National Library of Energy BETA

Sample records for bu tion cate

  1. CATEE Conference

    Energy.gov [DOE]

    The Clean Air Through Energy Efficiency (CATEE) Conference is coming to North Texas on Nov. 18-20, 2014, at the Sheraton Dallas Hotel.

  2. Cate Street Capital Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Cate Street Capital Inc Jump to: navigation, search Name: Cate Street Capital, Inc. Place: Portsmouth, New Hampshire Zip: 3801 Sector: Renewable Energy Product: New Hampshire-based...

  3. James TenCate elected Acoustical

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    James TenCate elected Acoustical Society of America fellow August 30, 2016 LOS ALAMOS, N.M., Aug. 30, 2016-Los Alamos National Laboratory mechanical engineer James TenCate was recently elected fellow by the Acoustical Society of America (ASA). TenCate, who leads the Modeling and Simulation Team in the Geophysics Group in the Earth and Environmental Sciences Division (EES), was honored for his contributions to nonlinear acoustics of earth materials. "Jim's research over the years has been

  4. James TenCate elected Acoustical Society of America fellow

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    TenCate elected Acoustical Society of America fellow James TenCate elected Acoustical Society of America fellow TenCate's research focuses on nonlinear acoustics and elasticity, seismology and nonlinear imaging. August 30, 2016 James TenCate James TenCate Contact Nancy Ambrosiano Communications Office (505) 667-0471 Email "We are thrilled to see Jim receive this recognition from the acoustics community for his efforts." LOS ALAMOS, N.M., Aug. 30, 2016-Los Alamos National Laboratory

  5. CLASSIFICdTION CAWXL~ DAm

    Office of Legacy Management (LM)

    CLASSIFICdTION CAWXL DAm NAR 6 1969 For the Atomic EhergY hDh+ ,' ROBERT L JACKSON (' t' for the Chief, Declassification BJx

  6. Haskel/BuTech/PPI

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Presentation For Argonne National Laboratory Haskel/BuTech/PPI Products * 100,000psi Liquid Pumps * 37,000psi Gas Boosters * 15,000psi Diaphragm Comp * 4,500psi Air Amplifiers * 150,000psi Valves, Fittings, and Tubing * 15,000psi Sub-Sea Valves (1" orifice) * Air Pilot Switches & Relief Valves Valves, Fittings & Tubing Pumps, Boosters, & Diaphragm Compressors & Systems Hydraulic Gas Booster Challenges * Global Material Regulations - KHK Japan recommends A286 & 316 SS

  7. Bu Sung: Noncompliance Determination (2015-SE-42007)

    Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Bu Sung America Corporation d/b/a Everest Refrigeration finding that basic model ESRF2, a commercial refrigerator-freezer does not comport with the energy conservation standards.

  8. Bu Sung: Order (2015-SE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Bu Sung: Order (2015-SE-42007) Bu Sung: Order (2015-SE-42007) October 13, 2015 DOE ordered Bu Sung America Corporation to pay a $71,480 civil penalty after finding Bu Sung had manufactured and distributed in commerce in the U.S. at least 361 units of basic model ESRF2, a noncompliant commercial refrigerator-freezer. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Bu Sung. Bu Sung: Order (2015-SE-42007) (123.64 KB) More Documents & Publications Bu

  9. Haskel/BuTech/PPI | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Haskel/BuTech/PPI Haskel/BuTech/PPI This presentation was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013. csd_workshop_5_walti.pdf (460.91 KB) More Documents & Publications DOE-HDBK-1018/2-93 Improving Compressed Air System Performance: A Sourcebook for Industry, Third Edition Improving Compressed Air System Performance: A Sourcebook for Industry

  10. BIG SANDY IDA ONEID A WILL IAM SBU RG BU RNIN G SPRIN GS WIN

    Annual Energy Outlook

    ... ASH BU RN C REEK HUNT ING CREEK RED BIRD C OALBED GREEN GROVE RPD-WAYNE-3 LOC UST HILL BU ... Division, Office of Oil and Gas, Energy Information Administration pursuant to ...

  11. BuD, a helix–loop–helix DNA-binding domain for genome modification

    SciTech Connect (OSTI)

    Stella, Stefano; Molina, Rafael; López-Méndez, Blanca; Juillerat, Alexandre; Bertonati, Claudia; Daboussi, Fayza; Campos-Olivas, Ramon; Duchateau, Phillippe; Montoya, Guillermo

    2014-07-01

    Crystal structures of BurrH and the BurrH–DNA complex are reported. DNA editing offers new possibilities in synthetic biology and biomedicine for modulation or modification of cellular functions to organisms. However, inaccuracy in this process may lead to genome damage. To address this important problem, a strategy allowing specific gene modification has been achieved through the addition, removal or exchange of DNA sequences using customized proteins and the endogenous DNA-repair machinery. Therefore, the engineering of specific protein–DNA interactions in protein scaffolds is key to providing ‘toolkits’ for precise genome modification or regulation of gene expression. In a search for putative DNA-binding domains, BurrH, a protein that recognizes a 19 bp DNA target, was identified. Here, its apo and DNA-bound crystal structures are reported, revealing a central region containing 19 repeats of a helix–loop–helix modular domain (BurrH domain; BuD), which identifies the DNA target by a single residue-to-nucleotide code, thus facilitating its redesign for gene targeting. New DNA-binding specificities have been engineered in this template, showing that BuD-derived nucleases (BuDNs) induce high levels of gene targeting in a locus of the human haemoglobin β (HBB) gene close to mutations responsible for sickle-cell anaemia. Hence, the unique combination of high efficiency and specificity of the BuD arrays can push forward diverse genome-modification approaches for cell or organism redesign, opening new avenues for gene editing.

  12. Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator

    SciTech Connect (OSTI)

    Zhang, Honghai; Xing, Chun-Hui; Hu, Qiao-Sheng; Hong, Kunlun

    2015-02-05

    The synthesis of well-defined and functionalized conjugated polymers, which are essential in the development of efficient organic electronics, through Suzuki cross-coupling polymerizations has been a challenging task. We developed controlled Pd(0)/t-Bu3P-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers via the chain-growth mechanism with a series of in situ generated ArPd(t-Bu3P)X (X = I, Br, Cl) complexes as initiators. Among them, the combinations of Pd2(dba)3/t-Bu3P/p-BrC6H4I, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br were identified as highly robust initiator systems, resulting in polymers with predictable molecular weight and narrow polydispersity (PDI~1.13-1.20). In addition, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br initiator systems afforded functional polymers with >95% fidelity. Our results paved the road to access well-defined conjugated polymers, including conjugated polymers with complex polymer architectures such as block copolymers and branch copolymers.

  13. Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator

    DOE PAGES-Beta [OSTI]

    Zhang, Honghai; Xing, Chun-Hui; Hu, Qiao-Sheng; Hong, Kunlun

    2015-02-05

    The synthesis of well-defined and functionalized conjugated polymers, which are essential in the development of efficient organic electronics, through Suzuki cross-coupling polymerizations has been a challenging task. We developed controlled Pd(0)/t-Bu3P-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers via the chain-growth mechanism with a series of in situ generated ArPd(t-Bu3P)X (X = I, Br, Cl) complexes as initiators. Among them, the combinations of Pd2(dba)3/t-Bu3P/p-BrC6H4I, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br were identified as highly robust initiator systems, resulting in polymers with predictable molecular weight and narrow polydispersity (PDI~1.13-1.20). In addition, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br initiator systems afforded functional polymers with >95% fidelity. Our results pavedmore » the road to access well-defined conjugated polymers, including conjugated polymers with complex polymer architectures such as block copolymers and branch copolymers.« less

  14. B.U. Students Talk Energy Research at Lost Dog Cafe > Archived News Stories

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    > The Energy Materials Center at Cornell Archived News Stories Latest News The perfect atom sandwich requires an extra layer › Cornell boasts 22 'highly cited' researchers › Postdoc brings open access issue to the table › In This Section EMC2 News Archived News Stories B.U. Students Talk Energy Research at Lost Dog Cafe April 10th, 2014 › There was a science café at the Lost Dog Cafe in Binghamton last night. A group of Binghamton University students and professors talked about

  15. Closure Plan for Corrective Action Unit 109: U-2bu Subsidence Crater Nevada Test Site, Nevada

    SciTech Connect (OSTI)

    Shannon Parsons

    1999-03-01

    The U-2bu subsidence crater, Corrective Action Unit 109, will be closed in accordance with the Resource Conservation and Recovery Act, the Nevada Division of Environmental Protection operational permit, and the Federal Facilities Agreement and Consent Order. The U-2bu subsidence crater is located in Area 2 of the Nevada Test Site. It was created in 1971 by an underground nuclear test with the name Miniata. The crater has a diameter of 288 meters (944 feet) and an approximate depth of 35 meters (115 feet). The subsidence crater was used as a land disposal unit for radioactive and hazardous waste from 1973 to 1988. Site disposal history is supported by memorandums, letters, and personnel who worked at the Nevada Test Site at the time of active disposal. Closure activities will include the excavation and disposal of impacted soil form the tip of the crater. Upon completion of excavation, verification samples will be collected to show that lead has been removed to concentrations be low regulatory action level. The area will then be backfilled and a soil flood diversion berm will be constructed, and certified by an independent professional engineer as to having followed the approved Closure Plan.

  16. Au133(SPh-tBu)52 Nanomolecules: X-ray Crystallography, Optical, Electrochemical, and Theoretical Analysis

    SciTech Connect (OSTI)

    Dass, Amala; Theivendran, Shevanuja; Nimmala, Praneeth Reddy; Kumara, Chanaka; Jupally, Vijay Reddy; Fortunelli, Alessandro; Sementa, Luca; Barcaro, Giovanni; Zuo, Xiaobing; Noll, Bruce C.

    2015-04-15

    Crystal structure determination has revolutionized modern science in biology, chemistry, and physics. However, the difficulty in obtaining periodic crystal lattices which are needed for X-ray crystal analysis has hindered the determination of atomic structure in nanomaterials, known as the nanostructure problem. Here, by using rigid and bulky ligands, we have overcome this limitation and successfully solved the X-ray crystallographic structure of the largest reported thiolated gold nanomolecule, Au133S52. The total composition, Au133(SPh-tBu)52, was verified using high resolution electrospray ionization mass spectrometry (ESI-MS). The experimental and simulated optical spectra show an emergent surface plasmon resonance that is more pronounced than in the slightly larger Au144(SCH2CH2Ph)60. Theoretical analysis indicates that the presence of rigid and bulky ligands is the key to the successful crystal formation.

  17. CUSSSFIC4TION CMUXLLq

    Office of Legacy Management (LM)

    At the timeofoastiug, the slutemperatame 188 probably scmewbere betaem Baja md 42000. These pieoee were oasttith thend ate; thfities wUbouttUbmmlopen.lng. Cnnone of these pieces ...

  18. The SpallaTion

    Office of Environmental Management (EM)

    ORNL had deep expertise in nuclear science, but it had never built an ... charged hydrogen ion (h - ) beam from 2.5 to 1000 million electron volts, as well as the low energy ...

  19. Pressure Build-Up During the Fire Test in Type B(U) Packages Containing Water - 13280

    SciTech Connect (OSTI)

    Feldkamp, Martin; Nehrig, Marko; Bletzer, Claus; Wille, Frank

    2013-07-01

    The safety assessment of packages for the transport of radioactive materials with content containing liquids requires special consideration. The main focus is on water as supplementary liquid content in Type B(U) packages. A typical content of a Type B(U) package is ion exchange resin, waste of a nuclear power plant, which is not dried, normally only drained. Besides the saturated ion exchange resin, a small amount of free water can be included in these contents. Compared to the safety assessment of packages with dry content, attention must be paid to some more specific issues. An overview of these issues is provided. The physical and chemical compatibility of the content itself and the content compatibility with the packages materials must be demonstrated for the assessment. Regarding the mechanical resistance the package has to withstand the forces resulting from the freezing liquid. The most interesting point, however, is the pressure build-up inside the package due to vaporization. This could for example be caused by radiolysis of the liquid and must be taken into account for the storage period. If the package is stressed by the total inner pressure, this pressure leads to mechanical loads to the package body, the lid and the lid bolts. Thus, the pressure is the driving force on the gasket system regarding the activity release and a possible loss of tightness. The total pressure in any calculation is the sum of partial pressures of different gases which can be caused by different effects. The pressure build-up inside the package caused by the regulatory thermal test (30 min at 800 deg. C), as part of the cumulative test scenario under accident conditions of transport is discussed primarily. To determine the pressure, the temperature distribution in the content must be calculated for the whole period from beginning of the thermal test until cooling-down. In this case, while calculating the temperature distribution, conduction and radiation as well as evaporation

  20. Accessing conjugated polymers with precisely controlled heterobisfunctional chain ends via post-polymerization modification of the OTf group and controlled Pd(0)/t-Bu3P-catalyzed Suzuki cross-coupling polymerization

    DOE PAGES-Beta [OSTI]

    Hu, Qiao -Sheng; Hong, Kunlun; Zhang, Hong -Hai

    2015-08-12

    In this study, a general strategy toward the synthesis of well-defined conjugated polymers with controlled heterobisfunctional chain ends via combination of controlled Pd(0)/t-Bu3P Suzuki cross-coupling polymerization with the post-polymerization modification of the triflate (OTf) group was disclosed.

  1. A Linear trans -Bis(imido) Neptunium(V) Actinyl Analog: NpV (NDipp)2 ( tBu2 bipy)2Cl (Dipp = 2,6- i Pr2C6H3)

    DOE PAGES-Beta [OSTI]

    Brown, Jessie L.; Batista, Enrique R.; Boncella, James M.; Gaunt, Andrew J.; Reilly, Sean D.; Scott, Brian L.; Tomson, Neil C.

    2015-07-22

    We present the discovery that imido analogs of actinyl dioxo cations can be extended beyond uranium into the transuranic elements. Synthesis of the Np(V) complex, Np(NDipp)2(tBu2bipy)2Cl (1), is achieved through treatment of a Np(IV) precursor with a bipyridine co-ligand and lithium-amide reagent. Complex 1 has been structurally characterized, analyzed by 1H NMR and UV/vis/NIR spectroscopies, and the electronic structure evaluated by DFT calculations.

  2. Synthesis and x-ray crystal structure determination of the first homoleptic four-coordinate phosphido complex of samarium: Sm[({mu}-P{sup 5}Bu{sub 2}){sub 2}Li(thf)]{sub 2}

    SciTech Connect (OSTI)

    Rabe, G.W.; Riede, J.; Schier, A.

    1996-04-24

    As part of an effort to develop the coordination environments of the lanthanides using phosphido ligands, as well as to investigate the corresponding bonding aspects, the authors have been examining the reaction behavior of lanthanide triflates with lithium bis(tert-butyl) phosphide. Recently, the authors described the synthesis and structural characterization of a novel four-coordinate homoleptic phosphido complex of divalent ytterbium: Yb[({mu}-P{sup t}Bu{sub 2}){sub 2}Li(thf)]{sub 2}. A question of considerable interest is how the size of the lanthanide cation influences the observed structure. To probe this issue, the authors decided to determine whether the structure of the above-mentioned ytterbium species in the solid state would change employing the larger samarium(II) cation in place of ytterbium-(II). Additionally, Yb[({mu}-P{sup t}Bu{sub 2}){sub 2}Li(thf)]{sub 2} was found to exhibit strongly photoluminescent properties. The authors wanted to find out whether this behavior is determined by the ligand system or the metal center. Here, the authors report the synthesis and X-ray crystal structure determination of a tetrakis(phosphido) species of divalent samarium.

  3. Michael J. Cates- 2014 Walter W. Maybee Award for Fire Protection

    Energy.gov [DOE]

    The DOE Fire Safety Committee recognizes Mr. Cates’ direct and indirect actions towards the protection of life and property both within and beyond the realm of DOE by presenting him the 2014 Walter W. Maybee Award.

  4. Microsoft PowerPoint - Geiser, 4-22-10, via Cate.ppt [Compatibility...

    Office of Environmental Management (EM)

    to LM: Pinellas, Weldon Spring, Monticello, Category 1 37 FY09 Sites by Category 6% Category 1 44% p g the Grand Junction Site, Fernald, Rocky Flats, and the 9 Nevada Off-Sites. ...

  5. UTICA 4, NEW YORK COFIPOR~TION

    Office of Legacy Management (LM)

    H. J. Zmjian, GE", of the ncmbers of our orzaniza- has a "Q" cl:arance and our President is rcqueoting an 'L" clearance for some of us. -'n would appreciate it very much if you ...

  6. Energy and charge transfers between (Bu{sub 4}N){sub 2}(Ru)(dcbpyH){sub 2}(NCS){sub 2} (N719) and ZnO thin films

    SciTech Connect (OSTI)

    Ni Manman; Cheng Qiang; Zhang, W. F.

    2010-03-15

    ZnO thin films and (Bu{sub 4}N){sub 2}(Ru)(dcbpyH){sub 2}(NCS){sub 2} (called N719) sensitized ZnO thin films are grown on fluorine-doped tin oxide (FTO) conducting glass substrates using laser molecular beam epitaxy. Ultraviolet-visible absorption, photoluminescence (PL), surface photovoltage spectroscopy, and Raman scattering are employed to probe into the transition process of photogenerated charges and the interaction between ZnO and N719. The experimental results indicate that there is a significant electronic interaction between N719 and ZnO through chemiadsorption. The interaction greatly enhances the photogenerated charge separation and thus the photovoltaic response of the ZnO film but remarkedly weakens its radiative recombination, i.e., PL, implying strong energy and charge transfer occurring between N719 and ZnO. In addition, a new PL peak observed at about 720 nm in N719 sensitized ZnO/FTO is attributed to the electron-hole recombination of N719.

  7. BPA CPTC BU Certification.pdf

    Energy Savers

    BETO Monthly News Blast, August 2013r BETO Monthly News Blast, August 2013r Copy of the BETO Monthly News Blast from August 2013 august_2013_newsblast.pdf (213.15 KB) More Documents & Publications Monthly News Blast: March 2013 BETO Monthly News Blast, June 2013 Monthly News Blast: July 2013

    BETO Monthly News Blast, June 2013 BETO Monthly News Blast, June 2013 The June 2013 monthly news blast covers Biomass 2013, the Program Management Review, upcoming industry events, and more.

  8. Combined Heat and Power Technology Fact Sheets Series: Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fuel cells use an electrochemical process to convert the chemical energy in a fuel to electricity. In contrast to recipro- cating engines and gas turbines, fuel cells generate electric- ity without combusting the fuel. The first practical applica- tion for fuel cells emerged in the 1950s when fuel cells were used to provide onboard power for spacecraft. Fuel cells continue to be used in space exploration, but over the past few decades the technology has migrated to other applica- tions,

  9. A Linear trans -Bis(imido) Neptunium(V) Actinyl Analog: NpV (NDipp)2 ( tBu2 bipy)2Cl (Dipp = 2,6- i Pr2C6H3)

    SciTech Connect (OSTI)

    Brown, Jessie L.; Batista, Enrique R.; Boncella, James M.; Gaunt, Andrew J.; Reilly, Sean D.; Scott, Brian L.; Tomson, Neil C.

    2015-07-22

    We present the discovery that imido analogs of actinyl dioxo cations can be extended beyond uranium into the transuranic elements. Synthesis of the Np(V) complex, Np(NDipp)2(tBu2bipy)2Cl (1), is achieved through treatment of a Np(IV) precursor with a bipyridine co-ligand and lithium-amide reagent. Complex 1 has been structurally characterized, analyzed by 1H NMR and UV/vis/NIR spectroscopies, and the electronic structure evaluated by DFT calculations.

  10. SANDIA COKPOK4TION SANDIA BASE, .QLDUQUERQUE. N. M.

    Office of Legacy Management (LM)

    F. k e r s , R. F. Beers, Inc. S. E . J e r m e , Univ. of Nev., Xeno %. L, B r m e , i h z e l t o n Nuclear Science Corp. 0. R. P l a c k , USPXS, Las Vegas, Nev. G. H. H i g ...

  11. Bu Sung: Proposed Penalty (2015-SE-42007) | Department of Energy

    Energy Savers

    Brett Humble About Us Brett Humble - New Hampshire State Energy Program Project Officer Brett Humble is the State Energy Program Project Officer for the State of New Hampshire. Most Recent Green Launching Pad Taps Six More Companies for Take-off April 29

    Brian Deese About Us Brian Deese - Deputy Director of the National Economic Council Most Recent Building Momentum June 28

    Industries | Department of Energy

    Bridging the Gap: Helping Small Businesses With Big Ideas Develop New

  12. Microsoft PowerPoint - Camper, ORNL-TN CAB-04-2010-final, via Cate 4-19-10.ppt [Compatibility Mode]

    Office of Environmental Management (EM)

    Chairs of the Environmental Management Site- Specific Advisory Board Specific Advisory Board Larry W. Camper, Director Division of Waste Management and Environmental Protection Off f S Office of Federal and State Materials and Environmental Management Programs April 28 2010 April 28, 2010 West Valley Demonstration Project * WVDP 1981 * WV Decommissioning Criteria * Interagency/Core Team Meetings * Review/Comment on Decommissioning Plan Review/Comment on Decommissioning Plan * Cooperating Agency

  13. Measurement of BR(Bu to phi K)/BR(Bu to J/psi K) at the collider detector at Fermilab

    SciTech Connect (OSTI)

    Napora, Robert A

    2004-10-01

    This thesis presents evidence for the decay mode B{sup {+-}} {yields} {phi}K{sup {+-}} in p{bar p} collisions at {radical}s = 1.96 TeV using (120 {+-} 7)pb{sup -1} of data collected by the Collider Detector at Fermilab (CDF). This signal is then used to measure the branching ratio relative to the decay mode B{sup {+-}} {yields} J/{psi}K{sup {+-}}. The measurement starts from reconstructing the two decay modes: B{sup {+-}} {yields} {phi}K{sup {+-}}, where {phi} {yields} K{sup +}K{sup -} and B{sup {+-}} {yields} J/{psi}K{sup {+-}}, where J/{psi} {yields} {mu}{sup +}{mu}{sup -}. The measurement yielded 23 {+-} 7 B{sup {+-}} {yields} {phi}K{sup {+-}} events, and 406 {+-} 26 B{sup {+-}} {yields} J/{psi}K{sup {+-}} events. The fraction of B{sup {+-}} {yields} J/{psi}K{sup {+-}} events where the J/{psi} subsequently decayed to two muons (as opposed to two electrons) was found to be f{sub {mu}{mu}} = 0.839 {+-} 0.066. The relative branching ratio of the two decays is then calculated based on the equation: BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = N{sub {phi}K}/N{sub {psi}K} {center_dot}f{sub {mu}{mu}} BR(J/{psi} {yields} {mu}{sup +}{mu}{sup -})/BR({phi} {yields} K{sup +}K{sup -}) {epsilon}{sub {mu}{mu}}K/{epsilon}KKK R({epsilon}{sub iso}). The measurement finds BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = 0.0068 {+-} 0.0021(stat.) {+-} 0.0007(syst.). The B{sup {+-}} {yields} {phi}K{sup {+-}} branching ratio is then found to be BR(B{sup {+-}} {yields} {phi}K{sup {+-}}) = [6.9 {+-} 2.1(stat.) {+-} 0.8(syst.)] x 10{sup -6}. This value is consistent with similar measurements reported by the e{sup +}e{sup -} collider experiments BaBar[1], Belle[2], and CLEO[3].

  14. ADVANTG 3.0.1: AutomateD VAriaNce reducTion Generator

    Energy Science and Technology Software Center (OSTI)

    2015-08-17

    Version 00 ADVANTG is an automated tool for generating variance reduction parameters for fixed-source continuous-energy Monte Carlo simulations with MCNP5 V1.60 (CCC-810, not included in this distribution) based on approximate 3-D multigroup discrete ordinates adjoint transport solutions generated by Denovo (included in this distribution). The variance reduction parameters generated by ADVANTG consist of space and energy-dependent weight-window bounds and biased source distributions, which are output in formats that can be directly used with unmodified versionsmore » of MCNP5. ADVANTG has been applied to neutron, photon, and coupled neutron-photon simulations of real-world radiation detection and shielding scenarios. ADVANTG is compatible with all MCNP5 geometry features and can be used to accelerate cell tallies (F4, F6, F8), surface tallies (F1 and F2), point-detector tallies (F5), and Cartesian mesh tallies (FMESH).« less

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Chen, Jian-Ping (6) Deur, Alexandre (6) Cates, Gordon (5) Chudakov, Eugene (5) Gao, Haiyan ... Ameya ; Miller, Jonathan ; Cates, Gordon ; Liyanage, Nilanga ; Wojtsekhowski, ...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Benmokhtar, Fatiha (4) Camsonne, Alexandre (4) Cates, Gordon (4) Save Results Save this ... Ameya ; Miller, Jonathan ; Cates, Gordon ; Liyanage, Nilanga ; Wojtsekhowski, ...

  17. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Aniol, Konrad (4) Averett, Todd (4) Cates, Gordon (4) Chudakov, Eugene (4) Save Results ... Ameya ; Miller, Jonathan ; Cates, Gordon ; Liyanage, Nilanga ; Wojtsekhowski, ...

  18. Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization...

    Office of Scientific and Technical Information (OSTI)

    systems afforded functional polymers with >95% fidelity. Our results paved the road to access well-defined conjugated polymers, including conjugated polymers with complex ...

  19. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    Annual Energy Outlook

    SEVEN SPRIN GS BR ISTORIA BELLEVERN ON MAYFIELD BIG MOSES BEN WOOD HUSTON KEY CRADDOCK DUF ... The boundaries are not informed by subsurface structural information. The data and methods ...

  20. BIG SANDY IDA ONEID A WILL IAM SBU RG BU RNIN G SPRIN GS WIN

    U.S. Energy Information Administration (EIA) (indexed site)

    315 Miles 2001 BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Appalachian Basin ...

  1. BIG SANDY IDA ONEID A WILL IAM SBU RG BU RNIN G SPRIN GS WIN

    U.S. Energy Information Administration (EIA) (indexed site)

    100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Appalachian Basin Boundary Appalachian Basin, TN-KY (Panel 7 of 7) Oil and Gas Fields By 2001 BOE

  2. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED WASH

    U.S. Energy Information Administration (EIA) (indexed site)

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline Total Total Total Number Liquid Gas BOE of Reserves Reserves Reserves Fields (Mbbl) (MMcf) (Mbbl) Uinta-Piceance 180 254,329 7,181,669 1,451,274 Basin Uinta-Piceance Basin Oil & Gas Fields By 2001 BOE

  3. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED WASH

    U.S. Energy Information Administration (EIA) (indexed site)

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline Total Total Total Number Liquid Gas BOE of Reserves Reserves Reserves Fields (Mbbl) (MMcf) (Mbbl) Uinta-Piceance 180 254,329 7,181,669 1,451,274 Basin Uinta-Piceance Basin Oil & Gas Fields By 2001 Gas

  4. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED WASH

    U.S. Energy Information Administration (EIA) (indexed site)

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Basin Outline Total Total Total Number Liquid Gas BOE of Reserves Reserves Reserves Fields (Mbbl) (MMcf) (Mbbl) Uinta-Piceance 180 254,329 7,181,669 1,451,274 Basin Uinta-Piceance Basin Oil & Gas Fields By 2001 Liquids

  5. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE DOME

    U.S. Energy Information Administration (EIA) (indexed site)

    Liquids Reserve Class 0 20 40 10 30 Miles ± The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface structural information. The data and methods used in their creation are detailed in a report, "Scientific Inventory of

  6. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) (indexed site)

    WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK ... Authors: Sam Limerick (1), Lucy Luo (1), Gary Long (2), David Morehouse (2), Jack Perrin ...

  7. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE...

    U.S. Energy Information Administration (EIA) (indexed site)

    studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface structural information. ...

  8. BIG SANDY IDA ONEID A WILL IAM SBU RG BU RNIN G SPRIN GS WIN

    U.S. Energy Information Administration (EIA) (indexed site)

    Miles 2001 Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Appalachian ...

  9. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE...

    U.S. Energy Information Administration (EIA) (indexed site)

    Lands' Oil and Gas Resources and Reserves and the Extent and Nature of Restrictions to Their Development", prepared by the US Departments of Interior, Agriculture and Energy. ...

  10. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline Total Total Total...

  11. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Basin Outline Total Total Total Number...

  12. ALT AMONT BLU EBELL NATUR AL BU TT ES PLAT EAU CATHED RAL RED...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline Total Total Total...

  13. Synthesis and fluxional behavior of [Bis(trialkylphosphine)nickelio]anthracene (Alkyl = Et, Bu)

    SciTech Connect (OSTI)

    Stanger, A.; Vollhardt, K.P.C. |

    1992-01-01

    The title compounds were prepared from the respective (R{sub 3}P){sub 2}NiCl{sub 2} complexes and magnesium-anthracene-(THF){sub 3} (or anthracene in the presence of Mg or C{sub 8}K). The assignment of the anthracene proton NMR signals using NOE in conjunction with magnetization-transfer techniques is described. The complexes undergo haptotropic rearrangements in which the (R{sub 3}P){sub 2}Ni moiety migrates between the two terminal rings of the coordinated anthracene. The rates of these processes are concentration independent and unaffected by the presence of free anthracene and tris(trialkylphosphine)nickel. Kinetic studies in the temperature range-60 to +70 {degrees}C using line shape analysis and spin saturation transfer techniques were carried out. It was found that {Delta}H{sup {double_dagger}} = 13.6 kcal mol{sup {minus}1} and {Delta}S{sup {double_dagger}} = 4.3 eu for the haptotropic rearrangement in 2, and similar values were found for 1. Possible mechanisms are discussed. According to {sup 1}H, {sup 13}C, and {sup 31}P NMR data, the coordination number between the anthracene and the (R{sub 3}P){sub 2}Ni moiety is 4. However, an equilibrium between two {eta}{sup 2} structures with {Delta}G{sup {double_dagger}} {le} 4 kcal mol{sup {minus}1} cannot be ruled out. 19 refs., 4 figs.

  14. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE...

    Annual Energy Outlook

    Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). ...

  15. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE...

    U.S. Energy Information Administration (EIA) (indexed site)

    Map created June 2005; projection is UTM-13, NAD-27. Authors: Sam Limerick (1), Lucy Luo (1), Gary Long (2), David Morehouse (2), Jack Perrin (1), Steve Jackson (1) and Robert King ...

  16. BASIN VER DE GREAT ER ANETH BU G BAR KER DOME HOR SESH OE UTE...

    U.S. Energy Information Administration (EIA) (indexed site)

    Authors: Sam Limerick (1), Lucy Luo (1), Gary Long (2), David Morehouse (2), Jack Perrin (1), Steve Jackson (1) and Robert King (2) (1) Z, Inc., (2) Energy Information ...

  17. DOE Hydrogen and Fuel Cells Program Record #13007: Industry Deployed Fuel Cell Backup Power (BuP)

    Energy.gov [DOE]

    This record from the DOE Hydrogen and Fuel Cells Program describes the number of current and planned fuel cell deployments for backup power applications.

  18. Hydrolysis of DFP and the Nerve Agent (S)-Sarin by DFPase Proceeds Along Two Different Reaction Pathways: Implica-tions for Engineering Bioscavengers

    SciTech Connect (OSTI)

    Wymore, Troy W; Langan, Paul; Smith, Jeremy C; Field, Martin J.; Parks, Jerry M

    2014-01-01

    Organophosphorus (OP) nerve agents such as (S)-sarin are among the most highly toxic compounds that have been synthesized. Engineering enzymes that catalyze the hydrolysis of nerve agents ( bioscavengers ) is an emerging prophylactic approach to diminishing their toxic effects. Although its native function is not known, diisopropyl fluorophosphatase (DFPase) from Loligo vulgaris catalyzes the hydrolysis of OP compounds. Here, we investigate the mechanisms of diisopropylfluorophosphate (DFP) and (S)-sarin hydrolysis by DFPase with quantum mechanical/molecular mechanical (QM/MM) umbrella sampling simulations. We find that the mechanism for hydrolysis of DFP involves nucleophilic attack by Asp229 on phosphorus to form a pentavalent intermediate. P F bond dissociation then yields a phosphoacyl enzyme intermediate in the rate-limiting step. The simulations suggest that a water molecule, coordinated to the catalytic Ca2+, donates a proton to Asp121 and then attacks the tetrahedral phosphoacyl intermediate to liberate the diisopropylphosphate product. In contrast, the calculated free energy barrier for hydrolysis of (S)-sarin by the same mechanism is highly unfavorable, primarily due to the instability of the pentavalent phosphoenzyme species. Instead, simulations suggest that hydrolysis of (S)-sarin proceeds by a mechanism in which Asp229 could activate an intervening water molecule for nucleophilic attack on the substrate. These findings may lead to improved strategies for engineering DFPase and related six-bladed -propeller folds for more efficient degradation of OP compounds.

  19. August

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    August August We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. James TenCate James TenCate elected Acoustical Society of America fellow TenCate's research focuses on nonlinear acoustics and elasticity, seismology and nonlinear imaging. - 8/30/16 The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary selection that occurs in response to

  20. Earth

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Earth Earth Climate impacts, including global temperatures, drought and forest fires as well as ocean and sea ice modeling. News Releases Science Briefs Photos Picture of the Week Publications Social Media Videos Fact Sheets James TenCate James TenCate elected Acoustical Society of America fellow TenCate's research focuses on nonlinear acoustics and elasticity, seismology and nonlinear imaging. - 8/30/16 The thermal traits of a leaf, critical for photosynthesis, may be under strong evolutionary

  1. Portsmouth, New Hampshire: Energy Resources | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Cate Street Capital Inc Environmental Power Corp Eolian Renewable Energy LLC Microgy Financial Services Inc Energy Generation Facilities in Portsmouth, New Hampshire Schiller...

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... WY (United States) S. M. Stoller (United States) SLAC ... Camsonne, Alexandre (1) Canan, Mustafa (1) Cates, Gordon (1) ... Katich, Joseph ; Qian, Xin ; Zhao, ...

  3. Small Business Opportunities at the Idaho National Laboratory...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Jennifer Cate DOE-ID Small Business Program Manager Idaho National Laboratory (INL) One of only 10 DOE multiprogram labs DOE's designated lead lab for nuclear energy ...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Benmokhtar, Fatiha (1) Bertozzi, William (1) Camsonne, Alexandre (1) Canan, Mustafa (1) Cates, Gordon (1) Chen, Chunhua (1) Chen, Jian-Ping (1) Choi, Seonho (1) Chudakov, Eugene ...

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    ... Bosted, Peter (1) Bradshaw, Elliott (1) Camsonne, Alexandre (1) Canan, Mustafa (1) Cates, Gordon (1) Chen, Chunhua (1) Chen, Jian -Ping (1) Chen, Wei (1) Chirapatpimol, Khem (1) ...

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    Office of Scientific and Technical Information (OSTI)

    ... Benmokhtar, Fatiha (2) Bertozzi, William (2) Camsonne, Alexandre (2) Canan, Mustafa (2) Cates, Gordon (2) Chen, Chunhua (2) Chen, Jian-Ping (2) Chudakov, Eugene (2) Cusanno, ...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Bosted, Peter (1) Bradshaw, Elliott (1) Camsonne, Alexandre (1) Canan, Mustafa (1) Cates, Gordon (1) Chen, Chunhua (1) Chen, Wei (1) Chirapatpimol, Khem (1) Choi, Seonho (1) ...

  8. 3He Spin-Dependent Cross Sections and Sum Rules (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Todd ; Berthot, J. ; Bertin, Pierre ; Bertozzi, William ; Black, Tim ; Brash, Edward ; Brown, D. ; Burtin, Etienne ; Calarco, John ; Cates, Gordon ; Chai, Zhengwei ; Chen, ...

  9. Microsoft Word - EMSSABChairs conferencecall Nov20 FINAL.doc

    Office of Environmental Management (EM)

    REMARKS Cate Brennan welcomed participants to the call and reviewed the afternoon's agenda. Transition Update James Fiore, Director for the Office of Management Analysis,...

  10. Indian Energy Blog Archive | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sandra Begay-Campbell, an engineer at Sandia National Laboratories in Albuquerque, New Mexico. July 22, 2014 The 2014 SandiaTribal Energy Program summer interns: Aaron Cate,...

  11. Integrating Two Worlds: a Supportive Pathway for Native American...

    Energy.gov (indexed) [DOE]

    ... Program summer interns: Aaron Cate, Sandra Begay-Campbell, Thomas Jones, and Len Necefer. Photo from Sandra Begay-Campbell, Sandia National Laboratories DOE Tribal Intern ...

  12. The proteome and phosphoproteome of Neurospora crassa in response...

    Office of Scientific and Technical Information (OSTI)

    T. ; Li, Xin ; Gritsenko, Marina A. ; Clauss, Therese ; Petyuk, Vlad ; Camp, David ; Smith, Richard ; Cate, Jamie H.D. ; Yang, Feng ; Glass, N. Louise Publication Date: ...

  13. Quark-Hadron Duality in Neutron (3He) Spin Structure (Journal...

    Office of Scientific and Technical Information (OSTI)

    Solvignon, Patricia ; Liyanage, Nilanga ; Chen, Jian-Ping ; Choi, Seonho ; Aniol, Konrad ; Averett, Todd ; Boeglin, Werner ; Camsonne, Alexandre ; Cates, Gordon ; Chang, C. ; Chang...

  14. New Hampshire's 1st congressional district: Energy Resources...

    Open Energy Information (Open El) [EERE & EIA]

    New Hampshire. Registered Energy Companies in New Hampshire's 1st congressional district Bio Energy US New Hampshire Cate Street Capital Inc Environmental Power Corp Eolian...

  15. Microsoft Word - FINAL_Preliminary Agenda_EM SSAB_Fall Chairs...

    Office of Environmental Management (EM)

    Remarks, Co-DDFOs, NNMCAB * Ralph Phelps, Chair, Northern New Mexico SSAB * Kevin Smith, Site Manager, Los Alamos Site Office * Cate Brennan, EM SSAB Designated Federal ...

  16. Final Report for grant 50105251, entitled AN OPEN SOURCE PLATFORM FOR MULTI-SCALE SPATIALLY DISTRIBUTED SIMULA TIONS OF MICROBIAL ECOSYSTEMS, DOE # DE-SC0004962, period 8/15/2010 – 8/14/2014

    SciTech Connect (OSTI)

    Segre, Daniel

    2015-12-09

    The goal of this project was to develop a tool for facilitating simulation, validation and discovery of multiscale dynamical processes in microbial ecosystems. This led to the development of an open-source software platform for Computation Of Microbial Ecosystems in Time and Space (COMETS). COMETS performs spatially distributed time-dependent flux balance based simulations of microbial metabolism. Our plan involved building the software platform itself, calibrating and testing it through comparison with experimental data, and integrating simulations and experiments to address important open questions on the evolution and dynamics of cross-feeding interactions between microbial species.

  17. Assignment of the luminescing states of [Au{sup 1}Rh{sup 1}({sup t}BuNC){sub 2}({mu}-dppm){sub 2}][PF{sub 6}]{sub 2}

    SciTech Connect (OSTI)

    Striplin, D.R.; Crosby, G.A.

    1995-07-13

    Fluorescence, phosphorescence, and excitation spectra were measured on the title compound. These results were augmented with polarization ratios obtained at 77 K and detailed studies of the temperature dependence of the phosphorescence in the 77-4 K range. The phosphorescence decay rate at K was also recorded as a function of an applied magnetic field. All the results are consistent with a 4d{sub z}Rh{sup 1} {yields} 6p{sub 2}Au{sup 1} orbital promotion leading to emitting {sup 1}A, {sup 3}A{sub 1} terms in pseudo-C{sub 2v} symmetry. The {sup 3}A{sub 1} term is split by spin-orbit coupling into a forbidden A{sub 2} state lying lowest followed by a quasi-degenerate pair, [B{sub 1}(x), B{sub 2}(y)] lying approximately 16 cm{sup -1} higher that decays >500 times faster than the lowest one. 28 refs., 6 figs.

