National Library of Energy BETA

Sample records for ds cu ag

  1. High heat flux testing of HIP bonded DS-Cu/316SS first wall panel for fusion experimental reactors

    SciTech Connect (OSTI)

    Hatano, Toshihisa; Sato, Kazuyoshi; Dairaku, Masayuki

    1996-12-31

    A shielding blanket design in a fusion reactor such as ITER has been proposed to be a modulator structure integrated with the first wall. In terms of the fabrication, HIP (Hot Isostatic Pressing) method has been proposed for the joining of dispersion strengthened copper (DS-Cu) and type 316L stainless steel (SS316L) at FW. High heat flux tests of HIP bonded DS-Cu/SS316L first wall panel were performed at particle Beam Engineering Facility in JAERI to investigate its thermo-mechanical performance. After four campaigns of high heat flux testing, the FW panel was cut to observe the HIP bonded interface and heated surface of DS-Cu. Though melting of DS-Cu surface was observed, there were no cracks at the HIP bonded interface. 2 refs., 11 figs., 1 tab.

  2. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOE Patents [OSTI]

    Anderson, I.E.; Yost, F.G.; Smith, J.F.; Miller, C.M.; Terpstra, R.L.

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217 C and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid ``mushy`` zone) relative to the eutectic melting temperature (e.g. up to 15 C above the eutectic melting temperature). 5 figs.

  3. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOE Patents [OSTI]

    Anderson, Iver E.; Yost, Frederick G.; Smith, John F.; Miller, Chad M.; Terpstra, Robert L.

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217.degree. C. and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid "mushy" zone) relative to the eutectic melting temperature (e.g. up to 15.degree. C. above the eutectic melting temperature).

  4. Origin of Novel Diffusions of Cu and Ag in Semiconductors: The...

    Office of Scientific and Technical Information (OSTI)

    Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe Prev Next Title: Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe ...

  5. Characterization and device performance of (AgCu)(InGa)Se2 absorber layers

    SciTech Connect (OSTI)

    Hanket, Gregory; Boyle, Jonathan H.; Shafarman, William N.

    2009-06-08

    The study of (AgCu)(InGa)Se2 absorber layers is of interest in that Ag-chalcopyrites exhibit both wider bandgaps and lower melting points than their Cu counterparts. (AgCu)(InGa)Se2 absorber layers were deposited over the composition range 0 < Ag/(Ag+Cu) < 1 and 0.3 < Ga/(In+Ga) < 1.0 using a variety of elemental co-evaporation processes. Films were found to be singlephase over the entire composition range, in contrast to prior studies. Devices with Ga content 0.3 < Ga/(In+Ga) <0.5 tolerated Ag incorporation up to Ag/(Ag+Cu) = 0.5 without appreciable performance loss. Ag-containing films with Ga/(In+Ga) = 0.8 showed improved device characteristics over Cu-only control samples, in particular a 30-40% increase in short-circuit current. An absorber layer with composition Ag/(Ag+Cu) = 0.75 and Ga/(In+Ga) = 0.8 yielded a device with VOC = 890 mV, JSC = 20.5mA/cm2, fill factor = 71.3%, and ? = 13.0%.

  6. Optical and quantum efficiency analysis of (Ag,Cu)(In,Ga)Se2 absorber layers

    SciTech Connect (OSTI)

    Boyle, Jonathan; Hanket, Gregory; Shafarman, William

    2009-06-09

    (Ag,Cu)(In,Ga)Se2 thin films have been deposited by elemental co-evaporation over a wide range of compositions and their optical properties characterized by transmission and reflection measurements and by relative shift analysis of quantum efficiency device measurements. The optical bandgaps were determined by performing linear fits of (?h?)2 vs. h?, and the quantum efficiency bandgaps were determined by relative shift analysis of device curves with fixed Ga/(In+Ga) composition, but varying Ag/(Cu+Ag) composition. The determined experimental optical bandgap ranges of the Ga/(In+Ga) = 0.31, 0.52, and 0.82 groups, with Ag/(Cu+Ag) ranging from 0 to 1, were 1.19-1.45 eV, 1.32-1.56 eV, and 1.52-1.76 eV, respectively. The optical bowing parameter of the different Ga/(In+Ga) groups was also determined.

  7. Synthesis and anti-bacterial activity of Cu, Ag and Cu-Ag alloy nanoparticles: A green approach

    SciTech Connect (OSTI)

    Valodkar, Mayur; Modi, Shefaly; Pal, Angshuman; Thakore, Sonal

    2011-03-15

    Research highlights: {yields} Synthesis of novel nanosized copper-silver alloys of different compositions. {yields} Completely green approach for synthesis of water soluble bimetallic nanoparticle. {yields} Interesting anti-bacterial activity of as synthesized metal and alloy nanoparticle. -- Abstract: Metallic and bimetallic nanoparticles of copper and silver in various proportions were prepared by microwave assisted chemical reduction in aqueous medium using the biopolymer, starch as a stabilizing agent. Ascorbic acid was used as the reducing agent. The silver and copper nanoparticles exhibited surface plasmon absorption resonance maxima (SPR) at 416 and 584 nm, respectively; while SPR for the Cu-Ag alloys appeared in between depending on the alloy composition. The SPR maxima for bimetallic nanoparticles changes linearly with increasing copper content in the alloy. Transmission electron micrograph (TEM) showed monodispersed particles in the range of 20 {+-} 5 nm size. Both silver and copper nanoparticles exhibited emission band at 485 and 645 nm, respectively. The starch-stabilized nanoparticles exhibited interesting antibacterial activity with both gram positive and gram negative bacteria at micromolar concentrations.

  8. Energetics of the formation of CuAg coreshell nanoparticles

    DOE PAGES-Beta [OSTI]

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of coreshell CuAg nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a coreshell structure from two previously distinct, non-interacting nanoparticles. In most cases, the coreshell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a coreshell structure forms. In general, it was foundmorethat the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a coreshell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a CuAg interfacial energy, which is always smaller.less

  9. Atomic-scale investigation of interface-facilitated deformation twinning in severely deformed Ag-Cu nanolamellar composites

    SciTech Connect (OSTI)

    An, X. H. E-mail: xiaozhou.liao@sydenye.edu.au; Cao, Y.; Liao, X. Z. E-mail: xiaozhou.liao@sydenye.edu.au; Zhu, S. M.; Nie, J. F.; Kawasaki, M.; Ringer, S. P.; Langdon, T. G.; Zhu, Y. T.

    2015-07-06

    We report an atomic-scale investigation of interface-facilitated deformation twinning behaviour in Ag-Cu nanolamellar composites. Profuse twinning activities in Ag supply partial dislocations to directly transmit across the Ag-Cu lamellar interface that promotes deformation twinning in the neighbouring Cu lamellae although the interface is severely deformed. The trans-interface twin bands change the local structure at the interface. Our analysis suggests that the orientation relationship and interfacial structure between neighbouring Ag-Cu lamellae play a crucial role in such special interface-facilitated twinning behaviour.

  10. Energetics of the formation of Cu-Ag core–shell nanoparticles

    SciTech Connect (OSTI)

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of core–shell Cu-Ag nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a core–shell structure from two previously distinct, non-interacting nanoparticles. In most cases, the core–shell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a core–shell structure forms. In general, it was found that the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a core–shell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a Cu–Ag interfacial energy, which is always smaller.

  11. Energetics of the formation of Cu-Ag core–shell nanoparticles

    DOE PAGES-Beta [OSTI]

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of core–shell Cu-Ag nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a core–shell structure from two previously distinct, non-interacting nanoparticles. In most cases, the core–shell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a core–shell structure forms. In general, it was foundmore » that the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a core–shell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a Cu–Ag interfacial energy, which is always smaller.« less

  12. In-situ TEM study of Cu-Ag nanoparticle thermal interaction. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Conference: In-situ TEM study of Cu-Ag nanoparticle thermal interaction. Citation Details In-Document Search Title: In-situ TEM study of Cu-Ag nanoparticle thermal interaction. Abstract not provided. Authors: Lu, Ping Publication Date: 2013-10-01 OSTI Identifier: 1113336 Report Number(s): SAND2013-8356C 476492 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the Rio Grande symposium held October 7, 2013

  13. Potential energy curves for the ground and low-lying excited states of CuAg

    SciTech Connect (OSTI)

    Alizadeh, Davood; Shayesteh, Alireza E-mail: ashayesteh@ut.ac.ir; Jamshidi, Zahra E-mail: ashayesteh@ut.ac.ir

    2014-10-21

    The ground and low-lying excited states of heteronuclear diatomic CuAg are examined by multi-reference configuration interaction (MRCI) method. Relativistic effects were treated and probed in two steps. Scalar terms were considered using the spin-free DKH Hamiltonian as a priori and spin-orbit coupling was calculated perturbatively via the spin-orbit terms of the Breit-Pauli Hamiltonian based on MRCI wavefunctions. Potential energy curves of the spin-free states and their corresponding Ω components correlating with the separated atom limits {sup 2}S(Cu) + {sup 2}S(Ag) and {sup 2}D(Cu) + {sup 2}S(Ag) are obtained. The results are in fine agreement with the experimental measurements and tentative conclusions for the ion-pair B0{sup +} state are confirmed by our theoretical calculations. Illustrative results are presented to reveal the relative importance and magnitude of the scalar and spin-orbit effects on the spectroscopic properties of this molecule. Time dependent density functional theory calculations, using the LDA, BLYP, B3LYP, and SAOP functionals have been carried out for CuAg and the accuracy of TD-DFT has been compared with ab initio results.

  14. Size and alloying induced shift in core and valence bands of Pd-Ag and Pd-Cu nanoparticles

    SciTech Connect (OSTI)

    Sengar, Saurabh K.; Mehta, B. R.; Govind

    2014-03-28

    In this report, X-ray photoelectron spectroscopy studies have been carried out on Pd, Ag, Cu, Pd-Ag, and Pd-Cu nanoparticles having identical sizes corresponding to mobility equivalent diameters of 60, 40, and 20 nm. The nanoparticles were prepared by the gas phase synthesis method. The effect of size on valence and core levels in metal and alloy nanoparticles has been studied by comparing the values to those with the 60 nm nanoparticles. The effect of alloying has been investigated by comparing the valence and core level binding energies of Pd-Cu and Pd-Ag alloy nanoparticles with the corresponding values for Pd, Ag, and Cu nanoparticles of identical sizes. These effects have been explained in terms of size induced lattice contractions, alloying induced charge transfer, and hybridization effects. The observation of alloying and size induced binding energy shifts in bimetallic nanoparticles is important from the point of view of hydrogen reactivity.

  15. Ag-Pd-Cu alloy inserted transparent indium tin oxide electrodes for organic solar cells

    SciTech Connect (OSTI)

    Kim, Hyo-Joong; Seo, Ki-Won; Kim, Han-Ki; Noh, Yong-Jin; Na, Seok-In

    2014-09-01

    The authors report on the characteristics of Ag-Pd-Cu (APC) alloy-inserted indium tin oxide (ITO) films sputtered on a glass substrate at room temperature for application as transparent anodes in organic solar cells (OSCs). The effect of the APC interlayer thickness on the electrical, optical, structural, and morphological properties of the ITO/APC/ITO multilayer were investigated and compared to those of ITO/Ag/ITO multilayer electrodes. At the optimized APC thickness of 8 nm, the ITO/APC/ITO multilayer exhibited a resistivity of 8.55 × 10{sup −5} Ω cm, an optical transmittance of 82.63%, and a figure-of-merit value of 13.54 × 10{sup −3} Ω{sup −1}, comparable to those of the ITO/Ag/ITO multilayer. Unlike the ITO/Ag/ITO multilayer, agglomeration of the metal interlayer was effectively relieved with APC interlayer due to existence of Pd and Cu elements in the thin region of the APC interlayer. The OSCs fabricated on the ITO/APC/ITO multilayer showed higher power conversion efficiency than that of OSCs prepared on the ITO/Ag/ITO multilayer below 10 nm due to the flatness of the APC layer. The improved performance of the OSCs with ITO/APC/ITO multilayer electrodes indicates that the APC alloy interlayer prevents the agglomeration of the Ag-based metal interlayer and can decrease the thickness of the metal interlayer in the oxide-metal-oxide multilayer of high-performance OSCs.

  16. Photocatalytic performances and activities of Ag-doped CuFe{sub 2}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Zhu, Zhengru; Li, Xinyong; Zhao, Qidong; Li, Yonghua; Sun, Caizhi; Cao, Yongqiang

    2013-08-01

    Graphical abstract: - Highlights: CuFe{sub 2}O{sub 4} nanocrystals were synthesized by a co-precipitation method. Ag/CuFe{sub 2}O{sub 4} catalyst was prepared by the wetness impregnation strategy. The structural properties of Ag/CuFe{sub 2}O{sub 4} were investigated by XRD, TEM, DRS, and XPS techniques. Ag/CuFe{sub 2}O{sub 4} has higher photocatalytic activity. - Abstract: In this work, CuFe{sub 2}O{sub 4} nanoparticles were synthesized by a chemical co-precipitation route. The Ag/CuFe{sub 2}O{sub 4} catalyst was prepared based on the CuFe{sub 2}O{sub 4} nanoparticles by the incipient wetness impregnation strategy, which showed excellent photoelectric property and catalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction (XRD), transmission electronic microscopy (TEM), UVvis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR) techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage (SPV) measurement. The photocatalytic degradation of 4-CP by the Ag/CuFe{sub 2}O{sub 4} and CuFe{sub 2}O{sub 4} samples were comparatively studied under xenon lamp irradiation. The results indicate that the Ag/CuFe{sub 2}O{sub 4} sample exhibited the higher efficiency for the degradation of 4-CP.

  17. Effect of cooling rate on the microstructure and microhardness of the CuZrAgAl alloy

    SciTech Connect (OSTI)

    Liu, Y.; Blandin, J.J.; Suery, M.; Kapelski, G.

    2012-08-15

    The effect of cooling rate on the microstructure and microhardness of the Cu{sub 40}Zr{sub 44}Ag{sub 8}Al{sub 8} (at.%) alloy has been studied. The crystalline phases were characterized by X-ray diffraction, optical microscopy and scanning electron microscopy with energy dispersive X-ray spectroscopy, and identified as AlCu{sub 2}Zr, Cu{sub 10}Zr{sub 7} and CuZr{sub 2}. The solidification sequence was established as following: the Cu{sub 10}Zr{sub 7} phase forms first in the periphery of the rod, then following with AlCu{sub 2}Zr phase in the rod center and finally CuZr{sub 2} crystals in Cu-depleted areas. The effect of crystals on the mechanical properties of the Cu{sub 40}Zr{sub 44}Ag{sub 8}Al{sub 8} alloy was also estimated through the microhardness. According to the value of microhardness, inhomogeneous structure of the amorphous matrix is more easily formed for the alloy in the low cooling rate (i.e., 9 mm) as compared with the alloy with fully amorphous state in the large cooling rate (i.e., 3 mm). This inhomogeneous structure was attributed to the composition change of amorphous matrix arising from the forming of crystalline phases due to the low cooling rate. - Highlights: Black-Right-Pointing-Pointer The crystalline phases in the Cu{sub 40}Zr{sub 44}Ag{sub 8}Al{sub 8} alloy were identified. Black-Right-Pointing-Pointer The solidification sequence of Cu{sub 40}Zr{sub 44}Ag{sub 8}Al{sub 8} alloy was verified. Black-Right-Pointing-Pointer The softening and hardening of alloy could be observed due to the crystallization.

  18. Effect of filler metal composition on the strength of yttria stabilized zirconia joints brazed with Pd-Ag-CuOx

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2008-09-08

    The Ag-CuOx system is of interest to be used to be used as an air braze filler metal for joining high temperature electrochemical devices. Previous work has shown that the melting temperatures can be increased by adding palladium to Ag-CuOx and it is expected that this may aid high temperature stability. This work compares the room temperature bend strength of joints made between yttria-stabilized zirconia (YSZ) air brazed using Ag-CuOx without palladium and with 5 and 15mol% palladium additions. It has been found that in general palladium decreases joint strength, especially in low copper oxide compositions filler metals. At high copper oxide contents, brittle fracture through both copper oxide rich phases and the YSZ limits joint strength.

  19. Enhanced hydrogenation and reduced lattice distortion in size selected Pd-Ag and Pd-Cu alloy nanoparticles

    SciTech Connect (OSTI)

    Sengar, Saurabh K.; Mehta, B. R.; Kulriya, P. K.; Khan, S. A.

    2013-10-21

    Important correlation between valence band spectra and hydrogenation properties in Pd alloy nanoparticles is established by studying the properties of size selected and monocrystalline Pd, Ag, Cu, Pd-Ag, and Pd-Cu nanoparticles. The X-ray photoelectron spectroscopy and elastic recoil detection analysis show that size induced Pd4d centroid shift is related to enhanced hydrogenation with H/Pd ratio of 0.57 and 0.49 in Pd-Ag and Pd-Cu nanoparticles in comparison to reported bulk values of 0.2 and 0.1, respectively. Pd-alloy nanoparticles show lower hydrogen induced lattice distortion. The reduced distortion and higher hydrogen reactivity of Pd-alloy nanoparticles is important for numerous hydrogen related applications.

  20. Structural and magnetic phase transitions in CeCu6-xTx (T = Ag,Pd)

    DOE PAGES-Beta [OSTI]

    Poudel, Lekhanath N.; De la cruz, Clarina; Payzant, E. Andrew; Koehler, Michael R.; May, Andrew F.; Garlea, Vasile O.; Taylor, Alice E.; Parker, David S.; Cao, Huibo B.; McGuire, Michael A.; et al

    2015-12-15

    The structural and the magnetic properties of CeCu6-xAgx (0 ≤ x ≤ 0.85) and CeCu6-xPdx (0 ≤ x ≤ 0.4) have been studied using neutron diffraction, resonant ultrasound spectroscopy (RUS), x-ray diffraction measurements, and first principles calculations. The structural and magnetic phase diagrams of CeCu6-xAgx and CeCu6-xPdx as a function of Ag/Pd composition are reported. The end member, CeCu6, undergoes a structural phase transition from an orthorhombic (Pnma) to a monoclinic (P21/c) phase at 240 K. In CeCu6-xAgx, the structural phase transition temperature (Ts) decreases linearly with Ag concentration and extrapolates to zero at xS ≈ 0.1. The structural transitionmore » in CeCu6-xPdx remains unperturbed with Pd substitution within the range of our study. The lattice constant b slightly decreases with Ag/Pd doping, whereas a and c increase with an overall increase in the unit cell volume. Both systems, CeCu6-xAgx and CeCu6-xPdx, exhibit a magnetic quantum critical point (QCP), at x ≈ 0.2 and x ≈ 0.05, respectively. Near the QCP, long range antiferromagnetic ordering takes place at an incommensurate wave vector (δ1 0 δ2), where δ1 ~ 0.62, δ2 ~ 0.25, x = 0.125 for CeCu6-xPdx and δ1 ~ 0.64, δ2 ~ 0.3, x = 0.3 for CeCu6-xAgx. As a result, the magnetic structure consists of an amplitude modulation of the Ce moments which are aligned along the c axis of the orthorhombic unit cell.« less

  1. Structural and optical properties of (Ag,Cu)(In,Ga)Se{sub 2} polycrystalline thin film alloys

    SciTech Connect (OSTI)

    Boyle, J. H.; Shafarman, W. N.; Birkmire, R. W.; McCandless, B. E.

    2014-06-14

    The structural and optical properties of pentenary alloy (Ag,Cu)(In,Ga)Se{sub 2} polycrystalline thin films were characterized over the entire compositional range at a fixed (Cu + Ag)/(In + Ga) ratio. Films deposited at 550 °C on bare and molybdenum coated soda-lime glass by elemental co-evaporation in a single-stage process with constant incident fluxes exhibit single phase chalcopyrite structure, corresponding to 122 spacegroup (I-42d) over the entire compositional space. Unit cell refinement of the diffraction patterns show that increasing Ag substitution for Cu, the refined a{sub o} lattice constant, (Ag,Cu)-Se bond length, and anion displacement increase in accordance with the theoretical model proposed by Jaffe, Wei, and Zunger. However, the refined c{sub o} lattice constant and (In,Ga)-Se bond length deviated from theoretical expectations for films with mid-range Ag and Ga compositions and are attributed to influences from crystallographic bond chain ordering or cation electronegativity. The optical band gap, derived from transmission and reflection measurements, widened with increasing Ag and Ga content, due to influences from anion displacement and cation electronegativity, as expected from theoretical considerations for pseudo-binary chalcopyrite compounds.

  2. Efficient enhancement of hydrogen production by Ag/Cu{sub 2}O/ZnO tandem triple-junction photoelectrochemical cell

    SciTech Connect (OSTI)

    Liu, Ying; Ren, Feng Chen, Chao; Liu, Chang; Xing, Zhuo; Liu, Dan; Xiao, Xiangheng; Wu, Wei; Zheng, Xudong; Liu, Yichao; Jiang, Changzhong; Shen, Shaohua; Fu, Yanming

    2015-03-23

    Highly efficient semiconductor photoelectrodes for solar hydrogen production through photocatalytic water splitting are a promising and challenge solution to solve the energy problems. In this work, Ag/Cu{sub 2}O/ZnO tandem triple-junction photoelectrode was designed and prepared. An increase of 11 times of photocurrent is achieved in the Ag/Cu{sub 2}O/ZnO photoelectrode comparing to that of the Cu{sub 2}O film. The high performance of the Ag/Cu{sub 2}O/ZnO film is due to the optimized design of the tandem triple-junction structure, where the localized surface Plasmon resonance of Ag and the hetero-junctions efficiently absorb solar energy, produce, and separate electron-hole pairs in the photocathode.

  3. THE ELECTRONIC STRUCTURE OF AG/CU(100) SURFACE ALLOYS STUDIES BY AUGER-PHOTOELECTRON COINCIDENCE SPECTROSCOPY.

    SciTech Connect (OSTI)

    ARENA,D.A.; BARTYNSKI,R.A.; HULBERT,S.L.

    2001-10-08

    We have measured the Ag and Pd M{sub 5}VV Auger spectrum in coincidence with Ag and Pd 4d{sub 5/2} photoelectrons for the Ag/Cu(100) and Pd/Cu(100) systems, respectively, as a function of admetal coverage. These systems form surface alloys (i.e. random substitutional alloys in the first atomic layer) for impurity concentrations in the 0.1 monolayer range. For these systems, the centroid of the impurity 4d levels is expected to shift away from the Fermi level by {approx}1 eV [Ruban et al., Journal of Molecular Catalysis. A 115 (1997) 421], an effect that should be easily seen in coincidence core-valence-valence Auger spectra. We find that the impurity Auger spectra of both systems shift in a manner that is consistent with d-band moving away from EF. However, the shift for Pd is considerably smaller than expected, and a shift almost absent for Ag. The disagreement between theory and experiment is most likely caused by the neglect of lattice relaxations in the calculations.

  4. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    SciTech Connect (OSTI)

    Endrino, Jose L.; Horwat, David; Gago, Raul; Andersson, Joakim; Liu, Y.S.; Guo, Jinghua; Anders, Andre

    2008-05-14

    In this work, we study the influence of the incorporation of different metals (Me = Au, Ag, Cu, Mo) on the electronic structure of amorphous carbon (a-C:Me) films. The films were produced at room temperature using a novel pulsed dual-cathode arc deposition technique. Compositional analysis was performed with secondary neutral mass spectroscopy whereas X-ray diffraction was used to identify the formation of metal nanoclusters in the carbon matrix. The metal content incorporated in the nanocomposite films induces a drastic increase in the conductivity, in parallel with a decrease in the band gap corrected from Urbach energy. The electronic structure as a function of the Me content has been monitored by x-ray absorption near edge structure (XANES) at the C K-edge. XANES showed that the C host matrix has a dominant graphitic character and that it is not affected significantly by the incorporation of metal impurities, except for the case of Mo, where the modifications in the lineshape spectra indicated the formation of a carbide phase. Subtle modifications of the spectral lineshape are discussed in terms of nanocomposite formation.

  5. Structural and magnetic phase transitions in CeCu6-xTx (T = Ag,Pd)

    SciTech Connect (OSTI)

    Poudel, Lekhanath N.; De la cruz, Clarina; Payzant, E. Andrew; Koehler, Michael R.; May, Andrew F.; Garlea, Vasile O.; Taylor, Alice E.; Parker, David S.; Cao, Huibo B.; McGuire, Michael A.; Tian, Wei; Matsuda, Masaaki; Jeen, Hyoung Jeen; Lee, Ho Nyung; Hong, Tao; Calder, Stuart A.; Lumsden, Mark D.; Zhou, Haidong; Keppens, Veerle; Mandrus, D.; Christianson, Andrew D.

    2015-12-15

    The structural and the magnetic properties of CeCu6-xAgx (0 ≤ x ≤ 0.85) and CeCu6-xPdx (0 ≤ x ≤ 0.4) have been studied using neutron diffraction, resonant ultrasound spectroscopy (RUS), x-ray diffraction measurements, and first principles calculations. The structural and magnetic phase diagrams of CeCu6-xAgx and CeCu6-xPdx as a function of Ag/Pd composition are reported. The end member, CeCu6, undergoes a structural phase transition from an orthorhombic (Pnma) to a monoclinic (P21/c) phase at 240 K. In CeCu6-xAgx, the structural phase transition temperature (Ts) decreases linearly with Ag concentration and extrapolates to zero at xS ≈ 0.1. The structural transition in CeCu6-xPdx remains unperturbed with Pd substitution within the range of our study. The lattice constant b slightly decreases with Ag/Pd doping, whereas a and c increase with an overall increase in the unit cell volume. Both systems, CeCu6-xAgx and CeCu6-xPdx, exhibit a magnetic quantum critical point (QCP), at x ≈ 0.2 and x ≈ 0.05, respectively. Near the QCP, long range antiferromagnetic ordering takes place at an incommensurate wave vector (δ1 0 δ2), where δ1 ~ 0.62, δ2 ~ 0.25, x = 0.125 for CeCu6-xPdx and δ1 ~ 0.64, δ2 ~ 0.3, x = 0.3 for CeCu6-xAgx. As a result, the magnetic structure consists of an amplitude modulation of the Ce moments which are aligned along the c axis of the orthorhombic unit cell.

  6. Ab initio study of MXe{sub n}{sup +} (M=Cu, Ag, and Au; n=1,2)

    SciTech Connect (OSTI)

    Li Xinying; Cao Xue

    2008-02-15

    The equilibrium geometries, vibrational frequencies, dissociation energies, and populations of the title species were studied at Hartree-Fock (HF), second-order Moeller-Plesset (MP2), and coupled-cluster singles-doubles (triples) [CCSD(T)] levels. The electron correlation effects and relativistic effects on the geometry and stability were investigated at the CCSD(T) level. Both effects stabilize title species. The populations analyses show that M-Xe bonding is dominated by electrostatic interactions and the best theoretical estimate of the dissociation energies are 1.104 and 2.260 eV for AuXe{sup +} and AuXe{sub 2}{sup +}, respectively. The Cu and Ag are weakly bonded to Xe compared to Au.

  7. ESR of Gd{sup 3+} in the Kondo-lattice compound YbAgCu{sub 4} and its reference compounds RAgCu{sub 4} (R=Y,Lu)

    SciTech Connect (OSTI)

    Pagliuso, P.G.; Rettori, C.; Oseroff, S.B.; Sarrao, J.; Fisk, Z.; Cornelius, A.; Hundley, M.F.

    1997-10-01

    Low-temperature (T{lt}30thinspK) electron-spin-resonance (ESR) experiments of Gd{sup 3+} diluted in the Kondo-lattice compound YbAgCu{sub 4} and its reference compounds YAgCu{sub 4} and LuAgCu{sub 4} are interpreted in terms of an enhanced density of states at the Fermi level for the Yb-based compound. The results of susceptibility and ESR (Korringa rate and g-shift) measurements show negligible electron-electron exchange enhancement for all the studied compounds. The exchange interaction between the Gd{sup 3+} local moment and the conduction electrons (c-e) is c-e wave vector dependent in all three compounds. {copyright} {ital 1997} {ital The American Physical Society}

  8. Quench degradation limit of multifilamentary AgBi2Sr2CaCu2Ox round wires

    DOE PAGES-Beta [OSTI]

    Ye, Liyang; Li, Pei; Shen, Tengming; Schwartz, Justin

    2016-02-02

    Understanding safe operating limits of composite superconducting wires is important for the design of superconducting magnets. Here we report measurements of quench-induced critical current density Jc degradation in commercial Ag/Bi2Sr2CaCu2Ox (Bi-2212) round wires using heater-induced quenches at 4.2 K in self magnetic field that reveal a general degradation behavior. Jc degradation strongly depends on the local hot spot temperature Tmax, and is nearly independent of operating current, the temperature gradient along the conductor dTmax/dx, and the temperature rising rate dTmax/dt. Both Jc and n value (where n is an index of the sharpness of the superconductor-to-normal transition) exhibit small butmore » irreversible degradation when Tmax exceeds 400-450 K, and large degradation occurs when Tmax exceeds 550 K. This behavior was consistently found for a series of Bi-2212 wires with widely variable wire architectures and porosity levels in the Bi-2212 filaments, including a wire processed using a standard partial melt processing and in which Bi-2212 filaments are porous, an overpressure processed wire in which Bi-2212 filaments are nearly porosity-free and that has a Jc(4.2 K, self field) exceeding 8000 A/mm2, and a wire that has nearly no filament to filament bridges after reaction. Microstructural observations of degraded wires reveal cracks in the Bi-2212 filaments perpendicular to the wire axis, indicating that the quench-induced Ic degradation is primarily driven by strain. These results further suggest that the quench degradation temperature limit depends on the strain state of Bi-2212 filaments and this dependence shall be carefully considered when engineering a high-field Bi-2212 magnet.« less

  9. Photoelectron imaging and theoretical study on the structure and chemical binding of the mixed-ligand M(I) complexes, [HMSH]{sup ?} (M = Cu, Ag, and Au)

    SciTech Connect (OSTI)

    Qin, Zhengbo; Liu, Zhiling; Cong, Ran; Xie, Hua; Tang, Zichao, E-mail: zctang@dicp.ac.cn, E-mail: fanhj@dicp.ac.cn; Fan, Hongjun, E-mail: zctang@dicp.ac.cn, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)

    2014-03-21

    We have reported a combined photoelectron imaging and theoretical study on gaseous mixed-ligand M(I) complexes of [HMSH]{sup ?} (M = Cu, Ag, and Au). With the aid of Franck-Condon simulations, vibrationally resolved photoelectron spectra yield accurate electron affinities of 3.269(6), 3.669(10), and 3.591(6) eV for [HCuSH], [HAgSH], and [HAuSH], respectively. And low-frequency modes are observed: 368(12) cm{sup ?1} for [HCuSH], 286(12) cm{sup ?1} for [HAgSH], and 327(12) cm{sup ?1} for [HAuSH], respectively. Extensive theoretical calculations are performed to aid in the spectral assignments and the calculated values agree well with the experimental observations. Although the S and H atoms have little discrepancy in electronegativity (2.20 for H and 2.54 for S), distinct bonding properties are demonstrated between HM and MS bond. It is revealed that there exists significant ionic bonding between MS in [HMSH]{sup ?} (M = Cu, Ag, and Au), while a gradual transition from ionic behavior between HCu in [HCuSH]{sup ?} to quite strong covalent bonding between HAu in [HAuSH]{sup ?}, supported by a variety of chemical bonding analyses.

  10. Microstructure of Co/X (X=Cu,Ag,Au) epitaxial thin films grown on Al{sub 2}O{sub 3}(0001) substrates

    SciTech Connect (OSTI)

    Ohtake, Mitsuru; Akita, Yuta; Futamoto, Masaaki; Kirino, Fumiyoshi

    2007-05-01

    Epitaxial thin films of Co/X (X=Cu,Ag,Au) were prepared on Al{sub 2}O{sub 3}(0001) substrates at substrate temperatures of 100 and 300 degree sign C by UHV molecular beam epitaxy. A complicated microstructure was realized for the epitaxial thin films. In-situ reflection high-energy electron diffraction observation has shown that X atoms of the buffer layer segregated to the surface during Co layer deposition, and it yielded a unique epitaxial granular structure. The structure consists of small Co grains buried in the X buffer layer, where both the magnetic small Co grains and the nonmagnetic X layer are epitaxially grown on the single crystal substrate. The structure varied depending on the X element and the substrate temperature. The crystal structure of Co grains is influenced by the buffer layer material and determined to be hcp and fcc structures for the buffer layer materials of Au and Cu, respectively.

  11. Cu

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Cu rre n t Ge n e ratio n Lo w En e rg y Cro s s Se c tio n Me as u re m e n ts : Sc iBar an d Min iBo o NE MiniBooNE Beam ➢ 8 GeV protons on Be target ➢ <E ν > = 0.7 GeV ➢ Change horn polarity for ν, ν modes Detector ➢ 12 m diameter, 800 ton mineral oil (CH 2 ) tank ➢ 1280 inner PMTs, 240 veto PMTs ➢ Events produce prompt Cherenkov light and delayed, isotropic scintillation light ➢ A " subevent" is cluster of tank activity in time ν µ µ - e - e + π + µ + K2

  12. Spin and orbital magnetism of coinage metal trimers (Cu{sub 3}, Ag{sub 3}, Au{sub 3}): A relativistic density functional theory study

    SciTech Connect (OSTI)

    Afshar, Mahdi; Sargolzaei, Mohsen

    2013-11-15

    We have demonstrated electronic structure and magnetic properties of Cu{sub 3}, Ag{sub 3} and Au{sub 3} trimers using a full potential local orbital method in the framework of relativistic density functional theory. We have also shown that the non-relativistic generalized gradient approximation for the exchange-correlation energy functional gives reliable magnetic properties in coinage metal trimers compared to experiment. In addition we have indicated that the spin-orbit coupling changes the structure and magnetic properties of gold trimer while the structure and magnetic properties of copper and silver trimers are marginally affected. A significant orbital moment of 0.21μ{sub B} was found for most stable geometry of the gold trimer whereas orbital magnetism is almost quenched in the copper and silver trimers.

  13. Spin and orbital magnetism of coinage metal trimers (Cu{sub 3}, Ag{sub 3}, Au{sub 3}): A relativistic density functional theory study

    SciTech Connect (OSTI)

    Afshar, Mahdi; Sargolzaei, Mohsen

    2013-11-15

    We have demonstrated electronic structure and magnetic properties of Cu{sub 3}, Ag{sub 3} and Au{sub 3} trimers using a full potential local orbital method in the framework of relativistic density functional theory. We have also shown that the non-relativistic generalized gradient approximation for the exchange-correlation energy functional gives reliable magnetic properties in coinage metal trimers compared to experiment. In addition we have indicated that the spin-orbit coupling changes the structure and magnetic properties of gold trimer while the structure and magnetic properties of copper and silver trimers are marginally affected. A significant orbital moment of 0.21?{sub B} was found for most stable geometry of the gold trimer whereas orbital magnetism is almost quenched in the copper and silver trimers.

  14. Joining of zirconia ceramic to stainless steel and to itself using Ag{sub 57}Cu{sub 38}Ti{sub 5} filler metal

    SciTech Connect (OSTI)

    Hao, H.; Wang, Y.; Jin, Z.; Wang, X.

    1995-08-01

    The brazing of ZrO{sub 2} ceramic to 1Cr18Ni9Ti stainless steel and to itself was performed using Ag{sub 57}Cu{sub 38}Ti{sub 5} filler metal under a vacuum of t {times} 10{sup {minus}3} Pa. The effects o9f interlayer copper on the ceramic to stainless steel joint strength, and the brazing temperature (1,073 to 1,323 K) and holding time (0 to 60 min) on ceramic to ceramic joint strength were investigated. The joint strength was evaluated by shear testing. An interfacial reaction layer between the ceramic and the filler metal was found, and the reaction products were {delta}-TiO and {gamma}-AgTi{sub 3}. The joint strength of ZrO{sub 2} ceramic to stainless steel was improved by using a layer of copper of a suitable thickness. The brazing temperature and holding time had a strong influence on the joint strength of ceramic time had a strong influence on the joint strength of ceramic to ceramic, and the joint strength was mainly controlled by reaction layer thickness and the properties of the reaction products. The maximum shear strength was obtained for brazing at 1,123 K for 30 min and an interfacial reaction layer thickness of {approximately}4.4 {micro}m.

  15. Synthesis and catalytic application of nanofibrous La{sub 0.9}A{sub 0.1}MnO{sub 3} (A = Ca, Cu, Ag) with macroscopic shapes

    SciTech Connect (OSTI)

    Wu, Qiang Zhao, Li; Wu, Jiang; Yao, Weifeng

    2013-10-15

    Graphical abstract: Fabrication of nanofibrous La{sub 0.9}A{sub 0.1}MnO{sub 3} (A = Ca, Cu, Ag) perovskite-type oxides with macroscopic shapes was successfully obtained using carbon nanofibers (CNFs) as templates. Furthermore, their application for the combustion of carbon black (CB), which is a model of particulate matter exhausted from diesel engines, was demonstrated. - Highlights: Nanofibrous La{sub 0.9}A{sub 0.1}MnO{sub 3} with macroscopic shapes was successfully obtained. CNFs template method used here is facile, effective and reproducible. The obtained materials show superior catalytic activity in soot combustion. The catalytic order is La{sub 0.9}Ag{sub 0.1}MnO{sub 3} > La{sub 0.9}Cu{sub 0.1}MnO{sub 3} > La{sub 0.9}Ca{sub 0.1}MnO{sub 3}. - Abstract: Fabrication of nanofibrous La{sub 0.9}A{sub 0.1}MnO{sub 3} (A = Ca, Cu, Ag) perovskite-type oxides with macroscopic shapes can be successfully obtained by using CNFs as templates. Field emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) analysis confirmed the template effect and formation of nanofibrous perovskite-type oxides on macroscopic silica fiber. It turned out that it is reliable to control the desired single-phase La{sub 0.9}A{sub 0.1}MnO{sub 3} (A = Ca, Cu, Ag) perovskite-type oxides formation by tuning the corresponding metal ratio during preparation process. Furthermore, it showed that the as-prepared nanofibrous La{sub 0.9}A{sub 0.1}MnO{sub 3} (A = Ca, Cu, Ag) perovskite-type oxides can greatly decrease the combustion temperature of nanosized carbon black particles, and follows the order of La{sub 0.9}Ag{sub 0.1}MnO{sub 3} > La{sub 0.9}Cu{sub 0.1}MnO{sub 3} > La{sub 0.9}Ca{sub 0.1}MnO{sub 3}, indicating their high potential application prospects in diesel soot particles treatment.

  16. Ce{sub 2}AgYb{sub 5/3}Se{sub 6}, La{sub 2}CuErTe{sub 5}, and Ce{sub 2}CuTmTe{sub 5}: Three new quaternary interlanthanide chalcogenides

    SciTech Connect (OSTI)

    Babo, Jean-Marie; Albrecht-Schmitt, Thomas E.

    2013-01-15

    Three new ordered quaternary interlanthanide chalcogenides, Ce{sub 2}AgYb{sub 5/3}Se{sub 6}, La{sub 2}CuErTe{sub 5}, and Ce{sub 2}CuTmTe{sub 5}, have been prepared by direct reaction of the elements in molten NaBr at 900 Degree-Sign C. Each compound forms a new structure-type. The Ce{sub 2}AgYb{sub 5/3}Se{sub 6} structure consists of {infinity}{sup 2}{l_brace} [AgYb{sub 5/6}Se{sub 6}]{sup 6-}{r_brace} layers intercalated by Ce{sup 3+} cations. These layers are composed of {infinity}{sup 1}{l_brace} [Yb{sub 5/3}Se{sub 6}]{sup 7-}{r_brace} quadruplet ribbons of [YbSe{sub 6}]{sup 9-} octahedra and infinite {infinity}{sup 1}{l_brace} [AgSe{sub 6}]{sup 11-}{r_brace} double chains of [AgSe{sub 5}]{sup 9-}. The La{sub 2}CuErTe{sub 5} structure is made of one-dimensional {infinity}{sup 1}{l_brace} [CuErTe{sub 5}]{sup 6-}{r_brace} ribbons separated by La{sup 3+} cations. These ribbons are formed by cis-edge sharing {infinity}{sup 1}{l_brace} [CuTe{sub 2}]{sup 3-}{r_brace} tetrahedral chains and trans-edge sharing {infinity}{sup 1}{l_brace} [ErTe{sub 4}]{sup 5-}{r_brace} chains. While La{sub 2}CuErTe{sub 5} crystallizes in the orthorhombic space group Pnma, Ce{sub 2}CuTmTe{sub 5} crystallizes in the monoclinic space group C2/m. The latter crystal structure is assembled from {infinity}{sup 2}{l_brace} [CuTmTe{sub 5}]{sup 6-}{r_brace} layers intercalated by Ce{sup 3+} cations. These layers consist of single {infinity}{sup 1}{l_brace} [TmTe{sub 4}]{sup 5-}{r_brace} chains connected to each other through dimers or pseudo-double chains. - Graphical abstract: [CuTe{sub 4}]{sup 7-} tetrahedra sharing cis-edges to yield chains in the La{sub 2}CuErTe{sub 5}. Highlights: Black-Right-Pointing-Pointer New ordered interlanthanide tellurides. Black-Right-Pointing-Pointer New quaternary chalcogenides. Black-Right-Pointing-Pointer Low-dimensional lanthanide chalcogenide substructures. Black-Right-Pointing-Pointer Flux synthesis of new chalcogenides.

  17. SolarDS | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    fy10osti45832.pdf Language: English References: SolarDS1 Logo: SolarDS The Solar Deployment System (SolarDS) model evaluates the potential market penetration of solar...

  18. The problem of intermixing of metals possessing no mutual solubility upon explosion welding (Cu-Ta, Fe-Ag, Al-Ta)

    SciTech Connect (OSTI)

    Greenberg, B.A.; Ivanov, M.A.; Rybin, V.V.; Elkina, O.A.; Antonova, O.V.; Patselov, A.M.; Inozemtsev, A.V.; Plotnikov, A.V.; Volkova, A.Yu.; Besshaposhnikov, Yu.P.

    2013-01-15

    On the basis of the results obtained for joints of dissimilar metals such as copper-tantalum and iron-silver, the reason of immiscible suspensions mixing upon explosion welding has been cleared out. It has been found that the interface (plain or wavy) is not smooth and contains inhomogeneities, namely, cusps and local melting zones. The role of granulating fragmentation providing partitioning of initial materials as a main channel of input energy dissipation has been revealed. It has been shown that in joints of metals possessing normal solubility the local melting zones are true solutions, but if metals possess no mutual solubility the local melting zones are colloidal solutions. Realization of either emulsion or suspension variant takes place. The results can be used in the development of new joints of metals possessing no mutual solubility. - Highlights: Black-Right-Pointing-Pointer Immiscible pairs Ta/Cu and Fe/Ag are welded successfully by explosive welding. Black-Right-Pointing-Pointer Fragmentation provides for partitioning as the main energy dissipation channel. Black-Right-Pointing-Pointer Immiscible metals form colloidal solid solutions during solidification. Black-Right-Pointing-Pointer Melting and boiling temperatures ratio determines the colloidal solution type. Black-Right-Pointing-Pointer Local melting zones being in suspension form enhance welds hardening.

  19. Determining conductivity and mobility values of individual components in multiphase composite Cu{sub 1.97}Ag{sub 0.03}Se

    SciTech Connect (OSTI)

    Day, Tristan W.; Brown, David R.; Snyder, G. Jeffrey; Zeier, Wolfgang G.; Melot, Brent C.

    2014-10-27

    The intense interest in phase segregation in thermoelectrics as a means to reduce the lattice thermal conductivity and to modify the electronic properties from nanoscale size effects has not been met with a method for separately measuring the properties of each phase assuming a classical mixture. Here, we apply effective medium theory for measurements of the in-line and Hall resistivity of a multiphase composite, in this case Cu{sub 1.97}Ag{sub 0.03}Se. The behavior of these properties with magnetic field as analyzed by effective medium theory allows us to separate the conductivity and charge carrier mobility of each phase. This powerful technique can be used to determine the matrix properties in the presence of an unwanted impurity phase, to control each phase in an engineered composite, and to determine the maximum carrier concentration change by a given dopant, making it the first step toward a full optimization of a multiphase thermoelectric material and distinguishing nanoscale effects from those of a classical mixture.

  20. Microstructural Development and Mechanical Properties for Reactive Air Brazing of ZTA to Ni Alloys using Ag-CuO Braze Alloys

    SciTech Connect (OSTI)

    Prevost, Erica; DeMarco, A.Joseph; MacMichael, Beth; Joshi, Vineet V.; Meier, Alan; Hoffman, John W.; Walker, William J.

