National Library of Energy BETA

Sample records for dioxide emissions splits

  1. Future Sulfur Dioxide Emissions

    SciTech Connect

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  2. Fast, Efficient Isothermal Redox to Split Water or Carbon Dioxide...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Fast, Efficient Isothermal Redox to Split Water or Carbon Dioxide using Solar Energy ... the hercynite cycle allows faster, more efficient cycling and less wear on the equipment ...

  3. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update

    2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors

  4. Two for the Price of One: Water and Carbon Dioxide Splitting...

    Office of Science (SC)

    and carbon dioxide splitting, two difficult yet key reactions for solar energy conversion. ... Image courtesy of UNC Chapel Hill (graphic art by Yan Liang) Electrochemical cell for ...

  5. Fact #948: October 24, 2016 Carbon Dioxide Emissions from Transportation

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Exceeded those from the Electric Power Sector for the First Time in 38 Years - Dataset | Department of Energy 8: October 24, 2016 Carbon Dioxide Emissions from Transportation Exceeded those from the Electric Power Sector for the First Time in 38 Years - Dataset Fact #948: October 24, 2016 Carbon Dioxide Emissions from Transportation Exceeded those from the Electric Power Sector for the First Time in 38 Years - Dataset Excel file and dataset for Carbon Dioxide Emissions from Transportation

  6. Carbon Dioxide Emissions Associated with Bioenergy and Other...

    OpenEI (Open Energy Information) [EERE & EIA]

    and Other Biogenic Sources Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Emissions Associated with Bioenergy and Other Biogenic Sources AgencyCompany...

  7. CarBen Version 3: Multisector Carbon Dioxide Emissions Accounting...

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: CarBen Version 3: Multisector Carbon Dioxide Emissions Accounting Tool Focus Area: Geothermal Power Topics: Policy, Deployment, & Program Impact Website: www.netl.doe.gov...

  8. U.S. Energy-Related Carbon Dioxide Emissions, 2014

    Energy Information Administration (EIA) (indexed site)

    Related Carbon Dioxide Emissions, 2014 November 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 November 2015 U.S. Energy Information Administration | U.S. Energy-Related Carbon Dioxide Emissions, 2014 1 November 2015 U.S. Energy Information Administration | U.S. Energy-Related Carbon Dioxide Emissions, 2014 2 November 2015 U.S. Energy Information Administration | U.S. Energy-Related Carbon Dioxide Emissions, 2014 3 November 2015 U.S. Energy

  9. Estimates of State Energy-Related Carbon Dioxide Emissions

    Energy Information Administration (EIA) (indexed site)

    November 2016 Estimates of State Energy-Related Carbon Dioxide Emissions Because energy-related carbon dioxide (CO2) constitutes over 80% of total emissions, the state energy- related CO2 emission levels provide a good indicator of the relative contribution of individual states to total greenhouse gas emissions. The U.S. Energy Information Administration (EIA) emissions estimates at the state level for energy-related CO2 are based on data contained in the State Energy Data System (SEDS). 1 The

  10. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    2 Table 4. 2013 state energy-related carbon dioxide emission shares by sector percent of ... Administration | Energy-Related Carbon Dioxide Emissions at the State Level, ...

  11. Fact #948: October 24, 2016 Carbon Dioxide Emissions from Transportation

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Exceeded those from the Electric Power Sector for the First Time in 38 Years | Department of Energy 8: October 24, 2016 Carbon Dioxide Emissions from Transportation Exceeded those from the Electric Power Sector for the First Time in 38 Years Fact #948: October 24, 2016 Carbon Dioxide Emissions from Transportation Exceeded those from the Electric Power Sector for the First Time in 38 Years SUBSCRIBE to the Fact of the Week Beginning in 1978, carbon dioxide (CO2) emissions from the electric

  12. Fact #898: November 9, 2015 World Carbon Dioxide Emissions, 1990...

    Energy.gov [DOE] (indexed site)

    World Carbon Dioxide Emissions, 1990-2012 Year United States Rest of North America Central & South America Europe Eurasia Middle East Africa India China Rest of Asia & Oceania 1990 ...

  13. Short-Term Energy Carbon Dioxide Emissions Forecasts August 2009

    Reports and Publications

    2009-01-01

    Supplement to the Short-Term Energy Outlook. Short-term projections for U.S. carbon dioxide emissions of the three fossil fuels: coal, natural gas, and petroleum.

  14. U.S. Energy-Related Carbon Dioxide Emissions, 2013

    Annual Energy Outlook

    Energy-Related Carbon Dioxide Emissions, 2013 October 2014 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 October 2014 U.S. Energy...

  15. Carbon Dioxide Emissions From Vegetation-Kill Zones Around The...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Carbon Dioxide Emissions From Vegetation-Kill Zones Around The Resurgent Dome Of Long Valley...

  16. Table 21. Total Energy Related Carbon Dioxide Emissions, Projected...

    Energy Information Administration (EIA) (indexed site)

    Total Energy Related Carbon Dioxide Emissions, Projected vs. Actual Projected (million metric tons) 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 ...

  17. "Table 21. Total Energy Related Carbon Dioxide Emissions, Projected...

    Energy Information Administration (EIA) (indexed site)

    Total Energy Related Carbon Dioxide Emissions, Projected vs. Actual" "Projected" " (million metric tons)" ,1993,1994,1995,1996,1997,1998,1999,2000,2001,2002,2003,2004,2005,2006,200...

  18. Estimated Carbon Dioxide Emissions in 2008: United States

    SciTech Connect

    Smith, C A; Simon, A J; Belles, R D

    2011-04-01

    Flow charts depicting carbon dioxide emissions in the United States have been constructed from publicly available data and estimates of state-level energy use patterns. Approximately 5,800 million metric tons of carbon dioxide were emitted throughout the United States for use in power production, residential, commercial, industrial, and transportation applications in 2008. Carbon dioxide is emitted from the use of three major energy resources: natural gas, coal, and petroleum. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states, the District of Columbia, and one national) carbon dioxide flow charts representing a comprehensive systems view of national CO{sub 2} emissions. Lawrence Livermore National Lab (LLNL) has published flow charts (also referred to as 'Sankey Diagrams') of important national commodities since the early 1970s. The most widely recognized of these charts is the U.S. energy flow chart (http://flowcharts.llnl.gov). LLNL has also published charts depicting carbon (or carbon dioxide potential) flow and water flow at the national level as well as energy, carbon, and water flows at the international, state, municipal, and organizational (i.e. United States Air Force) level. Flow charts are valuable as single-page references that contain quantitative data about resource, commodity, and byproduct flows in a graphical form that also convey structural information about the system that manages those flows. Data on carbon dioxide emissions from the energy sector are reported on a national level. Because carbon dioxide emissions are not reported for individual states, the carbon dioxide emissions are estimated using published energy use information. Data on energy use is compiled by the U.S. Department of Energy's Energy Information Administration (U.S. EIA) in the State Energy Data System (SEDS). SEDS is updated annually and reports data from 2 years prior to the year of the update. SEDS contains data on primary

  19. Short-Term Energy Outlook Model Documentation: Carbon Dioxide (CO2) Emissions Model

    Reports and Publications

    2009-01-01

    Description of the procedures for estimating carbon dioxide emissions in the Short-Term Energy Outlook

  20. Carbon Dioxide Emission Factors for Coal

    Reports and Publications

    1994-01-01

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  1. Table 5. Per capita energy-related carbon dioxide emissions by...

    Energy Information Administration (EIA) (indexed site)

    Per capita energy-related carbon dioxide emissions by State (2000-2011)" "metric tons of carbon dioxide per person" ,,,"Change" ,,,"2000 to 2011"...

  2. Table 2. 2011 State energy-related carbon dioxide emissions by...

    Energy Information Administration (EIA) (indexed site)

    2011 State energy-related carbon dioxide emissions by fuel " ,"million metric tons of carbon dioxide",,,,,"shares" "State","Coal","Petroleum","Natural Gas ","Total",,"Coal","Petrol...

  3. Table 3. 2011 State energy-related carbon dioxide emissions by...

    Energy Information Administration (EIA) (indexed site)

    2011 State energy-related carbon dioxide emissions by sector " "million metric tons of carbon dioxide" "State","Commercial","Electric Power","Residential","Industrial","Transportat...

  4. Table 1. State energy-related carbon dioxide emissions by year...

    Energy Information Administration (EIA) (indexed site)

    State energy-related carbon dioxide emissions by year (2000-2011)" "million metric tons of carbon dioxide" ,,,"Change" ,,,"2000 to 2011" "State",2000,2001,2002,...

  5. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    0 Table 3. 2013 state energy-related carbon dioxide emissions by sector million metric tons carbon dioxide State Commercial Electric Power Residential Industrial Transportation ...

  6. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  7. Options for reducing carbon dioxide emissions

    SciTech Connect

    Rosenfeld, A.H.; Price, L.

    1991-08-01

    Improvements in energy efficiency can significantly reduce the annual growth in greenhouse gas emissions. Such improvements occur when energy intensity is reduced; no reduction in energy services is required. Using the concept of cost of conserved energy'' to develop conservation supply curves similar to resource supply curves, researchers consistently find that electricity and natural gas savings of nearly 50% of current consumption are possible for US buildings. Such reductions in energy consumption directly reduce emissions of greenhouse gases. To capture these savings, we must continue to develop energy-efficient technologies and strategies. This paper describes three recent energy-efficient technologies that benefited from energy conservation research and development (R D) funding: high-frequency ballasts, compact fluorescent lamps, and low-emissivity windows. Other advanced technologies and strategies of spectrally selective windows, superwindows, electrochromic windows, advanced insulation, low-flow showerheads, improved recessed lamp fixtures, whitening surfaces and planting urban trees, daylighting, and thermal energy storage are also discussed. 33 refs., 9 figs., 3 tabs.

  8. Utilizing the market to control sulfur dioxide emissions

    SciTech Connect

    Loeher, C.F. III

    1995-12-01

    Environmental policy in the United States is evolving; command and control approaches are being slowly replaced with market-based incentives. Market-based regulation is favorable because it provides the regulated community with flexibility in choosing between pollution control options. A recent application of a market-based approach is Title IV of the 1990 Clean Air Act Amendments. This paper evaluates the advantages of utilizing market-based incentives to control sulfur dioxide emissions. The evaluation embodies an extensive methodology, which provides an overview of the policy governing air quality, discusses pollution control philosophies and analyzes their associated advantages and limitations. Further, it describes the development and operation of a market for emissions trading, impediments to the market, and recommends strategies to improve the market. The evaluation concludes by analyzing the results of five empirical simulations demonstrating the cost-effectiveness of employing market-based incentives versus command-and-control regulation for controlling sulfur dioxide emissions. The results of the evaluation indicate that regulatory barriers and market impediments have inhibited allowance trading. However, many of these obstacles have been or are being eliminated through Federal and state regulations, and through enhancement of the market. Results also demonstrate that sulfur dioxide allowance trading can obtain identical levels of environmental protection as command-and-control approaches while realizing cost savings to government and industry.

  9. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    6 Table 1. State energy-related carbon dioxide emissions by year (2000-2013) million metric tons carbon dioxide Change (2000-2013) State 2000 2001 2002 2003 2004 2005 2006 2007 ...

  10. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    4 Table 5. Per capita energy-related carbon dioxide emissions by state (2000-2013) metric tons carbon dioxide per person Change (2000-2013) State 2000 2001 2002 2003 2004 2005 2006 ...

  11. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    8 Table 2. 2013 state energy-related carbon dioxide emissions by fuel million metric tons of carbon dioxide Shares State Coal Petroleum Natural Gas Total Coal Petroleum Natural Gas ...

  12. Table 11.1 Carbon Dioxide Emissions From Energy Consumption by...

    Energy Information Administration (EIA) (indexed site)

    ... minus denaturant. 5Distillate fuel oil, excluding biodiesel. RRevised. PPreliminary. ... Notes: * Data are estimates for carbon dioxide emissions from energy consumption, ...

  13. Table 11.2c Carbon Dioxide Emissions From Energy Consumption...

    Energy Information Administration (EIA) (indexed site)

    ... minus denaturant. 4Distillate fuel oil, excluding biodiesel. RRevised. PPreliminary. ... Notes: * Data are estimates for carbon dioxide emissions from energy consumption, ...

  14. Table 11.2b Carbon Dioxide Emissions From Energy Consumption...

    Energy Information Administration (EIA) (indexed site)

    ... minus denaturant. 4Distillate fuel oil, excluding biodiesel. RRevised. PPreliminary. ... Notes: * Data are estimates for carbon dioxide emissions from energy consumption. * See ...

  15. Fact #898: November 9, 2015 World Carbon Dioxide Emissions, 1990-2012 -

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Dataset | Department of Energy 8: November 9, 2015 World Carbon Dioxide Emissions, 1990-2012 - Dataset Fact #898: November 9, 2015 World Carbon Dioxide Emissions, 1990-2012 - Dataset Excel file and dataset for 2015 World Carbon Dioxide Emissions, 1990-2012 fotw#898_web.xlsx (25.25 KB) More Documents & Publications Fact #948: October 24, 2016 Carbon Dioxide Emissions from Transportation Exceeded those from the Electric Power Sector for the First Time in 38 Years - Dataset Enabling the

  16. Table 4. 2011 State energy-related carbon dioxide emission shares...

    Energy Information Administration (EIA) (indexed site)

    2011 State energy-related carbon dioxide emission shares by sector " "percent of total" ,"shares" "State","Commercial","Electric Power","Residential","Industrial","Transportation"...

  17. Impacts of urban transportation mode split on CO{sub 2} emissions in Jinan, China.

    SciTech Connect

    He, D.; Meng, F.; Wang, M.; He, K.

    2011-04-01

    As the world's largest developing country, China currently is undergoing rapid urbanization and motorization, which will result in far-reaching impacts on energy and the environment. According to estimates, energy use and carbon emissions in the transportation sector will comprise roughly 30% of total emissions by 2030. Since the late 1990s, transportation-related issues such as energy, consumption, and carbon emissions have become a policy focus in China. To date, most research and policies have centered on vehicle technologies that promote vehicle efficiency and reduced emissions. Limited research exists on the control of greenhouse gases through mode shifts in urban transportation - in particular, through the promotion of public transit. The purpose of this study is to establish a methodology to analyze carbon emissions from the urban transportation sector at the Chinese city level. By using Jinan, the capital of China's Shandong Province, as an example, we have developed an analytical model to simulate energy consumption and carbon emissions based on the number of trips, the transportation mode split, and the trip distance. This model has enabled us to assess the impacts of the transportation mode split on energy consumption and carbon emissions. Furthermore, this paper reviews a set of methods for data collection, estimation, and processing for situations where statistical data are scarce in China. This paper also describes the simulation of three transportation system development scenarios. The results of this study illustrate that if no policy intervention is implemented for the transportation mode split (the business-as-usual (BAU) case), then emissions from Chinese urban transportation systems will quadruple by 2030. However, a dense, mixed land-use pattern, as well as transportation policies that encourage public transportation, would result in the elimination of 1.93 million tons of carbon emissions - approximately 50% of the BAU scenario emissions.

  18. Impact of Light-Duty Vehicle Emissions on 21st Century Carbon Dioxide Concentrations

    SciTech Connect

    Smith, Steven J.; Kyle, G. Page

    2007-08-04

    The impact of light-duty passenger vehicle emissions on global carbon dioxide concentrations was estimated using the MAGICC reduced-form climate model combined with the PNNL contribution to the CCSP scenarios product. Our central estimate is that tailpipe light duty vehicle emissions of carbon-dioxide over the 21st century will increase global carbon dioxide concentrations by slightly over 12 ppmv by 2100.

  19. Sulfur dioxide emissions from primary copper smelters in the western US

    SciTech Connect

    Mangeng, C.A.; Mead, R.W.

    1980-01-01

    The body of information presented is directed to environmental scientists and policy makers without chemical or metallurgical engineering backgrounds. This paper addresses the problems of reducing sulfur dioxide emissions from primary copper smelters in the western United States and projects the future impact of emissions within a framework of legal, technological, and economic considerations. Methodology used to calculate historical sulfur dioxide emissions is described. Sulfur dioxide emission regulations are outlined as they apply to primary copper smelters. A discussion of available sulfur dioxide control technology and copper smelting processes summarizes the technological and economic problems of reducing copper smelter emissions. Based upon these technological and economic considerations, projections of smelter emissions indicate that compliance with existing legislative requirements will be achieved by 1990. Three smelters are projected to close by 1985.

  20. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  1. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    Energy-Related Carbon Dioxide Emissions at the State Level, 2000-2013 October 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. ...

  2. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    ... 10.8 -14.3% -1.8 October 2015 U.S. Energy Information Administration | Energy-Related Carbon Dioxide Emissions at the State Level, 2000-2013 17 Table 6. Energy intensity by state ...

  3. Table 8 U.S. Carbon Dioxide Emissions from Residential Sector...

    Energy Information Administration (EIA) (indexed site)

    U.S. Carbon Dioxide Emissions from Residential Sector Energy Consumption, 1990-2009" " (Million Metric Tons of Carbon Diioxide)" ,,1990,1991,1992,1993,1994,1995,1996,1997,1998,199...

  4. Further Sensitivity Analysis of Hypothetical Policies to Limit Energy-Related Carbon Dioxide Emissions

    Reports and Publications

    2013-01-01

    This analysis supplements the Annual Energy Outlook 2013 alternative cases which imposed hypothetical carbon dioxide emission fees on fossil fuel consumers. It offers further cases that examine the impacts of fees placed only on the emissions from electric power facilities, impacts of returning potential revenues to consumers, and two cap-and-trade policies.

  5. Energy use and carbon dioxide emissions in the steel sector in key developing countries

    SciTech Connect

    Price, L.K.; Phylipsen, G.J.M.; Worrell, E.

    2001-04-01

    Iron and steel production consumes enormous quantities of energy, especially in developing countries where outdated, inefficient technologies are still used to produce iron and steel. Carbon dioxide emissions from steel production, which range between 5 and 15% of total country emissions in key developing countries (Brazil, China, India, Mexico, and South Africa), will continue to grow as these countries develop and as demand for steel products such as materials, automobiles, and appliances increases. In this report, we describe the key steel processes, discuss typical energy-intensity values for these processes, review historical trends in iron and steel production by process in five key developing countries, describe the steel industry in each of the five key developing countries, present international comparisons of energy use and carbon dioxide emissions among these countries, and provide our assessment of the technical potential to reduce these emissions based on best-practice benchmarking. Using a best practice benchmark, we find that significant savings, in the range of 33% to 49% of total primary energy used to produce steel, are technically possible in these countries. Similarly, we find that the technical potential for reducing intensities of carbon dioxide emissions ranges between 26% and 49% of total carbon dioxide emissions from steel production in these countries.

  6. Carbon Dioxide and Helium Emissions from a Reservoir of Magmatic...

    OpenEI (Open Energy Information) [EERE & EIA]

    in eastern California. The gas is released mainly as diffuse emissions from normal-temperature soils, but some gas issues from steam vents or leaves the mountain dissolved...

  7. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOEpatents

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  8. Carbon Dioxide Emissions from the Generation of Electric Power in the United States 1998

    Reports and Publications

    1999-01-01

    The President issued a directive on April 15, 1999, requiring an annual report summarizing carbon dioxide (CO2) emissions produced by electricity generation in the United States, including both utilities and nonutilities. In response, this report is jointly submitted by the U.S. Department of Energy and the U.S. Environmental Protection Agency.

  9. Energy-Related Carbon Dioxide Emissions at the State Level, 2000-2013

    Reports and Publications

    2015-01-01

    This analysis examines some of the factors that influence state-level carbon dioxide emissions from the consumption of fossil fuels. These factors include: the fuel mix — especially in the generation of electricity; the state climate; the population density of the state; the industrial makeup of the state and whether the state is a net exporter or importer of electricity.

  10. Regional versus global? -- Will strategies for reduction of sulfur dioxide emissions from electric utilities increase carbon dioxide emissions?

    SciTech Connect

    Randolph, J.C.; Dolsak, N.

    1996-12-31

    Electric utilities, which are dependent on high-sulfur coal are expected to reduce their SO{sub 2} emissions. The strategies for reduction of SO{sub 2} emissions may result in increased CO{sub 2} emissions. Thereby decrease of regional pollution may cause increase of global pollution. Environmental, political, moral, and economic consequences of the two types of pollution differ significantly. Midwestern electric utilities, USA, which are dependent on high-sulfur coal, are analyzed in the paper. However, the same problem is relevant for some European coal fueled power plants. Strategies for reduction of SO{sub 2} emissions, employed by Midwestern electric utilities to comply with the clean Air Act amendments (CAAA) of 1990 and their possible affects on CO{sub 2} emissions, are presented. The paper focuses on two general strategies for reduction of SO{sub 2} emissions. First is coal-switching or blending with a low-sulfur coal. Second is construction and use of flue-gas desulfurization devices (scrubbers). A combination of both strategies is also a viable option. Switching to low-sulfur coal may result in larger CO{sub 2} emissions because that coal has different characteristics and has to be transported much greater distances. Scrubbers require significant amounts of energy for their operation which requires burning more coal. This increases the level of CO{sub 2} emissions.

  11. Outstanding field emission properties of wet-processed titanium dioxide coated carbon nanotube based field emission devices

    SciTech Connect

    Xu, Jinzhuo; Ou-Yang, Wei Chen, Xiaohong; Guo, Pingsheng; Piao, Xianqing; Sun, Zhuo; Xu, Peng; Wang, Miao; Li, Jun

    2015-02-16

    Field emission devices using a wet-processed composite cathode of carbon nanotube films coated with titanium dioxide exhibit outstanding field emission characteristics, including ultralow turn on field of 0.383 V μm{sup −1} and threshold field of 0.657 V μm{sup −1} corresponding with a very high field enhancement factor of 20 000, exceptional current stability, and excellent emission uniformity. The improved field emission properties are attributed to the enhanced edge effect simultaneously with the reduced screening effect, and the lowered work function of the composite cathode. In addition, the highly stable electron emission is found due to the presence of titanium dioxide nanoparticles on the carbon nanotubes, which prohibits the cathode from the influence of ions and free radical created in the emission process as well as residual oxygen gas in the device. The high-performance solution-processed composite cathode demonstrates great potential application in vacuum electronic devices.

  12. Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein

    DOEpatents

    Bamberger, C.E.; Robinson, P.R.

    A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cyclic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

  13. Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein

    DOEpatents

    Bamberger, Carlos E.; Robinson, Paul R.

    1980-01-01

    A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cylic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

  14. Short run effects of a price on carbon dioxide emissions from U.S. electric generators

    SciTech Connect

    Adam Newcomer; Seth A. Blumsack; Jay Apt; Lester B. Lave; M. Granger Morgan [Carnegie Mellon University, Pittsburgh, PA (United States). Carnegie Mellon Electricity Industry Center

    2008-05-01

    The price of delivered electricity will rise if generators have to pay for carbon dioxide emissions through an implicit or explicit mechanism. There are two main effects that a substantial price on CO{sub 2} emissions would have in the short run (before the generation fleet changes significantly). First, consumers would react to increased price by buying less, described by their price elasticity of demand. Second, a price on CO{sub 2} emissions would change the order in which existing generators are economically dispatched, depending on their carbon dioxide emissions and marginal fuel prices. Both the price increase and dispatch changes depend on the mix of generation technologies and fuels in the region available for dispatch, although the consumer response to higher prices is the dominant effect. We estimate that the instantaneous imposition of a price of $35 per metric ton on CO{sub 2} emissions would lead to a 10% reduction in CO{sub 2} emissions in PJM and MISO at a price elasticity of -0.1. Reductions in ERCOT would be about one-third as large. Thus, a price on CO{sub 2} emissions that has been shown in earlier work to stimulate investment in new generation technology also provides significant CO{sub 2} reductions before new technology is deployed at large scale. 39 refs., 4 figs., 2 tabs.

  15. Accounting for Carbon Dioxide Emissions from Biomass Energy Combustion (released in AEO2010)

    Reports and Publications

    2010-01-01

    Carbon Dioxide (CO2) emissions from the combustion of biomass to produce energy are excluded from the energy-related CO2 emissions reported in Annual Energy Outlook 2010. According to current international convention, carbon released through biomass combustion is excluded from reported energy-related emissions. The release of carbon from biomass combustion is assumed to be balanced by the uptake of carbon when the feedstock is grown, resulting in zero net emissions over some period of time]. However, analysts have debated whether increased use of biomass energy may result in a decline in terrestrial carbon stocks, leading to a net positive release of carbon rather than the zero net release assumed by its exclusion from reported energy-related emissions.

  16. Energy-Related Carbon Dioxide Emissions in U.S. Manufacturing

    Reports and Publications

    2006-01-01

    Based on the Manufacturing Energy Consumption Survey (MECS) conducted by the U.S. Department of Energy, Energy Information Administration (EIA), this paper presents historical energy-related carbon dioxide emission estimates for energy-intensive sub-sectors and 23 industries. Estimates are based on surveys of more than 15,000 manufacturing plants in 1991, 1994, 1998, and 2002. EIA is currently developing its collection of manufacturing data for 2006.

  17. Ternary Electrocatalysts for Oxidizing Ethanol to Carbon Dioxide: Making Ir Capable of Splitting C-C bond

    SciTech Connect

    Li, Meng; Cullen, David A; Sasaki, Kotaro; Marinkovic, N.; More, Karren Leslie; Adzic, Radoslav R.

    2013-01-01

    Splitting the C-C bond is the main obstacle to electroxidation of ethanol (EOR) to CO2. We recently demonstrated that the ternary PtRhSnO2 electrocatalyst can accomplish that reaction at room temperature with Rh having a unique capability to split the C-C bond. In this article we report the finding that Ir can be induced to split the C-C bond as a component of the ternary catalyst. We synthesized, characterized and compared the properties of several ternary electrocatalysts. Carbon-supported nanoparticle (NP) electrocatalysts comprising a SnO2 NP core decorated with multi-metallic nanoislands (MM = PtIr, PtRh, IrRh, PtIrRh) were prepared using a seeded growth approach. An array of characterization techniques were employed to establish the composition and architecture of the synthesized MM /SnO2 NPs, while electrochemical and in situ infrared reflection absorption spectroscopy studies elucidated trends in activity and the nature of the reaction intermediates and products. Both EOR reactivity and selectivity towards CO2 formation of several of these MM /SnO2/C electrocatalysts are significantly higher compared to conventional Pt/C and Pt/SnO2/C catalysts. We demonstrate that the PtIr/SnO2/C catalyst with high Ir content shows outstanding catalytic property with the most negative EOR onset potential and reasonably good selectivity towards ethanol complete oxidation to CO2. PtRh/SnO2/C catalysts with a moderate Rh content exhibit the highest EOR selectivity, as deduced from infrared studies.

  18. Inventory of Carbon Dioxide (CO2) Emissions at Pacific Northwest National Laboratory

    SciTech Connect

    Judd, Kathleen S.; Kora, Angela R.; Shankle, Steve A.; Fowler, Kimberly M.

    2009-06-29

    The Carbon Management Strategic Initiative (CMSI) is a lab-wide initiative to position the Pacific Northwest National Laboratory (PNNL) as a leader in science, technology and policy analysis required to understand, mitigate and adapt to global climate change as a nation. As part of an effort to walk the talk in the field of carbon management, PNNL conducted its first carbon dioxide (CO2) emissions inventory for the 2007 calendar year. The goal of this preliminary inventory is to provide PNNL staff and management with a sense for the relative impact different activities at PNNL have on the labs total carbon footprint.

  19. Carbon dioxide emission index as a mean for assessing fuel quality

    SciTech Connect

    Furimsky, E.

    2008-07-01

    Carbon dioxide emission index, defined as the amount of CO{sub 2} released per unit of energy value, was used to rate gaseous, liquid and solid fuels. The direct utilization of natural gas is the most efficient option. The conversion of natural gas to synthesis gas for production of liquid fuels represents a significant decrease in fuel value of the former. The fuel value of liquids, such as gasoline, diesel oil, etc. is lower than that of natural gas. Blending gasoline with ethanol obtained either from bio-mass or via synthesis may decrease fuel value of the blend when CO{sub 2} emissions produced during the production of ethanol are included in total emissions. The introduction of liquid fuels produced by pyrolysis and liquefaction of biomass would result in the increase in the CO{sub 2} emissions. The CO{sub 2} emissions from the utilization of coal and petroleum coke are much higher than those from gaseous and liquid fuels. However, for petroleum coke, this is offset by the high value gaseous and liquid fuels that are simultaneously produced during coking. Conversion of low value fuels such as coal and petroleum coke to a high value chemicals via synthesis gas should be assessed as means for replacing natural gas and making it available for fuel applications.

  20. Incorporation of catalytic dehydrogenation into fischer-tropsch synthesis to significantly reduce carbon dioxide emissions

    DOEpatents

    Huffman, Gerald P.

    2012-11-13

    A new method of producing liquid transportation fuels from coal and other hydrocarbons that significantly reduces carbon dioxide emissions by combining Fischer-Tropsch synthesis with catalytic dehydrogenation is claimed. Catalytic dehydrogenation (CDH) of the gaseous products (C1-C4) of Fischer-Tropsch synthesis (FTS) can produce large quantities of hydrogen while converting the carbon to multi-walled carbon nanotubes (MWCNT). Incorporation of CDH into a FTS-CDH plant converting coal to liquid fuels can eliminate all or most of the CO.sub.2 emissions from the water-gas shift (WGS) reaction that is currently used to elevate the H.sub.2 level of coal-derived syngas for FTS. Additionally, the FTS-CDH process saves large amounts of water used by the WGS reaction and produces a valuable by-product, MWCNT.

  1. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOEpatents

    Huffman, Gerald P

    2012-09-18

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  2. Estimating carbon dioxide emission factors for the California electric power sector

    SciTech Connect

    Marnay, Chris; Fisher, Diane; Murtishaw, Scott; Phadke, Amol; Price, Lynn; Sathaye, Jayant

    2002-08-01

    The California Climate Action Registry (''Registry'') was initially established in 2000 under Senate Bill 1771, and clarifying legislation (Senate Bill 527) was passed in September 2001. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) has been asked to provide technical assistance to the California Energy Commission (CEC) in establishing methods for calculating average and marginal electricity emissions factors, both historic and current, as well as statewide and for sub-regions. This study is exploratory in nature. It illustrates the use of three possible approaches and is not a rigorous estimation of actual emissions factors. While the Registry will ultimately cover emissions of all greenhouse gases (GHGs), presently it is focusing on carbon dioxide (CO2). Thus, this study only considers CO2, which is by far the largest GHG emitted in the power sector. Associating CO2 emissions with electricity consumption encounters three major complications. First, electricity can be generated from a number of different primary energy sources, many of which are large sources of CO2 emissions (e.g., coal combustion) while others result in virtually no CO{sub 2} emissions (e.g., hydro). Second, the mix of generation resources used to meet loads may vary at different times of day or in different seasons. Third, electrical energy is transported over long distances by complex transmission and distribution systems, so the generation sources related to electricity usage can be difficult to trace and may occur far from the jurisdiction in which that energy is consumed. In other words, the emissions resulting from electricity consumption vary considerably depending on when and where it is used since this affects the generation sources providing the power. There is no practical way to identify where or how all the electricity used by a certain customer was generated, but by reviewing public sources of data the total emission burden of a customer's electricity

  3. The costs of different energy taxes for stabilizing U. S. carbon dioxide emissions: An application of the Gemini model

    SciTech Connect

    Leary, N.A.; Scheraga, J.D. . Climate Change Div.)

