 19 and the underlying soil were found not to be radiologically contaminated; therefore, the building can be released for unrestricted use. Placards have been placed at the building entrances indicating the completion of the radiological release survey and prohibiting the introduction of any radioactive materials within the building without written approvals from the GJO Facilities Operations Manager. This document was prepared in response to a DOE-GJO request for an individual final release report for each GJO building.

  3. Final report of the radiological release survey of Building 54 at the Grand Junction Office Facility

    SciTech Connect

    Johnson, R.K.; Corle, S.G.

    1997-09-01

    The U.S. Department of Energy (DOE) Grand Junction Office (GJO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore concentrates and mill tailings during vanadium refining activities of the Manhattan Engineer District, and during sampling, assaying, pilot milling, storage, and brokerage activities conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJO Remedial Action Project (GJORAP) to clean up and restore the facility lands, improvements, and underlying aquifer. WASTREN-Grand Junction is the site contractor for the facility and the remedial action contractor for GJORAP. Building 54 and the underlying soil were found not to be radiologically contaminated, and can be released for unrestricted use. Placards have been placed at the building entrances indicating the completion of the radiological release survey and prohibiting the introduction of any radioactive materials within the building without written approvals from the GJO Facilities Operations Manager. This document was prepared in response to a DOE-GJO request for an individual release report for each GJO building.

  4. Final report of the radiological release survey of Building 29 at the Grand Junction Office Facility

    SciTech Connect

    Johnson, R.K.; Corle, S.G.

    1997-09-01

    The U.S. Department of Energy (DOE) Grand Junction Office (GJO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore concentrates and mill tailing during vanadium refining activities of the Manhattan Engineer District, and during sampling, assaying, pilot milling, storage, and brokerage activities conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJO Remedial Action Project (GJORAP) to clean up and restore the facility lands, improvements, and underlying aquifer. WASTREN-Grand Junction is the site contractor for the facility and the remedial action contractor for GJORAP. Building 29 and the underlying soil were found not to be radiologically contaminated; therefore, the building can be released for unrestricted use. Placards have been placed at the building entrances indicating the completion of the radiological release survey and prohibiting the introduction of any radioactive materials within the building without written approvals from the GJO Facilities Operations Manager. This document was prepared in response to a DOE-GJO request for an individual final release report for each GJO building.

  5. Ecosystem level assessment of the Grand Calumet Lagoons, Indiana Dunes National Lakeshore

    SciTech Connect

    Stewart, P.M. [National Biological Service, Porter, IN (United States)

    1995-12-31

    The Grand Calumet Lagoons make up the eastern section of the Grand Calumet River (GCR), Indiana Harbor and Ship Canal and nearshore Lake Michigan Area of Concern (AOC). The GCR AOC is the only one of the 42 Great Lakes Areas of Concern identified by the International Joint Commission with all 14 designated uses classified as impaired. Included within the boundaries of the Indiana Dunes National Lakeshore (INDU), is the central section of the Grand Calumet Lagoons. A number of biotic and abiotic factors were tested to determine the effects of an industrial landfill that borders the lagoons to assess the potential impact on park resources. Analysis included water quality testing, assessments of macroinvertebrate, fish, algae and aquatic plant communities and contaminant concentrations in water, sediment and plant and fish tissue. Surface water testing found very few contaminants, but significantly higher nutrient levels were found in the water column closest to the landfill. Macroinvertebrate, aquatic plant and fish communities all showed significant impairment in relationship to their proximity to the landfill. Aquatic plant growth habit became limited next to the landfill with certain growth habits disappearing entirely. Aquatic plants collected close to the landfill had high concentrations of several heavy metals in their stems and shoots. Using the index of biotic integrity (IBI), fish community assessment indicated impairment in the areas adjacent to the landfill. Sediments tested at one site had over 12% polycyclic aromatic hydrocarbons (PAH) and carp (Cyprinus carpio) collected from this site had whole fish tissue concentrations over 1 mg/kg PAH.

  6. Effect of Composition and Heat Treatment on MnBi Magnetic Materials

    SciTech Connect

    Cui, Jun; Choi, Jung-Pyung; Polikarpov, Evgueni; Bowden, Mark E.; Xie, Wei; Li, Guosheng; Nie, Zimin; Zarkevich, Nikolai; Kramer, Matthew J.; Johnson, Duane D.

    2014-08-17

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material. Compare to other rare-earth-free candidates, MnBi stands out for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. Several groups have demonstrated that the Hci of MnBi compound in thin film or in powder form can exceed 12 kOe and 26 kOe at 300 K and 523 K, respectively. Such steep increase in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. The reaction between Mn and Bi is peritectic, so Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, the composition of the Mn-Bi alloy with the largest amount of the desired LTP (low temperature phase) MnBi and highest saturation magnetization will be over-stoichiometric and rich in Mn. The amount of additional Mn required to compensate the Mn precipitation depends on solidification rate: the faster the quench speed, the less Mn precipitates. Here we report a systematic study of the effect of composition and heat treatments on the phase contents and magnetic properties of Mn-Bi alloys. In this study, Mn-Bi alloys with 14 compositions were prepared using conventional metallurgical methods such as arc melting and vacuum heat treatment, and the obtained alloys were analyzed for compositions, crystal structures, phase content, and magnetic properties. The results show that the composition with 55 at.% Mn exhibits the highest LTP MnBi content and the highest magnetization. The sample with this composition shows >90 wt.% LTP MnBi content. Its measured saturation magnetization is 68 emu/g with 2.3 T applied field at 300 K; its coercivity is 13 kOe and its energy product is 12 MGOe at 300 K. A bulk magnet fabricated using this powder exhibits an energy product of 8.2 MGOe.

  7. EIS-0126: Remedial Actions at the Former Climax Uranium Company Uranium Mill Site, Grand Junction, Mesa County, Colorado

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy developed this EIS to assess the environmental impacts of remediating the residual radioactive materials left from the inactive uranium processing site and associated properties located in Grand Junction, Colorado.

  8. Magnetostructural phase transformations in Tb 1-x Mn 2

    DOE PAGES [OSTI]

    Zou, Junding; Paudyal, Durga; Liu, Jing; Mudryk, Yaroslav; Pecharsky, Vitalij K.; Gschneidner, Karl A.

    2015-01-16

    Magnetism and phase transformations in non-stoichiometric Tb1-xMn2 (x = 0.056, 0.039) have been studied as functions of temperature and magnetic field using magnetization, heat capacity, and X-ray powder diffraction measurements. Lowering the temperature, the compounds sequentially order ferrimagnetically and antiferromagnetically, and finally, exhibit spin reorientation transitions. Moreover, these structural distortions from room temperature cubic to low temperature rhombohedral structures occur at TN, and are accompanied by large volume changes reaching ~-1.27% and -1.42%, respectively. First principles electronic structure calculations confirm the phase transformation from the ferrimagnetic cubic structure to the antiferromagnetic rhombohedral structure in TbMn2.

  9. On the state of Mn impurity implanted in Si

    SciTech Connect

    Orlov, A. F.; Bublik, V. T.; Vdovin, V. I.; Agafonov, Yu. A.; Balagurov, L. A.; Zinenko, V. I.; Kulemanov, I. V.; Shcherbachev, K. D.

    2009-07-15

    The state of manganese impurity in implanted silicon at implantation doses of up to 5 x 10{sup 16} cm{sup -2} has been investigated by X-ray diffraction and transmission electron microscopy. It is established that, after short-term vacuum annealing at 850{sup o}C, most of the implanted manganese impurities are in microinclusions up to 20 nm in size formed by a tetragonal silicide phase of the Mn{sub 15}Si{sub 26} type.

  10. High-pressure structural study of MnF2

    DOE PAGES [OSTI]

    Stavrou, Elissaios; Yao, Yansun; Goncharov, Alexander F.; Konopkova, Zuzana; Raptis, Constantine

    2015-02-01

    In this study, manganese fluoride (MnF2) with the tetragonal rutile-type structure has been studied using a synchrotron angle-dispersive powder x-ray diffraction and Raman spectroscopy in a diamond anvil cell up to 60 GPa at room temperature combined with first-principles density functional calculations. The experimental data reveal two pressure-induced structural phase transitions with the following sequence: rutile → SrI2 type (3 GPa)→ α–PbCl2 type (13 GPa). Complete structural information, including interatomic distances, has been determined in the case of MnF2 including the exact structure of the debated first high-pressure phase. First-principles density functional calculations confirm this phase transition sequence, and themore » two calculated transition pressures are in excellent agreement with the experiment. Lattice dynamics calculations also reproduce the experimental Raman spectra measured for the ambient and high-pressure phases. The results are discussed in line with the possible practical use of rutile-type fluorides in general and specifically MnF2 as a model compound to reveal the HP structural behavior of rutile-type SiO2 (Stishovite).« less

  11. Manganese valence and coordination structure in Mn,Mg-codoped {gamma}-AlON green phosphor

    SciTech Connect

    Takeda, Takashi; Xie, Rong-Jun; Hirosaki, Naoto; Matsushita, Yoshitaka; Honma, Tetuso

    2012-10-15

    The valence and coordination structure of manganese in a Mn,Mg-codoped {gamma}-AlON spinel-type oxynitride green phosphor were studied by synchrotron X-ray diffraction and absorption fine structure measurements. The absorption edge position of the XANES revealed the bivalency of Mn. Two cation sites are available in the spinel structure for cation doping: a tetrahedral site and an octahedral site. The pre-edge of the XANES and the distance to the nearest neighbor atoms obtained from the EXAFS measurement showed that Mn was situated at the tetrahedral site. Rietveld analysis showed that the vacancy occupied the octahedral site. The preferential occupation of the tetrahedral site by Mn and the roles of N and Mg are discussed in relation to the spinel crystal structure. - Graphical Abstract: Fourier transform of EXAFS of Mn K-edge for Mn,Mg-codoped green phosphor and Mn coordination structure. Highlights: Black-Right-Pointing-Pointer Mn, Mg-codoped {gamma}-AlON green phosphor for white LED. Black-Right-Pointing-Pointer The valence of Mn is divalent. Black-Right-Pointing-Pointer Mn occupies the tetrahedral site in the spinel structure.

  12. Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys

    SciTech Connect

    Lobo, D. N.; Priolkar, K. R.; Emura, S.; Nigam, A. K.

    2014-11-14

    The structure, magnetic, and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD), and EXAFS. While Ni{sub 2}MnIn{sub 1?x}Fe{sub x} (0???x???0.6) alloys are ferromagnetic and non martensitic, the martensitic transformation temperature in Ni{sub 2}Mn{sub 1.5}In{sub 1?y}Fe{sub y} and Ni{sub 2}Mn{sub 1.6}In{sub 1?y}Fe{sub y} increases for lower Fe concentrations (y???0.05) before decreasing sharply for higher Fe concentrations. XRD analysis reveals presence of cubic and tetragonal structural phases in Ni{sub 2}MnIn{sub 1?x}Fe{sub x} at room temperature with tetragonal phase content increasing with Fe doping. Even though the local structure around Mn and Ni in these Fe doped alloys is similar to martensitic Mn rich Ni-Mn-In alloys, presence of ferromagnetic interactions and structural disorder induced by Fe affect Mn-Ni-Mn antiferromagnetic interactions resulting in suppression of martensitic transformation in these Fe doped alloys.

  13. Effect of composition and heat treatment on MnBi magnetic materials

    SciTech Connect

    Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

    2014-10-01

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of MnBi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

  14. Dynamic study of (De)sodiation in alpha-MnO2 nanowires

    SciTech Connect

    Yuan, Yifei; Ma, Lu; He, Kun; Yao, Wentao; Nie, Anmin; Bi, Xuanxuan; Amine, Khalil; Wu, Tianpin; Lu, Jun; Shahbazian-Yassr, Reza

    2016-01-01

    In this report, the electrochemical sodiation and desodiation in single crystalline alpha-MnO2 nanowires are studied dynamically at both single particle level using in situ transmission electron microscopy (TEM) and bulk level using in situ synchrotron X-ray. The TEM results suggest that the first sodiation process starts with tunnel-based Na+ intercalation, experiences the formation of Na0.5MnO2 as a result of tunnel degradation, and ends with the Mn2O3 phase. The inserted Na+ can be partially extracted out of the sodiated products, and the following cycles are dominated by the reversible conversion reaction between Na0.5MnO2 and Mn2O3. The Mn valence evolution inside a cycling coin using alpha-MnO2 nanowire electrode also exhibits partially reversible characteristic, agreeing well with the in situ TEM analysis. The sodiation is compared with lithiation in the same alpha-MnO2 nanowires. Both Na+ and Li+ interact with the tunneled structure via a similar tunnel -driven intercalation mechanism before Mn4+ is reduced to Mn3.5+. For the following deep insertion, the tunnels survive up. to LiMnO2 (Mn3+) during lithiation, while the sodiation proceeds via a different mechanism that involves obvious phase transition and fast tunnel degradation after Mn's valence is below 3.5+. The difference in charge carrier insertion mechanisms can be ascribed to the strong interaction between the tunnel frame and inserted Na+ possessing a larger ionic size than inserted Li+.

  15. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Universit de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  16. Synthesis, characterization and electrochemical performance of Al-substituted Li₂MnO₃

    SciTech Connect

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectron spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. As a result, aluminum substitutions increased the formation of spinel phase which is responsible for cycling.

  17. The magnetic origin of multiferroic Y{sub 2}CoMnO{sub 6}

    SciTech Connect

    Jia, Ting; Zeng, Zhi; Li, X. G.; Lin, H. Q.

    2015-05-07

    It has been found experimentally that the ferroelectricity in Y{sub 2}CoMnO{sub 6} is driven by a magnetic ordering of collinear up-up-down-down (↑↑↓↓). Here, the origin of the magnetism and thereby ferroelectricity is studied using first-principles calculations. We first confirm that the experimentally observed ↑↑↓↓ antiferromagnetic structure is the ground state of Y{sub 2}CoMnO{sub 6}. Additionally, both the Co{sup 2+} and Mn{sup 4+} are in the high-spin state. By analyzing the exchange coupling and corresponding pathways, we conclude that the ↑↑↓↓ spin order in Y{sub 2}CoMnO{sub 6} originates from a subtle competition between the ferromagnetic Co-O-Mn super-exchange and antiferromagnetic Co-Mn direct-exchange along c axis.

  18. Investigation of structure, magnetic, and transport properties of Mn-doped SiC films

    SciTech Connect

    Sun Xianke; Guo Ruisong; An Yukai; Liu Jiwen

    2013-07-15

    Mn-doped SiC films were fabricated by radio frequency magnetron sputtering technique. The structure, composition, and magnetic and transport properties of the films were investigated. The results show the films have the 3C-SiC crystal structure and the doped Mn atoms in the form of Mn{sup 2+} ions substitute for C sites in SiC lattice. All the films are ferromagnetic at 300 K, and the ferromagnetism in films arises from the doped Mn atoms and some extended defects. In addition, the saturation magnetization increases with the Mn-doped concentration increasing. The Mn doping does not change the semiconductor characteristics of the SiC films.

  19. Dynamic characterization and damage detection in the I-40 bridge over the Rio Grande

    SciTech Connect

    Farrar, C.R.; Baker, W.E.; Bell, T.M.; Cone, K.M.; Darling, T.W.; Duffey, T.A.; Eklund, A.; Migliori, A.

    1994-06-01

    In the 1960`s and 1970`s over 2500 bridges were built in the U.S. with a design similar to those on Interstate 40 over the Rio Grande in Albuquerque, New Mexico. These bridges were built without structural redundancy and typically have only two plate girders carrying the entire dead and live loads. Failure of either girder is assumed to produce catastrophic failure of the bridge, hence these bridges are referred to as fracture-critical bridges. The Federal Highway Administration (FHWA) and the National Science Foundation (NSF) have provided funds to New Mexico State University (NMSU) through the New Mexico State Highway and Transportation Department (NMSH&TD) and The Alliance For Transportation Research (ATR) for evaluation and testing of the existing fracture critical bridges over the Rio Grande. Because the 1-40 bridges over the Rio Grande were to be razed during the summer of 1993, the investigators were able to introduce simulated fatigue cracks, similar to those observed in the field, into the structure in order to test various damage identification methods and to observe the changes in load paths through the structure caused by the cracking. To support this research effort, NMSU contracted Los Alamos National Laboratory (LANL) to perform experimental modal analyses, and to develop experimentally verified numerical models of the bridge. Scientists from the LANL`s Condensed Matter and Thermal Physics Group (P-10) applied state-of-the-art sensors and data acquisition software to the modal tests. Engineers from the LANL`s Advanced Engineering Technology Group (MEE-13) conducted ambient and forced vibration tests to verify detailed and simplified finite element models of the bridge. Forced vibration testing was done in conjunction with engineers from Sandia National Laboratory (SNL) who provided and operated a hydraulic shaker.

  20. Late Pleistocene landslide-dammed lakes along the Rio Grande, White Rock Canyon, New Mexico

    SciTech Connect

    Reneau, S.L.; Dethier, D.P.

    1996-11-01

    Massive slump complexes composed of Pliocene basaltic rocks and underlying Miocene and Pliocene sediments flank the Rio Grande along 16 km of northern White Rock Canyon, New Mexico. The toe area of at least one slump complex was active in the late Pleistocene, damming the Rio Grande at least four times during the period from 18 to 12 {sup 14}C ka and impounding lakes that extended 10-20 km upriver. Stratigraphic relationships and radiocarbon age constraints indicate that three separate lakes formed between 13.7 and 12.4 {sup 14}C ka. The age and dimensions of the ca. 12.4 ka lake are best constrained; it had an estimated maximum depth of {approx}30 m, a length of {approx}13 km, a surface area of {approx}2.7 km{sup 2}, and an initial volume of {approx}2.5 x 10{sup 7} m{sup 3}. The youngest landslide-dammed lakes formed during a period of significantly wetter regional climate, strongly suggesting that climate changes were responsible for reactivation of the slump complexes. We are not certain about the exact triggering mechanisms for these landslides, but they probably involved removal of lateral support due to erosion of the slope base by the Rio Grande during periods of exceptionally high flood discharge or rapid incision; increased pore pressures associated with higher water tables; higher seepage forces at sites of ground-water discharge; or some combination of these processes. Seismic shaking could also have contributed to triggering of some of the landslides, particularly if aided by wet antecedent conditions. 54 refs., 19 figs., 3 tabs.

  1. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE PAGES [OSTI]

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore » been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  2. Cr(OH)₃(s) Oxidation Induced by Surface Catalyzed Mn(II) Oxidation

    SciTech Connect

    Namgung, Seonyi; Kwon, M.; Qafoku, Nikolla; Lee, Gie Hyeon

    2014-09-16

    This study examined the feasibility of Cr(OH)₃(s) oxidation mediated by surface catalyzed Mn(II) oxidation under common groundwater pH conditions as a potential pathway of natural Cr(VI) contaminations. Dissolved Mn(II) (50 μM) was reacted with or without synthesized Cr(OH)₃(s) (1.0 g/L) at pH 7 – 9 under oxic or anoxic conditions. In the absence of Cr(OH)₃(s), homogeneous Mn(II) oxidation by dissolved O₂ was not observed at pH ≤ 8.0 for 50 d. At pH 9.0, by contrast, dissolved Mn(II) was completely removed within 8 d and precipitated as hausmannite. When Cr(OH)₃(s) was present, this solid was oxidized and released substantial amounts of Cr(VI) as dissolved Mn(II) was added into the suspension at pH ≥ 8.0 under oxic conditions. Our results suggest that Cr(OH)₃(s) was readily oxidized by a newly formed Mn oxide as a result of Mn(II) oxidation catalyzed on Cr(OH)₃(s) surface. XANES analysis of the residual solids after the reaction between 1.0 g/L Cr(OH)₃(s) and 204 μM Mn(II) at pH 9.0 for 22 d revealed that the product of surface catalyzed Mn(II) oxidation resembled birnessite. The rate and extent of Cr(OH)₃(s) oxidation was likely controlled by those of surface catalyzed Mn(II) oxidation as the production of Cr(VI) increased with increasing pH and initial Mn(II) concentrations. This study evokes the potential environmental hazard of sparingly soluble Cr(OH)₃(s) that can be a source of Cr(VI) in the presence of dissolved Mn(II).

  3. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    SciTech Connect

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have not been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.

  4. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  5. ,"Grand Island, NY Natural Gas Pipeline Exports to Canada (Million Cubic Feet)"

    Energy Information Administration (EIA) (indexed site)

    Exports to Canada (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Grand Island, NY Natural Gas Pipeline Exports to Canada (Million Cubic Feet)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  6. ,"Grand Island, NY Natural Gas Pipeline Imports From Canada (MMcf)"

    Energy Information Administration (EIA) (indexed site)

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Grand Island, NY Natural Gas Pipeline Imports From Canada (MMcf)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  7. PCB usage at the Grand Junction Area Office Facility. Final report

    SciTech Connect

    Miller, M.E.; Donivan, S.

    1982-06-01

    The development, implementation, and results of the polychlorinated biphenyl (PCB) identification project at the Grand Junction Area Office (GJAO) are summarized. Methodology for the PCB analysis is described, and results are tabulated. Of the 51 transformers and disconnects in use at GJAO, 15 unites were determined to be PCB-contaminated or filled with PCBs. This number falls within EPA's estimate of 25 to 40 percent of all transformers in use being at least contaminated. Approximately 324 gallons of PCBs and 515 gallons of PCB-contaminated fluids are being used currently. No contaminated transformers or disconnects are in a position to contaminate food or feed products at the facility.

  8. Interim long-term surveillance plan for the Cheney disposal site near, Grand Junction, Colorado

    SciTech Connect

    1997-08-01

    This interim long-term surveillance plan (LTSP) describes the U.S. Department of Energy`s (DOE) long-term care program for the Uranium Mill Tailings Remedial Action (UMTRA) Project Cheney Disposal Site in Mesa County near Grand Junction, Colorado. This LSTP describes the long-term surveillance program the DOE will implement to ensure the Cheney disposal site performs as designed and is cared for in a manner that protects the public health and safety and the environment. Before each disposal site is licensed for custody and long-term care, the Nuclear Regulatory Commission (NRC) requires the DOE to submit such a site-specific LTSP.

  9. Long-term surveillance plan for the Cheney disposal site near Grand Junction, Colorado

    SciTech Connect

    1997-07-01

    This long-term surveillance plan (LTSP) describes the U.S. Department of Energy`s (DOE) long-term care program for the Uranium Mill Tailings Remedial Action (UMTRA) Project Cheney Disposal Site near Grand Junction, Colorado. This LSTP describes the long-term surveillance program the DOE will implement to ensure the Cheney Disposal Site performs as designed and is cared for in a manner that protects the public health and safety and the environment. Before each disposal site is licensed for custody and long-term care, the Nuclear Regulatory Commission (NRC) requires the DOE to submit such a site-specific LTSP.

  10. Strobe Light Deterrent Efficacy Test and Fish Behavior Determination at Grand Coulee Dam Third Powerplant Forebay

    SciTech Connect

    Johnson, Robert L. ); Simmons, Mary Ann ); Simmons, Carver S. ); McKinstry, Craig A. ); Cook, Chris B. ); Thorsten, Susan L. ); Lecaire, Richard; Francis, Stephen

    2003-01-29

    This report describes the work conducted during the second year of a multi-year study to assess the efficacy of a prototype strobe light system in eliciting a negative phototactic response in kokanee and rainbow trout. The strobe light system is being evaluated as a means to prevent entrainment (and subsequent loss) of fish at the entrance to the forebay adjacent to the third powerplant at Grand Coulee Dam. Pacific Northwest National Laboratory and the Confederated Tribes of the Colville Reservation are collaborating on the three-year study being conducted for the Bonneville Power Administration and the Northwest Power Planning Council.