  18. NNMCAB Committee Minutes: September 2013 Cities of Gold

    Energy.gov [DOE]

    Minutes of the September 10, 2013 Combined Committee meeting: Presentation NMED, NMED's Perspective Regarding the 2005 Consent Order, Secretary Ryan Flynn Presentation DOE HQ, Department of Energy's Environmental Management Site Specific Advisory Board Member Appointment Process, Cate Alexander

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Averett, Todd (3) Benmokhtar, Fatiha (3) Camsonne, Alexandre (3) Canan, Mustafa (3) Cates, Gordon (3) Chen, Chunhua (3) Chen, Jian-Ping (3) Cusanno, Francesco (3) Dalton, Mark (3) ...

  20. HANFORD ADVISORY BOARD

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... Dennis Faulk, EPA Susan Hayman, EnviroIssues Steve Pfaff, DOE-ORP Robin Paul, EPA Hillary Johnson, EnviroIssues Cathy McCague, EnviroIssues Cate Brennan, DOE Sharon Braswell, ...

  1. Microsoft Word - ChairsMtg_Final Agenda.040313

    Office of Environmental Management (EM)

    25, 2013 * 1:00 - 5:30 PM EDT April 25, 2013 1:00 pm Welcome, Opening Remarks, and DOE-HQ News and Views * Cate Alexander, EM SSAB Designated Federal Officer 1:15 pm EM Program...

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Canan, Mustafa (2) Cates, Gordon (2) Chen, Chunhua (2) Chen, Jian-Ping (2) Cusanno, Francesco (2) Dalton, Mark (2) De Jager, Cornelis (2) Deconinck, Wouter (2) Deng, Xiaoyan (2) ...

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    Office of Scientific and Technical Information (OSTI)

    Li, Xin (59) Chen, Wei-Ren (18) Li Xin (16) Smith, Gregory Scott (16) Liu, Emily (12) Liu, ... Therese ; Petyuk, Vlad ; Camp, David ; Smith, Richard ; Cate, Jamie H.D. ; Yang, Feng ; ...

  4. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    Therese ; Petyuk, Vlad ; Camp, David ; Smith, Richard ; Cate, Jamie H.D. ; Yang, Feng ; ... Do, Changwoo ; Liu, Yun ; Hong, Kunlun ; Smith, Greg ; Chen, Wei-Ren In this work we ...

  5. Final Scientific/Technical Report Grant title: Use of ARM Measurements of Spectral Zenith Radiance for Better Understanding of 3D Cloud-Radiation Processes and Aerosol-Cloud Interaction This is a collaborative project with the NASA GSFC project of Dr. A. Marshak and W. Wiscombe (PIs). This report covers BU activities from February 2011 to June 2011 and BU "no-cost extension" activities from June 2011 to June 2012. This report summarizes results that complement a final technical report submitted by the PIs in 2011.

    SciTech Connect (OSTI)

    Knyazikhin, Y

    2012-09-10

    Main results are summarized for work in these areas: spectrally-invariant approximation within atmospheric radiative transfer; spectral invariance of single scattering albedo for water droplets and ice crystals at weakly absorbing wavelengths; seasonal changes in leaf area of Amazon forests from leaf flushing and abscission; and Cloud droplet size and liquid water path retrievals from zenith radiance measurements.

  6. DOE Hydrogen and Fuel Cells Program Record #13007: Industry Deployed...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Record 13007: Industry Deployed Fuel Cell Backup Power (BuP) DOE Hydrogen and Fuel Cells Program Record 13007: Industry Deployed Fuel Cell Backup Power (BuP) This record from the ...

  7. joe_arm08.ppt

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    clear stable day with tion applied. Should be he curvature, which is eric instability.

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Katz, Emanuel Stanford Institute for Theoretical Physics, Stanford University, Stanford, CA 94305 (United States) (1) Katz, Emanuel, E-mail: bfeldste@buphy.bu.edu, E-mail: ...

  9. A=19Ne (1978AJ03)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    8AJ03) (See Energy Level Diagrams for 19Ne) GENERAL: See (1972AJ02) and Table 19.24 [Table of Energy Levels] (in PDF or PS). Nuclear models: (1972EN03, 1972NE1B, 1972WE01, 1973DE13, 1977BU05). Electromagnetic transitions: (1972EN03, 1972LE06, 1973HA53, 1973PE09, 1977BU05). Special states: (1972EN03, 1972GA14, 1972HI17, 1972NE1B, 1972WE01, 1977BU05, 1977SC08). Complex reactions involving 19Ne: (1976HI05, 1977BU05). Astrophsyical questions: (1973CL1E). Muon capture: (1972MI11). Pion capture and

  10. Envirocapital | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Envirocapital Jump to: navigation, search Name: Envirocapital Place: London, United Kingdom Zip: EC4M 8BU Sector: Renewable Energy Product: Provides corporate finance advice to the...

  11. Lattice Quantum Chromodynamics

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Lattice Quantum Chromodynamics Lattice Quantum Chromodynamics QCD-BU.jpg Key Challenges: Although the QCD theory has been extensively tested at at high energies, at low energies or...

  12. Alternative Energy Finance | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Finance Jump to: navigation, search Name: Alternative Energy Finance Place: London, United Kingdom Zip: NW11 8BU Sector: Renewable Energy Product: String representation...

  13. Collegiate Teams on Track for May Competition | Wind | NREL

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Education & Training » College Student Internship Program College Student Internship Program 1 of 10 2011 interns pictured left to right at Sky City, traditional village of the Pueblo of Acoma: Devin Dick, Tammie Allen, Sandra Begay-Campbell, Gepetta Billie, and Chelsea Chee. 2 of 10 2014 interns Aaron Cate, Tommy Jones, and Len Necefer with supervisor Sandra Begay-Campbell. 3 of 10 2015 interns Tommy Jones, Kimberlynn Cameron, program adviser Sandra Begay-Campbell, Office of Indian Energy

  14. Capital Reporting Company

    National Nuclear Security Administration (NNSA)

    © 2013 2 1 A P P E A R A N C E S 2 Jeff Bedell, Los Alamos National Laboratory Alisa Beyninson, Government Accountability Office 3 David Blee, USNIC H. Brendan Burke, George Washington University Law School 4 Malcolm Burke, U.S. Department of Commerce Ian Butterfield, Livingston Group 5 Jorge Canovas, University of Pennsylvania Dwight Cates, Fluor Corporation 6 Preeti Chaudhari, U.S. Department of Energy Steve Clagett, Department of Commerce 7 Joyce Connery, National Security Staff Jean

  15. Capital Reporting Company

    National Nuclear Security Administration (NNSA)

    © 2013 2 1 A P P E A R A N C E S 2 Jeff Bedell, Los Alamos National Laboratory Alisa Beyninson, Government Accountability Office 3 David Blee, USNIC H. Brendan Burke, George Washington University Law School 4 Malcolm Burke, U.S. Department of Commerce Ian Butterfield, Livingston Group 5 Jorge Canovas, University of Pennsylvania Dwight Cates, Fluor Corporation 6 Preeti Chaudhari, U.S. Department of Energy Steve Clagett, Department of Commerce 7 Joyce Connery, National Security Staff Jean

  16. First Last Affiliation Janet Barsey U.S. Department of Energy

    National Nuclear Security Administration (NNSA)

    First Last Affiliation Janet Barsey U.S. Department of Energy Carol Berrigan NEI David Blee US Nuclear Infrastructure Council Brandi Boniface University of Florida Matt Bowen U.S. Department of Energy/ NNSA Mary Branham APS Ellie Busick Edlow International Corp. Amanda Campbell GE Dwight Cates Fluor Corporation Chris Charles Nuclear Energy Institute Preeti Chaudhari U.S. Department of Energy Steven Clagett U.S. Department of Commerce Jeremy Cohn Mitsubishi Nuclear Energy Systems, Inc. Susan

  17. with multiple torsional modes and when there are

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    multiple torsional modes and when there are hydrogen bonds formed for some of the geometries. The presence of hydrogen bonds particularly compli- cates things by coupling some of the other vibrational motions to the torsional motions. In particular, many of the bending frequencies become quite strongly de- pendent on the torsional geometry. Truhlar has devel- oped a method that treats this difficulty by explicitly considering the contributions from each of the differ- ent torsional minima. The

  18. The ARM Unmanned Aerospace Vehicle Program

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    The ARM Unmanned Aerospace Vehicle Program The ARM Program's focus is on climate research, specifi- cally research related to solar radiation and its interaction with clouds. The SGP CART site contains highly sophisti- cated surface instrumentation, but even these instruments cannot gather some crucial climate data from high in our atmosphere. The lowest layer of our atmosphere, known as the "troposphere," is where our weather events take place. The troposphere contains virtually all

  19. College Student Internship Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Education & Training » College Student Internship Program College Student Internship Program 1 of 10 2011 interns pictured left to right at Sky City, traditional village of the Pueblo of Acoma: Devin Dick, Tammie Allen, Sandra Begay-Campbell, Gepetta Billie, and Chelsea Chee. 2 of 10 2014 interns Aaron Cate, Tommy Jones, and Len Necefer with supervisor Sandra Begay-Campbell. 3 of 10 2015 interns Tommy Jones, Kimberlynn Cameron, program adviser Sandra Begay-Campbell, Office of Indian Energy

  20. Guide to FEMP-Designated Parking Structure Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Structure Lighting Guide to FEMP-Designated Parking Structure Lighting Document provides acquisition guidance and federal efficiency requirements across a variety of product cate-gories, including parking garage luminaires, which are a FEMP-designated product category. Federal laws and executive orders mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law. Download the guide to FEMP-designated parking

  1. HQ F 580

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Certi cate of Property/Property Removal Authorization NAME(Last, First, MI) Org Code Phone # Item Descrip n Make Model Tag Number Serial Number Exp. Date RECEIPT ACKNOWLEDGMENT I hereby acknowledge receipt for the listed item and will hold myself accountable for its safety. DOE Federal employees will be responsible and may be inancially liable for loss, damage, destruction, and unauthorized use of government personal property in their possession and control. Loss or stolen property should be

  2. Everest Refrigeration: Order (2015-SE-42001)

    Energy.gov [DOE]

    DOE ordered Bu Sung America Corporation (dba Everest Refrigeration) to pay a $12,080 civil penalty after finding Bu Sung had manufactured and distributed in commerce in the U.S. at least 64 units of noncompliant commercial refrigerator basic model ESGR3.

  3. A=18O (1983AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1979DA15, 1979WU06, 1980GO01, 1980KU05, 1980MA18, 1981EL1D, 1982KI02, 1982OL01). Cluster, collective and deformed models: (1977BU22, 1978BU03, 1978CH26, 1978PI1E,...

  4. A=18F (1983AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    83AJ01) (See Energy Level Diagrams for 18F) GENERAL: See also (1978AJ03) and Table 18.11 [Table of Energy Levels] (in PDF or PS). Shell model: (1977AN1P, 1977GR16, 1977SO1C, 1978CO08, 1978DA1N, 1978MA2H, 1979BU12, 1979DA15, 1980GO01, 1980KU05, 1980MA18, 1981EL1D, 1981ER03, 1981GR06, 1982KI02). Cluster, collective and deformed models: (1977BU22, 1978BU03, 1978PI1E, 1978SA15, 1978TA1A, 1979BU12, 1979SA31, 1980RO19, 1981CH24). Electromagnetic transitions: (1976MC1G, 1977BU22, 1977HA1Z, 1977HE1L,

  5. Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H2

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Liao, Qian; O'Hagan, Molly J.; Hulley, Elliott; DuBois, Daniel L.; Bullock, R. Morris

    2015-06-22

    The synthesis and spectroscopic characterization of CpC5F4NFe(PtBu2NBn2)Cl, [3-Cl] (where C5F4N is the tetrafluorpyridyl substituent and PtBu2NBn2 = 1,5-di(tert-butyl)-3,7-di(benzyl)-1,5-diaza-3,7-diphosphacyclooctane) are reported. Complex 3-Cl and previously reported [CpC5F4NFe(PtBu2NtBu2)Cl], 4-Cl, are precursors to intermediates in the catalytic oxidation of H2, including CpC5F4NFe(PtBu2NBn2)H (3-H), CpC5F4NFe(PtBu2NtBu2)H (4-H), [CpC5F4NFe(PtBu2NBn2)]BArF4 ([3](BArF4), [CpC5F4NFe(PtBu2NtBu2)]BArF4 ([4](BArF4), [CpC5F4NFe(PtBu2NBn2)(H2)]BArF4 ([3-H2]BArF4), and [CpC5F4NFe(PtBu2NtBu2H)H]BArF4 ([4-FeH(NH)]BArF4). All of these complexes were characterized by spectroscopic and electrochemical studies; 3-Cl, 3-H and 4-Cl were also characterized by single crystal diffraction studies. 3-H and 4-H are electrocatalysts for H2 (1.0 atm) oxidation in the presence of a excess of the amine base N-methylpyrrolidine, with turnover frequencies at 22 °C of 2.5 s-1 and 0.5 s-1, and overpotentials at Ecat/2 of 235 mV and 95 mV, respectively. Studies of individual chemical and/or electrochemical reactions of the various intermediates provide important insights into the factors governing the overall catalytic activity for H2 oxidation, and provide important insights into the role of the pendant base of the [FeFe] hydrogenase active site. This work was supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  6. Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H2 Production

    SciTech Connect (OSTI)

    Fang, Ming; Wiedner, Eric S.; Dougherty, William G.; Kassel, W. S.; Liu, Tianbiao L.; DuBois, Daniel L.; Bullock, R. Morris

    2014-10-27

    A series of heteroleptic 17e- cobalt complexes, [CpCoII(PtBu2NPh2)](BF4), [CpC6F5CoII(PtBu2NPh2)](BF4), [CpC5F4NCoII(PtBu2NPh2)](BF4), [where P2tBuN2Ph = 1,5-diphenyl-3,7-di(tert-butyl)-1,5-diaza-3,7-diphosphacyclooctane, CpC6F5 = C5H4(C6F5), and CpC5F4N = C5H4(C5F4N)] were synthesized, and structures of all three were determined by X-ray crystallography. Electrochemical studies showed that the CoIII/II couple of [CpC5F4NCoII(PtBu2NPh2)]+ appears 250 mV positive of the CoIII/II couple of [CpCoII(PtBu2NPh2)] as a result of the strongly electron-withdrawing perfluorpyridyl substituent on the Cp ring. Reduction of these paramagnetic CoII complexes by KC8 led to the diamagnetic 18e- complexes CpICo(PtBu2NPh2), CpC6F5CoI(PtBu2NPh2), CpC5F4NCoI(PtBu2NPh2), which were also characterized by crystallography. Protonation of these neutral CoI complexes led to the cobalt hydrides [CpCoIII(PtBu2NPh2)H](BF4), [CpC6F5CoIII(PtBu2NPh2)H](BF4), and [CpC5F4NCoIII(PtBu2NPh2)H](BF4). The cobalt hydride with the most electron-withdrawing Cp ligand, [CpC5F4NCoIII(PtBu2NPh2)H]+ is an electrocatalyst for production of H2 using 4-MeOC6H4NH3BF4 (pKaMeCN = 11.86) with a turnover frequency of 350 s-1 and an overpotential of 0.75 V. Experimental measurement of thermochemical data provided further insights into the thermodynamics of H2 elimination. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  7. Center for Nanophase Materials Sciences (CNMS) - Publications

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    M.; Decker, S. .R; Bu, L. T.; Zhao, X. C.; McCabe, C.; Wohlert, J.; Bergenstrahle, M.; Brady, J. W.; Adney, W. S.; Himmel, M. E.; Crowley, M. F., ":The O-Glycosylated Linker from...

  8. ATOMIC ENERGY COMMISSION Refer to File No. AEGR-1 The CommandinS...

    Office of Legacy Management (LM)

    Subject: REPORT CF F2GIATICN ' SUEiVZY radiation Transmitted herewith, in duplicate, is a ... the buZldizg.s, 2nd then othrrs were taken to cmclete the.ovemll radiation conditi:ns. ...

  9. Island Gas | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    United Kingdom Zip: W1J 7BU Sector: Renewable Energy Product: UK-based coal bed methane company, Island Gas was the subject of a reverse takeover by KP Renewables in...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Clayton, T. (4) Duan, L. (4) Hampton, E. (4) Harrison, Stephen C. (4) Haynes, Barton F. ... Moody, M. Anthony ; Haynes, Barton F. ; Harrison, Stephen C. ; BU-M) ; Duke-MED) ; et al ...

  11. Venture Capital Finance

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    15 GJ Oil (6.2 GJbbl) 100bbl 16 GJ Corn 4-7bu 10 - 20 GJ 2 * Higher oil prices create a disruptive opportunity for lower cost feedstocks * North American shale gas ...

  12. Newsletter July draft 070312 v2.pub

    Office of Environmental Management (EM)

    For more informa on, visit h p:go.usa.govvYZ. DOE Sustainability SPOtlight U.S. ... The app converts Green Bu on energy data into the number of trees required to offset pollu ...

  13. West Central Soy | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Soy Jump to: navigation, search Name: West Central Soy Place: Iowa Product: Biodiesel producer based in Iowa, Owned bu a soy farmer coop References: West Central Soy1 This...

  14. Atmospheric formation and removal of C3-C5 peroxyacyl nitrates

    SciTech Connect (OSTI)

    Grosjean, D.

    1993-12-31

    The C3-C5 peroxyacyl nitrates RC(O)OONO{sub 2} (R=Et, n-Pr, i-Pr, n-Bu, i-Bu, sec-Bu, t-Bu, Ch{sub 2}=CH- and CH{sub 2}=C(CH{sub 3})-) have been synthesized and prepared in situ and have been characterized by electron capture gas chromatography. Their thermal decomposition rates have been measured and are similar to that of PAN (R = CH{sub 3}). Carbonyl products have been identified and the corresponding reaction mechanisms have been outlined. Ambient levels of several peroxyacyl nitrates (R =CH{sub 3}, Et, n-Pr and CH{sub 2}=(CH{sub 3})-) have been measured. The results are discussed with focus on atmospheric hydrocarbons as precursors to C3-C5 peroxyacyl nitrates in the atmosphere.

  15. MHK Projects/Makah Bay Offshore Wave Pilot Project | Open Energy...

    Open Energy Information (Open El) [EERE & EIA]

    mooringanchoring and electrical connection system; (2) a 3.7-statute-mile-long, direct current (DC) submarine transmission cable connecting from one of the AquaBuOY's...

  16. Llr. Norgnn of the St. Louis office tolepbonod Dr. ;PuAuff mcently

    Office of Legacy Management (LM)

    Company of 122 East l&xi Btmot, f&w PO* 17, N. ,P., had also expressed an intereat ir.having their mbsidi.arg, the J. T. Baker Chemical Coqany, get into the field. BU aeked...

  17. Pontotoc Co. Greene Co. Hale Co. OAK GROVE C OAL D EGAS CEDAR...

    Gasoline and Diesel Fuel Update

    LITT LE SAND Y CREEK COAL D EGAS FAYETTE SW FAYETTE N WAT TS CR EEKALD YELLOW CR EEKALD RPDOKTIBBEHACNT Y-1 BALLS BRAN CH BU TT AH ATCH IE RIVER NETT LET ON ABERD EEN E ...

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    Gasoline and Diesel Fuel Update

    LITT LE SAND Y CREEK COAL D EGAS FAYETTE SW FAYETTE N WAT TS CR EEKALD YELLOW CR EEKALD RPDOKTIBBEHACNT Y-1 BALLS BRAN CH BU TT AH ATCH IE RIVER NETT LET ON ABERD EEN E ...

  19. Pontotoc Co. Greene Co. Hale Co. OAK GROVE C OAL D EGAS CEDAR...

    Annual Energy Outlook

    LITT LE SAND Y CREEK COAL DEGAS FAYETTE SW FAYETTE N WAT TS CR EEKALD YELLOW CR EEKALD RPDOKTIBBEHACNT Y-1 BALLS BRAN CH BU TT AH ATCH IE RIVER NETT LETON ABERD EEN E TAYLOR ...

  20. Class 1 Permit Modification Notification

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    Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Bu il ding 1 Santa Fe, New Mexico 87505-6303 JUL 0 5 2011 Subject: Notification of a Class 1 Permit...

  1. NREL: Biomass Research - Mary Ann Franden

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... Biotechnology for Biofuels (Manuscript in review). Franden, M.A.; Pienkos, P.T.; Zhang, M. ... Journal of Biotechnology (144); pp. 259-267. Knoshaug, E.; Franden, M.A.; Stambuk, B.U.; ...

  2. Everest Refrigeration: Proposed Penalty (2015-SE-42001)

    Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Bu Sung America Corporation (dba Everest Refrigeration) manufactured and distributed noncompliant commercial refrigeration equipment model ESGR3 in the U.S.

  3. Everest Refrigeration: Noncompliance Determination (2015-SE-42001)

    Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Bu Sung America Corporation (dba Everest Refrigeration) finding that commercial refrigeration equipment model number ESGR3 does not comport with the energy conservation standards.

  4. NREL: Biomass Research - Eric P. Knoshaug

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    "Algal Biofuels: The Process." Chem. Engin. Prog. (107); pp. 37-47. Knoshaug, E.P.; Franden, M.A.; Stambuk, B.U.; Zhang, M.; Singh, A. (2009). "Utilization and Transport of ...

  5. The selective catalytic reduction of NOx over Ag/Al2O3 with isobutanol as the reductant

    DOE PAGES-Beta [OSTI]

    Brookshear, Daniel William; Pihl, Josh A.; Toops, Todd J.; West, Brian H.; Prikhodko, Vitaly Y.

    2016-02-13

    Here, this study investigates the potential of isobutanol (iBuOH) as a reductant for the selective catalytic reduction (SCR) of NOx over 2 wt% Ag/Al2O3 between 150 and 550 °C and gas hourly space velocities (GHSV) between 10,000 and 35,000 h-1. The feed gas consists of 500 ppm NO, 5% H2O, 10% O2, and 375-1500 ppm iBuOH (C1:N ratios of 3-12); additionally, blends of 24 and 48% iBuOH in gasoline are evaluated. Over 90% NOx conversion is achieved between 300 and 400 C using pure iBuOH, including a 40% peak selectivity towards NH3 that could be utilized in a dual HC/NH3more » SCR configuration. The iBuOH/gasoline blends are only able to achieve greater than 90% NOx conversion when operated at a GHSV of 10,000 h-1 and employing a C1:N ratio of 12. Iso-butyraldehyde and NO2 appear to function as intermediates in the iBuOH-SCR mechanism, which mirrors the mechanism observed for EtOH-SCR. In general, the performance of iBuOH in the SCR of NOx over a Ag/Al2O3 catalyst is comparable with that of EtOH, although EtOH/gasoline blends display higher NOx reduction than iBuOH/gasoline blends. The key parameter in employing alcohols in SCR appears to be the C-OH:N ratio rather than the C1:N ratio.« less

  6. DOE Office of Indian Energy Interns | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Office of Indian Energy Interns DOE Office of Indian Energy Interns Addthis 1 of 10 2011 interns pictured left to right at Sky City, traditional village of the Pueblo of Acoma: Devin Dick, Tammie Allen, Sandra Begay-Campbell, Gepetta Billie, and Chelsea Chee. 2 of 10 2014 interns Aaron Cate, Tommy Jones, and Len Necefer with supervisor Sandra Begay-Campbell. 3 of 10 2015 interns Tommy Jones, Kimberlynn Cameron, program adviser Sandra Begay-Campbell, Office of Indian Energy Director Chris

  7. Homoleptic Ce(III) and Ce(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State

    SciTech Connect (OSTI)

    Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A.; Piro, Nicholas A.; Carroll, Patrick J.; Booth, Corwin H.; Schelter, Eric J.

    2014-06-25

    Electrochemical experiments performed on the complex Ce-IV[2-((BuNO)-Bu-t)py](4), where [2-((BuNO)-Bu-t)py](-) = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [(Bu4N)-Bu-n](2)[Ce(NO3)(6)] in acetonitrile and a 2.95 V stabilization compared to the standard potential for the ion under aqueous conditions. Density functional theory calculations suggest that this preference for the higher oxidation state is a result of the tetrakis(nitroxide) ligand framework at the Ce cation, which allows for effective electron donation into, and partial covalent overlap with, vacant 4f orbitals with delta symmetry. The results speak to the behavior of CeO2 and related solid solutions in oxygen uptake and transport applications, in particular an inherent local character of bonding that stabilizes the 4+ oxidation state. The results indicate a cerium(IV) complex that has been stabilized to an unprecedented degree through tuning of its ligand-field environment.

  8. nemsoverview_928.vp

    U.S. Energy Information Administration (EIA) (indexed site)

    581(2009) The Na tional En ergy Mod el ing Sys tem: An Over view 2009 October 2009 En ergy In for ma tion Ad min is tra tion Of fice of In te grated Anal y sis and Fore cast ing U.S. De part ment of En ergy Wash ing ton, DC 20585 This re port was pre pared by the En ergy In for ma tion Ad min is tra tion, the in de pend ent sta tis ti cal and an a lyt i cal agency within the U.S. De part ment of En ergy. The in for ma tion con tained herein should be at trib uted to the En ergy In for ma tion Ad

  9. ners-cp1-20130402104412

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    581(2009) The Na tional En ergy Mod el ing Sys tem: An Over view 2009 October 2009 En ergy In for ma tion Ad min is tra tion Of fice of In te grated Anal y sis and Fore cast ing U.S. De part ment of En ergy Wash ing ton, DC 20585 This re port was pre pared by the En ergy In for ma tion Ad min is tra tion, the in de pend ent sta tis ti cal and an a lyt i cal agency within the U.S. De part ment of En ergy. The in for ma tion con tained herein should be at trib uted to the En ergy In for ma tion Ad

  10. Field Communications Control Center Technical Organizational

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    ... and are appropriate authorization credentials (e.g., badges, identifica- tion cards, ... Are all factory default authentication credentials changed after installation? (RRCSS ...

  11. United States

    Office of Legacy Management (LM)

    ... notwithstanding any other provision of law, 10.000.000 to remain available until ... notwithstanding any other provision of law or regulation, the construe- tion' of any ...

  12. Relaxation

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    ... wall of tokamak reactors 8 and other possible applica- tions. This investigation is expected to contribute to the un- derstanding of the dynamics of fast tritium or deuterium ...

  13. Predicting Pressure-Dependent Combustion Chemical Reactions

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... Chemical Reactions HomeCapabilities, Computational Modeling & Simulation, CRF, Energy, ... in combus-tion and atmospheric chemistry that is expected to benefit auto and ...

  14. Alternative Fuels Data Center (Fact Sheet), Clean Cities, Vehicle...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Users can find real-life examples of delivery fleets that run on biodiesel, cities that ... The AFDC provides extensive informa- tion about alternative fuels, including biodiesel, ...

  15. Maintaining System Air Quality; Industrial Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2 * August 2004 Industrial Technologies Program Suggested Actions * Review compressed air applica- tions and determine the required level of air quality for each. * Review the ...

  16. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    9: Natural Gas (CBECS89.A09) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region ...

  17. Y NATIOXAL RESFARCH CORPCRATION

    Office of Legacy Management (LM)

    ... From the slices thus taken, ssm- ples will be taken for metallographic examina- tion and vacuum fusion gas analysis for oxygen, nitrogen, hydrogen, and carbcm . hfetallcgraphic and ...

  18. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    tion-wind-energy-wind-turbines Download Get Current: Switch on Clean Energy Activity Book Switching on clean energy technologies means strengthening the economy while protecting...

  19. Business Case for Energy Efficient Building Retrofit and Renovation

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... ripe for focusing on retrofit and renovation investments that could save energy and money. ... overall project valua- tion. the way this money is allocated to different products, ...

  20. ch_2

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    The Tank Farm consists of storage tanks, tank vaults, interconnecting waste transfer ... several small buildings that contain instrumenta- tion and equipment for the waste tanks. ...

  1. --No Title--

    Gasoline and Diesel Fuel Update

    Central Air Condi- tioners Heat Pumps Indiv- idual Air Condi- tioners District Chilled Water Central Chillers Pack- aged Air Condi- tioning Units Swamp Coolers Other All...

  2. About ASHRAE

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Weather Data Real- Time Energy Pricing Demand Response Energy Usage Info HVAC Lighting Security Facility Manage- ment Industrial Automa- tion FSGIM Device Energy Manager Load Meter ...

  3. untitled

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    ... The advanced accelerator and X-ray sources developed for this mission are being extended ... viscoelastic fric- tion to its potential energy, we developed a ther- modynamically ...

  4. DOE/EV-0005/27

    Office of Legacy Management (LM)

    ... tion of uranium in a water sample taken from a core ... This history is based on information given in refs. 1 ... DIGESTION I SOLVENT EXTRACTIONPURIFICATION DENITRATION ...

  5. Single-Column Modeling A Stratiform Cloud Parameterization for...

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    ... variables. where c is a coefficient that depends on the ... The same parameteriza- tions of radiative transfer and ... ratio rv with the condensation-conserved variables T ...

  6. Glossary

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    mixture of relatively volatile hydrocarbons, with or without small quantities of additives, blended to form a fuel suitable for use in spark-ignition engines. Specifica- tions...

  7. LED Color Characteristics

    Energy.gov (indexed) [DOE]

    a combina- tion of colored LEDs typically red, green, and blue (RGB) are also available. ... triphosphor uorescent, utilize a combination of red-, blue-, and green-emitting phosphors. ...

  8. Environmental Impacts of Increased Hydroelectric Development...

    Energy.gov (indexed) [DOE]

    ... and oil for electric power production also have impacts on water resources. These include impacts of offshore oil development and oil spills during transporta- tion and refining. ...

  9. N

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    ... Coatings in Fast Neutron and High Temperature Environments of Next Genera- tion Reactors May 2015 Highlights ... gas- and liquid-cooled (sodium, salt, and lead) systems. ...

  10. dudhia-98.pdf

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    wind components, vertical velocity, pressure perturba- tion, temperature, water vapor, ground temperature and microphysical water and ice content variables. It has an upper...

  11. In The News Feed

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    tion-affordable-alternative-platinum

    Microwave heat improves nanostructured molybdenum disulfide catalyst's ability to produce hydrogen.

    October 26, 2015 In The News Feed...

  12. Document

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    ... energy'' means energy produced by solar, wind, biomass, landfill gas, ocean ... and other requirements of present and future genera- tions of Americans; and (l) ...

  13. Scalable Analysis

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    ... computers, work- station clusters, and heterogeneous combinations of these systems. ... For example, if each instrumenta- tion event contained a workflow ID, then a separate file ...

  14. Search results | Department of Energy

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    tion-nevada-teachers-helping-students-learn-about-energy Download Infographics from the 2014 National Geothermal Student Competition With the theme of GeoEnergy is Beautiful, the...

  15. ARQfall99.pgm

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    ... for assembly into radioisotope thermoelectric generators (RTGs), but the LWRHU ... In addi- tion, an aqueous chloride processing line, CLEAR, will use enhanced organic ...

  16. An Assessment

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    ... and applications, Journal of Computational ... et al., The AMP (Advanced MultiPhysics) ... tions, in: 2013 International Conference on Mathematics and Compu- tational ...

  17. PPPL Races Ahead with Fusion Research

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    tion in ITER, an international fusion facility of ... David Gates, a principal research physicist at PPPL and ... Discovery through Advanced Computing (SciDAC) ...

  18. S A N D I A T E C H N O L O G Y A Q UA RT E R LY R E S E A R

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    ... methods relies on smart mathematics for realiza- tion in ... The research relies on atomistic simulations augmented by ... The FUEGO code was developed as part of DOE's Advanced ...

  19. Buildings and Energy in the 1980's (TABLES)

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    1982 End Uses RSE Row Fac- tors All End Uses Space Heating Water Heating Air Conditioning Appliances Building Characteristics Buildings (thou- sand) Consump- tion...

  20. Buildings and Energy in the 1980's (TABLES)

    U.S. Energy Information Administration (EIA) (indexed site)

    1980 End Uses RSE Row Fac- tors All End Uses Space Heating Water Heating Air Conditioning Appliances Building Characteristics Buildings (thou- sand) Consump- tion...

  1. Buildings and Energy in the 1980's (TABLES)

    U.S. Energy Information Administration (EIA) (indexed site)

    1981 End Uses RSE Row Fac- tors All End Uses Space Heating Water Heating Air Conditioning Appliances Building Characteristics Buildings (thou- sand) Consump- tion...

  2. --No Title--

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    segregation of elements in the steel matrix.The synergistic deployment of ... under- standing of the structural response of a 9CCr ODS steel to neutron irradia- tion. ...

  3. Microsoft Word - ViArray_Fact_ Sheet_SAND2011-3935P_updated_format...

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    decoupling ude: & Control tion itoring Parts & FPG vironment op ility System boratories ha pplications. services" wi me custom ra aging, test, fa om microele Hard S tructured Ap...

  4. William J. Clinton, 1998

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... To the extent feasible, remote sensing capabilities shall be developed and applied to this ... identifying the major causes and consequences of degrada- tion of coral reef ecosystems. ...

  5. Frequently Asked Questions about using the New DOE Energy Savings...

    Energy.gov (indexed) [DOE]

    ... FEDERAL ENERGY MANAGEMENT PROGRAM 2 One example of modern design replacing prior conventional wisdom has occurred with steam plant and boiler decentraliza- tion. Many older ...

  6. X:\\ARM_19~1\\PGS29-47.WPD

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    Clouds are one of the most important moderators of the earth radiation budget and one of ... tions including cloud base height determination and cloud-type occurrence statistics. ...

  7. Agenda for Transitioning the Transportation Sector: Exploring...

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    ... natural gas and erent transport mental Science a e Public Affairs, s Manager, Ho scussion gen in direct co tion applicatio structure rollo ass of stations & uilt to ...

  8. Molecular and Electronic Structure of Cyclic Trinuclear Gold(I) Carbeniate Complexes: Insights for Structure/Luminescence/Conductivity Relationships

    SciTech Connect (OSTI)

    McDougaldJr, Roy N; Chilukuri, Bhaskar; Jia, Huiping; Perez, Michael R; Rabaa, Hassan; Wang, Xiaoping; Nesterov, Vladimir; Cundari, Thomas R.; Gnade, Bruce E; Omary, Mohammad A

    2014-01-01

    An experimental and computational study of correlations between solid-state structure and optical/electronic properties of cyclotrimeric gold(I) carbeniates, [Au-3(RN=COR')(3)] (R, R' = H, Me, Bu-n, or (c)Pe), is reported. Synthesis and structural and photophysical characterization of novel complexes [Au-3(MeN=(COBu)-Bu-n)(3)], [Au-3((BuN)-Bu-n=COMe)(3)], [Au-3((BuN)-Bu-n=(COBu)-Bu-n)(3)], and [Au-3((c)PeN=COMe)(3)] are presented. Changes in R and R' lead to distinctive variations in solid-state stacking, luminescence spectra, and conductive properties. Solid-state emission and excitation spectra for each complex display a remarkable dependence on the solid-state packing of the cyclotrimers. The electronic structure of [Au-3(RN=COR')(3)] was investigated via molecular and solid-state simulations. Calculations on [Au-3(HN=COH)(3)] models indicate that the infinitely extended chain of eclipsed structures with equidistant Au-Au intertrimer aurophilic bonding can have lower band gaps, smaller Stokes shifts, and reduced reorganization energies (lambda). The action of one cyclotrimer as a molecular nanowire is demonstrated via fabrication of an organic field effect transistor and shown to produce a p-type field effect. Hole transport for the same cyclotrimer-doped within a poly(9-vinylcarbazole) host-produced a colossal increase in current density from similar to 1 to similar to 1000 mA/cm(2). Computations and experiments thus delineate the complex relationships between solid-state morphologies, electronic structures, and optoelectronic properties of gold(I) carbeniates.

  9. Tris(Cyclopentadienyl)Uranium-t-Butyl: Synthesis, reactions, and mechanisms

    SciTech Connect (OSTI)

    Weydert, M.

    1993-04-01

    Compounds (RC{sub 5}H{sub 4}){sub 3}U(t-Bu) were prepared for R = H, Me, Et. Their decomposition products in aromatic solvents are consistent with a radical decomposition pathway induced by solvent-assisted U-C bond homolysis. NMR was used to study the reactions of (RC{sub 5}H{sub 4}){sub 3}UCl with t-BuLi (R = t-Bu, Me{sub 3}Si). Reactions of (MeC{sub 5}H{sub 4}){sub 3}U(t-Bu) with Lewis bases and fluorocarbons were studied. Analogous reaction chemistry between (RC{sub 5}H{sub 4}){sub 3}ThX systems and t-BuLi was also studied, and reactivity differences between U and Th are discussed. Synthesis of sterically crowded (RC{sub 5}H{sub 4}){sub 4}U compounds is next considered. Reaction of the trivalent (RC{sub 5}H{sub 4}){sub 3}U with (RC{sub 5}H{sub 4}){sub 2}Hg results in formation of (RC{sub 5}H{sub 4}){sub 4}U. Steric congestion, cyclopentadienyl ligand exchange, and electron transfer are discussed. (DLC)

  10. Tris(Cyclopentadienyl)Uranium-t-Butyl: Synthesis, reactions, and mechanisms

    SciTech Connect (OSTI)

    Weydert, M.

    1993-04-01

    Compounds (RC[sub 5]H[sub 4])[sub 3]U(t-Bu) were prepared for R = H, Me, Et. Their decomposition products in aromatic solvents are consistent with a radical decomposition pathway induced by solvent-assisted U-C bond homolysis. NMR was used to study the reactions of (RC[sub 5]H[sub 4])[sub 3]UCl with t-BuLi (R = t-Bu, Me[sub 3]Si). Reactions of (MeC[sub 5]H[sub 4])[sub 3]U(t-Bu) with Lewis bases and fluorocarbons were studied. Analogous reaction chemistry between (RC[sub 5]H[sub 4])[sub 3]ThX systems and t-BuLi was also studied, and reactivity differences between U and Th are discussed. Synthesis of sterically crowded (RC[sub 5]H[sub 4])[sub 4]U compounds is next considered. Reaction of the trivalent (RC[sub 5]H[sub 4])[sub 3]U with (RC[sub 5]H[sub 4])[sub 2]Hg results in formation of (RC[sub 5]H[sub 4])[sub 4]U. Steric congestion, cyclopentadienyl ligand exchange, and electron transfer are discussed. (DLC)

  11. Uranium (VI)Bis(imido) chalcogenate complexes:synthesis and density functional theory analysis

    SciTech Connect (OSTI)

    Spencer, Liam P; Batista, Enrique R; Boncella, James M; Yang, Ping; Scott, Brian L

    2009-01-01

    Bis(imido) uranium(VI) trans- and cis-dichalcogenate complexes with the general formula U(NtBu)2(EAr)2(OPPh3)2 (EAr = O-2-tBuC6H4, SPh, SePh, TePh) and U(NtBu)2(EAr)2(R2bpy) (EAr = SPh, SePh, TePh) (R2bpy = 4,4'-disubstituted-2,2'-bipyridyl, R = Me, tBu) have been prepared. This family of complexes includes the first reported monodentate selenolate and tellurolate complexes of uranium(VI). Density functional theory calculations show that covalent interactions in the U-E bond increase in the trans-dichalcogenate series U(NtBu)2(EAr)2(OPPh3)2 as the size of the chalcogenate donor increases and that both 5f and 6d orbital participation is important in the M-E bonds of U-S, U-Se, and U-Te complexes.

  12. Nuclear Data Sheets for A = 50

    SciTech Connect (OSTI)

    Elekes, Zoltan; Timar, Janos; Singh, Balraj

    2011-01-15

    The experimental nuclear spectroscopic data for known nuclides of mass number 50 (Cl,Ar,K,Ca,Sc,Ti,V, Cr,Mn,Fe,Co,Ni) have been evaluated and presented together with Adopted properties for levels and {gamma} rays. This evaluation has been carried out about 15 years after the previous one by Thomas Burrows (1995Bu29). Except for {sup 50}Sc and {sup 50}V, extensive new data have become available for all the other nuclides in the intervening years. The data for {sup 50}Sc and {sup 50}V have also been checked again in detail and several changes made. No data are yet available for excited states in {sup 50}Cl, {sup 50}Ar and {sup 50}Ni. This work supersedes earlier evaluations (1995Bu29, 1990Bu18, 1984Al29, 1976Au07) of A=50 nuclides.