    1993-09-01

    In the absence of policies to mitigate emissions of carbon dioxide, US emissions will grow substantially over the period 1990 to 2030. One option for mitigation of carbon dioxide emissions is to tax energy use. For example, fossil energy might be taxed according to its carbon content, heating value, or market value. Using a partial equilibrium model of US energy markets that combines detailed representation of technological processes with optimizing behavior by energy users and suppliers, the authors compare the costs of using carbon, Btu, and ad valorem taxes as instruments to implement a policy of emission stabilization. The authors also examine the differential impacts of these taxes on the mix of primary energy consumed in the US. The carbon tax induces the substitution of renewables and natural gas for coal and stabilizes carbon dioxide emissions at an estimated annual cost of $125 billion. The Btu tax induces the substitution of renewables for coal, but does not encourage the use of natural gas. The estimated cost of stabilization with the Btu tax is $210 billion per year. The ad valorem tax, like the Btu tax, does not encourage the substitution of natural gas for coal. It also causes a significant shift away from oil in comparison to the carbon tax. The cost of stabilizing emissions with the ad valorem tax is estimated at $450 billion per year.

  4. MINIMIZING NET CARBON DIOXIDE EMISSIONS BY OXIDATIVE CO-PYROLYSIS OF COAL/BIOMASS BLENDS

    SciTech Connect

    Robert Hurt; Todd Lang

    2001-06-25

    Solid fuels vary significantly with respect to the amount of CO{sub 2} directly produced per unit heating value. Elemental carbon is notably worse than other solid fuels in this regard, and since carbon (char) is an intermediate product of the combustion of almost all solid fuels, there is an opportunity to reduce specific CO{sub 2} emissions by reconfiguring processes to avoid char combustion wholly or in part. The primary goal of this one-year Innovative Concepts project is to make a fundamental thermodynamic assessment of three modes of solid fuel use: (1) combustion, (2) carbonization, and (3) oxidative pyrolysis, for a wide range of coal and alternative solid fuels. This period a large set of thermodynamic calculations were carried out to assess the potential of the three processes. The results show that the net carbon dioxide emissions and the relative ranking of the different processes depends greatly on the particular baseline fossil fuel being displaced by the new technology. As an example, in a baseline natural gas environment, it is thermodynamically more advantageous to carbonize biomass than to combust it, and even more advantageous to oxidatively pyrolyze the biomass.

  5. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer

    Gurney, Kevin

    The Vulcan Project is a NASA/DOE funded effort under the North American Carbon Program (NACP) to quantify North American fossil fuel carbon dioxide (CO2) emissions at space and time scales much finer than has been achieved in the past. The purpose is to aid in quantification of the North American carbon budget, to support inverse estimation of carbon sources and sinks, and to support the demands posed by higher resolution CO2 observations (in situ and remotely sensed). The detail and scope of the Vulcan CO2 inventory has also made it a valuable tool for policymakers, demographers, social scientists and the public at large. The Vulcan project has achieved the quantification of the 2002 U.S. fossil fuel CO2 emissions at the scale of individual factories, powerplants, roadways and neighborhoods on an hourly basis. The entire inventory was built on a common 10 km x 10 km grid to facilitate atmospheric modeling. In addition to improvement in space and time resolution, Vulcan is quantified at the level of fuel type, economic sub-sector, and county/state identification. Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  6. Energy-Related Carbon Dioxide Emissions at the State Level, 2000-2013

    Energy Information Administration (EIA) (indexed site)

    2 Table 9. Net electricity trade index and primary electricity source for states with least and most energy-related carbon dioxide emissions per capita (2000-2013) 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 Primary 2011 2012 2013 Source Least CO2 per capita New York 0.9 1.0 0.9 0.9 0.9 0.9 1.0 1.0 1.0 0.9 0.9 1.0 1.0 1.0 Natural Gas Vermont 1.6 1.4 1.3 1.3 1.2 1.2 1.5 1.3 1.5 1.7 1.5 1.6 3.0 3.2 Nuclear California 0.8 0.7 0.7 0.7 0.7 0.7 0.8 0.7 0.7 0.7 0.7 0.7 0.7 0.7 Natural Gas

  7. Table 11.2e Carbon Dioxide Emissions From Energy Consumption...

    Energy Information Administration (EIA) (indexed site)

    ... from energy consumption. * See "Carbon Dioxide" in Glossary. * Totals may not equal sum of components due to independent rounding. 4Distillate fuel oil, excluding biodiesel. ...

  8. Table 11.2a Carbon Dioxide Emissions From Energy Consumption...

    Energy Information Administration (EIA) (indexed site)

    ... from energy consumption. * See "Carbon Dioxide" in Glossary. * Totals may not equal sum of components due to independent rounding. 4Distillate fuel oil, excluding biodiesel. ...

  9. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program`s Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  10. Current emission trends for nitrogen oxides, sulfur dioxide, and volatile organic compounds by month and state: Methodology and results

    SciTech Connect

    Kohout, E.J.; Miller, D.J.; Nieves, L.A.; Rothman, D.S.; Saricks, C.L.; Stodolsky, F.; Hanson, D.A.

    1990-08-01

    This report presents estimates of monthly sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and nonmethane voltatile organic compound (VOC) emissions by sector, region, and state in the contiguous United States for the years 1975 through 1988. This work has been funded as part of the National Acid Precipitation Assessment Program's Emissions and Controls Task Group by the US Department of Energy (DOE) Office of Fossil Energy (FE). The DOE project officer is Edward C. Trexler, DOE/FE Office of Planning and Environment.

  11. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE PAGES [OSTI]

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; Greene, S.; Thalasso, F.

    2014-09-12

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH4) and carbon dioxide (CO2) emissions from northern lakes. Here we assessed the relationship between CH4 and CO2 emission modes in 40 lakes along a latitudinal transect in Alaska to physicochemical limnology and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included Direct Ebullition, Diffusion, Storage flux, and a newly identified Ice-Bubble Storage (IBS) flux. We found that all lakes were net sources of atmospheric CH4 and CO2, but the climate warming impact of lake CH4more » emissions was two times higher than that of CO2. Ebullition and Diffusion were the dominant modes of CH4 and CO2 emissions respectively. IBS, ~ 10% of total annual CH4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH4 emissions from stratified, dystrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. Total CH4 emission was correlated with concentrations of phosphate and total nitrogen in lake water, Secchi depth and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH4 emissions from lakes by both supplying organic matter to methanogenesis directly from thawing permafrost and by enhancing nutrient availability to primary production, which can also fuel decomposition and methanogenesis.« less

  12. Table 11.2d Carbon Dioxide Emissions From Energy Consumption...

    Energy Information Administration (EIA) (indexed site)

    Residual Fuel Oil Total Fuel Ethanol 8 Biodiesel Total 1949 161 NA 12 30 NA (s) 4 306 91 ... than 0.5 million metric tons of carbon dioxide. 4Distillate fuel oil, excluding biodiesel. ...

  13. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    8 Table 7. Carbon intensity by state (2000-2013) kilograms of energy-related carbon dioxide per million Btu Change (2000-2013) State 2000 2001 2002 2003 2004 2005 2006 2007 2008 ...

  14. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    20 Table 8. Carbon intensity of the economy by state (2000-2013) metric tons of energy-related carbon dioxide per million chained 2009 dollars of GDP Change (2000-2013) State 2000 ...

  15. A New Method for Production of Titanium Dioxide Pigment - Eliminating CO2 Emission

    SciTech Connect

    Fang, Zhigang Zak

    2013-11-05

    The objective of this project was to demonstrate the potential of a new process technology to reduce the energy consumption and CO{sub 2} emission from the production of titanium dioxide (TiO{sub 2}) pigment. TiO{sub 2} is one of the most commonly used minerals in the chemical manufacturing industry. It has been commercially processed as a pigment since the early 1900's, and has a wide variety of domestic and industrial applications. TiO{sub 2} pigment is currently produced primarily by the use of the so called chloride process. A key step of the chloride process relies on high temperature carbo-chlorination of TiO{sub 2} bearing raw materials, hence producing large quantities of CO{sub 2}. The new method uses a chemical/metallurgical sequential extraction methodology to produce pigment grade TiO{sub 2} from high-TiO{sub 2} slag. The specific project objectives were to 1) study and prove the scientific validity of the concept, 2) understand the primary chemical reactions and the efficiency of sequential extraction schemes, 3) determine the properties of TiO{sub 2} produced using the technology, and 4) model the energy consumptions and environmental benefits of the technology. These objectives were successfully met and a new process for producing commercial quality TiO{sub 2} pigment was developed and experimentally validated. The process features a unique combination of established metallurgical processes, including alkaline roasting of titania slag followed by leaching, solvent extraction, hydrolysis, and calcination. The caustic, acidic, and organic streams in the process will also be regenerated and reused in the process, greatly reducing environmental waste. The purpose and effect of each of these steps in producing purified TiO{sub 2} is detailed in the report. The levels of impurities in our pigment meet the requirements for commercial pigment, and are nearly equivalent to those of two commercial pigments. Solvent extraction with an amine extractant proved to

  16. Methane and carbon dioxide emissions from 40 lakes along a north–south latitudinal transect in Alaska

    DOE PAGES [OSTI]

    Sepulveda-Jauregui, A.; Walter Anthony, K. M.; Martinez-Cruz, K.; Greene, S.; Thalasso, F.

    2015-06-02

    Uncertainties in the magnitude and seasonality of various gas emission modes, particularly among different lake types, limit our ability to estimate methane (CH4) and carbon dioxide (CO2) emissions from northern lakes. Here we assessed the relationship between CH4 and CO2 emission modes in 40 lakes along a latitudinal transect in Alaska to lakes' physicochemical properties and geographic characteristics, including permafrost soil type surrounding lakes. Emission modes included direct ebullition, diffusion, storage flux, and a newly identified ice-bubble storage (IBS) flux. We found that all lakes were net sources of atmospheric CH4 and CO2, but the climate warming impact of lakemore » CH4 emissions was 2 times higher than that of CO2. Ebullition and diffusion were the dominant modes of CH4 and CO2 emissions, respectively. IBS, ~10% of total annual CH4 emissions, is the release to the atmosphere of seasonally ice-trapped bubbles when lake ice confining bubbles begins to melt in spring. IBS, which has not been explicitly accounted for in regional studies, increased the estimate of springtime emissions from our study lakes by 320%. Geographically, CH4 emissions from stratified, mixotrophic interior Alaska thermokarst (thaw) lakes formed in icy, organic-rich yedoma permafrost soils were 6-fold higher than from non-yedoma lakes throughout the rest of Alaska. The relationship between CO2 emissions and geographic parameters was weak, suggesting high variability among sources and sinks that regulate CO2 emissions (e.g., catchment waters, pH equilibrium). Total CH4 emission was correlated with concentrations of soluble reactive phosphorus and total nitrogen in lake water, Secchi depth, and lake area, with yedoma lakes having higher nutrient concentrations, shallower Secchi depth, and smaller lake areas. Our findings suggest that permafrost type plays important roles in determining CH4 emissions from lakes by both supplying organic matter to methanogenesis directly from

  17. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  18. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2011...

    Annual Energy Outlook

    by sector" was revised to match the values given in Table 3. Paragraph entitled "Emissions by Sector" the following changes were made by state and sector: Vermont...

  19. Reducing Emissions of Sulfur Dioxide, Nitrogen Oxides, and Mercury from Electric Power Plants

    Reports and Publications

    2001-01-01

    This analysis responds to a request from Senators Bob Smith, George Voinovich, and Sam Brownback to examine the costs of specific multi-emission reduction strategies.

  20. Table 9 U.S. Carbon Dioxide Emissions from Commercial Sector...

    Energy Information Administration (EIA) (indexed site)

    table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008," "DOEEIA-0573(2008) (Washington, DC, December ...

  1. Table 6 U.S. Carbon Dioxide Emissions from Energy and Industry...

    Energy Information Administration (EIA) (indexed site)

    ... table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008," "DOEEIA-0573(2008) (Washington, DC, December ...

  2. Table 7. U.S. Energy-Related Carbon Dioxide Emissions by End...

    Energy Information Administration (EIA) (indexed site)

    table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008," "DOEEIA-0573(2008) (Washington, DC, December ...

  3. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  4. The last decade of global anthropogenic sulfur dioxide: 2000-2011 emissions

    SciTech Connect

    Klimont, Z.; Smith, Steven J.; Cofala, Janusz

    2013-01-09

    Evolution of global and regional anthropogenic SO2 emissions in the last decade has been estimated through a bottom-up calculation for recent years. After a strong increase in emissions that peaked about 2006, we estimate a declining trend continuing until 2011. However, there is a strong spatial variability with North America and Europe continuing to reduce emissions with an increasing role of Asia and international shipping. China remains a key contributor but the introduction of stricter emission limits followed by an ambitious program of installing flue gas desulfurization on power plants resulted in significant decline in emissions from energy sector and stabilization of Chinese SO2 emissions. Comparable mitigation strategies are not yet present in several other Asian countries and industrial sectors in general, while emissions from international shipping are expected to start declining soon following agreed reduction of sulfur content of fuel oil. Estimated trends in global SO2 emissions are within the range of RCP projections and uncertainty calculated for the year 2005.

  5. Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

    SciTech Connect

    Smith, P.V.

    1995-12-31

    Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

  6. Split gland

    DOEpatents

    Petranto, Joseph J.

    1982-01-01

    The disclosure relates to a split gland laterally fittable over tubing. Two essentially mirror image half glands are juxtaposed, held together by a spring clip and aligned by a retainer.

  7. Evaluation of carbon dioxide emission control strategies in New York State

    SciTech Connect

    Morris, S.C.; Lee, J.; Goldstein, G.; Hill, D.

    1992-01-01

    A MARKAL model was developed for the State of New York. It represents the state's energy system as a set of typical technologies for generating, converting, and using energy as it evolves over a 45-year period. NYMARKAL was applied here in demonstration analyses to explore strategies to reduce CO{sub 2} emissions. NYMARKAL was installed at the State Energy Office and in the Offices of the New York Power Pool. Staff members from both organizations and other state agencies were trained in its use. Example scenarios showed that it is more difficult and more expensive to reduce carbon emissions in New York State than in the United States as a whole. Were a common carbon tax instituted, it would have less effect in New York and most carbon emissions reduction would take place elsewhere in the country where it is more cost-effective. Alternatively, were all states required to reduce CO{sub 2} emission an equal percentage (say by 20%), the cost per unit emissions reduction to New York would be much greater than in the rest of the country.

  8. Evaluation of carbon dioxide emission control strategies in New York State. Final report, 1990--1991

    SciTech Connect

    Morris, S.C.; Lee, J.; Goldstein, G.; Hill, D.

    1992-01-01

    A MARKAL model was developed for the State of New York. It represents the state`s energy system as a set of typical technologies for generating, converting, and using energy as it evolves over a 45-year period. NYMARKAL was applied here in demonstration analyses to explore strategies to reduce CO{sub 2} emissions. NYMARKAL was installed at the State Energy Office and in the Offices of the New York Power Pool. Staff members from both organizations and other state agencies were trained in its use. Example scenarios showed that it is more difficult and more expensive to reduce carbon emissions in New York State than in the United States as a whole. Were a common carbon tax instituted, it would have less effect in New York and most carbon emissions reduction would take place elsewhere in the country where it is more cost-effective. Alternatively, were all states required to reduce CO{sub 2} emission an equal percentage (say by 20%), the cost per unit emissions reduction to New York would be much greater than in the rest of the country.

  9. New York MARKAL: An evaluation of carbon dioxide emission control strategies in New York State

    SciTech Connect

    Hamilton, L.D.

    1992-12-31

    A MARKAL model was developed for the State of New York. It represents the State`s energy system as a set of typical technologies for generating, converting, and using energy as it evolves over a 45-year period. NYMARKAL was applied here in demonstration analyses to explore strategies to reduce CO2 emissions. NYMARKAL was installed at the State Energy Office and in the Offices of the New York Power Pool. Example scenarios showed that it is more difficult and more expensive to reduce carbon emissions in New York State than in the United States as a whole. Were a common carbon tax instituted, it would have less effect in New York and most carbon emissions reduction would take place elsewhere in the country where it is more cost-effective. Alternatively, were all states required to reduce CO2 emission an equal percentage (say by 20%), the cost per unit emissions reduction to New York would be much greater than in the rest of the country.

  10. Impact of Increased Use of Hydrogen on Petroleum Consumption and Carbon Dioxide Emissions, The

    Reports and Publications

    2008-01-01

    This report responds to a request from Senator Byron L. Dorgan for an analysis of the impacts on U.S. energy import dependence and emission reductions resulting from the commercialization of advanced hydrogen and fuel cell technologies in the transportation and distributed generation markets.

  11. Input quality, trade liberalization, and abatement of carbon-dioxide emissions

    SciTech Connect

    Khanna, M.; Zilberman, D.

    1996-12-31

    This paper introduces a methodology to derive the incentives provided by two alternative policies--an emissions tax vs. liberalization of trade in higher quality coal--for increasing conversion-efficiency of electricity generation and for analyzing their impact on carbon emissions as well as on output of electricity. This methodology is applied empirically to examine the potential for abatement of carbon emissions from existing coal-based plants in the thermal power sector in India through the adoption of higher qualities of coal. The paper provides strong empirical support for achieving a complementarity between the goals of abatement and increased output, through policies which remove distortions in domestic and trade policies. It also demonstrates that abatement induced by an emissions-tax alone leads to a conflict between these goals. The authors examine a situation where the availability of higher quality coal is constrained by domestic and trade barriers. The role of coal quality in improving conversion-efficiency is analyzed when microunits are heterogeneous and have putty-clay technologies. The framework developed here juxtaposes engineering relationships governing plant performance and stylized features of electricity-generating technologies with a behavioral economic model.

  12. The Impact of Electric Passenger Transport Technology under an Economy-Wide Climate Policy in the United States: Carbon Dioxide Emissions, Coal Use, and Carbon Dioxide Capture and Storage

    SciTech Connect

    Wise, Marshall A.; Kyle, G. Page; Dooley, James J.; Kim, Son H.

    2010-03-01

    Plug-in hybrid electric vehicles (PHEVs) have the potential to be an economic means of reducing direct (or tailpipe) carbon dioxide (CO2) emissions from the transportation sector. However, without a climate policy that places a limit on CO2 emissions from the electric generation sector, the net impact of widespread deployment of PHEVs on overall U.S. CO2 emissions is not as clear. A comprehensive analysis must consider jointly the transportation and electricity sectors, along with feedbacks to the rest of the energy system. In this paper, we use the Pacific Northwest National Laboratory’s MiniCAM model to perform an integrated economic analysis of the penetration of PHEVs and the resulting impact on total U.S. CO2 emissions.

  13. Potentials for reductions of carbon dioxide emissions of industrial sector in transitional economies -- A case study of implementation of absorption heat devices and co-generation

    SciTech Connect

    Remec, J.; Dolsak, N.

    1996-12-31

    World carbon dioxide emissions, caused by commercial energy-generation, contribute to about 57% of global warming potential. Central and East European (CEE) countries together with former USSR emitted about 25% of the world carbon dioxide emissions, predominantly because of high energy intensity of their industries and dependence on coal. Energy efficiency improvements can reduce the high level of carbon dioxide emissions per unit of output, which significantly exceeds the levels of the industry in the European Union. CEE countries` most pressing environmental goal is a reduction of local air and water pollution. Therefore, when analyzing potentials for the reduction of greenhouse gases emissions in these countries, they need to concentrate on the activities which would also decrease local pollution. The paper focuses on technologies which would reduce the need for fossil fuel burning by improving energy efficiency in industry. Process industries are very energy intensive. Structure changes of the products are carried out with operations which require input and output of heat. Heat demand is usually met by combustion of fossil fuels, cold is produced with electricity. Technical potentials of absorption heat devices (AHD) and co-generation in process industry as well as their market penetration potentials are analyzed for Slovenia, one of the fastest transforming CEE economies.

  14. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  15. Split gland

    DOEpatents

    Petranto, Joseph J. (Los Alamos, NM)

    1989-01-01

    A split gland having only three parts is described. The gland has substantially the same stability to the relative motion of the constituent half-gland members during the attachment process to a female fitting as have more complicated designs. Ease of manufacture and use result from the reduction in complexity of the present invention.

  16. Split gland

    DOEpatents

    Petranto, J.J.

    1989-09-05

    A split gland having only three parts is described. The gland has substantially the same stability to the relative motion of the constituent half-gland members during the attachment process to a female fitting as have more complicated designs. Ease of manufacture and use result from the reduction in complexity of the present invention. 15 figs.

  17. DOE's Gasoline/Diesel PM Split Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Documents & Publications DOE's GasolineDiesel PM Split Study DOE's GasolineDiesel PM Split Study Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel ...

  18. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of ...

  19. Applications of carbon dioxide capture and storage technologies in reducing emissions from fossil-fired power plants

    SciTech Connect

    Balat, M.; Balat, H.; Oz, C.

    2009-07-01

    The aim of this paper is to investigate the global contribution of carbon capture and storage technologies to mitigating climate change. Carbon capture and storage is a technology that comprises the separation of from carbon dioxide industrial- and energy-related sources, transport to a storage location (e.g., saline aquifers and depleted hydrocarbon fields), and long-term isolation from the atmosphere. The carbon dioxides emitted directly at the power stations are reduced by 80 to 90%. In contrast, the life cycle assessment shows substantially lower reductions of greenhouse gases in total (minus 65 to 79%).

  20. How the Carbon Emissions Were Estimated

    Energy Information Administration (EIA) (indexed site)

    dioxide emissions are the main component of greenhouse gas emissions caused by human activity. Carbon dioxide is emitted mostly as a byproduct of the combustion of fossil fuels...

  1. DOE's Gasoline/Diesel PM Split Study | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005deerfujita.pdf More Documents & Publications DOE's GasolineDiesel PM Split Study DOE's ...

  2. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  3. The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...

    OpenEI (Open Energy Information) [EERE & EIA]

    Outputs include: The tool outputs greenhouse gas emissions (including carbon dioxide, methane, nitrous oxide, carbon dioxide equivalent, and biogenic carbon dioxide) for each...

  4. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  5. Thermocouple split follower

    DOEpatents

    Howell, deceased, Louis J.

    1980-01-01

    Thermoelectric generator assembly accommodating differential thermal expansion between thermoelectric elements by means of a cylindrical split follower forming a slot and having internal spring loaded wedges that permit the split follower to open and close across the slot.

  6. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However

  7. Fuel Mix and Emissions Disclosure | Department of Energy

    Energy.gov [DOE] (indexed site)

    customers the fuel mix of its electricity production and the associated sulfur dioxide, nitrogen oxide, and carbon dioxide emissions emissions, expressed in pounds per 1000...

  8. Bisphosphine dioxides

    DOEpatents

    Moloy, Kenneth G.

    1990-01-01

    A process for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  9. Bisphosphine dioxides

    DOEpatents

    Moloy, K.G.

    1990-02-20

    A process is described for the production of organic bisphosphine dioxides from organic bisphosphonates. The organic bisphosphonate is reacted with a Grignard reagent to give relatively high yields of the organic bisphosphine dioxide.

  10. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    OpenEI (Open Energy Information) [EERE & EIA]

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  11. Hydrogen Production: Photoelectrochemical Water Splitting | Department...

    Energy Saver

    Photoelectrochemical Water Splitting Hydrogen Production: Photoelectrochemical Water Splitting In photoelectrochemical (PEC) water splitting, hydrogen is produced from water using ...

  12. Hydrogen Production: Thermochemical Water Splitting | Department...

    Energy Saver

    Processes Hydrogen Production: Thermochemical Water Splitting Hydrogen Production: Thermochemical Water Splitting Thermochemical water splitting uses high temperatures-from ...

  13. Split University | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: Split University Place: Zagreb, Croatia Sector: Hydro, Solar Product: Croatia-based electrical engineering faculty of Split University. Involved in developing small hydro and...

  14. Geographic patterns of carbon dioxide emissions from fossil-fuel burning, hydraulic cement production, and gas flaring on a one degree by one degree grid cell basis: 1950 to 1990

    SciTech Connect

    Brenkert, A.L.; Andres, R.J.; Marland, G.; Fung, I. |; Matthews, E. |

    1997-03-01

    Data sets of one degree latitude by one degree longitude carbon dioxide (CO{sub 2}) emissions in units of thousand metric tons of carbon (C) per year from anthropogenic sources have been produced for 1950, 1960, 1970, 1980 and 1990. Detailed geographic information on CO{sub 2} emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional and national annual estimates for 1950 through 1992 were published previously. Those national, annual CO{sub 2} emission estimates were based on statistics on fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption and trade data, using the methods of Marland and Rotty. The national annual estimates were combined with gridded one-degree data on political units and 1984 human populations to create the new gridded CO{sub 2} emission data sets. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mix is uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in emissions over time are apparent for most areas.

  15. Carbon dioxide power plant for total emission control and enhanced oil recovery. [Removal, storage, and use of CO/sub 2/

    SciTech Connect

    Horn, F L; Steinberg, M

    1981-08-01

    The design of a compact environmentally acceptable carbon dioxide diluted coal-oxygen fired power plant is described. The plant releases no combustion products to the atmosphere. The oxygen for combustion is separated in an air liquefaction plant and the effluent nitrogen is available for use in oil well production. Recycle carbon dioxide mixed with oxygen replaces the nitrogen for the combustion of coal in the burners. The carbon dioxide produced is used in enhanced oil recovery operations and injected into spent wells and excavated salt cavities for long-term storage. The recovery of CO/sub 2/ from a coal-burning power plant by this method appears to have the lowest energy expenditure and the lowest byproduct cost compared to alternative removal and recovery processes.

  16. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    OpenEI (Open Energy Information) [EERE & EIA]

    Outputs include: The tool outputs greenhouse gas emissions (carbon dioxide, methane, nitrous oxide, and carbon dioxide equivalent) for each facility as well as total...

  17. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook

    grasslands 34 Net carbon dioxide sequestration in U.S. urban trees, yard trimmings, and food scraps 35 Emissions of carbon dioxide from biofuelbioenergy use by sector and fuel

  18. Split image optical display

    DOEpatents

    Veligdan, James T.

    2007-05-29

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  19. Split image optical display

    DOEpatents

    Veligdan, James T.

    2005-05-31

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  20. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Maine

    SciTech Connect

    2008-10-01

    Analysis of the expected impacts of 1000 MW of wind power in Maine, including economic benefits, CO2 emissions reductions, and water conservation.

  1. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1000 Megawatts (MW) of New Wind Power in Arizona

    SciTech Connect

    2008-10-01

    Analysis of the expected impacts of 1000 MW of wind power in Arizona, including economic benefits, CO2 emissions reductions, and water conservation.

  2. Economic Benefits, Carbon Dioxide (CO2) Emissions Reduction, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Georgia (Fact Sheet)

    SciTech Connect

    Not Available

    2008-06-01

    The U.S. Department of Energy's Wind Powering America Program is committed to educating state-level policy makers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Georgia. We forecast the cumulative economic benefits from 1000 MW of development in Georgia to be $2.1 billion, annual CO2 reductions are estimated at 3.0 million tons, and annual water savings are 1,628 million gallons.

  3. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Arizona (Fact Sheet)

    SciTech Connect

    Not Available

    2008-10-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Arizona. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Arizona to be $1.15 billion, annual CO2 reductions are estimated at 2.0 million tons, and annual water savings are 818 million gallons.

  4. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in Maine (Fact Sheet)

    SciTech Connect

    Not Available

    2008-10-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in Maine. Although construction and operation of 1000 MW of wind power is a significant effort, six states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in Maine to be $1.3 billion, annual CO2 reductions are estimated at 2.8 million tons, and annual water savings are 1,387 million gallons.

  5. Economic Benefits, Carbon Dioxide (CO2) Emissions Reductions, and Water Conservation Benefits from 1,000 Megawatts (MW) of New Wind Power in North Carolina (Fact Sheet)

    SciTech Connect

    Not Available

    2009-03-01

    The U.S. Department of Energy?s Wind Powering America Program is committed to educating state-level policymakers and other stakeholders about the economic, CO2 emissions, and water conservation impacts of wind power. This analysis highlights the expected impacts of 1000 MW of wind power in North Carolina. Although construction and operation of 1000 MW of wind power is a significant effort, seven states have already reached the 1000-MW mark. We forecast the cumulative economic benefits from 1000 MW of development in North Carolina to be $1.1 billion, annual CO2 reductions are estimated at 2.9 million tons, and annual water savings are 1,558 million gallons.

  6. Nitrogen dioxide detection

    DOEpatents

    Sinha, Dipen N.; Agnew, Stephen F.; Christensen, William H.

    1993-01-01

    Method and apparatus for detecting the presence of gaseous nitrogen dioxide and determining the amount of gas which is present. Though polystyrene is normally an insulator, it becomes electrically conductive in the presence of nitrogen dioxide. Conductance or resistance of a polystyrene sensing element is related to the concentration of nitrogen dioxide at the sensing element.

  7. Copper clusters capture and convert carbon dioxide to make fuel...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The benefit of enhanced binding is that the new catalyst requires lower pressure and less energy to produce the same amount of methanol. Carbon dioxide emissions are an ongoing...

  8. Split ring containment attachment device

    DOEpatents

    Sammel, Alfred G.

    1996-01-01

    A containment attachment device 10 for operatively connecting a glovebag 200 to plastic sheeting 100 covering hazardous material. The device 10 includes an inner split ring member 20 connected on one end 22 to a middle ring member 30 wherein the free end 21 of the split ring member 20 is inserted through a slit 101 in the plastic sheeting 100 to captively engage a generally circular portion of the plastic sheeting 100. A collar potion 41 having an outer ring portion 42 is provided with fastening means 51 for securing the device 10 together wherein the glovebag 200 is operatively connected to the collar portion 41.

  9. Carbon Dioxide Utilization Summit

    Energy.gov [DOE]

    The 6th Carbon Dioxide Utilization Summit will be held in Newark, New Jersey, from Feb. 24–26, 2016. The conference will look at the benefits and challenges of carbon dioxide utilization. Advanced Algal Systems Program Manager Alison Goss Eng and Technology Manager Devinn Lambert will be in attendance. Dr. Goss Eng will be chairing a round table on Fuels and Chemicals during the Carbon Dioxide Utilization: From R&D to Commercialization discussion session.