  11. Communication: Reduced density matrices in molecular systems: Grand-canonical electron states

    SciTech Connect

    Bochicchio, Roberto C.; Miranda-Quintana, Ramn A.; Rial, Diego

    2013-11-21

    Grand-canonical like descriptions of many electron atomic and molecular open systems which are characterized by a non-integer number of electrons are presented. Their associated reduced density matrices (RDMs) are obtained by introducing the contracting mapping for this type of distributions. It is shown that there is loss of information when connecting RDMs of different order by partial contractions. The energy convexity property of these systems simplifies the description. Consequently, this formulation opens the possibility to a new look for chemical descriptors such as chemical potential and reactivity among others. Examples are presented to discuss the theoretical aspects of this work.

  12. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

    SciTech Connect

    Yan, Jun; Wei, Tong; Cheng, Jie; Fan, Zhuangjun; Zhang, Milin

    2010-02-15

    Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

  13. In operando X-ray studies of the conversion reaction in Mn3O4...

    Office of Scientific and Technical Information (OSTI)

    of the conversion reaction in Mn3O4 lithium battery anodes Citation Details ... energy storage (including batteries and capacitors), hydrogen and fuel ...

  14. Phase stability of the SrMnO[subscript 3] hexagonal perovskite...

    Office of Scientific and Technical Information (OSTI)

    SrMnOsubscript 3 hexagonal perovskite system at high pressure and temperature Citation ... Country of Publication: United States Language: ENGLISH Word Cloud More Like This Full ...

  15. International Falls, MN Natural Gas Pipeline Imports From Canada (Dollars

    Energy Information Administration (EIA) (indexed site)

    per Thousand Cubic Feet) Dollars per Thousand Cubic Feet) International Falls, MN Natural Gas Pipeline Imports From Canada (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 1.71 2.03 2.00 2.33 2000's 2.77 4.85 3.01 -- -- 11.20 -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date: 11/30/2016 Referring Pages:

  16. A Coupled Modeling System to Simulate Water Resources in the Rio Grande Basin

    SciTech Connect

    Bossert, J.E.; Breshears, D.D.; Campbell, K.; Costigan, K.R.; Greene, R.K.; Keating, E.H.; Kleifgen, L.M.; Langley, D.L.; Martens, S.N.; Sanderson, J.G.; Springer, E.P.; Stalker, J.R.; Tartakovsky, D.M.; Winter, C.L.; Zyvoloski, G.A.

    1999-01-11

    Limited availability of fresh water in arid and semi-arid regions of the world requires prudent management strategies from accurate, science-based assessments. These assessments demand a thorough understanding of the hydrologic cycle over long time periods within the individual water-sheds that comprise large river basins. Measurement and simulation of the hydrologic cycle is a tremendous challenge, involving a coupling between global to regional-scale atmospheric precipitation processes with regional to local-scale land surface and subsurface water transport. Los Alamos National Laboratory is developing a detailed modeling system of the hydrologic cycle and applying this tool at high resolution to assess the water balance within the upper Rio Grande river basin. The Rio Grande is a prime example of a river system in a semiarid environment, with a high demand from agricultural, industrial, recreational, and municipal interests for its water supply. Within this river basin, groundwater supplies often augment surface water. With increasing growth projected throughout the river basin, however, these multiple water users have the potential to significantly deplete groundwater resources, thereby increasing the dependence on surface water resources.

  17. Network discovery, characterization, and prediction : a grand challenge LDRD final report.

    SciTech Connect

    Kegelmeyer, W. Philip, Jr.

    2010-11-01

    This report is the final summation of Sandia's Grand Challenge LDRD project No.119351, 'Network Discovery, Characterization and Prediction' (the 'NGC') which ran from FY08 to FY10. The aim of the NGC, in a nutshell, was to research, develop, and evaluate relevant analysis capabilities that address adversarial networks. Unlike some Grand Challenge efforts, that ambition created cultural subgoals, as well as technical and programmatic ones, as the insistence on 'relevancy' required that the Sandia informatics research communities and the analyst user communities come to appreciate each others needs and capabilities in a very deep and concrete way. The NGC generated a number of technical, programmatic, and cultural advances, detailed in this report. There were new algorithmic insights and research that resulted in fifty-three refereed publications and presentations; this report concludes with an abstract-annotated bibliography pointing to them all. The NGC generated three substantial prototypes that not only achieved their intended goals of testing our algorithmic integration, but which also served as vehicles for customer education and program development. The NGC, as intended, has catalyzed future work in this domain; by the end it had already brought in, in new funding, as much funding as had been invested in it. Finally, the NGC knit together previously disparate research staff and user expertise in a fashion that not only addressed our immediate research goals, but which promises to have created an enduring cultural legacy of mutual understanding, in service of Sandia's national security responsibilities in cybersecurity and counter proliferation.

  18. Lessons Learned: The Grand Junction Office Site Transfer to Private Ownership

    SciTech Connect

    none,

    2001-02-01

    The U.S. Department of Energy Grand Junction Office (DOE-GJO) in Grand Junction, Colorado, has played an integral role within the DOE complex for many years. GJO has a reputation for outstanding quality in the performance of complex environmental restoration projects, utilizing state-of-the-art technology. Many of the GJO missions have been completed in recent years. In 1998, DOE Headquarters directed GJO to reduce its mortgage costs by transferring ownership of the site and to lease space at a reasonable rate for its ongoing work. A local community group and GJO have entered into a sales contract; signing of the Quitclaim Deed is planned for February 16, 2001. Site transfer tasks were organized as a project with a critical-path schedule to track activities and a Site Transition Decision Plan was prepared that included a decision process flow chart, key tasks, and responsibilities. Specifically, GJO identified the end state with affected parties early on, successfully dealt with site contamination issues, and negotiated a lease-back arrangement, resulting in an estimated savings of more than 60 percent of facility maintenance costs annually. Lessons learned regarding these transition activities could be beneficial to many other sites.

  19. Characterization of Pump Flow at the Grand Coulee Pumping Station for Fish Passage, 2004

    SciTech Connect

    Carlson, Thomas J.; Duncan, Joanne P.; Johnson, Robert L.

    2005-03-31

    This report describes a study conducted by PNNL for the Bonneville Power Administration to characterized the conditions fish experience when entrained in pump flow at the Grand Coulee Dam. PNNL used the Sensor Fish to measure the acceleration and pressure conditions that might be experienced by fish who are pulled through the pumps and turbines at Grand Coulee Dam's pump generation station and transported up into the feeder canal leading to Banks Lake. The probability that fish would be struck by the pump generating plant's new 9-bladed turbines was also calculated using Monte Carlo simulations. Our measurements showed relatively low turbulence except in the immediate vicinity of the runner environment. The highest pressure experienced by the Sensor Fish was estimated at 157 psi (the pressure gauge saturated at 155 psi). The probability of strike was also calculated, based on the average length of hatchery-reared juvenile kokanee (land-locked sockeye). Strike probabilities ranged from 0.755 for 2.36-inch fish to 0.3890 for 11.8-inch fish. The probability of strike estimates indicate that the majority (77%) of kokanne would be carried through the pump without being struck and most likely without injury resulting from pressure and turbulence exposure. Of the 23% that might be struck it is expected that 60% would arrive in Banks Lake without visible external injuries. Thus more than 90% of entrained fish would be expected to arrive in Banks Lake without injury.

  20. Preliminary Analysis of Grande Ronde Basalt Formation Flow Top Transmissivity as it Relates to Assessment and Site Selection Applications for Fluid/Energy Storage and Sequestration Projects

    SciTech Connect

    Spane, Frank A.

    2013-04-29

    Preliminary Analysis of Grande Ronde Basalt Formation Flow Top Transmissivity as it Relates to Assessment and Site Selection Applications for Fluid/Energy Storage and Sequestration Projects

  1. Mn(II) oxidation by an ascomycete fungus is linked to superoxide production during asexual reproduction

    SciTech Connect

    Hansel, C. M.; Zeiner, C. A.; Santelli, C. M.; Webb, S. M.

    2012-07-16

    Manganese (Mn) oxides are among the most reactive minerals within the environment, where they control the bioavailability of carbon, nutrients, and numerous metals. Although the ability of microorganisms to oxidize Mn(II) to Mn(III/IV) oxides is scattered throughout the bacterial and fungal domains of life, the mechanism and physiological basis for Mn(II) oxidation remains an enigma. Here, we use a combination of compound-specific chemical assays, microspectroscopy, and electron microscopy to show that a common Ascomycete filamentous fungus, Stilbella aciculosa, oxidizes Mn(II) to Mn oxides by producing extracellular superoxide during cell differentiation. The reactive Mn oxide phase birnessite and the reactive oxygen species superoxide and hydrogen peroxide are colocalized at the base of asexual reproductive structures. Mn oxide formation is not observed in the presence of superoxide scavengers (e.g., Cu) and inhibitors of NADPH oxidases (e.g., diphenylene iodonium chloride), enzymes responsible for superoxide production and cell differentiation in fungi. Considering the recent identification of Mn(II) oxidation by NADH oxidase-based superoxide production by a common marine bacterium (Roseobacter sp.), these results introduce a surprising homology between some prokaryotic and eukaryotic organisms in the mechanisms responsible for Mn(II) oxidation, where oxidation appears to be a side reaction of extracellular superoxide production. Finally, given the versatility of superoxide as a redox reactant and the widespread ability of fungi to produce superoxide, this microbial extracellular superoxide production may play a central role in the cycling and bioavailability of metals (e.g., Hg, Fe, Mn) and carbon in natural systems.

  2. Electrochemical performance studies of MnO{sub 2} nanoflowers recovered from spent battery

    SciTech Connect

    Ali, Gomaa A.M.; Tan, Ling Ling; Jose, Rajan; Yusoff, Mashitah M.; Chong, Kwok Feng

    2014-12-15

    Highlights: MnO{sub 2} is recovered from spent zinccarbon batteries as nanoflowers structure. Recovered MnO{sub 2} nanoflowers show high specific capacitance. Recovered MnO{sub 2} nanoflowers show stable electrochemical cycling up to 900 cycles. Recovered MnO{sub 2} nanoflowers show low resistance in EIS data. - Abstract: The electrochemical performance of MnO{sub 2} nanoflowers recovered from spent household zinccarbon battery is studied by cyclic voltammetry, galvanostatic charge/discharge cycling and electrochemical impedance spectroscopy. MnO{sub 2} nanoflowers are recovered from spent zinccarbon battery by combination of solution leaching and electrowinning techniques. In an effort to utilize recovered MnO{sub 2} nanoflowers as energy storage supercapacitor, it is crucial to understand their structure and electrochemical performance. X-ray diffraction analysis confirms the recovery of MnO{sub 2} in birnessite phase, while electron microscopy analysis shows the MnO{sub 2} is recovered as 3D nanostructure with nanoflower morphology. The recovered MnO{sub 2} nanoflowers exhibit high specific capacitance (294 F g{sup ?1} at 10 mV s{sup ?1}; 208.5 F g{sup ?1} at 0.1 A g{sup ?1}) in 1 M Na{sub 2}SO{sub 4} electrolyte, with stable electrochemical cycling. Electrochemical data analysis reveal the great potential of MnO{sub 2} nanoflowers recovered from spent zinccarbon battery in the development of high performance energy storage supercapacitor system.

  3. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  4. Scientific Grand Challenges: Crosscutting Technologies for Computing at the Exascale - February 2-4, 2010, Washington, D.C.

    SciTech Connect

    Khaleel, Mohammad A.

    2011-02-06

    The goal of the "Scientific Grand Challenges - Crosscutting Technologies for Computing at the Exascale" workshop in February 2010, jointly sponsored by the U.S. Department of Energy’s Office of Advanced Scientific Computing Research and the National Nuclear Security Administration, was to identify the elements of a research and development agenda that will address these challenges and create a comprehensive exascale computing environment. This exascale computing environment will enable the science applications identified in the eight previously held Scientific Grand Challenges Workshop Series.

  5. EIS-0400: Granby Pumping Plant Switchyard-Windy Gap Substation Transmission Line Rebuild Project, Grand County, CO

    Energy.gov [DOE]

    Western Area Power Administration prepared an EIS, with the U.S. Forest Service, Bureau of Land Management, and Grand County (Colorado) as cooperating agencies, to evaluate the potential environmental impacts of rebuilding a 12-mile, 69 kV electric transmission line in Grand County. The proposed project would rebuild the single-circuit line as a double-circuit transmission line and add a second power transformer. Western identified potentially significant impacts while preparing an EA for this proposal (DOE/EA-1520) and prepared an EIS instead of completing the EA. Further information about the project is available on the project website.

  6. Magnetic and structural properties of Zn doped MnV{sub 2}O{sub 4}

    SciTech Connect

    Shahi, Prashant; Shukla, K. K.; Singh, Rahul; Chatterjee, Sandip; Das, A.; Ghosh, A. K.; Nigam, A. K.

    2014-04-24

    The magnetization, Neutron diffraction and X-ray diffraction of Zn doped MnV{sub 2}O{sub 4} as a function of temperature have been measured. It has been observed, with increase of Zn the non-linear orientation of Mn spins with the V spins will decrease which effectively decrease the structural transition temperature more rapidly than Curie Temperature.

  7. Spin correlations and electron transport in MnBi:Au films

    SciTech Connect

    Kharel, P.; Skomski, R.; Sellmyer, D. J.

    2011-04-01

    The structural, magnetic, and electron transport properties of Mn{sub 55-x}Au{sub x}Bi{sub 45} (x = 0, 4.5) thin films prepared by magnetron sputtering have been investigated. The magnetization of the MnBi films decreases and the coercivity increases due to Au doping. The temperature dependence of resistivity between 2 to 300 K shows that the films are metallic but the 4.5% Au-doped film shows a Kondo behavior with resistance minimum at 10.2 K. The magnetoresistance is anisotropic and the positive transverse magnetoresistance is significantly enhanced (16.3% at 70 kOe) by Au doping. We interpret these data in terms of a model in which Au atoms preferentially substitute for Mn atoms on the Mn lattice, and some Mn atoms are displaced to interstitial sites in the NiAs structure. These interstitial Mn atoms are coupled antiferromagnetically to the Mn atoms on the original Mn lattice leading to the large decrease in magnetization, Kondo effect, and the positive magnetoresistance.

  8. Impedance studies of the thin film LiMn2O4/electrolyteinterface

    SciTech Connect

    Striebel, Kathryn A.; Sakai, E.; Cairns, Elton J.

    2001-04-07

    Room-temperature impedance measurements of a thin-film LiMn2O4/LiPF6-EC-DMC interface have been used to identify the spontaneous formation Li2Mn2O4 at the interface at room temperature at voltages of 3.7 and higher. The impedance of the LiMn2O4 films exhibited two time constants: at about 14 kHz and 60 to 200 Hz. The high frequency loop is dependent on film morphology and was attributed to the substrate/oxide interface. The low frequency behavior was dependent on both state-of-charge (SOC) and time at a given SOC. At full charge the impedance in this electrolyte was stable at room temperature over several days. At high lithium contents, film OCV and impedance tended to grow logarithmically with time, with lower rates for lower Mn3+ content in the film. The increased impedance was removed by oxidation of the film to 4.5V vs. Li/Li+. The observations are consistent with a reversible disproportionation of part of the LiMn2O4 into Li2Mn2O4 and a lithium-deficient spinel. With extended constant current cycling part of the Li2Mn2O4 degrades to the Mn2O3 and the process is no longer reversible.

  9. Room temperature spin-polarizations of Mn-based antiferromagnetic nanoelectrodes

    SciTech Connect

    Yamada, Toyo Kazu; Vazquez de Parga, Amadeo L.

    2014-11-03

    Antiferromagnets produce no stray field, and therefore, a tip electrode made of antiferromagnetic material has been considered to be the most suitable choice to measure such as magnetoresistance (MR) through single isolated magnetic nanoparticles, molecules, and ultrathin films. Spin polarizations (P) of antiferromagnetic 3-nm, 6-nm, and annealed 3-nm Mn films grown on W tips with a bcc(110) apex as well as bulk-NiMn tips were obtained at 300?K by measuring MR in ultrahigh vacuum by means of spin-polarized scanning tunneling microscopy using a layerwise antiferromagnetically stacking bct-Mn(001) film electrode. The Mn-coated tips with coverages of 3 and 6?nm exhibited P values of 1??1% and 3??2%, respectively, which tips likely contain ?- or strained Mn. With a thermal assist, the crystalline quality and the magnetic stability of the film could increase. The annealed tip exhibited P?=?9??2%. The bulk-NiMn tips exhibit spin polarizations of 0 or 6??2% probably depending on the chemical species (Mn or Ni) present at the apex of the tip. Fe-coated W tips were used to estimate the bct-Mn(001) film spin polarization.

  10. Site Determination and Magnetism of Mn Doping in Protein Encapsulated Iron Oxide Nanoparticles

    SciTech Connect

    Pool, V.; Klem, M.; Jolley, J.; Arenholz, E.A.; Douglas, T.; Young, M.; Idzerda, Y.U.

    2010-01-11

    Soft-X-ray absorption spectroscopy, soft-X-ray magnetic circular dichroism, and alternating current magnetic susceptibility were performed on 6.7 nm iron oxide nanoparticles doped with (5-33%) Mn grown inside the horse-spleen ferritin protein cages and compared to similarly protein encapsulated pure Fe-oxide and Mn-oxide nanoparticles to determine the site of the Mn dopant and to quantify the magnetic behavior with varying Mn concentration. The Mn dopant is shown to substitute preferentially as Mn{sup +2} and prefers the octahedral site in the defected spinel structure. The Mn multiplet structure for the nanoparticles is simpler than for the bulk standards, suggesting that the nanoparticle lattices are relaxed from the distortions present in the bulk. Addition of Mn is found to alter the host Fe-oxide lattice from a defected ferrimagnetic spinel structure similar to {gamma}-Fe{sub 2}O{sub 3} to an non-ferromagnetic spinel structure with a local Fe environment similar to Fe{sub 3}O{sub 4}.

  11. Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions

    SciTech Connect

    Nishitani, Y.; Endo, M.; Chiba, D.; Matsukura, F.; Ohno, H.

    2010-01-04

    We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

  12. K and Mn co-doped BaCd{sub 2}As{sub 2}: A hexagonal structured...

    Office of Scientific and Technical Information (OSTI)

    K and Mn co-doped BaCdsub 2Assub 2: A hexagonal structured bulk diluted magnetic semiconductor with large magnetoresistance Citation Details In-Document Search Title: K and Mn ...

  13. Grande Ronde Basin Fish Habitat Enhancement Project, Annual Report 2002-2003.

    SciTech Connect

    McGowan, Vance

    2003-08-01

    On July 1, 1984 the Bonneville Power Administration and the Oregon Department of Fish and Wildlife entered into an agreement to initiate fish habitat enhancement work in the Joseph Creek subbasin of the Grande Ronde River Basin in northeast Oregon. In July of 1985 the Upper and Middle Grande Ronde River, and Catherine Creek subbasins were included in the intergovernmental contract, and on March 1, 1996 the Wallowa River subbasin was added. The primary goal of 'The Grande Ronde Basin Fish Habitat Enhancement Project' is to create, protect, and restore riparian and instream habitat for anadromous salmonids, thereby maximizing opportunities for natural fish production within the basin. This project provided for implementation of Program Measure 703 (C)(1), Action Item 4.2 of the Northwest Power Planning Council's Columbia River Basin Fish and Wildlife Program (NPPC, 1987), and continues to be implemented as offsite mitigation for mainstem fishery losses caused by the Columbia River hydro-electric system. All work conducted by the Oregon Department of Fish and Wildlife is on private lands and therefore requires that considerable time be spent developing rapport with landowners to gain acceptance of, and continued cooperation with this program throughout 10-15 year lease periods. This project calls for passive regeneration of habitat, using riparian exclosure fencing as the primary method to restore degraded streams to a normative condition. Active remediation techniques using plantings, off-site water developments, site-specific instream structures, or whole channel alterations are also utilized where applicable. Individual projects contribute to and complement ecosystem and basin-wide watershed restoration efforts that are underway by state, federal, and tribal agencies, and local watershed councils. Work undertaken during 2002 included: (1) Implementing 1 new fencing project in the Wallowa subbasin that will protect an additional 0.95 miles of stream and 22.9 acres

  14. Grand Coulee - Bell 500-kV Transmission Line Project, Draft Environmental Impact Statement

    SciTech Connect

    N /A

    2002-08-09

    BPA is proposing to construct a 500-kilovolt (kV) transmission line that would extend approximately 84 miles between the Grand Coulee 500-kV Switchyard, near Grand Coulee Dam, and the Bell Substation, in Mead just north of Spokane. The new line would cross portions of Douglas, Grant, Lincoln, and Spokane counties. In addition to the transmission line, new equipment would be installed at the substations at each end of the new line and at other facilities. The proposed action would remove an existing 115-kV transmission line and replace it with the new 500-kV line on existing right-of-way for most of its length. Additional right-of-way would be needed in the first 3.5 miles out of the Grand Coulee Switchyard to connect to the existing 115-kV right-of-way. Since the mid-1990s, the transmission path west of Spokane, called the West of Hatwai transmission pathway, has grown increasingly constrained. To date, BPA has been able to manage operation of the path through available operating practices, and customer needed have been met while maintaining the reliability of the path. however, in early 2001, operations showed that the amount of electricity that needs to flow from east to west along this path creates severe transmission congestion. Under these conditions, the system is at risk of overloads and violation of industry safety and reliability standards. The problem is particularly acute in the spring and summer months because of the large amount of power generated by dams east of the path. Large amounts of water cannot be spilled during that time in order for BPA to fulfill its obligation to protect threatened and endangered fish. The amount of power that needs to move through this area during these months at times could exceed the carrying capacity of the existing transmission lines. In additional capacity is not added, BPA will run a significant risk that it will not be able to continue to meet its contractual obligations to deliver power and maintain reliability

  15. Magnetic properties and photoabsorption of the Mn-doped CeO{sub 2} nanorods

    SciTech Connect

    Xia, Chuanhui; Science College of Chongqing Jiaotong University, Chongqing 400074 ; Hu, Chenguo; Chen, Peng; Wan, Buyong; He, Xiaoshan; Tian, Yongshu; Chongqing Communication College, Chongqing 400035

    2010-07-15

    Mn-doped CeO{sub 2} nanorods have been prepared from CeO{sub 2} particles through a facile composite-hydroxide-mediated (CHM) approach. The analysis from X-ray photoelectron spectroscopy indicates that the manganese doped in CeO{sub 2} exists as Mn{sup 2+}. The magnetic measurement of the Mn-doped CeO{sub 2} nanorods exhibits an enhanced ferromagnetic property at room temperature with a remanence magnetization (Mr) of 1.36 x 10{sup -3} emu/g and coercivity (Hc) of 22 Oe. Comparative UV-visible spectra reveal the shift of the absorption peak of the CeO{sub 2} from ultraviolet region to visible light region after being doped with Mn. The room temperature ferromagnetic properties and light absorption of the Mn-doped CeO{sub 2} nanorods would have potential applications in photocatalysis and building of photovoltaic devices.

  16. Giant atomic displacement at a magnetic phase transition in metastable Mn3O4

    SciTech Connect

    Hirai, Shigeto; Moreira Dos Santos, Antonio F; Shapiro, Max C; Molaison, Jamie J; Pradhan, Neelam; Guthrie, Malcolm; Tulk, Christopher A; Fisher, Ian R; Mao, Wendy

    2013-01-01

    We present x-ray, neutron scattering, and heat capacity data that reveal a coupled first-order magnetic and structural phase transition of the metastable mixed-valence postspinel compound Mn3O4 at 210 K. Powder neutron diffraction measurements reveal a magnetic structure in which Mn3+ spins align antiferromagnetically along the edge-sharing a axis, with a magnetic propagation vector k = [1/2,0,0]. In contrast, the Mn2+ spins, which are geometrically frustrated, do not order until a much lower temperature. Although the Mn2+ spins do not directly participate in the magnetic phase transition at 210 K, structural refinements reveal a large atomic shift at this phase transition, corresponding to a physical motion of approximately 0.25 angstrom, even though the crystal symmetry remains unchanged. This "giant" response is due to the coupled effect of built-in strain in the metastable postspinel structure with the orbital realignment of the Mn3+ ion.