  13. Synthesis, structure, and coordination chemistry of a tridentate, six-electron-donor amidinate ligand

    SciTech Connect (OSTI)

    Kincaid, K.; Gerlach, C.P.; Giesbrecht, G.R.; Hagadorn, J.R.; Whitener, G.D.; Shafir, A.; Arnold, J.

    1999-12-06

    The coordination chemistry of ancillary amidinate ligands with a pendant pyridine functionality is described. Reaction of p-toluoyl- or p-tBu benzoyl chloride with 2-amino-ethylpyridine generates the amides 2-Py-(CH{sub 2}){sub 2}NHCO(p-RPh) (R = Me 1a tBu 1b); these amides are then converted to the amidines 2-Py-(CH{sub 2}){sub 2}NHC(p-RPh)NR{prime} (R = Me, R{prime} = Ph (2a) (L{sup Me}H); R = tBu, R{prime} = 3,5-dimethylphenyl (2b) (L{sup tBu}H)) by reaction with PCl{sub 5} followed by R{prime}NH{sub 2}. The amidines 2a,b were characterized by {sup 1}H NMR and IR spectroscopy and elemental analyses, and 2b was characterized by X-ray crystallography. Reaction of 2a or 2b with homoleptic metal-alkyls or -amides yields the mono- or bis(amidinate) complexes (L{sup Me}){sub 2}Mg (3a), (L{sup tBu})AlMe{sub 2} (4), (L{sup tBu})Zr(CH{sub 2}Ph){sub 3} (5), and (L{sup Me}){sub 2}La[N(SiMe{sub 3}){sub 2}] (6). All metal complexes were characterized by {sup 1}H NMR and IR spectroscopy, elemental analyses, and X-ray crystallography. The X-ray crystal structures of compounds 3--6 show them to be monomeric, with the pendant pyridine coordinates intramolecularly in all cases. The tridentate amidinate coordinates meridionally to the metal center except in the case of the lanthanum derivative 6, where an approximate facial geometry is observed.

  14. The interactions of azure B, a metabolite of methylene blue, with acetylcholinesterase and butyrylcholinesterase

    SciTech Connect (OSTI)

    Petzer, Anél; Harvey, Brian H.; Petzer, Jacobus P.

    2014-02-01

    Methylene blue (MB) is reported to possess diverse pharmacological actions and is attracting increasing attention for the treatment of neurodegenerative disorders such as Alzheimer's disease. Among the pharmacological actions of MB, is the significant inhibition of acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE). These activities may, at least in part, underlie MB's beneficial effects in Alzheimer's disease. MB is metabolized to yield N-demethylated products of which azure B, the monodemethyl metabolite, is the predominant species. Azure B has been shown to be pharmacologically active and also possesses a variety of biological actions. Azure B therefore may contribute to the pharmacological profile of MB. Based on these considerations, the present study investigates the possibility that azure B may, similar to MB, act as an inhibitor of human AChE and BuChE. The results document that azure B inhibits AChE and BuChE with IC{sub 50} values of 0.486 μM and 1.99 μM, respectively. The results further show that azure B inhibits AChE and BuChE reversibly, and that the modes of inhibition are most likely competitive. Although the AChE and BuChE inhibitory activities of azure B are twofold and fivefold, respectively, less potent than those recorded for MB [IC{sub 50}(AChE) = 0.214 μM; IC{sub 50}(BuChE) = 0.389 μM] under identical conditions, azure B may be a contributor to MB's in vivo activation of the cholinergic system and beneficial effects in Alzheimer's disease. - Highlights: • Methylene blue (MB) is a known inhibitor of AChE and BuChE. • Azure B, the major metabolite of MB, also is an inhibitor of AChE and BuChE. • Azure B may be a contributor to MB's in vivo activation of the cholinergic system. • Azure B may contribute to MB's potential in Alzheimer's disease therapy.

  15. GNU Bug Reports

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  16. Indications of flow near maximum compression in layered deuterium-tritium implosions at the National Ignition Facility

    DOE PAGES-Beta [OSTI]

    Gatu Johnson, M.; Knauer, J. P.; Cerjan, C. J.; Eckart, M. J.; Grim, G. P.; Hartouni, E. P.; Hatarik, R.; Kilkenny, J. D.; Munro, D. H.; Sayre, D. B.; et al

    2016-08-15

    Here, an accurate understanding of burn dynamics in implosions of cryogenically layered deuterium (D) and tritium (T) filled capsules, obtained partly through precision diagnosis of these experiments, is essential for assessing the impediments to achieving ignition at the National Ignition Facility. We present measurements of neutrons from such implosions. The apparent ion temperatures Tion are inferred from the variance of the primary neutron spectrum. Consistently higher DT than DD Tion are observed and the difference is seen to increase with increasing apparent DT Tion. The line-of-sight rms variations of both DD and DT Tion are small, ~150eV, indicating an isotropicmore » source. The DD neutron yields are consistently high relative to the DT neutron yields given the observed Tion. Spatial and temporal variations of the DT temperature and density, DD-DT differential attenuation in the surrounding DT fuel, and fluid motion variations contribute to a DT Tion greater than the DD Tion, but are in a one-dimensional model insufficient to explain the data. We hypothesize that in a three-dimensional interpretation, these effects combined could explain the results.« less

  17. HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2003-07-25

    NEA completed the CFD simulations for all NBFZ tests. SRI resumed work on HPBO experiments and conducted preliminary tests using the UCONN impactor. UCONN prepared several samples of char for cross-sectional analysis by SEM and characterization is underway. BU completed the NBFZ char characterization program. CBK model had been implemented into Fluent.

  18. A=7Li (1988AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    See also (1984AJ01) and Table 7.2 Table of Energy Levels (in PDF or PS) here. Shell model: (1983BU1B, 1983KU17, 1983SH1D, 1983VA31, 1984CH24, 1984REZZ, 1984VA06,...

  19. A=7Be (1988AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    8AJ01) (See Energy Level Diagrams for 7Be) GENERAL: See also (1984AJ01) and Table 7.7 Table of Energy Levels (in PDF or PS) here. Nuclear models: (1983BU1B, 1983FU1D, 1983HO22,...

  20. A=19C (1972AJ02)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    2AJ02) (Not illustrated) 19C may have been observed in the 3 GeV proton bombardment of a 197Au target: if so it is particle stable (1970RA1A). Its mass excess must then be < 37.9 MeV (18C + n). See also (1960ZE03, 1971BU1E

  1. A=20N (1972AJ02)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    2AJ02) (Not illustrated) 20N has been observed in the bombardment of 232Th by 122 MeV 18O ions (1969AR13, 1970AR1D) and in the 3 GeV proton bombardment of 197Au (1970RA1A): it is particle stable. See also (1960ZE03, 1961BA1C, 1971BU1E

  2. Controlled Synthesis of Polyenes by Catalytic Methods. Progress Report, December 1, 1992 -- November 30, 1993

    DOE R&D Accomplishments [OSTI]

    Schrock, R. R.

    1993-12-01

    Four studies are reported: living cyclopolymerization of diethyl dipropargylmalonate by Mo(CH-t-Bu)(NAr)[OCMe(CF{sub 3}){sub 2}]{sub 2} in dimethoxyethane, effect of chain length on conductivity of polyacetylene, nonlinear optical analysis of a series of triblock copolymers containing model polyenes, and synthesis of bifunctional hexafluoro-t-butoxide Mo species and their use as initiators in ROMP reactions.

  3. Lanthanide(III) di- and tetra-nuclear complexes supported by a chelating tripodal tris(amidate) ligand

    DOE PAGES-Beta [OSTI]

    Brown, Jessie L.; Jones, Matthew B.; Gaunt, Andrew J.; Scott, Brian L.; MacBeth, Cora E.; Gordon, John C.

    2015-04-06

    Syntheses, structural, and spectroscopic characterization of multinuclear tris(amidate) lanthanide complexes is described. Addition of K3[N(o-PhNC(O)tBu)3] to LnX3 (LnX3 = LaBr3, CeI3, and NdCl3) in N,N-dimethylformamide (DMF) results in the generation of dinuclear complexes, [Ln(N(o-PhNC(O)tBu)3)(DMF)]2(μ-DMF) (Ln = La (1), Ce (2), Nd(3)), in good yields. Syntheses of tetranuclear complexes, [Ln(N(o-PhNC(O)tBu)3)]4 (Ln = Ce (4), Nd(5)), resulted from protonolysis of Ln[N(SiMe3)2]3 (Ln = Ce, Nd) with N(o-PhNCH(O)tBu)3. As a result, in the solid-state, complexes 1–5 exhibit coordination modes of the tripodal tris(amidate) ligand that are unique to the 4f elements and have not been previously observed in transition metal systems.

  4. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    Hong, Kunlun (1) Hu, Qiao-Sheng (1) Xing, Chun-Hui (1) Zhang, Honghai (1) Save Results ... or Pd2(dba)3t Bu3PArX as the Initiator Zhang, Honghai ; Xing, Chun-Hui ; Hu, Qiao-Sheng ...

  5. HEALTH AhO SAFETY DIVISION Industrial Hygiene or Medical Dept...

    Office of Legacy Management (LM)

    No, Ro Oil PH Be Th Nc0 NO 8506 BcA-j &A- ii JC cL"w-- Anolyticol Chemistry Secrion: Date Received--b4-56 by Lab* Date Reported 6-X-66 bu I&b , Method of Analyair Vluarima4rFpt ...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Similarly, di-n-propyl- or di-n-butylether gives Cp'2Ce(O-n-Pr) and propane or Cp'2Ce(O-n-Bu) and butane, respectively. Using Cp'2CeD, the propane and butane contain deuterium ...

  7. Microsoft Word - lblsubethers.doc

    Office of Scientific and Technical Information (OSTI)

    Similarly, di-n-propyl- or di-n-butylether gives Cp' 2 Ce(O-n- Pr) and propane or Cp' 2 Ce(O-n-Bu) and butane, respectively. Using Cp' 2 CeD, the propane and butane contain ...

  8. Splitting a C-O bond in dialkylethers withbis(1,2,4-tri-t-butylcyclop...

    Office of Scientific and Technical Information (OSTI)

    Similarly, di-n-propyl- or di-n-butylether gives Cp'2Ce(O-n-Pr) and propane or Cp'2Ce(O-n-Bu) and butane, respectively. Using Cp'2CeD, the propane and butane contain deuterium ...

  9. S?. LL-UIIS WLLM

    Office of Legacy Management (LM)

    No. 31 12187 IEmN wffi WE ST. Lulls m ST. cows awv m S?. LL-UIIS WLLM ftl M NV 9 HIC ltRElWXDwIDloIC6IC WVCf ., sm. m buTm1Iv IJm-n Fww. DECMPIISSI 1NltEEhU 1"O'S. llE...

  10. A=19F (1983AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1978DA1N, 1978MA2H, 1979DA15, 1980KU05, 1980MC1L, 1981ER03, 1981GR06, 1982KI02). Cluster, collective and rotational models: (1977BU22, 1977FO1E, 1978BR21, 1978CH26,...

  11. July 2010, Status and Outlook for Nuclear Energy In the United States

    Energy.gov [DOE]

    The U.S. nuclear power industry continues to make pro- gress toward the construction of new nuclear power plants in the United States. Currently, 13 license applica- tions are under active review...

  12. Using PHP format

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... the rapidly to the slowly rotating branch of solu- tions is shown as a dotted line. ... Technol. 19, 131 1991. 7 F. Gnesotto, P. Sonato, W. R. Baker et al., Fusion Eng. ...

  13. BPA-2013-01063-FOIA Request

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Gener ating Station Value Study, including all of its workpapers, author ed by Robert Petty, manager of Power Services Business Opera tions. The draft I have seen was dated as...

  14. LA-11569-M Manual UC-15

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    ... sample well.3 A motor- driven cable moves the source into position where it irradiates the sample for a few seconds, then quickly withdraws the source to a shielded posi- tion. ...

  15. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 9: Natural Gas and Fuel Oil (cb86f09.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted ...

  16. U.S. Energy Information Administration | State Energy Data 2014...

    Annual Energy Outlook

    3 Section 3. Natural Gas Physical units Eight natural gas data series are used to derive the natural gas consump- tion estimates in the State Energy Data System (SEDS). Several of ...

  17. US006753741Bl

    Office of Scientific and Technical Information (OSTI)

    ... separation of about 0.59 ns., Due to tion and dispersion in the nonlinear medium. ... A nonlinear wave crystal and about 10 V for the bi-layer-film waveguides. equation that ...

  18. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 3: Operating Hours (cb86f03.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ...

  19. Mr. John Kieling, Acting Chief Haza

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    or supervision according to a system designed to assure that qualified pers on nel prop erly gather and eva luate th e informa tion submitted . Based on our inquiry of the...

  20. DWIGHT D. EISENHOWER.

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Saving clause If any provision of this chapter, or the applica- tion thereof to any person or circumstance, shall be held invalid, the validity of the remain- der of the chapter...

  1. OAK RIDGE NATIONAL LABORATORY LABO RATO RY RESULTS OF THE INDEPENDENT...

    Office of Legacy Management (LM)

    AT 64 TRUDY DRIVE, LODI, NEW JERSEY (LN004V) M. G. Yalcintas C. A. Johnson* *Biology ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  2. O10'I'uf^^ff%

    Office of Legacy Management (LM)

    AT 59 AVENUE C, LODI, NEW JERSEY (LN008V) M. G. Yalcintas C. A. Johnson* *Biology Division ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  3. ORNL/RASA-86/67

    Office of Legacy Management (LM)

    AT 61 TRUDY DRIVE, LODI, NEW JERSEY (LN003V) M. G. Yalcintas C. A. Johnson* *Biology ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  4. OAK RIDGE NATIONAL LABORATORY LABORATORY RESULTS OF THE INDEPENDENT...

    Office of Legacy Management (LM)

    AT 121 AVENUE F, LODI, NEW JERSEY (LN006V) M. G. Yalcintas C. A. Johnson* *Biology ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  5. OAK RIDGE NATIONAL LABORATORY LABORATORY RESULTS OF THE INDEPENDENT...

    Office of Legacy Management (LM)

    (LNO05V) M. G. Yalcintas C. A. Johnson* *Biology Division Date of Issue - December 1986 ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  6. ORNL/RASA-86/71

    Office of Legacy Management (LM)

    AT 123 AVENUE F, LODI, NEW JERSEY (LN007V) M. G. Yalcintas C. A. Johnson* *Biology ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  7. ORNL/RASA-86/66

    Office of Legacy Management (LM)

    AT 59 TRUDY DRIVE, LODI, NEW JERSEY (LN002V) M. G. Yalcintas C. A. Johnson* *Biology ... In addi- tion, the authors appreciate the manuscript preparation by J. M. Wyrick, Biology ...

  8. U.S. Global Change Research Program Recommended Citation: Global...

    National Nuclear Security Administration (NNSA)

    ... A billboard on Pohnpei, in the Fed- erated States of Micronesia, encour- ages water conservation in prepara- tion for the 1997 to 1998 El Nio. Extreme Sea-Level Days: Honolulu, ...

  9. Section 52

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... This includes the Planck func- tion, the contribution of minor species to absorption in ... this was accomplished by map- ping the Planck function at T5780K in each band ...

  10. Paul Hommert PRESIDENT AND LABORATORIES DIRECTOR

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    The post-Cold War world has presented new and complex issues for America, ranging from ... on clean, renewable solu- tions such as solar, wind, and research into fusion technology. ...

  11. Estimation of changes in insulation resistance with various design parameters of interdigitated wire loops.

    SciTech Connect (OSTI)

    Cordaro, Joseph Gabriel; Jones, Reese E.; Neel, Wiley Christopher

    2015-09-01

    In this report we explore the sensitivities of the insulation resistance between two loops of wire embedded in insulating materials with a simple, approximate model. We discuss limita- tions of the model and ideas for improvements.

  12. Microsoft Word - anthrax3.doc

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Low pH condi- tions (around pH 5.5) then induce a pre-pore to pore conformational switch that allows the enzymes to enter and eventually kill the host cell. In severe cases, such ...

  13. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    U.S. Energy Information Administration (EIA) (indexed site)

    marked the beginning of new federal and state regula- tions governing gasoline. The phase-in period for fed- eral Tier 2 gasoline sulfur standards (with regulations to be fully...

  14. TITLE

    Office of Legacy Management (LM)

    ... April 4, 1968 (UCRL) (specific.- tions). MSA-23-2184 Well Temt Data, Volune 111, 1968, 1969 (EP1IG) (Specifications). USA-Not Cited Inventory of Wcllr and Springs Witbin a 10-Mile ...

  15. Explanatory Notes

    U.S. Energy Information Administration (EIA) (indexed site)

    complete enumera- tion has the same nonsampling errors as the sample survey. The sampling error, or standard error of the estimate, is a measure of the variability among the...

  16. VOLUME

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... source from ioniza- tion of neutral hydrogen (deuterium) and low-Z impuri- ties, a ... current drive, or PPCD) to alter the mag- netic fluctuations and particle transport 12. ...

  17. Section 65

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    American Meteorological Society, Boston, 241-242. Ellingson, R.G., S.H. Shen, and J. Warner, 1994b: Calibra- tion of radiation codes used in climate models: Comparison of...

  18. TECHNOLOGY PROGRAM PLAN

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    ... The exhaust gas of a combus- tion turbine is very hot and ... can be deployed for coal-based ad- vanced integrated ... have a working fuid that contains mostly CO 2 and water. ...

  19. --No Title--

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    File 8: Electricity (cb86f08.csv) Ques- tion- naire Variable Variable Variable Variable ... was completed YRCONC3 31- 32 YRCONC. Electricity supplied ELSUPL3 34- 34 XXSUPL. ...

  20. --No Title--

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    File 8: Electricity (CBECS89.A08) Ques- tion- naire Variable Variable Variable Variable ... 18 YRCONC. P1A Seasonal pricing for electricity ELSEAS4 20- 20 YESNO. P1B Time-of-day ...

  1. DOE/EIA-0207/2 Residential Energy Consumption Survey:

    Gasoline and Diesel Fuel Update

    to keep a log of their fuel purchases and odometer readings for a two-month period. The panel consists of 500 to 1,000 households reporting each month. Separate tabula tions of...

  2. SUBCHAPTER G-NATURAL GAS (ECONOMIC REGULATORY ADMINISTRATION...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    shall provide a time limit of not less than thirty (30) days from the notice's date of publica- tion in the FEDERAL REGISTER for per- sons to file protests, comments, or a...

  3. Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized...

    Office of Scientific and Technical Information (OSTI)

    ... tion up to 800C,1-3 high yield strengths at elevated temperatures,4 high ... lowest surface energy planes are the 111 family of planes, which have been numerically ...

  4. Data Center Energy Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Center Energy Efficiency In 2014, data centers in the U.S. con- sumed an estimated 70 billion kWh, 1.8% of total U.S. electricity consump- tion. 1 Thus, it is no surprise that both ...

  5. Tax Incentives

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    tax credits for each kilowatt-hour (kWh) of electricity generated by the facility power projects are eligible to receive 2.3 cents per kWh for the produc - tion of electricity ...

  6. MEMORANDUM TO: FILE

    Office of Legacy Management (LM)

    ... HISTORl' Li.YITELl ST.-ITES .4R.O' 1 I:iSHZ.% TO.- D. C., I985 tion plants. ... and lubri- cants-needed to operate the plants safelv and efficiently with the highly ...

  7. Search results | Department of Energy

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    tion-energy-electricity-consumption-and-efficiency Download An Exploration of Wind Energy & Wind Turbines This unit, which includes both a pre and post test on wind power engages...

  8. November 2007 BWXTymes

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    ... The 9731 Beta calutrons made a signifi cant contribu- tion to the Stable Isotope Program that produced the genesis of the medical radioisotopes used for diagnosis and treatment of ...

  9. Title

    National Nuclear Security Administration (NNSA)

    ... PHOTOGRAPHS TAKEN AUGUST, 1991 BY E G 8 G ENERGY MEASUREMENTS, INC. TION ALLUVIAL FAN ... AT DESIRED CALCULATION INTERVAL LOSS RATE:GREEN AND AMPT INFILTRATION KINEMATIC WAVE: NEW ...

  10. 29 CFR 1910 Occupational Safety and Health Standards

    National Nuclear Security Administration (NNSA)

    ... XVII (7-1-07 Edition) 1910.7 which will be available on the OSHA web site. APPENDIX A ... tion), and synthetic web (nylon, poly- ester, and polypropylene). (b) Definitions. ...

  11. Simplified P N Equations Steven P. Hamilton, Thomas M. Evans

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Laboratory, 1 Bethel Valley Rd., Oak Ridge, TN 37831 U.S.A. Abstract In this paper we show new solver strategies for the multigroup SP N equa- tions for nuclear reactor analysis. ...

  12. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    Flags for HVAC, Lighting and Shell Conservation Features (cb86f14.csv) Ques- tion- ... Flags for HVAC, Lighting, and Shell Conservation Features (cb86f14.csv) (continued) ...

  13. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 15: Imputation Flags for Lighting and Conservation Features (CBECS89.A15) Ques- tion- ... ZMAINT4 90- 90 ZVAR. Imputed utility conservation program ZUTCNS4 92- 92 ZVAR. Imputed ...

  14. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 7: HVAC, Lighting, and Building Shell Conservation Features (cb86f07.csv) Ques- tion- ... 52- 52 YESNO. G-3A3 Other HVAC conservation measures OTHVAC3 54- 54 YESNO. G-3A3 ...

  15. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 7: Lighting and Conservation Features (CBECS89.A07) Ques- tion- naire Variable ... 102 YESNO. H6 Participated in utility conservation pgm UTCNS4 104- 104 YESNO. Adjusted ...

  16. Figure2b.eps

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... except the bare Coulomb interaction is replaced by the screened Coulomb interac- tion: W GG ' (q ; ) -1 GG ' (q ; )v(q + G ' ) where v is the bare Coulomb interaction. ...

  17. Microsoft Word - $ASQrpt78020.DOC

    Office of Scientific and Technical Information (OSTI)

    ... Op-tions, National Academies Press, Washington, DC. 2. U.S. Department of Energy (2005) Emission of Green-house Gases in the United States, www.eia.doe.gov oiaf1605flash...

  18. Washington. DC,20585

    Office of Legacy Management (LM)

    you mayihave. ' ,. If you have any ques Dr. Y. Alexander Wil tions, please feel free to call me at 301-903-2531 or liams (301-903UW' of my staff..,, Sincerely, Enclosures...

  19. --No Title--

    U.S. Energy Information Administration (EIA) (indexed site)

    File 10: Fuel Oil (CBECS89.A10) Ques- tion- naire Variable Variable Variable Variable ... YRCONC4 17- 18 YRCONC. P3 Total fuel oil tank capacity (gallons) TOTCAP4 20- 25 ...

  20. Dr. Googin and his early days at Y-12, part 8 -- Googin made...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    to do just that. His first "assault" on the chemical process, as he called it in his biography, was on the peroxide precipita- tion. He wanted to make the process handle more...

  1. An Optimized Swinging Door Algorithm for Wind Power Ramp Event...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... An applica- tion of the optimized SDA is provided to ascertain the op- timal parameter of the original SDA. Measured wind power data from the Electric Reliability Council of Texas ...

  2. Energy Technology Solutions: Public-Private Partnerships Transforming...

    Energy.gov (indexed) [DOE]

    IndustrIal technologIes save energy and Boost competItIveness EnErgy TEchnology SoluTionS public-private partnerships transforming Industry december 2010 "We need a sustained ...

  3. CABLE AOORIs*. HICRONIZER. MOORLblOWN. NEW ,SRIEY

    Office of Legacy Management (LM)

    This provision, how- ever, ls.' subJect:to eny.prlor'arracmont between your Institu- tion and the government with respect to inventions and p?j,tents. ,.: 3,ri 'I :: .:v:ri ...

  4. ch_4

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    based on annual exposure for 1995, 1996, and 1999. Based on 1990 U.S. Census Bureau data, the surrounding popula- tion consisted of approximately 120,000 people within a ...

  5. BPA-2013-00334-FOIA Request

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    but not limited to, the use of existing access roads and tower loca tions on wetlands. Page 3 of 4 The subject of the request: Whether the subject of the requested records...

  6. Word Pro - S1

    U.S. Energy Information Administration (EIA) (indexed site)

    Table 1.7 Primary Energy Consumption, Energy Expenditures, and Carbon Dioxide Emissions Indicators Primary Energy Consumption a Energy Expenditures b Carbon Dioxide Emissions c Consump- tion Consump- tion per Capita Consumption per Real Dollar d of GDP e Expendi- tures Expendi- tures per Capita Expenditures as Share of GDP e Expenditures as Share of Gross Output f Emissions Emissions per Capita Emissions per Real Dollar d of GDP e Quadrillion Btu Million Btu Thousand Btu per Chained (2009)

  7. The Environmental Style: Writing Environmental Assessments and Impact

    Energy Savers

    NATIONAL AND HOMELAND SECURITY Continued next page Network Interconnectivity The business world is online. So are hackers. The dangers and complica- tions of controlling corporate network access and informa- tion flow from unauthorized users has been a consistent problem since the Inter- net's inception. The guiding principal seems to be that if a programmer can build it, a hacker can destroy it. A virtual back and forth battle of patches and worms, upgrades and viruses has evolved. In addition,

  8. Wind for Schools Project Curriculum Brief (Fact Sheet), Wind And Water Power Program (WWPP)

    WindExchange

    Introduction The U.S. Department of Energy's (DOE's) 20% Wind Energy by 2030 report recommends expanding educa- tion to ensure a trained workforce to meet the projected growth of the wind industry and deployment. Although a few U.S. higher education institu- tions offer wind technology education programs, most are found in community and technical colleges, resulting in a shortage of programs preparing highly skilled graduates for wind industry careers. Further, the United States lags behind

  9. The Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    NATIONAL AND HOMELAND SECURITY Continued next page Network Interconnectivity The business world is online. So are hackers. The dangers and complica- tions of controlling corporate network access and informa- tion flow from unauthorized users has been a consistent problem since the Inter- net's inception. The guiding principal seems to be that if a programmer can build it, a hacker can destroy it. A virtual back and forth battle of patches and worms, upgrades and viruses has evolved. In addition,

  10. One-step through-mask electrodeposition of a porous structure composed of manganese oxide nanosheets with electrocatalytic activity for oxygen reduction

    SciTech Connect (OSTI)

    Fukuda, Masaki; Iida, Chihiro; Nakayama, Masaharu

    2009-06-03

    Potentiostatic electrolysis of a mixed aqueous solution of Bu{sub 4}NBr and MnSO{sub 4} at +1.0 V (vs. Ag/AgCl) on Pt electrode led to the oxidation of Br{sup -} and Mn{sup 2+} ions. X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and X-ray diffraction (XRD) revealed that this anodic process was followed by the deposition of insulating crystals of bromide salt of Bu{sub 4}N{sup +} and the subsequent formation of layered manganese oxide in the interstitial spaces of the bromide grains already grown. Dissolution of the bromide crystals in water left a well-dispersed porous texture composed of manganese oxide nanosheets. The resulting MnO{sub x}-modified electrode exhibited a larger catalytic current for the reduction of oxygen in alkaline solution, compared to the bare Pt electrode.

  11. A=11C (1980AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    80AJ01) (See Energy Level Diagrams for 11C) GENERAL: See also (1975AJ02) and Table 11.19 [Table of Energy Levels] (in PDF or PS). Special levels: (1976IR1B). Astrophysical questions: (1976VI1A, 1977SC1D, 1977SI1D, 1978BU1B). Special reactions: (1975HU14, 1976BE1K, 1976BU16, 1976DI01, 1976HE1H, 1976LE1F, 1976SM07, 1977AR06, 1977AS03, 1977SC1G, 1978DI1A, 1978GE1C, 1978HE1C, 1979KA07, 1979VI05). Muon and neutrino capture and reactions: (1975DO1F, 1976DO1G). Pion capture and reactions (See also

  12. A=12N (1985AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    5AJ01) (See Energy Level Diagrams for 12N) GENERAL: See also (1980AJ01) and Table 12.22 [Table of Energy Levels] (in PDF or PS). Model calculations:(1980OK01). Muon and neutrino capture and reactions:(1979MA1U, 1982MI05). Pion capture and reactions (See also reactions 2, 4 and 5.):(1979BU1C, 1979NA1J, 1979RA1G, 1979SI16, 1980KE13, 1980KL03, 1980NA11, 1980RA05, 1980SI07, 1980TR1A, 1981DU1H, 1981SI09, 1981RA16, 1982BE1D, 1982RA28, 1982SC1L, 1983DE2G, 1983GI08). Hypernuclei:(1979BU1C, 1981WA1J,

  13. A=12O (1985AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    5AJ01) (See the Isobar Diagram for 12O) 12O has been observed in the 16O(α, 8He) reaction at Eα = 117.4 MeV (1978KE06) and in the 12C(π+, π-) reaction at Eπ = 164 MeV (1983BL08; see for angular distribution) and 180 MeV (1980BU15). The mass excess of 12O is 32.10 ± 0.12 MeV (1978KE06), 32.059 ± 0.048 MeV (1980BU15): we adopt 32.065 ± 0.045 MeV. 12O is thus unstable to decay into 10C + 2p by 1.79 MeV and into 11N* + p by 0.45 MeV [note that 11N* is probably not the ground state of 11N and

  14. A=15O (1981AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    81AJ01) (See Energy Level Diagrams for 15O) GENERAL: See also (1976AJ04) and Table 15.18 [Table of Energy Levels] (in PDF or PS) here. Shell model: (1976LI16, 1976SA37, 1977EM01, 1977PO16). Special states: (1976LI16, 1977RI08). Electromagnetic transitions: (1976LI16, 1976SH04, 1977HO04, 1978KR19). Astrophysical questions: (1977BA1V, 1977SI1D, 1978BU1B, 1978WO1E, 1979PE1E). Special reactions involving 15O: (1976AB04, 1976BU16, 1976HE1H, 1976HI05, 1976LE1F, 1977AR06, 1977SC1G, 1978AB08, 1978BO1W,

  15. Application of Gold Electrodes for the Study of Nickel Based Homogeneous Catalysts for Hydrogen Oxidation

    SciTech Connect (OSTI)

    Nepomnyashchii, Alexander B.; Liu, Fei; Roberts, John A.; Parkinson, Bruce A.

    2013-08-12

    Gold and glassy carbon working electrode materials are compared as suitable substrates for the hydrogen oxidation reaction with Ni(PCy2Nt-Bu2)2(BF4)2 used as a catalyst. Voltammetric responses showing electrocatalytic hydrogen oxidation mediated by the homogeneous electrocatalyst Ni(PCy2Nt-Bu2)2(BF4)2 are identical at glassy carbon and gold electrodes, which shows that gold electrode can be used for hydrogen oxidation reaction. This work is supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under FWP 56073.

  16. Evaluating ligands for use in polymer ligand film (PLF) for plutonium and uranium extraction

    DOE PAGES-Beta [OSTI]

    Rim, Jung H.; Peterson, Dominic S.; Armenta, Claudine E.; Gonzales, Edward R.; Ünlü, Kenan

    2015-05-08

    We describe a new analyte extraction technique using Polymer Ligand Film (PLF). PLFs were synthesized to perform direct sorption of analytes onto its surface for direct counting using alpha spectroscopy. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through a radiometric technique. 4'(5')-di-t-butylcyclohexano 18-crown-6 (DtBuCH18C6) and 2-ethylhexylphosphonic acid (HEH[EHP]) were examined for plutonium extraction. Di(2-ethyl hexyl) phosphoric acid (HDEHP) were examined for plutonium and uranium extraction. DtBuCH18C6 and HEH[EHP] were not effective in plutonium extraction. HDEHP PLFs were effective for plutonium but not for uranium.

  17. Evaluating ligands for use in polymer ligand film (PLF) for plutonium and uranium extraction

    SciTech Connect (OSTI)

    Rim, Jung H.; Peterson, Dominic S.; Armenta, Claudine E.; Gonzales, Edward R.; Ünlü, Kenan

    2015-05-08

    We describe a new analyte extraction technique using Polymer Ligand Film (PLF). PLFs were synthesized to perform direct sorption of analytes onto its surface for direct counting using alpha spectroscopy. The main focus of the new technique is to shorten and simplify the procedure for chemically isolating radionuclides for determination through a radiometric technique. 4'(5')-di-t-butylcyclohexano 18-crown-6 (DtBuCH18C6) and 2-ethylhexylphosphonic acid (HEH[EHP]) were examined for plutonium extraction. Di(2-ethyl hexyl) phosphoric acid (HDEHP) were examined for plutonium and uranium extraction. DtBuCH18C6 and HEH[EHP] were not effective in plutonium extraction. HDEHP PLFs were effective for plutonium but not for uranium.

  18. Synthesis and structural characterization of two half-sandwich nickel(II) complexes with the scorpionate ligands

    SciTech Connect (OSTI)

    Wang, G.-F. E-mail: s-shuwen@163.com; Zhang, X.; Sun, S.-W.; Sun, H.; Ma, H.-X.

    2015-12-15

    The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k{sup 3}-N, N',N''-Tp{sup t-Bu}, {sup Me}NiI] (1) and [k{sup 3}-N,N',N''-Tp{sup t-Bu}, {sup Me}NiNO{sub 3}] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II) ion of complex 1 is in a four-coordinate environment, in which the donor atoms are provided by three nitrogen atoms of a hydrotris(pyrazolyl) borate ligand and one iodide atom, while that of complex 2 is in a five-coordinate environment with three nitrogen atoms from a hydrotris(pyrazolyl)borate ligand and two oxygen atoms from a nitrate ion.

  19. Simulation of differential die-away instrument’s response to asymmetrically burned spent nuclear fuel

    SciTech Connect (OSTI)

    Martinik, Tomas; Henzl, Vladimir; Grape, Sophie; Svard, Staffan Jacobsson; Jansson, Peter; Swinhoe, Martyn T.; Tobin, Stephen J.

    2015-03-04

    Here, previous simulation studies of Differential Die–Away (DDA) instrument’s response to active interrogation of spent nuclear fuel from a pressurized water reactor (PWR) yielded promising results in terms of its capability to accurately measure or estimate basic spent fuel assembly (SFA) characteristics, such as multiplication, initial enrichment (IE) and burn-up (BU) as well as the total plutonium content. These studies were however performed only for a subset of idealized SFAs with a symmetric BU with respect to its longitudinal axis. Therefore, to complement the previous results, additional simulations have been performed of the DDA instrument’s response to interrogation of asymmetrically burned spent nuclear fuel in order to determine whether detailed assay of SFAs from all 4 sides will be necessary in real life applications or whether a cost and time saving single sided assay could be used to achieve results of similar quality as previously reported in case of symmetrically burned SFAs.

  20. Class 1 Permit Modification Notification

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Bu il ding 1 Santa Fe, New Mexico 87505-6303 JUL 0 5 2011 Subject: Notification of a Class 1 Permit Modification to the Hazardous Waste Facility Permit, Permit Number: NM4890139088-TSDF Dear Mr. Kieling : Enclosed is a Class 1 Permit Modification Notification 1 0: * Update Emergency Coordinator list We certify under penalty of law that this document and the enclosure were prepared under our direction or supervision in

  1. Hydro-Pac Inc., A High Pressure Company | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hydro-Pac Inc., A High Pressure Company Hydro-Pac Inc., A High Pressure Company This presentation was given at the DOE Hydrogen Compression, Storage, and Dispensing Workshop in March 2013. csd_workshop_6_siefert.pdf (71.03 KB) More Documents & Publications 2013 Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop Final Report Haskel/BuTech/PPI Hydrogen Transmission and Distribution Workshop

  2. Intermolecular C?H bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to a vanadium-benzyne complex

    SciTech Connect (OSTI)

    Andino, Jos G.; Kilgore, Uriah J.; Pink, Maren; Ozarowski, Andrew; Krzystek, J.; Telser, Joshua; Baik, Mu-Hyun; Mindiola, Daniel J.

    2012-01-20

    Breaking of the carbon-hydrogen bond of benzene and pyridine is observed with (PNP)V(CH{sub 2}tBu){sub 2} (1), and in the case of benzene, the formation of an intermediate benzyne complex (C) is proposed, and indirect proof of its intermediacy is provided by identification of (PNP)VO({eta}{sup 2}-C{sub 6}H{sub 4}) in combination with DFT calculations.

  3. Mr. John E. Kieling, Bureau Chief Hazardous Waste Bureau

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Carl sbad, New Mexico 88221 SEP 1 6 2015 Ms. Kathryn Roberts, Director Resource Protection Division New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, NM 87508-6303 New Mexico Environment Department Harold Runnels Bu ildi ng 1190 Saint Francis Drive, PO Box 5496 Santa Fe, NM 87502-5469 Subject: Fifth Supplement to the Report of Implementation of the Waste Isolation Pilot Plant Facility Resource Conservation and Recovery Act Contingency Plan on April 11, 2014 Dear

  4. Nuclear Data Sheets for A = 68

    SciTech Connect (OSTI)

    McCutchan, E. A.

    2012-07-01

    The experimental results from the various reaction and radioactive decay studies leading to nuclides in the A = 68 mass chain have been reviewed. Nuclides ranging from Cr (Z = 24) to Br (Z = 35) are included. For these nuclei, level and decay schemes, as well as tables of nuclear properties, are given. This work supersedes the previous evaluation of the data on these nuclides (2002Bu29).

  5. Radioisotope thermoelectric generator transportation system safety analysis report for packaging. Volumes 1 and 2

    SciTech Connect (OSTI)

    Ferrell, P.C.

    1996-04-18

    This SARP describes the RTG Transportation System Package, a Type B(U) packaging system that is used to transport an RTG or similar payload. The payload, which is included in this SARP, is a generic, enveloping payload that specifically encompasses the General Purpose Heat Source (GPHS) RTG payload. The package consists of two independent containment systems mounted on a shock isolation transport skid and transported within an exclusive-use trailer.

  6. Utility: Order (2016-CE-42007) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    CE-42007) Utility: Order (2016-CE-42007) January 5, 2016 DOE ordered Utility Refrigerator to pay a $8,000 civil penalty after finding Utility had failed to certify that certain models of commercial refrigerator equipment comply with the applicable energy conservation standards. The Order adopted a Compromise Agreement, which reflected settlement terms between DOE and Utility. Utility: Order (2016-CE-42007) (22.13 KB) More Documents & Publications Utility: Proposed Penalty (2016-CE-42007) Bu

  7. Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants

    DOE Patents [OSTI]

    Meikrantz, David H.; Todd, Terry A.; Riddle, Catherine L.; Law, Jack D.; Peterman, Dean R.; Mincher, Bruce J.; McGrath, Christopher A.; Baker, John D.

    2007-11-06

    A mixed extractant solvent including calix[4]arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The mixed extractant solvent may be used to remove cesium and strontium from an acidic solution. The DtBu18C6 may be present from approximately 0.01 M to approximately 0.4M, such as from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The mixed extractant solvent may form an organic phase in an extraction system that also includes an aqueous phase. Methods of extracting cesium and strontium as well as strontium alone are also disclosed.

  8. Extractant composition including crown ether and calixarene extractants

    DOE Patents [OSTI]

    Meikrantz, David H.; Todd, Terry A.; Riddle, Catherine L.; Law, Jack D.; Peterman, Dean R.; Mincher, Bruce J.; McGrath, Christopher A.; Baker, John D.

    2009-04-28

    An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

  9. EMPHASIS(TM)/Nevada Unstructured FEM Implementation Version 2.1.1.

    SciTech Connect (OSTI)

    Turner, C. David; Pointon, Timothy D.; Cartwright, Keith

    2014-08-01

    EMPHASIS TM /NEVADA is the SIERRA/NEVADA toolkit implementation of portions of the EMP HASIS TM code suite. The purpose of the toolkit i m- plementation is to facilitate coupling to other physics drivers such as radi a- tion transport as well as to better manage code design, implementation, co m- plexity, and important verification and validation processes. This document describes the theory and implementation of the unstructured finite - element method solver , associated algorithms, and selected verification and valid a- tion . Acknowledgement The author would like to recognize all of the ALEGRA team members for their gracious and willing support through this initial Nevada toolkit - implementation process. Although much of the knowledge needed was gleaned from document a- tion and code context, they were always willing to consult personally on some of the less obvious issues and enhancements necessary.