    2014-12-01

    Reactive air brazing (RAB) is a potential joining technique to join metal alloys to ceramics for a variety of applications. In the current study, nickel (Ni) alloys were heat treated to form an oxide layer prior to RAB joining to zirconia toughened alumina (ZTA). The Ni alloys evaluated were Nicrofer 6025 HT, Inconel 600, Inconel 693, Haynes 214 and Inconel 601. The ZTA studied had compositions of 0 to 15 wt% zirconia and 0 to 14 wt% glass. Four point-bend tests were performed to evaluate the joint strength of ZTA/ZTA and ZTA/nickel alloys brazed with Ag-2wt% CuO braze alloys. It was determined that the joint strength is not a function of the ZTA composition, but that the strength is a strong function of the chemistry and microstructure of the oxide layer formed on the nickel alloy. It was determined that an increase in the aluminum content of the Ni alloy resulted in an increase of the thickness of alumina in the oxide layer and was directly proportional to the bond strength with the exception of Inconel 601 which exhibited relatively high joint strengths even though it had a relatively low aluminum content.

  1. Low-cost spray-processed Ag{sub 1−x}Cu{sub x}InS{sub 2} nano-films: Structural and functional investigation within the Lattice Compatibility Theory framework

    SciTech Connect (OSTI)

    Gherouel, D.; Yumak, A.; Znaidi, M.; Bouzidi, A.; Boubaker, K.; Yacoubi, N.; Amlouk, M.

    2015-08-15

    Highlights: • Cu{sub x}Ag{sub 1−x}InS{sub 2} with a minimal lattice mismatch between absorbers and buffers. • The lattice compatibility for understanding silver–copper kinetics. • Controlled and enhanced spray pyrolisis method as a low-cost synthesis protocol. - Abstract: This work deals with some structural and optical investigations about Cu{sub x}Ag{sub 1−x}InS{sub 2} alloys sprayed films and the beneficial effect of copper incorporation in AgInS{sub 2} ternary matrices. The main purpose of this work is to obtain the band gap energy E{sub g} as well as different lattice parameters. The studied properties led to reaching minimum of lattice mismatch between absorber and buffer layers within solar cell devices. As a principal and original finding, the lattice compatibility between both silver and copper indium disulfide structures has been proposed as a guide for understanding kinetics of these materials crystallization.

  2. Schottky barrier height measurements of Cu/Si(001), Ag/Si(001), and Au/Si(001) interfaces utilizing ballistic electron emission microscopy and ballistic hole emission microscopy

    SciTech Connect (OSTI)

    Balsano, Robert; Matsubayashi, Akitomo; LaBella, Vincent P.

    2013-11-15

    The Schottky barrier heights of both n and p doped Cu/Si(001), Ag/Si(001), and Au/Si(001) diodes were measured using ballistic electron emission microscopy and ballistic hole emission microscopy (BHEM), respectively. Measurements using both forward and reverse ballistic electron emission microscopy (BEEM) and (BHEM) injection conditions were performed. The Schottky barrier heights were found by fitting to a linearization of the power law form of the Bell-Kaiser BEEM model. The sum of the n-type and p-type barrier heights are in good agreement with the band gap of silicon and independent of the metal utilized. The Schottky barrier heights are found to be below the region of best fit for the power law form of the BK model, demonstrating its region of validity.

  3. Method of quantitating dsDNA

    DOE Patents [OSTI]

    Stark, Peter C.; Kuske, Cheryl R.; Mullen, Kenneth I.

    2002-01-01

    A method for quantitating dsDNA in an aqueous sample solution containing an unknown amount of dsDNA. A first aqueous test solution containing a known amount of a fluorescent dye-dsDNA complex and at least one fluorescence-attenutating contaminant is prepared. The fluorescence intensity of the test solution is measured. The first test solution is diluted by a known amount to provide a second test solution having a known concentration of dsDNA. The fluorescence intensity of the second test solution is measured. Additional diluted test solutions are similarly prepared until a sufficiently dilute test solution having a known amount of dsDNA is prepared that has a fluorescence intensity that is not attenuated upon further dilution. The value of the maximum absorbance of this solution between 200-900 nanometers (nm), referred to herein as the threshold absorbance, is measured. A sample solution having an unknown amount of dsDNA and an absorbance identical to that of the sufficiently dilute test solution at the same chosen wavelength is prepared. Dye is then added to the sample solution to form the fluorescent dye-dsDNA-complex, after which the fluorescence intensity of the sample solution is measured and the quantity of dsDNA in the sample solution is determined. Once the threshold absorbance of a sample solution obtained from a particular environment has been determined, any similarly prepared sample solution taken from a similar environment and having the same value for the threshold absorbance can be quantified for dsDNA by adding a large excess of dye to the sample solution and measuring its fluorescence intensity.

  4. Investigation of electrochemical migration on Sn-0.7Cu-0.3Ag-0.03P-0.005Ni solder alloy in HNO{sub 3} solution

    SciTech Connect (OSTI)

    Sarveswaran, C.; Othman, N. K.; Ali, M. Yusuf Tura; Ani, F. Che; Samsudin, Z.

    2015-09-25

    Current issue in lead-free solder in term of its reliability is still under investigation. This high impact research attempts to investigate the electrochemical migration (ECM) on Sn-0.7Cu-0.3Ag-0.03P-0.005Ni solder alloy by Water Drop Test (WDT) in different concentration of HNO{sub 3} solution. The concentration of HNO{sub 3} solution used in this research was 0.05, 0.10, 0.50 and 1M. Optical Microscope (OM), Field Emission Scanning Electron Microscope (FESEM) and Energy Dispersive X-Ray Analysis (EDX) were carried out in order to analysis the ECM behavior based on the growth of dendrite formation after WDT. In general, the results demonstrated that dendrite growth is faster in higher concentration compared with low concentration of HNO{sub 3}. The concentration of HNO{sub 3} solution used has a strong correlation with Mean-Time-To-Failure (MTTF). As the concentration of HNO{sub 3} increases, the MTTF value decreases. Based on the MTTF results the solder alloy in 1M HNO{sub 3} solution is most susceptible to ECM. SnO{sub 2} forms as a corrosion by-product in the samples proved by EDX analysis. The solder alloy poses a high reliability risk in microelectronic devices during operation in 1M HNO{sub 3} solution.

  5. Temperature, pressure, and size dependence of Pd-H interaction in size selected Pd-Ag and Pd-Cu alloy nanoparticles: In-situ X-ray diffraction studies

    SciTech Connect (OSTI)

    Sengar, Saurabh K.; Mehta, B. R.; Kulriya, P. K.

    2014-03-21

    In this study, in-situ X-ray diffraction has been carried out to investigate the effect of temperature and pressure on hydrogen induced lattice parameter variation in size selected Pd-Ag and Pd-Cu alloy nanoparticles. The nanoparticles of three different mobility equivalent diameters (20, 40, and 60 nm) having a narrow size distribution were prepared by gas phase synthesis method. In the present range of temperature (350 K to 250 K) and pressure (10{sup −4} to 100 millibars), no α (H/Pd ≤ 0.03) ↔ β (H/Pd ≥ 0.54) phase transition is observed. At temperature higher than 300 °C or pressure lower than 25 millibars, there is a large difference in the rate at which lattice constant varies as a function of pressure and temperature. Further, the lattice variation with temperature and pressure is also observed to depend upon the nanoparticle size. At lower temperature or higher pressure, size of the nanoparticle seems to be relatively less important. These results are explained on the basis of the relative dominance of physical absorption and diffusion of H in Pd alloy nanoparticles at different temperature and pressure. In the present study, absence of α ↔ β phase transition points towards the advantage of using Pd-alloy nanoparticles in applications requiring long term and repeated hydrogen cycling.

  6. Synthesis and characterization of [Yb(NH{sub 3}){sub 8}][Cu(S{sub 4}){sub 2}]{center_dot}NH{sub 3}, [Yb(NH{sub 3}){sub 8}][Ag(S{sub 4}){sub 2}]{center_dot}2NH{sub 3}, and [La(NH{sub 3}){sub 9}][Cu(S{sub 4}){sub 2}] in supercritical ammonia: Metal sulfide salts of the first homoleptic lanthanide ammine complexes

    SciTech Connect (OSTI)

    Young, D.M.; Schimek, G.L.; Kolis, J.W.

    1996-12-18

    Three new lanthanide metal polysulfides have been synthesized in supercritical ammonia: [Yb(NH{sub 3}){sub 8}][Cu(S{sub 4}){sub 2}]{center_dot} NH{sub 3} (I), [Yb(NH{sub 3}){sub 8}][Ag(S{sub 4}){sub 2}]{center_dot}2NH{sub 3} (II), [La(NH{sub 3}){sub 9}][Cu(S{sub 4}){sub 2}] (III). Compounds were prepared in sealed quartz tubes which were filled to one-third volume with liquid ammonia and heated at 170 {degrees}C for 3 days. Compounds I and II were obtained from the reaction of a premade ytterbium polysulfide with M and S in the ratio of 1:1:4, while [La(NH{sub 3}){sub 9}][Cu(S{sub 4}){sub 2}], III, was obtained by reacting La, Cu and S in the ratio of 1:1:8. In all these compounds, the lanthanide cation is coordinated only by ammonia, while the M{sup +} is chelated by S{sub 4}{sup 2-} to form metal tetrasulfide rings. [Yb(NH{sub 3}){sub 8}][Cu(S{sub 4}){sub 2}]{center_dot}NH{sub 3} and [Yb(NH{sub 3}){sub 8}][Ag(S{sub 4}){sub 2}]{center_dot}2NH{sub 3} contain [M(S{sub 4}){sub 2}]{sup 3-} anionic units with M{sup +} in a distorted tetrahedral coordination environment chelated by two S{sub 4}{sup 2-} groups. Compound III, [La(NH{sub 3}){sub 9}][Cu-(S{sub 4}){sub 2}], also contains anionic [Cu (S{sub 4}){sub 2}]{sup 3-} units; however, Cu{sup +} is in a trigonal planar coordination geometry due to the presence of one monodentate S{sub 4}{sup 2-}. All the compounds are unstable with respect to loss of ammonia, and decomposition yielded known ternary and binary phases.

  7. Positive Parity $D_s$ Mesons

    SciTech Connect (OSTI)

    Leskovec, Luka; Lang, C. B.; Mohler, Daniel; Prelovsek, Sasa; Woloshyn, R. M.

    2015-11-12

    We study the positive parity charmed strange mesons using lattice QCD, the only reliable ab initio method to study QCD at low energies. Especially the experimentally observed $D_{s0}^*(2317)$ and $D_{s1}(2460)$ have challenged theory for quite some time. The dynamical lattice QCD simulations are performed at two distinct pion masses, $m_{\\pi}$ = 266 MeV and 156 MeV, using both $\\bar{c}s$ as well as $DK$ and $D^*K$ scattering operators in the construction of the correlation matrix in order to take into the account threshold effects. While the $J^P = 0^+$ channel benefited most from the inclusion of scattering operators, it was also crucial for the case of the $D_{s1}(2460)$. Using the L\\"uscher method, which relates the finite volume spectrum to the infinite volume scattering matrix, we were able to determine the near threshold behavior of the scattering amplitude. From it we extracted the binding momenta and the masses of the below-threshold bound states $D_{s0}^*(2317)$ and $D_{s1}(2460)$ by determining the pole positions of the scattering amplitudes. Our results compare well with experiment, resolving a long standing discrepancy between theory and experiment.

  8. Renewable Energy Engineering Consulting AG REECON AG | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Consulting AG REECON AG Jump to: navigation, search Name: Renewable Energy Engineering Consulting AG (REECON AG) Place: Heppenheim, Hessen, Germany Zip: D-64646 Sector: Solar...

  9. Antec Solar Energy AG formerly Oekologik Ecovest AG | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Antec Solar Energy AG formerly Oekologik Ecovest AG Jump to: navigation, search Name: Antec Solar Energy AG (formerly Oekologik Ecovest AG) Place: Arnstadt, Germany Zip: 99310...

  10. Abwicklungsgesellschaft Biogas I AG Formerly Schmack Biogas AG...

    Open Energy Information (Open El) [EERE & EIA]

    Abwicklungsgesellschaft Biogas I AG Formerly Schmack Biogas AG Jump to: navigation, search Name: Abwicklungsgesellschaft Biogas I AG (Formerly Schmack Biogas AG) Place: Schwandorf,...

  11. Observation of the Decay B??Ds(*)+K?l????l

    DOE PAGES-Beta [OSTI]

    del Amo Sanchez, P.; Lees, J. P.; Poireau, V.; Prencipe, E.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Palano, A.; Pappagallo, M.; et al

    2011-07-22

    We report the observation of the decay B??Ds(*)+K?l??l based on 342fb? of data collected at the ?(4S) resonance with the BABAR detector at the PEP-II e?e? storage rings at SLAC. A simultaneous fit to three D+s decay chains is performed to extract the signal yield from measurements of the squared missing mass in the B meson decay. We observe the decay B??Ds(*)+K?l??l with a significance greater than 5 standard deviations (including systematic uncertainties) and measure its branching fraction to be B(B??Ds(*)+K?l??l)=[6.13+1.04-1.03(stat)0.43(syst)0.51(B(Ds))]10??, where the last error reflects the limited knowledge of the Ds branching fractions.

  12. DS Deutsche Solargesellschaft mbH | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Germany Zip: 74074 Sector: Solar Product: DS Deutsche Solargesellschaft markets PV installations in Spain to mostly German private investors. Coordinates: 49.143145, 9.219295...

  13. Campa AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Campa AG Jump to: navigation, search Name: Campa AG Place: Ochsenfurt, Germany Zip: 97199 Product: String representation "Campa AG is one ... on and trading." is too long....

  14. Eifelstrom AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Eifelstrom AG Place: Germany Sector: Solar Product: Holding company belonging to the family of Frank Asbeck, founder of Solar World AG. References: Eifelstrom AG1 This article...

  15. VWind AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    VWind AG Jump to: navigation, search Name: VWind AG Place: Germany Sector: Wind energy Product: Germany-based offshore wind installation company. References: VWind AG1 This...

  16. Altus AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Altus AG Jump to: navigation, search Name: Altus AG Place: Germany Sector: Renewable Energy Product: Germany-based renewable energy project developer. References: Altus AG1 This...

  17. WKV AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    WKV AG Place: Gutach, Baden-Wrttemberg, Germany Zip: 79261 Sector: Hydro Product: German-based hydro turbines manufacturer, Wasserkraft Volk AG (WKV AG) provides technology...

  18. Solarsquare AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solarsquare AG Jump to: navigation, search Name: Solarsquare AG Place: Switzerland Sector: Solar Product: Solar modules distributor. References: Solarsquare AG1 This article is a...

  19. New experiments elucidating the current limiting mechanisms of Ag-sheathed (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} tapes.

    SciTech Connect (OSTI)

    Anderson, J.W.; Babcock, S.E.; Cai, X.Y.; Dorris, S.E.; Feldmann, M.; Jiang, J.; Larbalestier, D.C.; Li, Q.; Parrell, J.A.; Parrella, R.; Polak, M.; Polyanskii, A.; Riley, G.N. Jr.; Rupich, M.; Wu, Y.

    1999-01-15

    Multiple current limiting mechanisms exist from the nanometer to millimeter scale in Ag-sheathed (Bi,Pb)-2223 tapes. Recent studies of the zero-field critical current density (J{sub c} (0T, 77K)), the irreversibility field (H*) and the crack microstructure elucidate these properties. We show that H*(77K) can vary significantly over the range {approximately}120-260 mT, independently of J{sub c} (0T, 77K). Cracks, actual or incipient, exist on the sub to several hundred micron scale. Surface magneto optical imaging of whole tapes, correlated to subsequent ultrasonic fracture analysis of. the bare 2223 filaments extracted by dissolving away the Ag shows that even composites having J{sub c} (0T, 77K) values of 60 kA/cm{sup 2} exhibit strong signs of unhealed rolling damage. These combined studies show that today's very best 2223 tapes are still far from full optimization.

  20. Umwelt Management AG UMaAG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Management AG UMaAG Jump to: navigation, search Name: Umwelt Management AG (UMaAG) Place: Cuxhaven, Germany Zip: 27478 Sector: Wind energy Product: RE project developer, esp. wind...

  1. Young PhDs in Physics | Jefferson Lab

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    PhDs in Physics Young Ph.D.s in physics Young PhDs (left to right) William Luo, Jasmine Ellis, Shaun Lightfoot and Prakriti Verma made Oobleck with mechanical designer Joyce Miller during their visit to JLab. Young PhDs in Physics August 29, 2003 Jefferson Lab welcomes youngsters participating in summer science camp. Educating and exciting today's youth about science and technology is an important adjunct to Jefferson Lab's scientific mission. On July 16, the Department of Energy laboratory,

  2. Effect of Cu concentration on thermoelectric properties of nanostructured

    Office of Scientific and Technical Information (OSTI)

    p-type MgAg0.97-xCuxSb0.99 (Journal Article) | SciTech Connect Journal Article: Effect of Cu concentration on thermoelectric properties of nanostructured p-type MgAg0.97-xCuxSb0.99 Citation Details In-Document Search Title: Effect of Cu concentration on thermoelectric properties of nanostructured p-type MgAg0.97-xCuxSb0.99 Authors: Sui, Jiehe ; Shuai, Jing ; Lan, Yucheng ; Liu, Yuan ; He, Ran ; Wang, Dezhi ; Jie, Qing ; Ren, Zhifeng Publication Date: 2015-04-01 OSTI Identifier: 1250963

  3. 2011 CLOuDS Campaign | Princeton Plasma Physics Lab

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CLOuDS Campaign (photo credits: NASA Johnson Space Center) View larger image 11 PR 0706 29 View larger image 11 PR 0706 31 View larger image 11 PR 0706 32 View larger image Jsc ...

  4. Controlled preparation of Ag–Cu{sub 2}O nanocorncobs and their enhanced photocatalytic activity under visible light

    SciTech Connect (OSTI)

    Yang, Siyuan; Zhang, Shengsen; Wang, Hongjuan; Yu, Hao; Fang, Yueping; Peng, Feng

    2015-10-15

    Graphical abstract: The corncob-like Ag–Cu{sub 2}O nanostructure with suitably exposed Ag surface exhibited much higher photocatalytic activity than Ag@Cu{sub 2}O nanocables and Cu{sub 2}O nanowires. - Highlights: • Ag–Cu{sub 2}O nanocorncobs have been controllably prepared by a simple synthesis. • The possible formation mechanism of Ag–Cu{sub 2}O has been studied. • Ag–Cu{sub 2}O exhibits noticeable improved photocurrent compared with the pure Cu{sub 2}O NWs. • Ag–Cu{sub 2}O with suitably exposed Ag surface shows much higher photocatalytic activity. - Abstract: Novel corncob-like nano-heterostructured Ag–Cu{sub 2}O photocatalyst has been controllably prepared by adjusting the synthetic parameters, and the possible formation mechanism has been also studied. The photoelectrochemical and photocatalytic performances demonstrated that the as-prepared Ag–Cu{sub 2}O nanocorncobs exhibited higher photocatalytic activity than both pure Cu{sub 2}O nanowires and cable-like Ag@Cu{sub 2}O nano-composites. It was concluded that Ag–Cu{sub 2}O nanocorncobs with suitably exposed Ag surface not only effectively inhibit the recombination of electron–hole pairs but also suitably increase the active sites of electronic conduction, and thus increasing the photocatalytic activity under visible light irradiation.

  5. {bold {ital In situ}} measurements of texture and phase development in (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10}{endash}Ag tapes

    SciTech Connect (OSTI)

    Thurston, T.R.; Haldar, P.; Wang, Y.L.; Suenaga, M.; Jisrawi, N.M. |; Wildgruber, U.

    1997-04-01

    Hard x-rays from a synchrotron source were utilized in diffraction experiments performed at elevated temperatures (up to {approximately}870{degree}C) on (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} (Bi-2223) tapes {ital completely} encased in silver. The general behavior of the phase and texture development under typical processing conditions was determined, and the effects that several variations in processing conditions had on the phase and texture development were examined. These results and their implications for improving processing conditions are discussed. {copyright} {ital 1997 Materials Research Society.}

  6. Solarparc AG Former WindWelt AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Name: Solarparc AG (Former WindWelt AG) Place: Bonn, Germany Zip: 53115 Sector: Solar, Wind energy Product: Focused on planning, developing and operating wind and solar power...

  7. Tse AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Tse AG Jump to: navigation, search Name: tse.AG Place: Germany Product: Thenergo's German subsidiary. References: tse.AG1 This article is a stub. You can help OpenEI by expanding...

  8. Solarstocc AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Bad Zwischenahn, Germany Zip: 26160 Product: Designer and manufacturer of photovoltaic products and components. References: Solarstocc AG1 This article is a stub. You...

  9. Kopf AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Name: Kopf AG Place: Sulz-Bergfelden (DE), Germany Zip: 72172 Product: Focused on photovoltaic power systems, and energy and environmental technology. References: Kopf AG1 This...

  10. Evader AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Evader AG Place: Zug, Switzerland Product: Joint venture between Washington-based Evader Inc and the Schneider Group, in order to streamline...

  11. Solarvalue AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solarvalue AG Jump to: navigation, search Name: Solarvalue AG Place: Berlin, Berlin, Germany Zip: D-10719 Product: German manfuacturer of polysilicon made through metallurgical...

  12. Odersun AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Odersun AG Jump to: navigation, search Name: Odersun AG Place: Frankfurt, Germany Zip: 15236 Product: German manufacturer of copper indium disulphide on copper tape (CISCuT)...

  13. Varta AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Varta AG Jump to: navigation, search Name: Varta AG Place: Hanover, Germany Zip: 30419 Product: Headquartered in Hanover, concentrates on developing its global microbattery...

  14. ABIDAS AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    ABIDAS AG Jump to: navigation, search Name: ABIDAS AG Place: Werder, Brandenburg, Germany Zip: 14542 Product: Local energy consultant and PV systems installer and integrator....

  15. ENRO AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: ENRO AG Place: Essen, Germany Zip: 45128 Sector: Biomass Product: Focuses on distributed energy supply concepts for local authorities and...

  16. Interstrom AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Interstrom AG Place: Bayreuth, Bavaria, Germany Zip: 95448 Sector: Solar Product: Germany-based electricity provider. The firm is...

  17. Solare AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Solare AG Place: Cologne, North Rhine-Westphalia, Germany Zip: 50678 Sector: Solar Product: Germany-based equipment manufacturer and developer...

  18. Inergetic AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Inergetic AG Jump to: navigation, search Name: Inergetic AG Place: Schwerin, Germany Zip: 19061 Sector: Biomass Product: Biomass power plant developer and operator. Actively...

  19. Solarcomplex AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solarcomplex AG Jump to: navigation, search Name: solarcomplex AG Place: Singen, Germany Zip: 78224 Sector: Renewable Energy, Solar Product: Regional solar energy company with the...

  20. Energieteam AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energieteam AG Jump to: navigation, search Name: Energieteam AG Place: Lichtenau, Germany Zip: D-33165 Sector: Wind energy Product: Wind farm developer. Has developed 904MW wind in...

  1. Solea AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Solea AG Place: Plattling, Germany Zip: 94447 Product: A Germany PV project developer and building contractor, who also manufactures its own...

  2. REON AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    REON AG Jump to: navigation, search Name: REON AG Place: Worpswede, Germany Zip: D-27726 Sector: Services Product: Specialists in technical and strategic advisory services for...

  3. Wattner AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    to: navigation, search Name: Wattner AG Place: Kln, Germany Zip: 50679 Product: German project finance arranger. References: Wattner AG1 This article is a stub. You can...

  4. Eutropa AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Eutropa AG Jump to: navigation, search Name: Eutropa AG Place: Munich, Bavaria, Germany Zip: 82008 Sector: Renewable Energy Product: Munich-based consultancy providing information...

  5. Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

    SciTech Connect (OSTI)

    Demchyna, M.; Belan, B.; Manyako, M.; Pietraszko, A.; Kalychak, Ya.

    2012-08-15

    The phase equilibria of Tb-Ag-In and Dy-Ag-In ternary systems have been studied at 870 K in the whole concentration range by means of X-ray powder, single crystal X-ray diffraction and EDX analyses. Isothermal sections of Tb-Ag-In and Dy-Ag-In phase diagrams at this temperature have been constructed. Both systems are characterized by formation of three ternary compounds: REAg{sub 3}In{sub 3} (YbAg{sub 2}In{sub 4}-type, space group Im-3), REAg{sub 2}In (MnCu{sub 2}Al-type, space group Fm-3m) and RE{sub 2}AgIn{sub 3} (CaIn{sub 2}-type, space group P6{sub 3}/mmc) RE=Tb, Dy. Homogeneity ranges of the ternary phases with CaIn{sub 2} structure type lies from 35 to 60 at% of In for Tb-containing phase and from 39 to 50 at% of In for Dy-containing phase. The existence of solid solutions based on REAg (CsCl-type, space group Pm-3m) binary compounds up to 30 at% of In and REIn{sub 3} (AuCu{sub 3}-type, space group Pm-3 m) binary compounds up to 5 at% of Ag has been found. - Graphical Abstract: Phase relations in the ternary systems Tb-Ag-In and Dy-Ag-In have been established for the isothermal section at T=870 K based on X-ray powder and single crystal diffraction analyses. The existence of three ternary compounds in each system were observed. Highlights: Black-Right-Pointing-Pointer Isothermal section of Tb-Ag-In system at T=870 K was constructed. Black-Right-Pointing-Pointer Isothermal section of Dy-Ag-In system at T=870 K was constructed. Black-Right-Pointing-Pointer Three ternary compounds and two solid solutions in each system were detected.

  6. Stadtwerke Mainz AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Mainz AG Jump to: navigation, search Name: Stadtwerke Mainz AG Place: Mainz, Germany Zip: 55118 Product: Utility in Mainz, Germany. References: Stadtwerke Mainz AG1 This article...

  7. Loremo AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Loremo AG Place: Mnchen, Bavaria, Germany Zip: 80807 Product: Designer of a 157 mpg light weight 2 cylinder Turbo-Diesel car. References: Loremo AG1 This article is a...

  8. ASP AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: ASP AG Place: Laupen, Switzerland Zip: CH-8637 Product: Manufacturer of inverters for PV systems and other off- and on-grid applications. References: ASP AG1 This...

  9. CLOuDS: 2012 Workshop | Princeton Plasma Physics Lab

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CLOuDS: 2012 Workshop View larger image IMG 1124 View larger image IMG 1125 View larger image IMG 1126 View larger image IMG 1155 View larger image IMG 1156 View larger image IMG 1157 View larger image IMG 1127 View larger image IMG 1128 View larger image IMG 1130 View larger image IMG 1131 View larger image IMG 1132 View larger image IMG 1133 View larger image IMG 1134 View larger image IMG 1137 View larger image IMG 1146 View larger image IMG 1148 View larger image IMG 1151 View larger image

  10. Observation of the Decay B⁻→Ds(*)+K⁻l⁻ν⁻⁻l

    DOE PAGES-Beta [OSTI]

    del Amo Sanchez, P.; Lees, J. P.; Poireau, V.; Prencipe, E.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Palano, A.; Pappagallo, M.; et al

    2011-07-22

    We report the observation of the decay B⁻→Ds(*)+K⁻l⁻ν¯l based on 342fb⁻¹ of data collected at the Υ(4S) resonance with the BABAR detector at the PEP-II e⁺e⁻ storage rings at SLAC. A simultaneous fit to three D+s decay chains is performed to extract the signal yield from measurements of the squared missing mass in the B meson decay. We observe the decay B⁻→Ds(*)+K⁻l⁻ν¯l with a significance greater than 5 standard deviations (including systematic uncertainties) and measure its branching fraction to be B(B⁻→Ds(*)+K⁻l⁻ν¯l)=[6.13+1.04-1.03(stat)±0.43(syst)±0.51(B(Ds))]×10⁻⁴, where the last error reflects the limited knowledge of the Ds branching fractions.

  11. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, M.A.; Bingert, J.F.; Bingert, S.A.; Thoma, D.J.

    1998-09-08

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process. 5 figs.

  12. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, Mary Ann; Bingert, John F.; Bingert, Sherri A.; Thoma, Dan J.

    1998-01-01

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process.

  13. Nucleic acid encoding DS-CAM proteins and products related thereto

    DOE Patents [OSTI]

    Korenberg, Julie R.

    2005-11-01

    In accordance with the present invention, there are provided Down Syndrome-Cell Adhesion Molecule (DS-CAM) proteins. Nucleic acid sequences encoding such proteins and assays employing same are also disclosed. The invention DS-CAM proteins can be employed in a variety of ways, for example, for the production of anti-DS-CAM antibodies thereto, in therapeutic compositions and methods employing such proteins and/or antibodies. DS-CAM proteins are also useful in bioassays to identify agonists and antagonists thereto.

  14. Novel Approaches to Wide Bandgap CuInSe2 Based Absorbers

    SciTech Connect (OSTI)

    William N. Shafarman

    2011-04-28

    This project targeted the development of high performance wide bandgap solar cells based on thin film alloys of CuInSe2 to relax constraints on module design and enable tandem solar cell structures. This addressed goals of the Solar Energy Technologies Program for Next Generation PV to develop technology needed for higher thin film module efficiency as a means to reduce costs. Specific objectives of the research project were: 1) to develop the processes and materials required to improve the performance of wide bandgap thin film solar cells based on alloys of CuInSe2, and 2) to provide the fundamental science and engineering basis for the material, electronic, and device properties required to effectively apply these processes and materials to commercial manufacture. CuInSe2-based photovoltaics have established the highest efficiencies of the thin film materials at both the cell and module scales and are actively being scaled up to commercialization. In the highest efficiency cells and modules, the optical bandgap, a function of the CuInSe2-based alloy composition, is relatively low compared to the optimum match to the solar spectrum. Wider bandgap alloys of CuInSe2 produce higher cell voltages which can improve module performance and enable the development of tandem solar cells to boost the overall efficiency. A focus for the project was alloying with silver to form (AgCu)(InGa)Se2 pentenary thin films deposited by elemental co-evaporation which gives the broadest range of control of composition and material properties. This alloy has a lower melting temperature than Ag-free, Cu-based chalcopyrite compounds, which may enable films to be formed with lower defect densities and the (AgCu)(InGa)Se2 films give improved material properties and better device performance with increasing bandgap. A comprehensive characterization of optical, structural, and electronic properties of (AgCu)(InGa)Se2 was completed over the complete compositional range 0 ≤ Ga/(In+Ga) ≤ 1 and

  15. Bosch Solar Energy AG former ErSol Solar Energy AG | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    AG former ErSol Solar Energy AG Jump to: navigation, search Name: Bosch Solar Energy AG (former ErSol Solar Energy AG) Place: Erfurt, Germany Zip: D-99099 Product: Germany-based...

  16. PV Crystalox Solar AG formerly PV Silicon AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    PV Crystalox Solar AG formerly PV Silicon AG Jump to: navigation, search Name: PV Crystalox Solar AG (formerly PV Silicon AG) Place: Abingdon, England, United Kingdom Zip: OX14 4SE...

  17. Parabel AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: Parabel AG Place: Berlin-Pankow, Berlin, Germany Sector: Solar Product: Sells a thin-film roofing product using UniSolar laminates, and distributes and...

  18. Sunline AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Sector: Solar Product: German solar PV and thermal company active in planning and marketing solar installations. References: Sunline AG1 This article is a stub. You can help...

  19. Solarion AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Germany Zip: 4288 Sector: Solar Product: Focuses on the development, production and marketing of CIGS thin-film solar cells on flexible substrate. References: Solarion AG1 This...

  20. Ecodasa AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Berlin, Berlin, Germany Zip: 13435 Product: Ecodasa is an integrated biodiesel producer with a planned capacity of 774m litres biodiesel until 2008. References:...

  1. Solemaxx AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: Solemaxx AG Place: Zug, Switzerland Zip: CH-6300 Sector: Renewable Energy, Solar Product: Switzerland-based solar project developer and renewable energy...

  2. Meeco AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    navigation, search Name: meeco AG Place: Zug, Switzerland Zip: 6304 Sector: Renewable Energy Product: Switzerland-based company that offers engineering and management solutions in...

  3. Sunways AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Constance, Germany Zip: D-78467 Product: German manufacturer of PV cells, modules, inverters and integrated systems. References: Sunways AG1 This article is a stub. You can...

  4. Conergy AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: Conergy AG Place: Hamburg, Hamburg, Germany Zip: 20537 Sector: Biofuels, Biomass, Wind energy Product: PV and passive system integrator and inverter...

  5. Cowatec AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Cowatec AG Place: Burglengenfeld, Bavaria, Germany Zip: 93133 Product: Cowatec is a biogas plant turnkey provider, also offering financial and permission planning. References:...

  6. Ristma AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: Ristma AG Place: GlisVS, Switzerland Zip: 3902 Product: Swiss battery pack manufacturer primarily for the handheld cordless power tool market. It is laos...

  7. Gorlitz AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Sector: Services Product: Company providing products and services in energy data communication and processing. References: Gorlitz AG1 This article is a stub. You can help...

  8. Carpevigo AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Name: Carpevigo AG Place: Holzkirchen, Germany Zip: 83607 Product: Carpevigo is a German turnkey PV project developer that issues bonds to finance investments. References:...

  9. Solarpraxis AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Publishes technical journals and organises conferences in building services, the copper industry and solar technology. References: Solarpraxis AG1 This article is a stub....

  10. Bosch Solar Energy AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Bosch Solar Energy AG Jump to: navigation, search Logo: Bosch Solar Energy AG Name: Bosch Solar Energy AG Address: Wilhelm-Wolff-Strasse 23 Place: Arnstadt, Germany Product: solar...

  11. AG Land 5 | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    5 Jump to: navigation, search Name AG Land 5 Facility AG Land 5 Sector Wind energy Facility Type Community Wind Facility Status In Service Owner AG Land Energy LLC Developer...

  12. ABO Wind AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: ABO Wind AG Place: Hessen, Germany Zip: 65193 Sector: Bioenergy, Wind energy Product: German developer of wind and bioenergy generation assets....

  13. Seeger Engineering AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Seeger Engineering AG Place: Hessisch Lichtenau, Hessen, Germany Zip: 37235 Sector: Biomass, Services Product: Services range from project...

  14. SITIZN Group Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    SITIZN Group Holding AG Jump to: navigation, search Name: SITIZN Group Holding AG Place: Riederich, Germany Zip: 72585 Sector: Solar Product: Germany-based solar technology and...

  15. AG Solutions Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    navigation, search Name: AG Solutions Inc. Place: Gladstone, Michigan Product: 10Mgpy biodiesel producer in Gladstone, Michigan. References: AG Solutions Inc.1 This article is a...

  16. EOP Biodiesel AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    EOP Biodiesel AG Jump to: navigation, search Name: EOP Biodiesel AG Place: Falkenhagen, Germany Zip: 16928 Product: German producer of biodiesel from rapeseed. References: EOP...

  17. Clean Mobile AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Munich, Bavaria, Germany Sector: Vehicles Product: Manufacturer of fuel cell-powered drives for small vehicles. References: Clean Mobile AG1 This article is a...

  18. ADM Hamburg AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    ADM Hamburg AG Jump to: navigation, search Name: ADM Hamburg AG Place: Hamburg, Hamburg, Germany Zip: 21107 Product: Biodiesel producer with a capacity of 595m litresyear....

  19. Norddeutsche Affinerie AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Affinerie AG Jump to: navigation, search Name: Norddeutsche Affinerie AG Place: Hamburg, Germany Zip: 20539 Product: Producer and recycler of copper. Coordinates: 53.553345,...

  20. Centrosolar Group AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Group AG Jump to: navigation, search Name: Centrosolar Group AG Place: Munich, Germany Zip: 80807 Product: German holding company of various PV-related subsidiaries....

  1. ASSET LOGISTIC AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LOGISTIC AG Jump to: navigation, search Name: ASSET@LOGISTIC AG Place: Hamburg, Hamburg, Germany Zip: 20148 Sector: Wind energy Product: Developer of 3 wind farms in Almeria,...

  2. Power PLUS Communications AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    PLUS Communications AG Jump to: navigation, search Name: Power PLUS Communications AG Place: Mannheim, Germany Zip: 68167 Product: String representation "Power Plus Comm ... nergy...

  3. Sonne Wind Beteiligungen AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Sonne+Wind Beteiligungen AG Place: Berlin, Germany Zip: 10715 Sector: Efficiency, Solar, Wind energy Product: Berlin-based VC firm...

  4. Solar Millennium AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: Solar Millennium AG Place: Erlangen, Bavaria, Germany Zip: D-91052 Sector: Solar Product: Bavaria-based solar project developer; provides...

  5. Nature Elements Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Holding AG Jump to: navigation, search Name: Nature Elements Holding AG Place: Baar, Switzerland Zip: CH-6340 Sector: Renewable Energy Product: Swiss developer of renewable energy...

  6. Centrotec Sustainable AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Sustainable AG Jump to: navigation, search Name: Centrotec Sustainable AG Place: Brilon, Germany Zip: D - 59929 Sector: Solar Product: Provides gas flue and climate systems for...

  7. Energie AG Oberoesterreich | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energie AG Oberoesterreich Jump to: navigation, search Name: Energie AG Oberoesterreich Place: Linz, Austria Zip: 4021 Product: Utility focused on Upper Austria. Coordinates:...

  8. AGO AG Energie Anlagen | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AGO AG Energie Anlagen Jump to: navigation, search Name: AGO AG Energie + Anlagen Place: Kulmbach, Baden-Wrttemberg, Germany Zip: 95326 Sector: Biomass Product: Project...

  9. Edisun Power AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Zurich, Switzerland Zip: 8006 Sector: Solar Product: Edisun Power Europe AG finances, acquires and operates solar power installations, and markets solar power....

  10. Bernried Erdwarme AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Bernried Erdwarme AG Jump to: navigation, search Name: Bernried Erdwarme AG Place: Germany Sector: Geothermal energy Product: Germany-based geothermal development company....

  11. SolarHybrid AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    SolarHybrid AG Jump to: navigation, search Name: SolarHybrid AG Place: Germany Sector: Solar Product: Germany-based solar thermal hybrid product manufacturer References:...

  12. REpower Systems AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Systems AG Jump to: navigation, search Name: REpower Systems AG Place: Hamburg, Germany Zip: D-22297 Sector: Services, Wind energy Product: Wind turbine manufacturer with...

  13. In Trust AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Trust AG Jump to: navigation, search Name: in-Trust AG Place: Regensburg, Bavaria, Germany Zip: 93047 Product: Germany-based investment company focused mainly on investing in...

  14. SolarWorld AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    SolarWorld AG Jump to: navigation, search Name: SolarWorld AG Place: Bonn, Germany Zip: 53113 Product: Vertically integrated PV manufacturer, with factories in Freiberg, Germany...

  15. Krass Capital Group AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Krass Capital Group AG Jump to: navigation, search Name: Krass Capital Group AG Place: Grfelfing, Bulgaria Zip: 82166 Sector: Renewable Energy Product: Grafelfing-based firm...

  16. Meyer Burger AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Meyer Burger AG Jump to: navigation, search Name: Meyer Burger AG Place: Steffisburg, Switzerland Zip: 3613 Sector: Solar Product: Manufactures wire saws for cutting and processing...

  17. ENRO Geothermie AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    ENRO Geothermie AG Jump to: navigation, search Name: ENRO Geothermie AG Place: Essen, North Rhine-Westphalia, Germany Zip: 45128 Sector: Geothermal energy Product: Geothermal...

  18. Offshore Ostsee Wind AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Ostsee Wind AG Jump to: navigation, search Name: Offshore Ostsee Wind AG Place: Brgerende, Mecklenburg-Western Pomerania, Germany Zip: 18211 Sector: Wind energy Product: Joint...

  19. American Ag Fuels LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    American Ag Fuels LLC Jump to: navigation, search Name: American Ag Fuels LLC Place: Defiance, Ohio Zip: 43512 Product: Biodiesel producer in Defiance, Ohio. References: American...

  20. Swiss Wafers AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Wafers AG Jump to: navigation, search Name: Swiss Wafers AG Place: Weinfelden, Switzerland Zip: 8570 Sector: Services Product: Swiss-based manufacturer of mono and multicrystalline...

  1. Module Solar AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Module Solar AG Jump to: navigation, search Name: Module Solar AG Place: Baar, Switzerland Product: A Swiss PV module and materials supplier and developer Coordinates: 40.808083,...

  2. Huber and Suhner AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Suhner AG Jump to: navigation, search Name: Huber and Suhner AG Place: Pfaeffikon, Switzerland Zip: 8330 Sector: Solar Product: Huber and Suhner specialises in electrical and...

  3. Structural and optical properties of Ag-doped copper oxide thin films on polyethylene napthalate substrate prepared by low temperature microwave annealing

    SciTech Connect (OSTI)

    Das, Sayantan; Alford, T. L.

    2013-06-28

    Silver doped cupric oxide thin films are prepared on polyethylene naphthalate (flexible polymer) substrates. Thin films Ag-doped CuO are deposited on the substrate by co-sputtering followed by microwave assisted oxidation of the metal films. The low temperature tolerance of the polymer substrates led to the search for innovative low temperature processing techniques. Cupric oxide is a p-type semiconductor with an indirect band gap and is used as selective absorption layer solar cells. X-ray diffraction identifies the CuO phases. Rutherford backscattering spectrometry measurements confirm the stoichiometry of each copper oxide formed. The surface morphology is determined by atomic force microscopy. The microstructural properties such as crystallite size and the microstrain for (-111) and (111) planes are calculated and discussed. Incorporation of Ag led to the lowering of band gap in CuO. Consequently, it is determined that Ag addition has a strong effect on the structural, morphological, surface, and optical properties of CuO grown on flexible substrates by microwave annealing. Tauc's plot is used to determine the optical band gap of CuO and Ag doped CuO films. The values of the indirect and direct band gap for CuO are found to be 2.02 eV and 3.19 eV, respectively.

  4. Kondo-lattice formation in cubic-phase YbCu{sub 5}

    SciTech Connect (OSTI)

    Tsujii, N.; He, J.; Amita, F.; Yoshimura, K.; Kosuge, K.; Michor, H.; Hilscher, G.; Goto, T.

    1997-10-01

    The YbCu{sub 5} phase with C15b structure has been prepared by a high-pressure technique, and its physical properties have been investigated. The temperature dependence of magnetic susceptibility, electrical resistivity, and specific heat show Kondo-lattice formation. Furthermore, a heavy Fermi-liquid state without magnetic ordering down to 2.0 K is found to evolve below about 6 K. The electronic specific heat coefficient {gamma} is enhanced to values as large as to 550 mJ/molthinspK{sup 2}. The magnetization measured up to 40 T at 1.6 K has a field dependence which is expected for a Kondo system when the total angular momentum is J{gt}1. All results are in good agreement with the extrapolation of the previous results of YbCu{sub 5{minus}x}Ag{sub x} (0.125{le}x{le}1.0) for x{r_arrow}0. The concentration dependence of characteristic temperatures of YbCu{sub 5{minus}x}Ag{sub x} can be quantitatively explained by the chemical pressure effect within the compressible Kondo model for the full range of Ag concentration ( 0.0{le}x{le}1.0). The origins of Kondo-lattice formation in YbCu{sub 4}Ag and the valence transition in YbCu{sub 4}In are discussed. {copyright} {ital 1997} {ital The American Physical Society}

  5. Novel visible-light AgBr/Ag?PO? hybrids photocatalysts with surface plasma resonance effects

    SciTech Connect (OSTI)

    Wang, Yunfang Li, Xiuli; Wang, Yawen; Fan, Caimei

    2013-06-01

    Three kinds of AgBr/Ag?PO? hybrids were synthesised via an anion-exchange precipitation method and characterised by XRD, XPS, SEM, EDS, and UVvis. The results showed that AgBr/Ag?PO? hybrids displayed much higher photocatalytic activities than single Ag?PO? or AgBr under visible light (?>420 nm), and OH and h? were the major active species during the degradation process. Considering interstitial ions Ag?? on lattice gap of AgBr are easy to become sliver particle, we deduced the possible photocatalytic mechanism could be ascribed to the synergistic effects of the appropriate valence band position of Ag?PO? and AgBr, surface plasmon resonance effect of Ag?, reactive radical species Br?, and the Ag vacancy on the surface of catalysts. - Graphical abstract: The optical absorption and structural morphology of the as-prepared AgBr@Ag?PO? photocatalyst using an anion-exchange precipitation method are conductive to the photocatalytic degradation of organics in water. Highlights: Novel AgBr/Ag?PO? hybrids are synthesised by a facile method. AgBr/Ag?PO? hybrids show excellent photocatalytic activities under visible light. Interstitial ions are in favour of the formation of Ag particle. Surface plasmon resonance effect plays a key factor for light absorption. The photocatalytic mechanism for AgBr/Ag?PO? hybrids is studied.

  6. Systaic AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Duesseldorf, North Rhine-Westphalia, Germany Zip: D-40213 Sector: Solar Product: Has developed and is installing a building-integrated PV roof, which can be used as...

  7. Sinosol AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solar Product: Buys PV modules and solar passive systems in China and sells them in Europe. References: Sinosol AG1 This article is a stub. You can help OpenEI by expanding...