  17. Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor

    SciTech Connect

    Wijnheijmer, A. P.; Koenraad, P. M.; Marti, X.; Holy, V.; Cukr, M.; Novak, V.; Jungwirth, T.

    2012-03-12

    We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

  18. Rio Grande Erosion Potential Demonstration - Report for the National Border Technology Program

    SciTech Connect

    JEPSEN, RICHARD A.; ROBERTS, JESSE D.; LANGFORD, RICHARD; GAILANI, JOSEPH

    2001-11-01

    This demonstration project is a collaboration among DOE, Sandia National Laboratories, the University of Texas, El Paso (UTEP), the International Boundary and Water Commission (IBWC), and the US Army Corps of Engineers (USACE). Sandia deployed and demonstrated a field measurement technology that enables the determination of erosion and transport potential of sediments in the Rio Grande. The technology deployed was the Mobile High Shear Stress Flume. This unique device was developed by Sandia's Carlsbad Programs for the USACE and has been used extensively in collaborative efforts on near shore and river systems throughout the United States. Since surface water quantity and quality along with human health is an important part of the National Border Technology Program, technologies that aid in characterizing, managing, and protecting this valuable resource from possible contamination sources is imperative.

  19. EIS-0355: Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah, Environmental Impact Statement and associated supplements and amendments provides information on the environmental impacts of the U.S. Department of Energy’s (DOE’s) proposal to (1) remediate approximately 11.9 million tons of contaminated materials located on the Moab site and approximately 39,700 tons located on nearby vicinity properties and (2) develop and implement a ground water compliance strategy for the Moab site using the framework of the Programmatic Environmental Impact Statement for the Uranium Mill Tailings Remedial Action Ground Water Project (DOE/EIS-0198, October 1996). The surface remediation alternatives analyzed in the EIS include on-site disposal of the contaminated materials and off-site disposal at one of three alternative locations in Utah using one or more transportation options: truck, rail, or slurry pipeline.

  20. Assessment of cover systems at the Grand Junction, Colorado, uranium mill tailings pile: 1987 field measurements

    SciTech Connect

    Gee, G.W.; Campbell, M.D.; Freeman, H.D.; Cline, J.F.

    1989-02-01

    Four Pacific Northwest Laboratory (PNL) scientists and a technician conducted an onsite evaluation of radon gas exhalation, water content profiles, and plant and animal intrusion for a series of cover systems located on the uranium mill tailings pile at Grand Junction, Colorado. These six plots were sampled extensively down to the radon control layer (e.g., asphalt or wet clay) for soil moisture content and permeability. Radon gas emission through the surface was measured. Soil samples were collected and analyzed in the lab for particle-size distribution, particle density, bulk density, and ambient water content. Prairie dog burrows were excavated to discover the extent to which they penetrated the barriers. Plant type, density, and cover characteristics were measured.

  1. Grand Island, NY Natural Gas Pipeline Imports From Canada (Million Cubic

    Energy Information Administration (EIA) (indexed site)

    Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 42,832 42,302 44,981 33,140 2000's 49,012 95,639 110,417 76,421 66,612 92,474 80,907 88,886 61,641 81,898 2010's 63,548 47,616 23,000 5,758 1,413 4,940 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date: 11/30/2016 Referring Pages: U.S. Natural Gas Pipeline Imports by Point of Entry Grand

  2. Grand Island, NY Natural Gas Pipeline Imports From Canada (Dollars per

    Energy Information Administration (EIA) (indexed site)

    Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 3.35 3.42 2.80 3.07 2000's 4.24 4.08 3.57 6.26 6.63 9.07 7.61 7.41 8.94 4.85 2010's 5.20 4.68 3.01 3.92 9.80 4.23 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date: 11/30/2016 Referring Pages: U.S. Price of Natural Gas Pipeline Imports by Point of Entry Grand Island, NY

  3. Power council cites Tacoma homes - the Grand Coulee Dam of the future

    SciTech Connect

    Riley, M.

    1984-07-01

    The energy-efficient building codes adopted by Tacoma, Washington will give the city a reservoir of power comparable to the water stored behind Grand Coulee Dam. The code standards reduce energy requirements 60%, a saving that will continue through the 50- to 60-year service life of the houses. The first to adopt the Northwest Power Planning Council (NWPPC) Model Conservation Stardards, Tacoma recognized that current electric power surpluses are temporary and that conservation is the cheapest way to get new power. The city adopted the plan despite its low rates because economic growth is likely to come from power-intensive industries. A support package for the plan combines building code compliance, an information system, marketing, and financial incentives.

  4. Use of a dynamic simulation model to understand nitrogen cycling in the middle Rio Grande, NM.

    SciTech Connect

    Meixner, Tom; Tidwell, Vincent Carroll; Oelsner, Gretchen; Brooks, Paul; Roach, Jesse D.

    2008-08-01

    Water quality often limits the potential uses of scarce water resources in semiarid and arid regions. To best manage water quality one must understand the sources and sinks of both solutes and water to the river system. Nutrient concentration patterns can identify source and sink locations, but cannot always determine biotic processes that affect nutrient concentrations. Modeling tools can provide insight into these large-scale processes. To address questions about large-scale nitrogen removal in the Middle Rio Grande, NM, we created a system dynamics nitrate model using an existing integrated surface water--groundwater model of the region to evaluate our conceptual models of uptake and denitrification as potential nitrate removal mechanisms. We modeled denitrification in groundwater as a first-order process dependent only on concentration and used a 5% denitrification rate. Uptake was assumed to be proportional to transpiration and was modeled as a percentage of the evapotranspiration calculated within the model multiplied by the nitrate concentration in the water being transpired. We modeled riparian uptake as 90% and agricultural uptake as 50% of the respective evapotranspiration rates. Using these removal rates, our model results suggest that riparian uptake, agricultural uptake and denitrification in groundwater are all needed to produce the observed nitrate concentrations in the groundwater, conveyance channels, and river as well as the seasonal concentration patterns. The model results indicate that a total of 497 metric tons of nitrate-N are removed from the Middle Rio Grande annually. Where river nitrate concentrations are low and there are no large nitrate sources, nitrate behaves nearly conservatively and riparian and agricultural uptake are the most important removal mechanisms. Downstream of a large wastewater nitrate source, denitrification and agricultural uptake were responsible for approximately 90% of the nitrogen removal.

  5. Ferromagnetic (Ga,Mn)As nanostructures for spintronic applications

    SciTech Connect

    Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Makosa, Andrzej; Wrobel, Jerzy; Sadowski, Janusz

    2013-12-04

    Magneto-resistive, cross-like nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, composed of two perpendicular nanostripes crossing in the middle of their length, represent four-terminal devices, in which an electric current can be driven through any of the two nanostripes. In these devices, a novel magneto-resistive memory effect, related to a rearrangement of magnetic domain walls in the central part of the device, has been demonstrated. It consists in that the zero-field resistance of a nanostripe depends on the direction of previously applied magnetic field. The nanostructures can thus work as two-state devices providing basic elements of nonvolatile memory cells.

  6. CTUIR Grande Ronde River Watershed Restoration Program McCoy Creek/McIntyre Creek Road Crossing, 1995-1999 Progress Report.

    SciTech Connect

    Childs, Allen B.

    2000-08-01

    The Confederated Tribes of the Umatilla Indian Reservation (CTUIR) and Bonneville Power Administration (BPA) entered into a contract agreement beginning in 1996 to fund watershed restoration and enhancement actions and contribute to recovery of fish and wildlife resources and water quality in the Grande Ronde River Basin. The CTUIR's habitat program is closely coordinated with the Grande Ronde Model Watershed Program and multiple agencies and organizations within the basin. The CTUIR has focused during the past 4 years in the upper portions of the Grande Ronde Subbasin (upstream of LaGrande, Oregon) on several major project areas in the Meadow, McCoy, and McIntyre Creek watersheds and along the mainstem Grande Ronde River. This Annual Report provides an overview of individual projects and accomplishments.

  7. Technical basis for radiological release of Grand Junction Office Building 2. Volume 2, dose assessment supporting data

    SciTech Connect

    1997-07-01

    The second volume of the Grand Junction Office Action Program Technical Basis for Radiological Release of Grand Junction Office Building 2 report includes the data quality objectives (DQO), sampling plan, collected data, and analysis used to model future radiation doses to members of the public occupying Building 2 on the U.S. Department of Energy (DOE) Grand Junction Office (GJO) site. This volume was assembled by extracting relevant components of the Grand Junction Projects Office Remedial Action Project Building 2 Public Dose Evaluation (DOE 1996) and inserting recent additional data that was gathered and dose pathway modeling that was performed. The intent of this document is to provide all derived guidance decisions, assumptions, measured data, testing results, and pathway modeling software input and output data that supports the discussion and determinations presented in Volume 1 of this report. For constructive employment of this document, the reader is encouraged to closely follow Volume 1 for proper association with the segment of information being examined.

  8. Sequence stratigraphic model of the Rio Grande Delta, south west Texas: Potential analog for the Niger Delta

    SciTech Connect

    Banfield, L.A.; Anderson, J.B.; Vail, P.R.

    1996-12-31

    A sequence stratigraphic model developed from the ancient Rio Grande Delta in South West Texas is suggested as an analog for the Niger Delta. The two delta systems are characterized by high sand bedloads, shale diapirism with associated listric normal faulting, and large amounts of tidal and wave influence forming lower coastal plains characterized by swamps and estuaries. The sequence stratigraphic model of the ancient Rio Grande delta is based on approximately 1200 kilometers of single channel, 15 cubic inch water gun data, lithologic descriptions from approximately 25 long cores (28-30 m) located in 17-94 meters water depth, three gamma ray logs, paleontologic data from two cores, and oxygen isotopic data from one core (152 meters in length and located in 94 meters water depth). The combined data indicate that considerable quantities of sand are sequestered on the continental shelf and point sourcing the slope. The Rio Grande sequence stratigraphic model provides an improved understanding of sand deposits on the shelf, of the role of sediment bypass during lowstands, and of the base of slope deposits formed by headward eroding canyons (?) or channels (?) located at the shelf break. This information regarding the distribution of sand in the Rio Grande system can provide valuable insight into the reservoir distribution in the Niger system, improving existing reservoir predictions.

  9. Impedance analysis of MnCoCuO NTC ceramic

    SciTech Connect

    Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

    2005-07-12

    Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

  10. Ab initio study of Fe{sub 2}MnZ (Al, Si, Ge) Heusler alloy using GGA approximation

    SciTech Connect

    Jain, Vivek Kumar Jain, Vishal Lakshmi, N. Venugopalan, K.

    2014-04-24

    Density functional theory based on FP-LAPW method used to investigate the electronic structure of Fe{sub 2}MnZ, shows that the total spin magnetic moment shows a trend consistent with the Slater–Pauling curve. The Fe and Mn magnetic moment depend on choice of Z element although the magnetic moment of Z element is negative and less than 0.1 μ{sub B}. Spin polarization calculations evidence 100% spin polarization for Fe{sub 2}MnSi. Fe{sub 2}MnAl and Fe{sub 2}MnGe show metallic behavior with 93%, 98% spin polarization.

  11. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

    SciTech Connect

    Liu, Chao-Xing; Qi, Xiao-Liang; Dai, Xi; Fang, Zhong; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-03-19

    The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

  12. Recent progress of magnetocaloric effect and magnetic refrigerant materials of Mn compounds (invited)

    SciTech Connect

    Wada, H. Takahara, T.; Katagiri, K.; Ohnishi, T.; Soejima, K.; Yamashita, K.

    2015-05-07

    Magnetocaloric and related properties of Ru and Ni substituted (MnFe){sub 2}(PSi) are presented. It is found that Ru and Ni are effective doping elements to reduce the thermal hysteresis of (MnFe){sub 2}(PSi). The origin of the thermal hysteresis is discussed on the basis of a thermodynamic model. It is shown that the elastic energy is responsible for the thermal hysteresis. We also show recent developments of the production process of Mn compounds in an industrial scale.

  13. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy

    SciTech Connect

    Maniraj, M.; D?Souza, S. W.; Rai, Abhishek; Schlagel, D. L.; Lograsso, T. A.; Chakrabarti, Aparna; Barman, S. R.

    2015-08-20

    Momentum resolved inverse photoemission spectroscopy measurements show that the dispersion of the unoccupied bands of Ni2MnGa is significant in the austenite phase. Furthermore, in the martensite phase, it is markedly reduced, which is possibly related to the structural transition to an incommensurate modulated state in the martensite phase. Finally, based on the first principle calculations of the electronic structure of NiMnGa, we show that the modification of the spectral shape with surface composition is related to change in the hybridization between the Mn 3d and Ni 3d-like states that dominate the unoccupied conduction band.

  14. Unique light-induced degradation in yellow-emitting K₂SiF₆:Mn²⁺ phosphor

    SciTech Connect

    Oyama, Takuya; Adachi, Sadao

    2014-10-07

    Photo-induced luminescence intensity degradation in yellow-emitting K₂SiF₆:Mn²⁺ phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K₂SiF₆:Mn²⁺ phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (λ = 325 nm) > Ar⁺ (488 nm) > He–Ne laser (632.8 nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn²⁺ to Mn³⁺ by the photooxidation (Mn²⁺ → Mn³⁺) or disproportionation reaction (2Mn²⁺ → Mn⁺ + Mn³⁺). The ESR measurement confirms the decreased Mn²⁺ spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn³⁺ ions occurs through energy transfer upon absorption of exciting radiation by the Mn²⁺ ions. Thermal annealing of the degraded samples at ≥200 °C causes a blueshift in the PL emission band with an appearance of the Mn⁴⁺-related sharp red emission lines.

  15. Role of Cu-Ion Doping in Cu-α-MnO2 Nanowire Electrocatalysts for the Oxygen Reduction Reaction

    DOE PAGES [OSTI]

    Davis, Danae J.; Lambert, Timothy N.; Vigil, Julian A.; Rodriguez, Mark A.; Brumbach, Michael T.; Coker, Eric N.; Limmer, Steven J.

    2014-07-09

    The role of Cu-ion doping in α-MnO2 electrocatalysts for the oxygen reduction reaction in alkaline electrolyte was investigated. Copper doped α-MnO2 nanowires (Cu-α-MnO2) were prepared with varying amounts of Cu2+ using a solvothermal method. The electrocatalytic dataindicates that Cu-α-MnO2 nanowires have higher terminal current densities, enhanced kinetic rate constants, and improved charge transfer resistances that trend with Cu-content, exceeding values attained by α-MnO2 alone. The observed improvement in catalytic behavior correlates with an increase in Mn3+ content for the Cu-α-MnO2 nanowires. The Mn3+/Mn4+ couple is themediator for the rate-limiting redox driven O2-/OH- exchange. It is proposed that O2 adsorbs viaanmore » axial site (the eg orbital on the Mn3+ d4 ion) at the surface, or at edge defects, of the nanowireand that the increase in covalent nature of the nanowire with Cu-ion doping leads to stabilization of O2 adsorbates and faster rates of reduction. This work is applicable to other manganese oxide electrocatalysts and shows for the first time there is a correlation for manganese oxides between electrocatalytic activity for the ORR in alkaline electrolyte and an increase in Mn3+ character of the oxide.« less

  16. First-principles study of spin-transfer torque in Co{sub 2}MnSi/Al/Co{sub 2}MnSi spin-valve

    SciTech Connect

    Tang, Ling Yang, Zejin

    2013-11-21

    The spin-transfer torque (STT) in Co{sub 2}MnSi(CMS)/Al/Co{sub 2}MnSi spin-valve system with and without interfacial disorder is studied by a first-principles noncollinear wave-function-matching method. It is shown that in the case of clean interface the angular dependence of STT for CoCo/Al (the asymmetry parameter Λ≈4.5) is more skewed than that for MnSi/Al (Λ≈2.9), which suggests the clean CoCo/Al architecture is much more efficient for the application on radio frequency oscillation. We also find that even with interfacial disorder the spin-valve of half-metallic CMS still has a relatively large parameter Λ compared to that of conventional ferromagnet. In addition, for clean interface the in-plane torkance of MnSi/Al is about twice as large as that of CoCo/Al. However, as long as the degree of interfacial disorder is sufficiently large, the CoCo/Al and MnSi/Al will show approximately the same magnitude of in-plane torkance. Furthermore, our results demonstrate that CMS/Al/CMS system has very high efficiency of STT to switch the magnetic layer of spin-valve.

  17. Planar Hall effect in Y{sub 3}Fe{sub 5}O{sub 12}/IrMn films

    SciTech Connect

    Zhang, X. Zou, L. K.

    2014-12-29

    The planar Hall effect of IrMn on an yttrium iron garnet (YIG = Y{sub 3}Fe{sub 5}O{sub 12}) was measured in the magnetic field rotating in the film plane. The magnetic field angular dependence of planar Hall resistance (PHR) was observed in YIG/IrMn bilayer at different temperatures, while the Gd{sub 3}Ga{sub 5}O{sub 12}/IrMn film shows constant PHR for different magnetic field angles at both 10 K and 300 K. This provides evidence that IrMn has interfacial spins which can be led by ferrimagnetic layer in YIG/IrMn structure. A hysteresis can be observed in PHR-magnetic field angle loop of YIG/IrMn film at 10 K, indicative of the irreversible switching of IrMn interfacial spins at low temperature.

  18. Grand Challenges for Biological and Environmental Research: A Long-Term Vision

    SciTech Connect

    Arkin, A.; Baliga, N.; Braam, J.; Church, G.; Collins, J; Cottingham, R.; Ecker, J.; Gerstein, M.; Gilna, P.; Greenberg, J.; Handelsman, J.; Hubbard, S.; Joachimiak, A.; Liao, J.; Looger, L.; Meyerowitz, E.; Mjolness, E.; Petsko, G.; Sayler, G.; Simpson, M.; Stacey, G.; Sussman, M.; Tiedje, J.; Bader, D.; Cessi, P.; Collins, W.; Denning, S.; Dickinson, R.; Easterling, D.; Edmonds, J.; Feddema, J.; Field, C.; Fridlind, A.; Fung, I.; Held, I.; Jackson, R.; Janetos, A.; Large, W.; Leinen, M.; Leung, R.; Long, S.; Mace, G.; Masiello, C.; Meehl, G.; Ort, D.; Otto-Bliesner, B.; Penner, J.; Prather, M.; Randall, D.; Rasch, P.; Schneider, E.; Shugart, H.; Thornton, P.; Washington, W.; Wildung, R.; Wiscombe, W.; Zak, D.; Zhang, M.; Bielicki, J.; Buford, M.; Cleland, E.; Dale, V.; Duke, C.; Ehleringer, J.; Hecht, A.; Kammen, D.; Marland, G.; Pataki, D.; Riley, M. Robertson, P.; Hubbard, S.

    2010-12-01

    behaviors of complex biological and environmental systems, leading to robust solutions for DOE missions and strategic goals. In March 2010, the Biological and Environmental Research Advisory Committee held the Grand Challenges for Biological and Environmental Research: A Long-Term Vision workshop to identify scientific opportunities and grand challenges for BER science in the coming decades and to develop an overall strategy for drafting a long-term vision for BER. Key workshop goals included: (1) Identifying the greatest scientific challenges in biology, climate, and the environment that DOE will face over a 20-year time horizon. (2) Describing how BER should be positioned to address those challenges. (3) Determining the new and innovative tools needed to advance BER science. (4) Suggesting how the workforce of the future should be trained in integrative system science. This report lays out grand research challenges for BER - in biological systems, climate, energy sustainability, computing, and education and workforce training - that can put society on a path to achieve the scientific evidence and predictive understanding needed to inform decision making and planning to address future energy needs, climate change, water availability, and land use.

  19. Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams; 2000 Annual Report.

    SciTech Connect

    Crossley, Brian; Lockwood, Jr., Neil W.; McLellan, Jason G.

    2001-01-01

    The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, commonly known as the Joint Stock Assessment Project (JSAP) is a management tool using ecosystem principles to manage artificial fish assemblages and native fish in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (blocked area). The three-phase approach of this project will enhance the fisheries resources of the blocked area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information housed in a central location will allow managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP (NWPPC program measure 10.8B.26) is designed and guided jointly by fisheries managers in the blocked area and the Columbia Basin blocked area management plan (1998). The initial year of the project (1997) identified the need for a central data storage and analysis facility, coordination with the StreamNet project, compilation of blocked area fisheries information, and a report on the ecological condition of the Spokane River System. These needs were addressed in 1998 by acquiring a central location with a data storage and analysis system, coordinating a pilot project with StreamNet, compiling fisheries distribution data throughout the blocked area, identifying data gaps based on compiled information, and researching the ecological condition of the Spokane River. In order to ensure that any additional information collected throughout the life of this project will be easily stored and manipulated by the central storage facility, it was necessary to develop standardized methodologies between the JSAP fisheries managers. The use of common collection and analytical tools is essential to the process of streamlining joint management decisions. In 1999 and 2000 the project

  20. Nonuniversal gaugino masses and muong-<mn>2mn>

    SciTech Connect

    Gogoladze, Ilia; Nasir, Fariha; Shafi, Qaisar; n, Cem Salih

    2014-08-11

    We consider two classes of supersymmetric models with nonuniversal gaugino masses at the grand unification scale MGUT in an attempt to resolve the apparent muon g-2 anomaly encountered in the Standard Model. We explore two distinct scenarios, one in which all gaugino masses have the same sign at MGUT, and a second case with opposite sign gaugino masses. The sfermion masses in both cases are assumed to be universal at MGUT. We exploit the nonuniversality among gaugino masses to realize large mass splitting between the colored and noncolored sfermions. Thus, the sleptons can have masses in the few hundred GeV range, whereas the colored sparticles turn out to be an order of magnitude or so heavier. In both models the resolution of the muon g-2 anomaly is compatible, among other things, with a 125126 GeV Higgs boson mass and the WMAP dark matter bounds.

  1. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape...

    Office of Scientific and Technical Information (OSTI)

    shape memory alloy This content will become publicly available on August 20, 2016 Prev Next Title: Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy ...

  2. File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    MN.pdf Jump to: navigation, search File File history File usage Minnesota Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275...

  3. Pressure-Induced Metallization of the Mott Insulator MnO (Journal...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Induced Metallization of the Mott Insulator MnO Citation ... Publication Date: 2004-01-12 OSTI Identifier: 15013737 Report Number(s): UCRL-JRNL-201933 Journal ID: ISSN ...

  4. In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function...

    Office of Scientific and Technical Information (OSTI)

    of LixMnO2 Nanowires as a Function of "x" and Size Authors: Le, Mya ; Liu, Yu ; Wang, Hui ; Dutta, Rajen ; Yan, Wenbo ; Hemminger, John C ; Wu, Ruqian ; Penner, Reginald...

  5. Microstructure and Mechanical Properties of Two-Phase Fe30Ni20Mn20Al30...

    Office of Scientific and Technical Information (OSTI)

    Title: Microstructure and Mechanical Properties of Two-Phase Fe30Ni20Mn20Al30 Alloy Authors: Wu, Xiaolan 1 ; Baker, Ian 1 ; Wu, H 1 ; Miller, Michael K 2 ; More, Karren ...

  6. Magnetocaloric effect of Pr2Fe17-x Mn x alloys (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Magnetocaloric effect of Pr2Fe17-x Mn x ... OSTI Identifier: 1221829 Report Number(s): IS-J 8426 Journal ID: ISSN 1001-0521; PII: 134 ...

