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Sample records for bryan mound brine

  1. Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report

    SciTech Connect

    Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

    1981-01-01

    On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

  2. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect

    Not Available

    1993-09-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  3. Shrimp and redfish studies, bryan mound brine disposal site off Freeport, Texas, 1979-1981. Volume IV. Interview sampling survey of shrimp catch and effort. Technical memo

    SciTech Connect

    Johnson, M.F.

    1981-06-01

    An interview sampling survey of shrimp catch and fishing effort was conducted at specified ports along the Texas coast to strengthen the information base required to determine the effect of the disposal of brine from the Bryan Mound salt dome off Freeport, Texas on commercial brown shrimp (Penaeus aztecus) and white shrimp (Penaeus setiferus) populations in the Gulf of Mexico. The data recorded included port number, vessel name, official vessel number, shrimp dealer number, date of landing, area fished, depth of capture, days fished, and pounds of shrimp caught by species and size categories.

  4. Sulphur Extraction at Bryan Mound

    SciTech Connect

    Kirby, Carolyn L; Lord, Anna C. Snider

    2015-08-01

    The Bryan Mound caprock was subjected to extens ive sulphur mining prior to the development of the Strategic Petroleum Reserve. Undoubtedl y, the mining has modified the caprock integrity. Cavern wells at Bryan Mound have been subject to a host of well integr ity concerns with many likely compromised by the cavernous capro ck, surrounding corrosive environment (H 2 SO 4 ), and associated elevated residual temperatures al l of which are a product of the mining activities. The intent of this study was to understand the sulphur mining process and how the mining has affected the stability of the caprock and how the compromised caprock has influenced the integrity of the cavern wells. After an extensiv e search to collect pert inent information through state agencies, literature sear ches, and the Sandia SPR librar y, a better understanding of the caprock can be inferred from the knowledge gaine d. Specifically, the discovery of the original ore reserve map goes a long way towards modeling caprock stability. In addition the gained knowledge of sulphur mining - subs idence, superheated corrosive wa ters, and caprock collapse - helps to better predict the post mi ning effects on wellbore integrity. This page intentionally left blank

  5. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect

    Hann, R.W. Jr.; Randall, R.E.

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analysis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  6. EIS-0001: Strategic Petroleum Reserve, Bryan Mound Salt Dome, Brazoria County, Texas

    Energy.gov [DOE]

    The Strategic Petroleum Reserve prepared this SEIS to address the environmental impacts of construction and operation of two types of brine disposal systems and a new water supply system. This EIS supplements FES 76/77-6, Bryan Mound Storage Site.

  7. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. ...

    Office of Scientific and Technical Information (OSTI)

    Title: Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. The U.S. Strategic Petroleum Reserve implemented the first stage of a leach plan in 2011-2012 to expand storage ...

  8. Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site

    Office of Energy Efficiency and Renewable Energy (EERE)

    On September 13, 2011, a recently-hired, untrained subcontractor employee struck three large elevated pipes while operating a front deck mower at the Cavern 5 area of the Strategic Petroleum Reserve Bryan Mound (SPR-BM) site.

  9. Strategic Petroleum Reserve (SPR) additional geologic site characterization studies, Bryan Mound Salt Dome, Texas

    SciTech Connect

    Neal, J.T.; Magorian, T.R.; Ahmad, S.

    1994-11-01

    This report revises the original report that was published in 1980. Some of the topics covered in the earlier report were provisional and it is now practicable to reexamine them using new or revised geotechnical data and that obtained from SPR cavern operations, which involves 16 new caverns. Revised structure maps and sections show interpretative differences as compared with the 1980 report and more definition in the dome shape and caprock structural contours, especially a major southeast-northwest trending anomalous zone. The original interpretation was of westward tilt of the dome, this revision shows a tilt to the southeast, consistent with other gravity and seismic data. This interpretation refines the evaluation of additional cavern space, by adding more salt buffer and allowing several more caverns. Additional storage space is constrained on this nearly full dome because of low-lying peripheral wetlands, but 60 MMBBL or more of additional volume could be gained in six or more new caverns. Subsidence values at Bryan Mound are among the lowest in the SPR system, averaging about 11 mm/yr (0.4 in/yr), but measurement and interpretation issues persist, as observed values are about the same as survey measurement accuracy. Periodic flooding is a continuing threat because of the coastal proximity and because peripheral portions of the site are at elevations less than 15 ft. This threat may increase slightly as future subsidence lowers the surface, but the amount is apt to be small. Caprock integrity may be affected by structural features, especially the faulting associated with anomalous zones. Injection wells have not been used extensively at Bryan Mound, but could be a practicable solution to future brine disposal needs. Environmental issues center on the areas of low elevation that are below 15 feet above mean sea level: the coastal proximity and lowland environment combined with the potential for flooding create conditions that require continuing surveillance.

  10. Conversion of the Bryan Mound geological site characterization reports to a three-dimensional model.

    SciTech Connect

    Stein, Joshua S.; Rautman, Christopher Arthur

    2005-04-01

    The Bryan Mound salt dome, located near Freeport, Texas, is home to one of four underground crude oil-storage facilities managed by the U. S. Department of Energy Strategic Petroleum Reserve (SPR) Program. Sandia National Laboratories, as the geotechnical advisor to the SPR, conducts site-characterization investigations and other longer-term geotechnical and engineering studies in support of the program. This report describes the conversion of two-dimensional geologic interpretations of the Bryan Mound site into three-dimensional geologic models. The new models include the geometry of the salt dome, the surrounding sedimentary units, mapped faults, and the 20 oil-storage caverns at the site. This work provides an internally consistent geologic model of the Bryan Mound site that can be used in support of future work.

  11. Offshore oceanographic and environmental monitoring services for the Strategic Petroleum Reserve. Volume I. Appendices. Annual report for the Bryan Mound Site, September 1982-August 1983

    SciTech Connect

    1984-03-01

    The Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging brine into the coastal waters offshore of Freeport, Texas on March 10, 1980. This report describes the findings of a team of Texas A and M University scientists and engineers who have conducted a study to evaluate the effects of the Bryan Mound brine discharge on the marine environment. The study addresses the areas of physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos and data management. It focuses on the period from September 1982 through August 1983. The ambient physical environment and its temporal and spatial variability were studied by means of continuously recording in situ current/conductivitiy/temperature meters and twelve, one-day synoptic hydrographic cruises. The quarterly water and sediment quality data show a small increase in salinity, sodium and chloride ions occurs in the bottom waters and sediment pore waters near the diffuser relative to those values measured at stations farther away. Data from the brine plume study for this reporting study show the largest areal extent within the +1 o/oo above ambient salinity contour was 40.0 km/sup 2/ which occurred on August 11, 1983. It appears that brine disposal at Bryan Mound has had neglible if any influence on the nekton community surrounding the diffuser. The benthic quarterly data from 26 stations, including 7 collections made after the diffuser outflow rate was increased to 1,000,000 barrels/day, show the total numbers of species at the diffuser station were higher than most other nearfield stations as well as many farfield stations in both the pre- and post-1,000,000 barrels/day brine flow periods. 138 references, 175 figures, 53 tables.

  12. Chemistry and mineralogy of samples from the strategic petroleum reserve Bryan Mound site

    SciTech Connect

    Bild, R. W.

    1980-08-01

    The goal of the Strategic Petroleum Reserve (SPR) program is to protect the United States from a temporary cutoff of imported crude oil by stockpiling a reserve of oil in caverns in Gulf Coast salt domes. Some suitable caverns already exist as a result of solution mining activities by commercial mining companies. Most of the caverns for the program, however, will be solution mined specifically for the SPR program. The tasks assigned to Sandia National Laboratories include conducting a geotechnical program and providing interim technical support for the leaching of the first five caverns in the Bryan Mound, Texas, salt dome. This report describes chemical, mineralogical and petrological work done at Sandia as of May 1, 1980 in support of Bryan Mound activities. Samples of Bryan Mound salt cores, sidewall samples and drill cuttings have been subjected to chemical, mineralogical and petrographic analysis. Halite (NaCl) was the major mineral in all samples with anhydrite (CaSO/sub 4/) a common accessory. Minor or trace sylvite (KCl) and quartz (SiO/sub 2/) were detected in some sidewall samples. Other minor minerals found in drill cuttings included quartz; mixed carbonates of Fe, Ca and Mg; and several iron oxides. Possibly the carbonates are reaction products with the basic drilling mud or possibly pieces of caprock which contaminated the cuttings. The iron oxides were probably produced by corrosion of the drill stem or bit. Densities of several core samples were determined and insoluble residue was counted for radioactivity.

  13. A. Lawrence Bryan, Jr.

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    to the ecology, behavior and conservation of Wood Storks, including foraging ... Conservation Biology 14:414-419. Snodgrass, J.W., C.H. Jagoe, A.L. Bryan, Jr., H.A. Brant, ...

  14. Bryan Fry | Photosynthetic Antenna Research Center

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Bryan Fry Bryan Fry Bryan Fry Graduate Student E-mail: bryanfry@mail.med.upenn.edu Website: University of Pennsylvania Graduate...

  15. Bryan Hannegan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Bryan Hannegan About Us Bryan Hannegan - Associate Lab Director, Energy Systems Integration, at the National Renewable Energy Laboratory Most Recent Energy Systems Integration Facility Delivering on Promise to Strengthen America's Clean Energy Innovation September 1

  16. Bryan Wheeler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Bryan Wheeler About Us Bryan Wheeler - Intern, Office of Science Bryan Wheeler was an intern in the Energy Department's Office of Science in the summer of 2011. He is currently a student at Johns Hopkins University Most Recent Maximizing Potential of Diesel and Gasoline for a Cleaner, More Efficient Engine September 27

  17. Rice, Bryan Joseph

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The (4)He(gamma,dd) reaction at E(gamma) = 150--250 MeV Rice, Bryan Joseph ProQuest Dissertations and Theses; 1998; ProQuest Dissertations & Theses (PQDT) pg. n/a Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with

  18. Paul Bryan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Bryan About Us Paul Bryan - Biomass Program Manager, Office of Energy Efficiency & Renewable Energy Paul Bryan is Program Manager for the Office of Energy Efficiency and Renewable Energy's Biomass Program. Most Recent Producing Clean, Renewable Diesel from Biomass November 30 The How's and Why's of Replacing the Whole Barrel October 19 Billion-Ton Update: Home-Grown Energy Resources Across the Nation August 1

  19. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. ...

    Office of Scientific and Technical Information (OSTI)

    sonar surveys in order to aid in the analysis and offer projections of likely outcomes ... Sponsoring Org: USDOE National Nuclear Security Administration (NNSA) Country of ...

  20. William Bryan, OE-30 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    William Bryan, OE-30 About Us William Bryan, OE-30 - Deputy Assistant Secretary, Infrastructure Security & Energy Restoration Mr. Bryan is the Deputy Assistant Secretary for Infrastructure Security and Energy Restoration in the U.S. Department of Energy's (DOE) Office of Electricity Delivery and Energy Reliability (OE). The office of Infrastructure Security and Energy Restoration (ISER) works with the National Security Staff, other U.S. government agencies, and international partners to

  1. Lightning strike at Bryan, Ohio

    SciTech Connect

    Nichols, B. E.

    1980-02-01

    A week before the 29 August 1979 dedication of the photovoltaic power system at daytime AM radio station WBNO, in Bryan, Ohio, a lightning superbolt struck the FM radio tower, one of two towers at the station. Minor damage to the station and to components of the photovoltaic system, the latter designed by MIT Lincoln Laboratory under US Department of Energy sponsorship, is described. This rare strike suggested the need for increased protection and more voltage-transient suppressors were added to those already in place as a preventive measure in the event that such a phenomenon reoccurs.

  2. Bryan County, Georgia: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Number 2 Climate Zone Subtype A. Places in Bryan County, Georgia Pembroke, Georgia Richmond Hill, Georgia Retrieved from "http:en.openei.orgwindex.php?titleBryanCounty,Ge...

  3. Bryan Texas Utilities- SmartHOME Program

    Energy.gov [DOE]

    The Bryan Texas Utilities (BTU) SmartHOME Programs offers incentives to owners of single- and multi-family homes for insulation, windows, and solar screens.The incentive amount may not be less than...

  4. City of Bryan, Texas (Utility Company) | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Texas (Utility Company) Jump to: navigation, search Name: City of Bryan Place: Texas Phone Number: (979) 821-5700 Website: www.btutilities.com Twitter: @CityofBryan Facebook:...

  5. Dr. Bryan Hannegan - Associate Laboratory Director, Energy Systems

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Integration | NREL Bryan Hannegan - Associate Laboratory Director, Energy Systems Integration A photo of Bryan Hannegan In this role, Bryan Hannegan leads NREL's global initiative to optimize links between electricity, fuel, thermal, water, and communication networks in order to enable a more sustainable society. Prior to joining NREL, Hannegan held several research leadership positions in fossil energy, renewable energy, and environmental science and technology at the Electric Power

  6. Monsanto MOUND FACILITY

    Office of Legacy Management (LM)

    Monsanto . MOUND FACILITY Operated for the United States Department of Energy March 26, 1981 Dr. William E. Mott, Director Environmental and Safety Engineering Division U. S. ...

  7. CX-009718: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Brine Disposal System Header to Bryan Mound Brine Tank, GFE CX(s) Applied: B1.3 Date: 12/11/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  8. Mound Supports Galileo

    SciTech Connect

    Monsanto Research Corporation

    1986-01-01

    This video describes the invention of Radioisotope Thermoelectric Generators (RTGs) at Mound Laboratory, and radioisotope heat source production from 1 watt-thermal to 2400 watts-thermal. RTGs have been used in many space vehicles, but the RTG built for the Galileo mission to orbit Jupiter is the largest. This RTG unit will produce 4400 watts-thermal and convert to 300 watts-electric. The plutonium-238 heat source assembly and test at Mound is described. The RTGs are tested under simulated mission conditions. The RTG leakage radiation is carefully measured for background compensation for on-board radiation monitoring instruments.

  9. Mound, Ohio, Site Fact Sheet

    Office of Legacy Management (LM)

    Mound, Ohio, Site This fact sheet provides information about the Mound, Ohio, Site. These sites are managed by the U.S. Department of Energy Office of Legacy Management under the Comprehensive Environmental Response, Compensation, and Liability Act. Location of the Mound, Ohio, Site Site Description and History The Mound site 1 in Miamisburg, Ohio, named for a nearby Native American burial ground, is located approximately 10 miles southwest of Dayton, Ohio. The Great Miami River fows southwest

  10. Mound publications for 1991

    SciTech Connect

    Nowka, Stephen L.

    1992-05-01

    This document is a compilation of all Mound formal technical publications and oral presentations for calendar year 1991. It is intended to serve as an aid to personnel in obtaining or referring to specific publications by giving the proper complete reference for each information item published during the year. Some items, such as proceedings publications, may have issue dates or periods of coverage prior to 1991; however, they were formally published during 1991.

  11. Mound facility physical characterization

    SciTech Connect

    Tonne, W.R.; Alexander, B.M.; Cage, M.R.; Hase, E.H.; Schmidt, M.J.; Schneider, J.E.; Slusher, W.; Todd, J.E.

    1993-12-01

    The purpose of this report is to provide a baseline physical characterization of Mound`s facilities as of September 1993. The baseline characterizations are to be used in the development of long-term future use strategy development for the Mound site. This document describes the current missions and alternative future use scenarios for each building. Current mission descriptions cover facility capabilities, physical resources required to support operations, current safety envelope and current status of facilities. Future use scenarios identify potential alternative future uses, facility modifications required for likely use, facility modifications of other uses, changes to safety envelope for the likely use, cleanup criteria for each future use scenario, and disposition of surplus equipment. This Introductory Chapter includes an Executive Summary that contains narrative on the Functional Unit Material Condition, Current Facility Status, Listing of Buildings, Space Plans, Summary of Maintenance Program and Repair Backlog, Environmental Restoration, and Decontamination and Decommissioning Programs. Under Section B, Site Description, is a brief listing of the Site PS Development, as well as Current Utility Sources. Section C contains Site Assumptions. A Maintenance Program Overview, as well as Current Deficiencies, is contained within the Maintenance Program Chapter.

  12. CX-011223: Categorical Exclusion Determination

    Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement (Install) CX(s) Applied: B5.2 Date: 10/28/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  13. CX-010711: Categorical Exclusion Determination

    Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  14. EIS-0014: Mound Facility, Miamisburg, Ohio

    Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to assess the environmental implications of its continuing and future programs at the Mound Facility (formerly designated Mound Laboratory), located in Miamisburg, Ohio.

  15. Viscous heavy brines

    SciTech Connect

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  16. Microsoft Word - 20110322_MoundNotice.docx

    Office of Legacy Management (LM)

    Legal Notice for Mound Site 2011 CERCLA Five-Year Review has been removed from the LM website. This document is outdated and no longer neededrequired...

  17. Thickened heavy brines

    SciTech Connect

    House, R.F.; Hoover, L.D.

    1983-12-13

    A thickened brine solution useful as a well servicing fluid is prepared, said solution consisting essentially of water, at least 20% by weight zinc bromide, calcium bromide, and a viscosifying amount of hydroxyethyl cellulose.

  18. Mound Site Community Involvement Plan 2012

    Office of Legacy Management (LM)

    Involvement Plan for the U.S. Department of Energy Mound, Ohio, Site January 2015 LMS/MND/S02885-0.0 This page intentionally left blank U.S. Department of Energy Mound Community Involvement Plan January 2015 Doc. No. S02885-0.0 Page i Contents Abbreviations .................................................................................................................................. ii 1.0 Purpose and Introduction

  19. Brine stability study

    SciTech Connect

    Gary Garland

    2015-04-15

    This is a study of the brine formulations that we were using in our testing were stable over time. The data includes charts, as well as, all of the original data from the ICP-MS runs to complete this study.

  20. Reindustrialization Workshop Held at Mound Site

    Energy.gov [DOE]

    The U.S. Department of Energy (DOE) has partnered with local communities to determine the best reuse of land, assets, and facilities, and the Mound-site community is no exception. In May, DOE’s...

  1. DOE - Office of Legacy Management -- Mound Site

    Office of Legacy Management (LM)

    Ohio Mound, Ohio, Site Site Documents and Links All documents are Adobe Acrobat files. pdf_icon Key Documents Fact Sheet Annual Institutional Controls Report Community Involvement Plan Long-Term Surveillance and Maintenance Plan Operations and Maintenance Plan Internal Links Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Administrative Records External Links Mound Development Corporation (MDC) Ohio Environmental Protection Agency U.S. Environmental Protection

  2. Enforcement Letter, EG&G Mound Applied Technologies- August 22, 1996

    Energy.gov [DOE]

    Issued to EG&G Mound Applied Technologies related to the Inadvertent Transfer of Radiological Contamination at the Mound Plant

  3. City of Blue Mound, Kansas (Utility Company) | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Mound, Kansas (Utility Company) Jump to: navigation, search Name: City of Blue Mound Place: Kansas Phone Number: (913) 756-2447 Outage Hotline: (913) 756-2447 References: EIA Form...

  4. Mound, Ohio, Second Five-Year Review

    Office of Legacy Management (LM)

    Report Second Five-Year Review for the Mound, Ohio, Site Miamisburg, Ohio September 2006 Office of Legacy Management DOE M/1308-2006 -L Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management U.S. Department of Energy U.S. Department of Energy Mound, Ohio, Second Five-Year Review September 2006

  5. "Conflict Between Economic Growth and Environmental Protection", Dr. Bryan

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Czech, resident, Center for the Advancement of the Steady State of the Economy | Princeton Plasma Physics Lab 9, 2012, 4:15pm Colloquia MBG Auditorium "Conflict Between Economic Growth and Environmental Protection", Dr. Bryan Czech, resident, Center for the Advancement of the Steady State of the Economy Presentation: Office presentation icon Presentation Abstract: PDF icon Abstract Conflict Between Economic Growth and Environmental Protectio Colloquium Committee: The Princeton

  6. Investigation of the September 13, 2011, Fatality at the Strategic...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound ...

  7. Mound site environmental report for calendar year 1991

    SciTech Connect

    Bauer, L.R.