  10. Analysis of the neutron time-of-flight spectra from inertial confinement fusion experiments

    DOE PAGES-Beta [OSTI]

    Hatarik, R.; Sayre, D. B.; Caggiano, J. A.; Phillips, T.; Eckart, M. J.; Bond, E. J.; Cerjan, C.; Grim, G. P.; Hartouni, E. P.; Knauer, J. P.; et al

    2015-11-12

    For a long time, neutron time-of-flight diagnostics been used to characterize the neutron spectrum produced by inertial confinement fusion experiments. The primary diagnostic goals are to extract the d+t→n+α (DT) and d+d→n+³He (DD) neutron yields and peak widths, and the amount DT scattering relative to its unscattered yield, which is also known as the down-scatter ratio (DSR). These quantities are used to infer yield weighted plasma conditions, such as ion temperature (Tion) and cold fuel areal density. We explain such novel methodologies used to determine neutron yield, apparent Tion and DSR.

  11. S A V A N N A H R I V E R S I T E

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Excerpts from "Strengthening Energy Security through Federal Partnerships" 67 ENE RGY The Military Engineer * No. 676 The need to shrink depen dence on fos- sil fuels is not a new conce pt in the na- tion's energy discus sion, nor is the need to invest in clean, renew able energy . But the challe nge of how to deliver solar, bioma ss, wind, wave, geothe rmal and other power genera tion techno logies in a cost effecti ve, large-s cale mann er-an d meet the chang - ing energy deman ds of

  12. Superconductivity Program Overview High-Temperature Superconductivity

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SuperconducTiviTy program haS Three FocuS areaS: SuperconducTiviTy applicaTionS Developing HTS-based electric power equipment such as transmission and distribution cables and fault current limiters Second-generaTion Wire developmenT Developing high-performance, low-cost, second- generation HTS wire at long lengths STraTegic reSearch Supporting fundamental research activities to better understand relationships between the microstructure of HTS materials and their ability to carry large electric

  13. Microsoft Word - summer.doc

    U.S. Energy Information Administration (EIA) (indexed site)

    b trac ting fro m th e da ily a ve rag e hig h te m p e ra tu res fo r th e la st 10 y ea rs a n am o un t e qu al to tw ice a n estim ate o f the stan da rd de via tion for h igh...

  14. IoT Interoperability at Bosch

    Energy.gov (indexed) [DOE]

    Acquire d S oftwa re Innova tions , 2008 Bus ine s s proce s s ma na ge me nt Cloud-ba s e d IoT s olutions Acquiring P ros ys t (a nnounce d Fe brua ry 2015) P...

  15. The Honorable Aaron Thompson.

    Office of Legacy Management (LM)

    I lper ic. iiii SkIi lriili e 1 S.' ;e le ;hiT ' si viec I s'ii '0 ic It lb it i te L 1. ess In rma tjo ion I r Ai 'uil el a the I or .I . nls ,3"' .in : ,tion .' 'n is " eir ' ...

  16. Proposed Wild Horse Pass Substation Option

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    LAK E C ITY, U T PAN EL 2 ELEC TR IC ITY D ISTR IBU TION AN D EN D -U SE: H OW D O W E MAN AGE C H ALLEN GES AN D OPPOR TU N ITIES? AP R I L 2 5 , 2 0 1 6 Gila River Indian ...

  17. NUCLEAR EXPLOSIONS - PEACEFUI APPLICATIONS PROJECT WUL 1 SON

    Office of Legacy Management (LM)

    NUCLEAR EXPLOSIONS - PEACEFUI APPLICATIONS PROJECT WUL 1 SON F I N A L OPERATIONAL WAB$OACTIVI TY REPORT PRODUCT1 ON TESTS FEBRUARY 1972 PEACEFUL APPLICATIONS DIVISION NEVADA OPER4TIONS OFFICE This page intentionally left blank TABLE OF CONTENTS Subject Page N o . Abstract . . . . . . . . . . . . . . . . . . . . . . . . . . i i . . . . . . . . . . . . . . . . . . . . . . Acknowledgements i i i . . . . . . . . . . . . . . . . . . . . . . I . Introduction 1 I1 . F i r s t Production Test . . . . .

  18. Transforming PV Installations Toward Dispatchable, Schedulable...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Toward disPaTchable, schedulable energy soluTions MIChAEl MIllS-PrICE, SEGIS-AC ProGrAM MAnAGEr, AE SolAr EnErGy A B C N SATCON518kw1 B2+2 Cap Bank 7825S PHC870 6896 Aout Ain ...

  19. las

    Office of Legacy Management (LM)

    ... Net confining p r e s s u r e ( N C P ) , which is the oil p r e s s u r e minus mean gas ... C o r e Laboratories, Inc., Measurements for Austral Oil Co., private communica- tion ...

  20. Controlled Synthesis of Polyenes by Catalytic Methods. Progress Report, December 1, 1989 -- November 30, 1992

    DOE R&D Accomplishments [OSTI]

    Schrock, R. R.

    1992-01-01

    A more direct approach to polyenes by the direct polymerization of acetylenes has been achieved. We were able to show that polymerization of acetylene itself can be controlled with a well- characterized alkylidene catalyst, but only if a base such as quinuclidine is present in order to slow down the rate of propagation relative to initiation. (Quinuclidine may also stabilize vinylalkylidene intermediates formed in the reaction). Unfortunately, living polyenes were no more stable than isolated polyenes, and so this approach had its limitations. Direct polymerization of acetylene by Mo(CH-t-Bu)(NAr)(O-t-Bu){sub 2} was more successful, but inherent polyene instability was still a problem. The most important result of the past grant period is the finding that dipropargyl derivatives (HC=CCH{sub 2}XCH{sub 2}C=CH; X = CH{sub 2}, C(CO{sub 2}R){sub 2}, SiR{sub 2}, etc.), which have been reported to be cyclopolymerized by various classical catalysts by as yet unknown mechanisms, are polymerized by Mo(CH-t-Bu)(NAr)[OCMe(CF{sub 3}){sub 2}]{sub 2} in dimethoxyethane. We speculate that intramolecular formation of a five-membered ring in the product of {alpha} addition is fast enough to yield another terminal alkylidene on the time scale of the polymerization reaction, while a six-membered ring is formed in a reaction involving a more reaction terminal alkylidene. Either intermediate alkylidene, but most likely the terminal alkylidene, could react with additional monomer to lead to growth of a chain having dangling triple bonds that eventually could be employed to form crosslinks.

  1. Sample Preparation Report of the Fourth OPCW Confidence Building Exercise on Biomedical Sample Analysis

    SciTech Connect (OSTI)

    Udey, R. N.; Corzett, T. H.; Alcaraz, A.

    2014-07-03

    Following the successful completion of the 3rd biomedical confidence building exercise (February 2013 – March 2013), which included the analysis of plasma and urine samples spiked at low ppb levels as part of the exercise scenario, another confidence building exercise was targeted to be conducted in 2014. In this 4th exercise, it was desired to focus specifically on the analysis of plasma samples. The scenario was designed as an investigation of an alleged use of chemical weapons where plasma samples were collected, as plasma has been reported to contain CWA adducts which remain present in the human body for several weeks (Solano et al. 2008). In the 3rd exercise most participants used the fluoride regeneration method to analyze for the presence of nerve agents in plasma samples. For the 4th biomedical exercise it was decided to evaluate the analysis of human plasma samples for the presence/absence of the VX adducts and aged adducts to blood proteins (e.g., VX-butyrylcholinesterase (BuChE) and aged BuChE adducts using a pepsin digest technique to yield nonapeptides; or equivalent). As the aging of VX-BuChE adducts is relatively slow (t1/2 = 77 hr at 37 °C [Aurbek et al. 2009]), soman (GD), which ages much more quickly (t1/2 = 9 min at 37 °C [Masson et al. 2010]), was used to simulate an aged VX sample. Additional objectives of this exercise included having laboratories assess novel OP-adducted plasma sample preparation techniques and analytical instrumentation methodologies, as well as refining/designating the reporting formats for these new techniques.

  2. Billion Ton Study

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Billion-Ton Study Chapter 4 - At the Farmgate: Agricultural Residues and Biomass Energy Crops Maggie Davis Oak Ridge National Laboratory Co-authors: L. Eaton, M. Langholtz, A. Turhollow, C. Hellwinckel, C. Brandt, M. Hilliard Breakout Session 1-A July 13, 2016 Scope ◆ Consistent with BT2 (2011): * Anchored to USDA Long Term Forecast (Baseline) * Demands for food, feed, fiber, exports prioritized * Scenarios * Basecase * High Yield (2-4%) energy crop with high corn yield (265 bu/ac in 2040) ◆

  3. HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

    SciTech Connect (OSTI)

    Chris Guenther, Ph.D.

    2003-01-28

    SRI has completed the NBFZ test program, made modification to the experimental furnace for the HPBO test. The NBFZ datasets provide the information NEA needs to simulate the combustion and fuel-N conversion with detailed chemical reaction mechanisms. BU has determined a linear swell of 1.55 corresponding to a volumetric increase of a factor of 3.7 and a decrease in char density by the same factor. These results are highly significant, and indicate significantly faster burnout at elevated pressure due to the low char density and large diameter.

  4. Highly efficient greenish-blue platinum-based phosphorescent organic light-emitting diodes on a high triplet energy platform

    SciTech Connect (OSTI)

    Chang, Y. L. Gong, S. White, R.; Lu, Z. H.; Wang, X.; Wang, S.; Yang, C.

    2014-04-28

    We have demonstrated high-efficiency greenish-blue phosphorescent organic light-emitting diodes (PHOLEDs) based on a dimesitylboryl-functionalized C^N chelate Pt(II) phosphor, Pt(m-Bptrz)(t-Bu-pytrz-Me). Using a high triplet energy platform and optimized double emissive zone device architecture results in greenish-blue PHOLEDs that exhibit an external quantum efficiency of 24.0% and a power efficiency of 55.8?lm/W. This record high performance is comparable with that of the state-of-the-art Ir-based sky-blue organic light-emitting diodes.

  5. A=18C (1972AJ02)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    2AJ02) (Not illuatrated) 18C is particle stable. Therefore its atomic mass excess, M - A, must be < 29.84 MeV [16C + 2n] (1970WA1G). 18C has been observed in the bombardment of 232Th by 122 MeV 18O ions (1969AR13, 1970AR1D) and in the 3 GeV proton bombardment of Au (1970RA1A). See also (1960ZE03, 1968PO04, 1971BU1E

  6. A=18Ne (1983AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    83AJ01) (See Energy Level Diagrams for 18Ne) GENERAL: See also (1978AJ03) and Table 18.21 [Table of Energy Levels] (in PDF or PS). Model calculations: (1979DA15, 1979SA31, 1980ZH01). Electromagnetic transitions: (1977HA1Z, 1979SA31, 1982LA26). Special states: (1977HE18, 1978KR1G, 1979DA15, 1979SA31, 1980OK01, 1982ZH1D). Astrophysical questions: (1978WO1E). Complex reactions involving 18Ne: (1979HE1D). Pion-induced capture and reactions (See also reaction 6.): (1977PE12, 1977SP1B, 1978BU09,

  7. A=9C (1984AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    4AJ01) (See the Isobar Diagram for 9C) GENERAL: (See also (1979AJ01) for other references in this category and for some reactions on which no new work has been done.) and Table 9.12 [Table of Energy Levels] (in PDF or PS) here. Model calculations: (1979LA06). Complex reactions involving 9C: (1981MO20). Reactions involing pions: (1979AS01, 1979NA1E, 1980BU15, 1983HU02). Other topics: (1979BE1H, 1979LA06, 1982NG01). Mass of 9C: The recent Q0 value for the 12C(3He, 6He)9C reaction (see reaction 3)

  8. L AMENDMENT OF SOLICITATION/MODIFICATION OF CONTRACT

    National Nuclear Security Administration (NNSA)

    L _ AMENDMENT OF SOLICITATION/MODIFICATION OF CONTRACT 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 25 7 See Block 16C 6 . 1SSUED BY CODE 0500 8 NNSA/ Oa kridge Site Office u.s. De pa rtment of Energ y NNSA/ Y-12 S it e Offic e P. O. Box 2 05 0 Bu ilding 97 0 4- 2 Oak Ridge TN 37831 8 . NAME AND ADDRESS OF CONTRACTOR (No., street, county. state and ZIP Code) ABCOCK & WILCOX TECHNICAL B A t t n: W ILLIE J. W I LSON PO BOX 2009 SERVICES Y- 12 , LLC ,1 . CONTRACT ID CODE I PAGE OF PAGES 1 I

  9. QER- Comment of Mike Gray

    Energy.gov [DOE]

    The biggest issue with wind energy in ND is the Transmission System. There was a proposal recently by Clean Line Energy This type of forward thinking would allow wind energy to go forward.... The other huge issue is the blockade that the fossil fuel industry has placed on Master Limited Partnerships in 1978!! If the Master Limited Partner Parity Act is passed THAT WOULD BE A GAME CHANGER!! ( this is sponsored bu Senator Coons From DE) Call me directly..... You can also aske Heidi Heitkamp about me.... Mike Gray

  10. 18N

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    N β--Decay Evaluated Data Measurements 1964CH19: 18N; measured not abstracted; deduced nuclear properties. 1982OL01: 18N; measured Eγ, Iγ, T1/2; deduced log ft. 18O deduced levels, β-branches. 1989ZH04: 18N(β-); measured absolute β-decay branching ratios; deduced log ft, Gamow-Teller matrix elements. 18O(α) [from 18N β-decay]; measured total β-delayed α-yield. 18O deduced possible new levels. 1993BU21: 18N(β-); measured β-delayed Eα, Iα. 1991RE02, 1993REZX, 1994RE1R: 18N(β-n);

  11. 18Ne

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Ne β+-Decay Evaluated Data Measurements 1954GO17: 18Ne. 1961BU05: 18Ne; measured not abstracted; deduced nuclear properties. 1961EC02: 18Ne; measured not abstracted; deduced nuclear properties. 1963FR10: 18Ne; measured not abstracted; deduced nuclear properties. 1965FR09: 18Ne; measured not abstracted; deduced nuclear properties. 1968GO05: 18Ne; measured Eγ, Iγ; deduced Iβ, log ft. 18F deduced levels, branching ratios. 1970AL11: 18Ne; measured T1/2; deduced log ft, β-branching. 1970AS06,

  12. Carlsbad Field Office P. O. Box 3090 Carlsbad

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    W aste Bu reau New Mexico Environment Department 2905 Rodeo Park Drive East, Buitding 1 San ta Fe. New Mexico 87505-6303 FEB 1 3 20j~ Subject: Notification of Cla ss 1 Permit Modification to the Hazardous Waste Facility Permit, Number: NM4890139088-TSDF De ar Mr. Kieling : Enclosed is the Class 1 Permit Modification Notification listed below: * Change in th e Department of Energy, Carlsbad Field Office Manager We certify under penalty of law that this document and th e enclos ure were prepared

  13. Simultaneous separation of cesium and strontium from spent nuclear fuel using the fission-product extraction process

    SciTech Connect (OSTI)

    Law, J.D.; Peterman, D.R.; Riddle, C.L.; Meikrantz, D.A.; Todd, T.A.

    2008-07-01

    The Fission-Product Extraction (FPEX) Process is being developed as part of the United States Department of Energy Global Nuclear Energy Partnership (GNEP) for the simultaneous separation of cesium and strontium from spent LWR fuel. Separation of the Cs and Sr will reduce the short-term heat load in a geological repository and, when combined with the separation of Am and Cm, could increase the capacity of the geological repository by a factor of approximately 100. The FPEX process is based on two highly-specific extractants: 4,4',(5')-di-(t-butyl-dicyclohexano)- 18-crown-6 (DtBuCH18C6) and calix[4]arene-bis-(t-octyl-benzo-crown-6 ) (BOBCalixC6). The DtBuCH18C6 extractant is selective for strontium, and the BOBCalixC6 extractant is selective for cesium. Results of flowsheet testing of the FPEX process with simulated and actual spent-nuclear-fuel feed solution in centrifugal contactors are detailed. Removal efficiencies, co-extraction of metals, and process hydrodynamic performance ar e discussed along with recommendations for future flowsheet testing with actual spent nuclear fuel. Recent advances in the evaluation of alternative calixarenes with increased solubility and stability are also detailed. (authors)

  14. ADVANCED TECHNOLOGIES FOR THE SIMULTANEOUS SEPARATION OF CESIUM AND STRONTIUM FROM SPENT NUCLEAR FUEL

    SciTech Connect (OSTI)

    Jack D. Law; Terry A. Todd; R. Scott Herbst; David H. Meikrantz; Dean R. Peterman; Catherine L. Riddle; Richard D. Tillotson

    2005-02-01

    Two new solvent extraction technologies have been recently developed to simultaneously separate cesium and strontium from spent nuclear fuel, following dissolution in nitric acid. The first process utilizes a solvent consisting of chlorinated cobalt dicarbollide and polyethylene glycol extractants in a phenyltrifluoromethyl sulfone diluent. Recent improvements to the process include development of a new, non-nitroaromatic diluent and development of new stripping reagents, including a regenerable strip reagent that can be recovered and recycled. This new strip reagent reduces product volume by a factor of 20, over the baseline process. Countercurrent flowsheet tests on simulated spent nuclear fuel feed streams have been performed with both cesium and strontium removal efficiencies of greater than 99 %. The second process developed to simultaneously separate cesium and strontium from spent nuclear fuel is based on two highly-specific extractants: 4',4',(5')-Di-(t-butyldicyclo-hexano)-18-crown-6 (DtBuCH18C6) and Calix[4]arene-bis-(tert-octylbenzo-crown-6) (BOBCalixC6). The DtBuCH18C6 extractant is selective for strontium and the BOBCalixC6 extractant is selective for cesium. A solvent composition has been developed that enables both elements to be removed together and, in fact, a synergistic effect was observed with strontium distributions in the combined solvent that are much higher that in the strontium extraction (SREX) process. Initial laboratory test results of the new combined cesium and strontium extraction process indicate good extraction and stripping performance.

  15. Electron localization in a mixed-valence diniobium benzene complex

    SciTech Connect (OSTI)

    Gianetti, Thomas L.; Nocton, Grégory; Minasian, Stefan G.; Kaltsoyannis, Nikolas; Kilcoyne, A. L. David; Kozimor, Stosh A.; Shuh, David K.; Tyliszczak, Tolek; Bergman, Robert G.; Arnold, John

    2014-11-11

    Reaction of the neutral diniobium benzene complex {[Nb(BDI)NtBu]2(μ-C6H6)} (BDI = N,N'-diisopropylbenzene-β-diketiminate) with Ag[B(C6F5)4] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)NtBu]2(μ-C6H6)}{B(C6F5)4}. Investigation of the solid state and solution phase structure using single-crystal X-ray diffraction, cyclic voltammetry, magnetic susceptibility, and multinuclear NMR spectroscopy indicates that the oxidation results in an asymmetric molecule with two chemically inequivalent Nb atoms. Further characterization using density functional theory (DFT) calculations, UV-visible, Nb L3,2-edge X-ray absorption near-edge structure (XANES), and EPR spectroscopies supports assignment of a diniobium complex, in which one Nb atom carries a single unpaired electron that is not largely delocalized on the second Nb atom. During the oxidative transformation, one electron is removed from the δ-bonding HOMO, which causes a destabilization of the molecule and formation of an asymmetric product. Subsequent reactivity studies indicate that the oxidized product allows access to metal-based chemistry with substrates that did not exhibit reactivity with the starting neutral complex.

  16. Electron localization in a mixed-valence diniobium benzene complex

    DOE PAGES-Beta [OSTI]

    Gianetti, Thomas L.; Nocton, Grégory; Minasian, Stefan G.; Kaltsoyannis, Nikolas; Kilcoyne, A. L. David; Kozimor, Stosh A.; Shuh, David K.; Tyliszczak, Tolek; Bergman, Robert G.; Arnold, John

    2014-11-11

    Reaction of the neutral diniobium benzene complex {[Nb(BDI)NtBu]2(μ-C6H6)} (BDI = N,N'-diisopropylbenzene-β-diketiminate) with Ag[B(C6F5)4] results in a single electron oxidation to produce a cationic diniobium arene complex, {[Nb(BDI)NtBu]2(μ-C6H6)}{B(C6F5)4}. Investigation of the solid state and solution phase structure using single-crystal X-ray diffraction, cyclic voltammetry, magnetic susceptibility, and multinuclear NMR spectroscopy indicates that the oxidation results in an asymmetric molecule with two chemically inequivalent Nb atoms. Further characterization using density functional theory (DFT) calculations, UV-visible, Nb L3,2-edge X-ray absorption near-edge structure (XANES), and EPR spectroscopies supports assignment of a diniobium complex, in which one Nb atom carries a single unpaired electron that ismore » not largely delocalized on the second Nb atom. During the oxidative transformation, one electron is removed from the δ-bonding HOMO, which causes a destabilization of the molecule and formation of an asymmetric product. Subsequent reactivity studies indicate that the oxidized product allows access to metal-based chemistry with substrates that did not exhibit reactivity with the starting neutral complex.« less

  17. Technical Cross-Cutting Issues for the Next Generation Safeguards Initiative's Spent Fuel Nondestructive Assay Project

    SciTech Connect (OSTI)

    Tobin, S. J.; Menlove, H. O.; Swinhoe, Martyn T.; Blanc, P.; Burr, T.; Evans, L. G.; Favalli, A.; Fensin, M. L.; Freeman, C. R.; Galloway, J.; Gerhart, J.; Rajasingam, A.; Rauch, E.; Sandoval, N. P.; Trellue, H.; Ulrich, T. J.; Conlin, J. L.; Croft, S.; Hendricks, John; Henzl, V.; Henzlova, D.; Eigenbrodt, J. M.; Koehler, W. E.; Lee, D. W.; Lee, T. H.; Lafleur, A. M.; Schear, M. A.; Humphrey, M. A.; Smith, Leon E.; Anderson, Kevin K.; Campbell, Luke W.; Casella, Andrew M.; Gesh, Christopher J.; Shaver, Mark W.; Misner, Alex C.; Amber, S. D.; Ludewigt, Bernhard A.; Quiter, B.; Solodov, Alexander; Charlton, W.; Stafford, A.; Romano, C.; Cheatham, J.; Ehinger, Michael; Thompson, S. J.; Chichester, David; Sterbentz, James; Hu, Jianwei; Hunt, A.; Mozin, Vladimir V.; Richard, J. G.

    2012-03-01

    Ever since there has been spent fuel (SF), researchers have made nondestructive assay (NDA) measurements of that fuel to learn about its content. In general these measurements have focused on the simplest signatures (passive photon and total neutron emission) and the analysis has often focused on diversion detection and on determining properties such as burnup (BU) and cooling time (CT). Because of shortcomings in current analysis methods, inspectorates and policy makers are interested in improving the state-of-the-art in SF NDA. For this reason the U.S. Department of Energy, through the Next Generation Safeguards Initiative (NGSI), targeted the determination of elemental Pu mass in SF as a technical goal. As part of this research effort, 14 nondestructive assay techniques were studied . This wide range of techniques was selected to allow flexibility for the various needs of the safeguards inspectorates and to prepare for the likely integration of one or more techniques having complementary features. In the course of researching this broad range of NDA techniques, several cross-cutting issues were. This paper will describe some common issues and insights. In particular we will describe the following: (1) the role of neutron absorbers with emphasis on how these absorbers vary in SF as a function of initial enrichment, BU and CT; (2) the need to partition the measured signal among different isotopic sources; and (3) the importance of the “first generation” concept which indicates the spatial location from which the signal originates as well as the isotopic origins.

  18. Assessment of the Electrohol process to manufacture acetaldehyde from ethanol electrogeneratively. Final report

    SciTech Connect (OSTI)

    Trevino, A.A.

    1985-04-10

    Preliminary process economics data for the electrogenerative process to manufacture acetaldehyde from ethanol were generated based on patent information. The technology was assessed in four alternative processing options. The Electrohol process is viable in the US only if integrated to the production of 190 pf ethanol from corn in a large scale unit. To be competitive, the Electrohol process must show yields in excess of 93%. Its attractiveness depends on corn prices remaining under $2.90/bu and DDG selling for more than $132/T. A corn price of $2.00/bu is needed to make a farm-size corn-based processing alternative competitive. A plant based on the fermentation of molasses proved too expensive under the US economic assumptions. The Electrohol technology based on purchased ethanol cannot compete with the existing ethylene-based process under current conditions. To become attractive, the Electrohol process must have access to cheap ethanol ($1.43/gal). The zero electricity generation mode is the most attractive mode of operation for the Electrohol technology in the US. The penalty for low levels of generation (0.130 kwh/kg AcH) is, however, negligible. The optimum operating mode in W. Europe is the generation of 0.312 kwh/kg AcH. In Japan, the low generation level is perferred (0.130 kwh/kg AcH). In general, higher energy prices improve the competitiveness of the Electrohol processing alternatives.

  19. Simulation of differential die-away instrument’s response to asymmetrically burned spent nuclear fuel

    DOE PAGES-Beta [OSTI]

    Martinik, Tomas; Henzl, Vladimir; Grape, Sophie; Svard, Staffan Jacobsson; Jansson, Peter; Swinhoe, Martyn T.; Tobin, Stephen J.

    2015-03-04

    Here, previous simulation studies of Differential Die–Away (DDA) instrument’s response to active interrogation of spent nuclear fuel from a pressurized water reactor (PWR) yielded promising results in terms of its capability to accurately measure or estimate basic spent fuel assembly (SFA) characteristics, such as multiplication, initial enrichment (IE) and burn-up (BU) as well as the total plutonium content. These studies were however performed only for a subset of idealized SFAs with a symmetric BU with respect to its longitudinal axis. Therefore, to complement the previous results, additional simulations have been performed of the DDA instrument’s response to interrogation of asymmetricallymore » burned spent nuclear fuel in order to determine whether detailed assay of SFAs from all 4 sides will be necessary in real life applications or whether a cost and time saving single sided assay could be used to achieve results of similar quality as previously reported in case of symmetrically burned SFAs.« less

  20. Direct Measurement of Initial Enrichment and Burn-up of Spent Fuel Assembly with a Differential Die-Away Technique Based Instrument

    SciTech Connect (OSTI)

    Henzl, Vladimir; Swinhoe, Martyn T.; Tobin, Stephen J.

    2012-07-16

    A key objective of the Next Generation Safeguards Initiative (NGSI) is to utilize non-destructive assay (NDA) techniques to determine the elemental plutonium (Pu) content in a commercial-grade nuclear spent fuel assembly (SFA). In the third year of the NGSI Spent Fuel NDA project, the research focus is on the integration of a few NDA techniques. One of the reoccurring challenges to the accurate determination of Pu content has been the explicit dependence of the measured signal on the presence of neutron absorbers which build up in the assembly in accordance with its operating and irradiation history. The history of any SFA is often summarized by the parameters of burn-up (BU), initial enrichment (IE) and cooling time (CT). While such parameters can typically be provided by the operator, the ability to directly measure and verify them would significantly enhance the autonomy of the IAEA inspectorate. Within this paper, we demonstrate that an instrument based on a Differential Die-Away technique is in principle capable of direct measurement of IE and, should the CT be known, also the BU.

  1. Mixed N-Heterocyclic Carbene-Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions

    SciTech Connect (OSTI)

    Xu, Songchen; Manna, Kuntal; Ellern, Arkady; Sadow, Aaron D

    2014-12-08

    In order to facilitate oxidative addition chemistry of fac-coordinated rhodium(I) and iridium(I) compounds, carbenebis(oxazolinyl)phenylborate proligands have been synthesized and reacted with organometallic precursors. Two proligands, PhB(OxMe2)2(ImtBuH) (H[1]; OxMe2 = 4,4-dimethyl-2-oxazoline; ImtBuH = 1-tert-butylimidazole) and PhB(OxMe2)2(ImMesH) (H[2]; ImMesH = 1-mesitylimidazole), are deprotonated with potassium benzyl to generate K[1] and K[2], and these potassium compounds serve as reagents for the synthesis of a series of rhodium and iridium complexes. Cyclooctadiene and dicarbonyl compounds {PhB(OxMe2)2ImtBu}Rh(?4-C8H12) (3), {PhB(OxMe2)2ImMes}Rh(?4-C8H12) (4), {PhB(OxMe2)2ImMes}Rh(CO)2 (5), {PhB(OxMe2)2ImMes}Ir(?4-C8H12) (6), and {PhB(OxMe2)2ImMes}Ir(CO)2 (7) are synthesized along with ToMM(?4-C8H12) (M = Rh (8); M = Ir (9); ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The spectroscopic and structural properties and reactivity of this series of compounds show electronic and steric effects of substituents on the imidazole (tert-butyl vs mesityl), effects of replacing an oxazoline in ToM with a carbene donor, and the influence of the donor ligand (CO vs C8H12). The reactions of K[2] and [M(?-Cl)(?2-C8H14)2]2 (M = Rh, Ir) provide {?4-PhB(OxMe2)2ImMes?CH2}Rh(?-H)(?-Cl)Rh(?2-C8H14)2 (10) and {PhB(OxMe2)2ImMes}IrH(?3-C8H13) (11). In the former compound, a spontaneous oxidative addition of a mesityl ortho-methyl to give a mixed-valent dirhodium species is observed, while the iridium compound forms a monometallic allyl hydride. Photochemical reactions of dicarbonyl compounds 5 and 7 result in CH bond oxidative addition providing the compounds {?4-PhB(OxMe2)2ImMes?CH2}RhH(CO) (12) and {PhB(OxMe2)2ImMes}IrH(Ph)CO (13). In 12, oxidative addition results in cyclometalation of the mesityl ortho-methyl similar to 10, whereas the iridium compound reacts with the benzene solvent to give a rare crystallographically characterized cis-[Ir](H)(Ph) complex

  2. AOT & LANSCE The Pulse February 2011

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 VersAtile AutomAteD sAmple chAnger For texture meAsure- ments At lAnsce neutron DiFFrAc- tion sheDs light on crystAl structure oF hyDrogen storAge mAteriAl 4 Workshop spot- lights lujAn center neutron scAttering expertise 5 smArts exAmines irrADiAtion-inDuceD eVolution oF DeFormA- tion mechAnisms lAnsce

  3. NREL Delivers In-Home HVAC Efficiency Testing Solutions (Fact Sheet), Building America: Technical Highlight, Building Technologies Program (BTP)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Delivers In-Home HVAC Efficiency Testing Solutions Researchers at the National Renewable Energy Laboratory (NREL) have recently developed two simple in-home efficiency test methods that can be used by technicians, researchers, or interested homeowners to verify the correct opera- tion and energy efficiency of a home's air conditioning and heating equipment. An efficiency validation method for mini-split heat pumps (MSHPs)-highly efficient refrigerant-based air conditioning and heating systems

  4. NRELs Energy-Saving Technology for Air Conditioning Cuts Peak Power Loads Without Using Harmful Refrigerants (Fact Sheet), NREL (National Renewable Energy Laboratory)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    DEVAP Slashes Peak Power Loads Desiccant-enhanced evaporative (DEVAP) air-condi- tioning will provide superior comfort for commercial buildings in any climate at a small fraction of the elec- tricity costs of conventional air-conditioning equip- ment, releasing far less carbon dioxide and cutting costly peak electrical demand by an estimated 80%. Air conditioning currently consumes about 15% of the electricity generated in the United States and is a major contributor to peak electrical demand on

  5. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels (Fact Sheet), NREL Highlights in Science, NREL (National Renewable Energy Laboratory)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    New study determines the effect of catalyst structure on product yields and coking during vapor phase upgrading of biomass pyrolysis products. Converting biomass, an abun- dant and renewable resource, into liquid transportation fuels has attracted significant atten- tion because of depleting fossil fuel reserves and associated environmental concerns. In the quest for sustainable and eco-friendly fuel alternatives, much research is focusing on improving the properties of bio-oil. Scientists at

  6. Federal Alternative Motor Fuels Programs Fifth Annual Report to Congress - 1996

    Alternative Fuels and Advanced Vehicles Data Center

    Abstract This annual report to Congress presents the current status of the U.S. Department of Energy's alterna- tive fuel vehicle demonstration and performance tracking programs being conducted across the country in accordance with the Energy Policy and Conservation Act (42 U.S.C. 6374, et seq.). These programs, which comprise the most compre- hensive data collection effort ever undertaken on alternative transporta- tion fuels and alternative fuel vehi- cles, are beginning their sixth year. This

  7. Industry and Education Experts Work Together to Establish Alternative Fuel Vehicle (AFV) Technician Training Standards

    Alternative Fuels and Advanced Vehicles Data Center

    s more and more AFVs find their places in the transporta- tion industry, the need for qualified technicians to service these vehicles continues to grow. To help meet this need, transportation indus- try and education experts are working together to develop standards for AFV technician training, standards that will serve as a valuable tool for AFV technician training programs now and in the future. Background Section 411 of the Energy Policy Act of 1992 (EPAct) requires that the U.S. Department

  8. Departm

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Kie ling, Acting Bureau Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 San ta Fe, New Mexico 87 505-6303 MAY 2 4 2012 Subject: Notification of Class 1 Permit Modifica tion to the Hazard ous Waste Facility Permit, Number: NM4890139088-TSDF Dear Mr. Kieling: Enclosed is the fo llowing Class 1 Permit Modification Notification : * Update Emergency Coordinator Add ress and Telephone Numbers We certify under penalty of law that this document and

  9. CATALYTIC PROMOTION OF THE ADSORPTION OF VANADIUM ON AN ANIONIC EXCHANGE RESIN

    DOE Patents [OSTI]

    Bailes, R.H.; Ellis, D.A.

    1958-08-26

    An improvement in the process for the recovery of vanadium from acidic phosphatic solutions is presented. In this process the vanadium is first oxidized to the pentavaleat state, and is then separated by contacting such solutions with an anion exchange resin whereby adsorption of the complexed pentavalent vanadium is effected. The improvement lies in the fact that adsorp tion of the vanadium complex by the anion exchange resin is promoted and improved by providing fiuoride ions in solution to be contacted.

  10. Graduation Day

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Graduation Day Tevatron Impact Symposium Keynote Lisa Randall Graduation * grad*u*a*tion * [graj-oo-ey-shuhn * noun 1. an act of graduating; the state of being graduated. * 2. the ceremony of conferring degrees or diplomas, as at a college or school. * Today we celebrate the impact and legacy of the Tevatron * Both in terms of science and in its influence on technology and creative scientific thinking Legacy * Momentous time in particle physics. - Transition. - Many eyes on LHC. * But really

  11. BT16 Agricultural Residues and Biomass Energy Crops Factsheet

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    agricultural sector. POLYSYS was developed to simulate changes in eco- nomic policy, agricultural management, and natural resource conditions, as well as to estimate how agricultural producers may respond to new agricultural market opportunities, such as new demand for biomass, while considering the impact on other non-energy crops. For this analysis, the data in POLYSYS is anchored in a USDA-published baseline of yield, acreage, and price projec- tions for the agriculture sector, which are

  12. Operations & Maintenance Best Practices Guide: Release 3.0

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    C � Resources � Appendix C Resources for Energy and Facilities Professionals The references and resources provided below are by no means all-inclusive. The listed organiza- tions are not endorsed by the authors of this guide and are provided for your information only. To locate additional resources, the authors of this guide recommend contacting relevant trade groups, databases, and the world-wide web. Organizations American Society for Healthcare Engineering (ASHE) � Website: www.ashe.org

  13. Technical Sessions J. E. Penner Lawrence Livermore National Laboratory

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Penner Lawrence Livermore National Laboratory Livermore, California 94550 The stated goal of the Atmospheric Radiation Measure- ment (ARM) program is to improve the treatment of radia- tion in general circulation models (GCMs). The means for doing so will be to compare model-predicted radiative fluxes with measured fluxes at four to six permanent sites. The measured fluxes will characterize the fluxes expected on the scale of a GCM grid box. Because aerosol optical depths at solar wavelengths

  14. Final Environmental Impact Statement

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    EIS - 0097-F c f ` f= �c J m s= Final Environmental Impact Statement BONNEVILLE POWER ADMINISTRATION TRANSMISSION FACILITIES VEGETATION MANAGEMENT PROGRAM U.S. Department of Energy August 1983 Appendices albLbfp= J MMVTJc= Responsible Official: tfiif^j= ^K= s^rde^k= Assistant Secretary for Environmental Protection. Safety, and Emergency Prepafedness Final Environmental Impact Statement BONNEVILLE POWER ADM IN ISTRA TION TRANSMISSION FACILITIES VEGETATION MANAGEMENT PROGRAM U.S. Department of

  15. Flexible Hybrid Friction Stir Joining Technology

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Flexible Hybrid Friction Stir Joining Technology Improved Efficiency and Flexibility through the Development of Hybrid Friction Stir Joining Technology Welding is one of the most important and widely used fabrica- tion technologies in modern industry. Traditional fusion welding processes (e.g. arc welding and laser welding) require signifcant heat inputs and frequently lead to property deterioration, such as cracking and porosity during solidifcation. Friction Stir Welding (FSW) is a solid-state

  16. Fuel Cell Financing for Tax-Exempt Entities

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Financing for Tax-Exempt Entitities Facilitating deployments by structuring energy service contracts to include the Energy Investment Tax Credit. Introduction The Energy Investment Tax Credit (ITC) 1 can help reduce the cost of installing a fuel cell system. While Department of Treasury regulations prevent tax-exempt entities, e.g., not-for-proft organiza- tions, from directly taking advantage of tax benefts for property that they own, the Internal Revenue Code (IRC) and Treasury regulations

  17. Neutron-induced fission measurements at the time-of-flight facility nELBE

    DOE PAGES-Beta [OSTI]

    Kögler, T.; Beyer, R.; Junghans, A. R.; Massarczyk, R.; Schwengner, R.; Wagner, A.

    2015-05-18

    Neutron-induced fission of ²⁴²Pu is studied at the photoneutron source nELBE. The relative fast neutron fission cross section was determined using actinide fission chambers in a time-of-flight experiment. A good agreement of present nuclear data with evalua- tions has been achieved in the range of 100 keV to 10 MeV.

  18. International Training Course on Physical Protection (ITC-25) Report.

    SciTech Connect (OSTI)

    Overholt, Michelle Jungst

    2015-06-01

    The goal of this evaluation repor t is to provide the informa tion necessary to improve the effectiveness of the ITC provided to the In ternational Atomic Energy Agency Member States. This report examines ITC-25 training content, delivery me thods, scheduling, and logistics. Ultimately, this report evaluates whether the course pr ovides the knowledge and skills necessary to meet the students' needs in the protection of nuclear materials and facilities.

  19. San Francisco Operations Office

    Office of Legacy Management (LM)

    San Francisco Operations Office 1333 Broadway Oakland, California 94612 Dr. Joseph 0. Ward, Chief Radiological Health Section Department of Health Services 744 P Street Sacramento, California, 95814 SUBJECT: Certification Docket of Gilman Hall Dear Dr. Ward: The Department of Energy (DOE) has completed and reviewed the remedial ac- tions of Gilman Hall located at the University of California, Berkeley, California. Based on this review, DOE certifies that the condition of Gilman Hall is

  20. A Potential Role for Immersion Freezing in Arctic Mixed-Phase Stratus

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Potential Role for Immersion Freezing in Arctic Mixed-Phase Stratus Gijs de Boer, Edwin W. Eloranta, Tempei Hashino, and Gregory J. Tripoli The University of Wisconsin - Madison (1) Introduction Ice formation appears to a dominant factor controlling the lifecycle of Arctic mixed-phase clouds. To date, our understanding of ice formation in these long-lasting cloud structures does not explain the formation of observed ice amounts. Particularly puzzling are observa- tions taken from the 2004

  1. old.new.factsheets.indd

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    DARHT Dual-Axis Radiographic Hydrodynamic Test Facility At the Los Alamos National Laboratory (LANL), the Dual-Axis Radiographic Hydrodynamic Test Facility, or DARHT, supports a critical component of LANL's primary mission: to ensure the safety, security, and effectiveness of nuclear weapons in our na- tion's stockpile. Los Alamos scientists built DARHT, the world's most powerful x-ray machine, to analyze mockups of nuclear weapons. The DARHT Facility DARHT consists of two linear induction

  2. Patterns of Convection in the Tropical Western Pacific

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Patterns of Convection in the Tropical Western Pacific J. H. Mather Pacific Northwest National Laboratory Richland, Washington Introduction Convection is ubiquitous throughout the maritime continent region. However, the frequency of convec- tion is not uniform. While much of this region does not experience seasons to the same degree as one finds in mid-latitudes, the annual cycle of the sun's passage does have a large impact on convection throughout the maritime continent and the tropical

  3. QDP-JIT/PTX: A QDP++ Implementation for CUDA-Enabled GPUs

    SciTech Connect (OSTI)

    Winter, Frank T.; Edwards, Robert G.

