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  1. Lead Hexacyanoferrate(II) Tetrahydrate: Crystal Structure, FTIR...

    Office of Scientific and Technical Information (OSTI)

    Lead Hexacyanoferrate(II) Tetrahydrate: Crystal Structure, FTIR Spectroscopy and Thermal Decomposition Studies Citation Details In-Document Search Title: Lead Hexacyanoferrate(II) ...

  2. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    stimulate the digestion of fat and protein and acts as a satiety agent, suppressing hunger and inhibiting food intake. Tripeptidyl peptidase II (TPP II) is known to partly...

  3. Finding

    Office of Legacy Management (LM)

    Finding of No Significant Impact Ground Water Compliance at the Grand Junction UMTRA Project Site (Climax Uranium Millsite) September 1999 U.S. Department of Energy Grand Junction ...

  4. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    of fat and protein and acts as a satiety agent, suppressing hunger and inhibiting food intake. Tripeptidyl peptidase II (TPP II) is known to partly regulate CCK-8 (a CCK with...

  5. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and...

  6. First Structural Steel Erected at NSLS-II

    ScienceCinema (OSTI)

    None

    2010-01-08

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  7. First Structural Steel Erected at NSLS-II

    SciTech Connect (OSTI)

    2009-09-14

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  8. STRUCTURE AND FEEDBACK IN 30 DORADUS. II. STRUCTURE AND CHEMICAL ABUNDANCES

    SciTech Connect (OSTI)

    Pellegrini, E. W.; Baldwin, J. A.; Ferland, G. J.

    2011-09-01

    We use our new optical-imaging and spectrophotometric survey of key diagnostic emission lines in 30 Doradus, together with CLOUDY photoionization models, to study the physical conditions and ionization mechanisms along over 4000 individual lines of sight at points spread across the face of the extended nebula, out to a projected radius 75 pc from R136 at the center of the ionizing cluster NGC 2070. We focus on the physical conditions, geometry, and importance of radiation pressure on a point-by-point basis, with the aim of setting observational constraints on important feedback processes. We find that the dynamics and large-scale structure of 30 Dor are set by a confined system of X-ray bubbles in rough pressure equilibrium with each other and with the confining molecular gas. Although the warm (10,000 K) gas is photoionized by the massive young stars in NGC 2070, the radiation pressure does not currently play a major role in shaping the overall structure. The completeness of our survey also allows us to create a composite spectrum of 30 Doradus, simulating the observable spectrum of a spatially unresolved, distant giant extragalactic H II region. We find that the highly simplified models used in the 'strong line' abundance technique do in fact reproduce our observed line strengths and deduced chemical abundances, in spite of the more than one order of magnitude range in the ionization parameter and density of the actual gas in 30 Dor.

  9. Structure of the ESCRT-II endosomal trafficking complex

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    February 2005 Structure of the ESCRT-II Endosomal Trafficking Complex Aitor Hierro 1 , Ji Sun 2 , Alexander S. Rusnak 2 , Jaewon Kim 1 , Gali Prag 1 , Scott D. Emr 2 & James H. Hurley 1 1 Laboratory of Molecular Biology, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, US Department of Health and Human Services, Bethesda, Maryland 20892-0580, USA 2 Department of Cellular and Molecular Medicine and Department of Chemistry and Biochemistry and

  10. Structure Learning and Statistical Estimation in Distribution Networks - Part II

    SciTech Connect (OSTI)

    Deka, Deepjyoti; Backhaus, Scott N.; Chertkov, Michael

    2015-02-13

    Limited placement of real-time monitoring devices in the distribution grid, recent trends notwithstanding, has prevented the easy implementation of demand-response and other smart grid applications. Part I of this paper discusses the problem of learning the operational structure of the grid from nodal voltage measurements. In this work (Part II), the learning of the operational radial structure is coupled with the problem of estimating nodal consumption statistics and inferring the line parameters in the grid. Based on a Linear-Coupled(LC) approximation of AC power flows equations, polynomial time algorithms are designed to identify the structure and estimate nodal load characteristics and/or line parameters in the grid using the available nodal voltage measurements. Then the structure learning algorithm is extended to cases with missing data, where available observations are limited to a fraction of the grid nodes. The efficacy of the presented algorithms are demonstrated through simulations on several distribution test cases.

  11. Proofreading RNA: Structure of RNA Polymerase II's Backtracked...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    of RNA Polymerase II's Backtracked State Print Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary...

  12. Microbial Lithotrophic Oxidation of Structural Fe(II) in Biotite...

    Office of Scientific and Technical Information (OSTI)

    of the growth yield of lithoautotrophic circumneutral-pH Fe(II)-oxidizing bacteria. ... Subject: 54 ENVIRONMENTAL SCIENCES; AQUIFERS; BACTERIA; BIOTITE; IRON; MICA; ...

  13. Synthesis and structural characterisation of iron(II) and copper(II) diphosphates containing flattened metal oxotetrahedra

    SciTech Connect (OSTI)

    Keates, Adam C.; Wang, Qianlong; Weller, Mark T.

    2014-02-15

    Single crystal and bulk polycrystalline forms of K{sub 2}MP{sub 2}O{sub 7} (M=Fe(II), Cu(II)) have been synthesised and their structures determined from single crystal X-ray diffraction data. Both compounds crystallize in the tetragonal system, space group P-42{sub 1}m. Their structures are formed from infinite sheets of linked oxopolyhedra of the stoichiometry [MP{sub 2}O{sub 7}]{sup 2?} with potassium cations situated between the layers. The MO{sub 4} tetrahedra share oxygen atoms with [P{sub 2}O{sub 7}]{sup 4?} diphosphate groups and the potassium ions have KO{sub 8} square prismatic geometry. In both compounds the M(II) centre has an unusual strongly flattened, tetrahedral coordination to oxygen, as a result of the JahnTeller (JT) effect for the high spin d{sup 6} Fe(II) and p-orbital mixing or a second order JT effect for d{sup 9} Cu(II) centres in four fold coordination. The uncommon transition metal ion environments found in these materials are reflected in their optical absorption spectra and magnetism data. - Graphical abstract: The structures of the tetragonal polymorphs of K{sub 2}MP{sub 2}O{sub 7}, M=Cu(II), Fe(II), consist of infinite sheets of stoichiometry [MP{sub 2}O{sub 7}]{sup 2?}, formed from linked pyrophosphate groups and MO{sub 4} tetrahedra, separated by potassium ions. In both compounds the unusual tetrahedral coordination of the M(II) centre is strongly flattened as a result of JahnTeller (JT) effects for high spin, d{sup 6} Fe(II) and p-orbital mixing and second-order JT effects for d{sup 9} Cu(II). Display Omitted - Highlights: Tetrahedral copper and iron(II) coordinated by oxygen. New layered phosphate structure. JahnTeller and d{sup 10} distorted coordinations.

  14. Local-global alignment for finding 3D similarities in protein structures

    DOE Patents [OSTI]

    Zemla, Adam T.

    2011-09-20

    A method of finding 3D similarities in protein structures of a first molecule and a second molecule. The method comprises providing preselected information regarding the first molecule and the second molecule. Comparing the first molecule and the second molecule using Longest Continuous Segments (LCS) analysis. Comparing the first molecule and the second molecule using Global Distance Test (GDT) analysis. Comparing the first molecule and the second molecule using Local Global Alignment Scoring function (LGA_S) analysis. Verifying constructed alignment and repeating the steps to find the regions of 3D similarities in protein structures.

  15. Why Basin And Range Systems Are Hard To Find Ii- Structural Model...

    Open Energy Information (Open El) [EERE & EIA]

    geothermal reservoir definition and development. Authors David D. Blackwell, Richard P. Smith, Al Waibel, Maria C. Richards and Patrick Stepp Published GRC, 2009 DOI Not Provided...

  16. Why Basin and Range Systems are Hard to Find II- Structural Model...

    Open Energy Information (Open El) [EERE & EIA]

    geothermal reservoir definition and development. Authors David D. Blackwell, Richard P. Smith, Al Waibel, Maria C. Richards and Patrick Stepp Conference GRC Annual Meeting; Reno,...

  17. Synthesis and Structural Flexibility of a Series of Copper(II...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Synthesis and Structural Flexibility of a Series of Copper(II) Azolate-Based Metal-Organic ... solvent molecules in the expanded framework 2 induced no change in the pore size, ...

  18. IBEX satellite finds ribbon-like structure at edge of heliosphere

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    IBEX satellite IBEX satellite finds ribbon-like structure at edge of heliosphere The NASA IBEX mission has sent back data that indicates a "noodle soup" of solar material has accumulated at the outer fringes of the heliosphere bubble. October 15, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma

  19. Crystal structure of the sweet-tasting protein thaumatin II at 1.27 A

    SciTech Connect (OSTI)

    Masuda, Tetsuya; Ohta, Keisuke; Tani, Fumito; Mikami, Bunzo; Kitabatake, Naofumi

    2011-07-08

    Highlights: {yields} X-ray crystallographic structure of sweet-tasting protein, thaumatin II, was determined at a resolution of 1.27 A. {yields} The overall structure of thaumatin II is similar to that of thaumatin I, but a slight shift of the C{alpha} atom of G96 in thaumatin II was observed. {yields} The side chain of two critical residues, 67 and 82, for sweetness was modeled in two alternative conformations. {yields} The flexibility and fluctuation of side chains at 67 and 82 seems to be suitable for interaction of thaumatin molecules with sweet receptors. -- Abstract: Thaumatin, an intensely sweet-tasting protein, elicits a sweet taste sensation at 50 nM. Here the X-ray crystallographic structure of one of its variants, thaumatin II, was determined at a resolution of 1.27 A. Overall structure of thaumatin II is similar to thaumatin I, but a slight shift of the C{alpha} atom of G96 in thaumatin II was observed. Furthermore, the side chain of residue 67 in thaumatin II is highly disordered. Since residue 67 is one of two residues critical to the sweetness of thaumatin, the present results suggested that the critical positive charges at positions 67 and 82 are disordered and the flexibility and fluctuation of these side chains would be suitable for interaction of thaumatin molecules with sweet receptors.

  20. Rational assembly of Pb(II)/Cd(II)/Mn(II) coordination polymers based on flexible V-shaped dicarboxylate ligand: Syntheses, helical structures and properties

    SciTech Connect (OSTI)

    Yang, Gao-Shan; Liu, Chong-Bo; Liu, Hong; Robbins, Julianne; Zhang, Z. John; Yin, Hong-Shan; Wen, Hui-Liang; Wang, Yu-Hua

    2015-05-15

    Six new coordination polymers, namely, [Pb(L)(H{sub 2}O)] (1), [Pb(L)(phen)] (2), [Pb{sub 2}(L){sub 2}(4,4′-bipy){sub 0.5}] (3), [Cd(L)(phen)] (4), [Cd(L)(4,4′-bipy)]·H{sub 2}O (5) and [Mn(L)(4,4′-bipy)]·H{sub 2}O (6) have been synthesized by the hydrothermal reaction of 2,2′-[hexafluoroisopropylidenebis(p-phenyleneoxy)]diacetic acid (H{sub 2}L) with Pb(II)/Cd(II)/Mn(II) in the presence of ancillary ligands 4,4′-bipyridine (4,4′-bipy) or 1,10-phenanthroline (phen). Complexes 1 and 4–6 exhibit 2-D structures, and complexes 2–3 display 3-D frameworks, of which L{sup 2−} ligands join metal ions to single-stranded helical chains of 1, 3–6 and double-stranded helical chains of 2. Complexes 2 and 3 also contain double-stranded Metal–O helices. Topology analysis reveals that complexes 1 and 4 both represent 4-connected sql net, 2 represents 6-connected pcu net, 3 exhibits a novel (3,12)-connected net, while 5 and 6 display (3,5)-connected gek1 net. The six complexes exhibit two kinds of inorganic–organic connectivities: I{sup 0}O{sup 2} for 1, 4–6, and I{sup 1}O{sup 2} for 2–3. The photoluminescent properties of 4–5 and the magnetic properties of 6 have been investigated. - Graphical abstract: Six new Pb(II)/Cd(II)/Mn(II) coordination polymers with helical structures based on flexible V-shaped dicarboxylate ligand have been synthesized and structurally characterized. Photoluminescent and magnetic properties have been investigated. - Highlights: • Six novel M(II) coordination polymers with 2,2′-[hexafluoroisopropylidenebis(p-phenyleneoxy)]diacetic acid and N-donor ligands. • Complexes 1–6 show diverse intriguing helical characters. • The luminescent properties of complexes 1–5 were investigated. • Complex 6 shows antiferromagnetic coupling.

  1. II

    Office of Legacy Management (LM)

    . : " + ; . .Z + II . ? 8 . " ~. . . . a a' .; ,. ?> , . ' . : . ., ! , Environmental i r .,' : % , ~ ~ 9 . / ; i.3. -\ ,- I - 'I ' , 2 " .r: 1; . . , ~ . ,&- c . . a , ,, .,I;< . .' , , ? $ ; 1- !'I' . '...~ - .. :, , .I Closure Report for CAU No. 416 1: ' . Project Shoal Area I:' c!';,: .. 7. .. , . ~ 1 I' ,. Controlled Copy No. UNCONTROLLED { -* .. 4'. . 1 " . .. *. *" '.. . . , , ,I +' , ,.f.' I , I" I ', ', ctk;' . , I , '. :C, , I: : , . p . ? .,; .

  2. Structure of the ESCRT-II Endosomal Trafficking Complex

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    A Hurley1 1 Laboratory of Molecular Biology, National Institute of Diabetes and ... The SSRL Structural Molecular Biology Program is supported by the Department of Energy, ...

  3. The Three-Dimensional Structural Basis of Type II Hyperprolinemia...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: OTHERNIH Country of Publication: United States Language: ENGLISH Subject: 08 HYDROGEN; ALDEHYDES; CHAINS; CONFORMATIONAL CHANGES; CRYSTAL STRUCTURE; DEFECTS; ENZYMES; ...

  4. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    these processes; however, the DNA cleavage chemistry used to resolve these altered DNA structures can also operate as a weak link that can be exploited to kill cells-in a good way. ...

  5. Syntheses, structures and photoelectric properties of a series of Cd(II)/Zn(II) coordination polymers and coordination supramolecules

    SciTech Connect (OSTI)

    Jin Jing; Han Xiao; Meng Qin; Li Dan; Chi Yuxian; Niu Shuyun

    2013-01-15

    Five Cd(II)/Zn(II) complexes [Cd(1,2-bdc)(pz){sub 2}(H{sub 2}O)]{sub n} (1), [Cd1Cd2(btec)(H{sub 2}O){sub 6}]{sub n} (2), [Cd(3,4-pdc) (H{sub 2}O)]{sub n} (3), [Zn(2,5-pdc)(H{sub 2}O){sub 4}]{center_dot}2H{sub 2}O (4) and {l_brace} [Zn(2,5-pdc)(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O{r_brace} {sub n} (5) (H{sub 2}bdc=1,2-benzenedicarboxylic acid, pz=pyrazole, H{sub 4}btec=1,2,4,5-benzenetetracarboxylic acid, H{sub 2}pdc=pyridine-dicarboxylic acid) were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, surface photovoltage spectroscopy, XRD, TG analysis, IR and UV-vis spectra and elemental analysis. Structural analyses show that complexes 1-3 are 1D, 2D and 3D Cd(II) coordination polymers, respectively. Complex 4 is a mononuclear Zn(II) complex. Complex 5 is a 3D Zn(II) coordination polymer. The surface photoelectric properties of complexes were investigated by SPS. The results indicate that all complexes exhibit photoelectric responses in the range of 300-600 nm, which reveals that they all possess certain photoelectric conversion properties. By the comparative analyses, it can be found that the species and coordination micro-environment of central metal ion, the species and property of ligands affect the intensity and scope of photoelectric response. - Graphical abstract: Five Cd(II)/Zn(II) complexes have been hydrothermally synthesized and characterized. The photoelectric properties were studied with SPS. The species and coordination micro-environment of central metal ion, the species and property of ligands all affect the photoelectric responses. Highlights: Black-Right-Pointing-Pointer Five Cd/Zn complexes have been synthesized and characterized. Black-Right-Pointing-Pointer The SPS results indicate they possess obvious photoelectric conversion property. Black-Right-Pointing-Pointer The species and coordination environment of central metal ion affect SPS. Black-Right-Pointing-Pointer The species and property of ligands affect SPS

  6. Weatherization Works II - Summary of Findings from the ARRA Period Evaluation of the U.S. Department of Energy's Weatherization Assistance Program

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    139 Weatherization Works II - Summary of Findings From the ARRA Period Evaluation of the U.S. Department of Energy's Weatherization Assistance Program Bruce Tonn David Carroll Erin Rose Beth Hawkins Scott Pigg Daniel Bausch Greg Dalhoff Michael Blasnik Joel Eisenberg Claire Cowan Brian Conlon July 2015 xiii EXECUTIVE SUMMARY In April 2009, the U.S. Department of Energy (DOE) tasked Oak Ridge National Laboratory (ORNL) with conducting an evaluation of DOE's low-income Weatherization Assistance

  7. II

    Office of Legacy Management (LM)

    II rr r e3 c LI c - r F L - I - c LI c F - 794f zL.28 ORNL/RASA-91/8 OAK RIDGE NATIONAL LABORATORY Results of the Radiological Survey at the New Betatron Building, Granite City Steel Facility, Granite City, Illinois (GSG002) M . E. Murray M . S. Uziel MANAGED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITED STATES DEPARTMENT DF ENERGY FILE f$Q"f ry$ 4 - This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of

  8. II

    Office of Legacy Management (LM)

    II c )3 c F r c L LI L rr c - r I P- c OAK RlDGE NATIONAL LABORATORY h U W -l\ &?ir;; ITi' m . 8 ORNL/RASA-92/l Results of the Radiological Survey at the Former Chapman Valve Manufacturing Company, Indian Orchard, Massachusetts (cIooo1) R. D. Foley M . S. Uziel MANAGED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITED STATES DEPARTMENT OF ENERGY ORNLJRASA-92/l /- HEALTH AND SAFETY RESEARCH DIVISION Environmental Restoration and Waste Management Non-Defense Programs (Activity No. EX 20

  9. Substrate Specificity and Structure of Human Aminoadipate Aminotransferase/kynurenine Aminotransferase II

    SciTech Connect (OSTI)

    Han,Q.; Cai, T.; Tagle, D.; Robinson, H.; Li, J.

    2008-01-01

    KAT (kynurenine aminotransferase) II is a primary enzyme in the brain for catalysing the transamination of kynurenine to KYNA (kynurenic acid). KYNA is the only known endogenous antagonist of the N-methyl-D-aspartate receptor. The enzyme also catalyses the transamination of aminoadipate to a-oxoadipate; therefore it was initially named AADAT (aminoadipate aminotransferase). As an endotoxin, aminoadipate influences various elements of glutamatergic neurotransmission and kills primary astrocytes in the brain. A number of studies dealing with the biochemical and functional characteristics of this enzyme exist in the literature, but a systematic assessment of KAT II addressing its substrate profile and kinetic properties has not been performed. The present study examines the biochemical and structural characterization of a human KAT II/AADAT. Substrate screening of human KAT II revealed that the enzyme has a very broad substrate specificity, is capable of catalysing the transamination of 16 out of 24 tested amino acids and could utilize all 16 tested a-oxo acids as amino-group acceptors. Kinetic analysis of human KAT II demonstrated its catalytic efficiency for individual amino-group donors and acceptors, providing information as to its preferred substrate affinity. Structural analysis of the human KAT II complex with a-oxoglutaric acid revealed a conformational change of an N-terminal fraction, residues 15-33, that is able to adapt to different substrate sizes, which provides a structural basis for its broad substrate specificity.

  10. Modeling direct interband tunneling. II. Lower-dimensional structures

    SciTech Connect (OSTI)

    Pan, Andrew; Chui, Chi On

    2014-08-07

    We investigate the applicability of the two-band Hamiltonian and the widely used Kane analytical formula to interband tunneling along unconfined directions in nanostructures. Through comparisons with kp and tight-binding calculations and quantum transport simulations, we find that the primary correction is the change in effective band gap. For both constant fields and realistic tunnel field-effect transistors, dimensionally consistent band gap scaling of the Kane formula allows analytical and numerical device simulations to approximate non-equilibrium Green's function current characteristics without arbitrary fitting. This allows efficient first-order calibration of semiclassical models for interband tunneling in nanodevices.

  11. Development of structure in shearing, viscous media. II

    SciTech Connect (OSTI)

    Hunter, J.H. Jr.; Horak, T.

    1983-02-01

    In this paper we present an approximate, algebraic method for determining when local, self-gravitating structures can develop in viscous, shearing media, such as disks that may be generated by computer simulation. The great advantage of the technique is that it does not require the numerical solution of the linear differential equation. This is particularly important in the present context, since the general local problem considered here is characterized by five independent parameters. We show that the vorticity modes can grow spectacularly in viscous disks. Indeed, in the presence of significant shear viscosity, the familiar density waves damp strongly and only vortices survive. Thus, the growth of structure in circumstellar disks and in the solar nebula may have proceeded along fundamentally different lines from those of the density enhancements in the disks of galaxies.

  12. Engineering characterization of ground motion. Task II. Effects of ground motion characteristics on structural response considering localized structural nonlinearities and soil-structure interaction effects. Volume 2

    SciTech Connect (OSTI)

    Kennedy, R.P.; Kincaid, R.H.; Short, S.A.

    1985-03-01

    This report presents the results of part of a two-task study on the engineering characterization of earthquake ground motion for nuclear power plant design. Task I of the study, which is presented in NUREG/CR-3805, Vol. 1, developed a basis for selecting design response spectra taking into account the characteristics of free-field ground motion found to be significant in causing structural damage. Task II incorporates additional considerations of effects of spatial variations of ground motions and soil-structure interaction on foundation motions and structural response. The results of Task II are presented in four parts: (1) effects of ground motion characteristics on structural response of a typical PWR reactor building with localized nonlinearities and soil-structure interaction effects; (2) empirical data on spatial variations of earthquake ground motion; (3) soil-structure interaction effects on structural response; and (4) summary of conclusions and recommendations based on Tasks I and II studies. This report presents the results of the first part of Task II. The results of the other parts will be presented in NUREG/CR-3805, Vols. 3 to 5.

  13. Synthesis and crystal structure of three mixed-ligand copper(II) complexes with nitrilotriacetic acid

    SciTech Connect (OSTI)

    Polyakova, I. N. Sergienko, V. S.; Poznyak, A. L.

    2006-05-15

    The synthesis and X-ray diffraction study of three Ca[CuX(Nta)] . 2H{sub 2}O complexes, where X = Cl (I) or Br (II and III are the monoclinic and orthorhombic modifications, respectively), are performed. Structures I-III are built of [CuX(Nta)]{sup 2-} anionic complexes and hydrated Ca{sup 2+} cations, which are linked by Ca-O bonds into a three-dimensional framework. In I-III, the coordination of the Cu atom includes the N atom and three O atoms of the tetradentate chelate Nta{sup 3-} ligand and the X{sup -} anion in the trans position with respect to N. The Cu-O bond lengths vary in the ranges 1.971-2.268 A in I, 1.958-2.289 A in II, and 2.040-2.110 A in III. The Cu-X bond lengths are 2.223, 2.364, and 2.354 A in I, II, and III, respectively. In I and II, the coordination polyhedron of the Cu atom is approximated by a distorted square pyramid with an O atom at the apical vertex, whereas in III, the polyhedron is described as a distorted trigonal bipyramid with the N and Br atoms at the axial sites. The structures are additionally stabilized by O(w)-H-O and O(w)-H-X hydrogen bonds.

  14. Excitonic transitions in highly efficient (GaIn)As/Ga(AsSb) type-II quantum-well structures

    SciTech Connect (OSTI)

    Gies, S.; Kruska, C.; Berger, C.; Hens, P.; Fuchs, C.; Rosemann, N. W.; Veletas, J.; Stolz, W.; Koch, S. W.; Heimbrodt, W.; Ruiz Perez, A.; Hader, J.; Moloney, J. V.

    2015-11-02

    The excitonic transitions of the type-II (GaIn)As/Ga(AsSb) gain medium of a “W”-laser structure are characterized experimentally by modulation spectroscopy and analyzed using microscopic quantum theory. On the basis of the very good agreement between the measured and calculated photoreflectivity, the type-I or type-II character of the observable excitonic transitions is identified. Whereas the energetically lowest three transitions exhibit type-II character, the subsequent energetically higher transitions possess type-I character with much stronger dipole moments. Despite the type-II character, the quantum-well structure exhibits a bright luminescence.

  15. Two coordination polymers of manganese(II) isophthalate and their preparation, structures, and magnetic properties

    SciTech Connect (OSTI)

    Chen Jinxi; Wang Jingjing; Ohba, Masaaki

    2012-01-15

    Two manganese coordination polymers, [Mn{sub 2}(ip){sub 2}(dmf)]{center_dot}dmf (1) and [Mn{sub 4}(ip){sub 4}(dmf){sub 6}]{center_dot}2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) A, b=12.193(3) A, c=12.576(3) A, {alpha}=62.19(2) Degree-Sign , {beta}=66.423(17) Degree-Sign , {gamma}=72.72(2) Degree-Sign , Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) A, b=20.20(2) A, c=18.01(3) A, {beta}=108.40(4) Degree-Sign , Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions. - Graphical abstract: Three-dimensional porous and two-dimensional layered manganese isophthalates have been prepared. Magnetic susceptibility measurements exhibit overall weak antiferromagnetic interactions between the Mn(II) ions in both compounds. Highlights: Black-Right-Pointing-Pointer Two manganese isophthalates have been prepared. Black-Right-Pointing-Pointer Compound 1 adopts a three-dimensional porous structure. Black-Right-Pointing-Pointer Compound 2 adopts a two-dimensional layered structure. Black-Right-Pointing-Pointer Magnetic properties of both compounds are investigated.

  16. Structure of the minor pseudopilin XcpW from the Pseudomonas aeruginosa type II secretion system

    SciTech Connect (OSTI)

    Franz, Laura P.; Douzi, Badreddine; Durand, Eric; Dyer, David H.; Voulhouxd, Rom; Forest, Katrina T.

    2012-01-13

    Pseudomonas aeruginosa utilizes the type II secretion machinery to transport virulence factors through the outer membrane into the extracellular space. Five proteins in the type II secretion system share sequence homology with pilin subunits of type IV pili and are called the pseudopilins. The major pseudopilin X{sub cp}T{sub G} assembles into an intraperiplasmic pilus and is thought to act in a piston-like manner to push substrates through an outer membrane secretin. The other four minor pseudopilins, X{sub cp}U{sub H}, X{sub cp}V{sub I}, X{sub cp}W{sub J} and X{sub cp}X{sub K}, play less well defined roles in pseudopilus formation. It was recently discovered that these four minor pseudopilins form a quaternary complex that is presumed to initiate the formation of the pseudopilus and to localize to its tip. Here, the structure of X{sub cp}W{sub J} was refined to 1.85 {angstrom} resolution. The structure revealed the type IVa pilin fold with an embellished variable antiparallel {beta}-sheet as also found in the X{sub cp}W{sub J} homologue enterotoxigenic Escherichia coli G{sub sp}J{sub W} and the X{sub cp}U{sub H} homologue Vibrio cholerae E{sub ps}U{sub H}. It is proposed that the exposed surface of this sheet may cradle the long N-terminal 1 helix of another pseudopilin. The final 31 amino acids of the X{sub cp}W{sub J} structure are instrinsically disordered. Deletion of this unstructured region of X{sub cp}W{sub J} did not prevent type II secretion in vivo.

  17. Campylobacter jejuni fatty acid synthase II: Structural and functional analysis of [beta]-hydroxyacyl-ACP dehydratase (FabZ)

    SciTech Connect (OSTI)

    Kirkpatrick, Andrew S.; Yokoyama, Takeshi; Choi, Kyoung-Jae; Yeo, Hye-Jeong

    2009-08-14

    Fatty acid biosynthesis is crucial for all living cells. In contrast to higher organisms, bacteria use a type II fatty acid synthase (FAS II) composed of a series of individual proteins, making FAS II enzymes excellent targets for antibiotics discovery. The {beta}-hydroxyacyl-ACP dehydratase (FabZ) catalyzes an essential step in the FAS II pathway. Here, we report the structure of Campylobacter jejuni FabZ (CjFabZ), showing a hexamer both in crystals and solution, with each protomer adopting the characteristic hot dog fold. Together with biochemical analysis of CjFabZ, we define the first functional FAS II enzyme from this pathogen, and provide a framework for investigation on roles of FAS II in C. jejuni virulence

  18. Crystal structure and magnetic properties of NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl

    SciTech Connect (OSTI)

    Jin Tengteng; Liu Wei; Chen Shuang; Prots, Yurii; Schnelle, Walter; Zhao Jingtai; Kniep, Ruediger; Hoffmann, Stefan

    2012-08-15

    A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Single-crystal X-ray diffraction data show that the title compound crystallizes in the monoclinic system, space group P2{sub 1}/c (No. 14), with lattice parameters a=8.392(2) A, b=6.3960(10) A, c=16.670(2) A, {beta}=109.470(10) Degree-Sign , V=843.6(3) A{sup 3}, Z=4. The crystal structure is characterized by a complex chain of copper-centered polyhedra running along [0 1 0] which are connected by phosphate tetrahedra. The resulting three-dimensional polyhedra framework exhibits channels filled by additional copper and sodium atoms. Field and temperature dependent measurements of the specific heat and the magnetic susceptibility reveal low-dimensional magnetic behavior. The compound starts to decompose at 700 K under release of oxygen and evaporation of Cu{sup I}Cl as shown by simultaneous thermogravimetry and mass spectrometry. - Graphical abstract: The crystal structure of the new copper(II) phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], exhibits linear chains of copper tetrahedra which show low-dimensional magnetic behavior proven by specific heat and magnetic susceptibility measurements. Highlights: Black-Right-Pointing-Pointer A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Black-Right-Pointing-Pointer The crystal structure comprises chains of Cu{sub 4}O tetrahedra. Black-Right-Pointing-Pointer Low-dimensional behavior has been proven by magnetic and specific heat measurements. Black-Right-Pointing-Pointer On heating, Cu{sup I}Cl and oxygen are released shown by simultaneous thermogravimetry and mass spectrometry.

  19. Neutron structure of human carbonic anhydrase II in complex with methazolamide: mapping the solvent and hydrogen-bonding patterns of an effective clinical drug

    DOE PAGES-Beta [OSTI]

    Aggarwal, Mayank; Kovalevsky, Andrey Y.; Velazquez, Hector; Fisher, S. Zoë; Smith, Jeremy C.; McKenna, Robert

    2016-07-22

    Carbonic anhydrases (CAs; EC 4.2.1.1) catalyze the interconversion of CO 2 and HCO 3 − , and their inhibitors have long been used as diuretics and as a therapeutic treatment for many disorders such as glaucoma and epilepsy. Acetazolamide (AZM) and methazolamide (MZM, a methyl derivative of AZM) are two of the classical CA inhibitory drugs that have been used clinically for decades. The jointly refined X-ray/neutron structure of MZM in complex with human CA isoform II (hCA II) has been determined to a resolution of 2.2 Å with an R cryst of ∼16.0%. Presented in this article, along withmore » only the second neutron structure of a clinical drug-bound hCA, is an in-depth structural comparison and analyses of differences in hydrogen-bonding network, water-molecule orientation and solvent displacement that take place upon the binding of AZM and MZM in the active site of hCA II. Even though MZM is slightly more hydrophobic and displaces more waters than AZM, the overall binding affinity ( K i ) for both of the drugs against hCA II is similar (∼10 n M ). The plausible reasons behind this finding have also been discussed using molecular dynamics and X-ray crystal structures of hCA II–MZM determined at cryotemperature and room temperature. This study not only allows a direct comparison of the hydrogen bonding, protonation states and solvent orientation/displacement of AZM and MZM, but also shows the significant effect that the methyl derivative has on the solvent organization in the hCA II active site.« less

  20. Nuclear Shell Structure and Beta Decay I. Odd A Nuclei II. Even A Nuclei

    DOE R&D Accomplishments [OSTI]

    Mayer, M.G.; Moszkowski, S.A.; Nordheim, L.W.

    1951-05-01

    In Part I a systematics is given of all transitions for odd A nuclei for which sufficiently reliable data are available. The allowed or forbidden characters of the transitions are correlated with the positions of the initial and final odd nucleon groups in the nuclear shell scheme. The nuclear shells show definite characteristics with respect to parity of the ground states. The latter is the same as the one obtained from known spins and magnetic moments in a one-particle interpretation. In Part II a systematics of the beta transitions of even-A nuclei is given. An interpretation of the character of the transitions in terms of nuclear shell structure is achieved on the hypothesis that the odd nucleon groups have the same structure as in odd-A nuclei, together with a simple coupling rule between the neutron and proton groups in odd-odd nuclei.

  1. Two interpenetrating Cu{sup II}/Ni{sup II}-coordinated polymers based on an unsymmetrical bifunctional N/O-tectonic: Syntheses, structures and magnetic properties

    SciTech Connect (OSTI)

    Liu, Yong-Liang; Wu, Ya-Pan; Li, Dong-Sheng; Dong, Wen-Wen; Zhou, Chun-Sheng

    2015-03-15

    Two new interpenetrating Cu{sup II}/Ni{sup II} coordination polymers, based on a unsymmetrical bifunctional N/O-tectonic 3-(pyrid-4′-yl)-5-(4″-carbonylphenyl)-1,2,4-triazolyl (H{sub 2}pycz), ([Cu-(Hpycz){sub 2}]·2H{sub 2}O){sub n} (1) and ([Ni(Hpycz){sub 2}]·H{sub 2}O){sub n} (2), have been solvothermally synthesized and structure characterization. Single crystal X-ray analysis indicates that compound 1 shows 2-fold parallel interpenetrated 4{sup 4}-sql layers with the same handedness. The overall structure of 1 is achiral—in each layer of doubly interpenetrating nets, the two individual nets have the opposite handedness to the corresponding nets in the adjoining layers—while 2 features a rare 8-fold interpenetrating 6{sup 6}-dia network that belongs to class IIIa interpenetration. In addition, compounds 1 and 2 both show similar paramagnetic characteristic properties. - Graphical abstract: Two new Cu(II)/Ni(II) coordination polymers present 2D parallel 2-fold interpenetrated 4{sup 4}-sql layers and a rare 3D 8-fold interpenetrating 6{sup 6}-dia network. In addition, magnetic susceptibility measurements show similar paramagnetic characteristic for two complexes. - Highlights: • A new unsymmetrical bifunctional N/O-tectonic as 4-connected spacer. • A 2-fold parallel interpenetrated sql layer with the same handedness. • A rare 8-fold interpenetrating dia network (class IIIa)

  2. FINDING η CAR ANALOGS IN NEARBY GALAXIES USING Spitzer. II. IDENTIFICATION OF AN EMERGING CLASS OF EXTRAGALACTIC SELF-OBSCURED STARS

    SciTech Connect (OSTI)

    Khan, Rubab; Kochanek, C. S.; Stanek, K. Z.; Gerke, Jill

    2015-02-01

    Understanding the late-stage evolution of the most massive stars such as η Carinae is challenging because no true analogs of η Car have been clearly identified in the Milky Way or other galaxies. In Khan et al., we utilized Spitzer IRAC images of 7 nearby (≲ 4 Mpc) galaxies to search for such analogs, and found 34 candidates with flat or red mid-IR spectral energy distributions. Here, in Paper II, we present our characterization of these candidates using multi-wavelength data from the optical through the far-IR. Our search detected no true analogs of η Car, which implies an eruption rate that is a fraction 0.01 ≲ F ≲ 0.19 of the core-collapse supernova (ccSN) rate. This is roughly consistent with each M {sub ZAMS} ≳ 70 M {sub ☉} star undergoing one or two outbursts in its lifetime. However, we do identify a significant population of 18 lower luminosity (log (L/L {sub ☉}) ≅ 5.5-6.0) dusty stars. Stars enter this phase at a rate that is a fraction 0.09 ≲ F ≲ 0.55 of the ccSN rate, and this is consistent with all 25 < M {sub ZAMS} < 60 M {sub ☉} stars undergoing an obscured phase at most lasting a few thousand years once or twice. These phases constitute a negligible fraction of post-main-sequence lifetimes of massive stars, which implies that these events are likely to be associated with special periods in the evolution of the stars. The mass of the obscuring material is of order ∼M {sub ☉}, and we simply do not find enough heavily obscured stars for theses phases to represent more than a modest fraction (∼10% not ∼50%) of the total mass lost by these stars. In the long term, the sources that we identified will be prime candidates for detailed physical analysis with the James Webb Space Telescope.

  3. Synthesis and crystal structure of catena-bis(nicotinamide)aqua({mu}-phthalato)copper(II) hemihydrate

    SciTech Connect (OSTI)

    Sadikov, G. G.; Koksharova, T. V.; Antsyshkina, A. S.; Gritsenko, I. S.; Sergienko, V. S.

    2008-07-15

    The copper(II) phthalate complex with nicotinamide [CuL{sub 2}({mu}-Pht)(H{sub 2}O)] . 0.5H{sub 2}O(I) (where L is nicotinamide and Pht{sup 2-} is an anion of phthalic acid) is synthesized and investigated using IR spectroscopy and X-ray diffraction. The crystals of compound I are monoclinic, a = 13.368(2) A, b = 7.891(3) A, c = 20.480(2) A, {beta} = 108.69(2){sup o}, Z = 4, and space group P2{sub 1}/c. The structural units of crystal I are linear chains formed by bridging phthalate anions and crystallization water molecules. The copper atom is coordinated by two pyridine nitrogen atoms of two nicotinamide ligands (Cu-N, 2.001 and 2.045 A), two oxygen atoms of different phthalate anions (Cu-O, 1.964 and 2.235 A), and the oxygen atom of the H{sub 2} O molecule (Cu-O, 2.014 A). The coordination polyhedron of the copper atom is completed to an elongated (4 + 1 + 1) tetragonal bipyramid by the second (chelating) oxygen atom of the carboxyl group (Cu-O, 2.587 A), which is one of the anions of phthalic acid. The linear polymer molecules are joined into complex macromolecular dimers with the closest internal contacts of the specific type. The macromolecular dimers are the main supramolecular ensembles of the crystal structure.

  4. Synthesis, structures, and properties of three Zn(II), Mn(II), and Cd(II) compounds based on tetrazole-1-acetic ligand

    SciTech Connect (OSTI)

    Liu, Dong-Sheng Chen, Wen-Tong; Xu, Ya-Ping; Shen, Ping; Hu, Shao-Jun; Sui, Yan

    2015-03-15

    Three new compounds, ([Zn(tza){sub 2}(H{sub 2}O)]·H{sub 2}O){sub n} (1), ([Mn(tza){sub 2}(Htza){sub 2}]·2H{sub 2}O){sub n} (2) and [Cd(tza){sub 2}]{sub n} (3), were obtained by reactions of 1H-Tetrazole-1-acetic (Htza) with corresponding metal salts, and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction, respectively. The X-ray diffraction analysis reveals that compound 1 is three-dimensional (3D) supramolecular structure with line chains. Compound 2 is three-dimensional (3D) supramolecular structure with Mn-carboxylate chains. Compound 3 is a 3D framework with (3,6)-connected ‘ant’ topological network. Furthermore, the photoluminescence of 1 and 3 and the magnetic properties of 2 have also been investigated. - Graphical abstract: Three new Zn/Mn/Cd compounds were obtained by reactions of Htza with corresponding metal salts, and characterized by chemical methods. Different linear chains result in different final structures. Compounds 1 and 2 are 3D supramolecular structures. Compound 3 is a 3D framework with (3,6)-connected ‘ant’ topological network. - Highlights: • Three new Zn/Mn/Cd compounds based on Htza ligand has been synthesized. • Different linear chains result in different final structures. • The fluorescence or magnetic properties have been investigated.

  5. Cadmium(II) and Copper(II) coordination polymers based on 5-(Pyrazinyl) tetrazolate ligand: Structure, photoluminescence, theoretical calculations and magnetism

    SciTech Connect (OSTI)

    Chen, Hui-Fen; Yang, Wen-Bin; Lin, Lang; Guo, Xiang-Guang; Dui, Xue-jing; Wu, Xiao-Yuan; Lu, Can-Zhong; Zhang, Cui-Juan

    2013-05-01

    Two μ₂-tetrazolyl bridged metal complexes, ([CdI(PTZ)(H₂O)]·H₂O)ₙ1 and ([Cu(PTZ)₂]·H₂O)ₙ2 (HPTZ=5-(pyrazinyl) tetrazolate), were hydrothermally synthesized and fully characterized by X-ray crystallography, elemental analyses and spectrum techniques. In 1, cadmium ions are bridged by tridentate μ₂-κ²N2,N5:κ¹N1 chelating PTZ⁻ ligand and halide linkers into an infinite 1D chain, while in 2 copper ions are connected by tridentate μ₂-κ²N7,N12:κ¹N8 and bidentate μ₂-κ¹N1:κ¹N2 chelating-bridging PTZ⁻ ligands to form a 1D castellated chain structure. Compound 1 displays phosphorescence with a lifetime of ~7.74 ms in the visible region, and the origin of the luminescent emission is primary assigned to the combination of ligand-centered emission, metal-to-ligand charge transfer and ligand-to-ligand charge transfer, which has been probed by the density of states (DOS) calculations. Magnetic measurement reveals that compound 2 displays an anti-ferromagnetic ordering. - Graphical abstract: Two new complexes based on 5-(pyrazinyl) tertrazolate, namely ([CdI(PTZ)(H2O)]·H2O)n and ([Cu(PTZ)2]·H2O)n have been synthesized and characterized. Compound 1 exhibits interesting green luminescence. Compound 2 displays an anti-ferromagnetic ordering. Highlights: • We report two novel 1D μ₂-tetrazolyl bridged Cd(II) and Cu(II) compounds. • The cadmium(II) compound exhibits a green luminescence. • Theoretical calculations were conducted to elucidate the green luminescence. • The Cu(II) compound exhibits an anti-ferromagnetic ordering.