  7. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation...

    Office of Scientific and Technical Information (OSTI)

    Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex ...

  8. Effect of Mn substitution on the transport properties of co-sputtered...

    Office of Scientific and Technical Information (OSTI)

    on the transport properties of co-sputtered Fesub 3-xMnsub xSi epilayers Citation Details In-Document Search Title: Effect of Mn substitution on the transport properties of ...

  9. Spectroscopic properties of (PVA+ZnO):Mn{sup 2+} polymer films

    SciTech Connect

    Rani, Ch.; Raju, D. Siva; Bindu, S. Hima; Krishna, J. Suresh; Raju, Ch. Linga

    2015-05-15

    Electron Paramagnetic Resonance (EPR), optical absorption and infrared spectral studies have been carried out on Mn{sup 2+} ions doped in poly(vinyl alcohol) complexed with zinc oxide polymer films prepared by solution cast technique. The EPR spectra of 1 mol% Mn{sup 2+} ions doped polymer complex (PVA+ZnO) at room temperature exhibit sextet hyperfine structure (hfs), centered at 2.01. The spin-Hamiltonian parameter values indicate that the ground state of Mn{sup 2+} ion in d{sup 5} and the site symmetry around Mn{sup 2+} ions in tetragonally distorted octa hedral site. The optical absorption spectra exhibits two bands centered at 275nm at 437nm. The FTIR spectrum exhibits bands characteristic of stretching and banding vibrations of O-H, C-H and C=C groups.

  10. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    SciTech Connect

    Nicholson, Don M; Odbadrakh, Khorgolkhuu; Rios, Orlando; Hodges, Jason P; Ludtka, Gerard Michael; Porter, Wallace D; Sefat, A. S.; Rusanu, Aurelian; Evans III, Boyd Mccutchen

    2012-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system have been explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering (LSMS) method to explore the magnetic states responsible for the magnet-caloric effect in this material. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy were investigated using differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). Neutron scattering experiments were performed to observe the structural and magnetic phase transformations at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on alloys of Ni-Mn-Ga and Ni-Mn-Ga-Cu-Fe. Data from the observations are discussed in comparison with the computational studies.

  11. Electrochemical Performances of LiMnPO4 Synthesized from Non...

    Office of Scientific and Technical Information (OSTI)

    Li1.1MnPO4 exhibits the most stable cycling ability probably because of the existence of a trace amount of Li3PO4 impurity that functions as a solid-state electrolyte on...

  12. Synthesis and characterization of MnPS{sub 3} for hydrogen sorption

    SciTech Connect

    Ismail, N.; Temerk, Y.M.; El-Meligi, A.A.; Badr, M.A.; Madian, M.

    2010-05-15

    Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

  13. Superior magnetic and mechanical property of MnFe 3 N driven by electron

    Office of Scientific and Technical Information (OSTI)

    correlation and lattice anharmonicity (Journal Article) | SciTech Connect Journal Article: Superior magnetic and mechanical property of MnFe 3 N driven by electron correlation and lattice anharmonicity Citation Details In-Document Search Title: Superior magnetic and mechanical property of MnFe 3 N driven by electron correlation and lattice anharmonicity Authors: Wu, Hao ; Sun, Hong ; Chen, Changfeng Publication Date: 2015-02-05 OSTI Identifier: 1180768 Grant/Contract Number: NA0001982 Type:

  14. Understanding the Structural and Electronic Evolution of Li2MnO3 During

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Electron Irradiation Via Electron Microscopy - Joint Center for Energy Storage Research November 17, 2014, Research Highlights Understanding the Structural and Electronic Evolution of Li2MnO3 During Electron Irradiation Via Electron Microscopy In-situ electron beam irradiation induces localized pockets of damage (a) and (b) characterized by the Mn atoms migrating to occupy Li sites, as shown in the annular bright field image of (c). This effect is clearly visible in an intensity line profile

  15. The role of C and Mn at the austenite/pearlite reaction front during non-steady-state pearlite growth in a Fe-C-Mn steel

    DOE PAGES [OSTI]

    Aranda, M. M.; Rementeria, R.; Poplawsky, Jonathan D.; Urones-Garrote, E.; Capdevila, Carlos

    2015-04-18

    The role of C and Mn during the growth of pearlite under non-steady state conditions is analyzed by comparing the phase compositions of austenite, ferrite and cementite (γ+α+θ) through the use of transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), and atom probe tomography (APT) measurements across the austenite/pearlite interface. Furthermore, a local Mn enrichment and C depletion at the austenite/pearlite interface has been measured, which causes a change in the driving force with time during divergent pearlite growth.

  16. Technical basis for radiological release of Grand Junction Office Building 2. Volume 1, dose assessment

    SciTech Connect

    Morris, R.; Warga, J.; Thorne, D.

    1997-07-01

    Building 2 on the US Department of Energy (DOE) Grand Junction Office (GJO) site is part of the GJO Remedial Action Program (GJORAP). During evaluation of Building 2 for determination of radiological release disposition, some inaccessible surface contamination measurements were detected to be greater than the generic surface contamination guidelines of DOE Order 5400.5 (which are functionally equivalent to US Nuclear Regulatory Commission [NRC] Regulatory Guide 1.86). Although the building is nominal in size, it houses the site telecommunications system, that is critical to continued GJO operations, and demolition is estimated at $1.9 million. Because unrestricted release under generic surface contamination guidelines is cost-prohibitive, supplemental standards consistent with DOE Order 5400.5 are being pursued. This report describes measurements and dose analysis modeling efforts to evaluate the radiation dose to members of the public who might occupy or demolish Building 2, a 2,480 square-foot (ft) building constructed in 1944. The north portion of the building was used as a shower facility for Manhattan Project uranium-processing mill workers and the south portion was a warehouse. Many originally exposed surfaces are no longer accessible for contamination surveys because expensive telecommunications equipment have been installed on the floors and mounted on panels covering the walls. These inaccessible surfaces are contaminated above generic contamination limits.

  17. Electrolyte pore/solution partitioning by expanded grand canonical ensemble Monte Carlo simulation

    SciTech Connect

    Moucka, Filip; Bratko, Dusan Luzar, Alenka

    2015-03-28

    Using a newly developed grand canonical Monte Carlo approach based on fractional exchanges of dissolved ions and water molecules, we studied equilibrium partitioning of both components between laterally extended apolar confinements and surrounding electrolyte solution. Accurate calculations of the Hamiltonian and tensorial pressure components at anisotropic conditions in the pore required the development of a novel algorithm for a self-consistent correction of nonelectrostatic cut-off effects. At pore widths above the kinetic threshold to capillary evaporation, the molality of the salt inside the confinement grows in parallel with that of the bulk phase, but presents a nonuniform width-dependence, being depleted at some and elevated at other separations. The presence of the salt enhances the layered structure in the slit and lengthens the range of inter-wall pressure exerted by the metastable liquid. Solvation pressure becomes increasingly repulsive with growing salt molality in the surrounding bath. Depending on the sign of the excess molality in the pore, the wetting free energy of pore walls is either increased or decreased by the presence of the salt. Because of simultaneous rise in the solution surface tension, which increases the free-energy cost of vapor nucleation, the rise in the apparent hydrophobicity of the walls has not been shown to enhance the volatility of the metastable liquid in the pores.

  18. Measurements of air contaminants during the Cerro Grande fire at Los Alamos National Laboratory

    SciTech Connect

    Eberhart, Craig

    2010-08-01

    Ambient air sampling for radioactive air contaminants was continued throughout the Cerro Grande fire that burned part of Los Alamos National Laboratory. During the fire, samples were collected more frequently than normal because buildup of smoke particles on the filters was decreasing the air flow. Overall, actual sampling time was 96% of the total possible sampling time for the May 2000 samples. To evaluate potential human exposure to air contaminants, the samples were analyzed as soon as possible and for additional specific radionuclides. Analyses showed that the smoke from the fire included resuspended radon decay products that had been accumulating for many years on the vegetation and the forest floor that burned. Concentrations of plutonium, americium, and depleted uranium were also measurable, but at locations and concentrations comparable to non-fire periods. A continuous particulate matter sampler measured concentrations that exceeded the National Ambient Air Quality Standard for PM-10 (particles less than 10 micrometers in diameter). These high concentrations were caused by smoke from the fire when it was close to the sampler.

  19. Grand Junction Projects Office Remedial Action Project Building 2 public dose evaluation. Final report

    SciTech Connect

    Morris, R.

    1996-05-01

    Building 2 on the U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) site, which is operated by Rust Geotech, is part of the GJPO Remedial Action Program. This report describes measurements and modeling efforts to evaluate the radiation dose to members of the public who might someday occupy or tear down Building 2. The assessment of future doses to those occupying or demolishing Building 2 is based on assumptions about future uses of the building, measured data when available, and predictive modeling when necessary. Future use of the building is likely to be as an office facility. The DOE sponsored program, RESRAD-BUILD, Version. 1.5 was chosen for the modeling tool. Releasing the building for unrestricted use instead of demolishing it now could save a substantial amount of money compared with the baseline cost estimate because the site telecommunications system, housed in Building 2, would not be disabled and replaced. The information developed in this analysis may be used as part of an as low as reasonably achievable (ALARA) cost/benefit determination regarding disposition of Building 2.

  20. Wildlife Protection, Mitigation and Enhancement Planning for Grand Coulee Dam, Final Report.

    SciTech Connect

    Creveling, Jennifer

    1986-08-01

    The development and operation of Grand Coulee Dam inundated approximately 70,000 acres of wildlife habitat under the jurisdictions of the Colville Confederated Tribes, the Spokane Tribe, and the State of Washington. Under the provisions of the Pacific Northwest Electric Power Planning and Conservation Act of 1980, this study reviews losses to wildlife and habitat, and proposes mitigation for those losses. Wildlife loss estimates were developed from information available in the literature. Habitat losses and potential habitat gains through mitigation were estimated by a modified Habitat Evaluation Procedure. The mitigation plan proposes (1) acquisition of sufficient land or management rights to land to protect Habitat Units equivalent to those lost (approximately 73,000 acres of land would be required), (2) improvement and management of those lands to obtain and perpetuate target Habitat Units, and (3) protection and enhancement of suitable habitat for bald eagles. Mitigation is presented as four actions to be implemented over a 10-year period. A monitoring program is proposed to monitor mitigation success in terms of Habitat Units and wildlife population trends.

  1. Application and testing of a fiber optic communication system at Grand Coulee

    SciTech Connect

    Osburn, G.D.; Arnold, R.G.

    1988-03-01

    The U.S. Bureau of Reclamation (USBR) operates the world's largest, fully operational hydroelectric facility at Grand Coulee Dam located on the Columbia River in eastern Washington state. Data transmitted for control, protection, and communication between this facility's Third Powerplant and 500-kv switchyard are essential for the safe and efficient operation of the Bureau's equipment and the integrity of the connected power systems. To accomplish the reliable, high speed transmission of such data over the relatively long distance between these two locations having unequal ground potential rise (GPR) a fiber optic communication system was installed, tested, and placed into service. The paper discusses the rationale for applying fiber optic technology in this application with emphasis on the related design considerations important in control and protection of this large hydroelectric facility. Brief summaries of hardware used and installation considerations are given. Fundamentals and principles of fiber optic system design are not intended or covered. Discussion of factory and unique field testing, including electromagnetic interference (EMI) induced transient influence and timing tests, is included. Operating experience and projected future use are summarized.

  2. Features of ZnS-powder doping with a Mn impurity during synthesis and subsequent annealing

    SciTech Connect

    Korsunska, N. E. Bacherikov, Yu. Yu.; Stara, T. R.; Kladko, V. P.; Baran, N. P.; Polishchuk, Yu. O.; Kuchuk, A. V.; Zhuk, A. G.; Venger, Ye. F.

    2013-05-15

    Luminescence, electron spin resonance, and X-ray diffraction (XRD) methods were used to investigate the features of ZnS-powder doped by Mn impurity during self-propagating high-temperature synthesis and subsequent annealing. The obtained powder consists of ZnS microcrystals with mainly hexagonal phase (80 {+-} 5)%. It was found, that after synthesis Mn presents not only in the form of non-uniformly distributed microscopic impurities in ZnS, but also in the form of Mn metal nanocrystals. Thermal annealing at 800 Degree-Sign C leads to the additional doping of ZnS from metallic Mn, to the redistribution of the embedded Mn in the volume of microcrystals, and to the ZnS oxidation. At the same time, the ratio between the cubic and hexagonal phases does not change. It was shown that annealing causes a decrease in the concentration of the defects responsible for the luminescence-excitation bands, which correspond to transitions from the ground to the excited states of the Mn{sup 2+} ion. As a result of annealing, there is also a change in XRD coherent domain size. Simultaneously, the intensity of peaks in the luminescence-excitation spectrum with wavelengths of 375 and 395 nm was changed. The causes of these changes and the nature of the corresponding bands are discussed.

  3. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex

    DOE PAGES [OSTI]

    Hunter, Gary J.; Trinh, Chi H.; Bonetta, Rosalin; Stewart, Emma E.; Cabelli, Diane E.; Hunter, Therese

    2015-08-27

    C. elegans MnSOD-3 has been implicated in the longevity pathway and its mechanism of catalysis is relevant to the aging process and carcinogenesis. The structures of MnSOD-3 provide unique crystallographic evidence of a dynamic region of the tetrameric interface (residues 41–54). We have determined the structure of the MnSOD-3-azide complex to 1.77-Å resolution. The analysis of this complex shows that the substrate analog, azide, binds end-on to the manganese center as a sixth ligand and that it ligates directly to a third and new solvent molecule also positioned within interacting distance to the His30 and Tyr34 residues of the substratemore » access funnel. This is the first structure of a eukaryotic MnSOD-azide complex that demonstrates the extended, uninterrupted hydrogen-bonded network that forms a proton relay incorporating three outer sphere solvent molecules, the substrate analog, the gateway residues, Gln142, and the solvent ligand. This configuration supports the formation and release of the hydrogen peroxide product in agreement with the 5-6-5 catalytic mechanism for MnSOD. The high product dissociation constant k₄ of MnSOD-3 reflects low product inhibition making this enzyme efficient even at high levels of superoxide.« less

  4. B -meson decay constants from <mn>2mn>+>1mn> -flavor lattice QCD with domain-wall light quarks and relativistic heavy quarks

    SciTech Connect

    Christ, N. H.; Flynn, J. M.; Izubuchi, T.; Kawanai, T.; Lehner, C.; Soni, A.; Van de Water, R. S.; Witzel, O.

    2015-03-01

    We calculate the B-meson decay constants fB, fBs, and their ratio in unquenched lattice QCD using domain-wall light quarks and relativistic b quarks. We use gauge-field ensembles generated by the RBC and UKQCD collaborations using the domain-wall fermion action and Iwasaki gauge action with three flavors of light dynamical quarks. We analyze data at two lattice spacings of amn>0.11mn>, 0.086 fm with unitary pion masses as light as Mπmn>290mn>MeV; this enables us to control the extrapolation to the physical light-quark masses and continuum. For the b quarks we use the anisotropic clover action with the relativistic heavy-quark interpretation, such that discretization errors from the heavy-quark action are of the same size as from the light-quark sector. We renormalize the

  5. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect

    Pei, L.Z. Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15

    Graphical abstract: - Highlights: Mn vanadate nanosheets have been synthesized by simple hydrothermal process. The formation of Mn vanadate nanosheets can be controlled by growth conditions. Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 210 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  6. AVTA Federal Fleet PEV Readiness Data Logging and Characterization Study for the National Park Service: Grand Canyon National Park

    SciTech Connect

    Stephen Schey; Jim Francfort; Ian Nienhueser

    2014-08-01

    This report focuses on the Grand Canyon National Park (GCNP) fleet to identify daily operational characteristics of select vehicles and report findings on vehicle and mission characterizations to support the successful introduction of PEVs into the agencies’ fleets. Individual observations of these selected vehicles provide the basis for recommendations related to electric vehicle adoption and whether a battery electric vehicle or plug-in hybrid electric vehicle (collectively PEVs) can fulfill the mission requirements.

  7. EA-1679: Grand Coulee's Third Powerplant 500-kV Transmission Line Replacement Project, Grant and Okanogon Counties, Washington

    Energy.gov [DOE]

    This EA evaluates potential environmental impacts from the construction and operation of six new 500-kV overhead transmission lines to replace six existing underground lines at Grand Coulee Dam. DOE’s Bonneville Power Administration (BPA), a cooperating agency, was asked by the U. S. Department of the Interior’s Bureau of Reclamation to design and construct the proposed new transmission lines. A Finding of No Significant Impact was issued by BPA in December 2011.

  8. Final report of the radiological release survey of Building 30B at the Grand Junction Office Facility

    SciTech Connect

    Krauland, P.A.; Corle, S.G.

    1997-09-01

    The U.S. Department of Energy (DOE) Grand Junction Office (GJO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore concentrates and mill tailings during vanadium refining activities of the Manhattan Engineer District, and during sampling, assaying, pilot milling, storage, and brokerage activities conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJO Remedial Action Project (GJORAP) to clean up and restore the facility lands, improvements, and underlying aquifer. WASTREN-Grand Junction is the site contractor for the facility and the remedial action contractor for GJORAP. Building 30B and the underlying soil were found not to be radiologically contaminated; therefore, the building can be released for unrestricted use. Placards have been placed at the building entrances indicating the completion of the radiological release survey and prohibiting the introduction of any radioactive materials within the building without written approvals from the GJO Facilities Operations Manager. This document was prepared in response to a DOE-GJO request for an individual final release report for each GJO building.

  9. Final report of the decontamination and decommissioning of Building 34 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7 acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the Grand Junction Projects Office Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, was also the remedial action contractor. Building 34 was radiologically contaminated and the building was demolished in 1996. The soil area within the footprint of the building was analyzed and found to be not contaminated. The area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual closeout report for each contaminated GJPO building.

  10. U.S. Department of Energy Grand Junction Projects Office site environmental report for calendar year 1995

    SciTech Connect

    1996-05-01

    This report presents information pertaining to environmental activities conducted during calendar year 1995 at the US Department of Energy (DOE) Grand Junction Projects Office (GJPO) facility in Grand Junction, Colorado. Environmental activities conducted at the GJPO facility during 1995 were associated with mixed-waste treatment, site remediation, off-site dose modeling, and radiological and nonradiological monitoring. As part of the GJPO Mixed-Waste Treatment Program, on-site treatability studies were conducted in 1995 that made use of pilot-scale evaporative-oxidation and thermal-desorption units and bench-scale stabilization. DOE-GJPO used some of its own mixed-waste as well as samples received from other DOE sites for these treatability studies. These studies are expected to conclude in 1996. Removal of radiologically contaminated materials from GJPO facility buildings was conducted under the provisions of the Grand Junction Projects Office Remedial Action Project. Remediation activities included the removal of 394 metric tons of contaminated material from Buildings 18 and 28 and revegetation activities on the GJPO site; remediation was conducted in compliance with applicable permits.

  11. Final report of the decontamination and decommissioning of the exterior land areas at the Grand Junction Projects Office facility

    SciTech Connect

    Widdop, M.R.

    1995-09-01

    The US Department of Energy (DOE) Grand Junction Projects Office (GJPO) facility occupies approximately 56.4 acres (22.8 hectares) along the Gunnison River near Grand Junction, Colorado. The site was contaminated with uranium ore and mill tailings during uranium-refining activities conducted by the Manhattan Engineer District and during pilot-milling experiments conducted for the US Atomic Energy Commission`s (AEC`s) domestic uranium procurement program. The GJPO facility was the collection and assay point for AEC uranium and vanadium oxide purchases until the early 1970s. The DOE Decontamination and Decommissioning Program sponsored the Grand Junction Projects Office Remedial Action Project (GJPORAP) to remediate the facility lands, site improvements, and the underlying aquifer. The site contractor, Rust Geotech, was the Remedial Action Contractor for GJPORAP. The exterior land areas of the facility assessed as contaminated have been remediated in accordance with identified standards and can be released for unrestricted use. Restoration of the aquifer will be accomplished through the natural flushing action of the aquifer during the next 50 to 80 years. The remediation of the DOE-GJPO facility buildings is ongoing and will be described in a separate report.

  12. Inverse magnetocaloric effect in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys

    SciTech Connect

    Singh, Sanjay Barman, S. R.; Esakki Muthu, S.; Arumugam, S.; Senyshyn, A.; Rajput, P.; Suard, E.

    2014-02-03

    Inverse magnetocaloric effect is demonstrated in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys. The entropy change at the martensite transition is larger in Mn{sub 1.75}Ni{sub 1.25}Ga, and it increases linearly with magnetic field in both the specimens. Existence of inverse magnetocaloric effect is consistent with the observation that magnetization in the martensite phase is smaller than the austenite phase. Although the Mn content is smaller in Mn{sub 1.75}Ni{sub 1.25}Ga, from neutron diffraction, we show that the origin of inverse magnetocaloric effect is the antiferromagnetic interaction between the Mn atoms occupying inequivalent sites.

  13. Comments and responses on the Remedial Action Plan and site design for stabilization of the Inactive Uranium Mill Tailings Site, Grand Junction, Colorado. Revision 1

    SciTech Connect

    1994-01-01

    This report contains information concerning public comments and responses on the remedial action plan and site design for stabilization of the inactive uranium mill tailings site in Grand Junction, Colorado.

  14. Fish Research Project Oregon; Aspects of Life History and Production of Juvenile Oncorhynchus Mykiss in the Grande Ronde River Basin, Northeast Oregon, 1995-1999 Summary Report.

    SciTech Connect

    Van Dyke, Erick S.; Jonnasson, Brian C.; Carmichael, Richard W.

    2001-07-01

    Rotary screw traps, located at four sites in the Grande Ronde River basin, were used to characterize aspects of early life history exhibited by juvenile Onchorhychus mykiss during migration years 1995-99. The Lostine, Catherine Creek and upper Grande Ronde traps captured fish as they migrated out of spawning areas into valley rearing habitats. The Grande Ronde Valley trap captured fish as they left valley habitats downstream of Catherine Creek and upper Grande Ronde River rearing habitats. Dispersal downstream of spawning areas was most evident in fall and spring, but movement occurred during all seasons that the traps were fished. Seaward migration occurred primarily in spring when O. mykiss smolts left overwintering area located in both spawning area and valley habitats. Migration patterns exhibited by O. mykiss suggest that Grande Ronde Valley habitats are used for overwintering and should be considered critical rearing habitat. We were unable to positively differentiate anadromous and resident forms of O. mykiss in the Grande Ronde River basin because both forms occur in our study area. The Grande Ronde Valley trap provided the best information on steelhead production in the basin because it fished below valley habitats where O. mykiss overwinter. Length frequency histograms of O. mykiss captured below upper spawning and rearing habitats showed a bimodal distribution regardless of the season of capture. Scale analyses suggested that each mode represents a different brood year. Length frequency histograms of O. mykiss captured in the Grande Ronde Valley trap were not bimodal, and primarily represented a size range consistent with other researchers' accounts of anadromous smolts.

  15. Resident Fish Stock above Chief Joseph and Grand Coulee Dams; 2002 Annual Report.

    SciTech Connect

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2003-09-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial fish assemblages and native fish in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The

  16. Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams; 2002-2003 Annual Report.

    SciTech Connect

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2006-02-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial and native fish assemblages in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The

  17. Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams; 2001 Annual Report.

    SciTech Connect

    Connor, Jason M.; McLellan, Jason G.; O'Connor, Dick

    2003-01-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power Planning Council (NPPC). The NPPC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPPC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial fish assemblages and native fish in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area and the Columbia Basin Blocked Area Management Plan (1998

  18. Resident Fish Stock above Chief Joseph and Grand Coulee Dams; 2003-2004 Annual Report.

    SciTech Connect

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2005-11-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial and native fish assemblages in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The

  19. Steam Dryer Segmentation and Packaging at Grand Gulf Nuclear Station - 13577

    SciTech Connect

    Kreitman, Paul J.; Sirianni, Steve R.; Pillard, Mark M.