  8. Development and Fabrication of Nb3Sn Rutherford Cable for the 11 T DS Dipole Demonstration Model

    SciTech Connect (OSTI)

    Barzi, E.; Lombardo, V.; Nobrega, F.; Turrioni, D.; Yamada, R.; Zlobin, A.V.; Karppinen, M.; /CERN

    2011-11-30

    Fermilab and CERN started the development of 11 T 11-m long Nb{sub 3}Sn dipoles to replace few regular LHC NbTi dipoles and free space for cold collimators in LHC DS areas. An important step in the design of these magnets is the development of the high aspect ratio Nb{sub 3}Sn cable to achieve the nominal field of 11 T at the nominal LHC operating current of 11.85 kA with 20% margin. The keystoned cables 14.7 mm wide with and without a stainless steel core were made out of hard Cu wires and Nb{sub 3}Sn RRP strand 0.7 mm nominal diameter. The cable optimization process was aimed at achieving both mechanical stability and minimal damage to the delicate internal architecture of the Restacked-Rod-Process (RRP) Nb{sub 3}Sn strands with 127 restack design to be used in the magnet short models. Each cable was characterized electrically for transport properties degradation at high field and for low field stability, and metallographically for internal damage.

  9. Thermochemical process for recovering Cu from CuO or CuO.sub.2

    DOE Patents [OSTI]

    Richardson, deceased, Donald M.; Bamberger, Carlos E.

    1981-01-01

    A process for producing hydrogen comprises the step of reacting metallic Cu with Ba(OH).sub.2 in the presence of steam to produce hydrogen and BaCu.sub.2 O.sub.2. The BaCu.sub.2 O.sub.2 is reacted with H.sub.2 O to form Cu.sub.2 O and a Ba(OH).sub.2 product for recycle to the initial reaction step. Cu can be obtained from the Cu.sub.2 O product by several methods. In one embodiment the Cu.sub.2 O is reacted with HF solution to provide CuF.sub.2 and Cu. The CuF.sub.2 is reacted with H.sub.2 O to provide CuO and HF. CuO is decomposed to Cu.sub.2 O and O.sub.2. The HF, Cu and Cu.sub.2 O are recycled. In another embodiment the Cu.sub.2 O is reacted with aqueous H.sub.2 SO.sub.4 solution to provide CuSO.sub.4 solution and Cu. The CuSO.sub.4 is decomposed to CuO and SO.sub.3. The CuO is decomposed to form Cu.sub.2 O and O.sub.2. The SO.sub.3 is dissolved to form H.sub.2 SO.sub.4. H.sub.2 SO.sub.4, Cu and Cu.sub.2 O are recycled. In another embodiment Cu.sub.2 O is decomposed electrolytically to Cu and O.sub.2. In another aspect of the invention, Cu is recovered from CuO by the steps of decomposing CuO to Cu.sub.2 O and O.sub.2, reacting the Cu.sub.2 O with aqueous HF solution to produce Cu and CuF.sub.2, reacting the CuF.sub.2 with H.sub.2 O to form CuO and HF, and recycling the CuO and HF to previous reaction steps.

  10. Lake County Ag Park Greenhouse Low Temperature Geothermal Facility...

    Open Energy Information (Open El) [EERE & EIA]

    Ag Park Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Lake County Ag Park Greenhouse Low Temperature Geothermal Facility Facility Lake County Ag...

  11. Sol e Suisse AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Suisse AG Jump to: navigation, search Name: Sol-e Suisse AG Place: Berne, Switzerland Zip: 25 Sector: Renewable Energy Product: Renewable energy division of BKW FMB Energy Ltd....

  12. Ag Fuels Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    to: navigation, search Name: Ag Fuels Ltd Place: Sealy, Texas Product: 3.6Mgpl (13.6Mlpy) biodiesel producer in Sealy, Texas. References: Ag Fuels Ltd1 This article is a stub....

  13. AgPro | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name: AgPro Place: Massena, New York Product: Operator of biodiesel plant based on soy. References: AgPro1 This article is a stub. You can help OpenEI...

  14. MAN Ferrostaal AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Jump to: navigation, search Name: MAN Ferrostaal AG Place: Essen, Germany Zip: 45128 Sector: Solar Product: Germany-based firm that focuses on the development and realisation of...

  15. Payom Solar AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Payom Solar AG Jump to: navigation, search Name: Payom Solar AG Place: Merkendorf, Germany Zip: 91732 Product: Germany-based installer of roof-mounted PV plants, which also trades...

  16. SGL Carbon AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Carbon AG Jump to: navigation, search Name: SGL Carbon AG Place: Wiesbaden, Hessen, Germany Zip: 65203 Sector: Carbon Product: A Germany-based manufacturer of carbon-based products...

  17. Facile synthesis of Ag–Cu{sub 2}O composites with enhanced photocatalytic activity

    SciTech Connect (OSTI)

    Yang, Jianbo; Li, Zhen; Zhao, Caixin; Wang, Yang; Liu, Xueqin

    2014-12-15

    Highlights: • Ag–Cu{sub 2}O nanocomposites were synthesized via awet-chemical precipitation route. • The growth temperature does not exceed 50 °C in any step of the synthesis. • Enhanced photocurrent of Ag–Cu{sub 2}O composites, compared to pure Cu{sub 2}O particles. • The photocatalytic property was studied upon simulated sunlight. • Enhanced photocatalytic property of Ag–Cu{sub 2}O composites, compared to pure Cu{sub 2}O particles. - Abstract: Silver–cuprous oxide (Ag–Cu{sub 2}O) microcomposites are successfully prepared by a facile low-cost solution method. The obtained materials were characterized by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), field emission scanning electron microscopy (FESEM), ultraviolet–visible (UV–vis) spectroscopy, X-ray photoelectron spectroscopy (XPS). Experiments demonstrated that the formation of Ag–Cu{sub 2}O microcomposites was significantly influenced by the concentration of AgNO{sub 3}, and with increasing the concentration of AgNO{sub 3}, the optical absorption of the composites becomes strong. The photocatalytic activity of the prepared Ag–Cu{sub 2}O composites was determined by measuring the degradation of methyl orange solution under visible light, to find out its potential application in waste water treatment. The results reveal that the photocurrent of the composite is about 4 times higher than that of pure Cu{sub 2}O and the visible light photocatalytic activity of the composite is enhanced greatly on degradation of methyl orange. The reason for improvement in photocatalytic activity of the Ag–Cu{sub 2}O composites was also discussed.

  18. AGS 20th anniversary celebration

    SciTech Connect (OSTI)

    Baggett, N.V.

    1980-05-22

    On May 22, 1980, a symposium was held at Brookhaven to celebrate the 20th birthday of the AGS, to recall its beginnings, and to review major discoveries that have been made with its beams. The talks at the symposium are recorded in this volume.

  19. Review of dWindDS Model Initial Results; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Baring-Gould, Ian; Gleason, Michael; Preus, Robert; Sigrin, Ben

    2015-06-17

    The dWindDS model analyses the market diffusion of distributed wind generation for behind the meter applications. It is consumer decision based and uses a variety of data sets including a high resolution wind data set. It projects market development through 2050 based on input on specified by the user. This presentation covers some initial runs with draft base case assumptions.

  20. Solar Deployment System (SolarDS) Model: Documentation and Sample Results

    SciTech Connect (OSTI)

    Denholm, P.; Drury, E.; Margolis, R.

    2009-09-01

    The Solar Deployment System (SolarDS) model is a bottom-up, market penetration model that simulates the potential adoption of photovoltaics (PV) on residential and commercial rooftops in the continental United States through 2030. NREL developed SolarDS to examine the market competitiveness of PV based on regional solar resources, capital costs, electricity prices, utility rate structures, and federal and local incentives. The model uses the projected financial performance of PV systems to simulate PV adoption for building types and regions then aggregates adoption to state and national levels. The main components of SolarDS include a PV performance simulator, a PV annual revenue calculator, a PV financial performance calculator, a PV market share calculator, and a regional aggregator. The model simulates a variety of installed PV capacity for a range of user-specified input parameters. PV market penetration levels from 15 to 193 GW by 2030 were simulated in preliminary model runs. SolarDS results are primarily driven by three model assumptions: (1) future PV cost reductions, (2) the maximum PV market share assumed for systems with given financial performance, and (3) PV financing parameters and policy-driven assumptions, such as the possible future cost of carbon emissions.

  1. Determining System Parameters for Optimal Performance of Hybrid DS/FFH Spread-Spectrum

    SciTech Connect (OSTI)

    Ma, Xiao [ORNL; Olama, Mohammed M [ORNL; Kuruganti, Phani Teja [ORNL; Smith, Stephen Fulton [ORNL; Djouadi, Seddik M [ORNL

    2012-01-01

    In recent years there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their use in military communications because they accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct sequence (DS) modulation with "fast" frequency hopping (FFH), denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. In this paper, an optimization problem is formulated that maximizes the DS/FFH communication system performance in terms of probability of bit error and solves for the system design parameters. The objective function is non-convex and can be solved by applying the Karush-Kuhn-Tucker conditions. System design parameters of interest are the length of the DS code sequence, number of frequency hopping channels, number of channels corrupted by wide-band jamming, and number of hops per bit. The proposed formulation takes into account the effects from wide-band and partial-band jamming, multi-user interference and/or varying degrees of Rayleigh and Rician multipath fading. Numerical results are presented to demonstrate the method s viability.

  2. Using Tensor Momentum Dependent Deuteron Potential to Extract the Asymptotic D/S Ratio

    SciTech Connect (OSTI)

    Emad El-Deen, A. Sultan; Mustafa, Mustafa M.; Zahran, Elbadry S.

    2010-09-30

    A new value for the deuteron asymptotic D/S ratio {eta} = 0.02640{+-}0.00024 is extracted from an empirical linear {eta}-Q relation found for a class of deuteron momentum dependent potentials with tensor momentum dependent part. These potentials fit a recently published phase shift analysis and the binding energy of the deuteron.

  3. Effect of mechanical deformation on the evolution of c-axis texture of Bi{sub 1.6}Pb{sub 0.4}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub z} superconductor HIP cladded on Ag substrate

    SciTech Connect (OSTI)

    Yoo, J.M.; Mukherjee, K.

    1994-12-31

    The c-axis texture evolution of 2223 BSCCO superconductor has been studied by x-ray polefigure method, using ``popLA`` software package, which can elucidate the evolution of texture associated with mechanical processing of BSCCO compound. The specimens were fabricated on Ag substrate by a HIP cladding technique to induce randomly oriented state as the starting material, and to investigate the role of non (001) grain during deformation. As the amount of cold rolling reduction (%) increased, a tighter clustering of the (00{und 14}) poles around the surface normal, indicated that randomly oriented c-axes` grains from initial HIP cladded surface rotated towards the normal direction. In addition (105), (109), and (110) experimental polefigure studies indicated that under deformation, those plane normals tend to form a fiber texture around the compression direction of rolling (normal direction). After achieving certain degrees of texturing, saturation due to textural hardening was also observed. Detailed texture analysis, along with inverse polefigure, and microstructure analysis are reported.

  4. 3S Industries AG Formerly 3S Swiss Solar Systems AG | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    search Name: 3S Industries AG (Formerly 3S Swiss Solar Systems AG) Place: Bern, Switzerland Zip: CH-3006 Product: Swiss-based manufacturer of manual and semi-automatic PV...

  5. TriWo AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    TriWo AG Place: Trier, Denmark Zip: 54290 Sector: Solar Product: Developer of solar photovoltaic electricity generation project in Germany. Coordinates: 49.757256, 6.636521...

  6. ASP Aton Sunpower AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zug, Switzerland Product: Zug-based project developer focused on the installaion of photovoltaic facilities. References: ASP Aton Sunpower AG1 This article is a stub. You can...

  7. Ag Processing Inc AGP | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Nebraska Zip: 68103-2047 Product: Cooperative engaged in the procurement, processing, marketing, and transportation of grains and grain products. References: Ag Processing Inc....

  8. Husker Ag LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: Husker Ag LLC Place: Plainview, Nebraska Zip: 68769 Product: Bioethanol producer using corn as feedstock. Coordinates: 34.197675, -101.698139 Show Map...

  9. Getec AG Contracting | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name: Getec AG Contracting Place: Magdeburg, Saxony-Anhalt, Germany Zip: 39108 Sector: Efficiency Product: German Efficiency Service Company....

  10. 3C Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    am Main, Germany Zip: 61118 Sector: Services Product: 3C Holding AG develops trading strategies for EU allowances, JICDM Projects and climate neutral events, products...

  11. Energiecontracting Heidelberg AG ECH | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Baden-Wrttemberg, Germany Zip: 69126 Product: Consultancy specialised in local energy supply. References: Energiecontracting Heidelberg AG (ECH)1 This article is a...

  12. AG Plus Co operative | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Plus Co operative Jump to: navigation, search Name: AG Plus Co-operative Place: SE Kindred, North Dakota Zip: 58051 Product: Cooperative offering membership stock to agricultural...

  13. Unit Energy Europe AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Wind energy Product: Unit Energy develops and operates wind parks and hydroelectric power plants all across Europe. References: Unit Energy Europe AG1 This article is a stub....

  14. Inventux Technologies AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Steinhagen, Germany Zip: D-33803 Product: German manufacturer of micromorph tandem thin-film modules. Coordinates: 52.004606, 8.414257 Show Map Loading map......

  15. EnerVest AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: EnerVest AG Place: Mnchen, Germany Zip: 80538 Sector: Renewable Energy, Wind energy Product: EnerVest develops and manages renewable energy projects,...

  16. Denker Wulf AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    navigation, search Name: Denker & Wulf AG Place: Sehestedt, Germany Zip: 24814 Sector: Wind energy Product: Wind project developer, also provides innovative wind energy financing....

  17. EnergieKontor AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: EnergieKontor AG Place: Bremen, Bremen, Germany Zip: 28359 Sector: Wind energy Product: Bremen-based european wind project developer and wind farm operator....

  18. Bullith Batteries AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Batteries AG Place: Ismaning, Germany Zip: 85737 Product: Batteries producer using the lithium-polymer technology. Coordinates: 48.22727, 11.676305 Show Map Loading map......

  19. Solar Fabrik AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zip: 79111 Product: Freiburg-based manufacturer of wafers, PV cells, modules and inverters, largely through acquisitions. References: Solar Fabrik AG1 This article is a...

  20. MAMA Sustainable Incubation AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    for emerging green-markets such as renewable energy, sustainable architecture and water treatment. References: MAMA Sustainable Incubation AG1 This article is a stub. You...

  1. Centrotherm Photovoltaics AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Blaubeuren, Germany Zip: 89143 Sector: Services Product: Provides turnkey manufacturing equipment for crystalline silicon PV cells, and Siemens reactors and engineering...

  2. LEONI Studer AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Studer AG Place: Daniken, Switzerland Zip: 4658 Product: Switzerland-based cable manufacturing firm. The firm also produces PV junction boxes. Coordinates: 50.966671, 5.85...

  3. SolarMarkt AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    navigation, search Name: SolarMarkt AG Place: Freiburg, Germany Zip: 79114 Product: A German PV installation company for small to mid-sized projects and BIPV. References:...

  4. Enginion AG insolvent | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    (CHP) systems. The company's SteamCell product is targeted at the residential, automotive and portable power markets. References: Enginion AG (insolvent )1 This article is...

  5. BGZ Beteiligungsgesellschaft Zukunftsenergien AG | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Zukunftsenergien AG Place: Husum, Germany Zip: 25813 Sector: Solar, Wind energy Product: Finance and management holding, esp. for wind and solar projects....

  6. Pegasus Energietechnik AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG Place: Mhldorf am Inn, Germany Zip: 84453 Sector: Renewable Energy Product: Germany-based renewable energy developer assisting with projects in Europe. References:...

  7. Energiedienst Holding AG EDH | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name: Energiedienst Holding AG (EDH) Place: Laufenburg, Switzerland Zip: 5080 Product: Utility active in Switzerland and Germany. Coordinates:...

  8. Sunseeker Energy Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name: Sunseeker Energy Holding AG Place: Schindellegi, Switzerland Zip: 8834 Sector: Solar Product: Switzerland-based company seeking to developing...

  9. Stangl Semiconductor Equipment AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    German manufacturer of wet chemistry systems for processing silicon and thin-film solar cells. References: Stangl Semiconductor Equipment AG1 This article is a stub. You...

  10. Design, Implementation, and Evaluation of a Hybrid DS/FFH Spread-Spectrum Radio Transceiver

    SciTech Connect (OSTI)

    Olama, Mohammed M.; Killough, Stephen M.; Kuruganti, Teja; Carroll, Thomas E.

    2014-10-06

    In recent years there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their inherent uses in military communications. This is because HSS can accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct-sequence modulation with "fast" frequency-hopping, denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. In this paper, we present the efforts carried out at Oak Ridge National Laboratory toward exploring the design, implementation, and evaluation of a hardware prototypic hybrid DS/FFH spread-spectrum radio transceiver using a single Field Programmable Gate Array (FPGA). The high integration within a single FPGA allows the various subsystems to easily communicate with each other and thereby maintain tight synchronization. We investigate various hopping sequences against robustness to interference and jamming. Experimental results are presented to show the receiver sensitivity, radio data rate evaluation, and jamming-rejection capability of the implemented hybrid DS/FFH spread-spectrum system under widely varying design parameters.

  11. Design, Implementation, and Evaluation of a Hybrid DS/FFH Spread-Spectrum Radio Transceiver

    SciTech Connect (OSTI)

    Olama, Mohammed M; Killough, Stephen M; Kuruganti, Teja; Carroll, Thomas E.

    2014-01-01

    In recent years there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their inherent uses in military communications. This is because HSS can accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct-sequence modulation with "fast" frequency-hopping, denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. In this paper, we present the efforts carried out at Oak Ridge National Laboratory toward exploring the design, implementation, and evaluation of a hybrid DS/FFH spread-spectrum radio transceiver using a single Field Programmable Gate Array (FPGA). The FPGA allows the various subsystems to quickly communicate with each other and thereby maintain tight synchronization. We also investigate various hopping sequences against robustness to interference and jamming. Experimental results are presented that show the receiver sensitivity, radio data-rate/bit-error evaluations, and jamming and interference rejection capabilities of the implemented hybrid DS/FFH spread-spectrum system under widely varying design parameters.

  12. DB-Netz AG Offices

    High Performance Buildings Database

    Hamm, Germany The new office building for DB Netz AG was designed by the collaborative team of Architrav Architects and the Buildings Physics and Technical Building Services group of the University of Karlsruhe. The team developed an energy efficient building concept for the 64,304 sqft office building, located in Hamm, Germany. The design concept of the building is dominated by architectural solutions for ventilation, cooling and lighting. Use of HVAC and electric lighting is minimized as much as possible. 05/15/2015 - 10:35

  13. Visible light driven photocatalysis and antibacterial activity of AgVO{sub 3} and Ag/AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Singh, Anamika; Dutta, Dimple P.; Ballal, A.; Tyagi, A.K.; Fulekar, M.H.

    2014-03-01

    Graphical abstract: - Highlights: Ag/AgVO{sub 3} and pure AgVO{sub 3} nanowires synthesized by sonochemical process. Characterization done using XRD, SEM, TEM, EDX and BET analysis. Visible light degradation of RhB by Ag/AgVO{sub 3} within 45 min. Antibacterial activity of Ag/AgVO{sub 3} demonstrated. - Abstract: Ag/AgVO{sub 3} nanowires and AgVO{sub 3} nanorods were synthesized in aqueous media via a facile sonochemical route. The as-synthesized products were characterized by X-ray diffraction, BrunauerEmmettTeller surface area analysis, scanning electron microscopy together with an energy dispersion X-ray spectrum analysis, transmission electron microscopy and UVvis diffuse reflectance spectroscopy. The results revealed that inert atmosphere promotes the formation of Ag/AgVO{sub 3} nanowires. The photocatalytic studies revealed that the Ag/AgVO{sub 3} nanowires exhibited complete photocatalytic degradation of Rhodamine B within 45 min under visible light irradiation. The antibacterial activity of Ag/AgVO{sub 3} nanowires was tested against Escherechia coli and Bacillus subtilis. The minimum growth inhibitory concentration value was found to be 50 and 10 folds lower than for the antibiotic ciprofloxacin for E. coli and B. subtilis, respectively. The antibacterial properties of the ?-AgVO{sub 3} nanorods prove that in case of the Ag dispersed Ag/AgVO{sub 3} nanowires, the enhanced antibacterial action is also due to contribution from the AgVO{sub 3} support.

  14. Ag

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Secretary or the Commission, 2 as appropriate, shall - (A) make a survey of the causes and extent of damage; and (B) expeditiously submit a report setting forth the results of ...

  15. RENERCO Renewable Energy Concepts AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    RENERCO Renewable Energy Concepts AG Jump to: navigation, search Name: RENERCO Renewable Energy Concepts AG Place: Munich, Germany Zip: D-80336 Sector: Renewable Energy Product:...

  16. Gamesa Energie Deutschland formerly EBV Management Holding AG...

    Open Energy Information (Open El) [EERE & EIA]

    Energie Deutschland formerly EBV Management Holding AG Jump to: navigation, search Name: Gamesa Energie Deutschland (formerly EBV Management Holding AG) Place: Oldenburg, Germany...

  17. Alpen Adria Energie AG AAE | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Alpen Adria Energie AG AAE Jump to: navigation, search Name: Alpen Adria Energie AG (AAE) Place: Ktschach Mauthen, Austria Zip: 9640 Sector: Renewable Energy Product: Utility...

  18. GATE Global Alternative Energy Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energy Holding AG Place: Wrzburg, Bavaria, Germany Zip: 97080 Product: Germany-based biodiesel producer. References: GATE Global Alternative Energy Holding AG1 This article...

  19. European Energy Exchange AG EEX | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energy Exchange AG EEX Jump to: navigation, search Name: European Energy Exchange AG (EEX) Place: Leipzig, Germany Zip: D-04109 Product: Germany's energy exchange, which aims to...

  20. Mepsolar AG aka Munich Energy Partners | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AG aka Munich Energy Partners Jump to: navigation, search Name: Mepsolar AG (aka Munich Energy Partners) Place: Munich, Germany Zip: 81829 Product: Develops utility scale PV...

  1. Hydrodynamic evolution and jet energy loss in Cu + Cu collisions

    SciTech Connect (OSTI)

    Schenke, Bjoern; Jeon, Sangyong; Gale, Charles

    2011-04-15

    We present results from a hybrid description of Cu + Cu collisions using (3 + 1)-dimensional hydrodynamics (music) for the bulk evolution and a Monte Carlo simulation (martini) for the evolution of high-momentum partons in the hydrodynamical background. We explore the limits of this description by going to small system sizes and determine the dependence on different fractions of wounded nucleon and binary collisions scaling of the initial energy density. We find that Cu + Cu collisions are well described by the hybrid description at least up to 20% central collisions.

  2. Cu 2 S 3 complex on Cu(111) as a candidate for mass transport...

    Office of Scientific and Technical Information (OSTI)

    Cu 2 S 3 complex on Cu(111) as a candidate for mass transport enhancement Citation Details In-Document Search Title: Cu 2 S 3 complex on Cu(111) as a candidate for mass transport ...

  3. cu | OpenEI Community

    Open Energy Information (Open El) [EERE & EIA]

    ancient building system architect biomimicry building technology cooling cu daylight design problem energy use engineer fred andreas geothermal green building heat transfer...

  4. Preliminary characterization of interlayer for Be/Cu sintered compacts

    SciTech Connect (OSTI)

    Sakamoto, N.; Kawamura, H.

    1995-09-01

    At present, beryllium is under consideration as a main candidate material for plasma facing components of ITER, because of its many advantages such as low Z, high thermal conductivity, low tritium retention, low activation and so on. Among the different divertor design options, the duplex structure where the beryllium armor is bonded with heat sink structural materials (DS-copper, Cu-Cr-Zr and so on) is under consideration. And plasma facing components will be exposed to high heat load and high neutron flux generated by the plasma. Therefore, it is necessary to develop the reliable bonding technologies between beryllium and heat sink structural materials in order to fabricate plasma facing components which can resist those. Then, we started the bonding technology development of beryllium and copper alloy with FGM (functional gradient material) in order to reduce thermal stress due to the difference of thermal expansion between beryllium and copper alloy. As the interlayers for FGM, eleven kinds of sintered compacts in which the mixing ratio of beryllium powder and oxygen free copper powder is different, were fabricated by the hot press/HIP method. The dimension of each compact is 8mm in diameter, 2mm in thickness. Then, thermal diffusivity and specific heat of these compacts were measured by laser flash method, and thermal conductivity was calculated from those values. From metalographical observation, it became clear that the sintered compacts of mixture of beryllium powder and copper powder contain residual beryllium, copper and two kinds of intermetallic compounds, Be{sub 2}Cu({delta}) and BeCu({gamma}). From the results of thermal characterization, thermal diffusivity of interlayers increased with increase of copper containing ratio. And, specific heat gradually decreased with increase of copper containing ratio.

  5. How important is self-consistency for the dDsC density dependent dispersion correction?

    SciTech Connect (OSTI)

    Brémond, Éric; Corminboeuf, Clémence; Golubev, Nikolay; Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow 119991 ; Steinmann, Stephan N.

    2014-05-14

    The treatment of dispersion interactions is ubiquitous but computationally demanding for seamless ab initio approaches. A highly popular and simple remedy consists in correcting for the missing interactions a posteriori by adding an attractive energy term summed over all atom pairs to standard density functional approximations. These corrections were originally based on atom pairwise parameters and, hence, had a strong touch of empiricism. To overcome such limitations, we recently proposed a robust system-dependent dispersion correction, dDsC, that is computed from the electron density and that provides a balanced description of both weak inter- and intramolecular interactions. From the theoretical point of view and for the sake of increasing reliability, we here verify if the self-consistent implementation of dDsC impacts ground-state properties such as interaction energies, electron density, dipole moments, geometries, and harmonic frequencies. In addition, we investigate the suitability of the a posteriori scheme for molecular dynamics simulations, for which the analysis of the energy conservation constitutes a challenging tests. Our study demonstrates that the post-SCF approach in an excellent approximation.

  6. Modeling Sensitivities to the 20% Wind Scenario Report with the WinDS Model

    SciTech Connect (OSTI)

    Blair, N.; Hand, M.; Short, W.; Sullivan, P.

    2008-06-01

    In May 2008, DOE published '20% Wind Energy by 2030', a report which describes the costs and benefits of producing 20% of the nation's projected electricity demand in 2030 from wind technology. The total electricity system cost resulting from this scenario was modestly higher than a scenario in which no additional wind was installed after 2006. NREL's Wind Deployment System (WinDS) model was used to support this analysis. With its 358 regions, explicit treatment of transmission expansion, onshore siting considerations, shallow- and deep-water wind resources, 2030 outlook, explicit financing assumptions, endogenous learning, and stochastic treatment of wind resource variability, WinDS is unique in the level of detail it can bring to this analysis. For the 20% Wind Energy by 2030 analysis, the group chose various model structures (such as the ability to wheel power within an interconnect), and the wind industry agreed on a variety of model inputs (such as the cost of transmission or new wind turbines). For this paper, the analysis examined the sensitivity of the results to variations in those input values and model structure choices. These included wind cost and performance improvements over time, seasonal/diurnal wind resource variations, transmission access and costs, siting costs, conventional fuel cost trajectories, and conventional capital costs.

  7. Melt-processing of Y-Ba-Cu-O superconductors for improved levitation

    SciTech Connect (OSTI)

    Balachandran, U.; Zhong, W.; Emerson, J.E.; McDaniel, R.L.

    1994-04-01

    Melt processed bulk YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} (YBCO) superconductors are of considerable interest in the application of low-friction, superconducting permanent magnet bearings and flywheel-energy-storage devices. The mechanisms of enhanced flux pinning in the melt processed samples has been the subject of many investigations. Fine precipitates of Y{sub 2}BaCuO{sub 5} (211) are considered potential flux-pinning sites by many investigators. Several groups have reported the refinement of 211 precipitates through Pt additions. In this paper, the authors describe the melt processing of YBCO with additives such as 211, Pt, and Ag. Large single domain regions are obtained using small SmBa2Cu3O{sub 7{minus}{delta}} (Sm-123) single crystal seeds. The microstructure and levitation forces are measured and reported here.

  8. Sputnik Engineering AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zip: CH-2502 Sector: Solar Product: Manufacturer of SolarMax grid tie inverters for photovoltaic applications. References: Sputnik Engineering AG1 This article is a stub. You can...

  9. SES 21 AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Place: OderdingPolling, Germany Zip: 82398 Sector: Solar Product: A distributor of photovoltaic and solar thermal systems in Germany. References: SES 21 AG1 This article is a...

  10. SolarTec AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    SolarTec AG Place: Munich, Bavaria, Germany Product: Developing a technology it calls Sol*Con- 700x Fresnel concentrators for use with gallium arsenide or germanium cells, also...

  11. Bos ten AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Place: Regensburg-Westenviertel, Germany Zip: 93049 Sector: Solar Product: Partner of Beck Energy in development of a 3.2MW solar PV plant. References: Bos.ten AG1 This article...

  12. Multi Contact AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    firm in the field of renewable energy, produces Solarline - connector systems for photovoltaics. References: Multi-Contact AG1 This article is a stub. You can help OpenEI by...

  13. AG Land 1 | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.145531, -93.432161 Show Map Loading map... "minzoom":false,"mappings...

  14. AG Land 4 | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.206397, -93.325714 Show Map Loading map... "minzoom":false,"mappings...

  15. AG Land 2 | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 41.904231, -93.354864 Show Map Loading map... "minzoom":false,"mappings...

  16. AG Land 3 | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.146061, -93.428028 Show Map Loading map... "minzoom":false,"mappings...

  17. City Solar AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    services for large-scale PV power plants, also has a division called City Solar Invest to develop its own plants. References: City Solar AG1 This article is a stub. You...

  18. Solar Power Partners AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solar Product: Small Solar project developer with projects located in South Africa and France. References: Solar Power Partners AG1 This article is a stub. You can help OpenEI by...

  19. E ON AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    E.ON AG Place: Dusseldorf, North Rhine-Westphalia, Germany Zip: 40479 Sector: Renewable Energy Product: Dusseldorf-based company that operates as a public utility in the...

  20. Science DMZ Implemented at CU Boulder

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CU Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU ...

  1. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 New Hampshire - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle ...

  2. PIA - Form EIA-475 A/G Residential Energy Consumption Survey...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Form EIA-475 AG Residential Energy Consumption Survey PIA - Form EIA-475 AG Residential Energy Consumption Survey PIA - Form EIA-475 AG Residential Energy Consumption Survey PIA ...

  3. Ag on Si(111) from basic science to application

    SciTech Connect (OSTI)

    Belianinov, Aleksey

    2012-04-04

    In our work we revisit Ag and Au adsorbates on Si(111)-7x7, as well as experiment with a ternary system of Pentacene, Ag and Si(111). Of particular interest to us is the Si(111)-({radical}3x{radical}3)R30{degree}Ag (Ag-Si-{radical}3 hereafter). In this thesis I systematically e plore effects of Ag deposition on the Ag-Si-{radical}3 at different temperatures, film thicknesses and deposition fluxes. The generated insight of the Ag system on the Si(111) is then applied to generate novel methods of nanostructuring and nanowire growth. I then extend our expertise to the Au system on the Ag-Si(111) to gain insight into Au-Si eutectic silicide formation. Finally we explore behavior and growth modes of an organic molecule on the Ag-Si interface.

  4. Template synthesis of Ag/AgCl microrods and their efficient visible light-driven photocatalytic performance

    SciTech Connect (OSTI)

    Chen, Hua; Xiao, Liang; Huang, Jianhua

    2014-09-15

    Highlights: Preparation ofAg/AgCl microrods by reaction of Ag{sub 2}WO{sub 4} microrods with NaCl solution. Generation of metallic Ag is induced by the ambient light in the synthesis process. Ag/AgCl shows excellent visible light-driven photodegradation of organic dyes. - Abstract: Ag/AgCl microrods, aggregated by nanoparticles with a diameter ranging from 100 nm to 2 ?m, were prepared by an ion-exchange reaction at 80 C between Ag{sub 2}WO{sub 4} template and NaCl solution. The existence of metallic Ag species was confirmed by XRD, DRS and XPS measurements. Ag/AgCl microrods showed excellent photocatalytic activity for the degradation of rhodamine B and methylene blue under visible light irradiation. The degradation rate constants of rhodamine B and methylene blue are 0.176 and 0.114 min{sup ?1}, respectively. The cycling photodegradation experiments suggest that Ag/AgCl microds could be employed as stable plasmonic photocatalysts for the degradation of organic dyes under visible light irradiation.

  5. Characterization of Ag/Bi{sub 2}Sr{sub 2}Ca{sub n-1}O{sub 2n+4} interfacial resistivity.

    SciTech Connect (OSTI)

    Fang, Y.; Danyluk, S.; Lanagan, M. T.; Youngdahl, C. A.; Xu, X.; Numata, K.; Energy Technology; Georgia Inst. of Tech.; Mitsui Mining and Smelting Co. Ltd.

    1995-10-10

    Silver contacts to single-crystal Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub x} (Bi-2212) and polycrystalline (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} (B-2223) were prepared by sputtering or sinter-forging techniques. The interfacial resistivity of Ag/Bi-2212, defined as interfacial resistance times contact area, decreased from 10{sup -4} to 10{sup -10} {Omega} cm{sup 2} at 77 K when the thermal annealing time increased from 1 to 14 h at 600 C; it was also a function of the annealing temperature. The lowest interfacial resistivity of Ag/Bi-2223 that was sinter-forged at 840-845 C for 1 h was 10{sup -9} {Omega} cm{sup 2} at 77 K. Experimental data are compared with intrinsic interfacial resistivity and resistivity values found in the literature.

  6. Analysis, optimization, and implementation of a hybrid DS/FFH spread-spectrum technique for smart grid communications

    SciTech Connect (OSTI)

    Olama, Mohammed M.; Ma, Xiao; Killough, Stephen M.; Kuruganti, Teja; Smith, Stephen F.; Djouadi, Seddik M.

    2015-03-12

    In recent years, there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their inherent uses in military communications. This is because HSS can accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct sequence modulation with fast frequency hopping, denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. In this paper, error-probability analyses are performed for a hybrid DS/FFH system over standard Gaussian and fading-type channels, progressively including the effects from wide- and partial-band jamming, multi-user interference, and varying degrees of Rayleigh and Rician fading. In addition, an optimization approach is formulated that minimizes the bit-error performance of a hybrid DS/FFH communication system and solves for the resulting system design parameters. The optimization objective function is non-convex and can be solved by applying the Karush-Kuhn-Tucker conditions. We also present our efforts toward exploring the design, implementation, and evaluation of a hybrid DS/FFH radio transceiver using a single FPGA. Numerical and experimental results are presented under widely varying design parameters to demonstrate the adaptability of the waveform for varied harsh smart grid RF signal environments.

  7. Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants

    SciTech Connect (OSTI)

    Zhou, Wenhui; Cao, Minhua Li, Na; Su, Shuangyue; Zhao, Xinyu; Wang, Jiangqiang; Li, Xianghua; Hu, Changwen

    2013-06-01

    Graphical abstract: Ag@Ag{sub x}H{sub 3?x}PW12O40 (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant, which show a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation. - Highlights: A new visible-light driven photocatalyst Ag@Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} was designed. The photocatalyst shows a high activity for the degradation of methyl blue. The high activity can be ascribed to the synergy of photoexcited AgHPW and Ag. - Abstract: Ag@Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant. They show strong absorption in the visible region because of the localized surface plasmon resonance (LSPR) of Ag NPs. This plasmonic photocatalyst shows a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation, which could be attributed to the highly synergy of photoexcited Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} (AgHPW) and plasmon-excited Ag NPs and the confinement effects at interfaces between polyoxometalates (POMs) and silver. POM anions have redox ability and high photocatalytic activity, whereas Ag NPs could effectively accelerate the separation of electrons and holes, both of which contribute to their high activity.

  8. AgFe Management Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    AgFe Management Ltd Jump to: navigation, search Name: AgFe Management Ltd Place: London, England, United Kingdom Zip: W11 1QF Product: London-based, Financial Asset Management and...

  9. SiC Processing AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    SiC Processing AG Jump to: navigation, search Name: SiC Processing AG Place: Hirschau, Germany Zip: 92242 Sector: Solar Product: Offers management and recycling of slurry for solar...

  10. E ON Energy from Waste AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    from Waste AG Jump to: navigation, search Name: E.ON Energy from Waste AG Place: Helmstedt, Lower Saxony, Germany Zip: 38350 Product: Lower Saxony-based E.ON subsidiary is the...

  11. S R Biogas Energiesysteme AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Energiesysteme AG Jump to: navigation, search Name: S&R Biogas Energiesysteme AG Place: Frankfurt am Main, Hessen, Germany Zip: 60598 Product: S&R Biogas Energiesysteme is a biogas...

  12. Organic pollutant photodecomposition by Ag/KNbO3 nanocomposites...

    Office of Scientific and Technical Information (OSTI)

    In this study, Ag nanoparticles supported on well-defined perovskite orthorhombic KNbO3 ... slab models of KNbO3 (101) are employed to mimic large supportedmore Ag nanoparticles. ...

  13. Materials Data on Cu2Ag2O3 (SG:141) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Structural and magnetic phase transitions in CeCu6-xTx (T = Ag...

    Office of Scientific and Technical Information (OSTI)

    ... Type: Accepted Manuscript Journal Name: Physical Review. B, Condensed Matter and Materials ... Export Metadata Endnote Excel CSV XML Save to My Library Send to Email Send to Email ...

  15. The BNL AGS accelerator complex status and future plans

    SciTech Connect (OSTI)

    Tanaka, Mitsuyoshi

    1997-05-01

    This paper describes the present performance and capability of the BNL AGS accelerator complex and possible future intensity upgrade plans. In 1995, the AGS reached its design upgrade goal of 6.0 x 10(exp 13) ppp with the Booster. The AGS with a new fast extracted beam (FEB) system is able to perform single bunch multiple extraction at 30 Hz per AGS cycle for the g-2 experiment and for RHIC injection.

  16. EA-261 UBS AG, London Branch | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1 UBS AG, London Branch EA-261 UBS AG, London Branch Order authorizing UBS AG, London Branch to export electric energy to Mexico. EA-261 UBS AG, London Branch (24.57 KB) More Documents & Publications EA-184 Morgan Stanley Capital Group Inc. EA-167 PG&E Energy Trading-Power, L.P EA-181 H.Q Energy Services (U.S

  17. Inkjet Printed Metallizations for Cu(In1-xGax)Se2 Photovoltaic Cells

    SciTech Connect (OSTI)

    Hersh, P. A.; Curtis, C. J.; van Hest, M. F. A. M.; Kreuder, J. J.; Pasquarelli, R.; Miednaer, A.; Ginley, D. S.

    2011-12-01

    This study reports the inkjet printing of Ag front contacts on Aluminum doped Zinc Oxide (AZO)/intrinsic Zinc Oxide (i-ZnO)/CdS/Cu(In{sub 1-x}Ga{sub x})Se{sub 2} (CIGS)/Mo thin film photovoltaic cells. The printed Ag contacts are being developed to replace the currently employed evaporated Ni/Al bi-layer contacts. Inkjet deposition conditions were optimized to reduce line resistivity and reduce contact resistance to the Al:ZnO layer. Ag lines printed at a substrate temperature of 200 C showed a line resistivity of 2.06 {mu}{Omega} {center_dot} cm and a contact resistance to Al:ZnO of 8.2 {+-} 0.2 m{Omega} {center_dot} cm{sup 2} compared to 6.93 {+-} 0.3 m{Omega} {center_dot} cm{sup 2} for thermally evaporated contacts. These deposition conditions were used to deposit front contacts onto high quality CIGS thin film photovoltaic cells. The heating required to print the Ag contacts caused the performance to degrade compared to similar devices with evaporated Ni/Al contacts that were not heated. Devices with inkjet printed contacts showed 11.4% conversion efficiency compared to 14.8% with evaporated contacts. Strategies to minimize heating, which is detrimental for efficiency, during inkjet printing are proposed.

  18. Property:NEPA CU Document | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    CU Document Jump to: navigation, search Property Name NEPA CU Document Property Type Page Description CU files for NEPA Docs. Typically Casual Use Documentation consists of a...

  19. Thermodynamic estimation of minor element distribution between immiscible liquids in Fe-Cu-based metal phase generated in melting treatment of municipal solid wastes

    SciTech Connect (OSTI)

    Lu, X.; Nakajima, K.; Sakanakura, H.; Matsubae, K.; Bai, H.; Nagasaka, T.

    2012-06-15

    Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Two liquids separation of metal occurs in the melting of municipal solid waste. Black-Right-Pointing-Pointer The distribution of PGMs etc. between two liquid metal phases is studied. Black-Right-Pointing-Pointer Quite simple thermodynamic model is applied to predict the distribution ratio. Black-Right-Pointing-Pointer Au and Ag originated from WEEE are found to be concentrated into Cu-rich phase. - Abstract: Waste electrical and electronic equipment (WEEE) has become an important target in managing material cycles from the viewpoint of not only waste management and control of environmental pollution but also resource conservation. This study investigated the distribution tendency of trace elements in municipal solid waste (MSW) or incinerator ash, including valuable non-ferrous metals (Ni, Co, Cr, Mn, Mo, Ti, V, W, Zr), precious group metals (PGMs) originated from WEEE (Ag, Au, Pd, Pt), and others (Al, B, Pb, Si), between Fe-rich and Cu-rich metal phases by means of simple thermodynamic calculations. Most of the typical alloying elements for steel (Co, Cr, Mo, Nb, Ni, Si, Ti, V, and W) and Rh were preferentially distributed into the Fe-rich phase. PGMs, such as Au, Ag, and Pd, were enriched in the Cu-rich phase, whereas Pt was almost equally distributed into both phases. Since the primary metallurgical processing of Cu is followed by an electrolysis for refining, and since PGMs in crude copper have been industrially recovered from the resulting anode slime, our results indicated that Ag, Au, and Pd could be effectively recovered from MSW if the Cu-rich phase could be selectively collected.

  20. High intensity proton operation at the Brookhaven AGS accelerator complex

    SciTech Connect (OSTI)

    Ahrens, L.A.; Blaskiewicz, M.; Bleser, E.; Brennan, J.M.; Gardner, C.; Glenn, J.W.; Onillon, E.; Reece, R.K.; Roser, T.; Soukas, A.

    1994-08-01

    With the completion of the AGS rf upgrade, and the implementation of a transition {open_quotes}jump{close_quotes}, all of accelerator systems were in place in 1994 to allow acceleration of the proton intensity available from the AGS Booster injector to AGS extraction energy and delivery to the high energy users. Beam commissioning results with these new systems are presented. Progress in identifying and overcoming other obstacles to higher intensity are given. These include a careful exploration of the stopband strengths present on the AGS injection magnetic porch, and implementation of the AGS single bunch transverse dampers throughout the acceleration cycle.

  1. Enhanced thermal stability of Ag nanorods through capping

    SciTech Connect (OSTI)

    Bachenheimer, Lou; Elliott, Paul; Stagon, Stephen; Huang, Hanchen

    2014-11-24

    Ag nanorods may serve as sensors in the detection of trace amounts of chemical agents, even single molecules, through surface enhanced Raman spectroscopy (SERS). However, thermal coarsening of Ag nanorods near room temperature limits their applications. This letter proposes the use of a thin oxide capping layer to enhance the thermal stability of Ag nanorods beyond 100?C. Using electron microscopy characterization and SERS tests, the authors show that the proposed method is effective in stabilizing both morphology and sensitivity of Ag nanorods. The results of this work extend the applicability of Ag nanorods as chemical sensors to higher temperatures.

  2. Solidification analysis of a centrifugal atomizer using the Al-32.7wt.% Cu alloy

    SciTech Connect (OSTI)

    Osborne, M.G.

    1998-02-23

    A centrifugal atomizer (spinning disk variety) was designed and constructed for the production of spherical metal powders, 100--1,000 microns in diameter in an inert atmosphere. Initial atomization experiments revealed the need for a better understanding of how the liquid metal was atomized and how the liquid droplets solidified. To investigate particle atomization, Ag was atomized in air and the process recorded on high-speed film. To investigate particle solidification, Al-32.7 wt.% Cu was atomized under inert atmosphere and the subsequent particles were examined microscopically to determine solidification structure and rate. This dissertation details the experimental procedures used in producing the Al-Cu eutectic alloy particles, examination of the particle microstructures, and determination of the solidification characteristics (e.g., solidification rate) of various phases. Finally, correlations are proposed between the operation of the centrifugal atomizer and the observed solidification spacings.

  3. Movable Genetic Elements: Detection of Changes in Maize DNA at the Shrunken Locus Due to the Intervention of Ds Elements

    DOE R&D Accomplishments [OSTI]

    Burr, B.; Burr, F.A.

    1980-05-28

    This report describes our initial attempts at the molecular characterization of a maize controlling element. We have prepared a cDNA probe and used it to detect changes at a locus where Ds elements are found. Evidence of their presence are indicated by changes in the restriction patterns, but there is as yet no information on the physical nature of the controlling elements nor on the kinds of rearrangements they cause.