  10. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book

    2 2010 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 211.9 211.9 20.4% Space Heating 87.4 10.2 6.7 0.3 17.3 5.6 50.5 160.7 15.5% Space Cooling 2.3 149.1 151.3 14.6% Ventilation 95.2 95.2 9.2% Refrigeration 69.1 69.1 6.7% Electronics 46.4 46.4 4.5% Water Heating 23.2 2.0 2.0 16.2 41.4 4.0% Computers 37.7 37.7 3.6% Cooking 9.5 4.1 13.6 1.3%

  11. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book

    3 2015 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 160.0 160.0 16.6% Space Heating 89.9 9.0 6.2 0.3 15.5 5.5 26.4 137.3 14.2% Space Cooling 1.9 80.0 81.9 8.5% Ventilation 85.0 85.0 8.8% Refrigeration 55.8 55.8 5.8% Electronics 49.9 49.9 5.2% Water Heating 25.5 2.0 2.0 14.3 41.8 4.3% Computers 30.0 30.0 3.1% Cooking 10.2 3.6 13.8 1.4%

  12. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book

    4 2025 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 171.2 171.2 16.1% Space Heating 89.4 7.7 6.3 0.4 14.3 5.5 25.7 135.0 12.7% Ventilation 94.4 94.4 8.9% Space Cooling 1.8 81.5 83.3 7.8% Electronics 63.8 63.8 6.0% Refrigeration 53.7 53.7 5.1% Computers 31.2 31.2 2.9% Water Heating 27.5 2.3 2.3 14.0 43.7 4.1% Cooking 11.0 3.5 14.5 1.4%

  13. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book

    5 2035 Commercial Buildings Energy End-Use Carbon Dioxide Emissions Splits, by Fuel Type (Million Metric Tons) (1) Natural Petroleum Gas Distil. Resid. LPG Oth(2) Total Coal Electricity (3) Total Percent Lighting 179.6 179.6 15.5% Space Heating 87.3 6.7 6.6 0.4 13.7 5.5 25.5 132.0 11.4% Ventilation 100.7 100.7 8.7% Space Cooling 1.7 84.1 85.8 7.4% Electronics 72.3 72.3 6.2% Refrigeration 55.6 55.6 4.8% Water Heating 28.8 2.5 2.5 13.3 44.7 3.9% Computers 33.6 33.6 2.9% Cooking 11.9 3.4 15.2 1.3%

  14. Cool covered sky-splitting spectrum-splitting FK

    SciTech Connect

    Mohedano, Rubén; Chaves, Julio; Falicoff, Waqidi; Hernandez, Maikel; Sorgato, Simone; Miñano, Juan C.; Benitez, Pablo; Buljan, Marina

    2014-09-26

    Placing a plane mirror between the primary lens and the receiver in a Fresnel Köhler (FK) concentrator gives birth to a quite different CPV system where all the high-tech components sit on a common plane, that of the primary lens panels. The idea enables not only a thinner device (a half of the original) but also a low cost 1-step manufacturing process for the optics, automatic alignment of primary and secondary lenses, and cell/wiring protection. The concept is also compatible with two different techniques to increase the module efficiency: spectrum splitting between a 3J and a BPC Silicon cell for better usage of Direct Normal Irradiance DNI, and sky splitting to harvest the energy of the diffuse radiation and higher energy production throughout the year. Simple calculations forecast the module would convert 45% of the DNI into electricity.

  15. H. R. 4177: A Bill to amend the Internal Revenue Code of 1986 to impose an excise tax on sulfur dioxide and nitrogen oxide emissions from utility plants. Introduced in the House of Representatives, One Hundredth First Congress, Second Session, March 5, 1990

    SciTech Connect

    Not Available

    1990-01-01

    The tax imposed would begin in 1991 in the amount of 15 cents per pound of sulfur dioxide released and 10 cents per pound nitrogen oxide, and would increase so that the tax in 1997 and thereafter would be 45 cents per pound of sulfur dioxide and 30 cents per pound of nitrogen oxide released. An inflation adjustment is provided for years after 1997. The tax is imposed on emissions which exceed the exemption level for each pollutant, and these levels are specified herein as pounds exempted per million Btu's of fuel burned. No tax is imposed on units less than 75 megawatts, or units providing less than one-third of the electricity produced to a utility power distribution system for sale.

  16. Method for dissolving plutonium dioxide

    DOEpatents

    Tallent, Othar K.

    1976-01-01

    A method for dissolving plutonium dioxide comprises adding silver ions to a nitric acid-hydrofluoric acid solution to significantly speed up dissolution of difficultly soluble plutonium dioxide.

  17. EA-225 Split Rock Energy LLC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5 Split Rock Energy LLC EA-225 Split Rock Energy LLC Order authorizing Split Rock Energy LLC to export electric energy to Canada. EA-225 Split Rock Energy LLC (34.81

  18. Fact #576: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy 6: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel Fact #576: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel The amount of carbon dioxide released into the atmosphere by a vehicle is primarily determined by the carbon content of the fuel. However, there is a small portion of the fuel that is not oxidized into carbon dioxide when the fuel is burned. The Environmental Protection Agency (EPA) has published information on carbon dioxide emissions from

  19. Call for emission limits heats debate on global warming

    SciTech Connect

    Singer, S.F.

    1997-08-01

    Emission limits on carbon dioxide is recommended by an Intergovernmental Panel in a discussion on global warming. (AIP) {copyright} {ital 1997 American Institute of Physics.}

  20. Recycling Carbon Dioxide to Make Plastics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Recycling Carbon Dioxide to Make Plastics Recycling Carbon Dioxide to Make Plastics May 20, 2013 - 1:31pm Addthis Novomer’s thermoplastic pellets incorporate waste CO2 into a variety of consumer products. Novomer's thermoplastic pellets incorporate waste CO2 into a variety of consumer products. Why is this important? By using CO2 that would otherwise be emitted to the atmosphere, the process has the potential to cut greenhouse gas emissions while simultaneously reducing petroleum

  1. Carbon dioxide removal process

    DOEpatents

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  2. Algebraic techniques for diagonalization of a split quaternion matrix in split quaternionic mechanics

    SciTech Connect

    Jiang, Tongsong; Jiang, Ziwu; Zhang, Zhaozhong

    2015-08-15

    In the study of the relation between complexified classical and non-Hermitian quantum mechanics, physicists found that there are links to quaternionic and split quaternionic mechanics, and this leads to the possibility of employing algebraic techniques of split quaternions to tackle some problems in complexified classical and quantum mechanics. This paper, by means of real representation of a split quaternion matrix, studies the problem of diagonalization of a split quaternion matrix and gives algebraic techniques for diagonalization of split quaternion matrices in split quaternionic mechanics.

  3. Quantum-splitting oxide-based phosphors and method of producing the same

    DOEpatents

    Setlur, Anant Achyut; Srivastava, Alok Mani

    2003-09-02

    Strontium, calcium, strontium calcium, strontium calcium magnesium, calcium magnesium aluminates, and strontium borates activated with Pr.sup.3+ exhibit characteristics of quantum-splitting phosphors under VUV excitation. A large emission peak at about 405 nm under VUV excitation is used conveniently to identify quantum-splitting phosphors. Improvements may be achieved with addition of fluorides or boric acid as a flux during the preparation of the phosphors. It is also possible to predict improvement in quantum efficiency by observing the ratio of emission intensities at about 480 nm and about 610 nm.

  4. Ductless Mini-Split Air Conditioners

    Energy.gov [DOE]

    Ductless mini-split air conditioners are a good choice if you want a zoned air conditioning system but have no ducts in your house.

  5. DOE's Gasoline/Diesel PM Split Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE's GasolineDiesel PM Split Study Eric M. Fujita, David E. Campbell, William P. Arnott, Barbara Zielinska and Judith C. Chow Division of Atmospheric Sciences Desert Research ...

  6. Splitting the Cycle the Right Way

    Energy.gov [DOE]

    The unique opposed-cylinder configuration of the TourEngine allows superior thermal management and efficient gas transfer compared to other split-cycle designs.

  7. Minimal Doubling and Point Splitting

    SciTech Connect

    Creutz, M.

    2010-06-14

    Minimally-doubled chiral fermions have the unusual property of a single local field creating two fermionic species. Spreading the field over hypercubes allows construction of combinations that isolate specific modes. Combining these fields into bilinears produces meson fields of specific quantum numbers. Minimally-doubled fermion actions present the possibility of fast simulations while maintaining one exact chiral symmetry. They do, however, introduce some peculiar aspects. An explicit breaking of hyper-cubic symmetry allows additional counter-terms to appear in the renormalization. While a single field creates two different species, spreading this field over nearby sites allows isolation of specific states and the construction of physical meson operators. Finally, lattice artifacts break isospin and give two of the three pseudoscalar mesons an additional contribution to their mass. Depending on the sign of this mass splitting, one can either have a traditional Goldstone pseudoscalar meson or a parity breaking Aoki-like phase.

  8. TEMPORAL SPECTRAL SHIFT AND POLARIZATION OF A BAND-SPLITTING SOLAR TYPE II RADIO BURST

    SciTech Connect

    Du, Guohui; Chen, Yao; Lv, Maoshui; Kong, Xiangliang; Feng, Shiwei; Guo, Fan; Li, Gang

    2014-10-01

    In many type II solar radio bursts, the fundamental and/or the harmonic branches of the bursts can split into two almost parallel bands with similar spectral shapes and frequency drifts. However, the mechanisms accounting for this intriguing phenomenon remain elusive. In this study, we report a special band-splitting type II event in which spectral features appear systematically earlier on the upper band (with higher frequencies) than on the lower band (with lower frequencies) by several seconds. Furthermore, the emissions carried by the splitting band are moderately polarized with the left-hand polarized signals stronger than the right-hand ones. The polarization degree varies in a range of 0.3 to 0.6. These novel observational findings provide important constraints on the underlying physical mechanisms of band-splitting of type II radio bursts.

  9. Precision aligned split V-block

    DOEpatents

    George, Irwin S.

    1984-01-01

    A precision aligned split V-block for holding a workpiece during a milling operation having an expandable frame for allowing various sized workpieces to be accommodated, is easily secured directly to the mill table and having key lugs in one base of the split V-block that assures constant alignment.

  10. Weekly Wrap-Up: Testing Wind Blades, Converting Carbon Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    captured carbon dioxide (CO2) emissions from industrial sources into useful products. ... in private cost-share - will seek to use CO2 emissions from industrial sources to create ...

  11. China's transportation energy consumption and CO2 emissions from a global perspective

    SciTech Connect

    Yin, Xiang; Chen, Wenying; Eom, Jiyong; Clarke, Leon E.; Kim, Son H.; Patel, Pralit L.; Yu, Sha; Kyle, G. Page

    2015-07-01

    ABSTRACT Rapidly growing energy demand from China's transportation sector in the last two decades have raised concerns over national energy security, local air pollution, and carbon dioxide (CO2) emissions, and there is broad consensus that China's transportation sector will continue to grow in the coming decades. This paper explores the future development of China's transportation sector in terms of service demands, final energy consumption, and CO2 emissions, and their interactions with global climate policy. This study develops a detailed China transportation energy model that is nested in an integrated assessment model—Global Change Assessment Model (GCAM)—to evaluate the long-term energy consumption and CO2 emissions of China's transportation sector from a global perspective. The analysis suggests that, without major policy intervention, future transportation energy consumption and CO2 emissions will continue to rapidly increase and the transportation sector will remain heavily reliant on fossil fuels. Although carbon price policies may significantly reduce the sector's energy consumption and CO2 emissions, the associated changes in service demands and modal split will be modest, particularly in the passenger transport sector. The analysis also suggests that it is more difficult to decarbonize the transportation sector than other sectors of the economy, primarily owing to its heavy reliance on petroleum products.

  12. METHOD OF SINTERING URANIUM DIOXIDE

    DOEpatents

    Henderson, C.M.; Stavrolakis, J.A.

    1963-04-30

    This patent relates to a method of sintering uranium dioxide. Uranium dioxide bodies are heated to above 1200 nif- C in hydrogen, sintered in steam, and then cooled in hydrogen. (AEC)

  13. Innovative solar thermochemical water splitting.

    SciTech Connect

    Hogan, Roy E. Jr.; Siegel, Nathan P.; Evans, Lindsey R.; Moss, Timothy A.; Stuecker, John Nicholas; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D.; James, Darryl L.

    2008-02-01

    Sandia National Laboratories (SNL) is evaluating the potential of an innovative approach for splitting water into hydrogen and oxygen using two-step thermochemical cycles. Thermochemical cycles are heat engines that utilize high-temperature heat to produce chemical work. Like their mechanical work-producing counterparts, their efficiency depends on operating temperature and on the irreversibility of their internal processes. With this in mind, we have invented innovative design concepts for two-step solar-driven thermochemical heat engines based on iron oxide and iron oxide mixed with other metal oxides (ferrites). The design concepts utilize two sets of moving beds of ferrite reactant material in close proximity and moving in opposite directions to overcome a major impediment to achieving high efficiency--thermal recuperation between solids in efficient counter-current arrangements. They also provide inherent separation of the product hydrogen and oxygen and are an excellent match with high-concentration solar flux. However, they also impose unique requirements on the ferrite reactants and materials of construction as well as an understanding of the chemical and cycle thermodynamics. In this report the Counter-Rotating-Ring Receiver/Reactor/Recuperator (CR5) solar thermochemical heat engine and its basic operating principals are described. Preliminary thermal efficiency estimates are presented and discussed. Our ferrite reactant material development activities, thermodynamic studies, test results, and prototype hardware development are also presented.

  14. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide: ...

  15. Carbon dioxide sensor

    DOEpatents

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  16. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect

    K. K. Bloomfield; J. N. Moore

    1999-10-01

    Emission of �greenhouse gases� into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize �green power.� Geothermal power is classed as �green power� and has lower emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  17. Geothermal Electrical Production CO2 Emissions Study

    SciTech Connect

    Bloomfield, Kevin Kit; Moore, J. N.

    1999-10-01

    Emission of “greenhouse gases” into the environment has become an increasing concern. Deregulation of the electrical market will allow consumers to select power suppliers that utilize “green power.” Geothermal power is classed as “green power” and has power emissions of carbon dioxide per kilowatt-hour of electricity than even the cleanest of fossil fuels, natural gas. However, previously published estimates of carbon dioxide emissions are relatively old and need revision. This study estimates that the average carbon dioxide emissions from geothermal and fossil fuel power plants are: geothermal 0.18 , coal 2.13, petroleum 1.56 , and natural gas 1.03 pounds of carbon dioxide per kilowatt-hour respectively.

  18. HydroGEN Advanced Water Splitting Materials Consortium | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy HydroGEN Advanced Water Splitting Materials Consortium HydroGEN Advanced Water Splitting Materials Consortium Graphic shows icons for the three HydroGEN technologies: photoelectrochemical water splitting, solar thermochemical water splitting, and low- and high-temperature advanced electrolysis. The HydroGEN Advanced Water Splitting Materials consortium aims to accelerate the research, development, and deployment of advanced water splitting technologies for clean, sustainable hydrogen

  19. Strategies to Overcome Split Incentive Tenant / Landlord Issues...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Strategies to Overcome Split Incentive Tenant Landlord Issues Better Buildings Residential Network Multifamily and Low-Income Peer Exchange Call: Strategies to Overcome Split ...

  20. Two Electron Holes in Hematite Facilitate Water Splitting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    A molecular glance at water splitting. Hematite could play an important role in the generation of hydrogen by solar-powered water splitting, resulting in a truly...

  1. Two Electron Holes in Hematite Facilitate Water Splitting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Two Electron Holes in Hematite Facilitate Water Splitting Two Electron Holes in Hematite Facilitate Water Splitting Print Wednesday, 26 September 2012 00:00 Hydrogen is an...

  2. Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions...

    Office of Science (SC)

    Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ... Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ...

  3. Extremely stable bare hematite photoanode for solar water splitting...

    Office of Scientific and Technical Information (OSTI)

    Extremely stable bare hematite photoanode for solar water splitting Prev Next Title: Extremely stable bare hematite photoanode for solar water splitting Authors: Dias, Paula ; ...

  4. Strategies to Address Split Incentives in Multifamily Buildings...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    to Address Split Incentives in Multifamily Buildings Strategies to Address Split Incentives in Multifamily Buildings Better Buildings Neighborhood Program Multifamily Low-Income ...

  5. Advanced Water Splitting Materials Workshop | Department of Energy

    Energy Saver

    Water Splitting Materials Workshop Advanced Water Splitting Materials Workshop The U.S. Department of Energy's (DOE's) Lawrence Berkeley National Laboratory and Stanford University ...

  6. Fossil analysis pushes back human split from other primates by...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Fossil analysis pushes back human split from other primates Fossil analysis pushes back human split from other primates by two million years C. abyssinicus revealed answers about ...

  7. Quantum chaos in systems with ray splitting

    SciTech Connect

    Couchman, L. (Acoustics Division, Naval Research Laboratory, Washington, D.C. 20375 (United States)); Ott, E.; Antonsen, T.M. Jr. (Laboratory for Plasma Research, Department of Electrical Engineering, Department of Physics, University of Maryland, College Park, Maryland 20742 (United States))

    1992-11-15

    We consider wave systems in which rays split on reflection from sharp boundaries. Examples include the Schroedinger equation with the potential changing discontinuously across a surface, electromagnetic waves in a region with a discontinuous dielectric constant, elastic media with a clamped or free boundary, etc. By introducing a Monte Carlo treatment of the rays, it is possible to define chaotic rays via the standard Lyapunov number criterion. Numerical implementation of the Monte Carlo ray technique is carried out for the example of elastic media, and is utilized to investigate the extent to which these systems are globally ergodic. It is suggested that results from previous extensive work on quantum chaos without ray splitting can be extended to these ray splitting problems. In particular, we indicate a generalization of the Gutzwiller trace formula to cover ray splitting.

  8. Excitonic exchange splitting in bulk semiconductors

    SciTech Connect

    Fu, H.; Wang, L.; Zunger, A.

    1999-02-01

    We present an approach to calculate the excitonic fine-structure splittings due to electron-hole short-range exchange interactions using the local-density approximation pseudopotential method, and apply it to bulk semiconductors CdSe, InP, GaAs, and InAs. Comparing with previous theoretical results, the current calculated splittings agree well with experiments. Furthermore, we provide an approximate relationship between the short-range exchange splitting and the exciton Bohr radius, which can be used to estimate the exchange splitting for other materials. The current calculation indicates that a commonly used formula for exchange splitting in quantum dot is not valid. Finally, we find a very large pressure dependence of the exchange splitting: a factor of 4.5 increase as the lattice constant changes by 3.5{percent}. This increase is mainly due to the decrease of the Bohr radius via the change of electron effective mass. {copyright} {ital 1999} {ital The American Physical Society}

  9. Catalytic conversion of sulfur dioxide and trioxide

    SciTech Connect

    Solov'eva, E.L.; Shenfel'd, B.E.; Kuznetsova, S.M.; Khludenev, A.G.

    1987-11-10

    The reclamation and utilization of sulfur-containing wastes from the flue gas of fossil-fuel power plants and the subsequent reduction in sulfur emission is addressed in this paper. The authors approach this problem from the standpoint of the catalytic oxidation of sulfur dioxide on solid poison-resistant catalysts with subsequent sorption of the sulfur trioxide and its incorporation into the manufacture of sulfuric acid. The catalyst they propose is a polymetallic dust-like waste from the copper-smelting industry comprised mainly of iron and copper oxides. Experiments with this catalyst were carried out using multifactorial experiment planning.

  10. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of vehicles that use internal combustion engines. These vehicles can run on gasoline, diesel, biofuels, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs)

  11. Power Plant Emission Reductions Using a Generation Performance Standard

    Reports and Publications

    2001-01-01

    In an earlier analysis completed in response to a request received from Representative David McIntosh, Chairman of the Subcommittee on National Economic Growth, Natural Resources, and Regulatory Affairs, the Energy Information Administration analyzed the impacts of power sector caps on nitrogen oxides, sulfur dioxide, and carbon dioxide emissions, assuming a policy instrument patterned after the sulfur dioxide allowance program created in the Clean Air Act Amendments of 1990. This paper compares the results of that work with the results of an analysis that assumes the use of a dynamic generation performance standard as an instrument for reducing carbon dioxide emissions.

  12. AN ARECIBO SURVEY FOR ZEEMAN SPLITTING IN OH MEGAMASER GALAXIES

    SciTech Connect

    McBride, James; Heiles, Carl E-mail: heiles@astro.berkeley.edu

    2013-01-20

    We present the results of a comprehensive survey using the Arecibo Observatory for Zeeman splitting of OH lines in OH megamasers (OHMs). A total of 77 sources were observed with the Arecibo telescope. Of these, maser emission could not be detected for eight sources, and two sources were only ambiguously detected. Another 27 sources were detected at low signal-to-noise ratios or with interference that prevented placing any useful limits on the presence of magnetic fields. In 26 sources, it was possible to place upper limits on the magnitude of magnetic fields, typically between 10 and 30 mG. For 14 sources, the Stokes V spectra exhibit features consistent with Zeeman splitting. Eleven of these 14 are new detections, and the remaining three are re-detections of Stokes V detections in Robishaw et al. Among confident new detections, we derive magnetic fields associated with maser regions with magnitudes ranging from 6.1 to 27.6 mG. The distribution of magnetic field strengths suggests the magnetic fields in OH masing clouds in OHMs are larger than those in Galactic OH masers. The results are consistent with magnetic fields playing a dynamically important role in OH masing clouds in OHMs.

  13. Process for sequestering carbon dioxide and sulfur dioxide

    DOEpatents

    Maroto-Valer, M. Mercedes (State College, PA); Zhang, Yinzhi (State College, PA); Kuchta, Matthew E. (State College, PA); Andresen, John M. (State College, PA); Fauth, Dan J. (Pittsburgh, PA)

    2009-10-20

    A process for sequestering carbon dioxide, which includes reacting a silicate based material with an acid to form a suspension, and combining the suspension with carbon dioxide to create active carbonation of the silicate-based material, and thereafter producing a metal salt, silica and regenerating the acid in the liquid phase of the suspension.

  14. DOE's Gasoline/Diesel PM Split Study

    Office of Energy Efficiency and Renewable Energy (EERE)

    2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: National Renewable Energy Laboratory

  15. Advanced Water Splitting Materials Workshop Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4 Advanced Water Splitting Materials Workshop Agenda Thursday, April 14, 2016 Room 8:00 am Check-in Outside Clubhouse Ballroom Renewable H 2 Production and the Advanced Water Splitting EMN 8:30 am Welcome and Mission Overview, Eric Miller, DOE Clubhouse Ballroom 8:40 am The DOE Hydrogen and Fuel Cells Program, Sunita Satyapal, DOE 8:55 am Motivational Talk on Renewable Fuels: Former Acting Under Secretary of Energy, Arun Majumdar, Stanford University 9:25 am Motivational Talk on the Energy

  16. Carbon dioxide and climate

    SciTech Connect

    Not Available

    1990-10-01

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  17. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate ...

  18. Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions...

    OpenEI (Open Energy Information) [EERE & EIA]

    Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Jump to: navigation, search Geothermal Lab Call Projects for Supercritical Carbon Dioxide Reservoir Rock...

  19. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  20. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one year of ...

  1. Uranium dioxide electrolysis

    DOEpatents

    Willit, James L.; Ackerman, John P.; Williamson, Mark A.

    2009-12-29

    This is a single stage process for treating spent nuclear fuel from light water reactors. The spent nuclear fuel, uranium oxide, UO.sub.2, is added to a solution of UCl.sub.4 dissolved in molten LiCl. A carbon anode and a metallic cathode is positioned in the molten salt bath. A power source is connected to the electrodes and a voltage greater than or equal to 1.3 volts is applied to the bath. At the anode, the carbon is oxidized to form carbon dioxide and uranium chloride. At the cathode, uranium is electroplated. The uranium chloride at the cathode reacts with more uranium oxide to continue the reaction. The process may also be used with other transuranic oxides and rare earth metal oxides.

  2. Splitting of magnetic dipole modes in anisotropic TiO 2 micro-spheres: Splitting of magnetic dipole modes in anisotropic TiO 2 micro-spheres

    DOE PAGES [OSTI]

    Khromova, Irina; Kužel, Petr; Brener, Igal; Reno, John L.; Chung Seu, U-Chan; Elissalde, Catherine; Maglione, Mario; Mounaix, Patrick; Mitrofanov, Oleg

    2016-06-27

    Monocrystalline titanium dioxide (TiO2) micro-spheres support two orthogonal magnetic dipole modes at terahertz (THz) frequencies due to strong dielectric anisotropy. For the first time, we experimentally detected the splitting of the first Mie mode in spheres of radii inline imagem through near-field time-domain THz spectroscopy. By fitting the Fano lineshape model to the experimentally obtained spectra of the electric field detected by the sub-wavelength aperture probe, we found that the magnetic dipole resonances in TiO2 spheres have narrow linewidths of only tens of gigahertz. Lastly, anisotropic TiO2 micro-resonators can be used to enhance the interplay of magnetic and electric dipolemore » resonances in the emerging THz all-dielectric metamaterial technology.« less

  3. A Novel Split-Cycle Engine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Splitting the Cycle the Right Way Splitting the Cycle the Right Way Improving Diesel Engine Sweet-spot Efficiency and Adapting it to Improve Duty-cycle MPG - plus Increasing ...

  4. Ductless Mini-Split Air Conditioners | Department of Energy

    Office of Environmental Management (EM)

    Mini-Split Air Conditioners A ductless mini-split air conditioner is one solution to cooling part of a house. | Photo courtesy of iStockphotoLUke1138. A ductless...

  5. Ductless, Mini-Split Heat Pumps | Department of Energy

    Energy.gov [DOE] (indexed site)

    remodel and your home does not have heating and cooling ducts, a ductless mini-split heat pump may be a cost-effective, energy-efficient choice. Ductless, mini-split-system heat...

  6. Ductless, Mini-Split Heat Pumps | Department of Energy

    Energy Saver

    Heat Pump Systems Ductless, Mini-Split Heat Pumps Ductless, Mini-Split Heat Pumps ... Learn More Heat pump systems Air-source heat pumps Geothermal heat pumps Absorption heat ...

  7. Heating and Cooling with Mini Splits in the Northeast

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    buildingscience.com Heating and Cooling with Mini Splits in the Northeast Kohta Ueno October 23, 2014 2014 BA Webinar Mini Splits in Northeast 2 © buildingscience.com Background 2014 BA Webinar Mini Splits in Northeast 3 © buildingscience.com Overview  Transformations, Inc. currently building net-zero homes in Massachusetts  Mini split heat pumps (MSHPs) part of builder's strategy: tradeoff package  Single point of heating/ cooling on each floor  BA study of temperatures throughout

  8. Reducing carbon dioxide to products

    DOEpatents

    Cole, Emily Barton; Sivasankar, Narayanappa; Parajuli, Rishi; Keets, Kate A

    2014-09-30

    A method reducing carbon dioxide to one or more products may include steps (A) to (C). Step (A) may bubble said carbon dioxide into a solution of an electrolyte and a catalyst in a divided electrochemical cell. The divided electrochemical cell may include an anode in a first cell compartment and a cathode in a second cell compartment. The cathode may reduce said carbon dioxide into said products. Step (B) may adjust one or more of (a) a cathode material, (b) a surface morphology of said cathode, (c) said electrolyte, (d) a manner in which said carbon dioxide is bubbled, (e), a pH level of said solution, and (f) an electrical potential of said divided electrochemical cell, to vary at least one of (i) which of said products is produced and (ii) a faradaic yield of said products. Step (C) may separate said products from said solution.

  9. Advanced Water Splitting Materials EMN Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Advanced Water Splitting Materials EMN Workshop Stanford, CA April 14 th , 2016 Dr. Eric Miller Program Manager Hydrogen Production & Delivery Fuel Cell Technologies Office | 2 Importance of Renewable Hydrogen The great benefits & challenges are recognized world-wide * Hydrogen is a flexible energy carrier that can be produced from any regionally prevalent primary energy source. Moreover, it can be effectively transformed into any form of energy for diverse end-use applications. *

  10. Recuperative supercritical carbon dioxide cycle

    SciTech Connect

    Sonwane, Chandrashekhar; Sprouse, Kenneth M; Subbaraman, Ganesan; O'Connor, George M; Johnson, Gregory A

    2014-11-18

    A power plant includes a closed loop, supercritical carbon dioxide system (CLS-CO.sub.2 system). The CLS-CO.sub.2 system includes a turbine-generator and a high temperature recuperator (HTR) that is arranged to receive expanded carbon dioxide from the turbine-generator. The HTR includes a plurality of heat exchangers that define respective heat exchange areas. At least two of the heat exchangers have different heat exchange areas.

  11. METHOD OF MAKING PLUTONIUM DIOXIDE

    DOEpatents

    Garner, C.S.

    1959-01-13

    A process is presented For converting both trivalent and tetravalent plutonium oxalate to substantially pure plutonium dioxide. The plutonium oxalate is carefully dried in the temperature range of 130 to300DEC by raising the temperature gnadually throughout this range. The temperature is then raised to 600 C in the period of about 0.3 of an hour and held at this level for about the same length of time to obtain the plutonium dioxide.

  12. Researchers Uncover Copper's Potential for Reducing CO2 Emissions...

    Energy.gov [DOE] (indexed site)

    When used as a part of a promising coal combustion technology known as chemical looping, copper can help economically remove carbon dioxide (CO2) from fossil fuel emissions. In ...

  13. Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.

    SciTech Connect

    Allendorf, Mark D.; Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

    2009-01-01

    The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is

  14. Air-pollutant emissions from kerosene space heaters

    SciTech Connect

    Leaderer, B.P.

    1982-12-10

    Air pollutant emissions from portable convective and radiant kerosene space heaters were measured in an environmental chamber. Emission factors for nitrogen oxides, sulfur dioxide, carbon monoxide, carbon dioxide, and oxygen depletion are presented. The data suggest that the use of such heaters in residences can result in exposures to air pollutants in excess of ambient air quality standards and in some cases in excess of occupational health standards.

  15. Emissions of greenhouse gases in the United States 1995

    SciTech Connect

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  16. Beneficial Use of Carbon Dioxide in Precast Concrete Production

    SciTech Connect

    Shao, Yixin

    2014-06-26

    The feasibility of using carbon dioxide as feedstock in precast concrete production is studied. Carbon dioxide reacts with calcium compounds in concrete, producing solid calcium carbonates in binding matrix. Two typical precast products are examined for their capacity to store carbon dioxide during the production. They are concrete blocks and fiber-cement panels. The two products are currently mass produced and cured by steam. Carbon dioxide can be used to replace steam in curing process to accelerate early strength, improve the long-term durability and reduce energy and emission. For a reaction within a 24-hour process window, the theoretical maximum possible carbon uptake in concrete is found to be 29% based on cement mass in the product. To reach the maximum uptake, a special process is developed to promote the reaction efficiency to 60-80% in 4-hour carbon dioxide curing and improve the resistance to freeze-thaw cycling and sulfate ion attack. The process is also optimized to meet the project target of $10/tCO2 in carbon utilization. By the use of self-concentrating absorption technology, high purity CO2 can be produced at a price below $40/t. With low cost CO2 capture and utilization technologies, it is feasible to establish a network for carbon capture and utilization at the vicinity of carbon sources. If all block produces and panel producers in United States could adopt carbon dioxide process in their production in place of steam, carbon utilization in these two markets alone could consume more than 2 Mt CO2/year. This capture and utilization process can be extended to more precast products and will continue for years to come.