    2013-07-01

    Entergy recently performed an Extended Power Up-rate (EPU) on their Grand Gulf Nuclear Station, near Port Gibson, Mississippi. To support the EPU, a new Steam Dryer Assembly was installed during the last refueling outage. Due to limited access into the containment, the large Replacement Steam Dryer (RSD) had to be brought into the containment in pieces and then final assembly was completed on the refueling floor before installation into the reactor. Likewise, the highly contaminated Original Steam Dryer (OSD) had to be segmented into manageable sections, loaded into specially designed shielded containers, and rigged out of containment where they will be safely stored until final disposal is accomplished at an acceptable waste repository. Westinghouse Nuclear Services was contracted by Entergy to segment, package and remove the OSD from containment. This work was performed on critical path during the most recent refueling outage. The segmentation was performed underwater to minimize radiation exposure to the workers. Special hydraulic saws were developed for the cutting operations based on Westinghouse designs previously used in Sweden to segment ABB Reactor Internals. The mechanical cutting method was selected because of its proven reliability and the minimal cutting debris that is generated by the process. Maintaining stability of the large OSD sections during cutting was accomplished using a custom built support stand that was installed into the Moisture Separator Pool after the Moisture Separator was installed back in the reactor vessel. The OSD was then moved from the Steam Dryer Pool to the Moisture Separator Pool for segmentation. This scenario resolved the logistical challenge of having two steam dryers and a moisture separator in containment simultaneously. A water filtration/vacuum unit was supplied to maintain water clarity during the cutting and handling operations and to collect the cutting chips. (authors)

  20. Annotated bibliography for the humpback chub (Gila cypha) with emphasis on the Grand Canyon population.

    SciTech Connect

    Goulet, C. T.; LaGory, K. E.; Environmental Science Division

    2009-10-05

    Glen Canyon Dam is a hydroelectric facility located on the Colorado River in Arizona that is operated by the U.S. Bureau of Reclamation (Reclamation) for multiple purposes including water storage, flood control, power generation, recreation, and enhancement of fish and wildlife. Glen Canyon Dam operations have been managed for the last several years to improve conditions for the humpback chub (Gila cypha) and other ecosystem components. An extensive amount of literature has been produced on the humpback chub. We developed this annotated bibliography to assist managers and researchers in the Grand Canyon as they perform assessments, refine management strategies, and develop new studies to examine the factors affecting humpback chub. The U.S. Geological Survey recently created a multispecies bibliography (including references on the humpback chub) entitled Bibliography of Native Colorado River Big Fishes (available at www.fort.usgs.gov/Products/data/COFishBib). That bibliography, while quite extensive and broader in scope than ours, is not annotated, and, therefore, does not provide any of the information in the original literature. In developing this annotated bibliography, we have attempted to assemble abstracts from relevant published literature. We present here abstracts taken unmodified from individual reports and articles except where noted. The bibliography spans references from 1976 to 2009 and is organized in five broad topical areas, including: (1) biology, (2) ecology, (3) impacts of dam operations, (4) other impacts, and (5) conservation and management, and includes twenty subcategories. Within each subcategory, we present abstracts alphabetically by author and chronologically by year. We present relevant articles not specific to either the humpback chub or Glen Canyon Dam, but cited in other included reports, under the Supporting Articles subcategory. We provide all citations in alphabetical order in Section 7.

  1. The prominent role of oxygen in the multiferroicity of DyMnO3 and TbMnO3: a resonant soft x-ray scattering spectroscopy study

    DOE PAGES [OSTI]

    S. W. Huang; Lee, J. M.; Jeng, H. -T.; Shao, Y.; Wray, L. A.; Chen, J. M.; Qiao, R.; Yang, W. L.; Cao, Y.; Lin, J. -Y.; et al

    2016-07-21

    Oxygen is known to play an important role in the multiferroicity of rare earth manganites; however, how this role changes with rare earth elements is still not fully understood. To address this question, we have used resonant soft x-ray scattering spectroscopy to study the F-type (0; ; 0) diffraction peak from the antiferromagnetic order in DyMnO3 and TbMnO3. We focus on the measurements at O K-edge of these two manganites, supplemented by the results at Mn L2- and Dy M5-edge of DyMnO3. We show that the electronic states of di erent elements are coupled more strongly in DyMnO3 than inmore » TbMnO3, presumably due to the stronger lattice distortion and the tendency to develop E-type antiferromagnetism in the ferroelectric state that promote the orbital hybridization. We also show that the anomaly in the correlation length of (0; ; 0) peak in DyMnO3 signifies the exchange interaction between Mn and rare earth spins, which is absent in TbMnO3. Our findings reveal the prominent role of oxygen orbitals in the multiferroicity of rare earth manganites and the distinct energetics between them.« less

  2. Synthesis of spherical LiMnPO{sub 4}/C composite microparticles

    SciTech Connect

    Bakenov, Zhumabay; Taniguchi, Izumi

    2011-08-15

    Highlights: {yields} We could prepare LiMnPO{sub 4}/C composites by a novel preparation method. {yields} The LiMnPO{sub 4}/C composites were spherical particles with a mean diameter of 3.65 {mu}m. {yields} The LiMnPO{sub 4}/C composite cathode exhibited 112 mAh g{sup -1} at 0.05 C. {yields} It also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C. -- Abstract: Spherical LiMnPO{sub 4}/C composite microparticles were prepared by a combination of spray pyrolysis and spray drying followed by heat treatment and examined as a cathode material for lithium batteries. The structure, morphology and electrochemical performance of the resulting spherical LiMnPO{sub 4}/C microparticles were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electronic microscopy and standard electrochemical techniques. The final sample was identified as a single phase orthorhombic structure of LiMnPO{sub 4} and spherical powders with a geometric mean diameter of 3.65 {mu}m and a geometric standard deviation of 1.34. The electrochemical cells contained the spherical LiMnPO{sub 4}/C microparticles exhibited first discharge capacities of 112 and 130 mAh g{sup -1} at 0.05 C at room temperature and 55 {sup o}C, respectively. These also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C.

  3. Electron scattering mechanisms in Cu-Mn films for interconnect applications

    SciTech Connect

    Misjk, F.; Nagy, K. H.; Radnczi, G.; Lobotka, P.

    2014-08-28

    Electrical properties and corresponding structural features of Cu-Mn alloy films with potential application as barrier and interconnect layers were studied. Cu-Mn films were deposited by DC magnetron sputtering at room temperature on SiO{sub 2} substrates. Electrical resistivity measurements were made as a function of film composition and temperature. The specific resistivity varies linearly with the Mn content showing a maximum of 205???cm at 80 at. % Mn. The temperature coefficient of resistance (TCR) of all alloy films is low, showing non-metallic conductivity for most compositions. Also a minimum TCR has been observed in the 4080 at. % Mn range which was attributed to a magnetic transformation around 200300?K. Electrical resistivity measurements are correlated with the film structure revealed by transmission electron microscopy to clarify the phase regions throughout the composition range. In the 2040 at. % and 7080 at. % Mn ranges, two-phase structures were identified, where Cu- or Mn-rich solid solution grains were surrounded by a thin amorphous covering layer. Based on the revealed phase regions and morphologies electron scattering mechanisms in the system were evaluated by combining the Matthiessen's rule and the Mayadas-Schatzkes theory. Grain boundary reflectivity coefficients (r?=?0.60.8) were calculated from fitting the model to the measurements. The proposed model indicates that, in a binary system, the special arrangement of the two phases results in new scattering mechanisms. The results are of value in optimizing the various parameters needed to produce a suitable barrier layer.

  4. Peculiarly strong room-temperature ferromagnetism from low Mn-doping in ZnO grown by molecular beam epitaxy

    SciTech Connect

    Zuo Zheng; Morshed, Muhammad; Liu Jianlin; Beyermann, W. P.; Zheng Jianguo; Xin Yan

    2013-03-15

    Strong room-temperature ferromagnetism is demonstrated in single crystalline Mn-doped ZnO thin films grown by molecular beam epitaxy. Very low Mn doping concentration is investigated, and the measured magnetic moment is much larger than what is expected for an isolated ion based on Hund's rules. The ferromagnetic behavior evolves with Mn concentration. Both magnetic anisotropy and anomalous Hall effect confirm the intrinsic nature of ferromagnetism. While the Mn dopant plays a crucial role, another entity in the system is needed to explain the observed large magnetic moments.

  5. Mn-Stabilized Zirconia: From Imitation Diamonds to a New Potential High-T{sub C} Ferromagnetic Spintronics Material

    SciTech Connect

    Ostanin, S.; Ernst, A.; Sandratskii, L. M.; Bruno, P.; Daene, M.; Hergert, W.; Mertig, I.; Hughes, I. D.; Staunton, J. B.; Kudrnovsky, J.

    2007-01-05

    From the basis of ab initio electronic structure calculations which include the effects of thermally excited magnetic fluctuations, we predict Mn-stabilized cubic zirconia to be ferromagnetic above 500 K. We find this material, which is well known both as an imitation diamond and as a catalyst, to be half-metallic with the majority and minority spin Mn impurity states lying in zirconia's wide gap. The Mn concentration can exceed 40%. The high-T{sub C} ferromagnetism is robust to oxygen vacancy defects and to how the Mn impurities are distributed on the Zr fcc sublattice. We propose this ceramic as a promising future spintronics material.

  6. Properties of Ga{sub 1-x}Mn{sub x}As with high x (>0.1)

    SciTech Connect

    Chiba, D.; Yu, K. M.; Walukiewicz, W.; Nishitani, Y.; Matsukura, F.; Ohno, H.

    2008-04-01

    We have investigated the magnetic and the crystalline properties of a set of Ga{sub 1-x}Mn{sub x}As layers with high nominal Mn compositions (x=0.101-0.198). Magnetization measurements and combined channeling Rutherford backscattering (c-RBS) and particle induced x-ray emission (c-PIXE) measurements have been performed to determine the effective Mn composition x{sub eff} and the fraction of Mn atoms at various lattice sites. Here, x{sub eff} determined from magnetization measurements, which increases with increasing x, is consistent with the results determined from c-RBS-PIXE measurements.

  7. Absorption and biological half-life in humans of intrinsic and extrinsic sup 54 Mn tracers from foods of plant origin

    SciTech Connect

    Johnson, P.E.; Lykken, G.I.; Korynta, E.D. )

    1991-05-01

    Absorption and biological half-life of {sup 54}Mn were measured in adult men and women fed foods labeled intrinsically or extrinsically with {sup 54}Mn. Each subject consumed a series of three test meals consisting of a food labeled intrinsically, a food labeled extrinsically or MnCl{sub 2} (control) served in random order. The foods tested were lettuce, spinach, wheat and sunflower seeds. Lettuce meals and their controls contained 9.65 mumol Mn; other meals contained 22.50 mumol Mn. In addition to the test food or MnCl{sub 2}, each meal consisted of vegetable oil (5 g), salt (NaCl, 0.15 g) and crackers (10 g), which provided 0.55 mumol Mn. There were no differences in percentage of Mn absorption or biological half-life of {sup 54}Mn for any of the intrinsically/extrinsically labeled food pairs. Absorption of {sup 54}Mn from MnCl{sub 2} (8.90%) was greater than from lettuce (5.20%), spinach (3.81%), wheat (2.16%) or sunflower seeds (1.71%), but the biological half-life did not vary with the source of Mn. Absorption of {sup 54}Mn from lettuce was significantly (P less than 0.05) greater than from wheat or sunflower seeds. Although the Mn dose in the test meal was less for lettuce than for the other foods, there was no difference in Mn absorption from MnCl{sub 2} between the subjects fed lettuce and subjects fed other foods. There was no correlation of either {sup 54}Mn absorption or biological half-life with whole blood or plasma Mn.

  8. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ∞} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4−x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1−x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect

    West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory; He, Jian; Hitchcock, Dale; Yan, Yonggao; Hwu, Shiou-Jyh

    2013-10-15

    Crystals of Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x∼0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x∼0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ∞} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1−x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4−x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1−x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1

  9. Disorder dependent half-metallicity in Mn{sub 2}CoSi inverse Heusler alloy

    SciTech Connect

    Singh, Mukhtiyar; Saini, Hardev S.; Thakur, Jyoti; Reshak, Ali H.; Kashyap, Manish K.

    2013-12-15

    Heusler alloys based thin-films often exhibit a degree of atomic disorder which leads to the lowering of spin polarization in spintronic devices. We present ab-initio calculations of atomic disorder effects on spin polarization and half-metallicity of Mn{sub 2}CoSi inverse Heusler alloy. The five types of disorder in Mn{sub 2}CoSi have been proposed and investigated in detail. The A2{sub a}-type and B2-type disorders destroy the half-metallicity whereas it sustains for all disorders concentrations in DO{sub 3a}- and A2{sub b}-type disorder and for smallest disorder concentration studied in DO{sub 3b}-type disorder. Lower formation energy/atom for A2{sub b}-type disorder than other four disorders in Mn{sub 2}CoSi advocates the stability of this disorder. The total magnetic moment shows a strong dependence on the disorder and the change in chemical environment. The 100% spin polarization even in the presence of disorders explicitly supports that these disorders shall not hinder the use of Mn{sub 2}CoSi inverse Heusler alloy in device applications. - Graphical abstract: Minority-spin gap (E{sub g↓}) and HM gap (E{sub sf}) as a function of concentrations of various possible disorder in Mn{sub 2}CoSi inverse Heusler alloy. The squares with solid line (black color)/dotted line (blue color)/dashed line (red color) reperesents E{sub g↓} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi and the spheres with solid line (black color)/dottedline (blue color)/dashed line (red color) represents E{sub sf} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi. - Highlights: • The DO{sub 3}- and A2-type disorders do not affect the half-metallicity in Mn{sub 2}CoSi. • The B2-type disorder solely destroys half-metallicity in Mn{sub 2}CoSi. • The A2-type disorder most probable to occur out of all three types. • The total spin magnetic moment strongly depends on the disorder concentrations.

  10. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-05-15

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak

  11. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-10-12

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident

  12. Novel Solar Energy Conversion Materials by Design of Mn(II) Oxides

    SciTech Connect

    Lany, S.; Peng, H.; Ndione, P.; Zakutayev, A.; Ginley, D. S.

    2013-01-01

    Solar energy conversion materials need to fulfill simultaneously a number of requirements in regard of their band-structure, optical properties, carrier transport, and doping. Despite their desirable chemical properties, e.g., for photo-electrocatalysis, transition-metal oxides usually do not have desirable semiconducting properties. Instead, oxides with open cation d-shells are typically Mott or charge-transfer insulators with notoriously poor transport properties, resulting from large effective electron/hole masses or from carrier self-trapping. Based on the notion that the electronic structure features (p-d interaction) supporting the p-type conductivity in d10 oxides like Cu2O and CuAlO2 occurs in a similar fashion also in the d5 (high-spin) oxides, we recently studied theoretically the band-structure and transport properties of the prototypical binary d5 oxides MnO and Fe2O3 [PRB 85, 201202(R)]. We found that MnO tends to self-trap holes by forming Mn+III, whereas Fe2O3 self-traps electrons by forming Fe+II. However, the self-trapping of holes is suppressed by when Mn is tetrahedrally coordinated, which suggests specific routes to design novel solar conversion materials by considering ternary Mn(II) oxides or oxide alloys. We are presenting theory, synthesis, and initial characterization for these novel energy materials.

  13. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    SciTech Connect

    Ohno, S.; Shimakura, H.; Tahara, S.; Okada, T.

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  14. Extended magnetic exchange interactions in the high-temperature ferromagnet MnBi

    DOE PAGES [OSTI]

    Christianson, Andrew D.; Hahn, Steven E.; Fishman, Randy Scott; Parker, David S.; McGuire, Michael A.; Sales, Brian C.; Lumsden, Mark D.; Williams, T. J.; Taylor, A. E.

    2016-05-09

    Here, the high-temperature ferromagnet MnBi continues to receive attention as a candidate to replace rare-earth-containing permanent magnets in applications above room temperature. This is due to a high Curie temperature, large magnetic moments, and a coercivity that increases with temperature. The synthesis of MnBi also allows for crystals that are free of interstitial Mn, enabling more direct access to the key interactions underlying the physical properties of binary Mn-based ferromagnets. In this work, we use inelastic neutron scattering to measure the spin waves of MnBi in order to characterize the magnetic exchange at low temperature. Consistent with the spin reorientationmore » that occurs below 140~K, we do not observe a spin gap in this system above our experimental resolution. A Heisenberg model was fit to the spin wave data in order to characterize the long-range nature of the exchange. It was found that interactions up to sixth nearest neighbor are required to fully parameterize the spin waves. Surprisingly, the nearest-neighbor term is antiferromagnetic, and the realization of a ferromagnetic ground state relies on the more numerous ferromagnetic terms beyond nearest neighbor, suggesting that the ferromagnetic ground state arises as a consequence of the long-ranged interactions in the system.« less

  15. High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy

    SciTech Connect

    Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

    2007-08-01

    The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

  16. Electronic structure and the origin of the Dzyaloshinskii-Moriya interaction in MnSi

    DOE PAGES [OSTI]

    Satpathy, S.; Shanavas, K. V.

    2016-05-02

    Here, the metallic helimagnet MnSi has been found to exhibit skyrmionic spin textures when subjected to magnetic fields at low temperatures. The Dzyaloshinskii-Moriya (DM) interaction plays a key role in stabilizing the skyrmion state. With the help of first-principles calculations, crystal field theory and a tight-binding model we study the electronic structure and the origin of the DM interaction in the B20 phase of MnSi. The strength ofmore » $$\\vec{D}$$ parameter is determined by the magnitude of the spin-orbit interaction and the degree of orbital mixing, induced by the symmetry-breaking distortions in the B20 phase. We find that, strong coupling between Mn-$d$ and Si-$p$ states lead to a mixed valence ground state $$|d^{7-x}p^{2+x}\\rangle$$ configuration. The experimental magnetic moment of $$0.4~\\mu_B$$ is consistent with the Coulomb-corrected DFT+$U$ calculations, which redistributes electrons between the majority and minority spin channels. We derive the magnetic interaction parameters $J$ and $$\\vec{D}$$ for Mn-Si-Mn superexchange paths using Moriya's theory assuming the interaction to be mediated by $e_g$ electrons near the Fermi level. Using parameters from our calculations, we get reasonable agreement with the observations.« less

  17. Synthesis, structures and magnetic properties of two 3D 3,4-pyridinedicarboxylate bridged manganese(II) coordination polymers incorporating 1D helical Mn(carboxylate){sub 2} chain or Mn{sub 3}(OH){sub 2} chain

    SciTech Connect

    Tong Mingliang . E-mail: cestml@zsu.edu.cn; Wang Jing; Hu Sheng

    2005-05-15

    The hydrothermal reactions of MnCl{sub 2}.4H{sub 2}O, 3,4-pyridinedicarboxylic acid (3,4-pydaH{sub 2}) and triethylamine in aqueous medium yield two 3D metal-organic hybrid materials, [Mn(3,4-pyda)] (1) and [Mn{sub 3}(OH){sub 2}(3,4-pyda){sub 2}(H{sub 2}O){sub 2}] (2), respectively. In both complexes, each 3,4-pyda acts as a pentadentate ligand to connect five Mn(II) atoms via the pyridyl group and the two {mu}{sub 2}-carboxylate groups (one in syn,anti-mode and one in syn-syn mode for 1 and both in syn,anti-mode for 2). Complex 1 possesses an interesting 3D coordination polymeric structure incorporating 1D helical Mn({mu}{sub 2}-carboxylate){sub 2} chain units, in which each Mn(II) atom is coordinated in less common square pyramidal geometry to four carboxylato oxygen atoms and one pyridyl nitrogen atom. Each 3,4-pyda links three helical Mn({mu}{sub 2}-carboxylate){sub 2} chains and each Mn({mu}{sub 2}-carboxylate){sub 2} chain is linked by other eight helical Mn({mu}{sub 2}-carboxylate){sub 2} chains via sharing 3,4-pyda bridges. Complex 2 is a 3D coordination network consisting of 1D Mn{sub 3}(OH){sub 2} chains and 3,4-pyda bridges. The repeating trimeric structural unit in the manganese(II) hydroxide chain consists of two edge-sharing symmetry-related manganese octahedra linked via {mu}{sub 3}-OH to a vertex of Mn{sub 2} octahedron. Each 3,4-pyda links three Mn{sub 3}(OH){sub 2} chains and each Mn{sub 3}(OH){sub 2} chain is linked by other six Mn{sub 3}(OH){sub 2} chains via 3,4-pyda bridges, resulting in a 3D coordination solid. Magnetic measurements reveal that a weak antiferromagnetic interaction between the Mn{sup II} ions occurs in complex 1 and a 3D magnetic ordering at about 7.0K in complex 2.

  18. Electronic structural and magnetic properties of Mn{sub 5}Ge{sub 3} clusters

    SciTech Connect

    Yuan, H. K.; Chen, H. Kuang, A. L.; Tian, C. L.; Wang, J. Z.

    2013-11-28

    Theoretical understanding of the stability, ferromagnetism, and spin polarization of Mn{sub 5}Ge{sub 3} clusters has been performed by using the density functional theory with generalized gradient approximation for exchange and correlation. The magnetic moments and magnetic anisotropy energy (MAE) have been calculated for both bulk and clusters, and the enhanced magnetic moment as well as the enlarged MAE have been identified in clusters. The most attractive achievement is that Mn{sub 5}Ge{sub 3} clusters show a fine half-metallic character with large energy scales. The present results may have important implications for potential applications of small Mn{sub 5}Ge{sub 3} clusters as both emerging spintronics and next-generation data-storage technologies.

  19. Theoretical study on the role of dynamics on the unusual magnetic properties in MnBi

    SciTech Connect

    Shanavas, K. V.; Parker, David; Singh, David J.

    2014-11-27

    Here we study the electronic structure and lattice dynamics in the ferromagnet MnBi using first-principles calculations and a tight-binding model. The band structure around the Fermi level is dominated by Bi-p states which are the primary contributors to the magnetic anisotropy energy in the low temperature structure. A tight-binding model consisting of Mn-d and Bi-p states is developed and the parameters are determined from first-principles calculations. Phonon dispersions and elastic moduli exhibit several interesting features. In conclusion, the results imply that the magnetic interaction with the crystal lattice in MnBi is considerably more complex than previously thought and in particular that there is a rich interplay between phonons and magnetism involving both magnetoelastic and magnetostrictive coupling.

  20. Pressure effect on hydrogen tunneling and vibrational spectrum in α-Mn

    DOE PAGES [OSTI]

    Kolesnikov, Alexander I; Podlesnyak, Andrey A; Sadykov, Ravil A.; Antonov, Vladimir E.; Kuzovnikov, Michael; Ehlers, Georg; Granroth, Garrett E

    2016-10-03

    Here in this paper, the pressure effect on the tunneling mode and vibrational spectra of hydrogen in α-MnH0.07 has been studied by inelastic neutron scattering. Applying hydrostatic pressure of up to 30 kbar is shown to shift both the hydrogen optical modes and the tunneling peak to higher energies. First-principles calculations show that the potential for hydrogen in α-Mn becomes overall steeper with increasing pressure. At the same time, the barrier height and its extent in the direction of tunneling decrease and the calculations predict significant changes of the dynamics of hydrogen in α-Mn at 100 kbar, when the estimatedmore » tunneling splitting of the hydrogen ground state exceeds the barrier height.« less

  1. Elasticity and magnetocaloric effect in MnFe4Si3

    DOE PAGES [OSTI]

    Herlitschke, Marcus; Klobes, B.; Sergueev, I.; Hering, Paul; Persson, Joerg; Hermann, Raphael P.