  4. Analysis, optimization, and implementation of a hybrid DS/FFH spread-spectrum technique for smart grid communications

    DOE PAGES-Beta [OSTI]

    Olama, Mohammed M.; Ma, Xiao; Killough, Stephen M.; Kuruganti, Teja; Smith, Stephen F.; Djouadi, Seddik M.

    2015-03-12

    In recent years, there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their inherent uses in military communications. This is because HSS can accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct sequence modulation with fast frequency hopping, denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. Inmore » this paper, error-probability analyses are performed for a hybrid DS/FFH system over standard Gaussian and fading-type channels, progressively including the effects from wide- and partial-band jamming, multi-user interference, and varying degrees of Rayleigh and Rician fading. In addition, an optimization approach is formulated that minimizes the bit-error performance of a hybrid DS/FFH communication system and solves for the resulting system design parameters. The optimization objective function is non-convex and can be solved by applying the Karush-Kuhn-Tucker conditions. We also present our efforts toward exploring the design, implementation, and evaluation of a hybrid DS/FFH radio transceiver using a single FPGA. Numerical and experimental results are presented under widely varying design parameters to demonstrate the adaptability of the waveform for varied harsh smart grid RF signal environments.« less

  5. Analysis, Optimization, and Implementation of a Hybrid DS/FFH Spread-Spectrum Technique for Smart Grid Communications

    SciTech Connect (OSTI)

    Olama, Mohammed M; Ma, Xiao; Killough, Stephen M; Kuruganti, Teja; Smith, Stephen Fulton; Djouadi, Seddik M

    2015-01-01

    In recent years, there has been great interest in using hybrid spread-spectrum (HSS) techniques for commercial applications, particularly in the Smart Grid, in addition to their inherent uses in military communications. This is because HSS can accommodate high data rates with high link integrity, even in the presence of significant multipath effects and interfering signals. A highly useful form of this transmission technique for many types of command, control, and sensing applications is the specific code-related combination of standard direct sequence modulation with fast frequency hopping, denoted hybrid DS/FFH, wherein multiple frequency hops occur within a single data-bit time. In this paper, error-probability analyses are performed for a hybrid DS/FFH system over standard Gaussian and fading-type channels, progressively including the effects from wide- and partial-band jamming, multi-user interference, and varying degrees of Rayleigh and Rician fading. In addition, an optimization approach is formulated that minimizes the bit-error performance of a hybrid DS/FFH communication system and solves for the resulting system design parameters. The optimization objective function is non-convex and can be solved by applying the Karush-Kuhn-Tucker conditions. We also present our efforts toward exploring the design, implementation, and evaluation of a hybrid DS/FFH radio transceiver using a single field-programmable gate array (FPGA). Numerical and experimental results are presented under widely varying design parameters to demonstrate the adaptability of the waveform for varied harsh smart grid RF signal environments.

  6. Quasi-two-dimensional Ag nanoparticle formation in silica by Xe ion irradiation and subsequent Ag ion implantation

    SciTech Connect (OSTI)

    Wang, Jun; Jia, Guangyi; Mu, Xiaoyu; Liu, Changlong

    2013-04-01

    Ag nanoparticles were fabricated in silica by Xe ion irradiation and subsequent Ag ion implantation, which distributed in a depth range from 4.8 to 14.3 nm, rather than dispersed from surface to a depth of 24.7 nm when no irradiation was made in advance. In addition, the suppression of Ag implants' sputtering loss was also evidenced by a greatly increased Ag content in the prepared sample. These results are mainly due to the defect-enhanced in-beam particle growth. Further, formation of polycrystalline Ag nanoparticles was revealed, whose effect on optical absorption was discussed according to the electron mean-free-path mode.

  7. X-ray diffraction analysis of LiCu{sub 2}O{sub 2} crystals with additives of silver atoms

    SciTech Connect (OSTI)

    Sirotinkin, V. P. Bush, A. A.; Kamentsev, K. E.; Dau, H. S.; Yakovlev, K. A.; Tishchenko, E. A.

    2015-09-15

    Silver-containing LiCu{sub 2}O{sub 2} crystals up to 4 × 8 × 8 mm in size were grown by the crystallization of 80(1-x)CuO · 20{sub x}AgNO{sub 3} · 20Li{sub 2}CO{sub 3} (0 ≤ x ≤ 0.5) mixture melt. According to the X-ray spectral and Rietveld X-ray diffraction data, the maximum amount of silver incorporated in the LiCu{sub 2}O{sub 2} structure is about 4 at % relative to the copper content. It was established that silver atoms occupy statistically crystallographic positions of lithium atoms. The incorporation of silver atoms is accompanied by a noticeable increase in parameter c of the LiCu{sub 2}O{sub 2} rhombic unit cell, a slight increase in parameter a, and a slight decrease in parameter b.

  8. Thermal-mechanical properties of epoxy-impregnated Bi-2212/Ag composite

    SciTech Connect (OSTI)

    Li, Pei; Wang, Yang; Godeke, Arno; Ye, Liyang; Flanagan, Gene; Shen, Tengming

    2014-11-26

    In this study, knowledge of the thermal-mechanical properties of epoxy/superconductor/insulation composite is important for designing, fabricating, and operating epoxy impregnated high field superconducting magnets near their ultimate potentials. We report measurements of the modulus of elasticity, Poisson's ratio, and the coefficient of thermal contraction of epoxy-impregnated composite made from the state-of-the-art powder-in-tube multifilamentary Ag/Bi2Sr2CaCu2Ox round wire at room temperature and cryogenic temperatures. Stress-strain curves of samples made from single-strand and Rutherford cables were tested under both monotonic and cyclic compressive loads, with single strands insulated using a thin TiO2 insulation coating and the Rutherford cable insulated with a braided ceramic sleeve.

  9. Thermal-mechanical Properties of Epoxy-impregnated Bi-2212/Ag Composite

    SciTech Connect (OSTI)

    Li, Pei [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States); Wang, Yang [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States); Godeke, Arno [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Ye, Liyang [North Carolina State Univ., Raleigh, NC (United States); Flanagan, Gene [Muons Inc., Batavia, IL (United States); Shen, Tengming [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States)

    2014-11-26

    Knowledge of the thermal-mechanical properties of epoxy/superconductor/insulation composite is important for designing, fabricating, and operating epoxy impregnated high field superconducting magnets near their ultimate potentials. We report measurements of the modulus of elasticity, Poissons ratio, and the coefficient of thermal contraction of epoxy-impregnated composite made from the state-of-the-art powder-in-tube multifilamentary Ag/Bi2Sr2CaCu2Ox round wire at room temperature and cryogenic temperatures. Stress-strain curves of samples made from single-strand and Rutherford cables were tested under both monotonic and cyclic compressive loads, with single strands insulated using a thin TiO2 insulation coating and the Rutherford cable insulated with a braided ceramic sleeve.

  10. Thermal-mechanical properties of epoxy-impregnated Bi-2212/Ag composite

    DOE PAGES-Beta [OSTI]

    Li, Pei; Wang, Yang; Fermi National Accelerator Lab.; Godeke, Arno; National High Magnetic Field Lab., Tallahassee, FL; Ye, Liyang; Fermi National Accelerator Lab.; Flanagan, Gene; Shen, Tengming

    2014-11-26

    In this study, knowledge of the thermal-mechanical properties of epoxy/superconductor/insulation composite is important for designing, fabricating, and operating epoxy impregnated high field superconducting magnets near their ultimate potentials. We report measurements of the modulus of elasticity, Poisson's ratio, and the coefficient of thermal contraction of epoxy-impregnated composite made from the state-of-the-art powder-in-tube multifilamentary Ag/Bi2Sr2CaCu2Ox round wire at room temperature and cryogenic temperatures. Stress-strain curves of samples made from single-strand and Rutherford cables were tested under both monotonic and cyclic compressive loads, with single strands insulated using a thin TiO2 insulation coating and the Rutherford cable insulated with a braided ceramicmore » sleeve.« less

  11. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.

    2010-11-01

    The flux of atomic oxygen generated in a electron cyclotron resonance (ECR) microwave plasma source was quantified by two different methods. The commonly applied approach of monitoring the frequency change of a silver-coated quartz crystal microbalance (QCM) deposition rate monitor as the silver is oxidized was found to underestimate the atomic oxygen flux by an order of magnitude compared to a more direct deposition approach. In the mixed-phase Ag/Ag2O deposition method, silver films were deposited in the presence of the plasma such that the films were partially oxidized to Ag2O; x-ray photoelectron spectroscopy (XPS) was utilized for quantification of the oxidized fraction. The inaccuracy of the QCM oxidation method was tentatively attributed to efficient catalytic recombination of O atoms on the silver surface.

  12. Double dumbbell shaped AgNi alloy by pulsed electrodeposition

    SciTech Connect (OSTI)

    Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy; Narayanan, V. Stephen, A.

    2014-01-28

    Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

  13. Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using...

    Office of Scientific and Technical Information (OSTI)

    Conference: Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using Low Dose In Situ Liquid STEM. Citation Details In-Document Search Title: Monitoring Galvanic ...

  14. High intensity performance and upgrades at the Brookhaven AGS...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 43 PARTICLE ACCELERATORS; BEAM EMITTANCE; BEAM OPTICS; BROOKHAVEN AGS; GEV RANGE; LINEAR ACCELERATORS; MEV RANGE; ...

  15. Solaxis GmbH Regetec Handels AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zip: 47475 Sector: Solar Product: Distributor and installer of photovoltaic modules and solar heating systems. References: Solaxis GmbH (Regetec Handels AG)1 This article is a...

  16. Schnell Z ndstrahlmotoren AG Co KG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zndstrahlmotoren is specialized on the production of dual fuel engines (CHPs) for biogas, dump and sewage gas. References: Schnell Zndstrahlmotoren AG & Co. KG1 This...

  17. EnviTec Biogas AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    EnviTec Biogas AG Place: Saerbeck, North Rhine-Westphalia, Germany Zip: 48369 Product: Plans, finances, installs and commissions biogas systems including technical and biological...

  18. Theoretical study of Ag- and Au-filled skutterudites. | Department...

    Energy.gov (indexed) [DOE]

    theoretical values of thermoelectric properties for Ag-filled skutterudites. stoica.pdf (3.05 MB) More Documents & Publications Thermoelectric Generator Development for ...

  19. EPURON GmbH formerly Voltwerk AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    EPURON GmbH (formerly Voltwerk AG) Place: Hamburg, Germany Zip: 20537 Sector: Solar, Wind energy Product: Develops, finances, implements and operates solar, wind and biogas...

  20. METAL MEDIA FILTERS, AG-1 SECTION FI

    SciTech Connect (OSTI)

    Adamson, D.

    2012-05-23

    One application of metal media filters is in various nuclear air cleaning processes including applications for protecting workers, the public and the environment from hazardous and radioactive particles. To support this application the development of the ASME AG-1 FI Standard on Metal Media has been under way for more than ten years. Development of the proposed section has required resolving several difficult issues associated with operating conditions (media velocity, pressure drop, etc.), qualification testing, and quality acceptance testing. Performance characteristics of metal media are dramatically different than the glass fiber media with respect to parameters like differential pressures, operating temperatures, media strength, etc. These differences make existing data for a glass fiber media inadequate for qualifying a metal media filter for AG-1. In the past much work has been conducted on metal media filters at facilities such as Lawrence Livermore National Laboratory (LLNL) and Savannah River National Laboratory (SRNL) to qualify the media as High Efficiency Particulate Air (HEPA) Filters. Particle retention testing has been conducted at Oak Ridge Filter Test Facility and at Air Techniques International (ATI) to prove that the metal media meets or exceeds the 99.97% particle retention required for a HEPA Filter. Even with his testing, data was lacking to complete an AG-1 FI Standard on metal media. With funding secured by Mississippi State University (MSU) from National Nuclear Security Administration (NNSA), a research test stand is being designed and fabricated at MSU's Institute for Clean Energy Technology (ICET) Facility to obtain qualification data on metal media. This in turn will support required data needed for the FI Standard. The paper will discuss in detail how the test stand at MSU will obtain the necessary data to complete the FI Standard.

  1. Disproportionation of Ag+ by pressure-and heat-induced Xe insertion into Ag-natrolite

    DOE PAGES-Beta [OSTI]

    Seoung, Donghoon; Cynn, Hyunchae; Park, Changyong; Choi, Kwang -Yong; Blom, Douglas A.; Evans, William J.; Kao, Chi -Chang; Vogt, Thomas; Lee, Yongjae

    2011-12-27

    In this study, pressure can drastically alter chemical and physical properties of materials and allow structural phase transitions and chemical reactions to occur that defy much of our understanding gained at ambient conditions. The observation and prediction of new exotic binary phases of sodium chlorides (1) and the auto-dissociat ions of XeF2 and NO2 at high pressures suggests new chemistry is within reach (2). Particularly exciting is the high-pressure chemistry of Xenon, which has been found to react with ice (3) and hydrogen (4) and predicted to form stable Mg-Xe compounds (5) under pressure. We show that Ag16Al16Si24O80 · 16H2Omore » inserts Xe at 1.7 GPa and 250 ° C and Ag+ disproportionates to metallic Ag and Ag2+ which is retained together with Xe within the pores after pressure release. This represents the first case of Xe acting as a chemical mediator based on its adduct forming capabilities within small pores.« less

  2. Microsoft Word - AG Chapter 6 1 Nov 2010 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AG Chapter 6 1 Nov 2010 Microsoft Word - AG Chapter 6 1 Nov 2010 PDF icon Microsoft Word - AG Chapter 6 1 Nov 2010 More Documents & Publications Competition Requirements AcqGuide ...

  3. EECH Group AG formerly European Energy Consult Holding P T Technology...

    Open Energy Information (Open El) [EERE & EIA]

    EECH Group AG formerly European Energy Consult Holding P T Technology AG Jump to: navigation, search Name: EECH Group AG (formerly European Energy Consult Holding, P&T Technology...

  4. Ag/AgBr/g-C{sub 3}N{sub 4}: A highly efficient and stable composite photocatalyst for degradation of organic contaminants under visible light

    SciTech Connect (OSTI)

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Graphical abstract: Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed excellent photocatalytic activities on the degradation of methyl orange (MO) under visible light. The improved photocatalytic performance and stability of Ag/AgBr/g-C{sub 3}N{sub 4} originated from the synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. O{sub 2}?, one of the reactive species, was responsible for the photodegradation of MO compared to H+ and OH. - Highlights: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalyst was reported. Ag/AgBr/g-C{sub 3}N{sub 4} had novel energy band combination between AgBr and g-C{sub 3}N{sub 4}. Synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. Electron trapping role of metallic Ag dominated the stability of Ag/AgBr/g-C{sub 3}N{sub 4}. - Abstract: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts were constructed via depositionprecipitation method and extensively characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UVvis diffuse reflectance spectroscopy (DRS). Under visible light (? > 420 nm), Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed much higher photocatalytic activities than those of Ag/AgBr and g-C{sub 3}N{sub 4} for degradation of methyl orange (MO). 50% Ag/AgBr/g-C{sub 3}N{sub 4} presented the best photocatalytic performance, which was mainly attributed to the synergistic effects of AgBr/g-C{sub 3}N{sub 4} interface and the in situ metallic Ag nanoparticles for efficiently separating electronhole pairs. Furthermore, Ag/AgBr/g-C{sub 3}N{sub 4} remained good photocatalytic activity through 5 times of cycle experiments. Additionally, the radical scavengers experiment indicated that O{sub 2}{sup ?} was the main reactive species for the MO degradation under visible light.

  5. Phase transformation between Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) compounds formed on single crystalline Cu substrate during solid state aging

    SciTech Connect (OSTI)

    Tian, Feifei; Liu, Zhi-Quan Guo, Jingdong

    2014-01-28

    Interfacial reactions between eutectic SnIn and single crystalline Cu during solid-state aging at low temperature were investigated systematically. Three types of phase transformations between Cu(In,Sn){sub 2} layer and Cu{sub 2}(In,Sn) layer were observed, which are Cu(In,Sn){sub 2} grows and Cu{sub 2}(In,Sn) consumes at 40?C, Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) grow simultaneously at 60?C, as well as Cu(In,Sn){sub 2} consumes and Cu{sub 2}(In,Sn) grows at 80 and 100?C. According to physicochemical approach, the chemical reactions at Cu/Cu{sub 2}(In,Sn)/Cu(In,Sn){sub 2}/SnIn interfaces were discussed in detail. It was concluded that the diffusion ability of Cu and In atoms dominated different phase transformations. When diffusion constants k{sub 1In2}?>?8/3k{sub 1Cu2} Cu(In,Sn){sub 2} will grow, and if k{sub 1Cu2}???k{sub 1In2} Cu{sub 2}(In,Sn) will grow. Both Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) can grow in the condition of k{sub 1In2} ? k{sub 1Cu2}. The values of k{sub 1Cu2} and k{sub 1In2} at different temperatures on (100)Cu and (111)Cu substrate were also calculated or estimated by analyzing the growth kinetics of the compound layers.

  6. Phoenix Solar AG formerly Phoenix SonnenStrom | Open Energy Informatio...

    Open Energy Information (Open El) [EERE & EIA]

    Solar AG formerly Phoenix SonnenStrom Jump to: navigation, search Name: Phoenix Solar AG (formerly Phoenix SonnenStrom) Place: Sulzemoos, Germany Zip: 85254 Product: Develops...

  7. Intruder states in odd-mass Ag isotopes

    SciTech Connect (OSTI)

    Rogowski, J.; Alstad, J.; Brant, S.; Daniels, W.R.; De Frenne, D.; Heyde, K.; Jacobs, E.; Kaffrell, N.; Paar, V.; Skarnemark, G.; Trautmann, N. (Institut fuer Kernchemie, Universitaet Mainz, D-6500 Mainz (Federal Republic of Germany) Department of Chemistry, University of Oslo, N-0315 Oslo (Norway) Prirodoslovno-matematicki fakultet, University of Zagreb, 41000 Zagreb (Yugoslavia) Los Alamos National Laboratory, Los Alamos, NM (USA) Laboratorium voor Kernfysica, Proeftuinstraat 86, B-9000 Gent (Belgium) Department of Nuclear Chemistry, Chalmers University of Technology, S-41296 Goeteborg (Sweden))

    1990-12-01

    The information on the coexistence of deformed intruder states and normal spherical hole-core coupled states in odd-mass Ag nuclei has been extended to the neutron-rich isotopes {sup 113}Ag{sub 66} and {sup 115}Ag{sub 68}. Data have been obtained from an investigation of the {gamma} rays following the {beta}{sup {minus}} decay of the {sup 113,115}Pd precursors. A minimum for the excitation energy of the intruder states occurs in {sup 113}Ag{sub 66}, exactly at neutron midshell. The properties of the intruder states in {sup 109,111,113,115}Ag are discussed and a description in the framework of the interacting-boson-fermion model is presented.

  8. Synthesis and photocatalytic performance of an efficient Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} composite photocatalyst under visible light

    SciTech Connect (OSTI)

    Liang, Yinghua; Lin, Shuanglong; Liu, Li; Hu, Jinshan; Cui, Wenquan

    2014-08-15

    Highlights: The plasmatic Ag@AgBr sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts. Ag@AgBr greatly increased visible light absorption for K{sub 2}Ti{sub 4}O{sub 9}. The plamonic photocatalysts exhibited enhanced activity for the degradation of RhB. - Abstract: Ag@AgBr nanoparticle-sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts (Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9}) were prepared by a facile precipitationphotoreduction method. The photocatalytic activities of the Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} nanocomposites were evaluated for photocatalytic degradation of (RhB) under visible light irradiation. The composites exhibited excellent visible light absorption, which was attributable to the surface plasmon effect of Ag nanoparticles. The Ag@AgBr was uniformly scattered on the surface of K{sub 2}Ti{sub 4}O{sub 9} and possessed sizes in the range of 2050 nm. The loading amount of Ag@AgBr was also studied, and was found to influence the absorption spectra of the resulting composites. Approximately 95.9% of RhB was degraded by Ag@AgBr (20 wt.%)/K{sub 2}Ti{sub 4}O{sub 9} after irradiation for 1 h. The stability of the material was also investigated by performing consecutive runs. Additionally, studies performed using radical scavengers indicated that O{sub 2}{sup ?} and Br{sup 0} acted as the main reactive species. Based on the experimental results, a photocatalytic mechanism for organics degradation over Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} photocatalysts was proposed.

  9. The potential effect of metallothionein 2A - 5 A/G single nucleotide polymorphism on blood cadmium, lead, zinc and copper levels

    SciTech Connect (OSTI)

    Kayaalti, Zeliha Aliyev, Vugar; Soeylemezoglu, Tuelin

    2011-10-01

    Metallothioneins (MTs) are low molecular weight, cysteine-rich, metal-binding proteins. Because of their rich thiol groups, MTs bind to the biologically essential metals and perform these metals' homeostatic regulations; absorb the heavy metals and assist with their transportation and extraction. The aim of this study was to investigate the association between the metallothionein 2A (MT2A) core promoter region - 5 A/G single nucleotide polymorphism (SNP) and Cd, Pb, Zn and Cu levels in the blood samples. MT2A polymorphism was determined by the standard polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) technique using the 616 blood samples and the genotype frequencies were found as 86.6% homozygote typical (AA), 12.8% heterozygote (AG) and 0.6% homozygote atypical (GG). Metal levels were analyzed by dual atomic absorption spectrophotometer system and the average levels of Cd, Pb, Zn and Cu in the blood samples were 1.69 {+-} 1.57 ppb, 30.62 {+-} 14.13 ppb, 0.98 {+-} 0.49 ppm and 1.04 {+-} 0.45 ppm, respectively. As a result; highly statistically significant associations were detected between the - 5 A/G core promoter region SNP in the MT2A gene and Cd, Pb and Zn levels (p = 0.004, p = 0.012 and p = 0.002, respectively), but no association was found with Cu level (p = 0.595). Individuals with the GG genotype had statistically lower Zn level and higher Cd and Pb levels in the blood samples than individuals with AA and AG genotypes. This study suggests that having the GG genotype individuals may be more sensitive for the metal toxicity and they should be more careful about protecting their health against the toxic effects of the heavy metals. - Highlights: > MT2A -5A/G SNP has strong effect on the Cd, Pb and Zn levels in the blood. > MT2A GG individuals should be more careful for their health against metal toxicity. > This SNP might be considered as a biomarker for risk of disease related to metals.

  10. Exclusive Production of Ds Ds-, Ds* Ds-, and Ds* Ds*- via e e- Annihilation with Initial-State-Radiation

    SciTech Connect (OSTI)

    del Amo Sanchez, P.; Lees, J.P.; Poireau, V.; Prencipe, E.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Sun, L.; Battaglia, M.; Brown, D.N.; Hooberman, B.; Kerth, L.T.; Kolomensky, Yu.G.; Lynch, G.; Osipenkov, I.L.; Tanabe, T.; /UC, Berkeley /Birmingham U. /Ruhr U., Bochum /British Columbia U. /Brunel U. /Novosibirsk, IYF /UC, Irvine /UC, Riverside /UC, Santa Barbara /UC, Santa Cruz /Caltech /Cincinnati U. /Colorado U. /Colorado State U. /Dortmund U. /Dresden, Tech. U. /Ecole Polytechnique /Edinburgh U. /INFN, Ferrara /Ferrara U. /INFN, Ferrara /INFN, Ferrara /Ferrara U. /INFN, Ferrara /Frascati /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /Indian Inst. Tech., Guwahati /Harvard U. /Heidelberg U. /Humboldt U., Berlin /Imperial Coll., London /Iowa State U. /Iowa State U. /Johns Hopkins U. /Paris U., VI-VII /LLNL, Livermore /Liverpool U. /Queen Mary, U. of London /Royal Holloway, U. of London /Royal Holloway, U. of London /Louisville U. /Mainz U., Inst. Kernphys. /Manchester U. /Maryland U. /Massachusetts U., Amherst /MIT /McGill U. /INFN, Milan /Milan U. /INFN, Milan /INFN, Milan /Milan U. /Mississippi U. /Montreal U. /INFN, Naples /Naples U. /NIKHEF, Amsterdam /NIKHEF, Amsterdam /Notre Dame U. /Ohio State U. /Oregon U. /INFN, Padua /Padua U. /INFN, Padua /INFN, Padua /Padua U. /Paris U., VI-VII /INFN, Perugia /Perugia U. /INFN, Pisa /Pisa U. /INFN, Pisa /Pisa, Scuola Normale Superiore /INFN, Pisa /Pisa U. /INFN, Pisa /Princeton U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /Rostock U. /Rutherford /DAPNIA, Saclay /SLAC /South Carolina U. /Southern Methodist U. /Stanford U., Phys. Dept. /SUNY, Albany /Tel Aviv U. /Tennessee U. /Texas U. /Texas U., Dallas /INFN, Turin /Turin U. /INFN, Trieste /Trieste U. /Valencia U. /Victoria U. /Warwick U. /Wisconsin U., Madison

    2010-10-27

    The authors perform a study of exclusive production of D{sub s}{sup +}D{sub s}{sup -}, D*{sub s}{sup +}D{sub s}{sup -}, and D*{sub s}{sup +}D*{sub s}{sup -} final states in initial-state-radiation events from e{sup +}e{sup -} annihilations at a center-of-mass energy near 10.58 GeV, to search for charmonium 1{sup --} states. The data sample corresponds to an integrated luminosity of 525 fb{sup -1} and was recorded by the BABAR experiment at the PEP-II storage ring. The D{sub s}{sup +} D{sub s}{sup -}, D*{sub s}{sup +}D{sub s}{sup -}, and D*{sub s}{sup +}D*{sub s}{sup -} mass spectra show evidence of the known {psi} resonances. Limits are extracted for the branching ratios of the decays X(4260) {yields} D{sub s}{sup (*)+}D{sub s}{sup (*)-}.

  11. Accelerating Fatigue Testing for Cu Ribbon Interconnects | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Accelerating Fatigue Testing for Cu Ribbon Interconnects Accelerating Fatigue Testing for Cu Ribbon Interconnects Presented at the 2013 Photovoltaic Module Reliability Workshop; ...

  12. Arizona - Natural Gas 2015 Million Cu. Feet Percent...

    Gasoline and Diesel Fuel Update

    4 Arizona - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: ...

  13. Performance and mix measurements of indirect drive Cu doped Be...

    Office of Scientific and Technical Information (OSTI)

    Performance and mix measurements of indirect drive Cu doped Be implosions Citation Details In-Document Search Title: Performance and mix measurements of indirect drive Cu doped Be ...

  14. Origins of optical absorption characteristics of Cu2+ complexes...

    Office of Scientific and Technical Information (OSTI)

    Origins of optical absorption characteristics of Cu2+ complexes in solutions Citation Details In-Document Search Title: Origins of optical absorption characteristics of Cu2+ ...

  15. Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Deactivation Mechanisms of CuZeolite SCR Catalysts in Diesel Application Understanding the Deactivation Mechanisms of CuZeolite SCR Catalysts in Diesel Application To understand ...

  16. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur ...

  17. Work Function Reduction by BaO: Growth of Crystalline Barium Oxide on Ag(001) and Ag(111) Surfaces

    SciTech Connect (OSTI)

    Droubay, Timothy C.; Kong, Lingmei; Chambers, Scott A.; Hess, Wayne P.

    2015-02-01

    Ultrathin films of barium oxide were grown on Ag(001) and Ag(111) using the evaporation of Ba metal in an O2 atmosphere by molecular beam epitaxy. Ultraviolet photoemission spectroscopy reveals that films consisting of predominantly BaO or BaO2 result in Ag(001) work function reductions of 1.74 eV and 0.64 eV, respectively. On the Ag(001) surface, Ba oxide growth is initiated by two-dimensional nucleation of epitaxial BaO, followed by a transition to three-dimensional dual-phase nucleation of epitaxial BaO and BaO2. Three-dimensional islands of primarily BaO2(111) nucleate epitaxially on the Ag(111) substrate leaving large patches of Ag uncovered. We find no indication of chemical reaction or charge transfer between the films and the Ag substrates. These data suggest that the origin of the observed work function reduction is largely due to a combination of BaO surface relaxation and an electrostatic compressive effect.

  18. EA-263 UBS AG, London Branch | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mexico. EA-263 UBS AG, London Branch (35.25 KB) More Documents & Publications EA-232 OGE Energy Resources Inc EA-249 Exelon Generation Company LLC EA-122-A Dynegy Power Marketing,

  19. PVA TePla AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    search Name: PVA TePla AG Place: Asslar, Germany Zip: 35614 Product: Supplier of plants and equipment for vacuum systems, crystal-growing systems and plasma systems, some of...

  20. Otter Tail Ag Enterprises LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Enterprises LLC Jump to: navigation, search Name: Otter Tail Ag Enterprises LLC Place: Fergua Falls, Minnesota Zip: 56537-7518 Product: Developed a 55m gallon ethanol facility in...

  1. SFC Smart Fuel Cell AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zip: D-85649 Product: Smart Fuel Cell designs, develops and manufactures direct methanol fuel cell systems. References: SFC Smart Fuel Cell AG1 This article is a stub. You...

  2. Cu-Cu direct bonding achieved by surface method at room temperature

    SciTech Connect (OSTI)

    Utsumi, Jun [Advanced Technology Research Center, Mitsubishi Heavy Industries, Ltd., 1-8-1 Sachiura, Kanazawa-ku, Yokohama 236-8515 (Japan); Ichiyanagi, Yuko, E-mail: yuko@ynu.ac.jp [Department of Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501 (Japan)

    2014-02-20

    The metal bonding is a key technology in the processes for the microelectromechanical systems (MEMS) devices and the semiconductor devices to improve functionality and higher density integration. Strong adhesion between surfaces at the atomic level is crucial; however, it is difficult to achieve close bonding in such a system. Cu films were deposited on Si substrates by vacuum deposition, and then, two Cu films were bonded directly by means of surface activated bonding (SAB) at room temperature. The two Cu films, with the surface roughness Ra about 1.3nm, were bonded by using SAB at room temperature, however, the bonding strength was very weak in this method. In order to improve the bonding strength between the Cu films, samples were annealed at low temperatures, between 323 and 473 K, in air. As the result, the Cu-Cu bonding strength was 10 times higher than that of the original samples without annealing.

  3. Commissioning of the new AGS MMPS transformers

    SciTech Connect (OSTI)

    Bajon,E.; Badea, V. S.; Bannon, M.; Bonati, R.; Marneris, I. M.; Porqueddu, r.; Roser, T.; Sandberg, J.; Savatteri, S.

    2009-05-04

    The Brookhaven AGS Main Magnet Power Supply (MMPS) is a thyristor control supply rated at 5500 Amps. +/-9000 Volts. The peak magnet power is 50 MWatts. The power supply is fed from a motor/generator manufactured by Siemens. During rectify and invert operation the P Bank power supplies are used. During the flattops the F Bank power supplies are used. The P Bank power supplies are fed from two 23 MVA transformers and the F Bank power supplies are fed from two 5.3 MYA transformers. The fundamental frequency of the F Bank power supplies is 1440 Hz, however the fundamental frequency of the P banks was 720 Hz. It was very important to reduce the ripple during rectify to improve polarized proton operations. For this reason and also because the original transformers were 45 years old we replaced these transformers with new ones and we made the fundamental frequency of both P and F banks 1440 Hz. This paper will highlight the major hurdles that were involved during the installation of the new transformers. It will present waveforms while running at different power levels up to 6MW full load. It will show the transition from the F-Bank power supplies to the P-Banks and also show the improvements in ripple made on the P-Bank power supplies.

  4. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    DOE PAGES-Beta [OSTI]

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  5. Accelerating Fatigue Testing for Cu Ribbon Interconnects (Presentation)

    SciTech Connect (OSTI)

    Bosco, N.; Silverman, T.; Wohlgemuth , J.; Kurtz, S.; Inoue, M.; Sakurai, K.; Shioda, T.; Zenkoh, H.; Miyashita, M.; Tadanori, T.; Suzuki, S.

    2013-05-01

    This presentation describes fatigue experiments and discusses dynamic mechanical loading for Cu ribbon interconnects.

  6. Theoretical study on the CuH + H. -->. Cu + H/sub 2/ reaction pathway

    SciTech Connect (OSTI)

    Ruiz, M.E.; Garcia-Prieto, J.; Poulain, E.; Ozin, G.A.; Poirier, R.A.; Matta, S.M.; Czismadia, I.G.; Gracie, C.; Novaro, O.

    1986-01-16

    Quite recently, experimental results on the CuH + H ..-->.. Cu + H/sub 2/ thermal matrix phase reaction were reported, indicating that it proceeds with no activation barrier, and no evidence exists for an intermediate CuH/sub 2/ species at 10-13 K. Here the authors present a theoretical study of this reaction using variational and perturbational configuration interaction calculations with a relativistic pseudopotential (PSHONDO-CIPSI) set of programs. The results confirm the lack of a barrier and provide an explanation as to why the CuH/sub 2/ species may not be observed. 11 references, 3 figures, 3 tables.

  7. Preparation, characterization and photocatalytic activity of visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites

    SciTech Connect (OSTI)

    Li, Xiaojuan Tang, Duanlian; Tang, Fan; Zhu, Yunyan; He, Changfa; Liu, Minghua Lin, Chunxiang; Liu, Yifan

    2014-08-15

    Highlights: A plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst has been successfully synthesized. Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibit high visible light photocatalytic activity. Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst is stable and magnetically separable. - Abstract: A visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has been successfully synthesized via a depositionprecipitation and photoreduction through a novel one-pot process. X-ray diffraction spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and UVvis diffuse reflectance spectroscopy were employed to investigate the crystal structure, chemical composition, morphology, and optical properties of the as-prepared nanocomposites. The photocatalytic activities of the nanocomposites were evaluated by photodegradation of Rhodamine B (RhB) and phenol under visible light. The results demonstrated that the obtained Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibited higher photocatalytic activity as compared to pure ZnFe{sub 2}O{sub 4}. In addition, the sample photoreduced for 20 min and calcined at 500 C achieved the highest photocatalytic activity. Furthermore, the Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has high stability under visible light irradiation and could be conveniently separated by using an external magnetic field.

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Delaware - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S8. Summary statistics for natural gas - Delaware, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals

  9. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Massachusetts - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S23. Summary statistics for natural gas - Massachusetts, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross

  10. Effect of Ag nanoparticle concentration on the electrical and ferroelectric properties of Ag/P(VDF-TrFE) composite films

    DOE PAGES-Beta [OSTI]

    Paik, Haemin; Choi, Yoon -Young; Hong, Seungbum; No, Kwangsoo

    2015-09-04

    We investigated the effect of the Ag nanoparticles on the ferroelectric and piezoelectric properties of Ag/poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) composite films. We found that the remanent polarization and direct piezoelectric coefficient increased up to 12.14 μC/cm2 and 20.23 pC/N when the Ag concentration increased up to 0.005 volume percent (v%) and decreased down to 9.38 μC/cm2 and 13.45 pC/N when it increased up to 0.01 v%. Further increase in Ag concentration resulted in precipitation of Ag phase and significant leakage current that hindered any meaningful measurement of the ferroelectric and piezoelectric properties. 46% increase of the remanent polarization value and 27% increasemore » of the direct piezoelectric coefficient were observed in the film with the 0.005 v% of the Ag nanoparticles added without significant changes to the crystalline structure confirmed by both X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) experiments. The enhancements of both the ferroelectric and piezoelectric properties are attributed to the increase in the effective electric field induced by the reduction in the effective volume of P(VDF-TrFE) that results in more aligned dipoles.« less

  11. Effect of Ag nanoparticle concentration on the electrical and ferroelectric properties of Ag/P(VDF-TrFE) composite films

    SciTech Connect (OSTI)

    Paik, Haemin; Choi, Yoon -Young; Hong, Seungbum; No, Kwangsoo

    2015-09-04

    We investigated the effect of the Ag nanoparticles on the ferroelectric and piezoelectric properties of Ag/poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) composite films. We found that the remanent polarization and direct piezoelectric coefficient increased up to 12.14 μC/cm2 and 20.23 pC/N when the Ag concentration increased up to 0.005 volume percent (v%) and decreased down to 9.38 μC/cm2 and 13.45 pC/N when it increased up to 0.01 v%. Further increase in Ag concentration resulted in precipitation of Ag phase and significant leakage current that hindered any meaningful measurement of the ferroelectric and piezoelectric properties. 46% increase of the remanent polarization value and 27% increase of the direct piezoelectric coefficient were observed in the film with the 0.005 v% of the Ag nanoparticles added without significant changes to the crystalline structure confirmed by both X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) experiments. The enhancements of both the ferroelectric and piezoelectric properties are attributed to the increase in the effective electric field induced by the reduction in the effective volume of P(VDF-TrFE) that results in more aligned dipoles.

  12. EDDY CURRENT EFFECT OF THE BNL-AGS VACUUM CHAMBER ON THE OPTICS OF THE BNL-AGS SYNCHROTRON.

    SciTech Connect (OSTI)

    TSOUPAS,N.; AHRENS,L.; BROWN,K.A.; GLENN,J.W.; GARDNER,K.

    1999-03-29

    During the acceleration cycle of the AGS synchrotron, eddy currents are generated within the walls of the vacuum chambers of the AGS main magnets. The vacuum chambers have elliptical cross section, are made of inconel material with a wall thickness of 2 mm and are placed within the gap of the combined-function main magnets of the AGS synchrotron. The generation of the eddy currents in the walls of the vacuum chambers, creates various magnetic multipoles, which affect the optics of the AGS machine. In this report these magnetic multipoles are calculated for various time interval starting at the acceleration cycle, where the magnetic field of the main magnet is {approx}0.1 T, and ending before the beam extraction process, where the magnetic field of the main magnet is almost constant at {approx}1.1 T. The calculations show that the magnetic multipoles generated by the eddy-currents affect the optics of the AGS synchrotron during the acceleration cycle and in particular at low magnetic fields of the main magnet. Their effect is too weak to affect the optics of the AGS machine during beam extraction at the nominal energies.

  13. Half-life determination for {sup 108}Ag and {sup 110}Ag

    SciTech Connect (OSTI)

    Zahn, Guilherme S.; Genezini, Frederico A.

    2014-11-11

    In this work, the half-life of the short-lived silver radionuclides {sup 108}Ag and {sup 110}Ag were measured by following the activity of samples after they were irradiated in the IEA-R1 reactor. The results were then fitted using a non-paralizable dead time correction to the regular exponential decay and the individual half-life values obtained were then analyzed using both the Normalized Residuals and the Rajeval techniques, in order to reach the most exact and precise final values. To check the validity of dead-time correction, a second correction method was also employed by means of counting a long-lived {sup 60}Co radioactive source together with the samples as a livetime chronometer. The final half-live values obtained using both dead-time correction methods were in good agreement, showing that the correction was properly assessed. The results obtained are partially compatible with the literature values, but with a lower uncertainty, and allow a discussion on the last ENSDF compilations' values.

  14. Evidence for hybrid surface metallic band in (4??4) silicene on Ag(111)

    SciTech Connect (OSTI)

    Tsoutsou, D. Xenogiannopoulou, E.; Golias, E.; Tsipas, P.; Dimoulas, A.

    2013-12-02

    The electronic band structure of monolayer (4??4) silicene on Ag(111) is imaged by angle resolved photoelectron spectroscopy. A dominant hybrid surface metallic band is observed to be located near the bulk Ag sp-band which is also faintly visible. The two-dimensional character of the hybrid band has been distinguished against the bulk character of the Ag(111) sp-band by means of photon energy dependence experiments. The surface band exhibits a steep linear dispersion around the K{sup }{sub Ag} point and has a saddle point near the M{sup }{sub Ag} point of Ag(111) resembling the ?-band dispersion in graphene.

  15. The AGS Ggamma Meter and Calibrating the Gauss Clock

    SciTech Connect (OSTI)

    Ahrens, Leif

    2014-03-31

    During AGS Polarized Proton acceleration periods, one output from the AGS Ggamma Meter, namely the energy (or Ggamma) calculated from the magnetic field in the AGS main magnets and the beam radius- both measured in particular instant, is used to figure out the times in the AGS magnet acceleration cycle when the beam passes through a particular set of depolarizing resonances. The resonance set occur whenever a particle’s Ggamma (energy*(G/m) becomes nearly equal to n*Qx (i.e. any integer multiplied by the horizontal betatron tune). This deliverable is why the machinery is referred to as the ''Ggamma Meter'' rather than the AGS energy meter. The Ggamma Meter takes as inputs a set of measurements of frequency (F(t)), radius (r(t)), and gauss clock counts (GCC(t)). The other energy (GgammaBr) assumes the field when the gauss clock starts counting is known. The change in field to time t is given by the measured accumulated gauss clock counts multiplied by the gauss clock calibration (gauss/GCC). In order to deal with experimental data, this calibration factor gets an added ad hoc complication, namely a correction dependent on the rate of change the counting rate. The Ggamma meter takes GCC(t) and together with the past history for this cycle calculates B(t).

  16. Progress and status of the AGS Booster project

    SciTech Connect (OSTI)

    Weng, W.T. )

    1989-01-01

    New physics opportunities, such as: rare K-decay, neutrino and heavy ion physics demand that a rapid-cycling high vacuum and high intensity Booster be built for the AGS at Brookhaven National Laboratory. The circumference of the Booster ring is one-quarter that of the AGS. Three modes of operation for various particles are envisioned. For unpolarized protons, four Booster pulses would be injected at a 7.5 Hz repetition rate within a 400 ms flat bottom of the AGS, enabling the present 1.5 {times} 10{sup 13} ppp to be increased to 6 {times} 10{sup 13} ppp. The protons would be accelerated to 1.5 GeV although the bending capability provided for heavy ions would eventually allow protons to be accelerated to 2.5 GeV. For heavy ions the rep rates is about 1 Hz and only one pulse would be injected into the AGS. For polarized protons 20 or so pulses can be stored in the Booster ring before injecting them into the AGS. Provisions for mixed modes of operation into a super cycle has been provided for future needs. In this paper, the lattice design and magnet characteristics will be briefly reviewed and major design issues will be discussed and design choices explained. Finally, the construction status and schedule will be presented. 9 refs., 3 figs.

  17. Complexation and phase evolution at dimethylformamide-Ag(111) interfaces

    DOE PAGES-Beta [OSTI]

    Song, Wentao; Leung, Kevin; Shao, Qian; Gaskell, Karen J.; Reutt-Robey, Janice E.

    2016-09-15

    The interaction of solvent molecules with metallic surfaces impacts many interfacial chemical processes. We investigate the chemical and structure evolution that follows adsorption of the polar solvent dimethylformamide (DMF) on Ag(111). An Ag(DMF)2 coordination complex forms spontaneously by DMF etching of Ag(111), yielding mixed films of the complexes and DMF. Utilizing ultrahigh vacuum scanning tunneling microscopy (UHV-STM), in combination with X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) computations, we map monolayer phases from the 2-D gas regime, consisting of a binary mixture of DMF and Ag(DMF)2, through the saturation monolayer limit, in which these two chemical species phasemore » separate into ordered islands. Structural models for the near-square DMF phase and the chain-like Ag(DMF)2 phase are presented and supported by DFT computation. Interface evolution is summarized in a surface pressure-composition phase diagram, which allows structure prediction over arbitrary experimental conditions. In conclusion, this work reveals new surface coordination chemistry for an important electrolyte-electrode system, and illustrates how surface pressure can be used to tune monolayer phases.« less

  18. Fabrication, characterization and photocatalytic properties of Ag/AgI/BiOI heteronanostructures supported on rectorite via a cation-exchange method

    SciTech Connect (OSTI)

    Chen, Yunfang; Fang, Jianzhang; Lu, Shaoyou; Wu, Yan; Chen, Dazhi; Huang, Liyan; Xu, Weicheng; Zhu, Ximiao; Fang, Zhanqiang

    2015-04-15

    Highlights: • Ag/AgI/BiOI-rectorite was prepared by twice cation-exchange process. • Ag/AgI/BiOI-rectorite photocatalyst possessed SPR and adsorption capacity. • Ag/AgI/BiOI-rectorite exhibited highly photocatalytic activity. • Trapped holes and ·O{sub 2}{sup −} were formed active species in the photocatalytic system. - Abstract: In this work, a new plasmonic photocatalyst Ag/AgI/BiOI-rectorite was prepared via a cation exchange process. The photocatalyst had been characterized by X-ray powder diffraction (XRD), Raman spectra, nitrogen sorption (BET), field-emission scanning electron microscope (FE-SEM), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity, which was evaluated by degradation of rhodamine B (RhB) and bisphenol A (BPA) under visible light irradiation, was enhanced significantly by loading Ag/AgI/BiOI nanoparticles onto rectorite. The photogenerated holes and superoxide radical (·O{sub 2}{sup −}) were both formed as active species for the photocatalytic reactions under visible light irradiation. The existence of metallic Ag particles, which possess the surface plasmon resonance effect, acted as an indispensable role in the photocatalytic reaction.

  19. Advanced Precursor Reaction Processing for Cu(InGa)(SeS)2 Solar Cells

    SciTech Connect (OSTI)

    Shafarman, William N.