    1992-06-01

    Mound is a government-owned facility operated by EG&G Mound Applied Technologies for the U.S. Department of Energy (DOE). This integrated production, development, and research site performs work in support of DOE`s weapon and energy related programs, with emphasis on explosive, nuclear, and energy technology. The purpose of this report is to inform the public about the impact of Mound`s operations on the population and the environment. This report summarizes data from the Environmental Monitoring Program, through which Mound maintains continuous surveillance of radiological and nonradiological substances released from the facility.

  8. Independent technical review of the Mound Plant

    SciTech Connect

    Not Available

    1994-06-01

    This report documents an Independent Technical Review (ITR) of the facilities, organizations, plans, and activities required to transition particular elements of the Mound Plant from Defense Program (DP) funded operation as appropriate either to community developed reuse or safe deactivation leading to decontamination and decommissioning (D&D). The review was conducted at the request of the Dr. Willis Bixby, Deputy Assistant Secretary, U.S. Department of Energy EM-60, Office of Facility Transition and Management and is a consensus of the nine member ITR Team. Information for the review was drawn from documents provided to the ITR Team by the Miamisburg Area Office (MB) of the DOE, EG&G, the City of Miamisburg, and others; and from presentations, discussions, interviews, and facility inspections at the Mound Plant during the weeks of March 14 and March 28, 1994. During the week of April 25, 1994, the ITR Team met at Los Alamos, New Mexico to develop consensus recommendations. A presentation of the core recommendations was made at the Mound Plant on May 5, 1994. This is an independent assessment of information available to, and used by, the Mound Plant personnel. Repetition of the information is not meant to imply discovery by the ITR Team. Team members, however, acting as independent reviewers, frequently assess the information from a perspective that differs significantly from that of the Mound Plant personnel. The report is based on information obtained and conditions observed during the March 1994 review interval. The ITR process and normal site work often initiate rapid, beneficial changes in understanding and organization immediately following the review. These changes frequently alter conditions observed during the review, but the report does not address changes subsequent to the review interval.

  9. Mound site environmental report for calendar year 1992

    SciTech Connect

    Bauer, L.R.

    1993-07-01

    The purpose of this report is to inform the public about the impact of Mound operations on the population and the environment. Mound is a government-owned facility operated by EG&G Mound Applied Technologies for the US Department of Energy (DOE). This integrated production, development, and research site performs work in support of DOE`s weapon and energy related programs, with emphasis on explosive, nuclear and energy technologies.

  10. DOE - Office of Legacy Management -- Mound_Benefits

    Office of Legacy Management (LM)

    Ohio > Mound_Benefits Mound, Ohio, Site Former Workers' Employment Verification and Benefits Administration Contractor Employment Verification Mercer, Mound Benefits Center (866) 296-5036 Medical and Life Insurance for Former EG&G, BWXTO, and CH2M HILL Employees For questions about health insurance coverage and/or dependent information, life insurance and/or beneficiaries, etc.: Mound Benefits Center P.O. Box 10361 Des Moines, IA 50306-0361 Benefit Center Website (866) 296-5036 9:00 a.m.

  11. Mound Museum Volunteers: Preserving a Laboratory’s Legacy

    Energy.gov [DOE]

    The Mound Science and Energy Museum (MSEM) owes its success to dedicated volunteers and supporters. The MSEM currently has 40 active volunteers and 200 dues-paying members.

  12. Miamisburg Mound Community Improvement Corp | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    finances; Manufacturing; Research and development; Trainining and education;Other:Economic Development Phone Number: 937-865-4462 Website: www.mound.com...

  13. Renewed Importance of the Mound Site Annual Institutional Controls...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Annual, routine IC inspections are conducted at many LM sites. However, inspections at the Mound site are anything but routine, due to its unique nature. 1862.jpg Collaboration ...

  14. Enforcement Letter-Mound-08/22/1996

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy (DOE) by EG&G Mound (EG&G) in the Noncompliance Tracking System (NTS). ... We also reviewed your Contamination Control Review Team investigation report which ...

  15. Gas evolution from geopressured brines

    SciTech Connect

    Matthews, C.S.

    1980-06-01

    The process of gas evolution from geopressured brine is examined using as a basis the many past studies of gas evolution from liquids in porous media. A discussion of a number of speculations that have been made concerning gas evolution from geopressured brines is provided. According to one, rapid pressure reduction will cause methane gas to evolve as when one opens a champagne bottle. It has been further speculated that evolved methane gas would migrate up to form an easily producible cap. As a result of detailed analyses, it can be concluded that methane gas evolution from geopressured brines is far too small to ever form a connected gas saturation except very near to the producing well. Thus, no significant gas cap could ever form. Because of the very low solubility of methaned in brine, the process of methane gas evolution is not at all analogous to evolution of carbon dioxide from champagne. A number of other speculations and questions on gas evolution are analyzed, and procedures for completing wells and testing geopressured brine reservoirs are discussed, with the conclusion that presently used procedures will provide adequate data to enable a good evaluation of this resource.

  16. Batteries from Brine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Batteries from Brine Batteries from Brine March 31, 2014 - 2:59pm Addthis Low-temp geothermal technologies are meeting a growing demand for strategic materials in clean manufacturing. Here, lithium is extracted from geothermal brines in California. Low-temp geothermal technologies are meeting a growing demand for strategic materials in clean manufacturing. Here, lithium is extracted from geothermal brines in California. Consumer uses of lithium batteries have soared over the last decade,

  17. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  18. CX-000482: Categorical Exclusion Determination

    Energy.gov [DOE]

    Project Number MS-09-116 - Structural Assessment of Big Hill Raw Water Intake Structure, Big Hill Brine Disposal Pump Pad and Bryan Mound Raw Water Intake StructureCX(s) Applied: B1.3Date: 12/29/2009Location(s): TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  19. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  20. Environmental assessment for Mound Plant decontamination and decommissioning projects, Mound Plant, Miamisburg, Ohio

    SciTech Connect

    1995-05-01

    The U.S. Department of Energy (DOE) has prepared an Environmental Assessment (EA) for seven decontamination and decommissioning (D&D) projects at the Mound Plant in Miamisburg, Ohio, that have not been previously addressed in the Final Environmental Impact Statement for the Mound Facility (June 1979). Based on the information presented in the EA, the DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, the preparation of an Environmental Impact Statement (EIS) is not required and the Department is issuing this Finding of No Significant Impact (FONSI).

  1. Improved Water Flooding through Injection Brine Modification

    SciTech Connect

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  2. EA-1001: Commercialization of the Mound Plant, Golden, Colorado

    Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to commercialize surplus facilities such as the U.S. Department of Energy's Mound Plant in Miamisburg, Ohio.  Commercialization will make...

  3. EA-1239: Disposition of Mound Plant's South Property, Miamisburg, Ohio

    Energy.gov [DOE]

    DOE prepared an EA for the proposed title transfer of 123 acres of land referred to as the “South Property” at the Miamisburg Environmental Management Project Mound Plant in Miamisburg, Ohio.

  4. Blue Mounds, Wisconsin: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Hide Map This article is a stub. You can help OpenEI by expanding it. Blue Mounds is a village in Dane County, Wisconsin. It falls under Wisconsin's 2nd...

  5. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    No. S07757 Page A-1 Scope: Entire Mound Site Preliminary inspections performed on: April 5 and 7, 2011 Physical Inspection Walk around on: April 12, 2011 Review led by: Art ...

  6. Renewed Importance of the Mound Site Annual Institutional Controls Assessments

    Energy.gov [DOE]

    The U.S. Department of Energy (DOE) Office of Legacy Management (LM) completed its 2014 annual institutional controls (IC) assessment of the Mound site in Miamisburg, Ohio, and confirmed that the...

  7. DOE - Office of Legacy Management -- Mound Laboratory - OH 19

    Office of Legacy Management (LM)

    U.S. Department of Energy (DOE) Office of Legacy Management (LM) is conducting the fourth ... and current Office of Legacy Management activities at the Mound Site in Miamisburg, Ohio. ...

  8. Environmental assessment for commercialization of the Mound Plant

    SciTech Connect

    Not Available

    1994-10-26

    In November 1993 US DOE decided to phase out operations at the Mound Plant in Miamisburg, Ohio, with the goal of releasing the site for commercial use. The broad concept is to transform the plant into an advanced manufacturing center with the main focus on commercializing products and other technology. DOE proposes to lease portions of the Mound Plant to commercial enterprises. This Environmental Impact statement has a finding of no significant impact in reference to such action.

  9. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    Site-Wide Institutional Controls Applied to the Former DOE Mound Site Property June 2011 LMS/MND/S07757 This page intentionally left blank LMS/MND/S07757 Annual Assessment of the Effectiveness of Site-Wide Institutional Controls Applied to the Former DOE Mound Site Property June 2011 This page intentionally left blank U.S. Department of Energy Annual Assessment of the Effectiveness of Site-Wide Institutional Controls June 2011 Doc. No. S07757 Page i Contents Abbreviations

  10. Brine disposal process for Morcinek coal mine

    SciTech Connect

    Tait, J.H.

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  11. Mounded LPG storage - Experience and developments

    SciTech Connect

    Barber, D.

    1988-01-01

    Liquefied petroleum gas (LPG) is stored after production, and for distribution and use, in pressure vessels which vary in size from a few kilogrammes to many thousands of tons. The types of LPG under consideration are commercial butane, commercial propane, or mixtures of the two gases in varying proportions. Mounded storage systems are becoming popular as an alternative to the better-known traditional systems. The most widely used and therefore best-known of the traditional systems are the above-ground pressure-vessel designs. These more commonly comprise factory-made cylinders which are installed horizontally, being supported on saddles at each end of the vessel. When such vessels are installed in an LPG terminal, depot, or filling plant, they are required in multiple units to facilitate the storage of more than one grade of product and to enable regular maintenance and inspection to be carried out. Today's safety regulations require such installations to be divided into sub-groups of six tanks, with all the tanks located at a safe distance from one another, and from other facilities in the immediate area. These safety distances are being increased as a result of experience, which means terminals now require large areas of land.

  12. Brine Migration Experimental Studies for Salt Repositories

    Office of Energy Efficiency and Renewable Energy (EERE)

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  13. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  14. Summary Results for Brine Migration Modeling Performed by LANL...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program Summary Results for Brine Migration Modeling Performed by LANL, LBNL and ...

  15. Modeling acid-gas generation from boiling chloride brines (Journal...

    Office of Scientific and Technical Information (OSTI)

    Modeling acid-gas generation from boiling chloride brines Citation Details In-Document Search Title: Modeling acid-gas generation from boiling chloride brines This study ...

  16. Raft River Geothermal Field Well Head Brine Sample

    SciTech Connect

    Tim Lanyk

    2015-12-18

    Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

  17. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems...

    Office of Scientific and Technical Information (OSTI)

    Title: TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems Deep saline formations and oil and gas reservoirs often contain concentrated brine solutions of ionic ...

  18. Environmental survey preliminary report, Mound Plant, Miamisburg, Ohio

    SciTech Connect

    Not Available

    1987-03-01

    This report presents the preliminary findings from the first phase of the Environmental Survey of the United States Department of Energy (DOE) Mound Plant, conducted August 18 through 29, 1986. The objective of the Survey is to identify environmental problems and areas of environmental risk associated with the Mound Plant. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. The on-site phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at the Mound Plant, and interviews with site personnel. The Survey found no environmental problems at the Mound Plant that represent an immediate threat to human life. The environmental problems identified at the Mound Plant by the Survey confirm that the site is confronted with a number of environmental problems which are by and large a legacy from past practices at a time when environmental problems were less well understood. Theses problems vary in terms of their magnitude and risk, as described in this report. Although the sampling and analysis performed by the Mound Plant Survey will assist in further identifying environmental problems at the site, a complete understanding of the significance of some of the environmental problems identified requires a level of study and characterization that is beyond the scope of the Survey. Actions currently under way or planned at the site, particularly the Phase II activities of the Comprehensive Environmental Analysis and Response Program (CEARP) as developed and implemented by the Albuquerque Operations Office, will contribute toward meeting this requirement. 85 refs., 24 figs., 20 tabs.

  19. How temperature and pressure affect clear brines

    SciTech Connect

    Hubbard, J.T.

    1984-04-01

    The correct application of the expansivity and compressibility of brine fluids under the influence of temperature and pressure is needed to calculate the actual hydrostatic pressure in a well. Well operations can benefit by reducing unintentional overbalance, lessening fluid losses, and lowering recommended fluid densities, hence reducing fluid costs. Since the early 1970s, the effects of temperature and pressure on the density of clear brine fluids have been questioned. As early as 1973, studies were started to define density loss with increased temperature in zinc bromide brines. This article describes a continuing study, begun in 1978, which has characterized the expansivity and compressibility of single salt brine solutions, such as are used in workover and completion fluids.

  20. Property:BrineConstituents | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Chloride type brine, "The content of potassium and calcium are high, while that of lithium, boron and sulfate is very low", See table 1 of Izquierdo et al. (2006). + Chena...

  1. Test fire environmental testing operations at Mound Applied Technologies

    SciTech Connect

    1992-03-01

    This paper describes Mound Laboratory`s environmental testing operations. The function of environmental testing is to perform quality environmental (thermal, mechanical, spin, resistance, visual) testing/conditioning of inert/explosive products to assure their compliance with specified customer acceptance criteria. Capabilities, organization, equipment specifications, and test facilities are summarized.

  2. Integrated process for coalbed brine disposal

    SciTech Connect

    Brandt, H. |; Bourcier, W.L.; Jackson, K.J.

    1994-03-01

    A brine disposal process is described that converts the brine stream of a coalbed gas producing site into clean water for agricultural use, combustion products and water vapor that can be released into the atmosphere and dry solids that can be recycled for industrial consumption. The process uses a reverse osmosis unit, a submerged combustion evaporator and a pulse combustion dryer. Pretreatment of the brine feedstream is necessary to prevent fouling of the membranes of the reverse osmosis unit and to separate from the brine stream hazardous metal and other constituents that may make the permeate from the reverse osmosis unit unsuitable for agricultural or other use. A chemical modeling code is used to calculate the saturation states of solids that may precipitate and foul the reverse osmosis membranes. Sodium carbonate is added to the brine to precipitate carbonates of Ba, Ca, Mg and Sr prior to filtration, acidification, and passage into the reverse osmosis unit. Optimization of the process in terms of types and amounts of additives is possible with analysis using the modeling code. The minimum amounts of additives to prevent scaling are calculated. In a typical operation, a brine feedstream of 1,000 m{sup 3}/day (6,290 bpd) that may have a total dissolved salt concentration (TDS) of 7,000 ppm will be separated into a permeate stream of 750 m{sup 3}/day (4,718 bpd) with a TDS of 400 ppm and a concentrated brine stream of 250 m{sup 3}/day (1,573 bpd) with a TDS of 26,800 ppm. The submerged combustion evaporator will concentrate this latter stream to a concentration of 268,000 ppm and reduce the volume to 25 m{sup 3}/day (158 bpd). The pulse combustion dryer can dry the concentrated brine mixture to a low moisture salt. Energy costs to operate the reverse osmosis unit are primarily the pumping costs.

  3. Hydrocarbon content of geopressured brines. Final report

    SciTech Connect

    Osif, T.L.

    1985-08-01

    Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

  4. Brine flow in heated geologic salt.

    SciTech Connect

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  5. Portable brine evaporator unit, process, and system

    DOEpatents

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  6. CX-004344: Categorical Exclusion Determination

    Energy.gov [DOE]

    Bryan Mound Replace Interior and Exterior Entryway to Building 201CX(s) Applied: B1.3Date: 10/13/2010Location(s): Bryan Mound, TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  7. Strategic Petroleum Reserve | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Strategic Petroleum Reserve Strategic Petroleum Reserve Crude oil pipes at SPR Bryan Mound site near Freeport, TX. Crude oil pipes at SPR Bryan Mound site near Freeport, TX. The ...

  8. Strategic Petroleum Reserve | Department of Energy

    Energy.gov [DOE] (indexed site)

    Crude oil pipes at SPR Bryan Mound site near Freeport, TX. Crude oil pipes at SPR Bryan Mound site near Freeport, TX. The Strategic Petroleum Reserve (SPR) is the world's largest...

  9. Audit of Shutdown and Transition of the Mound Plant, IG-0408 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Shutdown and Transition of the Mound Plant, IG-0408 Audit of Shutdown and Transition of the Mound Plant, IG-0408 Audit of Shutdown and Transition of the Mound Plant, IG-0408 (68.17 KB) More Documents & Publications EIS-0302: Notice of Intent to Prepare an Environmental Impact Statement EIS-0302: Withdrawal of Notice of Intent to Prepare an Environmental Impact Statement Semiannual Report to Congress: April 1 - September 30, 1997

  10. Enforcement Letter, CH2M Hill Mound, Inc- December 22, 2004

    Energy.gov [DOE]

    Issued to CH2M Hill Mound, Inc. related to a Radioactive Contamination Event during Remediation Activities at the Miamisburg Closure Project

  11. Fourth Five-Year Review for the Mound, Ohio, Site Miamisburg, Ohio

    Office of Legacy Management (LM)

    for the Mound, Ohio, Site Miamisburg, Ohio September 2016 LMS/MND/S14085 This page intentionally left blank Approved by: Five-Year Review Report Fourth Five-Year Review for the Mound, Ohio, Site Miamisburg, Ohio September 2016 ~ ~ '"-..._ ~ :~.< Susan Smiley Mound Site Manager U .S. Department of Energy Office of Legacy Management LMS/MND/S14085 Date: I I This page intentionally left blank U.S. Department of Energy Mound, Ohio, Fourth Five-Year Review September 2016 Doc. No. S14085 Page

  12. Method of removing benzene from petroleum desalter brine

    SciTech Connect

    Hart, P.R.

    1993-08-17

    A method is described for removing benzene from petroleum refinery desalter effluent brine containing dispersed oil, solids, oily solids and benzene comprising contacting the brine with a sufficient amount for the purpose of flocculating oily solids of a combination of a aluminum chlorohydrate and a water soluble cationic polymer selected from the group consisting of polyamines and dialkyldiallylammonium polymers, in a ratio of from 1:10 to 100:1 at a temperature of about 250 F, separating the resulting floc from the brine; and thereafter contacting the brine with a sufficient amount for the purpose of reducing benzene levels in the brine of an oil solvent in combination with a demulsifier.

  13. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  14. Characteristics and origin of Earth-mounds on the Eastern Snake River Plain, Idaho

    SciTech Connect

    Tullis, J.A.

    1995-09-01

    Earth-mounds are common features on the Eastern Snake River Plain, Idaho. The mounds are typically round or oval in plan view, <0.5 m in height, and from 8 to 14 m in diameter. They are found on flat and sloped surfaces, and appear less frequently in lowland areas. The mounds have formed on deposits of multiple sedimentary environments. Those studied included alluvial gravel terraces along the Big Lost River (late Pleistocene/early Holocene age), alluvial fan segments on the flanks of the Lost River Range (Bull Lake and Pinedale age equivalents), and loess/slopewash sediments overlying basalt flows. Backhoe trenches were dug to allow characterization of stratigraphy and soil development. Each mound has features unique to the depositional and pedogenic history of the site; however, there are common elements to all mounds that are linked to the history of mound formation. Each mound has a {open_quotes}floor{close_quotes} of a sediment or basement rock of significantly different hydraulic conductivity than the overlying sediment. These paleosurfaces are overlain by finer-grained sediments, typically loess or flood-overbank deposits. Mounds formed in environments where a sufficient thickness of fine-grained sediment held pore water in a system open to the migration to a freezing front. Heaving of the sediment occurred by the growth of ice lenses. Mound formation occurred at the end of the Late Pleistocene or early in the Holocene, and was followed by pedogenesis. Soils in the mounds were subsequently altered by bioturbation, buried by eolian deposition, and eroded by slopewash runoff. These secondary processes played a significant role in maintaining or increasing the mound/intermound relief.