    2016-03-16

    The room temperature magnetocaloric material MnFe4Si3 was investigated with nuclear inelastic scattering (NIS) and resonant ultrasound spectroscopy (RUS) at different temperatures and applied magnetic fields in order to assess the infuence of the magnetic transition and the magnetocaloric effect on the lattice dynamics. The NIS data give access to phonons with energies above 3 meV, whereas RUS probes the elasticity of the material in the MHz frequency range and thus low energy, ~5 neV, phonon modes. A significant infuence of the magnetic transition on the lattice dynamics is observed only in the low energy region. Here, MnFe4Si3 and other compoundsmore » in the Mn5-xFexSi3 series were also investigated with vibrating sample magnetometry, resistivity measurements and Moessbauer spectroscopy in order to study the magnetic transitions and to complement the obtained results on the lattice dynamics.« less

  2. Theoretical study on the role of dynamics on the unusual magnetic properties in MnBi

    DOE PAGES [OSTI]

    Shanavas, K. V.; Parker, David; Singh, David J.

    2014-11-27

    Here we study the electronic structure and lattice dynamics in the ferromagnet MnBi using first-principles calculations and a tight-binding model. The band structure around the Fermi level is dominated by Bi-p states which are the primary contributors to the magnetic anisotropy energy in the low temperature structure. A tight-binding model consisting of Mn-d and Bi-p states is developed and the parameters are determined from first-principles calculations. Phonon dispersions and elastic moduli exhibit several interesting features. In conclusion, the results imply that the magnetic interaction with the crystal lattice in MnBi is considerably more complex than previously thought and in particularmore » that there is a rich interplay between phonons and magnetism involving both magnetoelastic and magnetostrictive coupling.« less

  3. Anomalous magnetic configuration of Mn{sub 2}NiAl ribbon and the role of hybridization in the martensitic transformation of Mn{sub 50}Ni{sub 50−x}Al{sub x} ribbons

    SciTech Connect

    Zhao, R. B.; Zhao, D. W.; Li, G. K.; Ma, L. E-mail: houdenglu@mail.hebtu.edu.cn; Zhen, C. M.; Hou, D. L. E-mail: houdenglu@mail.hebtu.edu.cn; Wang, W. H.; Liu, E. K.; Chen, J. L.; Wu, G. H.

    2014-12-08

    The magnetic configuration of Mn{sub 2}NiAl ribbon has been investigated. In contrast to Ni{sub 2}MnAl, the compound Mn{sub 2}NiAl with considerable disorder does exhibit ferromagnetism and, due to exchange interaction competition, both ferromagnetic and antiferromagnetic moment orientations can coexist between nearest neighbor Mn atoms. This is unexpected in Heusler alloys. Regarding the mechanism of the martensitic transformation in Mn{sub 50}Ni{sub 50−x}Al{sub x}, it is found that increasing the Al content results in an unusual change in the lattice constant, a decrease of the transformation entropy change, and enhancement of the calculated electron localization. These results indicate that the p-d covalent hybridization between Mn (or Ni) and Al atoms gradually increases at the expense of the d-d hybridization between Ni and Mn atoms. This leads to an increased stability of the austenite phase and a decrease of the martensitic transformation temperature. For 11 ≤ x ≤ 14, Mn{sub 50}Ni{sub 50−x}Al{sub x} ferromagnetic shape memory alloys are obtained.

  4. Storm-water characterization and lagoon sediment analysis, Grand Forks Air Force Base, North Dakota. Final report

    SciTech Connect

    Garland, J.G.; Vaughn, R.W.; Scott, P.T.

    1990-08-01

    Sampling was conducted in the wastewater treatment lagoons and stormwater runoff at Grand Forks AFB. The base was concerned about whether the unlined lagoons were creating a potential groundwater contamination problem and whether their stormwater runoff met North Dakota state stream standards. Lagoon sediment did not contain Extraction Procedure hazardous chemicals. Stormwater runoff exceeded state standards for boron, phosphates, and phenols and contained trace levels of methylene chloride. Characterization of lagoon influent showed it to be generally representative of domestic sewage, but also contained trace levels of boron, phenols, toluene, cyanide, chloroform, methylene chloride and ethyl benzene.

  5. Fabrication of (Mn,Co)3O4 Surface Coatings onto Alloy Substrates

    SciTech Connect

    Yang, Zhenguo; Xia, Guanguang; Li, Xiaohong S.; Singh, Prabhakar; Stevenson, Jeffry W.

    2007-04-30

    Ferritic stainless steels are promising candidates for IT-SOFC interconnect applications due to their low cost and resistance to oxidation at SOFC operating temperatures. However, several challenges remain, including long term electrical conductivity and surface stability under interconnect exposure conditions and chromia scale evaporation. One means of extending interconnect lifetime and improving performance is to apply a protective coating, such as (Mn,Co)3O4 spinel, to the cathode side of the interconnect. These coatings have proven effective in reducing scale growth kinetics and Cr volatility. This report describes several procedures developed at PNNL for fabricating (Mn,Co)3O4 spinel coatings onto ferritic stainless steels.

  6. Unoccupied electronic structure of Ni2MnGa ferromagnetic shape memory alloy

    DOE PAGES [OSTI]

    Maniraj, M.; D׳Souza, S. W.; Rai, Abhishek; Schlagel, D. L.; Lograsso, T. A.; Iowa State Univ., Ames, IA; Chakrabarti, Aparna; Barman, S. R.

    2015-08-20

    Momentum resolved inverse photoemission spectroscopy measurements show that the dispersion of the unoccupied bands of Ni2MnGa is significant in the austenite phase. Furthermore, in the martensite phase, it is markedly reduced, which is possibly related to the structural transition to an incommensurate modulated state in the martensite phase. Finally, based on the first principle calculations of the electronic structure of Ni–Mn–Ga, we show that the modification of the spectral shape with surface composition is related to change in the hybridization between the Mn 3d and Ni 3d-like states that dominate the unoccupied conduction band.

  7. Study of lattice dynamics in yttrium doped NdMnO{sub 3} using Raman spectroscopy

    SciTech Connect

    Yadav, Ruchika Elizabeth, Suja; Nair, Harikrishnan S.

    2014-04-24

    A systematic study of Raman spectra on Yttrium doped NdMnO{sub 3} polycrystalline samples was undertaken to understand the lattice dynamics in this compound. Raman active phonons were analyzed and the observed peak were assigned to elucidate various phonon modes in the range (200 - 800) cm{sup −1}. It was observed that at 325 cm{sup −1} phonon frequency shifts upward as much as upto 4 % with increase in Yttrium content. Lattice distortions manifest themselves by frequency shifts in both bending and tilt modes of MnO{sub 6} octahedra, resulting in increase of Raman band line-widths.

  8. Perpendicularly magnetized {tau}-MnAl (001) thin films epitaxied on GaAs

    SciTech Connect

    Nie, S. H.; Zhu, L. J.; Lu, J.; Pan, D.; Wang, H. L.; Yu, X. Z.; Xiao, J. X.; Zhao, J. H.

    2013-04-15

    Perpendicularly magnetized {tau}-MnAl films have been epitaxied on GaAs (001) by molecular-beam epitaxy. Crystalline quality and magnetic properties of the samples were strongly dependent on growth temperature. The highest coercivity of 10.7 kOe, saturation magnetization of 361.4 emu/cm{sup 3}, perpendicular magnetic anisotropy constant of 13.65 Merg/cm{sup 3}, and magnetic energy product of 4.44 MGOe were achieved. These tunable magnetic properties make MnAl films valuable as excellent and cost-effective alternative for not only high density perpendicular magnetic recording storage and spintronics devices but also permanent magnets.

  9. Study of structural and electronic properties of Mn{sub 3}O{sub 4}

    SciTech Connect

    Kaur, Ramandeep Maitra, Tulika Nautiyal, Tashi

    2014-04-24

    Using density functional theory calculations we have examined the structural and electronic properties of magnetic spinel Mn{sub 3}O{sub 4}. We have optimized the structure (both volume and c/a ratio) within GGA. Then Coulomb correlations are included in the calculations to study the electronic properties. We observe that both the band gap and magnetic moment increase with the increase in Coulomb correlation due to the increased Jahn-Teller splitting and localization of the single e{sub g} electron of Mn{sup 3+}.

  10. Antiferromagentic resonance detected by direct current voltages in MnF{sub 2}/Pt bilayers

    SciTech Connect

    Ross, Philipp; Schreier, Michael Lotze, Johannes; Huebl, Hans; Goennenwein, Sebastian T. B.; Gross, Rudolf

    2015-12-21

    We performed coplanar waveguide-based broadband ferromagnetic resonance experiments on the antiferromagnetic insulator MnF{sub 2}, while simultaneously recording the DC voltage arising in a thin platinum film deposited onto the MnF{sub 2}. The antiferromagnetic resonance is clearly reflected in both the transmission through the waveguide as well as the DC voltage in the Pt strip. The DC voltage remains largely unaffected by field reversal and thus presumably stems from microwave rectification and/or heating effects. However, we identify a small magnetic field orientation dependent contribution, compatible with antiferromagnetic spin pumping theory.

  11. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    SciTech Connect

    Nicholson, Don M; Odbadrakh, Khorgolkhuu; Shassere, Benjamin; Rios, Orlando; Hodges, Jason P; Ludtka, Gerard Michael; Porter, Wallace D; Safa-Sefat, Athena; Rusanu, Aurelian; Brown, Greg; Evans III, Boyd Mccutchen

    2014-01-01

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system are explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering method. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy are investigated using differential scanning calorimetry and superconducting quantum interference device. Experiments are performed at the Spallation Neutron Source at Oak Ridge National Laboratory to observe the structural and magnetic phase transformations.

  12. ,"International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)"

    Energy Information Administration (EIA) (indexed site)

    International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)",1,"Annual",2006 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016"

  13. Electron-hole asymmetry, Dirac fermions, and quantum magnetoresistance in BaMnBi2

    DOE PAGES [OSTI]

    Li, Lijun; Wang, Kefeng; Graf, D.; Wang, Limin; Wang, Aifeng; Petrovic, C.

    2016-03-28

    Here, we report two-dimensional quantum transport and Dirac fermions in BaMnBi2 single crystals. BaMnBi2 is a layered bad metal with highly anisotropic conductivity and magnetic order below 290 K. Magnetotransport properties, nonzero Berry phase, small cyclotron mass, and the first-principles band structure calculations indicate the presence of Dirac fermions in Bi square nets. Quantum oscillations in the Hall channel suggest the presence of both electron and hole pockets, whereas Dirac and parabolic states coexist at the Fermi level.

  14. MnO spin-wave dispersion curves from neutron powder diffraction

    SciTech Connect

    Goodwin, Andrew L.; Dove, Martin T.; Tucker, Matthew G.; Keen, David A.

    2007-02-15

    We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

  15. Structural transformations in Mn{sub 2}NiGa due to residual stress

    SciTech Connect

    Singh, Sanjay; Maniraj, M.; D'Souza, S. W.; Barman, S. R.; Ranjan, R.

    2010-02-22

    Powder x-ray diffraction study of Mn{sub 2}NiGa ferromagnetic shape memory alloy shows the existence of a 7M monoclinic modulated structure at room temperature (RT). The structure of Mn{sub 2}NiGa is found to be highly dependent on residual stress. For higher stress, the structure is tetragonal at RT, and for intermediate stress it is 7M monoclinic. However, only when the stress is considerably relaxed, the structure is cubic, as is expected at RT since the martensitic transition temperature is 230 K.

  16. Graphene in proximity to magnetic insulating LaMnO{sub 3}

    SciTech Connect

    Cheng, Guanghui; Wei, Laiming, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn; Cheng, Long; Liang, Haixing; Zhang, Xiaoqiang; Li, Hui [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yu, Guolin [Shanghai Institute of Technical Physics, Chinese Academy of Science, Shanghai 200083 (China); Zeng, Changgan, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); International Center for Quantum Design of Functional Materials (ICQD), HFNL, University of Science and Technology of China, Hefei, Anhui 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-09-29

    Proximity to functional substrates may enhance the coupling between the quantum degrees of freedom and thus develop nontrivial quantum effects in graphene. Here, we demonstrate the successful fabrication of graphene in proximity to atomically flat magnetic insulating LaMnO{sub 3} films. The insulating nature of the LaMnO{sub 3} films not only ensures the electronic transport only occur in the graphene layers but also allow them to serve as dielectric layers for gating. Transport measurements reveal anomalous behaviors, including asymmetrical longitudinal magnetoresistivity and nonlinear Hall effect. This work may pave a way toward the realization of intriguing quantum phases in graphene.

  17. Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films Title: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films The orbital two-channel Kondo effect displaying exotic non-Fermi liquid behaviour arises in the intricate scenario of two conduction electrons compensating a pseudo-spin-1/2 impurity of two-level system. Despite extensive efforts for several decades, no material system has been clearly identified to exhibit

  18. Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films Citation Details In-Document Search Title: Orbital two-channel Kondo effect in epitaxial ferromagnetic L10-MnAl films The orbital two-channel Kondo effect displaying exotic non-Fermi liquid behaviour arises in the intricate scenario of two conduction electrons compensating a pseudo-spin-1/2 impurity of two-level system. Despite extensive efforts for several decades, no material

  19. Enlarged Mn 3s splitting and room-temperature ferromagnetism in epitaxially grown oxygen doped Mn{sub 2}N{sub 0.86} films

    SciTech Connect

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2014-11-07

    Single-phase and oxygen doped Mn{sub 2}N{sub 0.86} thin films have been grown on MgO (111) by plasma-assisted molecular beam epitaxy. The films grow under tensile strain and, remarkably, they show ferromagnetic-like interactions at low temperature and ferromagnetic ordering agreed well with the Bloch-law T{sup 3/2} at room-temperature. We further demonstrate the enlarged Mn 3s splitting (6.46 eV) and its possible relation to the observed ferromagnetism. Our study not only provide a strategy for further theoretical work on oxygen doped manganese nitrides, but also shed promising light on utilizing its room-temperature FM property to fabricate spintronic devices.

  20. Enhanced performance of branched TiO{sub 2} nanorod based Mn-doped CdS and Mn-doped CdSe quantum dot-sensitized solar cell

    SciTech Connect

    Kim, Soo-Kyoung; Gopi, Chandu V. V. M.; Lee, Jae-Cheol; Kim, Hee-Je

    2015-04-28

    TiO{sub 2} branched nanostructures could be efficient as photoanodes for quantum dot-sensitized solar cells (QDSCs) due to their large surface area for QD deposition. In this study, Mn-doped CdS/Mn-doped CdSe deposited branched TiO{sub 2} nanorods were fabricated to enhance the photovoltaic performance of QDSCs. Mn doping in CdS and CdSe retards the recombination losses of electrons, while branched TiO{sub 2} nanorods facilitate effective electron transport and compensate for the low surface area of the nanorod structure. As a result, the charge-transfer resistance (R{sub CT}), electron lifetime (?{sub e}), and the amount of QD deposition were significantly improved with branched TiO{sub 2} nanorod based Mn-doped CdS/Mn-doped CdSe quantum dot-sensitized solar cell.

  1. Synthesis of MnO{sub 2}-graphene composites with enhanced supercapacitive performance via pulse electrodeposition under supergravity field

    SciTech Connect

    Liu, Tingting; Shao, Guangjie; Ji, Mingtong; Wang, Guiling

    2014-07-01

    A method of pulse electrodeposition under supergravity field was proposed to synthesize MnO{sub 2}-graphene composites. Supergravity is very efficient for promoting mass transfer and decreasing concentration polarization during the electrodeposition process. The synthesis was conducted on our homemade supergravity equipment. The strength of supergravity field depended on the rotating speed of the ring electrode. 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired when the rotating speed was 3000 rpm. Graphene nanosheets play as a role of conductive substrates for MnO{sub 2} growing. The composites are evaluated as electrode materials for supercapacitors. Electrochemical results show that the maximum specific capacitance of the MnO{sub 2}-graphene composite is 595.7 F g{sup ?1} at a current density of 0.5 A g{sup ?1}. In addition, the composite exhibits excellent cycle stability with no capacitance attenuation after 1000 cycles. The approach provides new ideas for developing supercapacitor electrode materials with high performance. - Graphical abstract: 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired at 3000 rpm. - Highlights: MnO{sub 2}-graphene composites were prepared by pulse electrodeposition under supergravity. 3D flower like MnO{sub 2} spheres are anchored on the graphene nanosheets. The MnO{sub 2}-graphene electrode exhibits a specific capacitance of 595.7 F g{sup ?1}.

  2. Photoelectron spectra and structure of the Mn{sub n}{sup −} anions (n = 2–16)

    SciTech Connect

    Gutsev, G. L. Weatherford, C. A.; Ramachandran, B. R.; Gutsev, L. G.; Zheng, W.-J.; Thomas, O. C.; Bowen, Kit H.

    2015-07-28

    Photoelectron spectra of the Mn{sub n}{sup −} anion clusters (n = 2–16) are obtained by anion photoelectron spectroscopy. The electronic and geometrical structures of the anions are computed using density functional theory with generalized gradient approximation and a basis set of triple-ζ quality. The electronic and geometrical structures of the neutral Mn{sub n} clusters have also been computed to estimate the adiabatic electron affinities. The average absolute difference between the computed and experimental vertical detachment energies of an extra electron is about 0.2 eV. Beginning with n = 6, all lowest total energy states of the Mn{sub n}{sup −} anions are ferrimagnetic with the spin multiplicities which do not exceed 8. The computed ionization energies of the neutral Mn{sub n} clusters are in good agreement with previously obtained experimental data. According to the results of our computations, the binding energies of Mn atoms are nearly independent on the cluster charge for n > 6 and possess prominent peaks at Mn{sub 13} and Mn{sub 13}{sup −} in the neutral and anionic series, respectively. The density of states obtained from the results of our computations for the Mn{sub n}{sup −} anion clusters show the metallic character of the anion electronic structures.

  3. Metallic behavior induced by potassium doping of the trigonal antiferromagnetic insulator EuMn2As2

    DOE PAGES [OSTI]

    Anand, V. K.; Johnston, D. C.

    2016-07-22

    Here, we report magnetic susceptibility χ, isothermal magnetization M, heat capacity Cp, and electrical resistivity ρ measurements on undoped EuMn2As2 and K-doped Eu0.96K0.04Mn2As2 and Eu0.93K0.07Mn2As2 single crystals with the trigonal CaAl2Si2-type structure as a function of temperature T and magnetic field H. EuMn2As2 has an insulating ground state with an activation energy of 52 meV and exhibits antiferromagnetic (AFM) ordering of the Eu+2 spins S=7/2 at TN1=15 K from Cp(T) and χ(T) data with a likely spin-reorientation transition at TN2=5.0 K. The Mn+2 3d5 spins-5/2 exhibit AFM ordering at TN=142 K from all three types of measurements. The M(H) isothermmore » and χ(T) data indicate that the Eu AFM structure is both noncollinear and noncoplanar. The AFM structure of the Mn spins is also unclear. A 4% substitution of K for Eu in Eu0.96K0.04Mn2As2 is sufficient to induce a metallic ground state. We found evidence for a difference in the AFM structure of the Eu moments in the metallic crystals from that of undoped EuMn2As2 versus both T and H. For metallic Eu0.96K0.04Mn2As2 and Eu0.93K0.07Mn2As2, an anomalous S-shape T dependence of ρ related to the Mn magnetism is found. Upon cooling from 200 K, ρ exhibits a strong negative curvature, reaches maximum positive slope at the Mn TN≈150 K, and then continues to decrease but more slowly below TN. Finally, this suggests that dynamic short-range AFM order of the Mn spins above the Mn TN strongly suppresses the resistivity, contrary to the conventional decrease of ρ that is only observed upon cooling below TN of an antiferromagnet.« less

  4. Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes

    SciTech Connect

    Chen Yong; Liu Chenguang; Liu Chang; Lu Gaoqing; Cheng Huiming

    2007-11-06

    Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

  5. Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel using Atom Probe Tomography

    SciTech Connect

    Pereloma, E. V.; Stohr, R A; Miller, Michael K; Ringer, S. P.

    2009-01-01

    We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe){sub 3}Ti and (Ni,Fe){sub 3}(Al,Mn) precipitates eventually form after isothermal aging for {approx}60 seconds. The morphology of the (Ni,Fe){sub 3}Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe){sub 3}(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe){sub 3}Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation.

  6. X-ray absorption spectroscopy of Mn doped ZnO thin films prepared by rf sputtering technique

    SciTech Connect

    Yadav, Ashok Kumar; Jha, S. N.; Bhattacharyya, D.; Haque, Sk Maidul; Shukla, Dinesh; Choudhary, Ram Janay

    2015-11-15

    A set of r.f. sputter deposited ZnO thin films prepared with different Mn doping concentrations have been characterised by Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Absorption Near Edge Spectroscopy (XANES) measurements at Zn, Mn and O K edges and at Mn L{sub 2,3} edges apart from long range structural characterisation by Grazing Incident X-ray Diffraction (GIXRD) technique. Magnetic measurements show room temperature ferromagnetism in samples with lower Mn doping which is however, gets destroyed at higher Mn doping concentration. The results of the magnetic measurements have been explained using the local structure information obtained from EXAFS and XANES measurements.

  7. Low frequency sonochemical synthesis of nanoporous amorphous manganese dioxide (MnO{sub 2}) and adsorption of remazol reactive dye

    SciTech Connect

    Hasan, Siti Zubaidah; Yusop, Muhammad Rahimi; Othman, Mohamed Rozali

    2015-09-25

    Nanoporous amorphous-MnO{sub 2} was synthesized by sonochemical process (sonication) on the solid manganese (II) acetate tetrahydrate (Mn(CH{sub 3}COO){sub 2}.4H{sub 2}O) in 0.1 M KMnO{sub 4}. The product was characterized by X-ray diffraction (XRD), morphology of the material was scanned by Field Emission Scanning Electron Microscopy (FE-SEM) and absorptions of MnO{sub 2} bonding was characterized by Fourier Transform Infra-Red Spectrometer (FT-IR). Remazol reactive dye or Red 3BS, was used in the adsorption study using nanoporous amorphous-MnO{sub 2}. In batch experiment, 10 ppm of Remazol reactive dye was used and experiment was carried out at room temperature. Adsorption of Remazol dye on 0.2g synthesized nanoporous amorphous-MnO{sub 2} showed 99 – 100% decolorization.

  8. Microstructures and Mechanical Properties of Compositionally Complex Co-free FeNiMnCr18 FCC Solid Solution Alloy

    SciTech Connect

    Wu, Zhenggang; Bei, Hongbin

    2015-01-01

    Recently,a structurally-simplebutcompositionally-complex FeNiCoMnCr highentropyalloywasfoundto haveexcellentmechanicalproperties(e.g.,highstrengthandductility).Tounderstandthepotentialof using highentropyalloysasstructuralmaterialsforadvancednuclearreactorandpowerplants,itis necessary tohaveathoroughunderstandingoftheirstructuralstabilityandmechanicalpropertiesde- gradation underneutronirradiation.ThisrequiresustodevelopasimilarmodelalloywithoutCobe- cause materialwithCowillmakepost-neutron-irradiationtestingdifficult duetotheproductionofthe 60Co radioisotope.Toachievethisgoal,aFCC-structuredsingle-phasealloywithacompositionof FeNiMnCr18 wassuccessfullydeveloped.Thisnear-equiatomicFeNiMnCr18 alloy hasgoodmalleability and itsmicrostructurecanbecontrolledbythermomechanicalprocessing.Byrollingandannealing,the as-cast elongated-grained-microstructureisreplacedbyhomogeneousequiaxedgrains.Themechanical properties (e.g.,strengthandductility)oftheFeNiMnCr18 alloy arecomparabletothoseoftheequiatomic FeNiCoMnCr highentropyalloy.Bothstrengthandductilityincreasewithdecreasingdeformation temperature,withthelargestdifferenceoccurringbetween293and77K.Extensivetwin-bandswhich are bundlesofnumerousindividualtwinsareobservedwhenitistensile-fracturedat77K.Notwin bands aredetectedbyEBSDformaterialsdeformedat293Kandhigher.Theunusualtemperature-de- pendencies ofUTSanduniformelongationcouldbecausedbythedevelopmentofthedensetwin substructure, twin-dislocationinteractionsandtheinteractionsbetweenprimaryandsecondarytwin- ning systemswhichresultinamicrostructurerefinement andhencecauseenhancedstrainhardening and postponednecking.