  6. Structural oxidation state studies of the manganese cluster in the oxygen evolving complex of photosystem II

    SciTech Connect (OSTI)

    Liang, W.

    1994-11-01

    X-ray absorption spectroscopy (XAS) was performed on Photosystem II (PSII)-enriched membranes prepared from spinach to explore: (1) the correlation between structure and magnetic spin state of the Mn cluster in the oxygen evolving complex (OEC) in the S{sub 2} state; and (2) the oxidation state changes of the Mn cluster in the flash-induced S-states. The structure of the Mn cluster in the S{sub 2} state with the g{approx}4 electron paramagnetic resonance (EPR) signal (S{sub 2}-g4 state) was compared with that in the S{sub 2} state with multiline signal (S{sub 2}-MLS state) and the S{sub 1} state. The S{sub 2}-g4 state has a higher XAS inflection point energy than that of the S{sub 1} state, indicating the oxidation of Mn in the advance from the S{sub 1} to the S{sub 2}-g4 state. Differences in the edge shape and in the extended X-ray absorption fine structure (EXAFS) show that the structure of the Mn cluster in the S{sub 2}-g4 state is different from that in the S{sub 2}-MLS or the S{sub 1} state. In the S{sub 2}-g4 state, the second shell of backscatterers from the Mn absorber contains two Mn-Mn distances of 2.73 {angstrom} and 2.85 {angstrom}. Very little distance disorder exists in the second shell of the S{sub 1} or S{sub 2}-MLS states. The third shell of the S{sub 2}-g4 state at about 3.3 {angstrom} also contains increased heterogeneity relative to that of the S{sub 2}-MLS or the S{sub 1} state. Various S-states were prepared at room-temperature by saturating, single-turnover flashes. The flash-dependent oscillation in the amplitude of the MLS was used to characterize the S-state composition and to construct {open_quotes}pure{close_quotes} S-state Mn K-edge spectra. The edge position shifts to higher energy by 1.8 eV upon the S{sub 1} {yields} S{sub 2} transition.

  7. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  8. Cu{sup II} coordination polymers based on 5-methoxyisophthalate and flexible N-donor ligands: Structures and magnetic properties

    SciTech Connect (OSTI)

    Chang, Xin-Hong; Qin, Jian-Hua; Ma, Lu-Fang; Wang, Li-Ya

    2014-04-01

    Three Cu{sup II} coordination polymers, ([Cu{sub 2}(CH{sub 3}O-ip){sub 2}(bmib)]){sub n} (1), ([Cu{sub 2}(CH{sub 3}O-ip){sub 2}(bmib){sub 2}]){sub n} (2) and ([Cu(CH{sub 3}O-ip)(bbip)]∙2H{sub 2}O){sub n} (3) (CH{sub 3}O-H{sub 2}ip is 5-methoxyisophthalic acid, bmib is 1,4-bis(2-methylimidazol-1-yl)butane and bbip is 1,3-bis(1H-benzimidazolyl)propane), have been synthesized by hydrothermal methods. Complexes 1–3 were structurally characterized by elemental analysis, infrared (IR) spectra and X-ray single-crystal diffraction. Complex 1 shows a 3D six-connected self-penetrating network based on paddlewheel secondary building units. Complex 2 has a 3-fold interpenetrating 3D diamond framework. Complex 3 possesses a 1D tube-like chain. Thermo-gravimetric and magnetic properties of 1–3 were also investigated. - Graphical abstract: Structures and magnetic properties of copper(II) coordination polymers constructed from 5-methoxyisophthalate linker and two flexible N-donor ancillary ligands. Three copper(II) coordination polymers with 5-methoxyisophthalate and two related flexible N-donor ancillary ligands have been synthesized and structurally characterized. Moreover, thermal behaviors and magnetic properties of these complexes have also been investigated. - Highlights: • Three Cu(II) coordination polymers were synthesized. • The conformations of N-donor ligands and pH value have an effect on the final structures. • The magnetic properties of 1–3 have been investigated.

  9. Photosystem II

    ScienceCinema (OSTI)

    James Barber

    2016-07-12

    James Barber, Ernst Chain Professor of Biochemistry at Imperial College, London, gives a BSA Distinguished Lecture titled, "The Structure and Function of Photosystem II: The Water-Splitting Enzyme of Photosynthesis."

  10. Now on display: a gallery of group II intron structures at different...

    Office of Scientific and Technical Information (OSTI)

    DOI: 10.11861759-8753-4-14 Select the DOI to obtain a copy of this journal article from the publisher. Find in Google Scholar Find in Google Scholar Search WorldCat Search ...

  11. High resolution structures of the bone morphogenetic protein type II receptor in two crystal forms: Implications for ligand binding

    SciTech Connect (OSTI)

    Mace, Peter D.; Cutfield, John F.; Cutfield, Sue M. . E-mail: sue.cutfield@otago.ac.nz

    2006-12-29

    BMPRII is a type II TGF-{beta} serine threonine kinase receptor which is integral to the bone morphogenetic protein (BMP) signalling pathway. It is known to bind BMP and growth differentiation factor (GDF) ligands, and has overlapping ligand specificity with the activin type II receptor, ActRII. In contrast to activin and TGF-{beta} type ligands, BMPs bind to type II receptors with lower affinity than type I receptors. Crystals of the BMPRII ectodomain were grown in two different forms, both of which diffracted to high resolution. The tetragonal form exhibited some disorder, whereas the entire polypeptide was seen in the orthorhombic form. The two structures retain the basic three-finger toxin fold of other TGF-{beta} receptor ectodomains, and share the main hydrophobic patch used by ActRII to bind various ligands. However, they present different conformations of the A-loop at the periphery of the proposed ligand-binding interface, in conjunction with rearrangement of a disulfide bridge within the loop. This particular disulfide (Cys94-Cys117) is only present in BMPRII and activin receptors, suggesting that it is important for their likely shared mode of binding. Evidence is presented that the two crystal forms represent ligand-bound and free conformations of BMPRII. Comparison with the solved structure of ActRII bound to BMP2 suggests that His87, unique amongst TGF-{beta} receptors, may play a key role in ligand recognition.

  12. Mechanism of Bacterial Cell-Surface Attachment Revealed by the Structure of Cellulosomal Type II Cohesin-dockerin Complex

    SciTech Connect (OSTI)

    Adams,J.; Pal, G.; Jia, Z.; Smith, S.

    2006-01-01

    Bacterial cell-surface attachment of macromolecular complexes maintains the microorganism in close proximity to extracellular substrates and allows for optimal uptake of hydrolytic byproducts. The cellulosome is a large multienzyme complex used by many anaerobic bacteria for the efficient degradation of plant cell-wall polysaccharides. The mechanism of cellulosome retention to the bacterial cell surface involves a calcium-mediated protein-protein interaction between the dockerin (Doc) module from the cellulosomal scaffold and a cohesin (Coh) module of cell-surface proteins located within the proteoglycan layer. Here, we report the structure of an ultra-high-affinity (K{sub a} = 1.44 x 10{sup 10} M{sup 1-}) complex between type II Doc, together with its neighboring X module from the cellulosome scaffold of Clostridium thermocellum, and a type II Coh module associated with the bacterial cell surface. Identification of X module-Doc and X module-Coh contacts reveal roles for the X module in Doc stability and enhanced Coh recognition. This extremely tight interaction involves one face of the Coh and both helices of the Doc and comprises significant hydrophobic character and a complementary extensive hydrogen-bond network. This structure represents a unique mechanism for cell-surface attachment in anaerobic bacteria and provides a rationale for discriminating between type I and type II Coh modules.

  13. Cross-Linking and Mass Spectrometry Methodologies to Facilitate Structural Biology: Finding a Path through the Maze

    SciTech Connect (OSTI)

    Merkley, Eric D.; Cort, John R.; Adkins, Joshua N.

    2013-09-01

    Multiprotein complexes, rather than individual proteins, make up a large part of the biological macromolecular machinery of a cell. Understanding the structure and organization of these complexes is critical to understanding cellular function. Chemical cross-linking coupled with mass spectrometry is emerging as a complementary technique to traditional structural biology methods and can provide low-resolution structural information for a multitude of purposes, such as distance constraints in computational modeling of protein complexes. In this review, we discuss the experimental considerations for successful application of chemical cross-linking-mass spectrometry in biological studies and highlight three examples of such studies from the recent literature. These examples (as well as many others) illustrate the utility of a chemical cross-linking-mass spectrometry approach in facilitating structural analysis of large and challenging complexes.

  14. Synthesis and structural characterization of two half-sandwich nickel(II) complexes with the scorpionate ligands

    SciTech Connect (OSTI)

    Wang, G.-F. E-mail: s-shuwen@163.com; Zhang, X.; Sun, S.-W.; Sun, H.; Ma, H.-X.

    2015-12-15

    The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k{sup 3}-N, N',N''-Tp{sup t-Bu}, {sup Me}NiI] (1) and [k{sup 3}-N,N',N''-Tp{sup t-Bu}, {sup Me}NiNO{sub 3}] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II) ion of complex 1 is in a four-coordinate environment, in which the donor atoms are provided by three nitrogen atoms of a hydrotris(pyrazolyl) borate ligand and one iodide atom, while that of complex 2 is in a five-coordinate environment with three nitrogen atoms from a hydrotris(pyrazolyl)borate ligand and two oxygen atoms from a nitrate ion.

  15. Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties

    SciTech Connect (OSTI)

    Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li

    2013-09-15

    Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

  16. Find Journals

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  17. Molecular, crystal, and electronic structure of the cobalt(II) complex with 10-(2-benzothiazolylazo)-9-phenanthrol

    SciTech Connect (OSTI)

    Linko, R. V.; Sokol, V. I.; Polyanskaya, N. A.; Ryabov, M. A.; Strashnov, P. V.; Davydov, V. V.; Sergienko, V. S.

    2013-05-15

    The reaction of 10-(2-benzothiazolylazo)-9-phenanthrol (HL) with cobalt(II) acetate gives the coordination compound [CoL{sub 2}] {center_dot} CHCl{sub 3} (I). The molecular and crystal structure of I is determined by X-ray diffraction. The coordination polyhedron of the Co atom in complex I is an octahedron. The anion L acts as a tridentate chelating ligand and is coordinated to the Co atom through the phenanthrenequinone O1 atom and the benzothiazole N1 atom of the moieties L and the N3 atom of the azo group to form two five-membered metallocycles. The molecular and electronic structures of the compounds HL, L, and CoL{sub 2} are studied at the density functional theory level. The results of the quantum-chemical calculations are in good agreement with the values determined by X-ray diffraction.

  18. Find Reports

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    Classified reports - contact the SI-RMS Technical Report Collection for an appointment: ... Office 94 Cities of Gold Road Santa Fe, NM 87506 Where can I find Classified Reports? ...

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    Books Find Books The Library Catalog is available to the public, though many eBooks are limited to LANL researchers. Question? 667-5809 Email Library Catalog: Search here for all...

  1. STRUCTURE IN THE 3D GALAXY DISTRIBUTION. II. VOIDS AND WATERSHEDS OF LOCAL MAXIMA AND MINIMA

    SciTech Connect (OSTI)

    Way, M. J.; Gazis, P. R.; Scargle, Jeffrey D. E-mail: PGazis@sbcglobal.net

    2015-01-20

    The major uncertainties in studies of the multi-scale structure of the universe arise not from observational errors but from the variety of legitimate definitions and detection methods for individual structures. To facilitate the study of these methodological dependencies, we have carried out 12 different analyses defining structures in various ways. This has been done in a purely geometrical way by utilizing the HOP algorithm as a unique parameter-free method of assigning groups of galaxies to local density maxima or minima. From three density estimation techniques (smoothing kernels, Bayesian blocks, and self-organizing maps) applied to three data sets (the Sloan Digital Sky Survey Data Release 7, the Millennium simulation, and randomly distributed points) we tabulate information that can be used to construct catalogs of structures connected to local density maxima and minima. We also introduce a void finder that utilizes a method to assemble Delaunay tetrahedra into connected structures and characterizes regions empty of galaxies in the source catalog.

  2. Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption

    SciTech Connect (OSTI)

    Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C.

    2014-09-24

    The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

  3. Structural Dimensions, Fabrication, Materials, and Operational History for Types I and II Waste Tanks

    SciTech Connect (OSTI)

    Wiersma, B.J.

    2000-08-16

    Radioactive waste is confined in 48 underground storage tanks at the Savannah River Site. The waste will eventually be processed and transferred to other site facilities for stabilization. Based on waste removal and processing schedules, many of the tanks, including those with flaws and/or defects, will be required to be in service for another 15 to 20 years. Until the waste is removed from storage, transferred, and processed, the materials and structures of the tanks must maintain a confinement function by providing a leak-tight barrier to the environment and by maintaining acceptable structural stability during design basis event which include loading from both normal service and abnormal conditions.

  4. Structure And Dynamics of the Hydrated Palladium(II) Ion in Aqueous Solution a QMCF MD Simulation And EXAFS Spectroscopic Study

    SciTech Connect (OSTI)

    Hofer, T.S.; Randolf, B.R.; Shah, S.Adnan Ali; Rode, B.M.; Persson, I.

    2009-06-01

    The pharmacologically and industrially important palladium(II) ion is usually characterised as square-planar structure in aqueous solution, similar to the platinum(II) ion. Our investigations by means of the most modern experimental and theoretical methods give clear indications, however, that the hydrated palladium(II) ion is hexa-coordinated, with four ligands arranged in a plane at 2.0 {angstrom} plus two additional ligands in axial positions showing an elongated bond distance of 2.7-2.8 A. The second shell consists in average of 8.0 ligands at a mean distance of 4.4 {angstrom}. This structure provides a new basis for the interpretation of the kinetic properties of palladium(II) complexes.

  5. The crystal and molecular structure of bis[1,3-bis(diphenylphosphino)propane] dichlororuthenium(II)

    SciTech Connect (OSTI)

    Fontes, M.R.M.; Oliva, G.; Cordeiro, L.A.C.; Batista, A.A.

    1993-12-31

    The title compound, trans-[Ru(dpp){sub 2}Cl{sub 2}], crystallizes in the triclinic space group P1, with a = 9.529(1), b = 11.071(1), c = 11.936(1) {angstrom}, {alpha} = 71.967(9), {beta} = 72.879(6), {gamma} = 88.703(9){degrees}, V = 1141.1(2) {angstrom}{sup 3} and Z = 1. The structure was solved and refined to a final R = 0.039, for 3126 independently observed reflections with I > 3{sigma} (I). The ruthenium(II) ion is located on a crystallographic centre of symmetry and shows a distorted octahedral coordination with the chloride atoms in an exactly trans configuration. 19 refs., 1 fig., 3 tabs.

  6. Find Clear

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    p align="left"></p> <p align="left"></p> Find Clear Slide Title Duration Status myMail@adobe.com http://Adobe.com More Info>> <p align="left"></p> <p align="left"></p> <p align="left"></p> Go No Matches Found

  7. Synthesis, crystal structures and luminescent properties of zinc(II) metal–organic frameworks constructed from terpyridyl derivative ligand

    SciTech Connect (OSTI)

    Yang, Xiao-Le; Shangguan, Yi-Qing; Hu, Huai-Ming Xu, Bing; Wang, Bao-Cheng; Xie, Juan; Yuan, Fei; Yang, Meng-Lin; Dong, Fa-Xin; Xue, Gang-Lin

    2014-08-15

    Five zinc(II) metal–organic frameworks, [Zn{sub 3}(344-pytpy){sub 2}Cl{sub 6}]{sub n}·n(H{sub 2}O) (1), [Zn(344-pytpy)(ox)]{sub n} (2), [Zn{sub 2}(344-pytpy)(bdc){sub 2}]{sub n}·1.5n(H{sub 2}O) (3), [Zn{sub 2}(344-pytpy){sub 2} (sfdb){sub 2}]{sub n}·1.5n(H{sub 2}O) (4) and [Zn{sub 3}(344-pytpy){sub 2}(btc){sub 2}]{sub n}·2n(H{sub 2}O) (5), (344-pytpy=4′-(3-pyridyl)-4,2′:6′,4″-terpyridine, H{sub 2}ox=oxalic acid, H{sub 2}bdc=1,4-benzenedi-carboxylic acid, H{sub 2}sfdb=4,4′-sulfonyldibenzoic acid and H{sub 3}btc=1,3,5-benzene-tricarboxylic acid) have been prepared by hydrothermal reactions. Compound 1 is a 1D chain structure, in which 344-pytpy ligand links three Zn{sup II} centers through three of terminal N-donors. Compound 2 is a 4-connected 3D framework with the dia topological net and the Schläfli symbol of 6{sup 6}. Compound 3 displays a unusual 3-fold interpenetrating 3D coordination network which exhibits a new intriguing (3,3,4)-connected topological net with the Schläfli symbol of (4.8{sup 2})(4.8{sup 5})(8{sup 3}). Compound 4 features a two-fold interpenetrating 4-connected 2D framework with the sql topological net and the Schläfli symbol of (4{sup 4}.6{sup 2}). Compound 5 is a new self-interpenetrating (3,3,4,4)-connected topological net with the Schläfli symbol of (6.8{sup 2}){sub 2}(6{sup 2}.8{sup 2}.10.12)(6{sup 2}.8{sup 3}.10){sub 2}(6{sup 2}.8){sub 2}. The luminescence properties of 1–5 have been investigated by emission spectra and they possess great thermal stabilities which can be stable up to around 400 °C. - Graphical abstract: Five new Zn(II) metal–organic frameworks based on dicarboxylate and terpyridyl derivative ligands have been synthesized by hydrothermal reactions, giving networks from 1D to 3D structures. The thermal stability and luminescent property have been investigated. - Highlights: • Five zinc(II) metal–organic frameworks have been prepared under hydrothermal conditions. • Their crystal and

  8. Physics with gamma-beams and charged particle detectors: I) Nuclear structure II) Nuclear astrophysics

    SciTech Connect (OSTI)

    Gai, Moshe

    2015-02-24

    The Charged Particle Working Group (CPWG) is proposing to construct large area Silicon Strip Detector (SSD), a gas Time Projection Chamber detector read by an electronic readout system (eTPC) and a Bubble Chamber (BC) containing superheated high purity water to be used in measurements utilizing intense gamma-ray beams from the newly constructed ELI-NP facility at Magurele, Bucharest in Romania. We intend to use the SSD and eTPC detectors to address essential problems in nuclear structure physics, such as clustering and the many alpha-decay of light nuclei such as {sup 12}C and {sup 16}O. All three detectors (SSD, eTPC and BC) will be used to address central problems in nuclear astrophysics such as the astrophysical cross section factor of the {sup 12}C(α,γ) reaction and other processes central to stellar evolution. The CPWG intends to submit to the ELI-NP facility a Technical Design Report (TDR) for the proposed detectors.

  9. Structural properties and band offset determination of p-channel mixed As/Sb type-II staggered gap tunnel field-effect transistor structure

    SciTech Connect (OSTI)

    Zhu, Y.; Jain, N.; Hudait, M. K.; Mohata, D. K.; Datta, S.; Lubyshev, D.; Fastenau, J. M.; Liu, A. K.

    2012-09-10

    The structural properties and band offset determination of p-channel staggered gap In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} heterostructure tunnel field-effect transistor (TFET) grown by molecular beam epitaxy (MBE) were investigated. High resolution x-ray diffraction revealed that the active layers are strained with respect to 'virtual substrate.' Dynamic secondary ion mass spectrometry confirmed an abrupt junction profile at the In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} heterointerface and minimal level of intermixing between As and Sb atoms. The valence band offset of 0.37 {+-} 0.05 eV was extracted from x-ray photoelectron spectroscopy. A staggered band lineup was confirmed at the heterointerface with an effective tunneling barrier height of 0.13 eV. Thus, MBE-grown staggered gap In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} TFET structures are a promising p-channel option to provide critical guidance for the future design of mixed As/Sb type-II based complementary logic and low power devices.

  10. Three tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole and different aromatic carboxylates: Assembly, structures, electrochemical and magnetic properties

    SciTech Connect (OSTI)

    Wang, Xiu-Li; Zhao, Wei; Zhang, Ju-Wen; Lu, Qi-Lin

    2013-02-15

    Three new tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole (atrz) and three types of aromatic carboxylates, [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(DNBA){sub 6}] (1), [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(1,3-BDC){sub 3}]{center_dot}2H{sub 2}O (2) and [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(SIP){sub 2}]{center_dot}4H{sub 2}O (3) (HDNBA=3,5-dinitrobenzoic acid, 1,3-H{sub 2}BDC=1,3-benzenedicarboxylic acid and NaH{sub 2}SIP=sodium 5-sulfoisophthalate), have been hydrothermally synthesized and structurally characterized. Complex 1 displays a single-molecular Cu{sup II}{sub 4} cluster structure, which is further connected by the intermolecular hydrogen-bonding interactions to form a 2D supramolecular layer. In 2, there also exist tetranuclear Cu{sup II}{sub 4} clusters, which are linked by the 1,3-BDC anions to give a 3D NaCl-type framework. In 3, the Cu{sup II}{sub 4} clusters are connected by the carboxyl and sulfo groups of SIP anions to generate 3D (4,8)-connected framework with a (4{sup 10}{center_dot}6{sup 14}{center_dot}8{sup 4})(4{sup 5}{center_dot}6){sub 2} topology. The atrz ligand conduces to the construction of tetranuclear copper(II) clusters and the carboxylates with different non-carboxyl substituent show important effects on the final structures of the title complexes. The electrochemical and magnetic properties of 1-3 have been investigated. - Graphical abstract: Three tetranuclear copper(II) cluster-based complexes based on different carboxylates have been synthesized under hydrothermal conditions. The carboxylate anions play a key role in the formation of three different structures. Highlights: Black-Right-Pointing-Pointer Three new tetranuclear copper(II) cluster-based complexes have been obtained. Black-Right-Pointing-Pointer The atrz conduces to the construction of tetranuclear copper(II) clusters. Black-Right-Pointing-Pointer Carboxylates show important effect on the structures of

  11. In situ ligand generation for novel Mn(II) and Ni(II) coordination polymers with disulfide ligand: Solvothermal syntheses, structures and magnetic properties

    SciTech Connect (OSTI)

    Han, Yinfeng Wang, Chang'an; Zheng, Zebao; Sun, Jiafeng; Nie, Kun; Zuo, Jian; Zhang, Jianping

    2015-07-15

    Two coordination polymers, ([Mn{sub 2}(L1){sub 2}(μ{sub 2}-H{sub 2}O)(H{sub 2}O){sub 4}]·5H{sub 2}O){sub n}1 and ([Ni(L1)(H{sub 2}O){sub 2}]·2H{sub 2}O){sub n}2 (H{sub 2}L1=2,2′-dithiobisnicotinic acid), were prepared by the solvothermal reactions of the Mn(II) or Ni(II) ions with 2-mercaptonanicotinic acid. In 1, the [Mn{sub 2}(COO){sub 4}] units are connected by the 2,2′-dithiobisnicotinic dianion to form a two-dimensional (4,4)-connected network. In 2, the adjacent Ni(II) ions are connected by the carboxyl groups of the 2,2′-dithiobisnicotinic dianion to form an one-dimensional inorganic rod-shaped chain [Ni(COO){sub 2}]{sub n}, which are further interconnected by the 2,2′-dithiobisnicotinic ligand, giving rise to a two-dimensional framework. Variable-temperature magnetic susceptibilities of 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent metal ions. - Graphical abstract: Two 2D coordination polymers were synthesized by transition-metal/in-situ oxidation of 2-mercaptonicotinic acid. The compounds pack into 2D frameworks by the carboxyl groups of 2,2′-dithiobisnicotinic dianion and exhibit overall weak antiferromagnetic coupling. - Highlights: • Two 2D coordination polymers containing 2,2′-dithiobisnicotinic dianion. • In situ oxidation and dehydro coupling reaction of 2-mercaptonbenzoic acid. • Two compounds display weak antiferromagnetic exchanges.

  12. THE POSSIBLE ROLE OF CORONAL STREAMERS AS MAGNETICALLY CLOSED STRUCTURES IN SHOCK-INDUCED ENERGETIC ELECTRONS AND METRIC TYPE II RADIO BURSTS

    SciTech Connect (OSTI)

    Kong, Xiangliang; Chen, Yao; Feng, Shiwei; Wang, Bing; Du, Guohui; Guo, Fan; Li, Gang

    2015-01-10

    Two solar typeII radio bursts, separated by ?24 hr in time, are examined together. Both events are associated with coronal mass ejections (CMEs) erupting from the same active region (NOAA 11176) beneath a well-observed helmet streamer. We find that the typeII emissions in both events ended once the CME/shock fronts passed the white-light streamer tip, which is presumably the magnetic cusp of the streamer. This leads us to conjecture that the closed magnetic arcades of the streamer may play a role in electron acceleration and typeII excitation at coronal shocks. To examine such a conjecture, we conduct a test-particle simulation for electron dynamics within a large-scale partially closed streamer magnetic configuration swept by a coronal shock. We find that the closed field lines play the role of an electron trap via which the electrons are sent back to the shock front multiple times and therefore accelerated to high energies by the shock. Electrons with an initial energy of 300 eV can be accelerated to tens of keV concentrating at the loop apex close to the shock front with a counter-streaming distribution at most locations. These electrons are energetic enough to excite Langmuir waves and radio bursts. Considering the fact that most solar eruptions originate from closed field regions, we suggest that the scenario may be important for the generation of more metric typeIIs. This study also provides an explanation of the general ending frequencies of metric typeIIs at or above 20-30 MHz and the disconnection issue between metric and interplanetary typeIIs.

  13. Hybrid type-I InAs/GaAs and type-II GaSb/GaAs quantum dot structure with enhanced photoluminescence

    SciTech Connect (OSTI)

    Ji, Hai-Ming; Liang, Baolai Simmonds, Paul J.; Juang, Bor-Chau; Yang, Tao; Young, Robert J.; Huffaker, Diana L.

    2015-03-09

    We investigate the photoluminescence (PL) properties of a hybrid type-I InAs/GaAs and type-II GaSb/GaAs quantum dot (QD) structure grown in a GaAs matrix by molecular beam epitaxy. This hybrid QD structure exhibits more intense PL with a broader spectral range, compared with control samples that contain only InAs or GaSb QDs. This enhanced PL performance is attributed to additional electron and hole injection from the type-I InAs QDs into the adjacent type-II GaSb QDs. We confirm this mechanism using time-resolved and power-dependent PL. These hybrid QD structures show potential for high efficiency QD solar cell applications.

  14. Syntheses, structures, and properties of Co(II)/Zn(II) mixed-ligand coordination polymers based on 4-[(3,5-dinitrobenzoyl)amino]benzoic acid and 1,4-bis(1-imidazolyl) benzene

    SciTech Connect (OSTI)

    Yin, Fei; Chen, Jing; Liang, Yongfeng; Zou, Yang; Yinzhi, Jiang; Xie, Jingli

    2015-05-15

    Two coordination polymers [Co(dnbab){sub 2}(bimb)](H{sub 2}O){sub 4} (1) and [Zn(dnbab){sub 2}(bimb)](H{sub 2}O){sub 5} (2) (Hdnbab=4-[(3,5-dinitrobenzoyl)amino]benzoic acid, bimb=1,4-bis(1-imidazolyl) benzene) have been solvothermally synthesized. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by powder X-ray diffraction (PXRD) and thermogravimetric (TG) analyses. Complexes 1 and 2 are isostructures and each displays an one-dimensional (1D) zigzag chain, which further forms a 3D supramolecular architecture with 1-D channels via inter-chain π–π interactions and hydrogen bonds. Moreover, the magnetic properties of 1 and fluorescent properties of 2 have been investigated. - Graphical abstract: Two coordination supramolecular frameworks [Co(dnbab){sub 2}(bimb)](H{sub 2}O){sub 4}(1) and [Zn(dnbab){sub 2}(bimb)](H{sub 2}O){sub 5}(2) (Hdnbab=4-[(3,5-dinitrobenzoyl)amino]benzoic acid, bimb=1,4-bis(1-imidazolyl) benzene) have been synthesized and characterized by X-ray single-crystal diffraction. Their thermal, magnetic and fluorescent properties have also been studied. - Highlights: • Two isomorphic Co(II)/Zn(II) complexes with the mixed-ligands have been synthesized. • Hydrogen bonds and π–π stacking interactions directed the final 3-D architecture assembly. • Both Co(II) and Zn(II) complexes show good thermal stability. • Co complex exhibits antiferromagnetic interaction. • The fluorescent property of Zn(II) complex has been investigated in the solid state.

  15. Sputtered II-VI Alloys and Structures forTandem PV: Final Subcontract Report, 9 December 2003 - 30 July 2007

    SciTech Connect (OSTI)

    Compaan, A. D.; Collins, R.; Karpov, V. G.; Giolando, D.

    2008-09-01

    This report elaborates on Phase 3 and provides summaries of the first two Phases. Phase 3 research work was divided into five task areas covering different aspects of the II-VI tandem cell.

  16. Copper(II)-lanthanide(III) coordination polymers constructed from pyridine-2,5-dicarboxylic acid: Preparation, crystal structure and photoluminescence

    SciTech Connect (OSTI)

    Xia Zhengqiang; Wei Qing; Chen Sanping; Feng Xinming; Xie Gang; Qiao Chengfang; Zhang Guochun; Gao Shengli

    2013-01-15

    A series of 3d-4f heterometallic coordination polymers, formulated as {l_brace} [Cu{sub 3}Ln{sub 2}(pydc){sub 6}(H{sub 2}O){sub 12}]{center_dot}4H{sub 2}O{r_brace} {sub n} [Ln=Tb (1), Eu (2), Dy (3), Ho (4), Lu (5)], {l_brace} [CuNd{sub 2}(pydc){sub 4}(H{sub 2}O){sub 3}]{center_dot}H{sub 2}O{r_brace} {sub n} (6) and {l_brace} [Cu{sub 3}Pr{sub 2}(pydc){sub 6}(H{sub 2}O){sub 13}]{center_dot}4H{sub 2}O{r_brace} {sub n} (7) (where H{sub 2}pydc=pyridine-2,5-dicarboxylic acid), have been hydrothermally prepared by reactions of H{sub 2}pydc ligand with lanthanide ions in the presence of Cu(II) ion. X-ray crystal structure analysis reveals that these compounds exhibit rich structural chemistry. 1-5 are isomorphous and present a two-dimensional network constructed from Ln{sub 2}Cu{sub 2}L{sub 2}(H{sub 2}O){sub 2} SBU rings and CuL{sub 2}(H{sub 2}O) building blocks. In 6, two-dimensional ladder-like layers based on Nd(III) belts and CuL{sub 2}O{sub 2} units are assembled by H{sub 2}pydc ligands into a three-dimensional open framework. Polymer 7 displays a two-dimensional wave-like layer structure containing two distinct ring units, in which a new coordination mode of the pydc{sup 2-} ligand is observed. The results indicate that the coordination flexibility of the pydc{sup 2-} ligand and lanthanide contraction effect play cooperative roles in the formation of coordination polymers with different polymeric architectures. Compounds 1-2 exhibit intense green and red luminescence emission characteristics of Tb(III) and Eu(III), respectively. Furthermore, elemental analyses (EA), infrared spectra (IR) and thermogravimetric analyses (TGA) of these compounds were also studied. - Graphical abstract: Seven 3d-4f heterometallic coordination polymers were synthesized by reactions of H{sub 2}pydc with lanthanide metal ions in the presence of Cu{sup 2+}, the effects of Cu{sup 2+} on the structures and photoluminescent properties of Ln-pydc{sup 2-} systems were investigated. Highlights

  17. Synthesis, structure, and magnetic properties of a novel mixed-valence copper(I/II) phosphate, Cu{sub 2}PO{sub 4}

    SciTech Connect (OSTI)

    Etheredge, K.M.S.; Hwu, S.J.

    1995-09-27

    Via phase compatibility studies, a novel mixed-valence copper(I/II) phosphate, Cu{sub 2}PO{sub 4}, has been isolated from a direct reaction of Cu{sub 2}{sup I}O, Cu{sup II}O, and P{sub 2}O{sub 5} in fused silica. The single-crystal X-ray diffraction shows that the title compound crystallizes in a triclinic (P1) unit cell, with lattice dimensions a = 6.145(2) {angstrom}, b = 9.348(2) {angstrom}, c = 6.009(1) {angstrom}, {alpha} = 96.46(2){degrees}, {beta} = 100.16(2){degrees}, {gamma} = 73.97(2){degrees}, V = 325.8(1) {angstrom}{sup 3}; Z =4. The structure has been refined by the least-squares method to R = 0.019, R{sub w} = 0.030, and GOF = 1.43 for 128 variables. The four copper atoms in each asymmetric unit adopt three distorted coordination geometries that are consistent with the corresponding electronic states, e.g., square pyramidal Cu(1){sup II}O{sub 5}, octahedral Cu(2){sup II}O{sub 6}, and linear Cu(3,4){sup I}O{sub 2}. A low-dimensional framework exists consisting of arrays of nearly parallel CuO{sub 2} units which are separated by the nonmagnetic, closed-shell P{sup 5+} cation in PO{sub 4} tetrahedra. Closely spaced CuO{sub 2} chains and a relatively short Cu{sup I}-Cu{sup I} distance, e.g., 2.737 {angstrom} for Cu(3)-Cu(3), are attributed to the bond strength of the cross-linked PO{sub 4} tetrahedra. In the extended Cu(I/II)-O framework, short linkages of Cu{sup I}-O-Cu{sup II}-O-Cu{sup I} and Cu{sup II}-O-Cu{sup II}, composed of regular Cu-O bonds (1.86-1.99 {angstrom}), are interconnected through long Cu{sup II}-O bonds (2.36-2.74 {angstrom}). The magnetic measurements indicate that the Cu-O framework exhibits a spin 1/2 ground state and an antiferromagnetic ordering with a broad susceptibility maximum between 95 and 105 K. The results of stoichiometric synthesis, thermal analysis, and bond valence sum calculations of the title compound are also discussed.

  18. Copper(II) complexes with 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid: Syntheses, crystal structures and antifungal activities

    SciTech Connect (OSTI)

    Xiong, Pingping; Li, Jie; Bu, Huaiyu; Wei, Qing; Zhang, Ruolin; Chen, Sanping

    2014-07-01

    Reaction of Cu(II) with an asymmetric semi-rigid organic ligand 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid (HL), yielded five compounds, [Cu{sub 0.5}L]{sub n} (1), [Cu(HL){sub 2}Cl{sub 2}]{sub n} (2), [Cu(HL){sub 2}Cl{sub 2}(H{sub 2}O)] (3), [Cu(L){sub 2}(H{sub 2}O)]{sub n} (4) and [Cu(L)(phen)(HCO{sub 2})]{sub n} (5), which have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. As for compounds 1, 2 and 5, Cu(II) is bridged through HL, Cl{sup -}, and formic acid, respectively, featuring 1D chain-structure. In compound 3, Cu(II) with hexahedral coordination sphere is assembled through hydrogen-bonding into 3D supramolecular framework. In compound 4, 1D chain units –Cu–O–Cu–O– are ligand-bridged into a 3D network. All compounds were tested on fungi (Fusarium graminearum, Altemaria solani, Macrophoma kawatsukai, Alternaria alternata and Colletotrichum gloeosporioides). Compound 1 exhibits a better antifungal effect compared to other compounds. An effect of structure on the antifungal activity has also been correlated. - Graphical abstract: Copper(II) compounds with 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid, were prepared, structurally characterized and investigated for antifungal activity. - Highlights: • The title compounds formed by thermodynamics and thermokinetics. • The five compounds show higher inhibition percentage than reactants. • The structure effect on the antifungal activity.

  19. The H I chronicles of little things BCDs II: The origin of IC 10's H I structure

    SciTech Connect (OSTI)

    Ashley, Trisha; Simpson, Caroline E.; Pokhrel, Nau Raj; Elmegreen, Bruce G.; Johnson, Megan; Nidever, David L. E-mail: simpsonc@fiu.edu E-mail: bge@us.ibm.com E-mail: dnidever@umich.edu

    2014-12-01

    In this paper we analyze Very Large Array (VLA) telescope and Green Bank Telescope (GBT) atomic hydrogen (H I) data for the LITTLE THINGS (Local Irregulars That Trace Luminosity Extremes, The H I Nearby Galaxy Survey; https://science.nrao.edu/science/surveys/littlethings) blue compact dwarf galaxy IC 10. The VLA data allow us to study the detailed H I kinematics and morphology of IC 10 at high resolution while the GBT data allow us to search the surrounding area at high sensitivity for tenuous H I. IC 10's H I appears highly disturbed in both the VLA and GBT H I maps with a kinematically distinct northern H I extension, a kinematically distinct southern plume, and several spurs in the VLA data that do not follow the general kinematics of the main disk. We discuss three possible origins of its H I structure and kinematics in detail: a current interaction with a nearby companion, an advanced merger, and accretion of intergalactic medium. We find that IC 10 is most likely an advanced merger or a galaxy undergoing accretion.

  20. A 3D complex containing novel 2D Cu{sup II}-azido layers: Structure, magnetic properties and effects of 'Non-innocent' reagent

    SciTech Connect (OSTI)

    Gao, Xue-Miao; Guo, Qian; Zhao, Jiong-Peng; Liu, Fu-Chen

    2012-12-15

    A novel copper-azido coordination polymer, [Cu{sub 2}(N{sub 3}){sub 3}(L)]{sub n} (1, HL=pyrazine-2-carboxylic acid), has been synthesized by hydrothermal reaction with 'Non-innocent' reagent in the aqueous solution. In the reaction system, Cu{sup II} ions are avoided to reduce to Cu{sup I} ions due to the existence of Nd{sup III}. It is found that the complex is a 3D structure based on two double EO azido bridged trimmers and octahedron Cu{sup II} ions, in which the azide ligands take on EO and {mu}{sub 1,1,3} mode to form Cu{sup II}-azido 2D layers, furthermore L ligands pillar 2D layers into an infinite 3D framework with the Schlaefli symbol of {l_brace}4;6{sup 2}{r_brace}4{l_brace}4{sup 2};6{sup 12};8{sup 10};10{sup 4}{r_brace}{l_brace}4{sup 2};6{sup 4}{r_brace}. Magnetic studies revealed that the interactions between the Cu{sup II} ions in the trimmer are ferromagnetic for the Cu-N-Cu angle nearly 98 Degree-Sign , while the interactions between the trimmer and octahedron Cu{sup II} ion are antiferromgantic and result in an antiferromagnetic state. - Graphical abstract: A 3D complex containing novel 2D Cu{sup II}-azido layers, [Cu{sub 2}(N{sub 3}){sub 3}(L)]{sub n} (HL=pyrazine-2-carboxylic acid), was synthesized by hydrothermal reaction and exhibit interesting structure and magnetic properties. Highlights: Black-Right-Pointing-Pointer 'Non-innocent' reagents plays a key role in the process of formation of this complex. Black-Right-Pointing-Pointer 2D layer is formed only by Cu{sup II} ions and azido ligands. Black-Right-Pointing-Pointer Pyrazine-2-carboxylate ligands reinforce 2D layers and pillar them into an infinite 3D framework. Black-Right-Pointing-Pointer Magnetic study indicates that alternating FM-AF coupling exists in the complex.

  1. IMPROVED V II log(gf) VALUES, HYPERFINE STRUCTURE CONSTANTS, AND ABUNDANCE DETERMINATIONS IN THE PHOTOSPHERES OF THE SUN AND METAL-POOR STAR HD 84937

    SciTech Connect (OSTI)

    Wood, M. P.; Lawler, J. E.; Den Hartog, E. A.; Sneden, C.; Cowan, J. J. E-mail: jelawler@wisc.edu E-mail: chris@verdi.as.utexas.edu

    2014-10-01

    New experimental absolute atomic transition probabilities are reported for 203 lines of V II. Branching fractions are measured from spectra recorded using a Fourier transform spectrometer and an echelle spectrometer. The branching fractions are normalized with radiative lifetime measurements to determine the new transition probabilities. Generally good agreement is found between this work and previously reported V II transition probabilities. Two spectrometers, independent radiometric calibration methods, and independent data analysis routines enable a reduction in systematic uncertainties, in particular those due to optical depth errors. In addition, new hyperfine structure constants are measured for selected levels by least squares fitting line profiles in the FTS spectra. The new V II data are applied to high resolution visible and UV spectra of the Sun and metal-poor star HD 84937 to determine new, more accurate V abundances. Lines covering a range of wavelength and excitation potential are used to search for non-LTE effects. Very good agreement is found between our new solar photospheric V abundance, log ε(V) = 3.95 from 15 V II lines, and the solar-system meteoritic value. In HD 84937, we derive [V/H] = –2.08 from 68 lines, leading to a value of [V/Fe] = 0.24.

  2. NMR studies of chiral P,S-chelate platinum, rhodium, and iridium complexes and the X-ray structure of a palladium(II) allyl derivative

    SciTech Connect (OSTI)

    Albinati, A. [Univ. of Milan (Italy)] [Univ. of Milan (Italy); Eckert, J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Pregosin, P.; Ruegger, H.; Salzmann, R.; Stoessel, C. [ETH-Zentrum, Zuerich (Switzerland)] [ETH-Zentrum, Zuerich (Switzerland)

    1997-02-18

    Several Rh(I), Ir(III), and Pt(II) complexes of the chiral P,S-bidentate ligand 2 have been prepared and characterized. Detailed two-dimensional NMR studies show that (i) the boat-type chelate ring and the stereogenic sulfur center can invert rapidly at ambient temperature and (ii) the sulfur donor may dissociate, essentially destroying the chiral pocket. The solid-state structure of [Pt({eta}{sup 3}-C{sub 3}H{sub 5})(2)]PF{sub 6} (3) has been determined and the sulfur substituent shown to have an axial orientation. The six-membered chelate ring takes up a boat-like conformation. As shown by an X-ray diffraction study for 3, and via incoherent inelastic neutron scattering (IINS) measurements for the Pd analog, 4, the OH group is remote from the metal atom. 42 refs., 11 figs., 6 tabs.