  15. U.S. Department of Energy N N E E W W S S For Immediate Release Media Contact: Bryan Wilkes

    National Nuclear Security Administration (NNSA)

    N N E E W W S S For Immediate Release Media Contact: Bryan Wilkes October 10, 2002 (202) 586-7371 NNSA Names Tyler Przybylek as Acting Chief Operating Officer WASHINGTON, D.C. - National Nuclear Security Administration (NNSA) Acting Administrator Linton Brooks today named NNSA General Counsel Tyler Przybylek the organization's acting chief operating officer. In his new position, Przybylek will coordinate the work of the NNSA headquarters and field components, and oversee day-to-day continuity

  16. Independent Review of the July 8, 2010 Fatality at the Strategic Petroleum Reserve Bryan Mound Site- May 25, 2011 Addendum closing the Investigation based upon the Galveston County Medical Examiner's Report

    Energy.gov [DOE]

    In consultation with the Assistant Secretary for Fossil Energy (FE), the Chief Health, Safety and Security Officer appointed an Independent Review Board (IRE3) on July 20,201 0, under the provisions of the Department of Energy (DOE) Order 225.1 A, Accident Investigations, that represented a modified Type A accident investigation.

  17. EIS-0075: Strategic Petroleum Reserve Phase III Development, Texoma and Seaway Group Salt Domes (West Hackberry and Bryan Mound Expansion, Big Hill Development) Cameron Parish, Louisiana, and Brazoria and Jefferson Counties, Texas

    Energy.gov [DOE]

    Also see EIS-0021 and EIS-0029. The Strategic Petroleum Reserve (SPR) Office developed this EIS to assess the environmental impacts of expanding the existing SPR storage capacity from 538 million to 750 million barrels of storage and increasing the drawdown capability from 3.5 million to 4.5 million barrels per day. This EIS incorperates two previously issued EISs: DOE/EIS-0021, Seaway Group of Salt Domes, and DOE/EIS-0029, Texoma Group of Salt Domes.

  18. FIELD IMPLEMENTATION PLAN FOR A WILLISTON BASIN BRINE EXTRACTION AND

    Office of Scientific and Technical Information (OSTI)

    STORAGE TEST (Other) | SciTech Connect Other: FIELD IMPLEMENTATION PLAN FOR A WILLISTON BASIN BRINE EXTRACTION AND STORAGE TEST Citation Details In-Document Search Title: FIELD IMPLEMENTATION PLAN FOR A WILLISTON BASIN BRINE EXTRACTION AND STORAGE TEST The Energy & Environmental Research Center (EERC) successfully completed all technical work of Phase I, including development of a field implementation plan (FIP) for a brine extraction and storage test (BEST) in the North Dakota portion

  19. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  20. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  1. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests ...

  2. Overview of surface studies on high energy materials at Mound

    SciTech Connect

    Moddeman, W.E.; Collins, L.W.; Wang, P.S.; Haws, L.D.; Wittberg, T.N.

    1980-01-01

    Since 1975 Mound has been examining the surface structure of high energy materials and the interaction of these materials with various metal containers. The high energy materials that have been studied include: the pyrotechnic TiH/sub x//KClO/sub 4/, the Al/Cu/sub 2/O machinable thermite, the PETN, HMX and RDX explosives, and two plastic bonded explosives (PBX). Aluminum and alloys of Fe, Ni and Cr have been used as the containment materials. Two aims in this research are: (1) the elucidation of the mechanism of pyrotechnic ignition and (2) the compatibility of high energy materials with their surroundings. New information has been generated by coupling Auger electron spectroscopy (AES) and x-ray photoelectron spectroscopy (XPS) with thermal data. In particular, AES and XPS studies on the pyrotechnic materials and on thermites have shown the mechanism of ignition to be nearly independent of the type of oxidizer present but directly related to surface chemistry of the fuels. In studies on the two PBX's, PBX-9407 and LX-16, it was concluded that the Exon coating on 9407 was complete and greater than or equal to 100A; whereas in LX-16, the coating was < 100A or even incomplete. AES and scanning Auger have been used to characterize the surface composition and oxide thickness for an iron-nickel alloy and showed the thicker oxides to have the least propensity for atmospheric hydrocarbon adsorption. Data are presented and illustrations made which highlight this new approach to studying ignition and compatibility of high energy materials. Finally, the salient features of the X-SAM-800 purchased by Mound are discussed in light of future studies on high energy materials.

  3. Origin, distribution, and movement of brine in the Permian Basin (U. S. A. ). A model for displacement of connate brine

    SciTech Connect

    Bein, A.; Dutton, A.R. )

    1993-06-01

    Na-Cl, halite Ca-Cl, and gypsum Ca-Cl brines with salinities from 45 to >300 g/L are identified and mapped in four hydrostratigraphic units in the Permian Basin area beneath western Texas and Oklahoma and eastern New Mexico, providing spatial and lithologic constraints on the interpretation of the origin and movement of brine. Na-Cl brine is derived from meteoric water as young as 5-10 Ma that dissolved anhydrite and halite, whereas Ca-Cl brine is interpreted to be ancient, modified-connate Permian brine that now is mixing with, and being displaced by, the Na-Cl brine. Displacement fronts appear as broad mixing zones with no significant salinity gradients. Evolution of Ca-Cl brine composition from ideal evaporated sea water is attributed to dolomitization and syndepositional recycling of halite and bittern salts by intermittent influx of fresh water and sea water. Halite Ca-Cl brine in the evaporite section in the northern part of the basin differs from gypsum Ca-Cl brine in the south-central part in salinity and Na/Cl ratio and reflects segregation between halite- and gypsum-precipitating lagoons during the Permian. Ca-Cl brine moved downward through the evaporite section into the underlying Lower Permian and Pennsylvanian marine section that is now the deep-basin brine aquifer, mixing there with pre-existing sea water. Buoyancy-driven convection of brine dominated local flow for most of basin history, with regional advection governed by topographically related forces dominant only for the past 5 to 10 Ma. 71 refs., 11 figs.

  4. Reduce completion fluid costs with on-site brine tests

    SciTech Connect

    Thomas, D.C.; Darlington, R.K.; Kinney, W.R.; Lowell, J.L.

    1982-09-01

    A newly developed field kit makes on-site brine completion fluid testing practical. Simple titration procedures are used to analyze brine for calcium, zinc, chloride and bromide with an accuracy and repeatability that compares favorably with expensive laboratory techniques. This article describes the field testing theory and details analytical procedures used.

  5. Progress Toward Operable Unit 1 Groundwater Cleanup at the Mound, Ohio,

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Site | Department of Energy Progress Toward Operable Unit 1 Groundwater Cleanup at the Mound, Ohio, Site Progress Toward Operable Unit 1 Groundwater Cleanup at the Mound, Ohio, Site July 2, 2015 - 12:41pm Addthis What does this project do? Goal 1. Protect human health and the environment. Groundwater in Operable Unit 1 (OU-1) has been impacted by volatile organic compound (VOC)-contaminated materials in the former solid waste landfill. The remedy for controlling contamination from residual

  6. Cost estimate for muddy water palladium production facility at Mound

    SciTech Connect

    McAdams, R.K.

    1988-11-30

    An economic feasibility study was performed on the ''Muddy Water'' low-chlorine content palladium powder production process developed by Mound. The total capital investment and total operating costs (dollars per gram) were determined for production batch sizes of 1--10 kg in 1-kg increments. The report includes a brief description of the Muddy Water process, the process flow diagram, and material balances for the various production batch sizes. Two types of facilities were evaluated--one for production of new, ''virgin'' palladium powder, and one for recycling existing material. The total capital investment for virgin facilities ranged from $600,000 --$1.3 million for production batch sizes of 1--10 kg, respectively. The range for recycle facilities was $1--$2.3 million. The total operating cost for 100% acceptable powder production in the virgin facilities ranged from $23 per gram for a 1-kg production batch size to $8 per gram for a 10-kg batch size. Similarly for recycle facilities, the total operating cost ranged from $34 per gram to $5 per gram. The total operating cost versus product acceptability (ranging from 50%--100% acceptability) was also evaluated for both virgin and recycle facilities. Because production sizes studied vary widely and because scale-up factors are unknown for batch sizes greater than 1 kg, all costs are ''order-of-magnitude'' estimates. All costs reported are in 1987 dollars.

  7. Earth-mounded concrete bunker PLAP technical approach

    SciTech Connect

    Eng, R.

    1989-11-01

    Under the US DOE Prototype License Application Project (PLAP), Ebasco Services Incorporated was commissioned to develop a preliminary design of the Earth-Mounded Concrete Bunker (EMCB) concept for low-level radioactive waste (LLW) disposal. The EMCB disposal concept is of great interest because it represents the only engineered LLW disposal technology currently in use in the commercial sector. By definition, the EMCB disposal structure is located partially below grade and partially above grade. The concrete bunker is an engineered structure designed to be structurally stable for the prerequisite time horizon. The basic design parameters of the disposal facility were stipulated by US DOE, a northeast site location, representative waste, 30 year operational life, and a 250,000 ft{sup 3}/year disposal capacity. The design was developed to satisfy only US NRC Part 61 disposal requirements, not individual state requirements that may go beyond Part 61 requirements. The technical safety analysis of the preliminary design was documented according to the format specifications of NUREG-1199, to the extent practicable with quite limited resources.

  8. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  9. Technique for thermodynamic crystallization temperature of brine fluids

    SciTech Connect

    Clark, D.E.; Hubbard, J.T.

    1983-03-01

    The application of high density solids free brine fluids has proven to be technically and economically successful in hydrocarbon completion and workover operations. The use of inorganic salts such as calcium chloride, calcium bromide, zinc bromide, and sodium bromide has contributed to the development of complex salt systems. As the density and complexity of these systems becomes more detailed, the requirement for proper fluid design becomes increasingly important. When a brine solution is cooled sufficiently, a temperature is reached where the solution will be saturated. A further decrease in temperature will result in the precipitation of salt from the solution. The temperature at which this transpires, provided no super-cooling occurs, is the crystallization point of the solution. A correctly formulated solids free brine should have the optimum crystallization point for the temperature conditions it will encounter. A recently developed semiautomatic procedure constructs a cooling curve plot of each brine tested. This cooling curve plot allows the determination of the super-cooling potential, the Thermodynamic Crystallization Temperature, and the Last Crystal To Dissolve Temperature. The device provides a permanent record of the cooling curve with repeatable accuracy, which assists in the development of error free brine formulation tables, brine density, and/or crystallization point adjustments, and brine analysis.

  10. Concentration of Actinides in Plant Mounds at Safety Test Nuclear Sites in Nevada

    SciTech Connect

    David S. Shafer; Jenna Gommes

    2008-09-15

    Plant mounds or blow-sand mounds are accumulations of soil particles and plant debris around large shrubs and are common features in deserts in the southwestern United States. Believed to be an important factor in their formation, the shrubs create surface roughness that causes wind-suspended particles to be deposited and resist further suspension. Shrub mounds occur in some plant communities on the Nevada Test Site, the Nevada Test and Training Range (NTTR), and Tonopah Test Range (TTR), including areas of surface soil contamination from past nuclear testing. In the 1970s as part of early studies to understand properties of actinides in the environment, the Nevada Applied Ecology Group (NAEG) examined the accumulation of isotopes of Pu, {sup 241}Am, and U in plant mounds at safety test sites. The NAEG studies found concentrations of these contaminants to be greater in shrub mounds than in the surrounding areas of desert pavement. For example, at Project 57 on the NTTR, it was estimated that 15 percent of the radionuclide inventory of the site was associated with shrub mounds, which accounted for 17 percent of the surface area of the site, a ratio of inventory to area of 0.85. At Clean Slate III at the TTR, 29 percent of the inventory was associated with approximately 32 percent of the site covered by shrub mounds, a ratio of 0.91. While the total inventory of radionuclides in intershrub areas was greater, the ratio of radionuclide inventory to area was 0.40 and 0.38, respectively, at the two sites. The comparison between the shrub mounds and adjacent desert pavement areas was made for only the top 5 cm since radionuclides at safety test sites are concentrated in the top 5 cm of intershrub areas. Not accounting for radionuclides associated with the shrub mounds would cause the inventory of contaminants and potential exposure to be underestimated. As part of its Environmental Restoration Soils Subproject, the U.S. Department of Energy (DOE), National Nuclear

  11. Formate brines -- New fluids for drilling and completions

    SciTech Connect

    Ramsey, M.S.; Shipp, J.A.

    1996-01-01

    The term ``formate brines`` refers broadly to three primary compounds dissolved in water -- sodium formate (NaCOOH), potassium formate (KCOOH) and cesium formate (CsCOOH). Each is chemically classified as an alkali-metal salt of formic acid. They offer properties that in many respects are superior to their predecessors, halide brines such as zinc bromide and calcium bromide, without the undesirable side effects of those more common halide brine systems. This article introduces the technology and provides an overview of published work to date regarding formates.

  12. Office of Inspector General report on audit of shutdown and transition of the Mound Plant

    SciTech Connect

    1997-06-24

    With the end of the Cold War, the Department of Energy (Department) has greatly reduced the production of nuclear weapons and redirected the capabilities and focus of the weapons complex. As part of this redirection, the Mound Plant was transferred from a Defense Program site to an Environmental Management site with emphasis on accelerated cleanup and transition of facilities and personal property to the local community. This audit was initiated to determine if the shutdown and transition of the Mound Plant was progressing effectively and efficiently. The Department prepared a Nonnuclear Consolidation Plan (NCP) designed to reduce its costs of operation by closing and consolidating facilities. In contrast to the goal of the NCP, the Department plans to keep a portion of the Mound Plant open solely to perform work for other Federal agencies. Specifically, the Department has decided to continue assembling and testing isotopic heat sources and radioisotope thermoelectric generators (HS/RTG) at the Mound Plant despite the transfer or planned transfer of all other production operations.The Office of Nuclear Energy, Science and Technology decided to continue its HS/RTG operations at the Mound Plant without adequately considering the overall economic goals of the Department. As a result, the Department may not achieve the savings envisioned by the NCP. Also, the Department may incur between $4 million and $8.5 million more than necessary each year to continue its HS/RTG operations at the Mound Plant. Additionally, if the HS/RTG operations stay at the Mound Plant, the Department will spend more than $3 million to consolidate these operations into one location.

  13. Environmental assessment and planning at Mound - environmental monitoring capabilities and personnel profiles

    SciTech Connect

    1996-07-01

    Through its long experience with radioactive materials, Mound has developed a comprehensive, routine, offsite, environmental surveillance program to safeguard its employees, the physical plant, and the integrity of the surrounding environment from any potential adverse effects of its widely diverse operations. Effluent samples are analyzed for radiological and non-radiological parameters. The environment surrounding Mound Facility is continuously monitored - air, water, foodstuffs, vegetation, soil, and silt samples are analyzed to ensure that radioisotopic concentrations and other possible pollutants are well within the stringent standards adopted by the Department of Energy, the Environmental Protection Agencies (both federal and state), and various regional and local agencies. Moreover, this environmental surveillance program has been designed to ensure that the facility is designed, constructed, managed, operated, and maintained in a manner that continues to meet all federal, state, and local standards for environmental protection. Work in environmental science has been broadened to assess environmental factors associated with various aspects of the National Energy Plan. Both the management and staff at Mound have undertaken a firm commitment to make Mound`s environmental monitoring capabilities available to agencies that have the responsibility for the resolution of important environmental issues.

  14. From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits— Mound Science and Energy Museum Programs Cover a Wide Range of Topics

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Mound Science and Energy Museum (MSEM) is an active, volunteer-led organization located at the former U.S. Department of Energy (DOE) Mound site in Miamisburg, Ohio. MSEM keeps the 60-year...

  15. Overview of the earth mounded concrete bunker prototype license application project: Objectives and approach

    SciTech Connect

    Conner, J.E.

    1989-11-01

    This paper presents an overview of the objectives and approach taken in developing the Earth-mounded Concrete Bunker Prototype License Application Project. The Prototype License Application Project was initiated by the Department of Energy`s National Low-Level Waste Management Program in early 1987 and completed in November 1988. As part of this project a prototype safety analysis report was developed. The safety analysis report evaluates the licensibility of an earth-mounded concrete bunker for a low-level radioactive waste (LLW) disposal facility located on a hypothetical site in the northeastern United States. The project required approximately five person-years and twenty months to develop.

  16. Annual Assessment of the Effectiveness of Institutional Controls at the Mound, Ohio, Site Miamisburt, Ohio

    Office of Legacy Management (LM)

    6 LMS/MND/S14084 This page intentionally left blank U.S. Department of Energy Annual Assessment of the Effectiveness of Institutional Controls, Mound Site June 2016 Doc. No. S14084 Page i Contents Abbreviations ...................................................................................................................................v 1.0 Introduction ............................................................................................................................1 2.0 Period of

  17. Marketing research for EE G Mound Applied Technologies' heat treatment process of high strength materials

    SciTech Connect

    Shackson, R.H.

    1991-10-09

    This report summarizes research conducted by ITI to evaluate the commercialization potential of EG G Mound Applied Technologies' heat treatment process of high strength materials. The remainder of the report describes the nature of demand for maraging steel, extent of demand, competitors, environmental trends, technology life cycle, industry structure, and conclusion. (JL)

  18. Actinide (III) solubility in WIPP Brine: data summary and recommendations

    SciTech Connect

    Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

    2009-09-01

    The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

  19. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential...

    Office of Environmental Management (EM)

    Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a 1...

  20. Brine pH Modification Scale Control Technology. 2. A Review.pdf...

    OpenEI (Open Energy Information) [EERE & EIA]

    Brine pH Modification Scale Control Technology. 2. A Review.pdf Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Brine pH Modification Scale...

  1. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    SciTech Connect

    Lucchini, Jean-francois; Khaing, Hnin; Reed, Donald T

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  2. Durability of concrete materials in high-magnesium brine

    SciTech Connect

    Wakeley, L.D.; Poole, T.S.; Burkes, J.P.

    1994-03-01

    Cement pastes and mortars representing 11 combinations of candidate concrete materials were cast in the laboratory and monitored for susceptibility to chemical deterioration in high-magnesium brine. Mixtures were selected to include materials included in the current leading candidate concrete for seals at the Waste Isolation Pilot Plant (WIPP). Some materials were included in the experimental matrix to answer questions that had arisen during study of the concrete used for construction of the liner of the WIPP waste-handling shaft. Mixture combinations compared Class C and Class F fly ashes, presence or absence of an expansive component, and presence or absence of salt as a mixture component. Experimental conditions exposed the pastes and mortars to extreme conditions, those being very high levels of Mg ion and an effectively unlimited supply of brine. All pastes and mortars showed deterioration with brine exposure. In general, mortars deteriorated more extensively than the corresponding pastes. Two-inch cube specimens of mortar were not uniformly deteriorated, but showed obvious zoning even after a year in the brine, with a relatively unreacted zone remaining at the center of each cube. Loss of calcium from the calcium hydroxide of paste/aggregate interfaces caused measurable strength loss in the reacted zone comprising the outer portion of every mortar specimen. The current candidate mass concrete for WIPP seals includes salt as an initial component, and has a relatively closed initial microstructure. Both of these features contribute to its suitability for use in large placements within the Salado Formation.

  3. EIS-0302: Transfer of the Heat Source/Radioisotope Thermoelectric Generator Assembly and Test Operations From the Mound Site

    Energy.gov [DOE]

    This EIS analyzes DOE's proposed transfer of the Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) operations at the Mound Site near Miamisburg, Ohio, to an alternative DOE site.

  4. Assessment of Brine Management for Geologic Carbon Sequestration

    SciTech Connect

    Breunig, Hanna M.; Birkholzer, Jens T.; Borgia, Andrea; Price, Phillip N.; Oldenburg, Curtis M.; McKone, Thomas E.