    2015-10-12

    This project “Advanced Precursor Reaction Processing for Cu(InGa)(SeS)2 Solar Cells”, completed by the Institute of Energy Conversion (IEC) at the University of Delaware in collaboration with the Department of Chemical Engineering at the University of Florida, developed the fundamental understanding and technology to increase module efficiency and improve the manufacturability of Cu(InGa)(SeS)2 films using the precursor reaction approach currently being developed by a number of companies. Key results included: (1) development of a three-step H2Se/Ar/H2S reaction process to control Ga distribution through the film and minimizes back contact MoSe2 formation; (2) Ag-alloying to improve precursor homogeneity by avoiding In phase agglomeration, faster reaction and improved adhesion to allow wider reaction process window; (3) addition of Sb, Bi, and Te interlayers at the Mo/precursor junction to produce more uniform precursor morphology and improve adhesion with reduced void formation in reacted films; (4) a precursor structure containing Se and a reaction process to reduce processing time to 5 minutes and eliminate H2Se usage, thereby increasing throughput and reducing costs. All these results were supported by detailed characterization of the film growth, reaction pathways, thermodynamic assessment and device behavior.

  20. Oxygen Reduction at Very Low Overpotential on Nanoporous Ag Catalysts

    DOE PAGES-Beta [OSTI]

    Zhou, Yang; Lu, Qi; Zhuang, Zhongbin; Hutchings, Gregory S.; Kattel, Shyam; Yan, Yushan; Chen, Jingguang G.; Xiao, John Q.; Jiao, Feng

    2015-05-07

    Here we report a monolithic nanoporous Ag (np-Ag) material, synthesized using the dealloying method, as high-performance catalysts for ORR in alkaline media. As shown in Scheme 1, when there is insufficient potential input, the O2 molecules are more likely to rebound off from a planar electrode surface (i.e. bulk polycrystalline metal, films made from nanoparticles or nanowires) before they could be reduced. In contrast, they are more likely to be trapped inside the monolithic nanoporous structure, contacting with catalytic surface for multiple time, which greatly enhances the chance for them to be fully reduced. As a result, the np-Ag catalystmore » is able to achieve an equivalent or better ORR performance than the state-of the-art Pt/C catalyst at low overpotentials, which is most desired in electrochemical energy applications for maximizing efficiency.« less

  1. Oxygen Reduction at Very Low Overpotential on Nanoporous Ag Catalysts

    SciTech Connect (OSTI)

    Zhou, Yang; Lu, Qi; Zhuang, Zhongbin; Hutchings, Gregory S.; Kattel, Shyam; Yan, Yushan; Chen, Jingguang G.; Xiao, John Q.; Jiao, Feng

    2015-05-07

    Here we report a monolithic nanoporous Ag (np-Ag) material, synthesized using the dealloying method, as high-performance catalysts for ORR in alkaline media. As shown in Scheme 1, when there is insufficient potential input, the O2 molecules are more likely to rebound off from a planar electrode surface (i.e. bulk polycrystalline metal, films made from nanoparticles or nanowires) before they could be reduced. In contrast, they are more likely to be trapped inside the monolithic nanoporous structure, contacting with catalytic surface for multiple time, which greatly enhances the chance for them to be fully reduced. As a result, the np-Ag catalyst is able to achieve an equivalent or better ORR performance than the state-of the-art Pt/C catalyst at low overpotentials, which is most desired in electrochemical energy applications for maximizing efficiency.

  2. Vibration Testing of Dallas/Maxim iButton Temperature Logger, Model DS1999L, for Flight Qualification on Captive Flight Test Unit?B (CFTU-B)

    SciTech Connect (OSTI)

    Jacobson, G; Lavietes, A

    2005-06-20

    This report documents the flight qualification testing of the Dallas/Maxim iButton temperature logger, model DS1922L, for internal mounting to the W80 Air Launched Cruise Missile (ALCM). A single test was performed utilizing a Labworks Inc. LW-140-110 electro-dynamic vibration system in Building 131, Room 2272, at Lawrence Livermore National Laboratory, Livermore, California. Two DS1922L temperature loggers were tested simultaneously, one horizontally and one vertically. The test consisted of random excitation in the vertical axis for 5-hours. The test spectrum used is a shaped random spectrum defined by the Boeing Company for flight qualification of all modifications flown on ALCM flight tests. The spectrum is defined from 10 to 2000 Hz with a 8.52 g RMS magnitude. The spectrum is given in Table 1 and shown graphically in Figure 1.1.

  3. Comparative study of the alloying effect on the initial oxidation of Cu-Au(100) and Cu-Pt(100)

    SciTech Connect (OSTI)

    Luo, Langli; Zhou, Guangwen; Kang, Yihong; Yang, Judith C.; Su, Dong; Stach, Eric A.

    2014-03-24

    Using in situ transmission electron microscopy, we show that the oxidation of the Cu-Au(100) results in the formation of Cu{sub 2}O islands that deeply embed into the Cu-Au substrate while the oxidation of the Cu-Pt(100) leads to the formation of Cu{sub 2}O islands that highly protrude above the Cu-Pt substrate. Their difference is attributed to the different mobilities of Pt and Au in the Cu base alloys for which the sluggish mobility of Pt in Cu results in trapped Pt atoms at the oxide/alloy interface while the faster mobility of Au in Cu leads to enhanced rehomogenization of the alloy composition.

  4. Field-induced quantum criticality in YbAgGe

    SciTech Connect (OSTI)

    Bud'ko, S.; Canfield, P.

    2008-01-01

    YbAgGe is one of the very few stoichiometric, Yb-based, heavy fermion materials that exhibit field-induced quantum criticality. We will present an overview of thermodynamic and transport measurements in YbAgGe single crystals. Moderate magnetic field (45-90 kOe, depending on orientation) suppresses long range magnetic order, giving rise to non-Fermi-liquid behavior followed at higher field by a crossover to a heavy Fermi-liquid. Given the more accessible temperature and field scales, a non-Fermi liquid region rather than point for T {yields} 0 K may be detected.

  5. Wacker Chemie AG formerly Wacker GmbH | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Wacker Chemie AG formerly Wacker GmbH Jump to: navigation, search Name: Wacker Chemie AG (formerly Wacker GmbH) Place: Munich, Germany Zip: 81737 Sector: Solar Product: German...

  6. Solar World USA not SolarWorld AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    World USA not SolarWorld AG Jump to: navigation, search Name: Solar World USA (not SolarWorld AG) Place: Colorado Springs, Colorado Zip: 80907 Sector: Solar Product: Solar World...

  7. Deutsche Solar AG formerly Bayer Solar GmbH | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Solar AG formerly Bayer Solar GmbH Jump to: navigation, search Name: Deutsche Solar AG (formerly Bayer Solar GmbH) Place: FreibergSachsen, Germany Zip: 9599 Sector: Solar Product:...

  8. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine ...

  9. Bull Solar GmbH Bull Holding AG | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    (Bull Holding AG) Place: North Rhine-Westphalia, Germany Sector: Solar Product: German solar installer. References: Bull Solar GmbH (Bull Holding AG)1 This article is a stub....

  10. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Alabama - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S1. Summary statistics for natural gas - Alabama, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 346 367 402 436 414 Gas Wells R 6,243 R 6,203 R 6,174 R 6,117 6,044 Production

  11. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    2 Alaska - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S2. Summary statistics for natural gas - Alaska, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 2,040 1,981 2,006 2,042 2,096 Gas Wells R 274 R 281 R 300 R 338 329 Production

  12. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Colorado - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S6. Summary statistics for natural gas - Colorado, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 5,963 6,456 6,799 7,771 7,733 Gas Wells R 43,792 R 46,141 R 46,883 R 46,876

  13. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 District of Columbia - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S9. Summary statistics for natural gas - District of Columbia, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic

  14. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Hawaii - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S13. Summary statistics for natural gas - Hawaii, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  15. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Idaho - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S14. Summary statistics for natural gas - Idaho, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  16. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    20 Maine - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S21. Summary statistics for natural gas - Maine, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From

  17. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Mississippi - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S26. Summary statistics for natural gas - Mississippi, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 561 618 581 540 501 Gas Wells R 1,703 R 1,666 R 1,632 R 1,594 1,560

  18. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Montana - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S28. Summary statistics for natural gas - Montana, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 1,956 2,147 2,268 2,377 2,277 Gas Wells R 6,615 R 6,366 R 5,870 R 5,682 5,655

  19. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 New Mexico - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S33. Summary statistics for natural gas - New Mexico, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 12,887 13,791 14,171 14,814 14,580 Gas Wells R 40,231 R 40,441 R 40,119 R

  20. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 New York - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S34. Summary statistics for natural gas - New York, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 988 1,170 1,589 1,731 1,697 Gas Wells R 7,372 R 7,731 R 7,553 R 7,619 7,605

  1. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 North Dakota - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S36. Summary statistics for natural gas - North Dakota, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 5,561 7,379 9,363 11,532 12,799 Gas Wells R 526 R 451 R 423 R 398 462

  2. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    2 Ohio - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S37. Summary statistics for natural gas - Ohio, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 6,775 6,745 7,038 7,257 5,941 Gas Wells R 31,966 R 31,647 R 30,804 R 31,060 26,599

  3. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Oklahoma - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S38. Summary statistics for natural gas - Oklahoma, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 6,723 7,360 8,744 7,105 8,368 Gas Wells R 51,712 R 51,472 R 50,606 R 50,044

  4. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Oregon - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S39. Summary statistics for natural gas - Oregon, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 0 0 0 0 0 Gas Wells R 28 R 24 R 24 R 12 14 Production (million cubic feet) Gross

  5. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    8 Pennsylvania - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S40. Summary statistics for natural gas - Pennsylvania, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 7,046 7,627 7,164 8,481 7,557 Gas Wells R 61,815 R 62,922 R 61,838 R

  6. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    6 Tennessee - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S44. Summary statistics for natural gas - Tennessee, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 52 75 NA NA NA Gas Wells R 1,027 R 1,027 1,089 NA NA Production (million cubic

  7. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    8 Texas - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S45. Summary statistics for natural gas - Texas, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 85,030 94,203 96,949 104,205 105,159 Gas Wells R 139,368 R 140,087 R 140,964 R 142,292

  8. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    0 Utah - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S46. Summary statistics for natural gas - Utah, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 3,119 3,520 3,946 4,249 3,966 Gas Wells R 7,603 R 8,121 R 8,300 R 8,537 8,739 Production

  9. Million Cu. Feet Percent of National Total

    U.S. Energy Information Administration (EIA) (indexed site)

    4 Virginia - Natural Gas 2015 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S48. Summary statistics for natural gas - Virginia, 2011-2015 2011 2012 2013 2014 2015 Number of Wells Producing Natural Gas at End of Year Oil Wells 2 1 1 2 2 Gas Wells R 7,781 R 7,874 7,956 R 8,061 8,111 Production (million

  10. Science DMZ Implemented at CU Boulder

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CU Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU Science DMZ @ Penn & VTTI Science DMZ @ NOAA Science DMZ @ NERSC Science DMZ @ ALS Multi-facility Workflow Case Study Contact Us Technical Assistance: 1 800-33-ESnet (Inside US) 1 800-333-7638 (Inside US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site

  11. Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) with a two-dimensional square lattice of Ag 2+ ions (Ag=silver, Pyz-pyrdzine, S2O8=sulfate)

    SciTech Connect (OSTI)

    Singleton, John; Mc Donald, R; Sengupta, P; Cox, S; Manson, J; Southerland, H; Warter, M; Stone, K; Stephens, P; Lancaster, T; Steele, A; Blundell, S; Baker, P; Pratt, F; Lee, C; Whangbo, M

    2009-01-01

    X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz){sub 2}(S{sub 2}O{sub 8}) consists of 2D square nets of Ag{sup 2+} ions resulting from the corner-sharing of axially elongated AgN{sub 4}O{sub 2} octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, {mu}{sup +}Sr measurements indicate that Ag(pyz){sub 2}(S{sub 2}O{sub 8}) undergoes 3D magnetic ordering below 7.8(3) K.

  12. filedjDsQu

    U.S. Department of Energy (DOE) all webpages (Extended Search)

  13. The AGS Booster main ring power supply system

    SciTech Connect (OSTI)

    Soukas, A.; Hughes, K.; Sandberg, J.; Toldo, F.; Zhang, S.Y. )

    1989-01-01

    The AGS Booster is being designed as a very versatile particle accelerator. Its primary function is to be a high quality injector to the currently operating Alternating Gradient Synchrotron (AGS). The Booster/AGS combination will produce proton intensities greater than 5 {times} 10{sup 13}protons per pulse (ppp), and accelerate heavy ions, with mass up to 200, to a maximum energy of 15 GeV per atomic mass unit (GeV/amu). The power supply for the Booster Main Ring (BMRPS) has to accommodate a wide range of cycles and a wide range of operating parameters. The cycles range from storage for several seconds to rapid cycling at 7.5 Hz. The peak output power is 18 MW. This paper will describe the AGS Booster machine powering requirements, the choice of power supply, the a.c. circuit tie-in and its associated problems and some of the details of the design of the BMRPS. 9 refs., 2 figs.

  14. Water dissociation on Mn(1×1)/Ag(100)

    DOE PAGES-Beta [OSTI]

    Arble, Chris; Tong, Xiao; Giordano, Livia; Ferrari, Anna Maria; Newberg, John T.

    2016-08-19

    In this work we utilize experimental and simulation techniques to examine the molecular level interaction of water with a MnO(1×1) thin film deposited onto Ag(100). The formation of MnO(1×1)/Ag(100) was characterized by low energy electron diffraction and scanning tunneling microscopy. Density functional theory (DFT) shows MnO(1×1) is thermodynamically more stable than MnO(2×1) by –0.4 eV per MnO. Upon exposure to 2.5 Torr water vapor at room temperature, X-ray photoemission spectroscopy results show extensive surface hydroxylation attributed to reactivity at MnO(1×1) terrace sites. DFT calculations of a water monomer on MnO(1×1)/Ag(100) show the dissociated form is energetically more favorable than molecularmore » adsorption, with a hydroxylation activation barrier 0.4 eV per H2O. Lastly, these results are discussed and contrasted with previous studies of MgO/Ag(100) which show a stark difference in behavior for water dissociation.« less

  15. Beam energy evolution of HBT systematics at the AGS

    SciTech Connect (OSTI)

    Best, D.; Ajitanand, N.N.; Alexander, J.M.; Anderson, M.; Brady,F.P.; Case, T.; Caskey, W.; Cebra, D.; Chance, J.L.; Chung, P.; Cole, B.; Crowe, K.; Das, A.C.; Draper, J.E.; Gilkes, M.L.; Gushue, S.; Heffner,M.; Hirsch, A.S.; Hjort, E.L.; Huo, L.; Justice, M.; Kaplan, M.; Keane,D.; Kintner, J.C.; Klay, J.; Krofcheck, D.; Lacey, R.A.; Lisa, M.A.; Liu,H.; Liu, Y.M.; McGrath, R.; Milosevich, Z.; Odyniec, G.; Olson, D.L.; Panitkin, S.Y.; Pinkenburg, C.; Porile, N.T.; Rai, G.; Ritter, H.G.; Romero, J.L.; Scharenberg, R.P.; Schroeder, L.S.; Srivastava, B.; Stone,N.T.B.; Symons, T.J.M.; Wang, S.; Wells, R.; Whitfield, J.; Wienold, T.; Witt, R.; Wood, L.; Yang, X.; Zhang, W.; Zhang, Y.; E895 Collaboration

    1999-07-31

    We present preliminary results of the first pi interferometry (HBT) excitation function at intermediate AGS energies. The beam energy evolution of the correlations' dependence on mr:centrality, and emission angle with respect to the reaction I,lane are discussed. Comparisons with predictions of the RQMD cascade model are made.

  16. The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst

    Energy.gov [DOE]

    Examines the effect of hydrothermal aging on the Nox reduction over a commercial Cu-zeolite SCR catalyst.

  17. Cu(II) promotes amyloid pore formation

    SciTech Connect (OSTI)

    Zhang, Hangyu; Rochet, Jean-Christophe; Stanciu, Lia A.

    2015-08-14

    The aggregation of α-synuclein is associated with dopamine neuron death in Parkinson's disease. There is controversy in the field over the question of which species of the aggregates, fibrils or protofibrils, are toxic. Moreover, compelling evidence suggested the exposure to heavy metals to be a risk of PD. Nevertheless, the mechanism of metal ions in promoting PD remains unclear. In this research, we investigated the structural basis of Cu(II) induced aggregation of α-synuclein. Using transmission electron microscopy experiments, Cu(II) was found to promote in vitro aggregation of α-synuclein by facilitating annular protofibril formation rather than fibril formation. Furthermore, neuroprotective baicalein disaggregated annular protofibrils accompanied by considerable decrease of β-sheet content. These results strongly support the hypothesis that annular protofibrils are the toxic species, rather than fibrils, thereby inspiring us to search novel therapeutic strategies for the suppression of the toxic annular protofibril formation. - Highlights: • Cu(II) promoted the annular protofibril formation of α-synuclein in vitro. • Cu(II) postponed the in vitro fibrillization of α-synuclein. • Neuroprotective baicalein disaggregated annular protofibrils.

  18. OPERATIONS AND PERFORMANCE OF RHIC AS A CU-CU COLLIDER.

    SciTech Connect (OSTI)

    PILAT, R.; AHRENS, L.; BAI, M.; BARTON, D.S.; ET AL.

    2005-05-16

    The 5th year of RHIC operations, started in November 2004 and expected to last till June 2005, consists of a physics run with Cu-Cu collisions at 100 GeV/u followed by one with polarized protons (pp) at 100 GeV [l]. We will address here the overall performance of the RHIC complex used for the first time as a Cu-Cu collider, and compare it with previous operational experience with Au, PP and asymmetric d-Au collisions. We will also discuss operational improvements, such as a {beta}* squeeze to 85cm in the high luminosity interaction regions from the design value of 1m, system improvements, machine performance and limitations, and address reliability and uptime issues.

  19. Formation of two-dimensional CuSe on Cu(111) at very low selenium coverage

    DOE PAGES-Beta [OSTI]

    Walen, Holly; Liu, Da -Jiang; Oh, Junepyo; Yang, Hyun Jin; Kim, Yousoo; Thiel, Patricia A.

    2016-05-09

    Here, using scanning tunneling microscopy (STM), we observe that adsorption of Se on Cu(111) produces islands with (√3 x √3)R30° structure, at Se coverages far below the structure's ideal coverage of 1/3 ML. Based on density functional theory (DFT), these islands cannot form due to attractive interactions between chemisorbed Se atoms. DFT shows that incorporating Cu atoms into the √3-Se lattice stabilizes the structure, which provides a plausible explanation for the experimental observations.

  20. Synthesis of CuO by Cu-CPPs with the determination of Cu(II) coordination modes from a novel complex of [Cu(terpyOH){sub 2}]·(HBTC)·2H{sub 2}O

    SciTech Connect (OSTI)

    Wang, Yu Chen, Gang Han, Li; Pei, Jian

    2013-10-15

    In this study, we investigated the synthesis of CuO microrods by simple calcination of copper-based coordination polymer particles (Cu-CPPs) at high temperature in air. The photocatalytic activity of the CuO microrods was tested by the decomposition of aqueous solution of RhB, which was completely decomposed by irradiation with light. To analyze the relationship of metal ions and ligands in the Cu-CPPs, the single crystal of [Cu(terpyOH){sub 2}]∙(HBTC)∙2H{sub 2}O (1) (terpyOH=4′-hydroxy-2,2′:6′,2″-terpyridine, BTC=1,3,5-benzene tricarboxylate) was first prepared and characterized by X-ray single crystal structural analysis. A variety of hydrogen bonds constructing the 3D complex structure in [Cu(terpyOH){sub 2}]∙(HBTC)∙2H{sub 2}O (1) were observed. - Graphical abstract: Demonstrating a general method to synthesize CuO microrods via simple calcination of Cu-CPPs and Cu(II) coordination modes from a novel complex of [Cu(terpyOH){sub 2}]∙(HBTC)·2H{sub 2}O constructed by hydrogen bonding. Display Omitted - Highlights: • The formation of microrods CuO from thermal treatment of Cu-CPPs through an “escape-by-crafty-scheme” strategy has been studied. • Determination of Cu(II) coordination modes in Cu-CPPs from a novel complex of [Cu(terpyOH){sub 2}]∙(HBTC) 2H{sub 2}O. • Invested the behave of hydrogen bonding to construct the 3D complex structure. • Commendable photodegradation performance was observed.

  1. Triaxial Stress Distributions in Cu / low-k Interconnect Features

    SciTech Connect (OSTI)

    C Murray; P Besser; E Ryan; J Jordan-Sweet

    2011-12-31

    The distribution of triaxial stresses within single damascene Cu/organosilicate interconnect structures as a function of linewidth, ranging from 45 to 250 nm, was measured using x-ray diffraction. Least-squares minimization techniques were employed to determine the volume-averaged stress tensors of the Cu features. Longitudinal Cu stress values increased for linewidths below 100 nm, while transverse stresses decreased with decreasing linewidth below 100 nm due to the interplay between the Cu microstructure and the feature geometry. Large tensile out-of-plane stresses were observed in all of the lines demonstrating the constraint imposed by the barrier layers that encapsulate the Cu.

  2. Bi-Se doped with Cu, p-type semiconductor

    DOE Patents [OSTI]

    Bhattacharya, Raghu Nath; Phok, Sovannary; Parilla, Philip Anthony

    2013-08-20

    A Bi--Se doped with Cu, p-type semiconductor, preferably used as an absorber material in a photovoltaic device. Preferably the semiconductor has at least 20 molar percent Cu. In a preferred embodiment, the semiconductor comprises at least 28 molar percent of Cu. In one embodiment, the semiconductor comprises a molar percentage of Cu and Bi whereby the molar percentage of Cu divided by the molar percentage of Bi is greater than 1.2. In a preferred embodiment, the semiconductor is manufactured as a thin film having a thickness less than 600 nm.

  3. Method of producing .sup.67 Cu

    DOE Patents [OSTI]

    O'Brien, Jr., Harold A.; Barnes, John W.; Taylor, Wayne A.; Thomas, Kenneth E.; Bentley, Glenn E.

    1984-01-01

    A method of producing carrier-free .sup.67 Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including .sup.67 Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  4. Method for producing /sup 67/Cu

    DOE Patents [OSTI]

    O'Brien, H.A. Jr.; Barnes, J.W.; Taylor, W.A.; Thomas, K.E.; Bentley, G.E.

    A method of producing carrier-free /sup 67/Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including /sup 67/Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  5. Synthesis of Cu{sub 2}O from CuO thin films: Optical and electrical properties

    SciTech Connect (OSTI)

    Murali, Dhanya S. Jain, Mahaveer K.; Subrahmanyam, A.; Kumar, Shailendra; Choudhary, R. J.; Wadikar, Avinash D.

    2015-04-15

    Hole conducting, optically transparent Cu{sub 2}O thin films on glass substrates have been synthesized by vacuum annealing (5×10{sup −6} mbar at 700 K for 1 hour) of magnetron sputtered (at 300 K) CuO thin films. The Cu{sub 2}O thin films are p-type and show enhanced properties: grain size (54.7 nm), optical transmission 72% (at 600 nm) and Hall mobility 51 cm{sup 2}/Vs. The bulk and surface Valence band spectra of Cu{sub 2}O and CuO thin films are studied by temperature dependent Hall effect and Ultra violet photo electron Spectroscopy (UPS). CuO thin films show a significant band bending downwards (due to higher hole concentration) than Cu{sub 2}O thin films.

  6. Injection and acceleration of Au31+ in the BNL AGS.

    SciTech Connect (OSTI)

    Fischer,W.; Ahrens, L.; Brown, K.; Gardner, C.; Glenn, W.; Huang, H.; Mapes, M.; Smart, L.; Thieberger, P.; Tsoupas, N.; Zhang, S.Y.; Zeno, K.; Omet, C.; Spiller, P.

    2008-06-23

    Injection and acceleration of ions in a lower charge state reduces space charge effects, and, if further elcctron stripping is needed, may allow elimination of a stripping stage and the associated beam losses. The former is of interest to the accelerators in the GSI FAIR complex, the latter for BNL RHIC collider operation at energies lower than the current injection energy. Lower charge state ions, however, have a higher likelihood of electron stripping which can lead to dynamic pressures rises and subsequent beam losses. We report on experiments in the AGS where Au{sup 31+} ions were injected and accelerated instead of the normally used Au{sup 77+} ions. Beam intensities and the average pressure in the AGS ring are recorded, and compared with calculations for dynamic pressures and beam losses. The experimental results will be used to benchmark the StrahlSim dynamic vacuum code and will be incorporated in the GSI FAIR SIS100 design.

  7. Broadband enhancement of infrared absorption in microbolometers using Ag nanocrystals

    SciTech Connect (OSTI)

    Hyun, Jerome K.; Ahn, Chi Won; Kim, Woo Choong; Kim, Tae Hyun; Hyun, Moon Seop; Kim, Hee Yeoun E-mail: jhpark@nnfc.re.kr; Park, Jae Hong E-mail: jhpark@nnfc.re.kr; Lee, Won-Oh

    2015-12-21

    High performance microbolometers are widely sought for thermal imaging applications. In order to increase the performance limits of microbolometers, the responsivity of the device to broadband infrared (IR) radiation needs to be improved. In this work, we report a simple, quick, and cost-effective approach to modestly enhance the broadband IR response of the device by evaporating Ag nanocrystals onto the light entrance surface of the device. When irradiated with IR light, strong fields are built up within the gaps between adjacent Ag nanocrystals. These fields resistively generate heat in the nanocrystals and underlying substrate, which is transduced into an electrical signal via a resistive sensing element in the device. Through this method, we are able to enhance the IR absorption over a broadband spectrum and improve the responsivity of the device by ∼11%.

  8. CONTINUOUS EXTRACTED BEAM IN THE AGS FAST EXTERNAL BEAM LINE.

    SciTech Connect (OSTI)

    GLENN,J.W.; TSOUPAS,N.; BROWN,K.A.; BIRYUKOV,V.M.

    2001-06-18

    A method to split off a few percent of the 6 x 10{sup 13} AGS beam delivered to the Slow External Beam (SEB) lines and send it down the Fast External Beam line (FEB) has been developed. The mission is to feed a counter experiment off the FEB that directly measures the neutrino mass using the muon storage ring. The use of normal thin septum splitters would have an excessive loss overhead and been optically difficult. The AGS Slow Extraction uses a third integer resonance with sextuple strength so the resonance width is a few percent of the beam width. This results in a low density tail which will be clipped by a bent crystal and deflected into the FEB channel. This clipping off of the tail should reduce losses in the SEB transport line. Details of modeled orbits, particle distribution and extraction trajectories into and out off the crystal will be given.

  9. Reduced Cu(InGa)Se2 Thickness in Solar Cells Using a Superstrate Configuration

    SciTech Connect (OSTI)

    Shafarman, William N.

    2015-03-30

    is incident through the substrate into the back of the absorber layer. The primary junction is then formed after Cu(InGa)Se2 deposition. This allows the potential benefits of superstrate cells for optical enhancement while maintaining processing advantages of the substrate configuration and avoiding the harmful effects of high temperature deposition on p-n junction formation. Backwall devices have outperformed substrate cells at absorber thicknesses of 0.1-0.5 µm through enhanced JSC due to easy incorporation of a Ag reflector and, with light incident on the absorber, the elimination of parasitic absorption in the CdS buffer. An efficiency of 9.7% has been achieved for a backwall Cu(InGa)Se2 device with absorber thickness ~0.4 μm. A critical achievement that enabled implementation of the backwall cell was the development of a transparent back contact using MoO3 or WO3. Processes for controlled deposition of each material by reactive rf sputtering from metal targets were developed. These contacts have wide bandgaps making them well-suited for application as contacts for backwall devices as well as potential use in bifacial cells and as the top cell of tandem CuInSe2-based devices. Optical enhancement will be critical for further improvements. Wet chemical texturing of ZnO films has been developed for a simple, low cost light-trapping scheme for backwall superstrate devices to enhance long wavelength quantum efficiency. An aqueous oxalic acid etch was developed and found to strongly texture sputtered ZnO with high haze ≈ 0.9 observed across the whole spectrum. And finally, advanced optical models have been developed to assist the characterization and optimization of Cu(InGa)Se2 cells with thin absorbers

  10. Application of a new coordination compound for the preparation of AgI nanoparticles

    SciTech Connect (OSTI)

    Mohandes, Fatemeh; Salavati-Niasari, Masoud

    2013-10-15

    Graphical abstract: Silver iodide nanoparticles have been sonochemically synthesized by using silver salicylate complex, [Ag(HSal)], as silver precursor. A series of control experiments were carried out to investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures. - Highlights: • Silver salicylate as a new precursor was applied to fabricate γ-AgI nanoparticles. • To further decrease the particle size of AgI, SDS was used as surfactant. • The effect of preparation parameters on the particle size of AgI was investigated. - Abstract: AgI nanoparticles have been sonochemically synthesized by using silver salicylate, [Ag(HSal)], as silver precursor. To investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures, several experiments were carried out. The products were characterized by SEM, TEM, XRD, TGA/DTA, UV–vis, and FT-IR. Based on the experimental findings in this research, it was found that the size of AgI nanoparticles was dramatically dependent on the silver precursor, sonochemical irradiation, and surfactant concentration. Sodium dodecyl sulfate (SDS) was applied as surfactant. When the concentration of SDS was 0.055 mM, very uniform sphere-like AgI nanoparticles with grain size of about 25–30 nm were obtained. These results indicated that the high concentration of SDS could prevent the aggregation between colloidal nanoparticles due to its steric hindrance effect.

  11. Synthesis of Ag{sub 2}S nanorods by biomimetic method in the lysozyme matrix

    SciTech Connect (OSTI)

    Qin, Dezhi Zhang, Li; He, Guoxu; Zhang, Qiuxia

    2013-09-01

    Graphical abstract: - Highlights: • Firstly, Ag{sub 2}S nanorods were synthesized by biomimetic method in the lysozyme solutions. • The study of the interaction between Ag{sup +} and the lysozyme. • Discussion of possible formation mechanism of Ag{sub 2}S nanorods. • The synthesis process of lyso-conjugated Ag{sub 2}S nanocrystals is facile, effective and environment friendly. - Abstract: Ag{sub 2}S nanorods were successfully synthesized by biomimetic route in the lysozyme solution at physiological temperature and atmospheric pressure. The transmission electron microscopy (TEM) images revealed that the prepared nanorods are uniform and monodisperse with homogeneous size about 50 nm in diameter and 150 nm in length. The optical property of Ag{sub 2}S nanocrystals was studied by the ultraviolet–visible (UV–vis) and photoluminescence (PL) spectroscopy, the results show that the products exhibit well-defined emission at 471 nm and 496 nm excited by 292 nm. The interaction of Ag{sup +}/Ag{sub 2}S with the lysozyme was investigated through Fourier transform infrared (FT-IR) spectroscopy, which shows that the cooperation effect of the lysozyme and Ag{sup +} could be responsible for the formation of as obtained Ag{sub 2}S nanorods.

  12. Trends in wetting behavior for Ag–CuO braze alloys on Ba0.5Sr0.5Co0.8Fe0.2O(3−δ) at elevated temperatures in air

    SciTech Connect (OSTI)

    Joshi, Vineet V.; Meier, Alan; Darsell, Jens T.; Weil, K. Scott; Bowden, Mark E.

    2013-10-01

    Ba0.5Sr0.5Co0.8Fe0.2O(3- (BSCF) is a potential oxygen separation membrane material for advanced coal based power plants. For this application, BSCF must be joined to a metal. In the current study, Ag-CuO, a reactive air brazing (RAB) alloy was evaluated for brazing BSCF. In-situ contact angle tests were performed on BSCF using Ag-CuO binary mixtures at 950 and 1000°C and the interfacial microstructures were evaluated. Wetting contact angles (<90°) were obtained at short times at 950°C and the contact angles remained constant at 1000°C for 1, 2 and 8 mol% CuO contents. Microstructural analysis revealed the dissolution of copper oxide into the BSCF matrix to form copper-cobalt-oxygen rich dissolution products along the BSCF grain boundary. The formation of a thick interfacial reaction product layer and ridging at the sessile drop triple point indicate that the reaction kinetics are very rapid and that it will require careful process control to obtain the desired thin but continuous interfacial product layer.

  13. Measurement of the B?s lifetime in the flavor-specific decay channel B?s ? D?s ???X

    DOE PAGES-Beta [OSTI]

    Abazov, V.? M.; Abbott, B.; Acharya, B.? S.; Adams, M.; Adams, T.; Agnew, J.? P.; Alexeev, G.? D.; Alkhazov, G.; Alton, A.; Askew, A.; et al

    2015-02-09

    We present an updated measurement of the B?s lifetime using the semileptonic decays B?s ? D?s ???X, with D?s ? ??? and ? ? K?K? (and the charge conjugate process). This measurement uses the full Tevatron Run II sample of proton-antiproton collisions at ?s = 1.96 TeV, comprising an integrated luminosity of 10.4 fb?1. We find a flavor-specifc lifetime Tfs(B?s) = 1.479 0.010 (stat) 0.021 (syst) ps. This technique is also used to determine the B? lifetime using the analogous B? ? D????X decay with D? ? ??? and ? ? K?K? , yielding T(B?) = 1.534 more0.019 (stat) 0.021 (syst) ps. Both measurements are consistent with the current world averages, and the B?s lifetime measurement is one of the most precise to date. Taking advantage of the cancellation of systematic uncertainties, we determine the lifetime ratio Tfs(B?s)/T(B?) = 0.964 0.013 (stat) 0.007 (syst).less

  14. Theoretical investigation of structural properties of CuCl, CuBr and CuI compounds under hydrostatic pressure

    SciTech Connect (OSTI)

    Louhibi-Fasla, S.; Djabri, H. Rekab; Achour, H.; Kefif, K.

    2013-12-16

    We have applied a recent version of the full potential linear muffin-tin orbitals method (FPLMTO) to study the structural properties of copper halides CuX (X=Cl, Br, I) under high pressure using the generalized gradient approximation (GGA) for the exchange and correlation potential by Perdew et al. Results are given for lattice parameters, bulk modulus and its first derivatives in the wurtzite(B4), zinc-blende (B3), CsCl (B2), rock-salt (B1), and PbO (B10) structures. The results of these calculations are compared with the available theoretical and experimental data.

  15. Magnetic dipole moments of {sup 57,58,59}Cu

    SciTech Connect (OSTI)

    Cocolios, T. E.; Andreyev, A. N.; Bastin, B.; Bree, N.; Buescher, J.; Elseviers, J.; Gentens, J.; Huyse, M.; Kudryavtsev, Yu.; Pauwels, D.; Bergh, P. Van den; Van Duppen, P.; Sonoda, T.

    2010-01-15

    In-gas-cell laser spectroscopy of the isotopes {sup 57,58,59,63,65}Cu has been performed at the LISOL facility using the 244.164-nm optical transition from the atomic ground state of copper. A detailed discussion on the hyperfine structure of {sup 63}Cu is presented. The magnetic dipole moments of the isotopes {sup 57,58,59,65}Cu are extracted based on that of {sup 63}Cu. The new value mu=+0.479(13)mu{sub N} is proposed for {sup 58}Cu, consistent with that of a pip{sub 3/2} x nup{sub 3/2} ground-state configuration. Spin assignments for the radioactive isotopes {sup 57,58,59}Cu are confirmed. The isotope shifts between the different isotopes are also given and discussed.

  16. W{sub 18}O{sub 49} nanorods decorated with Ag/AgCl nanoparticles as highly-sensitive gas-sensing material and visible-light-driven photocatalyst

    SciTech Connect (OSTI)

    Sun Shibin; Chang Xueting; Dong Lihua; Zhang Yidong; Li Zhenjiang; Qiu Yanyan

    2011-08-15

    A novel gas-sensing material and photocatalyst was successfully obtained by decorating Ag/AgCl nanoparticles on the W{sub 18}O{sub 49} nanorods through a clean photochemical route. The as-prepared samples were characterized using combined techniques of X-ray diffractometry, electron microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy. Gas-sensing measurements indicate that the Ag/AgCl/W{sub 18}O{sub 49} NRs sensors exhibit superior reducing gas-sensing properties to those of bare W{sub 18}O{sub 49} NRs, and they are highly selective and sensitive to NH{sub 3}, acetone, and H{sub 2}S with short response and recovery times. The Ag/AgCl/W{sub 18}O{sub 49} NRs photocatlysts also possess higher photocatalytic performance than bare W{sub 18}O{sub 49} NRs for degradation of methyl orange under simulated sunlight irradiation. Possible mechanisms concerning the enhancement of gas-sensing and photocatalytic activities of the Ag/AgCl/W{sub 18}O{sub 49} NRs composite were proposed. - Graphical Abstract: The Ag/AgCl nanoparticles adhered well to the W{sub 18}O{sub 49} nanorod. The Ag could act as transfer center of the photoexcited carriers, prohibiting their recombinations in both W{sub 18}O{sub 49} and AgCl. Highlights: > Ag/AgCl/W{sub 18}O{sub 49} NRs were successfully obtained via a clean photochemical route. > The Ag/AgCl nanoparticles decorated on the W{sub 18}O{sub 49} NRs possessed cladding structure. > The Ag/AgCl/W{sub 18}O{sub 49} NRs exhibited excellent gas-sensing and photocatalytic properties.

  17. Surface-supported Ag islands stabilized by a quantum size effect: Their interaction with small molecules relevant to ethylene epoxidation

    SciTech Connect (OSTI)

    Shao, Dahai

    2013-05-15

    This dissertation focuses on how QSE-stabilized, surface-supported Ag nanoclusters will interact with ethylene or oxygen. Experiments are performed to determine whether the QSE-mediated Ag islands react differently toward adsorption of ethylene or oxygen, or whether the adsorption of these small molecules will affect the QSE-mediated stability of Ag islands. Studies of the interaction of oxygen with Ag/Si(111)-77 were previously reported, but these studies were performed at a low Ag coverage where 3D Ag islands were not formed. So the study of such a system at a higher Ag coverage will be a subject of this work. The interaction of ethylene with Ag/Si(111)-77, as well as the interaction of oxygen with Ag/NiAl(110) are also important parts of this study.

  18. AG490 inhibits NFATc1 expression and STAT3 activation during RANKL induced osteoclastogenesis

    SciTech Connect (OSTI)

    Li, Chang-hong; Zhao, Jin-xia; Sun, Lin; Yao, Zhong-qiang; Deng, Xiao-li; Liu, Rui; Liu, Xiang-yuan

    2013-06-14

    Highlights: AG490 inhibits RANKL-induced osteoclastogenesis in RAW264.7 cells. AG490 affects cell proliferation and cell cycle distribution. AG490 reduces NFATc1 expression during RANKL-induced osteoclastogenesis. AG490 disrupts the activation of RANKL-mediated JAK2/STAT3 signaling pathway. STAT3 depletion partly mimics the effect of AG490 on RANKL-induced osteoclastogenesis. -- Abstract: Commonly, JAK/STAT relays cytokine signals for cell activation and proliferation, and recent studies have shown that the elevated expression of JAK/STAT is associated with the immune rejection of allografts and the inflammatory processes of autoimmune disease. However, the role which JAK2/STAT3 signaling plays in the receptor activator of nuclear factor-?B ligand (RANKL)-mediated osteoclastogenesis is unknown. In this study, we investigated the effects of AG490, specific JAK2 inhibitor, on osteoclast differentiation in vitro. AG490 significantly inhibited osteoclastogenesis in murine osteoclast precursor cell line RAW264.7 induced by RANKL. AG490 suppressed cell proliferation and delayed the G1 to S cell cycle transition. Furthermore, AG490 also suppressed the expression of nuclear factor of activated T cells (NFAT) c1 but not c-Fos in RAW264.7. Subsequently, we investigated various intracellular signaling components associated with osteoclastogenesis. AG490 had no effects on RANKL-induced activation of Akt, ERK1/2. Interestingly, AG490 partly inhibited RANKL-induced phosphorylation of Ser{sup 727} in STAT3. Additionally, down-regulation of STAT3 using siRNA resulted in suppression of TRAP, RANK and NFATc1 expression. In conclusion, we demonstrated that AG490 inhibited RANKL-induced osteoclastogenesis by suppressing NFATc1 production and cell proliferation via the STAT3 pathway. These results suggest that inhibition of JAK2 may be useful for the treatment of bone diseases characterized by excessive osteoclastogenesis.

  19. Spin glass in semiconducting KFe1.05Ag0.88Te2 single crystals

    DOE PAGES-Beta [OSTI]

    Ryu, H.; Lei, H.; Klobes, B.; Warren, J. B.; Hermann, R. P.; Petrovic, C.

    2015-05-26

    We report discovery of KFe1.05Ag0.88Te2 single crystals with semiconducting spin glass ground state. Composition and structure analysis suggest nearly stoichiometric I4/mmm space group but allow for the existence of vacancies, absent in long range semiconducting antiferromagnet KFe1.05Ag0.88Te2. The subtle change in stoichometry in Fe/Ag sublattice changes magnetic ground state but not conductivity, giving further insight into the semiconducting gap mechanism.

  20. Multi-component Cu-Strengthened Steel Welding Simulations: Atom...

    Office of Scientific and Technical Information (OSTI)

    Steel Welding Simulations: Atom Probe Tomography and Synchrotron X-ray Diffraction Analyses Citation Details In-Document Search Title: Multi-component Cu-Strengthened Steel Welding ...

  1. Cu Migration in Polycrystalline CdTe Solar Cells

    SciTech Connect (OSTI)

    Guo, Da; Akis, Richard; Brinkman, Daniel; Sankin, Igor; Fang, Tian; Vasileska, Dragica; Ringhofer, Christian

    2014-03-12

    An impurity reaction-diffusion model is applied to Cu defects and related intrinsic defects in polycrystalline CdTe for a better understanding of Cu’s role in the cell level reliability of CdTe PV devices. The simulation yields transient Cu distributions in polycrystalline CdTe during solar cell processing and stressing. Preliminary results for Cu migration using available diffusivity and solubility data show that Cu accumulates near the back contact, a phenomena that is commonly observed in devices after back-contact processing or stress conditions.

  2. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite...

    Office of Scientific and Technical Information (OSTI)

    Book: Understanding NOx SCR Mechanism and Activity on CuChabazite Structures throughout the Catalyst Life Cycle Citation Details In-Document Search Title: Understanding NOx SCR...

  3. Enhanced Photocatalytic Property of Cu Doped Sodium Niobate

    SciTech Connect (OSTI)

    Xu, Jianbin; Zhang, Feng; Sun, Bingyang; Du, Yingge; Li, Guoqiang; Zhang, Weifeng

    2015-09-29

    We investigate the photocatalytic activity of Cu doped NaNbO3 powder sample prepared by the modified polymer complex method. The photocatalytic activity of hydrogen evolution from methanol aqueous solution was improved by Cu 2.6 at% doping. The photocatalytic degradation of rhodamine B under visible light irradiation was enhanced in comparison with pure NaNbO3. Cu inctroduction improved the adsorption property of NaNbO3, judging from the Fourier transform infrared spectra. Moreover, the ultraviolet light excitation in Cu doped sample was found to accelerate the mineralized process.

  4. NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts

    Energy.gov [DOE]

    DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3

  5. Organic pollutant photodecomposition by Ag/KNbO3 nanocomposites: A combined experimental and theoretical study

    DOE PAGES-Beta [OSTI]

    Zhang, Tingting; Liu, Ping; Lei, Wanying; Rodriguez, J. A.; Yu, Jiaguo; Qi, Yang; Liu, Gang; Liu, Minghua

    2016-01-12

    In this study, Ag nanoparticles supported on well-defined perovskite orthorhombic KNbO3 nanowires are synthesized via facile photoreduction and systematically characterized by XRD, Raman, DRUV–vis, XPS, PL, TEM, HRTEM, and HAADF-STEM. The photoreactivity of Ag/KNbO3 nanocomposites as a function of Ag contents (0.4–2.8 wt %) is assessed toward aqueous rhodamine B degradation under UV- and visible-light, respectively. It is found that the UV-induced photoreactivity initially increases and then decreases with increasing Ag contents. At an optimal Ag content (ca. 1.7 wt %), the greatest photoreactivity is achieved under UV light, with the photocatalytic reaction rate of 1.7 wt % Ag/KNbO3 exceedingmore » that of pristine KNbO3 by a factor of ca. 13. In contrast, visible light-induced photoreactivity monotonically increases with increasing Ag contents in the range of 0.4–2.8 wt %. On the basis of the detected active species and intermediate products in the photocatalytic processes, conjugated structure cleavage and N-deethylation are revealed to be the respective predominant pathway under UV and visible-light illumination. To gain an insight into the observed photoreactivity, the electronic properties of Ag/KNbO3 have been investigated using spin-polarized DFT calculations. Herein, Ag extended adlayers (1–4 ML) on the slab models of KNbO3 (101) are employed to mimic large supported Ag nanoparticles. A Bader analysis of the electron density shows a small net charge transfer (ca. 0.1 e) from KNbO3 to Ag. The electron localization function of Ag/KNbO3 (101) illustrates that Ag adlayers with thickness larger than 2 ML are essentially metallic, and weak polarization occurs at the interface. In addition, the metallic Ag adlayers generate a continuum of Ag bandgap states, which play a key role in determining different Ag content-dependent behavior between UV and visible-light illumination.« less

  6. NuCellSys GmbH formerly Ballard AG formerly XCellsis | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    Germany Product: Focused on developing and manufacturing fuel cell systems for automotive applications. References: NuCellSys GmbH (formerly Ballard AG, formerly XCellsis)1...