  3. Aerobic C-H Acetoxylation of 8-Methylquinoline in PdII-Pyridinecarboxylic Acid Systems: Some Structure-Reactivity Relationships

    SciTech Connect (OSTI)

    Wang, Daoyong; Zavalij, Peter Y.; Vedernikov, Andrei N.

    2013-09-09

    Catalytic oxidative CH acetoxylation of 8-methylquinoline as a model substrate with O2 as oxidant was performed using palladium(II) carboxylate catalysts derived from four different pyridinecarboxylic acids able to form palladium(II) chelates of different size. A comparison of the rates of the substrate CH activation and the O2 activation steps shows that the CH activation step is rate-limiting, whereas the O2 activation occurs at a much faster rate already at 20 C. The chelate ring size and the chelate ring strain of the catalytically active species are proposed to be the key factors affecting the rate of the CH activation.

  4. Syntheses, crystal structures and fluorescent properties of Cd(II), Hg(II) and Ag(I) coordination polymers constructed from 1H-1,2,4-triazole-1-acetic acid

    SciTech Connect (OSTI)

    Ding Degang; Xie Lixia; Fan Yaoting; Hou Hongwei; Xu Yan

    2009-06-15

    Three new d{sup 10} coordination polymers, namely [Cd(taa)Cl]{sub n}1, [Hg(taa)Cl]{sub n}2, and [Ag{sub 1.5}(taa)(NO{sub 3}){sub 0.5}]{sub n}3 (taa=1H-1,2,4-triazole-1-acatate anion) have been prepared and characterized by elemental analysis, IR, and single crystal X-ray diffraction. Compound 1 consists of two-dimensional layers constructed by carboxyl-linked helical chains, which are further linked through carboxyl group to generate a unique 3D open framework. Topological analysis reveals that the structure of 1 can be classified as an unprecedented (3,8)-connected network with the Schlaefli symbol (4.5{sup 2}){sub 2}(4{sup 2}.5{sup 8}.6{sup 14}.7{sup 3}.8). Compound 2 manifests a doubly interpenetrated decorated alpha-polonium cubic network with the Schlaefli symbol of (4{sup 10}.6{sup 2}.8{sup 3}). Compound 3 consists of 2D puckered layers made up of Ag centers and taa{sup -} bridges. In addition, all of these compounds are photoluminescent in the solid state with spectra that closely resemble those of the ligand precursor. - Graphical abstract: Three new compounds based on 1H-1,2,4-triazole-1-acetic acid and Cd(II), Hg(II) and Ag(I) salts display luminescent properties and may be potential candidates for luminescent materials.

  5. Two new Co(II)-MOFs based on polymeric chain building units: Crystal structures, and magnetic properties

    SciTech Connect (OSTI)

    Han, Min-Le; Wu, Ya-Pan; Zhao, Jun; Li, Dong-Sheng; Wang, Yao-Yu

    2015-10-15

    Two new Co(II) metal-organic frameworks, namely [Co{sub 2}(bpm)(H{sub 2}O){sub 3}(L)]{sub n} (1) and ([Co(bpe)(H{sub 2}O)(H{sub 2}L)]·(bpe){sub 0.5}·(H{sub 2}O)){sub n} (2), (H{sub 4}L=1,1′:2′,1″-terphenyl-3,3″,4′,5′-tetracarboxylic acid, bpm=bis(4-pyridyl)amine, bpe=1,2-bis(4-pyridyl)ethene), have been obtained under hydrothermal conditions. Both complexes 1 and 2 have been characterized by elemental analysis, IR spectra, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). Complexes 1 and 2 consist of 1D Co(II) chains bridging by carboxylate groups in syn-anti fashion. 1 shows a novel 3D tri-nodal (4,6,10)-connected net with a (3.4{sup 3}.5{sup 2}){sub 2}(3{sup 2}.4{sup 14}.5{sup 12}.6{sup 12}.7{sup 4}.8)(3{sup 2}.4{sup 2}.5{sup 5}.6{sup 4}.7{sup 2}) topology. While 2 exhibits a 2D sql layer. Magnetic susceptibility measurements indicate that both 1 and 2 show weak antiferromagnetic interactions between the adjacent Co(II) ions in 300–8 K for 1 and 300–16 K for 2, respectively, and then 2 also displays ferromagnetic coupling at lower temperatures. - Graphical abstract: Two Co(II) coordination polymers with similar metal chain bridging by carboxylates in syn-anti fashion have been synthesized. Both 1 and 2 show weak antiferromagnetic interactions in high temperature, and then 2 also displays ferromagnetic coupling at lower temperatures. - Highlights: • Two Co(II) coordination polymers with similar metal chain bridging by carboxylates. • A novel 3D (4,6,10)-connected net and a 2D sql layers. • A antiferromagnetic coupling at high temperature for 1 and 2. • A ferromagnetic coupling at lower temperature for 2.

  6. Five new Zn(II) and Cd(II) coordination polymers constructed by 3,5-bis-oxyacetate-benzoic acid: Syntheses, crystal structures, network topologies and luminescent properties

    SciTech Connect (OSTI)

    Jiang Xianrong; Yuan Hongyan; Feng Yunlong

    2012-07-15

    Five Zn(II) and Cd(II) coordination polymers, [Zn{sub 2}(BOABA)(bpp)(OH)]{center_dot}0.5H{sub 2}O (1), [Cd{sub 3}(BOABA){sub 2}(bpp){sub 2}(H{sub 2}O){sub 6}]{center_dot}2H{sub 2}O (2), [Cd{sub 3}(BOABA){sub 2}(2,2 Prime -bipy){sub 3}(H{sub 2}O){sub 4}]{center_dot}5.5H{sub 2}O (3), [CdNa(BOABA)(H{sub 2}O)]{sub 2}{center_dot}H{sub 2}O (4) and [Cd{sub 2}(BOABA)(bimb)Cl(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O (5) (H{sub 3}BOABA=3,5-bis-oxyacetate-benzoic acid, bpp=1,3-bi(4-pyridyl)propane, 2,2 Prime -bipy=2,2 Prime -bipyridine, bimb=1,4-bis(imidazol-1 Prime -yl)butane), have been solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra and TG analyses. 1 is an uninodal 4-connected 2D square grid network based on binuclear zinc clusters. 2 is 2D wavelike layer structure and further linked by hydrogen bonds into the final 3D (5,6,6)-connected topology network. 3 is 3-connected 2D topology network and the 2,2 Prime -bipy ligands decorate in two different types. 4 is a (4,8)-connected 2D topology network with heterocaryotic {l_brace}Cd{sub 2}Na{sub 2}{r_brace} clusters and BOABA{sup 3-} ligands. 5 can be rationalized as a (3,10)-connected 3D topology network with tetranuclear {l_brace}Cd{sub 4}Cl{sub 2}{r_brace} clusters and BOABA{sup 3-} ligands. Meanwhile, photoluminescence studies revealed that these five coordination polymers display strong fluorescent emission bands in the solid state at room temperature. - Graphical abstract: Five new d{sup 10} metal(II) coordination polymers based on H{sub 3}BOABA ligand were obtained and characterized. They display different topological structures and luminescent properties. Highlights: Black-Right-Pointing-Pointer Five d{sup 10} metal(II) polymers based on 3,5-bis-oxyacetate-benzoic acid were obtained. Black-Right-Pointing-Pointer The polymers were structurally characterized by single-crystal X-ray diffraction. Black-Right-Pointing-Pointer Polymers 1-5 display different

  7. Inter-cage dynamics in structure I, II, and H fluoromethane hydrates as studied by NMR and molecular dynamics simulations

    SciTech Connect (OSTI)

    Trueba, Alondra Torres; Kroon, Maaike C.; Peters, Cor J.; Moudrakovski, Igor L.; Ratcliffe, Christopher I.; Ripmeester, John A.; Alavi, Saman

    2014-06-07

    Prospective industrial applications of clathrate hydrates as materials for gas separation require further knowledge of cavity distortion, cavity selectivity, and defects induction by guest-host interactions. The results presented in this contribution show that under certain temperature conditions the guest combination of CH{sub 3}F and a large polar molecule induces defects on the clathrate hydrate framework that allow intercage guest dynamics. {sup 13}C NMR chemical shifts of a CH{sub 3}F/CH{sub 4}/TBME sH hydrate and a temperature analysis of the {sup 2}H NMR powder lineshapes of a CD{sub 3}F/THF sII and CD{sub 3}F/TBME sH hydrate, displayed evidence that the populations of CH{sub 4} and CH{sub 3}F in the D and D{sup ?} cages were in a state of rapid exchange. A hydrogen bonding analysis using molecular dynamics simulations on the TBME/CH{sub 3}F and TBME/CH{sub 4} sH hydrates showed that the presence of CH{sub 3}F enhances the hydrogen bonding probability of the TBME molecule with the water molecules of the cavity. Similar results were obtained for THF/CH{sub 3}F and THF/CH{sub 4} sII hydrates. The enhanced hydrogen bond formation leads to the formation of defects in the water hydrogen bonding lattice and this can enhance the migration of CH{sub 3}F molecules between adjacent small cages.

  8. Effect of three bis-pyridyl-bis-amide ligands with various spacers on the structural diversity of new multifunctional cobalt(II) coordination polymers

    SciTech Connect (OSTI)

    Lin, Hong-Yan; Lu, Huizhe; Le, Mao; Luan, Jian; Wang, Xiu-Li; Liu, Guocheng; Zhang, Juwen

    2015-03-15

    Three new cobalt(II) coordination polymers [Co{sub 2}(1,4-NDC){sub 2}(3-bpye)(H{sub 2}O)] (1), [Co(1,4-NDC)(3-bpfp)(H{sub 2}O)] (2) and [Co(1,4-NDC)(3-bpcb)] (3) [3-bpye=N,N′-bis(3-pyridinecarboxamide)-1,2-ethane, 3-bpfp=bis(3-pyridylformyl)piperazine, 3-bpcb=N,N′-bis(3-pyridinecarboxamide)-1,4-benzene, and 1,4-H{sub 2}NDC=1,4-naphthalenedicarboxylic acid] have been hydrothermally synthesized. The structures of complexes 1–3 have been determined by X-ray single crystal diffraction analyses and further characterized by infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Complex 1 is a 3D coordination structure with 8-connected (4{sup 20}.6{sup 8}) topology constructed from 3D [Co{sub 2}(1,4-NDC){sub 2}(H{sub 2}O)]{sub n} framework and bidentate 3-bpye ligands. Complex 2 shows 1D “cage+cage”-like chain formed by 1D [Co{sub 2}(1,4-NDC){sub 2}]{sub n} ribbon chains and [Co{sub 2}(3-bpfp){sub 2}] loops, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Complex 3 displays a 3D coordination network with a 6-connected (4{sup 12}.6{sup 3}) topology based on 2D [Co{sub 2}(1,4-NDC){sub 2}]{sub n} layers and bidentate 3-bpcb bridging ligands. The influences of different bis-pyridyl-bis-amide ligands with various spacers on the structures of title complexes are studied. Moreover, the fluorescent properties, electrochemical behaviors and magnetic properties of complexes 1–3 have been investigated. - Graphical abstract: Three multifunctional cobalt(II) complexes constructed from three bis-pyridyl-bis-amide and 1,4-naphthalenedicarboxylic acid have been hydrothermally synthesized and characterized. The fluorescent, electrochemical and magnetic properties of 1–3 have been investigated. - Highlights: • Three multifunctional cobalt(II) complexes based on various bis-pyridyl-bis-amide ligands. • Complex 1 is a 3D coordination structure with 8-connected (4{sup 20}.6{sup 8

  9. Dicarboxylate assisted synthesis of the monoclinic heterometallic tetrathiocyanato bridged copper(II) and mercury(II) coordination polymer {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n}: Synthesis, structural, vibration, luminescence, EPR studies and DFT calculations

    SciTech Connect (OSTI)

    Khandar, Ali Akbar; Klein, Axel; Bakhtiari, Akbar; Mahjoub, Ali Reza; Pohl, Roland W.H.

    2011-02-15

    The synthesis of the monoclinic polymorph of {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} is reported. The compound, as determined by X-ray diffraction of a twinned crystal, consists of mercury and copper atoms linked by {mu}{sub 1,3}-SCN bridges. The crystal packing shows a highly porous infinite 3D structure. Diagnostic resonances for the SCN{sup -} ligand and metal-ligand bonds in the IR, far-IR and Raman spectra are assigned and discussed. The electronic band structure along with density of states (DOS) calculated by the DFT method indicates that the compound is an indirect band gap semiconductor. The DFT calculations show that the observed luminescence of the compound arises mainly from an excited LLCT state with small MLCT contributions (from the copper to unoccupied {pi}{sup *} orbital of the thiocyanate groups). The X-band EPR spectrum of the powdered sample at room temperature reveals an axial signal with anisotropic g factors consistent with the unpaired electron of Cu(II) ion in the d{sub x}{sup 2}{sub -y}{sup 2} orbital. -- Graphical abstract: Synthesis and X-ray structure determination of the monoclinic {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} is reported. The IR, far-IR, Raman, photoluminescence as well as EPR spectra of the compound is discussed. Also, the emission and semiconducting behavior of the compound is illustrated through the density functional theory calculation of electronic band structure along with density of states. Display Omitted Research highlights: > The monoclinic {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} has been prepared. > The structure of the compound is determined by XRD of a twinned crystal. > The IR, far-IR, Raman, EPR and emission spectra of the compound is investigated. > As shown by DFT calculations, the emission bands of the compound are mainly LLCT. > Small MLCT from the copper to the thiocyanate groups contributes to these bands.

  10. Synthesis, structure and properties of zinc(II) coordination polymers with 9H-carbazole-2,7-dicarboxylic acid

    SciTech Connect (OSTI)

    Yi, Xiu-Chun; Xi, Fu-Gui; Wang, Kun; Su, Zhao; Gao, En-Qing

    2013-10-15

    From a new dicarboxylate ligand, 9H-carbazole-2,7-dicarboxylic acid (2,7-H{sub 2}CDC), three Zn(II) metal-organic frameworks were synthesized in the absence or presence of ditopic N-donor ligands. They are formulated as [Zn{sub 5}(μ{sub 3}-OH){sub 2}(2,7-CDC){sub 4}(DEF){sub 2}] (1) (DEF=N,N-diethylformamide), [Zn{sub 2}(2,7-CDC){sub 2}(DABCO)(H{sub 2}O)]·5DMF·H{sub 2}O (2) (DABCO=1-diaza-bicyclo[2.2.2]octane, DMF=N,N-dimethylformamide), and [Zn{sub 2}(2,7-CDC){sub 2}(bpea)]·3DMA·2 H{sub 2}O (3) (bpea=1,2-bis(4-pyridyl)ethylane, DMA=N,N-dimethylacetamide). Compounds 1 and 3 display the 3D pcu frameworks. In 1 the unusual pentanuclear [Zn{sub 5}(μ{sub 3}-OH){sub 2}(COO){sub 8}] secondary building units (SBUs) are linked by dicarboxylate ligands. Differently, in 3 the well-known paddle–wheel [Zn{sub 2}(COO){sub 4}] SBUs are linked by dicarboxylate and dipyridyl ligands. Compound 2 shows the rare self-catenated 3D alb-3,6-C2/c net topology based on the dinuclear paddle–wheel SBU and a mononuclear unit. The stability and fluorescent properties of the compounds have been studied. - Graphical abstract: A new dicarboxylate ligand, 9H-carbazole-2,7-dicarboxylic acid, was used to construct Zn(II) metal-organic frameworks, including a novel self-catenated network with the rare 3D alb-3,6-C2/c net and two pcu-type networks based on an unprecedented pentanuclear clusters and the common paddle–wheel units. The compounds show blue fluorescent properties. Display Omitted - Highlights: • MOFs with a new carbazole-based dicarboxylate ligand. • New pentanuclear [Zn{sub 5}(μ{sub 3}-OH){sub 2}(COO){sub 8}] secondary building unit. • The rare self-catenated 3D alb-3,6-C2/c net.

  11. A series of Cd(II) complexes with {pi}-{pi} stacking and hydrogen bonding interactions: Structural diversities by varying the ligands

    SciTech Connect (OSTI)

    Wang Xiuli; Zhang Jinxia; Liu Guocheng; Lin Hongyan

    2011-02-15

    Seven new Cd(II) complexes consisting of different phenanthroline derivatives and organic acid ligands, formulated as [Cd(PIP){sub 2}(dnba){sub 2}] (1), [Cd(PIP)(ox)].H{sub 2}O (2), [Cd(PIP)(1,4-bdc)(H{sub 2}O)].4H{sub 2}O (3), [Cd(3-PIP){sub 2}(H{sub 2}O){sub 2}].4H{sub 2}O (4), [Cd{sub 2}(3-PIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].5H{sub 2}O (5), [Cd(3-PIP)(nip)(H{sub 2}O)].H{sub 2}O (6), [Cd{sub 2}(TIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].3H{sub 2}O (7) (PIP=2-phenylimidazo[4,5-f]1,10-phenanthroline, 3-PIP=2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline, TIP=2-(2-thienyl)imidazo[4,5-f]1,10-phenanthroline, Hdnba=3,5-dinitrobenzoic acid, H{sub 2}ox=oxalic acid, 1,4-H{sub 2}bdc=benzene-1,4-dicarboxylic acid, 4,4'-H{sub 2}bpdc=biphenyl-4,4'-dicarboxylic acid, H{sub 2}nip=5-nitroisophthalic acid) have been synthesized under hydrothermal conditions. Complexes 1 and 4 possess mononuclear structures; complexes 5 and 7 are isostructural and have dinuclear structures; complexes 2 and 3 feature 1D chain structures; complex 6 contains 1D double chain, which are further extended to a 3D supramolecular structure by {pi}-{pi} stacking and hydrogen bonding interactions. The N-donor ligands with extended {pi}-system and organic acid ligands play a crucial role in the formation of the final supramolecular frameworks. Moreover, thermal properties and fluorescence of 1-7 are also investigated. -- Graphical abstract: Seven new supramolecular architectures have been successfully isolated under hydrothermal conditions by reactions of different phen derivatives and Cd(II) salts together with organic carboxylate anions auxiliary ligands. Display Omitted Research highlights: {yields} Complexes 1-7 are 0D or 1D polymeric structure, the {pi}-{pi} stacking and H-bonding interactions extend the complexes into 3D supramolecular network. To our knowledge, systematic study on {pi}-{pi} stacking and H-bonding interactions in cadmium(II) complexes are still limited. {yields} The structural

  12. Phase II Accident Investigation Board Briefing | Department of...

    Office of Environmental Management (EM)

    Phase II Accident Investigation Board Briefing Phase II Accident Investigation Board Briefing Topic: Ted Wyka DOE, Provided a Brief on the Findings in the WIPP Accident ...

  13. Galaxy evolution and large-scale structure in the far-infrared. II. The IRAS faint source survey

    SciTech Connect (OSTI)

    Lonsdale, C.J.; Hacking, P.B.; Conrow, T.P.; Rowan-Robinson, M. Queen Mary College, London )

    1990-07-01

    The new IRAS Faint Source Survey data base is used to confirm the conclusion of Hacking et al. (1987) that the 60 micron source counts fainter than about 0.5 Jy lie in excess of predictions based on nonevolving model populations. The existence of an anisotropy between the northern and southern Galactic caps discovered by Rowan-Robinson et al. (1986) and Needham and Rowan-Robinson (1988) is confirmed, and it is found to extend below their sensitivity limit to about 0.3 Jy in 60 micron flux density. The count anisotropy at f(60) greater than 0.3 can be interpreted reasonably as due to the Local Supercluster; however, no one structure accounting for the fainter anisotropy can be easily identified in either optical or far-IR two-dimensional sky distributions. The far-IR galaxy sky distributions are considerably smoother than distributions from the published optical galaxy catalogs. It is likely that structure of the large size discussed here have been discriminated against in earlier studies due to insufficient volume sampling. 105 refs.

  14. A new 3D nickel(II) framework composed of large rings: Ionothermal synthesis and crystal structure

    SciTech Connect (OSTI)

    Xu Ling; Choi, Eun-Young; Kwon, Young-Uk

    2008-11-15

    Ionothermal reaction between Ni{sup 2+} and 1,3,5-benzentricarboxylic acid (H{sub 3}BTC) with [AMI]Cl (AMI=1-amyl-3-methylimidazolium) as the reaction medium produced a novel 3D mixed-ligand metal-organic framework [AMI][Ni{sub 3}(BTC){sub 2}(OAc)(MI){sub 3}] (1) (MI=1-methylimidazole) with [AMI]{sup +} incorporated in the framework. The framework is formed by connecting 2D planes, made up of 32- and 48-membered rings, through 1D chains composed of 32-membered rings. The two BTC{sup 3-} ligands in 1 show the same connectivity mode with two bidentate and one {mu}{sub 2} bridging carboxylic groups. This is a new connectivity mode to the already existing 17 in the Ni-BTC system. The role of MI and [AMI]Cl in the structure formation is discussed. - Graphical Abstract: A novel 3D framework [AMI][Ni{sub 3}(BTC){sub 2}(OAc)(MI){sub 3}] is obtained in ionothermal system with [AMI]{sup +} incorporating in the cavities as structure directing template and BTC{sup 3-} showing a new coordination fashion. The 3D framework is constructed by 2D layers linked with 1D double chains. The title compound has the middle thermal stability at ca. 280 deg. C.

  15. Finding Large Aperture Fractures in Geothermal Resource Areas Using a Three-Component Long-Offset Surface Seismic Survey, PSInSAR and Kinematic Structural Analysis

    SciTech Connect (OSTI)

    Teplow, William J.; Warren, Ian

    2015-08-12

    The DOE cost-share program applied innovative and cutting edge seismic surveying and processing, permanent scatter interferometry-synthetic aperture radar (PSInSAR) and structural kinematics to the exploration problem of locating and mapping largeaperture fractures (LAFs) for the purpose of targeting geothermal production wells. The San Emidio geothermal resource area, which is under lease to USG, contains production wells that have encountered and currently produce from LAFs in the southern half of the resource area (Figure 2). The USG lease block, incorporating the northern extension of the San Emidio geothermal resource, extends 3 miles north of the operating wellfield. The northern lease block was known to contain shallow thermal waters but was previously unexplored by deep drilling. Results of the Phase 1 exploration program are described in detail in the Phase 1 Final Report (Teplow et al., 2011). The DOE cost shared program was completed as planned on September 30, 2014. This report summarizes results from all of Phase 1 and 2 activities.

  16. Part II

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    December 31, 2015 Part II Department of Defense General Services Administration National ... Rules and Regulations DEPARTMENT OF DEFENSE GENERAL SERVICES ADMINISTRATION NATIONAL ...

  17. EA-1809: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1809: Finding of No Significant Impact White Earth Nation Wind Energy Project II, Becker and Mahnomen Counties, MN DOE's Golden Field Office has...

  18. EA-1904: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1904: Finding of No Significant Impact Linac Coherent Light Source II at Stanford Linear Accelerator Laboratory, San Mateo, CA Based on the findings in the EA, DOE has...

  19. Synthesis and X-ray structure analysis of a new binuclear Schiff base Co(II) complex with the ligand N,N'-bis(3-methoxysalicylidene)-1,4-butanediamine

    SciTech Connect (OSTI)

    Nasr-Esfahani, M.

    2009-12-15

    The title binuclear complex, tris[N,N-bis(3-methoxysalicylidene)-1,4-diaminobutane] dicobalt(II), C{sub 60}H{sub 70}Co{sub 2}N{sub 6}O{sub 15}, was prepared by the reaction of the tetradentate Schiff base ligand bis(3-methoxysalicylidene)-1,4-diaminobutane and Co(CH{sub 3}COO){sub 2} . 4H{sub 2}O in a ethanol solution and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two Co(II) ions are bridged by one N{sup 0},N'-bis(3-methoxysalicylidene)-1,4-diaminobutane. The two Co(II) ions, have two distorted octahedral coordination involving two O and two N atoms.

  20. Synthesis, crystal structure and magnetic characterization of metal(II) coordination polymers based on 2-carboxyethylphosphonic acid and 1,10-phenanthroline (metal=Cu, Co, Cd)

    SciTech Connect (OSTI)

    Fernandez-Zapico, Eva; Montejo-Bernardo, Jose Manuel; D'Vries, Richard; Garcia, Jose R.; Garcia-Granda, Santiago; Rodriguez Fernandez, Jesus; Pedro, Imanol de; Blanco, Jesus A.

    2011-12-15

    Three non-isostructural metal(II) coordination polymers (metal=copper, cobalt, cadmium) were synthesized under the same mild hydrothermal conditions (T=408 K) by mixture of the corresponding metal acetate with 2-carboxyethylphosphonic acid and 1,10-phenanthroline (1:1:1 M ratio) and their structures were determined by single-crystal X-ray diffraction. Cu{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2}(H{sub 2}O){sub 2} and Cd{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2} are triclinic (space group P-1) with a=7.908(5) A, b=10.373(5) A, c=11.515(5) A, {alpha}=111.683(5) Degree-Sign , {beta}=95.801(5) Degree-Sign , {gamma}=110.212(5) Degree-Sign (T=120 K), and a=8.162(5) A, b=9.500(5) A, c=11.148(5) A, {alpha}=102.623(5) Degree-Sign , {beta}=98.607(5) Degree-Sign , {gamma}=113.004(5) Degree-Sign (T=293 K), respectively. In contrast, [Co{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2}({mu}-OH{sub 2})](H{sub 2}O) is orthorhombic (space group Pbcn) with a=21.1057(2) A, b=9.8231(1) A, c=15.4251(1) A (T=120 K). For these three compounds, structural features, including H-bond network and the {pi}-{pi} stacking interactions, and thermal stability are reported and discussed. None of the materials present a long-range magnetic order in the range of temperatures investigated from 300 K down to 1.8 K. - Graphical abstract: In same synthetic conditions, both the chemical and structural features of three transition metal(II) coordination polymers based on 2-carboxyethylphosphonate and 1-10 Prime -phenanthroline are influenced by the metal cation characteristics, leading to non-homologous materials with different properties, which show the high chemical versatility of this interesting system. Highlights: Black-Right-Pointing-Pointer Non-isostructural metal coordination polymers were synthesized under mild hydrothermal conditions. Black-Right-Pointing-Pointer Ligand's flexibility

  1. PARS II Training Materials | Department of Energy

    Energy.gov (indexed) [DOE]

    attachments, and running standard, pre-built reports. PARS 102 Presentation PARS 102 Workbook PARS 103 - Updating Projects and Reporting Introduction to PARS II, finding and...

  2. PARS II

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... September 9, 2010 (V1.1) PARS II 103 Project Updating and Reporting Page 49 4. Click to begin entering funding values. 5. Click + sign to expand detail for OPC, TEC, and UND, if ...

  3. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume II. Data repository and reports published during fiscal year 1979-1980: regional structure, surface structure, surface fractures, hydrology

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This volume comprises appendices giving regional structure data, surface structure data, surface fracture data, and hydrology data. The fracture data covers oriented Devonian shale cores from West Virginia, Ohio, Virginia, Pennsylvania, and Kentucky. The subsurface structure of the Eastern Kentucky gas field is also covered. (DLC)

  4. Three Pb{sup II} coordination polymers based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid: Syntheses, crystal structures, and fluorescent properties

    SciTech Connect (OSTI)

    Yu, Xiao-Yang; Xin, Rui; Gao, Wei-Ping; Wang, Na; Zhang, Xiao; Yang, Yan-Yan; Qu, Xiao-Shu

    2013-08-15

    Three lead coordination polymers, [PbCl(C{sub 10}H{sub 6}N{sub 3}O{sub 4})(H{sub 2}O)·H{sub 2}O]{sub n} (1), [Pb(C{sub 10}H{sub 6}N{sub 3}O{sub 4}){sub 2}(H{sub 2}O)]{sub n} (2) and [Pb{sub 3}(C{sub 10}H{sub 5}N{sub 3}O{sub 4}){sub 3}]{sub n} (3) (C{sub 10}H{sub 7}N{sub 3}O{sub 4}=2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid), have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. In 1, Cl anions connected neighboring wave-like 2D layers, which are constructed with left- and right-handed helical chains, into a 3D network structure with a (6{sup 3})(6{sup 5}·8) topology. In 2, Pb cations are linked into a 3D 6{sup 6} network with left- and right-handed helixes by μ{sub 2}-bridging C{sub 10}H{sub 6}N{sub 3}O{sub 4}{sup −} ligands. In 3, C{sub 10}H{sub 5}N{sub 3}O{sub 4}{sup 2−} ligands link Pb{sub 6}O{sub 12} clusters into a 3D (4{sup 12}·6{sup 3}) network. Their fluorescent properties were also investigated. - Graphical abstract: Three 3D lead compounds based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid have been hydrothermally synthesized. Four new coordination modes of the organic ligand are first reported. Display Omitted - Highlights: • Three new Pb(II) complexes have been synthesized and characterized. • Left- and right-handed helical chains can be found in the 3D networks of 1 and 2. • Pb{sub 6}O{sub 12} clusters are connected into (4{sup 12}·6{sup 3}) network in 3.

  5. H I ABSORPTION TOWARD H II REGIONS AT SMALL GALACTIC LONGITUDES

    SciTech Connect (OSTI)

    Jones, C.; Dickey, J. M.; Dawson, J. R.; McClure-Griffiths, N. M.; Anderson, L. D.; Bania, T. M.

    2013-09-10

    We make a comprehensive study of H I absorption toward H II regions located within |l| < 10 Degree-Sign . Structures in the extreme inner Galaxy are traced using the longitude-velocity space distribution of this absorption. We find significant H I absorption associated with the Near and Far 3 kpc Arms, the Connecting Arm, Bania's Clump 1, and the H I Tilted Disk. We also constrain the line-of-sight distances to H II regions, by using H I absorption spectra together with the H II region velocities measured by radio recombination lines.

  6. Find Los Alamos Publications

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Los Alamos Publications Find Los Alamos Publications Some of these resources are Lab-only and will require SSL Portal. Questions? 667-5809 Email Current Lab publications 1663 ...

  7. Thermodynamical and structural insights of orange II adsorption by Mg{sub R}AlNO{sub 3} layered double hydroxides

    SciTech Connect (OSTI)

    Mustapha Bouhent, Mohamed; Derriche, Zoubir; Denoyel, Renaud; Prevot, Vanessa; Forano, Claude

    2011-05-15

    [Mg{sub 1-x} Al{sub x}(OH){sub 2}][(NO{sub 3}){sub x}, nH{sub 2}O] Layered Double Hydroxide (LDH) sorbents with variable Mg/Al molar (R=(1-x)/x) ratios were investigated for adsorption of azo dye, orange II (OII) at various pH and temperature conditions. Mg{sub 2}AlNO{sub 3} displays the highest adsorption capacity with 3.611 mmol of OII per gram of Mg{sub 2}AlNO{sub 3} at 40 {sup o}C. Adsorption isotherms have been fitted using the Langmuir model and free energy of adsorption ({Delta}G{sup o}), enthalpy ({Delta}H{sup o}) and entropy ({Delta}S{sup o}) were calculated. The experimental values for {Delta}G{sup o} in temperature range between 10 and 40 {sup o}C were found to be negative indicating that a spontaneous process occurred. Positive calculated enthalpy values, characteristic of an endothermic process were found. Characterization of solids (PXRD, FTIR, UV-vis, TGA/DTA, adsorption isotherm BET analysis, SEM and Zetametry) before and after adsorption showed that adsorption proceeds in two steps. First, adsorption occurs at the LDH surface, followed by intercalation via anion exchange. -- Graphical Abstract: Structural and thermodynamical insight of adsorption/Intercalation of OII in Mg{sub R}Al LDH Display Omitted Highlights: {yields} The nitrate containing hydrotalcite-like compounds (Mg{sub R}AlNO{sub 3} LDH) were prepared by the coprecipitation method. {yields} Adsorption of anionic orange dye(OII) is studied on LDHs at different temperatures. {yields} The adsorption process is well described by the Langmuir isotherm model. {yields} Mg{sub 2}AlNO{sub 3} displays the highest adsorption capacity with 3.611 mmol of OII per gram of Mg{sub 2}AlNO{sub 3} at 40 {sup o}C. {yields} Adsorption process does not occur on the surface of the LDH only but an intercalation process is also occurring concomitantly according to the thermodynamical values.

  8. BORE II

    Energy Science and Technology Software Center (OSTI)

    2015-08-01

    Bore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and for improving remediation of contaminated sites. Termed "hydrophysical logging," this technology is based on the concept of measuring repeated depth profiles of fluid electric conductivity in a borehole that is pumping. As fluid enters the wellbore, its distinct electric conductivity causes peaks in the conductivity log that grow and migratemore » upward with time. Analysis of the evolution of the peaks enables characterization of groundwater flow distribution more quickly, more cost effectively, and with higher resolution than ever before. Combining the unique interpretation software Bore II with advanced downhole instrumentation (the hydrophysical logging tool), the method quantifies inflow and outflow locations, their associated flow rates, and the basic water quality parameters of the associated formation waters (e.g., pH, oxidation-reduction potential, temperature). In addition, when applied in conjunction with downhole fluid sampling, Bore II makes possible a complete assessment of contaminant concentration within groundwater.« less

  9. BORE II

    SciTech Connect (OSTI)

    2015-08-01

    Bore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and for improving remediation of contaminated sites. Termed "hydrophysical logging," this technology is based on the concept of measuring repeated depth profiles of fluid electric conductivity in a borehole that is pumping. As fluid enters the wellbore, its distinct electric conductivity causes peaks in the conductivity log that grow and migrate upward with time. Analysis of the evolution of the peaks enables characterization of groundwater flow distribution more quickly, more cost effectively, and with higher resolution than ever before. Combining the unique interpretation software Bore II with advanced downhole instrumentation (the hydrophysical logging tool), the method quantifies inflow and outflow locations, their associated flow rates, and the basic water quality parameters of the associated formation waters (e.g., pH, oxidation-reduction potential, temperature). In addition, when applied in conjunction with downhole fluid sampling, Bore II makes possible a complete assessment of contaminant concentration within groundwater.

  10. A novel inorganic-organic compound: Synthesis and structural characterization of tin(II) phenylbis(phosphonate), Sn{sub 2}(PO{sub 3}C{sub 6}H{sub 4}PO{sub 3})

    SciTech Connect (OSTI)

    Subbiah, Ayyappan; Bhuvanesh, Nattamai; Clearfield, Abraham . E-mail: clearfield@mail.chem.tamu.edu

    2005-04-15

    A novel tin(II) phenylbis(phosphonate) compound has been synthesized hydrothermally and its structure has been determined by single crystal X-ray diffraction. The structure is monoclinic, space group P2{sub 1}/c (no. 14), a=4.8094(4), b=16.2871(13), c=6.9107(6)A; {beta}=106.292(6){sup o}, V=519.59(7)A{sup 3}, Z=2. The three-dimensional structure consists of 3-coordinated tin and 4-coordinated phosphorus double layers separated (pillared) by phenyl rings. These phenyl rings are placed 4.8A apart along the a-axis in the structure resulting in lower surface area ({approx}14m{sup 2}/g). The porosity has been increased by replacing phenyl groups by methyl groups ({approx}31m{sup 2}/g)

  11. Find Theses and Dissertations

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Theses and Dissertations Find Theses and Dissertations Most of the theses sources below are publicly accessible. Questions? 667-5809 Email Electronic Databases Open Access Theses and Dissertations - Results limited to freely accessible, full-text ETDs Center for Research Libraries - Foreign Dissertations Collection Theses Canada - Canadian theses from Library and Archives Canada EThOS (Electronic Theses Online Service) - UK theses from the British Library Networked Digital Library of Theses and

  12. Find eBooks

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    eBooks Find eBooks Many of these resources are Lab-only and will require Remote Access. Question? 667-5809 Email The Library Catalog offers the most comprehensive search for scientific Ebooks. The following is a selection of Ebook sources, in case you want to search them directly. [See also Conference Proceedings.] Key eBook Providers Ebook Central information - online access to thousands of ebooks across scientific subject areas Elsevier ScienceDirect - Includes books, book series, and

  13. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²⁺ or Ca²⁺ substituted by Sr²⁺

    DOE PAGES-Beta [OSTI]

    Vogt, Leslie; Ertem, Mehmed Z.; Pal, Rhitankar; Brudvig, Gary W.; Batista, Victor S.

    2015-01-15

    The oxygen-evolving complex of photosystem II can function with either Ca²⁺ or Sr²⁺ as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S₁) and in a series of reduced states (S₀, S₋₁, and S-₂). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²⁺ or Sr²⁺ are most consistent with the S-₂ state, Mn₄[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²⁺/Sr²⁺ substitutionmore » results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²⁺ as the heterocation, suggesting that this water may play a critical role during water oxidation.« less

  14. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²⁺ or Ca²⁺ substituted by Sr²⁺

    SciTech Connect (OSTI)

    Vogt, Leslie; Ertem, Mehmed Z.; Pal, Rhitankar; Brudvig, Gary W.; Batista, Victor S.

    2015-01-15

    The oxygen-evolving complex of photosystem II can function with either Ca²⁺ or Sr²⁺ as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S₁) and in a series of reduced states (S₀, S₋₁, and S-₂). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²⁺ or Sr²⁺ are most consistent with the S-₂ state, Mn₄[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²⁺/Sr²⁺ substitution results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²⁺ as the heterocation, suggesting that this water may play a critical role during water oxidation.

  15. Raman spectra of Cu{sub 2}B{sup II}C{sup IV}X{sub 4}{sup VI} magnetic quaternary semiconductor compounds with tetragonal stannite type structure

    SciTech Connect (OSTI)

    Rincón, C. Quintero, M.; Power, Ch.; Moreno, E.; Quintero, E.; Morocoima, M.; Henao, J. A.; Macías, M. A.

    2015-05-28

    A comparative study of the Raman spectra of Cu{sub 2}B{sup II}C{sup IV}S{sub 4}{sup VI} and Cu{sub 2}B{sup II}C{sup IV}Se{sub 4}{sup VI}(where B = Mn or Fe) magnetic quaternary semiconductor compounds with stannite-type structure (I4{sup ¯}2m) has been done. Most of the fourteen Raman lines expected for these materials were observed in the spectra. The two strongest lines observed have been assigned to the IR inactive A{sub 1}{sup 1} and A{sub 1}{sup 2} stannite modes that originated from the motion of the S or Se anion around the Cu and C{sup IV} cations remaining at rest. The shift in the frequency of these two lines of about 150 cm{sup −1} to lower energies observed in Cu{sub 2}B{sup II}C{sup IV}Se{sub 4}{sup VI} compounds as compared to those in Cu{sub 2}B{sup II}C{sup IV}S{sub 4}{sup VI} ones, can then be explained as due to the anion mass effect. Based on the fact that values of these frequencies depend mainly on anion mass and bond-stretching forces between nearest-neighbor atoms, the vibrational frequencies v{sup ¯}(A{sub 1}{sup 2}) and v{sup ¯}(A{sub 1}{sup 2}) of both modes for several Cu{sub 2}B{sup II}C{sup IV}X{sub 4}{sup VI} stannite compounds (where X = S, Se, or Te) very close to the experimental data reported for these materials were calculated from a simple model that relates these stretching forces to the anion-cation bond-distances.

  16. Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands

    SciTech Connect (OSTI)

    Wang, G.-F.; Zhang, X.; Sun, S.-W. Han, Q.-P.; Yang, X.; Li, H.; Ma, H.-X.; Yao, C.-Z.; Sun, H.; Dong, H.-B.

    2015-12-15

    3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L{sup 1}, 1) and its Mn(II) complex, [Mn(L{sup 1}){sub 2}(SCN){sub 2}]{sub ∞} (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L{sup 1} ligands, two SCN-ligands, and two oxygen atoms of other two L{sup 1} ligands to form a distorted octahedral geometry. Therefore, each L{sup 1} links Mn ions through the O and N atoms to generate 2D sheet structure.

  17. Removal of Ca2+ from the Oxygen-Evolving Complex in Photosystem II Has Minimal Effect on the Mn4O5 Core Structure: A Polarized Mn X-ray Absorption Spectroscopy Study

    DOE PAGES-Beta [OSTI]

    Lohmiller, Thomas; Shelby, Megan L.; Long, Xi; Yachandra, Vittal K.; Yano, Junko

    2015-05-19

    We studied Ca2+ -depleted and Ca2+ -reconstituted spinach photosystem II using polarized X-ray absorption spectroscopy of oriented PS II preparations to investigate the structural and functional role of the Ca2+ ion in the Mn4O5Ca cluster of the oxygen-evolving complex (OEC). Samples were prepared by low pH/citrate treatment as one-dimensionally ordered membrane layers and poised in the Ca2+ -depleted S1 (S1') and S2 (S2') states, the S2'YZ• state, at which point the catalytic cycle of water oxidation is inhibited, and the Ca2+ -reconstituted S1 state. Polarized Mn K-edge XANES and EXAFS spectra exhibit pronounced dichroism. Polarized EXAFS data of all statesmore » of Ca2+ -depleted PS II investigated show only minor changes in distances and orientations of the Mn-Mn vectors compared to the Ca2+ -containing OEC, which may be attributed to some loss of rigidity of the core structure. Thus, removal of the Ca2+ ion does not lead to fundamental distortion or rearrangement of the tetranuclear Mn cluster, which indicates that the Ca2+ ion in the OEC is not critical for structural maintenance of the cluster, at least in the S1 and S2 states, but fulfills a crucial catalytic function in the mechanism of the water oxidation reaction. On the basis of this structural information, reasons for the inhibitory effect of Ca2+ removal are discussed, attributing to the Ca2+ ion a fundamental role in organizing the surrounding (substrate) water framework and in proton-coupled electron transfer to YZ• (D1-Tyr161).« less

  18. PARS II TRAINING

    Energy.gov [DOE]

    PARS II 102 Monthly Updating and Reporting Training Workbook (PARS II Release 1.1), September 13, 2010.