    2013-06-13

    Geologic carbon sequestration (GCS) is the injection of carbon dioxide (CO2), typically captured from stationary emission sources, into deep geologic formations to prevent its entry into the atmosphere. Active pilot facilities run by regional United States (US) carbon sequestration partnerships inject on the order of one million metric tonnes (mt) CO2 annually while the US electric power sector emits over 2000 million mt-CO2 annually. GCS is likely to play an increasing role in US carbon mitigation initiatives, but scaling up GCS poses several challenges. Injecting CO2 into sedimentary basins raises fluid pressure in the pore space, which is typically already occupied by naturally occurring, or native, brine. The resulting elevated pore pressures increase the likelihood of induced seismicity, of brine or CO2 escaping into potable groundwater resources, and of CO2 escaping into the atmosphere. Brine extraction is one method for pressure management, in which brine in the injection formation is brought to the surface through extraction wells. Removal of the brine makes room for the CO2 and decreases pressurization. Although the technology required for brine extraction is mature, this form of pressure management will only be applicable if there are cost-­effective and sustainable methods of disposing of the extracted brine. Brine extraction, treatment, and disposal may increase the already substantial capital, energy, and water demands of Carbon dioxide Capture and Sequestration (CCS). But, regionally specific brine management strategies may be able to treat the extracted water as a source of revenue, energy, and water to subsidize CCS costs, while minimizing environmental impacts. By this approach, value from the extracted water would be recovered before disposing of any resulting byproducts. Until a price is placed on carbon, we expect that utilities and other CO2 sources will be

  5. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  6. Pre-operational safety appraisal Tritiated Scrap Recovery Facility, Mound facility

    SciTech Connect

    Dauby, J.J.; Flanagan, T.M.; Metcalf, L.W.; Rhinehammer, T.B.

    1996-07-01

    The purpose of this report is to identify, assess, and document the hazards which are associated with the proposed operation of the Tritiated Scrap Recovery Facility at Mound Facility. A Pre-operational Safety Appraisal is a requirement as stated in Department of Energy Order 5481.1, Safety Analysis and Review System. The operations to be conducted in the new Tritiated Scrap Waste Recovery Facility are not new, but a continuation of a prime mission of Mound`s i.e. recovery of tritium from waste produced throughout the DOE complex. The new facility is a replacement of an existing process started in the early 1960`s and incorporates numerous design changes to enhance personnel and environmental safety. This report also documents the safety of a one time operation involving the recovery of tritium from material obtained by the Department of Energy from the State of Arizona. This project will involve the processing of 240,000 curies of tritium contained in glass ampoules that were to be used in items such as luminous dial watches. These were manufactured by the now defunct American Atomics Corporation, Tucson, Arizona.

  7. Operating Experience Summary- 2014-02 – April 23, 2014

    Energy.gov [DOE]

    Inside this issue: Laboratory Worker Safety: Work Planning, Hazard Analysis, and Supervision - Page 1 Accident Investigation into Mower Fatality at the Bryan Mound Site - Page 13

  8. DEPARTMENT OF ENERGY Strategic Petroleum Reserve Annual Report

    Energy.gov [DOE] (indexed site)

    and planned projects for the Strategic Petroleum Reserve. ... Oil Inventory Status 18 Oil Acquisition Market ... 32 Bayou Choctaw Pipeline: 32 Bryan Mound Pipelines: 32 St. ...

  9. Operating Experience Summary- 2012-02 – May 11, 2012

    Energy.gov [DOE]

    Inside this issue: Improper Use of Dewar Carts Results in Serious Hand Injuries - Page 1 Strategic Petroleum Reserve Investigation Results - Fatality at the Bryan Mound Site - Page 5

  10. DOE F 3304.2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    More Documents & Publications Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site DOE F 241 5 Headquarters Facilities Master ...

  11. POTENTIAL IMPACT OF BLENDING RESIDUAL SOLIDS FROM TANKS 18/19 MOUNDS WITH TANK 7 OPERATIONS

    SciTech Connect

    Eibling, R; Erich Hansen, E; Bradley Pickenheim, B

    2007-03-29

    High level waste tanks 18F and 19F have residual mounds of waste which may require removal before the tanks can be closed. Conventional slurry pump technology, previously used for waste removal and tank cleaning, has been incapable of removing theses mounds from tanks 18F and 19F. A mechanical cleaning method has been identified that is potentially capable of removing and transferring the mound material to tank 7F for incorporation in a sludge batch for eventual disposal in high level waste glass by the Defense Waste Processing Facility. The Savannah River National Laboratory has been requested to evaluate whether the material transferred from tanks 18F/19F by the mechanical cleaning technology can later be suspended in Tank 7F by conventional slurry pumps after mixing with high level waste sludge. The proposed mechanical cleaning process for removing the waste mounds from tanks 18 and 19 may utilize a high pressure water jet-eductor that creates a vacuum to mobilize solids. The high pressure jet is also used to transport the suspended solids. The jet-eductor system will be mounted on a mechanical crawler for movement around the bottom of tanks 18 and 19. Based on physical chemical property testing of the jet-eductor system processed IE-95 zeolite and size-reduced IE-95 zeolite, the following conclusions were made: (1) The jet-eductor system processed zeolite has a mean and median particle size (volume basis) of 115.4 and 43.3 microns in water. Preferential settling of these large particles is likely. (2) The jet-eductor system processed zeolite rapidly generates settled solid yield stresses in excess of 11,000 Pascals in caustic supernates and will not be easily retrieved from Tank 7 with the existing slurry pump technology. (3) Settled size-reduced IE-95 zeolite (less than 38 microns) in caustic supernate does not generate yield stresses in excess of 600 Pascals in less than 30 days. (4) Preferential settling of size-reduced zeolite is a function of the amount of

  12. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  13. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    DOE PAGES [OSTI]

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be usedmore » directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.« less

  14. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    SciTech Connect

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be used directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.

  15. Geothermal Brine Brings Low-Cost Power with Big Potential | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Brine Brings Low-Cost Power with Big Potential Geothermal Brine Brings Low-Cost Power with Big Potential January 3, 2014 - 9:05am Addthis John Fox, CEO of Electratherm, with Tim Reinhardt, Low-Temperature and Coproduced Technology Manager for the Department of Energy, join Joel Murphy, general manager of the Florida Canyon Mine for Jipangu International. The mine's byproduct of geothermal brine allows for an additional revenue stream from existing infrastructure. John Fox, CEO of

  16. Summary Results for Brine Migration Modeling Performed by LANL, LBNL and

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SNL for the Used Fuel Disposition Program | Department of Energy Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program Summary Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program The report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies

  17. The Mound site survey project for the characterization of radioactive materials in site soils

    SciTech Connect

    Stought, R.L.; Edling, D.A.; Draper, D.G.

    1988-05-16

    This report summarizes the results of a site survey project conducted at Monsanto Research Corporation's Mound Facility during 1982--1985. The objectives of the site survey were: To characterize the nineteen sites previously identified as having known levels of contamination; to identify and characterize by quantity and type of radionuclide(s) any additional major sites having levels of contamination exceeding 10 pCi/g (for Pu-238) of soil; to estimate the volume of contaminated soil; and to estimate the cost of stabilizing or removing the contaminated soil. This report provides information on objectives 1 and 2 above. A separate report will address objectives 3 and 4.

  18. The Mound site survey project for the characterization of radioactive materials in site soils

    SciTech Connect

    Stought, R.L.; Edling, D.A.; Draper, D.G.

    1988-05-16

    This report summarizes the results of a site survey project conducted at Monsanto Research Corporation`s Mound Facility during 1982--1985. The objectives of the site survey were: To characterize the nineteen sites previously identified as having known levels of contamination; to identify and characterize by quantity and type of radionuclide(s) any additional major sites having levels of contamination exceeding 10 pCi/g (for Pu-238) of soil; to estimate the volume of contaminated soil; and to estimate the cost of stabilizing or removing the contaminated soil. This report provides information on objectives 1 and 2 above. A separate report will address objectives 3 and 4.

  19. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  20. Community Geothermal Technology Program: Electrodeposition of minerals in geothermal brine

    SciTech Connect

    Not Available

    1990-12-31

    Objective was to study the materials electrodeposited from geothermal brine, from the HGP-A well in Puna, Hawaii. Due to limitations, only one good set of electrodeposited material was obtained; crystallography indicates that vaterite forms first, followed by calcite and then perhaps aragonite as current density is increased. While the cost to weight ratio is reasonable, the deposition rate is very slow. More research is needed, such as reducing the brittleness. The electrodeposited material possibly could be used as building blocks, tables, benches, etc. 49 figs, 4 tabs, 7 refs.

  1. Focused risk assessment: Mound Plant, Miami-Erie Canal Operable Unit 4

    SciTech Connect

    Rogers, D.R.; Dunning, D.F.

    1994-09-29

    In 1969, an underground waste line at Mound Plant ruptured and released plutonium-238 in a dilute nitric acid solution to the surrounding soils. Most of the acid was neutralized by the native soils. The plutonium, which in a neutral solution is tightly sorbed onto clay particles, remained within the spill area. During remediation, a severe storm eroded some of the contaminated soil. Fine grained plutonium-contaminated clay particles were carried away through the natural drainage courses to the remnants of the Miami-Erie Canal adjacent to Mound Plant, and then into the Great Miami River. This focused risk assessment considers exposure pathways relevant to site conditions, including incidental ingestion of contaminated soils, ingestion of drinking water and fish, and inhalation of resuspended soils and sediments. For each potential exposure pathway, a simplified conceptual model and exposure scenarios have been used to develop conservative estimates of potential radiation dose equivalents and health risks. The conservatism of the dose and risk estimates provides a substantive margin of safety in assuring that the public health is protected.

  2. Thermal Enhanced Oil Recovery Using Geopressured-Geothermal Brine

    SciTech Connect

    1989-12-01

    This white paper presents a unique plan for an Oil Industry-DOE cost sharing research project for Thermal Enhanced Oil Recovery (TEOR) of medium and heavy oil using geopressured-geothermal brine. This technology would provide an environmentally clean method of recovery as opposed to the burning of crude oil or natural gas used widely by the industry, but presently under scrutiny by federal and state air quality agencies, as well as provide an alternative to the very expensive operational and mechanical problems associated with heating water on the surface for injection. An example test reservoir is a shallow, small structural reservoir about 1-l/2 miles long by 1/2 mile wide. It is presently producing heavy oil (18.6 API gravity) from 5 wells, and is marginally economic. One of three nearby geopressured-geothermal wells could be re-entered and recompleted to supply about 400 F brine from 13-16,000 feet. This brine can be used to heat and drive the heavy oil. It is anticipated that about one million barrels of oil may be recovered by this project. Over 3 million barrels are estimated to be in place; only 2.7% of the oil in place has been produced. The suggested teaming arrangement includes: (1) EG&G Idaho, Inc., which presently provides technical and management support to DOE in the Gulf EG&G would supply coordination, management and Coast Geopressured-Geothermal Program. technical support to DOE for the Thermal Enhanced Oil Recovery Project. (2) A small business which would supply the field, geologic and well data, production wells, and production operation. They would cost-share the project and provide revenue from increased production (5% of increased production) to help offset DOE costs. Though DOE would cost-share brine supply and injection system, they would not assume well ownership. The small business would supply engineering and operations for brine supply, injection system, and collection of field producing and injection data. Phase 1--Geologic, reservoir

  3. A Computer Program To Calculate The Leaching of Radionuclides and the Corrosion of Cemented Waste Forms in Water or Brine

    Energy Science and Technology Software Center

    1990-12-01

    DIFMOD calculates the leaching of radionuclides and the corrosion of cemented waste forms in contact with water or brine.

  4. An aerial radiological survey of the EG G Mound Applied Technologies and surrounding area, Miamisburg, Ohio

    SciTech Connect

    Not Available

    1992-11-01

    An aerial radiological survey was conducted over EG G Mound Applied Technologies, Miamisburg, Ohio, during the period of June 9--24, 1989. The purpose of the 41-square-kilometer (16-square-mile) survey was to document the terrestrial gamma environment of the plant and surrounding area. In addition, ground-based exposure rate measurements and soil samples were obtained to support the aerial data. An exposure rate contour map at 1 meter above ground level was.constructed from the gamma data and overlaid on an aerial photograph and map of the area. Exposure rates measured in the area typically ranged from 9 to 11 microroentgens per hour ([mu]R/h).

  5. A radioactive waste excavation at Mound Area 7 using INEL dig-face monitoring technology

    SciTech Connect

    Carpenter, M.V.; Josten, N.E.

    1996-12-31

    Dig-face characterization is a method to improve the safety and efficiency during hazardous waste retrieval. A dig-face characterization system consists of on-site hardware for collecting detailed information on the changing chemical, radiological, and physical conditions in the subsurface throughout a hazardous site excavation. The dig-face characterization concept originated at the Idaho National Engineering Laboratory where it has been under development since 1992. In August 1995, a prototype dig-face system was taken to Mound Laboratory, Ohio, to monitor a hazardous waste site excavation. Mound Area 7 was the site of previous disposal of {sup 232}Th, {sup 227}Ac, and other waste. The dig-face characterization system was used to monitor a 20-ft x 20-ft x 5-ft-deep excavation intended to remove the {sup 227}Ac contaminated soils. Radiological, geophysical, and topographical sensors were scanned across each of four successive excavated soil levels, each 1-ft to 2-ft thick. The radiation sensors produced highly detailed images showing the location of the contaminants {sup 232}Th and {sup 227}Ac, and the clear delineation between them. When combined into a single data set, the four levels of collected data produced a three dimensional image of the contamination. The radiation sensor data indicated that only a small portion of the excavated soil was actually contaminated. The information produced by the dig-face system was used to direct precise excavation activities in the area containing the {sup 227}Ac and to plan subsequent removal of the separate {sup 232}Th plume.

  6. Chemical-equilibrium calculations for aqueous geothermal brines

    SciTech Connect

    Kerrisk, J.F.

    1981-05-01

    Results from four chemical-equilibrium computer programs, REDEQL.EPAK, GEOCHEM, WATEQF, and SENECA2, have been compared with experimental solubility data for some simple systems of interest with geothermal brines. Seven test cases involving solubilities of CaCO/sub 3/, amorphous SiO/sub 2/, CaSO/sub 4/, and BaSO/sub 4/ at various temperatures from 25 to 300/sup 0/C and in NaCl or HCl solutions of 0 to 4 molal have been examined. Significant differences between calculated results and experimental data occurred in some cases. These differences were traced to inaccuracies in free-energy or equilibrium-constant data and in activity coefficients used by the programs. Although currently available chemical-equilibrium programs can give reasonable results for these calculations, considerable care must be taken in the selection of free-energy data and methods of calculating activity coefficients.

  7. Tests of proprietary chemical additives as antiscalants for hypersaline geothermal brine. Final report

    SciTech Connect

    Harrar, J.E.; Locke, F.E.; Otto, C.H. Jr.; Deutscher, S.B.; Frey, W.P.; Lorensen, L.E.; Snell, E.O.; Lim, R.; Ryon, R.W.; Quong, R.

    1980-01-01

    The Lawrence Livermore Laboratory brine treatment test system has been used to carry out a short-term evaluation of a number of proprietary chemical additives as antiscalants for the hypersaline brine of the Salton Sea Geothermal Field. In addition, a test of sludge seeding was conducted as a technique for scale control. The effect of each additive on the rate of precipitation of silica from the effluent brine at 90/sup 0/C was measured, and scaling rates of brine treated with nine of the additives were measured at 125 and 210/sup 0/C. Corrosion rates of mild steel in the treated brines were estimated using Petrolite linear polarization resistance equipment. None of the additives had a direct effect on the rates of silica precipitation, and none had a beneficial effect on the scale formed at 210/sup 0/C. At 125/sup 0/C, two additives, Drewsperse 747 (Drew Chemical) and SC-210 (Southwest Specialty Chemicals) afforded a marginal degree of scale reduction. The Austral-Erwin additive diminished the adherence of scale formed at points of high velocity fluid flow but increased solids accumulation at other points. Sludge seeding shows some promise because it reduces the degree of silica supersaturation of the brine. Results of analyses of solids precipitated from effluent brines (Woolsey No. 1 and acidified Magmamax No. 1) are presented.

  8. Weeks Island brine diffuser site study: baseline conditions and environmental assessment technical report

    SciTech Connect

    1980-12-12

    This technical report presents the results of a study conducted at two alternative brine diffuser sites (A and B) proposed for the Weeks Island salt dome, together with an analysis of the potential physical, chemical, and biological effects of brine disposal for this area of the Gulf of Mexico. Brine would result from either the leaching of salt domes to form or enlarge oil storage caverns, or the subsequent use of these caverns for crude oil storage in the Strategic Petroleum Reserve (SPR) program. Brine leached from the Weeks Island salt dome would be transported through a pipeline which would extend from the salt dome either 27 nautical miles (32 statute miles) for Site A, or 41 nautical miles (47 statute miles) for Site B, into Gulf waters. The brine would be discharged at these sites through an offshore diffuser at a sustained peak rate of 39 ft/sup 3//sec. The disposal of large quantities of brine in the Gulf could have a significant impact on the biology and water quality of the area. Physical and chemical measurements of the marine environment at Sites A and B were taken between September 1977 and July 1978 to correlate the existing environmental conditions with the estimated physical extent of tthe brine discharge as predicted by the MIT model (US Dept. of Commerce, 1977a). Measurements of wind, tide, waves, currents, and stratification (water column structure) were also obtained since the diffusion and dispersion of the brine plume are a function of the local circulation regime. These data were used to calculate both near- and far-field concentrations of brine, and may also be used in the design criteria for diffuser port configuration and verification of the plume model. Biological samples were taken to characterize the sites and to predict potential areas of impact with regard to the discharge. This sampling focused on benthic organisms and demersal fish. (DMC)

  9. Calculation of brine properties. [Above 80/sup 0/F and for salt...

    Office of Scientific and Technical Information (OSTI)

    Brine saturation pressure is calculated as a percentage of the pure water saturation ... temperature and pressure and are obtained from the ASME equation-of-state for pure water. ...

  10. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  11. Recovery of energy from geothermal brine and other hot water sources

    DOEpatents

    Wahl, III, Edward F.; Boucher, Frederic B.

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  12. Brine Sampling and Evaluation Program 1992--1993 report and summary of BSEP data since 1982

    SciTech Connect

    Deal, D.E.; Abitz, R.J.; Belski, D.S.

    1995-04-01

    This report is the last one that is currently scheduled in the sequence of reports of new data, and therefore, also includes summary comments referencing important data obtained by BSEP since 1983. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the (WIPP) Waste Isolation Pilot Plant. A project concern is that enough brine might be present after sealing and closure to generate large quantities of hydrogen gas by corroding the metal in the waste drums and waste inventory. This report describes progress made during the calendar years 1992 and 1993 and focuses on four major areas: (1) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes from the underground drifts; (2) observations of weeps in the Air Intake Shaft (AIS); (3) further characterization of brine geochemistry; and (4) additional characterization of the hydrologic conditions in the fractured zone beneath the excavations.

  13. Dig-face monitoring during excavation of a radioactive plume at Mound Laboratory, Ohio

    SciTech Connect

    Josten, N.E.; Gehrke, R.J.; Carpenter, M.V.

    1995-12-01

    A dig-face monitoring system consists of onsite hardware for collecting information on changing chemical, radiological, and physical conditions in the subsurface soil during the hazardous site excavation. A prototype dig-face system was take to Mount Laboratory for a first trial. Mound Area 7 was the site of historical disposals of {sup 232}Th, {sup 227}Ac, and assorted debris. The system was used to monitor a deep excavation aimed at removing {sup 227}Ac-contaminated soils. Radiological, geophysical, and topographic sensors were used to scan across the excavation dig-face at four successive depths as soil was removed. A 3-D image of the contamination plumes was developed; the radiation sensor data indicated that only a small portion of the excavated soil volume was contaminated. The spatial information produced by the dig-face system was used to direct the excavation activities into the area containing the {sup 227}Ac and to evaluate options for handling the separate {sup 232}Th plume.

  14. Certification of the Mound 1 kW package for shipping of plutonium dioxide source material

    SciTech Connect

    Annese, C.E.; Mount, M.K.