    2014-11-01

    These proceedings describe briefly the QDP-JIT/PTX framework for lattice field theory calcula- tions on the CUDA architecture. The framework generates compute kernels in the PTX assembler language which can be compiled to efficient GPU machine code by the NVIDIA JIT compiler. A comprehensive memory management was added to the framework so that applications, e.g. Chroma, can run unaltered on GPU clusters and supercomputers.

  4. New Design Methods and Algorithms for Multi-component Distillation Processes

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Methods and Algorithms for Multi-component Distillation Processes Improved Energy Efficiency through the Determination of Optimal Distillation Configuration The ability to apply low-energy distillation confgurations can allow chemical manufacturers to reduce energy consumption of both existing and grassroots plants. However, the determina- tion of an appropriate confguration is limited by an incomplete knowledge of the 'search space' for a proper distillation network. Currently, no systematic

  5. Final Technical Report - Stochastic Analysis of Advection-Diffusion-reaction Systems with Applications to Reactive Transport in Porous Media - DE-FG02-07ER24818

    SciTech Connect (OSTI)

    Karniadakis, George Em

    2014-03-11

    The main objective of this project is to develop new computational tools for uncertainty quantifica- tion (UQ) of systems governed by stochastic partial differential equations (SPDEs) with applications to advection-diffusion-reaction systems. We pursue two complementary approaches: (1) generalized polynomial chaos and its extensions and (2) a new theory on deriving PDF equations for systems subject to color noise. The focus of the current work is on high-dimensional systems involving tens or hundreds of uncertain parameters.

  6. Microsoft Word - Mitoneet.doc

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    October 2007 MitoNEET is a Uniquely Folded Outer Mitochondrial Membrane Protein Stabilized by Diabetes Drugs The rise in obesity in the United States parallels a dramatic increase in obesity-associated diseases, most notably type-2 diabetes. This disease is predicted to reach epidemic propor- tions in the next several decades (Zimmet et al 2001, Urek et al 2007). Thus, understand- ing the biochemical processes underlying type-2 diabetes and identifying new targets for therapeutic intervention

  7. Cross-Cutting Hydrogen Station Infrastructure Review Report

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    HYDROGEN STATION INFRASTRUCTURE REVIEW REPORT June 10th, 2016 U.S. Department of Energy Fuel Cell Technologies Office Annual Merit Review NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any informa- tion,

  8. Chapter 5: Lighting, HVAC, and Plumbing

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Lighting, HVAC, and Plumbing High-Performance Engineering Design Lighting System Design Mechanical System Design Central Plant Systems Plumbing and Water Use Building Control Systems Electrical Power Systems Metering LANL | Chapter 5 High-Performance Engineering Design Lighting, HVAC, and Plumbing By now, the building envelope serves multiple roles. It protects the occupants from changing weather condi- tions and it plays a key part in meeting the occupants' comfort needs. The heating,

  9. American Recovery & Reinvestment Act Newsletter - Issue 16

    Office of Environmental Management (EM)

    The Savannah River Site (SRS) is committed to performing the Cold War-era cleanup safely and with transparency. Oversight and direc- tion provided by stakeholders is key to keeping American taxpayers informed of American Recovery and Reinvestment Act spending and progress as America works toward economic prosperity. SRS's $1.6 billion Recovery Act pack- age invests in the workforce and area businesses to complete important cleanup projects years ahead of origi- nal projections. "We are

  10. VTA, SamTrans Look into Future with Bus Demo

    Alternative Fuels and Advanced Vehicles Data Center

    induction motor for propulsion. Although there are several fuel cell chemistries and configura- tions, PEM is generally recog- nized as the best combination of electrochemistry, operating temperature, and weight for transportation applications. The fuel cell supplies electric current via an inverter to the propulsion motor, which is a proprietary design. This chassis- mounted, three-phase, induction motor is rated at 225 kW (369 horsepower). Hydrogen is stored onboard in eleven 5,000-psi

  11. NREL Assesses National Design Standards for Offshore Wind (Fact Sheet), NREL Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Report summarizes regulations, standards, and guidelines for the design and operation of offshore wind projects in the United States. In 2012, the American Wind Energy Association (AWEA) published its Offshore Compliance Recommended Practices that are based on existing standards (Inter- national Electrotechnical Commission, International Organization for Standardiza- tion, and American Petroleum Institute) and guidelines (American Bureau of Ship- ping and DNV GL). Although the AWEA document

  12. NREL's Cyanobacteria Engineering Shortens Biofuel Production Process, Captures CO2 (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    The flexibility of cyanobacterial metabolism supports direct conversion of carbon dioxide (CO 2 ) to ethylene. Photosynthesis fuels growth in plants and algae, two of the primary components of biomass. Biomass, in turn, can be converted into various fuels and chemicals. NREL researchers have shortened this process by engineering one photosynthetic organism, cyanobacterium, so that it converts CO 2 directly into the target chemical ethylene, bypassing the biomass produc- tion and processing

  13. Summary and Comparison of BT16 with BT11

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    have substantial potential. Algae have a higher fuel yield per unit of biomass than terrestrial feedstocks. At higher farmgate prices, additional algal biomass could be available, but the prices will need to decrease for the full potential to be realized. Approach Biomass availability is dependent on many factors, including market, innova- tion, and time. As with BT2, terrestrial biomass supply increases with increasing price, higher yields, and over time. A major difference between BT2 and BT16

  14. Atmospheric Radiation Measurement Convective and Orographically Induced

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Convective and Orographically Induced Precipitation Study The U.S. Department of Energy's Atmospheric Radiation Measurement (ARM) Climate Research Facility is providing the ARM Mobile Facility (AMF) to support a long-term precipitation study in the Black Forest region of Germany. Requested by researchers from the University of Hohenheim, the AMF will be deployed as one of four heav- ily instrumented supersites established for the Convective and Orographically Induced Precipita- tion Study

  15. Reducing Power Factor Cost

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Low power factor is expensive and inefficient. Many utility companies charge you an additional fee if your power factor is less than 0.95. Low power factor also reduces your electrical system's distribu- tion capacity by increasing current flow and causing voltage drops. This fact sheet describes power factor and explains how you can improve your power factor to reduce electric bills and enhance your electrical system's capacity. REDUCING POWER FACTOR COST To understand power factor, visualize a

  16. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Rock the Watt was a direct applica- tion of the Framework for Organiza- tional Change that included building sustainability champions, integration of a sustainability checklist, and sup- port for employees to come up with their own energy saving actions. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Pacifc Northwest National Laboratory (PNNL), one of the seventeen Department of Energy laboratories, implemented the 3-month Rock the Watt campaign in FY2015 to

  17. SSL EVALUATION: OLED Lighting in the Offices of Aurora Lighting Design, Inc.

    Energy Savers

    EVALUATION: OLED Lighting in the Offices of Aurora Lighting Design, Inc. The first GATEWAY demonstra- tion involving OLEDs is also the first office test site for the use of OLEDs in general lighting. In March 2014, Aurora Lighting Design, Inc., in Grayslake, IL, made the bold decision to install an OLED lighting system during offce renovations. Aurora is a small architectural lighting design offce located in the lower level of a residence. With large windows overlook- ing a lake, the offce uses

  18. Industry | U.S. DOE Office of Science (SC)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    s more and more AFVs find their places in the transporta- tion industry, the need for qualified technicians to service these vehicles continues to grow. To help meet this need, transportation indus- try and education experts are working together to develop standards for AFV technician training, standards that will serve as a valuable tool for AFV technician training programs now and in the future. Background Section 411 of the Energy Policy Act of 1992 (EPAct) requires that the U.S. Department

  19. DOE/EIA-0202(89/2Q)

    Gasoline and Diesel Fuel Update

    2Q) 11989 SHORT-TERM t . t QUARTERLY PROJECTIONS ENERGY INFORMATION ADMINISTRATION This publication is available from the Superintendent of Documents, U.S. Government Printing Office (GPO). Informa tion about purchasing this or other Energy Information Administration (EIA) publications may be obtained from the GPO or the ElA's National Energy Information Center (NEIC). Questions on energy statistics should be directed to the NEIC by mail, telephone or telecommunications device for the deaf

  20. DOE/EIA-0202(89/4Q) SHOKT-TERM

    Gasoline and Diesel Fuel Update

    4Q) SHOKT-TERM t . t QUARTERLY PROJECTIONS This publication is available from the Superintendent of Documents, U.S. Government Printing Office (QPO). Informa tion about purchasing this or other Energy Information Administration (EIA) publications may be obtained from the GPO or the ElA's National Energy Information Center (NEIC). Questions on energy statistics should be directed to the NEIC by mail, telephone or telecommunications device for the deaf (TDD). Addresses, telephone numbers and hours

  1. Gina Pearson Assistant Administrator

    Gasoline and Diesel Fuel Update

    Gina Pearson Assistant Administrator for Communications Duties Gina Pearson is the Assistant Administrator (AA) for Communications, and in this capacity provides leadership and direction to conduct the U.S. Energy Information Administration's comprehensive communications program for diverse external customer groups and agency employees. The AA for Communications is responsible for Agency communications policies and standards, the www.eia.gov website, press and media rela- tions, marketing and

  2. HTS Cable Projects

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Superconductivity Partnerships with Industry ANL Air Liquide DOE Golden LANL AEP ORNL Nexans Niagara Mohawk Super Power American Superconductor NYSERDA BOC Praxair W ? tion systems. This is the most the nation. W superconductivity? HTS Cable Projects www.oe.energy.gov Phone: 202 \ 586-1411 Office of Electricity Delivery and Energy Reliability, OE-1 U.S. Department of Energy - 1000 Independence Avenue, SW - Washington, DC 20585. Plugging America Into the Future of Power "A National Effort to

  3. PON1 status does not influence cholinesterase activity in Egyptian agricultural workers exposed to chlorpyrifos

    SciTech Connect (OSTI)

    Ellison, Corie A.; Crane, Alice L.; Bonner, Matthew R.; Knaak, James B.; Browne, Richard W.; Lein, Pamela J.; Olson, James R.

    2012-12-15

    Animal studies have shown that paraoxonase 1 (PON1) genotype can influence susceptibility to the organophosphorus pesticide chlorpyrifos (CPF). However, Monte Carlo analysis suggests that PON1 genotype may not affect CPF-related toxicity at low exposure conditions in humans. The current study sought to determine the influence of PON1 genotype on the activity of blood cholinesterase as well as the effect of CPF exposure on serum PON1 in workers occupationally exposed to CPF. Saliva, blood and urine were collected from agricultural workers (n = 120) from Egypt's Menoufia Governorate to determine PON1 genotype, blood cholinesterase activity, serum PON1 activity towards chlorpyrifos-oxon (CPOase) and paraoxon (POase), and urinary levels of the CPF metabolite 3,5,6-trichloro-2-pyridinol (TCPy). The PON1 55 (P ≤ 0.05) but not the PON1 192 genotype had a significant effect on CPOase activity. However, both the PON1 55 (P ≤ 0.05) and PON1 192 (P ≤ 0.001) genotypes had a significant effect on POase activity. Workers had significantly inhibited AChE and BuChE after CPF application; however, neither CPOase activity nor POase activity was associated with ChE depression when adjusted for CPF exposure (as determined by urinary TCPy levels) and stratified by PON1 genotype. CPOase and POase activity were also generally unaffected by CPF exposure although there were alterations in activity within specific genotype groups. Together, these results suggest that workers retained the capacity to detoxify chlorpyrifos-oxon under the exposure conditions experienced by this study population regardless of PON1 genotype and activity and that effects of CPF exposure on PON1 activity are minimal. -- Highlights: ► CPF exposure resulted in an increase in TCPy and decreases in BuChE and AChE. ► CPOase activity decreased in subjects with the PON1 55LM and PON1 55 MM genotypes. ► Neither PON1 genotype nor CPOase activity had an effect on BuChE or AChE inhibition.

  4. Derivatives of Dictyostelium differentiation-inducing factors inhibit lysophosphatidic acid–stimulated migration of murine osteosarcoma LM8 cells

    SciTech Connect (OSTI)

    Kubohara, Yuzuru; Komachi, Mayumi; Homma, Yoshimi; Kikuchi, Haruhisa; Oshima, Yoshiteru

    2015-08-07

    Osteosarcoma is a common metastatic bone cancer that predominantly develops in children and adolescents. Metastatic osteosarcoma remains associated with a poor prognosis; therefore, more effective anti-metastatic drugs are needed. Differentiation-inducing factor-1 (DIF-1), −2, and −3 are novel lead anti-tumor agents that were originally isolated from the cellular slime mold Dictyostelium discoideum. Here we investigated the effects of a panel of DIF derivatives on lysophosphatidic acid (LPA)-induced migration of mouse osteosarcoma LM8 cells by using a Boyden chamber assay. Some DIF derivatives such as Br-DIF-1, DIF-3(+2), and Bu-DIF-3 (5–20 μM) dose-dependently suppressed LPA-induced cell migration with associated IC{sub 50} values of 5.5, 4.6, and 4.2 μM, respectively. On the other hand, the IC{sub 50} values of Br-DIF-1, DIF-3(+2), and Bu-DIF-3 versus cell proliferation were 18.5, 7.2, and 2.0 μM, respectively, in LM8 cells, and >20, 14.8, and 4.3 μM, respectively, in mouse 3T3-L1 fibroblasts (non-transformed). Together, our results demonstrate that Br-DIF-1 in particular may be a valuable tool for the analysis of cancer cell migration, and that DIF derivatives such as DIF-3(+2) and Bu-DIF-3 are promising lead anti-tumor agents for the development of therapies that suppress osteosarcoma cell proliferation, migration, and metastasis. - Highlights: • LPA induces cell migration (invasion) in murine osteosarcoma LM8 cells. • DIFs are novel lead anti-tumor agents found in Dictyostelium discoideum. • We examined the effects of DIF derivatives on LPA-induced LM8 cell migration in vitro. • Some of the DIF derivatives inhibited LPA-induced LM8 cell migration.

  5. A Singular Differential Equation Stemming from an Optimal Control Problem in Financial Economics

    SciTech Connect (OSTI)

    Brunovsky, Pavol; Cerny, Ales; Winkler, Michael

    2013-10-15

    We consider the ordinary differential equation x{sup 2} u'' = axu'+bu-c(u'-1){sup 2}, x Element-Of (0,x{sub 0}), with a Element-Of R, b Element-Of R , c>0 and the singular initial condition u(0)=0, which in financial economics describes optimal disposal of an asset in a market with liquidity effects. It is shown in the paper that if a+b<0 then no continuous solutions exist, whereas if a+b>0 then there are infinitely many continuous solutions with indistinguishable asymptotics near 0. Moreover, it is proved that in the latter case there is precisely one solution u corresponding to the choice x{sub 0}={infinity} which is such that 0{<=}u(x){<=}x for all x>0, and that this solution is strictly increasing and concave.

  6. INL DPAH STAAR 2015 Annual Report

    SciTech Connect (OSTI)

    Peterman, Dean Richard

    2015-09-15

    Research conducted at the INL has demonstrated the synergistic extraction of americium using solvents comprised of bis(o,o-(trifluoromethyl)phenyl) dithiophosphinic acid (DPAH “1”) and trioctylphosphine oxide (TOPO), butyl bis(2,4,4-trimethylpentyl) phosphinate (BuCy272), or dibutyl butylphosphonate (DBBP). One potential drawback of this separations scheme is that soft metals such as silver, cadmium, or palladium and fission products such as zirconium are well extracted by these solvents. Several potential scrubbing reagents were examined. Of the scrubbing reagents studied, cysteine and methione exhibited some ability to scrub soft metals from the loaded solvent. More conventional scrub reagents such as ammonium fluoride or oxalic acid were not effective. Reagents like Bimet and CDTA were not soluble at the acidities used in these studies. Unfortunately, these results indicate that the identification of effective scrubbing reagents for use in a flowsheet based upon the INL DPAH is going to be very difficult.

  7. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  8. I

    Office of Legacy Management (LM)

    ?am-3 . ,' .*. . - yp: -.* : .- ., ._ ' Yi * <. ? :+". thfa prcbputir. 80,UUU lb. of tmmiuu, J.m,cDu lb. of 3wukdlw crper' tiwu 5.8 t&i8 l atr:irur ral u&d i.Wttd&?# Bir;n8 i;orammant end rUl rid nrtrlcial by uo&utboFlwd putqlm. ). The ~&&a, ' 8m ;altielJ 79 p-rmlt arrgora ted and ttw tap t.ha aikalini~, . L pokotlal brlf)r, bU88M 8-i .ii.i co# sat8 awtaet wltb the mBtmtl8a. aada q*iast fb a8v0-*..u @ow +.ta p-?Y h&al. . .; . ' 6 G.. ..*... . ,,z.. ,. ..*,::

  9. Final Technical Report

    SciTech Connect (OSTI)

    D. Paul Mehta

    2006-09-01

    The Industrial Assessment Center at Bradley University (BU IAC) has been successful in promoting the wise use of energy resources, reduction of environmental waste and increased productivity in the industrial sector. Over 1100 assessment recommendations have been made to 94 industrial clients from September 1, 2002 to August 31, 2006. The projected savings from these recommendations exceeded $15.5 million of which just under $10 million or 62% were implemented. In addition to this over 50 students have been trained to idientify opportunities to reduce costs in induatrial facilities. Many of these students have gone on to careers where they influence the costs of manufacturing thus multiplying the efforts of the center. The details of how this was accomplished is contained in the report which follows.

  10. A=10B (66LA04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 10B) GENERAL: See (BA59F, BR59M, TA60L, TR61, IN62, BU63D, KU63B, ME63A, MO63C, OL63B, VL63A, WA63C, AM64, BA64V, FR64D, GR64C, MA64HH, NE64C, OL64A, ST64, VA64F, FA65C, NE65). See also Table 10.6 [Table of Energy Levels] (in PDF or PS). Ground State: μ = +1.8007 nm (FU65E). Q = +0.08 b (FU65E). 1. 6Li(α, γ)10B Qm = 4.461 Six resonances are observed in the range Eα = 0.5 to 2.6 MeV, corresponding to 10B*(4.76 - 6.06 MeV): see Table 10.8 (in PDF or PS).

  11. A=10C (1979AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    9AJ01) (See Energy Level Diagrams for 10C) GENERAL: See also (1974AJ01) and Table 10.22 [Table of Energy Levels] (in PDF or PS). Model calculations: (1974IR04, 1976IR1B). Special reactions (See also reaction 2 in (1974AJ01).): (1973BA81, 1974RI1A, 1975BA1Q, 1976BE1K, 1976BU16, 1977AR06). Pion reactions (See also reactions 3 and 9 here.): (1975GI1B, 1975RE01, 1977HO1B, 1977WA02, 1978AM01). Astrophysical questions: (1972PA1C, 1976VI1A, 1977SI1D). Other topics: (1974IR04, 1976IR1B, 1976VO1C).

  12. A=11Be (1985AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    85AJ01) (See Energy Level Diagrams for 11Be) GENERAL: See also (1980AJ01) and Table 11.3 [Table of Energy Levels] (in PDF or PS). Model calculations:(1981RA06, 1981SE06, 1983MI1E, 1984VA06). Electromagnetic transitions:(1980MI1G). Complex reactions involving 11Be:(1979BO22, 1980WI1L, 1983EN04, 1983WI1A, 1984GR08, 1984HI1A). Hypernuclei:(1979BU1C, 1982IK1A, 1982KA1D, 1982KO11, 1983FE07, 1983KO1D, 1983MI1E). Other topics:(1981SE06, 1982NG01). Ground-state properties of 11Be:(1981AV02, 1982NG01,

  13. A=12N (1980AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    0AJ01) (See Energy Level Diagrams for 12N) GENERAL: See also (1975AJ02) and Table 12.21 [Table of Energy Levels] (in PDF or PS). Model calculations: (1976IR1B). Pion reactions (See also reaction 2.): (1975NA16, 1976NA16, 1978BU1J, 1978EP01, 1978NA1N, 1979BO1W, 1979BO2C, 1979DI1A, 1979EP1B, 1979NA1Q, 1979WI1A). Other topics: (1975HU14, 1976AB04, 1976BE1K, 1976IR1B, 1977SI1D, 1978SE1B, 1979WI1A). Ground state of 12N: (1974SHYR, 1975BE31, 1977YO1D, 1978LEZA). μ = +(0.4571 ± 0.005) nm (1968SU05).

  14. A=13B (1981AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1AJ01) (See Energy Level Diagrams for 13B) GENERAL: See also (1976AJ04) and Table 13.1 [Table of Energy Levels] (in PDF or PS). Experimental work on complex reactions in which 13B is observed: (1976BU16, 1977AR06, 1978GE1C, 1978KO01, 1979LE1J). Reviews and theoretical papers: (1976AB04, 1976VA29, 1977DO06, 1978AB08, 1978DE15, 1979AL22, 1979BE1H, 1979BO22, 1980MA1F, 1980MU1B). Q = 0.0478 ± 0.0046 b (1973HAVZ, 1978LEZA). μ = +3.17778 ± 0.00051 nm (1978LEZA). 1. 13B(β-)13C Qm = 13.437 The

  15. A=13N (1991AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    91AJ01) (See Energy Level Diagrams for 13N) GENERAL: See also (1986AJ01) and Table Prev. Table 13.14 preview 13.14 [Table of Energy Levels] (in PDF or PS) here. Nuclear models:(1989AM02). Special states:(1984KO40, 1985RO1J, 1986AN07, 1988RO1R, 1989RO03). Electromagnetic transitions:(1984VA06, 1987HO1L). Astrophysical questions:(1985TA1A, 1987RA1D, 1989ST14). Applied work:(1986HI1B, 1986MA2F, 1986MA1T, 1986WE1E, 1987BU12, 1987LE1H, 1988HI1F, 1988VO1D, 1989AR1J, 1989AR1N, 1989AR1Q, 1989TR1B,

  16. A=14O (1976AJ04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    76AJ04) (See Energy Level Diagrams for 14O) GENERAL: See also (1970AJ04) and Table 14.29 [Table of Energy Levels] (in PDF or PS). Nuclear models: (1973SA30, 1974KU1F). Special reactions involving 14O: (1971AR02, 1973BA81, 1975BA1Q, 1975HU14). Reactions involving pions: (1973CH20, 1973DA37, 1975HU1D, 1975RE01). Other topics: (1970FO1B, 1972AN05, 1972CA37, 1972KU1C, 1973GO1H, 1973KA1H, 1973PA1F, 1973RO1R, 1973SP1A, 1974BO22, 1974KU1F, 1974SE1B, 1974VA24, 1975BU1M). Ground state: (1975BE31). 1.

  17. A=15C (1976AJ04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    6AJ04) (See Energy Level Diagrams for 15C) GENERAL: See also (1970AJ04) and Table 15.1 [Table of Energy Levels] (in PDF or PS) here. Model calculations: (1973PH03, 1973RE17). Special levels: (1973PH03, 1974VA24). Muon and neutrino capture and reactions: (1973BE16, 1973BU20). Pion capture and reactions: (1970JA11). Special reactions: (1971AR02, 1973KO1D, 1973WI15, 1974KO25, 1975UD01). Other topics: (1970SU1B, 1973PH03, 1973RE17, 1974VA24, 1975BE31). 1. 15C(β-)15N Qm = 9.772 The half-life is

  18. A=15N (1970AJ04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    0AJ04) (See Energy Level Diagrams for 15N) GENERAL: See Table 15.4 [Table of Energy Levels] (in PDF or PS) here. Model calculations: (1957HA1E, 1959BR1E, 1959FE1B, 1960TA1C, 1961BA1E, 1963BU1C, 1963KU1B, 1964MA1G, 1965CO25, 1965FA1B, 1965GR1H, 1965GU1A, 1965ZA1B, 1966EL08, 1966SO05, 1967CO32, 1967EL03, 1967PA05, 1968EL1A, 1968HO1H, 1968MA2B, 1968SH08, 1968WA04, 1968ZH05, 1969CH1R, 1969EL1B). General calculations and reviews: (1964EV1A, 1965BE1B, 1966OL1C, 1966WI1E, 1967FA1A, 1967LO03, 1968BI1C,

  19. A=16Ne (1986AJ04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    6AJ04) (See the Isobar Diagram for 16Ne) GENERAL: See also (1982AJ01) and Table 16.26 [Table of Energy Levels] (in PDF or PS) here. See (1981SE1B, 1983ANZQ, 1985AN28, 1985MA1X). Mass of 16Ne: The Q-values of the 20Ne(α, 8He) and 16O(π+, π-) reactions lead to atomic mass excesses of 23.93 ± 0.08 MeV (1978KE06), 23.978 ± 0.024 MeV (1983WO01) and 24.048 ± 0.045 MeV (1980BU15) [recalculated using the (1985WA02) masses for 8He, 16O and 20Ne]. The weighted mean is 23.989 ± 0.020 MeV which is

  20. A=16Ne (1993TI07)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    93TI07) (See the Isobar Diagram for 16Ne) GENERAL: See Table Prev. Table 16.29 preview 16.29 [General Table] (in PDF or PS) and Table Prev. Table 16.32 preview 16.32 [Table of Energy Levels] (in PDF or PS). Mass of 16Ne: The Q-values of the 20Ne(α, 8He) and 16O(π+, π-) reactions lead to atomic mass excesses of 23.93 ± 0.08 MeV (1978KE06), 23.978 ± 0.024 MeV (1983WO01) and 24.048 ± 0.045 MeV (1980BU15) [recalculated using the (1985WA02) masses for 8He, 16O and 20Ne]. The weighted mean is

  1. A=17C (1977AJ02)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    7AJ02) (Not illustrated) 17C has been observed in the 5.5 GeV proton bombardment of uranium: it is particle stable (1968PO04). Its atomic mass excess is calculated to be 21.27 MeV (transverse form of the mass equation): it is then stable with respect to decay into 16C + n by 0.50 MeV (1974TH01, 1975JE02). The Eβ-(maQ) for the decay to 17N would then be 13.4 MeV. See also (1971AJ02), (1971AR02, 1971BU1E), (1973TO16) and (1972TH13, 1973WI15, 1975BE31, 1975WI1E; theor.

  2. A=19F (1978AJ03)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    8AJ03) (See Energy Level Diagrams for 19F) GENERAL: See (1972AJ02) and Table 19.6 [Table of Energy Levels] (in PDF or PS). Shell model: (1970FL1A, 1972EN03, 1972GU05, 1972LE13, 1972NE1B, 1973DE13, 1973JU1A, 1973LA1D, 1973MA1K, 1973MC06, 1973MC1E, 1973ME1D, 1973SM1C, 1974CO39, 1975BA81, 1975GA1L, 1975MA1U, 1975SUZR, 1977HA33, 1977SH11). Cluster, collective and rotational models: (1972NE1B, 1973DE06, 1973MC1E, 1973NE1C, 1973RO19, 1976LE19, 1977BU05, 1977HO1F). Electromagnetic transitions:

  3. A=7He (1984AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    4AJ01) (See the Isobar Diagram for 7He) GENERAL: See also (1979AJ01) and Table 7.1 [Table of Energy Levels] (in PDF or PS). Reactions involving pions: (1978FU09, 1979BA1M, 1979PE1C). Hypernuclei: (1978DA1A, 1978SO1A, 1979BU1C, 1981WA1J, 1982KO11). Other topics: (1979BE1H, 1981AV02, 1982AW02, 1982NG01). 1. 7Li(π-, γ)7He Qm = 128.36 See (1979AJ01). 2. 7Li(n, p)7He Qm = -10.42 At En = 14.8 MeV a proton group is reported corresponding to 7Heg.s.: Γ < 0.2 MeV: see (1979AJ01). See also

  4. A=9Li (1979AJ01)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    9AJ01) (See Energy Level Diagrams for 9Li) GENERAL: See also (1974AJ01) and Table 9.1 [Table of Energy Levels] (in PDF or PS). Model calculations: (1974IR04, 1976IR1B, 1977JA14). Special reactions: (1975AB1D, 1975ZE01, 1976AL1F, 1976BE67, 1976BU16, 1977YA1B). Pion and kaon reactions (See also reaction 3.): (1973CA1C, 1976TR1A, 1977BA1Q, 1977DO06, 1977SH1C). Other topics: (1970KA1A, 1973TO16, 1974IR04, 1975BE56, 1976IR1B). Ground state properties: (1975BE31). μ = 3.4359 ± 0.0010 nm (1976CO1L;

  5. An Assessment of Technologies to Provide Extended Sludge Retrieval from Underground Storage Tanks at the Hanford Site

    SciTech Connect (OSTI)

    JA Bamberger

    2000-08-02

    The purpose of this study was to identify sludge mobilization technologies that can be readily installed in double-shell tanks along with mixer pumps to augment mixer pump operation when mixer pumps do not adequately mobilize waste. The supplementary technologies will mobilize sludge that may accumulate in tank locations out-of-reach of the mixer-pump jet and move the sludge into the mixer-pump range of operation. The identified technologies will be evaluated to determine if their performances and configurations are adequate to meet requirements developed for enhanced sludge removal systems. The study proceeded in three parallel paths to identify technologies that: (1) have been previously deployed or demonstrated in radioactive waste tanks, (2) have been specifically evaluated for their ability to mobilize or dislodge waste simulants with physical and theological properties similar to those anticipated during waste retrieval, and (3) have been used in similar industrial conditions, bu t not specifically evaluated for radioactive waste retrieval.

  6. 7Li Cross Section

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    p, X) (Current as of 12/16/2015) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 1997GO13 7Li(pol. p, γ): total σ, S-factor for capture to third-excited state 0 - 80 keV X4 06/12/2014 1994CH23 7Li(pol. p, γ): deduced S-factor ≤ 80 keV X4 06/12/2014 1999SP09 7Li(p, α): deduced S-factor < 0.4 X4 06/12/2014 1974BU16 7Li(p, n): σ < 3.8 X4 03/14/2012 2011PI04 7Li(p, α): analyzed excitation functions Ecm = 0 - 7 X4 06/12/2014 2001LA35 7Li(p, α): deduced S(E)-factor 10 -

  7. Atmospheric Pressure Chemical Vapor Deposition of High Silica SiO2-TiO2 Antireflective Thin Films for Glass Based Solar Panels

    SciTech Connect (OSTI)

    Klobukowski, Erik R; Tenhaeff, Wyatt E; McCamy, James; Harris, Caroline; Narula, Chaitanya Kumar

    2013-01-01

    The atmospheric pressure chemical vapor deposition (APCVD) of SiO2-TiO2 thin films employing [[(tBuO)3Si]2O-Ti(OiPr)2], which can be prepared from commercially available materials, results in antireflective thin films on float glass under industrially relevant manufacturing conditions. It was found that while the deposition temperature had an effect on the SiO2:TiO2 ratio, the thickness was dependent on the time of deposition. This study shows that it is possible to use APCVD employing a single source precursor containing titanium and silicon to produce thin films on float glass with high SiO2:TiO2 ratios.

  8. Data Mining Techniques to Estimate Plutonium, Initial Enrichment, Burnup, and Cooling Time in Spent Fuel Assemblies

    SciTech Connect (OSTI)

    Trellue, Holly Renee; Fugate, Michael Lynn; Tobin, Stephen Joesph

    2015-03-19

    The Next Generation Safeguards Initiative (NGSI), Office of Nonproliferation and Arms Control (NPAC), National Nuclear Security Administration (NNSA) of the U.S. Department of Energy (DOE) has sponsored a multi-laboratory, university, international partner collaboration to (1) detect replaced or missing pins from spent fuel assemblies (SFA) to confirm item integrity and deter diversion, (2) determine plutonium mass and related plutonium and uranium fissile mass parameters in SFAs, and (3) verify initial enrichment (IE), burnup (BU), and cooling time (CT) of facility declaration for SFAs. A wide variety of nondestructive assay (NDA) techniques were researched to achieve these goals [Veal, 2010 and Humphrey, 2012]. In addition, the project includes two related activities with facility-specific benefits: (1) determination of heat content and (2) determination of reactivity (multiplication). In this research, a subset of 11 integrated NDA techniques was researched using data mining solutions at Los Alamos National Laboratory (LANL) for their ability to achieve the above goals.

  9. Synthesis of peptide .alpha.-thioesters

    DOE Patents [OSTI]

    Camarero, Julio A.; Mitchell, Alexander R.; De Yoreo, James J.

    2008-08-19

    Disclosed herein is a new method for the solid phase peptide synthesis (SPPS) of C-terminal peptide .alpha. thioesters using Fmoc/t-Bu chemistry. This method is based on the use of an aryl hydrazine linker, which is totally stable to conditions required for Fmoc-SPPS. When the peptide synthesis has been completed, activation of the linker is achieved by mild oxidation. The oxidation step converts the acyl-hydrazine group into a highly reactive acyl-diazene intermediate which reacts with an .alpha.-amino acid alkylthioester (H-AA-SR) to yield the corresponding peptide .alpha.-thioester in good yield. A variety of peptide thioesters, cyclic peptides and a fully functional Src homology 3 (SH3) protein domain have been successfully prepared.

  10. Nucleophilic fluorination of aromatic compounds

    DOE Patents [OSTI]

    Satyamurthy, Nagichettiar; Barrio, Jorge R

    2014-03-18

    Iodylbenzene derivatives substituted with electron donating as well as electron withdrawing groups on the aromatic ring are used as precursors in aromatic nucleophilic substitution reactions. The iodyl group (IO.sub.2) is regiospecifically substituted by nucleophilic fluoride to provide the corresponding fluoroaryl derivatives. No-carrier-added [F-18]fluoride ion derived from anhydrous [F-18](F/Kryptofix, [F-18]CsF or a quaternary ammonium fluoride (e.g., Me.sub.4NF, Et.sub.4NF, n-Bu.sub.4NF, (PhCH.sub.2).sub.4NF) exclusively substitutes the iodyl moiety in these derivatives and provides high specific activity F-18 labeled fluoroaryl analogs. Iodyl derivatives of a benzothiazole analog and 6-iodyl-L-dopa derivatives have been synthesized as precursors and have been used in the preparation of no-carrier-added [F-18]fluorobenzothiazole as well as 6-[F-18]fluoro-L-dopa.

  11. 2011 Chevrolet Volt VIN 0815 Plug-In Hybrid Electric Vehicle Battery Test Results

    SciTech Connect (OSTI)

    Tyler Gray; Matthew Shirk; Jeffrey Wishart

    2013-07-01

    The U.S. Department of Energy (DOE) Advanced Vehicle Testing Activity (AVTA) program consists of vehicle, battery, and infrastructure testing on advanced technology related to transportation. The activity includes tests on plug-in hybrid electric vehicles (PHEVs), including testing the PHEV batteries when both the vehicles and batteries are new and at the conclusion of 12,000 miles of on-road fleet testing. This report documents battery testing performed for the 2011 Chevrolet Volt PHEV (VIN 1G1RD6E48BU100815). The battery testing was performed by the Electric Transportation Engineering Corporation (eTec) dba ECOtality North America. The Idaho National Laboratory and ECOtality North America collaborate on the AVTA for the Vehicle Technologies Program of the DOE.

  12. Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap

    SciTech Connect (OSTI)

    Adam C. Powell, IV

    2012-07-19

    Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

  13. CRC handbook of neurohypophyseal hormone analogs. Volume I

    SciTech Connect (OSTI)

    Jost, K.; Lebl, M.; Brtnik, F.

    1987-01-01

    This book is discussed in two parts. Part one discusses Introductory Remarks. Nomenclature. Natural Forms of Neurohypophyseal Hormones. Synthesis, Purification, and Stability of the Neurohypophyseal Hormone Analogs. Isotopically Modified Analogs. Studies of Analogs Using Physiocochemical and Theoretical Methods. Conformational properties of Neurohypophyseal Hormone Analogs in Solution as Determined bu NMR and Laser Raman Spectroscopies. Other Methods used in the Investigation of Neurohypophyseal Hormone Analog Conformations. Conformation Properties of Analogs in Solution as Revealed by Circular Dichroism Spectroscopy. Conformational Energy Calculations. Quantitative Structure Activity Relationships. References. Part 2 discusses The Use of Neurohypophyseal Hormone Analogs in the Study of Neurophysin-Hormone Interactions. Enzymatic Inactivation. Immunochemistry. Studies of Neurohypopophyseal Hormone Activities at the Cellular Level. Fundamental Biological Evaluation. Important Structural Modifications. Noncoded Amino Acids. Modification of ..cap alpha..-Amino Group; 1-Deamino and 1-Hydroxy Analogs. Modifications in the Issulfide Bridge (Carba-Analogs). Modification of Other Functional Groups. Changes in the Backbone. References. Index.

  14. 12C Cross Section

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    p, X) (Current as of 05/15/2012) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2001NE15 12C(p, γ): σ, deduced S(E) ratio < 160 keV X4 10/28/2014 1993CH02 12C(p, X): σ for η production ≤ 0.9 GeV X4 03/07/2012 1974RO29 12C(p, γ): σ 150 - 3000 keV X4 08/27/2013 1951GO1B 12C(p, p): yield curve of elastic scattering 0.2 - 4.0 θ = 164° 11/05/2014 1976ME22 12C(p, p): absolute σ 0.3 - 2.0 X4 08/07/2013 2008BU19 12C(p, γ): σ, deduced S-factors. 354, 390, 460, 463, 565,

  15. 12O

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    O Ground-State Decay Evaluated Data Measured Ground-State Γcm for 12O Adopted value: 0.40 ± 0.25 MeV (1990AJ01) Measured Mass Excess for 12O Adopted value: 32048 ± 18 keV (2003AU02) Measurements 1978KE06: 16O(α, 8He), E = 117 MeV; measured σ(θ); deduced Q. 12O deduced mass excess, Γcm, diproton decay. 1980BU15: 12C(π+, π-), E = 180 MeV; measured σ(θ), Q. 12O deduced masses. 1980MOZX: 12C(π+, π-), E = 180 MeV; measured mass spectra, θ = 5°. 12O deduced masses. 1986FAZY: 12C(π+,

  16. 16C

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    C β--Decay Evaluated Data Measurements 1961HI01: 16C; measured not abstracted; deduced nuclear properties. 1976AL02: 16C; measured Eγ, Iγ, γ(t), T1/2, delayed neutrons log ft. 16N deduced levels. 1976FI03: 16C; measured T1/2, delayed γ, delayed neutrons. 1983GA03: 16C(β-), (β-n); measured β(t), γ(t), βγ-coin; deduced log ft. 16N levels deduced β-branching ratio. 2000BU33, 2001GR06: 16C(β-n); measured β-delayed neutron spectra. 16N deduced level, J, π. Comparison with shell model

  17. 16Ne

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Ne Ground-State Decay Evaluated Data Measured Ground-State Γcm for 16Ne Adopted value: 122 ± 37 keV (1993TI07) Measured Mass Excess for 16Ne Adopted value: 23996 ± 20 keV (2003AU02) Measurements 1971MAXQ: 16O(π+, π-); measured particle spectra, σ. 1977HO13: 16O(π+, π-), E = 145 MeV; measured σ; deduced Q. 16Ne deduced mass excess. 1977KEZX: 20Ne(α, 8He), E = 118 MeV; measured σ. 16Ne deduced levels, mass excess. 1978BU09: 16O(π+, π-), E = 145 MeV; measured σ. 16Ne deduced mass

  18. Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-Out and Tailpipe Particulate Matter Emissions: Preprint

    SciTech Connect (OSTI)

    He, X.; Ireland, J. C.; Zigler, B. T.; Ratcliff, M. A.; Knoll, K. E.; Alleman, T. L.; Tester, J. T.