  19. Atomic structure of the sweet-tasting protein thaumatin I at pH 8.0 reveals the large disulfide-rich region in domain II to be sensitive to a pH change

    SciTech Connect (OSTI)

    Masuda, Tetsuya; Ohta, Keisuke; Mikami, Bunzo; Kitabatake, Naofumi; Tani, Fumito

    2012-03-02

    Highlights: Black-Right-Pointing-Pointer Structure of a recombinant thaumatin at pH 8.0 determined at a resolution of 1.0 A. Black-Right-Pointing-Pointer Substantial fluctuations of a loop in domain II was found in the structure at pH 8.0. Black-Right-Pointing-Pointer B-factors for Lys137, Lys163, and Lys187 were significantly affected by pH change. Black-Right-Pointing-Pointer An increase in mobility might play an important role in the heat-induced aggregation. -- Abstract: Thaumatin, an intensely sweet-tasting plant protein, elicits a sweet taste at 50 nM. Although the sweetness remains when thaumatin is heated at 80 Degree-Sign C for 4 h under acid conditions, it rapidly declines when heating at a pH above 6.5. To clarify the structural difference at high pH, the atomic structure of a recombinant thaumatin I at pH 8.0 was determined at a resolution of 1.0 A. Comparison to the crystal structure of thaumatin at pH 7.3 and 7.0 revealed the root-mean square deviation value of a C{alpha} atom to be substantially greater in the large disulfide-rich region of domain II, especially residues 154-164, suggesting that a loop region in domain II to be affected by solvent conditions. Furthermore, B-factors of Lys137, Lys163, and Lys187 were significantly affected by pH change, suggesting that a striking increase in the mobility of these lysine residues, which could facilitate a reaction with a free sulfhydryl residue produced via the {beta}-elimination of disulfide bonds by heating at a pH above 7.0. The increase in mobility of lysine residues as well as a loop region in domain II might play an important role in the heat-induced aggregation of thaumatin above pH 7.0.

  20. Synthesis, structure, magnetism and nuclease activity of tetranuclear copper(II) phosphonates contatining ancillary 2,2'-bipyridine or 1,10-phenanthroline ligands

    SciTech Connect (OSTI)

    Chandrasekhar, V.; Azhakar, R.; Senapati, T.; Thilagar, P.; Gosh, S.; Verma, S.; Boomishankar, R.; Steiner, A.; Kogerler, P.

    2008-01-07

    The reaction of cyclohexylphosphonic acid (C{sub 6}H{sub 11}PO{sub 3}H{sub 2}), anhydrous CuCl{sub 2} and 2,2{prime}-bipyridine (bpy) in the presence of triethylamine followed by a metathesis reaction with KNO{sub 3} afforded [Cu{sub 4}({micro}-Cl){sub 2}({micro}{sub 3}-C{sub 6}H{sub 11}PO{sub 3}){sub 2}(bpy){sub 4}](NO{sub 3}){sub 2} (1). In an analogous reaction involving Cu(OAc){sub 2} {center_dot} H{sub 2}O, the complex [Cu{sub 4}({micro}-CH{sub 3}COO){sub 2}({micro}{sub 3}-C{sub 6}H{sub 11}PO{sub 3}){sub 2}(2,2-bpy){sub 4}](CH{sub 3}COO){sub 2} (2) has been isolated. The three-component reaction involving Cu(NO{sub 3}){sub 2} {center_dot} 3H{sub 2}O, cyclohexylphosphonic acid and 2,2{prime}-bipyridine in the presence of triethylamine afforded the tetranuclear assembly [Cu{sub 4}({micro}-OH)({micro}{sub 3}-C{sub 6}H{sub 11}PO{sub 3}){sub 2}(2,2{prime}-bpy){sub 4} (H{sub 2}O){sub 2}](NO{sub 3}){sub 3} (3). Replacing 2,2{prime}-bipyridine with 1,10-phenanthroline (phen) in the above reaction resulted in [Cu{sub 4}({micro}-OH)({micro}{sub 3}-C{sub 6}H{sub 11}PO{sub 3}){sub 2}(phen){sub 4}(H{sub 2}O){sub 2}](NO{sub 3}){sub 3} (4). In all the copper(II) phosphonates (1-4) the two phosphonate ions bridge the four copper(II) ions in a capping coordination action. Each phosphonate ion bridges four copper(II) ions in a {micro}{sub 4}, coordination mode or 4.211 of the Harris notation. Variable-temperature magnetic studies on 1-4 reveal that all four complexes exhibit moderately strong intramolecular antiferromagnetic coupling. The DNA cleavage activity of complexes 1-4 is also described. Compounds 1 and 3 were able to completely convert the supercoiled pBR322 DNA form I to nick form II without any co-oxidant. In contrast, 50% conversion occurred with 2 and 40% with 4. In the presence of magnesium monoperoxyphthalate all four compounds achieved rapid conversion of form I to form II.

  1. Hydrothermal syntheses, crystal structures and luminescence properties of zinc(II) and cadmium(II) coordination polymers based on bifunctional 3,2 Prime :6 Prime ,3 Prime Prime -terpyridine-4 Prime -carboxylic acid

    SciTech Connect (OSTI)

    Li, Na; Guo, Hui-Lin; Hu, Huai-Ming; Song, Juan; Xu, Bing; Yang, Meng-Lin; Dong, Fa-Xin; Xue, Gang-Lin

    2013-02-15

    Five new coordination polymers, [Zn{sub 2}(ctpy){sub 2}Cl{sub 2}]{sub n} (1), [Zn{sub 2}(ctpy){sub 2}(ox)(H{sub 2}O){sub 2}]{sub n} (2), [Zn{sub 2}(ctpy)(3-btc)(H{sub 2}O)]{sub n}{center_dot}0.5nH{sub 2}O (3), [Cd(ctpy){sub 2}(H{sub 2}O)]{sub n} (4), [Cd{sub 4}(ctpy){sub 2}(2-btc){sub 2}(H{sub 2}O){sub 2}]{sub n}{center_dot}2nH{sub 2}O (5), (Hctpy=3,2 Prime :6 Prime ,3 Prime Prime -terpyridine-4 Prime -carboxylic acid, H{sub 2}ox=oxalic acid, H{sub 3}(3-btc)=1,3,5-benzenetricarboxylic acid, H{sub 3}(2-btc)=1,2,4-benzenetricarboxylic acid) have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Compounds 1-2 are a one-dimensional chain with weak interactions to form 3D supramolecular structures. Compound 3 is a 4-nodal 3D topology framework comprised of binuclear zinc units and (ctpy){sup -} anions. Compound 4 shows two dimensional net. Compound 5 is a (4,5,6)-connected framework with {l_brace}4{sup 4}{center_dot}6{sup 2}{r_brace}{l_brace}4{sup 6}{center_dot}6{sup 4}{r_brace}{sub 2}{l_brace}4{sup 9}{center_dot}6{sup 6}{r_brace} topology. In addition, the thermal stabilities and photoluminescence properties of 1-5 were also studied in the solid state. - Graphical abstract: Five new Zn/Cd compounds with 3,2 Prime :6 Prime ,3 Prime Prime -terpyridine-4 Prime -carboxylic acid were prepared. The photoluminescence and thermal stabilities properties of 1-5 were investigated in the solid state. Highlights: Black-Right-Pointing-Pointer Five new zinc/cadmium metal-organic frameworks have been hydrothermal synthesized. Black-Right-Pointing-Pointer The structural variation is attributed to the diverse metal ions and auxiliary ligand. Black-Right-Pointing-Pointer Compounds 1-5 exhibit 1D ring chain, 2D layer and 3D open-framework, respectively. Black-Right-Pointing-Pointer These compounds exhibit strong solid state luminescence emission at room temperature.

  2. PARS II TRAINING

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    13, 2010 (V1.1) PARS II 102 Monthly Updating and Reporting i Project Assessment and Reporting System PARS II 102 Monthly Updating and Reporting Training Workbook (PARS II Release ...

  3. Synthesis, structures and magnetic properties of two 3D 3,4-pyridinedicarboxylate bridged manganese(II) coordination polymers incorporating 1D helical Mn(carboxylate){sub 2} chain or Mn{sub 3}(OH){sub 2} chain

    SciTech Connect (OSTI)

    Tong Mingliang . E-mail: cestml@zsu.edu.cn; Wang Jing; Hu Sheng

    2005-05-15

    The hydrothermal reactions of MnCl{sub 2}.4H{sub 2}O, 3,4-pyridinedicarboxylic acid (3,4-pydaH{sub 2}) and triethylamine in aqueous medium yield two 3D metal-organic hybrid materials, [Mn(3,4-pyda)] (1) and [Mn{sub 3}(OH){sub 2}(3,4-pyda){sub 2}(H{sub 2}O){sub 2}] (2), respectively. In both complexes, each 3,4-pyda acts as a pentadentate ligand to connect five Mn(II) atoms via the pyridyl group and the two {mu}{sub 2}-carboxylate groups (one in syn,anti-mode and one in syn-syn mode for 1 and both in syn,anti-mode for 2). Complex 1 possesses an interesting 3D coordination polymeric structure incorporating 1D helical Mn({mu}{sub 2}-carboxylate){sub 2} chain units, in which each Mn(II) atom is coordinated in less common square pyramidal geometry to four carboxylato oxygen atoms and one pyridyl nitrogen atom. Each 3,4-pyda links three helical Mn({mu}{sub 2}-carboxylate){sub 2} chains and each Mn({mu}{sub 2}-carboxylate){sub 2} chain is linked by other eight helical Mn({mu}{sub 2}-carboxylate){sub 2} chains via sharing 3,4-pyda bridges. Complex 2 is a 3D coordination network consisting of 1D Mn{sub 3}(OH){sub 2} chains and 3,4-pyda bridges. The repeating trimeric structural unit in the manganese(II) hydroxide chain consists of two edge-sharing symmetry-related manganese octahedra linked via {mu}{sub 3}-OH to a vertex of Mn{sub 2} octahedron. Each 3,4-pyda links three Mn{sub 3}(OH){sub 2} chains and each Mn{sub 3}(OH){sub 2} chain is linked by other six Mn{sub 3}(OH){sub 2} chains via 3,4-pyda bridges, resulting in a 3D coordination solid. Magnetic measurements reveal that a weak antiferromagnetic interaction between the Mn{sup II} ions occurs in complex 1 and a 3D magnetic ordering at about 7.0K in complex 2.

  4. ARM - RHUBC II Instruments

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Instruments Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II Backgrounder (PDF, 300K) News & Press Images Experiment Planning RHUBC-II Proposal Abstract Science Plan (PDF, 267KB) Science Objectives Contacts Eli Mlawer, Principal Investigator Dave Turner, Principal Investigator RHUBC II Instruments RHUBC-II Instruments - Cerro Toco, Chile Guest Instruments Instrument

  5. Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene

    SciTech Connect (OSTI)

    Su Zhi; Xu Jing; Huang Yongqing; Okamura, Taka-aki; Liu Guangxiang; Bai Zhengshuai; Chen Mansheng; Chen Shuisheng; Sun Weiyin

    2009-06-15

    Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN{sub 3}, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L){sub 2}(H{sub 2}O){sub 2}].3H{sub 2}O (1), [Cd{sub 3}(L){sub 5}(OH)] (2) and [Ag{sub 2}(L){sub 2}] (3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analysis revealed that 1 has 1D hinged-chain structure containing 24-membered ring with a Cd...Cd intra-chain distance of 13.18 A, while 2 is 1D ladder-like chain with Cd{sub 3}O core. However, the complex 3 is a 3D 4-connected framework with Schlaefli symbol of (4{sup 2}.6{sup 3}.8)(4{sup 3}.6{sup 2}.8). The L{sup -} ligand was found to show four different coordination modes in 1-3, as 2-, 3- and 4-connector, respectively. The results indicate that the coordination modes of the ligand and metal centers with different coordination geometry have great influence on the structures of the complexes. In addition, the photoluminescence of the complexes were studied in the solid state at room temperature. - Graphical abstract: Three novel coordination polymers were obtained with in situ ligand formation through Sharpless's [3+2] reaction. The structure and luminescence properties of the complexes were investigated.

  6. Synthesis and Structural Features of [4,4'-Diisopropoxyester-2,2'-bipyridine], [Dichloro(4,4'-diisopropoxyester-2,2'-bi-pyridine)-platinum(ii)] and Its Dichloromethane Solvated Pseudo-Polymorph: Versatile Supramolecular Interactions

    DOE PAGES-Beta [OSTI]

    Browning, Charles; Nesterov, Vladimir N.; Wang, Xiaoping; Omary, Mohammad A.

    2015-06-03

    We report that the organic ligand 4,4'-diisopropoxyester-2,2'-bipyridine, C18H20N2O4 (1), crystallizes in the triclinic crystal system P-1 and the molecule occupies a special position in the unit cell. In the crystal, molecules form stacks with partial overlapping of the pyridine rings. The Pt(II) dichloro complex of 1 crystallizes from a mixture of ethanol/hexane and from dichloromethane to form orange and yellow crystals, respectively. The orange non-solvated crystals of the (bipyridine)(dichloro)platinum(II) complex C18H20N2O4PtCl2 (2) crystallize in the triclinic crystal system P-1 as well with two independent molecules in the unit cell. In the crystal packing, molecules form two types of dimers withmore » Pt1 ··· Pt1A and Pt2···Pt2A distances of 3.478 and 5.186 angstrom respectively. The yellow crystals, as a solvated pseudo-polymorph C18H20N2O4PtCl2·1.5 CH2Cl2 (3) also crystallize in the triclinic crystal system P-1 with two independent molecules in the unit cell. In the crystal packing, molecules form Pt2 ···Pt1 ···Pt1A ···Pt2A intermolecular contacts with alternating distances 3.501 and 3.431 angstrom, respectively, forming infinite chains. Graphical Abstract The dichloro(bipyridine)platinum complex, dichloro(4,4'-diisopropoxyester-2,2'-bipyridine)platinum(II), forms single crystals as a stable non-solvated form and a solvated polymorph with dramatically different supramolecular structure and short contacts.« less

  7. Biofoam II

    DOE Patents [OSTI]

    Morrison, Robert L.

    1994-01-01

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties.

  8. Biofoam II

    DOE Patents [OSTI]

    Morrison, R.L.

    1994-11-01

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties. 1 fig.

  9. Development of improved processing and evaluation methods for high reliability structural ceramics for advanced heat engine applications Phase II. Final report

    SciTech Connect (OSTI)

    Pujari, V.J.; Tracey, D.M.; Foley, M.R.

    1996-02-01

    The research program had as goals the development and demonstration of significant improvements in processing methods, process controls, and nondestructive evaluation (NDE) which can be commercially implemented to produce high reliability silicon nitride components for advanced heat engine applications at temperatures to 1370{degrees}C. In Phase I of the program a process was developed that resulted in a silicon nitride - 4 w% yttria HIP`ed material (NCX 5102) that displayed unprecedented strength and reliability. An average tensile strength of 1 GPa and a strength distribution following a 3-parameter Weibull distribution were demonstrated by testing several hundred buttonhead tensile specimens. The Phase II program focused on the development of methodology for colloidal consolidation producing green microstructure which minimizes downstream process problems such as drying, shrinkage, cracking, and part distortion during densification. Furthermore, the program focused on the extension of the process to gas pressure sinterable (GPS) compositions. Excellent results were obtained for the HIP composition processed for minimal density gradients, both with respect to room-temperature strength and high-temperature creep resistance. Complex component fabricability of this material was demonstrated by producing engine-vane prototypes. Strength data for the GPS material (NCX-5400) suggest that it ranks very high relative to other silicon nitride materials in terms of tensile/flexure strength ratio, a measure of volume quality. This high quality was derived from the closed-loop colloidal process employed in the program.

  10. THE ZURICH ENVIRONMENTAL STUDY (ZENS) OF GALAXIES IN GROUPS ALONG THE COSMIC WEB. II. GALAXY STRUCTURAL MEASUREMENTS AND THE CONCENTRATION OF MORPHOLOGICALLY CLASSIFIED SATELLITES IN DIVERSE ENVIRONMENTS

    SciTech Connect (OSTI)

    Cibinel, A.; Carollo, C. M.; Lilly, S. J.; Miniati, F.; Cameron, E.; Peng, Y.; Pipino, A.; Rudick, C. S.; Silverman, J. D.; Van Gorkom, J. H.; Finoguenov, A.; Norberg, P. E-mail: marcella@phys.ethz.ch

    2013-10-20

    We present structural measurements for the galaxies in the 0.05 < z < 0.0585 groups of the Zurich Environmental Study, aimed at establishing how galaxy properties depend on four environmental parameters: group halo mass (M{sub GROUP}), group-centric distance (R/R{sub 200}), ranking into central or satellite, and large-scale structure density (?{sub LSS}). Global galaxy structure is quantified both parametrically and non-parametrically. We correct all these measurements for observational biases due to point-spread function blurring and surface brightness effects as a function of galaxy size, magnitude, steepness of light profile, and ellipticity. Structural parameters are derived also for bulges, disks, and bars. We use the galaxy bulge-to-total ratios (B/T) together with the calibrated non-parametric structural estimators to implement a quantitative morphological classification that maximizes purity in the resulting morphological samples. We investigate how the concentration C of satellite galaxies depends on galaxy mass for each Hubble type and on M{sub GROUP}, R/R{sub 200}, and ?{sub LSS}. At galaxy masses M ? 10{sup 10} M{sub ?}, the concentration of disk satellites increases with increasing stellar mass separately within each morphological bin of B/T. The known increase in concentration with stellar mass for disk satellites is thus due, at least in part, to an increase in galaxy central stellar density at constant B/T. The correlation between concentration and galaxy stellar mass becomes progressively steeper for later morphological types. The concentration of disk satellites shows a barely significant dependence on ?{sub LSS} or R/R{sub 200}. The strongest environmental effect is found with group mass for >10{sup 10} M{sub ?} disk-dominated satellites, which are ?10% more concentrated in high mass groups than in lower mass groups.

  11. Structure and spectroscopic properties of ruthenium(II) bipyridyl N-benzoyl-N'-(1,10-phenanthrolin-5-Yl)-thiourea

    SciTech Connect (OSTI)

    Tan, Siew San; Kassim, Mohammad B.

    2015-09-25

    Ruthenium bipyridyl incorporating phenanthroline with thiourea molecules, [Ru(bpy){sub 2}(Phen-BT)](PF{sub 6}){sub 2}], has been synthesized and characterized by spectroscopic and electrochemical techniques. The infrared spectra of the complex shows the characteristics stretching frequencies for N-H at 3646 and 3585 cm{sup −1}, ν(C-N){sub phen} 1426 cm{sup −1}, ν(C=O) 1675 cm{sup −1}, ν(C=S) 1246 cm{sup −1}, ν(C-H){sub aromatic} 3353-3086 cm{sup −1}, ν(C-N){sub aliphatic} 1169-1026 cm{sup −1}, ν(C-H){sub bend} 764 cm{sup −1} and ν(PF{sub 6}{sup −}){sub free} 842 cm{sup −1}. The complex reveals two π→π* absorption bands at 237 (ε=26,302) and 286 nm (ε=36,848), which were assigned to the phenanthroline and bipyridyl moieties, respectively. A slightly broad and low energy band in the UV-vis spectrum at 450 nm (ε=7,209) of the complex was assigned to a MLCT transition. Besides, the complex also exhibits an emission band at 615 nm that arises from an excitation with a 440 nm light energy. The cyclic voltammetry of the complex shows an oxidation potential at +1.305 V vs. SCE that corresponds to the formal oxidation of Ru(II) to Ru(III)

  12. Spectroscopic study on deuterated benzenes. II. High-resolution laser spectroscopy and rotational structure in the S{sub 1} state

    SciTech Connect (OSTI)

    Kunishige, Sachi; Katori, Toshiharu; Baba, Masaaki; Hayashi, Masato; Hasegawa, Hirokazu; Ohshima, Yasuhiro

    2015-12-28

    High-resolution spectra of the S{sub 1}←S{sub 0} transition in jet-cooled deuterated benzenes were observed using pulse dye amplification of single-mode laser light and mass-selective resonance enhanced multiphoton ionization (REMPI) detection. The vibrational and rotational structures were accurately analyzed for the vibronic levels in the S{sub 1} state. The degenerate 6{sup 1} levels of C{sub 6}H{sub 6} or C{sub 6}D{sub 6} are split into 6a{sup 1} and 6b{sup 1} in many of deuterated benzenes. The rigid-rotor rotational constants were assessed and found to be slightly different between 6a and 6b because of different mean molecular structures. Their rotational levels are significantly shifted by Coriolis interactions. It was found that the Coriolis parameter proportionally changed with the number of substituted D atoms.

  13. Synergetic effects of II-VI sensitization upon TiO{sub 2} for photoelectrochemical water splitting; a tri-layered structured scheme

    SciTech Connect (OSTI)

    Mumtaz, Asad; Mohamed, Norani Muti

    2014-10-24

    World's energy demands are growing on a higher scale increasing the need of more reliable and long term renewable energy resources. Efficient photo-electrochemical (PEC) devices based on novel nano-structured designs for solar-hydrogen generation need to be developed. This study provides an insight of the tri-layered-TiO2 based nanostructures. Observing the mechanism of hydrogen production, the comparison of the structural order during the synthesis is pronounced. The sequence in the tri-layered structure affects the photogenerated electron (e{sup −}) and hole (h{sup +}) pair transfer and separation. It is also discussed that not only the semiconductors band gaps alignment is important with respect to the water redox potential but also the interfacial regions. Quasi-Fermi-level adjustment at the interfacial regions plays a key role in deciding the solar to hydrogen efficiency. More efficient multicomponent semiconductor nano-design (MCSN) could be developed with the approach given in this study.

  14. Finding of No Significant Impact

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    U.S. Department of Energy Finding of No Significant Impact 2 June 2001 This page intentionally left blank. U.S. Department of Energy Finding of No Significant Impact 12 June 2001 This page intentionally left blank.

  15. Finding of No Significant Impact

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Bonneville Power Administration Northern Mid-Columbia Joint Project Finding of No Significant Impact March 2016 Bonneville Power Administration 1 Northern Mid-Columbia Joint Project DEPARTMENT OF ENERGY Bonneville Power Administration Finding of No Significant Impact (FONSI) and Floodplain Statement of Findings DOE/EA-1945 Summary: Bonneville Power Administration (BPA) announces its environmental findings on one of the routing alternatives - West Route D-E - identified for the Northern

  16. Final Report: Design & Evaluation of Energy Efficient Modular Classroom Structures Phase II / Volume I-VII, January 17, 1995 - October 30, 1999

    SciTech Connect (OSTI)

    1999-10-30

    We are developing innovations to enable modular builders to improve the energy performance of their classrooms with no increase in first cost. The Modern Building Systems' (MBS) classroom building conforms to the stringent Oregon energy code, and at $18/ft{sup 2} ($1.67/m{sup 2}) (FOB the factory) it is at the low end of the cost range for modular classrooms. We have investigated daylighting, cross-ventilation, solar preheat of ventilation air, air-to-air heat exchanger, electric lighting controls, and down-sizing HVAC systems as strategies to improve energy performance. We were able to improve energy performance with no increase in first cost in all climates examined. Two papers and a full report on Phase I of this study are available. The work described in this report is from the second phase of the project. In the first phase we redesigned the basic modular classroom to incorporate energy strategies including daylighting, cross-ventilation, solar preheating of ventilation air, and insulation. We also explored thermal mass but determined that it was not a cost-effective strategy in the five climates we examined. Energy savings ranged from 6% to 49% with an average of 23%. Paybacks ranged from 1.3 years to 23.8 years, an average of 12.1 years. In Phase II the number of baseline buildings was expanded by simulating buildings that would be typical of those produced by Modern Building Systems, Inc. (MBS) for each of the seven locations/climates. A number of parametric simulations were performed for each energy strategy. Additionally we refined our previous algorithm for a solar ventilation air wall preheater and developed an algorithm for a roof preheater configuration. These algorithms were coded as functions in DOE 2.1E. We were striving for occupant comfort as well as energy savings. We performed computer analyses to verify adequate illumination on vertical surfaces and acceptable glare levels when using daylighting. We also used computational fluid dynamics

  17. ARM - Research Highlights: Notable Findings

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    HighlightsNotable Research Findings Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Notable Research Findings for the Past Five Years Aerosols Cloud Parameterization and Modeling (Currently Cloud Modeling) Cloud Properties Instantaneous Radiative Flux (Currently Radiative Processes)

  18. I IIII1IiI II1Ii

    Office of Legacy Management (LM)

    * 'I I IIII1IiI II1Ii 1111 1111 I - I' p. r. * *: * * * .** I I ,e L 'I r - I OFFICIAL PHOTOGRAPH ADEC ?Date ______ Time - Location /oie_ / I C 4'.'-?- 1D& Reason for Photo ' 1 By _________ Ro1 # 7'93 Frame' # ,'9 I *.' ' .- - . *c *\ I '' . *. , * " . ... *l; .; . '' N 1 * ' ' * ' '" ), q . L *" ' r 'I . I ' , * I ", * _; . ':. -* - - ! .) f' '' . . * 'i; . ,- , . F) .* :-- .' *, 'I 1 - . '.. ' t; , çv ' . ,* I i * #' *. '3 "' i * '- *1 '4 *' ,:- - a 4 t ' - * ', %

  19. Neutron and X-ray structural characterization of the hexaaquavanadium(II) compound VSO{sub 4}{center_dot}7H{sub 2}O

    SciTech Connect (OSTI)

    Cotton, F.A.; Falvello, L.R.; Pascual, I.; Tomas, M.; Murillo, C.A. |; Schultz, A.J.

    1994-11-23

    The title compound, for which crystals are more reactive toward oxygen than the chemically similar compound VSO{sub 4}{center_dot}6H{sub 2}O, has been prepared as large single crystals and characterized by both X-ray diffraction at room temperature and neutron diffraction at 11-16 K. VSO{sub 4}{center_dot}7H{sub 2}O crystallizes in the monoclinic space group P2{sub 1}/c, Z = 4, with the following cell dimensions, where in each case the room temperature X-ray value is given first followed by the 11-16 K neutron value: a = 14.130(3), 14.013(2) {angstrom}; b = 6.501(1), 6.481(1) {angstrom}; c = 11.017(2), 10.981(2) {angstrom}; {beta} = 105.64(2), 105.39(1){degrees}; V = 974.5(3), 961.5(3) {angstrom}{sup 3}. The structure was refined to residuals of R = 0.0289 and 0.0766 and quality of fit = 1.047 and 1.427 for X-ray and neutron data, respectively. It consists of two independent centrosymmetric V(H{sub 2}O){sub 6}{sup 2+} ions connected to a sulfate ion and an interstitial water molecule by an extensive network of hydrogen bonds. The room temperature and low-temperature structures are qualitatively identical. Each hydrogen atom is involved in a hydrogen bond. The network of hydrogen bonds is implicated in the stability of VSO{sub 4}{center_dot}7H{sub 2}O in the solid state in dry surroundings.

  20. THE STRUCTURE OF PRE-TRANSITIONAL PROTOPLANETARY DISKS. II. AZIMUTHAL ASYMMETRIES, DIFFERENT RADIAL DISTRIBUTIONS OF LARGE AND SMALL DUST GRAINS IN PDS 70 {sup ,}

    SciTech Connect (OSTI)

    Hashimoto, J.; Wisniewski, J.; Tsukagoshi, T.; Brown, J. M.; Dong, R.; Muto, T.; Zhu, Z.; Ohashi, N.; Kudo, T.; Egner, S.; Guyon, O.; Kusakabe, N.; Akiyama, E.; Abe, L.; Brandner, W.; Carson, J.; Feldt, M.; Brandt, T.; Currie, T.; Grady, C. A.; and others

    2015-01-20

    The formation scenario of a gapped disk, i.e., transitional disk, and its asymmetry is still under debate. Proposed scenarios such as disk-planet interaction, photoevaporation, grain growth, anticyclonic vortex, eccentricity, and their combinations would result in different radial distributions of the gas and the small (sub-μm size) and large (millimeter size) dust grains as well as asymmetric structures in a disk. Optical/near-infrared (NIR) imaging observations and (sub-)millimeter interferometry can trace small and large dust grains, respectively; therefore multi-wavelength observations could help elucidate the origin of complicated structures of a disk. Here we report Submillimeter Array observations of the dust continuum at 1.3 mm and {sup 12}CO J = 2 → 1 line emission of the pre-transitional protoplanetary disk around the solar-mass star PDS 70. PDS 70, a weak-lined T Tauri star, exhibits a gap in the scattered light from its disk with a radius of ∼65 AU at NIR wavelengths. However, we found a larger gap in the disk with a radius of ∼80 AU at 1.3 mm. Emission from all three disk components (the gas and the small and large dust grains) in images exhibits a deficit in brightness in the central region of the disk, in particular, the dust disk in small and large dust grains has asymmetric brightness. The contrast ratio of the flux density in the dust continuum between the peak position to the opposite side of the disk reaches 1.4. We suggest the asymmetries and different gap radii of the disk around PDS 70 are potentially formed by several (unseen) accreting planets inducing dust filtration.

  1. Thermoelectric and transport properties of sintered n-type K{sub 8}Ba{sub 16}Ga{sub 40}Sn{sub 96} with type-II clathrate structure

    SciTech Connect (OSTI)

    Koda, Shota; Kishimoto, Kengo Asada, Hironori; Koyanagi, Tsuyoshi; Akai, Koji

    2014-07-14

    This clathrate had a maximum dimensionless figure-of-merit, ZT, of 0.93 at 637 K, which was slightly higher than that of 0.83 for the sintered type-VIII clathrate Ba{sub 8}Ga{sub 16}Sn{sub 30}. We investigated the high-temperature thermoelectric properties, transport properties, electronic structures, and thermal stabilities of the clathrates. The type-II clathrate was found to be superior to the type-VIII clathrate as a thermoelectric material; it had a high thermal stability and melting point, 859 K, high mobility, 141 cm{sup 2}V{sup −1}s{sup −1} at 300 K, because of its low inertial mass, and low high-temperature lattice thermal conductivity, approximately 4 mW cm{sup −1}K{sup −1}, resulting from a larger unit cell and weaker bipolar thermal conduction. We discuss these properties in terms of the electronic structure and the differences between the two types of clathrate.

  2. Synthesis, crystal structures, and luminescent properties of Cd(II) coordination polymers assembled from semi-rigid multi-dentate N-containing ligand

    SciTech Connect (OSTI)

    Yuan, Gang; Shao, Kui-Zhan; Chen, Lei; Liu, Xin-Xin; Su, Zhong-Min; Ma, Jian-Fang

    2012-12-15

    Three new polymers, [Cd(L){sub 2}(H{sub 2}O){sub 2}]{sub n} (1), [Cd{sub 3}(L){sub 2}({mu}{sub 3}-OH){sub 2}({mu}{sub 2}-Cl){sub 2}(H{sub 2}O){sub 2}]{sub n} (2), {l_brace}[Cd{sub 2}(L){sub 2}(nic){sub 2}(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O{r_brace}{sub n} (3) (HL=5-(4-((1H-1,2,4-triazol-1-yl)methyl)phenyl)-1H-tetrazole, Hnic=nicotinic acid) have been prepared and structurally characterized. Compounds 1 and 2 display 2D monomolecular layers built by the inter-linking single helical chains and L{sup -} ligands connecting chain-like [Cd({mu}{sub 3}-OH)({mu}{sub 2}-Cl)]{sub n} secondary building units, respectively. Compound 3 is constructed from the mixed ligands and possesses a (3,4)-connected framework with (4{center_dot}8{sup 2})(4{center_dot}8{sup 2}{center_dot}10{sup 3}) topology. Moreover, the fluorescent properties of HL ligand and compounds 1-3 are also been investigated. - Graphical abstract: Three new coordination polymers based on the semi-rigid multidentate N-donor ligand have been successfully synthesized by hydrothermal reaction. Complexes 1 and 2 exhibit the 2D layers formed by inter-linking single helices and L{sup -} anions bridging 1D chain-like SBUs, respectively. Complex 3 is buit by L{sup -} and assistant nic{sup -} ligands connecting metal centers and possesses a (3,4)-connected framework with (4 Multiplication-Sign 8{sup 2})(4 Multiplication-Sign 8{sup 2} Multiplication-Sign 10{sup 3}) topology. Moreover, these complexes display fluorescent properties indicating that they may have potential applications as optical materials. Highlights: Black-Right-Pointing-Pointer Three Cd-compounds were prepared from semi-rigid HL ligand with different N-containing groups. Black-Right-Pointing-Pointer They exhibit diverse structures from 2D monomolecular layer to 3D covalent framework. Black-Right-Pointing-Pointer The HL ligands displayed various coordination modes under different reaction conditions. Black-Right-Pointing-Pointer These compounds exhibit

  3. pH- and mol-ratio dependent formation of zinc(II) coordination polymers with iminodiacetic acid: Synthesis, spectroscopic, crystal structure and thermal studies

    SciTech Connect (OSTI)

    Ni Lubin; Zhang Ronghua; Liu Qiongxin; Xia Wensheng; Wang Hongxin; Zhou Zhaohui

    2009-10-15

    Three novel zinc coordination polymers (NH{sub 4}){sub n}[Zn(Hida)Cl{sub 2}]{sub n} (1), [Zn(ida)(H{sub 2}O){sub 2}]{sub n} (2), [Zn(Hida){sub 2}]{sub n}.4nH{sub 2}O (3) (H{sub 2}ida=iminodiacetic acid) and a monomeric complex [Zn(ida)(phen)(H{sub 2}O)].2H{sub 2}O (4) (phen=1,10-phenanthroline) have been synthesized and characterized by X-ray diffraction methods. 1 and 2 form one-dimensional (1-D) chain structures, whereas 3 exhibits a three-dimensional (3-D) diamondoid framework with an open channel. The mononuclear complex 4 is extended into a 3-D supramolecular architecture through hydrogen bonds and pi-pi stacking. Interestingly, cyclic nonplanar tetrameric water clusters are observed that encapsulated in the 3-D lattice of 4. Based on {sup 1}H and {sup 13}C NMR observations, there is obvious coordination of complex 2 in solution, while 1 and 3 decompose into free iminodiacetate ligand. Monomer [Zn(ida)(H{sub 2}O){sub 3}] (5) is considered as a possible discrete species from 2. These coordination polymers can serve as good molecular precursors for zinc oxide. - Text3: Reaction of zinc salt with iminodiacetic acid afforded three new coordination polymers 1-3 and a monomer 4, which is dependent on pH value and molar ratio of the reactants.

  4. Synthesis and Structural Features of [4,4'-Diisopropoxyester-2,2'-bipyridine], [Dichloro(4,4'-diisopropoxyester-2,2'-bi-pyridine)-platinum(ii)] and Its Dichloromethane Solvated Pseudo-Polymorph: Versatile Supramolecular Interactions

    SciTech Connect (OSTI)

    Browning, Charles; Nesterov, Vladimir N.; Wang, Xiaoping; Omary, Mohammad A.

    2015-06-03

    We report that the organic ligand 4,4'-diisopropoxyester-2,2'-bipyridine, C18H20N2O4 (1), crystallizes in the triclinic crystal system P-1 and the molecule occupies a special position in the unit cell. In the crystal, molecules form stacks with partial overlapping of the pyridine rings. The Pt(II) dichloro complex of 1 crystallizes from a mixture of ethanol/hexane and from dichloromethane to form orange and yellow crystals, respectively. The orange non-solvated crystals of the (bipyridine)(dichloro)platinum(II) complex C18H20N2O4PtCl2 (2) crystallize in the triclinic crystal system P-1 as well with two independent molecules in the unit cell. In the crystal packing, molecules form two types of dimers with Pt1 ··· Pt1A and Pt2···Pt2A distances of 3.478 and 5.186 angstrom respectively. The yellow crystals, as a solvated pseudo-polymorph C18H20N2O4PtCl2·1.5 CH2Cl2 (3) also crystallize in the triclinic crystal system P-1 with two independent molecules in the unit cell. In the crystal packing, molecules form Pt2 ···Pt1 ···Pt1A ···Pt2A intermolecular contacts with alternating distances 3.501 and 3.431 angstrom, respectively, forming infinite chains. Graphical Abstract The dichloro(bipyridine)platinum complex, dichloro(4,4'-diisopropoxyester-2,2'-bipyridine)platinum(II), forms single crystals as a stable non-solvated form and a solvated polymorph with dramatically different supramolecular structure and short contacts.

  5. Find R&D Results

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Find technical reports, journal articles, accepted manuscripts, conference papers, patents, theses, books, multimedia, and data information. Use the basic or advanced search to get ...

  6. Aegir II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Aegir II Jump to: navigation, search Name Aegir II Facility Aegir II Sector Wind energy Facility Type Offshore Wind Facility Status Proposed Location Lake Michigan MI Coordinates...

  7. Penascal II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Penascal II Jump to: navigation, search Name Penascal II Facility Penascal II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Developer Iberdrola...

  8. Glacier II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Glacier II Facility Glacier II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NaturEner Developer...

  9. Wilton Wind Energy Center II II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Wilton Wind Energy Center II II Facility Wilton Wind Energy Center II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  10. Find a Job | Careers | NREL

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Find a Job We're looking for scientists, research technicians, engineers, analysts, managers and project leaders, administrators, and communicators, along with information technology, security, facilities, and clerical/administrative support specialists. Interested in joining our team? Find your opportunity We're passionate about our mission-to develop clean energy and energy efficiency technologies and practices, advance related science and engineering, and provide knowledge and innovations to

  11. Synthesis, structure and photoluminescence of (PLAGH){sub 2}[ZnCl{sub 4}] and comparative analysis of photoluminescence properties with tris(2,2′-bipyridine)ruthenium(II)

    SciTech Connect (OSTI)

    Radanović, Mirjana M.; Jelić, Miodrag G.; Romčević, Nebojša Ž.; Boukos, Nikos; Vojinović-Ješić, Ljiljana S.; Leovac, Vukadin M.; Hadžić, Branka B.; Bajac, Branimir M.; Nađ, Laslo F.; Chandrinou, Chrysoula; Baloš, Sebastian S.

    2015-10-15

    Highlights: • New zinc(II) complex with pyridoxalaminoguanidine was synthesized. • The enhancement of the photoluminescence due to the compound formation was achieved. • Very high photoluminescence of Zn(II) compound was noticed. • Comparative analysis of photoluminescence with tris(2,2′-bipyridine) ruthenium(II) was provided. - Abstract: The first compound of zinc(II) containing pyridoxalaminoguanidine has been synthesized and characterized by elemental analysis, infrared spectra, conductometric measurements and X-ray crystallography. Single crystals of the compound were obtained in the reaction of methanolic solution of zinc(II) chloride and pyridoxalaminoguanidine hydrochloride. In this compound the coordination of chelate ligand is absent and tetrachlorido complex of zinc(II) with pyridoxalaminuguanidinium cation as contraion is obtained. Photoluminescence spectra were measured. Lorentzian multipeak technique was used to determine peak wavelengths and their intensities. Photoluminescence spectroscopy upon 325, 488 and 514 nm laser excitation light was used to obtain results. This novel compound of zinc(II) was compared to the well-known organic light emitting diode material—ruthenium(II) complex with bypiridine i.e., tris(2,2′-bipyridine)ruthenium(II), under the same circumstances and the identical experimental setup. A scheme of energy levels and transitions is proposed to explain the obtained experimental results.

  12. Synthesis, characterization and crystal structure of a novel Os(II)-supported tungstoarsenate [HAsW{sub 7}O{sub 28}Os(dmso){sub 3}]{sup 6-}

    SciTech Connect (OSTI)

    Bi Lihua Li Bao; Wu Lixin Shao Kuizhan; Su Zhongmin

    2009-01-15

    Reaction of tri-lacunary Keggin tungstoarsenate with osmium complex Os(dmso){sub 4}Cl{sub 2} under mild condition led to the formation of a novel Os (II)-supported tungstoarsenate Na{sub 5}(NH{sub 4})[HAsW{sub 7}O{sub 28}Os(dmso){sub 3}].15H{sub 2}O (1a). Single-crystal X-ray diffraction analysis shows that compound 1a crystallizes in the monoclinic space group P2{sub 1}/c (no. 14) with a=14.9166(12) A, b=23.6935(19) A, c=16.5349(14) A, {beta}=92.7950(10){sup o}, V=5836.9(8) A{sup 3}, Z=4 with R{sub 1}=0.0453. The crystal structure reveals two features: (1) the polyanion [HAsW{sub 7}O{sub 28}Os(dmso){sub 3}]{sup 6-} (1) consists of a Os(dmso){sub 3} unit linked to a tungstoarsenate fragment {l_brace}HAsW{sub 7}O{sub 28}{r_brace} via two Os-O-W bonds and one Os-O-As bond resulting in an assembly with C{sub s} symmetry, which represents a novel mode of Os-coordination to a polyoxoanion framework; (2) 3D architecture assembled by the polyanion 1 and sodium linkers. In addition, the compound 1a was well characterized by the multinuclear NMR ({sup 13}C, {sup 1}H), IR spectroscopy, UV-vis spectroscopy, elemental analysis, and cyclic voltammetry (CV). - Graphical abstract: A new tungstoarsenate containing a Os(dmso){sub 3} unit [HAsW{sub 7}O{sub 28}Os(dmso){sub 3}]{sup 6-} (1) has been synthesized using [HAsW{sub 9}O{sub 34}]{sup 8-} as polyanion precursor and structurally characterized.

  13. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ......II-1 S. ...

  14. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    of California, Berkeley, and the Max Planck Institute of Biochemistry combined ... J. Peters, and W. Baumeister (Max Planck Institute of Biochemistry); P.J. Walian ...

  15. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    at ALS Beamline 8.2.2. Treating Obesity with Satiety Cholecystokinin (CCK) is a hormone in the brain and gastrointestinal system that helps stimulate the digestion of fat...

  16. Giant Protease TPP II's Structure, Mechanism Uncovered

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    The protein "skeleton" of this giant protease is depicted in magenta ribbon. The grey enclosure represents a lower-resolution surface and is included to aid visualization of...

  17. Peak finding using biorthogonal wavelets

    SciTech Connect (OSTI)

    Tan, C.Y.