  17. RESULTS FROM THE U.S. DOE 2006 SAVE ENERGY NOW ASSESSMENT INITIATIVE: DOE's Partnership with U.S. Industry to Reduce Energy Consumption, Energy Costs, and Carbon Dioxide Emissions

    SciTech Connect

    Wright, Anthony L; Martin, Michaela A; Gemmer, Bob; Scheihing, Paul; Quinn, James

    2007-09-01

    --those that consume a total of 1 trillion British thermal units (Btu) or more annually. The approximately 6800 U.S. facilities that fall into this category collectively account for about 53% of all energy consumed by industry in the United States. The 2006 Save Energy Now energy assessments departed from earlier DOE plant assessments by concentrating solely on steam and process heating systems, which are estimated to account for approximately 74% of all natural gas use for manufacturing. The assessments also integrated a strong training component designed to teach industrial plant personnel how to use DOE's steam or process heating opportunity assessment software tools. This approach had the advantages of promoting strong buy-in of plant personnel for the assessment and its outcomes and preparing them better to independently replicate the assessment process at the company's other facilities. The Save Energy Now initiative also included provisions to help plants that applied for but did not qualify for assessments (based on the 1 trillion Btu criterion). Services offered to these plants included (1) an assessment by one of DOE's 26 university-based Industrial Assessment Centers (IACs), (2) a telephone consultation with a systems expert at the DOE's Energy Efficiency and Renewable Energy Information Center, or (3) other technical materials and services available through ITP (e.g., the Save Energy Now CD). By the end of 2006, DOE had completed all 200 of the promised assessments, identifying potential natural gas savings of more than 50 trillion Btu and energy cost savings of about $500 million. These savings, if fully implemented, could reduce CO2 emissions by 4.04 million metric tons annually. These results, along with the fact that a large percentage of U.S. energy is used by a relatively small number of very large plants, clearly suggest that assessments are an expedient and cost-effective way to significantly affect large amounts of energy use. Building on the success of

  18. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book

    6 2009 Methane Emissions for U.S. Commercial Buildings Energy Production, by Fuel Type (1) Fuel Type Petroleum 0.5 Natural Gas 26.8 Coal 0.3 Wood 0.4 Electricity (2) 50.5 Total 78.5 Note(s): Source(s): MMT CO2 Equivalent 1) Sources of emissions include oil and gas production, processing, and distribution; coal mining; and utility and site combustion. Carbon Dioxide equivalent units are calculated by converting methane emissions to carbon dioxide emissions (methane's global warming potential is

  19. Splitting of magnetic dipole modes in anisotropic TiO2 micro-spheres

    DOE PAGES [OSTI]

    Khromova, Irina; Kuzel, Petr; Brener, Igal; Reno, John L.; Chung Seu, U-Chan; Elissalde, Catherine; Maglione, Mario; Mounaix, Patrick; Mitrofanov, Oleg

    2016-06-27

    Monocrystalline titanium dioxide (TiO2) micro-spheres support two orthogonal magnetic dipole modes at terahertz (THz) frequencies due to strong dielectric anisotropy. For the first time, we experimentally detected the splitting of the first Mie mode in spheres of radii inline imagem through near-field time-domain THz spectroscopy. By fitting the Fano lineshape model to the experimentally obtained spectra of the electric field detected by the sub-wavelength aperture probe, we found that the magnetic dipole resonances in TiO2 spheres have narrow linewidths of only tens of gigahertz. Lastly, anisotropic TiO2 micro-resonators can be used to enhance the interplay of magnetic and electric dipolemore » resonances in the emerging THz all-dielectric metamaterial technology.« less

  20. Splitting of the Pygmy Dipole Resonance

    SciTech Connect

    Endres, J.; Zilges, A.; Butler, P.; Herzberg, R.-D.; Scheck, M.; Harakeh, M. N.; Harissopulos, S.; Lagoyannis, A.; Kruecken, R.; Ring, P.; Litvinova, E.; Pietralla, N.; Ponomarev, V. Yu.; Sonnabend, K.; Popescu, L.; Savran, D.; Stoica, V. I.; Woertche, H. J.

    2011-10-28

    In recent years investigations have been made to study the electric Pygmy Dipole Resonance (PDR) systematically, mainly in semi-magic nuclei. For this purpose the well understood high resolution ({gamma},{gamma}') photon scattering method is used. In complementary ({alpha},{alpha}'{gamma}) coincidence experiments at E{sub {alpha}} = 136 MeV a similar {gamma}-energy resolution and a high selectivity to E1 transitions can be obtained at the Big-Bite Spectrometer (BBS) at KVI, Groningen. In comparison to the ({gamma},{gamma}') method a structural splitting of the PDR is observed in the N = 82 nuclei {sup 138}Ba and {sup 140}Ce and in the Z = 50 nucleus {sup 124}Sn. The low energy part is excited in ({gamma},{gamma}') as well as in ({alpha},{alpha}'{gamma}) while the high energy part is observed in ({gamma},{gamma}') only. The experimental results together with theoretical QPM and RQTBA calculations on {sup 124}Sn which are able to reproduce the splitting of the PDR qualitatively are presented. The low-lying group of J{sup {pi}} = 1{sup -} states seem to represent the more isoscalar neutron-skin oscillation of the PDR while the energetically higher-lying states seemingly belong to the transitional region between the PDR and the isovector Giant Dipole Resonance (IVGDR).

  1. Flow Split Venturi, Axially-Rotated Valve

    DOEpatents

    Walrath, David E.; Lindberg, William R.; Burgess, Robert K.; LaBelle, James

    2000-02-22

    The present invention provides an axially-rotated valve which permits increased flow rates and lower pressure drop (characterized by a lower loss coefficient) by using an axial eccentric split venturi with two portions where at least one portion is rotatable with respect to the other portion. The axially-rotated valve typically may be designed to avoid flow separation and/or cavitation at full flow under a variety of conditions. Similarly, the valve is designed, in some embodiments, to produce streamlined flow within the valve. An axially aligned outlet may also increase the flow efficiency. A typical cross section of the eccentric split venturi may be non-axisymmetric such as a semicircular cross section which may assist in both throttling capabilities and in maximum flow capacity using the design of the present invention. Such a design can include applications for freeze resistant axially-rotated valves and may be fully-opened and fully-closed in one-half of a complete rotation. An internal wide radius elbow typically connected to a rotatable portion of the eccentric venturi may assist in directing flow with lower friction losses. A valve actuator may actuate in an axial manner yet be uniquely located outside of the axial flow path to further reduce friction losses. A seal may be used between the two portions that may include a peripheral and diametrical seal in the same plane. A seal separator may increase the useful life of the seal between the fixed and rotatable portions.

  2. Split Venturi, Axially-Rotated Valve

    DOEpatents

    Walrath, David E.; Lindberg, William R.; Burgess, Robert K.

    2000-08-29

    The present invention provides an axially-rotated valve which permits increased flow rates and lower pressure drop (characterized by a lower loss coefficient) by using an axial eccentric split venturi with two portions where at least one portion is rotatable with respect to the other portion. The axially-rotated valve typically may be designed to avoid flow separation and/or cavitation at full flow under a variety of conditions. Similarly, the valve is designed, in some embodiments, to produce streamlined flow within the valve. A typical cross section of the eccentric split venturi may be non-axisymmetric such as a semicircular cross section which may assist in both throttling capabilities and in maximum flow capacity using the design of the present invention. Such a design can include applications for freeze resistant axially-rotated valves and may be fully-opened and fully-closed in one-half of a complete rotation. An internal wide radius elbow typically connected to a rotatable portion of the eccentric venturi may assist in directing flow with lower friction losses. A valve actuator may actuate in an axial manner yet be uniquely located outside of the axial flow path to further reduce friction losses. A seal may be used between the two portions that may include a peripheral and diametrical seal in the same plane.

  3. SEPARATING PROTOACTINIUM WITH MANGANESE DIOXIDE

    DOEpatents

    Seaborg, G.T.; Gofman, J.W.; Stoughton, R.W.

    1958-04-22

    The preparation of U/sup 235/ and an improved method for isolating Pa/ sup 233/ from foreign products present in neutronirradiated thorium is described. The method comprises forming a solution of neutron-irradiated thorium together with a manganous salt, then adding potassium permanganate to precipitate the manganese as manganese dioxide whereby protoactinium is carried down with the nnanganese dioxide dissolving the precipitate, adding a soluble zirconium salt, and adding phosphate ion to precipitate zirconium phosphate whereby protoactinium is then carried down with the zirconium phosphate to effect a further concentration.

  4. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    SciTech Connect

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  5. White Papers on Materials for Photoelectrochemical Water Splitting

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Revision: October 2013 White Papers on Materials for Photoelectrochemical Water Splitting CONTENTS III-V Semiconductor Systems for High-Efficiency Solar Water Splitting Applications Todd Deutsch, Heli Wang, Zhebo Chen, Shane Ardo, Shu Hu, Mahendra Sunkara, Dan Esposito, Yat Li, Shannon Boettcher I-III-VI 2 Copper Chalcopyrites for Photoelectrochemical Water Splitting Jess Kaneshiro, Todd Deutsch, Nicolas Gaillard, Zhebo Chen, Alan Kleiman-Shwarsctein, Feng Zhu, Michael Weir The Viability of

  6. Enforcement Policy: Split-System Central Air Conditioners Without HSVC |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Split-System Central Air Conditioners Without HSVC Enforcement Policy: Split-System Central Air Conditioners Without HSVC December 16, 2015 DOE issued an enforcement policy that it would begin investigating the methods manufacturers are using to rate split-system central air conditioners that do not have a highest sales volume combination (HSVC) to test as required by the applicable regulations and that it would assess penalties for units manufactured after February 1,

  7. Learning How Nature Uses Sunlight to Split Water

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mn4Ca Structure. (click on image for diagram portraying the water-splitting catalytic cycle) Scientific Highlight LBNL Press Release Physical Biosciences, LBNL 30 November 2006 Learning How Nature Splits Water (Condensed by Brad Plummer from a press release issued by Lawrence Berkeley National Laboratory) Billions of years ago, primitive bacteria developed a way to harness sunlight to split water molecules into protons, electrons and oxygen-the cornerstone of photosynthesis. Now, a team of

  8. Synthesis and characterization of ferrite materials for thermochemical CO2 splitting using concentrated solar energy.

    SciTech Connect

    Stechel, Ellen Beth; Ambrosini, Andrea; Coker, Eric Nicholas; Rodriguez, Mark Andrew; Miller, James Edward; Evans, Lindsey R.; Livers, Stephanie

    2010-07-01

    The Sunshine to Petrol effort at Sandia aims to convert carbon dioxide and water to precursors for liquid hydrocarbon fuels using concentrated solar power. Significant advances have been made in the field of solar thermochemical CO{sub 2}-splitting technologies utilizing yttria-stabilized zirconia (YSZ)-supported ferrite composites. Conceptually, such materials work via the basic redox reactions: Fe{sub 3}O{sub 4} {yields} 3FeO + 0.5O{sub 2} (Thermal reduction, >1350 C) and 3FeO + CO{sub 2} {yields} Fe{sub 3}O{sub 4} + CO (CO{sub 2}-splitting oxidation, <1200 C). There has been limited fundamental characterization of the ferrite-based materials at the high temperatures and conditions present in these cycles. A systematic study of these composites is underway in an effort to begin to elucidate microstructure, structure-property relationships, and the role of the support on redox behavior under high-temperature reducing and oxidizing environments. In this paper the synthesis, structural characterization (including scanning electron microscopy and room temperature and in-situ x-ray diffraction), and thermogravimetric analysis of YSZ-supported ferrites will be reported.

  9. Synthesis and characterization of metal oxide materials for thermochemical CO2 splitting using concentrated solar energy.

    SciTech Connect

    Stechel, Ellen Beth; Ambrosini, Andrea; Coker, Eric Nicholas; Rodriguez, Mark Andrew; Miller, James Edward; Evans, Lindsey R.; Livers, Stephanie

    2010-07-01

    The Sunshine to Petrol effort at Sandia aims to convert carbon dioxide and water to precursors for liquid hydrocarbon fuels using concentrated solar power. Significant advances have been made in the field of solar thermochemical CO{sub 2}-splitting technologies utilizing yttria-stabilized zirconia (YSZ)-supported ferrite composites. Conceptually, such materials work via the basic redox reactions: Fe{sub 3}O{sub 4} {yields} 3FeO + 0.5O{sub 2} (Thermal reduction, >1350 C) and 3FeO + CO{sub 2} {yields} Fe{sub 3}O{sub 4} + CO (CO{sub 2}-splitting oxidation, <1200 C). There has been limited fundamental characterization of the ferrite-based materials at the high temperatures and conditions present in these cycles. A systematic study of these composites is underway in an effort to begin to elucidate microstructure, structure-property relationships, and the role of the support on redox behavior under high-temperature reducing and oxidizing environments. In this paper the synthesis, structural characterization (including scanning electron microscopy and room temperature and in-situ x-ray diffraction), and thermogravimetric analysis of YSZ-supported ferrites will be reported.

  10. Enforcement Policy Statement: Split-System Central Air Conditioners...

    Energy Saver

    Split-System Central Air Conditioners Without HSVC December 16, 2015 In the November 9, 2015 central air conditioner test procedure supplemental notice of proposed rulemaking (80 ...

  11. Two Electron Holes in Hematite Facilitate Water Splitting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Two Electron Holes in Hematite Facilitate Water Splitting Print Hydrogen is an attractive form of fuel because its only by-product is nonpolluting water vapor. The problem,...

  12. Strategies to Overcome Split Incentive Tenant / Landlord Issues

    Energy.gov [DOE]

    Better Buildings Residential Network Multifamily and Low-Income Peer Exchange Call: Strategies to Overcome Split Incentive Tenant / Landlord Issues, call slides and discussion summary, September 25, 2014.

  13. Designing spectrum-splitting dichroic filters to optimize current...

    Office of Scientific and Technical Information (OSTI)

    Title: Designing spectrum-splitting dichroic filters to optimize current-matched photovoltaics Authors: Miles, Alexander ; Cocilovo, Byron ; Wheelwright, Brian ; Pan, Wei ; Tweet, ...

  14. San Andreas Split Geothermal Region | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ENERGYGeothermal Home San Andreas Split Geothermal Region Details Areas (0) Power Plants (0) Projects (0) Techniques (0) Assessment of Moderate- and High-Temperature...

  15. Two Electron Holes in Hematite Facilitate Water Splitting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    been suspected that in hematite, two different holes are formed with different water-splitting power. The existence of different types of holes with disparate reactivity...

  16. Strategies to Address Split Incentives in Multifamily Buildings

    Energy.gov [DOE]

    Better Buildings Neighborhood Program Multifamily / Low-Income Peer Exchange Call: Strategies to Address Split Incentives in Multifamily Buildings, Call Slides and Discussion Summary, April 26, 2012.

  17. DOE - Office of Legacy Management -- WNI Split Rock Site - 043

    Office of Legacy Management (LM)

    Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: The Western Nuclear, Inc. (WNI) Split Rock site is a Uranium Mill ...

  18. Ductless, Mini-Split Heat Pump Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Ductless, Mini-Split Heat Pump Basics Ductless, Mini-Split Heat Pump Basics August 19, 2013 - 11:04am Addthis Ductless, mini-split-system heat pumps (mini splits), as their name implies, do not have ducts. Therefore, they make good retrofit add-ons to houses or buildings with "non-ducted" heating systems, such as hydronic (hot water heat), radiant panels, and space heaters (wood, kerosene, propane). They can also be a good choice for room additions, where extending or installing

  19. Ductless, Mini-Split Heat Pumps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Heat Pump Systems » Ductless, Mini-Split Heat Pumps Ductless, Mini-Split Heat Pumps Ductless, mini-split-system heat pumps (mini splits) make good retrofit add-ons to houses with "non-ducted" heating systems, such as hydronic (hot water heat), radiant panels, and space heaters (wood, kerosene, propane). They can also be a good choice for room additions where extending or installing distribution ductwork is not feasible, and very efficient new homes that require only a small space

  20. Method for dissolving plutonium dioxide

    DOEpatents

    Tallent, Othar K.

    1978-01-01

    The fluoride-catalyzed, non-oxidative dissolution of plutonium dioxide in HNO.sub.3 is significantly enhanced in rate by oxidizing dissolved plutonium ions. It is believed that the oxidation of dissolved plutonium releases fluoride ions from a soluble plutonium-fluoride complex for further catalytic action.

  1. Zero emission coal

    SciTech Connect

    Ziock, H.; Lackner, K.

    2000-08-01

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  2. Split driveshaft pump for hazardous fluids

    DOEpatents

    Evans, II, Thomas P.; Purohit, Jwalit J.; Fazio, John M.

    1995-01-01

    A pump having a split driveshaft for use in pumping hazardous fluids wherein only one driveshaft becomes contaminated by the fluid while the second remains isolated from the fluid. The pump has a first portion and a second portion. The first portion contains a pump motor, the first driveshaft, a support pedestal, and vapor barriers and seals. The second portion contains a second, self-lubricating driveshaft and an impeller. The first and second driveshafts are connected together by a releasable coupling. A shield and a slinger deployed below the coupling prevent fluid from the second portion from reaching the first portion. In operation, only the second assembly comes into contact with the fluid being pumped, so the risk of contamination of the first portion by the hazardous fluid is reduced. The first assembly can be removed for repairs or routine maintenance by decoupling the first and second driveshafts and disconnecting the motor from the casing.

  3. Split-field pupil plane determination apparatus

    DOEpatents

    Salmon, Joseph T.

    1996-01-01

    A split-field pupil plane determination apparatus (10) having a wedge assembly (16) with a first glass wedge (18) and a second glass wedge (20) positioned to divide a laser beam (12) into a first laser beam half (22) and a second laser beam half (24) which diverge away from the wedge assembly (16). A wire mask (26) is positioned immediately after the wedge assembly (16) in the path of the laser beam halves (22, 24) such that a shadow thereof is cast as a first shadow half (30) and a second shadow half (32) at the input to a relay telescope (14). The relay telescope (14) causes the laser beam halves (22, 24) to converge such that the first shadow half (30) of the wire mask (26) is aligned with the second shadow half (32) at any subsequent pupil plane (34).

  4. Carbon Dioxide Emissions From Vegetation-Kill Zones Around The...

    OpenEI (Open Energy Information) [EERE & EIA]

    from locations west and east of the plant revealed the presence of isobutane related to plant operations. The 13C values of diffuse CO2 range from - 5.7 to - 3.4, similar...

  5. "1. Carbon Dioxide Emission Factors for Stationary Combustion1...

    Energy Information Administration (EIA) (indexed site)

    ... composition for 2006 reported in U.S. Environmental Protection Agency, 2006 MSW Characterization Data Tables, http:www.epa.govepaoswernon-hwmuncplpubs06data.pdf. " "8 ...

  6. Modified dry limestone process for control of sulfur dioxide emissions

    DOEpatents

    Shale, Correll C.; Cross, William G.

    1976-08-24

    A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

  7. Improving the efficiency of water splitting in dye-sensitized...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    bound to the water oxidation catalyst, a colloidal iridium oxide particle, and is coadsorbed onto a porous titanium dioxide electrode with a Ruthenium polypyridyl sensitizer. ...

  8. Environmental Emissions from Energy Technology Systems: The Total Fuel Cycle

    SciTech Connect

    San Martin, Robert L.

    1989-01-01

    This is a summary report that compares emissions during the entire project life cycle for a number of fossil-fueled and renewable electric power systems, including geothermal steam (probably modeled after The Geysers). The life cycle is broken into Fuel Extraction, Construction, and Operation. The only emission covered is carbon dioxide.

  9. Environmental Emissions From Energy Technology Systems: The Total Fuel Cycle

    SciTech Connect

    San Martin, Robert L.

    1989-04-01

    This is a summary report that compares emissions during the entire project life cycle for a number of fossil-fueled and renewable electric power systems, including geothermal steam (probably modeled after The Geysers). The life cycle is broken into Fuel Extraction, Construction, and Operation. The only emission covered is carbon dioxide. (DJE 2005)

  10. High capacity carbon dioxide sorbent

    DOEpatents

    Dietz, Steven Dean; Alptekin, Gokhan; Jayaraman, Ambalavanan

    2015-09-01

    The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.

  11. Method for carbon dioxide sequestration

    DOEpatents

    Wang, Yifeng; Bryan, Charles R.; Dewers, Thomas; Heath, Jason E.

    2015-09-22

    A method for geo-sequestration of a carbon dioxide includes selection of a target water-laden geological formation with low-permeability interbeds, providing an injection well into the formation and injecting supercritical carbon dioxide (SC--CO.sub.2) into the injection well under conditions of temperature, pressure and density selected to cause the fluid to enter the formation and splinter and/or form immobilized ganglia within the formation. This process allows for the immobilization of the injected SC--CO.sub.2 for very long times. The dispersal of scCO2 into small ganglia is accomplished by alternating injection of SC--CO.sub.2 and water. The injection rate is required to be high enough to ensure the SC--CO.sub.2 at the advancing front to be broken into pieces and small enough for immobilization through viscous instability.

  12. Excitonic fine-structure splitting in telecom-wavelength InAs/GaAs quantum dots: Statistical distribution and height-dependence

    SciTech Connect

    Goldmann, Elias Barthel, Stefan; Florian, Matthias; Jahnke, Frank; Schuh, Kolja

    2013-12-09

    The variation of the excitonic fine-structure splitting is studied for semiconductor quantum dots under the influence of a strain-reducing layer, utilized to shift the emission wavelength of the excitonic transition into the telecom-wavelength regime of 1.31.5 ?m. By means of a sp{sup 3}s{sup *}-tight-binding model and configuration interaction, we calculate wavelength shifts and fine-structure splittings for various quantum dot geometries. We find the splittings remaining small and even decreasing with strain-reducing layer composition for quantum dots with large height. Combined with an observed increased emission efficiency, the applicability for generation of entanglement photons is persistent.

  13. CARBON DIOXIDE AS A FEEDSTOCK.

    SciTech Connect

    CREUTZ,C.; FUJITA,E.

    2000-12-09

    This report is an overview on the subject of carbon dioxide as a starting material for organic syntheses of potential commercial interest and the utilization of carbon dioxide as a substrate for fuel production. It draws extensively on literature sources, particularly on the report of a 1999 Workshop on the subject of catalysis in carbon dioxide utilization, but with emphasis on systems of most interest to us. Atmospheric carbon dioxide is an abundant (750 billion tons in atmosphere), but dilute source of carbon (only 0.036 % by volume), so technologies for utilization at the production source are crucial for both sequestration and utilization. Sequestration--such as pumping CO{sub 2} into sea or the earth--is beyond the scope of this report, except where it overlaps utilization, for example in converting CO{sub 2} to polymers. But sequestration dominates current thinking on short term solutions to global warming, as should be clear from reports from this and other workshops. The 3500 million tons estimated to be added to the atmosphere annually at present can be compared to the 110 million tons used to produce chemicals, chiefly urea (75 million tons), salicylic acid, cyclic carbonates and polycarbonates. Increased utilization of CO{sub 2} as a starting material is, however, highly desirable, because it is an inexpensive, non-toxic starting material. There are ongoing efforts to replace phosgene as a starting material. Creation of new materials and markets for them will increase this utilization, producing an increasingly positive, albeit small impact on global CO{sub 2} levels. The other uses of interest are utilization as a solvent and for fuel production and these will be discussed in turn.

  14. Open-split interface for mass spectrometers

    DOEpatents

    Diehl, John W.

    1991-01-01

    An open-split interface includes a connector body having four leg members projecting therefrom within a single plane, the first and third legs being coaxial and the second and fourth legs being coaxial. A tubular aperture extends through the first and third legs and a second tubular aperture extends through the second and fourth legs, connecting at a juncture within the center of the connector body. A fifth leg projects from the connector body and has a third tubular aperture extending therethrough to the juncture of the first and second tubular apertures. A capillary column extends from a gas chromatograph into the third leg with its end adjacent the juncture. A flow restrictor tube extends from a mass spectrometer through the first tubular aperture in the first and third legs and into the capillary columnm end, so as to project beyond the end of the third leg within the capillary column. An annular gap between the tube and column allows excess effluent to pass to the juncture. A pair of short capillary columns extend from separate detectors into the second tubular aperture in the second and fourth legs, and are oriented with their ends spaced slightly from the first capillary column end. A sweep flow tube is mounted in the fifth leg so as to supply a helium sweep flow to the juncture.

  15. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants with Advanced Technology

    Reports and Publications

    2001-01-01

    This analysis responds to a request of Senators James M. Jeffords and Joseph I. Lieberman. This report describes the impacts of technology improvements and other market-based opportunities on the costs of emissions reductions from electricity generators, including nitrogen oxides, sulfur dioxide, mercury, and carbon dioxide.

  16. Analysis of Strategies for Reducing Multiple Emissions from Electric Power Plants: SO2, Nox, CO2

    Reports and Publications

    2001-01-01

    This report responds to a request received from Senator David McIntosh on June 29, 2000 to analyze the impacts on energy consumers and producers of coordinated strategies to reduce emissions of sulfur dioxide, nitrogen oxides, and carbon dioxide at U.S. power plants.

  17. Thermoelectric-induced unitary Cooper pair splitting efficiency

    SciTech Connect

    Cao, Zhan; Fang, Tie-Feng; Li, Lin; Luo, Hong-Gang

    2015-11-23

    Thermoelectric effect is exploited to optimize the Cooper pair splitting efficiency in a Y-shaped junction, which consists of two normal leads coupled to an s-wave superconductor via double noninteracting quantum dots. Here, utilizing temperature difference rather than bias voltage between the two normal leads, and tuning the two dot levels such that the transmittance of elastic cotunneling process is particle-hole symmetric, we find current flowing through the normal leads are totally contributed from the splitting of Cooper pairs emitted from the superconductor. Such a unitary splitting efficiency is significantly better than the efficiencies obtained in experiments so far.

  18. How Atomic Vibrations Transform Vanadium Dioxide

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    How Atomic Vibrations Transform Vanadium Dioxide How Atomic Vibrations Transform Vanadium Dioxide Calculations Confirm Material's Potential for Next-Generation Electronics, Energy November 10, 2014 Contact: Dawn Levy, levyd@ornl.gov, 865.576.6448 Budaivibe Vanadium atoms (blue) have unusually large thermal vibrations that stabilize the metallic state of a vanadium dioxide crystal. Red depicts oxygen atoms. Image credit: Oak Ridge National Laboratory For more than 50 years, scientists have

  19. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  20. Optimize carbon dioxide sequestration, enhance oil recovery

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate the potential of storing carbon dioxide in depleted oil fields while simultaneously maximizing oil production. January 8, 2014 Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery. Schematic of a water-alternating-with-gas flood for CO2 sequestration and enhanced oil recovery.

  1. ARM - Measurement - Carbon dioxide (CO2) flux

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    carbon dioxide, a heavy, colorless greenhouse gas. Categories Atmospheric Carbon, Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  2. Project Profile: Carbon Dioxide Shuttling Thermochemical Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Project Profile: Carbon Dioxide Shuttling Thermochemical Storage Using Strontium Carbonate University of Florida Logo -- This project is inactive -- The University of Florida (UF), ...

  3. Method of Making Uranium Dioxide Bodies

    DOEpatents

    Wilhelm, H. A.; McClusky, J. K.

    1973-09-25

    Sintered uranium dioxide bodies having controlled density are produced from U.sub.3 O.sub.8 and carbon by varying the mole ratio of carbon to U.sub.3 O.sub.8 in the mixture, which is compressed and sintered in a neutral or slightly oxidizing atmosphere to form dense slightly hyperstoichiometric uranium dioxide bodies. If the bodies are to be used as nuclear reactor fuel, they are subsequently heated in a hydrogen atmosphere to achieve stoichiometry. This method can also be used to produce fuel elements of uranium dioxide -- plutonium dioxide having controlled density.

  4. Mini-Split Heat Pumps Multifamily Retrofit Feasibility Study

    SciTech Connect

    Dentz, Jordan; Podorson, David; Varshney, Kapil

    2014-05-01

    Mini-split heat pumps can provide space heating and cooling in many climates and are relatively affordable. These and other features make them potentially suitable for retrofitting into multifamily buildings in cold climates to replace electric resistance heating or other outmoded heating systems. This report investigates the suitability of mini-split heat pumps for multifamily retrofits. Various technical and regulatory barriers are discussed and modeling was performed to compare long-term costs of substituting mini-splits for a variety of other heating and cooling options. A number of utility programs have retrofit mini-splits in both single family and multifamily residences. Two such multifamily programs are discussed in detail.

  5. Two Electron Holes in Hematite Facilitate Water Splitting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    by-product is nonpolluting water vapor. The problem, however, is that the production of hydrogen-via the process of water splitting-currently requires the burning of traditional...

  6. Performance Models for Split-execution Computing Systems

    SciTech Connect

    Humble, Travis S; McCaskey, Alex; Schrock, Jonathan; Seddiqi, Hadayat; Britt, Keith A; Imam, Neena

    2016-01-01

    Split-execution computing leverages the capabilities of multiple computational models to solve problems, but splitting program execution across different computational models incurs costs associated with the translation between domains. We analyze the performance of a split-execution computing system developed from conventional and quantum processing units (QPUs) by using behavioral models that track resource usage. We focus on asymmetric processing models built using conventional CPUs and a family of special-purpose QPUs that employ quantum computing principles. Our performance models account for the translation of a classical optimization problem into the physical representation required by the quantum processor while also accounting for hardware limitations and conventional processor speed and memory. We conclude that the bottleneck in this split-execution computing system lies at the quantum-classical interface and that the primary time cost is independent of quantum processor behavior.

  7. Field Monitoring Protocol: Mini-Split Heat Pumps

    SciTech Connect

    Christensen, D.; Fang, X.; Tomerlin, J.; Winkler, J.; Hancock, E.

    2011-03-01

    The report provides a detailed method for accurately measuring and monitoring performance of a residential Mini-Split Heat Pump. It will be used in high-performance retrofit applications, and as part of DOE's Building America residential research program.

  8. Field Monitoring Protocol. Mini-Split Heat Pumps

    SciTech Connect

    Christensen, Dane; Fang, Xia; Tomerlin, Jeff; Winkler, Jon; Hancock, E.

    2011-03-01

    This Building America program report provides a detailed method for accurately measuring and monitoring performance of a residential mini-split heat pump, which will be used in high-performance retrofit applications.

  9. Shear-wave splitting and reservoir crack characterization: the...

    OpenEI (Open Energy Information) [EERE & EIA]

    of its geothermal potential and day-to-day production. To detect the geometry and density of fracture systems we applied the shear-wave splitting technique to a large number...

  10. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Transport Membrane (OTM) (Presentation) | Department of Energy Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 11_anl_distributed_reforming_using_otm.pdf (809.59 KB) More Documents & Publications Cost

  11. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Electrosynthesis with Synthetic Electromicrobiology and System Design | Department of Energy Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Presentation by Derek Lovley, UMass Amherst, during the "Targeting High-Value Challenges" panel at the Hydrogen, Hydrocarbons,

  12. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  13. Why taxes do distort emissions trading

    SciTech Connect

    Garnett, S.I. II

    1995-02-15

    The truth is that the federal tax system seriously interferes with the intended operation on the emission allowance market. The Clean Air Act Amendments (CAAA) of 1990 created a unique system of transferable sulfur dioxide emission allowances. Congress designed these allowances to facilitate cutailment of sulfur dioxide emissions in two phases. The allowances may be sold, which triggers a tax liability from the IRS based on a capital gain of the selling price. Therefore, internal use and stockpiling is favored due to the tax consequences. To correct the problem, a proposal has been made to allow selling utilities the option of deferring taxation by applying allowance sale proceeds to reduce the tax basis of capital investments in scrubbers and other technology to reduce sulfur dioxide emissions. The proposal does not eliminate taxation, only defers it. It prevents utilities from gaming the system, the gain that qualifies for deferral would be offset by any amounts the taxpayer expends to purchase allowances within two years of the sale. This proposal would help achieve the objectives of the CAAA, and remove any tax anomaly in allowance trading before phase two of the CAAA begins.

  14. Nuclear Hydrogen and Captured Carbon Dioxide for Alternative...

    Office of Scientific and Technical Information (OSTI)

    Conference: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Citation Details In-Document Search Title: Nuclear Hydrogen and Captured Carbon Dioxide for ...

  15. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  16. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined...

    Office of Scientific and Technical Information (OSTI)

    the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer Citation Details In-Document Search Title: Modeling the Impact of Carbon Dioxide Leakage ...

  17. NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Citation Details In-Document Search Title: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE ...

  18. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  19. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine NREL logo -- This project is inactive -- The ...

  20. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers This fact sheet describes a supercritical carbon ...

  1. Los Alamos probes mysteries of uranium dioxide's thermal conductivity

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Mysteries of uranium dioxide's thermal conductivity Los Alamos probes mysteries of uranium dioxide's thermal conductivity New research is showing that the thermal conductivity of ...