    2011-02-01

    The influences of ethanol and iso-butanol blended with gasoline on engine-out and post Three-Way Catalyst (TWC) particle size distribution and number concentration were studied using a GM 2.0L turbocharged Spark Ignition Direct Injection (SIDI) engine. The engine was operated using the production ECU with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. US federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at ten selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm. Idle and low speed / low load conditions emitted higher total particle numbers than other operating conditions. At idle, the engine-out Particulate Matter (PM) emissions were dominated by nucleation mode particles, and the production TWC reduced these nucleation mode particles by more than 50%, while leaving the accumulation mode particle distribution unchanged. At engine load higher than 6 bar NMEP, accumulation mode particles dominated the engine-out particle emissions and the TWC had little effect. Compared to the baseline gasoline (E0), E10 does not significantly change PM emissions, while E20 and BU12 both reduce PM emissions under the conditions studied. Iso-butanol was observed to impact PM emissions more than ethanol, with up to 50% reductions at some conditions. In this paper, the issues related to PM measurement using FMPS are also discussed. While some uncertainties are due to engine variation, the FMPS must be operated under careful maintenance procedures in order to achieve repeatable measurement results.

  19. Development and Pilot Manufacture of Pseudo-Electric Double Layer Capacitors

    SciTech Connect (OSTI)

    Dae Young Jung,

    2011-01-26

    Binghamton University carried out basic studies on thermal characteristics of the current ELDC design and characterization of current active and conductive carbon materials used to fabricate ELDC and p-ELDC. Multi physics approach was take for thermal modeling to understand the temperature distribution of an individual cell as well as multi-cell systems, which is an important factor to the reliability of ELDC?s and p-ELDC?s. Structure and properties were characterized for various raw active carbon materials which can be used as electrode to look into potential cost reduction opportunity without degrading the performance. BU team also performed experiments for compositional optimization studies for active carbon, conductive carbon, and binder formulation. A few laboratory instruments were installed for this project at BU. These instruments will continued to be used to carry out further research and development tasks relevant to ELDC and p-ELDC. Project subawardee, Ioxus, Inc., successfully created, enhanced, and then generated a product line of hybrid capacitors which now range in size from 220 Farads (F) to 1000F. These products have been proven to work as the primary energy storage method for LED lighting applications, and two significant commercial applications are evaluating these devices for use. Both of these applications will be used in LED lighting, which replaces traditional batteries and allows for a very fast charge and a high cycle life, over a wide temperature range. This will lead to a significant reduction of waste that ends up in landfills. These products are 70% recyclable, with a 10 year life. In one both applications, it is expected that the hybrid capacitor will power the LED lights for the life of the product, which would have required at least 10 battery changes.

  20. Tetrahalide Complexes of the [U(NR)(2)]2+ Ion: Synthesis, Theory, and Chlorine K-Edge X-ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Spencer, Liam P.; Yang, Ping; Minasian, Stefan G.; Jilek, Robert E.; Batista, Enrique R.; Boland, Kevin S.; Boncella, James M.; Conradson, S. D.; Clark, David L.; Hayton, Trevor W.; Kozimor, Stosh A.; Martin, Richard L.; MacInnes, Molly M.; Olson, Angela C.; Scott, Brian L.; Shuh, D. K.; Wilkerson, Marianne P.

    2013-02-13

    Synthetic routes to salts containing uranium bisimido tetrahalide anions [U(NR)(2)X-4](2-) (X = Cl-, Br-) and non-coordinating NEt4+ and PPh4+ countercations are reported. In general, these compounds can be prepared from U(NR)(2)I-2(THF)(x) (x = 2 and R = 'Bu, Ph; x = 3 and R = Me) upon addition of excess halide. In addition to providing stable coordination complexes with Cl-, the [U(NMe)(2)](2 +) cation also reacts with Br- to form stable [NEt4](2)[U(NMe)(2)Br-4] complexes. These materials were used as a platform to compare electronic structure and bonding in [U(NR)(2)](2+) with [UO2](2+). Specifically, Cl K-edge X-ray absorption spectroscopy (XAS) and both ground-state and time-dependent hybrid density functional theory (DFT and TDDFT) were used to probe U-Cl bonding interactions in [PPh4](2)[U((NBu)-Bu-t)(2)Cl-4] and [PPh4](2)[UO2Cl4]. The DFT and XAS results show the total amount of Cl 3p character mixed with the U 5f orbitals was roughly 7-10% per U-Cl bond for both compounds, which shows that moving from oxo to imido has little effect on orbital mixing between the U 5f and equatorial Cl 3p orbitals. The results are presented in the context of recent Cl K-edge XAS and DFT studies on other hexavalent uranium chloride systems with fewer oxo or imido ligands.

  1. Synthesis and oxidation catalysis of [tris(oxazolinyl)borato]cobalt(II) scorpionates

    DOE PAGES-Beta [OSTI]

    Reinig, Regina R.; Mukherjee, Debabrata; Weinstein, Zachary B.; Xie, Weiwei; Albright, Toshia; Baird, Benjamin; Gray, Tristan S.; Ellern, Arkady; Miller, Gordon J.; Winter, Arthur H.; et al

    2016-04-28

    The reaction of CoCl2·THF and thallium tris(4,4-dimethyl-2-oxazolinyl)phenylborate (TlToM) in tetrahydrofuran (THF) provides ToMCoCl (1) in 95 % yield; however, appropriate solvents and starting materials are required to favor 1 over two other readily formed side-products, (ToM)2Co (2) and {HToM}CoCl2 (3). ESR, NMR, FTIR, and UV/Vis spectroscopies were used to distinguish these cobalt(II) products and probe their electronic and structural properties. Even after the structures indicated by these methods were confirmed by X-ray crystallography, the spectroscopic identification of trace contaminants in the material was challenging. The recognition of possible contaminants in the synthesis of ToMCoCl in combination with the paramagnetic naturemore » of these complexes provided impetus for the utilization of X-ray powder diffraction to measure the purity of the ToMCoCl bulk sample. Furthermore, the X-ray powder diffraction results provide support for the bulk-phase purity of ToMCoCl in preparations that avoid 2 and 3. Thus, 1 is a precursor for new [tris(oxazolinyl)borato]cobalt chemistry, as exemplified by its reactions with KOtBu and NaOAc to give ToMCoOtBu (4) and ToMCoOAc (5), respectively. Compound 5 is a catalyst for the oxidation of cyclohexane with meta-chloroperoxybenzoic acid (mCPBA), and the rate constants and selectivity for cyclohexanol versus cyclohexanone and ϵ-caprolactone were assessed.« less

  2. Summary

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Summary * The neighborhoods in which larger deep convective cloud objects occur tend to have higher values of albedo, cloud top height, ice water path, τ, and lower values of OLR, and cloud top temperature. These changes in the overall distributions with size are a combination of changes in the DC distribu- tions (similar to Xu et al. 2007) and an increase in the proportion of DC footprints. The non-DC distributions of these proper- ties change very little with cloud object size. * As SST

  3. Summary - Small Column Ion Exchange (SCIX)Technology at the SRS

    Office of Environmental Management (EM)

    ETR R Un Baseline The Sm being The SC operat which Sr, and waste critical the SC deploy Specif exchan [CST]) CST, a (mono and so (RMF) maturi readin design moving The pu techni projec Site: S roject: S E Report Date: F ited States Sma Why DOE e SCIX System Pr mall Column Io developed at S CIX system is tions (ion excha function to rem d actinides) fro and prepare th l technology ele CIX system tha yment and thes fically the critica nge on a selec ) housed in an actinide and Sr osodium titanat

  4. T:\ClearanceEMEUConsumption\cbecs\pubuse86\txt\cb86sasfmt&layout.txt

    U.S. Energy Information Administration (EIA) (indexed site)

    6/txt/cb86sasfmt&layout.txt[3/17/2009 4:43:14 PM] File 1: Summary File (cb86f01.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. Metropolitan statistical area MSA3 25- 25 $MSA. Climate zone CLIMATE3 27- 27 $CLIMAT. B-1 Square footage SQFT3 29- 35

  5. Word Pro - S4

    U.S. Energy Information Administration (EIA) (indexed site)

    3 Table 4.1 Natural Gas Overview (Billion Cubic Feet) Gross With- drawals a Marketed Production (Wet) b NGPL Production c Dry Gas Production d Supple- mental Gaseous Fuels e Trade Net Storage With- drawals f Balancing Item g Consump- tion h Imports Exports Net Imports 1950 Total .................... 8,480 i 6,282 260 i 6,022 NA 0 26 -26 -54 -175 5,767 1955 Total .................... 11,720 i 9,405 377 i 9,029 NA 11 31 -20 -68 -247 8,694 1960 Total .................... 15,088 i 12,771 543 i

  6. Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 lujAn Center reseArCh FeAtureD on Cover oF Langmuir 4 FunCtionAl oxiDes unDer extreme ConDi- tions-quest For new mAteriAls 6 heADs uP! By Diana Del Mauro ADEPS Communications Inside the Lujan Neutron Scattering Center, Victor Fanelli is busy preparing a superconducting magnet. In a series of delicate steps,

  7. M

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Deviation of static en- ergy (s=c p T+gz) from mesonet mean (location of cold pool) over- laid with gridded hourly precipita- tion amount contours. Figure 2. Divergence overlaid with gridded hourly precipitation amount. M u M d correlation with CRM precip M c,d M c,u M u M d M d + M u + MSE std dev wind std dev div i < -10 -4 S -1 div i > 10 -4 S -1 div i > 0 div i < 0 ] Mesoanalysis of the Interactions of Precipitating Convection and the Boundary Layer Ruiyu Sun, Steven K. Krueger,

  8. JJ'

    Office of Legacy Management (LM)

    ^x .,.,..,,, .,_...,,, .~, .~~ ,.,_,. _ . . ^..~ .,.-....-.. ~.~ .,,_,_ I-.~ ___:-._ ,,_ I --,,,,-.I I -... "I _-_,, i ,,,, (__. ..-;.mss,.r^-' . :' _.' i' . ' . r*911;&& --- _. JJ' 4)&-] " ]+-ic 7-g &Lc u.4 u - 7 S' JJ-- ,C- iki?rdC~L\T $' Y' IEThLS COP?O~,~TION d - I8 4.1 INROAD STREET (In ciuplicste) Xovezber 30, 1942. The I)ist?ict Eng~Gi U. S. EZi<i3eef Office, 2Zi%XttZ?l Cistrict, ? . 0 . z,ox 42, CL',t'~~'.' -~-~: ~,'y:-y;, :.yz --'- -- Station F., ,y: r:

  9. Research Portfolio Report Small Producers: Operations/Improved Recovery

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Small Producers: Operations/Improved Recovery Cover image: Drill rigs and pump jacks are some typical tools used in natural gas and oil opera- tions and for improved recovery Research Portfolio Report Small Producers: Operations/Improved Recovery DOE/NETL-2015/1698 Prepared by: Mari Nichols-Haining and Christine Rueter KeyLogic Systems, Inc. National Energy Technology Laboratory (NETL) Contact: James Ammer james.ammer@netl.doe.gov Contract DE-FE0004003 Activity 4003.200.03 DISCLAIMER This report

  10. Case Study: Fuel Cells Provide Combined Heat and Power at Verizon's Garden Central Office

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Case Study: Fuel Cells Provide Com- bined Heat and Power at Verizon's Garden City Central Office With more than 67 million customers nationwide, Verizon Communications is one of the largest telecommunica- tions providers in the U.S. Power inter- ruptions can severely impact network operations and could result in losses in excess of $1 million/minute. 1 In 2005, Verizon Communications installed a 1.4 MW phosphoric acid fuel cell (PAFC) system, consisting of seven 200 kW units, at its Central

  11. Fuel Cell Technologies Program: Delivery Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Distribution and Delivery Most of the hydrogen used in the U.S. is produced at or near where it is used - typically at large industrial sites. As a result, an efficient means of delivering large quantities of hydrogen fuel over long distances and at low cost does not yet exist. Before hydrogen can become a mainstream energy carrier, we must first develop and build the infrastructure (e.g. the miles of transmission and distribu- tion pipelines, bulk storage vessels, and refueling stations) that

  12. NTSF Spring 2012 Agenda

    Office of Environmental Management (EM)

    hilTon Knoxville Knoxville, Tennessee May 15-17 naTional TransporTaTion sTaKeholders ForuM 2012 2 3 Tuesday, May 15 Regional Meetings 8:15 am - 3:30 pm Western Governors' Association (WGA) Transportation Safety Technical Advisory Group Meeting - Salon A 8:30 am - 3:15 pm Southern States Energy Board (SSEB) Radioactive Materials Transportation Committees - Salon B 9:00 am - 3:30 pm Council of State Governments (CSG Midwest) Midwestern Radioactive Materials Transportation Committee Meeting - Salon

  13. Quantum Statistical Testing of a Quantum Random Number Generator

    SciTech Connect (OSTI)

    Humble, Travis S

    2014-01-01

    The unobservable elements in a quantum technology, e.g., the quantum state, complicate system verification against promised behavior. Using model-based system engineering, we present methods for verifying the opera- tion of a prototypical quantum random number generator. We begin with the algorithmic design of the QRNG followed by the synthesis of its physical design requirements. We next discuss how quantum statistical testing can be used to verify device behavior as well as detect device bias. We conclude by highlighting how system design and verification methods must influence effort to certify future quantum technologies.

  14. UNITED STATES GOVERNMENT DEPARTMENT OF ENERGY

    Office of Environmental Management (EM)

    UHlfED STATES OF AMERICA BEFORE THE FEDERAL U B O R RElATlONS AUTHORITY DEPARTMENT 0 1 . ' E3iERGY ALBAkY RESEARCH CEhTER ALBANJ', OREGON -Actlvit)' -Ahill- SATIONAL. FEDEMTION OF FEDERAL EMYLOYEES, LOCAL 1141 -Peti tionerlExclus~v c Repmmbtlve -and- AMENCAN FEDERATION OF GOVERNMENT EMPLOYEES, LOCAL I 104, AFL-CIO CASE NO. SF-RP-90042 Pursuant to Scc [ton 2422 1 of the Regulations of the Federal Labor Relations Authoriry, a pen t ~ o n was Filed seeking to amend rhe rscogni tion granted to the

  15. Pareto Efficient Policy for Supervisory Power Management Control

    SciTech Connect (OSTI)

    Malikopoulos, Andreas

    2015-01-01

    n this paper we address the problem of online optimization of the supervisory power management control in parallel hybrid electric vehicles (HEVs). We model HEV opera- tion as a controlled Markov chain using the long-run expected average cost per unit time criterion, and we show that the control policy yielding the Pareto optimal solution minimizes the average cost criterion online. The effectiveness of the proposed solution is validated through simulation and compared to the solution derived with dynamic programming using the average cost criterion.

  16. Search for CPT-odd decays of positronium

    SciTech Connect (OSTI)

    Vetter, Paul A.; Freedman, Stuart J.

    2003-07-11

    We have limited a CPT-violating correlation in annihilationsof polarized ortho-positronium. We searched for an asymmetry in thetriple correlations dot k1 cross k2, where k1 and k2 are the two largestphoton momenta, and s is the spin of the positronium. Using theGammasphere array of Compton-suppressed high-purity germanium detectors,we detected 2.65e7 events of ortho-Ps annihila tion. The amplitude of aCPT-violating asymmetry in the data set is found to be 0.0026 plus orminus 0.0031, a factor of 6 smaller than previousexperiments.

  17. Build-

    U.S. Energy Information Administration (EIA) (indexed site)

    0. Cooling Equipment, Number of Buildings for Non-Mall Buildings, 2003" ,"Number of Buildings (thousand)" ,"All Build- ings*","Cooled Build- ings","Cooling Equipment (more than one may apply)" ,,,"Resid- ential- Type Central Air Condi- tioners","Heat Pumps","Indiv- idual Air Condi- tioners","District Chilled Water","Central Chillers","Pack- aged Air Condi- tioning Units","Swamp

  18. Build-

    U.S. Energy Information Administration (EIA) (indexed site)

    1. Cooling Equipment, Floorspace for Non-Mall Buildings, 2003" ,"Total Floorspace (million square feet)" ,"All Build- ings*","Cooled Build- ings","Cooling Equipment (more than one may apply)" ,,,"Resid- ential- Type Central Air Condi- tioners","Heat Pumps","Indiv- idual Air Condi- tioners","District Chilled Water","Central Chillers","Pack- aged Air Condi- tioning Units","Swamp

  19. The Impact of Abrupt Suspension of Solar Radiation Management (Termination Effect) in Experiment G2 of the Geoengineering Model Intercomparison Project (GeoMIP)

    SciTech Connect (OSTI)

    Jones, Andrew; Haywood, J.; Alterskjaer, Kari; Boucher, Olivier; Cole, Jason N.; Curry, Charles L.; Irvine, Peter; Ji, Duoying; Kravitz, Benjamin S.; Kristjansson, Jon E.; Moore, John; Niemeier, Ulrike; Robock, Alan; Schmidt, Hauke; Singh, Balwinder; Tilmes, S.; Watanabe, Shingo; Yoon, Jin-Ho

    2013-09-11

    We have examined changes in climate which result from the sudden termination of geoengineering after 50 years of offsetting a 1% per annum increase in CO2 concentra- tions as simulated by 11 different climate models in experiment G2 of the Geoengineering Model Intercomparison Project. The models agree on a rapid rate of global-mean warming following termination, accompanied by increases in global-mean precipitation rate and in plant net primary productivity, and decreases in sea-ice cover. While there is a considerable degree of consensus for the geographical distribution of warming, there is much less of an agreement regarding the patterns of change in the other quantities.

  20. U.S. Energy Information Administration (EIA) (indexed site)

    File 2: Building Activity (cb86f02.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. B-3 Any residential use RESUSE3 28- 28 $YESNO. B-4 Percent residential RESPC3 30- 30 $RESPC. Principal building activity PBA3 32-

  1. U.S. Energy Information Administration (EIA) (indexed site)

    5: End Uses of Major Energy Sources (cb86f05.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year construction was completed YRCONC3 31- 32 $YRCONC.

  2. U.S. Energy Information Administration (EIA) (indexed site)

    6: End Uses of Minor Energy Sources (cb86f06.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year construction was completed YRCONC3 31- 32 $YRCONC.

  3. U.S. Energy Information Administration (EIA) (indexed site)

    File10: District Steam and Hot Water (cb86f10.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year construction was completed YRCONC3 31- 32 $YRCONC.

  4. U.S. Energy Information Administration (EIA) (indexed site)

    1: Propane and District Chilled Water (cb86f11.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year construction was completed YRCONC3 31- 32 $YRCONC.

  5. U.S. Energy Information Administration (EIA) (indexed site)

    File 11: District Steam and Hot Water (CBECS89.A11) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region REGION4 7- 7 $REGION. Census division CENDIV4 9- 9 $CENDIV. B2 Square footage SQFTC4 11- 12 $SQFTC. Principal building activity PBA4 14- 15 $ACTIVTY. F3 Year construction was completed YRCONC4 17- 18 $YRCONC. Adjusted weight ADJWT4 20- 27 Variance stratum STRATUM4 29- 30 Pair indicator PAIR4 32- 32

  6. U.S. Energy Information Administration (EIA) (indexed site)

    File 12: District Chilled Water (CBECS89.A12) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region REGION4 7- 7 $REGION. Census division CENDIV4 9- 9 $CENDIV. B2 Square footage SQFTC4 11- 12 $SQFTC. Principal building activity PBA4 14- 15 $ACTIVTY. F3 Year construction was completed YRCONC4 17- 18 $YRCONC. Adjusted weight ADJWT4 20- 27 Variance stratum STRATUM4 29- 30 Pair indicator PAIR4 32- 32

  7. U.S. Energy Information Administration (EIA) (indexed site)

    File 14: Imputation Flags for End Uses (CBECS89.A14) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region REGION4 7- 7 $REGION. Census division CENDIV4 9- 9 $CENDIV. B2 Square footage SQFTC4 11- 12 $SQFTC. Principal building activity PBA4 14- 15 $ACTIVTY. F3 Year construction was completed YRCONC4 17- 18 $YRCONC. Imputed main heating ZHT14 20- 20 $ZVAR. Imputed secondary heating ZHT24 22- 22 $ZVAR.

  8. U.S. Energy Information Administration (EIA) (indexed site)

    5: End Uses of Major Energy Sources (CBECS89.A05) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region REGION4 7- 7 $REGION. Census division CENDIV4 9- 9 $CENDIV. B2 Square footage SQFTC4 11- 12 $SQFTC. Principal building activity PBA4 14- 15 $ACTIVTY. C3AA Electricity used for main heating ELHT14 17- 17 $XXSUPL. C3BA Electricity used for secondary heating ELHT24 19- 19 $XXSUPL. C3CA Electricity used for

  9. U.S. Energy Information Administration (EIA) (indexed site)

    6: End Uses of Minor Energy Sources (CBECS89.A06) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format CASEID Building identifier BLDGID4 1- 5 Census region REGION4 7- 7 $REGION. Census division CENDIV4 9- 9 $CENDIV. B2 Square footage SQFTC4 11- 12 $SQFTC. Principal building activity PBA4 14- 15 $ACTIVTY. C1D Propane used in past 12 months PRUSED4 17- 17 $YESNO. C3AD Propane used for main heating PRHT14 19- 19 $YESNO. C3BD Propane used for secondary heating

  10. Hanford Radiological Protection Support Services Annual Report for 1998

    SciTech Connect (OSTI)

    DE Bihl; JA MacLellan; ML Johnson; RK Piper; TP Lynch

    1999-05-14

    During calendar year (CY) 1998, the Pacific Northwest National Laboratory (PNNL) performed its customary radiological protection support services in support of the U.S. Department of Energy (DOE) Richland Operations OffIce (RL) and the Hanford contractors. These services included: 1) external dosimetry, 2) internal dosimetry, 3) in vivo measurements, 4) radiological records, 5) instrument calibra- tion and evaluation, and 6) calibration of radiation sources traceable to the National Institute of Standards and Technology (MST). The services were provided under a number of projects as summarized here.

  11. UHlfED STATES OF AMERICA BEFORE THE FEDERAL U B O R RElATlONS AUTHORITY

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    UHlfED STATES OF AMERICA BEFORE THE FEDERAL U B O R RElATlONS AUTHORITY DEPARTMENT 0 1 . ' E3iERGY ALBAkY RESEARCH CEhTER ALBANJ', OREGON -Actlvit)' -Ahill- SATIONAL. FEDEMTION OF FEDERAL EMYLOYEES, LOCAL 1141 -Peti tionerlExclus~v c Repmmbtlve -and- AMENCAN FEDERATION OF GOVERNMENT EMPLOYEES, LOCAL I 104, AFL-CIO CASE NO. SF-RP-90042 Pursuant to Scc [ton 2422 1 of the Regulations of the Federal Labor Relations Authoriry, a pen t ~ o n was Filed seeking to amend rhe rscogni tion granted to the

  12. WTP Communications Strategy Discussion Topics

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Discussion Topics For discussion at the April 7, 2015 PIC meeting Issue Managers: Bob Suyama, Dave Bernhard, Melanie Myers-Magnuson, Dirk Dunning, Liz Mattson, Pam Larsen, Ken Niles Some potential questions and areas that the TWC/PIC need to discuss in order to develop a Communica- tions Strategy for the Waste Treatment Plant. These questions represent the data that the TWC/PIC might need in order to provide a plan that will be of value to the Tri-Party Agencies and the Public and Stakeholders.

  13. ch_4

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    40 Affected Environment playas 15 to 20 miles northeast of INTEC, where the water infiltrates. The water in Birch Creek and the Little Lost River is diverted in summer months for irriga- tion prior to reaching INEEL. During periods of unusually high precipitation or rapid snow melt, water from Birch Creek and the Little Lost River may enter INEEL from the northwest and infil- trate the ground, recharging the underlying aquifer. 4.8.1.2 Local Drainage INTEC is located on an alluvial plain

  14. ch_5

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    HLW & FD EIS 5-73 DOE/EIS-0287 tion dose to the nonin- volved worker and maximally exposed offsite individual and the collective dose to the population residing within 50 miles of INTEC. The radiation dose values for the var- ious alternatives were then multiplied by the dose-to-risk conversion factors, which are based on the 1993 Limitations of Exposure to Ionizing Radiation (NCRP 1993). DOE has adopted these risk fac- tors of 0.0005 and 0.0004 latent cancer fatality (LCF) for each

  15. Mr. John Kiel

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Kiel ing , Acting Chief Hazardous Waste Bureau De p artm ent of En e rgy Carlsbad Field Office P. O. Box 3090 Carlsbad. New Mexico 8822 1 NOV 2 1 2011 New M exico Environment Department 2905 Rodeo Park Drive East. Building 1 Santa Fe . New Mexico 87505-6303 Subject: Notification of Class 1 Permit Modifica tions to the Hazardous Waste Facility Permit , Number: NM4890139088-TSDF Dea r Mr. Kielin g: Enclosed are til e following Class 1 Permit Modification Notificatio ns: * Editorial Correction to

  16. Division, NN-43, Office of Arms Control

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8 10 CFR Ch. III (1-1-10 Edition) § 810.14 Division, NN-43, Office of Arms Control and Nonproliferation. [51 FR 44574, Dec. 10, 1986, as amended at 58 FR 39639, July 16, 1993; 65 FR 16128, Mar. 27, 2000] § 810.14 Additional information. The Department of Energy may at any time require a person engaging in any generally or specifically author- ized activity to submit additional in- formation. § 810.15 Violations. (a) The Atomic Energy Act provides that: (1) Permanent or temporary injunc- tions

  17. Grain Boundary Percolation Modeling of Fission Gas Release in Oxide Fuels

    SciTech Connect (OSTI)

    Paul C. Millett; Michael R. Tonks; S. B. Biner

    2012-05-01

    We present a new approach to fission gas release modeling in oxide fuels based on grain boundary network percolation. The method accounts for variability in the bubble growth and coalescence rates on individual grain boundaries, and the resulting effect on macroscopic fission gas release. Two-dimensional representa- tions of fuel pellet microstructures are considered, and the resulting gas release rates are compared with traditional two-stage Booth models, which do not account for long-range percolation on grain boundary net- works. The results show that the requirement of percolation of saturated grain boundaries can considerably reduce the total gas release rates, particularly when gas resolution is considered.

  18. October 2007 BWXTymes

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    7 J a w s o f l i f e a t Y- 12 , p g . 4 , * A l p h a b e t s o u p , p g . 6 * Y- 12 a w a r d w i n n e r s , p g . 8 Y-12: a good environmental steward The Y-12 National Security Complex was recognized for its environmental stewardship and received "Honorable Men- tion for Environmental Achievement" in Environmental Protection magazine's 2007 Facilities of the Year competition. Y-12's commitment to the environment is not a one-time occurrence, but the result of continued

  19. PROTON RESONANCE SPECTROSCOPY

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    as a i i . : lJIiaSJ :ShUiI,,:;II. Iii II; PROTON RESONANCE SPECTROSCOPY IN 29p LAWRENCE H. JAMES Triangle Universities Nuclear Laboratory Department of Physics North Carolina State University 1989 - - .. - .. - .. Abstract James, Lawrence Hoy Proton Resonance Spectroscopy in 29 p (Under the direc- tion of Gary E. Mitchell) Proton elastic scattering on 28Si was measured with good beam energy resolution in the proton energy range Ep=1.4 to E =3.75 MeV, and proton inelastic scattering on p 28Si

  20. Energy Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    the Deployment of Energy Efficiency & Renewable Energy Technologies in South Africa A Summary of the Trust for Conservation Global Cool Cities Alliance Project In 2010, the Deputy Secretary of the U.S. Department of Energy and the Energy Minister of the Republic of South Africa (RSA) launched the U.S. - RSA Energy Dialogue to facilitate coopera- tion in a number of areas, including energy effciency and renew- able energy. In support of the U.S. - RSA Energy Dialogue, the U.S. Department of

  1. Microsoft Word - NiR.doc

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Side-on Cu-Nitrosyl Coordination by Nitrite Reductase Elitza I. Tocheva and Michael E. P. Murphy Department of Microbiology & Immunology, The University of British Columbia, Vancouver, BC, Canada V6T 1Z3. Nitric oxide (NO) is one of the smallest and simplest biologically active molecules. In mammals, NO is produced from arginine by isoforms of nitric oxide synthase, and it func- tions in signal transduction and as a cytoprotective or cytotoxic agent. In bacteria, NO is produced by nitrite

  2. Microsoft Word - Rad_Hard_Assurance_Fact_Sheet_SAND2011-0937P_updated_format.docx

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Rad Radiatio Rad-Har systems hardenin Radiat Gamma The Rad includin of Sandi the phys semicon the parts low-dos radiation X-ray R The Rad Sandia a irradiato especiall one of th tube is lo irradiatio wafer-le technolo Sandia's that have Figure 2 Gamma diation on Hardening rd electronic or in close p ng provides a tion Phys a Ray Radi diation Physi ng two 60 Co s ia and comm sical mechan nductor devic s to be tested e-rate irradia n sources sho Radiation S diation Physi also maintain ors use X-ray

  3. BWXTymes, A newsletter for the employees and friends of the Y-12 National Security Complex, September 2007

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    7 B e r y l l i u m a n d y o u , p g . 2 , * S n i f f e r s a t w o r k , p g . 3 * A l o c k o n s u c c e s s , p g . 6 The Uranium Processing Facility project team received federal approval on July 25 to begin preliminary design, another major milestone for the new facility. The Y-12 facility will play a major role in helping the National Nuclear Security Administra- tion achieve its Complex 2030 vision of establishing a smaller, more effi cient Nuclear Weapons Complex able to respond to

  4. BWXTymes, October 2004: Y-12 newsletter

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Loudon $31,600 Blount $15,600 Knox $260,300 Anderson $208,600 Roane $67,800 OCTOBER 2004 Out with the old and in with the new A newsletter for the employees and friends of the Y-12 National Security Complex Y-12's 2004 United Way campaign was a resounding success, raising more than $650,000 for local charitable organiza- tions. Included in this amount was a corpo- rate contribution of $40,000. Special events dur- ing the drive included a book fair, a silent online auction, a bake sale, a

  5. Energy Information Administration (EIA)- About the Commercial Buildings

    Gasoline and Diesel Fuel Update

    Energy Consumption Survey (CBECS) 0. Cooling equipment, number of buildings, 2012 Released: May 2016 Number of buildings (thousand) All buildings Buildings with cooling Cooling equipment (more than one may apply) Resid- ential- type central air condi- tioners Heat pumps Indiv- idual air condi- tioners District chilled water Central chillers Pack- aged air condi- tioning units Swamp coolers Other All buildings 5,557 4,461 1,546 692 709 54 163 1,909 109 Q Building floorspace (square feet)

  6. Energy Information Administration (EIA)- About the Commercial Buildings

    Gasoline and Diesel Fuel Update

    Energy Consumption Survey (CBECS) 1. Cooling equipment, floorspace, 2012 Released: May 2016 Total floorspace (million square feet) All buildings Buildings with cooling Cooling equipment (more than one may apply) Resid- ential- type central air condi- tioners Heat pumps Indiv- idual air condi- tioners District chilled water Central chillers Pack- aged air condi- tioning units Swamp coolers Other All buildings 87,093 79,294 14,765 12,538 12,420 4,608 17,041 45,153 1,918 328 Building floorspace

  7. LANL: AOT & LANSCE The Pulse April 2010

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    0 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 KovalevsKy and Fisher receive post- doctoral awards nuclear cross sec- tions For accelera- tor production oF a therapy isotope 3 understanding the pathogenesis oF alzheimer's disease 4 heads up! Ultracold neutron accomplishments at LANSCE The weak nuclear force is one of the four fundamental forces in nature, along with

  8. The Role of The fedeRal PRojecT diRecToR

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Role of The fedeRal PRojecT diRecToR: lessons fRom The naTional igniTion faciliTy The national ignition facility (nif) is home of the world's largest laser. With 192 laser beams that can deliver more than 60 times the energy of any previous laser system, NIF represents a significant step in enabling the study of high-energy density science, and should demonstrate fusion ignition and burn in the laboratory for the first time. The design and construction of this unique, highly complex facility

  9. GADRAS isotope ID users manual for analysis of gamma-ray measurements and API for Linux and Android .

    SciTech Connect (OSTI)

    Mitchell, Dean J; Harding, Lee T.

    2014-05-01

    Isotope identification algorithms that are contained in the Gamma Detector Response and Analysis Software (GADRAS) can be used for real-time stationary measurement and search applications on platforms operating under Linux or Android operating sys-tems. Since the background radiation can vary considerably due to variations in natu-rally-occurring radioactive materials (NORM), spectral algorithms can be substantial-ly more sensitive to threat materials than search algorithms based strictly on count rate. Specific isotopes or interest can be designated for the search algorithm, which permits suppression of alarms for non-threatening sources, such as such as medical radionuclides. The same isotope identification algorithms that are used for search ap-plications can also be used to process static measurements. The isotope identification algorithms follow the same protocols as those used by the Windows version of GADRAS, so files that are created under the Windows interface can be copied direct-ly to processors on fielded sensors. The analysis algorithms contain provisions for gain adjustment and energy lineariza-tion, which enables direct processing of spectra as they are recorded by multichannel analyzers. Gain compensation is performed by utilizing photopeaks in background spectra. Incorporation of this energy calibration tasks into the analysis algorithm also eliminates one of the more difficult challenges associated with development of radia-tion detection equipment.

  10. Improved DC Gun Insulator Assembly

    SciTech Connect (OSTI)

    Sah, R.; Dudas, A.; Neubauer, M. L.; Poelker, M.; Surles-Law, K. E.L.

    2010-05-23

    Many user fa­cil­i­ties such as syn­chrotron ra­di­a­tion light sources and free elec­tron lasers re­quire ac­cel­er­at­ing struc­tures that sup­port elec­tric fields of 10-100 MV/m, es­pe­cial­ly at the start of the ac­cel­er­a­tor chain where ce­ram­ic in­su­la­tors are used for very high gra­di­ent DC guns. These in­su­la­tors are dif­fi­cult to man­u­fac­ture, re­quire long com­mis­sion­ing times, and often ex­hib­it poor re­li­a­bil­i­ty. Two tech­ni­cal ap­proach­es to solv­ing this prob­lem will be in­ves­ti­gat­ed. First­ly, in­vert­ed ce­ram­ics offer so­lu­tions for re­duced gra­di­ents be­tween the elec­trodes and ground. An in­vert­ed de­sign will be pre­sent­ed for 350 kV, with max­i­mum gra­di­ents in the range of 5-10 MV/m. Sec­ond­ly, novel ce­ram­ic man­u­fac­tur­ing pro­cess­es will be stud­ied, in order to pro­tect triple junc­tion lo­ca­tions from emis­sion, by ap­ply­ing a coat­ing with a bulk re­sis­tiv­i­ty. The pro­cess­es for cre­at­ing this coat­ing will be op­ti­mized to pro­vide pro­tec­tion as well as be used to coat a ce­ram­ic with an ap­pro­pri­ate gra­di­ent in bulk re­sis­tiv­i­ty from the vac­u­um side to the air side of an HV stand­off ce­ram­ic cylin­der. Ex­am­ple in­su­la­tor de­signs are being com­put­er mod­elled, and in­su­la­tor sam­ples are being man­u­fac­tured and test­ed

  11. Photonics Research and Development

    SciTech Connect (OSTI)

    Pookpanratana, Sujitra; Shlayan, Neveen; Venkat, Rama; Das, Bisjwajit; Boehm, Bob; Heske, Clemens; Fraser, Donald; Moustakas, Theodore

    2010-01-15

    During the period August 2005 through October 2009, the UNLV Research Foundation (UNLVRF), a non-profit affiliate of the University of Nevada, Las Vegas (UNLV), in collaboration with UNLV’s Colleges of Science and Engineering; Boston University (BU); Oak Ridge National Laboratory (ORNL); and Sunlight Direct, LLC, has managed and conducted a diverse and comprehensive research and development program focused on light-emitting diode (LED) technologies that provide significantly improved characteristics for lighting and display applications. This final technical report provides detailed information on the nature of the tasks, the results of the research, and the deliverables. It is estimated that about five percent of the energy used in the nation is for lighting homes, buildings and streets, accounting for some 25 percent of the average home’s electric bill. However, the figure is significantly higher for the commercial sector. About 60 percent of the electricity for businesses is for lighting. Thus replacement of current lighting with solid-state lighting technology has the potential to significantly reduce this nation’s energy consumption – by some estimates, possibly as high as 20%. The primary objective of this multi-year R&D project has been to develop and advance lighting technologies to improve national energy conversion efficiencies; reduce heat load; and significantly lower the cost of conventional lighting technologies. The UNLVRF and its partners have specifically focused these talents on (1) improving LED technologies; (2) optimizing hybrid solar lighting, a technology which potentially offers the benefits of blending natural with artificial lighting systems, thus improving energy efficiency; and (3) building a comprehensive academic infrastructure within UNLV which concentrates on photonics R&D. Task researchers have reported impressive progress in (1) the development of quantum dot laser emitting diodes (QDLEDs) which will ultimately

  12. Electrochemical Oxidation of H? Catalyzed by Ruthenium Hydride Complexes Bearing P?N? Ligands With Pendant Amines as Proton Relays

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2014-01-01

    Two Ru hydride complexes (Cp*Ru(PPh?NBn?)H, (1-H) and Cp*Ru(PtBu?NBn?)H, (2-H) supported by cyclic PR?NR'? ligands (Cp* = n?-C?Me?; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H? (1 atm, 22 C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H?O facilitates oxidation of H? by 2-H and increases its turnover frequency to 1.9 s-1 while , H?O slows down the catalysis by 1-H. The different effects of H?O for 1-H and 2-H are ascribed to different binding affinities of H?O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh?NBn?)]+ and [Cp*Ru(PPh?NBn?)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P?N? ligands for oxidation of H?. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  13. Experimental Systems-Biology Approaches for Clostridia-Based Bioenergy Production

    SciTech Connect (OSTI)

    Papoutsakis, Elefterios

    2015-04-30

    This is the final project report for project "Experimental Systems-Biology Approaches for Clostridia-Based Bioenergy Production" for the funding period of 9/1/12 to 2/28/2015 (three years with a 6-month no-cost extension) OVERVIEW AND PROJECT GOALS The bottleneck of achieving higher rates and titers of toxic metabolites (such as solvents and carboxylic acids that can used as biofuels or biofuel precursors) can be overcome by engineering the stress response system. Thus, understanding and modeling the response of cells to toxic metabolites is a problem of great fundamental and practical significance. In this project, our goal is to dissect at the molecular systems level and build models (conceptual and quantitative) for the stress response of C. acetobutylicum (Cac) to its two toxic metabolites: butanol (BuOH) and butyrate (BA). Transcriptional (RNAseq and microarray based), proteomic and fluxomic data and their analysis are key requirements for this goal. Transcriptional data from mid-exponential cultures of Cac under 4 different levels of BuOH and BA stress was obtained using both microarrays (Papoutsakis group) and deep sequencing (RNAseq; Meyers and Papoutsakis groups). These two sets of data do not only serve to validate each other, but are also used for identification of stress-induced changes in transcript levels, small regulatory RNAs, & in transcriptional start sites. Quantitative proteomic data (Lee group), collected using the iTRAQ technology, are essential for understanding of protein levels and turnover under stress and the various protein-protein interactions that orchestrate the stress response. Metabolic flux changes (Antoniewicz group) of core pathways, which provide important information on the re-allocation of energy and carbon resources under metabolite stress, were examined using 13C-labelled chemicals. Omics data are integrated at different levels and scales. At the metabolic-pathway level, omics data are integrated into a 2nd generation genome

  14. MicroRNA Regulation of Ionizing Radiation-Induced Premature Senescence

    SciTech Connect (OSTI)

    Wang Yong; Scheiber, Melissa N.; Neumann, Carola; Calin, George A.; Zhou Daohong

    2011-11-01

    Purpose: MicroRNAs (miRNAs) have emerged as critical regulators of many cellular pathways. Ionizing radiation (IR) exposure causes DNA damage and induces premature senescence. However, the role of miRNAs in IR-induced senescence has not been well defined. Thus, the purpose of this study was to identify and characterize senescence-associated miRNAs (SA-miRNAs) and to investigate the role of SA-miRNAs in IR-induced senescence. Methods and Materials: In human lung (WI-38) fibroblasts, premature senescence was induced either by IR or busulfan (BU) treatment, and replicative senescence was accomplished by serial passaging. MiRNA microarray were used to identify SA-miRNAs, and real-time reverse transcription (RT)-PCR validated the expression profiles of SA-miRNAs in various senescent cells. The role of SA-miRNAs in IR-induced senescence was characterized by knockdown of miRNA expression, using anti-miRNA oligonucleotides or by miRNA overexpression through the transfection of pre-miRNA mimics. Results: We identified eight SA-miRNAs, four of which were up-regulated (miR-152, -410, -431, and -493) and four which were down-regulated (miR-155, -20a, -25, and -15a), that are differentially expressed in both prematurely senescent (induced by IR or BU) and replicatively senescent WI-38 cells. Validation of the expression of these SA-miRNAs indicated that down-regulation of miR-155, -20a, -25, and -15a is a characteristic miRNA expression signature of cellular senescence. Functional analyses revealed that knockdown of miR-155 or miR-20a, but not miR-25 or miR-15a, markedly enhanced IR-induced senescence, whereas ectopic overexpression of miR-155 or miR-20a significantly inhibited senescence induction. Furthermore, our studies indicate that miR-155 modulates IR-induced senescence by acting downstream of the p53 and p38 mitogen-activated protein kinase (MAPK) pathways and in part via regulating tumor protein 53-induced nuclear protein 1 (TP53INP1) expression. Conclusion: Our

  15. XAS/EXAFS studies of Ge nanoparticles produced by reaction between Mg{sub 2}Ge and GeCl{sub 4}

    SciTech Connect (OSTI)

    Pugsley, Andrew J.; Bull, Craig L.; Sella, Andrea; Sankar, Gopinathan; McMillan, Paul F.