  9. MxMn8O16 (M = Ag or K) as promising cathode materials for secondary Mg based batteries: The role of the cation M

    DOE PAGES [OSTI]

    Huang, Jianping; Takeuchi, Esther S.; Altug S. Poyraz; Takeuchi, Kenneth J.; Marschilok, Amy C.

    2016-02-15

    Here, AgxMn8O16 (Ag-OMS-2) and KxMn8O16 (K-OMS-2) were investigated as high voltage cathode materials for Mg based batteries. Both MxMn8O16 materials delivered high initial capacities (>180 mA h g–1), and KxMn8O16 showed high cycle stability with a reversible capacity of >170 mA h g–1 after 20 cycles.

  10. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect

    Liu, Hao; Gao, G. Y. Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L.

    2014-01-21

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52 eV and the magnetic moment of 1.00 μ{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  11. Magnetochromic effect in multiferroic R In <mn>1mn> x Mn x O <mn>3mn> ( R = Tb , Dy)

    SciTech Connect

    Chen, P.; Holinsworth, B. S.; O'Neal, K. R.; Brinzari, T. V.; Mazumdar, D.; Topping, C. V.; Luo, X.; Cheong, S.-W.; Singleton, J.; McGill, S.; Musfeldt, J. L.

    2015-05-26

    We combined high field magnetization and magneto-optical spectroscopy to investigate spin-charge coupling in Mn-substituted rare-earth indium oxides of chemical formula RIn₁₋xMnxO₃ (R=Tb, Dy). The edge states, on-site Mn³⁺d to d excitations, and rare-earth f-manifold excitations all track the magnetization energy due to dominant Zeeman interactions. The field-induced modifications to the rare-earth excitations are quite large because spin-orbit coupling naturally mixes spin and charge, suggesting that the next logical step in the design strategy should be to bring spin-orbit coupling onto the trigonal bipyramidal chromophore site with a 4 or 5d center.

  12. Data collection for cooperative water resources modeling in the Lower Rio Grande Basin, Fort Quitman to the Gulf of Mexico.

    SciTech Connect

    Passell, Howard David; Pallachula, Kiran; Tidwell, Vincent Carroll; Villalobos, Joshua; Piccinni, Giovanni; Brainard, James Robert; Gerik, Thomas; Morrison, Wendy; Serrat-Capdevila, Aleix; Valdes, Juan; Sheng, Zhuping; Lovato, Rene; Guitron, Alberto; Ennis, Martha Lee; Aparicio, Javier; Newman, Gretchen Carr; Michelsen, Ari M.

    2004-10-01

    Water resource scarcity around the world is driving the need for the development of simulation models that can assist in water resources management. Transboundary water resources are receiving special attention because of the potential for conflict over scarce shared water resources. The Rio Grande/Rio Bravo along the U.S./Mexican border is an example of a scarce, transboundary water resource over which conflict has already begun. The data collection and modeling effort described in this report aims at developing methods for international collaboration, data collection, data integration and modeling for simulating geographically large and diverse international watersheds, with a special focus on the Rio Grande/Rio Bravo. This report describes the basin, and the data collected. This data collection effort was spatially aggregated across five reaches consisting of Fort Quitman to Presidio, the Rio Conchos, Presidio to Amistad Dam, Amistad Dam to Falcon Dam, and Falcon Dam to the Gulf of Mexico. This report represents a nine-month effort made in FY04, during which time the model was not completed.

  13. Residential and commercial space heating and cooling with possible greenhouse operation; Baca Grande development, San Luis Valley, Colorado. Final report

    SciTech Connect

    Goering, S.W.; Garing, K.L.; Coury, G.E.; Fritzler, E.A.

    1980-05-01

    A feasibility study was performed to evaluate the potential of multipurpose applications of moderate-temperature geothermal waters in the vicinity of the Baca Grande community development in the San Luis Valley, Colorado. The project resource assessment, based on a thorough review of existing data, indicates that a substantial resource likely exists in the Baca Grande region capable of supporting residential and light industrial activity. Engineering designs were developed for geothermal district heating systems for space heating and domestic hot water heating for residences, including a mobile home park, an existing motel, a greenhouse complex, and other small commercial uses such as aquaculture. In addition, a thorough institutional analysis of the study area was performed to highlight factors which might pose barriers to the ultimate commercial development of the resource. Finally, an environmental evaluation of the possible impacts of the proposed action was also performed. The feasibility evaluation indicates the economics of the residential areas are dependent on the continued rate of housing construction. If essentially complete development could occur over a 30-year period, the economics are favorable as compared to existing alternatives. For the commercial area, the economics are good as compared to existing conventional energy sources. This is especially true as related to proposed greenhouse operations. The institutional and environmental analyses indicates that no significant barriers to development are apparent.

  14. Final report of the decontamination and decommissioning of Building 39 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-07-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, is also the remedial action contractor. The soil beneath Building 39 was radiologically contaminated and the building was demolished in 1992. The soil area within the footprint of the building has been remediated in accordance with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  15. Final report of the decontamination and decommissioning of Building 6 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-07-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the domestic uranium procurement program funded by the U.S. Atomic Energy Commission. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, is also the remedial action contractor. Radiological contamination was identified in Building 6, and the building was demolished in 1992. The soil area within the footprint of the building has been remediated in accordance with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  16. Final report of the decontamination and decommissioning of Building 44 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-07-01

    The U.S. Department of Energy (DOE) Junction Projects Office (GJPO) occupies a 61.7 acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the Grand Junction Projects Office Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, is also the remedial action contractor. Building 44 was radiologically contaminated and the building was demolished in 1994. The soil area within the footprint of the building was not contaminated; it complies with the identified standards and the area can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  17. Final report of the decontamination and decommissioning of Building 1 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. Building 1 was found to be radiologically contaminated and was demolished in 1996. The soil beneath and adjacent to the building was remediated in accordance with identified standards and can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  18. Final report of the decontamination and decommission of Building 31 at the Grand Junction Projects Office Facility

    SciTech Connect

    Krabacher, J.E.

    1996-07-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the domestic uranium procurement program funded by the U.S. Atomic Energy Commission. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also was the remedial action contractor. Radiological contamination was identified in Building 31 and the building was demolished in 1992. The soil area within the footprint of the building has been remediated in accordance with the identified standards and the area can be released for unlimited exposure and unrestricted use. This area was addressed in the summary final report of the remediation of the exterior areas of the GJPO facility. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  19. Final report of the decontamination and decommissioning of Building 18 at the Grand Junction Projects Office Facility

    SciTech Connect

    Widdop, M.R.

    1996-08-01

    The U.S. Department of Energy (DOE) Grand Junction Projects Office (GJPO) occupies a 61.7-acre facility along the Gunnison River near Grand Junction, Colorado. This site was contaminated with uranium ore and mill tailings during uranium refining activities of the Manhattan Engineer District and during pilot milling experiments conducted for the U.S. Atomic Energy Commission`s domestic uranium procurement program. The DOE Defense Decontamination and Decommissioning Program established the GJPO Remedial Action Project to clean up and restore the facility lands, improvements, and the underlying aquifer. The site contractor for the facility, Rust Geotech, also is the remedial action contractor. The soil beneath Building 18 was found to be radiologically contaminated; the building was not contaminated. The soil was remediated in accordance with identified standards. Building 18 and the underlying soil can be released for unlimited exposure and unrestricted use. This document was prepared in response to a DOE request for an individual final report for each contaminated GJPO building.

  20. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

    SciTech Connect

    Kam, Kinson; Doeff, Marca M.

    2010-12-01

    Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

  1. On the structural defects in synthetic {gamma}-MnO{sub 2}s

    SciTech Connect

    Hill, L.I.; Verbaere, A. . E-mail: alain.verbaere@cnrs-imn.fr

    2004-12-01

    In the literature, the {gamma}-MnO{sub 2} structure is considered to be that of ramsdellite (R), in which two types of defects exist. The occurrence of a slab of pyrolusite (r) is named a De Wolff defect and random faults r in R give intergrowths of ramsdellite and pyrolusite, which account well for the global features of many experimental diffraction patterns. The other type of defect results from 'microtwinning', which allows the so-called {epsilon}-MnO{sub 2} to be put with {gamma}-MnO{sub 2} in the same classification. This paper discusses the previous models of defect and what could be the features of the 'microtwinning', giving for each possible model the corresponding expected features in reciprocal space. The results of a selected area electron diffraction study of rather well crystallized samples of {gamma}-MnO{sub 2} are presented. The splitting of particular diffraction spots and new diffuse intensity are interpreted as the first experimental evidence for 'microtwinning', and a model with orientation variants within microdomains embedded in a 'normal' structure is proposed, which is rather different from the previous hypotheses involving parallel twin planes and parallel twin boundaries.

  2. Redox Dynamics of Mixed Metal (Mn, Cr, and Fe) Ultrafine Particles

    SciTech Connect

    Nico, Peter S.; Kumfer, Benjamin M.; Kennedy, Ian M.; Anastasio, Cort

    2008-08-01

    The impact of particle composition on metal oxidation state, and on changes in oxidation state with simulated atmospheric aging, are investigated experimentally in flame-generated nanoparticles containing Mn, Cr, and Fe. The results demonstrate that the initial fraction of Cr(VI) within the particles decreases with increasing total metal concentration in the flame. In contrast, the initial Mn oxidation state was only partly controlled by metal loading, suggesting the importance of other factors. Two reaction pathways, one reductive and one oxidative, were found to be operating simultaneously during simulated atmospheric aging. The oxidative pathway depended upon the presence of simulated sunlight and O{sub 3}, whereas the reductive pathway occurred in the presence of simulated sunlight alone. The reductive pathway appears to be rapid but transient, allowing the oxidative pathway to dominate with longer aging times, i.e. greater than {approx}8 hours. The presence of Mn within the particles enhanced the importance of the oxidative pathway, leading to more net Cr oxidation during aging implying that Mn can mediate oxidation by removal of electrons from other particulate metals.

  3. CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice

    DOE PAGES [OSTI]

    McNally, D. E.; Simonson, J. W.; Kistner-Morris, J. J.; Smith, G. J.; Hassinger, J. E.; DeBeer-Schmidt, L.; Kolesnikov, A. I.; Zaliznyak, I.; Aronson, M. C.

    2015-05-22

    We present inelastic neutron scattering measurements of the antiferromagnetic insulator CaMn2Sb2:, which consists of corrugated honeycomb layers of Mn. The dispersion of magnetic excitations has been measured along the H and L directions in reciprocal space, with a maximum excitation energy of ≈ 24 meV. These excitations are well described by spin waves in a Heisenberg model, including first and second neighbor exchange interactions, J1 and J2, in the Mn plane and also an exchange interaction between planes. The determined ratio J2/J1 ≈ 1/6 suggests that CaMn2Sb2: is the first example of a compound that lies very close to themore » mean field tricritical point, known for the classical Heisenberg model on the honeycomb lattice, where the N´eel phase and two different spiral phases coexist. The magnitude of the determined exchange interactions reveal a mean field ordering temperature ≈ 4 times larger than the reported N´eel temperature TN = 85 K, suggesting significant frustration arising from proximity to the tricritical point.« less

  4. Modulation on Ni{sub 2}MnGa(001) surface

    SciTech Connect

    D'Souza, S. W.; Rai, Abhishek; Nayak, J.; Maniraj, M.; Dhaka, R. S.; Barman, S. R.; Schlagel, D. L.; Lograsso, T. A.

    2011-07-15

    We report periodic modulation on (001) surface of Ni2MnGa ferromagnetic shape memory alloy. For the stoichiometric surface, analysis of the low energy electron diffraction (LEED) spot profiles shows that the modulation is incommensurate. The modulation appears at 200 K, concomitant with the first order structural transition to the martensitic phase.

  5. Short- and long-range magnetic order in LaMnAsO

    DOE PAGES [OSTI]

    McGuire, Michael A.; Garlea, Vasile Ovidiu

    2016-02-02

    The magnetic properties of the layered oxypnictide LaMnAsO have been revisited using neutron scattering and magnetization measurements. The present measurements identify the Néel temperature TN = 360(1) K. Below TN the critical exponent describing the magnetic order parameter is β=0.33–0.35 , consistent with a three-dimensional Heisenberg model. Above this temperature, diffuse magnetic scattering indicative of short-range magnetic order is observed, and this scattering persists up to TSRO = 650(10) K. Morevoer, the magnetic susceptibility shows a weak anomaly at TSRO and no anomaly at TN. Analysis of the diffuse scattering data using a reverse Monte Carlo algorithm indicates that abovemore » TN nearly two-dimensional, short-range magnetic order is present with a correlation length of 9.3(3) Å within the Mn layers at 400 K. The inelastic scattering data reveal a spin gap of 3.5 meV in the long-range ordered state, and strong, low-energy (quasielastic) magnetic excitations emerging in the short-range ordered state. When we compared it with other related compounds correlates the distortion of the Mn coordination tetrahedra to the sign of the magnetic exchange along the layer-stacking direction, and suggests that short-range order above TN is a common feature in the magnetic behavior of layered Mn-based pnictides and oxypnictides.« less

  6. Electrodeposited nanostructured MnO{sub 2} for non-enzymatic hydrogen peroxide sensing

    SciTech Connect

    Saha, B. Jana, S. K.; Banerjee, S.

    2015-06-24

    Electrodeposited MnO{sub 2} nanostructure was synthesized on indium tin oxide coated glass electrode by cyclic voltammetry. The as obtained samples were subsequently characterized by atomic force microscopy and their electro-catalytic response towards hydrogen peroxide in alkaline medium of 0.1M NaOH was studied using cyclic voltammetry and amperometry.

  7. Ordering ferromagnetic In{sub 1?x}Mn{sub x}As quantum dots

    SciTech Connect

    Ferri, Fabio A.; Marega Jr, Euclydes; Kunets, Vasyl P.; Salamo, Gregory J.

    2013-12-04

    In this work, we present a method to order low temperature (LT) self-assembled ferromagnetic In{sub 1?x}Mn{sub x}As quantum dots (QDs) grown by molecular beam epitaxy (MBE). The ordered In{sub 1?x}Mn{sub x}As QDs were grown on top of a non-magnetic In{sub 0.4}Ga{sub 0.6}As/GaAs(100) QDs multi-layered structure. The modulation of the chemical potential, due to the stacking, provides a nucleation center for the LT In{sub 1?x}Mn{sub x}As QDs. For particular conditions, such as surface morphology and growth conditions, the In{sub 1?x}Mn{sub x}As QDs align along lines like chains. For comparison purposes, we also report the study of QDs grown on plain GaAs(100) substrates. Ferromagnetic behavior was observed for all structures at 2 K.

  8. A stochastically forced time delay solar dynamo model: Self-consistent recovery from a maunder-like grand minimum necessitates a mean-field alpha effect

    SciTech Connect

    Hazra, Soumitra; Nandy, Dibyendu; Passos, Dário E-mail: dariopassos@ist.utl.pt

    2014-07-01

    Fluctuations in the Sun's magnetic activity, including episodes of grand minima such as the Maunder minimum have important consequences for space and planetary environments. However, the underlying dynamics of such extreme fluctuations remain ill-understood. Here, we use a novel mathematical model based on stochastically forced, non-linear delay differential equations to study solar cycle fluctuations in which time delays capture the physics of magnetic flux transport between spatially segregated dynamo source regions in the solar interior. Using this model, we explicitly demonstrate that the Babcock-Leighton poloidal field source based on dispersal of tilted bipolar sunspot flux, alone, cannot recover the sunspot cycle from a grand minimum. We find that an additional poloidal field source effective on weak fields—e.g., the mean-field α effect driven by helical turbulence—is necessary for self-consistent recovery of the sunspot cycle from grand minima episodes.

  9. Identification of source contributions to visibility-reducing organic aerosols in the vicinity of Grand Canyon National Park. Interim final report

    SciTech Connect

    Mazurek, M.A.; Hallock, K.A.; Leach, M.; Mason-Jones, M.; Mason-Jones, H.; Salmon, L.G.; Winner, D.A.; Cass, G.R.

    1993-06-01

    Sulfates and carbonaceous aerosols are the largest contributors to the fine particle burden in the atmosphere near Grand Canyon National Park. While the effects of sulfate particles on visibility at the Grand Canyon has been extensively studied, much less is known about the nature and origin of the carbonaceous aerosols that are present. This disparity in understanding arises from at least two causes: aerosol carbon data for the region are less plentiful and many of the sources that could contribute to that organic aerosol are both diverse and not well characterized. The objective of this present study is to examine the origin of the carbonaceous aerosol at Grand Canyon National Park during the summer season based on molecular tracer techniques applied to source and ambient samples collected specifically for this purpose.

  10. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect

    Goetsch, Ryan J; Anand, V K; Johnston, David C

    2014-08-01

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=2429 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  11. Investigation of rifting processes in the Rio Grande Rift using data from an unusually large earthquake swarm. Final report, October 1, 1992--September 30, 1993

    SciTech Connect

    Sanford, A.; Balch, R. [New Mexico Institute of Mining and Technology, Socorro, NM (United States); Hartse, H.; House, L. [Los Alamos National Lab., NM (United States)

    1995-03-01

    Because the Rio Grande Rift is one of the best seismically instrumented rift zones in the world, studying its seismicity provides an exceptional opportunity to elucidate the active tectonic processes within continental rifts. Beginning on 29 November 1989, a 15 square km region near Bernardo, NM, produced the strongest and longest lasting sequence of earthquakes in the rift in 54 years. Our research focuses on the Bernardo swarm which occurred 40 km north of Socorro, New Mexico in the axial region of the central Rio Grande rift. Important characteristics concerning hypocenters, fault mechanisms, and seismogenic zones are discussed.

  12. Structural relationships between new carbide La{sub 14}Sn(MnC{sub 6}){sub 3} and fully ordered La{sub 11}(MnC{sub 6}){sub 3}

    SciTech Connect

    Zaikina, Julia V.; Zhou, Haidong; Latturner, Susan E.

    2010-12-15

    Crystals of the ternary La{sub 11}(MnC{sub 6}){sub 3} and new quaternary carbide La{sub 14}Sn(MnC{sub 6}){sub 3} phases were grown from La/Ni eutectic flux and their structures were determined by means of X-ray single crystal diffraction. La{sub 11}(MnC{sub 6}){sub 3} is a new superstructure variant of La{sub 3.67}MnC{sub 6} (previously reported disordered subcell: P6{sub 3}/m; a{sub 0}=8.806 A; c{sub 0}=5.329 A, Z=2). The superstructure (R3-bar ; a={radical}3a{sub 0}=15.2649(9) A; c=3c{sub 0}=16.013(1) A, Z=6; R{sub 1}=0.022) is realized by complete ordering of the La chains within the columns of face-sharing carbon octahedra, with alternating La-La distances leading to R-centering and enlargement of the unit cell. The structure of the quaternary carbide La{sub 14}Sn(MnC{sub 6}){sub 3} (P6-bar ; a=8.756(1) A; c=10.483(2) A, Z=1; R{sub 1}=0.026) is closely related to that of La{sub 11}(MnC{sub 6}){sub 3} with part of the MnC{sub 6} units replaced by Sn atoms. The structure and precise composition of La{sub 14}Sn(MnC{sub 6}){sub 3} can be derived from that of La{sub 11}(MnC{sub 6}){sub 3} by taking into account the extent of this substitution and variation in lanthanum siting in the chain of carbon octahedra. Band structure calculations indicate both phases are metallic; the La{sub 11}(MnC{sub 6}){sub 3} phase is stabilized by the ordering of La atoms which induces a pseudogap at E{sub F}. -- La{sub 11}(MnC{sub 6}){sub 3} with fully ordered superstructure and a new carbide La{sub 14}Sn(MnC{sub 6}){sub 3} were obtained from La/Ni eutectic flux. Display Omitted

  13. X-ray and Raman spectroscopic studies on Ru substituted LiMn{sub 2}O{sub 4}

    SciTech Connect

    Kalavathi, S.; Ravindran, T. R.; Sahu, P. Ch.; Kalaivani, D.

    2015-06-24

    Phase pure Ru substituted LiMn{sub 2}O{sub 4} charge frustrated spinel compounds have been synthesized. Ru substitution for Mn is possible only up to 7.5%. Powder diffraction measurements confirm sustenance of charge frustrated cubic phase with space group Fd3m upon substitution of Ru for Mn. An increase in lattice parameter has been observed indicating replacement of Mn as Ru{sup 3+} or Ru{sup 4+} rather than Ru{sup 5+}. Raman spectroscopic measurements show that the crystal structure is robust against an increase of laser power and the observed bands show an expected red shift. In the case of Ru substituted LiMn{sub 2}O{sub 4}, the A{sub 1g} symmetric stretching mode, the F{sup (1)}{sub 2g} and the F{sup (2)}{sub 2g} symmetric bending modes identified with the Mn-O octahedra show a red shift up to Ru 0.075 and at higher Ru concentrations, revert back to the frequency corresponding to the pristine LiMn{sub 2}O{sub 4}.

  14. The effects of annealing on the microstructure and mechanical properties of Fe28Ni18Mn33Al21

    DOE PAGES [OSTI]

    Meng, Fanling; Qiu, Jingwen; Baker, Ian; Bei, Hongbin

    2015-08-20

    In this paper, As-cast Fe28Ni18Mn33Al21, which consists of aligned, 50 nm, (Ni, Al)-rich B2, and (Fe, Mn)-rich f.c.c. phases, was annealed at a variety of temperatures up to 1423 K and the microstructure and mechanical properties were examined. It was shown that the as-cast microstructure arises from a eutectoid transformation at ~1300 K. Annealing at temperatures ≤1073 K produces β-Mn-structured precipitates and hardness values up to 816 HV, while annealing at temperatures >1073 K leads to dramatic coarsening of the two-phase B2/f.c.c. microstructure (up to 5.5 µm after 50 h at 1273 K), but does not lead to β-Mn precipitation.more » Interestingly, annealing at temperatures >1073 K delays the onset of β-Mn precipitation during subsequent anneals at lower temperatures. Coarsening the B2/f.c.c. lamellar structure by annealing at higher temperatures softens it and leads to increases in ductility from fracture before yield to ~8 % elongation. Finally, the presence of β-Mn precipitates makes the very fine, brittle B2/f.c.c. microstructures even more brittle, but significant ductility (8.4 % elongation) is possible even with β-Mn precipitates present if the B2/f.c.c. matrix is coarse and, hence, more ductile.« less

  15. First-principles study on the ferrimagnetic half-metallic Mn{sub 2}FeAs alloy

    SciTech Connect

    Qi, Santao; Zhang, Chuan-Hui; Chen, Bao; Shen, Jiang; Chen, Nanxian

    2015-05-15

    Mn-based full-Heusler alloys are kinds of promising candidates for new half-metallic materials. Basing on first principles, the electronic structures and magnetic properties of the Mn{sub 2}FeAs full-Heusler alloy have been investigated in detail. The Hg{sub 2}CuTi-type Mn{sub 2}FeAs compound obeys the Slater-Pauling rule, while the anti-parallel alignment atomic magnetic moments of Mn locating at different sites indicate it a ferrimagnetic alloy. The calculated spin-down bands behave half-metallic character, exhibiting a direct gap of 0.46 eV with a 100% spin polarization at the Fermi level. More studies show the compound would maintain half-metallic nature in a large range of variational lattice constants. We expect that our calculated results may trigger Mn{sub 2}FeAs applying in the future spintronics field. - Graphical abstract: The d orbitals of Mn and Fe atoms split into multi-degenerated levels which create new bonding and nonbonding states. These exchange splitting shift the Fermi level to origin band gap.▪ - Highlights: • The electronic structure and magnetic properties of Mn{sub 2}FeAs full-Heusler alloy were studied. • A total magnetic moment of 3μ{sub B} was obtained for Mn{sub 2}FeAs alloy, following the SP rule M{sub t}=Z{sub t}−24. • The origin of ferrimagnetism and half-metallic character in Mn{sub 2}FeAs were discussed.