  2. Array of titanium dioxide nanostructures for solar energy utilization...

    Office of Scientific and Technical Information (OSTI)

    Patent: Array of titanium dioxide nanostructures for solar energy utilization Citation Details In-Document Search Title: Array of titanium dioxide nanostructures for solar energy ...

  3. Electrochemical Membrane for Carbon Dioxide Separation and Power...

    Office of Scientific and Technical Information (OSTI)

    for Carbon Dioxide Separation and Power Generation Citation Details In-Document Search Title: Electrochemical Membrane for Carbon Dioxide Separation and Power Generation ...

  4. Thermodynamic properties of uranium dioxide

    SciTech Connect

    Fink, J.K.; Chasanov, M.G.; Leibowitz, L.

    1981-04-01

    In order to provide reliable and consistent data on the thermophysical properties of reactor materials for reactor safety studies, this revision is prepared for the thermodynamic properties of the uranium dioxide portion of the fuel property section of the report Properties for LMFBR Safety Analysis. Since the original report was issued in 1976, there has been international agreement on a vapor pressure equation for the total pressure over UO/sub 2/, new methods have been suggested for the calculation of enthalpy and heat capacity, and a phase change at 2670 K has been proposed. In this report, an electronic term is used in place of the Frenkel defect term in the enthalpy and heat capacity equation and the phase transition is accepted.

  5. Electrocatalysts for carbon dioxide conversion

    DOEpatents

    Masel, Richard I; Salehi-Khojin, Amin

    2015-04-21

    Electrocatalysts for carbon dioxide conversion include at least one catalytically active element with a particle size above 0.6 nm. The electrocatalysts can also include a Helper Catalyst. The catalysts can be used to increase the rate, modify the selectivity or lower the overpotential of electrochemical conversion of CO.sub.2. Chemical processes and devices using the catalysts also include processes to produce CO, HCO.sup.-, H.sub.2CO, (HCO.sub.2).sup.-, H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, or (COO.sup.-).sub.2, and a specific device, namely, a CO.sub.2 sensor.

  6. FETC Programs for Reducing Greenhouse Gas Emissions

    SciTech Connect

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  7. Enabling unassisted solar water splitting by iron oxide and silicon

    SciTech Connect

    Jang, Ji-Wook; Du, Chun; Ye, Yifan; Lin, Yongjing; Yao, Xiahui; Thorne, James; Liu, Erik; McMahon, Gregory; Zhu, Junfa; Javey, Ali; Guo, Jinghua; Wang, Dunwei

    2015-06-16

    A solution for large-scale solar energy storage is photoelectrochemical (PEC) water splitting. However, its development has been impeded by the poor performance of photoanodes, particularly in their capability for photovoltage generation. Many examples employing photovoltaic modules to correct the deficiency for unassisted solar water splitting have been reported to-date. We show that, by using the prototypical photoanode material of haematite as a study tool, structural disorders on or near the surfaces are important causes of the low photovoltages. We develop a facile re-growth strategy to reduce surface disorders and as a consequence, a turn-on voltage of 0.45 V (versus reversible hydrogen electrode) is achieved. In conclusion, this result permits us to construct a photoelectrochemical device with a haematite photoanode and Si photocathode to split water at an overall efficiency of 0.91%, with NiFeOx and TiO2/Pt overlayers, respectively.

  8. Enabling unassisted solar water splitting by iron oxide and silicon

    DOE PAGES [OSTI]

    Jang, Ji-Wook; Du, Chun; Ye, Yifan; Lin, Yongjing; Yao, Xiahui; Thorne, James; Liu, Erik; McMahon, Gregory; Zhu, Junfa; Javey, Ali; et al

    2015-06-16

    A solution for large-scale solar energy storage is photoelectrochemical (PEC) water splitting. However, its development has been impeded by the poor performance of photoanodes, particularly in their capability for photovoltage generation. Many examples employing photovoltaic modules to correct the deficiency for unassisted solar water splitting have been reported to-date. We show that, by using the prototypical photoanode material of haematite as a study tool, structural disorders on or near the surfaces are important causes of the low photovoltages. We develop a facile re-growth strategy to reduce surface disorders and as a consequence, a turn-on voltage of 0.45 V (versus reversiblemore » hydrogen electrode) is achieved. In conclusion, this result permits us to construct a photoelectrochemical device with a haematite photoanode and Si photocathode to split water at an overall efficiency of 0.91%, with NiFeOx and TiO2/Pt overlayers, respectively.« less

  9. Crystal Splitting in the Growth of Bi2S3

    SciTech Connect

    Tang, Jing; Alivisatos, A. Paul

    2006-06-15

    Novel Bi{sub 2}S{sub 3} nanostructures with a sheaf-like morphology are obtained via reaction of bismuth acetate-oleic acid complex with elemental sulfur in 1-octadecence. We propose these structures form by the splitting crystal growth mechanism, which is known to account for the morphology some mineral crystals assume in nature. By controlling the synthetic parameters, different forms of splitting, analogous to observed in minerals, are obtained in our case of Bi{sub 2}S{sub 3}. These new and complex Bi{sub 2}S{sub 3} nanostructures are characterized by TEM, SEM, XRD and ED.

  10. Split-System Cold Climate Heat Pump | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Split-System Cold Climate Heat Pump Split-System Cold Climate Heat Pump Photo of the prototype cold climate heat pump outdoor unit, installed at the Ohio field test site in January 2015. <br />Credit: Oak Ridge National Laboratory Photo of the prototype cold climate heat pump outdoor unit, installed at the Ohio field test site in January 2015. Credit: Oak Ridge National Laboratory Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partners: -- Unico Inc. - St. Louis, MO --

  11. Why Do Atoms Explode When They Split? | GE Global Research

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Why Do Atoms Explode When They Split? Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Why Do Atoms Explode When They Split? 2012.08.13 Chief Scientist Jim Bray describes how nuclear fission in heavy atoms releases energy. 1 Comment Comment Name Email Submit Comment hirthik sunder 2014.05.30 viewing this website

  12. Carbon dioxide-soluble polymers and swellable polymers for carbon dioxide applications

    DOEpatents

    DeSimone, Joseph M.; Birnbaum, Eva; Carbonell, Ruben G.; Crette, Stephanie; McClain, James B.; McCleskey, T. Mark; Powell, Kimberly R.; Romack, Timothy J.; Tumas, William

    2004-06-08

    A method for carrying out a catalysis reaction in carbon dioxide comprising contacting a fluid mixture with a catalyst bound to a polymer, the fluid mixture comprising at least one reactant and carbon dioxide, wherein the reactant interacts with the catalyst to form a reaction product. A composition of matter comprises carbon dioxide and a polymer and a reactant present in the carbon dioxide. The polymer has bound thereto a catalyst at a plurality of chains along the length of the polymer, and wherein the reactant interacts with the catalyst to form a reaction product.

  13. ARM - Measurement - Carbon dioxide (CO2) concentration

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Carbon dioxide (CO2) concentration The amount of carbon dioxide, a heavy, colorless greenhouse gas, per unit of volume. Categories Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  14. Copper mercaptides as sulfur dioxide indicators

    DOEpatents

    Eller, Phillip G.; Kubas, Gregory J.

    1979-01-01

    Organophosphine copper(I) mercaptide complexes are useful as convenient and semiquantitative visual sulfur dioxide gas indicators. The air-stable complexes form 1:1 adducts in the presence of low concentrations of sulfur dioxide gas, with an associated color change from nearly colorless to yellow-orange. The mercaptides are made by mixing stoichiometric amounts of the appropriate copper(I) mercaptide and phosphine in an inert organic solvent.

  15. Thorium dioxide: properties and nuclear applications

    SciTech Connect

    Belle, J.; Berman, R.M.

    1984-01-01

    This is the sixth book on reactor materials published under sponsorship of the Naval Reactors Office of the United States Department of Energy, formerly the United States Atomic Energy Commission. This book presents a comprehensive compilation of the most significant properties of thorium dioxide, much like the book Uranium Dioxide: Properties and Nuclear Applications presented information on the fuel material used in the Shippingport Pressurized Water Reactor core.

  16. Beneficial Use of Carbon Dioxide in Precast Concrete Production (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Beneficial Use of Carbon Dioxide in Precast Concrete Production Citation Details In-Document Search Title: Beneficial Use of Carbon Dioxide in Precast Concrete Production The feasibility of using carbon dioxide as feedstock in precast concrete production is studied. Carbon dioxide reacts with calcium compounds in concrete, producing solid calcium carbonates in binding matrix. Two typical precast products are examined for their capacity to store carbon dioxide during

  17. Limiting net greenhouse gas emissions in the United States

    SciTech Connect

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  18. Higgs, Binos and Gluinos: Split Susy within Reach

    SciTech Connect

    Alves, Daniele S.M.; Izaguirre, Eder; Wacker, Jay G.; /SLAC /Stanford U., ITP

    2012-09-14

    Recent results from the LHC for the Higgs boson with mass between 142 GeV {approx}< m{sub h{sup 0}} {approx}< 147 GeV points to PeV-scale Split Supersymmetry. This article explores the consequences of a Higgs mass in this range and possible discovery modes for Split Susy. Moderate lifetime gluinos, with decay lengths in the 25 {micro}m to 10 yr range, are its imminent smoking gun signature. The 7TeV LHC will be sensitive to the moderately lived gluinos and trilepton signatures from direct electroweakino production. Moreover, the dark matter abundance may be obtained from annihilation through an s-channel Higgs resonance, with the LSP almost purely bino and mass m{sub {chi}{sub 1}{sup 0}} {approx_equal} 70 GeV. The Higgs resonance region of Split Susy has visible signatures in dark matter direct and indirect detection and electric dipole moment experiments. If the anomalies go away, the majority of Split Susy parameter space will be excluded.

  19. Ductless Mini-Split Heat Pump Comfort Evaluation

    SciTech Connect

    Roth, K.; Sehgal, N.; Akers, C.

    2013-03-01

    Field tests were conducted in two homes in Austin, TX to evaluate the comfort performance of ductless mini-split heat pumps (DMSHPs), measuring temperature and relative humidity measurements in four rooms in each home before and after retrofitting a central HVAC system with DMSHPs.

  20. DOE Technical Targets for Hydrogen Production from Photoelectrochemical Water Splitting

    Energy.gov [DOE]

    These tables list the U.S. Department of Energy (DOE) technical targets and example cost and performance parameter values that achieve the targets for hydrogen production from photoelectrochemical water splitting. The tables are organized into separate sections for photoelectrode systems and dual bed photocatalyst systems.

  1. Dual-frequency terahertz emission from splitting filaments induced by lens tilting in air

    SciTech Connect

    Zhang, Zhelin; Chen, Yanping Yang, Liu; Yuan, Xiaohui; Liu, Feng; Chen, Min; Xu, Jianqiu; Zhang, Jie; Sheng, Zhengming

    2014-09-08

    Dual-frequency terahertz radiation from air-plasma filaments produced with two-color lasers in air has been demonstrated experimentally. When a focusing lens is tilted for a few degrees, it is shown that the laser filament evolves from a single one to two sub-filaments. Two independent terahertz sources emitted from the sub-filaments with different frequencies and polarizations are identified, where the frequency of terahertz waves from the trailing sub-filament is higher than that from the leading sub-filament.

  2. Transportable Emissions Testing Laboratory for Alternative Vehicles Emissions Testing

    SciTech Connect

    Clark, Nigel

    2012-01-31

    The overall objective of this project was to perform research to quantify and improve the energy efficiency and the exhaust emissions reduction from advanced technology vehicles using clean, renewable and alternative fuels. Advanced vehicle and alternative fuel fleets were to be identified, and selected vehicles characterized for emissions and efficiency. Target vehicles were to include transit buses, school buses, vocational trucks, delivery trucks, and tractor-trailers. Gaseous species measured were to include carbon monoxide, carbon dioxide, oxides of nitrogen, hydrocarbons, and particulate matter. An objective was to characterize particulate matter more deeply than by mass. Accurate characterization of efficiency and emissions was to be accomplished using a state-of-the-art portable emissions measurement system and an accompanying chassis dynamometer available at West Virginia University. These two units, combined, are termed the Transportable Laboratory. An objective was to load the vehicles in a real-world fashion, using coast down data to establish rolling resistance and wind drag, and to apply the coast down data to the dynamometer control. Test schedules created from actual vehicle operation were to be employed, and a specific objective of the research was to assess the effect of choosing a test schedule which the subject vehicle either cannot follow or can substantially outperform. In addition the vehicle loading objective was to be met better with an improved flywheel system.

  3. Carbon dioxide capture process with regenerable sorbents

    DOEpatents

    Pennline, Henry W.; Hoffman, James S.

    2002-05-14

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  4. Investigation of the carbon dioxide sorption capacity and structural deformation of coal

    SciTech Connect

    Hur, Tae-Bong; Fazio, James; Romanov, Vyacheslav; Harbert, William

    2010-01-01

    Due to increasing atmospheric CO2 concentrations causing the global energy and environmental crises, geological sequestration of carbon dioxide is now being actively considered as an attractive option to mitigate greenhouse gas emissions. One of the important strategies is to use deep unminable coal seams, for those generally contain significant quantities of coal bed methane that can be recovered by CO2 injection through enhanced coal bed natural gas production, as a method to safely store CO2. It has been well known that the adsorbing CO2 molecules introduce structural deformation, such as distortion, shrinkage, or swelling, of the adsorbent of coal organic matrix. The accurate investigations of CO2 sorption capacity as well as of adsorption behavior need to be performed under the conditions that coals deform. The U.S. Department of Energy-National Energy Technology Laboratory and Regional University Alliance are conducting carbon dioxide sorption isotherm experiments by using manometric analysis method for estimation of CO2 sorption capacity of various coal samples and are constructing a gravimetric apparatus which has a visual window cell. The gravimetric apparatus improves the accuracy of carbon dioxide sorption capacity and provides feasibility for the observation of structural deformation of coal sample while carbon dioxide molecules interact with coal organic matrix. The CO2 sorption isotherm measurements have been conducted for moist and dried samples of the Central Appalachian Basin (Russell County, VA) coal seam, received from the SECARB partnership, at the temperature of 55 C.

  5. SEQUESTERING CARBON DIOXIDE IN COALBEDS

    SciTech Connect

    K.A.M. Gasem; R.L. Robinson, Jr.; J.E. Fitzgerald; Z. Pan; M. Sudibandriyo

    2003-04-30

    The authors' long-term goal is to develop accurate prediction methods for describing the adsorption behavior of gas mixtures on solid adsorbents over complete ranges of temperature, pressure, and adsorbent types. The originally-stated, major objectives of the current project are to: (1) measure the adsorption behavior of pure CO{sub 2}, methane, nitrogen, and their binary and ternary mixtures on several selected coals having different properties at temperatures and pressures applicable to the particular coals being studied, (2) generalize the adsorption results in terms of appropriate properties of the coals to facilitate estimation of adsorption behavior for coals other than those studied experimentally, (3) delineate the sensitivity of the competitive adsorption of CO{sub 2}, methane, and nitrogen to the specific characteristics of the coal on which they are adsorbed; establish the major differences (if any) in the nature of this competitive adsorption on different coals, and (4) test and/or develop theoretically-based mathematical models to represent accurately the adsorption behavior of mixtures of the type for which measurements are made. As this project developed, an important additional objective was added to the above original list. Namely, we were encouraged to interact with industry and/or governmental agencies to utilize our expertise to advance the state of the art in coalbed adsorption science and technology. As a result of this additional objective, we participated with the Department of Energy and industry in the measurement and analysis of adsorption behavior as part of two distinct investigations. These include (a) Advanced Resources International (ARI) DOE Project DE-FC26-00NT40924, ''Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on Wet Tiffany Coal'', and (b) the DOE-NETL Project, ''Round Robin: CO{sub 2} Adsorption on Selected Coals''. These activities, contributing directly to the DOE projects listed above, also

  6. MANGANESE DIOXIDE METHOD FOR PREPARATION OF PROTACTINIUM

    DOEpatents

    Katzin, L.I.

    1958-08-12

    A method of obtaining U/sup 233/ is described. An aqueous solution of neutriln irradiated thoriunn is treated by forming tberein a precipitate of manganese dioxide which carries and thus separates the Pa/sup 233/ from the solution. The carrier precipitate so formed is then dissolved in an acidic solution containing a reducing agent sufficiently electronegative to reduce the tetravalent manganese to the divalent state. Further purification of the Pa/sup 233/ may be obtained by forming another manganese dioxide carrier precipitate and subsequently dissolving it. Ater a sufficient number of such cycles have brought the Pa/sup 233/ to the desired purity, the solution is aged, allowing the formation ot U/sup 233/ by radioaetive decay. A manganese dioxide precipitate is then formed in the U/sup 233/ containing solution. This precipitate carries down any remaining Pa/sup 233/ thus leaving the separated U/sup 233/solution, from whieh it may be easily recovered.

  7. Polymers for metal extractions in carbon dioxide

    DOEpatents

    DeSimone, Joseph M.; Tumas, William; Powell, Kimberly R.; McCleskey, T. Mark; Romack, Timothy J.; McClain, James B.; Birnbaum, Eva R.

    2001-01-01

    A composition useful for the extraction of metals and metalloids comprises (a) carbon dioxide fluid (preferably liquid or supercritical carbon dioxide); and (b) a polymer in the carbon dioxide, the polymer having bound thereto a ligand that binds the metal or metalloid; with the ligand bound to the polymer at a plurality of locations along the chain length thereof (i.e., a plurality of ligands are bound at a plurality of locations along the chain length of the polymer). The polymer is preferably a copolymer, and the polymer is preferably a fluoropolymer such as a fluoroacrylate polymer. The extraction method comprises the steps of contacting a first composition containing a metal or metalloid to be extracted with a second composition, the second composition being as described above; and then extracting the metal or metalloid from the first composition into the second composition.

  8. Optimization of the main parameters of miniature split Stirling cooler

    SciTech Connect

    Tsesarsky, J.

    1995-12-01

    Unlike other modern industrial products Stirling refrigerators development is based mainly on experimental methods. Newly developed high accuracy numerical model for Stirling refrigerators analysis provides good approximation of gas stream process assured by large number of nodes placed in regenerator (300) and large number of time steps (240 per one machine turn). Confidence in accuracy of equations solution makes possible Stirling coolers optimization. In addition to information about refrigerator temperature field the model provides information about driving force of split cooler displacer for computer aided design of displacer driver. In this paper, four parameters of split Stirling refrigerator are optimized: compressor-expander swept volume ratio; phase angle; regenerator length; and regenerator diameter. In each program run power delivered to gas was kept constant by continuous correction of compressor and expander strokes without changing their ratio. Collection of the results produce the optimum cooler structure. Driving displacer force-theta function is also available.

  9. Protein subcellular localization assays using split fluorescent proteins

    DOEpatents

    Waldo, Geoffrey S.; Cabantous, Stephanie

    2009-09-08

    The invention provides protein subcellular localization assays using split fluorescent protein systems. The assays are conducted in living cells, do not require fixation and washing steps inherent in existing immunostaining and related techniques, and permit rapid, non-invasive, direct visualization of protein localization in living cells. The split fluorescent protein systems used in the practice of the invention generally comprise two or more self-complementing fragments of a fluorescent protein, such as GFP, wherein one or more of the fragments correspond to one or more beta-strand microdomains and are used to "tag" proteins of interest, and a complementary "assay" fragment of the fluorescent protein. Either or both of the fragments may be functionalized with a subcellular targeting sequence enabling it to be expressed in or directed to a particular subcellular compartment (i.e., the nucleus).

  10. Permanent split capacitor single phase electric motor system

    DOEpatents

    Kirschbaum, H.S.

    1984-08-14

    A permanent split capacitor single phase electric motor achieves balanced operation at more than one operating point by adjusting the voltage supplied to the main and auxiliary windings and adjusting the capacitance in the auxiliary winding circuit. An intermediate voltage tap on an autotransformer supplies voltage to the main winding for low speed operation while a capacitive voltage divider is used to adjust the voltage supplied to the auxiliary winding for low speed operation. 4 figs.

  11. Towards a Design of a Complete Solar Water Splitting System

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Towards a Design of a Complete Solar Water Splitting System 1 Feb 2013 BISfuel© : A team of Bisfuel researchers led by Devens Gust, Ana Moore and Tom Moore has designed and characterized an artificial photosynthetic reaction center inspired by natural Photosystem II and comprising a highly oxidizing porphyrin linked to a biomimetic electron transfer relay and a porphyrin electron acceptor. Two articles with the results of the study have appeared in September special issue of PNAS "Chemical

  12. Internal/External Split Field Generator - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Internal/External Split Field Generator Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryThese technologies are designs and methods that boost the efficiency of electric generators by decoupling the magnetic polarity of the driving mechanism while increasing the operational frequency of the machine. Both are unique, low cost methods to develop a generator with a higher power density.DescriptionCommercial applications include stationary, rotational or

  13. Permanent split capacitor single phase electric motor system

    DOEpatents

    Kirschbaum, Herbert S.

    1984-01-01

    A permanent split capacitor single phase electric motor achieves balanced operation at more than one operating point by adjusting the voltage supplied to the main and auxiliary windings and adjusting the capacitance in the auxiliary winding circuit. An intermediate voltage tap on an autotransformer supplies voltage to the main winding for low speed operation while a capacitive voltage divider is used to adjust the voltage supplied to the auxiliary winding for low speed operation.

  14. Rational design of a split-Cas9 enzyme complex

    SciTech Connect

    Wright, Addison V.; Sternberg, Samuel H.; Taylor, David W.; Staahl, Brett T.; Bardales, Jorge A.; Kornfeld, Jack E.; Doudna, Jennifer A.

    2015-02-23

    Cas9, an RNA-guided DNA endonuclease found in clustered regularly interspaced short palindromic repeats (CRISPR) bacterial immune systems, is a versatile tool for genome editing, transcriptional regulation, and cellular imaging applications. Structures of Streptococcus pyogenes Cas9 alone or bound to single-guide RNA (sgRNA) and target DNA revealed a bilobed protein architecture that undergoes major conformational changes upon guide RNA and DNA binding. To investigate the molecular determinants and relevance of the interlobe rearrangement for target recognition and cleavage, we designed a split-Cas9 enzyme in which the nuclease lobe and ?-helical lobe are expressed as separate polypeptides. The lobes do not interact on their own, the sgRNA recruits them into a ternary complex that recapitulates the activity of full-length Cas9 and catalyzes site-specific DNA cleavage. The use of a modified sgRNA abrogates split-Cas9 activity by preventing dimerization, allowing for the development of an inducible dimerization system. We propose that split-Cas9 can act as a highly regulatable platform for genome-engineering applications.

  15. Rational design of a split-Cas9 enzyme complex

    DOE PAGES [OSTI]

    Wright, Addison V.; Sternberg, Samuel H.; Taylor, David W.; Staahl, Brett T.; Bardales, Jorge A.; Kornfeld, Jack E.; Doudna, Jennifer A.

    2015-02-23

    Cas9, an RNA-guided DNA endonuclease found in clustered regularly interspaced short palindromic repeats (CRISPR) bacterial immune systems, is a versatile tool for genome editing, transcriptional regulation, and cellular imaging applications. Structures of Streptococcus pyogenes Cas9 alone or bound to single-guide RNA (sgRNA) and target DNA revealed a bilobed protein architecture that undergoes major conformational changes upon guide RNA and DNA binding. To investigate the molecular determinants and relevance of the interlobe rearrangement for target recognition and cleavage, we designed a split-Cas9 enzyme in which the nuclease lobe and α-helical lobe are expressed as separate polypeptides. The lobes do not interactmore » on their own, the sgRNA recruits them into a ternary complex that recapitulates the activity of full-length Cas9 and catalyzes site-specific DNA cleavage. The use of a modified sgRNA abrogates split-Cas9 activity by preventing dimerization, allowing for the development of an inducible dimerization system. We propose that split-Cas9 can act as a highly regulatable platform for genome-engineering applications.« less

  16. Nanoscale Strontium Titanate Photocatalysts for Overall Water Splitting

    SciTech Connect

    Townsend, Troy K.; Browning, Nigel D.; Osterloh, Frank

    2012-08-28

    SrTiO3 (STO) is a large band gap (3.2 eV) semiconductor that catalyzes the overall water splitting reaction under UV light irradiation in the presence of a NiO cocatalyst. As we show here, the reactivity persists in nanoscale particles of the material, although the process is less effective at the nanoscale. To reach these conclusions, Bulk STO, 30 5 nm STO, and 6.5 1 nm STO were synthesized by three different methods, their crystal structures verified with XRD and their morphology observed with HRTEM before and after NiO deposition. In connection with NiO, all samples split water into stoichiometric mixtures of H2 and O2, but the activity is decreasing from 28 ?mol H2 g1 h1 (bulk STO), to 19.4 ?mol H2 g1 h1 (30 nm STO), and 3.0 ?mol H2 g1 h1 (6.5 nm STO). The reasons for this decrease are an increase of the water oxidation overpotential for the smaller particles and reduced light absorption due to a quantum size effect. Overall, these findings establish the first nanoscale titanate photocatalyst for overall water splitting.

  17. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon dioxide instead of steam allows higher...

  18. Crystal structure and compressibility of lead dioxide up to 140...

    Office of Scientific and Technical Information (OSTI)

    Crystal structure and compressibility of lead dioxide up to 140 GPa Citation Details In-Document Search Title: Crystal structure and compressibility of lead dioxide up to 140 GPa ...

  19. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  20. Geothermal Startup Will Put Carbon Dioxide to Good Use

    Energy.gov [DOE]

    Geothermal power holds enormous opportunities to provide affordable, clean energy that avoids greenhouse gases like carbon dioxide (CO2).

  1. Secretary Chu Announces Six Projects to Convert Captured CO2 Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Industrial Sources into Useful Products | Department of Energy Six Projects to Convert Captured CO2 Emissions from Industrial Sources into Useful Products Secretary Chu Announces Six Projects to Convert Captured CO2 Emissions from Industrial Sources into Useful Products July 22, 2010 - 12:00am Addthis Washington, D.C. - U.S. Energy Secretary Steven Chu announced today the selections of six projects that aim to find ways of converting captured carbon dioxide (CO2) emissions from industrial

  2. Game-Changing Process Mitigates CO2 Emissions Using Renewable Energy |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Process Mitigates CO2 Emissions Using Renewable Energy Game-Changing Process Mitigates CO2 Emissions Using Renewable Energy October 21, 2015 - 7:58am Addthis Game-Changing Process Mitigates CO2 Emissions Using Renewable Energy Gold nanoparticles are at the heart of a new process conceived and developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory (NETL) that can efficiently convert carbon dioxide (CO2) into usable chemicals and

  3. Chapter 9 - Energy-related CO2 emission

    Gasoline and Diesel Fuel Update

    9 U.S. Energy Information Administration | International Energy Outlook 2016 Chapter 9 Energy-related CO2 emissions Overview Because anthropogenic emissions of carbon dioxide (CO2) result primarily from the combustion of fossil fuels, energy consumption is at the center of the climate change debate. In the International Energy Outlook 2016 (IEO2016) Reference case, world energy- related CO2 emissions 331 increase from 32.3 billion metric tons in 2012 to 35.6 billion metric tons in 2020 and to

  4. The California Climate Action Registry: Development of methodologies for calculating greenhouse gas emissions from electricity generation

    SciTech Connect

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Muritshaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-08-01

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We find that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  5. Array of titanium dioxide nanostructures for solar energy utilization

    SciTech Connect

    Qiu, Xiaofeng; Parans Paranthaman, Mariappan; Chi, Miaofang; Ivanov, Ilia N; Zhang, Zhenyu

    2014-12-30

    An array of titanium dioxide nanostructures for solar energy utilization includes a plurality of nanotubes, each nanotube including an outer layer coaxial with an inner layer, where the inner layer comprises p-type titanium dioxide and the outer layer comprises n-type titanium dioxide. An interface between the inner layer and the outer layer defines a p-n junction.

  6. Acid sorption regeneration process using carbon dioxide

    DOEpatents

    King, C. Judson; Husson, Scott M.

    2001-01-01

    Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent in the presence of carbon dioxide under pressure. The acids are freed from the sorbent phase by a suitable regeneration method, one of which is treating them with an organic alkylamine solution thus forming an alkylamine-carboxylic acid complex which thermally decomposes to the desired carboxylic acid and the alkylamine.

  7. Influence of Shrinkage and Swelling Properties of Coal on Geologic Sequestration of Carbon Dioxide

    SciTech Connect

    Siriwardane, H.J.; Gondle, R.; Smith, D.H.

    2007-05-01

    The potential for enhanced methane production and geologic sequestration of carbon dioxide in coalbeds needs to be evaluated before large-scale sequestration projects are undertaken. Geologic sequestration of carbon dioxide in deep unmineable coal seams with the potential for enhanced coalbed methane production has become a viable option to reduce greenhouse gas emissions. The coal matrix is believed to shrink during methane production and swell during the injection of carbon dioxide, causing changes in tlie cleat porosity and permeability of the coal seam. However, the influence of swelling and shrinkage, and the geomechanical response during the process of carbon dioxide injection and methane recovery, are not well understood. A three-dimensional swelling and shrinkage model based on constitutive equations that account for the coupled fluid pressure-deformation behavior of a porous medium was developed and implemented in an existing reservoir model. Several reservoir simulations were performed at a field site located in the San Juan basin to investigate the influence of swelling and shrinkage, as well as other geomechanical parameters, using a modified compositional coalbed methane reservoir simulator (modified PSU-COALCOMP). The paper presents numerical results for interpretation of reservoir performance during injection of carbon dioxide at this site. Available measured data at the field site were compared with computed values. Results show that coal swelling and shrinkage during the process of enhanced coalbed methane recovery can have a significant influence on the reservoir performance. Results also show an increase in the gas production rate with an increase in the elastic modulus of the reservoir material and increase in cleat porosity. Further laboratory and field tests of the model are needed to furnish better estimates of petrophysical parameters, test the applicability of thee model, and determine the need for further refinements to the mathematical

  8. Impacts of High Resolution Extreme Events on U.S. Energy Demand and CO{sub 2} Emissions in the 21st Century

    SciTech Connect

    Diffenbaugh, Noah

    2013-06-21

    Progress is reported in these areas: Validation of temperature and precipitation extremes; Time of emergence of severe heat stress in the United States; Quantifying the effects of temperature extremes on energy demand and carbon dioxide emissions.

  9. Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

    SciTech Connect

    Garcia, Julio Enrique

    2003-12-18

    Injection of carbon dioxide (CO{sub 2}) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO{sub 2} will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO{sub 2} and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO{sub 2}-H{sub 2}O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO{sub 2}. The basic problem of CO{sub 2} injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO{sub 2} injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO{sub 2} injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO{sub 2}. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO{sub 2} into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO{sub 2}) the viscosity of carbon dioxide can be less than the viscosity of the aqueous

  10. Efficient photocatalytic hydrogen generation by silica supported and platinum promoted titanium dioxide

    SciTech Connect

    Joshi, Meenal M.; Labhsetwar, Nitin K.; Parwate, D.V.; Rayalu, Sadhana S.