    1994-01-01

    The Department of Energy (DOE) has established procedures for obtaining certification of packagings used by DOE and its contractors for the transport of radioactive materials. Specifically, DOE Orders 5480.3 and 1540.2 provide references for other DOE Orders which must be followed when an applicant submits a Safety Analysis Report for Packaging (SARP). From the orders, Department EH of DOE, has internal oversight responsibility for transportation and Packaging safety; package certification falls under EH responsibility; transportation and packaging safety division in EH certifies packages for DOE; and use of DOE certified packages is authorized by DOT. An independent review of the SARP must confirm that the packaging designs and operations meet safety criteria at least equivalent to these standards. This paper will discuss the independent review process of the shielding section of the Mound 1 kW SARP; describe the geometry of the packaging and the load configurations; discuss the analysis of the various neutron and photon source terms that were used for the load configuration under analysis; and provide illustrations of the use of the monte-carlo code, COG{sup 3}, which was utilized to perform the shielding analysis.

  15. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    SciTech Connect

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  16. Behavior of natural uranium, thorium, and radium isotopes in the Wolfcamp brine aquifers, Palo Duro Basin, Texas

    SciTech Connect

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1984-10-01

    Previously reported results for Palo Duro deep brines show that Ra is highly soluble and not retarded. Relative to Ra, U and Th are highly sorbed. Uranium, like thorium, is in the +4 valence state, indicating a reducing environment. Additional data reported here support these results. However, one Wolfcamp brine sample gives somewhat different results. Radium appears to be somewhat sorbed. Uranium is largely in the +6 valence state, indicating a less reducing condition. In all brines, kinetics for sorption (/sup 228/Th) and desorption (/sup 224/Ra) are rapid. This Wolfcamp brine was tested for the effects of colloids for Ra, U, and Th concentrations. No effects were found.

  17. Early diagenesis of a phylloid algal-mound complex, Laborcita Formation, southeastern New Mexico

    SciTech Connect

    Ward, W.B.; Meyers, W.J.; Goldstein, R.

    1985-02-01

    Marine carbonate cementation was the initial stage in the paragenesis of phylloid algal mounds in the Laborcita Formation (Wolfcampian), Sacramento Mountains, New Mexico, and the cements are almost identical to those in Holocene coral reefs of Belize. These cements include relics of botryoids and crusts of needle crystals, in part defined by inclusion patterns and luminescent ghosts in mosaic calcite. Individual needle crystals are pseudohexagonal in cross section and range from less than 1 to 30 ..mu..m wide. These nonluminescent early cements line cavity walls, coat phylloid-algal blades and stromatolites, and are interlayered with marine sediment. Early cements also include bladed, fibrous, and rare radiaxial fibrous calcites, which are microdolomite-rich. They have a proximal nonluminescent zone, a central bright-luminescent zone, and a distal blotchy, moderate-luminescent zone. The bright zone may be time equivalent to bright-luminescent micritic coatings on botryoids and grains. Botryoids are encrusted by isopachous bladed cement, some of which has prismatic overgrowths containing an early inclusion-rich zone. This initial cementation was followed closely by: (1) dissolution of algal blades and mollusks, (2) in-situ brecciation, and (3) cementation by blocky calcite. Botryoidal and acicular cements are interpreted as originally marine aragonite precipitates, based on morphology, occurrence, susceptibility to diagenesis, and similarity to Holocene reef cements. The same criteria, plus the microdolomite inclusions, indicate that the bladed, fibrous, and radiaxial cements had a marine Mg-calcite precursor. This assemblage followed by prismatic overgrowths, dissolution, and blocky-calcite cementation indicates an evolution from marine to freshwater diagenesis.

  18. Silica separation from reinjection brines at Monte Amiata geothermal plants, Italy

    SciTech Connect

    Vitolo, S.; Cialdella, M.L. . Dipartimento di Ingegneria Chimica)

    1994-06-01

    A process for the separation of silica from geothermal reinjection brines is reported, in which the phases of coagulation, sedimentation and filtration of silica are involved. The effectiveness of lime and calcium chloride as coagulating agents has been investigated and the separating operations have been set out. Attention has been focused on Monte Amiata reinjection geothermal brines, whose scaling effect causes serious problems in the operation and maintenance of reinjection facilities. The study has been conducted using different amounts of added coagulants and at different temperatures, to determine optimal operating conditions. Though calcium chloride was revealed to be effective as a coagulant of the polymeric silica fraction, lime has also proved capable of removing monomeric dissolved silica at high dosages. Investigation on the behavior of coagulated brine has revealed the feasibility of separating the coagulated silica by sedimentation and filtration.

  19. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-09-30

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria.

  20. EERE Success Story-Nevada: Geothermal Brine Brings Low-Cost Power with

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Big Potential | Department of Energy Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential EERE Success Story-Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a $1 million EERE investment, heat from geothermal fluids-a byproduct of gold mining-will be generating electricity this year for less than $0.06 per kilowatt hour with ElectraTherm's new plug-and-play technology. Building on this first-of-its-kind success, this

  1. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  2. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    SciTech Connect

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  3. Performance of CRA in concentrated brines at 130 to 180 C -- Effect of H{sub 2}S, elemental sulfur and brine composition

    SciTech Connect

    Schmitt, G.; Pankoke, U.; Klemp, G.; Bruckhoff, W.; Siegmund, G.

    1997-08-01

    Failure analysis of localized corrosion at 28Cr32Ni (Alloy 28) tubing in a sour gas well prompted systematic investigations on the performance of relevant corrosion resistant alloys (CRA) in synthetic high salinity brines at high H{sub 2}S partial pressures in the absence and presence of elemental sulfur at 130 to 180 C. The CRAs included superaustenitic steels, nickel and nickel-cobalt base alloys and titanium alloys. CRAs with pitting resistance equivalents (PRE) of 39 and lower (including 28Cr32Ni) suffered in unbuffered brines from pitting and crevice corrosion already at 130 C. Alloy C276 and Ti Beta-C alloys proved complete resistance in all media tested up to 180 C. The effect of medium composition on CRA performance was studied at 130 C with respect to the presence of elemental sulfur, H{sub 2}S, iron sulfide, and CaCo{sub 3} in NaCl/CaCl{sub 2} brines with a total of 160 g/l chloride.

  4. Shaker Table Experiments with Rare Earth Elements Sorption from Geothermal Brine

    SciTech Connect

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  5. RealGasBrine v1.0 option of TOUGH+ v1.5

    SciTech Connect

    Moridis, George

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.

  6. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    SciTech Connect

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

  7. Field test of plutonium and thorium contaminated clay soils from the Mound Site using the ACT*DE*CON Process

    SciTech Connect

    Johnson, J.O.; Swift, N.A.; Church, R.H.; Neff, R.A.

    1998-12-31

    A treatability test was run during the summer and fall of 1997 to demonstrate the effectiveness of ACT*DE*CON for removing plutonium and thorium from the clay soils around Mound. ACT*DE*CON is a proprietary solution patented by Selentec. The process utilized a highly selective dissolution of the contaminants by the use of a chemical wash. The pilot scale process involved pretreatment of the soil in an attrition scrubber with ACT*DE*CON solution. This blended solution was then passed through a counter-current extraction chamber where additional contact with ACT*DE*CON solution occurred, followed by a rinse cycle. During this process sand was added to aid contact of the solution with the soil particles. The sand is removed during the rinse step and reused. The chelating agent is separated from the contaminant and recycled back into the process, along with the reverse osmosis permeate. The resulting solution can be further treated to concentrate the contaminant. Three different types of environmental soils were tested -- plutonium and thorium contaminated soils with the natural clay content, and plutonium contaminated soils with a high percentage of fine clay particles. The goal of these tests was to reduce the plutonium levels from several hundreds of pCi/g to between 25 and 75 pCi/g and the thorium from a couple hundred pCi/g to less than 5 pCi/g. The results of these four tests are presented along with a discussion of the operating parameters and the lessons learned relating to full scale implementation at Mound as well as other potential applications of this process.

  8. CX-009212: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Replace Three Wood Poles-In-Kind at Bryan Mound West Gate CX(s) Applied: B1.3 Date: 08/23/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  9. CX-011848: Categorical Exclusion Determination

    Energy.gov [DOE]

    Bryan Mound Upgrade Wood to Steel Light Poles CX(s) Applied: B1.3 Date: 02/14/2014 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  10. CX-006600: Categorical Exclusion Determination

    Energy.gov [DOE]

    Bryan Mound Site Building Upgrades, Phase IICX(s) Applied: B1.3Date: 07/12/2011Location(s): Freeport, TexasOffice(s): Strategic Petroleum Reserve Field Office

  11. CX-008350: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Re-work Bryan Mound 30 Crude Oil Pipeline Mainline Valves CX(s) Applied: B1.3 Date: 04/10/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  12. CX-013886: Categorical Exclusion Determination

    Energy.gov [DOE]

    Remove Oil from Bryan Mound Crude Oil Tank BMT-4 Sump CX(s) Applied: B1.3Date: 07/06/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  13. CX-014107: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Windows on Big Hill and Bryan Mound Entry Portal Buildings CX(s) Applied: B1.3Date: 08/03/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  14. v7DOE OIG SemiAnn RPT.qxd

    Office of Environmental Management (EM)

    A barge shown docked at Phillips Terminal at the Strategic Petroleum Reserve in Bryan Mound, Texas. Wind turbines at Storm Lake, Iowa. High pressure water being used to blast salt ...

  15. CX-009218: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Sparge Piping at Bryan Mound Raw Water Intake Structure CX(s) Applied: B1.3 Date: 09/20/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  16. CX-007513: Categorical Exclusion Determination

    Energy.gov [DOE]

    Record of Categorical Exclusion for Driver Inspection of Bryan Mound 36 inch Raw Water Pipeline CX(s) Applied: B1.3 Date: 12/20/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  17. CX-009509: Categorical Exclusion Determination

    Energy.gov [DOE]

    Power Monitoring, Communication and Control Upgrade at Bryan Mound Degas Plant (Install) CX(s) Applied: B1.7 Date: 10/31/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  18. CX-014467: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clean Bryan Mound Crude Oil Tank, BMT-4 (BM-MM-738B) CX(s) Applied: B1.3Date: 11/11/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  19. CX-009792: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Video Inspection of Bryan Mound 36-inch Raw Water Pipeline CX(s) Applied: B1.3 Date: 01/07/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  20. CX-009511: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Alternate Source of Firewater at Bryan Mound CX(s) Applied: B5.2 Date: 11/05/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  1. CX-012731: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Windows of Bryan Mound Portal Building #281 CX(s) Applied: B1.3Date: 41884 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  2. CX-014288: Categorical Exclusion Determination

    Energy.gov [DOE]

    Dredging of Bryan Mound Raw Water Intake Structure Inlet Channel CX(s) Applied: B1.3Date: 09/28/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  3. CX-013883: Categorical Exclusion Determination

    Energy.gov [DOE]

    Clean Bryan Mound Crude Oil Tank, BMT-4 CX(s) Applied: B1.3Date: 07/06/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  4. EIS-0075: Final Environmental Impact Statement

    Energy.gov [DOE]

    Petroleum Reserve Phase III Development, Texoma and Seaway Group Salt Domes (West Hackberry and Bryan Mound Expansion, Big Hill Development) Cameron Parish, Louisiana, and Brazoria and Jefferson Counties, Texas

  5. Mortality Among Mound Workers Exposed to Polonium-210 and Other Sources of Radiation, 1944–1979

    SciTech Connect

    Boice, John D.; Cohen, Sarah S.; Mumma, Michael T.; Ellis, Elizabeth Dupree; Cragle, Donna L.; Eckerman, Keith F.; Wallace, Phillip W.; Chadda, Bandana; Sonderman, Jennifer S.; Wiggs, Laurie D.; Richter, Bonnie S.; Leggett, Richard W.

    2014-02-14

    Polonium-210 is a naturally occurring radioactive element that decays by emitting an alpha particle. It is in the air we breathe and also a component of tobacco smoke. Polonium-210 is used as an anti-static device in printing presses and gained widespread notoriety in 2006 after the poisoning and subsequent death of a Russian citizen in London. More is known about the lethal effects of polonium-210 at high doses than about late effects from low doses. In this paper, cancer mortality was examined among 7,270 workers at the Mound nuclear facility near Dayton, OH where polonium-210 was used (1944–1972) in combination with beryllium as a source of neutrons for triggering nuclear weapons. Other exposures included external gamma radiation and to a lesser extent plutonium-238, tritium and neutrons. Vital status and cause of death was determined through 2009. Standardized mortality ratios (SMRs) were computed for comparisons with the general population. Lifetime occupational doses from all places of employment were sought and incorporated into the analysis. Over 200,000 urine samples were analyzed to estimate radiation doses to body organs from polonium and other internally deposited radionuclides. Cox proportional hazards models were used to evaluate dose-response relationships for specific organs and tissues. Vital status was determined for 98.7% of the workers of which 3,681 had died compared with 4,073.9 expected (SMR 0.90; 95% CI 0.88–0.93). The mean dose from external radiation was 26.1 mSv (maximum 939.1 mSv) and the mean lung dose from external and internal radiation combined was 100.1 mSv (maximum 17.5 Sv). Among the 4,977 radiation workers, all cancers taken together (SMR 0.86; 95% CI 0.79–0.93), lung cancer (SMR 0.85; 95% CI 0.74–0.98), and other types of cancer were not significantly elevated. Cox regression analysis revealed a significant positive dose-response trend for esophageal cancer [relative risk (RR) and 95% confidence interval at 100 mSv of 1

  6. Mortality Among Mound Workers Exposed to Polonium-210 and Other Sources of Radiation, 1944–1979

    DOE PAGES [OSTI]

    Boice, John D.; Cohen, Sarah S.; Mumma, Michael T.; Ellis, Elizabeth Dupree; Cragle, Donna L.; Eckerman, Keith F.; Wallace, Phillip W.; Chadda, Bandana; Sonderman, Jennifer S.; Wiggs, Laurie D.; et al

    2014-02-14

    Polonium-210 is a naturally occurring radioactive element that decays by emitting an alpha particle. It is in the air we breathe and also a component of tobacco smoke. Polonium-210 is used as an anti-static device in printing presses and gained widespread notoriety in 2006 after the poisoning and subsequent death of a Russian citizen in London. More is known about the lethal effects of polonium-210 at high doses than about late effects from low doses. In this paper, cancer mortality was examined among 7,270 workers at the Mound nuclear facility near Dayton, OH where polonium-210 was used (1944–1972) in combinationmore » with beryllium as a source of neutrons for triggering nuclear weapons. Other exposures included external gamma radiation and to a lesser extent plutonium-238, tritium and neutrons. Vital status and cause of death was determined through 2009. Standardized mortality ratios (SMRs) were computed for comparisons with the general population. Lifetime occupational doses from all places of employment were sought and incorporated into the analysis. Over 200,000 urine samples were analyzed to estimate radiation doses to body organs from polonium and other internally deposited radionuclides. Cox proportional hazards models were used to evaluate dose-response relationships for specific organs and tissues. Vital status was determined for 98.7% of the workers of which 3,681 had died compared with 4,073.9 expected (SMR 0.90; 95% CI 0.88–0.93). The mean dose from external radiation was 26.1 mSv (maximum 939.1 mSv) and the mean lung dose from external and internal radiation combined was 100.1 mSv (maximum 17.5 Sv). Among the 4,977 radiation workers, all cancers taken together (SMR 0.86; 95% CI 0.79–0.93), lung cancer (SMR 0.85; 95% CI 0.74–0.98), and other types of cancer were not significantly elevated. Cox regression analysis revealed a significant positive dose-response trend for esophageal cancer [relative risk (RR) and 95% confidence interval at 100 m

  7. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  8. Development of bushings and bearings for use in hot brine pumps

    SciTech Connect

    Hosang, George W.; Stetson, Alvin, R.

    1982-10-08

    The exploitation of geothermal resources often requires that naturally heated subterranean brines be pumped to the surface from depths of up to 6000 feet underground while minimizing heat losses and maintaining sufficient fluid pressure to prevent boiling. To accomplish this requires the use of downhole brine pumps capable of months of uninterrupted operation. Significant problems have occurred with pump lineshaft bearings in the geothermal wells. The objective of this research program was to determine the nature of the problems associated with commonly reported premature failures of downhole lineshaft pump bearings. Using the information gathered, a series of bearing endurance tests was performed on a variety of candidate bearing materials. These tests were accomplished using test rigs specially developed to simulate actual geothermal field conditions and to isolate specific bearing wear problems.

  9. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    SciTech Connect

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.

    1982-01-01

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  10. Comparison of selected oil-field brines from fields in the Permian basin, West Texas-southeast New Mexico

    SciTech Connect

    White, H.G. III

    1992-04-01

    Stiff diagrams of oil-field brines from the west Texas Permian basin are identifiable within the geological framework. Plotted from a simple analysis of three cations and three anions, older Paleozoic waters can be categorized as either 'pristine' or modified, usually by a later influx of Permian or early Pennsylvanian water. These different plots can be segregated by geologic province. The Permian brines differ by age and also by environment (shelf, basin, etc.).

  11. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOEpatents

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  12. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOEpatents

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  13. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE PAGES [OSTI]

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore » control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  14. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at a proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ

  15. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  16. Assessment of Contaminated Brine Fate and Transport in MB139 at WIPP

    SciTech Connect

    Kuhlman, Kristopher L.; Malama, Bwalya

    2014-07-01

    Following the radionuclide release event of February 14, 2014 at the Waste Isolation Pilot Plant (WIPP), actinide contamination has been found on the walls and floor in Panel 7 as a result of a release in Room 7 of Panel 7. It has been proposed to decontaminate Panel 7 at the WIPP by washing contaminated surfaces in the underground with fresh water. A cost-effective cleanup of this contamination would allow for a timely return to waste disposal operations at WIPP. It is expected that the fresh water used to decontaminate Panel 7 will flow as contaminated brine down into the porosity of the materials under the floor – the run-of-mine (ROM) salt above Marker Bed 139 (MB139) and MB139 itself – where its fate will be controlled by the hydraulic and transport properties of MB139. Due to the structural dip of MB139, it is unlikely that this brine would migrate northward towards the Waste-Handling Shaft sump. A few strategically placed shallow small-diameter observation boreholes straddling MB139 would allow for monitoring the flow and fate of this brine after decontamination. Additionally, given that flow through the compacted ROM salt floor and in MB139 would occur under unsaturated (or two-phase) conditions, there is a need to measure the unsaturated flow properties of crushed WIPP salt and salt from the disturbed rock zone (DRZ).

  17. Operating Experience Summary, 2015-02

    Office of Environmental Management (EM)

    Energy 4-02 - April 23, 2014 Operating Experience Summary - 2014-02 - April 23, 2014 April 23, 2014 OE Summary 2014-02 Inside this issue: Laboratory Worker Safety: Work Planning, Hazard Analysis, and Supervision - Page 1 Accident Investigation into Mower Fatality at the Bryan Mound Site - Page 13 Operating Experience Summary - 2014-02 - April 23, 2014 (3.61 MB) More Documents & Publications Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound

  18. Strategic Plan for Groundwater Monitoring at the Waste Isolation Pilot Plant

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Reserves » Strategic Petroleum Reserve Strategic Petroleum Reserve Crude oil pipes at the Bryan Mound site, the largest of the four SPR storage sites - near Freeport, TX. Crude oil pipes at the Bryan Mound site, the largest of the four SPR storage sites - near Freeport, TX. The Strategic Petroleum Reserve (SPR) is the world's largest supply of emergency crude oil. The federally-owned oil stocks are stored in huge underground salt caverns along the coastline of the Gulf of Mexico. Decisions to

  19. RealGasBrine v1.0 option of TOUGH+ v1.5

    Energy Science and Technology Software Center

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRANmore » 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.« less

  20. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally

  1. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE PAGES [OSTI]

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir

  2. Larry Bryan | Savannah River Ecology Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Barn swallows as biological indicators Contaminant uptake by grackles nesting in coal Combustion waste impoundments Aquatic ecology Characterization of aquatic species ...

  3. Bryan Long (Acting) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    support; Project Management Office (PMO) support; and commodity IT services and infrastructure services supporting mission IT and corporate applications enterprise-wide. ...

  4. Wet processing of palladium for use in the tritium facility at Westinghouse, Savannah River, SC. Preparation of palladium using the Mound Muddy Water process

    SciTech Connect

    Baldwin, D.P.; Zamzow, D.S.