    2011-09-15

    We present results of an XAS and EXAFS study of the synthesis of Ge nanoparticles formed by a metathesis reaction between Mg{sub 2}Ge and GeCl{sub 4} in diglyme (diethylene glycol dimethyl ether). The progress of the formation reaction and the products formed at various stages in the processing was characterised by TEM and optical spectroscopy as well as in situ XAS/EXAFS studies using specially designed reaction cells. - Graphical abstract: Nano-Ge particles 2-10 nm in diameter were prepared by reaction between Mg{sub 2}Ge Zintl phase and GeCl{sub 4} in diglyme followed by capping with BuLi and extraction into hexane. We used synchrotron X-ray absorption spectroscopy (XAS) at the Ge K edge with analysis of the EXAFS region combined with room temperature photoluminescence and TEM to characterise the nature of the nanoparticles and model compounds and to follow the course of the reaction. A TEM image of the germanium nanoparticles is shown. Highlights: > In situ characteristaion of germanium nanoparticles. > X-ray spectroscopic technique development. > Improving quality of nanoparticles grown by metathesis route.

  16. A Fmoc-compatible Method for the Solid-Phase Synthesis of Peptide C-Terminal (alpha)-Thioesters based on the Safety-Catch Hydrazine Linker

    SciTech Connect (OSTI)

    Camarero, J A; Hackel, B J; de Yoreo, J J; Mitchell, A R

    2003-11-22

    C-terminal peptide thioesters are key intermediates for the synthesis/semisynthesis of proteins and for the production of cyclic peptides by native chemical ligation. They can be synthetically prepared by solid-phase peptide synthesis (SPPS) methods or biosynthetically by protein splicing techniques. Until recently, the chemical synthesis of C-terminal a-thioester peptides by SPPS was largely restricted to the Boc/Benzyl methodology because of the poor stability of the thioester bond to the basic conditions employed for the deprotection of the N{sup {alpha}}-Fmoc group. In the present work, we describe a new method for the SPPS of C-terminal thioesters by Fmoc/t-Bu chemistry. This method is based on the use of an aryl hydrazide linker, which is totally stable to the Fmoc-SPPS conditions. Once the peptide synthesis has been completed, activation of the linker can be achieved by mild oxidation. This step transforms the hydrazide group into a highly reactive diazene intermediate which can react with different H-AA-SEt to yield the corresponding {alpha}-thioester peptide in good yields. This method has been successfully used for the generation of different thioester peptides, circular peptides and a fully functional SH3 protein domain.

  17. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  18. A=6Li (66LA04)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 6Li) GENERAL: See Table 6.4 [Table of Energy Levels] (in PDF or PS). See also (AU55, LA55, ME56, FR57, HU57D, LE57F, PI58, BA59K, BR59M, FE59E, SK59, UB59, AN60, JA60G, KO60E, PH60A, TA60L, WA60F, BA61N, KO61A, SH61B, TA61G, VA61, CO62B, CR62A, DI62B, FO62E, GA62C, IN62, IN62A, IN62B, JA62, ME62A, NA62C, SA62C, ST62B, WA62H, BO63B, BU63D, DA63D, EL63D, HA63K, JA63C, JO63B, KL63, KU63B, KU63I, MO63C, OL63B, SA63K, SC63E, SC63I, VL63A, WA63, GR64C, JI64,

  19. The effect of alkali metal on the surface properties of potassium doped Au-Beta zeolites

    SciTech Connect (OSTI)

    Sobczak, Izabela; Rydz, Michal; Ziolek, Maria

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ► Interaction of gold with K leads to the change of electronic state and redox properties of gold. ► The amount of potassium incorporated into Au-zeolites determines the size of gold particles. ► K(0.2 wt.%)/Au-Beta exhibits the best performance in decomposition of N{sub 2}O and removal of Bu{sub 2}S. -- Abstract: Beta zeolite was applied as support for gold introduced by gold-precipitation method and potassium added by impregnation or adsorption. The effect of zeolite composition and the amount of potassium introduced on the surface properties of the final materials was considered. Moreover, the interaction of gold and potassium species was found to be related to the adsorptive and catalytic behaviour of zeolites in NO reduction with propene and deodorization. K/Au-Beta(Impregnated) exhibits the best performance in the above mentioned processes because of the small gold particles (between 2 and 5 nm) and interaction of gold with potassium species leading to the change of electronic properties of the surface (the appearance of cationic gold species). Potassium added as a promoter improves the catalytic properties of Au-zeolite in N{sub 2}O decomposition and also in deodorization (increase of the ability to dibutyl sulphide oxidation). The catalysts prepared were characterized by XRD, XPS, UV–vis, TEM, pyridine adsorption combined with FTIR and test reaction (2-propanol transformation).

  20. Camp Sacajawea Passive Solar Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1983-08-31

    The intent of the Passive Solar Demonstration Project was to have: an actual demonstration of the effectiveness of a passive solar design and working automatic shading devices; accurate data of energy saved by the passive design and shading devices; a brochure distributed to architects, builders, and consumers, with the monitoring data and information about the project; and the continued monitoring of the building to help explain to those who are using the building the value of the system; this would not only include the 7000 members, bu visitors and other users of the facility. To accomplish these goals, a monitoring system was installed in the recently build Passive Solar Lodge at Camp Sacajawea on Casper Mountain south of Casper, Wyoming. The building was monitored continously for the remainder of the project. The installation of the automatic shading device, a curtain wall was accomplished but had some difficulty. The results indicate there is some effectiveness of the Curtain Wall, but a quantitative value would be impossible at this time.

  1. 3H Cross Section

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    3H(α, X) (Current as of 02/01/2016) NSR Reaction Eα (MeV) Cross Section File X4 Dataset Date Added 2001TO07 3H(α, γ): deduced S-factor Ecm = 0.05 - 0.8 X4 01/09/2012 1994BR25 3H(α, γ): deduced σ and S-factor Ecm = 50 - 1200 keV X4 01/09/2012 1987SC18 3H(α, γ): σ, deduced S-factor Ecm = 79 - 464 keV X4 01/09/2012 1988SA13 3H(α, α): recoil σ 0.5 - 2.5 X4 01/09/2012 1987BU18 3H(α, γ): σ and S-factor 0.7 - 2 X4 01/09/2012 1968IV01 3H(α, α): elastic scattering σ 3 - 11 Table 9 X4

  2. EsxB, a secreted protein from Bacillus anthracis forms two distinct helical bundles

    DOE PAGES-Beta [OSTI]

    Fan, Yao; Tan, Kemin; Chhor, Gekleng; Butler, Emily K.; Jedrzejczak, Robert P.; Missiakas, Dominique; Joachimiak, Andrzej

    2015-07-03

    The EsxB protein from Bacillus anthracis belongs to the WXG100 family, a group of proteins secreted by a specialized secretion system. We have determined the crystal structures of recombinant EsxB and discovered that the small protein (~10 kDa), comprised of a helix-loop-helix (HLH) hairpin, is capable of associating into two different helical bundles. The two basic quaternary assemblies of EsxB are an antiparallel (AP) dimer and a rarely observed bisecting U (BU) dimer. This structural duality of EsxB is believed to originate from the heptad repeat sequence diversity of the first helix of its HLH hairpin, which allows for twomore » alternative helix packing. The flexibility of EsxB and the ability to form alternative helical bundles underscore the possibility that this protein can serve as an adaptor in secretion and can form hetero-oligomeric helix bundle(s) with other secreted members of the WXG100 family, such as EsxW. The highly conserved WXG motif is located within the loop of the HLH hairpin and is mostly buried within the helix bundle suggesting that its role is mainly structural. The exact functions of the motif, including a proposed role as a secretion signal, remain unknown.« less

  3. EsxB, a secreted protein from Bacillus anthracis forms two distinct helical bundles

    SciTech Connect (OSTI)

    Fan, Yao; Tan, Kemin; Chhor, Gekleng; Butler, Emily K.; Jedrzejczak, Robert P.; Missiakas, Dominique; Joachimiak, Andrzej

    2015-07-03

    The EsxB protein from Bacillus anthracis belongs to the WXG100 family, a group of proteins secreted by a specialized secretion system. We have determined the crystal structures of recombinant EsxB and discovered that the small protein (~10 kDa), comprised of a helix-loop-helix (HLH) hairpin, is capable of associating into two different helical bundles. The two basic quaternary assemblies of EsxB are an antiparallel (AP) dimer and a rarely observed bisecting U (BU) dimer. This structural duality of EsxB is believed to originate from the heptad repeat sequence diversity of the first helix of its HLH hairpin, which allows for two alternative helix packing. The flexibility of EsxB and the ability to form alternative helical bundles underscore the possibility that this protein can serve as an adaptor in secretion and can form hetero-oligomeric helix bundle(s) with other secreted members of the WXG100 family, such as EsxW. The highly conserved WXG motif is located within the loop of the HLH hairpin and is mostly buried within the helix bundle suggesting that its role is mainly structural. The exact functions of the motif, including a proposed role as a secretion signal, remain unknown.

  4. Pressure-dependent magnetism and electrical resistivity of UFe/sub 4/P/sub 12/

    SciTech Connect (OSTI)

    Guertin, R.P.; Rossel, C.; Torikachvili, M.S.; McElfresh, M.W.; Maple, M.B.; Bloom, S.H.; Yao, Y.S.; Kuric, M.V.; Meisner, G.P.

    1987-12-01

    UFe/sub 4/P/sub 12/ is the first reported uranium-based ferromagnetic semiconductor. The Curie temperature T/sub C/ is 3.15 K, and the spontaneous magnetic moment sigma/sub 0/ which at T = 1.14 K was found to be approx. =1.0 ..mu../sub B//(U atom), is associated entirely with the uranium ions. The electrical resistivity rho(T) increases by nearly 7 orders of magnitude as temperature is decreased from room temperature to 4.2 K. The behavior of the ferromagnetic and electrical properties of UFe/sub 4/P/sub 12/ in hydrostatic pressures up to 16 kbar is reported. Quasihydrostatic-pressure effects on rho(T) to 100 kbar are also reported. Although T/sub C/ increases sharply with increasing pressure at the rate dT/sub C//dP = 0.26 K/kbar (in contrast to similar data on the isomorphic ferromagnet NdFe/sub 4/P/sub 12/, where dT/sub C//dP = 0.03 K/kbar), sigma/sub 0/ decreases, (1/sigma/sub 0/)(dsigma/sub 0//dp) = -0.007 kbar/sup -1/. Hydrostatic and quasihydrostatic pressure have little effect on rho(T).

  5. Air Shipment of Highly Enriched Uranium Spent Nuclear Fuel from Romania

    SciTech Connect (OSTI)

    K. J. Allen; I. Bolshinsky; L. L. Biro; M. E. Budu; N. V. Zamfir; M. Dragusin

    2010-07-01

    Romania safely air shipped 23.7 kilograms of Russian origin highly enriched uranium (HEU) spent nuclear fuel from the VVR S research reactor at Magurele, Romania, to the Russian Federation in June 2009. This was the world’s first air shipment of spent nuclear fuel transported in a Type B(U) cask under existing international laws without special exceptions for the air transport licenses. This shipment was coordinated by the Russian Research Reactor Fuel Return Program (RRRFR), part of the U.S. Department of Energy Global Threat Reduction Initiative (GTRI), in cooperation with the Romania National Commission for Nuclear Activities Control (CNCAN), the Horia Hulubei National Institute of Physics and Nuclear Engineering (IFIN-HH), and the Russian Federation State Corporation Rosatom. The shipment was transported by truck to and from the respective commercial airports in Romania and the Russian Federation and stored at a secure nuclear facility in Russia where it will be converted into low enriched uranium. With this shipment, Romania became the 3rd country under the RRRFR program and the 14th country under the GTRI program to remove all HEU. This paper describes the work, equipment, and approvals that were required to complete this spent fuel air shipment.

  6. Augmenting Traditional Static Analysis With Commonly Available Metadata

    SciTech Connect (OSTI)

    Cook, Devin

    2015-05-10

    Developers and security analysts have been using static analysis for a long time to analyze programs for defects and vulnerabilities with some success. Generally a static analysis tool is run on the source code for a given program, flagging areas of code that need to be further inspected by a human analyst. These areas may be obvious bugs like potential bu er over flows, information leakage flaws, or the use of uninitialized variables. These tools tend to work fairly well - every year they find many important bugs. These tools are more impressive considering the fact that they only examine the source code, which may be very complex. Now consider the amount of data available that these tools do not analyze. There are many pieces of information that would prove invaluable for finding bugs in code, things such as a history of bug reports, a history of all changes to the code, information about committers, etc. By leveraging all this additional data, it is possible to nd more bugs with less user interaction, as well as track useful metrics such as number and type of defects injected by committer. This dissertation provides a method for leveraging development metadata to find bugs that would otherwise be difficult to find using standard static analysis tools. We showcase two case studies that demonstrate the ability to find 0day vulnerabilities in large and small software projects by finding new vulnerabilities in the cpython and Roundup open source projects.

  7. Iron Complexes for the Electrocatalytic Oxidation of Hydrogen: Tuning Primary and Secondary Coordination Spheres

    SciTech Connect (OSTI)

    Darmon, Jonathan M.; Raugei, Simone; Liu, Tianbiao L.; Hulley, Elliott B.; Weiss, Charles J.; Bullock, R. Morris; Helm, Monte L.

    2014-04-04

    A series of iron hydride complexes featuring PRNR'PR (PRNR'PR = R2PCH2N(R')CH2PR2 where R = Ph, R' = Me; R = Et, R' = Ph, Bn, Me, tBu) and cyclopentadienyl (CpX = C5H4X where X = H, C5F4N) ligands has been synthesized, characterized by NMR spectroscopy, X-ray diffraction and cyclic voltammetry, and examined by quantum chemistry calculations. Each compound was tested for the electrocatalytic oxidation of H2 and the most active complex, (CpC5F4N)Fe(PEtNMePEt)(H), exhibited a turnover frequency of 8.6 s-1 at 1 atm of H2 with an overpotential of 0.41 V, as measured from the half peak potential of the catalytic wave. Control complexes that do not contain pendant amine groups were also prepared and characterized, but no catalysis was observed. This work demonstrates the importance of the pendant amine in facilitating heterolytic H2 cleavage and subsequent proton movement necessary for electrocatalytic H2 oxidation. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  8. Electrochemistry in neutral ambient-temperature ionic liquids. 1. Studies of iron (III), neodymium (III), and lithium(I)

    SciTech Connect (OSTI)

    Osteryoung, R.A.

    1985-01-01

    An ambient-temperature neutral ionic liquid composed of aluminum chloride and either N-1-butylpyridinium or 1-methyl-3-ethylimidazolium chloride, BuPyCl or ImCl, respectively, was employed in studies that take advantage of their unusual properties. These include an extended electrochemical window, readily controlled additions of excess chloride (base) or aluminum chloride (acid), and the fact that the physical properties of the neutral melt do not change about the 1:1 mole ratio of AlCl/sub 3/ to RCl. Li/sup +/ was found to be reducible in the neutral AlCl/sub 3/-ImCl melt, and its diffusion coefficient was found to be .00000086 sq cm/s. The stoichiometry of the complex formed between Nd(III) and Cl/sup +/ in the molten salt system was investigated by what is essentially an amperometric titration and was found to be NdC/sub 6/(3-). The structure of the Fe(III) chloro complex that exists in basic or acidic melts just slightly varying in composition from the neutral melt was also investigated; a constant value for the diffusion coefficient-viscosity product in both systems suggests no change in structure.

  9. Efficient alkene epoxidation catalyzed by molybdenyl acetylacetonate supported on aminated UiO-66 metal−organic framework

    SciTech Connect (OSTI)

    Kardanpour, Reihaneh; Tangestaninejad, Shahram; Mirkhani, Valiollah; Moghadam, Majid; Mohammadpoor-Baltork, Iraj; Zadehahmadi, Farnaz

    2015-03-15

    Metal–organic frameworks (MOFs) containing Mo Schiff base complexes were prepared by post-synthesis method and applied as efficient catalysts in the epoxidation of alkenes with tert-BuOOH. In this manner, UiO-66-NH{sub 2} (UiO=University of Oslo) MOF was reacted with salicylaldehyde and thiophene-2-carbaldehyde to produce bidentate Schiff bases. Then, the Schiff base ligands were used for immobilization of molybdenyl acetylacetonate. These new catalysts were characterized by FT-IR, UV–vis spectroscopic techniques, X-ray diffraction (XRD), BET, inductively coupled plasma atomic emission spectroscopy (ICP-AES) and field emission scanning electron microscopy (FE-SEM). These catalytic systems showed excellent activity in the epoxidation of alkenes such as cyclic and linear ones with tert-butyl hydroperoxide (TBHP) in 1,2-dichloroethane, and reused several times without any appreciable loss of their activity. - Graphical abstract: Efficient alkene epoxidation with TBHP catalyzed by heterogeneous and reusable molybdenum base catalysts is reported. - Highlights: • UiO-66-NH{sub 2} was modified with salicylaldehyde and thiophene-2-carbaldehyde. • The Schiff base groups were used for immobilization of MoO{sub 2}(acac){sub 2}. • The heterogeneous catalysts were prepared. • The prepared catalysts were used for epoxidation of alkenes. • Compared to other catalyst, our catalysts were more efficient and forceful.

  10. Alkane functionalization at ([mu]-Oxo)diiron(III) centers

    SciTech Connect (OSTI)

    Leising, R.A.; Kim, J.; Perez, M.A.; Que, L. Jr. )

    1993-10-20

    The reactivity of ([mu]-oxo)diferric complexes with [sup t]BuOOH (TBHP) for the functionalization of alkanes in CH[sub 3]CN has been investigated as part of our efforts to model dinuclear sites in nonheme iron enzymes. [Fe[sub 2](TPA)[sub 2]O(OAc)](CIO[sub 4])[sub 3] (1) (TPA = tris(2-pyridylmethyl)amine, OAc = acetate) is an efficient catalyst for cyclohexane oxidation, affording cyclohexanol (A, 9 equiv), cyclohexanone (K, 11 equiv), and (tert-butylperoxy)cyclohexane (P, 16 equiv) in 0.25 h at ambient temperature and pressure under an argon atmosphere. The catalyst is remarkably robust, as indicated by the [sup 1]H NMR and UV-vis spectra of the reaction mixture during the catalytic reaction and by its ability to maintain its turnover efficiency with subsequent additions of oxidant. The catalytic mechanism for TBHP utilization was explored by observing the effects of varying the tripodal ligands on the ([mu]-oxo)([mu]-carboxylato)diferric catalysts and varying the bridge on Fe[sub 2]O(TPA)[sub 2] catalysts. The (A + K)/P ratio increased as the ligands became more electron donating. Solvent also played an important role in determining the partitioning of products between A + K and P, with benzonitrile favoring hydroxylated products at the expense of P and pyridine having the opposite effect. 49 refs., 2 figs., 3 tabs.

  11. Synthesis of two novel heterobimetallic cluster compounds [NEt{sub 4}]{sub 4}[MS{sub 4}Cu{sub 4}I{sub 6}] (M = Mo, W). Crystal structure of [NEt{sub 4}]{sub 4}[MoS{sub 4}Cu{sub 4}I{sub 6}

    SciTech Connect (OSTI)

    Jianping Lang; Weiyang Zhou; Xinquan Xin; Kaibei Yu

    1993-12-31

    Two new cluster compounds [NEt{sub 4}]{sub 4}[MS{sub 4}Cu{sub 4}I{sub 6}] (1:M = Mo; 2: M = W) have been obtained by the reaction of [NH{sub 4}]{sub 2}[MS{sub 4}] (M = Mo, W), CuBr, [NEt{sub 4}]I and [Bu{sup n}{sub 4}N]I in the solid state. Dark red crystals of 1 are monoclinic, space group C2/m with cell dimensions a = 29.686(6), b = 12.778(2), c = 15.308(3) {angstrom}, {beta} = 99.53(2){degrees}, Z = 4, D{sub calc} = 2.04g cm{sup {minus}3}, R = 0.052 for 4021 observed reflections. The X-ray analysis shows that four edges of the tetrahedral MoS{sup 2{minus}}{sub 4} core are coordinated by four copper atoms, giving a MoS{sub 4}Cu{sub 4} aggregate for approximate C{sub 2v} symmetry. The Mo-Cu lengths range from 2.650(2) to 2.686(1) {angstrom}. 27 refs., 4 figs., 3 tabs.

  12. Electrodeposition From Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni-S Film on Glassy Carbon

    SciTech Connect (OSTI)

    Fang, Ming; Engelhard, Mark H.; Zhu, Zihua; Helm, Monte L.; Roberts, John A.

    2014-01-03

    Films electrodeposited onto glassy carbon electrodes from acidic acetonitrile solutions of [Bu4N][Ni(bdt)2] (bdt = 1,2-benzenedithiolate) are active toward electrocatalytic hydrogen production at potentials 0.2-0.4 V positive of untreated electrodes. This activity is preserved on rinsing the electrode and transfer to fresh acid solution. X-ray photoelectron spectra indicate that the deposited material contains Ni and S. Correlations between voltammetric and spectroscopic results indicate that the deposited material is active, i.e. that catalysis is heterogeneous rather than homogeneous. Control experiments establish that obtaining the observed catalytic response requires both Ni and the 1,2 benzenedithiolate ligand to be present during deposition. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. A portion of the research was performed using EMSL, a 17 national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  13. BandelierDirections2011

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    a r k i n g M E R G E T o T o w n s it e D ia m o n d D ri v e To Sa n ta Fe T o J e m e z M ts . Co mm ut er Bu s Dr op Of f P a r k i n g M E R G E M E R G E T o T o w n s i t e D i a m o n d D r i v e T o J e m e z M t s . C o m m u t e r B u s D r o p O ff 4 To Valles Caldera National Preserve (12 miles), Jemez Springs (33 miles), and Albuquerque (88 miles) To Bandelier National Monument and White Rock DIRECTIONS TO BANDELIER 502 To Pajarito Ski Hill E A S T J E M E Z R O A D ( A L T E R N A

  14. Development of a Novel Bi-Directional Isolated Multiple-Input DC-DC Converter

    SciTech Connect (OSTI)

    Li, H.

    2005-10-24

    There is vital need for a compact, lightweight, and efficient energy-storage system that is both affordable and has an acceptable cycle life for the large-scale production of electric vehicles (EVs) and hybrid electric vehicles (HEVs). Most of the current research employs a battery-storage unit (BU) combined with a fuel cell (FC) stack in order to achieve the operating voltage-current point of maximum efficiency for the FC system. A system block diagram is shown in Fig.1.1. In such a conventional arrangement, the battery is sized to deliver the difference between the energy required by the traction drive and the energy supplied by the FC system. Energy requirements can increase depending on the drive cycle over which the vehicle is expected to operate. Peak-power transients result in an increase of losses and elevated temperatures which result in a decrease in the lifetime of the battery. This research will propose a novel two-input direct current (dc) dc to dc converter to interface an additional energy-storage element, an ultracapacitor (UC), which is shown in Fig.1.2. It will assist the battery during transients to reduce the peak-power requirements of the battery.

  15. 17O Cross Section

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    p, X) (Current as of 05/15/2012) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2010SE11 17O(p, α): nuclear excitation function 0 - 0.7 1 06/22/2011 1973RO03 17O(p, γ): γ-ray yield 0.15 - 1.4 1 08/01/2012 2015BU02 17O(p, γ): total S(E)-factors 0.17 - 0.53 X4 03/03/2016 2012SC16, 2014DI01 17O(p, γ): σ, deduced S-factors Ecm = 0.2 - 0.4 X4 03/03/2016 1973RO34 17O(p, γ): S(E) 0.3 - 1.9 S-Factor X4 06/22/2011 17O(p, γ): σ for the γ-ray transition 0.94 → 0 MeV 17O(p, γ):

  16. Optimal Control and Coordination of Connected and Automated Vehicles at Urban Traffic Intersections

    SciTech Connect (OSTI)

    Zhang, Yue J.; Malikopoulos, Andreas; Cassandras, Christos G.

    2016-01-01

    We address the problem of coordinating online a continuous flow of connected and automated vehicles (CAVs) crossing two adjacent intersections in an urban area. We present a decentralized optimal control framework whose solution yields for each vehicle the optimal acceleration/deceleration at any time in the sense of minimizing fuel consumption. The solu- tion, when it exists, allows the vehicles to cross the intersections without the use of traffic lights, without creating congestion on the connecting road, and under the hard safety constraint of collision avoidance. The effectiveness of the proposed solution is validated through simulation considering two intersections located in downtown Boston, and it is shown that coordination of CAVs can reduce significantly both fuel consumption and travel time.

  17. ASC Tri-lab Co-design Level 2 Milestone Report 2015

    SciTech Connect (OSTI)

    Hornung, Rich; Jones, Holger; Keasler, Jeff; Neely, Rob; Pearce, Olga; Hammond, Si; Trott, Christian; Lin, Paul; Vaughan, Courtenay; Cook, Jeanine; Hoekstra, Rob; Bergen, Ben; Payne, Josh; Womeldorff, Geoff

    2015-09-23

    In 2015, the three Department of Energy (DOE) National Laboratories that make up the Advanced Sci- enti c Computing (ASC) Program (Sandia, Lawrence Livermore, and Los Alamos) collaboratively explored performance portability programming environments in the context of several ASC co-design proxy applica- tions as part of a tri-lab L2 milestone executed by the co-design teams at each laboratory. The programming environments that were studied included Kokkos (developed at Sandia), RAJA (LLNL), and Legion (Stan- ford University). The proxy apps studied included: miniAero, LULESH, CoMD, Kripke, and SNAP. These programming models and proxy-apps are described herein. Each lab focused on a particular combination of abstractions and proxy apps, with the goal of assessing performance portability using those. Performance portability was determined by: a) the ability to run a single application source code on multiple advanced architectures, b) comparing runtime performance between \

  18. Low-temperature Mechanical Properties of Fe-0.06C-18Cr-10Ni-0.4Ti Austenitic Steel Determined Using Ring-Pull Tensile Tests and Microhardness Measurements

    SciTech Connect (OSTI)

    Neustroev, V. S.; Boev, E. V.; Garner, Francis A.

    2007-08-01

    Irradiated austenitic stainless steels removed from Russian water-cooled VVERs experience irradiation temperatures and He/dpa conditions that are very similar to steels to be used in ITER. Data are presented on the radiation hardening of the Russian analog of AISI 321 at 0.2 to 15 dpa in the range of 285 to 320??. The Russian variant of the ring-pull tensile test was used to obtain mechanical prop-erty data. Microhardness tests on the ring specimens provide useful information throughout the deformed regions, but at high hardening levels caution must be exercised before application of a widely accepted hardness-yield stress correla-tion to prediction of tensile properties. Low-nickel austenitic steels are very prone to form deformation martensite, a phase that increases strongly with the larger deformation levels characteristic of microhardness tests, especially when compared to the 0.2% deformation used to define yield stress.

  19. Low-Temperature Mechanical Properties Of Fe-0.06c-18cr-10ni-0.4ti Austenitic Steel Determined Using Ring-Pull Tensile Tests And Microhardness Measurements

    SciTech Connect (OSTI)

    Neustroev, V. S.; Boev, E. V.; Garner, Francis A.

    2007-03-01

    Irradiated austenitic stainless steels removed from Russian water-cooled VVERs experience irradia-tion temperatures and He/dpa conditions that are very similar to steels to be used in ITER. Data are presented on the radiation hardening of the Russian analog of AISI 321 at 0.2 to 15 dpa in the range of 285 to 320??. The Russian variant of the ring-pull tensile test was used to obtain mechanical prop-erty data. Microhardness tests on the ring specimens provide useful information throughout the de-formed regions, but at high hardening levels caution must be exercised before application of a widely accepted hardness-yield stress correlation to prediction of tensile properties. Low-nickel austenitic steels are very prone to form deformation martensite, a phase that increases strongly with the larger deformation levels characteristic of microhardness tests, especially when compared to the 0.2% de-formation used to define yield stress.

  20. P U S T O

    Office of Legacy Management (LM)

    ."<"! . , . A , * 4 04 04 b ' s- . r EYNOLD; riI,ECTRRCC& l, ENGINEERING CO., INC. P U S T O r - F I L E O O X 1 4 4 0 0 L A S V C G A S . N E V A D A 0 4 1 i 4 l~lr, D, TJ. Ileazdri clca , Dis-ecf;or Radiolo@.cnl 0por;ltinng Divio5.aiz U . S . Atonric Ekier&y Co!lxni.ssion % Nevada Opcxna-tions Office Post Office Box 14 100 La9 Vegaa , I\Jevada 6'91 14 Attention: M r . It, J, ' W 1 . l i t m . n mC)3ECT SHOAL CWLQTJP SURVEY K!FC;i'F. Dear M r . Hendricka: Attached is the

  1. Experimental Evaluation of the Free Piston Engine - Linear Alternator (FPLA).

    SciTech Connect (OSTI)

    Leick, Michael T.; Moses, Ronald W.

    2015-03-01

    This report describes the experimental evaluation of a prototype free piston engine - linear alternator (FPLA) system developed at Sandia National Laboratories. The opposed piston design wa developed to investigate its potential for use in hybrid electric vehicles (HEVs). The system is mechanically simple with two - stroke uniflow scavenging for gas exchange and timed port fuel injection for fuel delivery, i.e. no complex valving. Electrical power is extracted from piston motion through linear alternators wh ich also provide a means for passive piston synchronization through electromagnetic coupling. In an HEV application, this electrical power would be used to charge the batteries. The engine - alternator system was designed, assembled and operated over a 2 - year period at Sandia National Laboratories in Livermore, CA. This report primarily contains a description of the as - built system, modifications to the system to enable better performance, and experimental results from start - up, motoring, and hydrogen combus tion tests.

  2. Java Parallel Secure Stream for Grid Computing

    SciTech Connect (OSTI)

    Chen, Jie; Akers, Walter; Chen, Ying; Watson, William

    2001-09-01

    The emergence of high speed wide area networks makes grid computing a reality. However grid applications that need reliable data transfer still have difficulties to achieve optimal TCP performance due to network tuning of TCP window size to improve the bandwidth and to reduce latency on a high speed wide area network. This paper presents a pure Java package called JPARSS (Java Par-allel Secure Stream) that divides data into partitions that are sent over several parallel Java streams simultaneously and allows Java or Web applications to achieve optimal TCP performance in a gird environment without the necessity of tuning the TCP window size. Several experimental results are provided to show that using parallel stream is more effective than tuning TCP window size. In addi-tion X.509 certificate based single sign-on mechanism and SSL based connection establishment are integrated into this package. Finally a few applications using this package will be discussed.

  3. Print

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    GFDL GCM Model Output with ARM CMBE Dataset: A First Look Jean-Christophe Golaz, UCAR VSP, GFDL Leo J. Donner and V. Ramaswamy, Geophysical Fluid Dynamics Laboratory, Princeton, NJ U . S . D E P A R T M E NT O F C O M M E R C E N A TION A L O C E A N I C A N D A T MO S P H E R I C A D M I N I S T R ATIO N What is CMBE? - CMBE (Climate Modeling Best Estimate) is a new ARM dataset specifically designed to evaluate climate models against ARM observations. - CMBE contains best estimates of selected

  4. Evaluating System Parameters on a Dragonfly using Simulation and Visualization

    SciTech Connect (OSTI)

    Bhatele, Abhinav; Jain, Nikhil; Livnat, Yarden; Pascucci, Valerio; Bremer, Peer-Timo

    2015-04-24

    The dragon y topology is becoming a popular choice for build- ing high-radix, low-diameter networks with high-bandwidth links. Even with a powerful network, preliminary experi- ments on Edison at NERSC have shown that for communica- tion heavy applications, job interference and thus presumably job placement remains an important factor. In this paper, we explore the e ects of job placement, job sizes, parallel workloads and network con gurations on network through- put to better understand inter-job interference. We use a simulation tool called Damsel y to model the network be- havior of Edison and study the impact of various system parameters on network throughput. Parallel workloads based on ve representative communication patters are used and the simulation studies on up to 131,072 cores are aided by a new visualization of the dragon y network.

  5. In Silico Identification Software (ISIS): A Machine Learning Approach to Tandem Mass Spectral Identification of Lipids

    SciTech Connect (OSTI)

    Kangas, Lars J.; Metz, Thomas O.; Isaac, Georgis; Schrom, Brian T.; Ginovska-Pangovska, Bojana; Wang, Luning; Tan, Li; Lewis, Robert R.; Miller, John H.

    2012-05-15

    Liquid chromatography-mass spectrometry-based metabolomics has gained importance in the life sciences, yet it is not supported by software tools for high throughput identification of metabolites based on their fragmentation spectra. An algorithm (ISIS: in silico identification software) and its implementation are presented and show great promise in generating in silico spectra of lipids for the purpose of structural identification. Instead of using chemical reaction rate equations or rules-based fragmentation libraries, the algorithm uses machine learning to find accurate bond cleavage rates in a mass spectrometer employing collision-induced dissocia-tion tandem mass spectrometry. A preliminary test of the algorithm with 45 lipids from a subset of lipid classes shows both high sensitivity and specificity.

  6. Analysis of Modeling Parameters on Threaded Screws.

    SciTech Connect (OSTI)

    Vigil, Miquela S.; Brake, Matthew Robert; Vangoethem, Douglas

    2015-06-01

    Assembled mechanical systems often contain a large number of bolted connections. These bolted connections (joints) are integral aspects of the load path for structural dynamics, and, consequently, are paramount for calculating a structure's stiffness and energy dissipation prop- erties. However, analysts have not found the optimal method to model appropriately these bolted joints. The complexity of the screw geometry cause issues when generating a mesh of the model. This paper will explore different approaches to model a screw-substrate connec- tion. Model parameters such as mesh continuity, node alignment, wedge angles, and thread to body element size ratios are examined. The results of this study will give analysts a better understanding of the influences of these parameters and will aide in finding the optimal method to model bolted connections.

  7. FNCS: A Framework for Power System and Communication Networks Co-Simulation

    SciTech Connect (OSTI)

    Ciraci, Selim; Daily, Jeffrey A.; Fuller, Jason C.; Fisher, Andrew R.; Marinovici, Laurentiu D.; Agarwal, Khushbu

    2014-04-13

    This paper describes the Fenix framework that uses a federated approach for integrating power grid and communication network simulators. Compared existing approaches, Fenix al- lows co-simulation of both transmission and distribution level power grid simulators with the communication network sim- ulator. To reduce the performance overhead of time synchro- nization, Fenix utilizes optimistic synchronization strategies that make speculative decisions about when the simulators are going to exchange messages. GridLAB-D (a distribution simulator), PowerFlow (a transmission simulator), and ns-3 (a telecommunication simulator) are integrated with the frame- work and are used to illustrate the enhanced performance pro- vided by speculative multi-threading on a smart grid applica- tion. Our speculative multi-threading approach achieved on average 20% improvement over the existing synchronization methods

  8. Software-defined Quantum Communication Systems

    SciTech Connect (OSTI)

    Humble, Travis S; Sadlier, Ronald J

    2014-01-01

    Quantum communication systems harness modern physics through state-of-the-art optical engineering to provide revolutionary capabilities. An important concern for quantum communication engineering is designing and prototyping these systems to prototype proposed capabilities. We apply the paradigm of software-defined communica- tion for engineering quantum communication systems to facilitate rapid prototyping and prototype comparisons. We detail how to decompose quantum communication terminals into functional layers defining hardware, software, and middleware concerns, and we describe how each layer behaves. Using the super-dense coding protocol as a test case, we describe implementations of both the transmitter and receiver, and we present results from numerical simulations of the behavior. We find that while the theoretical benefits of super dense coding are maintained, there is a classical overhead associated with the full implementation.

  9. Microsoft Word - Panel 5 Disposal Operations Complete.docx

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    th re s c th W se lo o s e U.S. D Carls Waste P.O. B Carls CARL hat disposa epository ar hipment wa "All T redit for this heir dedicat Waste Mana The W even dispo ong and can f the 6.2 m igned in 19 With d quivalent o Department bad Field Of e Isolation P Box 3090 bad, New M DOE in P LSBAD, N.M al operation re complete as emplace RU waste m s accomplis tion to perfo agement Pr WIPP unde sal rooms. n hold appr illion cubic 992, has be disposal op of about fou of Energy ffice Pilot Plant

  10. A review of macroscopic ductile failure criteria.

    SciTech Connect (OSTI)

    Corona, Edmundo; Reedlunn, Benjamin

    2013-09-01

    The objective of this work was to describe several of the ductile failure criteria com- monly used to solve practical problems. The following failure models were considered: equivalent plastic strain, equivalent plastic strain in tension, maximum shear, Mohr- Coulomb, Wellman's tearing parameter, Johnson-Cook and BCJ MEM. The document presents the main characteristics of each failure model as well as sample failure predic- tions for simple proportional loading stress histories in three dimensions and in plane stress. Plasticity calculations prior to failure were conducted with a simple, linear hardening, J2 plasticity model. The resulting failure envelopes were plotted in prin- cipal stress space and plastic strain space, where the dependence on stress triaxiality and Lode angle are clearly visible. This information may help analysts select a ductile fracture model for a practical problem and help interpret analysis results.

  11. Technology Solutions Case Study: Insulated Siding Retrofit in a Cold Climate

    SciTech Connect (OSTI)

    2015-05-01

    In this study, the U.S. Department of Energy’s team Building America Partner¬ship for Improved Residential Construction (BA-PIRC) worked with Kinsley Construction Company to evaluate the real-world performance of insulated sid¬ing when applied to an existing home. A 1960s home was selected for analysis. It is located in a cold climate (zone 6) where the addition of insulated siding and a carefully detailed water-resistive barrier have the potential to offer significant benefits. In particular, the team quantified building airtightness and heating energy use as a function of outdoor temperatures before and after the installa¬tion of the insulated siding.

  12. URANIUM DECONTAMINATION

    DOE Patents [OSTI]

    Buckingham, J.S.; Carroll, J.L.

    1959-12-22

    A process is described for reducing the extractability of ruthenium, zirconium, and niobium values into hexone contained in an aqueous nitric acid uranium-containing solution. The solution is made acid-deficient, heated to between 55 and 70 deg C, and at that temperature a water-soluble inorganic thiosulfate is added. By this, a precipitate is formed which carries the bulk of the ruthenium, and the remainder of the ruthenium as well as the zirconium and niobium are converted to a hexone-nonextractable form. The rutheniumcontaining precipitate can either be removed from the solu tion or it can be dissolved as a hexone-non-extractable compound by the addition of sodium dichromate prior to hexone extraction.