  7. [Purification of {sup 67}Cu]. Progress report

    SciTech Connect (OSTI)

    DeNardo, S.J.

    1994-09-01

    This report documents progress made in several areas of research and describes results which have not yet been published. These areas include: Purification of {sup 67}Cu; Macrocyclic chelates for targeted therapy; Studies of biologic activation associated with molecular receptor increase and tumor response in ChL6/L6 protocol patients; Lym-1 single chain genetically engineered molecules; Analysis of molecular genetic coded messages to enhance tumor response; Human dosimetry and therapeutic human use radiopharmaceuticals; studies in phantoms; Quantitative SPECT; Preclinical studies; and Clinical studies.

  8. New Resolved Resonance Region Evaluation for 63Cu and 65Cu for Nuclear Criticality Safety Program

    SciTech Connect (OSTI)

    Sobes, Vladimir; Leal, Luiz C; Guber, Klaus H; Forget, Benoit; Kopecky, S.; Schillebeeckx, P.; Siegler, P.

    2014-01-01

    A new resolved resonance region evaluation of 63Cu and 65Cu was done in the energy region from 10-5 eV to 99.5 keV. The R-Matrix SAMMY method using the Reich-Moore approximation was used to create a new set of consistent resonance parameters. The new evaluation was based on three experimental transmission data sets; two measured at ORELA and one from MITR, and two radiative capture experimental data sets from GELINA. A total of 141 new resonances were identied for 63Cu and 117 for 65Cu. The corresponding set of external resonances for each isotope was based on the identied resonances above 99.5 keV from the ORELA transmission data. The negative external levels (bound levels) were determined to match the dierential thermal cross section measured at the MITR. Double dierential elastic scattering cross sections were calculated from the new set of resonance parameters. Benchmarking calculations were carried out on a set of ICSBEP benchmarks. This work is in support of the DOE Nuclear Criticality Safety Program.

  9. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn

    SciTech Connect (OSTI)

    Provino, A.; Paudyal, D.; Fornasini, ML; Dhiman, I.; Dhar, SK.; Das, A.; Mudryk, Y.; Manfrinetti, P.; Pecharsky, VK

    2013-01-29

    We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the MnCu2In and MnCu2Sn alloys. In contrast, the homologous compound MnCu4Sn, which crystallizes in the cubic MgCu4Sn-type, orders antiferromagnetically with TN = 110 K. The neutron diffraction studies show ferromagnetic spin orientation in the {1 0 1} plane in MnCu4In with a magnetic moment of 4.5 ?B/Mn at 22 K, and a corresponding value of 4.7 ?B/Mn in the antiferromagnetic MnCu4Sn with propagation vector View the MathML source. The first-principles electronic structure calculations show that the unexpected difference in both magnetic and crystal structures of MnCu4In and MnCu4Sn is due to the difference in the Mn-3d bands and exchange interactions relating to different crystal anisotropy, coordination numbers, and interatomic distances.

  10. Spectral investigation of nonlinear local field effects in Ag nanoparticles

    SciTech Connect (OSTI)

    Sato, Rodrigo Takeda, Yoshihiko; Ohnuma, Masato; Oyoshi, Keiji

    2015-03-21

    The capability of Ag nanoparticles to modulate their optical resonance condition, by optical nonlinearity, without an external feedback system was experimentally demonstrated. These optical nonlinearities were studied in the vicinity of the localized surface plasmon resonance (LSPR), using femtosecond pump-and-probe spectroscopy with a white-light continuum probe. Transient transmission changes ΔT/T exhibited strong photon energy and particle size dependence and showed a complex and non-monotonic change with increasing pump light intensity. Peak position and change of sign redshift with increasing pump light intensity demonstrate the modulation of the LSPR. These features are discussed in terms of the intrinsic feedback via local field enhancement.

  11. Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Aging on Super Duty Diesel Truck Aged Urea CuZeolite SCR Catalysts Non-uniform Aging on Super Duty Diesel Truck Aged Urea CuZeolite SCR Catalysts CuZeolite SCR catalysts aged ...

  12. Antiferromagnetism in EuCu2As2 and EuCu1.82Sb2 single crystals

    DOE PAGES-Beta [OSTI]

    Anand, V. K.; Johnston, D. C.

    2015-05-07

    Single crystals of EuCu2As2 and EuCu2Sb2 were grown from CuAs and CuSb self-flux, respectively. The crystallographic, magnetic, thermal, and electronic transport properties of the single crystals were investigated by room-temperature x-ray diffraction (XRD), magnetic susceptibility χ versus temperature T, isothermal magnetization M versus magnetic field H, specific heat Cp(T), and electrical resistivity ρ(T) measurements. EuCu2As2 crystallizes in the body-centered tetragonal ThCr2Si2-type structure (space group I4/mmm), whereas EuCu2Sb2 crystallizes in the related primitive tetragonal CaBe2Ge2-type structure (space group P4/nmm). The energy-dispersive x-ray spectroscopy and XRD data for the EuCu2Sb2 crystals showed the presence of vacancies on the Cu sites, yielding themore » actual composition EuCu1.82Sb2. The ρ(T) and Cp(T) data reveal metallic character for both EuCu2As2 and EuCu1.82Sb2. Antiferromagnetic (AFM) ordering is indicated from the χ(T),Cp(T), and ρ(T) data for both EuCu2As2 (TN = 17.5 K) and EuCu1.82Sb2 (TN = 5.1 K). In EuCu1.82Sb2, the ordered-state χ(T) and M(H) data suggest either a collinear A-type AFM ordering of Eu+2 spins S = 7/2 or a planar noncollinear AFM structure, with the ordered moments oriented in the tetragonal ab plane in either case. This ordered-moment orientation for the A-type AFM is consistent with calculations with magnetic dipole interactions. As a result, the anisotropic χ(T) and isothermal M(H) data for EuCu2As2, also containing Eu+2 spins S = 7/2, strongly deviate from the predictions of molecular field theory for collinear AFM ordering and the AFM structure appears to be both noncollinear and noncoplanar.« less

  13. Synthesis of Bi.sub.1.8 Pb.sub.0.4 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x superconductor

    DOE Patents [OSTI]

    Smith, Michael G.

    1996-01-01

    Two-powder processes for the synthesis of superconducting (Bi, Pb)-2223/Ag-clad wires by the oxide-powder-in-the-robe are provided. The first precursor powder, of nominal stoichiometry CaCuO.sub.x, is a solution-synthesized mixture of Ca.sub.0.45 Cu.sub.0.55 O.sub.2 and CaO. Using these oxide precursor mixtures, superconducting tapes with well-aligned grains and reproducible critical current densities J.sub.c in the range of 20,000 to 26,000 A/cm.sup.2 at 75 K in self-field after annealing less than 200 hours were obtained.

  14. Synthesis of Bi{sub 1.8}Pb{sub 0.4}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} superconductor

    DOE Patents [OSTI]

    Smith, M.G.

    1996-10-29

    Two-powder processes for the synthesis of superconducting (Bi, Pb)-2223/Ag-clad wires by the oxide-powder-in-the-robe are provided. The first precursor powder, of nominal stoichiometry CaCuO{sub x}, is a solution-synthesized mixture of Ca{sub 0.45}Cu{sub 0.55}O{sub 2} and CaO. Using these oxide precursor mixtures, superconducting tapes with well-aligned grains and reproducible critical current densities J{sub c} in the range of 20,000 to 26,000 A/cm{sup 2} at 75 K in self-field after annealing less than 200 hours were obtained. 2 figs.

  15. Observations of Ag diffusion in ion implanted SiC

    DOE PAGES-Beta [OSTI]

    Gerczak, Tyler J.; Leng, Bin; Sridharan, Kumar; Jerry L. Hunter, Jr.; Giordani, Andrew J.; Allen, Todd R.

    2015-03-17

    The nature and magnitude of Ag diffusion in SiC has been a topic of interest in connection with the performance of tristructural isotropic (TRISO) coated particle fuel for high temperature gas-cooled nuclear reactors. Ion implantation diffusion couples have been revisited to continue developing a more complete understanding of Ag fission product diffusion in SiC. Ion implantation diffusion couples fabricated from single crystal 4H-SiC and polycrystalline 3C-SiC substrates and exposed to 1500–1625°C, were investigated in this study by transmission electron microscopy and secondary ion mass spectrometry (SIMS). The high dynamic range of SIMS allowed for multiple diffusion régimes to be investigated,more » including enhanced diffusion by implantation-induced defects and grain boundary (GB) diffusion in undamaged SiC. Lastly, estimated diffusion coefficients suggest GB diffusion in bulk SiC does not properly describe the release observed from TRISO fuel.« less

  16. SIMULATIONS OF THE AGS MMPS STORING ENERGY IN CAPACITOR BANKS

    SciTech Connect (OSTI)

    MARNERIS,I.; BADEA, V.S.; BONATI, R.; ROSER, T.; SANDBERG, J.

    2007-06-25

    The Brookhaven AGS Main Magnet Power Supply (MMPS) is a thyristor control supply rated at 5500 Amps, +/-9000 Volts. The peak magnet power is 50 MWatts. The power supply is fed from a motor/generator manufactured by Siemens. The generator is 3 phase 7500 Volts rated at 50 MVA. The peak power requirements come from the stored energy in the rotor of the motor/generator. The motor generator is about 45 years old, made by Siemens and it is not clear if companies will be manufacturing similar machines in the future. We are therefore investigating different ways of storing energy for future AGS MMPS operations. This paper will present simulations of a power supply where energy is stored in capacitor banks. Two dc to dc converters will be presented along with the control system of the power section. The switching elements will be IGCT's made by ABB. The simulation program used is called PSIM version 6.1. The average power from the local power authority into the power supply will be kept constant during the pulsing of the magnets at +/-50 MW. The reactive power will also be kept constant below 1.5 MVAR. Waveforms will be presented.

  17. Robust Ag nanoplate ink for flexible electronics packaging

    SciTech Connect (OSTI)

    Li, Ruo -Zhou; Hu, Anming; Bridges, Denzel; Oakes, Ken D.; Peng, Rui; Tumuluri, Uma; Wu, Zili; Feng, Zhili; Zhang, Tong

    2015-03-24

    Nanoinks are currently a topic of heightened interest with respect to low temperature bonding processes and printable electronics. We have developed an innovative polyvinylpyrrolidone (PVP)-stabilized Ag nanoplate ink amenable to very strong low temperature packaging, and investigated the relationship between bonding strength and electrical conductivity post-bonding. PVP shell plastic deformations observed in failure microcracks with the formation of PVP nanofibers, revealed bonding strength at low temperatures (<250 °C) was primarily due to adhesive bonding. It is found that, utilizing photonic sintering, ~70 °C reduction of transformation temperature from adhesive to metallic bonding was achieved compared to that of thermal sintering. A numerical simulation was developed to better understand the influences of the light-induced heat generation, which demonstrated near-infrared light can facilitate sintering. Bonding strengths of 27 MPa were achieved at room temperatures, and 29.4 MPa at 210 °C with photonic sintering. Moreover, the anisotropic resistivity was observed with different thermal dependences. Furthermore, these results demonstrate Ag nanoplate inks have potential for low temperature 3D interconnections in lead-free microcircuits, flexible electronic packaging, and diverse sensing applications.

  18. Robust Ag nanoplate ink for flexible electronics packaging

    DOE PAGES-Beta [OSTI]

    Li, Ruo -Zhou; Hu, Anming; Bridges, Denzel; Oakes, Ken D.; Peng, Rui; Tumuluri, Uma; Wu, Zili; Feng, Zhili; Zhang, Tong

    2015-03-24

    Nanoinks are currently a topic of heightened interest with respect to low temperature bonding processes and printable electronics. We have developed an innovative polyvinylpyrrolidone (PVP)-stabilized Ag nanoplate ink amenable to very strong low temperature packaging, and investigated the relationship between bonding strength and electrical conductivity post-bonding. PVP shell plastic deformations observed in failure microcracks with the formation of PVP nanofibers, revealed bonding strength at low temperatures (<250 °C) was primarily due to adhesive bonding. It is found that, utilizing photonic sintering, ~70 °C reduction of transformation temperature from adhesive to metallic bonding was achieved compared to that of thermal sintering.more » A numerical simulation was developed to better understand the influences of the light-induced heat generation, which demonstrated near-infrared light can facilitate sintering. Bonding strengths of 27 MPa were achieved at room temperatures, and 29.4 MPa at 210 °C with photonic sintering. Moreover, the anisotropic resistivity was observed with different thermal dependences. Furthermore, these results demonstrate Ag nanoplate inks have potential for low temperature 3D interconnections in lead-free microcircuits, flexible electronic packaging, and diverse sensing applications.« less

  19. The Synthesis of Ag-Doped Mesoporous TiO2

    SciTech Connect (OSTI)

    Li, Xiaohong S.; Fryxell, Glen E.; Wang, Chong M.; Engelhard, Mark H.

    2008-04-15

    Ag-doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium precursors, under mild reaction conditions. In contrast to the stabilizing effect of Cd-doping on mesoporous TiO2, Ag-doping was found to significantly destabilize the mesoporous structure.

  20. Preparation and photocatalytic properties of AgISnO{sub 2} nano-composites

    SciTech Connect (OSTI)

    Wen, Biao; Wang, Xiao-Hui; Lu, Juan; Cao, Jia-Lei; Wang, Zuo-Shan

    2013-05-15

    Highlights: ? AgISnO{sub 2} nano-composites have been successfully synthesized. ? As-prepared AgISnO{sub 2} nano-composites own the excellent visible light photocatalytic activity. ? As-prepared AgISnO{sub 2} nano-composites own the excellent stability. - Abstract: AgI doped SnO{sub 2} nano-composites were prepared by the chemical coprecipitation method and were characterized by the X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Results showed that main of the I{sup ?} ions remained in the AgI lattice which is highly dispersed in the system. The photo-catalytic experiments performed under visible light irradiation using methylene blue as the pollutant revealed that not only the photo-catalytic activity but also the stability of SnO{sub 2} based photocatalyst could be improved by introduction of an appropriate amount of AgI, and the result was further supported by the UVVis diffuse reflection spectra and the electron spin-resonance spectra. Among all of the samples, AgISnO{sub 2} nano-composite with 2At% AgI exhibited the best catalytic efficiency and stability.

  1. Function Specific Analysis of the Thermal Durability of Cu-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Presentation given ...

  2. Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mechanism of CuZeolite SCR Catalyst Due to Reductive Hydrothermal Aging Deactivation Mechanism of CuZeolite SCR Catalyst Due to Reductive Hydrothermal Aging Better control for ...

  3. Application of cluster-plus-glue-atom model to barrierless CuNiTi and CuNiTa films

    SciTech Connect (OSTI)

    Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

    2014-11-01

    To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless CuNiM (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?C for 1?h. After annealing at 500?C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of MNi is more negative than that of MCu.

  4. Preparation of Ag/AgCl/BiMg{sub 2}VO{sub 6} composite and its visible-light photocatalytic activity

    SciTech Connect (OSTI)

    Guo, Rui; Zhang, Gaoke; Liu, Jiu

    2013-05-15

    Graphical abstract: - Abstract: A novel composite photocatalyst Ag/AgCl/BiMg{sub 2}VO{sub 6} was synthesized by depositing Ag/AgCl nanoparticles on BiMg{sub 2}VO{sub 6} substrate via a precipitation–photoreduction method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDXA), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectrophotometer (UV–vis DRS). The photocatalyst showed high and stable photocatalytic activity for photocatalytic degradation of acid red G under visible-light irradiation (λ > 420 nm). In addition, the active ·O{sub 2}{sup −} and h{sup +}, as main reactive species, played the major roles during the reaction process. The high photocatalytic activity of the composite may be related to the efficient electron–hole pairs separation at the photocatalyst interfaces, as well as the surface plasmon resonance of Ag nanoparticles formed on AgCl particles in the degradation reaction.

  5. Joint contributions of Ag ions and oxygen vacancies to conducting filament evolution of Ag/TaO{sub x}/Pt memory device

    SciTech Connect (OSTI)

    Chung, Yu-Lung; Cheng, Wen-Hui; Chen, Wei-Chih; Jhan, Sheng-An; Chen, Jen-Sue; Jeng, Jiann-Shing

    2014-10-28

    The electroforming and resistive switching behaviors in the Ag/TaO{sub x}/Pt trilayer structure are investigated under a continual change of temperatures between 300 K and 100 K to distinguish the contributions of Ag ions and oxygen vacancies in developing of conducting filaments. For either electroforming or resistive switching, a significantly higher forming/set voltages is needed as the device is operated at 100 K, as compared to that observed when operating at 300 K. The disparity in forming/set voltages of Ag/TaO{sub x}/Pt operating at 300 K and 100 K is attributed to the contribution of oxygen vacancies, in addition to Ag atoms, in formation of conducting filament at 100 K since the mobilities of oxygen vacancies and Ag ions become comparable at low temperature. The presence of oxygen vacancy segment in the conducting filament also modifies the reset current from a gradually descending behavior (at 300 K) to a sharp drop (at 100 K). Furthermore, the characteristic set voltage and reset current are irreversible as the operation temperature is brought from 100 K back to 300 K, indicating the critical role of filament constituents on the switching behaviors of Ag/oxide/Pt system.

  6. Low-temperature ferromagnetic properties in Co-doped Ag{sub 2}Se nanoparticles

    SciTech Connect (OSTI)

    Yang, Fengxia E-mail: xia9020@hust.edu.cn; Yu, Gen; Han, Chong; Liu, Tingting; Zhang, Duanming; Xia, Zhengcai E-mail: xia9020@hust.edu.cn

    2014-01-06

    β-Ag{sub 2}Se is a topologically nontrivial insulator. The magnetic properties of Co-doped Ag{sub 2}Se nanoparticles with Co concentrations up to 40% were investigated. The cusp of zero-field-cooling magnetization curves and the low-temperature hysteresis loops were observed. With increasing concentration of Co{sup 2+} ions mainly substituting Ag{sub I} sites in the Ag{sub 2}Se structure, the resistivity, Curie temperature T{sub c}, and magnetization increased. At 10 T, a sharp drop of resistance near T{sub c} was detected due to Co dopants. The ferromagnetic behavior in Co-doped Ag{sub 2}Se might result from the intra-layer ferromagnetic coupling and surface spin. This magnetic semiconductor is a promising candidate in electronics and spintronics.

  7. Conducting mechanisms of forming-free TiW/Cu{sub 2}O/Cu memristive devices

    SciTech Connect (OSTI)

    Yan, P.; Li, Y.; Hui, Y. J.; Zhong, S. J.; Zhou, Y. X.; Xu, L.; Liu, N.; Qian, H.; Sun, H. J. Miao, X. S.

    2015-08-24

    P-type Cu{sub 2}O is a promising CMOS-compatible candidate to fabricate memristive devices for next-generation memory, logic and neuromorphic computing. In this letter, the microscopic switching and conducting mechanisms in TiW/Cu{sub 2}O/Cu memristive devices have been thoroughly investigated. The bipolar resistive switching behaviors without an electro-forming process are ascribed to the formation and rupture of the conducting filaments composed of copper vacancies. In the low resistive state, the transport of electrons in the filaments follows Mott's variable range hopping theory. When the devices switch back to high resistive state, the coexistence of Schottky emission at the Cu/Cu{sub 2}O interface and electron hopping between the residual filaments is found to dominate the conducting process. Our results will contribute to the further understanding and optimization of p-type memristive materials.

  8. How to stabilize highly active Cu+ cations in a mixed-oxide catalyst

    DOE PAGES-Beta [OSTI]

    Mudiyanselage, Kumudu; Luo, Si; Kim, Hyun You; Yang, Xiaofang; Baber, Ashleigh E.; Hoffmann, Friedrich M.; Senanayake, Sananayake; Rodriguez, Jose A.; Chen, Jingguang G.; Liu, Ping; et al

    2015-09-12

    Mixed-metal oxides exhibit novel properties that are not present in their isolated constituent metal oxides and play a significant role in heterogeneous catalysis. In this study, a titanium-copper mixed-oxide (TiCuOx) film has been synthesized on Cu(111) and characterized by complementary experimental and theoretical methods. At sub-monolayer coverages of titanium, a Cu2O-like phase coexists with TiCuOx and TiOx domains. When the mixed-oxide surface is exposed at elevated temperatures (600–650 K) to oxygen, the formation of a well-ordered TiCuOx film occurs. Stepwise oxidation of TiCuOx shows that the formation of the mixed-oxide is faster than that of pure Cu2O. As the Timore » coverage increases, Ti-rich islands (TiOx) form. The adsorption of CO has been used to probe the exposed surface sites on the TiOx–CuOx system, indicating the existence of a new Cu+ adsorption site that is not present on Cu2O/Cu(111). Adsorption of CO on Cu+ sites of TiCuOx is thermally more stable than on Cu(111), Cu2O/Cu(111) or TiO2(110). The Cu+ sites in TiCuOx domains are stable under both reducing and oxidizing conditions whereas the Cu2O domains present on sub-monolayer loads of Ti can be reduced or oxidized under mild conditions. Furthermore, the results presented here demonstrate novel properties of TiCuOx films, which are not present on Cu(111), Cu2O/Cu(111), or TiO2(110), and highlight the importance of the preparation and characterization of well-defined mixed-metal oxides in order to understand fundamental processes that could guide the design of new materials.« less

  9. Photoelectrochemistry, Electronic Structure, and Bandgap Sizes of Semiconducting Cu(I)-Niobates and Cu(I)-Tantalates

    SciTech Connect (OSTI)

    Maggard, Paul A.

    2013-11-14

    Semiconducting metal-oxides have remained of intense research interest owing to their potential for achieving efficient solar-driven photocatalytic reactions in aqueous solutions that occur as a result of their bandgap excitation. The photocatalytic reduction of water or carbon dioxide to generate hydrogen or hydrocarbon fuels, respectively, can be driven on p-type (photocathodic) electrodes with suitable band energies. However, metal-oxide semiconductors are typically difficult to dope as p-type with a high mobility of carriers. The supported research led to the discovery of new p-type Cu(I)-niobate and Cu(I)-tantalate film electrodes that can be prepared on FTO glass. New high-purity flux syntheses and the full structural determination of several Cu(I)-containing niobates and tantalates have been completed, as well as new investigations of their optical and photoelectrochemical properties and electronic structures via density-functional theory calculations. For example, CuNbO3, Cu5Ta11O30 and CuNb3O8 were prepared in high purity and their structures were characterized by both single-crystal and powder X-ray diffraction techniques. These two classes of Cu(I)-containing compounds exhibit optical bandgap sizes ranging from ~1.3 eV to ~2.6 eV. Photoelectrochemical measurements of these compounds show strong photon-driven cathodic currents that confirm the p-type semiconductor behavior of CuNbO3, CuNb3O8, and Cu5Ta11O30. Incident-photon-to-current efficiencies are measured that approach greater than ~1%. Electronic-structure calculations based on density functional theory reveal the visible-light absorption stems from a nearly-direct bandgap transition involving a copper-to-niobium or tantalum (d10 to d0) charge-transfer excitations.

  10. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer

    2013-07-15

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with μ{sub eff}=7.87(1) μ{sub B}/Eu atom and θ{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of −9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  11. Structure and electrochemical properties of nanometer Cu substituted ?-nickel hydroxide

    SciTech Connect (OSTI)

    Bao, Jie; Zhu, Yanjuan; Zhang, Zhongju; Xu, Qingsheng; Zhao, Weiren; Chen, Jian; Zhang, Wei; Han, Quanyong

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ? Cu substituted ?-nickel hydroxide was prepared by ultrasonic assisted precipitation. ? The XRD peaks are anisotropic broadening. ? The electrode for 0.9 wt.% Cu has the highest capacity of 310 mAh/g at 0.2 C. -- Abstract: Nanometer Cu-substituted ?-nickel hydroxide was synthesized by means of ultrasonic-assisted precipitation. Particle size distribution (PSD) measurement, X-ray diffraction (XRD), and high-resolution transmission electron microscope (HR-TEM) were used to characterize the physical properties of the synthesized samples. The results indicate that the average particle size of the samples is about 96110 nm and the XRD diffraction peaks are anisotropic broadening. The crystal grains are mainly polycrystal structure with columnar or needle-like morphology, containing many defects. With increase of Cu content, the shape of primary particles transform from columnar to needle-like. The influences of doping amounts of Cu on the electrochemical performance were investigated through constant current charge/discharge and cyclic voltammetric measurements. The specific capacity increases initially and then decreases with increasing Cu-doping ratio, the electrode C containing 0.9 wt.% Cu shows the maximum discharge capacity of 310 mAh/g at 0.2 C, and it has the lowest charging voltage, higher discharge voltage plateau, better cycle performance and larger proton diffusion coefficient than the other electrodes.

  12. Effect of Ag addition to L1{sub 0} FePt and L1{sub 0} FePd films grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Tokuoka, Y.; Seto, Y.; Kato, T.; Iwata, S.

    2014-05-07

    L1{sub 0} ordered FePt-Ag (5?nm) and FePd-Ag (5?nm) films were grown on MgO (001) substrate at temperatures of 250400?C by using molecular beam epitaxy method, and their crystal and surface structures, perpendicular magnetic anisotropies and Curie temperatures were investigated. In the case of FePt-Ag, Ag addition with the amount of 1020 at.?% was effective to promote L1{sub 0} ordering and granular growth, resulting in the increase of the perpendicular magnetic anisotropy and coercivity of the FePt-Ag films. On the other hand, in the case of FePd-Ag, Ag addition changed the surface morphology from island to continuous film associated with the reductions of its coercivity and perpendicular anisotropy. The variations of lattice constants and Curie temperature with Ag addition were significantly different between FePt-Ag and FePd-Ag. For FePd-Ag, the c and a axes lattice spacings and Curie temperature gradually changed with increasing Ag content, while they unchanged for FePt-Ag. These results suggest the possibility of the formation of FePdAg alloy in FePd-Ag, while Ag segregation in FePt-Ag.

  13. Intermediate hearth repair technique at Thyssen Stahl AG

    SciTech Connect (OSTI)

    Kowalski, W.; Bachhofen, H.J.; Ruether, P.; Ballewski, T.

    1996-12-31

    Nowadays various techniques for the fastest possible intermediate repair and/or emplacement of refractory materials above the tuyere level allow a significant extension of furnace campaign life. The latter are hence now exclusively determined by the service life of the hearth. The improvement of hearth monitoring and the estimation of residual brick strength of the refractory lining on the basis of temperature measurements in the hearth enable the location of individual zones of premature wear. These measurement methods, which were developed by Thyssen Stahl AG, aid the decision to undertake selective repair of the hearth. Three areas of repair are differentiated: taphole zone; hearth wall, localized; and hearth wall, extensive. This hearth repair method is described in this report using the example of hearth refurbishing blast furnace 8, Hamborn.

  14. Optimization of the AGS superconducting helical partial snake strength.

    SciTech Connect (OSTI)

    Lin,F.; Huang, H.; Luccio, A.U.; Roser, T.

    2008-06-23

    Two helical partial snakes, one super-conducting (a.k.a cold snake) and one normal conducting (a.k.a warm snake), have preserved the polarization of proton beam up to 65% in the Brookhaven Alternating Gradient Synchrotron (AGS) at the extraction energy from 85% at injection. In order to overcome spin resonances, stronger partial snakes would be required. However, the stronger the partial snake, the more the stable spin direction tilted producing a stronger horizontal intrinsic resonance. The balance between increasing the spin tune gap generated by the snakes and reducing the tilted stable spin direction has to be considered to maintain the polarization. Because the magnetic field of the warm snake has to be a constant, only the cold snake with a maximum 3T magnetic field can be varied to find out the optimum snake strength. This paper presents simulation results by spin tracking with different cold snake magnetic fields. Some experimental data are also analyzed.

  15. AGS tune jump power supply design and test

    SciTech Connect (OSTI)

    Mi, J.; Glenn, J.W.; Huang, H.; Marneris, I.; Rosas, P.; Sandberg, J.; Tan, Y.; Zhang, W.

    2011-03-28

    A horizontal tune jump system has been installed to overcome the horizontal intrinsic spin resonances, which requires jumping the horizontal tune 0.04 units 82 times, 41 up and 41 down. Two quadruple magnets have been installed in AGS ring to perform this. The pulsed magnet current ranges from about 140A near injection to about 1400A later. The current pulse rise and fall time are around 100uS and flat tops time is around 4mS. These quadruples have separated supplies. This tune jump pulse power supply employees all semiconductor parts as well as the main switches. During dummy load and magnet testing, the test results showed that the power supply could meet the specification. This article will describe some details of power supply simulation, design and testing. Some test waveforms and pictures are presented in this paper.

  16. Recent development of Bi(2223)/Ag tapes for practical applications

    SciTech Connect (OSTI)

    Grasso, G.; Siri, A.S.; Marti, F.; Huang, Y.; Fluekiger, R.; Caracino, P.; Martini, L.

    1999-04-20

    In this paper the authors report about some of the major developments of Ag sheathed Bi(2223) tapes that are actually under study in view of a possible practical application of these conductors. Efforts on improving the tape behavior in presence of alternating currents and high magnetic fields have to be done together with a severe optimization of the Powder-In-Tube method. A clear reduction of the magnetic AC losses is observed by AC susceptibility measurements performed on twisted Bi(2223) tapes prepared at the University of Geneva, with a resistive barrier capable of reducing the coupling losses between filaments. Finally, the authors report on multifilamentary tapes developed with a special configuration that can be of great interest when a magnetic field is applied to the tape at a significant angle with respect to the a-b planes of the superconductor.

  17. Transverse impedance measurement in RHIC and the AGS

    SciTech Connect (OSTI)

    Biancacci, Nicolo; Blaskiewicz, M.; Dutheil, Y.; Liu, C.; Mernick, M.; Minty, M.; White, S. M.

    2014-05-12

    The RHIC luminosity upgrade program aims for an increase of the polarized proton luminosity by a factor 2. To achieve this goal a significant increase in the beam intensity is foreseen. The beam coupling impedance could therefore represent a source of detrimental effects for beam quality and stability at high bunch intensities. For this reason it is essential to quantify the accelerator impedance budget and the major impedance sources, and possibly cure them. In this MD note we summarize the results of the 2013 transverse impedance measurements in the AGS and RHIC. The studies have been performed measuring the tune shift as a function of bunch intensity and deriving the total accelerator machine transverse impedance. For RHIC, we could obtain first promising results of impedance localization measurements as well.

  18. Manipulating Stress in Cu/low-k Dielectric Nanocomposites

    SciTech Connect (OSTI)

    C Murray; P Besser; E Ryan; J Jordan-Sweet

    2011-12-31

    The interaction of x-rays with organic dielectric materials, which alters their mechanical properties, affects values of stress generated within encapsulated Cu structures. In particular, the evolution of stress within submicron Cu interconnect structures encapsulated by an organosilicate glass can be investigated in situ using synchrotron-based x-ray diffraction. The overall geometry of the composite, along with the amount of irradiation, dictates the change in stress of the Cu features. A quantitative comparison of these findings to mechanical modeling results reveals two modes of modification within the dielectric film: a densification that changes the effective eigenstrain followed by an increase in elastic modulus.

  19. Coupled skyrmion sublattices in Cu2OSeO3

    SciTech Connect (OSTI)

    Langner, M.C.; Roy,, S.; Mishra, S. K.; Lee, J. C. T.; Shi,, X. W.; Hossain, M. A.; Chuang, Y.-D.; Seki, S.; Tokura, Y.; Kevan, S. D.; Schoenlein, R. W.

    2014-04-18

    We report the observation of a skyrmion lattice in the chiral multiferroic insulator Cu2OSeO3 using Cu L3-edge resonant soft x-ray diffraction. We observe the unexpected existence of two distinct skyrmion sub-lattices that arise from inequivalent Cu sites with chemically identical coordination numbers but different magnetically active orbitals . The skyrmion sublattices are rotated with respect to each other implying a long wavelength modulation of the lattice. The modulation vector is controlled with an applied magnetic field, associating this Moir'e-like phase with a continuous phase transition. Our findings will open a new class of science involving manipulation of quantum topological states.

  20. Role of Cu-Ion Doping in Cu-α-MnO2 Nanowire Electrocatalysts for the Oxygen Reduction Reaction

    DOE PAGES-Beta [OSTI]

    Davis, Danae J.; Lambert, Timothy N.; Vigil, Julian A.; Rodriguez, Mark A.; Brumbach, Michael T.; Coker, Eric N.; Limmer, Steven J.

    2014-07-09

    The role of Cu-ion doping in α-MnO2 electrocatalysts for the oxygen reduction reaction in alkaline electrolyte was investigated. Copper doped α-MnO2 nanowires (Cu-α-MnO2) were prepared with varying amounts of Cu2+ using a solvothermal method. The electrocatalytic dataindicates that Cu-α-MnO2 nanowires have higher terminal current densities, enhanced kinetic rate constants, and improved charge transfer resistances that trend with Cu-content, exceeding values attained by α-MnO2 alone. The observed improvement in catalytic behavior correlates with an increase in Mn3+ content for the Cu-α-MnO2 nanowires. The Mn3+/Mn4+ couple is themediator for the rate-limiting redox driven O2-/OH- exchange. It is proposed that O2 adsorbs viaanmore » axial site (the eg orbital on the Mn3+ d4 ion) at the surface, or at edge defects, of the nanowireand that the increase in covalent nature of the nanowire with Cu-ion doping leads to stabilization of O2 adsorbates and faster rates of reduction. This work is applicable to other manganese oxide electrocatalysts and shows for the first time there is a correlation for manganese oxides between electrocatalytic activity for the ORR in alkaline electrolyte and an increase in Mn3+ character of the oxide.« less

  1. Hierarchical Ag/ZnO micro/nanostructure: Green synthesis and enhanced photocatalytic performance

    SciTech Connect (OSTI)

    Gao, Shuyan; Jia, Xiaoxia; Yang, Shuxia; Li, Zhengdao; Jiang, Kai

    2011-04-15

    Ag/ZnO metal-semiconductor nanocomposites with hierarchical micro/nanostructure have been prepared by the hydrothermal synthesis in the presence of bovine serum albumin (BSA). The results suggest that this biomolecule-assisted hydrothermal method is an efficient route for the fabrication of Ag/ZnO nanocomposites by using BSA both a shape controller and a reducing agent of Ag{sup +} ions. Moreover, Ag nanoparticles on the ZnO act as electron sinks, improving the separation of photogenerated electrons and holes, increasing the surface hydroxyl contents of ZnO, facilitating trapping the photoinduced electrons and holes to form more active hydroxyl radicals, and thus, enhancing the photocatalytic efficiency of ZnO. This is a good example for the organic combination of green chemistry and functional materials. -- Graphical Abstract: A green strategy is report to construct Ag/ZnO metal-semiconductor nanocomposites with hierarchical micro/nanostructure and enhanced photocatalytic activity. Display Omitted Research highlights: > Hierarchical micro/nanostructured Ag/ZnO nanocomposites have been prepared via a green route. > Ag nanoparticles improve the separation of photogenerated electrons and holes. > This facilitates trapping the photoinduced electrons and holes to form more hydroxyl radicals. Therefore, it enhances the photocatalytic efficiency of ZnO.

  2. Light-dependent controlled synthesis and photocatalytic properties of stable Ag{sub 3} nanocrystals

    SciTech Connect (OSTI)

    Wang, Jian-Dong; Liu, Jin-Ku; Luo, Chong-Xiao; Yang, Xiao-Hong

    2014-12-15

    The silver phosphate (Ag{sub 3}PO{sub 4}) is applied in organic matter photodegradation as a novel catalyst materials, however, its instability reduces the photocatalytic life and limits its further applications. In this work, a series of Ag{sub 3}PO{sub 4} crystalline nanoparticle clusters have been synthesized by a photocontrol method. By comparing their sunlight photocatalytic properties, the Ag{sub 3}PO{sub 4} nanoparticles with dominant (2 2 0) facets have a lower surface energy (1.05 J m{sup ?2}) than existing Ag{sub 3}PO{sub 4} crystals which can offer a longer catalyst service life. The photodegradation rate of the Ag{sub 3}PO{sub 4} nanoparticles is about 3 times that of common Ag{sub 3}PO{sub 4} bulk materials and the sunlight is used as the power source instead of high cost artificial visible light sources in this catalytic system. An effective continuous photodegradation reactor using Ag{sub 3}PO{sub 4} nanoparticles is successfully fabricated to degrade rhodamine B solution. At the same time, this work provides an example for how oxidation photocatalyst works without extra adding sacrificial reagent.

  3. A novel polythreading Ag(I) coordination polymer with blue photoluminescence

    SciTech Connect (OSTI)

    Duan, Xian-Ying; Yao, Jing; Lu, Chang-Sheng; Meng, Qing-Jin

    2013-04-15

    One new compound, [Ag(p-bix)]{sub 3}[Ag(Hbtc){sub 2}]·2H{sub 2}O (H{sub 3}btc=1,2,4-benzenetricarboxylate, p-bix=1,4-bis(imidazol-1-ylmethyl)-benzene), has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, PXRD, luminescent analysis, and single-crystal X-ray diffraction. X-ray structural analysis revealed that 0-D unit [Ag(Hbtc){sub 2}]{sup 3−} and two kinds of 1-D linear chain [Ag(p-bix)]{sub ∞}{sup +}, can be found within the crystal structure. The combination of 0-D [Ag(Hbtc){sub 2}]{sup 3−} unit and 1-D undulated chain [Ag1(p{sub 1}-bix)]{sub ∞}{sup +} through weak Ag–O bond gave rise to 2-D anionic supramolecular doublelayer. Then the grids of the 2-D layer are threaded by 1-D linear cationic chain [Ag2(p{sub 2}-bix)]{sub ∞}{sup +} to generate entangled 3-D architecture with unusual poly(pseudo-rotaxane)-type arrangements. Luminescent properties of the title complex were also studied in this paper. - Graphical abstract: Novel 3D polythreading supramolecular architecture was constructed, in which 1D linear cationic chains [Ag(p{sub 2}-bix)]{sub ∞}{sup +} threaded into the grid of weak Ag–O bonded anionic 2D sheet. Highlights: ► Novel 1D{sup +}+2D{sup −}→3D polythreading coordination complex was reported. ► Diverse conformations of p-bix result in different 1D [Ag(p-bix)]{sub ∞}{sup +} chains. ► The title complex displayed blue photoluminescence at room temperature.

  4. Crystallization of Zr2PdxCu(1-x) and Zr2NixCu(1-x) Metallic Glass

    SciTech Connect (OSTI)

    Min Xu

    2008-08-18

    One interesting aspect of rretallic glasses is the numerous instances of the deviation of the phase selection from the amorphous state to thermodynamically stable phases during the crystallization process. Their devitrification pathways allow us to study the relationship between the original amorphous structure and their crystalline counter parts. Among the various factors of phase selections, size and electronic effects have been most extensively studied. Elucidating the phase selection process of a glassy alloy will be helpful to fill in the puzzle of the changes from disordered to ordered structures. In this thesis, Two model Zr{sub 2}Pd{sub x}Cu{sub (1-x)} and Zr{sub 2}Ni{sub x}Cu{sub (1-x)} (x = 0, 0.25, 0.5, 0.75 and 1) glassy systems were investigated since: (1) All of the samples can be made into a homogenous metallic glass; (2) The atomic radii differ from Pd to Cu is by 11%, while Ni has nearly the identical atomic size compare to Cu. Moreover, Pd and Ni differ by only one valence electron from Cu. Thus, these systems are ideal to test the idea of the effects of electronic structure and size factors; (3) The small number of components in these pseudo binary systems readily lend themselves to theoretical modeling. Using high temperature X-ray diffraction {HTXRD) and thermal analysis, topological, size, electronic, bond and chemical distribution factors on crystallization selections in Zr{sub 2}Pd{sub x}Cu{sub (1-x)} and Zr{sub 2}Ni{sub x}Cu{sub (1-x)} metallic glass have been explored. All Zr{sub 2}Pd{sub x}Cu{sub (1-x)} compositions share the same Cu11b phase with different pathways of meta-stable, icosahedral quasicrystalline phase (i-phase), and C16 phase formations. The quasicrystal phase formation is topologically related to the increasing icosahedral short range order (SRO) with Pd content in Zr{sub 2}Pd{sub x}Cu{sub (1·x)} system. Meta-stable C16 phase is competitive with C11b phase at x = 0.5, which is dominated by electronic structure rather than

  5. An overview of Booster and AGS polarized proton operation during Run 15

    SciTech Connect (OSTI)

    Zeno, K.

    2015-10-20

    This note is an overview of the Booster and AGS for the 2015 Polarized Proton RHIC run from an operations perspective. There are some notable differences between this and previous runs. In particular, the polarized source intensity was expected to be, and was, higher this year than in previous RHIC runs. The hope was to make use of this higher input intensity by allowing the beam to be scraped down more in the Booster to provide a brighter and smaller beam for the AGS and RHIC. The RHIC intensity requirements were also higher this run than in previous runs, which caused additional challenges because the AGS polarization and emittance are normally intensity dependent.

  6. Longitudinal emittance measurements in the Booster and AGS during the 2014 RHIC gold run

    SciTech Connect (OSTI)

    Zeno, K.

    2014-08-18

    This note describes longitudinal emittance measurements that were made in the Booster and AGS during the 2014 RHIC Gold run. It also contains an overview of the longitudinal aspects of their setup during this run. Each bunch intended for RHIC is composed of beam from 4 Booster cycles, and there are two of them per AGS cycle. For each of the 8 Booster cycles required to produce the 2 bunches in the AGS, a beam pulse from EVIS is injected into the Booster and captured in four h=4 buckets. Then those bunches are accelerated to a porch where they are merged into 2 bunches and then into 1 bunch.

  7. Effect of Ag doping and annealing on thermoelectric properties of PbTe

    SciTech Connect (OSTI)

    Bala, Manju Tripathi, T. S.; Avasthi, D. K.; Asokan, K.; Gupta, Srashti

    2015-06-24

    The present study reveals that annealing Ag doped PbTe thin films enhance thermoelectric properties. Phase formation was identified by using X-ray diffraction measurement. Annealing increases the crystallinity of both undoped and Ag doped PbTe. Electrical resistivity and thermoelectric power measurements are done using four probe and bridge method respectively. The increase in thermoelectric power of Ag doped PbTe is 29 % in comparison to undoped PbTe and it further increases to 34 % after annealing at 250{sup o} C for 1 hour whereas thermoelectric power increases by 14 % on annealing undoped PbTe thin films at same temperature.

  8. Nanoscale structure in AgSbTe2 determined by diffuse elastic neutron scattering

    SciTech Connect (OSTI)

    Specht, Eliot D [ORNL; Ma, Jie [ORNL; Delaire, Olivier A [ORNL; Budai, John D [ORNL; May, Andrew F [ORNL; Karapetrova, Evguenia A. [Argonne National Laboratory (ANL)

    2015-01-01

    Diffuse elastic neutron scattering measurements confirm that AgSbTe2 has a hierarchical structure, with defects on length scales from nanometers to microns. While scattering from mesoscale structure is consistent with previously-proposed structures in which Ag and Sb order on a NaCl lattice, more diffuse scattering from nanoscale structure suggests a structural rearrangement in which hexagonal layers form a combination of (ABC), (ABA), and (AAB) stacking sequences. The AgCrSe2 structure is the best-fitting model for the local atomic arrangements.

  9. Current-perpendicular-to-the-plane giant magnetoresistance in spin-valves with AgSn alloy spacers

    SciTech Connect (OSTI)

    Read, J. C.; Nakatani, T. M.; Smith, Neil; Choi, Y.-S.; York, B. R.; Brinkman, E.; Childress, J. R.

    2015-07-28

    We investigate the use of AgSn alloys as the spacer layer in current-perpendicular-to-the-plane magnetoresistance devices. Alloying with Sn increases resistivity but results in a reasonably long (>10 nm) spin-diffusion length, so large magnetoresistance can be achieved with thin AgSn spacers. Compared to Ag thin films, AgSn forms smaller grain sizes, reduced roughness, and exhibits less interdiffusion upon annealing, resulting in decreased interlayer magnetic coupling in exchange biased spin-valves. AgSn also shows improved corrosion resistance compared to Ag, which is advantageous for nanofabrication, including magnetic recording head sensors. Combining a AgSn spacer with Co-based Heusler alloy ferromagnet in an exchange biased, polycrystalline trilayer thinner than 12 nm results in magnetoresistance values up to 15% at room temperature.