    1998-11-10

    Palladium used at Savannah River for tritium storage is currently obtained from a commercial source. In order to better understand the processes involved in preparing this material, Savannah River is supporting investigations into the chemical reactions used to synthesize this material and into the conditions necessary to produce palladium powder that meets their specifications. This better understanding may help to guarantee a continued reliable source for this material in the future. As part of this evaluation, a work-for-others contract between Westinghouse Savannah River Company and the Ames Laboratory Metallurgy and Ceramics Program was initiated. During FY98, the process for producing palladium powder developed in 1986 by Dan Grove of Mound Applied Technologies (USDOE) was studied to understand the processing conditions that lead to changes in morphology in the final product. This report details the results of this study of the Mound Muddy Water process, along with the results of a round-robin analysis of well-characterized palladium samples that was performed by Savannah River and Ames Laboratory. The Mound Muddy Water process is comprised of three basic wet chemical processes, palladium dissolution, neutralization, and precipitation, with a number of filtration steps to remove unwanted impurity precipitates.

  5. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect

    Burnett, David

    2012-12-31

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field

  6. Geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro basin, Texas

    SciTech Connect

    Langmuir, D.; Melchior, D.

    1985-11-01

    The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin of north Texas, was studied to define geochemical controls on radionuclides such as /sup 90/Sr and /sup 226/Ra. Published solubility data for gypsum, anhydrite, celestite, barite and RaSO/sub 4/ were first reevaluated, in most cases using the ion interaction approach of Pitzer, to determine solubility products of the sulfates as a function of temperature and pressure. Ionic strengths of the brines were from 2.9 to 4.8 m, their temperatures and pressures up to 40/sup 0/C and 130 bars. Saturation indices of the sulfates were computed with the ion-interaction approach in one brine from the arkosic granite wash facies and four from the carbonate Wolfcamp Formation. All five brines are saturated with respect to gypsum, anhydrite and celestite, and three of the five with respect to barite. All are undersaturated by from 5 to 6 orders of magnitude with respect to pure RaSO/sub 4/. /sup 226/Ra concentrations in the brines, which ranged from 10/sup -11.3/ to 10/sup -12.7/ m, are not controlled by RaSO/sub 4/ solubility or adsorption, but possibly by the solubility of trace Ra solid solutions in sulfates including celestite and barite.

  7. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  8. Brine migration test for Asse Mine, Federal Republic of Germany: final test plan

    SciTech Connect

    Not Available

    1983-07-01

    The United States and the Federal Republic of Germany (FRG) will conduct a brine migration test in the Asse Salt Mine in the FRG as part of the US/FRG Cooperative Radioactive Waste Management Agreement. Two sets of two tests each will be conducted to study both liquid inclusion migration and vapor migration in the two salt types chosen for the experiments: (1) pure salt, for its characteristics similar to the salt that might occur in potential US repositories, and (2) transitional salt, for its similarity to the salt that might occur in potential repositories in Germany.

  9. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect

    1997-10-01

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  10. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE PAGES [OSTI]

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  11. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  12. Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981

    SciTech Connect

    Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

    1982-07-01

    The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

  13. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  14. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program.

    SciTech Connect

    Kuhlman, Kristopher L

    2014-09-01

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  15. Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report

    SciTech Connect

    Coyle, A.J.; Eckert, J.; Kalia, H.

    1987-01-01

    This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

  16. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  17. THE ROLE OF LAND USE IN ENVIRONMENTAL DECISION MAKING AT THREE DOE MEGA-CLEANUP SITES FERNALD & ROCKY FLATS & MOUND

    SciTech Connect

    JEWETT MA

    2011-01-14

    This paper explores the role that future land use decisions have played in the establishment of cost-effective cleanup objectives and the setting of environmental media cleanup levels for the three major U.S. Department of Energy (DOE) sites for which cleanup has now been successfully completed: the Rocky Flats, Mound, and Fernald Closure Sites. At each site, there are distinct consensus-building histories throughout the following four phases: (1) the facility shut-down and site investigation phase, which took place at the completion of their Cold War nuclear-material production missions; (2) the decision-making phase, whereby stakeholder and regulatory-agency consensus was achieved for the future land-use-based environmental decisions confronting the sites; (3) the remedy selection phase, whereby appropriate remedial actions were identified to achieve the future land-use-based decisions; and (4) the implementation phase, whereby the selected remedial actions for these high-profile sites were implemented and successfully closed out. At each of the three projects, there were strained relationships and distrust between the local community and the DOE as a result of site contamination and potential health effects to the workers and local residents. To engage citizens and interested stakeholder groups - particularly in the role of final land use in the decision-making process, the site management teams at each respective site developed new public-participation strategies to open stakeholder communication channels with site leadership, technical staff, and the regulatory agencies. This action proved invaluable to the success of the projects and reaching consensus on appropriate levels of cleanup. With the implementation of the cleanup remedies now complete, each of the three DOE sites have become models for future environmental-remediation projects and associated decision making.

  18. Environmental Assessment for the Operation of the Glass Melter Thermal Treatment Unit at the US Department of Energy`s Mound Plant, Miamisburg, Ohio

    SciTech Connect

    1995-06-01

    The glass melter would thermally treat mixed waste (hazardous waste contaminated with radioactive constituents largely tritium, Pu-238, and/or Th-230) that was generated at the Mound Plant and is now in storage, by stabilizing the waste in glass blocks. Depending on the radiation level of the waste, the glass melter may operate for 1 to 6 years. Two onsite alternatives and seven offsite alternatives were considered. This environmental assessment indicates that the proposed action does not constitute a major Federal action significantly affecting the human environment according to NEPA, and therefore the finding of no significant impact is made, obviating the need for an environmental impact statement.

  19. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  20. Evaluation of materials for systems using cooled, treated geothermal or high-saline brines

    SciTech Connect

    Suciu, D.F.; Wikoff, P.M.

    1982-09-01

    Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

  1. Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

    DOE PAGES [OSTI]

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

  2. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  3. Multicomponent Seismic Analysis and Calibration to Improve Recovery from Algal Mounds: Application to the Roadrunner/Towaoc area of the Paradox Basin, UTE Mountain UTE Reservation, Colorado

    SciTech Connect

    Joe Hachey

    2007-09-30

    The goals of this project were: (1) To enhance recovery of oil contained within algal mounds on the Ute Mountain Ute tribal lands. (2) To promote the use of advanced technology and expand the technical capability of the Native American Oil production corporations by direct assistance in the current project and dissemination of technology to other Tribes. (3) To develop an understanding of multicomponent seismic data as it relates to the variations in permeability and porosity of algal mounds, as well as lateral facies variations, for use in both reservoir development and exploration. (4) To identify any undiscovered algal mounds for field-extension within the area of seismic coverage. (5) To evaluate the potential for applying CO{sub 2} floods, steam floods, water floods or other secondary or tertiary recovery processes to increase production. The technical work scope was carried out by: (1) Acquiring multicomponent seismic data over the project area; (2) Processing and reprocessing the multicomponent data to extract as much geological and engineering data as possible within the budget and time-frame of the project; (3) Preparing maps and data volumes of geological and engineering data based on the multicomponent seismic and well data; (4) Selecting drilling targets if warranted by the seismic interpretation; (5) Constructing a static reservoir model of the project area; and (6) Constructing a dynamic history-matched simulation model from the static model. The original project scope covered a 6 mi{sup 2} (15.6 km{sup 2}) area encompassing two algal mound fields (Towaoc and Roadrunner). 3D3C seismic data was to acquired over this area to delineate mound complexes and image internal reservoir properties such as porosity and fluid saturations. After the project began, the Red Willow Production Company, a project partner and fully-owned company of the Southern Ute Tribe, contributed additional money to upgrade the survey to a nine-component (3D9C) survey. The purpose

  4. REE Sorption Study on sieved -50 +100 mesh fraction of Media #1 in Brine #1 with Different Starting pH's at 70C

    DOE Data Explorer

    Gary Garland

    2015-09-29

    This is a continuation of the REE sorption study for shaker bath tests on 2g media #1 in 150mL brine #1 with different starting pH's at 70C. In a previous submission we reported data for shaker bath tests for brine #1 with starting pH's of 3.5, 4.5 and 5.5. In this submission we these pH's compared to starting brine #1 pH's of 6, and 7.

  5. Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds. Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters

    SciTech Connect

    Lutken, Carol; Macelloni, Leonardo; D'Emidio, Marco; Dunbar, John; Higley, Paul

    2015-01-31

    This study was designed to investigate temporal variations in hydrate system dynamics by measuring changes in volumes of hydrate beneath hydrate-bearing mounds on the continental slope of the northern Gulf of Mexico, the landward extreme of hydrate occurrence in this region. Direct Current Resistivity (DCR) measurements were made contemporaneously with measurements of oceanographic parameters at Woolsey Mound, a carbonate-hydrate complex on the mid-continental slope, where formation and dissociation of hydrates are most vulnerable to variations in oceanographic parameters affected by climate change, and where changes in hydrate stability can readily translate to loss of seafloor stability, impacts to benthic ecosystems, and venting of greenhouse gases to the water-column, and eventually, the atmosphere. We focused our study on hydrate within seafloor mounds because the structurally-focused methane flux at these sites likely causes hydrate formation and dissociation processes to occur at higher rates than at sites where the methane flux is less concentrated and we wanted to maximize our chances of witnessing association/dissociation of hydrates. We selected a particularly well-studied hydrate-bearing seafloor mound near the landward extent of the hydrate stability zone, Woolsey Mound (MC118). This mid-slope site has been studied extensively and the project was able to leverage considerable resources from the team’s research experience at MC118. The site exhibits seafloor features associated with gas expulsion, hydrates have been documented at the seafloor, and changes in the outcropping hydrates have been documented, photographically, to have occurred over a period of months. We conducted observatory-based, in situ measurements to 1) characterize, geophysically, the sub-bottom distribution of hydrate and its temporal variability, and 2) contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents) to

  6. MOUND Environmental Restoration Program

    Office of Legacy Management (LM)

    ... Th de two aboveground propane tanks (Building 43 tank and' Building nk) and two piec ... The sandblasting operations were part of the cleaning of the large clariflocculator tanks ...

  7. Mound History and Information

    Office of Legacy Management (LM)

    weapons, devel- opment of radioisotopic thermoelectric generators used to provide electrical power for space exploration, and other non-nuclear research and development activities. ...

  8. Radioactive waste isolation in salt: geochemistry of brine in rock salt in temperature gradients and gamma-radiation fields - a selective annotated bibliography

    SciTech Connect

    Hull, A.B.; Williams, L.B.

    1985-07-01

    Evaluation of the extensive research concerning brine geochemistry and transport is critically important to successful exploitation of a salt formation for isolating high-level radioactive waste. This annotated bibliography has been compiled from documents considered to provide classic background material on the interactions between brine and rock salt, as well as the most important results from more recent research. Each summary elucidates the information or data most pertinent to situations encountered in siting, constructing, and operating a mined repository in salt for high-level radioactive waste. The research topics covered include the basic geology, depositional environment, mineralogy, and structure of evaporite and domal salts, as well as fluid inclusions, brine chemistry, thermal and gamma-radiation effects, radionuclide migration, and thermodynamic properties of salts and brines. 4 figs., 6 tabs.

  9. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    SciTech Connect

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in

  10. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    DOE PAGES [OSTI]

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additionalmore » wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7

  11. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  12. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    SciTech Connect

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extraction control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing Area of Review, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.

  13. Experimental Study of Porosity Changes in Shale Caprocks Exposed to Carbon Dioxide-Saturated Brine II: Insights from Aqueous Geochemistry

    DOE PAGES [OSTI]

    Miller, Quin R. S.; Wang, Xiuyu; Kaszuba, John P.; Mouzakis, Katherine M.; Navarre-Sitchler, Alexis K.; Alvarado, Vladimir; McCray, John E.; Rother, Gernot; Bañuelos, José Leobardo; Heath, Jason E.

    2016-07-18

    Laboratory experiments evaluated two shale caprock formations, the Gothic Shale and Marine Tuscaloosa Formation, at conditions relevant to carbon dioxide (CO2) sequestration. Both rocks were exposed to CO2-saturated brines at 160°C and 15 MPa for ~45 days. Baseline experiments for both rocks were pressurized with argon to 15 MPa for ~35 days. Varying concentrations of iron, aqueous silica, sulfate, and initial pH decreases coincide with enhanced carbonate and silicate dissolution due to reaction between CO2-saturated brine and shale. Saturation indices were calculated and activity diagrams were constructed to gain insights into sulfate, silicate, and carbonate mineral stabilities. We found thatmore » upon exposure to CO2-saturated brines, the Marine Tuscaloosa Formation appeared to be more reactive than the Gothic Shale. Evolution of aqueous geochemistry in the experiments is consistent with mineral precipitation and dissolution reactions that affect porosity. Finally, this study highlights the importance of tracking fluid chemistry to clarify downhole physicochemical responses to CO2 injection and subsequent changes in sealing capacity in CO2 storage and utilization projects.« less

  14. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  15. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the

  16. Technology transfer report: feasibility study for the use of geothermal brine in the Ashdod area, Israel

    SciTech Connect

    Benson, S.M.

    1984-08-01

    The hydrothermal potential of the Ashdod area, Israel, was evaluated to determine its suitability as the low grade energy source required to operate the Ashdod desalination plant. An estimated 1250 cubic meters per hour of 120/sup 0/C brine would be adequate to supply the hot water necessary for operating the desalination plant. Considerable interest in oil exploration in the Ashdod area resulted in the drilling of six wells into the Jurassic formations by Oil Exploration (Investments) Ltd. (OEL) in 1976-1980. A small amount of oil was found in two wells, Ashdod 2 and 5. The remaining wells were abandoned as ''dry holes''. Evaluation of the drill cuttings, cores, and the electric logs defined two lithologic units of potential interest for hydrothermal exploitation, the Zohar and Shderot Dolomites. Investigation of the hydrothermal potential of the Jurassic formations underlying the Ashdod area has revealed that the aquifer temperatures range between 85 and 92/sup 0/C. The hydrologic parameters are not well defined; however the matrix permeability of the dolomites and limestones is probably between 1 and 10 md. This is insufficient permeability for a large scale pumping operation such as the one required to operate the desalination plant. Therefore, successful utilization of the resource requires the presence of significant fractures and/or connected vugs in the formation. The very low well productivity and formation plugging may indicate that permeability of the fracture zones may easily be impaired, suggesting that the fracture zones are not suitable production intervals. Until a test is conducted on a properly completed well, it is not possible to evaluate the deliverability of wells tapping these aquifers. 14 refs., 8 figs.

  17. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE PAGES [OSTI]

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  18. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  19. The implications of UIC and NPDES regulations on selection of disposal options for spent geothermal brine

    SciTech Connect

    1982-07-01

    This document reviews and evaluates the various options for the disposal of geothermal wastewater with respect to the promulgated regulations for the protection of surface and groundwaters. The Clean Water Act of 1977 and the Safe Drinking Water Act Amendments are especially important when designing disposal systems for geothermal fluids. The former promulgates regulations concerning the discharge of wastewater into surface waters, while the latter is concerned with the protection of ground water aquifers through the establishment of underground injection control (UIC) programs. There is a specific category for geothermal fluid discharge if injection is to be used as a method of disposal. Prior to February 1982, the UIC regulations required geothermal power plant to use Class III wells and direct use plants to use Class V wells. More stringent regulatory requirements, including construction specification and monitoring, are imposed on the Class III wells. On February 3, 1982, the classification of geothermal injection wells was changed from a Class III to Class V on the basis that geothermal wells do not inject for the extraction of minerals or energy, but rather they are used to inject brines, from which heat has been extracted, into formations from which they were originally taken. This reclassification implies that a substantial cost reduction will be realized for geothermal fluid injection primarily because well monitoring is no longer mandatory. The Clean Water Act of 1977 provides the legal basis for regulating the discharge of liquid effluent into the nation's surface waters, through a permitting system called the National Pollution Discharge Elimination System (NPDES) Discharge quantities, rates, concentrations and temperatures are regulated by the NPDES permits. These permits systems are based upon effluent guidelines developed by EPA on an industry by industry basis. For geothermal energy industry, effluent guidelines have not been formulated and are not

  20. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel

  1. Evaporite Caprock Integrity. An experimental study of reactive mineralogy and pore-scale heterogeneity during brine-CO2 exposure

    DOE PAGES [OSTI]

    Smith, Megan M.; Sholokhova, Yelena; Hao, Yue; Carroll, Susan A.

    2012-07-25

    Characterization and geochemical data are presented from a core-flooding experiment on a sample from the Three Fingers evaporite unit forming the lower extent of caprock at the Weyburn-Midale reservoir, Canada. This low-permeability sample was characterized in detail using X-ray computed microtomography before and after exposure to CO 2-acidified brine, allowing mineral phase and voidspace distributions to be quantified in three dimensions. Solution chemistry indicated that CO 2-acidified brine preferentially dissolved dolomite until saturation was attained, while anhydrite remained unreactive. Dolomite dissolution contributed to increases in bulk permeability through the formation of a localized channel, guided by microfractures as well asmore » porosity and reactive phase distributions aligned with depositional bedding. An indirect effect of carbonate mineral reactivity with CO 2-acidified solution is voidspace generation through physical transport of anhydrite freed from the rock matrix following dissolution of dolomite. The development of high permeability fast pathways in this experiment highlights the role of carbonate content and potential fracture orientations in evaporite caprock formations considered for both geologic carbon sequestration and CO 2-enhanced oil recovery operations.« less

  2. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  3. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    SciTech Connect

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  4. EVALUATIONS OF RADIONUCLIDES OF URANIUM, THORIUM, AND RADIUM ASSOCIATED WITH PRODUCED FLUIDS, PRECIPITATES, AND SLUDGES FROM OIL, GAS, AND OILFIELD BRINE INJECTION WELLS IN MISSISSIPPI

    SciTech Connect

    Charles Swann; John Matthews; Rick Ericksen; Joel Kuszmaul

    2004-03-01

    Naturally occurring radioactive materials (NORM) are known to be produced as a byproduct of hydrocarbon production in Mississippi. The presence of NORM has resulted in financial losses to the industry and continues to be a liability as the NORM-enriched scales and scale encrusted equipment is typically stored rather than disposed of. Although the NORM problem is well known, there is little publically available data characterizing the hazard. This investigation has produced base line data to fill this informational gap. A total of 329 NORM-related samples were collected with 275 of these samples consisting of brine samples. The samples were derived from 37 oil and gas reservoirs from all major producing areas of the state. The analyses of these data indicate that two isotopes of radium ({sup 226}Ra and {sup 228}Ra) are the ultimate source of the radiation. The radium contained in these co-produced brines is low and so the radiation hazard posed by the brines is also low. Existing regulations dictate the manner in which these salt-enriched brines may be disposed of and proper implementation of the rules will also protect the environment from the brine radiation hazard. Geostatistical analyses of the brine components suggest relationships between the concentrations of {sup 226}Ra and {sup 228}Ra, between the Cl concentration and {sup 226}Ra content, and relationships exist between total dissolved solids, BaSO{sub 4} saturation and concentration of the Cl ion. Principal component analysis points to geological controls on brine chemistry, but the nature of the geologic controls could not be determined. The NORM-enriched barite (BaSO{sub 4}) scales are significantly more radioactive than the brines. Leaching studies suggest that the barite scales, which were thought to be nearly insoluble in the natural environment, can be acted on by soil microorganisms and the enclosed radium can become bioavailable. This result suggests that the landspreading means of scale disposal

  5. REE Sorption Study of Sieved -50 +100 mesh Media #1 in Brine #1 with Different Starting pH's at 70C

    SciTech Connect

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  6. Rare-earth elements in hot brines (165 to 190 degree C) from the Salton Sea geothermal field

    SciTech Connect

    Lepel, E.A.; Laul, J.C.; Smith, M.R.

    1988-01-01

    Rare-earth element (REE) concentrations are important indicators for revealing various chemical fractionation processes (water/rock interactions) and source region geochemistry. Since the REE patterns are characteristic of geologic materials (basalt, granite, shale, sediments, etc.) and minerals (K-feldspar, calcite, illite, epidote, etc.), their study in geothermal fluids may serve as a geothermometer. The REE study may also enable us to address the issue of groundwater mixing. In addition, the behavior of the REE can serve as analogs of the actinides in radioactive waste (e.g., neodymium is an analog of americium and curium). In this paper, the authors port the REE data for a Salton Sea Geothermal Field (SSGF) brine (two aliquots: port 4 at 165{degree}C and port 5 at 190{degree}C) and six associated core samples.