    2000-02-01

    The authors show in this paper how they can find the peaks in the input data if the underlying signal is a sum of Lorentzians. In order to project the data into a space of Lorentzian like functions, they show explicitly the construction of scaling functions which look like Lorentzians. From this construction, they can calculate the biorthogonal filter coefficients for both the analysis and synthesis functions. They then compare their biorthogonal wavelets to the FBI (Federal Bureau of Investigations) wavelets when used for peak finding in noisy data. They will show that in this instance, their filters perform much better than the FBI wavelets.

  18. EA-1744: Finding of No Significant Impact

    Office of Energy Efficiency and Renewable Energy (EERE)

    Brea Power II, LLC's Olinda Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas, Brea, California

  19. EA-1828: Finding of No Significant Impact

    Energy.gov [DOE]

    Carbon Dioxide Capture from Biofuels Production and Sequestration into the Mount Simon Sandstone Phase II Project in Decatur, Illinois

  20. Cori Phase II Preparations

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Cori Phase II Preparations Cori Phase II Preparations May 9, 2016 by Rebecca Hartman-Baker We expect the first cabinets of Cori Phase II to arrive in CRT/Wang Hall on the LBL campus in July. NERSC personnel will immediately get to work on bringing the machine into production. Before the machine can be released to the NERSC user community, a number of tasks must be completed, some of which will have a direct impact on NERSC users. We've created the Cori Phase II Schedule page to keep users

  1. ACRA-II

    Energy Science and Technology Software Center (OSTI)

    003089IBMPC00 ACRA-II: Kernel Integration Code System for Estimation of Radiation Doses Caused by a Hypothetical Reactor Accident

  2. Writing audit findings: Be reasonable!

    SciTech Connect (OSTI)

    Girvin, N.W.

    1992-05-01

    A customary approach to auditing and reporting deficiencies is to keep a running list of those that are found, evaluate the severity of each, and based on the evidence, document findings or observations or concerns in an audit report. The report is issued and the auditee is normally requested to address ``root cause`` as part of their corrective action. This paper describes a ``root problems`` approach to documenting audit findings that is designed not only to put the QA auditor in a more favorable light, but to more effectively enable the auditee to identify root cause and meaningful corrective action. The positive results of this approach are considerable. You will have fewer findings but those you do have will be substantial. You will cite requirements that sound reasonable and make arguments difficult. If some of the supporting deficiencies (examples) prove to be incorrect, you will still have ample support for the original finding. You will be seen as reasonable individual who can help lead the auditee towards identification of root cause without taking away part of the responsibility. You even have a fair chance of fostering a sense of commitment to quality improvement on the auditee`s part. This in itself, is its own reward.

  3. Writing audit findings: Be reasonable

    SciTech Connect (OSTI)

    Girvin, N.W.

    1992-05-01

    A customary approach to auditing and reporting deficiencies is to keep a running list of those that are found, evaluate the severity of each, and based on the evidence, document findings or observations or concerns in an audit report. The report is issued and the auditee is normally requested to address root cause'' as part of their corrective action. This paper describes a root problems'' approach to documenting audit findings that is designed not only to put the QA auditor in a more favorable light, but to more effectively enable the auditee to identify root cause and meaningful corrective action. The positive results of this approach are considerable. You will have fewer findings but those you do have will be substantial. You will cite requirements that sound reasonable and make arguments difficult. If some of the supporting deficiencies (examples) prove to be incorrect, you will still have ample support for the original finding. You will be seen as reasonable individual who can help lead the auditee towards identification of root cause without taking away part of the responsibility. You even have a fair chance of fostering a sense of commitment to quality improvement on the auditee's part. This in itself, is its own reward.

  4. Find Internships | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Internships Find Internships Internships in energy efficiency and renewable energy-related fields, such as solar and fuel cells, energy efficiency, atmospheric sciences, ecology, global carbon cycles, climatology, and more, include EERE's own student internship program. Featured Internships Clean Cities University Workforce Development Program Clean Cities logo Science Undergraduate Laboratory Internships (SULI) Fall 2013 Picture of tow people in a labratory working Minority Educational

  5. Nanocrystal structures

    DOE Patents [OSTI]

    Eisler, Hans J.; Sundar, Vikram C.; Walsh, Michael E.; Klimov, Victor I.; Bawendi, Moungi G.; Smith, Henry I.

    2008-12-30

    A structure including a grating and a semiconductor nanocrystal layer on the grating, can be a laser. The semiconductor nanocrystal layer can include a plurality of semiconductor nanocrystals including a Group II-VI compound, the nanocrystals being distributed in a metal oxide matrix. The grating can have a periodicity from 200 nm to 500 nm.

  6. Nanocrystal structures

    DOE Patents [OSTI]

    Eisler, Hans J.; Sundar, Vikram C.; Walsh, Michael E.; Klimov, Victor I.; Bawendi, Moungi G.; Smith, Henry I.

    2006-12-19

    A structure including a grating and a semiconductor nanocrystal layer on the grating, can be a laser. The semiconductor nanocrystal layer can include a plurality of semiconductor nanocrystals including a Group IIVI compound, the nanocrystals being distributed in a metal oxide matrix. The grating can have a periodicity from 200 nm to 500 nm.

  7. EA-1849-S1: Finding of No Significant Impact | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1849-S1: Finding of No Significant Impact Phase II Facility - Ormat Tuscarora Geothermal Power Plant in Tuscarora, Nevada On the basis of the Final SEA, DOE has determined that ...

  8. Project Final Report: HPC-Colony II

    SciTech Connect (OSTI)

    Jones, Terry R; Kale, Laxmikant V; Moreira, Jose

    2013-11-01

    This report recounts the HPC Colony II Project which was a computer science effort funded by DOE's Advanced Scientific Computing Research office. The project included researchers from ORNL, IBM, and the University of Illinois at Urbana-Champaign. The topic of the effort was adaptive system software for extreme scale parallel machines. A description of findings is included.

  9. EA-1929: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    CA | Department of Energy 0: California Valley Solar Ranch Project in San Luis Obispo County, CA EA-1840: California Valley Solar Ranch Project in San Luis Obispo County, CA August 3, 2011 EA-1840: Final Environmental Assessment California Valley Solar Ranch Project in San Luis Obispo and Kern Counties, California August 3, 2011 EA-1840: Finding of No Significant Impact Loan Guarantee to High Plains II, LLC for the California Valley Solar Ranch Project in San Luis Obispo County and Kern

  10. FINDING OF NO SIGNIFICANT IMPACT

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    COMMERCIAL DEMONSTRATION OF THE MANUFACTURED AGGREGATE PROCESSING TECHNOLOGY UTILIZING SPRAY DRYER ASH 1 AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), DOE/EA-1449, to analyze the potential environmental consequences of participating in a cooperative agreement with Universal Aggregates, LLC, for the design, construction, and operation of a plant to manufacture lightweight aggregates. The

  11. Find Jobs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Jobs Find Jobs Clean energy jobs can be found in the public, private, and nonprofit sectors and can range from entry-level to professional positions in a wide range of fields. This section can help you familiarize yourself with different types of green energy jobs as you begin your search for a job that meets your interests and skills. EERE Career Opportunities EERE Career Opportunities Energy Efficency and Renewable Energy, the DOE office leading the nation's effort to enhance energy efficiency

  12. Algorithm for Finding Similar Shapes in Large Molecular Structures Libraries

    Energy Science and Technology Software Center (OSTI)

    1994-10-19

    The SHAPES software consists of methods and algorithms for representing and rapidly comparing molecular shapes. Molecular shapes algorithms are a class of algorithm derived and applied for recognizing when two three-dimensional shapes share common features. They proceed from the notion that the shapes to be compared are regions in three-dimensional space. The algorithms allow recognition of when localized subregions from two or more different shapes could never be superimposed by any rigid-body motion. Rigid-body motionsmore » are arbitrary combinations of translations and rotations.« less

  13. Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}

    SciTech Connect (OSTI)

    Grossholz, Hagen; Hartenbach, Ingo; Kotzyba, Gunter; Poettgen, Rainer; Trill, Henning; Mosel, Bernd D.; Schleid, Thomas

    2009-11-15

    Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent

  14. EA-1523: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1523: Finding of No Significant Impact Modifications at the Strategic Petroleum Reserve's West Hackberry Raw Water Intake Structure Site, Calcasieu Parish, Louisiana The U.S. Department of Energy Strategic Petroleum Reserve (SPR) prepared an Environmental Assessment (EA) (Attachment A) in response to a proposal to modify the West Hackberry (WH) Raw Water Intake Structure (RWIS) located near Hackberry, Louisiana. Based on the results of the EA and

  15. Preliminary PBFA II design

    SciTech Connect (OSTI)

    Johnson, D. L.; VanDevender, J. P.; Martin, T. H.

    1980-01-01

    The upgrade of Sandia National Laboratories particle beam fusion accelerator, PBFA I, to PBFA II presents several interesting and challenging pulsed power design problems. PBFA II requires increasing the PBFA I output parameters from 2 MV, 30 TW, 1 MJ to 4 MV, 100 TW, 3.5 MJ with the constraint of using much of the same PBFA I hardware. The increased PBFA II output will be obtained by doubling the number of modules (from 36 to 72), increasing the primary energy storage (from 4 MJ to 15 MJ), lowering the pulse forming line (PFL) output impedance, and adding a voltage doubling network.

  16. Limon II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Limon II Facility Limon II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NextEra Energy Resources...

  17. ARM - RHUBC II Science Objectives

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Objectives Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II...

  18. Network II Database

    Energy Science and Technology Software Center (OSTI)

    1994-11-07

    The Oak Ridge National Laboratory (ORNL) Rail and Barge Network II Database is a representation of the rail and barge system of the United States. The network is derived from the Federal Rail Administration (FRA) rail database.

  19. _Part II - Contract Clauses

    National Nuclear Security Administration (NNSA)

    M0572 dated 3215 Contract DE-AC04-94AL85000 Modification No. M202 Page I - 1 Part II - Contract Clauses Section I TABLE OF CONTENTS 1. FAR 52.202-1 DEFINITIONS (JAN 2012)...

  20. MS, II-J

    Office of Legacy Management (LM)

    I' ; ,' Departm&th of Energy 1 MS, II-J Washington. DC 20585 ' . I I The Honorable John ... ,, If.you have,any questions, please feel free to call me at 301-427-1721 or Dr. ...

  1. PARS II Training Materials

    Energy.gov [DOE]

    PARS II presentation hand-outs and step-by-step "how to" exercises for each course are available for download. Users who are attending Web classes should download these documents prior to attending...

  2. Luz II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name: Luz II Place: Jerusalem, Israel Zip: 91450 Sector: Solar Product: Jerusalem-based utility-scale solar power plant developer. Coordinates:...

  3. Type II InAs/GaAsSb quantum dots: Highly tunable exciton geometry and topology

    SciTech Connect (OSTI)

    Llorens, J. M.; Wewior, L.; Cardozo de Oliveira, E. R.; Alén, B.; Ulloa, J. M.; Utrilla, A. D.; Guzmán, A.; Hierro, A.

    2015-11-02

    External control over the electron and hole wavefunctions geometry and topology is investigated in a p-i-n diode embedding a dot-in-a-well InAs/GaAsSb quantum structure with type II band alignment. We find highly tunable exciton dipole moments and largely decoupled exciton recombination and ionization dynamics. We also predicted a bias regime where the hole wavefunction topology changes continuously from quantum dot-like to quantum ring-like as a function of the external bias. All these properties have great potential in advanced electro-optical applications and in the investigation of fundamental spin-orbit phenomena.

  4. A Study of Resonant Excitation of Longitudinal HOMs in the Cryomodules of LCLS-II

    SciTech Connect (OSTI)

    Bane, Karl

    2015-09-23

    The Linac Coherent Light Source (LCLS) at SLAC, the world’s first hard X-ray FEL, is being upgraded to the LCLS-II. The major new feature will be the installation of 35 cryomodules (CMs) of TESLA-type, superconducting accelerating structures, to allow for high rep-rate operation. It is envisioned that eventually the LCLS-II will be able to deliver 300 pC, 1 kA pulses of beam at a rate of 1 MHz. At a cavity temperature of 2 K, any heat generated (even on the level of a few watts) is expensive to remove. In the last linac of LCLS-II, L3—where the peak current is highest—the power radiated by the bunches in the CMs is estimated at 13.8 W (charge 300 pC option, rep rate 1 MHz). But this calculation ignores resonances that can be excited between the bunch frequency and higher order mode (HOM) frequencies in the CMs, which in principle can greatly increase this number. In the present work we calculate the multi-bunch wakefields excited in a CM of LCLS-II, in order to estimate the probability of the beam losing a given amount of power. Along theway, we find some interesting properties of the resonant interaction. In detail, we begin this report by finding the wakes experienced by bunches far back in the bunch train. Then we present a complementary approach that calculates the field amplitude excited in steady-state by a train of bunches, and show that the two approaches agree. Next we obtain the properties of the 450 longitudinal HOMs that cover the range 3–5 GHz in the CMs of LCLS-II, where we include the effects of the inter-CM ceramic dampers. At the end we apply our method using these modes.

  5. Regional Transmission Projects: Finding Solutions

    SciTech Connect (OSTI)

    The Keystone Center

    2005-06-15

    The Keystone Center convened and facilitated a year-long Dialogue on "Regional Transmission Projects: Finding Solutions" to develop recommendations that will help address the difficult and contentious issues related to expansions of regional electric transmission systems that are needed for reliable and economic transmission of power within and across regions. This effort brought together a cross-section of affected stakeholders and thought leaders to address the problem with the collective wisdom of their experience and interests. Transmission owners sat at the table with consumer advocates and environmental organizations. Representatives from regional transmission organizations exchanged ideas with state and federal regulators. Generation developers explored common interests with public power suppliers. Together, the Dialogue participants developed consensus solutions about how to begin unraveling some of the more intractable issues surrounding identification of need, allocation of costs, and reaching consensus on siting issues that can frustrate the development of regional transmission infrastructure. The recommendations fall into three broad categories: 1. Recommendations on appropriate institutional arrangements and processes for achieving regional consensus on the need for new or expanded transmission infrastructure 2. Recommendations on the process for siting of transmission lines 3. Recommendations on the tools needed to support regional planning, cost allocation, and siting efforts. List of Dialogue participants: List of Dialogue Participants: American Electric Power American Transmission Company American Wind Energy Association California ISO Calpine Corporation Cinergy Edison Electric Institute Environmental Defense Federal Energy Regulatory Commission Great River Energy International Transmission Company ISO-New England Iowa Public Utility Board Kanner & Associates Midwest ISO National Association of Regulatory Utility Commissioners National Association

  6. About APPLE II Operation

    SciTech Connect (OSTI)

    Schmidt, T.; Zimoch, D.

    2007-01-19

    The operation of an APPLE II based undulator beamline with all its polarization states (linear horizontal and vertical, circular and elliptical, and continous variation of the linear vector) requires an effective description allowing an automated calculation of gap and shift parameter as function of energy and operation mode. The extension of the linear polarization range from 0 to 180 deg. requires 4 shiftable magnet arrrays, permitting use of the APU (adjustable phase undulator) concept. Studies for a pure fixed gap APPLE II for the SLS revealed surprising symmetries between circular and linear polarization modes allowing for simplified operation. A semi-analytical model covering all types of APPLE II and its implementation will be presented.

  7. ARM - RHUBC II Science Team

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Team Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II Backgrounder (PDF, 300K) News & Press Images Experiment Planning RHUBC-II Proposal Abstract Science Plan (PDF, 267KB) Science Objectives Contacts Eli Mlawer, Principal Investigator Dave Turner, Principal Investigator RHUBC II Science Team Principal Investigators Eli Mlawer, Atmospheric & Environmental Research, Inc.

  8. Cori Phase II

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Cori Phase II The Cori Phase II system will be a Cray XC system based on the second generation of the Intel® Xeon Phi(tm) product family, part of the Intel® Many Integrated Core (MIC) Architecture; the code name for this architecture is "Knights Landing" ("KNL"). The system will have a sustained performance that is at least ten times that of the NERSC-6 "Hopper" system, based on a set of characteristic benchmarks. Some important characteristics of the system

  9. Mars Rover finds changing rocks, surprising scientists

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Mars Rover finds changing rocks, surprising scientists Mars Rover finds changing rocks, surprising scientists As NASA's Curiosity rover treks up a three-mile-high mountain on Mars, ...

  10. Fernald Environmental Management Project Director's Final Findings...

    Office of Environmental Management (EM)

    Environmental Protection Agency ("Ohio EPA") in Ohio Revised Code ("ORC") ... I-V. FINDINGS OF FACT The Director of the Ohio EPA has determined the following findings ...

  11. Finding Hidden Oil and Gas Reserves

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Finding Hidden Oil and Gas Reserves Finding Hidden Oil and Gas Reserves Key Challenges: Seismic imaging methods, vital in our continuing search for deep offshore oil and gas...

  12. Canfield's Couplet Clues for Finding Superconductors

    SciTech Connect (OSTI)

    Canfield, Paul

    2015-04-28

    Ames Laboratory scientist, Paul Canfield, summarizes his thoughts about finding new superconducting materials.

  13. Canfield's Couplet Clues for Finding Superconductors

    ScienceCinema (OSTI)

    Canfield, Paul

    2015-06-30

    Ames Laboratory scientist, Paul Canfield, summarizes his thoughts about finding new superconducting materials.

  14. Ribosomal Database Project II

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Ribosomal Database Project (RDP) provides ribosome related data and services to the scientific community, including online data analysis and aligned and annotated Bacterial small-subunit 16S rRNA sequences. As of March 2008, RDP Release 10 is available and currently (August 2009) contains 1,074,075 aligned 16S rRNA sequences. Data that can be downloaded include zipped GenBank and FASTA alignment files, a histogram (in Excel) of the number of RDP sequences spanning each base position, data in the Functional Gene Pipeline Repository, and various user submitted data. The RDP-II website also provides numerous analysis tools.[From the RDP-II home page at http://rdp.cme.msu.edu/index.jsp

  15. Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Contamination - Energy Innovation Portal Geothermal Geothermal Energy Analysis Energy Analysis Find More Like This Return to Search Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and Contamination Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryBore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and

  16. _Part II - Contract Clauses

    National Nuclear Security Administration (NNSA)

    09/30/2015 to Mod 0588 Contract DE-AC04-94AL85000 Modification No. M202 Page I - 1 Part II - Contract Clauses Section I TABLE OF CONTENTS 1. FAR 52.202-1 DEFINITIONS (JAN 2012) (REPLACED M473) ............................................................. 8 2. FAR 52.203-3 GRATUITIES (APR 1984) ................................................................................................. 8 3. FAR 52.203-5 COVENANT AGAINST CONTINGENT FEES (APR 1984) ........................................... 9

  17. Enclosure II June

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Enclosure II June 10,2010 Hanford Radiological Health and Safety Document 1 Forward The Richland Operations Office and the Office of River Protection have established a supplemental set of contractual requirements and an expectation that the contractor organizations establish the mechanisms necessary to maintain site consistency, optimize site-wide radiological programs to provide an overall benefit to the government, and support DOE in the management oflong-term risks relative to radiological

  18. Annex II Technical Specifications

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Mechanical - opto-mechanical design development and structural assessment for Diagnostics .........7 14 CAD DESIGN REQUIREMENTS (IF APPLICABLE) ...

  19. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Temperature dependence of the isospin distillation in nuclear fragmentation ................................ II-1 D. V. Shetty for the NIMROD Collaboration Midrapidity emission in nuclear fragmentation .................................................................................. II-2 D. V. Shetty for the NIMROD Collaboration Isospin dependence of the <N/Z> in nuclear fragmentation .............................................................. II-3 D. V. Shetty, for the NIMROD

  20. Finding Nonoverlapping Substructures of a Sparse Matrix

    SciTech Connect (OSTI)

    Pinar, Ali; Vassilevska, Virginia

    2005-08-11

    Many applications of scientific computing rely on computations on sparse matrices. The design of efficient implementations of sparse matrix kernels is crucial for the overall efficiency of these applications. Due to the high compute-to-memory ratio and irregular memory access patterns, the performance of sparse matrix kernels is often far away from the peak performance on a modern processor. Alternative data structures have been proposed, which split the original matrix A into A{sub d} and A{sub s}, so that A{sub d} contains all dense blocks of a specified size in the matrix, and A{sub s} contains the remaining entries. This enables the use of dense matrix kernels on the entries of A{sub d} producing better memory performance. In this work, we study the problem of finding a maximum number of nonoverlapping dense blocks in a sparse matrix, which is previously not studied in the sparse matrix community. We show that the maximum nonoverlapping dense blocks problem is NP-complete by using a reduction from the maximum independent set problem on cubic planar graphs. We also propose a 2/3-approximation algorithm that runs in linear time in the number of nonzeros in the matrix. This extended abstract focuses on our results for 2x2 dense blocks. However we show that our results can be generalized to arbitrary sized dense blocks, and many other oriented substructures, which can be exploited to improve the memory performance of sparse matrix operations.

  1. Finding nonoverlapping substructures of a sparse matrix

    SciTech Connect (OSTI)

    Pinar, Ali; Vassilevska, Virginia

    2004-08-09

    Many applications of scientific computing rely on computations on sparse matrices, thus the design of efficient implementations of sparse matrix kernels is crucial for the overall efficiency of these applications. Due to the high compute-to-memory ratio and irregular memory access patterns, the performance of sparse matrix kernels is often far away from the peak performance on a modern processor. Alternative data structures have been proposed, which split the original matrix A into A{sub d} and A{sub s}, so that A{sub d} contains all dense blocks of a specified size in the matrix, and A{sub s} contains the remaining entries. This enables the use of dense matrix kernels on the entries of A{sub d} producing better memory performance. In this work, we study the problem of finding a maximum number of non overlapping rectangular dense blocks in a sparse matrix, which has not been studied in the sparse matrix community. We show that the maximum non overlapping dense blocks problem is NP-complete by using a reduction from the maximum independent set problem on cubic planar graphs. We also propose a 2/3-approximation algorithm for 2 times 2 blocks that runs in linear time in the number of nonzeros in the matrix. We discuss alternatives to rectangular blocks such as diagonal blocks and cross blocks and present complexity analysis and approximation algorithms.

  2. Ashtabula II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Ashtabula II Wind Farm Facility Ashtabula II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  3. Heber II Geothermal Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Heber II Geothermal Facility Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Heber II Geothermal Facility General Information Name Heber II Geothermal Facility...

  4. Kibby Mountain II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Kibby Mountain II Jump to: navigation, search Name Kibby Mountain II Facility Kibby Mountain II Sector Wind energy Facility Type Commercial Scale Wind Facility Status Under...

  5. Papalote Creek II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Papalote Creek II Jump to: navigation, search Name Papalote Creek II Facility Papalote Creek II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  6. Marengo II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Marengo II Wind Farm Facility Marengo II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  7. Springview II Wind Project | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Springview II Wind Project Jump to: navigation, search Name Springview II Wind Project Facility Springview II Wind Project Sector Wind energy Facility Type Commercial Scale Wind...

  8. Meadow Lake II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Meadow Lake II Facility Meadow Lake II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Horizon Wind...

  9. Klondike II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Klondike II Wind Farm Jump to: navigation, search Name Klondike II Wind Farm Facility Klondike II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  10. Vansycle Ridge II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Vansycle Ridge II Jump to: navigation, search Name Vansycle Ridge II Facility Vansycle Ridge II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  11. Carleton College II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Carleton College II Jump to: navigation, search Name Carleton College II Facility Carleton College II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  12. Little Pringle II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Little Pringle II Facility Little Pringle II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner SWI Wind...

  13. TE Connectivity Finds Answers in Tomography

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    TE Connectivity Finds Answers in Tomography TE Connectivity Finds Answers in Tomography Print Thursday, 22 August 2013 10:50 TE Connectivity is a world leader in connectivity-the...

  14. National Electric Transmission Congestion Study: Preliminary Findings |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Study: Preliminary Findings National Electric Transmission Congestion Study: Preliminary Findings The Department hosted three webinars in August 2012 to receive input and suggestions concerning the preliminary findings of the National Electric Transmission Congestion Study. The updated presentation used in the webinars is now available. National Electric Transmission Congestion Study: Preliminary Findings - updated presentation (908.32 KB) More Documents &

  15. Structures of Pseudomonas aeruginosa β-ketoacyl-(acyl-carrier-protein) synthase II (FabF) and a C164Q mutant provide templates for antibacterial drug discovery and identify a buried potassium ion and a ligand-binding site that is an artefact of the crystal form

    SciTech Connect (OSTI)

    Baum, Bernhard; Lecker, Laura S. M.; Zoltner, Martin; Jaenicke, Elmar; Schnell, Robert; Hunter, William N.; Brenk, Ruth

    2015-07-28

    Three crystal structures of recombinant P. aeruginosa FabF are reported: the apoenzyme, an active-site mutant and a complex with a fragment of a natural product inhibitor. The characterization provides reagents and new information to support antibacterial drug discovery. Bacterial infections remain a serious health concern, in particular causing life-threatening infections of hospitalized and immunocompromised patients. The situation is exacerbated by the rise in antibacterial drug resistance, and new treatments are urgently sought. In this endeavour, accurate structures of molecular targets can support early-stage drug discovery. Here, crystal structures, in three distinct forms, of recombinant Pseudomonas aeruginosa β-ketoacyl-(acyl-carrier-protein) synthase II (FabF) are presented. This enzyme, which is involved in fatty-acid biosynthesis, has been validated by genetic and chemical means as an antibiotic target in Gram-positive bacteria and represents a potential target in Gram-negative bacteria. The structures of apo FabF, of a C164Q mutant in which the binding site is altered to resemble the substrate-bound state and of a complex with 3-(benzoylamino)-2-hydroxybenzoic acid are reported. This compound mimics aspects of a known natural product inhibitor, platensimycin, and surprisingly was observed binding outside the active site, interacting with a symmetry-related molecule. An unusual feature is a completely buried potassium-binding site that was identified in all three structures. Comparisons suggest that this may represent a conserved structural feature of FabF relevant to fold stability. The new structures provide templates for structure-based ligand design and, together with the protocols and reagents, may underpin a target-based drug-discovery project for urgently needed antibacterials.

  16. Fossil Energy Word Find | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Word Find Fossil Energy Word Find Word Find (inlcuidng answer key) Fossil Energy Word Search (96.6 KB) More Documents & Publications Fossil Energy Crossword Puzzle Coal Study Guide for Elementary School Guide to Low-Emission Boiler and Combustion Equipment Selection

  17. Impact of substrate temperature on the structural and optical properties of strain-balanced InAs/InAsSb type-II superlattices grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Liu, Shi; Li, Hua; Cellek, Oray O.; Ding, Ding; Lin, Zhi-Yuan; Steenbergen, Elizabeth H.; He, Zhao-Yu; Johnson, Shane R.; Zhang, Yong-Hang; Center for Photonics Innovation, Arizona State University, Tempe, Arizona 85287 ; Shen, Xiao-Meng; School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287 ; Fan, Jin; Smith, David J.; Department of Physics, Arizona State University, Tempe, Arizona 85287 ; Lu, Jing

    2013-02-18

    Molecular beam epitaxial growth of strain-balanced InAs/InAs{sub 1-x}Sb{sub x} type-II superlattices on GaSb substrates has been investigated for substrate temperatures from 400 Degree-Sign C to 450 Degree-Sign C. The Sb composition is found to vary linearly with substrate temperature at constant V/III ratios. For samples grown at the optimized substrate temperature (410 Degree-Sign C), superlattice zero-order peak full-width at half-maximums are routinely less than 25 arc sec using high-resolution X-ray diffraction. Cross-sectional transmission electron microscopy images show the absence of any visible defects. Strong photoluminescence covers a wavelength range from 5.5 to 13 {mu}m at 12 K. Photoluminescence linewidth simulations show satisfactory agreement with experiments.

  18. Inert doublet model and LEP II limits

    SciTech Connect (OSTI)

    Lundstroem, Erik; Gustafsson, Michael; Edsjoe, Joakim

    2009-02-01

    The inert doublet model is a minimal extension of the standard model introducing an additional SU(2) doublet with new scalar particles that could be produced at accelerators. While there exists no LEP II analysis dedicated for these inert scalars, the absence of a signal within searches for supersymmetric neutralinos can be used to constrain the inert doublet model. This translation however requires some care because of the different properties of the inert scalars and the neutralinos. We investigate what restrictions an existing DELPHI Collaboration study of neutralino pair production can put on the inert scalars and discuss the result in connection with dark matter. We find that although an important part of the inert doublet model parameter space can be excluded by the LEP II data, the lightest inert particle still constitutes a valid dark matter candidate.

  19. L I II C

    Office of Legacy Management (LM)

    -- - L I II C rr u c c c 7 i' :- ' r' ' 7 i ' -- A' t i ()lL.H~ ORAU 89/i-29 Prepared by Oak Ridge Associated Universities Prepared for Division of Facility and Site Decommissioning Projects U.S. Department of Energy VERIFICATION OF REMEDIAL ACTIONS ALBANYRESEARCHCENTER ALBANY, OREGON P. R. C O lTEN Environmental Survey and Site Assessment Program Energy/Environment Systems Division FINAL REPORT OCTOBER 1989 NOTICES Tha opiniona l xprSaaJd harJln do not n acoaa~rlly ranKI thy oplnioru of thJ l

  20. PART II - CONTRACT CLAUSES

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    I Contract No. DE-AC27-08RV14800 Modification No. 391 I-1 PART II - CONTRACT CLAUSES SECTION I CONTRACT CLAUSES I.1 FAR 52.252-2 CLAUSES INCORPORATED BY REFERENCE (FEB 1998) This Contract incorporates one or more clauses by reference, with the same force and effect as if they were given in full text. Upon request, the Contracting Officer will make their full text available. Also, the full text of a clause may be accessed electronically at these addresses: http://www.arnet.gov/far/

  1. Cori Phase II Schedule

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Schedule Cori Phase II Schedule Before Cori can be released to users, it must be delivered, integrated with Phase I, and accepted. This page is the resource for the Cori upgrade and installation schedule. For the current status of Cori, please see the Cori Updates and Status page. Impact on NERSC Users While NERSC is making every effort to minimize inconvenience to users, there are some unavoidable downtimes of Cori Phase I for the upgrade of its operating system and integration with Cori Phase

  2. Breezy Bucks II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Breezy Bucks II Facility Breezy Bucks II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Breezy Bucks II...

  3. Salty Dog II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Salty Dog II Facility Salty Dog II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Salty Dog II LLC...

  4. Cu(II) promotes amyloid pore formation

    SciTech Connect (OSTI)

    Zhang, Hangyu; Rochet, Jean-Christophe; Stanciu, Lia A.

    2015-08-14

    The aggregation of α-synuclein is associated with dopamine neuron death in Parkinson's disease. There is controversy in the field over the question of which species of the aggregates, fibrils or protofibrils, are toxic. Moreover, compelling evidence suggested the exposure to heavy metals to be a risk of PD. Nevertheless, the mechanism of metal ions in promoting PD remains unclear. In this research, we investigated the structural basis of Cu(II) induced aggregation of α-synuclein. Using transmission electron microscopy experiments, Cu(II) was found to promote in vitro aggregation of α-synuclein by facilitating annular protofibril formation rather than fibril formation. Furthermore, neuroprotective baicalein disaggregated annular protofibrils accompanied by considerable decrease of β-sheet content. These results strongly support the hypothesis that annular protofibrils are the toxic species, rather than fibrils, thereby inspiring us to search novel therapeutic strategies for the suppression of the toxic annular protofibril formation. - Highlights: • Cu(II) promoted the annular protofibril formation of α-synuclein in vitro. • Cu(II) postponed the in vitro fibrillization of α-synuclein. • Neuroprotective baicalein disaggregated annular protofibrils.

  5. Removal of Ca2+ from the Oxygen-Evolving Complex in Photosystem II Has Minimal Effect on the Mn4O5 Core Structure: A Polarized Mn X-ray Absorption Spectroscopy Study

    SciTech Connect (OSTI)

    Lohmiller, Thomas; Shelby, Megan L.; Long, Xi; Yachandra, Vittal K.; Yano, Junko

    2015-05-19

    We studied Ca2+ -depleted and Ca2+ -reconstituted spinach photosystem II using polarized X-ray absorption spectroscopy of oriented PS II preparations to investigate the structural and functional role of the Ca2+ ion in the Mn4O5Ca cluster of the oxygen-evolving complex (OEC). Samples were prepared by low pH/citrate treatment as one-dimensionally ordered membrane layers and poised in the Ca2+ -depleted S1 (S1') and S2 (S2') states, the S2'YZ• state, at which point the catalytic cycle of water oxidation is inhibited, and the Ca2+ -reconstituted S1 state. Polarized Mn K-edge XANES and EXAFS spectra exhibit pronounced dichroism. Polarized EXAFS data of all states of Ca2+ -depleted PS II investigated show only minor changes in distances and orientations of the Mn-Mn vectors compared to the Ca2+ -containing OEC, which may be attributed to some loss of rigidity of the core structure. Thus, removal of the Ca2+ ion does not lead to fundamental distortion or rearrangement of the tetranuclear Mn cluster, which indicates that the Ca2+ ion in the OEC is not critical for structural maintenance of the cluster, at least in the S1 and S2 states, but fulfills a crucial catalytic function in the mechanism of the water oxidation reaction. On the basis of this structural information, reasons for the inhibitory effect of Ca2+ removal are discussed, attributing to the Ca2+ ion a fundamental role in organizing the surrounding (substrate) water framework and in proton-coupled electron transfer to YZ• (D1-Tyr161).

  6. Nemesis I: Parallel Enhancements to ExodusII

    Energy Science and Technology Software Center (OSTI)

    2006-03-28

    NEMESIS I is an enhancement to the EXODUS II finite element database model used to store and retrieve data for unstructured parallel finite element analyses. NEMESIS I adds data structures which facilitate the partitioning of a scalar (standard serial) EXODUS II file onto parallel disk systems found on many parallel computers. Since the NEMESIS I application programming interface (APl)can be used to append information to an existing EXODUS II files can be used on filesmore » which contain NEMESIS I information. The NEMESIS I information is written and read via C or C++ callable functions which compromise the NEMESIS I API.« less

  7. THE SURVEY OF LINES IN M31 (SLIM): INVESTIGATING THE ORIGINS OF [C II] EMISSION

    SciTech Connect (OSTI)

    Kapala, M. J.; Sandstrom, K.; Groves, B.; Kreckel, K.; Schinnerer, E.; Walter, F.; Fouesneau, M. [Max Planck Institut fr Astronomie, Knigstuhl 17, D-69117 Heidelberg (Germany); Croxall, K. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Dalcanton, J. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Leroy, A., E-mail: kapala@mpia.de [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States)

    2015-01-01

    The [C II] 158 ?m line is one of the strongest emission lines observed in star-forming galaxies and has been empirically measured to correlate with the star-formation rate (SFR) globally and on kiloparsec scales. However, because of the multiphase origins of [C II], one might expect this relation to break down at small scales. We investigate the origins of [C II] emission by examining high spatial resolution observations of [C II] in M31 with the Survey of Lines in M31. We present five ?700 700 pc (3' 3') fields mapping the [C II] emission, H? emission, and the ancillary infrared (IR) data. We spatially separate star-forming regions from diffuse gas and dust emission on ?50 pc scales. We find that the [C II]-SFR correlation holds even at these scales, although the relation typically has a flatter slope than found at larger (kiloparsec) scales. While the H? emission in M31 is concentrated in the SFR regions, we find that a significant amount (?20%-90%) of the [C II] emission comes from outside star-forming regions and that the total IR emission (TIR) has the highest diffuse fraction of all SFR tracers. We find a weak correlation of the [C II]/TIR to dust color in each field and find a large-scale trend of increasing [C II]/TIR with galactocentric radius. The differences in the relative diffuse fractions of [C II], H?, and IR tracers are likely caused by a combination of energetic photon leakage from H II regions and heating by the diffuse radiation field arising from older (B-star) stellar populations. However, we find that by averaging our measurements over kiloparsec scales, these effects are minimized, and the relation between [C II] and SFR found in other nearby galaxy studies is retrieved.

  8. Heterodifunctional ligands derived from monooxidized Bis(phosphino)amines. Synthesis and transition metal (Molybdenum(0), Tungsten(0), Rhodium(I), Palladium(II), and Platinum(II)) complexes of (Diphenylphosphino)(diphenylphosphinothioyl)- and (Diphenylphosphino) (diphenylphosphinoselenoyl)phenylamine, Ph[sub 2]PN(Ph)P(E)PH[sub 2] (E = S, Se). Crystal and molecular structure of the Pt(II) Complex [Cl[sub 2]P[ovr tPPh[sub 2]N(Ph)P(S)]Ph[sub 2

    SciTech Connect (OSTI)

    Balakrishna, M.S.; Klein, R.; Uhlenbrock, S.; Pinkerton, A.A.; Cavell, R.G. )

    1993-12-08

    Bis(diphenylphosphino)phenylamine can be selectivity oxidized by S or Se in toluene or hexane solvents to the monooxidized thioyl or selenoyl products Ph[sub 2]PN(PH)PPh[sub 2]=E, (E = S, Se). These compounds act as bidentate chelate ligands toward metal complexes forming (CO)[sub 4]M(LL) (M = Mo, W), CO(Cl)Rh(LL), and Cl[sub 2]M(LL), (M = Pt, Pd) where (LL) is the thioyl or selenoyl derivative of the aminobis(phosphine). IR and NMR data are given for all complexes. The carbonyl infrared stretching frequencies show that the chelates form with the phosphine cis to any CO which is present. The [sup 31]P NMR of all complexes of two doublets except for the Rh complexes wherein the Rh spin also couples to phosphorous to produce two doublets of doublets. The [sup 2]J[sub PP] values range from 56 to 112 Hz. [sup 1]J[sub PSe] coupling provide valuable assistance for the assignment of the phosphorus resonances which range widely from 55 to 126 ppm for P[sup III] and from 60 to 80 ppm for the P[sup v] case. Assignment of P[sup III] and P[sup V] signals, which invert relative shift positions on occasion, is aided by the analysis of appropriate spin satellites arising from the substituents. It is concluded that coordination shifts for P[sup III] are always positive, ranging from 22 ppm for Pt[sup II] complexes to 70 ppm for Rh[sup I] complexes. Coordination shifts for P[sup V] centers are much smaller, e.g. 0.12 ppm, and in some cases the coordination shifts for the P[sup V] centers are negative versus the free ligand.

  9. Right rock: Finding/refining customer expectations

    SciTech Connect (OSTI)

    Ashby, R.

    1997-11-01

    This report contains viewgraphs on methods of finding customer expectations of software and then refining the documentation and software to fit these expectations.

  10. Distributed PV Interconnection: Recent Analysis Findings

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    survey of utility interconnection practices. o SEPA finds that utilities confront common challenges as they move towards more streamlined interconnection application ...

  11. Distributed PV Interconnection Recent Analysis Findings

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Thank you for joining the Distributed Generation Interconnection Collaborative ... which each will discuss recent research and analysis findings related to interconnection. ...

  12. ORISE: Forensic scientist finds truth in fingerprints

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Forensic scientist finds truth in fingerprints For more than 30 years, Imogene Van Buren has searched for truth in the friction ridges of fingerprints. She has identified victims...

  13. Mod II Stirling engine overviews

    SciTech Connect (OSTI)

    Farrell, R.A.

    1988-01-01

    The Mod II engine is a second-generation automotive Stirling engine (ASE) optimized for part-power operation. It has been designed specifically to meet the fuel economy and exhaust emissions objectives of the ASE development program. The design, test experience, performance, and comparison of data to analytical performance estimates of the Mod II engine to date are reviewed. Estimates of Mod II performance in its final configuration are also given. 12 references.

  14. Mod II engine performance

    SciTech Connect (OSTI)

    Richey, A.E.; Huang, S.C.

    1987-01-01

    The Automotive Stirling Engine Program (ASE) is directed at the development of a kinematic Stirling engine for automotive use. This program is sponsored by the Department of Energy (DOE) and managed by the NASA-Lewis Research Center (NASA-LeRC). Following proof-of-concept testing and development of promising performance values with early versions of the Stirling engine, a production-type automotive design, the Mod II engine, was developed. The design of this engine and its systems has been previously presented. Based on this design, the first engine has been built and development testing has started. Projections for this first engine build are presented in this paper. Results of initial tests are also given including identification of development items and formulation of plans for resolution of existing deficiencies.

  15. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    for heavy element production...II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui,...

  16. Project Home Again Phase II

    SciTech Connect (OSTI)

    2010-01-30

    Phase II is a continuation of a charitable residential community project in New Orleans that builds affordable and energy efficient single detached residences that are storm resistant.

  17. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate; White, David; Hoste, Graeme

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  18. Synthesis, X-ray crystal structure, optical properties and DFT studies of a new 2D layered iodide bridged Pb(II) coordination polymer with 2,3-bis(2-pyridyl)pyrazine

    SciTech Connect (OSTI)

    Saghatforoush, Lotfali Bakhtiari, Akbar; Gheleji, Hojjat

    2015-01-15

    The synthesis of two dimensional (2D) coordination polymer [Pb{sub 2}(µ-I){sub 2}(µ-dpp-N,N,N,N)(µ-dpp-N,N)I{sub 2}]{sub n} (dpp=2,3-bis(2-pyridyl)pyrazine) is reported. As determined by X-ray diffraction of a twinned crystal, the dpp ligand simultaneously adopts a bis–bidentate and bis–monodentate coordination mode in the crystal structure of compound. The electronic band structure along with density of states (DOS) calculated by the DFT method indicates that the compound is an indirect band gap semiconductor. According to the DFT calculations, the observed emission of the compound at 600 nm in solid phase could be attributed to arise from an excited LLCT state (dpp-π{sup ⁎} [C-2p and N-2p states, CBs] to I-6p state [VBs]). The linear optical properties of the compound are also calculated by DFT method. The structure of the compound in solution phase is discussed based on the measured {sup 1}H NMR and fluorescence spectra in DMSO. TGA studies indicate that the compound is thermally stable up to 210 °C. - Graphical abstract: The synthesis, crystal structure and emission spectra of [Pb{sub 2}(µ-I){sub 2}(µ-dpp-N,N,N,N)(µ-dpp-N,N)I{sub 2}]{sub n} is presented. The electronic band structure and linear optical properties of the compound are calculated by the DFT method. - Highlights: • Two dimensional [Pb{sub 2}(µ-I){sub 2}(µ-dpp-N,N,N,N)(µ-dpp-N,N)I{sub 2}]{sub n} has been prepared. • The structure of the compound is determined by XRD of a twinned crystal. • DFT calculations indicate that the compound is an indirect band gap semiconductor. • As shown by DFT calculations, the emission band of the compound is LLCT. • Solution phase structure of compound is explored by {sup 1}H NMR and emission spectra.