  10. Improving properties of Mg with AlCu additions

    SciTech Connect (OSTI)

    Rashad, Muhammad; Pan, Fusheng; Asif, Muhammad; Hussain, Shahid; Saleem, Muhammad

    2014-09-15

    The present work reports improvement in tensile properties of the Mg matrix reinforced with micron-sized copperaluminum particulate hybrids. The AlCu particulate hybrids were incorporated into the Mg matrix through powder metallurgy method. The synthesized alloys exhibited homogeneously dispersed Mg{sub 2}Cu particles in the matrix, therefore leading to a 110% increase in yield strength (221 MPa) and a 72% enhancement in ultimate tensile strength (284 MPa) by addition of 1.0 wt.%Al0.6 wt.%Cu particle hybrids. Optical microscopy, scanning election microscopy, transmission electron microscopy and X-ray diffraction were used to investigate the microstructure and intermetallic phases of the synthesized alloys. - Highlights: Mg matrix is reinforced with AlCu particulate hybrids. Powder metallurgic method is used to fabricate the alloys. Tensile strength and ductility were increased simultaneously.

  11. Microwave assisted hydrothermal synthesis of Ag/AgCl/WO{sub 3} photocatalyst and its photocatalytic activity under simulated solar light

    SciTech Connect (OSTI)

    Adhikari, Rajesh; Gyawali, Gobinda; Sekino, Tohru; Wohn Lee, Soo

    2013-01-15

    Simulated solar light responsive Ag/AgCl/WO{sub 3} composite photocatalyst was synthesized by microwave assisted hydrothermal process. The synthesized powders were characterized by X-Ray Diffraction (XRD) spectroscopy, X-Ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Diffuse Reflectance Spectroscopy (UV-Vis DRS), and BET surface area analyzer to investigate the crystal structure, morphology, chemical composition, optical properties and surface area of the composite photocatalyst. This photocatalyst exhibited higher photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation. Dye degradation efficiency of composite photocatalyst was found to be increased significantly as compared to that of the commercial WO{sub 3} nanopowder. Increase in photocatalytic activity of the photocatalyst was explained on the basis of surface plasmon resonance (SPR) effect caused by the silver nanoparticles present in the composite photocatalyst. Highlights: Black-Right-Pointing-Pointer Successful synthesis of Ag/AgCl/WO{sub 3} nanocomposite. Black-Right-Pointing-Pointer Photocatalytic experiment was performed under simulated solar light. Black-Right-Pointing-Pointer Nanocomposite photocatalyst was very active as compared to WO{sub 3} commercial powder. Black-Right-Pointing-Pointer SPR effect due to Ag nanoparticles enhanced the photocatalytic activity.

  12. Impact of the Stack Order in Cu-Zn-Sn Metal Precursors on the Properties of

    Office of Scientific and Technical Information (OSTI)

    Cu2ZnSnS4 Thin Films (Conference) | SciTech Connect Impact of the Stack Order in Cu-Zn-Sn Metal Precursors on the Properties of Cu2ZnSnS4 Thin Films Citation Details In-Document Search Title: Impact of the Stack Order in Cu-Zn-Sn Metal Precursors on the Properties of Cu2ZnSnS4 Thin Films Cu2ZnSnS4 (CZTS) thin films were grown by the annealing of metallic precursors with different stack orders in sulfur atmosphere. The sequential deposition of the metal layers from single Cu, Zn, and Sn

  13. Characteristics of Cu stabilized Nb3Al strands with low Cu ratio

    SciTech Connect (OSTI)

    Kikuchi, A.; Yamada, R.; Barzi, E.; Kobayashi, M.; Lamm, M.; Nakagawa, K.; Sasaki, K.; Takeuchi, T.; Turrioni, D.; Zlobin, A.V.; /NIMC, Tsukuba /Fermilab /Hitachi, Tsuchiura Works /KEK, Tsukuba

    2008-12-01

    Characteristics of recently developed F4-Nb{sub 3}Al strand with low Cu ratio are described. The overall J{sub c} of the Nb{sub 3}Al strand could be easily increased by decreasing of the Cu ratio. Although the quench of a pulse-like voltage generation is usually observed in superconducting unstable conductor, the F4 strand with a low Cu ratio of 0.61 exhibited an ordinary critical transition of gradual voltage generation. The F4 strand does not have magnetic instabilities at 4.2 K because of the tantalum interfilament matrix. The overall J{sub c} of the F4 strand achieved was 80-85% of the RRP strand. In the large mechanical stress above 100 MPa, the overall J{sub c} of the F4 strand might be comparable to that of high J{sub c} RRP-Nb{sub 3}Sn strands. The Rutherford cable with a high packing factor of 86.5% has been fabricated using F4 strands. The small racetrack magnet, SR07, was also fabricated by a 14 m F4 cable. The quench current, I{sub q}, of SR07 were obtained 22.4 kA at 4.5 K and 25.2 kA at 2.2 K. The tantalum matrix Nb{sub 3}Al strands are promising for the application of super-cooled high-field magnets as well as 4.2 K operation magnets.

  14. Cu--Pd--M hydrogen separation membranes

    DOE Patents [OSTI]

    Do{hacek over }an, Omer N; Gao, Michael C; Young, Rongxiang Hu; Tafen, De Nyago

    2013-12-17

    The disclosure provides an H2 separation membrane comprised of an allow having the composition Cu.Sub.(100-x-y)Pd.sub.xM.sub.y, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the allow, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the allow is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600.degree. C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the allow at a steady-state temperature of 400.degree. C. The B2 phase stability is experimentally validated through HT-XRD.

  15. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on γ-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

  16. Comparison of plasma temperature and electron density on nanosecond laser ablation of Cu and nano-Cu

    SciTech Connect (OSTI)

    Chen, Anmin; Jiang, Yuanfei; Wang, Tingfeng; Shao, Junfeng; Jin, Mingxing

    2015-03-15

    Laser-induced breakdown spectroscopy is performed through the collection of spectra by spectral detection equipment at different delay times and distances from targets composed of Cu and nano-Cu, which are ablated using a Nd:YAG laser (532 nm, 10 ns, 10 Hz) in our experiments. The measured wavelength range is from 475 nm to 525 nm. Using the local thermodynamic equilibrium model, we analyze the characteristics of the plasma temperature and the electron number density for different distances between the target surface and the lens. The results show that when compared with the nano-Cu plasma case, the temperature of the Cu plasma is higher, while its electron number density is lower.

  17. ZnO/Ag composite nanorod arrays for surface-plasmon-enhanced emission study

    SciTech Connect (OSTI)

    Pal, Anil Kumar E-mail: d.bharathimohan@gmail.com; Mohan, D. Bharathi E-mail: d.bharathimohan@gmail.com

    2014-04-24

    The surface plasmon resonance enhanced emission through coupling of surface plasmons and exciton band energies is studied in hybrid ZnO/Ag nanostructure. The catalytic growth of ZnO nanorods is controlled in seed mediated growth by altering size distribution of Ag nanoislands. X-ray diffraction shows a predominant (002) crystal plane confirming the preferential growth of ZnO nanorods on as-deposited Ag. Increase of surface roughness in Ag film by post deposition annealing process enhances the light emission due to momentum matching between surface plasmons and excitons as well as a red shift of 32 meV occurs due to multi phonon and phonon-exciton interaction.

  18. Ternary eutectic growth of nanostructured thermoelectric Ag-Pb-Te materials

    SciTech Connect (OSTI)

    Wu, Hsin-jay; Chen, Sinn-wen; Foo, Wei-jian; Jeffrey Snyder, G.

    2012-07-09

    Nanostructured Ag-Pb-Te thermoelectric materials were fabricated by unidirectionally solidifying the ternary Ag-Pb-Te eutectic and near-eutectic alloys using the Bridgeman method. Specially, the Bridgman-grown eutectic alloy exhibited a partially aligned lamellar microstructure, which consisted of Ag{sub 5}Te{sub 3} and Te phases, with additional 200-600 nm size particles of PbTe. The self-assembled interfaces altered the thermal and electronic transport properties in the bulk Ag-Pb-Te eutectic alloy. Presumably due to phonon scattering from the nanoscale microstructure, a low thermal conductivity ({kappa} = 0.3 W/mK) was achieved of the eutectic alloy, leading to a zT peak of 0.41 at 400 K.

  19. DEPARTlIiIENT OF ENERGY EERE PROJECT MAN AG EMENT CENTER NEPA...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    lAUIl) u.s. DEPARTlIiIENT OF ENERGY EERE PROJECT MAN AG EMENT CENTER NEPA DETERMINATION RECIPIENT:Ocean Engineering and Energy Systems Intemational, Inc. (OCEES) Page lof3 STATE: ...

  20. Feasible voltage-tap based quench detection in a Ag/Bi-2212 coil...

    Office of Scientific and Technical Information (OSTI)

    Small insert solenoids have been built using a commercial AgBi-2212 multifilamentary round wire, insulated with a new thin TiO2 - polymer coating insulation (thickness in 20 m ...

  1. Influence of Ag doping concentration on structural and optical properties of CdS thin film

    SciTech Connect (OSTI)

    Kumar, Pragati; Saxena, Nupur; Gupta, Vinay; Agarwal, Avinash

    2015-05-15

    This work shows the influence of Ag concentration on structural properties of pulsed laser deposited nanocrystalline CdS thin film. X-ray photoelectron spectroscopy (XPS) studies confirm the dopant concentration in CdS films and atomic concentration of elements. XPS studies show that the samples are slightly sulfur deficient. GAXRD scan reveals the structural phase transformation from cubic to hexagonal phase of CdS without appearance of any phase of CdO, Ag{sub 2}O or Ag{sub 2}S suggesting the substitutional doping of Ag ions. Photoluminescence studies illustrate that emission intensity increases with increase in dopant concentration upto 5% and then decreases for higher dopant concentration.

  2. Partial gamma-ray cross section measurements in 109Ag(n, x n...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Partial gamma-ray cross section measurements in 109Ag(n, x n y p gamma) reactions Citation Details In-Document Search Title: Partial gamma-ray cross section ...

  3. The U5+ compound Ba9Ag10U4S24: Synthesis, structure, and electronic...

    Office of Scientific and Technical Information (OSTI)

    The U5+ compound Ba9Ag10U4S24: Synthesis, structure, and electronic properties This ... Sponsoring Org: USDOE Country of Publication: United States Language: English Word Cloud ...

  4. Growth, characterization and electrochemical properties of hierarchical CuO nanostructures for supercapacitor applications

    SciTech Connect (OSTI)

    Krishnamoorthy, Karthikeyan; Kim, Sang-Jae

    2013-09-01

    Graphical abstract: - Highlights: Hierarchical CuO nanostructures were grown on Cu foil. Monoclinic phase of CuO was grown. XPS analysis revealed the presence of Cu(2p{sub 3/2}) and Cu(2p{sub 1/2}) on the surfaces. Specific capacitance of 94 F/g was achieved for the CuO using cyclic voltammetry. Impedance spectra show their pseudo capacitor applications. - Abstract: In this paper, we have investigated the electrochemical properties of hierarchical CuO nanostructures for pseudo-supercapacitor device applications. Moreover, the CuO nanostructures were formed on Cu substrate by in situ crystallization process. The as-grown CuO nanostructures were characterized using X-ray diffraction (XRD), Fourier transform-infra red spectroscopy (FT-IR), X-ray photoelectron spectroscopy and field emission-scanning electron microscope (FE-SEM) analysis. The XRD and FT-IR analysis confirm the formation of monoclinic CuO nanostructures. FE-SEM analysis shows the formation of leave like hierarchical structures of CuO with high uniformity and controlled density. The electrochemical analysis such as cyclic voltammetry and electrochemical impedance spectroscopy studies confirms the pseudo-capacitive behavior of the CuO nanostructures. Our experimental results suggest that CuO nanostructures will create promising applications of CuO toward pseudo-supercapacitors.

  5. Analysis of the structure, configuration, and sizing of Cu and Cu oxide nanoparticles generated by fs laser ablation of solid target in liquids

    SciTech Connect (OSTI)

    Santillan, J. M. J.; Videla, F. A.; Schinca, D. C.; Scaffardi, L. B.; Fernandez van Raap, M. B.

    2013-04-07

    We report on the analysis of structure, configuration, and sizing of Cu and Cu oxide nanoparticles (Nps) produced by femtosecond (fs) laser ablation of solid copper target in liquids. Laser pulse energy ranged between 500 {mu}J and 50 {mu}J. Water and acetone were used to produce the colloidal suspensions. The study was performed through optical extinction spectroscopy using Mie theory to fit the full experimental spectra, considering free and bound electrons size dependent contributions to the metal dielectric function. Raman spectroscopy and AFM technique were also used to characterize the sample. Considering the possible oxidation of copper during the fabrication process, two species (Cu and Cu{sub 2}O) arranged in two structures (bare core or core-shell) and in two configuration types (Cu-Cu{sub 2}O or Cu{sub 2}O-Cu) were considered for the fitting depending on the laser pulse energy and the surrounding media. For water at high energy, it can be observed that a Cu-Cu{sub 2}O configuration fits the experimental spectra of the colloidal suspension, while for decreasing energy and below a certain threshold, a Cu{sub 2}O-Cu configuration needs to be included for the optimum fit. Both species coexist for energies below 170 {mu}J for water. On the other hand, for acetone at high energy, optimum fit of the full spectrum suggests the presence a bimodal Cu-Cu{sub 2}O core-shell Nps distribution while for decreasing energy and below a 70 {mu}J threshold energy value, Cu{sub 2}O-Cu core-shell Nps must be included, together with the former configuration, for the fit of the full spectrum. We discuss possible reasons for the changes in the structural configuration of the core-shell Nps.

  6. Magnetic dipole moments of {sup 58}Cu and {sup 59}Cu by in-source laser spectroscopy

    SciTech Connect (OSTI)

    Stone, N. J.; Koester, U.; Stone, J. Rikovska; Fedorov, D. V.; Fedoseyev, V. N.; Flanagan, K. T.; Hass, M.; Lakshmi, S.

    2008-06-15

    Online measurements of the magnetic dipole moments and isotope shifts of {sup 58}Cu and {sup 59}Cu by the in-source laser spectroscopy method are reported. The results for the magnetic moments are {mu} ({sup 58}Cu) =+0.52(8) {mu}{sub N},{mu}({sup 59}Cu) =+1.84(3) {mu}{sub N} and for the isotope shifts {delta}{nu}{sup 59,65}=1.72(22) GHz and {delta}{nu}{sup 58,65}=1.99(30) GHz in the transition from the 3d{sup 10}4s {sup 2}S{sub 1/2} ground state to the 3d{sup 10}4p {sup 2}P{sub 1/2} state in Cu I. The magnetic moment of {sup 58}Cu is discussed in the context of the strength of the subshell closure at {sup 56}Ni, additivity rules and large-scale shell model calculations.

  7. HIGH ENERGY PULSED POWER SYSTEM FOR AGS SUPER NEUTRINO FOCUSING HORN.

    SciTech Connect (OSTI)

    ZHANG, S.Y.; SANDBERG, J.; WENG, W.-T.

    2005-05-16

    This paper present a preliminary design of a 300 kA, 2.5 Hz pulsed power system. This system will drive the focusing horn of proposed Brookhaven AGS Neutrino Super Beam Facility for Very Long Baseline Neutrino Oscillation Experiment. The peak output power of the horn pulsed power system will reach Giga-watts, and the upgraded AGS will be capable of delivering 1 MW in beam power.

  8. Non-toxic silver iodide (AgI) quantum dots sensitized solar cells

    SciTech Connect (OSTI)

    Moosakhani, S.; Sabbagh Alvani, A.A.; Sarabi, A.A.; Sameie, H.; Salimi, R.; Kiani, S.; Ebrahimi, Y.

    2014-12-15

    Highlights: • We have demonstrated AgI sensitized solar cell for the first time. • Obtained mesoporous titania powders possessed small crystallite size, high purity and surface area, and developed mesopores with a narrow pore size distribution. • Photovoltaic measurements revealed the electron injection from AgI to TiO{sub 2}. • The assembled AgI-QD solar cells yielded a power conversion efficiency of 0.64% under one sun illumination. • AgI may be a suitable candidate material for use as a non-toxic sensitizer in QDSSC. - Abstract: The present study reports the performance of a new photosensitizer -AgI quantum dots (QDs)- and mesoporous titania (TiO{sub 2}) nanocrystals synthesized by sol–gel (SG) method for solar cells. Furthermore, the effects of n-heptane on the textural properties of TiO{sub 2} nanocrystals were comprehensively investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), N{sub 2} adsorption–desorption measurements, and UV–vis spectroscopy. TiO{sub 2} powders exhibited an anatase-type mesoporous structure with a high surface area of 89.7 m{sup 2}/g. Afterwards, the QDs were grown on mesoporous TiO{sub 2} surface to fabricate a TiO{sub 2}/AgI electrode by a successive ionic layer adsorption and reaction (SILAR) deposition route. Current–voltage characteristics and electrochemical impedance spectroscopy (EIS) data demonstrated that the injection of photoexcited electrons from AgI QDs into the TiO{sub 2} matrix produces photocurrents. The assembled AgI-QD solar cells yielded a power conversion efficiency of 0.64% and a short-circuit current of 2.13 mA/cm{sup 2} under one sun illumination.

  9. Facile synthesis of pompon-like ZnO-Ag nanocomposites and their enhanced photocatalytic performance

    SciTech Connect (OSTI)

    Cheng, Yang; An, Liang; Lan, Jing; Gao, Fang; Tan, Ruiqin; Li, Xiao-min; Wang, Guang-hui

    2013-10-15

    Graphical abstract: - Highlights: • Pompon-like ZnO-Ag was prepared via heterothermal and photodeposition method. • Pompon-like ZnO-Ag is a excellent photocatalyst for degradation of azo dyes. • The photocatalytic and wetting properties were studied upon UV irradiation. • The discoloring efficiency of ZnO-Ag heterostructure toward to azo dyes is 99.1%. - Abstract: A series of pompon-like ZnO-Ag nanocomposites were prepared by hydrothermal method and photochemical deposition technique. Several characterizations indicated the successful deposition of Ag nanoparticles on ZnO. As a whole, the as-prepared composites present pompon-like nanostructures with a diameter of ∼10 μm. In detail, the nanostructural, chemical and optical properties were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), infrared spectroscopy (IR), ultra-visible spectra (UV). The photocatalytic degradation experiments under UV irradiation using Methyl Orange (MO) as a model dye were executed here. The relative results demonstrated that the pompon-like ZnO-Ag nanocomposite with a suitable content of Ag nanoparticles (about 4.82 wt%) has the highest photochemical activity, and the removal ratio of MO was 99.1% after 0.5 h adsorption and subsequent 2 h photodegradation processes. The excellent photocatalytic performance was attributed to the high surface areas of ZnO nanostructure and effectively separation of photo-generated charge on flower-like ZnO by employing Ag nanoparticles as a conductor.

  10. Effect of carbon ion irradiation on Ag diffusion in SiC

    SciTech Connect (OSTI)

    Leng, Bin; Ko, Hyunseok; Gerczak, Tyler J.; Deng, Jie; Giordani, Andrew J.; Hunter, Jerry L.; Morgan, Dane; Szlufarska, Izabela; Sridharan, Kumar

    2015-11-14

    Transport of Ag fission product through the silicon-carbide (SiC) diffusion barrier layer in TRISO fuel particles is of considerable interest given the application of this fuel type in high temperature gas-cooled reactor (HTGR) and other future reactor concepts. The reactor experiments indicate that radiation may play an important role in release of Ag; however so far the isolated effect of radiation on Ag diffusion has not been investigated in controlled laboratory experiments. In this study, we investigate the diffusion couples of Ag and polycrystalline 3C–SiC, as well as Ag and single crystalline 4H–SiC samples before and after irradiation with C2+ ions. The diffusion couple samples were exposed to temperatures of 1500 °C, 1535 °C, and 1569 °C, and the ensuing diffusion profiles were analyzed by secondary ion mass spectrometry (SIMS). We found that diffusion coefficients calculated from these measurements indicate that Ag diffusion was greatly enhanced by carbon irradiation due to a combined effect of radiation damage on diffusion and the presence of grain boundaries in polycrystalline SiC samples.

  11. Effect of carbon ion irradiation on Ag diffusion in SiC

    DOE PAGES-Beta [OSTI]

    Leng, Bin; Ko, Hyunseok; Gerczak, Tyler J.; Deng, Jie; Giordani, Andrew J.; Hunter, Jerry L.; Morgan, Dane; Szlufarska, Izabela; Sridharan, Kumar

    2015-11-14

    Transport of Ag fission product through the silicon-carbide (SiC) diffusion barrier layer in TRISO fuel particles is of considerable interest given the application of this fuel type in high temperature gas-cooled reactor (HTGR) and other future reactor concepts. The reactor experiments indicate that radiation may play an important role in release of Ag; however so far the isolated effect of radiation on Ag diffusion has not been investigated in controlled laboratory experiments. In this study, we investigate the diffusion couples of Ag and polycrystalline 3C–SiC, as well as Ag and single crystalline 4H–SiC samples before and after irradiation with C2+more » ions. The diffusion couple samples were exposed to temperatures of 1500 °C, 1535 °C, and 1569 °C, and the ensuing diffusion profiles were analyzed by secondary ion mass spectrometry (SIMS). We found that diffusion coefficients calculated from these measurements indicate that Ag diffusion was greatly enhanced by carbon irradiation due to a combined effect of radiation damage on diffusion and the presence of grain boundaries in polycrystalline SiC samples.« less

  12. Simulations of Merging Helion Bunches on the AGS Injection Porch

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-08-29

    During the setup of helions for the FY2014 RHIC run it was discovered that the standard scheme for merging bunches on the AGS injection porch required an injection kicker pulse shorter than what was available. To overcome this difficulty, K. Zeno proposed and developed an interesting and unusual alternative which uses RF harmonic numbers 12, 4, 2 (rather than the standard 8, 4, 2) to merge 8 helion bunches into 2. In this note we carry out simulations that illustrate how the alternative scheme works and how it compares with the standard scheme. This is done in Sections 13 and 14. A scheme in which 6 bunches are merged into 1 is simulated in Section 15. This may be useful if more helions per merged bunch are needed in future runs. General formulae for the simulations are given in Sections 9 through 12. For completeness, Sections 1 through 8 give a derivation of the turn-by-turn equations of longitudinal motion at constant magnetic field. The derivation is based on the work of MacLachlan. The reader may wish to skip over these Sections and start with Section 9.

  13. Remaining Sites Verification Package for the 100-B-21:2 Subsite (100-B/C Discovery Pipeline DS-100BC-002), Waste Site Reclassification Form 2008-003

    SciTech Connect (OSTI)

    J. M. Capron

    2008-06-16

    The 100-B-21:2 waste site consists of the immediate area of the DS-100BC-02 pipeline. In accordance with this evaluation, the confirmatory and verification sampling results support a reclassification of this site to Interim Closed Out. The results of verification sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

  14. Subcellular metal imaging identifies dynamic sites of Cu accumulation in Chlamydomonas

    DOE PAGES-Beta [OSTI]

    Hong-Hermesdorf, Anne; Miethke, Marcus; Gallaher, Sean D.; Kropat, Janette; Dodani, Sheel C.; Chan, Jefferson; Barupala, Dulmini; Domaille, Dylan W.; Shirasaki, Dyna I.; Loo, Joseph A.; et al

    2014-10-26

    Here we identified a Cu-accumulating structure with a dynamic role in intracellular Cu homeostasis. During Zn limitation, Chlamydomonas reinhardtii hyperaccumulates Cu, a process dependent on the nutritional Cu sensor CRR1, but it is functionally Cu deficient. Visualization of intracellular Cu revealed major Cu accumulation sites coincident with electron-dense structures that stained positive for low pH and polyphosphate, suggesting that they are lysosome-related organelles. Nano-secondary ion MS showed colocalization of Ca and Cu, and X-ray absorption spectroscopy was consistent with Cu+ accumulation in an ordered structure. Zn resupply restored Cu homeostasis concomitant with reduced abundance of these structures. Cu isotope labelingmore » demonstrated that sequestered Cu+ became bioavailable for the synthesis of plastocyanin, and transcriptome profiling indicated that mobilized Cu became visible to CRR1. Cu trafficking to intracellular accumulation sites may be a strategy for preventing protein mismetallation during Zn deficiency and enabling efficient cuproprotein metallation or remetallation upon Zn resupply.« less

  15. Subcellular metal imaging identifies dynamic sites of Cu accumulation in Chlamydomonas

    SciTech Connect (OSTI)

    Hong-Hermesdorf, Anne; Miethke, Marcus; Gallaher, Sean D.; Kropat, Janette; Dodani, Sheel C.; Chan, Jefferson; Barupala, Dulmini; Domaille, Dylan W.; Shirasaki, Dyna I.; Loo, Joseph A.; Weber, Peter K.; Pett-Ridge, Jennifer; Stemmler, Timothy L.; Chang, Christopher J.; Merchant, Sabeeha S.

    2014-10-26

    Here we identified a Cu-accumulating structure with a dynamic role in intracellular Cu homeostasis. During Zn limitation, Chlamydomonas reinhardtii hyperaccumulates Cu, a process dependent on the nutritional Cu sensor CRR1, but it is functionally Cu deficient. Visualization of intracellular Cu revealed major Cu accumulation sites coincident with electron-dense structures that stained positive for low pH and polyphosphate, suggesting that they are lysosome-related organelles. Nano-secondary ion MS showed colocalization of Ca and Cu, and X-ray absorption spectroscopy was consistent with Cu+ accumulation in an ordered structure. Zn resupply restored Cu homeostasis concomitant with reduced abundance of these structures. Cu isotope labeling demonstrated that sequestered Cu+ became bioavailable for the synthesis of plastocyanin, and transcriptome profiling indicated that mobilized Cu became visible to CRR1. Cu trafficking to intracellular accumulation sites may be a strategy for preventing protein mismetallation during Zn deficiency and enabling efficient cuproprotein metallation or remetallation upon Zn resupply.

  16. Processing of R-Ba-Cu-O superconductors

    SciTech Connect (OSTI)

    Wu, H.

    1998-02-23

    Precipitation processes were developed to introduce second phases as flux pinning centers in Gd-Ba-Cu-O and Nd-Ba-Cu-O superconductors. In Gd-Ba-Cu-O, precipitation is caused by the decrease of the upper solubility limit of Gd{sub 1+x}Ba{sub 2{minus}x}Cu{sub 3}O{sub 7} solid solution (Gd123ss) in low oxygen partial pressure. Processing of supersaturated Gd{sub 1.2}Ba{sub 1.8}Cu{sub 3}O{sub 7} in low oxygen partial pressure can produce dispersed second phases. Gd211 is formed as a separate phase while extensive Gd124 type stacking fault is formed instead of a separate CuO phase. As a result of the precipitation reaction, the transition temperature and critical current density are increased. In Nd-Ba-Cu-O, precipitation is caused by the decrease of the lower solubility limit of Nd{sub 1+x}Ba{sub 2{minus}x}Cu{sub 3}O{sub 7} solid solution (Nd123ss) in oxygen. DTA results reveal the relative stability of Nd123ss in different oxygen partial pressures. In 1 bar oxygen partial pressure, Nd123ss with x = 0.1 is the most stable phase. In lower oxygen partial pressures, the most stable composition shifts towards the stoichiometric composition. The relative stability changes faster with decreasing oxygen partial pressure. Therefore, processing in oxygen and air tends to produce broad superconducting transitions but sharp transitions can be achieved in 0.01 bar and 0.001 bar oxygen partial pressures. While the lower solubility limits in 0.01 bar and 0.001 bar oxygen partial pressures remain at x = 0.00, the solubility limits in oxygen and air show a narrowing with decreasing temperature. Because of the narrowing of the solubility range in oxygen, oxygen annealing of Nd123 initially processed in low oxygen partial pressures will result in precipitation of second phases. The equilibrium second phase is BaCuO{sub 2} for temperature above 608 C, and at lower temperatures the equilibrium second phases are Ba{sub 2}CuO{sub 3.3} and Ba{sub 2}Cu{sub 3}O{sub 5+y}. However, annealing at

  17. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible

  18. Thermoelectric properties of chalcopyrite type CuGaTe{sub 2} and chalcostibite CuSbS{sub 2}

    SciTech Connect (OSTI)

    Kumar Gudelli, Vijay; Kanchana, V.; Vaitheeswaran, G.; Svane, A.; Christensen, N. E.

    2013-12-14

    Electronic and transport properties of CuGaTe{sub 2}, a hole-doped ternary copper based chalcopyrite type semiconductor, are studied using calculations within the Density Functional Theory and solving the Boltzmann transport equation within the constant relaxation time approximation. The electronic band structures are calculated by means of the full-potential linear augmented plane wave method, using the Tran-Blaha modified Becke-Johnson potential. The calculated band gap of 1.23 eV is in agreement with the experimental value of 1.2 eV. The carrier concentration- and temperature dependent thermoelectric properties of CuGaTe{sub 2} are derived, and a figure of merit of zT = 1.69 is obtained at 950 K for a hole concentration of 3.7·10{sup 19} cm{sup −3}, in agreement with a recent experimental finding of zT = 1.4, confirming that CuGaTe{sub 2} is a promising material for high temperature thermoelectric applications. The good thermoelectric performance of p-type CuGaTe{sub 2} is associated with anisotropic transport from a combination of heavy and light bands. Also for CuSbS{sub 2} (chalcostibite), a better performance is obtained for p-type than for n-type doping. The variation of the thermopower as a function of temperature and concentration suggests that CuSbS{sub 2} will be a good thermoelectric material at low temperatures, similarly to the isostructural CuBiS{sub 2} compound.

  19. THE AGS-BASED SUPER NEUTRINO BEAM FACILITY CONCEPTUAL DESIGN REPORT

    SciTech Connect (OSTI)

    WENG,W.T.; DIWAN,M.; RAPARIA,D.

    2004-10-08

    After more than 40 years of operation, the AGS is still at the heart of the Brookhaven hadron accelerator complex. This system of accelerators presently comprises a 200 MeV linac for the pre-acceleration of high intensity and polarized protons, two Tandem Van der Graaffs for the pre-acceleration of heavy ion beams, a versatile Booster that allows for efficient injection of all three types of beams into the AGS and, most recently, the two RHIC collider rings that produce high luminosity heavy ion and polarized proton collisions. For several years now, the AGS has held the world intensity record with more than 7 x 10{sup 13} protons accelerated in a single pulse. The requirements for the proton beam for the super neutrino beam are summarized and a schematic of the upgraded AGS is shown. Since the present number of protons per fill is already close to the required number, the upgrade is based on increasing the repetition rate and reducing beam losses (to avoid excessive shielding requirements and to maintain activation of the machine components at workable level). It is also important to preserve all the present capabilities of the AGS, in particular its role as injector to RHIC. The AGS Booster was built not only to allow the injection of any species of heavy ion into the AGS but to allow a fourfold increase of the AGS intensity. It is one-quarter the circumference of the AGS with the same aperture. However, the accumulation of four Booster loads in the AGS takes about 0.6 s, and is therefore not well suited for high average beam power operation. To minimize the injection time to about 1 ms, a 1.2 GeV linac will be used instead. This linac consists of the existing warm linac of 200 MeV and a new superconducting linac of 1.0 GeV. The multi-turn H{sup -} injection from a source of 30 mA and 720 {micro}s pulse width is sufficient to accumulate 9 x 10{sup 13} particle per pulse in the AGS[10]. The minimum ramp time of the AGS to full energy is presently 0.5 s; this must

  20. Ab initio molecular dynamics simulations of short-range order in Zr50Cu45Al5 and Cu50Zr45Al5 metallic glasses

    DOE PAGES-Beta [OSTI]

    Huang, Yuxiang; Huang, Li; Wang, C. Z.; Kramer, M. J.; Ho, K. M.

    2016-02-01

    Comparative analysis between Zr-rich Zr50Cu45Al5 and Cu-rich Cu50Zr45Al5 metallic glasses (MGs) is extensively performed to locate the key structural motifs accounting for their difference of glass forming ability. Here we adopt ab initio molecular dynamics simulations to investigate the local atomic structures of Zr50Cu45Al5 and Cu50Zr45Al5 MGs. A high content of icosahedral-related (full and distorted) orders was found in both samples, while in the Zr-rich MG full icosahedrons < 0,0,12,0 > is dominant, and in the Cu-rich one the distorted icosahedral orders, especially < 0,2,8,2 > and < 0,2,8,1 >, are prominent. And the < 0,2,8,2 > polyhedra in Cu50Zr45Al5more » MG mainly originate from Al-centered clusters, while the < 0,0,12,0 > in Zr50Cu45Al5 derives from both Cu-centered clusters and Al-centered clusters. These difference may be ascribed to the atomic size difference and chemical property between Cu and Zr atoms. Lastly, the relatively large size of Zr and large negative heat of mixing between Zr and Al atoms, enhancing the packing density and stability of metallic glass system, may be responsible for the higher glass forming ability of Zr50Cu45Al5.« less

  1. Ab initio molecular dynamics simulations of short-range order in Zr50Cu45Al5 and Cu50Zr45Al5 metallic glasses

    DOE PAGES-Beta [OSTI]

    Huang, Yuxiang; Huang, Li; Wang, C. Z.; Kramer, M. J.; Ho, K. M.

    2016-02-01

    In this study, comparative analysis between Zr-rich Zr50Cu45Al5 and Cu-rich Cu50Zr45Al5 metallic glasses (MGs) is extensively performed to locate the key structural motifs accounting for their difference of glass forming ability. Here we adopt ab initio molecular dynamics simulations to investigate the local atomic structures of Zr50Cu45Al5 and Cu50Zr45Al5 MGs. A high content of icosahedral-related (full and distorted) orders was found in both samples, while in the Zr-rich MG full icosahedrons <0,0,12,0> is dominant, and in the Cu-rich one the distorted icosahedral orders, especially <0,2,8,2> and <0,2,8,1>, are prominent. And the <0,2,8,2> polyhedra in Cu50Zr45Al5 MG mainly originate from Al-centeredmore » clusters, while the <0,0,12,0> in Zr50Cu45Al5 derives from both Cu-centered clusters and Al-centered clusters. These difference may be ascribed to the atomic size difference and chemical property between Cu and Zr atoms. The relatively large size of Zr and large negative heat of mixing between Zr and Al atoms, enhancing the packing density and stability of metallic glass system, may be responsible for the higher glass forming ability of Zr50Cu45Al5.« less

  2. Thermodynamic understanding of Sn whisker growth on the Cu surface in Cu(top)-Sn(bottom) bilayer system upon room temperature aging

    SciTech Connect (OSTI)

    Huang, Lin; Jian, Wei; Lin, Bing; Wang, Jiangyong; Wen, Yuren; Gu, Lin

    2015-06-07

    Sn whiskers are observed by scanning electron microscope on the Cu surface in Cu(top)-Sn(bottom) bilayer system upon room temperature aging. Only Cu{sub 6}Sn{sub 5} phase appears in the X-ray diffraction patterns and no Sn element is detected in the Cu sublayer by scanning transmission electron microscopy. Based on the interfacial thermodynamics, the intermetallic Cu{sub 6}Sn{sub 5} compound phase may form directly at the Sn grain boundary. Driven by the stress gradient during the formation of Cu{sub 6}Sn{sub 5} compound at Sn grain boundaries, Sn atoms segregate onto the Cu surface and accumulate to form Sn whisker.

  3. Progress in Solving the Elusive Ag Transport Mechanism in TRISO Coated Particles: What is new?

    SciTech Connect (OSTI)

    Isabella Van Rooyen

    2014-10-01

    The TRISO particle for HTRs has been developed to an advanced state where the coating withstands internal gas pressures and retains fission products during irradiation and under postulated accidents. However, one exception is Ag that has been found to be released from high quality TRISO coated particles when irradiated and can also during high temperature accident heating tests. Although out- of- pile laboratory tests have never hither to been able to demonstrate a diffusion process of Ag in SiC, effective diffusion coefficients have been derived to successfully reproduce measured Ag-110m releases from irradiated HTR fuel elements, compacts and TRISO particles It was found that silver transport through SiC does not proceed via bulk volume diffusion. Presently grain boundary diffusion that may be irradiation enhanced either by neutron bombardment or by the presence of fission products such as Pd, are being investigated. Recent studies of irradiated AGR-1 TRISO fuel using scanning transmission electron microscopy (STEM), transmission kukuchi diffraction (TKD) patterns and high resolution transmission electron microscopy (HRTEM) have been used to further the understanding of Ag transport through TRISO particles. No silver was observed in SiC grains, but Ag was identified at triple-points and grain boundaries of the SiC layer in the TRISO particle. Cadmium was also found in some of the very same triple junctions, but this could be related to silver behavior as Ag-110m decays to Cd-110. Palladium was identified as the main constituent of micron-sized precipitates present at the SiC grain boundaries and in most SiC grain boundaries and the potential role of Pd in the transport of Ag will be discussed.

  4. Extracting Cu Diffusion Parameters in Polycrystalline CdTe

    SciTech Connect (OSTI)

    Akis, Richard; Brinkman, Daniel; Sankin, Igor; Fang, Tian; Guo, Da; Dragica, Vasileska; Ringhofer, Christian

    2014-06-13

    It is well known that Cu plays an important role in CdTe solar cell performance as a dopant. In this work, a finite-difference method is developed and used to simulate Cu diffusion in CdTe solar cells. In the simulations, which are done on a two-dimensional (2D) domain, the CdTe is assumed to be polycrystal-line, with the individual grains separated by grain boundaries. When used to fit experimental Cu concentration data, bulk and grain boundary diffusion coefficients and activation energies for CdTe can be extracted. In the past, diffusion coefficients have been typically obtained by fitting data to simple functional forms of limited validity. By doing full simulations, the simplifying assumptions used in those analytical models are avoided and diffusion parameters can thus be determined more accurately.

  5. A Window on Surface Explosions: Tartaric Acid on Cu(110)

    SciTech Connect (OSTI)

    Mhatre, B S; Pushkarev, V; Holsclaw, B; Lawton, T J; Sykes, E C. H.; Gellman, A J

    2013-04-18

    Autocatalytic reaction mechanisms are observed in a range of important chemical processes including catalysis, radical-mediated explosions, and biosynthesis. Because of their complexity, the microscopic details of autocatalytic reaction mechanisms have been difficult to study on surfaces and heterogeneous catalysts. Autocatalytic decomposition reactions of S,S- and R,R-tartaric acid (TA) adsorbed on Cu(110) offer molecular-level insight into aspects of these processes, which until now, were largely a matter of speculation. The decomposition of TA/Cu(110) is initiated by a slow, irreversible process that forms vacancies in the adsorbed TA layer, followed by a vacancy-mediated, explosive decomposition process that yields CO{sub 2} and small hydrocarbon products. Initiation of the explosive decomposition of TA/Cu(110) has been studied by measurement of the reaction kinetics, time-resolved low energy electron diffraction (LEED), and time-resolved scanning tunneling microscopy (STM). Initiation results in a decrease in the local coverage of TA and a concomitant increase in the areal vacancy concentration. Observations of explosive TA decomposition on the Cu(651)S surface suggest that initiation does not occur at structural defects in the surface, as has been suggested in the past. Once the vacancy concentration reaches a critical value, the explosive, autocatalytic decomposition step dominates the TA decomposition rate. The onset of the explosive decomposition of TA on Cu(110) is accompanied by the extraction of Cu atoms from the surface to form a (±6,7; {-+}2,1) overlayer that is readily observable using LEED and STM. The explosive decomposition step is second-order in vacancy concentration and accelerates with increasing extent of reaction.

  6. Characterization of Na+- beta-Zeolite Supported Pd and Pd Ag Bimetallic Catalysts using EXAFS, TEM and Flow Reactor

    SciTech Connect (OSTI)

    Huang,W.; Lobo, R.; Chen, J.

    2008-01-01

    Flow reactor studies of the selective hydrogenation of acetylene in the presence of ethylene have been performed on Na+ exchanged {beta}-zeolite supported Pd, Ag and PdAg catalysts, as an extension of our previous batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. Results from flow reactor studies show that the PdAg/Na+-{beta}-zeolite bimetallic catalyst has lower activity than Pd/Na+-{beta}-zeolite monometallic catalyst, while Ag/Na+-{beta}-zeolite does not show any activity for acetylene hydrogenation. However, the selectivity for the PdAg bimetallic catalyst is much higher than that for either the Pd catalyst or Ag catalyst. The selectivity to byproduct (ethane) is greatly inhibited on the PdAg bimetallic catalyst as well. The results from the current flow reactor studies confirmed the pervious results from batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. In addition, we used transmission electron microscope (TEM), extended X-ray absorption fine structure (EXAFS), and FTIR of CO adsorption to confirm the formation of Pd-Ag bimetallic alloy in the PdAg/Na+-{beta}-zeolite catalyst.

  7. Itinerant magnetism in metallic CuFe2Ge2

    DOE PAGES-Beta [OSTI]

    Shanavas, K. V.; Singh, David J.; He, Ruihua

    2015-03-25

    Theoretical calculations are performed to understand the electronic structure and magnetic properties of CuFe2Ge2. The band structure reveals large electron density N(EF) at the Fermi level suggesting a strong itinerant character of magnetism. The Fermi surface is dominated by two dimensional sheet like structures, with potentially strong nesting between them. The magnetic ground state appears to be ferromagnetic along a and antiferromagnetic in other directions. The results show that CuFe2Ge2 is an antiferromagnetic metal, with similarities to the Fe-based superconductors; such as magnetism with substantial itinerant character and coupling between magnetic order and electrons at the Fermi energy.

  8. How to stabilize highly active Cu+ cations in a mixed-oxide catalyst

    SciTech Connect (OSTI)

    Mudiyanselage, Kumudu; Luo, Si; Kim, Hyun You; Yang, Xiaofang; Baber, Ashleigh E.; Hoffmann, Friedrich M.; Senanayake, Sananayake; Rodriguez, Jose A.; Chen, Jingguang G.; Liu, Ping; Stacchiola, Dario J.

    2015-09-12

    Mixed-metal oxides exhibit novel properties that are not present in their isolated constituent metal oxides and play a significant role in heterogeneous catalysis. In this study, a titanium-copper mixed-oxide (TiCuOx) film has been synthesized on Cu(111) and characterized by complementary experimental and theoretical methods. At sub-monolayer coverages of titanium, a Cu2O-like phase coexists with TiCuOx and TiOx domains. When the mixed-oxide surface is exposed at elevated temperatures (600–650 K) to oxygen, the formation of a well-ordered TiCuOx film occurs. Stepwise oxidation of TiCuOx shows that the formation of the mixed-oxide is faster than that of pure Cu2O. As the Ti coverage increases, Ti-rich islands (TiOx) form. The adsorption of CO has been used to probe the exposed surface sites on the TiOxCuOx system, indicating the existence of a new Cu+ adsorption site that is not present on Cu2O/Cu(111). Adsorption of CO on Cu+ sites of TiCuOx is thermally more stable than on Cu(111), Cu2O/Cu(111) or TiO2(110). The Cu+ sites in TiCuOx domains are stable under both reducing and oxidizing conditions whereas the Cu2O domains present on sub-monolayer loads of Ti can be reduced or oxidized under mild conditions. Furthermore, the results presented here demonstrate novel properties of TiCuOx films, which are not present on Cu(111), Cu2O/Cu(111), or TiO2(110), and highlight the importance of the preparation and characterization of well-defined mixed-metal oxides in order to understand fundamental processes that could guide the design of new materials.

  9. Radiation from Ag high energy density Z-pinch plasmas and applications to lasing

    SciTech Connect (OSTI)

    Weller, M. E. Safronova, A. S.; Kantsyrev, V. L.; Esaulov, A. A.; Shrestha, I.; Stafford, A.; Keim, S. F.; Shlyaptseva, V. V.; Osborne, G. C.; Petkov, E. E.; Apruzese, J. P.; Giuliani, J. L.; Chuvatin, A. S.

    2014-03-15

    Silver (Ag) wire arrays were recently introduced as efficient x-ray radiators and have been shown to create L-shell plasmas that have the highest electron temperature (>1.8?keV) observed on the Zebra generator so far and upwards of 30?kJ of energy output. In this paper, results of single planar wire arrays and double planar wire arrays of Ag and mixed Ag and Al that were tested on the UNR Zebra generator are presented and compared. To further understand how L-shell Ag plasma evolves in time, a time-gated x-ray spectrometer was designed and fielded, which has a spectral range of approximately 3.55.0?. With this, L-shell Ag as well as cold L{sub ?} and L{sub ?} Ag lines was captured and analyzed along with photoconducting diode (PCD) signals (>0.8?keV). Along with PCD signals, other signals, such as filtered XRD (>0.2?keV) and Si-diodes (SiD) (>9?keV), are analyzed covering a broad range of energies from a few eV to greater than 53?keV. The observation and analysis of cold L{sub ?} and L{sub ?} lines show possible correlations with electron beams and SiD signals. Recently, an interesting issue regarding these Ag plasmas is whether lasing occurs in the Ne-like soft x-ray range, and if so, at what gains? To help answer this question, a non-local thermodynamic equilibrium (LTE) kinetic model was utilized to calculate theoretical lasing gains. It is shown that the Ag L-shell plasma conditions produced on the Zebra generator at 1.7 maximum current may be adequate to produce gains as high as 6?cm{sup ?1} for various 3p???3s transitions. Other potential lasing transitions, including higher Rydberg states, are also included in detail. The overall importance of Ag wire arrays and plasmas is discussed.