  7. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  8. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  9. Strategic petroleum reserve site environmental report for calendar year 1995

    SciTech Connect

    1996-05-31

    The purpose of this Site Environmental Report (SER) is to characterize site environmental management performance, confirm compliance with environmental standards and requirements, and highlight significant programs and efforts. Included in this report is a description of each site`s environment, an overview of the Strategic Petroleum Reserve (SPR) environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1995. Two of these highlights include decommissioning of 3 the weeks Island facility, involving the disposition of 11.6 million m{sup 3} (73 million barrels) of crude oil inventory, as well as the degasification of over 4.5 million m{sup 3} (30 million barrels) of crude oil inventory at the Bryan Mound and West Hackberry facilities. The decision to decommission the weeks Island facility is a result of diminishing mine integrity from ground water intrusion. Transfer of Weeks Island oil began in November, 1995 with 2.0 million m{sup 3} (12.5 million barrels) transferred by December 31, 1995. Degasifying the crude oil is a major pollution prevention initiative because it will reduce potentially harmful emissions that would occur during oil movements by three or more orders of magnitude. Spills to the environment, another major topic, indicates a positive trend. There were only two reportable oil and three reportable brine spills during 1995, down from a total of 10 reportable spills in 1994. Total volume of oil spilled in 1995 was 56.3 m{sup 3} (354 barrels), and the total volume of brine spilled was 131.1 m{sup 3} (825 barrels). The longer term trend for oil and brine spills has declined substantially from 27 in 1990 down to five in 1995. All of the spills were reported to appropriate agencies and immediately cleaned up, with no long term impacts observed.

  10. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  11. Bryan County, Oklahoma: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Oklahoma Bennington, Oklahoma Bokchito, Oklahoma Caddo, Oklahoma Calera, Oklahoma Colbert, Oklahoma Durant, Oklahoma Hendrix, Oklahoma Kemp, Oklahoma Kenefic, Oklahoma Mead,...

  12. Microsoft PowerPoint - 8-Mound Connector Presentation for Mound...

    Office of Legacy Management (LM)

    CONNECTOR Miamisburg-Springboro Pike and Benner Road Benner Road Miamisburg- Springboro Pike PURPOSE OF PROJECT * Improve access between the I-75Austin Boulevard interchange the ...

  13. REE Sorption Study of Seived -50 +100 Mesh Fraction of Media #1 in Brine #1 at Different Concentrations of REE at 70C

    SciTech Connect

    Gary Garland

    2015-06-29

    This dataset shows the sorption capacities of smaller grain size (-50 +100 mesh) of media #1 in brine #1 at different starting concentrations of REE's at elevated temperature of 70C. The experimental conditions are 2g of -50 +100 mesh media #1 to 150mL of REE solution at concentartions of .2ppm each, 2ppm each, and 20ppm each. The pH of the solution is 5.5, and the temperature was at 70C.

  14. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  15. 1989 Annual environmental report for the Strategic Petroleum Reserve

    SciTech Connect

    Not Available

    1990-06-01

    This report, provided annually, summarizes monitoring data collected to assess Strategic Petroleum Reserve (SPR) impacts on the environment. The report serves as a management tool for mitigating such impacts, thus serving the public interest by ensuring environmentally sound operation of the Strategic Petroleum Reserve (SPR). Included is a description of each site's environment, an overview of the SPR environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1989. The active permits and the results of the environmental monitoring program (i.e., air, surface water, groundwater, and waste discharges) are discussed by site. The quality assurance program is presented which includes results from laboratory and field audits and studies performed internally and by regulatory agencies. In general, no significant adverse environmental impact resulted from SPR activities during 1989, except for a brine release from a pipeline perforation south of the Bryan Mound site adversely affecting a small area of marsh vegetation which is recovering at this time. 22 refs., 15 figs., 17 tabs.

  16. CX-006881: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replacement of Obsolete Siemens S5-115H Programmable Logic ControllersCX(s) Applied: B1.3Date: 09/22/2011Location(s): Big Hill, Bryan Mound, West Hackberry, Louisiana, TexasOffice(s): Strategic Petroleum Reserve Field Office

  17. CX-013440: Categorical Exclusion Determination

    Energy.gov [DOE]

    Record of Categorical Exclusion Determination to Replace Piping Header at Bryan Mound RWIS and RWIP (BM-MM-1027) CX(s) Applied: B1.3Date: 02/18/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  18. CX-014462: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Oil Water Separators at Bryan Mound Caverns 1, 2, 4 and 5 - GFE (BM-MM-1203A) CX(s) Applied: B1.3Date: 12/15/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  19. CX-014463: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Oil Water Separators at Bryan Mound Caverns 1, 2, 4 and 5 - Install (BM-MM-1203) CX(s) Applied: B1.3Date: 12/15/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  20. CX-007508: Categorical Exclusion Determination

    Energy.gov [DOE]

    Record of Categorical Exclusion for Rework Bryan Mound Seaway Dock Terminal Bypass Valve MOV-C308 CX(s) Applied: B1.3 Date: 11/16/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  1. CX-012334: Categorical Exclusion Determination

    Energy.gov [DOE]

    Install Single Split System Air Conditioning Unit in Bryan Mound Building No. 281 (BM-OM-1229) CX(s) Applied: B1.4 Date: 06/30/2014 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  2. Contracts Awarded to Repurchase Oil for the Strategic Petroleum Reserve

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U. S. Department of Energy announced the award of contracts for delivery of crude oil to the Strategic Petroleum Reserve. BP Products North America, Inc., will deliver 2,197,500 barrels and Noble Americas will deliver 2,000,000 barrels to the Reserve’s Bryan Mound site in Freeport, Texas. Deliveries are expected to be completed by July 31, 2015.

  3. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  4. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE PAGES [OSTI]

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  5. Finding of No Significant Impact and Final Environmental Assessment for the Future Location of Heat Source/Radioisotope Power System Assembly and Testing and Operations Currently Located at the Mound Site

    SciTech Connect

    N /A

    2002-08-30

    The U.S. Department of Energy (the Department) has completed an Environmental Assessment for the Future Location of the Heat Source/Radioisotope Power System Assembly and Test. Operations Currently Located at the Mound Site. Based on the analysis in the environmental assessment, the Department has determined that the proposed action, the relocation of the Department's heat source and radioisotope power system operations, does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the ''National Environmental Policy Act'' of 1969 (NEPA). Therefore, the preparation of an Environmental Impact Statement is not required, and the Department is issuing this Finding of No Significant Impact (FONSI).

  6. International shipment of light weight radioisotopic heater units (LWRHU) using the USA/9516/B(U)F Mound 1 kW shipping package in support of the {open_quotes}Pluto Express{close_quotes} mission

    SciTech Connect

    Barklay, C.D.; Merten, C.W.

    1997-01-01

    Radioisotopes have provided heat that has been used to maintain specific operating environments within remote satellites and spacecraft. For the {open_quotes}Pluto Express{close_quotes} mission the {sup 238}PuO{sub 2} fueled light weight radioisotopic heater unit (LWRHU) will be used within the spacecraft. Since the current plan for the {open_quotes}Pluto Express{close_quotes} mission incorporates the use of a Russian launch platform for the spacecraft, the LWRHUs must be transported in an internationally certified shipping container. An internationally certified shipping package that is versatile enough to be reconfigured to transport the LWRHUs that will be required to support the {open_quotes}Pluto Express{close_quotes} mission is the Mound USA/9516/B(U)F. {copyright} {ital 1997 American Institute of Physics.}

  7. Strategic Petroleum Reserve Site Environmental Report for calendar year 1994

    SciTech Connect

    1995-05-31

    The purpose of this Site Environmental Report (SER) is to characterize site environmental management performance, confirm compliance with environmental standards and requirements, and highlight significant programs and efforts. The SER, provided annually in accordance with Department of Energy DOE Order 5400.1, serves the public by summarizing monitoring data collected to assess how the Strategic Petroleum Reserve (SPR) impacts the environment. This report (SER) provides a balanced synopsis of non-radiological monitoring and regulatory compliance data and affirms that the SPR has been operating within acceptable regulatory limits. Included in this report is a description of each site`s environment, an overview of the SPR environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1994. Two of these highlights include decommissioning of the Weeks Island facility (disposition of 73 million barrels of crude oil inventory) as well as the degasification of up to 144 million barrels of crude oil inventory at the Bayou Choctaw, Big Hill, Bryan Mound, and West Hackberry facilities. The decision to decommission the Weeks Island facility is a result of diminishing mine integrity from ground water intrusion. Degasifying the crude oil is required to reduce potentially harmful emissions that would occur during oil movements. With regard to still another major environmental action, 43 of the original 84 environmental findings from the 1992 DOE Tiger Team Assessment were closed by the end of 1994. Spills to the environment, another major topic, indicates a positive trend. Total volume of oil spilled in 1994 was only 39 barrels, down from 232 barrels in 1993, and the total volume of brine spilled was only 90 barrels, down from 370 barrels in 1993. The longer term trend for oil and brine spills has declined substantially from 27 in 1990 down to nine in 1994.

  8. Accident Investigation of the February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA

    Energy.gov [DOE]

    On February 15, 2013, an Accident Investigation Board (the Board) was appointed to investigate an accident that resulted in serious injuries caused when a scissor lift tipped over in Brine Tank-14 (WHT-14) at the Strategic Petroleum Reserve, West Hackberry, Louisiana, site on February 7, 2013. The Board’s responsibilities have been completed with respect to this investigation. The analysis and the identification of the direct cause, root causes, contributing causes, and judgments of need resulting from this investigation were performed in accordance with the Department of Energy (DOE) Order 225.1B, Accident Investigations.

  9. Evaluations of Radionuclides of Uranium, Thorium, and Radium Associated with Produced Fluids, Precipitates, and Sludges from Oil, Gas, and Oilfield Brine Injection Wells in Mississippi

    SciTech Connect

    Ericksen, R.L.

    1999-10-28

    There is an unsurpassed lack of scientific data with respect to the concentrations and isotopic compositions of uranium, thorium, and radium in the produced formation fluids (brine), precipitates, and sludges generated with the operation of oil and gas wells in Mississippi. These radioactive elements when contained in the formation fluids have been given the term NORM, which is an acronym for naturally occurring radioactive materials. When they are technologically enhanced during oil and gas production activities resulting in the formation of scale (precipitates) and sludges they are termed TENORM (technologically enhanced naturally occurring radioactive materials). As used in this document, NORM and TENORM will be considered equivalent terms and the occurrence of NORM in the oilfield will be considered the result of production operations. As a result of the lack of data no scientifically sound theses may be developed concerning the presence of these radionuclides in the fluid brine, precipitate (scale), or sludge phases. Over the period of just one year, 1997 for example, Mississippi produced over 39,372,963,584 liters (10,402,368,186 gallons or 247,675,433 barrels) of formation water associated with hydrocarbon production from 41 counties across the state.

  10. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    SciTech Connect

    Hobart, D.E.; Bruton, C.J.; Millero, F.J.; Chou, I.M.; Trauth, K.M.; Anderson, D.R.

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer`s equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs.

  11. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  12. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  13. An objective rapid screening tool for surfactants used in foam-like dispersions of CO{sub 2} into Permian Basin brines

    SciTech Connect

    Horton, R.L.; Wicks, J.P.; Prieditis, J.; Turbeville, J.B.

    1995-11-01

    Foam-like dispersions of CO{sub 2} into brines can reduce the mobility of drive fluids in CO{sub 2} floods. To evaluate the effectiveness of such foam-like dispersions, time-consuming laboratory coreflood tests are routinely used. Because of the costliness of such coreflood tests, simple qualitative tests have long been employed to screen potential surfactants. Then only a few of the better candidates are subsequently evaluated in coreflood tests. There are a number of disadvantages of such qualitative tests; therefore the authors developed, instead, a quantitative screening process. Their quantitative process is based on two simple, quick laboratory tests and a neural network interpretation of the test data. The neural network predicted CO{sub 2} mobility reduction values which correlated well with the mobility reductions seen in coreflood tests.

  14. Alternative methods for dispoal of low-level radioactive wastes. Task 1. Description of methods and assessment of criteria. [Alternative methods are belowground vaults, aboveground vaults; earth mounded concrete bunkers, mined cavities, augered holes

    SciTech Connect

    Bennett, R.D.; Miller, W.O.; Warriner, J.B.; Malone, P.G.; McAneny, C.C.

    1984-04-01

    The study reported herein contains the results of Task 1 of a four-task study entitled Criteria for Evaluating Engineered Facilities. The overall objective of this study is to ensure that the criteria needed to evaluate five alternative low-level radioactive waste (LLW) disposal methods are available to the Nuclear Regulatory Commission (NRC) and the Agreement States. The alternative methods considered are belowground vaults, aboveground vaults, earth mounded concrete bunkers, mined cavities, and augered holes. Each of these alternatives is either being used by other countries for low-level radioactive waste (LLW) disposal or is being considered by other countries or US agencies. In this report the performance requirements are listed, each alternative is described, the experience gained with its use is discussed, and the performance capabilities of each method are addressed. Next, the existing 10 CFR Part 61 Subpart D criteria with respect to paragraphs 61.50 through 61.53, pertaining to site suitability, design, operations and closure, and monitoring are assessed for applicability to evaluation of each alternative. Preliminary conclusions and recommendations are offered on each method's suitability as an LLW disposal alternative, the applicability of the criteria, and the need for supplemental or modified criteria.

  15. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Suns model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  16. Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance

    SciTech Connect

    Not Available

    1993-08-01

    Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

  17. Property:Incentive/OwnRenewEnrgyCrdts | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Ridge EMC Bryan Texas Utilities - Solar Hot Water Rebate Program (Texas) + Bryan Texas Utility Bryan Texas Utilities - Solar PV Rebate Program (Texas) + Bryan Texas Utilities...

  18. West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report

    SciTech Connect

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

  19. The deep hydrogeologic flow system underlying the Oak Ridge Reservation -- Assessing the potential for active groundwater flow and origin of the brine

    SciTech Connect

    Nativ, R.; Halleran, A.; Hunley, A.

    1997-08-01

    The deep hydrogeologic system underlying the Oak Ridge Reservation (ORR) contains contaminants such as radionuclides, heavy metals, nitrates, and organic compounds. The groundwater in the deep system is saline and has been considered to be stagnant in previous studies. This study was designed to address the following questions: is groundwater in the deep system stagnant; is contaminant migration controlled by diffusion only or is advection a viable mechanism; where are the potential outlet points? On the basis of existing and newly collected data, the nature of saline groundwater flow and potential discharge into shallow, freshwater systems was assessed. Data used for this purpose included (1) spatial and temporal pressures and hydraulic heads measured in the deep system, (2) hydraulic parameters of the formations in question, (3) spatial and temporal temperature variations at depth, and (4) spatial and temporal chemical and isotopic composition of the saline groundwater. The observations suggest that the saline water contained at depth is old but not isolated (in terms of recharge and discharge) from the overlying active, freshwater-bearing units. Influx of recent water does occur. Groundwater volumes involved in this flow are likely to be small. The origin of the saline groundwater was assessed by using existing and newly acquired chemical and isotopic data. The proposed model that best fits the data is modification of residual brine from which halite has been precipitated. Other models, such as ultrafiltration and halite dissolution, were also evaluated.

  20. Use of data obtained from core tests in the design and operation of spent brine injection wells in geopressured or geothermal systems

    SciTech Connect

    Jorda, R.M.

    1980-03-01

    The effects of formation characteristics on injection well performance are reviewed. Use of data acquired from cores taken from injection horizons to predict injectivity is described. And methods for utilizing data from bench scale testing of brine and core samples to optimize injection well design are presented. Currently available methods and equipment provide data which enable the optimum design of injection wells through analysis of cores taken from injection zones. These methods also provide a means of identifying and correcting well injection problems. Methods described in this report are: bulk density measurement; porosity measurement; pore size distribution analysis; permeability measurement; formation grain size distribution analysis; core description (lithology) and composition; amount, type and distribution of clays and shales; connate water analysis; consolidatability of friable reservoir rocks; grain and pore characterization by scanning electron microscopy; grain and pore characterization by thin section analysis; permeability damage and enhancement tests; distribution of water-borne particles in porous media; and reservoir matrix acidizing effectiveness. The precise methods of obtaining this information are described, and their use in the engineering of injection wells is illustrated by examples, where applicable. (MHR)

  1. 'Chemistry Summit' Aids Idaho Waste Treatment Facility Startup |

    Energy Saver

    Front Cover From left to right: A barge shown docked at Phillips Terminal at the Strategic Petroleum Reserve in Bryan Mound, Texas. Wind turbines at Storm Lake, Iowa. High pressure water being used to blast salt cake into manageable fragments in a waste tank mockup at the Hanford Site. The McNary Dam, which is one entity of the Bonneville Power Administration's responsibility for transmission and wholesale marketing of power generated at dams in the Federal River Power System. A sodium cooled

  2. CX-009717: Categorical Exclusion Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    717: Categorical Exclusion Determination CX-009717: Categorical Exclusion Determination Pumping System for 100 MBD Cavern Capacity Maintenance CX(s) Applied: B1.15 Date: 12/12/2012 Location(s): Texas, Louisiana, Texas Offices(s): Strategic Petroleum Reserve Field Office Subcontractor shall provide all labor, tools, materials, equipment, services, transportation, storage and supervision required to install new Variable Frequency Drive (VFD) buildings at the Big Hill (BH), Bryan Mound (BM), and

  3. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  4. {gamma}-Radiolysis of NaCl Brine in the Presence of UO{sub 2}(s): Effects of Hydrogen and Bromide

    SciTech Connect

    Metz, Volker; Bohnert, Elke; Kelm, Manfred; Schild, Dieter; Kienzler, Bernhard

    2007-07-01

    A concentrated NaCl solution was {gamma}-irradiated in autoclaves under a pressure of 25 MPa. A set of experiments were conducted in 6 mol (kg H{sub 2}O){sup -1} NaCl solution in the presence of UO{sub 2}(s) pellets; in a second set of experiments, {gamma}-radiolysis of the NaCl brine was studied without UO{sub 2}(s). Hydrogen, oxygen and chlorate were formed as long-lived radiolysis products. Due to the high external pressure, all radiolysis products remained dissolved. H{sub 2} and O{sub 2} reached steady state concentrations in the range of 5.10{sup -3} to 6.10{sup -2} mol (kg H{sub 2}O){sup -1} corresponding to a partial gas pressure of {approx}2 to {approx}20 MPa. Radiolytic formation of hydrogen and oxygen increased with the concentration of bromide added to solution. Both, in the presence of bromide, resulting in a relatively high radiolytic yield, and in the absence of bromide surfaces of the UO{sub 2}(s) samples were oxidized, and concentration of dissolved uranium reached the solubility limit of the schoepite / NaUO{sub 2}O(OH)(cr) transition. At the end of the experiments, the pellets were covered by a surface layer of a secondary solid phase having a composition close to Na{sub 2}U{sub 2}O{sub 7}. The experimental results demonstrate that bromide counteracts an H{sub 2} inhibition effect on radiolysis gas production, even at a concentration ratio of [H{sub 2}] / [Br{sup -}] > 100. The present observations are related to the competitive reactions of OH radicals with H{sub 2}, Br{sup -} and Cl{sup -}. A similar competition of hydrogen and bromide, controlling the yield of {gamma}-radiolysis products, is expected for solutions of lower Cl{sup -} concentration. (authors)

  5. Mound_2000_Risk_Management.pdf

    Office of Legacy Management (LM)

  6. DOE - Office of Legacy Management -- Mound Site

    Office of Legacy Management (LM)

    The site long-term monitoring responsibility transferred to the Office of Legacy Management(LM) in 2010 and requires operation and maintenance of a pump and treatment system, ...