    2013-09-01

    Graphical abstract: Titanium dioxide was supported on mesoporous silica and promoted with Pt and Ru. The supported photocatalysts show high surface area and better photocatalytic activity in visible light as compared to the benchmark Degussa P25. These photocatalysts were characterized using XRD, BET-SA, and UV-DRS techniques. The surface area of supported photocatalyst was 140.6 m{sup 2}/g which is higher than Degussa P-25. Supported photocatalyst was evaluated for hydrogen evolution via water splitting reaction using ethanol as a sacrificial donor. Hydrogen yield observed is 4791.43 ?mol/h/g of TiO{sub 2} and that for P-25 is 161 ?mol/h/g of TiO{sub 2} under visible light irradiation. The value is 30 times higher than benchmark material Degussa P-25. This photocatalyst is also found stable up to 24 h without replenishing with sacrificial donor ethanol. - Highlights: Semiconductor titanium dioxide has been supported on silica gel and promoted with Pt by simple wet impregnation route. This synthesized photocatalyst is showing high surface area of 140.6 m{sup 2}/g with crystallite size in the range of 15.44 ?. This photocatalyst is showing enhanced hydrogen yield of about 4791.43 ?mol/h/g of TiO{sub 2}. This photocatalyst is also found stable up to 24 h without replenishing with sacrificial donor ethanol. The effect of various operating parameters on supported photocatalyst also has been studied. - Abstract: Titanium dioxide was supported on mesoporous silica and promoted with Pt and Ru. The supported photocatalysts show high surface area and better photocatalytic activity in visible light as compared to the benchmark Degussa P25. These photocatalysts were characterized using XRD, BET-SA, and UV-DRS techniques. The surface area of supported photocatalyst was 140.6 m{sup 2}/g which is higher than Degussa P-25. Supported photocatalyst was evaluated for hydrogen evolution via water splitting reaction using ethanol as a sacrificial donor. Hydrogen yield

  11. Preconceptual design of a salt splitting process using ceramic membranes

    SciTech Connect

    Kurath, D.E.; Brooks, K.P.; Hollenberg, G.W.; Clemmer, R.; Balagopal, S.; Landro, T.; Sutija, D.P.

    1997-01-01

    Inorganic ceramic membranes for salt splitting of radioactively contaminated sodium salt solutions are being developed for treating U. S. Department of Energy tank wastes. The process consists of electrochemical separation of sodium ions from the salt solution using sodium (Na) Super Ion Conductors (NaSICON) membranes. The primary NaSICON compositions being investigated are based on rare- earth ions (RE-NaSICON). Potential applications include: caustic recycling for sludge leaching, regenerating ion exchange resins, inhibiting corrosion in carbon-steel tanks, or retrieving tank wastes; reducing the volume of low-level wastes volume to be disposed of; adjusting pH and reducing competing cations to enhance cesium ion exchange processes; reducing sodium in high-level-waste sludges; and removing sodium from acidic wastes to facilitate calcining. These applications encompass wastes stored at the Hanford, Savannah River, and Idaho National Engineering Laboratory sites. The overall project objective is to supply a salt splitting process unit that impacts the waste treatment and disposal flowsheets and meets user requirements. The potential flowsheet impacts include improving the efficiency of the waste pretreatment processes, reducing volume, and increasing the quality of the final waste disposal forms. Meeting user requirements implies developing the technology to the point where it is available as standard equipment with predictable and reliable performance. This report presents two preconceptual designs for a full-scale salt splitting process based on the RE-NaSICON membranes to distinguish critical items for testing and to provide a vision that site users can evaluate.

  12. Split ring floating air riding seal for a turbine

    SciTech Connect

    Mills, Jacob A

    2015-11-03

    A floating air riding seal for a gas turbine engine with a rotor and a stator, an annular piston chamber with an axial moveable annular piston assembly within the annular piston chamber, an annular cavity formed on the annular piston assembly that faces a seal surface on the rotor, and a central passage connecting the annular cavity to the annular piston chamber to supply compressed air to the seal face, where the annular piston assembly is a split piston assembly to maintain a tight seal as coning of the rotor disk occurs.

  13. Systems and methods for displaying data in split dimension levels

    DOEpatents

    Stolte, Chris; Hanrahan, Patrick

    2015-07-28

    Systems and methods for displaying data in split dimension levels are disclosed. In some implementations, a method includes: at a computer, obtaining a dimensional hierarchy associated with a dataset, wherein the dimensional hierarchy includes at least one dimension and a sub-dimension of the at least one dimension; and populating information representing data included in the dataset into a visual table having a first axis and a second axis, wherein the first axis corresponds to the at least one dimension and the second axis corresponds to the sub-dimension of the at least one dimension.

  14. Regional Opportunities for Carbon Dioxide Capture and Storage in China: A Comprehensive CO2 Storage Cost Curve and Analysis of the Potential for Large Scale Carbon Dioxide Capture and Storage in the People’s Republic of China

    SciTech Connect

    Dahowski, Robert T.; Li, Xiaochun; Davidson, Casie L.; Wei, Ning; Dooley, James J.

    2009-12-01

    This study presents data and analysis on the potential for carbon dioxide capture and storage (CCS) technologies to deploy within China, including a survey of the CO2 source fleet and potential geologic storage capacity. The results presented here indicate that there is significant potential for CCS technologies to deploy in China at a level sufficient to deliver deep, sustained and cost-effective emissions reductions for China over the course of this century.

  15. Trading permanent and temporary carbon emissions credits

    SciTech Connect

    Marland, Gregg; Marland, Eric

    2009-08-01

    In this issue of Climatic Change, Van Kooten (2009) addresses an issue that has bedeviled negotiators since the drafting stage of the Kyoto Protocol. If we accept that increasing withdrawals of carbon dioxide from the atmpshere has the same net impact on the climate system as reducing emissions of carbon dioxide to the atmosphere, how do we design a system that allows trading of one for the other? As van Kooten expresses the challenge: 'The problem is that emissions reduction and carbon sequestration, while opposite sides of the same coin in some sense, are not directly comparable, thereby inhibiting their trade in carbon markets.' He explains: 'The difficulty centers on the length of time that mitigation strategies without CO{sub 2} from entering the atmosphere - the duration problem.' While reducing emissions of CO{sub 2} represents an essentially permanent benefit for the atmosphere, capturing CO{sub 2} that has been produced (whether capture is from the atmosphere or directly from, for example, the exhaust from power plants) there is the challenge of storing the carbon adn the risk that it will yet escape to the atmosphere. Permanent benefit to the atmosphere is often not assured for carbon sequestration activities. This is especially true if the carbon is taken up and stored in the biosphere - e.g. in forest trees or agricultural soils.

  16. Low Cost Open-Path Instrument for Monitoring Surface Carbon Dioxide at Sequestration Sites Phase I SBIR Final Report

    SciTech Connect

    Sheng Wu

    2012-10-02

    Public confidence in safety is a prerequisite to the success of carbon dioxide (CO2) capture and storage for any program that intends to mitigate greenhouse gas emissions. In that regard, this project addresses the security of CO2 containment by undertaking development of what is called ?¢????an open path device?¢??? to measure CO2 concentrations near the ground above a CO2 storage area.

  17. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  18. Understanding the contribution of non-carbon dioxide gases in deep mitigation scenarios

    SciTech Connect

    Gernaat, David; Calvin, Katherine V.; Lucas, Paul; Luderer, Gunnar; Otto, Sander; Rao, Shilpa; Strefler, Jessica; Van Vuuren, Detlef

    2015-07-01

    The combined 2010 emissions of methane (CH4), nitrous oxide (N2O) and the fluorinated gasses (F-gas) account for about 20-30% of total emissions and about 30% of radiative forcing. At the moment, most studies looking at reaching ambitious climate targets project the emission of carbon dioxide (CO2) to be reduced to zero (or less) by the end of the century. As for non-CO2 gases, the mitigation potential seem to be more constrained, we find that by the end of the century in the current deep mitigation scenarios non-CO2 emissions could form the lion’s share of remaining greenhouse gas emissions. In order to support effective climate policy strategies, in this paper we provide a more in-depth look at the role of non-CO2¬ emission sources (CH4, N2O and F-gases) in achieving deep mitigation targets (radiative forcing target of 2.8 W/m2 in 2100). Specifically, we look at the sectorial mitigation potential and the remaining non-CO2 emissions. By including a set of different models, we provide some insights into the associated uncertainty. Most of the remaining methane emissions in 2100 in the climate mitigation scenario come from the livestock sector. Strong reductions are seen in the energy supply sector across all models. For N2O, less reduction potential is seen compared to methane and the sectoral differences are larger between the models. The paper shows that the assumptions on remaining non-CO2 emissions are critical for the feasibility of reaching ambitious climate targets and the associated costs.

  19. Sequestration of Carbon Dioxide with Enhanced Gas Recovery-CaseStudy Altmark, North German Basin

    SciTech Connect

    Rebscher, Dorothee; Oldenburg, Curtis M.

    2005-10-12

    Geologic carbon dioxide storage is one strategy for reducingCO2 emissions into the atmosphere. Depleted natural gas reservoirs are anobvious target for CO2 storage due to their proven record of gascontainment. Germany has both large industrial sources of CO2 anddepleting gas reservoirs. The purpose of this report is to describe theanalysis and modeling performed to investigate the feasibility ofinjecting CO2 into nearly depleted gas reservoirs in the Altmark area inNorth Germany for geologic CO2 storage with enhanced gasrecovery.

  20. SULPHUR DIOXIDE LEACHING OF URANIUM CONTAINING MATERIAL

    DOEpatents

    Thunaes, A.; Rabbits, F.T.; Hester, K.D.; Smith, H.W.

    1958-12-01

    A process is described for extracting uranlum from uranium containing material, such as a low grade pitchblende ore, or mill taillngs, where at least part of the uraniunn is in the +4 oxidation state. After comminuting and magnetically removing any entrained lron particles the general material is made up as an aqueous slurry containing added ferric and manganese salts and treated with sulfur dioxide and aeration to an extent sufficient to form a proportion of oxysulfur acids to give a pH of about 1 to 2 but insufficient to cause excessive removal of the sulfur dioxide gas. After separating from the solids, the leach solution is adjusted to a pH of about 1.25, then treated with metallic iron in the presence of a precipitant such as a soluble phosphate, arsonate, or fluoride.

  1. Methane and carbon dioxide production from simulated anaerobic degradation of cattle carcasses

    SciTech Connect

    Yuan Qi; Saunders, Samuel E.; Bartelt-Hunt, Shannon L.

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer This study evaluates methane and carbon dioxide production after land burial of cattle carcasses. Black-Right-Pointing-Pointer Disposal of animal mortalities is often overlooked in evaluating the environmental impacts of animal production. Black-Right-Pointing-Pointer we quantify annual emissions from cattle carcass disposal in the United States as 1.6 Tg CO{sub 2} equivalents. - Abstract: Approximately 2.2 million cattle carcasses require disposal annually in the United States. Land burial is a convenient disposal method that has been widely used in animal production for disposal of both daily mortalities as well as during catastrophic mortality events. To date, greenhouse gas production after mortality burial has not been quantified, and this study represents the first attempt to quantify greenhouse gas emissions from land burial of animal carcasses. In this study, anaerobic decomposition of both homogenized and unhomogenized cattle carcass material was investigated using bench-scale reactors. Maximum yields of methane and carbon dioxide were 0.33 and 0.09 m{sup 3}/kg dry material, respectively, a higher methane yield than that previously reported for municipal solid waste. Variability in methane production rates were observed over time and between reactors. Based on our laboratory data, annual methane emissions from burial of cattle mortalities in the United States could total 1.6 Tg CO{sub 2} equivalents. Although this represents less than 1% of total emissions produced by the agricultural sector in 2009, greenhouse gas emissions from animal carcass burial may be significant if disposal of swine and poultry carcasses is also considered.

  2. Emissions of greenhouse gases in the United States 1997

    SciTech Connect

    1998-10-01

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  3. Carbon Cycle Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Information related to carbon cycle includes: • Terrestrial Carbon Sequestration Data Sets • Area and Carbon Content of Sphagnum Since Last Glacial Maximum (2002) (Trends Online) • Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2002) (Trends Online) • Estimates of Monthly CO2 Emissions and Associated 13C/12C Values from Fossil-Fuel Consumption in the U.S.A., (2004) (Trends Online) • Estimates of Annual Fossil-Fuel CO2 Emitted for Each State in the U.S.A. and the District of Columbia for Each Year from 1960 through 2001 (Trends Online) • Global, Regional, and National Annual CO2 Emissions from Fossil-Fuel Burning, Cement Production, and Gas Flaring: 1751-1999 (updated 2002) • Geographic Patterns of Carbon Dioxide Emissions from Fossil-Fuel Burning, Hydraulic Cement Production, and Gas Flaring on a One Degree by One Degree Grid Cell Basis: 1950 to 1990 (1997) • Carbon Dioxide Emission Estimates from Fossil-Fuel Burning, Hydraulic Cement Production, and Gas Flaring for 1995 on a One Degree Grid Cell Basis (1998) • AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Intergovernmental Panel on Climate Change (IPCC), Working Group 1, 1994: Modelling Results Relating Future Atmospheric CO2 Concentrations to Industrial Emissions (1995) • Interannual Variability in Global Soil Respiration on a 0.5 Degree Grid Cell Basis (1980-1994) (2003) • Global

  4. Extraction of furfural with carbon dioxide

    SciTech Connect

    Gamse, T.; Marr, R.; Froeschl, F.; Siebenhofer, M.

    1997-01-01

    A new approach to separate furfural from aqueous waste has been investigated. Recovery of furfural and acetic acid from aqueous effluents of a paper mill has successfully been applied on an industrial scale since 1981. The process is based on the extraction of furfural and acetic acid by the solvent trooctylphosphineoxide (TOPO). Common extraction of both substances may cause the formation of resin residues. Improvement was expected by selective extraction of furfural with chlorinated hydrocarbons, but ecological reasons stopped further development of this project. The current investigation is centered in the evaluation of extraction of furfural by supercritical carbon dioxide. The influence of temperature and pressure on the extraction properties has been worked out. The investigation has considered the multi-component system furfural-acetic acid-water-carbon dioxide. Solubility of furfural in liquid and supercritical carbon dioxide has been measured, and equilibrium data for the ternary system furfural-water-CO{sub 2} as well as for the quaternary system furfural-acetic acid-water-CO{sub 2} have been determined. A high-pressure extraction column has been used for evaluation of mass transfer rates.

  5. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  6. Emissions of greenhouse gases in the United States 1996

    SciTech Connect

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  7. EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions

    Gasoline and Diesel Fuel Update

    4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13

  8. Closing the Circle on the Splitting of the Atom | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Closing the Circle on the Splitting of the Atom Closing the Circle on the Splitting of the Atom This report was the first report published in the new Departmental era of openness that described existing environmental, safety, and health problems throughout the nuclear weapons complex and the cleanup challenges that DOE faced. It also provided initial plans for what DOE was doing to address these problems. Closing the Circle on the Splitting of the Atom (4.77 MB) More Documents & Publications

  9. Spin rotators and split Siberian Snakes (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Spin rotators and split Siberian Snakes Citation Details In-Document ... DOE Contract Number: AC02-98CH10886 Resource Type: Journal Article Resource Relation: ...

  10. Process and apparatus for split feed of spent catalyst to high...

    Office of Scientific and Technical Information (OSTI)

    Title: Process and apparatus for split feed of spent catalyst to high efficiency catalyst regenerator This patent describes a fluidized catalytic cracking process for catalytic ...

  11. Isoscalar and Isovector Splitting of Pygmy Dipole Structures

    SciTech Connect

    Paar, N.; Vretenar, D.; Niu, Y. F.; Meng, J.

    2009-07-17

    The electric-dipole response of {sup 140}Ce is investigated using the fully consistent relativistic quasiparticle random phase approximation. By analyzing the isospin structure of the E1 response, it is shown that the low-energy (pygmy) strength separates into two segments with different isospin character. The more pronounced pygmy structure at lower energy is composed of predominantly isoscalar states with surface-peaked transition densities. At somewhat higher energy the calculated E1 strength is primarily of isovector character, as expected for the low-energy tail of the giant dipole resonance. The results are in qualitative agreement with those obtained in recent (gamma, gamma{sup '}) and (alpha, alpha{sup '}gamma) experiments, and provide a simple explanation for the splitting of low-energy E1 strength into two groups of states with different isospin structure and radial dependence of the corresponding transition densities.

  12. Method of immobilizing carbon dioxide from gas streams

    DOEpatents

    Holladay, David W.; Haag, Gary L.

    1979-01-01

    This invention is a method for rapidly and continuously immobilizing carbon dioxide contained in various industrial off-gas streams, the carbon dioxide being immobilized as dry, stable, and substantially water-insoluble particulates. Briefly, the method comprises passing the gas stream through a fixed or fluidized bed of hydrated barium hydroxide to remove and immobilize the carbon dioxide by converting the bed to barium carbonate. The method has several important advantages: it can be conducted effectively at ambient temperature; it provides a very rapid reaction rate over a wide range of carbon dioxide concentrations; it provides high decontamination factors; and it has a high capacity for carbon dioxide. The invention is especially well suited for the removal of radioactive carbon dioxide from off-gases generated by nuclear-fuel reprocessing facilities and nuclear power plants.

  13. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  14. Historic Patterns of CO{sub 2} Emissions from Fossil Fuels: Implications for Stabilization of Emissions

    DOE R&D Accomplishments

    Andres, R. J.; Marland, G.

    1994-06-01

    This paper examines the historical record of greenhouse gas emissions since 1950, reviews the prospects for emissions into the future, and projects what would be the short-term outcome if the stated targets of the FCCC were in fact achieved. The examination focuses on the most important of the greenhouse gases, CO{sub 2}. The extensive record of historic CO{sub 2} emissions is explored to ascertain if it is an adequate basis for useful extrapolation into the near future. Global carbon dioxide emissions from fossil fuel consumption have been documented. Emissions grew at 4.3% per year from 1950 until the time of the 1973 oil crisis. Another disruption in growth followed the oil price increases of 1979. Global total emissions have been increasing steadily since the 1982-1983 minimum and have grown by more than 20% since then. At present, emission Of CO{sub 2} from fossil fuel burning is dominated by a few countries: the U.S., the former Soviet Union, China, the developed countries of Europe and Japan. Only 20 countries emit 84% of emissions from all countries. However, rates of growth in many of the developed countries are now very low. In contrast, energy use has grown rapidly over the last 20 years in some of the large, developing economies. Emissions from fossil fuel consumption are now nearly 4 times those from land use change and are the primary cause of measured increases in the atmospheric concentration of CO{sub 2}. The increasing concentration of atmospheric CO{sub 2} has led to rising concern about the possibility of impending changes in the global climate system. In an effort to limit or mitigate potential negative effects of global climate change, 154 countries signed the United Nations Framework Convention on Climate Change (FCCC) in Rio de Janeiro in June, 1992. The FCCC asks all countries to conduct an inventory of their current greenhouse gas emissions setting non-binding targets.

  15. Carbon dioxide postcombustion capture: a novel screening study of the carbon dioxide absorption performance of 76 amines

    SciTech Connect

    Graeme Puxty; Robert Rowland; Andrew Allport; Qi Yang; Mark Bown; Robert Burns; Marcel Maeder; Moetaz Attalla

    2009-08-15

    The significant and rapid reduction of greenhouse gas emissions is recognized as necessary to mitigate the potential climate effects from global warming. The postcombustion capture (PCC) and storage of carbon dioxide (CO{sub 2}) produced from the use of fossil fuels for electricity generation is a key technology needed to achieve these reductions. The most mature technology for CO{sub 2} capture is reversible chemical absorption into an aqueous amine solution. In this study the results from measurements of the CO{sub 2} absorption capacity of aqueous amine solutions for 76 different amines are presented. Measurements were made using both a novel isothermal gravimetric analysis (IGA) method and a traditional absorption apparatus. Seven amines, consisting of one primary, three secondary, and three tertiary amines, were identified as exhibiting outstanding absorption capacities. Most have a number of structural features in common including steric hindrance and hydroxyl functionality 2 or 3 carbons from the nitrogen. Initial CO{sub 2} absorption rate data from the IGA measurements was also used to indicate relative absorption rates. Most of the outstanding performers in terms of capacity also showed initial absorption rates comparable to the industry standard monoethanolamine (MEA). This indicates, in terms of both absorption capacity and kinetics, that they are promising candidates for further investigation. 30 refs., 8 figs.

  16. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    California" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",1231,659,1067,2192,1784,1685,1521,3276,3458,3317,2740,2961,2100,5191,31138,26808,28804,28716,30315,28932,27401,36452,38256,34966,35118 "Natural

  17. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Georgia" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",70007,90671,111585,201596,232586,271800,530275,680050,682504,642737,577847,569995,545792,527893,537663,539691,547446,536134,498669,508871,581609,714951,793006,802209,887372 "Natural

  18. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Illinois" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",187419,203816,190049,228280,255068,261594,379321,332295,339864,386689,422783,406276,405000,442941,533290,806603,915074,927928,828237,722001,838330,856101,888651,883212,931708 "Natural

  19. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Indiana" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",296237,272707,285211,381921,423894,422362,611096,728833,834982,883283,876816,817139,788519,806646,901203,970849,1004788,1031517,985754,929710,1254199,1273057,1252700,1466280,1403502 "Natural

  20. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Kentucky" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",199709,185073,183247,241651,265949,247826,338318,370877,418872,490422,507490,522200,471904,535303,584707,658445,624913,669016,642197,676214,895584,983464,893411,871431,902063 "Natural

  1. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Louisiana" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",63526,68216,73702,75879,71513,64087,68625,71467,89748,90139,96242,95639,97918,95986,101453,112255,109681,117039,94470,97854,126282,117281,110572,107938,99934 "Natural

  2. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Massachusetts" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",3229,10397,11717,23520,37512,33573,42205,42039,39260,47569,45178,52634,58508,60644,69422,70840,70629,78943,69863,78900,70225,77311,93718,104570,100041 "Natural

  3. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Michigan" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",156939,200702,203862,230553,252712,294302,362921,358465,346823,362690,354593,369039,358670,370730,396468,406682,453444,439598,409709,388720,425868,392676,374114,405484,400043 "Natural

  4. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Mississippi" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",90609,77393,37116,43057,54267,40125,65730,67796,75871,66365,68531,68116,66065,69615,88588,78278,78763,76762,94981,82425,77122,89686,94690,97996,106348 "Natural

  5. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Missouri" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",149428,157176,149531,208591,255793,258025,278644,276798,279119,293134,292645,280869,247379,239803,214011,264723,301916,318865,368301,348474,537257,481519,683418,746419,794530 "Natural

  6. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    York" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",21804,21923,26957,48632,56528,51264,75552,102252,110055,133084,174467,205767,213903,217822,245827,243631,282135,265797,169786,235651,245005,257386,300430,290808,298461 "Natural

  7. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Ohio" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",328298,314945,360893,649158,643705,664660,760207,1022707,1037604,1157246,1150521,1250636,1193241,1191814,1258662,1318060,1426879,1462973,1485827,1209189,2085965,2172699,2204132,2247165,2213291 "Natural

  8. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Oklahoma" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",74880,76673,78406,95907,89405,100412,108043,108024,114991,112210,108869,117506,115993,110039,102417,110454,109339,116982,114705,122615,106452,118616,118121,113826,109400 "Natural

  9. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Pennsylvania" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",280590,262221,259319,338397,419602,635141,851401,958827,903023,1096135,996972,979095,949261,1041860,1113082,1049810,1118338,1159444,1158512,1191338,1209571,1240828,1266369,1269116,1288932 "Natural

  10. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Carolina" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",30379,35219,54683,80578,104316,104355,165245,177379,226662,226553,228180,216716,210658,216996,215214,230523,223531,207801,218040,191445,205896,195251,171280,177034,182269 "Natural

  11. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Texas" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",334864,364291,337533,430430,458950,448084,480396,494970,576589,592090,585566,632119,612135,581623,594287,721440,716364,718321,683539,636769,563557,619731,562293,544624,534050 "Natural

  12. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Virginia" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",55972,56438,49857,83949,117386,111860,136911,189547,190542,223296,200877,220539,279910,231117,277674,289507,268063,278805,263005,276636,220087,238627,227184,226261,213816 "Natural

  13. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    West Virginia" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",102380,93865,91218,107963,116023,184338,315497,388675,470639,483344,492024,558143,526538,681326,625874,713793,695681,701570,694797,630859,1091442,1045752,1102087,1068857,965899 "Natural

  14. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    United States" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",3425770,3537968,3625314,4890928,5468885,6100901,8103586,9247549,9774485,10470741,10402086,10679025,10787045,10918087,11761081,12624901,13241327,13459993,13019310,12332252,14768599,15258782,15498937,15696398,15741783 "Natural

  15. Updated State Air Emissions Regulations (released in AEO2010)

    Reports and Publications

    2010-01-01

    The Regional Greenhouse Gas Initiative (RGGI) is a program that includes 10 Northeast states that have agreed to curtail and reverse growth in their carbon dioxide (CO2) emissions. The RGGI program includes all electricity generating units with a capacity of at least 25 megawatts and requires an allowance for each ton of CO2 emitted. The first year of mandatory compliance was in 2009.

  16. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Alabama" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",123615,113429,135133,186320,213725,288261,368728,466093,474527,472326,424044,468920,460025,479716,532836,567267,598960,591936,609416,554692,537679,573035,537827,532016,534873 "Natural

  17. Haverford College Researchers Create Carbon Dioxide-Separating Polymer

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 Rebecca Raber, rraber@haverford.edu, +1 610 896 1038 gtoc.jpg Carbon dioxide gas separation is important for many environmental and energy applications. Molecular dynamics simulations are used to characterize a two-dimensional hydrocarbon polymer, PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon

  18. ARM - Lesson Plans: Plant Growth and Carbon Dioxide

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Plant Growth and Carbon Dioxide Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Lesson Plans: Plant Growth and Carbon Dioxide Objective The objective is to show how carbon dioxide in the air affects plant growth. Materials Each group of students will need the following: Graph paper Pencil

  19. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock

  20. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one year of operating experience with a transcritical carbon dioxide (TC CO2) booster refrigeration system at Delhaize America's Hannaford supermarket location in Turner, Maine. This supermarket, which began operation in June 2013, is the first supermarket installation in the U.S. of a TC CO2 booster

  1. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect

    Benson, Steven; Palo, Daniel; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-01

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, an Environmental Health and Safety (EH&S) Assessment was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment addressed air and particulate emissions as well as solid and liquid waste streams. The magnitude of the emissions and waste streams was estimated for evaluation purposes. EH&S characteristics of materials used in the system are also described. This document contains data based on the mass balances from both the 40 kJ/mol CO2 and 80 kJ/mol CO2 desorption energy cases evaluated in the Final Technical and Economic Feasibility study also conducted by Barr Engineering.

  2. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  3. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: ...

  4. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces...

    Office of Scientific and Technical Information (OSTI)

    Surfaces in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Authors: ...

  5. Carbon Dioxide Capture and Storage Demonstration in Developing...

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Capture and Storage Demonstration in Developing Countries: Analysis of Key Policy Issues and Barriers...

  6. Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X-ray Computed Microtomography Citation Details In-Document ...

  7. High-Efficiency Receivers for Supercritical Carbon Dioxide Cycles

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Brayton Energy's supercritical carbon dioxide (s-CO 2 ) solar receiver has the potential to significantly improve reliability, increase efficiency, and reduce costs of CSP systems. ...

  8. Comprehensive study of carbon dioxide adsorption in the metal...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Comprehensive study of carbon dioxide adsorption in the metal-organic frameworks M2(dobdc) (M ... physisorptive interaction with the framework surface and sheds more light on the ...

  9. Beneficial Use of Carbon Dioxide in Precast Concrete Production...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide in Precast Concrete Production Shao, Yixin 36 MATERIALS SCIENCE Clean Coal Technology Coal - Environmental Processes Clean Coal Technology Coal - Environmental...

  10. Method for carbon dioxide sequestration (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    interbeds, providing an injection well into the formation and injecting supercritical carbon dioxide (SC--CO.sub.2) into the injection well under conditions of ...

  11. Carbon dioxide absorbent and method of using the same

    DOEpatents

    Perry, Robert James; O'Brien, Michael Joseph

    2014-06-10

    In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.

  12. Carbon dioxide absorbent and method of using the same

    DOEpatents

    Perry, Robert James; O'Brien, Michael Joseph

    2015-12-29

    In accordance with one aspect, the present invention provides a composition which contains the amino-siloxane structures I, or III, as described herein. The composition is useful for the capture of carbon dioxide from process streams. In addition, the present invention provides methods of preparing the amino-siloxane composition. Another aspect of the present invention provides methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention, as species which react with carbon dioxide to form an adduct with carbon dioxide.

  13. Theoretical analysis of uranium-doped thorium dioxide: Introduction...

    Office of Scientific and Technical Information (OSTI)

    polarization Citation Details In-Document Search Title: Theoretical analysis of uranium-doped thorium dioxide: Introduction of a thoria force field with explicit polarization ...

  14. Project Profile: Supercritical Carbon Dioxide Turbo-Expander...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Project Profile: ... Concentrating Solar Power (CSP) SunShot R&D funding opportunity announcement (FOA), are ...

  15. Synthesis, Structure, and Carbon Dioxide Capture Properties of...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks Previous Next List Anh Phan, Christian J. Doonan, Fernando J. Uribe-Romo, Carolyn B....

  16. Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    carbon dioxide (CO2) from low temperature and low pressure gas streams. In this process, the clay minerals are modified with organic materials to retain the amines....

  17. Thermo Scientific Sulfur Dioxide Analyzer Instrument Handbook (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Sulfur Dioxide Analyzer Instrument Handbook Citation Details In-Document Search Title: Thermo Scientific Sulfur Dioxide Analyzer Instrument Handbook The Sulfur Dioxide Analyzer measures sulfur dioxide based on absorbance of UV light at one wavelength by SO2 molecules which then decay to a lower energy state by emitting UV light at a longer wavelength. Specifically, SO2 + hυ1 →SO2 *→SO2 + hυ2 The emitted light is proportional to the concentration of SO2 in the

  18. Haverford College Researchers Create Carbon Dioxide-Separating...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    dioxide gas separation is important for many environmental and energy applications. Molecular dynamics simulations are used to characterize a two-dimensional hydrocarbon...

  19. Carbon Dioxide Geological Sequestration in Fractured Porous Rocks

    Office of Scientific and Technical Information (OSTI)

    Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Gutierrez, Marte 54 ENVIRONMENTAL...

  20. A Novel System for Carbon Dioxide Capture Utilizing Electrochemical...

    Office of Scientific and Technical Information (OSTI)

    Electric Power and Carbon-Dioxide Separation (CEPACS) system, under a contract from ... The unique chemistry of carbonate fuel cells offers an innovative approach for separation ...

  1. OSTIblog Articles in the carbon dioxide Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    regions and seasons, increasing intensity and frequency of storm events, flooding and... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  2. Development of methodologies for calculating greenhouse gas emissions from electricity generation for the California climate action registry

    SciTech Connect

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Murtishaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-04-01

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We fi nd that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  3. Enhanced control of mercury emissions through modified speciation

    SciTech Connect

    Livengood, C.D.; Mendelsohn, M.H.

    1997-07-01

    In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonne`s work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg{sup 0}.

  4. Rapid growth in CO2 emissions after the 2008-2009 global financial crisis

    SciTech Connect

    Peters, Glen P.; Marland, Gregg; Le Quere, Corinne; Boden, Thomas A; Canadell, Josep; Raupach, Michael

    2011-01-01

    Global carbon dioxide emissions from fossil-fuel combustion and cement production grew 5.9% in 2010, surpassed 9 Pg of carbon (Pg C) for the first time, and more than offset the 1.4% decrease in 2009. The impact of the 2008 2009 global financial crisis (GFC) on emissions has been short-lived owing to strong emissions growth in emerging economies, a return to emissions growth in developed economies, and an increase in the fossil-fuel intensity of the world economy.