  13. DOE

    Gasoline and Diesel Fuel Update

    DOE /E/A- 0202( 83//Q J Sh or t-T er m En er gy O ut lo ok a to m Quar terly Proje ction s Febru ary 1983 Ene rgy Info rma tion Adm inist ratio n Was hing ton, D.C. t rt jrt .or t lor t lor t .lor t- ior t- ior t <.o rt ort . m .er m -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -Te rm -T erm -T erm -T erm Nrm ue rgy En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En erg y En

  14. LANL: AOT & LANSCE The Pulse December 2010

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    10 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 lANsCe-Ns hosts NNsA ACADemiC AlliANCe CeNter oF exCelleNCe leADer 4 Workshop oN isotope hArvestiNg At the FACility For rAre isotope BeAms iN situ ChArACterizA- tioN oF multiphAse polymeriC mAteriAls upoN DeFormAtioN 5 NeutroN sCAtteriNg reveAls the AtomiC motioN iN A NeW ClAss oF CerAmiC- metAl mAteriAls

  15. LANL: AOT & LANSCE The Pulse June 2011

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 CollAborAtion meeting on Fission meAsurements mAjewski to give leC- tures CommemorAting AnniversAry oF mArie Curie's nobel Prize 4 CholerA toxin binDing to moDel membrAnes reveAls PotentiAl signAling PAthwAy neutron DiFFrAC- tion stuDy oF γ-ChymotryPsin At the Protein CrystAllog- rAPhy stAtion 5 heADs uP!

  16. LANL: AOT & LANSCE The Pulse November 2009

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    9 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 Vogel receiVes lANsce Director's excelleNce AwArD 2 AccelerAtor struc- ture DeVelopmeNt AND thiN coAtiNg oN Niobium sAmples 3 NANogrAiNs DemoN- strAte extrAorDiNAry thermAl stAbility 3 competitiVe ADsorp- tioN of luNg surfAc- tANt AND AlbumiN 4 heADs up! For more than 15 years, Yusheng Zhao has been on a scientifc journey

  17. LANL: AOT & LANSCE The Pulse November 2010

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    10 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 First beAm tests with the time Projection chAmber 4 Discovery oF new Phys- ics in leAD-zirconium- titAnium voltAge bArs 5 los AlAmos lenDs its exPertise to cleAn energy AnD cArbon sequestrAtion Projects 6 electric-FielD moDiFicA- tion oF mAgnetism in A thin Film 7 Aot & lAnsce Division stAFF AwArDeD

  18. A Reduced Order Model of Force Displacement Curves for the Failure of Mechanical Bolts in Tension.

    SciTech Connect (OSTI)

    Moore, Keegan J.; Brake, Matthew Robert

    2015-12-01

    Assembled mechanical systems often contain a large number of bolted connections. These bolted connections (joints) are integral aspects of the load path for structural dynamics, and, consequently, are paramount for calculating a structure's stiffness and energy dissipation prop- erties. However, analysts have not found the optimal method to model appropriately these bolted joints. The complexity of the screw geometry causes issues when generating a mesh of the model. This report will explore different approaches to model a screw-substrate connec- tion. Model parameters such as mesh continuity, node alignment, wedge angles, and thread to body element size ratios are examined. The results of this study will give analysts a better understanding of the influences of these parameters and will aide in finding the optimal method to model bolted connections.

  19. Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx

    SciTech Connect (OSTI)

    Xiong, F.; McAvey, Kevin; Pratt, Kerri A.; Groff, C. J.; Hostetler, M. A.; Lipton, M. A.; Starn, T. K.; Seeley, J. V.; Bertman, Steven; Teng, A. P.; Crounse, J. D.; Nguyen, Tran B.; Wennberg, P. O.; Misztal, Pawel K.; Goldstein, Allen H.; Guenther, Alex B.; Koss, A.; Olson, K. F.; de Gouw, J. A.; Baumann, K.; Edgerton, Eric S.; Feiner, P. A.; Zhang, L.; Miller, D. O.; Brune, W. H.; Shepson, Paul B.

    2015-10-09

    Isoprene hydroxynitrates (IN) are tracers of the photochemical oxidation of isoprene in high NOx environ-ments. Production and loss of IN have a significant influ-ence on the NOx cycle and tropospheric O3 chemistry. To better understand IN chemistry, a series of photochemical re-action chamber experiments was conducted to determine the IN yield from isoprene photooxidation at high NO concentra-tions (> 100 ppt). By combining experimental data and cal-culated isomer distributions, a total IN yield of 9(+4/-3) %was derived. The result was applied in a zero-dimensional model to simulate production and loss of ambient IN ob-served in a temperate forest atmosphere, during the Southern Oxidant and Aerosol Study (SOAS) field campaign, from 27 May to 11 July 2013. The 9 % yield was consistent with the observed IN/(MVK+MACR) ratios observed during SOAS. By comparing field observations with model simulations, we identified NO as the limiting factor for ambient IN produc-tion during SOAS, but vertical mixing at dawn might also contribute (~ 27 %) to IN dynamics. A close examination of isoprene’s oxidation products indicates that its oxidation transitioned from a high-NO dominant chemical regime in the morning into a low-NO dominant regime in the after-noon. A significant amount of IN produced in the morning high NO regime could be oxidized in the low NO regime, and a possible reaction scheme was proposed.

  20. Methodology for Preliminary Design of Electrical Microgrids

    SciTech Connect (OSTI)

    Jensen, Richard P.; Stamp, Jason E.; Eddy, John P.; Henry, Jordan M; Munoz-Ramos, Karina; Abdallah, Tarek

    2015-09-30

    Many critical loads rely on simple backup generation to provide electricity in the event of a power outage. An Energy Surety Microgrid TM can protect against outages caused by single generator failures to improve reliability. An ESM will also provide a host of other benefits, including integration of renewable energy, fuel optimization, and maximizing the value of energy storage. The ESM concept includes a categorization for microgrid value proposi- tions, and quantifies how the investment can be justified during either grid-connected or utility outage conditions. In contrast with many approaches, the ESM approach explic- itly sets requirements based on unlikely extreme conditions, including the need to protect against determined cyber adversaries. During the United States (US) Department of Defense (DOD)/Department of Energy (DOE) Smart Power Infrastructure Demonstration for Energy Reliability and Security (SPIDERS) effort, the ESM methodology was successfully used to develop the preliminary designs, which direct supported the contracting, construction, and testing for three military bases. Acknowledgements Sandia National Laboratories and the SPIDERS technical team would like to acknowledge the following for help in the project: * Mike Hightower, who has been the key driving force for Energy Surety Microgrids * Juan Torres and Abbas Akhil, who developed the concept of microgrids for military installations * Merrill Smith, U.S. Department of Energy SPIDERS Program Manager * Ross Roley and Rich Trundy from U.S. Pacific Command * Bill Waugaman and Bill Beary from U.S. Northern Command * Melanie Johnson and Harold Sanborn of the U.S. Army Corps of Engineers Construc- tion Engineering Research Laboratory * Experts from the National Renewable Energy Laboratory, Idaho National Laboratory, Oak Ridge National Laboratory, and Pacific Northwest National Laboratory

  1. Final Report: Large-Scale Optimization for Bayesian Inference in Complex Systems

    SciTech Connect (OSTI)

    Ghattas, Omar

    2013-10-15

    The SAGUARO (Scalable Algorithms for Groundwater Uncertainty Analysis and Robust Optimiza- tion) Project focuses on the development of scalable numerical algorithms for large-scale Bayesian inversion in complex systems that capitalize on advances in large-scale simulation-based optimiza- tion and inversion methods. Our research is directed in three complementary areas: efficient approximations of the Hessian operator, reductions in complexity of forward simulations via stochastic spectral approximations and model reduction, and employing large-scale optimization concepts to accelerate sampling. Our efforts are integrated in the context of a challenging testbed problem that considers subsurface reacting flow and transport. The MIT component of the SAGUARO Project addresses the intractability of conventional sampling methods for large-scale statistical inverse problems by devising reduced-order models that are faithful to the full-order model over a wide range of parameter values; sampling then employs the reduced model rather than the full model, resulting in very large computational savings. Results indicate little effect on the computed posterior distribution. On the other hand, in the Texas-Georgia Tech component of the project, we retain the full-order model, but exploit inverse problem structure (adjoint-based gradients and partial Hessian information of the parameter-to- observation map) to implicitly extract lower dimensional information on the posterior distribution; this greatly speeds up sampling methods, so that fewer sampling points are needed. We can think of these two approaches as "reduce then sample" and "sample then reduce." In fact, these two approaches are complementary, and can be used in conjunction with each other. Moreover, they both exploit deterministic inverse problem structure, in the form of adjoint-based gradient and Hessian information of the underlying parameter-to-observation map, to achieve their speedups.

  2. Study of new states in visible light active W, N co-doped TiO{sub 2} photo catalyst

    SciTech Connect (OSTI)

    Sajjad, Ahmed Khan Leghari; Shamaila, Sajjad; Zhang, Jinlong

    2012-11-15

    Highlights: ? Visible light efficient W, N co-doped TiO{sub 2} photo catalysts are prepared by solgel. ? Oxygen vacancies are detected in the form of new linkages as N-Ti-O, N-W-O, Ti-O-N and W-O-N. ? W, N co-doped titania has new energy states which narrows the band gap effectively. ? Oxygen vacancies are proved to be the cause for high photo catalytic activity. ? W and N co-doping plays the major role to make the composite thermally stable. -- Abstract: The visible light efficient W, N co-doped TiO{sub 2} photo catalysts are prepared by solgel method. New linkages of N, W and O are formed as N-Ti-O, N-W-O, Ti-O-N and W-O-N. Electron paramagnetic resonance illustrates the presence of oxygen vacancies in W, N co-doped TiO{sub 2} acting as trapping agencies for electrons to produce active species. X-ray photoelectron spectroscopy confirms the presence of new energy states. New linkages and oxygen vacancies are proved to be the main cause for the improved photo catalytic performances. W, N co-doped TiO{sub 2} has new energy states which narrow the band gap effectively. W, N co-doped TiO{sub 2} is thermally stable and retains its anatase phase up to 900 C. 4.5% W, N co-doped TiO{sub 2} showed superior activity for the degradation of Rhodamine B and 2,4-dichlorophenol as compared to pure titania, Degussa P-25, traditional N-doped TiO{sub 2} and pure WO{sub 3}.

  3. NSRD-06. Computational Capability to Substantiate DOE-HDBK-3010 Data

    SciTech Connect (OSTI)

    Louie, David L.Y.; Brown, Alexander L.

    2015-12-01

    Safety basis analysts throughout the U.S. Department of Energy (DOE) complex rely heavily on the information provided in the DOE Hand book, DOE-HDBK-3010, Airborne Release Fractions/Rates and Resp irable Fractions for Nonreactor Nuclear Facilities , to determine source terms. In calcula ting source terms, analysts tend to use the DOE Handbook's bounding values on airbor ne release fractions (ARFs) and respirable fractions (RFs) for various cat egories of insults (representing potential accident release categories). This is typica lly due to both time constraints and the avoidance of regulatory critique. Unfort unately, these bounding ARFs/RFs represent extremely conservative values. Moreover, th ey were derived from very limited small- scale table-top and bench/labo ratory experiments and/or fr om engineered judgment. Thus the basis for the data may not be re presentative to the actual unique accident conditions and configura tions being evaluated. The goal of this res earch is to develop a more ac curate method to identify bounding values for the DOE Handbook using the st ate-of-art multi-physics-based high performance computer codes. This enable s us to better understand the fundamental physics and phenomena associated with the ty pes of accidents for the data described in it. This research has examined two of the DOE Handbook's liquid fire experiments to substantiate the airborne release frac tion data. We found th at additional physical phenomena (i.e., resuspension) need to be included to derive bounding values. For the specific cases of solid powder under pre ssurized condition and mechanical insult conditions the codes demonstrated that we can simulate the phenomena. This work thus provides a low-cost method to establis h physics-justified sa fety bounds by taking into account specific geometri es and conditions that may not have been previously measured and/or are too costly to do so.

  4. LANDSCAPE MANAGEMENT FOR SUSTAINABLE SUPPLIES OF BIOENERGY FEEDSTOCK AND ENHANCED SOIL QUALITY

    SciTech Connect (OSTI)

    Douglas L. Karlen; David J. Muth, Jr.

    2012-09-01

    yields are less than 11 Mg ha-1 (175 bu ac-1) unless more intensive landscape management practices are implemented. Furthermore, although non-irrigated corn grain yields east and west of the primary Corn Belt may not consistently achieve the 11 Mg ha-1 yield levels, corn can still be part of an overall landscape approach for sustainable feedstock production. Another option for producers with consistently high yields (> 12.6 Mg ha-1 or 200 bu ac-1) that may enable them to sustainably harvest even more stover is to decrease their tillage intensity which will reduce fuel use, preserve rhizosphere carbon, and/or help maintain soil structure and soil quality benefits often attributed to no-till production systems. In conclusion, I challenge all ISTRO scientists to critically ask if your research is contributing to improved soil and crop management strategies that effectively address the complexity associated with sustainable food, feed, fiber and fuel production throughout the world.

  5. A faux hawk fullerene with PCBM-like properties

    SciTech Connect (OSTI)

    San, Long K.; Bukovsky, Eric V.; Larson, Bryon W.; Whitaker, James B.; Deng, Shihu; Kopidakis, Nikos; Rumbles, Garry; Popov, Alexey A.; Chen, Yu-Sheng; Wang, Xue B.; Boltalina, Olga V.; Strauss, Steven H.

    2014-12-16

    Reaction of C60, C6F5CF2I, and SnH(n-Bu)3 produced, among other unidentified fullerene derivatives, the two new compounds 1,9-C60(CF2C6F5)H (1) and 1,9-C60(cyclo-CF2(2-C6F4)) (2). The highest isolated yield of 1 was 35% based on C60. Depending on the reaction conditions, the relative amounts of 1 and 2 generated in situ were as high as 85% and 71%, respectively, based on HPLC peak integration and summing over all fullerene species present other than unreacted C60. Compound 1 is thermally stable in 1,2-dichlorobenzene (oDCB) at 160 °C but was rapidly converted to 2 upon addition of Sn2(n-Bu)6 at this temperature. In contrast, complete conversion of 1 to 2 occurred within minutes, or hours, at 25 °C in 90/10 (v/v) PhCN/C6D6 by addition of stoichiometric, or sub-stoichiometric, amounts of proton sponge (PS) or cobaltocene (CoCp2). DFT calculations indicate that when 1 is deprotonated, the anion C60(CF2C6F5)- can undergo facile intramolecular SNAr annulation to form 2 with concomitant loss of F-. To our knowledge this is the first observation of a fullerene-cage carbanion acting as an SNAr nucleophile towards an aromatic C–F bond. The gas-phase electron affinity (EA) of 2 was determined to be 2.805(10) eV by low-temperature PES, higher by 0.12(1) eV than the EA of C60 and higher by 0.18(1) eV than the EA of phenyl-C61-butyric acid methyl ester (PCBM). In contrast, the relative E1/2(0/-) values of 2 and C60, -0.01(1) and 0.00(1) V, respectively, are virtually the same (on this scale, and under the same conditions, the E1/2(0/-) of PCBM is -0.09 V). Time-resolved microwave conductivity charge-carrier yield x mobility values for organic

  6. A faux hawk fullerene with PCBM-like properties

    SciTech Connect (OSTI)

    San, Long K.; Bukovsky, Eric V.; Larson, Bryon W.; Whitaker, James B.; Deng, S. H.M.; Kopidakis, Nikos; Rumbles, Garry; Popov, Alexey A.; Chen, Yu-Sheng; Wang, Xue-Bin; Boltalina, Olga V.; Strauss, Steven H.

    2014-12-16

    Reaction of C60, C6F5CF2I, and SnH(n-Bu)3 produced, among other unidentified fullerene derivatives, the two new compounds 1,9-C60(CF2C6F5)H (1) and 1,9-C60(cyclo-CF2(2-C6F4)) (2). The highest isolated yield of 1 was 35% based on C60. Depending on the reaction conditions, the relative amounts of 1 and 2 generated in situ were as high as 85% and 71%, respectively, based on HPLC peak integration and summing over all fullerene species present other than unreacted C60. Compound 1 is thermally stable in 1,2-dichlorobenzene (oDCB) at 160 °C but was rapidly converted to 2 upon addition of Sn2(n-Bu)6 at this temperature. In contrast, complete conversion of 1 to 2 occurred within minutes, or hours, at 25 °C in 90/10 (v/v) PhCN/C6D6 by addition of stoichiometric, or sub-stoichiometric, amounts of proton sponge (PS) or cobaltocene (CoCp2). DFT calculations indicate that when 1 is deprotonated, the anion C60(CF2C6F5)- can undergo facile intramolecular SNAr annulation to form 2 with concomitant loss of F-. To our knowledge this is the first observation of a fullerene-cage carbanion acting as an SNAr nucleophile towards an aromatic C–F bond. The gas-phase electron affinity (EA) of 2 was determined to be 2.805(10) eV by low-temperature PES, higher by 0.12(1) eV than the EA of C60 and higher by 0.18(1) eV than the EA of phenyl-C61-butyric acid methyl ester (PCBM). In contrast, the relative E1/2(0/-) values of 2 and C60, -0.01(1) and 0.00(1) V, respectively, are virtually the same (on this scale, and under the same conditions, the E1/2(0/-) of PCBM is -0.09 V). Time-resolved microwave conductivity charge-carrier yield × mobility values for organic photovoltaic active-layer-type blends

  7. A faux hawk fullerene with PCBM-like properties

    DOE PAGES-Beta [OSTI]

    San, Long K.; Bukovsky, Eric V.; Larson, Bryon W.; Whitaker, James B.; Deng, S. H.M.; Kopidakis, Nikos; Rumbles, Garry; Popov, Alexey A.; Chen, Yu-Sheng; Wang, Xue-Bin; et al

    2014-12-16

    Reaction of C60, C6F5CF2I, and SnH(n-Bu)3 produced, among other unidentified fullerene derivatives, the two new compounds 1,9-C60(CF2C6F5)H (1) and 1,9-C60(cyclo-CF2(2-C6F4)) (2). The highest isolated yield of 1 was 35% based on C60. Depending on the reaction conditions, the relative amounts of 1 and 2 generated in situ were as high as 85% and 71%, respectively, based on HPLC peak integration and summing over all fullerene species present other than unreacted C60. Compound 1 is thermally stable in 1,2-dichlorobenzene (oDCB) at 160 °C but was rapidly converted to 2 upon addition of Sn2(n-Bu)6 at this temperature. In contrast, complete conversion ofmore » 1 to 2 occurred within minutes, or hours, at 25 °C in 90/10 (v/v) PhCN/C6D6 by addition of stoichiometric, or sub-stoichiometric, amounts of proton sponge (PS) or cobaltocene (CoCp2). DFT calculations indicate that when 1 is deprotonated, the anion C60(CF2C6F5)- can undergo facile intramolecular SNAr annulation to form 2 with concomitant loss of F-. To our knowledge this is the first observation of a fullerene-cage carbanion acting as an SNAr nucleophile towards an aromatic C–F bond. The gas-phase electron affinity (EA) of 2 was determined to be 2.805(10) eV by low-temperature PES, higher by 0.12(1) eV than the EA of C60 and higher by 0.18(1) eV than the EA of phenyl-C61-butyric acid methyl ester (PCBM). In contrast, the relative E1/2(0/-) values of 2 and C60, -0.01(1) and 0.00(1) V, respectively, are virtually the same (on this scale, and under the same conditions, the E1/2(0/-) of PCBM is -0.09 V). Time-resolved microwave conductivity charge-carrier yield × mobility values for organic photovoltaic active-layer-type blends of 2 and poly-3-hexylthiophene (P3HT) were comparable to those for equimolar blends of PCBM and P3HT. The structure of solvent-free crystals of 2 was determined by single-crystal X-ray diffraction. The number of nearest-neighbor fullerene–fullerene interactions with centroid

  8. A faux hawk fullerene with PCBM-like properties

    DOE PAGES-Beta [OSTI]

    San, Long K.; Bukovsky, Eric V.; Larson, Bryon W.; Whitaker, James B.; Deng, Shihu; Kopidakis, Nikos; Rumbles, Garry; Popov, Alexey A.; Chen, Yu-Sheng; Wang, Xue B.; et al

    2014-12-16

    Reaction of C60, C6F5CF2I, and SnH(n-Bu)3 produced, among other unidentified fullerene derivatives, the two new compounds 1,9-C60(CF2C6F5)H (1) and 1,9-C60(cyclo-CF2(2-C6F4)) (2). The highest isolated yield of 1 was 35% based on C60. Depending on the reaction conditions, the relative amounts of 1 and 2 generated in situ were as high as 85% and 71%, respectively, based on HPLC peak integration and summing over all fullerene species present other than unreacted C60. Compound 1 is thermally stable in 1,2-dichlorobenzene (oDCB) at 160 °C but was rapidly converted to 2 upon addition of Sn2(n-Bu)6 at this temperature. In contrast, complete conversion ofmore » 1 to 2 occurred within minutes, or hours, at 25 °C in 90/10 (v/v) PhCN/C6D6 by addition of stoichiometric, or sub-stoichiometric, amounts of proton sponge (PS) or cobaltocene (CoCp2). DFT calculations indicate that when 1 is deprotonated, the anion C60(CF2C6F5)- can undergo facile intramolecular SNAr annulation to form 2 with concomitant loss of F-. To our knowledge this is the first observation of a fullerene-cage carbanion acting as an SNAr nucleophile towards an aromatic C–F bond. The gas-phase electron affinity (EA) of 2 was determined to be 2.805(10) eV by low-temperature PES, higher by 0.12(1) eV than the EA of C60 and higher by 0.18(1) eV than the EA of phenyl-C61-butyric acid methyl ester (PCBM). In contrast, the relative E1/2(0/-) values of 2 and C60, -0.01(1) and 0.00(1) V, respectively, are virtually the same (on this scale, and under the same conditions, the E1/2(0/-) of PCBM is -0.09 V). Time-resolved microwave conductivity charge-carrier yield x mobility values for organic photovoltaic active-layer-type blends of 2 and poly-3-hexylthiophene (P3HT) were comparable to those for equimolar blends of PCBM and P3HT. The structure of solvent-free crystals of 2 was determined by single-crystal X-ray diffraction. The number of nearest-neighbor fullerene–fullerene interactions with centroid

  9. A primer for criticality calculations with DANTSYS

    SciTech Connect (OSTI)

    Busch, R.D.

    1997-08-01

    With the closure of many experimental facilities, the nuclear safety analyst has to rely on computer calculations to identify safe limits for the handling and storage of fissile materials. Although deterministic methods often do not provide exact models of a system, a substantial amount of reliable information on nuclear systems can be obtained using these methods if the user understands their limitations. To guide criticality specialists in this area, the Nuclear Criticality Safety Group at the University of New Mexico (UNM) in cooperation with the Radiation Transport Group at Los Alamos National Laboratory (LANL) has designed a primer to help the analyst understand and use the DANTSYS deterministic transport code for nuclear criticality safety analyses. DANTSYS is the new name of the group of codes formerly known as: ONEDANT, TWODANT, TWOHEX, TWOGQ, and THREEDANT. The primer is designed to teach bu example, with each example illustrating two or three DANTSYS features useful in criticality analyses. Starting with a Quickstart chapter, the primer gives an overview of the basic requirements for DANTSYS input and allows the user to quickly run a simple criticality problem with DANTSYS. Each chapter has a list of basic objectives at the beginning identifying the goal of the chapter and the individual DANTSYS features covered in detail in the chapter example problems. On completion of the primer, it is expected that the user will be comfortable doing criticality calculations with DANTSYS and can handle 60--80% of the situations that normally arise in a facility. The primary provides a set of input files that can be selective modified by the user to fit each particular problem.

  10. De novo synthesis and properties of analogues of the self-assembling chlorosomal bacteriochlorophylls

    SciTech Connect (OSTI)

    Mass, Olga [North Carolina State Univ., Raleigh, NC (United States); Pandithavidana, Dinesh R. [North Carolina State Univ., Raleigh, NC (United States); Ptaszek, Marcin [North Carolina State Univ., Raleigh, NC (United States); Santiago, Koraliz [North Carolina State Univ., Raleigh, NC (United States); Springer, Joseph W. [Washington Univ., St. Louis, MO (United States); Jiao, Jieying [Univ. Of California, Riverside, CA (United States); Tang, Qun [Univ. Of California, Riverside, CA (United States); Kirmaier, Christine [Washington Univ., St. Louis, MO (United States); Bocian, David F. [Univ. Of California, Riverside, CA (United States); Holten, Dewey [Washington Univ., St. Louis, MO (United States); Lindsey, Jonathan S. [North Carolina State Univ., Raleigh, NC (United States)

    2011-01-01

    Natural photosynthetic pigments bacteriochlorophyllsc, d and e in green bacteria undergo self-assembly to create an organized antenna system known as the chlorosome, which collects photons and funnels the resulting excitation energy toward the reaction centers. Mimicry of chlorosome function is a central problem in supramolecular chemistry and artificial photosynthesis, and may have relevance for the design of photosynthesis-inspired solar cells. The main challenge in preparing artificial chlorosomes remains the synthesis of the appropriate pigment (chlorin) equipped with a set of functional groups suitable to direct the assembly and assure efficient energy transfer. Prior approaches have entailed derivatization of porphyrins or semisynthesis beginning with chlorophylls. This paper reports a third approach, the de novo synthesis of macrocycles that contain the same hydrocarbon skeleton as chlorosomal bacteriochlorophylls. The synthesis here of Zn(II) 3-(1-hydroxyethyl)-10-aryl-13-oxophorbines (the aryl group consists of phenyl, mesityl, or pentafluorophenyl) entails selective bromination of a 3,13-diacetyl-10-arylchlorin, palladium-catalyzed 13-oxophorbine formation, and selective reduction of the 3-acetyl group using BH?tBuNH?. Each macrocycle contains a geminal dimethyl group in the pyrroline ring to provide stability toward adventitious dehydrogenation. A Zn(II) 7-(1-hydroxyethyl)-10-phenyl-17-oxochlorin also has been prepared. Altogether, 30 new hydroporphyrins were synthesized. The UV-Vis absorption spectra of the new chlorosomal bacteriochlorophyll mimics reveal a bathochromic shift of [similar]1800 cm-1 of the Qy band in nonpolar solvent, indicating extensive assembly in solution. The Zn(II) 3-(1-hydroxyethyl)-10-aryl-13-oxophorbines differ in the propensity to form assemblies based on the 10-substituent in the following order: mesityl

  11. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  12. AIR SHIPMENT OF HIGHLY ENRICHED URANIUM SPENT NUCLEAR FUEL FROM ROMANIA AND LIBYA

    SciTech Connect (OSTI)

    Christopher Landers; Igor Bolshinsky; Ken Allen; Stanley Moses

    2010-07-01

    In June 2009 Romania successfully completed the world’s first air shipment of highly enriched uranium (HEU) spent nuclear fuel transported in Type B(U) casks under existing international laws and without special exceptions for the air transport licenses. Special 20-foot ISO shipping containers and cask tiedown supports were designed to transport Russian TUK 19 shipping casks for the Romanian air shipment and the equipment was certified for all modes of transport, including road, rail, water, and air. In December 2009 Libya successfully used this same equipment for a second air shipment of HEU spent nuclear fuel. Both spent fuel shipments were transported by truck from the originating nuclear facilities to nearby commercial airports, were flown by commercial cargo aircraft to a commercial airport in Yekaterinburg, Russia, and then transported by truck to their final destinations at the Production Association Mayak facility in Chelyabinsk, Russia. Both air shipments were performed under the Russian Research Reactor Fuel Return Program (RRRFR) as part of the U.S. National Nuclear Security Administration (NNSA) Global Threat Reduction Initiative (GTRI). The Romania air shipment of 23.7 kg of HEU spent fuel from the VVR S research reactor was the last of three HEU fresh and spent fuel shipments under RRRFR that resulted in Romania becoming the 3rd RRRFR participating country to remove all HEU. Libya had previously completed two RRRFR shipments of HEU fresh fuel so the 5.2 kg of HEU spent fuel air shipped from the IRT 1 research reactor in December made Libya the 4th RRRFR participating country to remove all HEU. This paper describes the equipment, preparations, and license approvals required to safely and securely complete these two air shipments of spent nuclear fuel.

  13. Organometallic complexes of bulky, optically active, C3-symmetric tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*)

    DOE PAGES-Beta [OSTI]

    Xu, Songchen; Magoon, Yitzhak; Reinig, Regina R.; Schmidt, Bradley M.; Ellern, Arkady; Sadow, Aaron D.

    2015-07-16

    A bulky, optically active monoanionic scorpionate ligand, tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*), is synthesized from the naturally occurring amino acid l-valine as its lithium salt, Li[ToP*] (1). That compound is readily converted to the thallium complex Tl[ToP*] (2) and to the acid derivative H[ToP*] (3). Group 7 tricarbonyl complexes ToP*M(CO)3 (M = Mn (4), Re (5)) are synthesized by the reaction of MBr(CO)5 and Li[ToP*] and are crystallographically characterized. The νCO bands in their infrared spectra indicate that π back-donation in the rhenium compounds is greater with ToP* than with non-methylated tris(4S-isopropyl-2-oxazolinyl)phenylborate (ToP). The reaction of H[ToP*] and ZnEt2 gives ToP*ZnEt (6), whilemore » ToP*ZnCl (7) is synthesized from Li[ToP*] and ZnCl2. The reaction of ToP*ZnCl and KOtBu followed by addition of PhSiH3 provides the zinc hydride complex ToP*ZnH (8). In this study, compound 8 is the first example of a crystallographically characterized optically active zinc hydride. We tested its catalytic reactivity in the cross-dehydrocoupling of silanes and alcohols, which provided Si-chiral silanes with moderate enantioselectivity.« less

  14. Organometallic complexes of bulky, optically active, C3-symmetric tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*)

    SciTech Connect (OSTI)

    Xu, Songchen; Magoon, Yitzhak; Reinig, Regina R.; Schmidt, Bradley M.; Ellern, Arkady; Sadow, Aaron D.

    2015-07-16

    A bulky, optically active monoanionic scorpionate ligand, tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*), is synthesized from the naturally occurring amino acid l-valine as its lithium salt, Li[ToP*] (1). That compound is readily converted to the thallium complex Tl[ToP*] (2) and to the acid derivative H[ToP*] (3). Group 7 tricarbonyl complexes ToP*M(CO)3 (M = Mn (4), Re (5)) are synthesized by the reaction of MBr(CO)5 and Li[ToP*] and are crystallographically characterized. The νCO bands in their infrared spectra indicate that π back-donation in the rhenium compounds is greater with ToP* than with non-methylated tris(4S-isopropyl-2-oxazolinyl)phenylborate (ToP). The reaction of H[ToP*] and ZnEt2 gives ToP*ZnEt (6), while ToP*ZnCl (7) is synthesized from Li[ToP*] and ZnCl2. The reaction of ToP*ZnCl and KOtBu followed by addition of PhSiH3 provides the zinc hydride complex ToP*ZnH (8). In this study, compound 8 is the first example of a crystallographically characterized optically active zinc hydride. We tested its catalytic reactivity in the cross-dehydrocoupling of silanes and alcohols, which provided Si-chiral silanes with moderate enantioselectivity.

  15. Air Shipment of Spent Nuclear Fuel from Romania to Russia

    SciTech Connect (OSTI)

    Igor Bolshinsky; Ken Allen; Lucian Biro; Alexander Buchelnikov

    2010-10-01

    Romania successfully completed the world’s first air shipment of spent nuclear fuel transported in Type B(U) casks under existing international laws and without shipment license special exceptions when the last Romanian highly enriched uranium (HEU) spent nuclear fuel was transported to the Russian Federation in June 2009. This air shipment required the design, fabrication, and licensing of special 20 foot freight containers and cask tiedown supports to transport the eighteen TUK 19 shipping casks on a Russian commercial cargo aircraft. The new equipment was certified for transport by road, rail, water, and air to provide multi modal transport capabilities for shipping research reactor spent fuel. The equipment design, safety analyses, and fabrication were performed in the Russian Federation and transport licenses were issued by both the Russian and Romanian regulatory authorities. The spent fuel was transported by truck from the VVR S research reactor to the Bucharest airport, flown by commercial cargo aircraft to the airport at Yekaterinburg, Russia, and then transported by truck to the final destination in a secure nuclear facility at Chelyabinsk, Russia. This shipment of 23.7 kg of HEU was coordinated by the Russian Research Reactor Fuel Return Program (RRRFR), as part of the U.S. Department of Energy Global Threat Reduction Initiative (GTRI), in close cooperation with the Rosatom State Atomic Energy Corporation and the International Atomic Energy Agency, and was managed in Romania by the National Commission for Nuclear Activities Control (CNCAN). This paper describes the planning, shipment preparations, equipment design, and license approvals that resulted in the safe and secure air shipment of this spent nuclear fuel.

  16. Highly alloyed stainless steels for sea water applications

    SciTech Connect (OSTI)

    Audouard, J.P.; Verneau, M.

    1996-10-01

    Natural sea water is known as a very aggressive environment which generates pitting and crevice corrosion on stainless steels. High chromium grades with sufficient molybdenum and nitrogen additions (PREN > 40) are generally recognized as resistant materials in natural sea water bu the material selection criteria must be improved to take into account the effect of climatic conditions and of biocide treatments which are widely used as anti-fouling agents in sea water circuits. The paper deals with the localized corrosion properties of conventional stainless steels (SS), duplex and superaustenitic alloys. The results of laboratory investigations conducted in more or less oxidizing chloride containing media are discussed. Then, immersion tests carried out in natural sea waters in different climatic conditions are presented and discussed. Finally, the effect of biocide addition on fouling and its consequences on corrosion is investigated. The results are interpreted taking into account the chemical composition of the stainless steels and biofilm criteria. The results showed the Mediterranean Sea to be slightly more aggressive than other European seas but a PREN value higher than 40 is sufficient for stainless steels to withstand localized corrosion in European natural sea waters. A residual chlorine level around 0.3--0.4 ppm was found to be very effective to limit the fouling and to avoid localized corrosion on SS. Nevertheless, due to difficulties in monitoring chlorine addition, PREN values higher than 50 are recommended to withstand localized corrosion in treated sea waters. As an example, the new super-austenitic grade 25Cr-22Ni-5.8Mo-1.5Cu-2W-0.45N with a PRENW value of 54 was found to be perfectly resistant to crevice corrosion with 0.5 ppm free chlorine at ambient temperature.

  17. Synthesis and structural characterization of [eta superscript 3]-allyl([alpha]-diimine)nickel(II) complexes bearing trimethylsilyl groups

    SciTech Connect (OSTI)

    Ionkin, Alex S.; Marshall, William J.

    2012-02-10

    A set of isomeric para- and meta-trimethylsilylphenyl ortho-substituted N,N-phenyl {alpha}-diimine ligands [(Ar-N C(Me)-(Me)C N-Ar) Ar=2,6-di(4-trimethylsilylphenyl)phenyl (16); Ar=2,6-di(3-trimethylsilylphenyl)phenyl (17)] have been synthesized through a two-step procedure. The palladium-catalyzed cross-coupling reaction between 2,6-dibromophenylamine (7) and 4-trimethylsilylphenylboronic acid (8), 3-trimethylsilylphenylboronic acid (9) was used to prepare 4,4-bis(trimethylsilyl)-[1,1;3,1]terphenyl-2-ylamine (10) and 3,3-bis(trimethylsilyl)-[1,1;3,1]terphenyl-2-ylamine (11). The di-1-adamantylphosphine oxide Ad{sub 2}P(O)H (13) and di-tert-butyl-trimethylsilylanylmethylphosphine tert-Bu{sub 2}P-CH{sub 2}-SiMe{sub 3} (14) were used for the first time as ligands for the Suzuki coupling. The condensation of 2,2,3,3-tetramethoxybutane (15) with anilines 10 and 11 afforded {alpha}-diimines 16 and 17. The reaction of {pi}-allylnickel chloride dimer (18), {alpha}-diimines (16), (17) and sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BAF) (19) or silver hexafluoroantimonate (20) led to two sets of isomeric complexes [{eta}{sup 3}-allyl(Ar-N C(Me)-(Me)C N-Ar)Ni]{sup +} X{sup -}, [Ar=2,6-di(4-trimethylsilylphenyl)phenyl, X=BAF (3), X=SbF6 (4); Ar=2,6-di(3-trimethylsilylphenyl)phenyl, X=BAF (5), X=SbF6 (6)]. The steric repulsion of closely positioned trimethylsilyl groups in 4 caused the distortion of the nickel square planar coordination by 17.6{sup o} according to X-ray analysis.

  18. Efficient Aho-Corasick String Matching on Emerging Multicore Architectures

    SciTech Connect (OSTI)

    Tumeo, Antonino; Villa, Oreste; Secchi, Simone; Chavarría-Miranda, Daniel

    2013-12-12

    String matching algorithms are critical to several scientific fields. Beside text processing and databases, emerging applications such as DNA protein sequence analysis, data mining, information security software, antivirus, ma- chine learning, all exploit string matching algorithms [3]. All these applica- tions usually process large quantity of textual data, require high performance and/or predictable execution times. Among all the string matching algorithms, one of the most studied, especially for text processing and security applica- tions, is the Aho-Corasick algorithm. 1 2 Book title goes here Aho-Corasick is an exact, multi-pattern string matching algorithm which performs the search in a time linearly proportional to the length of the input text independently from pattern set size. However, depending on the imple- mentation, when the number of patterns increase, the memory occupation may raise drastically. In turn, this can lead to significant variability in the performance, due to the memory access times and the caching effects. This is a significant concern for many mission critical applications and modern high performance architectures. For example, security applications such as Network Intrusion Detection Systems (NIDS), must be able to scan network traffic against very large dictionaries in real time. Modern Ethernet links reach up to 10 Gbps, and malicious threats are already well over 1 million, and expo- nentially growing [28]. When performing the search, a NIDS should not slow down the network, or let network packets pass unchecked. Nevertheless, on the current state-of-the-art cache based processors, there may be a large per- formance variability when dealing with big dictionaries and inputs that have different frequencies of matching patterns. In particular, when few patterns are matched and they are all in the cache, the procedure is fast. Instead, when they are not in the cache, often because many patterns are matched and the caches are

  19. A spectral analysis of the domain decomposed Monte Carlo method for linear systems

    SciTech Connect (OSTI)

    Slattery, Stuart R.; Evans, Thomas M.; Wilson, Paul P. H.

    2015-09-08

    The domain decomposed behavior of the adjoint Neumann-Ulam Monte Carlo method for solving linear systems is analyzed using the spectral properties of the linear oper- ator. Relationships for the average length of the adjoint random walks, a measure of convergence speed and serial performance, are made with respect to the eigenvalues of the linear operator. In addition, relationships for the effective optical thickness of a domain in the decomposition are presented based on the spectral analysis and diffusion theory. Using the effective optical thickness, the Wigner rational approxi- mation and the mean chord approximation are applied to estimate the leakage frac- tion of random walks from a domain in the decomposition as a measure of parallel performance and potential communication costs. The one-speed, two-dimensional neutron diffusion equation is used as a model problem in numerical experiments to test the models for symmetric operators with spectral qualities similar to light water reactor problems. We find, in general, the derived approximations show good agreement with random walk lengths and leakage fractions computed by the numerical experiments.

  20. A spectral analysis of the domain decomposed Monte Carlo method for linear systems

    DOE PAGES-Beta [OSTI]

    Slattery, Stuart R.; Evans, Thomas M.; Wilson, Paul P. H.

    2015-09-08

    The domain decomposed behavior of the adjoint Neumann-Ulam Monte Carlo method for solving linear systems is analyzed using the spectral properties of the linear oper- ator. Relationships for the average length of the adjoint random walks, a measure of convergence speed and serial performance, are made with respect to the eigenvalues of the linear operator. In addition, relationships for the effective optical thickness of a domain in the decomposition are presented based on the spectral analysis and diffusion theory. Using the effective optical thickness, the Wigner rational approxi- mation and the mean chord approximation are applied to estimate the leakagemore » frac- tion of random walks from a domain in the decomposition as a measure of parallel performance and potential communication costs. The one-speed, two-dimensional neutron diffusion equation is used as a model problem in numerical experiments to test the models for symmetric operators with spectral qualities similar to light water reactor problems. We find, in general, the derived approximations show good agreement with random walk lengths and leakage fractions computed by the numerical experiments.« less