  19. A THOUSAND SHADOWS OF ANDROMEDA: ROTATING PLANES OF SATELLITES IN THE MILLENNIUM-II COSMOLOGICAL SIMULATION

    SciTech Connect (OSTI)

    Ibata, Rodrigo A.; Martin, Nicolas F.; Ibata, Neil G.; Lewis, Geraint F.; Conn, Anthony; Elahi, Pascal; Arias, Veronica; Fernando, Nuwanthika

    2014-03-20

    In a recent contribution, Bahl and Baumgardt investigated the incidence of planar alignments of satellite galaxies in the Millennium-II simulation and concluded that vast, thin planes of dwarf galaxies, similar to that observed in the Andromeda galaxy (M31), occur frequently by chance in ?-cold dark matter cosmology. However, their analysis did not capture the essential fact that the observed alignment is simultaneously radially extended, yet thin, and kinematically unusual. With the caveat that the Millennium-II simulation may not have sufficient mass resolution to identify confidently simulacra of low-luminosity dwarf galaxies, we re-examine that simulation for planar structures, using the same method as employed by Ibata etal. on the real M31 satellites. We find that 0.04% of host galaxies display satellite alignments that are at least as extreme as the observations, when we consider their extent, thickness, and number of members rotating in the same sense. We further investigate the angular momentum properties of the co-planar satellites, and find that the median of the specific angular momentum derived from the line-of-sight velocities in the real M31 structure (1.3 10{sup 4} km s{sup 1} kpc) is very high compared to systems drawn from the simulations. This analysis confirms that it is highly unlikely that the observed structure around the Andromeda galaxy is due to a chance occurrence. Interestingly, the few extreme systems that are similar to M31 arise from the accretion of a massive sub-halo with its own spatially concentrated entourage of orphan satellites.

  20. Project Final Report: HPC-Colony II (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Project Final Report: HPC-Colony II Citation Details In-Document Search Title: Project Final Report: HPC-Colony II This report recounts the HPC Colony II Project which was a computer science effort funded by DOE's Advanced Scientific Computing Research office. The project included researchers from ORNL, IBM, and the University of Illinois at Urbana-Champaign. The topic of the effort was adaptive system software for extreme scale parallel machines. A description of findings is included. Authors:

  1. National Synchrotron Light Source II

    ScienceCinema (OSTI)

    Steve Dierker

    2010-01-08

    The National Synchrotron Light Source II (NSLS-II) at the U.S. Department of Energy's Brookhaven National Laboratory is a proposed new state-of-the-art medium energy storage ring designed to deliver world-leading brightness and flux with top-off operation

  2. Cloud structure of the nearest brown dwarfs. II: High-amplitude variability for Luhman 16 A and B in and out of the 0.99 μm FeH feature

    SciTech Connect (OSTI)

    Buenzli, Esther; Marley, Mark S.; Apai, Daniel; Saumon, Didier; Biller, Beth A.; Crossfield, Ian J. M.; Radigan, Jacqueline

    2015-10-20

    The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm. We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.

  3. Cloud structure of the nearest brown dwarfs. II: High-amplitude variability for Luhman 16 A and B in and out of the 0.99 μm FeH feature

    DOE PAGES-Beta [OSTI]

    Buenzli, Esther; Marley, Mark S.; Apai, Daniel; Saumon, Didier; Biller, Beth A.; Crossfield, Ian J. M.; Radigan, Jacqueline

    2015-10-20

    The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm.more » We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.« less

  4. EA-1375: Finding of No Significant Impact

    Energy.gov [DOE]

    Construction and Operation of a New Office Building and Related Structures Within TA-3 at Los Alamos National Laboratory, Los Alamos, New Mexico

  5. Missourian Finds New Opportunity in Energy Industry

    Energy.gov [DOE]

    How one Missouri man decided to take matters into his own hands - creating a company that improves energy efficiency in homes and buildings - after not being able to find work during the recession.

  6. Distributed PV Interconnection Recent Analysis Findings

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Recent Analysis Findings Page 1 of 18 Kristen Ardani, Miriam Makhyoun Page 1 of 18 [Speaker: Kristen Ardani] Cover Slide: Good afternoon, everyone. Thank you for joining the Distributed Generation Interconnection Collaborative informational webinar. Today, we are kicking off 2015 with a joint presentation from SEPA and NREL, in which each will discuss recent research and analysis findings related to interconnection. Slide 2: So really, the purpose of today's meeting is to hear recent research

  7. Distributed PV Interconnection: Recent Analysis Findings

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    January 21, 2015 "NREL and SEPA Recent Analysis Findings" Miriam Makhyoun, Solar Electric Power Association (SEPA) Kristen Ardani, National Renewable Energy Laboratory (NREL) 2 Purpose of Today's Meeting * Hear results from SEPA's recent survey of utility interconnection practices. o SEPA finds that utilities confront common challenges as they move towards more streamlined interconnection application processing. * Hear NREL results of forthcoming DGIC data collection and analysis,

  8. Mars Rover finds changing rocks, surprising scientists

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Mars Rover finds changing rocks, surprising scientists Mars Rover finds changing rocks, surprising scientists As NASA's Curiosity rover treks up a three-mile-high mountain on Mars, the rocks are changing. Back on Earth, scientists analyzing the data realized this was something different: It turned out to be the first of the high-silica rocks. December 24, 2015 Mars landscape This color-adjusted composite of images taken by NASA's Curiosity rover in September shows the lower portion of Mount

  9. Floodplain Assessment and Statement of Findings

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    and Statement of Findings for Installation of a Renewable Energy Anaerobic Digester Facility at the University of California, Davis in Yolo County, California January 28, 2013 1.0 Introduction This Floodplain Assessment and Statement of Findings has been prepared in accordance with 10 Code of Federal Regulations (CFR) 1022, "Compliance with Floodplain and Wetland Environmental Review Requirements" which were promulgated to implement the requirements of the U.S. Department of Energy's

  10. Floodplain Statement of Findings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Floodplain Statement of Findings Floodplain Statement of Findings Loan Guarantee to AES Energy Storage, LLC Project Dyno Electric Grid Stability Advanced Battery Systems Project Dyno would provide ancillary services within the New York power market. The Project is composed of advanced lithium ion battery cells and power control technologies to store power to help maintain the stability of the electric power grid. The Project would be composed of ten fifty-three foot metal containers each housing

  11. Jefferson Laboratory Findings Excite Theoreticians, Experimentatlists |

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Jefferson Lab Laboratory Findings Excite Theoreticians, Experimentatlists Jefferson Laboratory Findings Excite Theoreticians, Experimentatlists March 1999 Seemingly reasonable assumptions define the human view of the world. But ruled of thumb can mislead - or be altogether incorrect. Fortunately, in physics, most assumptions can be tested. Those that don't measure up are amended. An experiment at the Department of Energy's Thomas Jefferson National Accelerator Facility (Jefferson Lab) has

  12. Current-wave spectra coupling project. Volume IV. Part A. Formulation of the three-dimensional structure of storm-generated currents. Part B. Summaries of Volumes I, II and III

    SciTech Connect (OSTI)

    Venezian, G.; Bretschneider, C.L.

    1980-09-01

    An attempt is made to formulate the technical approach to the problem of three dimensional wind driven currents under hurricane conditions. Reference is given to the splendid piece of research on the subject by Forristall (1974) Three-dimensional structure of storm-generated currents, J. Geophys. Res. 79, 2721-2727. The present approach, although not entirely satisfactory, seems to be an improvement on the work by Forristall, but this remains to be verified with future work, including the use of measured data. An improvement could be made if there were some better way of representing the shear stress as a function of the wind velocity (wind speed and direction). It seems that the wind velocity relative to the water motion is what matters, but in turbulent flow the surface value is not well defined. This difficulty leaves one with an unbalanced vortex stretching which accounts for the spin-up of the fluid, but the details of that are lacking. Essentially, it appears that it is feasible to modify Forristall's approach to obtain a more realistic representation of the structure of the boundary layer to take into account the turbulent nature of the flow.

  13. Dimorphism in iron(II) methylphosphonate: Low-temperature crystal structure and temperature-dependent Mossbauer studies of a new form of the layered weak ferromagnet Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)

    SciTech Connect (OSTI)

    Leone, Philippe . E-mail: philippe.leone@cnrs-imn.fr; Palvadeau, Pierre; Boubekeur, Kamal; Meerschaut, Alain; Bellitto, Carlo; Bauer, Elvira M.; Righini, Guido; Fabritchnyi, Pavel

    2005-04-15

    A second form of the literature-known layered weak ferromagnet Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)] has been isolated. The crystal structure determination of this new form (2) has been carried out at T=300, 200 and 130K. It crystallizes in the orthorhombic space group Pmn2{sub 1}: a=5.7177(11), b=8.8093(18), c=4.8154(10)A, while form (1) crystallizes in the space group Pna2{sub 1}: a=17.58(2), b=4.814(1), c=5.719(1)A. Moessbauer spectroscopy on form (2) has been performed in the temperature range 4-300K; and, at T{approx}160K, a drastic change in the quadrupole splitting ({delta}E) and a broadening of the doublet components is noticed. But surprisingly, on cooling the crystal, no structural change is observed, which could account for the increase in {delta}E. Below T=25K, {sup 57}Fe spectra transform into hyperfine splitting patterns which reveal a magnetically ordered state in agreement with the results of earlier magnetic susceptibility studies.

  14. Methods for preparation of cyclopentadienyliron (II) arenes

    DOE Patents [OSTI]

    Keipert, Steven J.

    1991-01-01

    Two improved methods for preparation of compounds with the structure shown in equation X [(Cp)--Fe--(Ar)].sup.+.sub.b X.sup.b- (X) where Cp is an eta.sup.5 complexed, substituted or unsubstituted, cyclopentadienyl or indenyl anion, Ar is an eta.sup.6 complexed substituted or unsubstituted, pi-arene ligand anad X is a b-valent anion where b is an integer between 1 and 3. The two methods, which differ in the source of the cyclopentadienyl anion - Lewis acid complex, utilize a Lewis acid assisted ligand transfer reaction. The cyclopentadienyl anion ligand, assisted by a Lewis acid is transferred to ferrous ion in the presence of an arene. In the first method, the cyclopentadienyl anion is derived from ferrocene and ferrous chloride. In this reaction, the cyclopentadienyliron (II) arene product is derived partially from ferrocene and partially from the ferrous salt. In the second method, the cyclopentadienyl anion - Lewis acid complex is formed by direct reaction of the Lewis acid with an inorganic cyclopentadienide salt. The cyclopentadienyliron (II) arene product of this reaction is derived entirely from the ferrous salt. Cyclopentadienyliron (II) arene cations are of great interest due to their utility as photoactivatable catalysts for a variety of polymerization reactions.

  15. Competing retention pathways of uranium upon reaction with Fe(II)

    SciTech Connect (OSTI)

    Massey, Michael S.; Lezama Pacheco, Juan S.; Jones, Morris; Ilton, Eugene S.; Cerrato, Jose M.; Bargar, John R.; Fendorf, Scott

    2014-10-01

    Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in contaminant transport, remediation, and geologic deposition of uranium. Recent work has shown that U can become incorporated into iron (hydr)oxide minerals, with a key pathway arising from Fe(II)-induced transformation of ferrihydrite, (Fe(OH)3nH2O) to goethite (?-FeO(OH)); this is a possible U retention mechanism in soils and sediments. Several key questions, however, remain unanswered regarding U incorporation into iron (hydr)oxides and this pathways contribution to U retention, including: (i) the competitiveness of U incorporation versus reduction to U(IV) and subsequent precipitation of UO2; (ii) the oxidation state of incorporated U; (iii) the effects of uranyl aqueous speciation on U incorporation; and, (iv) the mechanism of U incorporation. Here we use a series of batch reactions conducted at pH ~7, [U(VI)] from 1 to 170 ?M, [Fe(II)] from 0 to 3 mM, and [Ca] at 0 or 4 mM) coupled with spectroscopic examination of reaction products of Fe(II)-induced ferrihydrite transformation to address these outstanding questions. Uranium retention pathways were identified and quantified using extended x-ray absorption fine structure (EXAFS) spectroscopy, x-ray powder diffraction, x-ray photoelectron spectroscopy, and transmission electron microscopy. Analysis of EXAFS spectra showed that 14 to 89% of total U was incorporated into goethite, upon reaction with Fe(II) and ferrihydrite. Uranium incorporation was a particularly dominant retention pathway at U concentrations ? 50 ?M when either uranyl-carbonato or calcium-uranyl-carbonato complexes were dominant, accounting for 64 to 89% of total U. With increasing U(VI) and Fe(II) concentrations, U(VI) reduction to U(IV) became more prevalent, but U incorporation remained a functioning retention pathway. These findings highlight the potential importance of U(V) incorporation within iron

  16. Options Study - Phase II

    SciTech Connect (OSTI)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to

  17. Timber Road II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Road II Jump to: navigation, search Name Timber Road II Facility Timber Road II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Horizon Wind...

  18. Nobles Wind Farm II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Farm II Jump to: navigation, search Name Nobles Wind Farm II Facility Nobles Wind Farm II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  19. Shiloh II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Shiloh II Wind Farm Jump to: navigation, search Name Shiloh II Wind Farm Facility Shiloh II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  20. Oliver II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Oliver II Wind Farm Facility Oliver II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NextEra...

  1. CWES II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name CWES II Wind Farm Facility CWES II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner SeaWest...

  2. Lab employee helps veterans find work

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Lab employee helps veterans find work Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:November 2, 2016 all issues All Issues » submit Lab employee helps veterans find work Cody Nevala-Amraen recruits vets to Los Alamos. November 1, 2016 Ken and Laura McClellan traveled to the Ha-Mokuba village in Lesotho, Africa, to help build a new home for the Lecheko family. Cody Nevala-Amraen is a U.S. Marine Corps veteran who served in Iraq and

  3. Investigators find hundreds of intentional nuclear releases

    SciTech Connect (OSTI)

    Lobsenz, G.

    1994-10-24

    Investigators with the federal Advisory Committee on Human Radiation Experiments have said that the category of intentional releases is now known to be larger, in variety and quantity, than the 13 releases identified prior to the committee`s formation in January 1994 by President Clinton. The committee is now aware of hundreds of additional intentional releases. In addition to the intentional releases, the committee said it had compiled documents on 400 biomedical experiments involving radiation prior to 1975, and had at least fragmentary evidence of more than 1,000 more. The committee also discovered a top secret 1953 Defense Department policy statement on human experimentation that was based on the World War II-era Nuremberg Code. The committee said it was looking into how or whether the policy was implemented. The committee is expected to issue a final report, including recommendations on possible compensation for victims by April 1995.

  4. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    II-12 Y. G. Ma, R. Wada, K. Hagel, J. Wang, T. Keutgen, Z. Majka, M. Murray, L. Qin, P. Smith, J. B. Natowitz, R. Alfarro, J. Cibor, M. Cinausero, Y. El Masri, D....

  5. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... L. W. May, S. Wuenschel, B. Stein, and S. J. Yennello Analysis of 86,78Kr + 64,58Ni data taken on the upgraded NIMROD-ISiS...... II-28 S. Wuenschel, S. ...

  6. PARS II 104 Contractor Monthly Upload | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    104 Contractor Monthly Upload PARS II 104 Contractor Monthly Upload PDF icon PARS II 104 Contractor Monthly Upload More Documents & Publications PARS II TRAINING PARS II Training ...

  7. Cinergy Ventures II LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Cinergy Ventures II LLC Jump to: navigation, search Name: Cinergy Ventures II, LLC Place: Cincinnati, Ohio Zip: OH 45202 Product: The venture capital arm of Cinergy Corp....

  8. Harvest Wind Farm II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Harvest Wind Farm II Facility Harvest Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner John...

  9. Kotzebue Wind Project II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Kotzebue Wind Project II Facility Kotzebue Wind Project Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  10. Tatanka Wind Project II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Tatanka Wind Project II Facility Tatanka Wind Project Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  11. Cabazon Wind Farm II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Cabazon Wind Farm II Facility Cabazon Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Goldman Sachs...

  12. Endicott Biofuels II LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Endicott Biofuels II LLC Jump to: navigation, search Name: Endicott Biofuels II, LLC Place: Houston, Texas Zip: 77060-3235 Sector: Biofuels Product: Houston-based biofuels producer...

  13. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ....................................................................II-1 S. Kowalski, J.B. Natowitz, S. Shlomo, R. Wada, K. Hagel, J.S. Wang, T. Keutgen, T. Materna, Z. Chen, Y. Ma, L. Qin, A.S. Botvina, M. Cinausero, Y. El Masri, D. Fabris, M. Lunardon, Z. Majka, S. Moretto, G. Nebbia, S. Presente, G. Prete, V. Rizzi, G. Viesti, and A. Ono Refining Reaction Dynamics in Fermi Energy Heavy Ion

  14. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    HEAVY ION REACTIONS Alternative mechanisms for heavy element production......................................................II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui, S. Moretto, D. Fabris, M. Lunardon, M. Morando, G. Nebbia, S. Pesente, V. Rizzi, G. Viesti, V. Bocci, A. Andrighetto, M. Cinausero, G. Prete, Z. Majka, A. Wieloch, and S. Kowalski Z-dependence of isoscaling parameter in central heavy ion collisions at intermediate energy......II-3 Z.

  15. SECTION II: HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Light particle clusterization in nuclear matter at very low density.......................................... II-1 L. Qin, J. B. Natowitz, G. Roepke, K. Hagel, R. Wada, Z. Chen, P. Sahu, S. Kowalski, C. Bottosso , S. Shlomo, M. Barbui, D. Fabris, M. Lunardon, S. Moretto, G. Nebbia, S. Pesente, V. Rizzi, G. Viesti, M. Cinausero, G. Prete, T. Keutgen, Y. El Masri, and Z. Majka A new order parameter for IMF isotope distributions.............................................................. II-4 Z.

  16. Oak Ridge Associated Universities II

    Office of Legacy Management (LM)

    Prepared by Oak Ridge Associated Universities II Prepared for Division of Fuel - Cycle and Material Safety II U.S. Nuclear Regulatory Commission L RADIOLOGICAL SURVEY OF THE W. R. GRACE PROPERTY WAYNE, NEW JERSEY P. W. FRAME Radiological Site Assessment Program Manpower Education, Research, and Training Division FINAL REPORT January 1983 RADIOLOGICAL SURVEY OF THE W.R. GRACE PROPERTY WAYNE, NEW JERSEY Prepared for Division of Fuel Cycle and Material Safety U.S. Nuclear Regulatory Commission P.

  17. An interesting finding in sup 229 Th

    SciTech Connect (OSTI)

    Reich, C.W.

    1990-01-01

    Work at INEL has recently established that the first excited states of {sup 229}Th forms a closely spaced doublet with the ground state, the separation being 1 {plus minus} 4 electron volts. A discussion of the data and the reasoning supporting this unprecedented finding is given. Some potential applications are briefly mentioned. 27 refs., 3 figs., 2 tabs.

  18. Finding a Career in Energy Efficiency

    Energy.gov [DOE]

    Kendra went to a county agency hoping they could help her find work, but what she really wanted was a career. That’s when she was referred to an upcoming weatherization training program hosted by the Laborers’ International Union of North America, a half-million strong labor union for construction workers, including weatherization workers.

  19. DOE issues Finding of No Significant Impact on the Disposition of Five Signature Properties at Idaho National Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy (DOE) has determined that tearing down four World War II-era historic structures and part of another structure at Idaho National Laboratory’s Central Facilities Area that remain from when the area served as the U.S. Naval Proving Ground will not have a significant impact on the environment.

  20. Lab supercomputer finds new home at UNM

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Lab supercomputer to UNM Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:November 2, 2016 all issues All Issues » submit Lab supercomputer finds new home at UNM Chance of a lifetime for students with complex research projects March 1, 2015 UNM logo. UNM logo. Contact Community Programs Director Kurt Steinhaus Email Editor Ute Haker Email The New Mexico Consortium has donated Los Alamos National Laboratory's Ulam supercomputer to the

  1. National Synchrotron Light Source II (NSLS-II) Project | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy National Synchrotron Light Source II (NSLS-II) Project National Synchrotron Light Source II (NSLS-II) Project National Synchrotron Light Source II (NSLS-II) Project Frank Crescenzo, NSLS-II FPD, FPD of the Year March 23, 2016 Presentation (2.39 MB) Key Resources Internal DOE Tools PMCDP EVMS PARS IIe FPD Resource Center PM Newsletter Forms and Templates More Documents & Publications EA-1558: Final Environmental Assessment EA-1321: Final Environmental Assessment National

  2. Fusion Power Demonstrations I and II

    SciTech Connect (OSTI)

    Doggett, J.N.

    1985-01-01

    In this report we present a summary of the first phase of the Fusion Power Demonstration (FPD) design study. During this first phase, we investigated two configurations, performed detailed studies of major components, and identified and examined critical issues. In addition to these design specific studies, we also assembled a mirror-systems computer code to help optimize future device designs. The two configurations that we have studied are based on the MARS magnet configuration and are labeled FPD-I and FPD-II. The FPD-I configuration employs the same magnet set used in the FY83 FPD study, whereas the FPD-II magnets are a new, much smaller set chosen to help reduce the capital cost of the system. As part of the FPD study, we also identified and explored issues critical to the construction of an Engineering Test Reactor (ETR). These issues involve subsystems or components, which because of their cost or state of technology can have a significant impact on our ability to meet FPD's mission requirements on the assumed schedule. General Dynamics and Grumman Aerospace studied two of these systems, the high-field choke coil and the halo pump/direct converter, in great detail and their findings are presented in this report.

  3. Five new Mn(II)/Co(II) coordination polymers constructed from flexible multicarboxylate ligands with varying magnetic properties

    SciTech Connect (OSTI)

    Liu, Sui-Jun; Zeng, Yong-Fei; Hu, Xin; Xue, Li; Han, Song-De; Jia, Ji-Min; Hu, Tong-Liang

    2013-08-15

    Five new Mn(II)/Co(II) coordination polymers [Mn{sub 2}(Adi){sub 2}(DMA)]{sub n} (1), [Mn{sub 2}(Adi){sub 2}(DMF)]{sub n} (2), [Mn{sub 4}(Adi){sub 4}(DMF){sub 2}]{sub n} (3), [Co{sub 4}(Adi){sub 4}(DMF){sub 2}]{sub n} (4) and ([Co{sub 3}(Cit){sub 2}(H{sub 2}O){sub 3}]·(H{sub 2}O)){sub n} (5) [Adi=adipate anion, Cit=citrate anion, DMA=N,N′-dimethylacetamide and DMF=N,N′-dimethylformamide] have been successfully constructed from two flexible multicarboxylate ligands under solvothermal conditions. Complexes 1 and 2 exhibit 2-D network featured 1-D Mn{sup II} chain, 3 and 4 are 3-D frameworks containing different 1-D carboxylate–metal chain, while 5 shows a 3-D structure based on Co{sub 6} wheel clusters. Magnetic investigations indicate antiferromagnetic behaviors for 1–4 and weak ferromagnetic behavior for 5 because of distinct linkage modes of metal ions. - Graphical abstract: Five new Mn(II)/Co(II) coordination polymers display 2-D/3-D structures containing 1-D carboxylate–metal chains or wheel clusters. Magnetic analyses reveal that they show antiferromagnetic, canted antiferromagnetic and weak ferromagnetic behaviors, respectively. Highlights: ●Five new Mn(II)/Co(II) coordination polymers have been synthesized. ●A complex-based Co{sub 6} wheel cluster was obtained. ●The different magnetic properties of the complexes are discussed.

  4. BEATRIX-II, phase II: Data summary report

    SciTech Connect (OSTI)

    Slagle, O.D.; Hollenberg, G.W.

    1996-05-01

    The BEATRIX-II experimental program was an International Energy Agency sponsored collaborative effort between Japan, Canada, and the United States to evaluate the performance of ceramic solid breeder materials in a fast-neutron environment at high burnup levels. This report addresses the Phase II activities, which included two in situ tritium-recovery canisters: temperature-change and temperature-gradient. The temperature-change canister contained a Li{sub 2}O ring specimen that had a nearly uniform temperature profile and was capable of temperature changes between 530 and 640{degrees}C. The temperature-gradient canister contained a Li{sub 2}ZrO{sub 3} pebble bed operating under a thermal gradient of 440 to 1100{degrees}C. Postirradiation examination was carried out to characterize the Phase II in situ specimens and a series of nonvented capsules designed to address the compatibility of beryllium with lithium-ceramic solid-breeder materials. The results of the BEATRIX-II, Phase II, irradiation experiment provided an extensive data base on the in situ tritium-release characteristics of Li{sub 2}O and Li{sub 2}ZrO{sub 3} for lithium burnups near 5%. The composition of the sweep gas was found to be a critical parameter in the recovery of tritium from both Li{sub 2}O and Li{sub 2}ZrO{sub 3}. Tritium inventories measured confirmed that Li{sub 2}O and Li{sub 2}ZrO{sub 3} exhibited very low tritium retention during the Phase II irradiation. Tritium inventories in Li{sub 2}ZrO{sub 3} after Phase II tended to be larger than those found for Li{sub 2}ZrO{sub 3} in other in situ experiments, but the larger values may reflect the larger generation rates in BEATRIX-II. A series of 20 capsules was irradiated to determine the compatibility of lithium ceramics and beryllium under conditions similar to a fusion blanket. It is concluded that Li{sub 2}O and Li{sub 2}ZrO{sub 3} should remain leading candidates for use in a solid-breeder fusion-blanket application.

  5. The lick AGN monitoring project 2011: Fe II reverberation from the outer broad-line region

    SciTech Connect (OSTI)

    Barth, Aaron J.; Cooper, Michael C.; Pancoast, Anna; Treu, Tommaso; Bennert, Vardha N.; Brewer, Brendon J.; Canalizo, Gabriela; Filippenko, Alexei V.; Li, Weidong; Cenko, S. Bradley; Clubb, Kelsey I.; Gates, Elinor L.; Greene, Jenny E.; Malkan, Matthew A.; Sand, David J.; Stern, Daniel; Assef, Roberto J.; Woo, Jong-Hak; Bae, Hyun-Jin; Buehler, Tabitha; and others

    2013-06-01

    The prominent broad Fe II emission blends in the spectra of active galactic nuclei have been shown to vary in response to continuum variations, but past attempts to measure the reverberation lag time of the optical Fe II lines have met with only limited success. Here we report the detection of Fe II reverberation in two Seyfert 1 galaxies, NGC 4593 and Mrk 1511, based on data from a program carried out at Lick Observatory in Spring 2011. Light curves for emission lines including H? and Fe II were measured by applying a fitting routine to decompose the spectra into several continuum and emission-line components, and we use cross-correlation techniques to determine the reverberation lags of the emission lines relative to V-band light curves. In both cases, the measured lag (?{sub cen}) of Fe II is longer than that of H?, although the inferred lags are somewhat sensitive to the choice of Fe II template used in the fit. For spectral decompositions done using the Fe II template of Vron-Cetty et al., we find ?{sub cen}(Fe II)/?{sub cen}(H?) = 1.9 0.6 in NGC 4593 and 1.5 0.3 in Mrk 1511. The detection of highly correlated variations between Fe II and continuum emission demonstrates that the Fe II emission in these galaxies originates in photoionized gas, located predominantly in the outer portion of the broad-line region.

  6. FAR-INFRARED FINE-STRUCTURE LINE DIAGNOSTICS OF ULTRALUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Farrah, D.; Petty, S. M.; Harris, K.; Lebouteiller, V.; Spoon, H. W. W.; Bernard-Salas, J.; Pearson, C.; Rigopoulou, D.; Smith, H. A.; Gonzlez-Alfonso, E.; Clements, D. L.; Efstathiou, A.; Cormier, D.; Afonso, J.; Hurley, P.; Borys, C.; Verma, A.; Cooray, A.; Salvatelli, V.

    2013-10-10

    We present Herschel observations of 6 fine-structure lines in 25 ultraluminous infrared galaxies at z < 0.27. The lines, [O III]52 ?m, [N III]57 ?m, [O I]63 ?m, [N II]122 ?m, [O I]145 ?m, and [C II]158 ?m, are mostly single Gaussians with widths <600 km s{sup 1} and luminosities of 10{sup 7}-10{sup 9} L{sub ?}. There are deficits in the [O I]63/L{sub IR}, [N II]/L{sub IR}, [O I]145/L{sub IR}, and [C II]/L{sub IR} ratios compared to lower luminosity systems. The majority of the line deficits are consistent with dustier H II regions, but part of the [C II] deficit may arise from an additional mechanism, plausibly charged dust grains. This is consistent with some of the [C II] originating from photodissociation regions or the interstellar medium (ISM). We derive relations between far-IR line luminosities and both the IR luminosity and star formation rate. We find that [N II] and both [O I] lines are good tracers of the IR luminosity and star formation rate. In contrast, [C II] is a poor tracer of the IR luminosity and star formation rate, and does not improve as a tracer of either quantity if the [C II] deficit is accounted for. The continuum luminosity densities also correlate with the IR luminosity and star formation rate. We derive ranges for the gas density and ultraviolet radiation intensity of 10{sup 1} < n < 10{sup 2.5} and 10{sup 2.2} < G{sub 0} < 10{sup 3.6}, respectively. These ranges depend on optical type, the importance of star formation, and merger stage. We do not find relationships between far-IR line properties and several other parameters: active galactic nucleus (AGN) activity, merger stage, mid-IR excitation, and SMBH mass. We conclude that these far-IR lines arise from gas heated by starlight, and that they are not strongly influenced by AGN activity.

  7. EBR-II Data Digitization

    SciTech Connect (OSTI)

    Yoon, Su-Jong; Rabiti, Cristian; Sackett, John

    2014-08-01

    1. Objectives To produce a validation database out of those recorded signals it will be necessary also to identify the documents need to reconstruct the status of reactor at the time of the beginning of the recordings. This should comprehends the core loading specification (assemblies type and location and burn-up) along with this data the assemblies drawings and the core drawings will be identified. The first task of the project will be identify the location of the sensors, with respect the reactor plant layout, and the physical quantities recorded by the Experimental Breeder Reactor-II (EBR-II) data acquisition system. This first task will allow guiding and prioritizing the selection of drawings needed to numerically reproduce those signals. 1.1 Scopes and Deliverables The deliverables of this project are the list of sensors in EBR-II system, the identification of storing location of those sensors, identification of a core isotopic composition at the moment of the start of system recording. Information of the sensors in EBR-II reactor system was summarized from the EBR-II system design descriptions listed in Section 1.2.

  8. Site Environmental Report for 1999 - Volume II

    SciTech Connect (OSTI)

    Ruggieri, M.

    2000-08-01

    Each year, Ernest Orlando Lawrence Berkeley National Laboratory prepares an integrated report on its environmental programs to satisfy the requirements of United States Department of Energy Order 231.1. The Site Environmental Report for 1999 is intended to summarize Berkeley Lab's compliance with environmental standards and requirements, characterize environmental management efforts through surveillance and monitoring activities, and highlight significant programs and efforts for calendar year 1999. The report is separated into two volumes. Volume I contains a general overview of the Laboratory, the status of environmental programs, and summary results from surveillance and monitoring activities. Each chapter in Volume I begins with an outline of the sections that follow, including any tables or figures found in the chapter. Readers should use section numbers (e.g., {section}1.5) as navigational tools to find topics of interest in either the printed or the electronic version of the report. Volume II contains the individual data results from monitoring programs.

  9. Safety analysis report for the TRUPACT-II shipping package (condensed version). Volume 1, Rev. 14

    SciTech Connect (OSTI)

    1994-10-01

    The condensed version of the TRUPACT-II Contact Handled Transuranic Waste Safety Analysis Report for Packaging (SARP) contains essential material required by TRUPACT-II users, plus additional contents (payload) information previously submitted to the U.S. Nuclear Regulatory Commission. All or part of the following sections, which are not required by users of the TRUPACT-II, are deleted from the condensed version: (i) structural analysis, (ii) thermal analysis, (iii) containment analysis, (iv) criticality analysis, (v) shielding analysis, and (vi) hypothetical accident test results.

  10. Best Possible Strategy for Finding Ground States

    SciTech Connect (OSTI)

    Franz, Astrid; Hoffmann, Karl Heinz; Salamon, Peter

    2001-06-04

    Finding the ground state of a system with a complex energy landscape is important for many physical problems including protein folding, spin glasses, chemical clusters, and neural networks. Such problems are usually solved by heuristic search methods whose efficacy is judged by empirical performance on selected examples. We present a proof that, within the large class of algorithms that simulate a random walk on the landscape, threshold accepting is the best possible strategy. In particular, it can perform better than simulated annealing and Tsallis statistics. Our proof is the first example of a provably optimal strategy in this area.

  11. NSLS-II INJECTION CONCEPT.

    SciTech Connect (OSTI)

    SHAFTAN, T.; PINAYEV, I.; ROSE, J.; WANG, X.J.; ET AL.

    2005-05-16

    Currently the facility upgrade project is in progress at the NSLS (at Brookhaven National Laboratory). The goal of the NSLS-II is a 3 GeV ultra-low-emittance storage ring that will increase radiation brightness by three orders of magnitude over that of the present NSLS X-ray ring. The low emittance of the high brightness ring's lattice results in a short lifetime, so that a top-off injection mode becomes an operational necessity. Therefore, the NSLS-II injection system must provide, and efficiently inject, an electron beam at a high repetition rate. In this paper, we present our concept of the NSLS-II injection system and discuss the conditions for, and constraints on, its design.

  12. Focus Series: Program Finds Community "Readiness" Is the Key...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Program Finds Community "Readiness" Is the Key to More Retrofits Focus Series: Program Finds Community "Readiness" Is the Key to More Retrofits Focus Series: Program Finds ...

  13. Department of Energy Helping Americans Find Alternative Fuel...

    Office of Environmental Management (EM)

    Helping Americans Find Alternative Fuel Stations Department of Energy Helping Americans Find ... to find fuel stations, post custom fueling location maps on their own websites, ...

  14. Portsmouth Site Treatment Plan Director's Final Findings and...

    Energy Savers

    Treatment Plan Director's Final Findings and Orders Portsmouth Site Treatment Plan Director's Final Findings and Orders Portsmouth Site Treatment Plan Director's Final Findings and ...

  15. EA-2006: Finding of No Significant Impact and Mitigation Action Plan |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Finding of No Significant Impact and Mitigation Action Plan EA-2006: Finding of No Significant Impact and Mitigation Action Plan Columbia Estuary Ecosystem Restoration Program Bonneville Power Administration issued a FONSI and a floodplain and wetland statement of findings for a proposed program of actions to help restore ecological structure, function, and biodiversity within the Columbia River estuary. The mitigation measures listed in the Mitigation Action Plan and

  16. NSLS-II Preliminary Design Report

    SciTech Connect (OSTI)

    Dierker, S.

    2007-11-01

    Following the CD0 approval of the National Synchrotron Light Source II (NSLS-II) during August 2005, Brookhaven National Laboratory prepared a conceptual design for a worldclass user facility for scientific research using synchrotron radiation. DOE SC review of the preliminary baseline in December 2006 led to the subsequent CD1 approval (approval of alternative selection and cost range). This report is the documentation of the preliminary design work for the NSLS-II facility. The preliminary design of the Accelerator Systems (Part 1) was developed mostly based of the Conceptual Design Report, except for the Booster design, which was changed from in-storage-ring tunnel configuration to in external- tunnel configuration. The design of beamlines (Part 2) is based on designs developed by engineering firms in accordance with the specification provided by the Project. The conventional facility design (Part 3) is the Title 1 preliminary design by the AE firm that met the NSLS-II requirements. Last and very important, Part 4 documents the ES&H design and considerations related to this preliminary design. The NSLS-II performance goals are motivated by the recognition that major advances in many important technology problems will require scientific breakthroughs in developing new materials with advanced properties. Achieving this will require the development of new tools that will enable the characterization of the atomic and electronic structure, chemical composition, and magnetic properties of materials, at nanoscale resolution. These tools must be nondestructive, to image and characterize buried structures and interfaces, and they must operate in a wide range of temperatures and harsh environments. The NSLS-II facility will provide ultra high brightness and flux and exceptional beam stability. It will also provide advanced insertion devices, optics, detectors, and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility

  17. The MORPHEUS II protein crystallization screen

    SciTech Connect (OSTI)

    Gorrec, Fabrice

    2015-06-27

    MORPHEUS II is a 96-condition initial crystallization screen formulated de novo. The screen incorporates reagents selected from the Protein Data Bank to yield crystals that are not observed in traditional conditions. In addition, the formulation facilitates the optimization and cryoprotection of crystals. High-quality macromolecular crystals are a prerequisite for the process of protein structure determination by X-ray diffraction. Unfortunately, the relative yield of diffraction-quality crystals from crystallization experiments is often very low. In this context, innovative crystallization screen formulations are continuously being developed. In the past, MORPHEUS, a screen in which each condition integrates a mix of additives selected from the Protein Data Bank, a cryoprotectant and a buffer system, was developed. Here, MORPHEUS II, a follow-up to the original 96-condition initial screen, is described. Reagents were selected to yield crystals when none might be observed in traditional initial screens. Besides, the screen includes heavy atoms for experimental phasing and small polyols to ensure the cryoprotection of crystals. The suitability of the resulting novel conditions is shown by the crystallization of a broad variety of protein samples and their efficiency is compared with commercially available conditions.

  18. Landfill aeration worldwide: Concepts, indications and findings

    SciTech Connect (OSTI)

    Ritzkowski, M.; Stegmann, R.

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Different landfill aeration concepts and accordant application areas are described. Black-Right-Pointing-Pointer Examples of full scale projects are provided for Europe, North-America and Asia. Black-Right-Pointing-Pointer Major project findings are summarised, including prospects and limitations. Black-Right-Pointing-Pointer Inconsistencies between laboratory and full scale results have been elaborated. Black-Right-Pointing-Pointer An explanatory approach in connection with the inconsistencies is provided. - Abstract: The creation of sustainable landfills is a fundamental goal in waste management worldwide. In this connection landfill aeration contributes towards an accelerated, controlled and sustainable conversion of conventional anaerobic landfills into a biological stabilized state associated with a minimised emission potential. The technology has been successfully applied to landfills in Europe, North America and Asia, following different strategies depending on the geographical region, the specific legislation and the available financial resources. Furthermore, methodologies for the incorporation of landfill aeration into the carbon trade mechanisms have been developed in recent years. This manuscript gives an overview on existing concepts for landfill aeration; their application ranges and specifications. For all of the described concepts examples from different countries worldwide are provided, including details regarding their potentials and limitations. Some of the most important findings from these aeration projects are summarised and future research needs have been identified. It becomes apparent that there is a great demand for a systematisation of the available results and implications in order to further develop and optimise this very promising technology. The IWWG (International Waste Working Group) Task Group 'Landfill Aeration' contributes towards the achievement of this goal.

  19. Annex II Technical Specifications Feeders and TF Coil Structures...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... of the Chinese Academy of Sciences (ASIPP) is responsible for the Feeder System in China. ... and partly in China at the Chinese Domestic Agency (CNDA) and its sub-contractors. ...

  20. Tech Area II: A history

    SciTech Connect (OSTI)

    Ullrich, R.

    1998-07-01

    This report documents the history of the major buildings in Sandia National Laboratories` Technical Area II. It was prepared in support of the Department of Energy`s compliance with Section 106 of the National Historic Preservation Act. Technical Area II was designed and constructed in 1948 specifically for the final assembly of the non-nuclear components of nuclear weapons, and was the primary site conducting such assembly until 1952. Both the architecture and location of the oldest buildings in the area reflect their original purpose. Assembly activities continued in Area II from 1952 to 1957, but the major responsibility for this work shifted to other sites in the Atomic Energy Commission`s integrated contractor complex. Gradually, additional buildings were constructed and the original buildings were modified. After 1960, the Area`s primary purpose was the research and testing of high-explosive components for nuclear weapons. In 1994, Sandia constructed new facilities for work on high-explosive components outside of the original Area II diamond-shaped parcel. Most of the buildings in the area are vacant and Sandia has no plans to use them. They are proposed for decontamination and demolition as funding becomes available.

  1. NSLS-II RF SYSTEMS

    SciTech Connect (OSTI)

    Rose, J.; Gash, W.; Holub, B.; Kawashima, Y.; Ma, H.; Towne, N.; Yeddulla, M.

    2011-03-28

    The NSLS-II is a new third generation light source being constructed at Brookhaven Lab. The storage ring is optimized for low emittance by use of damping wigglers to reduce the emittance to below 1 nm-rad. The RF systems are designed to provide stable beam through tight RF phase and amplitude stability requirements.