  16. Structural and magnetic properties of magnetron sputtered Ni-Mn-Sn ferromagnetic shape memory alloy thin films

    SciTech Connect

    Vishnoi, Ritu; Kaur, Davinder

    2010-05-15

    In the present study, structural and magnetic properties of Mn-rich, off-stoichiometric, nanocrystalline Ni-Mn-Sn ferromagnetic shape memory alloy thin films, grown on Si (100) substrates at 550 deg. C by dc magnetron sputtering have been systematically investigated. The crystallization, surface morphology, and structural features were studied using x-ray diffraction, atomic force microscopy, and field emission scanning electron microscopy. The structural transition from austenite to martensite was observed with an increase of Mn content. Austenitic phase with mixed L2{sub 1}/A2+B2 structure has been observed at room temperature in Ni{sub 52.6}Mn{sub 23.7}Sn{sub 23.6} (S{sub 1}) and Ni{sub 51.5}Mn{sub 26.1}Sn{sub 22.2} (S{sub 2}) films, while those with composition of Ni{sub 58.9}Mn{sub 28.0}Sn{sub 13.0} (S{sub 3}) and Ni{sub 58.3}Mn{sub 29.0}Sn{sub 12.6} (S{sub 4}) show martensitic phase with 14M modulated monoclinic structures. Field induced martensite-austenite transformation has been observed in magnetization studies using superconducting quantum interference device magnetometer. Temperature dependent magnetization measurements demonstrate the influence of magnetic field on the structural phase transition temperature. The investigations reveal an increase of martensitic transformation temperature (T{sub M}) with corresponding increase in substitution of Mn. The films exhibit ferromagnetic behavior at low temperatures below Curie temperature (T{sub C}). The decrease in saturation moment with increasing Mn content, indicates the existence of antiferromagnetic correlations within ferromagnetic matrix.

  17. Facile and template-free preparation of {alpha}-MnO{sub 2} nanostructures and their enhanced adsorbability

    SciTech Connect

    Ma, Hongwei; Shen, Jianfeng; Shi, Min; Yan, Bo; Li, Na; Ye, Mingxin

    2011-09-15

    Graphical abstract: . The as-obtained ({alpha}-MnO{sub 2}) nanomaterials could act as an adsorbent to remove Conge red. More significantly, the nanomaterials are nontoxic and environmentally friendly though a biological MTT assay experiment. Plots of the capacity to remove Conge red with time by the commercial and new-prepared {alpha}-MnO{sub 2}. Inset shows absorption of Congo Red with time by new-prepared rod-clusters {alpha}-MnO{sub 2} (0, 10, 20, 40 and 60 min, respectively). Highlights: {yields} Nanostructured {alpha}-MnO{sub 2} was prepared through a template-free hydrothermal method. {yields} The obtained {alpha}-MnO{sub 2} could act as effective adsorbents to remove organic dyes. {yields} The obtained adsorbents are environmentally friendly. -- Abstract: In this paper, nanostructured MnO{sub 2} materials were successfully prepared through a simple and template-free hydrothermal method. X-ray diffraction pattern indicates that the as-prepared nanomaterials are {alpha}-MnO{sub 2}. Transmission Electron Microscopy and Scanning Electron Microscopy images demonstrate that nanostructured rod-clusters {alpha}-MnO{sub 2} could be evolved from the nanorods. Brunauer-Emmett-Teller (BET) surface area measurement was employed to characterize the surface property. Moreover, the as-obtained ({alpha}-MnO{sub 2}) nanomaterials could act as an efficient adsorbent to remove Congo Red and Methlylene Blue. More significantly, the nanomaterials are nontoxic and environmentally friendly via biological methylthiazolyldiphenyltetrazoliumbromide assay experiments. Its nontoxic and enhanced adsorbability properties guarantee their safe applications in environmental protection and industrial aspects.

  18. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE PAGES [OSTI]

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  19. Atomic moments in Mn{sub 2}CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect

    Jamer, M. E.; Assaf, B. A.; Heiman, D.; Sterbinsky, G. E.; Arena, D. A.

    2014-12-07

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn{sub 2}CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  20. Large enhancement of Blocking temperature by control of interfacial structures in Pt/NiFe/IrMn/MgO/Pt multilayers

    SciTech Connect

    Chen, Xi; Wang, Shouguo Han, Gang; Jiang, Shaolong; Yang, Kang; Liu, Qianqian; Yu, Guanghua; Liu, Jialong; Wang, Rongming

    2015-09-15

    The Blocking temperature (T{sub B}) of Pt/NiFe/IrMn/MgO/Pt multilayers was greatly enhanced from far below room temperature (RT) to above RT by inserting 1 nm thick Mg layer at IrMn/MgO interface. Furthermore, the exchange bias field (H{sub eb}) was increased as well by the control of interfacial structures. The evidence for a significant fraction of Mn-O bonding at IrMn/MgO interface without Mg insertion layer was provided by X-ray photoelectron spectroscopy. The bonding between Mn and O can decrease the antiferromagnetism of IrMn film, leading to lower value of T{sub B} in Pt/NiFe/IrMn/MgO/Pt multilayers. Ultrathin Mg film inserted at IrMn/MgO interface acting as an oxygen sinking layer can suppress the oxidation reactions between Mn and O and reduce the formation of Mn-O bonding greatly. The oxidation suppression results in the recovery of the antiferromagnetism of IrMn film, which can enhance T{sub B} and H{sub eb}. Furthermore, the high resolution transmission electron microscopy demonstrates that the Mg insertion layer can efficiently promote a high-quality MgO (200) texture. This study will enhance the understanding of physics in antiferromagnet-based spintronic devices.

  1. Grand Challenges of Advanced Computing for Energy Innovation Report from the Workshop Held July 31-August 2, 2012

    SciTech Connect

    Larzelere, Alex R.; Ashby, Steven F.; Christensen, Dana C.; Crawford, Dona L.; Khaleel, Mohammad A.; John, Grosh; Stults, B. Ray; Lee, Steven L.; Hammond, Steven W.; Grover, Benjamin T.; Neely, Rob; Dudney, Lee Ann; Goldstein, Noah C.; Wells, Jack; Peltz, Jim

    2013-03-06

    On July 31-August 2 of 2012, the U.S. Department of Energy (DOE) held a workshop entitled Grand Challenges of Advanced Computing for Energy Innovation. This workshop built on three earlier workshops that clearly identified the potential for the Department and its national laboratories to enable energy innovation. The specific goal of the workshop was to identify the key challenges that the nation must overcome to apply the full benefit of taxpayer-funded advanced computing technologies to U.S. energy innovation in the ways that the country produces, moves, stores, and uses energy. Perhaps more importantly, the workshop also developed a set of recommendations to help the Department overcome those challenges. These recommendations provide an action plan for what the Department can do in the coming years to improve the nation’s energy future.

  2. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H. E-mail: helene.bea@cea.fr; Baltz, V. E-mail: helene.bea@cea.fr

    2014-01-20

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  3. Visible Light-Induced Electron Transfer from Di-mu-oxo Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores

    SciTech Connect

    Frei, Heinz; Weare, Walter W.; Pushkar, Yulia; Yachandra, Vittal K.; Frei, Heinz

    2008-06-03

    The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. These findings will allow for the assembly and photochemical characterization of well defined transition metal molecular units, with the ultimate goal of performing endothermic, multi-electron transformations that are coupled to visible light electron pumps in nanostructured scaffolds.

  4. Structural distortion and band gap opening of hard MnB{sub 4} in comparison with CrB{sub 4} and FeB{sub 4}

    SciTech Connect

    Yang, Meng; Wang, Yachun; Yao, Jinlei; Li, Zhiping; Zhang, Jian; Wu, Lailei; Li, Hui; Zhang, Jingwu; Gou, Huiyang

    2014-05-01

    MnB{sub 4} was newly synthesized to crystallize in a monoclinic P2{sub 1}/c structure, different from previous experimental and theoretical reports. Here, based on first-principles calculations, we perform a comparative study of geometric and energetic features, mechanical behaviors, electronic property and chemical bonding of the experimentally identified monoclinic MnB{sub 4}, as well as orthorhombic CrB{sub 4} and FeB{sub 4}. The results demonstrate that the presence of distorted rhomboidal-B{sub 4} units and one-dimensional Mn chains in the monoclinic MnB{sub 4} breaks the structural symmetry and lowers the total energy in comparison to the orthorhombic phase. The opening of band gap in MnB{sub 4} is induced by Peierls-paired Mn atoms, differing from the metallic behaviors of recently studied tetraborides. Specifically, the preservations of covalent bonding in distorted boron-rhomboids in MnB{sub 4} explain the relatively higher incompressibility and hardness. - Graphical abstract: P2{sub 1}/c-type structure for MnB{sub 4} characterizes rhomboid-B{sub 4} units and alternately short and long Mn–Mn chains. - Highlights: • The novel P2{sub 1}/c-type MnB{sub 4} compound is studied by first-principles calculations. • P2{sub 1}/c-type MnB{sub 4} has lower total energy and relatively higher stability. • An energy gap opening is found for P2{sub 1}/c-type MnB{sub 4} induced by Mn atom pairs. • P2{sub 1}/c-type MnB{sub 4} exhibits excellent mechanical properties. • The mechanical properties of TcB{sub 4} and ReB{sub 4} in P2{sub 1}/c structure are also studied.

  5. DOE/EIS-0355 Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah, Final Environmental Impact Statement

    Office of Environmental Management (EM)

    Volumes IV Chapters 4 -5 Comment Responses U.S. Department of Energy Office of Environmental Management Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah Final Environmental Impact Statement i Contents Volume IV 4.0 Responses............................................................................................................................4-1 4.1 Response Index Tables

  6. Polychlorinated Biphenyls (PCBs) in Catfish and Carp Collected from the Rio Grande Upstream and Downstream of Los Alamos National Laboratory: Revision 1

    SciTech Connect

    Gilbert J. Gonzales Philip R. Fresquez

    2008-05-12

    Concern has existed for years that the Los Alamos National Laboratory (LANL), a complex of nuclear weapons research and support facilities, has released polychlorinated biphenyls (PCBs) to the environment that may have reached adjacent bodies of water through canyons that connect them. In 1997, LANL's Ecology Group began measuring PCBs in fish in the Rio Grande upstream and downstream of ephemeral streams that cross LANL and later began sampling fish in Abiquiu and Cochiti reservoirs, which are situated on the Rio Chama and Rio Grande upstream and downstream of LANL, respectively. In 2002, we electroshocked channel catfish (Ictalurus punctatus) and common carp (Carpiodes carpio) in the Rio Grande upstream and downstream of LANL and analyzed fillets for PCB congeners. We also sampled soils along the Rio Chama and Rio Grande drainages to discern whether a background atmospheric source of PCBs that could impact surface water adjacent to LANL might exist. Trace concentrations of PCBs measured in soil (mean = 4.7E-05 {micro}g/g-ww) appear to be from background global atmospheric sources, at least in part, because the bimodal distribution of low-chlorinated PCB congeners and mid-chlorinated PCB congeners in the soil samples is interpreted to be typical of volatilized PCB congeners that are found in the atmosphere and dust from global fallout. Upstream catfish (n = 5) contained statistically (P = 0.047) higher concentrations of total PCBs (mean = 2.80E-02 {micro}g/g-ww) than downstream catfish (n = 10) (mean = 1.50E-02 {micro}g/g-ww). Similarly, upstream carp (n = 4) contained higher concentrations of total PCBs (mean = 7.98E-02 {micro}g/g-ww) than downstream carp (n = 4) (3.07E-02 {micro}g/g-ww); however, the difference was not statistically significant (P = 0.42). The dominant PCB homologue in all fish samples was hexachlorobiphenyls. Total PCB concentrations in fish in 2002 are lower than 1997; however, differences in analytical methods and other uncertainties exist. A

  7. Influence of Mn concentration on magnetic topological insulator MnxBi2−xTe3 thin-film Hall-effect sensor

    SciTech Connect

    Ni, Y.; Zhang, Z.; Nlebedim, I. C.; Hadimani, R. L.; Jiles, D. C.

    2015-06-11

    Hall-effect (HE) sensors based on high-quality Mn-doped Bi2Te3 topological insulator (TI) thin films have been systematically studied in this paper. Improvement of Hall sensitivity is found after doping the magnetic element Mn into Bi2Te3. The sensors with low Mn concentrations, MnxBi2-xTe3, x = 0.01 and 0.08 show the linear behavior of Hall resistance with sensitivity about 5 Ω/T. And their Hall sensitivity shows weak dependence on temperature. For sensors with high Mn concentration (x = 0.23), the Hall resistance with respect to magnetic field shows a hysteretic behavior. Moreover, its sensitivity shows almost eight times as high as that of the HE sensors with low Mn concentration. The highest sensitivity can reach 43 Ω/T at very low magnetic field. This increase of Hall sensitivity is caused by the occurrence of anomalous HE (AHE) after ferromagnetic phase transition. Our work indicates that the magnetic-element-doped TIs with AHE are good candidates for HE sensors.

  8. Spintronic properties of Li1.5Mn0.5Z (Z=As, Sb) compounds in...

    Office of Scientific and Technical Information (OSTI)

    Publisher's Accepted Manuscript: Spintronic properties of Li1.5Mn0.5Z (ZAs, Sb) compounds in the Cu2Sb structure This content will become publicly available on January 26, 2017 ...

  9. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance

    DOE PAGES [OSTI]

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (β-MnO₂) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of β-MnO₂ powders as a function of electrical resistance in the range of RP = 10 - 80Ω were measured. Based on the data presented, we propose a model for the β-MnO₂ system in which nanometer-scale MnO₂ crystallites bond together through weak van der Waals forces to form larger conglomerates that span inmore » size from nanometer to micrometer scale.« less

  10. Electronic properties of Mn-phthalocyanine–C{sub 60} bulk heterojunctions: Combining photoemission and electron energy-loss spectroscopy

    SciTech Connect

    Roth, Friedrich; Lupulescu, Cosmin; Darlatt, Erik; Gottwald, Alexander; Eberhardt, Wolfgang

    2015-11-14

    The electronic properties of co-evaporated mixtures (blends) of manganese phthalocyanine and the fullerene C{sub 60} (MnPc:C{sub 60}) have been studied as a function of the concentration of the two constituents using two supplementary electron spectroscopic methods, photoemission spectroscopy (PES) and electron energy-loss spectroscopy (EELS) in transmission. Our PES measurements provide a detailed picture of the electronic structure measured with different excitation energies as well as different mixing ratios between MnPc and C{sub 60}. Besides a relative energy shift, the occupied electronic states of the two materials remain essentially unchanged. The observed energy level alignment is different compared to that of the related CuPc:C{sub 60} bulk heterojunction. Moreover, the results from our EELS investigations show that, despite the rather small interface interaction, the MnPc related electronic excitation spectrum changes significantly by admixing C{sub 60} to MnPc thin films.

  11. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance

    SciTech Connect

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (β-MnO₂) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of β-MnO₂ powders as a function of electrical resistance in the range of RP = 10 - 80Ω were measured. Based on the data presented, we propose a model for the β-MnO₂ system in which nanometer-scale MnO₂ crystallites bond together through weak van der Waals forces to form larger conglomerates that span in size from nanometer to micrometer scale.

  12. Post-Growth Annealing of Bridgman-grown CdZnTe and CdMnTe Crystals...

    Office of Scientific and Technical Information (OSTI)

    Nuclear Radiation Detectors Citation Details In-Document Search Title: Post-Growth Annealing of Bridgman-grown CdZnTe and CdMnTe Crystals for Room-temperature Nuclear ...

  13. Anti-site disorder and improved functionality of Mn?NiX (X = Al, Ga, In, Sn) inverse Heusler alloys

    SciTech Connect

    Paul, Souvik; Kundu, Ashis; Ghosh, Subhradip; Sanyal, Biplab

    2014-10-07

    Recent first-principles calculations have predicted Mn?NiX (X = Al, Ga, In, Sn) alloys to be magnetic shape memory alloys. Moreover, experiments on Mn?NiGa and Mn?NiSn suggest that the alloys deviate from the perfect inverse Heusler arrangement and that there is chemical disorder at the sublattices with tetrahedral symmetry. In this work, we investigate the effects of such chemical disorder on phase stabilities and magnetic properties using first-principles electronic structure methods. We find that except Mn?NiAl, all other alloys show signatures of martensitic transformations in presence of anti-site disorder at the sublattices with tetrahedral symmetry. This improves the possibilities of realizing martensitic transformations at relatively low fields and the possibilities of obtaining significantly large inverse magneto-caloric effects, in comparison to perfect inverse Heusler arrangement of atoms. We analyze the origin of such improvements in functional properties by investigating electronic structures and magnetic exchange interactions.

  14. Laser activation of ferromagnetism in hydrogenated Ga{sub 1-x}Mn{sub x}As

    SciTech Connect

    Farshchi, R.; Dubon, O. D.; Hwang, D. J.; Misra, N.; Grigoropoulos, C. P.; Ashby, P. D.

    2008-01-07

    We demonstrate the local depassivation of hydrogenated Ga{sub 1-x}Mn{sub x}As by pulsed-laser annealing. The controlled removal of Mn-H defect complexes, which form upon hydrogenation and render Mn acceptors inactive, is achieved by focused laser irradiation. As a result, regions of electrically and ferromagnetically active Ga{sub 1-x}Mn{sub x}As are formed within a nonactive, otherwise structurally identical film. The hydrogenated films subjected to blanket laser depassivation display a Curie temperature T{sub C} up to 60 K, or 60% of the T{sub C} of the as-grown films. These results demonstrate the direct laser writing of mesoscopic ferromagnetically active regions as a viable route for the realization of planar, nanoscale spintronic systems.

  15. Evaluating Born and Local Effective Charges in Nanoscale MnO

    SciTech Connect

    Sun, Qi; Xu, Xiaoshan; Baker, Sheila N; Christianson, Andrew D; Musfeldt, J. L.

    2011-01-01

    Phonons are exquisitely sensitive to finite-length scale effects in complex materials because they are intimately connected to charge, polarizability, and structure, and a quantitative analysis of their behavior can reveal microscopic aspects of chemical bonding. To investigate these effects in a model correlated oxide, we measured the infrared vibrational properties of 8-nm particles of MnO, compared the results with the analogous bulk material, and quantified the phonon confinement with a calculation of the Born effective charge. Our analysis reveals that the Born effective charge decreases by {approx}20%, compared to the bulk material. Moreover, this change impacts both ionicity and polarizability. Specifically, we find that MnO nanoparticles are {approx}12% less ionic than the corresponding bulk. This discovery is important for understanding finite-length scale effects in this simple binary oxide and the more complicated functional oxides that emanate from this parent compound.

  16. Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}

    SciTech Connect

    Sattibabu, Bhumireddi Bhatnagar, Anil K. Mohan, Dasari Das, Dibakar Sundararaman, Mahadevan; Siruguri, Vasudeva; Rayaprol, Sudhindra

    2014-04-24

    Structural and magnetic properties of polycrystalline Yb{sub 1−x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, χ{sub ac}(T), shows no signature of spin-glass behavior. χ”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

  17. What is the valence of Mn in Ga1-xMnxN?

    DOE PAGES [OSTI]

    Berlijn, Tom; Jarrell, Mark; Nelson, Ryky; Ku, Wei; Moreno, Juana

    2015-11-04

    Motivated by the potential high Curie temperature of Ga1-xMnxN, we investigate the controversial Mn valence in this diluted magnetic semiconductor. From a first-principles Wannier-function analysis of the high energy Hilbert space, we find unambiguously the Mn valence to be close to 2+(d5), but in a mixed spin configuration with average magnetic moments of 4µB. By integrating out high-energy degrees of freedom differently, we further demonstrate the feasibility of both effective d4 and d5 descriptions. These two descriptions offer simple pictures for local and extended properties of the system, and highlight the dual nature of its doped hole. Specifically, in themore » effective d5 description, we demonstrate novel physical effects absent in previous studies. Thus, our derivation highlights the richness of low-energy sectors in interacting many-body systems and the generic need for multiple effective descriptions.« less

  18. Magnetochromic effect in multiferroic R In 1 ₋ x Mn x O 3 ( R = Tb , Dy)

    DOE PAGES [OSTI]

    Chen, P.; Holinsworth, B. S.; O'Neal, K. R.; Brinzari, T. V.; Mazumdar, D.; Topping, C. V.; Luo, X.; Cheong, S.-W.; Singleton, J.; McGill, S.; et al

    2015-05-26

    We combined high field magnetization and magneto-optical spectroscopy to investigate spin-charge coupling in Mn-substituted rare-earth indium oxides of chemical formula RIn₁₋xMnxO₃ (R=Tb, Dy). The edge states, on-site Mn³⁺d to d excitations, and rare-earth f-manifold excitations all track the magnetization energy due to dominant Zeeman interactions. The field-induced modifications to the rare-earth excitations are quite large because spin-orbit coupling naturally mixes spin and charge, suggesting that the next logical step in the design strategy should be to bring spin-orbit coupling onto the trigonal bipyramidal chromophore site with a 4 or 5d center.

  19. Extrinsic anomalous Hall effect in epitaxial Mn{sub 4}N films

    SciTech Connect

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2015-01-19

    Anomalous Hall effect (AHE) in ferrimagnetic Mn{sub 4}N epitaxial films grown by molecular-beam epitaxy is investigated. The longitudinal conductivity σ{sub xx} is within the superclean regime, indicating Mn{sub 4}N is a highly conducting material. We further demonstrate that the AHE signal in 40-nm-thick films is mainly due to the extrinsic contributions based on the analysis fitted by ρ{sub AH}=a′ρ{sub xx0}+bρ{sub xx}{sup 2} and σ{sub AH}∝σ{sub xx}. Our study not only provide a strategy for further theoretical work on antiperovskite manganese nitrides but also shed promising light on utilizing their extrinsic AHE to fabricate spintronic devices.

  20. Magnetostructural phase transformations in Tb 1-x Mn 2

    SciTech Connect

    Zou, Junding; Paudyal, Durga; Liu, Jing; Mudryk, Yaroslav; Pecharsky, Vitalij K.; Gschneidner, Karl A.

    2015-01-16

    Magnetism and phase transformations in non-stoichiometric Tb1-xMn2 (x = 0.056, 0.039) have been studied as functions of temperature and magnetic field using magnetization, heat capacity, and X-ray powder diffraction measurements. Lowering the temperature, the compounds sequentially order ferrimagnetically and antiferromagnetically, and finally, exhibit spin reorientation transitions. Moreover, these structural distortions from room temperature cubic to low temperature rhombohedral structures occur at TN, and are accompanied by large volume changes reaching ~-1.27% and -1.42%, respectively. First principles electronic structure calculations confirm the phase transformation from the ferrimagnetic cubic structure to the antiferromagnetic rhombohedral structure in TbMn2.