  5. Update: Financing Innovation is Preventing Emissions Now and in the Future

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy Financing Innovation is Preventing Emissions Now and in the Future Update: Financing Innovation is Preventing Emissions Now and in the Future July 12, 2016 - 3:56pm Addthis Update: Financing Innovation is Preventing Emissions Now and in the Future Mark A. McCall Mark A. McCall Executive Director of the Loan Programs Office What are the key facts? As of April 2016, LPO's portfolio has prevented 30 million metric tons of carbon dioxide emissions, the equivalent of taking

  6. Work Together or Go It Alone? Microbes Are Split on the Answer...

    Office of Science (SC)

    ... In these syntrophies, consumption of lactate (a common product of fermentation in anoxic environments) by D. vulgaris provided hydrogen and carbon dioxide to M. maripaludis, which ...

  7. High-emission cold cathode

    DOEpatents

    Mancebo, L.

    1974-01-29

    A field-emission cathode having a multitude of field emission points for emitting a copious stream of electrons when subjected to a high field is described. The cathode is constructed by compressing a multitude of tungsten strips alternately arranged with molybdenum strips and copper ribbons or compressing alternately arranged copper plated tungsten and molybdenum strips, heating the arrangement to braze the tungsten and molybdenum strips together with the copper, machining and grinding the exposed strip edges of one side of the brazed arrangement to obtain a precisely planar surface, etching a portion of the molybdenum and copper to leave the edges of the tungsten strips protruding for electron emission, and subjecting the protruding edges of the tungsten strips to a high electric field to degas and roughen the surface to pnovide a large number of emitting points. The resulting structure is particularly useful as a cathode in a transversely excited gaseous laser where the cathode is mounted in a vacuum chamber for emitting electrons under the influence of a high electric field between the cathode and an extractor grid. The electrons pass through the extractor grid, a thin window in the wall of the laser chamber and into the laser chamber which is filled with a gaseous mixture of helium, nitrogen, and carbon dioxide. A second grid is mounted on the gaseous side of the window. The electrons pass into the laser chamber under the influence of a second electric field between the second grid and an anode in the laser chamber to raise selected gas atoms of the gaseous mixture to appropriately excited states so that a subsequent coherent light beam passing through the mixture transversely to the electron stream through windows in opposite ends of the laser chamber stimulates the excited atoms to amplify the beam. (Official Gazette)

  8. Carbon Dioxide Capture and Transportation Options in the Illinois Basin

    SciTech Connect

    M. Rostam-Abadi; S. S. Chen; Y. Lu

    2004-09-30

    This report describes carbon dioxide (CO{sub 2}) capture options from large stationary emission sources in the Illinois Basin, primarily focusing on coal-fired utility power plants. The CO{sub 2} emissions data were collected for utility power plants and industrial facilities over most of Illinois, southwestern Indiana, and western Kentucky. Coal-fired power plants are by far the largest CO{sub 2} emission sources in the Illinois Basin. The data revealed that sources within the Illinois Basin emit about 276 million tonnes of CO2 annually from 122 utility power plants and industrial facilities. Industrial facilities include 48 emission sources and contribute about 10% of total emissions. A process analysis study was conducted to review the suitability of various CO{sub 2} capture technologies for large stationary sources. The advantages and disadvantages of each class of technology were investigated. Based on these analyses, a suitable CO{sub 2} capture technology was assigned to each type of emission source in the Illinois Basin. Techno-economic studies were then conducted to evaluate the energy and economic performances of three coal-based power generation plants with CO{sub 2} capture facilities. The three plants considered were (1) pulverized coal (PC) + post combustion chemical absorption (monoethanolamine, or MEA), (2) integrated gasification combined cycle (IGCC) + pre-combustion physical absorption (Selexol), and (3) oxygen-enriched coal combustion plants. A conventional PC power plant without CO2 capture was also investigated as a baseline plant for comparison. Gross capacities of 266, 533, and 1,054 MW were investigated at each power plant. The economic study considered the burning of both Illinois No. 6 coal and Powder River Basin (PRB) coal. The cost estimation included the cost for compressing the CO{sub 2} stream to pipeline pressure. A process simulation software, CHEMCAD, was employed to perform steady-state simulations of power generation systems

  9. Method for extracting and sequestering carbon dioxide

    DOEpatents

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2005-05-10

    A method and apparatus to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said method and apparatus hydrates CO.sub.2, and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  10. Apparatus for extracting and sequestering carbon dioxide

    DOEpatents

    Rau, Gregory H. (Castro Valley, CA); Caldeira, Kenneth G. (Livermore, CA)

    2010-02-02

    An apparatus and method associated therewith to extract and sequester carbon dioxide (CO.sub.2) from a stream or volume of gas wherein said apparatus hydrates CO.sub.2 and reacts the resulting carbonic acid with carbonate. Suitable carbonates include, but are not limited to, carbonates of alkali metals and alkaline earth metals, preferably carbonates of calcium and magnesium. Waste products are metal cations and bicarbonate in solution or dehydrated metal salts, which when disposed of in a large body of water provide an effective way of sequestering CO.sub.2 from a gaseous environment.

  11. Capture of carbon dioxide by hybrid sorption

    DOEpatents

    Srinivasachar, Srivats

    2014-09-23

    A composition, process and system for capturing carbon dioxide from a combustion gas stream. The composition has a particulate porous support medium that has a high volume of pores, an alkaline component distributed within the pores and on the surface of the support medium, and water adsorbed on the alkaline component, wherein the proportion of water in the composition is between about 5% and about 35% by weight of the composition. The process and system contemplates contacting the sorbent and the flowing gas stream together at a temperature and for a time such that some water remains adsorbed in the alkaline component when the contact of the sorbent with the flowing gas ceases.

  12. Non-polar InGaN quantum dot emission with crystal-axis oriented linear polarization

    SciTech Connect

    Reid, Benjamin P. L. Chan, Christopher C. S.; Taylor, Robert A.; Kocher, Claudius; Zhu, Tongtong; Oehler, Fabrice; Oliver, Rachel A.

    2015-04-27

    Polarization sensitive photoluminescence is performed on single non-polar InGaN quantum dots. The studied InGaN quantum dots are found to have linearly polarized emission with a common polarization direction defined by the [0001] crystal axis. Around half of ∼40 studied dots have a polarization degree of 1. For those lines with a polarization degree less than 1, we can resolve fine structure splittings between −800 μeV and +800 μeV, with no clear correlation between fine structure splitting and emission energy.

  13. Limiting net greenhouse gas emissions in the United States

    SciTech Connect

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  14. Fact #949: October 31, 2016 Reduced CO2 Emissions in the Electric Power

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sector Will Benefit the Transportation Sector as Electrification Grows | Department of Energy 9: October 31, 2016 Reduced CO2 Emissions in the Electric Power Sector Will Benefit the Transportation Sector as Electrification Grows Fact #949: October 31, 2016 Reduced CO2 Emissions in the Electric Power Sector Will Benefit the Transportation Sector as Electrification Grows SUBSCRIBE to the Fact of the Week In 1973, the electric power sector produced 691 metric tons of carbon dioxide (CO2)

  15. Effect of low emission sources on air quality in Cracow

    SciTech Connect

    Nedoma, J.

    1995-12-31

    The paper presents calculation of power engineering low emission and results of stimulation of the effect of this emission on air quality in Cracow, Poland. It has been stated that the segment of low emission in central areas of the town makes up ca. 40% of the observed concentration of sulfur dioxide. Furthermore it has been stated that the capital investment must be concentrated in the central part of the town in order to reach noticeable improvement of air quality in Cracow. Neither the output of a separate power source nor the emission level and its individual harmful effect, but the location of the source and especially packing density of the sources must decide the priority of upgrading actions.

  16. Researchers Uncover Copper’s Potential for Reducing CO2 Emissions in Chemical Looping

    Energy.gov [DOE]

    Researchers at the Department of Energy’s National Energy Technology Laboratory (NETL) believe copper may play an important role in combatting climate change. When used as a part of a promising coal combustion technology known as chemical looping, copper can help economically remove carbon dioxide (CO2) from fossil fuel emissions.

  17. ZERO EMISSION COAL POWER, A NEW CONCEPT

    SciTech Connect

    H. -J. ZIOCK; K. S. LACKNER; D. P. HARRISON

    2001-04-01

    The Zero Emission Coal Alliance (ZECA) is developing an integrated zero emission process that generates clean energy carriers (electricity or hydrogen) from coal. The process exothermically gasifies coal using hydrogen to produce a methane rich intermediate state. The methane is subsequently reformed using water and a CaO based sorbent. The sorbent supplies the energy needed to drive the reforming reaction and simultaneously removes the generated CO{sub 2} by producing CaCO{sub 3}. The resulting hydrogen product stream is split, approximately 1/2 going to gasify the next unit of coal, and the other half being the product. This product stream could then be split a second time, part being cleaned up with a high temperature hydrogen separation membrane to produce pure hydrogen, and the remainder used to generate electricity via a solid oxide fuel cell (SOFC). The inevitable high temperature waste heat produced by the SOFC would in turn be used to regenerate the CaO by calcining the CaCO{sub 3} product of the reforming stage thereby generating a pure stream of CO{sub 2}. The CO{sub 2} will be dealt with a mineral sequestration process discussed in other papers presented at this conference. The SOFC has the added advantage of doubling as an oxygen separation membrane, thereby keeping its exhaust stream, which is predominantly steam, free of any air. This exhaust stream is largely recycled back to the reforming stage to generate more hydrogen, with a slipstream being extracted and condensed. The slipstream carries with it the other initial contaminants present in the starting coal. Overall the process is effectively closed loop with zero gaseous emissions to the atmosphere. The process also achieves very high conversion efficiency from coal energy to electrical energy ({approximately} 70%) and naturally generates a pure stream of CO{sub 2} ready for disposal via the mineral sequestration process.

  18. Method for synthesis of titanium dioxide nanotubes using ionic liquids

    SciTech Connect

    Qu, Jun; Luo, Huimin; Dai, Sheng

    2013-11-19

    The invention is directed to a method for producing titanium dioxide nanotubes, the method comprising anodizing titanium metal in contact with an electrolytic medium containing an ionic liquid. The invention is also directed to the resulting titanium dioxide nanotubes, as well as devices incorporating the nanotubes, such as photovoltaic devices, hydrogen generation devices, and hydrogen detection devices.

  19. New experimental techniques with the split Hopkinson pressure bar

    SciTech Connect

    Frantz, C.E.; Follansbee, P.S.; Wright, W.J.

    1984-01-01

    The split Hopkinson pressure bar or Kolsky bar has provided for many years a technique for performing compression tests at strain rates approaching 10/sup 4/ s/sup -1/. At these strain rates, the small dimensions possible in a compression test specimen give an advantage over a dynamic tensile test by allowing the stress within the specimen to equilibrate within the shortest possible time. The maximum strain rates possible with this technique are limited by stress wave propagation in the elastic pressure bars as well as in the deforming specimen. This subject is reviewed in this paper, and it is emphasized that a slowly rising excitation is preferred to one that rises steeply. Experimental techniques for pulse shaping and a numerical procedure for correcting the raw data for wave dispersion in the pressure bars are presented. For tests at elevated temperature a bar mover apparatus has been developed which effectively brings the cold pressure bars into contact with the specimen, which is heated with a specially designed furnace, shortly before the pressure wave arrives. This procedure has been used successfully in tests at temperatures as high as 1000/sup 0/C.

  20. Electro-optic voltage sensor with beam splitting

    DOEpatents

    Woods, Gregory K.; Renak, Todd W.; Davidson, James R.; Crawford, Thomas M.

    2002-01-01

    The invention is a miniature electro-optic voltage sensor system capable of accurate operation at high voltages without use of the dedicated voltage dividing hardware typically found in the prior art. The invention achieves voltage measurement without significant error contributions from neighboring conductors or environmental perturbations. The invention employs a transmitter, a sensor, a detector, and a signal processor. The transmitter produces a beam of electromagnetic radiation which is routed into the sensor. Within the sensor the beam undergoes the Pockels electro-optic effect. The electro-optic effect produces a modulation of the beam's polarization, which is in turn converted to a pair of independent conversely-amplitude-modulated signals, from which the voltage of the E-field is determined by the signal processor. The use of converse AM signals enables the signal processor to better distinguish signal from noise. The sensor converts the beam by splitting the beam in accordance with the axes of the beam's polarization state (an ellipse) into at least two AM signals. These AM signals are fed into a signal processor and processed to determine the voltage between a ground conductor and the conductor on which voltage is being measured.

  1. Electro-optic voltage sensor with Multiple Beam Splitting

    DOEpatents

    Woods, Gregory K.; Renak, Todd W.; Crawford, Thomas M.; Davidson, James R.

    2000-01-01

    A miniature electro-optic voltage sensor system capable of accurate operation at high voltages without use of the dedicated voltage dividing hardware. The invention achieves voltage measurement without significant error contributions from neighboring conductors or environmental perturbations. The invention employs a transmitter, a sensor, a detector, and a signal processor. The transmitter produces a beam of electromagnetic radiation which is routed into the sensor. Within the sensor the beam undergoes the Pockels electro-optic effect. The electro-optic effect produces a modulation of the beam's polarization, which is in turn converted to a pair of independent conversely-amplitude-modulated signals, from which the voltage of the E-field is determined by the signal processor. The use of converse AM signals enables the signal processor to better distinguish signal from noise. The sensor converts the beam by splitting the beam in accordance with the axes of the beam's polarization state (an ellipse) into at least two AM signals. These AM signals are fed into a signal processor and processed to determine the voltage between a ground conductor and the conductor on which voltage is being measured.

  2. Carbon dioxide absorbent and method of using the same

    DOEpatents

    Perry, Robert James; Lewis, Larry Neil; O'Brien, Michael Joseph; Soloveichik, Grigorii Lev; Kniajanski, Sergei; Lam, Tunchiao Hubert; Lee, Julia Lam; Rubinsztajn, Malgorzata Iwona

    2011-10-04

    In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

  3. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect

    1995-09-25

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  4. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  5. Carbon Dioxide Information Analysis Center and World Data Center for Atmospheric Trace Gases, Fiscal Year 2002 Annual Report

    SciTech Connect

    Cushman, R.M.

    2003-08-28

    The Carbon Dioxide Information Analysis Center (CDIAC), which includes the World Data Center (WDC) for Atmospheric Trace Gases, is the primary global change data and information analysis center of the U.S. Department of Energy (DOE). More than just an archive of data sets and publications, CDIAC has, since its inception in 1982, enhanced the value of its holdings through intensive quality assurance, documentation, and integration. Whereas many traditional data centers are discipline-based (for example, meteorology or oceanography), CDIAC's scope includes potentially anything and everything that would be of value to users concerned with the greenhouse effect and global climate change, including atmospheric concentrations and atmospheric emissions of carbon dioxide (CO{sub 2}) and other radiatively active gases; the role of the terrestrial biosphere and the oceans in the biogeochemical cycles of greenhouse gases; long-term climate trends; the effects of elevated CO{sub 2} on vegetation; and the vulnerability of coastal areas to rising sea levels.

  6. Emissions Benefits of Distributed Generation in the Texas Market

    SciTech Connect

    Hadley, SW

    2005-06-16

    One potential benefit of distributed generation (DG) is a net reduction in air emissions. While DG will produce emissions, most notably carbon dioxide and nitrogen oxides, the power it displaces might have produced more. This study used a system dispatch model developed at Oak Ridge National Laboratory to simulate the 2012 Texas power market with and without DG. This study compares the reduction in system emissions to the emissions from the DG to determine the net savings. Some of the major findings are that 85% of the electricity displaced by DG during peak hours will be simple cycle natural gas, either steam or combustion turbine. Even with DG running as baseload, 57% of electricity displaced will be simple cycle natural gas. Despite the retirement of some gas-fired steam units and the construction of many new gas turbine and combined cycle units, the marginal emissions from the system remain quite high (1.4 lb NO{sub x}/MWh on peak and 1.1 lb NO{sub x}/MWh baseload) compared to projected DG emissions. Consequently, additions of DG capacity will reduce emissions in Texas from power generation in 2012. Using the DG exhaust heat for combined heat and power provides an even greater benefit, since it eliminates further boiler emissions while adding none over what would be produced while generating electricity. Further studies are warranted concerning the robustness of the result with changes in fuel prices, demands, and mixes of power generating technology.

  7. Laboratory Test Report for Fujitsu 12RLS and Mitsubishi FE12NA Mini-Split Heat Pumps

    SciTech Connect

    Winkler, Jon

    2011-09-01

    Mini-split heat pumps are being proposed as a new retrofit option to replace resistance heating in the Pacific Northwest. NREL has previously developed a field test protocol for mini-split systems to ensure consistent results from field tests. This report focuses on the development of detailed system performance maps for mini-split heat pumps so that the potential benefits of mini-split systems can be accurately analyzed for different climate regions and housing types.

  8. Diesel Emission Control Review

    Energy.gov [DOE]

    Reviews regulatory requirements and technology approaches for diesel emission control for heavy and light duty applications

  9. Vehicle Emissions Review- 2012

    Energy.gov [DOE]

    Reviews vehicle emission control highlighting representative studies that illustrate the state-of-the-art

  10. Molten uranium dioxide structure and dynamics

    DOE PAGES [OSTI]

    Skinner, L. B.; Parise, J. B.; Benmore, C. J.; Weber, J. K.R.; Williamson, M. A.; Tamalonis, A.; Hebden, A.; Wiencek, T.; Alderman, O. L.G.; Guthrie, M.; et al

    2014-11-21

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. Onmore » melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.« less

  11. Helium Migration Mechanisms in Polycrystalline Uranium Dioxide

    SciTech Connect

    Martin, Guillaume; Desgardin, Pierre; Sauvage, Thierry; Barthe, Marie-France; Garcia, Philippe; Carlot, Gaelle

    2007-07-01

    This study aims at identifying the release mechanisms of helium in uranium dioxide. Two sets of polycrystalline UO{sub 2} sintered samples presenting different microstructures were implanted with {sup 3}He ions at concentrations in the region of 0.1 at.%. Changes in helium concentrations were monitored using two Nuclear Reaction Analysis (NRA) techniques based on the {sup 3}He(d,{alpha}){sup 1}H reaction. {sup 3}He release is measured in-situ during sample annealing at temperatures ranging between 700 deg. C and 1000 deg. C. Accurate helium depth profiles are generated after each annealing stage. Results that provide data for further understanding helium release mechanisms are discussed. It is found that helium diffusion appears to be enhanced above 900 deg. C in the vicinity of grain boundaries possibly as a result of the presence of defects. (authors)

  12. Carbon dioxide research plan. A summary

    SciTech Connect

    Trivelpiece, Alvin W.; Koomanoff, F. A.; Suomi, Verner E.

    1983-11-01

    The Department of Energy is the lead federal agency for research related to atmospheric carbon dioxide. Its responsibility is to sponsor a program of relevant research, and to coordinate this research with that of others. As part of its responsibilities, the Department of Energy has prepared a research plan. The plan documented in this Summary delineated the logic, objectives, organization, background and current status of the research activities. The Summary Plan is based on research subplans in four specific areas: global carbon cycle, climate effects, vegetative response and indirect effects. These subplans have emanated from a series of national and international workshops, conferences, and from technical reports. The plans have been peer reviewed by experts in the relevant scientific fields. Their execution is being coordinated between the responsible federal and international government agencies and the involved scientific community.

  13. Layered solid sorbents for carbon dioxide capture

    DOEpatents

    Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

    2014-11-18

    A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

  14. Molten uranium dioxide structure and dynamics

    SciTech Connect

    Skinner, L. B.; Parise, J. B.; Benmore, C. J.; Weber, J. K.R.; Williamson, M. A.; Tamalonis, A.; Hebden, A.; Wiencek, T.; Alderman, O. L.G.; Guthrie, M.; Leibowitz, L.

    2014-11-21

    Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

  15. Coiled tubing drilling with supercritical carbon dioxide

    DOEpatents

    Kolle , Jack J.

    2002-01-01

    A method for increasing the efficiency of drilling operations by using a drilling fluid material that exists as supercritical fluid or a dense gas at temperature and pressure conditions existing at a drill site. The material can be used to reduce mechanical drilling forces, to remove cuttings, or to jet erode a substrate. In one embodiment, carbon dioxide (CO.sub.2) is used as the material for drilling within wells in the earth, where the normal temperature and pressure conditions cause CO.sub.2 to exist as a supercritical fluid. Supercritical carbon dioxide (SC--CO.sub.2) is preferably used with coiled tube (CT) drilling equipment. The very low viscosity SC--CO.sub.2 provides efficient cooling of the drill head, and efficient cuttings removal. Further, the diffusivity of SC--CO.sub.2 within the pores of petroleum formations is significantly higher than that of water, making jet erosion using SC--CO.sub.2 much more effective than water jet erosion. SC--CO.sub.2 jets can be used to assist mechanical drilling, for erosion drilling, or for scale removal. A choke manifold at the well head or mud cap drilling equipment can be used to control the pressure within the borehole, to ensure that the temperature and pressure conditions necessary for CO.sub.2 to exist as either a supercritical fluid or a dense gas occur at the drill site. Spent CO.sub.2 can be vented to the atmosphere, collected for reuse, or directed into the formation to aid in the recovery of petroleum.

  16. Electrochemical Membrane for Carbon Dioxide Separation and Power Generation

    SciTech Connect

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Hunt, Jennifer; Patel, Dilip; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

    2012-12-28

    uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric power while capturing CO2 from flue gas, such as from an existing pulverized coal (PC) plant. Laboratory scale testing of the ECM has verified the feasibility of the technology for CO2 separation from simulated flue gases of PC plants as well as combined cycle power plants and other industrial facilities. Recently, FCE was awarded a contract (DE-FE0007634) from the U.S. Department of Energy to evaluate the use of ECM to efficiently and cost effectively separate CO2 from the emissions of existing coal fired power plants. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of an existing PC plant with no more than 35% increase in the cost of electricity (COE) produced by the plant. The specific objectives and related activities planned for the project include: 1) conduct bench scale tests of a planar membrane assembly consisting of ten or more cells of about 0.8 m2 area each, 2) develop the detailed design for an ECM-based CO2 capture system applied to an existing PC plant, and 3) evaluate the effects of impurities (pollutants such as SO2, NOx, Hg) present in the coal plant flue gas by conducting laboratory scale performance tests of the membrane. The results of this project are anticipated to demonstrate that the ECM is an advanced technology, fabricated from inexpensive materials, based on proven operational track records, modular, scalable to large sizes, and a viable candidate for >90% carbon capture from existing PC plants. In this paper, the fundamentals of ECM technology including: material of construction, principal mechanisms of operation, carbon capture test results and the benefits of applications to PC plants will be presented.

  17. Active Diesel Emission Control Systems

    Office of Energy Efficiency and Renewable Energy (EERE)

    2004 Diesel Engine Emissions Reduction (DEER) Conferencen Presentation: RYPOS Active Diesel Emission Control Systems

  18. Designer organisms for photosynthetic production of ethanol from carbon dioxide and water

    DOEpatents

    Lee, James Weifu

    2011-07-05

    The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

  19. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions

  20. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOEpatents

    Johnson, R.; Steinberg, M.

    This invention relates to high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280/sup 0/C and containing as little as 36 mo1% ethylene and about 41 to 51 mo1% sulfur dioxide, and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10 to 50/sup 0/C, and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  1. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOEpatents

    Johnson, Richard; Steinberg, Meyer

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  2. DOE Announces $80 Million Investment to Build Supercritical Carbon Dioxide

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Pilot Plant Test Facility | Department of Energy Announces $80 Million Investment to Build Supercritical Carbon Dioxide Pilot Plant Test Facility DOE Announces $80 Million Investment to Build Supercritical Carbon Dioxide Pilot Plant Test Facility October 17, 2016 - 11:39am Addthis WASHINGTON - The U.S. Department of Energy (DOE) is awarding up to $80 million for a six-year project to design, build, and operate a 10-MWe (megawatts electrical) supercritical carbon dioxide (sCO2) pilot plant

  3. Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers Supercritical Carbon Dioxide Turbo-Expander and Heat Exchangers This fact sheet describes a supercritical carbon dioxide turbo-expander and heat exchangers project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Southwest Research Institute, is working to develop a megawatt-scale s-CO2 hot-gas turbo-expander optimized for the highly transient solar

  4. Design and demonstration of a spectrum-splitting photovoltaic concentrator module

    SciTech Connect

    Borden, P.G.; Gregory, P.E.; Moore, O.E.

    1982-11-01

    A spectrum splitting, concentrating photovoltaic module has been designed and fabricated that uses point focus curved facet Fresnel lenses to concentrate incident sunlight. The concentrated sunlight beam spectrum is split into a high and low energy part by a dichroic filter. The high energy part of the spectrum is transmitted to an AlGaAs solar cell and the low energy part is reflected to a Si cell. Spectrum splitting and using cells that respond best to the two parts of the spectrum splitting and using cells that respond best to the two parts of the spectrum gives a higher efficiency than the use of either cell alone. The experimental module has been tested which consists of 10 AlGaAs and 10 Si cells, and a sunlight to electricity conversion efficiency of 20% has been measured.

  5. Replacing Resistance Heating with Mini-Split Heat Pumps, Sharon, Connecticut (Fact Sheet)

    SciTech Connect

    Not Available

    2014-05-01

    Mini-split heat pumps can provide space heating and cooling in many climates and are relatively affordable. These and other features make them potentially suitable for retrofitting into multifamily buildings in cold climates to replace electric resistance heating or other outmoded heating systems. This report investigates the suitability of mini-split heat pumps for multifamily retrofits. Various technical and regulatory barriers are discussed and modeling was performed to compare long-term costs of substituting mini-splits for a variety of other heating and cooling options. A number of utility programs have retrofit mini-splits in both single family and multifamily residences. Two such multifamily programs are discussed in detail.

  6. Giant and tunable valley degeneracy splitting in MoTe 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    This content will become publicly available on September 7, 2016 Title: Giant and tunable valley degeneracy splitting in MoTe 2 Authors: Qi, Jingshan ; Li, Xiao ; Niu, Qian ; Feng, ...

  7. Quantum-splitting oxide-based phosphors, method of producing, and rules for designing the same

    DOEpatents

    Setlur, Anant Achyut; Comanzo, Holly Ann; Srivastava, Alok Mani

    2003-09-16

    Strontium and strontium calcium aluminates and lanthanum and lanthanum magnesium borates activated with Pr.sup.3+ and Mn.sup.2+ exhibit characteristics of quantum-splitting phosphors. Improved quantum efficiency may be obtained by further doping with Gd.sup.3+. Refined rules for designing quantum-splitting phosphors include the requirement of incorporation of Gd.sup.3+ and Mn.sup.2+ in the host lattice for facilitation of energy migration.

  8. Solar High Temperature Water-Splitting Cycle with Quantum Boost

    SciTech Connect

    Taylor, Robin; Davenport, Roger; Talbot, Jan; Herz, Richard; Genders, David; Symons, Peter; Brown, Lloyd

    2014-04-25

    A sulfur family chemical cycle having ammonia as the working fluid and reagent was developed as a cost-effective and efficient hydrogen production technology based on a solar thermochemical water-splitting cycle. The sulfur ammonia (SA) cycle is a renewable and sustainable process that is unique in that it is an all-fluid cycle (i.e., with no solids handling). It uses a moderate temperature solar plant with the solar receiver operating at 800°C. All electricity needed is generated internally from recovered heat. The plant would operate continuously with low cost storage and it is a good potential solar thermochemical hydrogen production cycle for reaching the DOE cost goals. Two approaches were considered for the hydrogen production step of the SA cycle: (1) photocatalytic, and (2) electrolytic oxidation of ammonium sulfite to ammonium sulfate in aqueous solutions. Also, two sub-cycles were evaluated for the oxygen evolution side of the SA cycle: (1) zinc sulfate/zinc oxide, and (2) potassium sulfate/potassium pyrosulfate. The laboratory testing and optimization of all the process steps for each version of the SA cycle were proven in the laboratory or have been fully demonstrated by others, but further optimization is still possible and needed. The solar configuration evolved to a 50 MW(thermal) central receiver system with a North heliostat field, a cavity receiver, and NaCl molten salt storage to allow continuous operation. The H2A economic model was used to optimize and trade-off SA cycle configurations. Parametric studies of chemical plant performance have indicated process efficiencies of ~20%. Although the current process efficiency is technically acceptable, an increased efficiency is needed if the DOE cost targets are to be reached. There are two interrelated areas in which there is the potential for significant efficiency improvements: electrolysis cell voltage and excessive water vaporization. Methods to significantly reduce water evaporation are

  9. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude

  10. Greenhouse gas emissions from forest, land use and biomass burning in Tanzania

    SciTech Connect

    Matitu, M.R.

    1994-12-31

    Carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) gases are the main contributors to the greenhouse effect that consequently results in global warming. This paper examines the sources and sinks of these gases from/to forest, land use and biomass burning and their likely contribution to climate change using IPCC/OECD methodology. Emissions have been calculated in mass units of carbon and nitrogen Emissions and uptake have been summed for each gas and the emissions converted to full molecular weights. Mismanagement of forests and land misuse have contributed much to greenhouse gas emissions in Tanzania. For example, cultivation methods, forest clearing, burning of savannah grass and indiscriminate logging (non-sustainable logging) have contributed significantly to greenhouse gas emissions. These categories contribute more than 90% of total CO{sub 2} emissions. However, the study shows that shifting cultivation, savannah burning and forest clearing for conversion to permanent crop land and pasture are the main contributors.

  11. Slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures

    DOEpatents

    Aines, Roger D.; Bourcier, William L.; Viani, Brian

    2013-01-29

    A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.

  12. International Energy Outlook 2016-Energy-related CO2 emissions - Energy

    Gasoline and Diesel Fuel Update

    Information Administration 9. Energy-related CO2 emissions print version Overview Because anthropogenic emissions of carbon dioxide (CO2) result primarily from the combustion of fossil fuels, energy consumption is at the center of the climate change debate. In the International Energy Outlook 2016 (IEO2016) Reference case, world energy-related CO2 emissions [331] increase from 32.3 billion metric tons in 2012 to 35.6 billion metric tons in 2020 and to 43.2 billion metric tons in 2040. The

  13. Pollutant emissions from portable kerosene-fired space heaters

    SciTech Connect

    Traynor, G.W.; Allen, J.R.; Apte, M.G.; Girman, J.R.; Hollowell, C.D.

    1983-06-01

    Indoor use of unvented combustion appliances is known to cause an increase in indoor air pollutants. We conducted laboratory tests on two radiant and two convective portable kerosene-fired space heaters to identify the pollutants they emit and to determine their emission rates. Results show that carbon dioxide, carbon monoxide, nitric oxide, nitrogen dioxide, and formaldehyde were emitted by both types of heaters and that the radiant heaters and one of the convective heaters also emitted trace amounts of fine particles. When such heaters are operated for 1 h in a 27-m/sup 3/ chamber with 0.4 air changes per hour, the resultant CO/sub 2/ concentrations are well above the U.S. occupational standard, and NO/sub 2/ concentrations are well above California's short-term outdoor standard.

  14. Membranes for separation of carbon dioxide

    DOEpatents

    Ku, Anthony Yu-Chung; Ruud, James Anthony; Ramaswamy, Vidya; Willson, Patrick Daniel; Gao, Yan

    2011-03-01

    Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

  15. A versatile metal-organic framework for carbon dioxide capture...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    versatile metal-organic framework for carbon dioxide capture and cooperative catalysis Previous Next List Jinhee Park, Jian-Rong Li, Ying-Pin Chen, Jiamei Yu, Andrey A. Yakovenko, ...