  2. Finding new perovskite halides via machine learning

    DOE PAGES-Beta [OSTI]

    Pilania, Ghanshyam; Balachandran, Prasanna V.; Kim, Chiho; Lookman, Turab

    2016-04-26

    Advanced materials with improved properties have the potential to fuel future technological advancements. However, identification and discovery of these optimal materials for a specific application is a non-trivial task, because of the vastness of the chemical search space with enormous compositional and configurational degrees of freedom. Materials informatics provides an efficient approach toward rational design of new materials, via learning from known data to make decisions on new and previously unexplored compounds in an accelerated manner. Here, we demonstrate the power and utility of such statistical learning (or machine learning, henceforth referred to as ML) via building a support vectormore » machine (SVM) based classifier that uses elemental features (or descriptors) to predict the formability of a given ABX3 halide composition (where A and B represent monovalent and divalent cations, respectively, and X is F, Cl, Br, or I anion) in the perovskite crystal structure. The classification model is built by learning from a dataset of 185 experimentally known ABX3 compounds. After exploring a wide range of features, we identify ionic radii, tolerance factor, and octahedral factor to be the most important factors for the classification, suggesting that steric and geometric packing effects govern the stability of these halides. As a result, the trained and validated models then predict, with a high degree of confidence, several novel ABX3 compositions with perovskite crystal structure.« less

  3. UDAC 2014 Findings and Recommendations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2014 Findings and Recommendations UDAC 2014 Findings and Recommendations UDAC 2014 Findings and Recommendations (162.67 KB) More Documents & Publications Minutes from December 16, 2013 UDAC Meeting UDAC 2014 Report UDAC Findings and Recommendations 2014

  4. UDAC Findings and Recommendations 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Findings and Recommendations 2014 UDAC Findings and Recommendations 2014 UDAC Findings and Recommendations 2014 (228.2 KB) More Documents & Publications Minutes from December 16, 2013 UDAC Meeting UDAC 2014 Report UDAC 2014 Findings and Recommendations

  5. GASPAR II: Technical reference and user guide

    SciTech Connect (OSTI)

    Strenge, D.L.; Bander, T.J.; Soldat, J.K.

    1987-03-01

    This report describes the computer program GASPAR II used by the staff of the US Nuclear Regulatory Commission to perform environmental dose analyses for releases of radioactive effluents from nuclear power plants into the atmosphere. The analyses estimate radiation dose to individuals and population groups from inhalation, ingestion (terrestrial foods), and external-exposure (ground and plume) pathways. The calculated doses provide information for National Environmental Policy Act (NEPA) evaluations and for determining compliance with Appendix I of 10 CFR 50 (the ''ALARA'' philosophy). The report also instructs the user in preparing input to the program, describes the mathematical models that are used, and supplies detailed information on program structure and parameters used to modify the program. 20 refs., 11 figs., 77 tabs.

  6. HPC Colony II: FAST_OS II: Operating Systems and Runtime Systems...

    Office of Scientific and Technical Information (OSTI)

    Title: HPC Colony II: FASTOS II: Operating Systems and Runtime Systems at Extreme Scale ... task made difficult by the emerging variety of more complex computer architectures. ...

  7. Sloan Digital Sky Survey II (SDSS-II) Supernova Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Sloan Digital Sky Survey (SDSS) is a series of three interlocking imaging and spectroscopic surveys, carried out over an eight-year period with a dedicated 2.5m telescope located at Apache Point Observatory in Southern New Mexico. The SDSS Supernova Survey was one of those three components of SDSS and SDSS-II, a 3-year extension of the original SDSS that operated from July 2005 to July 2008. The Supernova Survey was a time-domain survey, involving repeat imaging of the same region of sky every other night, weather permitting. The primary scientific motivation was to detect and measure light curves for several hundred supernovae through repeat scans of the SDSS Southern equatorial stripe 82 (about 2.5? wide by ~120? long). Over the course of three 3-month campaigns SDSS-II SN discovered and measured multi-band lightcurves for ~500 spectroscopically confirmed Type Ia supernovae in the redshift range z=0.05-0.4. In addition, the project harvested a few hundred light curves for SNe Ia and discovered about 80 spectroscopically confirmed core-collapse supernovae (supernova types Ib/c and II).

  8. Russian research capabilities: Findings of site visits

    SciTech Connect (OSTI)

    Wester, D.W.

    1994-02-01

    In June 1993, a proposal was presented to the International Environmental Institute (IEI) in Kennewick, Washington, to establish cooperation and coordination to further pursue the interests of the United States of America and the Republic of Russia in the application and promotion of environmental technology; characterization, treatment, handling, isolation, and disposal of hazardous and radioactive materials; conversion of defense sites to other purposes; and technology transfer, cooperative programs, joint technology development and contractual research. In response to this proposal, IEI and Pacific Northwest Laboratory (PNL) jointly provided funding to send Dr. Dennis W. Wester on a fact-finding mission to Novosibirsk, Moscow, and St. Petersburg, Russia. The trip covered a period of eight weeks, six of which were spent in Novosibirsk and adjoining or related cities and one of which was spent in each of Moscow and St. Petersburg. The general objectives of the trip were to establish a basis for cooperation between IEI and the Russian Academy of Sciences (RAS) for future coordination of mutual interests and objectives such as technology acquisition, development, demonstration, application, and commercialization; use of capabilities and assets developed by the U.S. Department of Energy (DOE) and the RAS; and expediting of cooperative agreements, personnel exchanges, joint ventures and other contractual relationships. The particular objectives of this trip were to evaluate the capabilities of the RAS to satisfy the technology needs associated with the cleanup of the Hanford Site and similar sites in the U.S. and to evaluate the expediency of establishing an IEI presence in Russia.

  9. Offshore Code Comparison Collaboration, Continuation: Phase II Results of a Floating Semisubmersible Wind System: Preprint

    SciTech Connect (OSTI)

    Robertson, A.; Jonkman, J.; Musial, W.; Vorpahl, F.; Popko, W.

    2013-11-01

    Offshore wind turbines are designed and analyzed using comprehensive simulation tools that account for the coupled dynamics of the wind inflow, aerodynamics, elasticity, and controls of the turbine, along with the incident waves, sea current, hydrodynamics, and foundation dynamics of the support structure. The Offshore Code Comparison Collaboration (OC3), which operated under the International Energy Agency (IEA) Wind Task 23, was established to verify the accuracy of these simulation tools [1]. This work was then extended under the Offshore Code Comparison Collaboration, Continuation (OC4) project under IEA Wind Task 30 [2]. Both of these projects sought to verify the accuracy of offshore wind turbine dynamics simulation tools (or codes) through code-to-code comparison of simulated responses of various offshore structures. This paper describes the latest findings from Phase II of the OC4 project, which involved the analysis of a 5-MW turbine supported by a floating semisubmersible. Twenty-two different organizations from 11 different countries submitted results using 24 different simulation tools. The variety of organizations contributing to the project brought together expertise from both the offshore structure and wind energy communities. Twenty-one different load cases were examined, encompassing varying levels of model complexity and a variety of metocean conditions. Differences in the results demonstrate the importance and accuracy of the various modeling approaches used. Significant findings include the importance of mooring dynamics to the mooring loads, the role nonlinear hydrodynamic terms play in calculating drift forces for the platform motions, and the difference between global (at the platform level) and local (at the member level) modeling of viscous drag. The results from this project will help guide development and improvement efforts for these tools to ensure that they are providing the accurate information needed to support the design and

  10. FIRST HIGH-RESOLUTION IMAGES OF THE SUN IN THE 2796 Mg II k LINE

    SciTech Connect (OSTI)

    Riethmller, T. L.; Solanki, S. K.; Hirzberger, J.; Danilovic, S.; Barthol, P.; Gandorfer, A.; Gizon, L.; Berkefeld, T.; Schmidt, W.; Knlker, M.; Del Toro Iniesta, J. C.

    2013-10-10

    We present the first high-resolution solar images in the Mg II k 2796 line. The images, taken through a 4.8 broad interference filter, were obtained during the second science flight of Sunrise in 2013 June by the Sunrise Filter Imager (SuFI) instrument. The Mg II k images display structures that look qualitatively very similar to images taken in the core of Ca II H. The Mg II images exhibit reversed granulation (or shock waves) in the internetwork regions of the quiet Sun, at intensity contrasts that are similar to those found in Ca II H. Very prominent in Mg II are bright points, both in the quiet Sun and in plage regions, particularly near the disk center. These are much brighter than at other wavelengths sampled at similar resolution. Furthermore, Mg II k images also show fibril structures associated with plage regions. Again, the fibrils are similar to those seen in Ca II H images, but tend to be more pronounced, particularly in weak plage.

  11. Destilaria Joao Paulo II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Joao Paulo II Jump to: navigation, search Name: Destilaria Joao Paulo II Place: Sao Simao, Sao Paulo, Brazil Zip: 14200-000 Product: Brazil based ethanol producer located in Sao...

  12. Swift Progress on NSLS-II Booster

    ScienceCinema (OSTI)

    None

    2013-07-17

    Get an inside look around the booster ring at the National Synchrotron Light Source II. The booster is part of the injector complex for NSLS-II, now under construction at Brookhaven Lab.

  13. ALTERNATES I AND II.PDF

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ALTERNATES I AND II TO RIGHTS IN DATA - GENERAL AND RIGHTS IN DATA - PROGRAMS COVERED UNDER SPECIAL DATA STATUES As prescribed in 600.325(d)(1), the following Alternate I andor II ...

  14. GRED III Phase II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    2010 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for GRED III Phase II Citation Bernie Karl. 2010. GRED III Phase II. p....

  15. II

    Annual Energy Outlook

    describes the concen- 1) because control devices, such as baghouse filters and tration of hydrogen ions along a scale (from 0 to 14) that electrostatic precipitators, remove most...

  16. II*

    Gasoline and Diesel Fuel Update

    alone. That number represents the net inflow of foreign oil as a percentage of total oil consumption. By this measure, U.S. Trends dependence has never reached 50.0 percent on...

  17. II

    Office of Legacy Management (LM)

    Jersey is currently owned by the United States Department of Energy (DOE). It was used from 1943 to 1967 as a sampling and storage facility for uranium and thorium concentrates. ...

  18. II

    Office of Legacy Management (LM)

    Granite City Steel Division, Granite City, Illinois . . . . . . . . . . . . . . . ' . . . . . . . . . . 7 3 Diagram of the New Betatron Building, Granite City Steel facility, ...

  19. ALCC Allocation Final Report: HPC Colony II

    SciTech Connect (OSTI)

    Jones, Terry R

    2013-11-01

    The report describes those activities of the HPC Colony II Project as they relate to their FY2013 ALCC Award.

  20. Copper (II) chloride-tetrachloroaluminate battery

    SciTech Connect (OSTI)

    Erbacher, J.K.; Hussey, C.L.; King, L.A.

    1980-06-10

    A pelletized, light weight, thermal battery having copper (II) chloride and an alkali tetrachloroaluminate as electrolytic components is disclosed.

  1. Nanotechnology finding its way into flame retardancy

    SciTech Connect (OSTI)

    Schartel, Bernhard

    2014-05-15

    Nanotechnology is one of the key technologies of the 21{sup st} century. The exploitation of 'new' effects that arise from materials structured on the nano-scale has also been proposed successfully for flame retardancy of polymers since the end of the 90s. Of all of the approaches these include, at this time the use of nanocomposites offers the best potential for industrial application, also some other ideas are sketched, such as using electrospun nanofibers mats or layer-by-layer deposits as protection coatings, as well as sub-micrometer multilayer coatings as effective IR-mirrors. The general phenomena, inducing a flow limit in the pyrolysing melt and changing the fire residue, are identified in nanocomposites. Key experiments are performed such as quasi online investigation of the protection layer formation to understand what is going on in detail. The flame retardancy mechanisms are discussed and their impact on fire behaviour quantified. With the latter, the presentation pushes forward the state of the art. For instance, the heat shielding is experimentally quantified for a layered silicate epoxy resin nanocomposite proving that it is the only import mechanism controlling the reduction in peak heat release rate in the investigated system for different irradiations. The flame retardancy performance is assessed comprehensively illuminating not only the strengths but also the weak points of the concepts. Guidelines for materials development are deduced and discussed. Apart from inorganic fillers (layered silicate, boehmite, etc.) not only carbon nanoobjects such as multiwall carbon nanotubes, multilayer graphene and graphene are investigated, but also nanoparticles that are more reactive and harbor the potential for more beneficial interactions with the polymer matrix.

  2. Latest findings from the OECD Rasplav Project

    SciTech Connect (OSTI)

    Asmolov, V.

    1997-01-01

    During the late phase of a severe accident in a light water reactor (current and future designs of BWRs, PWRs and VVERs), a significant amount of core material may relocate downward to the lower head of the reactor vessel. If molten core materials were to relocate to the lower head of the reactor pressure vessel (RPV), a molten pool consisting primarily of a mixture of ZrO{sub 2} and UO{sub 2} and some combination of a metal would form on the lower head. A solid crust of material would form around the boundaries of the pool, but internal heat generation resulting from radioactive decay of fission products would assure that most of the pool remains molten. In fact, the molten pool would undergo significant internal natural convection which would reach steady state conditions in about a few hours. Detailed understanding of all aspects of this natural convection process, in conjunction with the thermal boundary conditions imposed on the outer surface, determines the fraction of the total heat dissipation that is transferred through the upper crust to the inside of the reactor vessel by radiative heat exchange and the fraction which must be conducted through the wall of the reactor vessel lower head. This distribution is critical in determining whether and under what conditions the molten material can be cooled and retained in the reactor pressure vessel. The OECD Rasplav Project was established in 1994 as a three year program to study molten pool behavior and its interactions with structural materials in the lower head. This paper reviews the establishment of the project, its initial studies and proposed experimental testing, and the construction, preparation, and actual testing of a chamber of corium heated to well above liquid temperature.

  3. Windland (Boxcar II) Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Windland (Boxcar II) Wind Farm Jump to: navigation, search Name Windland (Boxcar II) Wind Farm Facility Windland (Boxcar II) Sector Wind energy Facility Type Commercial Scale Wind...

  4. Kotzebue Wind Project Phase II & III | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II & III Jump to: navigation, search Name Kotzebue Wind Project Phase II & III Facility Kotzebue Wind Project Phase II & III Sector Wind energy Facility Type Commercial Scale Wind...

  5. Champion (Roscoe II) Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Champion (Roscoe II) Wind Farm Jump to: navigation, search Name Champion (Roscoe II) Wind Farm Facility Champion (Roscoe II) Sector Wind energy Facility Type Commercial Scale Wind...

  6. University of Minnesota Morris II - PES | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Morris II - PES Jump to: navigation, search Name University of Minnesota Morris II - PES Facility University of Minnesota Morris II - PES Sector Wind energy Facility Type Community...

  7. Mountain View Power Partners II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Mountain View Power Partners II Wind Farm Facility Mountain View Power Partners II Sector Wind energy Facility Type Commercial Scale...

  8. Langdon II - FPL Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Langdon II - FPL Wind Farm Jump to: navigation, search Name Langdon II - FPL Wind Farm Facility Langdon II - FPL Sector Wind energy Facility Type Commercial Scale Wind Facility...

  9. Karen Avenue Wind Farm II (San Gorgonio Farms) | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Farm II (San Gorgonio Farms) Jump to: navigation, search Name Karen Avenue Wind Farm II (San Gorgonio Farms) Facility Karen Avenue Windfarm II (San Gorgonio Farms) Sector Wind...

  10. Buffalo Ridge II Wind Power Project | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Power Project Jump to: navigation, search Name Buffalo Ridge II Wind Power Project Facility Buffalo Ridge II Wind Power Project Sector Wind energy Facility Type Commercial...

  11. Milford Wind Corridor Phase II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Jump to: navigation, search Name Milford Wind Corridor Phase II Facility Milford Wind Corridor Phase II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  12. AE Biofuels Inc formerly Marwich II Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Marwich II Ltd Jump to: navigation, search Name: AE Biofuels Inc. (formerly Marwich II Ltd.) Place: West Palm Beach, Florida Zip: 33414 Sector: Biofuels Product: Marwich II, Ltd....

  13. Condon Wind Project phase II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Project phase II Jump to: navigation, search Name Condon Wind Project phase II Facility Condon Wind Project phase II Sector Wind energy Facility Type Commercial Scale Wind Facility...

  14. EA-1922: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1922: Finding of No Significant Impact Combined Power and Biomass Heating System, Fort Yukon, Alaska Based on the EA, DOE finds that providng ...

  15. LCLS-II New Instruments Workshops Report

    SciTech Connect (OSTI)

    Baradaran, Samira; Bergmann, Uwe; Durr, Herrmann; Gaffney, Kelley; Goldstein, Julia; Guehr, Markus; Hastings, Jerome; Heimann, Philip; Lee, Richard; Seibert, Marvin; Stohr, Joachim; /SLAC

    2012-08-08

    The LCLS-II New Instruments workshops chaired by Phil Heimann and Jerry Hastings were held on March 19-22, 2012 at the SLAC National Accelerator Laboratory. The goal of the workshops was to identify the most exciting science and corresponding parameters which will help define the LCLS-II instrumentation. This report gives a synopsis of the proposed investigations and an account of the workshop. Scientists from around the world have provided short descriptions of the scientific opportunities they envision at LCLS-II. The workshops focused on four broadly defined science areas: biology, materials sciences, chemistry and atomic, molecular and optical physics (AMO). Below we summarize the identified science opportunities in the four areas. The frontiers of structural biology lie in solving the structures of large macromolecular biological systems. Most large protein assemblies are inherently difficult to crystallize due to their numerous degrees of freedom. Serial femtosecond protein nanocrystallography, using the 'diffraction-before-destruction' approach to outrun radiation damage has been very successfully pioneered at LCLS and diffraction patterns were obtained from some of the smallest protein crystals ever. The combination of femtosecond x-ray pulses of high intensity and nanosized protein crystals avoids the radiation damage encountered by conventional x-ray crystallography with focused beams and opens the door for atomic structure determinations of the previously largely inaccessible class of membrane proteins that are notoriously difficult to crystallize. The obtained structures will allow the identification of key protein functions and help in understanding the origin and control of diseases. Three dimensional coherent x-ray imaging at somewhat lower resolution may be used for larger objects such as viruses. The chemistry research areas of primary focus are the predictive understanding of catalytic mechanisms, with particular emphasis on photo- and

  16. EBR-II Superheater Duplex Tube Examination

    SciTech Connect (OSTI)

    Daniel M. Wachs; Dennis D. Keiser; Douglas L. Porter; Naoyuki Kisohara

    2008-12-01

    After 30 years of operation, the Experimental Breeder Reactor II (EBR-II) Superheater 710 at Argonne National Laboratory-West (now Idaho National Laboratory) was decommissioned. As part of its post-service examination, four duplex tube sections were removed and Charpy impact testing was performed to characterize the crack arresting ability of nickel-bonded tube interfaces. Scanning electron microscopy (SEM) examination was also performed to characterize and identify changes in bond material microstructure. From room temperature to 400 degrees C, all samples demonstrated ductility and crack-stopping ability similar to that exhibited by beginning-of-life samples. However, at low temperature (-5 degrees C), samples removed from the lower region of the superheater (near the sodium inlet) failed while those from the upper region (near the sodium outlet) did not. SEM analysis revealed that all the tube-tube interfaces showed evidence of iron diffusion into the nickel braze, which resulted in the formation of a multiphase diffusion structure. Yet, significant void formation was only observed in the bond layer of the tubes removed from the lower region. This may be due to a change in the crystal microstructure of one of the phases within the bond layer that occurs in the 350 to 450 degrees C temperature range, which results in a lower density and the formation of porosity. Apparently, only the samples from the higher temperature region were exposed to this transition temperature, and the resulting large voids that developed acted as stress concentrators that led to low-temperature embrittlement and failure of the Charpy impact specimens.

  17. EA-1832: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    32: Finding of No Significant Impact EA-1832: Finding of No Significant Impact Rainer Biogas LLC Community Anaerobic Manure Digester, Enumclaw, King County, Washington The U.S....

  18. EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Find More Like This Return to Search EMGeo: Risk Minimizing Software for Finding Offshore ... developed advanced software for discovering and mapping offshore fossil fuel deposits. ...

  19. EA-1378: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    378: Finding of No Significant Impact EA-1378: Finding of No Significant Impact Site-Wide Environmental Assessment of National Renewable Energy Laboratory's National Wind ...

  20. EA-1938: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1938: Finding of No Significant Impact Grieve Unit CO2 Enhanced Recovery Project, Natrona County, WY Western has reviewed BLM's EA "Grieve...

  1. EA-1605: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    Finding of No Significant Impact EA-1605: Finding of No Significant Impact Biomass Cogeneration and Heating Facilities at the Savannah River Site, South Carolina The Department of...

  2. EA-1784: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4: Finding of No Significant Impact EA-1784: Finding of No Significant Impact Fotowatio Nevada Solar, LLC's APEX Solar Power Project in Clark County, Nevada The Department of...

  3. EA-1862: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1862: Finding of No Significant Impact Oneida Seven Generations Corporation: Energy Recovery Project, Green Bay, Wisconsin The U.S. Department...

  4. Innovative Financing Solutions: Finding Money for Your Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Innovative Financing Solutions: Finding Money for Your Energy Efficiency Projects Innovative Financing Solutions: Finding Money for Your Energy Efficiency Projects Provides an ...

  5. EA-1785: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Finding of No Significant Impact EA-1785: Finding of No Significant Impact Phase III Anthropogenic Test Characterization Project, Mobile County, Alabama Based on the analyses in...

  6. EA-1853: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of No Significant Impact EA-1853: Finding of No Significant Impact Perrin Ranch Wind Energy Interconnection Project, Coconino County, Arizona Based on findings and analysis in...

  7. EA-1923: Mitigated Finding of No Significant Impact | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mitigated Finding of No Significant Impact EA-1923: Mitigated Finding of No Significant Impact Green Energy School Wind Turbine Project on Saipan, Commonwealth of the Northern ...

  8. Jefferson Lab finds its man Mont (Inside Business) | Jefferson...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    https:www.jlab.orgnewsarticlesjefferson-lab-finds-its-man-mont-inside-business Jefferson Lab finds its man Mont Hugh Montgomery Hugh Montgomery, a British nuclear physicist...

  9. EA-1802: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2: Finding of No Significant Impact EA-1802: Finding of No Significant Impact Chicago View Wind Project Chicago Heights, Cook County, Illinois The Department of Energy's Proposed...

  10. Community Wind Handbook/Find an Installer | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    * Submit Permit Applications * Find an Installer * Purchase Equipment * Plan for Maintenance Find an Installer Homeowners, ranchers, and small businesses can install wind...

  11. EIS-0372: Record of Decision and Floodplain Statement of Findings...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Record of Decision and Floodplain Statement of Findings EIS-0372: Record of Decision and Floodplain Statement of Findings Bangor Hydro-Electric Company Northeast Reliability...

  12. EIS-0456: Record of Decision and Floodplain Statement of Findings...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Record of Decision and Floodplain Statement of Findings EIS-0456: Record of Decision and Floodplain Statement of Findings Cushman Hydroelectric Project, Mason County, Washington...

  13. EA-1698: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8: Finding of No Significant Impact EA-1698: Finding of No Significant Impact Baldwin Wind Energy Center Project Baldwin Wind, LLC has requested to interconnect their proposed new...

  14. EA-1807: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1807: Finding of No Significant Impact Heartland Community College Wind Energy Project, Normal, McLean County, Illinois The Department of...

  15. EA-1819: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1819: Finding of No Significant Impact Kilowatts for Kenston Wind Energy Project, Chagrin Falls, Geauga County, Ohio The Department of Energy's...

  16. EA-1829: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Final Environmental Assessment and Finding of No Significant Impact EA-1829: Final Environmental Assessment and Finding of No Significant Impact Phycal Algae Pilot Project, Wahiawa...

  17. EA-1866: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    6: Final Environmental Assessment and Finding of No Significant Impact EA-1866: Final Environmental Assessment and Finding of No Significant Impact Argonne National Laboratory...

  18. EA-1889: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Final Environmental Assessment and Finding of No Significant Impact EA-1889: Final Environmental Assessment and Finding of No Significant Impact Disposal of Decommissioned,...

  19. EA-1869: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    69: Final Environmental Assessment and Finding of No Significant Impact EA-1869: Final Environmental Assessment and Finding of No Significant Impact General Motors LLC, Electric...

  20. EA-1769: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    9: Final Environmental Assessment and Finding of No Significant Impact EA-1769: Final Environmental Assessment and Finding of No Significant Impact Houston Advanced Research...

  1. EA-1947: Draft Revised Finding of No Significant Impact | Department...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1947: Draft Revised Finding of No Significant Impact EA-1947: Draft Revised Finding of No Significant Impact Transfer of the Kansas City Plant, Kansas City, Missouri The National ...

  2. EA-1733: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1733: Finding of No Significant Impact Calpine Enhanced Geothermal Systems Project, Sonoma County, California DOE determined that providing...

  3. EA-1839: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    39: Final Environmental Assessment and Finding of No Significant Impact EA-1839: Final Environmental Assessment and Finding of No Significant Impact Department of Energy Loan ...

  4. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact Silver Peak Area Geothermal Exploration Project, Esmeralda County, NV December 7, 2012 EA-1863: Finding of No Significant Impact Vegetation...

  5. EA-1984: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1984: Finding of No Significant Impact Disposition of Five Signature Properties at Idaho National Laboratory DOE has decided to implement the...

  6. EA-1975: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    useful life the proposed LCLS-II project does not constitute a major federal action that would significantly affect the quality of the human environment within the meaning of the ...

  7. EA-1840: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    Loan Guarantee to High Plains II, LLC for the California Valley Solar Ranch Project in San Luis Obispo County and Kern County, California California Valley Solar Ranch Project in ...

  8. SECTION II. HEAVY ION REACTIONS

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    II. HEAVY ION REACTIONS Dynamic Evolution and the Caloric Curve for Medium Mass Nuclei J. Cibor, R. Wada, K. Hagel, M. Lunardon, N. Marie, R. Alfaro, W. Shen, B. Xiao, Y. Zhao, J. Li, M. Murray, J.B. Natowitz, Z. Majka and P. Staszel Search for 5He Emission from Hot Compound Nuclei R. Charity and L.G. Sobotka for the Washington University, NSCL, Legnaro, Padova, TAMU Collaboration IMF Production in 64Zn + 58Ni at 35A-79A MeV R. Wada, K. Hagel, J. Cibor, J. Li, M. Murray, J.B. Natowitz, A. Ono

  9. Commissioning of NSLS-II

    SciTech Connect (OSTI)

    Willeke, F.

    2015-05-03

    NSLS-II, the new 3rd generation light source at BNL was designed for a brightness of 1022 photons s-1mm-2mrad-2 (0.1%BW)-1. It was constructed between 2009 and 2014. The storage ring was commissioned in April 2014 which was followed by insertion device and beamline commissioning in the fall of 2014. All ambitious design parameters of the facility have already been achieved except for commissioning the full beam intensity of 500mA which requires more RF installation. This paper reports on the results of commissioning.

  10. Mercury(II) nitroprusside: A framework with an unusual topology

    SciTech Connect (OSTI)

    Cano, A.; Osiry, H.; Reguera, L.; Lemus-Santana, A.A.; Reguera, E.

    2015-05-15

    The titled compound was prepared by the precipitation method from diluted aqueous solution of sodium nitroprusside and mercury(II) nitrate. The orange solid formed, with formula unit Hg[Fe(CN){sub 5}NO], crystallizes with an orthorhombic unit cell in the Pmna space group with cell parameters: a=11.2788(3), b=6.1965(3), and c=12.3786(6) Å. The unit cell accommodates four formula of the compound (Z=4). Its crystal structure was solved from X-ray powder patterns and then refined by the Rietveld method. The material framework is formed by tetrahedral coordination of Hg atoms at the N end of the equatorial CN groups of the [Fe(CN){sub 5}NO] building block. That framework results from the interpenetration of two identical sub-frameworks with a relative shift of (a/2, b/2, c/2). The sub-framework has two types of cavities, ellipsoidal and rhombohedral, with transversal section of ca. 4.5×9.2 Å and ca. 8.5 Å transversal section, respectively. That system of cavities results eclipsed by the relative shift of neighboring sub-frameworks. No transport of H{sub 2} and N{sub 2} molecules through the material framework was observed. The thermal decomposition also reveals limitation for the decomposition products diffusion through the practically compact structure. The structural study was complemented with TG, IR, UV–vis and N{sub 2} and H{sub 2} adsorption data. Neighboring Hg atoms are distant 4.54(3) Å, a relatively large distance to suppose the existence of metal–metal interaction. No previous study on the crystal structure and related properties of mercury(II) nitroprusside has been reported. - Graphical abstract: Mercury(II) nitroprusside framework formed by two identical interpenetrated porous subframeworks where neighboring cavities appear eclipsed. - Highlights: • Interpenetrated frameworks in metal nitroprusside. • Eclipsed porous framework in metal nitroprusside. • Structure and related properties for mercury(II) nitroprusside. • Spectral features for

  11. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Liu, Haitao

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This method is first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  12. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Liu, Haitao

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This methodis first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  13. Controlled Co(II) Doping of Zinc Oxide Nanocrystals

    SciTech Connect (OSTI)

    S Bohle; C Spina

    2011-12-31

    Dopants are non-native atoms commonly used to modify the properties of bulk semiconductors. In this paper we demonstrate that by controlling the addition of cobalt(II) to growing zinc oxide nanocrystals (ZnO NCs) it is possible to modulate the resulting properties. We show that the environment of cobalt may be controlled by varying the synthetic conditions, mainly through varying the time of dopant-precursor addition and concentration. These conditions prove critical to the resulting Co(II) configuration, which affects both the luminescent and photocatalytic properties of the ZnO NCs. Presynthetic doping with 2% Co(II) results in a 98% quenching of the visible emission of ZnO, whereas the same quantity doped post synthesis results in only a 60% quenching. The environment of cobalt in the ZnO wurtzite lattice is identified through UV-vis spectroscopy. The wurtzite structure of the ZnO lattice for all nanocrystalline species is confirmed through X-ray diffraction patterns obtained from a synchrotron radiation source. Postsynthetically doped Co(II) in ZnO NC is demonstrated to have potential applications as an 'on-off' sensor, as exemplified with nitric oxide.

  14. Synthesis and crystal and molecular structure of three heterometallic polymeric compounds (Ln{sub 2}[LnGe{sub 6}(μ-Oedph){sub 6}(μ-O){sub 3}(μ-OH){sub 3}(H{sub 2}O){sub 4}] · xH{sub 2}O){sub n} [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H{sub 4}Oedph = 1-hydroxyethylidenediphosphonic acid

    SciTech Connect (OSTI)

    Sergienko, V. S.; Martsinko, E. E.; Ilyukhin, A. B.; Seifullina, I. I.

    2015-03-15

    The synthesis and X-ray diffraction study of three heterometallic compounds of general formula (Ln{sub 2}[LnGe{sub 6}(μ-Oedph){sub 6}(μ-O){sub 3}(μ-OH){sub 3}(H{sub 2}O){sub 4}] · xH{sub 2}O){sub n} [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼20 (III); H{sub 4}Oedph = 1-hydroxyethylidenediphosphonic acid] are performed. The basis element of structures I–III is a hexanuclear complex anion [Ge(μ-Oedph)(μ-O){sub 0.5}(μ-OH){sub 0.5}]{sub 6}{sup 9−}, in which bridging hydroxo and oxo ligands are statistically disordered with equally probability. Hexameric units are connected by Ln1(H{sub 2}O){sub 4} fragments into a framework whose channels are completely populated by disordered lanthanide atoms and water molecules.

  15. BNL ATF II beamlines design

    SciTech Connect (OSTI)

    Fedurin, M.; Jing, Y.; Stratakis, D.; Swinson, C.

    2015-05-03

    The Brookhaven National Laboratory. Accelerator Test Facility (BNL ATF) is currently undergoing a major upgrade (ATF-II). Together with a new location and much improved facilities, the ATF will see an upgrade in its major capabilities: electron beam energy and quality and CO2 laser power. The electron beam energy will be increased in stages, first to 100-150 MeV followed by a further increase to 500 MeV. Combined with the planned increase in CO2 laser power (from 1-100 TW), the ATF-II will be a powerful tool for Advanced Accelerator research. A high-brightness electron beam, produced by a photocathode gun, will be accelerated and optionally delivered to multiple beamlines. Besides the energy range (up to a possible 500 MeV in the final stage) the electron beam can be tailored to each experiment with options such as: small transverse beam size (<10 um), short bunch length (<100 fsec) and, combined short and small bunch options. This report gives a detailed overview of the ATFII capabilities and beamlines configuration.

  16. Find your scientific document; then quickly find "more like this" at

    Office of Scientific and Technical Information (OSTI)

    Information Bridge | OSTI, US Dept of Energy Office of Scientific and Technical Information your scientific document; then quickly find "more like this" at Information Bridge Back to the OSTI News Listing for 2010 The "go to" site for Department of Energy full-text research documents has added a ''more like this" feature on the search results page. Now you can search for technical reports on your topics of interest and quickly locate related documents. The "more

  17. Floodplain Assessment and Statement of Findings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    and Statement of Findings Floodplain Assessment and Statement of Findings Floodplain Assessment and Statement of Findings for Installation of a Renewable Energy Anaerobic Digester Facility at the University of California, Davis in Yolo County, California. Statement of Findings (450.47 KB) More Documents & Publications Floodplain Assessment for Installation of a Renewable Energy Anaerobic Digester Facility

  18. ANALYSIS OF TWO SMALL MAGELLANIC CLOUD H II REGIONS CONSIDERING THERMAL INHOMOGENEITIES: IMPLICATIONS FOR THE DETERMINATIONS OF EXTRAGALACTIC CHEMICAL ABUNDANCES

    SciTech Connect (OSTI)

    Pena-Guerrero, Maria A.; Peimbert, Antonio; Peimbert, Manuel; Ruiz, Maria Teresa E-mail: antonio@astroscu.unam.mx E-mail: mtruiz@das.uchile.cl

    2012-02-20

    We present long-slit spectrophotometry considering the presence of thermal inhomogeneities (t{sup 2}) of two H II regions in the Small Magellanic Cloud (SMC): NGC 456 and NGC 460. Physical conditions and chemical abundances were determined for three positions in NGC 456 and one position in NGC 460, first under the assumption of uniform temperature and then allowing for the possibility of thermal inhomogeneities. We determined t{sup 2} values based on three different methods: (1) by comparing the temperature derived using oxygen forbidden lines with the temperature derived using helium recombination lines (RLs), (2) by comparing the abundances derived from oxygen forbidden lines with those derived from oxygen RLs, and (3) by comparing the abundances derived from ultraviolet carbon forbidden lines with those derived from optical carbon RLs. The first two methods averaged t{sup 2} = 0.067 {+-} 0.013 for NGC 456 and t{sup 2} = 0.036 {+-} 0.027 for NGC 460. These values of t{sup 2} imply that when gaseous abundances are determined with collisionally excited lines they are underestimated by a factor of nearly two. From these objects and others in the literature, we find that in order to account for thermal inhomogeneities and dust depletion, the O/H ratio in low-metallicity H II regions should be corrected by 0.25-0.45 dex depending on the thermal structure of the nebula or by 0.35 dex if such information is not available.

  19. PHYSICAL STRUCTURE AND NATURE OF SUPERNOVA REMNANTS IN M101

    SciTech Connect (OSTI)

    Franchetti, Nicholas A.; Gruendl, Robert A.; Chu, You-Hua; Dunne, Bryan C.; Pannuti, Thomas G.; Grimes, Caleb K.; Kuntz, Kip D.; Chen, C.-H. Rosie; Aldridge, Tabitha M. E-mail: gruendl@astro.illinois.edu E-mail: bdunne@astro.illinois.edu E-mail: ckgrim01@moreheadstate.edu E-mail: rchen@mpifr-bonn.mpg.de

    2012-04-15

    Supernova remnant (SNR) candidates in the giant spiral galaxy M101 have been previously identified from ground-based H{alpha} and [S II] images. We have used archival Hubble Space Telescope (HST) H{alpha} and broadband images as well as stellar photometry of 55 SNR candidates to examine their physical structure, interstellar environment, and underlying stellar population. We have also obtained high-dispersion echelle spectra to search for shocked high-velocity gas in 18 SNR candidates, and identified X-ray counterparts to SNR candidates using data from archival observations made by the Chandra X-Ray Observatory. Twenty-one of these 55 SNR candidates studied have X-ray counterparts, although one of them is a known ultraluminous X-ray source. The multi-wavelength information has been used to assess the nature of each SNR candidate. We find that within this limited sample, {approx}16% are likely remnants of Type Ia SNe and {approx}45% are remnants of core-collapse SNe. In addition, about {approx}36% are large candidates which we suggest are either superbubbles or OB/H II complexes. Existing radio observations are not sensitive enough to detect the non-thermal emission from these SNR candidates. Several radio sources are coincident with X-ray sources, but they are associated with either giant H II regions in M101 or background galaxies. The archival HST H{alpha} images do not cover the entire galaxy and thus prevents a complete study of M101. Furthermore, the lack of HST [S II] images precludes searches for small SNR candidates which could not be identified by ground-based observations. Such high-resolution images are needed in order to obtain a complete census of SNRs in M101 for a comprehensive investigation of the distribution, population, and rates of SNe in this galaxy.

  20. Part II - Managerial Competencies: Organizational Representation and

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Liaison | Department of Energy Part II - Managerial Competencies: Organizational Representation and Liaison Part II - Managerial Competencies: Organizational Representation and Liaison Form for the SES program emphasizes the range of communications and public relations aspects of executive positions as found in official correspondence and documentation, as well as, formal and informal verbal communications, and it describes the major competencies within this activity Part II - Managerial

  1. GRED III Phase II | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    III Phase II GRED III Phase II Engineered Geothermal Systems, Low Temp, Exploration Demonstration Projects. Project objectives: To gain a better understanding of the geothermal reservoir at Chena Hot Springs Resort in Alaska; Test and document the reliability of previous predictions as to the nature of the reservoir. egs_karl_gred_3_phase_2.pdf (601.26 KB) More Documents & Publications Fairbanks Geothermal Energy Project GRED Drilling Award … GRED III Phase II; 2010 Geothermal Technology

  2. Role of amyloids in type II diabetes

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    July » Role of amyloids in type II diabetes Role of amyloids in type II diabetes A collaboration between Los Alamos, Yale University, and Worcester Polytechnic Institute published research that sheds light on pathological properties of amyloids identified in type II diabetes. July 6, 2016 Schematic of human amyloid (blue) partially removing a lipid bilayer (model membrane) on a solid support. Schematic of human amyloid (blue) partially removing a lipid bilayer (model membrane) on a solid

  3. ExodusII Finite Element Data Model

    Energy Science and Technology Software Center (OSTI)

    2005-05-14

    EXODUS II is a model developed to store and retrieve data for finite element analyses. It is used for preprocessing (problem definition), postprocessing (results visualization), as well as code to code data transfer. An EXODUS II data file is a random access, machine independent, binary file that is written and read via C, C++, or Fortran library routines which comprise the Application Programming Interface. (exodus II is based on netcdf)

  4. Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes with a non-coplanar dicarboxylate

    SciTech Connect (OSTI)

    Xin, Ling-Yun; Liu, Guang-Zhen; Ma, Lu-Fang; Wang, Li-Ya

    2013-10-15

    A non-coplanar dicarboxylate ndca (H{sub 2}ndca=5-norbornene-2,3-dicarboxylic acid), combining with various dipyridyl-typed tectons, constructs six Cd(II)/Co(II) coordination polymers under hydrothermal conditions, namely [Co(ndca)(H{sub 2}O)]{sub n} (1), ([Co(ndca)(bpe)(H{sub 2}O)]·H{sub 2}O){sub n} (2), [Co(ndca)(bpa){sub 0.5}(H{sub 2}O)]{sub n} (3), [Cd(ndca)(bpe)(H{sub 2}O)]{sub n} (4), ([Cd(ndca)(bpa)(H{sub 2}O)]·0.5H{sub 2}O){sub n} (5), and ([Cd(ndca)(bpp) (H{sub 2}O)]·H{sub 2}O){sub n} (6) (bpe=1,2-di(4-pyridyl)ethylene, bpa=1,2-bi(4-pyridyl)ethane, and bpp=1,3-bis(4-pyridyl)propane). All these compounds contain various metal(II)–carboxylate motifs, including carboxylate binuclear (2, 4, 5), carboxylate chain (1, 6) and carboxylate layer (3), which are further extended by dipyridyl-typed coligands to afford a vast diversity of the structures with 2D pyknotic layers (1, 6), 2D open layer (5), 2D→3D interpenetrated networks (2,4), and 3D pillared-layer framework (3), respectively. In addition, fluorescent spectra of Cd(II) complexes and magnetic properties of Co(II) complexes are also given. - Graphical abstract: Six various cadmium(II)/cobalt(II)–organic frameworks were constructed by 5-norbornene-2,3-dicarboxylic acid and different bis(pyridine) rod-like tectons, and Cd (II) complexes exhibit blue–violet emissions, whereas Co (II) complexes show antiferromagnetic behaviours. Display Omitted.

  5. Bistability of Cation Interstitials in II-VI Semiconductors

    SciTech Connect (OSTI)

    Wei, S. H.; Dalpian, G. M.

    2005-11-01

    The stability of cation interstitials in II-VI semiconductors is studied using ab initio methods. We find that interstitials in the neutral charge state are more stable in the tetrahedral interstitial site near the cation, whereas in the (2+) charge state, they are more stable near the anion. The diffusion energy barrier changes when the defect charge state changes. Therefore, if electrons/holes are taken from the defect level by light, changing its charge state, the interstitial atom will be able to diffuse almost spontaneously due to a reduced diffusion barrier.

  6. Transverse Field Perturbation For PIP-II SRF Cavities

    SciTech Connect (OSTI)

    Berrutti, Paolo; Khabiboulline, Timergali N.; Lebedev, Valeri; Yakovlev, Vyacheslav P.

    2015-06-01

    Proton Improvement Plan II (PIP-II) consists in a plan for upgrading the Fermilab proton accelerator complex to a beam power capability of at least 1 MW delivered to the neutrino production target. A room temperature section accelerates H⁻ ions to 2.1 MeV and creates the desired bunch structure for injection into the superconducting (SC) linac. Five cavity types, operating at three different frequencies 162.5, 325 and 650 MHz, provide acceleration to 800 MeV. This paper presents the studies on transverse field perturbation on particle dynamic for all the superconducting cavities in the linac. The effects studied include quadrupole defocusing for coaxial resonators, and dipole kick due to couplers for elliptical cavities. A multipole expansion has been performed for each of the cavity designs including effects up to octupole.