  10. Distinct oxygen hole doping in different layers of Sr₂CuO4-δ/La₂CuO₄ superlattices

    DOE PAGES-Beta [OSTI]

    Smadici, S.; Lee, J. C. T.; Rusydi, A.; Logvenov, G.; Bozovic, I.; Abbamonte, P.

    2012-03-28

    X-ray absorption in Sr₂CuO4-δ/La₂CuO₄ (SCO/LCO) superlattices shows a variable occupation with doping of a hole state different from holes doped for x≲xoptimal in bulk La2-xSrxCuO₄ and suggests that this hole state is on apical oxygen atoms and polarized in the a-b plane. Considering the surface reflectivity gives a good qualitative description of the line shapes of resonant soft x-ray scattering. The interference between superlattice and surface reflections was used to distinguish between scatterers in the SCO and the LCO layers, with the two hole states maximized in different layers of the superlattice.

  11. Determination of Desorbed Species During Heating of AgI-Mordenite Provided by ORNL

    SciTech Connect (OSTI)

    Croes, Kenneth James; Garino, Terry J.; Mowry, Curtis D.; Nenoff, Tina M.

    2015-12-15

    This study is focused on describing the desorbed off gases due to heating of the AgIMordenite (MOR) produced at ORNL for iodine (I2) gas capture from nuclear fuel aqueous reprocessing. In particular, the interest is for the incorporation of the AgI-MOR into a waste form, which might be the Sandia developed, low temperature sintering, Bi-Si oxide based, Glass Composite Material (GCM). The GCM has been developed as a waste form for the incorporation any oxide based getter material. In the case where iodine may be released during the sintering process of the GCM, additional Ag flake is added as further insurance in total iodine capture and retention. This has been the case for the incorporated ORNL developed AgIMOR. Thermal analysis studies were carried out to determine off gasing processes of ORNL AgIMOR. Independent of sample size, ~7wt% of total water is desorbed by 225°C. This includes both bulk surface and occluded water, and are monitored as H2O and OH. Of that total, ~5.5wt% is surface water which is removed by 125°C, and 1.5wt% is occluded (in zeolite pore) water. Less than ~1 wt% total water continues to desorb, but is completely removed by 500°C. Above 300°C, the detectable remaining desorbing species observed are iodine containing compounds, including I and I2.

  12. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and...

    Office of Scientific and Technical Information (OSTI)

    Controlling superconductivity in La2-xSrxCuO4+ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in La2-xSrxCuO4+ by ozone ...

  13. Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized...

    Office of Scientific and Technical Information (OSTI)

    Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter deposition Title: Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter ...

  14. High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase Title: High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase Authors: Wang, Lin-Wang Publication Date: 2012-02-24 OSTI Identifier: ...

  15. Deformation behavior of Nb nanowires in TiNiCu shape memory alloy...

    Office of Scientific and Technical Information (OSTI)

    in TiNiCu shape memory alloy matrix This content will become publicly available on August 18, 2016 Title: Deformation behavior of Nb nanowires in TiNiCu shape memory alloy matrix ...

  16. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system...

    Office of Scientific and Technical Information (OSTI)

    Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible ... Country of Publication: United States Language: English Word Cloud More Like This Free ...

  17. Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x Citation Details In-Document Search Title: Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x You are ...

  18. Engineered CuInSexS2-x Quantum Dots for Sensitized Solar Cells...

    Office of Scientific and Technical Information (OSTI)

    Engineered CuInSexS2-x Quantum Dots for Sensitized Solar Cells Citation Details In-Document Search Title: Engineered CuInSexS2-x Quantum Dots for Sensitized Solar Cells Authors: ...

  19. High-power Laser Interaction With Low-density C-Cu Foams (Journal...

    Office of Scientific and Technical Information (OSTI)

    High-power Laser Interaction With Low-density C-Cu Foams Citation Details In-Document Search Title: High-power Laser Interaction With Low-density C-Cu Foams You are accessing a ...

  20. Classification of Lattice Defects in the Kesterite Cu2ZnSnS4...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Classification of Lattice Defects in the Kesterite Cu2ZnSnS4 and Cu2ZnSnSe4 Earth-Abundant Solar Cell Absorbers Citation Details In-Document Search Title: ...

  1. First-principles study of carbon impurities in CuInSe{sub 2} and CuGaSe{sub 2}, present in non-vacuum synthesis methods

    SciTech Connect (OSTI)

    Bekaert, J. Saniz, R.; Partoens, B.; Lamoen, D.

    2015-01-07

    A first-principles study of the structural and electronic properties of carbon impurities in CuInSe{sub 2} and CuGaSe{sub 2} is presented. Carbon is present in organic molecules in the precursor solutions used in non-vacuum growth methods for CuInSe{sub 2} and CuGaSe{sub 2} based photovoltaic cells. These growth methods make more efficient use of material, time, and energy than traditional vacuum methods. The formation energies of several carbon impurities are calculated using the hybrid HSE06 functional. C{sub Cu} acts as a shallow donor, C{sub In} and interstitial C yield deep donor levels in CuInSe{sub 2}, while in CuGaSe{sub 2} C{sub Ga} and interstitial C act as deep amphoteric defects. So, these defects reduce the majority carrier (hole) concentration in p-type CuInSe{sub 2} and CuGaSe{sub 2} by compensating the acceptor levels. The deep defects are likely to act as recombination centers for the photogenerated charge carriers and are thus detrimental for the performance of the photovoltaic cells. On the other hand, the formation energies of the carbon impurities are high, even under C-rich growth conditions. Thus, few C impurities will form in CuInSe{sub 2} and CuGaSe{sub 2} in thermodynamic equilibrium. However, the deposition of the precursor solution in non-vacuum growth methods presents conditions far from thermodynamic equilibrium. In this case, our calculations show that C impurities formed in non-equilibrium tend to segregate from CuInSe{sub 2} and CuGaSe{sub 2} by approaching thermodynamic equilibrium, e.g., via thorough annealing.

  2. High strength-high conductivity Cu--Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, John D.; Spitzig, William A.; Gibson, Edwin D.; Anderson, Iver E.

    1991-08-27

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an "in-situ" Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite.

  3. High strength-high conductivity Cu-Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, J.D.; Spitzig, W.A.; Gibson, E.D.; Anderson, I.E.

    1991-08-27

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an ''in-situ'' Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite. 5 figures.

  4. Local structure order in Pd??Cu?Si?? liquid

    DOE PAGES-Beta [OSTI]

    Yue, G. Q.; Iowa State Univ., Ames, IA; Zhang, Y.; Sun, Y.; Shen, B.; Dong, F.; Wang, Z. Y.; Zhang, R. J.; Zheng, Y. X.; Kramer, M. J.; et al

    2015-02-05

    The short-range order (SRO) in Pd??Cu?Si?? liquid was studied by high energy x-ray diffraction and ab initio molecular dynamics (MD) simulations. The calculated pair correlation functions at different temperatures agree well with the experimental results. The partial pair correlation functions from ab intio MD simulations indicate that Si atoms prefer to be uniformly distributed while Cu atoms tend to aggregate. By performing structure analysis using Honeycutt-Andersen index, Voronoi tessellation, and atomic cluster alignment method, we show that the icosahedron and face-centered cubic SRO increase upon cooling. The dominant SRO is the Pd-centered Pd?Si? motif, namely the structure of which motifmoreis similar to the structure of Pd-centered clusters in the Pd?Si? crystal. The study further confirms the existence of trigonal prism capped with three half-octahedra that is reported as a structural unit in Pd-based amorphous alloys. The majority of Cu-centered clusters are icosahedra, suggesting that the presence of Cu is benefit to promote the glass forming ability.less

  5. Hydrogen isotope trapping in Al-Cu binary alloys

    SciTech Connect (OSTI)

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high; for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.

  6. Hydrogen isotope trapping in Al-Cu binary alloys

    DOE PAGES-Beta [OSTI]

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high;more » for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.« less

  7. Observation of second spin reorientation transition within ultrathin region in Fe films on Ag(001) surface

    SciTech Connect (OSTI)

    Khim, T.-Y.; Shin, M.; Lee, H. E-mail: jhp@postech.ac.kr; Park, B.-G.; Park, J.-H. E-mail: jhp@postech.ac.kr

    2014-06-21

    We acquired direct measurements for in-plane and perpendicular-to-plane magnetic moments of Fe films using an x-ray magnetic circular dichroism technique with increase of the Fe thickness (up to 40 Å) on the Ag(001) surface. Epitaxial Fe/Ag(001) films were grown in situ with the thickness varying from 2 Å to 40 Å, and the magnetic anisotropy was carefully investigated as a function of the film thickness. We found re-entrance of the in-plane magnetic anisotropy of the Fe film in ultrathin region. The results manifest that the epitaxial Fe/Ag(001) film undergoes two distinct spin reorientation transitions from in-plane to out-of-plane at the film thickness t ≈ 9 Å and back to in-plane at t ≈ 18 Å as t increases.

  8. Formation mechanism and properties of CdS-Ag2S nanorod superlattices

    SciTech Connect (OSTI)

    Wang, Lin-Wang; Demchenko, Denis O.; Robinson, Richard D.; Sadtler, Bryce; Erdonmez, Can K.; Alivisatos, A. Paul; Wang, Lin-Wang

    2008-08-11

    The mechanism of formation of recently fabricated CdS-Ag{sub 2}S nanorod superlattices is considered and their elastic properties are predicted theoretically based on experimental structural data. We consider different possible mechanisms for the spontaneous ordering observed in these 1D nanostructures, such as diffusion-limited growth and ordering due to epitaxial strain. A simplified model suggests that diffusion-limited growth partially contributes to the observed ordering, but cannot account for the full extent of the ordering alone. The elastic properties of bulk Ag{sub 2}S are predicted using a first principles method and are fed into a classical valence force field (VFF) model of the nanostructure. The VFF results show significant repulsion between Ag{sub 2}S segments, strongly suggesting that the interplay between the chemical interface energy and strain due to the lattice mismatch between the two materials drives the spontaneous pattern formation.

  9. Effects of annealing on antiwear and antibacteria behaviors of TaN-Cu nanocomposite thin films

    SciTech Connect (OSTI)

    Hsieh, J. H.; Cheng, M. K.; Chang, Y. K.; Li, C.; Chang, C. L.; Liu, P. C.

    2008-07-15

    TaN-Cu nanocomposite films were deposited by reactive cosputtering on Si and tool steel substrates. The films were then annealed using rapid thermal annealing (RTA) at 400 deg. C for 2, 4, and 8 min, respectively, to induce the nucleation and growth of Cu particles in TaN matrix and on film surface. Field emission scanning electron microscopy was applied to characterize Cu nanoparticles emerged on the surface of TaN-Cu thin films. The effects of annealing on the antiwear and antibacterial properties of these films were studied. The results reveal that annealing by RTA can cause Cu nanoparticles to form on the TaN surface. Consequently, the tribological behaviors, as well as the antibacterial behavior may vary depending on particle size, particle distribution, and total exposed Cu amount. For the samples with large Cu particles, the reduction of averaged friction and wear rate is obvious. Apparently, it is due to the smeared Cu particles adhered onto the wear tracks. This Cu layer may act as a solid lubricant. From the antibacterial testing results, it is found that both Cu particle size and total exposed Cu amount are critical in making short-term antibacterial effect. Overall, all the annealed TaN-Cu samples can reach >99% antibacterial efficiency in 24 h, with respect to uncoated Si substrate.

  10. Shock response of He bubbles in single crystal Cu

    SciTech Connect (OSTI)

    Li, B.; Wang, L.; E, J. C.; Luo, S. N.; Ma, H. H.

    2014-12-07

    With large-scale molecular dynamics simulations, we investigate shock response of He nanobubbles in single crystal Cu. For sufficient bubble size or internal pressure, a prismatic dislocation loop may form around a bubble in unshocked Cu. The internal He pressure helps to stabilize the bubble against plastic deformation. However, the prismatic dislocation loops may partially heal but facilitate nucleation of new shear and prismatic dislocation loops. For strong shocks, the internal pressure also impedes internal jetting, while a bubble assists local melting; a high speed jet breaks a He bubble into pieces dispersed among Cu. Near-surface He bubbles may burst and form high velocity ejecta containing atoms and small fragments, while the ejecta velocities do not follow the three-dimensional Maxwell-Boltzmann distributions expected for thermal equilibrium. The biggest fragment size deceases with increasing shock strength. With a decrease in ligament thickness or an increase in He bubble size, the critical shock strength required for bubble bursting decreases, while the velocity range, space extension and average velocity component along the shock direction, increase. Small bubbles are more efficient in mass ejecting. Compared to voids and perfect single crystal Cu, He bubbles have pronounced effects on shock response including bubble/void collapse, Hugoniot elastic limit (HEL), deformation mechanisms, and surface jetting. HEL is the highest for perfect single crystal Cu with the same orientations, followed by He bubbles without pre-existing prismatic dislocation loops, and then voids. Complete void collapse and shear dislocations occur for embedded voids, as opposed to partial collapse, and shear and possibly prismatic dislocations for He bubbles. He bubbles lower the threshhold shock strength for ejecta formation, and increase ejecta velocity and ejected mass.

  11. An in-situ phosphorus source for the synthesis of Cu3P and the subsequent conversion to Cu3PS4 nanoparticle clusters

    DOE PAGES-Beta [OSTI]

    Sheets, Erik J.; Stach, Eric A.; Yang, Wei -Chang; Balow, Robert B.; Wang, Yunjie; Walker, Bryce C.; Agrawal, Rakesh

    2015-09-20

    The search for alternative earth abundant semiconducting nanocrystals for sustainable energy applications has brought forth the need for nanoscale syntheses beyond bulk synthesis routes. Of particular interest are metal phosphides and derivative I-V-VI chalcogenides including copper phosphide (Cu3P) and copper thiophosphate (Cu3PS4). Herein, we report a one-pot, solution-based synthesis of Cu3P nanocrystals utilizing an in-situ phosphorus source: phosphorus pentasulfide (P2S5) in trioctylphosphine (TOP). By injecting this phosphorus source into a copper solution in oleylamine (OLA), uniform and size controlled Cu3P nanocrystals with a phosphorous-rich surface are synthesized. The subsequent reaction of the Cu3P nanocrystals with decomposing thiourea forms nanoscale Cu3PS4more » particles having p-type conductivity and an effective optical band gap of 2.36 eV.« less

  12. Synthesis of highly efficient antibacterial agent Ag doped ZnO nanorods: Structural, Raman and optical properties

    SciTech Connect (OSTI)

    Jan, Tariq; Iqbal, Javed; Ismail, Muhammad; Mahmood, Arshad

    2014-04-21

    Here, synthesis, structural, morphological, Raman, optical properties and antibacterial activity of undoped and Ag doped ZnO nanorods by chemical co-precipitation technique have been reported. Structural analysis has revealed that Ag doping cannot deteriorate the structure of ZnO and wurtzite phase is maintained. Lattice constants are found to be decreased with the Ag doping. Fourier transform infrared and Raman spectroscopy also confirm the X-ray diffraction results. Scanning electron microscopy results have demonstrated the formation of ZnO nanorods with average diameter and length of 96 nm and 700 nm, respectively. Raman spectroscopy results suggest that the Ag doping enhances the number of defects in ZnO crystal. It has been found from optical study that Ag doping results in positional shift of band edge absorption peak. This is attributed to the successful incorporation of Ag dopant into ZnO host matrix. The antibacterial activity of prepared nanorods has been determined by two different methods and compared to that of undoped ZnO nanorods. Ag doped ZnO nanorods exhibit excellent antibacterial activity as compared to that of undoped ZnO nanorods. This excellent antibacterial activity may be attributed to the presence of oxygen vacancies and Zn{sup 2+} interstitial defects. Our preliminary findings suggest that Ag doped ZnO nanorods can be used externally to control the spreading of infections related with tested bacterial strains.

  13. Thermoelectric properties of p-type PbTe/Ag{sub 2}Te bulk composites by extrinsic phase mixing

    SciTech Connect (OSTI)

    Lee, Min Ho; Rhyee, Jong-Soo

    2015-12-15

    We investigated the thermoelectric properties of PbTe/Ag{sub 2}Te bulk composites, synthesized by hand milling, mixing, and hot press sintering. From x-ray diffraction and energy dispersive x-ray spectroscopy measurements, we observed Ag{sub 2}Te phase separation in the PbTe matrix without Ag atom diffusion. In comparison with previously reported pseudo-binary (PbTe){sub 1−x}(Ag{sub 2}Te){sub x} composites, synthesized by high temperature phase separation, the PbTe/Ag{sub 2}Te bulk composites fabricated with a low temperature phase mixing process give rise to p-type conduction of carriers with significantly decreased electrical conductivity. This indicates that Ag atom diffusion in the PbTe matrix changes the sign of the Seebeck coefficient to n-type and also increases the carrier concentration. Effective p-type doping with low temperature phase separation by mixing and hot press sintering can enhance the thermoelectric performance of PbTe/Ag{sub 2}Te bulk composites, which can be used as a p-type counterpart of n-type (PbTe){sub 1−x}(Ag{sub 2}Te){sub x} bulk composites.

  14. Element-specific study of epitaxial NiO/Ag/CoO/Fe films grown on vicinal Ag(001) using photoemission electron microscopy

    SciTech Connect (OSTI)

    Meng, Y.; Li, J.; Tan, A.; Jin, E.; Son, J.; Park, J. S.; Doran, A.; Young, A. T.; Scholl, A.; Arenholz, E.; Wu, J.; Hwang, C.; Zhao, H. W.; Qiu, Z. Q.

    2011-01-10

    NiO/Ag/CoO/Fe single crystalline films are grown epitaxially on a vicinal Ag(001) substrate using molecular beam epitaxy and investigated by photoemission electron microscopy. We find that after zero-field cooling, the in-plane Fe magnetization switches from parallel to perpendicular direction of the atomic steps of the vicinal surface at thinner CoO thickness but remains in its original direction parallel to the steps at thicker CoO thickness. CoO and NiO domain imaging result shows that both CoO/Fe and NiO/CoO spins are perpendicularly coupled, suggesting that the Fe magnetization switching may be associated with the rotatable-frozen spin transition of the CoO film.

  15. CO sub 2 induced inhibition of the localized corrosion of aluminum, Al-0. 5% Cu, and Al-2% Cu in dilute HF solution

    SciTech Connect (OSTI)

    Scully, J.R. . Dept. of Materials Science); Peebles, D.E. )

    1991-01-01

    This study presents work on corrosion of aluminum, Al-.5% Cu, and Al-2% Cu. Electrochemical tests were performed in dilute HF solutions both with and without CO{sub 2} sparging. It is suggested that CO{sub 2} or its reaction products interact with the passive film so that exposure of Cu in the oxide-solution interface is minimized. CO{sub 2} is investigated as a corrosion inhibitor. 4 refs. (JDL)

  16. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    SciTech Connect (OSTI)

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  17. Influence of Al/CuO reactive multilayer films additives on exploding foil initiator

    SciTech Connect (OSTI)

    Zhou Xiang; Shen Ruiqi; Ye Yinghua; Zhu Peng; Hu Yan; Wu Lizhi

    2011-11-01

    An investigation on the influence of Al/CuO reactive multilayer films (RMFs) additives on exploding foil initiator was performed in this paper. Cu film and Cu/Al/CuO RMFs were produced by using standard microsystem technology and RF magnetron sputtering technology, respectively. Scanning electron microscopy characterization revealed the distinct layer structure of the as-deposited Al/CuO RMFs. Differential scanning calorimetry was employed to ascertain the amount of heat released in the thermite reaction between Al films and CuO films, which was found to be 2024 J/g. Electrical explosion tests showed that 600 V was the most matching voltage for our set of apparatus. The explosion process of two types of films was observed by high speed camera and revealed that compared with Cu film, an extra distinct combustion phenomenon was detected with large numbers of product particles fiercely ejected to a distance of about six millimeters for Cu/Al/CuO RMFs. By using the atomic emission spectroscopy double line technique, the reaction temperature was determined to be about 6000-7000 K and 8000-9000 K for Cu film and Cu/Al/CuO RMFs, respectively. The piezoelectricity of polyvinylidene fluoride film was employed to measure the average velocity of the slapper accelerated by the explosion of the films. The average velocities of the slappers were calculated to be 381 m/s and 326 m/s for Cu film and Cu/Al/CuO RMFs, respectively, and some probable reasons were discussed with a few suggestions put forward for further work.

  18. NO Chemisorption on Cu/SSZ-13: a Comparative Study from Infrared Spectroscopy and DFT Calculations

    SciTech Connect (OSTI)

    Zhang, Renqin; McEwen, Jean-Sabin; Kollar, Marton; Gao, Feng; Wang, Yilin; Szanyi, Janos; Peden, Charles HF

    2014-11-07

    The locations and energies of Cu ions in a Cu/SSZ-13 zeolite catalyst were investigated by density functional theory (DFT) calculations. For 'naked' Cu2+ ions (i.e., Cu2+ ions with no ligands in their coordination spheres other than zeolite lattice oxygen atoms), the more energetically favorable sites are within a 6-membered ring. However, with the presence of various adsorbates, the energy difference between 6- and 8-membered ring locations greatly diminishes. Specifically, Cu2+ ions are substantially stabilized by -OH ligands (as [CuII(OH)]+), making the extra-framework sites in an 8-membered ring energetically more favorable than 6-membered ring sites. Under fully dehydrated high vacuum conditions with different Si/Al and Cu/Al ratios, three chemisorbed NO species coexist upon exposure of NO to Cu/SSZ-13: NO+, Cu2+-NO and Cu+-NO. The relative signal intensities for these bands vary greatly with Si/Al ratios. The vibrational frequency of chemisorbed NO was found to be very sensitive to the location of Cu2+ ions. On the one hand, with the aid from DFT calculations, the nature for these vibrations can be assigned in detail. On the other hand, the relative intensities for various Cu2+-NO species provide a good measure of the nature of Cu2+ ions as functions of Si/Al and Cu/Al ratios and the presence of humidity. These new findings cast doubt on the generally accepted proposal that only Cu2+ ions located in 6-membered rings are catalytically active for NH3-SCR.

  19. Thermochemical and kinetic aspects of the sulfurization of Cu-Sb and Cu-Bi thin films

    SciTech Connect (OSTI)

    Colombara, Diego; Peter, Laurence M.; Rogers, Keith D.; Hutchings, Kyle

    2012-02-15

    CuSbS{sub 2} and Cu{sub 3}BiS{sub 3} are being investigated as part of a search for new absorber materials for photovoltaic devices. Thin films of these chalcogenides were produced by conversion of stacked and co-electroplated metal precursor layers in the presence of elemental sulfur vapour. Ex-situ XRD and SEM/EDS analyses of the processed samples were employed to study the reaction sequence with the aim of achieving compact layer morphologies. A new 'Time-Temperature-Reaction' (TTR) diagram and modified Pilling-Bedworth coefficients have been introduced for the description and interpretation of the reaction kinetics. For equal processing times, the minimum temperature required for CuSbS{sub 2} to appear is substantially lower than for Cu{sub 3}BiS{sub 3}, suggesting that interdiffusion across the interfaces between the binary sulfides is a key step in the formation of the ternary compounds. The effects of the heating rate and sulfur partial pressure on the phase evolution as well as the potential losses of Sb and Bi during the processes have been investigated experimentally and the results related to the equilibrium pressure diagrams obtained via thermochemical computation. - Graphical Abstract: Example of 3D plot showing the equilibrium pressure surfaces of species potentially escaping from chalcogenide films as a function of temperature and sulfur partial pressure. Bi{sub (g)}, Bi{sub 2(g)}, and BiS{sub (g)} are the gaseous species in equilibrium with solid Bi{sub 2}S{sub 3(s)} considered in this specific example. The pressure threshold plane corresponds to the pressure limit above which the elemental losses from 1 {mu}m thick films exceeds 10% of the original content per cm{sup 2} area of film and dm{sup 3} capacity of sulfurization furnace under static atmosphere conditions. The sulfurization temperature/sulfur partial pressure boundaries required to minimise the elemental losses below a given value can be easily read from the 2D projection of the

  20. Thermoelectric transport of Se-rich Ag{sub 2}Se in normal phases and phase transitions

    SciTech Connect (OSTI)

    Mi, Wenlong; Lv, Yanhong; Qiu, Pengfei; Shi, Xun E-mail: cld@mail.sic.ac.cn; Chen, Lidong E-mail: cld@mail.sic.ac.cn; Zhang, Tiansong

    2014-03-31

    Small amount of Se atoms are used to tune the carrier concentrations (n{sub H}) and electrical transport in Ag{sub 2}Se. Significant enhancements in power factor and thermoelectric figure of merit (zT) are observed in the compositions of Ag{sub 2}Se{sub 1.06} and Ag{sub 2}Se{sub 1.08}. The excessive Se atoms do not change the intrinsically electron-conducting character in Ag{sub 2}Se. The detailed analysis reveals the experiment optimum carrier concentration in Ag{sub 2}Se is around 5 × 10{sup 18} cm{sup −3}. We also investigate the temperature of maximum zT and the thermoelectric transport during the first order phase transitions using the recently developed measurement system.

  1. Measurement of the Bs0 Lifetime in Fully and Partially Reconstructed Bs0 -> Ds- (phi pi-)X Decays in pp? Collisions at ?s = 1.96 TeV

    DOE PAGES-Beta [OSTI]

    Aaltonen, T.

    2011-12-29

    The authors present a measurement of the Bs0 lifetime in fully and partially reconstructed Bs0 = Ds0(??-)X decays in 1.3 fb-1 collected in pp? collisions at ?s = 1.96 Tev by the CDF II detector at the Fermilab Tevatron. They measure ?(Bs0) = 1.518 0.041 (stat.) 0.027 (syst.) ps. The ratio of this result and the world average B0 lifetime yields ?(Bs0)/?(B0) = 0.99 0.03, which is in agreement with recent theoretical predictions.

  2. Measurement of the Bs0 Lifetime in Fully and Partially Reconstructed Bs0 -> Ds- (phi pi-)X Decays in pp¯ Collisions at √s = 1.96 TeV

    DOE PAGES-Beta [OSTI]

    Aaltonen, T.

    2011-12-29

    The authors present a measurement of the Bs0 lifetime in fully and partially reconstructed Bs0 = Ds0(φπ-)X decays in 1.3 fb-1 collected in pp¯ collisions at √s = 1.96 Tev by the CDF II detector at the Fermilab Tevatron. They measure τ(Bs0) = 1.518 ± 0.041 (stat.) ± 0.027 (syst.) ps. The ratio of this result and the world average B0 lifetime yields τ(Bs0)/τ(B0) = 0.99 ± 0.03, which is in agreement with recent theoretical predictions.

  3. Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4- x )

    Office of Scientific and Technical Information (OSTI)

    Se x (Journal Article) | SciTech Connect Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4- x ) Se x Citation Details In-Document Search Title: Contrasting the Material Chemistry of Cu 2 ZnSnSe 4 and Cu 2 ZnSnS (4- x ) Se x Authors: Aguiar, Jeffery A. [1] ; Patel, Maulik [2] ; Aoki, Toshihiro [3] ; Wozny, Sarah [4] ; Al-Jassim, Mowafak [1] + Show Author Affiliations National Renewable Energy Laboratory, Golden CO 80401 USA Department of Materials Science and Engineering,

  4. Methods for producing Cu-67 radioisotope with use of a ceramic capsule for medical applications

    DOE Patents [OSTI]

    Ehst, David A.; Willit, James L.

    2016-04-12

    The present invention provides a method for producing Cu67 radioisotope suitable for use in medical applications. The method comprises irradiating a metallic zinc-68 (Zn68) target within a sealed ceramic capsule with a high energy gamma ray beam. After irradiation, the Cu67 is isolated from the Zn68 by any suitable method (e.g. chemical and or physical separation). In a preferred embodiment, the Cu67 is isolated by sublimation of the zinc in a ceramic sublimation tube to afford a copper residue containing Cu67. The Cu67 can be further purified by chemical means.

  5. Long-term leaching test of incinerator bottom ash: Evaluation of Cu partition

    SciTech Connect (OSTI)

    Lin, Cheng-Fang Wu, Chung-Hsin; Liu, Yen-Chiun

    2007-07-01

    Two types of leaching tests were performed on the bottom ash from municipal solid waste incinerators. A short-term batch test specified by the America Nuclear Society (ANS) and long-term column tests with acetic acid (pH 5.2) as leaching solution were used to evaluate copper leachability. The Cu leaching after the 5-d ANS test is about 1% of the original Cu content of 5300 mg/kg. Upon addition of a stabilizing agent, the Cu leaching quantity is reduced; the extent of reduction depends on the type of chemical used (phosphate, carbonate and sulfide). The 1.6% Na{sub 2}S addition showed negligible Cu leaching, and Na{sub 2}S was, therefore, used in subsequent column tests. The 30-d column test indicates a steady increase of Cu leaching amount with time and reaches about 1.5% of the original Cu content after 30 d. A 180-d column test further increased the Cu leaching to about 5.1% of the original Cu content, whereas no appreciable Cu leaching was found with the addition of 1.6% Na{sub 2}S. A sequential extraction was conducted on the raw ash, ash with the addition of Na{sub 2}S and the residue ash after 30 d of operation to characterize Cu affinity for different solid fractions. The data were used to evaluate the fate of Cu through these interactions.

  6. Effect of CNTs dispersion on the thermal and mechanical properties of Cu/CNTs nanocomposites

    SciTech Connect (OSTI)

    Muhsan, Ali Samer E-mail: faizahmad@petronas.com.my; Ahmad, Faiz E-mail: faizahmad@petronas.com.my; Yusoff, Puteri Sri Melor Megat Bt; Mohamed, Norani M.; Raza, M. Rafi

    2014-10-24

    Modified technique of metal injection molding (MIM) was used to fabricate multiwalled carbon nanotube (CNT) reinforced Cu nanocomposites. The effect of adding different amount of CNTs (0-10 vol.%) on the thermal and mechanical behaviour of the fabricated nanocomposites is presented. Scanning electron microscope analysis revealed homogenous dispersion of CNTs in Cu matrices at different CNTs contents. The experimentally measured thermal conductivities of Cu/CNTs nanocomposites showed extraordinary increase (76% higher than pure sintered Cu) with addition of 10 vol.% CNTs. As compared to the pure sintered Cu, increase in modulus of elasticity (Young's modulus) of Cu/CNTs nanocomposites sintered at 1050°C for 2.5 h was measured to be 48%. However, in case of 7.5 vol.% CNTs, Young's modulus was increased significantly about 51% compared to that of pure sintered Cu.

  7. Utility of reactively sputtered CuN{sub x} films in spintronics devices

    SciTech Connect (OSTI)

    Fang Yeyu; Persson, J.; Zha, C.; Willman, J.; Miller, Casey W.; Aakerman, Johan

    2012-04-01

    We have studied nitrified copper (CuN{sub x}) thin films grown by reactive sputtering in the context of spintronic devices. The Ar-to-N{sub 2} flow ratio enables tunability of the electrical resistivity and surface roughness of the CuN{sub x} films, with the former increasing to nearly 20 times that of Cu, and the latter reduced to the atomic scale. Incorporating this into a Ta/CuN{sub x}/Ta seed stack for spin valves improves the current-in-plane (CIP) magnetoresistance; maximum magnetoresistance results with CuN{sub x} seed layer and Cu interlayer. Finally, finite element modeling results are presented that suggest the use of CuN{sub x} in nanocontact spin torque oscillators can enhance current densities by limiting the current spread through the device. This may positively impact threshold currents, power requirements, and device reliability.

  8. Measurement of the D-s Decay Constant fDs and Observation of New Charm Resonances Decaying to D*π

    SciTech Connect (OSTI)

    Benitez, Jose

    2012-03-01

    The absolute branching fractions for the decays D-s → ℓ-$\\bar{v}$-(ℓ = e, μ, or τ) are measured using a data sample corresponding to an integrated luminosity of 521 fb-1 collected at center of mass energies near 10.58 GeV with the BABAR detector at the PEPII e+e- collider at SLAC. The number of Ds- mesons is determined by reconstructing the recoiling system DKXγ in events of the type e+e- → DKXD*s-, where D*s- → Ds- γ and X represents additional pions from fragmentation. The Ds- → ℓ-v events are detected by full or partial reconstruction of the recoiling system DKX{gamma}ℓ. The following results are obtained: β(Ds- → μ-v) = (6.02 ± 0.38 ± 0.34) x 10-3, {Beta}(Ds-→ τ-v) = (5.00 ± 0.35 ± 0.49) x 10-2, and B(Ds- → e-ν) < 2.8 x 10-4 at 90% C.L., where the first uncertainty is statistical and the second is systematic. The branching fraction measurements are combined to determine the Ds- decay constant fDs = (258.6 ± 6.4 ± 7.5) MeV. In addition, a study has been performed of the D+π}-, D0π}+, and D*+π- systems in inclusive e+e- → cc interactions in a search for excited D meson states. The dataset used consists of {approx}454 fb-1. The mass spectra for these systems show, for the first time, candidates for the radial excitations of the D0, D*0, and D*+, as well as the L = 2 excited states of the D0 and D-, where L is the orbital angular momentum of the quarks. Finally, a prototype of a

  9. Comparative Study of the Defect Point Physics and Luminescence of the Kesterites Cu2ZnSnS4 and Cu2ZnSnSe4 and Chalcopyrite Cu(In,Ga)Se2: Preprint

    SciTech Connect (OSTI)

    Romero, M. J.; Repins, I.; Teeter, G.; Contreras, M.; Al-Jassim, M.; Noufi, R.

    2012-08-01

    In this contribution, we present a comparative study of the luminescence of the kesterites Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) and their related chalcopyrite Cu(In,Ga)Se2 (CIGSe). Luminescence spectroscopy suggests that the electronic properties of Zn-rich, Cu-poor kesterites (both CZTS and CZTSe) and Cu-poor CIGSe are dictated by fluctuations of the electrostatic and chemical potentials. The large redshift in the luminescence of grain boundaries in CIGSe, associated with the formation of a neutral barrier is clearly observed in CZTSe, and, to some extent, in CZTS. Kesterites can therefore replicate the fundamental electronic properties of CIGSe.

  10. FY2014 Parameters for Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-07-30

    The nominal parameters for gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are worked out using various formulas to derive mass, kinetic parameters, RF parameters, ring parameters, etc.. The ''standard setup'', ''medium-energy'', and ''low-energy'' parameters are summarized in separate sections.

  11. H{sub 2}AgCl: A spectroscopic study of a dihydrogen complex

    SciTech Connect (OSTI)

    Grubbs, G. S.; Obenchain, Daniel A.; Pickett, Herbert M.; Novick, Stewart E.

    2014-09-21

    H{sub 2}AgCl has been observed on a Fourier transform microwave spectrometer equipped with laser ablation source and determined to be a dihydrogen complex. Transitions up to J = 32 have been measured and analyzed for four isotopologues of the complex containing ortho and para H{sub 2}. The ortho and para spin states have been included in one fit, a deviation from the typical H{sub 2} complex. Rotational constants B and C, centrifugal distortion constants ?{sub J} and ?{sub JK}, nuclear electric quadrupole coupling constants ?{sub aa}, ?{sub bb}, and ?{sub cc} for {sup 35}Cl and {sup 37}Cl have been fit for both spin states while nuclear spin-nuclear spin constants D{sub aa}, D{sub bb}, and D{sub cc}, and nuclear spin-rotation constant C{sub aa} have been reported for the ortho spin state. Quantum chemical calculations predict a strong bonding interaction and the strength of the complex has been related to reported ?{sub aa} and ?{sub J} values amongst a host of comparable species, including the AgCl monomer itself. Bond lengths have been determined for AgCl, AgH{sub 2} center-of-mass, and HH and are reported.

  12. FY2014 Parameters for Helions and Gold Ions in Booster, AGS, and RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2014-08-15

    The nominal parameters for helions (helion is the bound state of two protons and one neutron, the nucleus of a helium-3 atom) and gold ions in Booster, AGS, and RHIC are given for the FY2014 running period. The parameters are found using various formulas to derive mass, helion anomalous g-factor, kinetic parameters, RF parameters, ring parameters, etc..

  13. A Novel Thermal Electrochemical Synthesis Method for Production of Stable Colloids of "Naked" Metal (Ag) Nanocrystals

    SciTech Connect (OSTI)

    Hu, Michael Z.; Easterly, Clay E

    2009-01-01

    Solution synthesis of nanocrystal silver is reviewed. This paper reports a novel thermal electrochemical synthesis (TECS) for producing metal Ag nanocrystals as small as a few nanometers. The TECS method requires mild conditions (25-100oC), low voltage (1-50 V DC) on Ag electrodes, and simple water or aqueous solutions as reaction medium. Furthermore, a tubular dialysis membrane surround electrodes proves favorable to produce nanosized (<10 nm) Ag nanocrystals. Different from those nanocrystals reported in literature, our nanocrystals have several unique features: (1) small nanometer size, (2) nakedness , i.e., surfaces of metal nanocrystals are free of organic ligands or capping molecules and no need of dispersant in synthesis solutions, and (3) colloidally stable in water solutions. It was discovered that Ag nanoparticles with initially large size distribution can be homogenized into near-monodispersed system by a low power (< 15 mW) He-Ne laser exposure treatment. The combination of the TECS technique and the laser treatment could lead to a new technology that produces metal nanoparticles that are naked, stable, and uniform sized. In the presence of stabilizing agent (also as supporting electrolyte) such as polyvinyl alcohol (PVA), large yield of silver nanoparticles (<100nm) in the form of thick milky sols are produced.

  14. Thermoelectric properties of AgSbTe₂ from first-principles calculations

    SciTech Connect (OSTI)

    Rezaei, Nafiseh; Akbarzadeh, Hadi; Hashemifar, S. Javad

    2014-09-14

    The structural, electronic, and transport properties of AgSbTe₂ are studied by using full-relativistic first-principles electronic structure calculation and semiclassical description of transport parameters. The results indicate that, within various exchange-correlation functionals, the cubic Fd3⁻m and trigonal R3⁻m structures of AgSbTe₂ are more stable than two other considered structures. The computed Seebeck coefficients at different values of the band gap and carrier concentration are accurately compared with the available experimental data to speculate a band gap of about 0.1–0.35 eV for AgSbTe₂ compound, in agreement with our calculated electronic structure within the hybrid HSE (Heyd-Scuseria-Ernzerhof) functional. By calculating the semiclassical Seebeck coefficient, electrical conductivity, and electronic part of thermal conductivity, we present the theoretical upper limit of the thermoelectric figure of merit of AgSbTe₂ as a function of temperature and carrier concentration.

  15. Irradiation-induced Ag nanocluster nucleation in silicate glasses: Analogy with photography

    SciTech Connect (OSTI)

    Espiau de Lamaestre, R.; Bea, H.; Bernas, H.; Belloni, J.; Marignier, J. L.

    2007-11-15

    The synthesis of Ag nanoclusters in soda lime silicate glasses and silica was studied by optical absorption and electron spin resonance experiments under both low (gamma ray) and high (MeV ion) deposited energy density irradiation conditions. Both types of irradiation create electrons and holes whose density and thermal evolution--notably via their interaction with defects--are shown to determine the clustering and growth rates of Ag nanocrystals. We thus establish the influence of redox interactions of defects and silver (poly)ions. The mechanisms are similar to the latent image formation in photography: Irradiation-induced photoelectrons are trapped within the glass matrix, notably on dissolved noble metal ions and defects, which are thus neutralized (reverse oxidation reactions are also shown to exist). Annealing promotes metal atom diffusion, which, in turn, leads to cluster nuclei formation. The cluster density depends not only on the irradiation fluence but also--and primarily--on the density of deposited energy and the redox properties of the glass. Ion irradiation (i.e., large deposited energy density) is far more effective in cluster formation, despite its lower neutralization efficiency (from Ag{sup +} to Ag{sup 0}) as compared to gamma photon irradiation.

  16. PdAgAu alloy with high resistance to corrosion by H{sub 2}S

    SciTech Connect (OSTI)

    Braun, Fernando; Miller, James B.; Gellman, Andrew J.; Tarditi, Ana M.; Fleutot, Benoit; Petro, Kondratyuk, Cornaglia, Laura M

    2012-12-01

    PdAgAu alloy films were prepared on porous stainless steel supports by sequential electroless deposition. Two specific compositions, Pd{sub 83}Ag{sub 2}Au{sub 15} and Pd{sub 74}Ag{sub 14}Au{sub 12}, were studied for their sulfur tolerance. The alloys and a reference Pd foil were exposed to 1000 H{sub 2}S/H{sub 2} at 623 K for periods of 3 and 30 hours. The microstructure, morphology and bulk composition of both nonexposed and H{sub 2}S-exposed samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). XRD and SEM analysis revealed time-dependent growth of a bulk Pd{sub 4}S phase on the Pd foil during H{sub 2}S exposure. In contrast, the PdAgAu ternary alloys displayed the same FCC structure before and after H{sub 2}S exposure. In agreement with the XRD and SEM results, sulfur was not detected in the bulk of either ternary alloy samples by EDS, even after 30 hours of H{sub 2}S exposure. X-ray photoelectron spectroscopy (XPS) depth profiles were acquired for both PdAgAu alloys after 3 and 30 hours of exposure to characterize sulfur contamination near their surfaces. Very low S 2p and S 2s XPS signals were observed at the top-surfaces of the PdAgAu alloys, and those signals disappeared before the etch depth reached ~ 10 nm, even for samples exposed to H{sub 2}S for 30 hours. The depth profile analyses also revealed silver and gold segregation to the surface of the alloys; preferential location of Au on the alloys surface may be related to their resistance to bulk sulfide formation. In preliminary tests, a PdAgAu alloy membrane displayed higher initial H{sub 2} permeability than a similarly prepared pure Pd sample and, consistent with resistance to bulk sulfide formation, lower permeability loss in H{sub 2}S than pure Pd.

  17. Solidification behavior and structure of Al-Cu alloy welds

    SciTech Connect (OSTI)

    Brooks, J.A.; Li, M.; Yang, N.C.Y.

    1997-09-01

    The microsegregation behavior of electron beam (EB) and gas tungsten arc (GTA) welds of Al-Cu alloys covering a range from 0.19 to 7.74 wt% Cu were characterized for dendrite core concentrations and fraction eutectic solidification. Although a single weld speed of 12.7 mm/sec was used, some differences were observed in the segregation behavior of the two weld types. The microsegregation behavior was also modeled using a finite differences technique considering dendrite tip and eutectic undercooling and solid state diffusion. Fairly good agreement was observed between measured and calculated segregation behavior although differences between the two weld types could not be completely accounted for. The concept of dendrite tip undercooling was used to explain the formation of a single through thickness centerline grain in the higher alloy content GTA welds.

  18. Intermixing in Cu/Ni multilayers induced by cold rolling

    SciTech Connect (OSTI)

    Wang, Z.; Perepezko, J. H.; Larson, D.; Reinhard, D.

    2015-04-28

    Repeated cold rolling was performed on multilayers of Cu60/Ni40 and Cu40/Ni60 foil arrays to study the details of driven atomic scale interfacial mixing. With increasing deformation, there is a significant layer refinement down to the nm level that leads to the formation of a solid solution phase from the elemental end members. Intriguingly, the composition of the solid solution is revealed by an oscillation in the composition profile across the multilayers, which is different from the smoothly varying profile due to thermally activated diffusion. During the reaction, Cu mixed into Ni preferentially compared to Ni mixing into Cu, which is also in contrast to the thermal diffusion behavior. This is confirmed by observations from X-ray diffraction, electron energy loss spectrum and atom probe tomography. The diffusion coefficient induced by cold rolling is estimated as 1.7 × 10{sup −17} m{sup 2}/s, which cannot be attributed to any thermal effect. The effective temperature due to the deformation induced mixing is estimated as 1093 K and an intrinsic diffusivity d{sub b}, which quantifies the tendency towards equilibrium in the absence of thermal diffusion, is estimated as 6.38 × 10{sup −18} m{sup 2}/s. The fraction of the solid solution phase formed is illustrated by examining the layer thickness distribution and is described by using an error function representation. The evolution of mixing in the solid solution phase is described by a simplified sinusoid model, in which the amplitude decays with increased deformation level. The promoted diffusion coefficient could be related to the effective temperature concept, but the establishment of an oscillation in the composition profile is a characteristic behavior that develops due to deformation.

  19. Impedance analysis of MnCoCuO NTC ceramic

    SciTech Connect (OSTI)

    Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

    2005-07-12

    Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

  20. CuC1 thermochemical cycle for hydrogen production

    DOE Patents [OSTI]

    Fan, Qinbai; Liu, Renxuan

    2012-01-03

    An electrochemical cell for producing copper having a dense graphite anode electrode and a dense graphite cathode electrode disposed in a CuCl solution. An anion exchange membrane made of poly(ethylene vinyl alcohol) and polyethylenimine cross-linked with a cross-linking agent selected from the group consisting of acetone, formaldehyde, glyoxal, glutaraldehyde, and mixtures thereof is disposed between the two electrodes.