  16. Recent advances in carbon dioxide capture with metal-organic...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Recent advances in carbon dioxide capture with metal-organic frameworks Previous Next List ... Great progress in MOF materials for CO2 capture has been made in the past and reviewed ...

  17. Carbon dioxide capture-related gas adsorption and separation...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks Previous Next List Jian-Rong Li, Yuguang Ma, M. Colin McCarthy, Julian Sculley, Jiamei Yu,...

  18. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Thomas Nelson; Raghubir P. Gupta

    2005-01-01

    This report describes research conducted between October 1, 2004 and December 31, 2004 on the use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Two supported sorbents were tested in a bench scale fluidized bed reactor system. The sorbents were prepared by impregnation of sodium carbonate on to an inert support at a commercial catalyst manufacturing facility. One sorbent, tested through five cycles of carbon dioxide sorption in an atmosphere of 3% water vapor and 0.8 to 3% carbon dioxide showed consistent reactivity with sodium carbonate utilization of 7 to 14%. A second, similarly prepared material, showed comparable reactivity in one cycle of testing. Batches of 5 other materials were prepared in laboratory scale quantities (primarily by spray drying). These materials generally have significantly greater surface areas than calcined sodium bicarbonate. Small scale testing showed no significant adsorption of mercury on representative carbon dioxide sorbent materials under expected flue gas conditions.

  19. Carbon Dioxide Capture in Metal-Organic Frameworks | Center for...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Carbon Dioxide Capture in Metal-Organic Frameworks Previous Next List Kenji Sumida , David L. Rogow , Jarad A. Mason , Thomas M. McDonald , Eric D. Bloch , Zoey R. Herm , Tae-Hyun...

  20. Carbon Dioxide Capture: Prospects for New Materials | Center...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Carbon Dioxide Capture: Prospects for New Materials Previous Next List D. M. D'Alessandro, B. Smit, and J. R. Long, Angew. Chem.-Int. Edit. 49 (35), 6058 (2010) DOI: 10.1002...

  1. Formation of rare earth carbonates using supercritical carbon dioxide

    DOEpatents

    Fernando, Quintus; Yanagihara, Naohisa; Dyke, James T.; Vemulapalli, Krishna

    1991-09-03

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  2. Emissions trading comes of age as a strategic tool

    SciTech Connect

    Pospisil, R.

    1996-03-01

    Trading of emissions credits has quickly evolved from a curiosity to a viable compliance strategy for electric utilities and power-generating industrial firms. A sure sign that emissions trading has matured is the entry of power marketers onto the scene; in bundling pollution allowances with their electricity offerings, they are making their product more attractive - and stealing a page from the coal companies` strategy book to boot. Although most current activity involves credits for sulfur dioxide (SO{sub 2}), nitrogen oxide (NO{sub x}) trading is under way in certain areas as well, although NO{sub x} markets are local and thus slower to develop. However, utilities see economic development potential in this area; some are providing NO{sub x} credits to their industrial customers to help them comply with environmental regulations - and to retain their loyalty when deregulation affords them a choice of electricity suppliers. This paper briefly discusses the issues related to emissions trading.

  3. Catalytic effects of minerals on NOx emission from coal combustion

    SciTech Connect

    Yao, M.Y.; Che, D.F.

    2007-07-01

    The catalytic effects of inherent mineral matters on NOx emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NOx are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NOx mostly. But the mechanistic effect on NOx formation varies from coal to coal. Ca and Mg promote NOx emission. Na, K, Fe suppress NOx formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions.

  4. Carbon dioxide storage potential in coalbeds: A near-term consideration for the fossil energy industry

    SciTech Connect

    Byrer, C.W.; Guthrie, H.D.

    1998-07-01

    The concept of using gassy unminable coalbeds for carbon dioxide (CO2) storage while concurrently initiating and enhancing coalbed methane production may be a viable near-term system for industry consideration. Coal is the most abundant and cheapest fossil fuel resource, and it has played a vital role in the stability and growth of the US economy. With the burning of coal in power plants, the energy source is also one of the fuel causing large CO2 emissions. In the near future, coal may also have a role in solving environmental greenhouse gas concerns with increasing CO2 emissions throughout the world. Coal resources may be an acceptable and significant geological sink for storing CO2 emissions in amenable unminable coalbeds while at the same time producing natural gas from gassy coalbeds. Industry proprietary research has shown that the recovery of coalbed methane can be enhanced by the injection of CO2 via well bores into coal deposits. Gassy coals generally have shown a 2:1 coal-absorption selectivity for CO2 over methane which could allow for the potential of targeting unminable coals near fossil fueled power plants to be utilized for storing stack gas CO2. Preliminary technical and economic assessments of this concept appear to merit further research leading to pilot demonstrations in selected regions of the US.

  5. Carbon dioxide storage potential in coalbeds: A near-term consideration for the fossil energy industry

    SciTech Connect

    Byrer, C.W.; Guthrie, H.D.

    1998-04-01

    The concept of using gassy unminable coalbeds for carbon dioxide (CO2) storage while concurrently initiating and enhancing coalbed methane production may be a viable near-term system for industry consideration. Coal is our most abundant and cheapest fossil fuel resource, and it has played a vital role in the stability and growth of the US economy. With the burning of coal in power plants, the energy source is also one of the fuels causing large CO2 emissions. In the near future, coal may also have a role in solving environmental greenhouse gas concerns with increasing CO2 emissions throughout the world. Coal resources may be an acceptable and significant {open_quotes}geological sink{close_quotes} for storing CO2 emissions in amenable unminable coalbeds while at the same time producing natural gas from gassy coalbeds. Industry proprietary research has shown that the recovery of coalbed methane can be enhanced by the injection of CO2 via well bores into coal deposits. Gassy coals generally have shown a 2:1 coal-absorption selectivity for CO2 over methane which could allow for the potential of targeting unminable coals near fossil fueled power plants to be utilized for storing stack gas CO2. Preliminary technical and economic assessments of this concept appear to merit further research leading to pilot demonstrations in selected re ions of the US.

  6. Integrated Energy System with Beneficial Carbon Dioxide (CO{sub 2}) Use

    SciTech Connect

    Sun, Xiaolei; Rink, Nancy

    2011-04-30

    To address the public concerns regarding the consequences of climate change from anthropogenic carbon dioxide (CO{sub 2}) emissions, the U.S. Department of Energy National Energy Technology Laboratory (DOE-NETL) is actively funding a CO{sub 2} management program to develop technologies capable of reducing the CO{sub 2} emissions from fossil fuel power plants and other industrial facilities. Over the past decade, this program has focused on reducing the costs of carbon capture and storage technologies. Recently, DOE-NETL launched an alternative CO{sub 2} mitigation program focusing on beneficial CO{sub 2} reuse and supporting the development of technologies that mitigate emissions by converting CO{sub 2} to solid mineral form that can be utilized for enhanced oil recovery, in the manufacturing of concrete or as a benign landfill, in the production of valuable chemicals and/or fuels. This project was selected as a CO{sub 2} reuse activity which would conduct research and development (R&D) at the pilot scale via a cost-shared Cooperative Agreement number DE-FE0001099 with DOE-NETL and would utilize funds setaside by the American Recovery and Reinvestment Act (ARRA) of 2009 for Industrial Carbon Capture and Sequestration R&D,

  7. NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

    SciTech Connect

    Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

    2011-07-15

    We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 – Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

  8. Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

    SciTech Connect

    Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer

    2005-07-01

    A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

  9. Project Profile: 10-Megawatt Supercritical Carbon Dioxide Turbine

    Energy.gov [DOE]

    The National Renewable Energy Laboratory (NREL) and its partners, under the 2012 SunShot Concentrating Solar Power (CSP) R&D funding opportunity announcement (FOA), aim to demonstrate a multi-megawatt power cycle using supercritical carbon dioxide (s-CO2) as the working fluid. The use of carbon dioxide instead of steam allows higher power-cycle efficiency and cycle components that are more compact.

  10. Tethered catalysts for the hydration of carbon dioxide

    DOEpatents

    Valdez, Carlos A; Satcher, Jr., Joe H; Aines, Roger D; Wong, Sergio E; Baker, Sarah E; Lightstone, Felice C; Stolaroff, Joshuah K

    2014-11-04

    A system is provided that substantially increases the efficiency of CO.sub.2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.

  11. New Texas Oil Project Will Help Keep Carbon Dioxide Underground |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Texas Oil Project Will Help Keep Carbon Dioxide Underground New Texas Oil Project Will Help Keep Carbon Dioxide Underground February 5, 2013 - 12:05pm Addthis The Air Products and Chemicals hydrogen production facilities in Port Arthur, Texas, is funded by the Energy Department through the 2009 Recovery Act. It is managed by the Office of Fossil Energy’s National Energy Technology Laboratory. | Photo credit Air Products and Chemicals hydrogen production facilities.

  12. First Direct Observation of Carbon Dioxide's Increasing Greenhouse Effect

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    at Earth's Surface First Direct Observation of Carbon Dioxide's Increasing Greenhouse Effect at Earth's Surface First Direct Observation of Carbon Dioxide's Increasing Greenhouse Effect at Earth's Surface Researchers Link Rising CO₂ Levels from Fossil Fuels to Radiative Forcing February 25, 2015 Contact: Dan Krotz, dakrotz@lbl.gov, 510-486-4019 ARM Alaska Caption: The scientists used incredibly precise spectroscopic instruments at two sites operated by the Department of Energy's

  13. Using supercritical carbon dioxide as a fracturing fluid

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Using supercritical carbon dioxide as a fracturing fluid Using supercritical carbon dioxide as a fracturing fluid The Laboratory team used a combination of experiments and modeling for the investigation. June 25, 2015 Simulation of a selection of the particle trajectories toward the well. Simulation of a selection of the particle trajectories toward the well. Communications Office (505) 667-7000 The Laboratory research is part of an ongoing project to make the necessary measurements and develop

  14. Evidence for impact ionization in vanadium dioxide (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Evidence for impact ionization in vanadium dioxide Citation Details In-Document Search This content will become publicly available on October 17, 2017 Title: Evidence for impact ionization in vanadium dioxide Authors: Holleman, Joshua ; Bishop, Michael M. ; Garcia, Carlos ; Vellore Winfred, J. S. R. ; Lee, Shinbuhm ; Lee, Ho Nyung ; Beekman, Christianne ; Manousakis, Efstratios ; McGill, Stephen A. Publication Date: 2016-10-17 OSTI Identifier: 1329101 Type: Publisher's

  15. Geologic Carbon Dioxide Storage Field Projects Supported by DOE's

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sequestration Program | Department of Energy Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program Geologic Carbon Dioxide Storage Field Projects Supported by DOE's Sequestration Program Background: The U.S. DOE's Sequestration Program began with a small appropriation of $1M in 1997 and has grown to be the largest most comprehensive CCS R&D program in the world. The U.S. DOE's sequestration program has supported a number of projects implementing CO2

  16. Carbon Ion Pump for Carbon Dioxide Removal - Energy Innovation Portal

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Carbon Ion Pump for Carbon Dioxide Removal Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary The limitation to reducing greenhouse gases in the atmosphere is the expense of stripping carbon dioxide from other combustion gases. Without a cost-effective means of accomplishing this, hydrocarbon resources cannot be used freely. A few power plants currently remove

  17. Carbon Emissions: Food Industry

    Energy Information Administration (EIA) (indexed site)

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  18. Nitrogen dioxide and respiratory illnesses in infants

    SciTech Connect

    Samet, J.M.; Lambert, W.E.; Skipper, B.J.; Cushing, A.H.; Hunt, W.C.; Young, S.A.; McLaren, L.C.; Schwab, M.; Spengler, J.D. )

    1993-11-01

    Nitrogen dioxide is an oxidant gas that contaminates outdoor air and indoor air in homes with unvented gas appliances. A prospective cohort study was carried out to test the hypothesis that residential exposure to NO2 increases incidence and severity of respiratory illnesses during the first 18 months of life. A cohort of 1,205 healthy infants from homes without smokers was enrolled. The daily occurrence of respiratory symptoms and illnesses was reported by the mothers every 2 wk. Illnesses with wheezing or wet cough were classified as lower respiratory tract. Indoor NO2 concentrations were serially measured with passive samplers place in the subjects' bedrooms. In stratified analyses, illness incidence rates did not consistently increase with exposure to NO2 or stove type. In multivariate analyses that adjusted for potential confounding factors, odds ratios were not significantly elevated for current or lagged NO2 exposures, or stove type. Illness duration, a measure of illness severity, was not associated with NO2 exposure. The findings can be extended to homes with gas stoves in regions of the United States where the outdoor air is not heavily polluted by NO2.

  19. Characteristics of titanium dioxide nanostructures synthesized via electrochemical anodization at different applied voltages

    SciTech Connect

    Cheong, Y. L.; Yam, F. K.; Hassan, Z.

    2015-05-15

    This paper presents the study of the growth of nanostructure titanium dioxide (TiO{sub 2}) via electrochemical anodization method. Both constant and alternating anodization voltage would be applied in this study. The effects of applied voltage on the morphological and structural properties were studied. Images of field emission scanning electron microscope (FE-SEM) revealed that morphology of nanostructure could be manipulated by changing the type and amount of applied voltage. Besides that, X-ray diffraction (XRD) results indicated that crystalline structures (anatase and rutile) could be obtained after being annealed at 700°C for 60 minutes. By analysing the data in XRD measurements, crystallite size of the TiO{sub 2} could be calculated by using the Scherrer method. Besides that, the relationship between mean crystallites sizes and anodization voltage would also be further studied in this paper.

  20. Table 10 U.S. Carbon Dioxide Emissions from Industrial Sector...

    Energy Information Administration (EIA) (indexed site)

    ...,14.243,16.98,14.158,13.246,15.45,17.492,19.881,16.376,13.226,13.586,11.604 " Asphalt & Road Oil",,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0 " Lubricants",,6.915,6.186,6.307,6.422,6....

  1. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Annual Energy Outlook

    Natural Gas Natural Gas Natural Gas Industrial Petroleum Asphalt and Road Oil Asphalt and Road Oil Industrial Petroleum Distillate Fuel Distillate Fuel Industrial Petroleum ...

  2. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2012

    Gasoline and Diesel Fuel Update

    ... Petroleum Hydrocarbon Gas Liquids Natural Gas Coal Nuclear Electricity Hydropower Biofuels: Ethanol & Biodiesel Wind Geothermal Solar ...

  3. Energy-Related Carbon Dioxide Emissions at the State Level, 2000...

    Energy Information Administration (EIA) (indexed site)

    ...www.eia.govnuclearstate United States energy map: http:www.eia.govstatemaps.cfm?srchome-f3 This is an interactive map of major energy facilities in the United ...

  4. Energy use and carbon dioxide emissions from steel production in China

    SciTech Connect

    Price, Lynn; Sinton, Jonathan; Worrell, Ernst; Phylipsen, Dian; Xiulian, Hu; Ji, Li

    2004-01-01

    In 1996, China manufactured just over 100 Mt of steel and became the world s largest steel producer. Official Chinese energy consumption statistics for the steel industry include activities not directly associated with the production of steel, double-count some coal-based energy consumption, and do not cover the entire Chinese steelmaking industry. In this paper, we make adjustments to the reported statistical data in order to provide energy use values for steel production in China that are comparable to statistics used internationally. We find that for 1996, official statistics need to be reduced by 1365 PJ to account for non-steel production activities and double-counting. Official statistics also need to be increased by 415 PJ in order to include steelmaking energy use of small plants not included in official statistics. This leads to an overall reduction of 950 PJ for steelmaking in China in 1996. Thus, the official final energy use value of 4018 PJ drops to 3067 PJ. In primary energy terms, the official primary energy use value of 4555 PJ is reduced to 3582 PJ when these adjustments are made.

  5. State-Level Energy-Related Carbon Dioxide Emissions, 2000-2012

    Energy Information Administration (EIA) (indexed site)

    Environment - Analysis & Projections - U.S. Energy Information Administration (EIA) U.S. Energy Information Administration - EIA - Independent Statistics and Analysis Sources & ...

  6. Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control

    SciTech Connect

    Li, Liyu; King, David L.

    2010-01-23

    It is known that sulfur oxides contribute significantly and deleteriously to the overall performance of lean-burn diesel engine aftertreatment systems, especially in the case of NOx traps. A Ag-based, fast regenerable SO2 absorbent has been developed and will be described. Over a temperature range of 300oC to 550oC, it absorbs almost all of the SO2 in the simulated exhaust gases during the lean cycles and can be fully regenerated by the short rich cycles at the same temperature. Its composition has been optimized as 1 wt% Pt-5wt%Ag-SiO2, and the preferred silica source for the supporting material has been identified as inert Cabosil fumed silica. The thermal instability of Ag2O under fuel-lean conditions at 230oC and above makes it possible to fast regenerate the sulfur-loaded absorbent during the following fuel-rich cycles. Pt catalyst helps reducing Ag2SO4 during rich cycles at low temperatures. And the chemically inert fumed SiO2 support gives the absorbent long term stability. This absorbent shows great potential to work under the same lean-rich cycling conditions as those imposed on the NOx traps, and thus, can protect the downstream particulate filter and the NOx trap from sulfur poisoning.

  7. Industrial market for sulfur dioxide emission-control systems. Final report. [Forecasting to 2000

    SciTech Connect

    Not Available

    1982-08-01

    Under the postulated EIA medium world oil price scenario, in which oil prices are projected to rise at a real rate of 2.2% per year, coal will represent from 78 to 91% of MFBI fuel consumption by the year 2000, up from the present 16%. This increase would occur even in the absence of FUA, because the cost of coal is substantially lower than the cost of oil or gas. Much of this market will develop in the relatively near to intermediate term (before 1990). Annual installations will be much lower (by about 40%) after that period, reflecting a lower overall steam demand growth rate and the fact that much of the discretionary conversion of gas and oil boilers to coal will have been completed. About 22% of the sales will be for discretionary conversion of oil and gas boilers still having some useful life; the rest will be for nondiscretionary expansion or replacement of worn-out boilers. Under the postulated cost and performance estimates for the competing coal-burning technologies, we expect that AFB combustors and lime spray dryer FGD systems will dominate the market, with 42% of the market in our base case scenario. If the attitudes of the industrial decision-makers are factored into the analyses, particularly their aversion to FGD systems with wet wastes, the AFB and lime spray dryer technologies will capture as much as 73% of the coal-burning market. Costs for the various flue gas desulfurization (FGD) technologies were projected to be sufficiently close that the selection of one over another will depend on site-specific factors such as the availability of waste disposal facilities, the demonstrated reliability of the particular systems, and the vendor's reputation.

  8. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  9. Environmental control technology for atmospheric carbon dioxide

    SciTech Connect

    Steinberg, M; Albanese, A S

    1980-01-01

    The impact of fossil fuel use in the United States on worldwide CO/sub 2/ emissions and the impact of increased coal utilization on CO/sub 2/ emission rates are assessed. The aspects of CO/sub 2/ control are discussed as well as the available CO/sub 2/ control points (CO/sub 2/ removal sites). Two control scenarios are evaluated, one based on the absorption of CO/sub 2/ contained in power plant flue gas by seawater; the other, based on absorption of CO/sub 2/ by MEA (Mono Ethanol Amine). Captured CO/sub 2/ is injected into the deep ocean in both cases. The analyses indicate that capture and disposal by seawater is energetically not feasible, whereas capture and disposal using MEA is a possibility. However, the economic penalities of CO/sub 2/ control are significant. The use of non-fossil energy sources, such as hydroelectric, nuclear or solar energy is considered as an alternative for limiting and controlling CO/sub 2/ emissions resulting from fossil energy usage.

  10. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  11. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Alaska" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",2678,2913,2945,2496,2411,2528,2657,2436,2377,2224,2352,2003,4545,4179,12561,8368,14490,13929,13523,14632,10598,10080,10152,10210,15458 "Natural gas",13,10,10,11,11,11,12,11,15,13,15,9,10,10,13,11,13,11,11,9,12,12,10,12,12

  12. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Arizona" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",22489,23613,21336,32674,36693,36140,48338,56547,49229,52823,60439,69394,70766,72877,74807,78901,105738,130165,124044,124899,142176,134872,131544,129444,125036 "Natural gas",74,79,70,55,67,80,83,86,73,64,79,58,51,58,36,17,17,9,3,7,8,6,10,6,7

  13. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Colorado" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",28407,39974,42818,46853,49433,47566,60452,64793,64512,63888,64999,77596,91396,93908,90489,93098,100573,101386,94727,96615,107836,99745,101864,98418,102580 "Natural gas",26,27,26,25,26,31,33,35,32,30,26,24,21,24,17,12,11,11,9,11,6,2,1,1,1

  14. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Connecticut" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",908,770,7247,503,1311,1313,3007,2737,2879,2816,2847,3419,5880,12228,21148,826,6824,12175,11335,11392,9645,9330,10225,11777,12265 "Natural gas",29,29,34,32,28,19,15,19,23,17,13,9,20,9,10,8,7,6,2,4,6,3,3,4,4

  15. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    District of Columbia" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Natural gas",0,0,0,0," "," "," "," "," "," "," "," "," "," "," "," "," "," "," ","

  16. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Hawaii" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",792,2209,1435,1287,1387,1663,1680,1060,1015,1274,1572,1475,2154,1433,12585,3354,4019,4820,4805,4357,3617,3211,2070,278,86 "Natural gas",403,373,325,426,95,121,93,89,89,110,122,127,106,76,902,582,579,537,455,588,53,50,52,51,49

  17. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Idaho" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",2094,3029,2301,1616,3801,1603,3358,4111,1689,1787,4238,3737,3116,987,2999,3506,3816,3005,3148,3177,5267,6079,6088,2978,6107 "Natural gas",6,8,4,2,3,2,3,3,2,2,3,3,1,2,2,2,2,2,1,1,2,2,1,1,1

  18. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Iowa" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",72805,92466,103353,107646,114216,99306,163998,147940,144691,148303,148788,152375,147800,153599,171226,170930,190205,168878,170396,182534,198945,218025,209712,224123,201125 "Natural gas",11,10,11,6,6,2,4,3,3,2,7,1,2,3,3,3,4,6,4,3,3,3,2,1,1

  19. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Kansas" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",31498,29975,32930,39191,44555,50230,93495,112481,108414,123188,114657,131419,124338,113912,112947,115880,117443,108221,116046,99115,71337,70094,65762,76140,85243 "Natural gas",4,6,17,6,7,6,6,2,2,2,1,2,3,4,2,64,4,1,2,6,6,4,3,10,7

  20. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Maine" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",559,540,292,401,546,476,1538,2006,2016,1840,1726,1423,1117,1593,6269,2349,2978,4015,3934,4090,4323,4505,4521,4465,5574 "Natural gas",8,8,11,13,14,14,13,13,12,15,20,22,23,22,7,0,0,0,0,0,0,0,0,0,0

  1. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Maryland" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",36332,37512,40857,51044,47095,214124,244867,278286,282500,284301,287448,272978,265412,259499,262294,261255,272677,254326,251603,229197,233251,251845,243295,238056,265492 "Natural gas",12,12,40,17,4,6,6,4,4,4,3,8,4,3,3,3,2,2,2,2,7,3,4,6,6

  2. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Minnesota" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",34022,30926,31068,52422,57174,66187,83399,85598,88204,89899,95334,91757,91775,77334,102028,108278,104657,109711,101136,97511,129370,125407,106236,90988,105228 "Natural gas",7,15,18,9,11,31,14,7,4,6,4,3,3,3,4,3,3,1,1,1,3,2,3,3,1

  3. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Montana" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",14254,16726,13490,16901,20469,20711,19989,22596,19849,19767,20971,17185,19797,30725,23733,25315,24694,22706,20068,36432,20996,20385,22070,20386,17702 "Natural gas",0,1,1,1,0,0,0,0,0,0,0,0,0,0,1,1,1,1,1,1,0,0,0,1,1

  4. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Nebraska" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",63940,66824,63689,74955,71501,77133,76598,69205,71725,73730,74657,69360,68130,70701,60647,61435,58084,62785,65736,61065,56657,60780,53652,53558,51742 "Natural gas",0,0,2,0,0,0,1,1,6,3,0,0,0,2,0,0,0,0,0,1,0,0,0,1,1

  5. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Nevada" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",10164,7366,4640,5225,7841,7856,9315,8488,9169,53291,54356,51433,49197,49926,52960,48612,49659,50086,52898,50190,52644,52075,56550,54099,53261 "Natural gas",52,57,58,49,53,60,55,63,53,45,37,28,21,97,41,12,20,13,18,13,15,12,11,6,7

  6. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Hampshire" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",2166,2689,1694,24041,36405,32333,36146,40115,38096,41306,37066,33607,38594,44473,46296,39840,40221,49137,41011,40508,37609,39548,42845,33246,41324 "Natural gas",8,8,16,15,13,11,14,7,11,10,7,15,0,0,1,0,0,0,0,0,0,0,0," ","

  7. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Jersey" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",2395,2333,2866,4464,15060,12671,38115,50089,61099,69561,51500,50631,48855,50013,80835,63535,61420,73406,67588,58450,50184,56327,55383,57266,69123 "Natural gas",33,37,73,79,51,32,29,23,25,22,14,29,23,33,40,41,36,41,43,51,49,46,40,30,22

  8. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Mexico" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",12014,17706,16538,17799,16546,19273,22214,26645,31168,30757,38493,51035,50982,62371,69031,73913,81488,82737,78595,75755,63018,57673,58306,50395,59574 "Natural gas",43,23,22,23,22,21,20,17,18,9,8,9,10,14,11,12,14,11,12,168,9,8,7,8,9

  9. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Carolina" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",43936,51793,63584,81442,127715,123709,246364,392943,482961,516957,488210,481288,481923,473655,497039,497620,532992,556780,522206,439975,415724,472747,424519,374981,378382 "Natural gas",62,54,43,36,21,9,8,8,4,7,4,8,8,4,2,2,2,1,1,2,1,2,1,1,1

  10. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Dakota" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",52698,56827,87164,94480,127427,132855,136415,137982,130699,138294,150488,141328,141498,156233,153590,191764,195793,178826,178368,210373,152684,147327,146371,189694,146402 "Natural gas",0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,1

  11. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Oregon" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",7425,13959,11463,13100,15640,11050,11305,14027,8697,12104,12828,13522,12580,18027,14858,17160,13840,7342,6383,6143,16823,14892,16478,10708,7280 "Natural gas",46,52,39,27,52,63,69,44,32,34,30,28,23,28,24,18,19,10,10,7,9,6,6,4,2

  12. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Rhode Island" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Natural Gas",10,11,19,20,18,17,14,15,15,13,12,18,17,19,15,14,18,14,14,10,11,11,11,7,3 "Natural gas",2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,0,0,0,0,0

  13. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Dakota" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",13839,15332,12825,11249,13129,11929,13720,9194,11957,10723,14375,12596,25263,14439,14224,26837,24162,26742,16418,35460,33368,30740,31866,32623,31176 "Natural gas",1,1,0,0,0,0,0,0,0,0,0,1,0,1,1,0,0,0,0,0,0,0,0,0,0 "Other","

  14. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Tennessee" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",80454,78177,89276,144447,143016,130005,234674,265029,290290,297970,341496,370895,374163,396595,500011,533235,563085,614328,610082,570892,849088,895318,843606,796681,838243 "Natural gas",4,7,20,7,4,1,1,0,0,0,0,2,1,1,3,1,2,1,1,2,1,1,3,1,2

  15. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Utah" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",23525,23545,21953,24864,28075,32614,24593,27565,37366,34547,37057,35348,32849,35716,33918,30837,33609,33601,32715,33485,29978,32977,30210,28162,31653 "Natural gas",22,17,17,12,12,15,18,19,8,1,3,6,3,3,2,1,1,1,1,3,2,1,1,1,0

  16. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Washington" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",3362,2820,1690,1695,3221,4203,3123,2707,2256,3945,7475,9309,19572,68959,85701,89418,76615,65080,80288,55300,71156,73657,73826,63973,62933 "Natural gas",36,43,21,19,41,46,43,33,30,29,23,23,22,43,41,17,15,12,19,18,17,12,7,2,2

  17. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Wyoming" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",45629,49564,48004,85490,74270,83774,91179,91675,92333,96307,92960,92260,102300,94749,87414,106527,115147,107547,105501,113255,94338,82028,85538,84633,108365 "Natural gas",2,1,2,3,1,2,1,2,2,0,0,2,172,3,2,1,1,1,1,1,1,1,1,1,1

  18. Table 7. Electric power industry emissions estimates, 1990 through 2014

    Energy Information Administration (EIA) (indexed site)

    Arkansas" "Emission type", 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1998, 1997, 1996, 1995, 1994, 1993, 1992, 1991, 1990 "Sulfur dioxide (short tons)" "Coal",75942,74612,77622,73584,67035,68211,73160,71833,72868,65726,78479,71176,70031,74549,76060,78823,77315,86718,97033,84291,72229,66566,70208,70953,73346 "Natural gas",24,32,43,31,32,28,24,20,22,26,21,32,23,11,21,21,18,18,15,67,17,17,18,17,17

  19. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    SciTech Connect

    Nils Johnson; Joan Ogden

    2010-12-31

    In this final report, we describe research results from Phase 2 of a technical/economic study of fossil hydrogen energy systems with carbon dioxide (CO{sub 2}) capture and storage (CCS). CO{sub 2} capture and storage, or alternatively, CO{sub 2} capture and sequestration, involves capturing CO{sub 2} from large point sources and then injecting it into deep underground reservoirs for long-term storage. By preventing CO{sub 2} emissions into the atmosphere, this technology has significant potential to reduce greenhouse gas (GHG) emissions from fossil-based facilities in the power and industrial sectors. Furthermore, the application of CCS to power plants and hydrogen production facilities can reduce CO{sub 2} emissions associated with electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) and, thus, can also improve GHG emissions in the transportation sector. This research specifically examines strategies for transitioning to large-scale coal-derived energy systems with CCS for both hydrogen fuel production and electricity generation. A particular emphasis is on the development of spatially-explicit modeling tools for examining how these energy systems might develop in real geographic regions. We employ an integrated modeling approach that addresses all infrastructure components involved in the transition to these energy systems. The overall objective is to better understand the system design issues and economics associated with the widespread deployment of hydrogen and CCS infrastructure in real regions. Specific objectives of this research are to: Develop improved techno-economic models for all components required for the deployment of both hydrogen and CCS infrastructure, Develop novel modeling methods that combine detailed spatial data with optimization tools to explore spatially-explicit transition strategies, Conduct regional case studies to explore how these energy systems might develop in different regions of the United States, and Examine how the

  20. The splitted laser beam filamentation in interaction of laser and an exponential decay inhomogeneous underdense plasma

    SciTech Connect

    Xia Xiongping; Yi Lin; Xu Bin; Lu Jianduo

    2011-10-15

    The splitted beam filamentation in interaction of laser and an exponential decay inhomogeneous underdense plasma is investigated. Based on Wentzel-Kramers-Brillouin (WKB) approximation and paraxial/nonparaxial ray theory, simulation results show that the steady beam width and single beam filamentation along the propagation distance in paraxial case is due to the influence of ponderomotive nonlinearity. In nonparaxial case, the influence of the off-axial of {alpha}{sub 00} and {alpha}{sub 02} (the departure of the beam from the Gaussian nature) and S{sub 02} (the departure from the spherical nature) results in more complicated ponderomotive nonlinearity and changing of the channel density and refractive index, which led to the formation of two/three splitted beam filamentation and the self-distortion of beam width. In addition, influence of several parameters on two/three splitted beam filamentation is discussed.