  7. Carbonic anhydrase II deficiency: Single-base deletion in exon 7 is the predominant mutation in Caribbean Hispanic patients

    SciTech Connect (OSTI)

    Hu, P.Y.; Ernst, A.R.; Sly, W.S. ); Venta, P.J. ); Skaggs, L.A.; Tashian, R.E. )

    1994-04-01

    To date, three different structural gene mutations have been identified in patients with carbonic anhydrase II deficiency (osteopetrosis with renal tubular acidosis and cerebral calcification). These include a missense mutation (H107Y) in two families, a splice junction mutation in intron 5 in one of these families, and a splice junction mutation in intron 2 for which many Arabic patients are homozygous. The authors report here a novel mutation for which carbonic anhydrase II-deficient patients from seven unrelated Hispanic families were found to be homozygous. The proband was a 2 1/2-year-old Hispanic girl of Puerto Rican ancestry who was unique clinically, in that she had no evidence of renal tubular acidosis, even though she did have osteopetrosis, developmental delay, and cerebral calcification. She proved to be homozygous for a single-base deletion in the coding region of exon 7 that produces a frameshift that changes the next 12 amino acids before leading to chain termination and that also introduces a new MaeIII restriction site. The 27-kD truncated enzyme produced when the mutant cDNA was expressed in COS cells was enzymatically inactive, present mainly in insoluble aggregates, and detectable immunologically at only 5% the level of the 29-kD normal carbonic anhydrase II expressed from the wild-type cDNA. Metabolic labeling revealed that this 27-kD mutant protein has an accelerated rate of degradation. Six subsequent Hispanic patients of Caribbean ancestry, all of whom had osteopetrosis and renal tubular acidosis but who varied widely in clinical severity, were found to be homozygous for the same mutation. These findings identify a novel mutation common to Hispanic patients from the Caribbean islands and provide a ready means for PCR-based diagnosis of the [open quotes]Hispanic mutation.[close quotes] The basis for their phenotypic variability is not yet clear. 15 refs., 5 figs., 1 tab.

  8. Safe substation grounding. Part II

    SciTech Connect (OSTI)

    Sverak, J.A.; Benson, R.V.; Dick, W.K.; Dodds, T.H.; Garret, D.C.; Idzkowski, J.E.; Keil, R.P.; Patel, S.A.

    1982-10-01

    Once the safe voltage limits for step and touch are determined, the design of a grounding system can be initiated. The criteria for determining these limits were already defined in Part I. This paper sets forth the fundamental aspects of a grounding design which are common to all substations and shows the differences between conventional and gas-insulated equipment installations. Other topics include: Characteristics of a combined grid - rod system, a general formula and tables for sizing of conductors and joints and methods for calculation of a ground resistance. Potentials of GIS enclosures during fault conditions, properties of concrete-encased electrodes and the use of bentonite are also discussed. The presented material of Part II is a preliminary version of updated information, proposed to replace Sections 7 - 12 of IEEE Std. 80/1976. Paragraphs 6.3 and 6.4 complement Section 6 of Part I, presented in the first report (Paper 80 SM 652-8).

  9. Part II - Managerial Competencies: Organizational Representation...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Part II - Managerial Competencies: Organizational Representation and Liaison Form for the SES program emphasizes the range of communications and publicrelations aspects of ...

  10. ARM - Campaign Instrument - splatt-ii

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Particle Laser Ablasion Time flown on Aircraft (SPLATT-II) Instrument Categories Aerosols Campaigns Carbonaceous Aerosol and Radiation Effects Study (CARES) - Surface ...

  11. Administrative Assistant II | Princeton Plasma Physics Lab

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Administrative Assistant II Department: ESH&S Supervisor(s): Rob Sheneman Requisition Number: 1600013 Position Summary: The successful candidate will manage critical data and...

  12. ARM - Field Campaign - ARESE II IOP

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Abstract The ARESE II Experiment was coordinated with the Atmospheric Radiation Measurement - Unmanned Aerospace Vehicle (ARM-UAV) Program. Other Contacts Doug Sisterson, SGP CART ...

  13. Concrete Pour in NSLS-II Ring

    ScienceCinema (OSTI)

    Bruno Semon

    2013-07-22

    The mezzanine floor of the ring building tunnel for NSLS-II was completed when the last concrete was placed in February 2011.

  14. SWAMI II technology transfer plan

    SciTech Connect (OSTI)

    Ward, C.R.; Peterson, K.D.; Harpring, L.J.; Immel, D.M.; Jones, J.D.; Mallet, W.R.

    1995-12-31

    Thousands of drums of radioactive/hazardous/mixed waste are currently stored at DOE sites throughout US; they are stored in warehouse facilities on an interim basis, pending final disposition. Recent emphasis on anticipated decommissioning of facilities indicates that many more drums of waste will be generated, requiring additional storage. Federal and state regulations dictate that hazardous waste covered by RCRA be inspected periodically for container degradation and to verify inventories. All known DOE waste storage facilities are currently inspected manually. A system to perform robotic inspection of waste drums is under development by the SRTC Robotics Group of WSRC; it is called the Stored Waste Autonomous Mobile Inspector (SWAMI). The first version, SWAMI I, was developed by the Savannah River Technology Center (SRTC) as a proof of principle system for autonomous inspection of drums in a warehouse. SWAMI I was based on the Transitions Research Corporation (TRC) HelpMate mobile robot. TRC modified the Helpmate to navigate in aisles of drums. SRTC added subsystems to SWAMI I to determine its position in open areas, read bar code labels on the drums up to three levels high, capture images of the drums and perform a radiation survey of the floor in the aisles. The radiation survey was based on SRTC patented technology first implemented on the Semi-Intelligent Mobile Observing Navigator (SIMON). The radiation survey is not essential for the inspection of drums, but is an option that can increase the utility and effectiveness of SWAMI in warehouses with radioactive and/or mixed waste. All the sensors on SWAMI I were fixed on the vehicle. From the success of SWAMI I, a second version, SWAMI II, was developed; it will be evaluated at Fernald and tested with two other mobile robots. Intent is to transfer the technology developed for SWAMI I and II to industry so that it can supply additional units for purchase for drum inspection.

  15. The Effect of Cellulose Crystal Structure and Solid-State Morphology on the Activity of Cellulases

    SciTech Connect (OSTI)

    Stipanovic, Arthur J

    2014-11-17

    Consistent with the US-DOE and USDA “Roadmap” objective of producing ethanol and chemicals from cellulosic feedstocks more efficiently, a three year research project entitled “The Effect of Cellulose Crystal Structure and Solid-State Morphology on the Activity of Cellulases” was initiated in early 2003 under DOE sponsorship (Project Number DE-FG02-02ER15356). A three year continuation was awarded in June 2005 for the period September 15, 2005 through September 14, 2008. The original goal of this project was to determine the effect of cellulose crystal structure, including allomorphic crystalline form (Cellulose I, II, III, IV and sub-allomorphs), relative degree of crystallinity and crystallite size, on the activity of different types of genetically engineered cellulase enzymes to provide insight into the mechanism and kinetics of cellulose digestion by “pure” enzymes rather than complex mixtures. We expected that such information would ultimately help enhance the accessibility of cellulose to enzymatic conversion processes thereby creating a more cost-effective commercial process yielding sugars for fermentation into ethanol and other chemical products. Perhaps the most significant finding of the initial project phase was that conversion of native bacterial cellulose (Cellulose I; BC-I) to the Cellulose II (BC-II) crystal form by aqueous NaOH “pretreatment” provided an increase in cellulase conversion rate approaching 2-4 fold depending on enzyme concentration and temperature, even when initial % crystallinity values were similar for both allomorphs.

  16. G-Zero Finds that Ghostly Strange Quarks Influence Proton Structure...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    strange quarks in the proton's quark-gluon sea contribute to a proton's properties. ... They determined that the next-lightest quark, the "strange" quark, would be the most ...

  17. STREAM II-V5: REVISION OF STREAM II-V4 AQUEOUS TRANSPORT CODE TO ACCOUNT FOR THE EFFECTS OF RAINFALL EVENTS

    SciTech Connect (OSTI)

    Chen, K.

    2011-05-18

    STREAM II is an aqueous transport model developed by the Savannah River National Laboratory (SRNL) for use in the Savannah River Site (SRS) emergency response program. The transport model of the Water Quality Analysis Simulation Program (WASP) is used by STREAM II to perform contaminant transport calculations. WASP5 is a US Environmental Protection Agency (EPA) water quality analysis program that simulates contaminant transport and fate through surface water. A recent version of the code (STREAM II-V4) predicts peak concentration and peak concentration arrival time at downstream locations for releases from the SRS facilities to the Savannah River. The input flows for STREAM II-V4 are derived from the historical flow records measured by the United States Geological Survey (USGS). The stream flow for STREAM II-V4 is fixed and the flow only varies with the month in which the releases are taking place. Therefore, the effects of flow surge due to a severe storm are not accounted for by STREAM IIV4. STREAM II-V5 is an upgraded version which accounts for the effects of a storm event. The revised model finds the proper stream inlet flow based on the total rainfall and rainfall duration as input by the user. STREAM II-V5 then adjusts the stream segment volumes (cross sections) based on the stream inlet flow. The rainfall based stream flow and the adjusted stream segment volumes are then used for contaminant transport calculations. This paper will discuss the required modifications to STREAM II and a comparison of results between the older and newer versions for an example involving a rainfall event.

  18. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Project, Zachary, Louisiana November 24, 2010 EA-1797: Finding of No Significant Impact Agua Caliente Solar Project in Yuma County, Arizona November 19, 2010 EA-1727: Finding of No...

  19. EA-1726: Finding of No Significant Impact | Department of Energy

    Energy Savers

    Finding of No Significant Impact EA-1726: Finding of No Significant Impact Kahuku Wind Power, LLC, Construction of the Kahuku Wind Power Facility in Kahuku, O'ahu, Hawaii The ...

  20. Accident Investigation Board (AIB) findings about the drum breach...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Accident Investigation Board findings Accident Investigation Board (AIB) findings about the drum breach at WIPP WHEN: Apr 23, 2015 5:30 PM - 7:00 PM WHERE: Fuller Lodge 2132 ...

  1. STEM Volunteer Training: Types of Volunteering and Where to Find...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Types of Volunteering and Where to Find Opportunities STEM Volunteer Training: Types of Volunteering and Where to Find Opportunities April 14, 2016 3:00PM to 4:00PM EDT

  2. EERE 2014 Wind Technologies Market Report Finds Wind Power at...

    Energy Savers

    2014 Wind Technologies Market Report Finds Wind Power at Record Low Prices EERE 2014 Wind Technologies Market Report Finds Wind Power at Record Low Prices August 10, 2015 - 11:00am ...

  3. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    County, Nevada June 9, 2011 EA-1770: Finding of No Significant Impact Photovoltaic Solar Project at the Durango, Colorado Site June 3, 2011 EA-1858: Finding of No Significant...

  4. Commercial Building Energy Asset Score: Pilot Findings and Program...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Commercial Building Energy Asset Score: Pilot Findings and Program Update The webinar was held on April 16, 2014, to share the findings from the 2013 Pilot and provide a program ...

  5. EA-1917: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1917: Finding of No Significant Impact Wave Energy Test Facility Project, Newport, OR Based on the information presented in the Final EA, (DOE...

  6. Show Me the Money!: How to Find Financing, Access Incentives...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Show Me the Money: How to Find Financing, Access Incentives, and Get Projects Done Show Me the Money: How to Find Financing, Access Incentives, and Get Projects Done December 6, ...

  7. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2012 EA-1812: Finding of No Significant Impact Haxtun Wind Energy Project, Logan and Phillips Counties, CO January 3, 2012 EA-1606: Finding of No Significant Impact Proposed Use...

  8. EA-1656: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1656: Finding of No Significant Impact MARET Center at Crowder College, Neosho, Missouri The U.S. Department of Energy is preparing an...

  9. EA-1894: Finding of No Significant Impact | Department of Energy

    Energy.gov (indexed) [DOE]

    Albeni Falls Flexible Winter Lake Operations, Bonner, Idaho As a result of the analysis in this EA, I have the following findings. I find that: 1) the FWPO is not a substantial...

  10. Title 16 USC 1600 Congressional Findings | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    600 Congressional Findings Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Title 16 USC 1600 Congressional FindingsLegal Abstract...

  11. Rainbows and Leprechauns: Finding Gold in Partnerships (101)...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Rainbows and Leprechauns: Finding Gold in Partnerships (101) Rainbows and Leprechauns: Finding Gold in Partnerships (101) March 17, 2016 1:00PM to 2:30PM EDT

  12. EA-1933: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1933: Finding of No Significant Impact Yakama Nation Drop 4 Hydropower Project, Yakama Nation Reservation, WA Based on the Final EA, DOE has...

  13. The World's Largest Solar Project Finds a Home in California...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Solar Project Finds a Home in California The World's Largest Solar Project Finds a Home in ... That's the impact that the Blythe Solar Power Project is projected to have upon ...

  14. Got a Minute? Which Higgs did we find?

    SciTech Connect (OSTI)

    Stupak, John

    2014-06-26

    Dr. John Stupak talks about the discovery of the Higgs boson. Did scientists find the Higgs boson predicted back in 1964 or did they find just one of a group of particles, with the others still to be found?

  15. ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND RECOMMENDATIONS 2014 ULTRA-DEEPWATER ADVISORY COMMITTEE COMMITTEE FINDINGS AND RECOMMENDATIONS i Table of Contents Research and Development Program Committee ............................................ 1 Sunset Committee .................................................................................................. 5 Advisory Committee Members ........................................................................... 7 ULTRA-DEEPWATER

  16. Got a Minute? Which Higgs did we find?

    ScienceCinema (OSTI)

    Stupak, John

    2014-09-15

    Dr. John Stupak talks about the discovery of the Higgs boson. Did scientists find the Higgs boson predicted back in 1964 or did they find just one of a group of particles, with the others still to be found?

  17. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    in Kahuku, O'ahu, Hawaii May 18, 2010 EA-1699: Finding of No Significant Impact PopeDouglas Third Combustor Expansion Project, Alexandria, Minnesota May 7, 2010 EA-1635: Finding...

  18. EIS-0365: Record of Decision and Floodplain Statement of Findings...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Record of Decision and Floodplain Statement of Findings EIS-0365: Record of Decision and Floodplain Statement of Findings Imperial-Mexicali 230-kV Transmission Lines DOE announces...

  19. EA-1767: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7: Finding of No Significant Impact EA-1767: Finding of No Significant Impact Virginia State Energy Program's Cephas C&D Wastes Biomass Project, Richmond, Virginia Based on the...

  20. EA-1814: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1814: Finding of No Significant Impact City of Montpelier Combined Heat and Power, and District Energy System, Montpelier, Vermont The U.S....

  1. EA-1665: Final Environmental Assessment and Finding of No Significant...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Final Environmental Assessment and Finding of No Significant Impact EA-1665: Final Environmental Assessment and Finding of No Significant Impact Davis-Kingman Tap 69-kV...

  2. EA-1947: Finding of No Significant Impact | Department of Energy

    Energy Savers

    7: Finding of No Significant Impact EA-1947: Finding of No Significant Impact Transfer of ... and NNSA is issuing this FONSI. EA-1947FONSI-2013.pdf (169.65 KB) More Documents ...

  3. EA-1833: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1833: Finding of No Significant Impact The City of El Dorado Wind Energy Project, El Dorado, Butler County, Kansas The U.S. Department of...

  4. EA-1928: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-1928: Finding of No Significant Impact White-Tailed Deer Management at Brookhaven National Lab, Upton, New York Based on the information in the...

  5. Nickel(II) and Copper(I,II)-based Metal-Organic Frameworks Incorporati...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    nickel(II) perchlorate or copper(II) nitrate afforded two new metal-organic frameworks, Ni3(BTPP)2solvent (Ni-BTPP) and CuI4CuII2(OH)2(BTPP)2 solvent (Cu-BTPP). Powder...

  6. Finding and Winning Simplified Acquisitions, Part 1 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding and Winning Simplified Acquisitions, Part 1 Finding and Winning Simplified Acquisitions, Part 1 Presented at the 15th Annual DOE Small Business Forum & Expo by: Guy Timberlake, Chief Visionary Officer and Chief Executive Officer, The American Small Business Coalition Finding and Winning Simplified Acquisitions, Part 1 (4.41 MB) More Documents & Publications Finding and Winning Simplified Acquisitions, Part 2 Chapter 17 - Special Contracting Methods Interagency Acquisition

  7. Finding and Winning Simplified Acquisitions, Part 2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding and Winning Simplified Acquisitions, Part 2 Finding and Winning Simplified Acquisitions, Part 2 Presented at the 15th Annual DOE Small Business Forum & Expo by: Guy Timberlake, Chief Visionary Officer and Chief Executive Officer, The American Small Business Coalition Finding and Winning Simplified Acquisitions, Part 2 (6.47 MB) More Documents & Publications Finding and Winning Simplified Acquisitions, Part 1 December 12, 2013 Business Opportunity Session Presentations Acquisition

  8. EIS-0369: Floodplain Statement of Finding | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    9: Floodplain Statement of Finding EIS-0369: Floodplain Statement of Finding Rail Alignment for the Construction and Operation of a Railroad in Nevada to a Geologic Repository at Yucca Mountain, Nye County, Nevada Floodplain Statement of Findings for the Final Environmental Impact Statement for a Rail Alignment for the Construction and Operation of a Railroad in Nevada to a Geologic Repository at Yucca Mountain, Nye County, Nevada Floodplain Statement of Findings for the Final Environmental

  9. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Findings of No Significant Impact (FONSI) Findings of No Significant Impact (FONSI) Findings of No Significant Impact are public documents issued by a Federal agency briefly presenting the reasons why an action for which the agency has prepared an environmental assessment will not have a significant effect on the human environment and, therefore, will not require preparation of an environmental impact statement. If you have any trouble finding a specific document, please contact

  10. Run II data analysis on the grid

    SciTech Connect (OSTI)

    Igor Mandrichenko, Igor Terekhov and Frank Wurthwein

    2002-12-02

    In this document, we begin the technical design for the distributed RunII computing for CDF and D0. The present paper defines the three components of the data handling area of Run II computing, namely the Data Handling System, the Storage System and the Application. We outline their functionality and interaction between them. We identify necessary and desirable elements of the interfaces.

  11. Synthesis of Monomeric Fe(II) and Ru(II) Complexes of Tetradentate Phosphines

    SciTech Connect (OSTI)

    Jana, Barun; Ellern, Arkady; Pestovsky, Oleg; Sadow, Aaron; Bakac, Andreja

    2011-03-07

    rac-Bis[{l_brace}(diphenylphosphino)ethyl{r_brace}-phenylphosphino]methane (DPPEPM) reacts with iron(II) and ruthenium(II) halides to generate complexes with folded DPPEPM coordination. The paramagnetic, five-coordinate Fe(DPPEPM)Cl{sub 2} (1) in CD{sub 2}Cl{sub 2} features a tridentate binding mode as established by {sup 31}P{l_brace}{sup 1}H{r_brace} NMR spectroscopy. Crystal structure analysis of the analogous bromo complex, Fe(DPPEPM)Br{sub 2} (2) revealed a pseudo-octahedral, cis-{alpha} geometry at iron with DPPEPM coordinated in a tetradentate fashion. However, in CD{sub 2}Cl{sub 2} solution, the coordination of DPPEPM in 2 is similar to that of 1 in that one of the external phosphorus atoms is dissociated resulting in a mixture of three tridentate complexes. The chloro ruthenium complex cis-Ru({kappa}{sup 4}-DPPEPM)Cl{sub 2} (3) is obtained from rac-DPPEPM and either [RuCl{sub 2}(COD)]{sub 2} [COD = 1,5-cyclooctadiene] or RuCl{sub 2}(PPh{sub 3}){sub 4}. The structure of 3 in both the solid state and in CD{sub 2}Cl{sub 2} solution features a folded {kappa}{sup 4}-DPPEPM. This binding mode was also observed in cis-[Fe({kappa}{sup 4}-DPPEPM)(CH{sub 3}CN){sub 2}](CF{sub 3}SO{sub 3}){sub 2} (4). Addition of an excess of CO to a methanolic solution of 1 results in the replacement of one of the chloride ions by CO to yield cis-[Fe({kappa}{sup 4}-DPPEPM)Cl(CO)](Cl) (5). The same reaction in CH{sub 2}Cl{sub 2} produces a mixture of 5 and [Fe({kappa}{sup 3}-DPPEPM)Cl{sub 2}(CO)] (6) in which one of the internal phosphines has been substituted by CO. Complexes 2, 3, 4, and 5 appear to be the first structurally characterized monometallic complexes of {kappa}{sup 4}-DPPEPM.

  12. TRUPACT-II, a regulatory perspective

    SciTech Connect (OSTI)

    Gregory, P.C.; Spooner, O.R.

    1995-12-31

    The Transuranic Package Transporter II (TRUPACT-II) is a US Nuclear Regulatory Commission (NRC) certified Type B packaging for the shipment of contact-handled transuranic (CH-TRU) material by the US Department of Energy (DOE). The NRC approved the TRUPACT-II design as meeting the requirements of Title 10, Code of Federal Regulations, Part 71 (10 CFR 71) and issued Certificate of Compliance (CofC) Number 9218 to the DOE. There are currently 15 certified TRUPACT-IIs. Additional TRUPACT-IIs will be required to make more than 15,000 shipments of CH-TRU waste to the Waste Isolation Pilot Plant (WIPP) site near Carlsbad, New Mexico. The TRUPACT-II may also be used for the DOE inter-site and intra-site shipments of CH-TRU waste. The Land Withdrawal Act (Public Law 102-579), enacted by the US Congress, October 30, 1992, and an agreement between the DOE and the State of New Mexico, signed August 4, 1987, both stipulate that only NRC approved packaging may be used for shipments of TRU waste to the WIPP. Early in the TRUPACT-II development phase it was decided that the transportation system (tractor, trailer, and TRUPACT-II) should be highway legal on all routes without the need for oversize and/or overweight permits. In large measure, public acceptance of the DOE`s efforts to safely transport CH-TRU waste depends on the public`s perception that the TRUPACT-II is in compliance with all applicable regulations, standards, and quality assurance requirements. This paper addresses some of the numerous regulations applicable to Type B packaging, and it describes how the TRUPACT-II complies with these regulations.

  13. Engineering characterization of ground motion. Task II: soil structure interaction effects on structural response. Volume 4

    SciTech Connect (OSTI)

    Luco, J.E.; Wong, H.L.; Chang, C.Y.; Power, M.S.; Idriss, I.M.

    1986-08-01

    This report presents the results of part of a two-task study on the engineering characterization of earthquake ground motion for nuclear power plant design. The overall objective of this research program sponsored by the US Nuclear Regulatory Commission (USNRC) is to develop recommendations for methods for selecting design response spectra or acceleration time histories to be used to characterize motion at the foundation level of nuclear power plants. 15 refs., 199 figs., 78 tabs.

  14. STRUCtural Simulator

    Energy Science and Technology Software Center (OSTI)

    2004-07-01

    STRUC-ANL is a derivative of the FLUSTR-ANL finite element code. It contains only the structural capabilities of the original fluid-structural FLUSTR code.

  15. Structural Materials

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Structural Materials Development enables advanced technologies through the discovery, development, and demonstration of cost-effective advanced structural materials for use in ...

  16. Inherent structure of a molten salt

    SciTech Connect (OSTI)

    La Violette, Randall A.; Budzien, Joanne L.; Stillinger, Frank H.

    2000-05-08

    We calculated the inherent structure of a model melt of zinc (II) bromide over a wide range of densities. Stable, metastable, and unstable branches were obtained for the zero temperature pressure-volume isotherm of the inherent structure. The pressure-volume isotherm, the void distribution, and the structure factor were used to identify the spinodal, independent of any model equation of state. (c) 2000 American Institute of Physics.

  17. Fractional distillation as a strategy for reducing the genotoxic potential of SRC-II coal liquids: a status report

    SciTech Connect (OSTI)

    Pelroy, R.A.; Wilson, B.W.

    1981-09-01

    This report presents results of studies on the effects of fractional distillation on the genotoxic potential of Solvent Refined Coal (SRC-II) liquids. SRC-II source materials and distilled liquids were provided by Pittsburg and Midway Coal Mining Co. Fractional distillations were conducted on products from the P-99 process development unit operating under conditions approximating those anticipated at the SRC-II demonstration facility. Distillation cuts were subjected to chemical fractionation, in vitro bioassay and initial chemical analysis. Findings are discussed as they relate to the temperature at which various distillate cuts were produced. This document is the first of two status reports scheduled for 1981 describing these studies.

  18. Hopkins Ridge II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Hopkins Ridge II Wind Farm Facility Hopkins Ridge II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  19. Panther Creek II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Panther Creek II Wind Farm Facility Panther Creek II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  20. Woodward Mountain I & II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Mountain I & II Wind Farm Jump to: navigation, search Name Woodward Mountain I & II Wind Farm Facility Woodward Mountain Wind Ranch I and II Sector Wind energy Facility Type...

  1. Michigan Wind II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Michigan Wind II Wind Farm Facility Michigan Wind II Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  2. North Dakota Wind II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name North Dakota Wind II Wind Farm Facility North Dakota Wind II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  3. Lake Benton II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Lake Benton II Wind Farm Facility Lake Benton II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  4. Smoky Hills II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Smoky Hills II Wind Farm Jump to: navigation, search Name Smoky Hills II Wind Farm Facility Smoky Hills II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  5. Tres Vaqueros II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Tres Vaqueros II Wind Farm Facility Tres Vaqueros II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  6. Venture Wind II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Venture Wind II Wind Farm Facility Venture Wind II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  7. Nine Canyon Wind Farm Phase II | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Farm Phase II Jump to: navigation, search Name Nine Canyon Wind Farm Phase II Facility Nine Canyon Wind Farm Phase II Sector Wind energy Facility Type Commercial Scale Wind...

  8. Meadow Lake II (3Q10) | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II (3Q10) Jump to: navigation, search Name Meadow Lake II (3Q10) Facility Meadow Lake II (3Q10) Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  9. Dry Lake II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Dry Lake II Wind Farm Facility Dry Lake II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  10. Foote Creek Rim II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Foote Creek Rim II Wind Farm Facility Foote Creek Rim II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  11. I 95 Landfill Phase II Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    I 95 Landfill Phase II Biomass Facility Jump to: navigation, search Name I 95 Landfill Phase II Biomass Facility Facility I 95 Landfill Phase II Sector Biomass Facility Type...

  12. Meridian Way II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Meridian Way II Wind Farm Facility Meridian Way II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  13. MinWind I & II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    I & II Wind Farm Jump to: navigation, search Name MinWind I & II Wind Farm Facility MinWind I & II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  14. Wild Horse II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Wild Horse II Wind Farm Facility Wild Horse II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  15. Adv. Fossil Solicitation Part II Due Date | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    II Due Date Adv. Fossil Solicitation Part II Due Date November 30, 2016 12:01AM to 12:59PM AST ADVANCED FOSSIL ENERGY PROJECTS SOLICITATION PART II

  16. FERN Blue Ribbon Wind Farm II* | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II* Jump to: navigation, search Name FERN Blue Ribbon Wind Farm II* Facility FERN Blue Ribbon Wind Farm II* Sector Wind energy Facility Type Offshore Wind Facility Status Proposed...

  17. Minco II Wind Energy Center | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Minco II Wind Energy Center Jump to: navigation, search Name Minco II Wind Energy Center Facility Minco II Wind Energy Center Sector Wind energy Facility Type Commercial Scale Wind...

  18. Hull Wind II Wind Farm | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    II Wind Farm Jump to: navigation, search Name Hull Wind II Wind Farm Facility Hull II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Hull...

  19. Fermilab | Directorate | PIP-II Machine Advisory Committee (XMAC...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    PIP-II Machine Advisory Committee (P2MAC) Meeting of the Fermilab PIP-II Advisory Committee March 9-11, 2015 2014 Recommendations Response 2014 XMAC Report P2MAC Charge PIP-II...

  20. REEE Solicitation Part II Due Date | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    REEE Solicitation Part II Due Date REEE Solicitation Part II Due Date April 13, 2016 12:01AM to 11:59PM EDT RENEWABLE ENERGY AND EFFICENT ENERGY PROJECTS SOLICITATION PART II DUE...

  1. REEE Solicitation Part II Due Date | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    REEE Solicitation Part II Due Date REEE Solicitation Part II Due Date June 15, 2016 12:01AM to 11:59PM EDT RENEWABLE ENERGY AND EFFICENT ENERGY PROJECTS SOLICITATION PART II DUE...

  2. REEE Solicitation Part II Due Date | Department of Energy

    Office of Environmental Management (EM)

    II Due Date REEE Solicitation Part II Due Date November 30, 2016 1:01AM EST to December 1, 2016 12:59AM EST RENEWABLE ENERGY AND EFFICENT ENERGY PROJECTS SOLICITATION PART II DUE ...

  3. Adv. Nuclear Solicitation Part II Due Date | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Adv. Nuclear Solicitation Part II Due Date Adv. Nuclear Solicitation Part II Due Date April 13, 2016 12:01AM to 11:59PM EDT ADVANCED NUCLEAR ENERGY PROJECTS SOLICITATION PART II ...

  4. How to Find Ames Laboratory | The Ames Laboratory

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    How to Find Ames Laboratory Finding the Ames Laboratory The Ames Laboratory has it's main administrative offices in the Technical and Administrative Services Facility (TASF) building on the Iowa State University Campus. Technical and Administrative Services Facility (TASF) 2408 Pammel Drive, Ames, IA 50011-1015 For directions from the Des Moines Airport please use the link with the following directions: https://goo.gl/maps/c6SOK Finding the Ames Laboratory on the ISU Campus Image Click on the

  5. Alternative Fuels Data Center: Minnesota School District Finds Cost

    Alternative Fuels and Advanced Vehicles Data Center

    Savings, Cold-Weather Reliability with Propane Buses Minnesota School District Finds Cost Savings, Cold-Weather Reliability with Propane Buses to someone by E-mail Share Alternative Fuels Data Center: Minnesota School District Finds Cost Savings, Cold-Weather Reliability with Propane Buses on Facebook Tweet about Alternative Fuels Data Center: Minnesota School District Finds Cost Savings, Cold-Weather Reliability with Propane Buses on Twitter Bookmark Alternative Fuels Data Center: Minnesota

  6. Find Funding | U.S. DOE Office of Science (SC)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Find Funding Funding Opportunities Funding Opportunities Home Grants & Contracts Support Award Search / Public Abstracts Find Funding Early Career Research Program Statement on Digital Data Management Acknowledgements of Federal Support Contact Information Office of Science U.S. Department of Energy 1000 Independence Ave., SW Washington, DC 20585 P: (202) 586-5430 Find Funding Print Text Size: A A A FeedbackShare Page Additional information on funding opportunities, including program

  7. EA-1495: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    5: Finding of No Significant Impact EA-1495: Finding of No Significant Impact USEC Inc. American Centrifuge Lead Cascade Facility at Piketon, Ohio The purpose of NRC's proposed action is to authorize possession and use of source and special nuclear material at the Lead Cascade in Piketon, Ohio. Finding of No Significant Impact for the United States Enrichment Corporation Incorporated, American Centrifuge Lead Cascade Facility at Piketon, Ohio (369.61 KB) More Documents & Publications

  8. Portsmouth Integration Director's Final Findings and Order | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Integration Director's Final Findings and Order Portsmouth Integration Director's Final Findings and Order Portsmouth Integration Director's Final Findings and Order purpose is to: integrate the on-site work required for specific units to avoid duplication of effort, and efficiently perform sitewide ground water monitoring and surveillance and maintenance activities; recognize that a substantial portion of the tasks required under existing approved closure plans for certain units have

  9. FOIA-Summary of Findings: Circumstances surrounding decisions regarding the

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    security clearance, access and work assignments | Department of Energy FOIA-Summary of Findings: Circumstances surrounding decisions regarding the security clearance, access and work assignments FOIA-Summary of Findings: Circumstances surrounding decisions regarding the security clearance, access and work assignments FOIA request FOIA-Summary of Findings: Circumstances surrounding decisions regarding the security clearance, access and work assignments (4.61 MB) More Documents &

  10. EA-2010: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-2010: Finding of No Significant Impact Alternating Gradient Synchrotron Complex Improvements at Brookhaven National Laboratory; Upton, New York DOE issued a Finding of No Significant Impact for the proposed activities at the Brookhaven National Laboratory Alternating Gradient Synchrotron Complex, including upgrading the Accelerator Test Facility to 10 GeV by adding laser acceleration, upgrading the Linac proton beam current, upgrading the facilities to produce

  11. EA-2018: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Finding of No Significant Impact EA-2018: Finding of No Significant Impact EA-2018: Front Range-Midway Solar Interconnection Project; El Paso County, Colorado Western Area Power Administration issued a Finding of No Significant Impact on September 21, 2016, for a proposal to interconnect a proposed photovoltaic solar facility adjacent to Western's existing Midway Substation in El Paso County, Colorado. For more information on this project, see: www.energy.gov/node/1907551. DOWNLOAD DOCUMENT

  12. EA-2024: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4: Finding of No Significant Impact EA-2024: Finding of No Significant Impact Gap Material Plutonium - Transport, Receipt, and Processing Based on the analysis in the environmental assessment, the U.S. Department of Energy, National Nuclear Security Administration (NNSA), issued this finding of no significant impact for transporting up to 900 kilograms of plutonium from foreign countries to the Savannah River Site in South Carolina for storage and processing pending final disposition. NNSA will

  13. EA-1440: Finding of No Signficant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    : Finding of No Signficant Impact EA-1440: Finding of No Signficant Impact National Renewable Energy Laboratory's South Table Mountain Complex The Proposed Action is to operate the STM complex for alternative energy research with new and improved capabilities to support DOE"s mission to research, develop and transfer to industry renewable energy technologies. Finding of No Signficant Impact for the Site-Wide Environmental Assessment of the National Renewable Energy Laboratory's South Table

  14. EA-1797: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7: Finding of No Significant Impact EA-1797: Finding of No Significant Impact Agua Caliente Solar Project in Yuma County, Arizona The Department of Energy has conducted an environmental assessment that analyzed the reasonably foreseeable environmental impacts associated with the 290 Megawatt gross output photovoltaic solar power project and associated interconnection transmission line proposed by Agua Caliente Solar, LLC in Yuma County, Arizona. Finding of No Significant Impact Department of

  15. EA-1406: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    06: Finding of No Significant Impact EA-1406: Finding of No Significant Impact Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site On the basis of the Environmental Assessment. which analyzed relevant environmental issues and addressed the concerns of stakeholders, DOE finds that no significant impact will result from implementing the planned action at the New Rifle site. This FONSI is documented pursuant to NEPA, the Council on Environmental Quality's "Regulations for

  16. Find Other Sources of EERE Funding | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Find Funding » Find Other Sources of EERE Funding Find Other Sources of EERE Funding Many financial opportunities are available besides EERE funding opportunity announcements (FOAs). Like FOAs, some are competitive, while others are non-competitive. Cooperative Research and Development Agreements (CRADAs) Formula Grants Acquisition Small Business Innovation Research (SBIR)/Small Business Technology Transfer (STTR) Awards Technology Investment Agreement (TIA) Unsolicited Proposals Cooperative

  17. Webinar Series: Presenting SEEDS Findings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Webinar Series: Presenting SEEDS Findings Webinar Series: Presenting SEEDS Findings The SunShot Solar Energy Evolution and Diffusion Studies (SEEDS) program investigates strategies for accelerating the pace of change for solar energy technologies as they are developed and deployed. In a series of three webinars, the National Renewable Energy Laboratory SEEDS research team discusses the findings and outcomes of their project. Date June 2016 Topic Financing, Incentives & Market Analysis

  18. dgtoexo2: A Distorted Grid Output File to Exodus II Finite Element Database Conversion Utility

    SciTech Connect (OSTI)

    Moffat, H.K.

    1998-12-01

    This report describes how to obtain publication-quality graphics from distorted grid electronic structure codes using the combination of the conversion utility, dgtoexo2, and mustafa, an AVS Express application. dgtoexo2 converts scalar function results from a format applicable to distorted grid codes into the Exodus II unstructured finite element data representation. nmstafa can read Exodus II files and use the AVS Express engine to visualize data on unix and Windows NT platforms. Though not designed for the purpose, the dgtoexo2/EXOdUS II/mustafa combination is sufficiently versatile to provide for the specialized graphics needs of electronic structure codes. The combination also scales well, producing robust performance for problems involving millions of grid points.

  19. Composition, apparatus, and process, for sorption of gaseous compounds of group II-VII elements

    DOE Patents [OSTI]

    Tom, Glenn M.; McManus, James V.; Luxon, Bruce A.

    1991-08-06

    Scavenger compositions are disclosed, which have utility for effecting the sorptive removal of hazardous gases containing Group II-VII elements of the Periodic Table, such as are widely encountered in the manufacture of semiconducting materials and semiconductor devices. Gas sorption processes including the contacting of Group II-VII gaseous compounds with such scavenger compositions are likewise disclosed, together with critical space velocity contacting conditions pertaining thereto. Further described are gas contacting apparatus, including mesh structures which may be deployed in gas contacting vessels containing such scavenger compositions, to prevent solids from being introduced to or discharged from the contacting vessel in the gas stream undergoing treatment. A reticulate heat transfer structure also is disclosed, for dampening localized exothermic reaction fronts when gas mixtures comprising Group II-VII constituents are contacted with the scavenger compositions in bulk sorption contacting vessels according to the invention.

  20. EA-1770: Finding of No Significant Impact | Department of Energy

    Energy.gov (indexed) [DOE]

    of the National Environmental Policy Act (NEPA). Finding of No Significant Impact Photovoltaic Solar Project at the Durango, Colorado, Disposal Site, La Plata County, DOEEA 1770...

  1. EA-1533: Finding of No Significant Impact | Department of Energy

    Energy Savers

    EA-1533: Finding of No Significant Impact Proposed Gas Main and Distribution System Upgrade, Pantex Plant, Amarillo, Texas This environmental assessment (EA) provides sufficient ...

  2. EA-1907: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Impact EA-1907: Finding of No Significant Impact Western Plains Energy, LLC Biogas Anaerobic Digester Facility, Oakley, Kansas Based on the analysis in the Final EA and...

  3. EA-1193: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1193: Finding of No Significant Impact Atmospheric Radiation Measurement (ARM) Program North Slope of Alaska and Adjacent Arctic Ocean Cloud and Radiation Testbed (CART) Site The ...

  4. EA-1762: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of No Significant Impact EA-1762: Finding of No Significant Impact Wellford Landfill Methane and Greenhouse Gas to Energy Project, Spartanburg County, South Carolina The...

  5. PPPL physicists find clue to formation of magnetic fields around...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    results, in the range in which they are done, strongly suggest that such dynamo action is possible." These findings might lead to greater understanding of the behavior of...

  6. EA-1685: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of No Significant Impact EA-1685: Finding of No Significant Impact Experimental Coal Flow Program at Clemson University The Western Area Power Administration (Western) is the...

  7. DOE Issues Finding of No Significant Impact and Final Environmental...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    DOE Issues Finding of No Significant Impact and Final Environmental Assessment on Road ... impacts of building an internal road to safely ship radioactive material within ...

  8. Floodplain and Wetland Assessment and Statement of Findings

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Findings for Construction of a Second Full Service Access Road over Lena Gulch from South Golden Road to the National Renewable Energy Laboratory's South Table Mountain ...

  9. Finding of No Significant Impact, Federal Register, 73 FR 2017...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    73 FR 2017, January 11, 2008 Document details the finding of no significant impact of the Energy-Efficient Performance Requirements for New Federal Commercial and Residential...

  10. EA-2022: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    Western issued a finding of no significant impact for the proposal. The new hydropower generator would interconnect to Western's transmission system at an existing transmission ...

  11. EA-1183: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1183: Finding of No Significant Impact Coal-fired Diesel Generator University of ... the performance of a coal-fired generator at the University of Alaska, Fairbanks, ...

  12. CLASS DEVIATION FINDINGS AND DETERMINATION TO IMPLEMENT AN APPROPRIATI...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    PROVISION RELATED TO INTERNAL CONFIDENTIALITY AGREEMENTS AND THE REPORTING OF FRAUD, WASTE, AND ABUSE Findings I. Section 743 of Division E, Title VII of the Consolidated...

  13. EA-0921: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-0921: Finding of No Significant Impact Ambulatory Research and Education Center, Oregon Health ... the meaning of NEPA. Therefore, an environmental impact statement is not required. ...

  14. EA-1801: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    EA-1801: Finding of No Significant Impact Granite Reliable Power Wind Project, Coos County, New Hampshire The Department of Energy is adopting an environmental assessment completed ...

  15. EA-1700: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    LBNLUniversity of California Berkeley programs that focus on computational and computer science research in a new facility on the LBNL site. PDF icon Finding of No Significant...

  16. Finding Large Aperture Fractures in Geothermal Resource Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ...-Offset Surface Seismic Survey, PSInSAR, and Kinematic Analysis Finding Large Aperture Fractures in Geothermal Resource Areas Using A Three-Component Long-Offset Surface Seismic ...

  17. Findings of No Significant Impact (FONSI) | Department of Energy

    Energy.gov (indexed) [DOE]

    Ridge Reservation for the biological control of the emerald ash borer, a nonnative invasive beetle. May 1, 2015 EA-1796: Finding of No Significant Impact Loan Guarantee to...

  18. EA-1747: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1747: Finding of No Significant Impact Rocky Flats Surface Water Configuration, Jefferson County, Colorado Surface Water Configuration Project at the Rocky Flats Site, Colorado ...

  19. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EA-1754: Finding of No Significant Impact Public Service Company of New Mexico, Photovoltaic Plus Battery for Simultaneous Voltage Smoothing and Peak Shifting Project,...

  20. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Uranium July 1, 2009 EA-1645: Finding of No Significant Impact Loan Guarantee for Sage Electrochromics SageGlass High Volume Manufacturing Facility in Faribault, MN June 26,...