  7. Microsoft PowerPoint - Bryan Hydro Conf 11 Jun 09.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    power, regulation of Red River flows, improvement of navigation, and recreation. ... Exceeded compliance goals. 4-year averages exceed compliance goals. - Red River: 625 ...

  8. Microsoft PowerPoint - 2-ECA Mound Presentation - Kirshenberg...

    Office of Legacy Management (LM)

    agreements, tax credits) What Do Communities Want? * Assets - Use Existing PolicyLaw and Models - Land - Technology * Support and Commitment - DOE taking steps to implement ...

  9. Mound Plant Federal Facility Agreement, July 15, 1993 Summary

    Office of Environmental Management (EM)

    Actions (IRAs) alternatives and implement US EPA and OEPA approved remedies for the site in accordance with CERCLA Parties EPA; Ohio EPA (OEPA); DOE Date 07151993 SCOPE * ...

  10. Mound Plant Director's Final Findings and Orders, October 4,...

    Office of Environmental Management (EM)

    portions of the STP, public notice by the Ohio EPA of availability of the revised STP, and consultation by Ohio EPA with affected states and U.S. EPA, pursuant to these ...

  11. Mound Plant Director's Final Findings and Orders, October 4,...

    Office of Environmental Management (EM)

    Director's Final Findings and Orders State Ohio Agreement Type Compliance Agreement Legal Driver(s) FFCAct Scope Summary Approve the Compliance Plan Volume of the amended PSTP, ...

  12. Microsoft PowerPoint - 3-ARI presentation - Mound - Tania Smith

    Office of Legacy Management (LM)

    ... chips for the lab's biomass facility RSI Brightfield and Vis Solis provide energy via solar demonstration projects Environmental Dimensions Inc. (EDi), a woman-owned ...

  13. Mound Site Five-Year Review Appendix A Community Notification...

    Office of Legacy Management (LM)

    ... Federal Government The White House USA.gov Services Sites Mission News About Us Page 1 of ... Between January and June 2016, DOE will review relevant documents and data; conduct site ...

  14. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    Listings and Photos of Monitoring Wells and Seeps This page intentionally left blank U.S. Department of Energy Annual Assessment of the Effectiveness of Site-Wide Institutional ...

  15. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    U.S. Department of Energy Doc. No. S07757 June 2011 Page B-2 U.S. Department of Energy Annual Assessment of the Effectiveness of Site-Wide Institutional Controls June 2011 Doc. ...

  16. Mound Plant Federal Facility Agreement, July 15, 1993

    Office of Environmental Management (EM)

  17. Microsoft PowerPoint - 4b-Mound Reindustrilaization Workshop...

    Office of Legacy Management (LM)

    Hanford 3000 Area Transferred by Maritime Administration to Port of Benton Richland Innovation (Industrial) Center Home to 18 Companies Tri-Cities Research District Long History ...

  18. Microsoft Word - S07757_2011 Mound IC Report

    Office of Legacy Management (LM)

    Department of Energy Annual Assessment of the Effectiveness of Site-Wide Institutional ... the Effectiveness of Site-Wide Institutional Controls U.S. Department of Energy Doc. No. ...

  19. Rock-brine chemical interactions. Final report

    SciTech Connect

    Not Available

    1982-02-01

    The results of experimental interaction of powdered volcanic rock with aqueous solutions are presented at temperatures from 200 to 400/sup 0/C, 500 to 1000 bars fluid pressure, with reaction durations of approximately 30 days under controlled laboratory conditions. The aim of this research is to develop data on the kinetics and equilibria of rock solution interactions that will provide insight into the complex geochemical processes attending geothermal reservoir development, stimulation, and reinjection. The research was done in the Stanford Hydrothermal Lab using gold cell equipment of the Dickson design. This equipment inverts the solution rock mixture several times a minute to ensure thorough mixing. Solution samples were periodically withdrawn without interruption of the experimental conditions. The data from these experiments suggests a path dependent series of reactions by which geothermal fluids might evolve from meteoric or magmatic sources.

  20. Development Operations Hypersaline Geothermal Brine Utilization...

    OpenEI (Open Energy Information) [EERE & EIA]

    Abstract NA Authors Whitescarver and Olin D. Published U.S. Department of Energy, 1984 Report Number NA DOI Not Provided Check for DOI availability: http:crossref.org...

  1. additive manufacturuing | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Laboratory engineer Bryan Moran won an award last month for his 3D printing innovation. It could revolutionize additive manufacturing.Lawrence Livermore Lab engineer Bryan Moran...

  2. Construction of hexahedral elements mesh capturing realistic geometries of Bayou Choctaw SPR site

    SciTech Connect

    Park, Byoung Yoon; Roberts, Barry L.

    2015-09-01

    The three-dimensional finite element mesh capturing realistic geometries of Bayou Choctaw site has been constructed using the sonar and seismic survey data obtained from the field. The mesh is consisting of hexahedral elements because the salt constitutive model is coded using hexahedral elements. Various ideas and techniques to construct finite element mesh capturing artificially and naturally formed geometries are provided. The techniques to reduce the number of elements as much as possible to save on computer run time with maintaining the computational accuracy is also introduced. The steps and methodologies could be applied to construct the meshes of Big Hill, Bryan Mound, and West Hackberry strategic petroleum reserve sites. The methodology could be applied to the complicated shape masses for not only various civil and geological structures but also biological applications such as artificial limbs.

  3. Cultural resources survey and assessment of the proposed Department of Energy Freeport to Texas City pipeline, Brazoria and Galveston Counties, Texas. Final report

    SciTech Connect

    Castille, G.J.; Whelan, J.P. Jr.

    1986-01-01

    An intensive survey and testing program of selected segments of a proposed Department of Energy pipeline were conducted by Coastal Environments, Inc., Baton Rouge, Louisiana, during December 1985 and January 1986. The proposed pipeline runs from Texas City, Galveston County to Bryan Mound, Brazoria County. The pedestrian survey was preceded by historical records survey to locate possible historic sites within the DOE righ-of-way. Four prehistoric sites within the ROW (41BO159, 160, 161, 162) and one outside the ROW (41BO163) were located. All are Rangia cuneata middens. The survey results are discussed with particular reference to the environmental settings of the sites and the effectiveness of the survey procedure. Two of the sites located within the ROW were subjected to additional testing. The results of the backhoe testing program are included in the site descriptions, and the scientific value of the sites are presented. 52 refs., 20 figs., 10 tabs.

  4. Environmental assessment of oil degasification at four Strategic Petroleum Reserve facilities in Texas and Louisiana

    SciTech Connect

    Not Available

    1994-09-01

    The U.S. Department of Energy (DOE) proposes to treat gassy oil at four Strategic Petroleum Reserve (SPR) storage sites to lower the gas content of the stored crude oil and help ensure safe transfer of the oil during drawdown. The crude oil is stored underground in caverns created in salt domes. The degree of gassiness of the oil varies substantially among sites and among caverns within a site. This environmental assessment describes the proposed degasification operation, its alternatives, and potential environmental impacts. The need for degasification has arisen because over time, gases, principally methane and nitrogen, have migrated into and become dissolved in the stored crude oil. This influx of gas has raised the crude oil vapor pressure above limits required by safety and emission guidelines. When oil is drawn from the caverns, excess gases may come out of solution. Based on preliminary data from an ongoing sampling program, between 200 and 350 million of the 587 million barrels of crude oil stored at these four sites would require processing to remove excess gas. Degasification, a commonly used petroleum industry process, would be done at four crude oil storage facilities: Bryan Mound and Big Hill in Texas, and West Hackberry and Bayou Choctaw in Louisiana. DOE would use a turnkey services contract for engineering, procurement, fabrication, installation, operation and maintenance of two degasification plants. These would be installed initially at Bryan Mound and West Hackberry. Degasification would be complete in less than three years of continuous operations. This report summarizes the environmental impacts of this gasification process.

  5. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Peer-review under responsibility of the Organizing Committee of GHGT-12 doi: 10.1016j.egy... + ajkXjXj + ai>i,kXi2, where i 1,22 and jl,22 and k 1,37 The goodness-of-fit (R2) ...

  6. GEOTHERMAL ENERGY; 59 BASIC BIOLOGICAL SCIENCES; BRINES; DETOXIFICATIO...

    Office of Scientific and Technical Information (OSTI)

    PROCESSING; BACTERIA; BIOCHEMISTRY; BIOREACTORS; BIOTECHNOLOGY; GEOCHEMISTRY; GEOTHERMAL ENERGY; METALS; SLUDGES; TOXIC MATERIALS; CHEMISTRY; ELEMENTS; ENERGY; ENERGY SOURCES;...

  7. Expediting the commercial disposal option: Low-level radioactive waste shipments from the Mound Plant

    SciTech Connect

    Rice, S.; Rothman, R.

    1995-12-31

    In April, Envirocare of Utah, Inc., successfully commenced operation of its mixed waste treatment operation. A mixed waste which was (a) radioactive, (b) listed as a hazardous waste under the Resource Conservation and Recovery Act (RCRA), and (c) prohibited from land disposal was treated using Envirocare`s full-scale Mixed Waste Treatment Facility. The treatment system involved application of chemical fixation/stabilization technologies to reduce the leachability of the waste to meet applicable concentration-based RCRA treatment standards. In 1988, Envirocare became the first licensed facility for the disposal of naturally occurring radioactive material. In 1990, Envirocare received a RCRA Part B permit for commercial mixed waste storage and disposal. In 1994, Envirocare was awarded a contract for the disposal of DOE mixed wastes. Envirocare`s RCRA Part B permit allows for the receipt, storage, treatment, and disposal of mixed wastes that do not meet the land-disposal treatment standards of 40 CFR (Code of Federal Regulations) 268. Envirocare has successfully received, managed, and disposed of naturally occurring radioactive material, low-activity radioactive waste, and mixed waste from government and private generators.

  8. Closure of Project Chariot Soil Disposal Mound and Cesium 137 Plot.

    Office of Legacy Management (LM)

  9. Five-Year Review Report Fourth Five-Year Review for the Mound...

    Office of Legacy Management (LM)

    ... of, to the extent permitted by applicable law, utilities at reasonable cost, to the State ... of, to the extent permitted by applicable law, utilities at reasonable cost to Gran tor. ...

  10. Mound Facility activities in chemical and physical research: July-December 1979

    SciTech Connect

    Not Available

    1980-06-18

    Research is reported in the following fields: isotope separation (Ar, C, He, Kr, Ne, O, Xe), low-temperature research (H intermolecular potential functions, gas analysis in trennschaukel), separation chemistry (/sup 229/Th, /sup 231/Pa, /sup 230/Th, /sup 234/U), separation research (liquid thermal diffusion, Ca isotope separation, molecular beam scattering, mutual diffusion of noble gas mixtures, lithium chemical exchange with cryptands), and calculations in plutonium chemistry (algorithms, valence in natural water). (DLC)

  11. MLM-462 Contract Number AT-33-l-GtiN-53 MOUND LABORATCRY Operatsd...

    Office of Legacy Management (LM)

    ... are presented in a letter to the Chief, .4pplieS BAopbys:zs Branch, Division of Biology and Xe.lcins (see TAB D). -5- m-451 3. Prelimlnsry Work in Connection with the ...

  12. Survivability of ancient man-made earthen mounds: implications for uranium mill tailings impoundments

    SciTech Connect

    Lindsey, C.G.; Mishima, J.; King, S.E.; Walters, W.H.

    1983-06-01

    As part of a study for the Nuclear Regulatory Commission (NRC), the Pacific Northwest Laboratory (PNL) is investigating long-term stabilization techniques for uranium mill impoundments. Part of this investigation involves the design of a rock armoring blanket (riprap) to mitigate wind and water erosion of the underlying soil cover, which in turn prevents exposure of the tailings to the environment. However, the need for the armoring blanket, as well as the blanket's effectiveness, depends on the stability of the underlying soil cap (radon suppression cover) and on the tailings themselves. Compelling evidence in archaeological records suggests that large man-made earthen structures can remain sound and intact for time periods comparable to those required for the stabilization of the tailings piles if properly constructed. We present archaeological evidence on the existence and survivability of man-made earthen and rock structures through specific examples of such structures from around the world. We also review factors contributing to their survival or destruction and address the influence of climate, building materials, and construction techniques on survivability.

  13. Five-Year Review Report Fourth Five-Year Review for the Mound...

    Office of Legacy Management (LM)

    ...... 3. Tanks, Vaults, Storage Vessels X NA Good ...... 3. Tanks, Vaults, Storage Vessels NA Good ...

  14. LEGAL NOTICE for Mound Site 2016 CERCLA Five-Year Review

    Office of Legacy Management (LM)

    Groundwater monitoring plans for each remedy are approved by the regulators. ICs are legal and administrative tools incorporated into deed restrictions on future land and ...

  15. Mound activities in chemical and physical research: July-December 1982

    SciTech Connect

    Not Available

    1983-06-20

    Research is reported in the following areas: low-temperature research (kinetics of DT formation in D/sub 2/ + T/sub 2/ mixtures, calculation of charged particle density in tritium containing CT/sub 4/, deuterium triple point cell), separation research (liquid thermal diffusion of methyl chloride and bromine-81 in bromobenzene, separation of Ca and Zr isotopes, triple-pumped detector, magnesium two-phase chemical exchange, extraction columns for Ca isotope enrichment, reflux-electrochemical NO-HNO/sub 3/ chemical exchange for /sup 15/N enrichment, testing of boron phosphate for Pu adsorption), and metal hydride studies (prediction of nonmagnetic Kondo effect in metal hydrides). (DLC)

  16. Ultrasonic processor reduces drill-cuttings size and eliminates subsea mounds

    SciTech Connect

    Gaddy, D.E.

    1997-10-06

    Drill cuttings size reduction using ultrasonics eliminated a subsea clean-up and significantly reduced the environmental impact in a North Sea drilling project. Reduction in cuttings size allows for a wider areal dispersion when released into the ocean because they are held in suspension longer than larger sizes. Thus, ocean currents carry the smaller cuttings farther away from the well template, leaving a much wider footprint than larger cuttings sizes. This eliminates the pile-up of cuttings that otherwise would contaminate and harm the marine habitat.

  17. Environmental/Interest Groups

    Office of Legacy Management (LM)

    Road Springboro, OH 45066 (937) 748-4757 No email address available Mound Museum Association Dr. Don Sullenger President Mound Advanced Technology Center 720 Mound Road ...

  18. Dining - Local Information - Radiation Effects Facility / Cyclotron...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The BryanCollege station area has a wide variety of restaurants ranging from fast food to fine dining. The bryan-College station Convention and Visitors bureau has a good...

  19. Gas intrusion into SPR caverns

    SciTech Connect

    Hinkebein, T.E.; Bauer, S.J.; Ehgartner, B.L.; Linn, J.K.; Neal, J.T.; Todd, J.L.; Kuhlman, P.S.; Gniady, C.T.; Giles, H.N.

    1995-12-01

    The conditions and occurrence of gas in crude oil stored in Strategic Petroleum Reserve, SPR, caverns is characterized in this report. Many caverns in the SPR show that gas has intruded into the oil from the surrounding salt dome. Historical evidence and the analyses presented here suggest that gas will continue to intrude into many SPR caverns in the future. In considering why only some caverns contain gas, it is concluded that the naturally occurring spatial variability in salt permeability can explain the range of gas content measured in SPR caverns. Further, it is not possible to make a one-to-one correlation between specific geologic phenomena and the occurrence of gas in salt caverns. However, gas is concluded to be petrogenic in origin. Consequently, attempts have been made to associate the occurrence of gas with salt inhomogeneities including anomalies and other structural features. Two scenarios for actual gas intrusion into caverns were investigated for consistency with existing information. These scenarios are gas release during leaching and gas permeation through salt. Of these mechanisms, the greater consistency comes from the belief that gas permeates to caverns through the salt. A review of historical operating data for five Bryan Mound caverns loosely supports the hypothesis that higher operating pressures reduce gas intrusion into caverns. This conclusion supports a permeability intrusion mechanism. Further, it provides justification for operating the caverns near maximum operating pressure to minimize gas intrusion. Historical gas intrusion rates and estimates of future gas intrusion are given for all caverns.

  20. Literature Survey Concerning the Feasibility of Remedial Leach for Select Phase I Caverns

    SciTech Connect

    Weber, Paula D.; Flores, Karen A.; Lord, David L.

    2015-09-01

    Bryan Mound 5 ( BM5 ) and West Hackberry 9 ( WH9 ) have the potential to create a significant amount of new storage space should the caverns be deemed "leach - ready". This study discusses the original drilling history of the caverns, surrounding geology, current stability, and, based on this culmination of data, makes a preliminary assessment of the leach potential for the cavern. The risks associated with leaching BM5 present substantial problems for the SPR . The odd shape and large amount of insoluble material make it difficult to de termine whether a targeted leach would have the desired effect and create useable ullage or further distort the shape with preferential leaching . T he likelihood of salt falls and damaged or severed casing string is significant . In addition, a targeted le ach would require the relocation of approximately 27 MMB of oil . Due to the abundance of unknown factors associated with this cavern, a targeted leach of BM5 is not recommended. A targeted leaching of the neck of WH 9 could potentially eliminate or diminis h the mid - cavern ledge result ing in a more stable cavern with a more favorable shape. A better understanding of the composition of the surrounding salt and a less complicated leaching history yields more confidence in the ability to successfully leach this region. A targeted leach of WH9 can be recommended upon the completion of a full leach plan with consideration of the impacts upon nearby caverns .

  1. Strategic Petroleum Reserve site environmental report for calendar year 1997

    SciTech Connect

    1998-11-01

    The purpose of this Site Environmental Report (SER) is to characterize site environmental management performance, confirm compliance with environmental standards and requirements, and highlight significant programs and efforts for the US Department of Energy (DOE) Strategic Petroleum Reserve (SPR). The SER, provided annually in accordance with DOE order 5400.1, serves the public by summarizing monitoring data collected to assess how the SPR impacts the environment. The SER provides a balanced synopsis of non-radiological monitoring and regulatory compliance data and affirms that the SPR has been operating within acceptable regulatory limits. Included in this report is a describe of each site`s environment, an overview of the SPR environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1997. Two of these highlights include decommissioning of the Weeks Island site, involving the disposition of 11.6 million m{sup 3} (73 million barrels) of crude oil inventory, as well as the degasification of over 12.6 million m{sup 3} (79.3 million barrels) of crude oil inventory at the Big Hill and Bryan Mound facilities.

  2. Sonar atlas of caverns comprising the U.S. Strategic Petroleum Reserve. Volume 2, Big Hill Site, Texas.

    SciTech Connect

    Rautman, Christopher Arthur; Lord, Anna Snider

    2007-08-01

    Downhole sonar surveys from the four active U.S. Strategic Petroleum Reserve sites have been modeled and used to generate a four-volume sonar atlas, showing the three-dimensional geometry of each cavern. This volume 2 focuses on the Big Hill SPR site, located in southeastern Texas. Volumes 1, 3, and 4, respectively, present images for the Bayou Choctaw SPR site, Louisiana, the Bryan Mound SPR site, Texas, and the West Hackberry SPR site, Louisiana. The atlas uses a consistent presentation format throughout. The basic geometric measurements provided by the down-cavern surveys have also been used to generate a number of geometric attributes, the values of which have been mapped onto the geometric form of each cavern using a color-shading scheme. The intent of the various geometrical attributes is to highlight deviations of the cavern shape from the idealized cylindrical form of a carefully leached underground storage cavern in salt. The atlas format does not allow interpretation of such geometric deviations and anomalies. However, significant geometric anomalies, not directly related to the leaching history of the cavern, may provide insight into the internal structure of the relevant salt dome.

  3. Microsoft Word - NO1113_Dewatering report.doc

    Office of Legacy Management (LM)

    Dewatering Cost Estimate This page intentionally left blank Pinellas Site: Bryan Dairy Road Construction Dewatering Preliminary Layout Cost Estimate Dewatering Near Side and Far Side of Streets No. Item Qty. Unit Unit Cost Cost Cost Basis 1 6" Header w/Well Points 3 Bryan Dairy - North- No.1 A&B 200 LF $5.25 $1,050.00 Croy Dewatering 2 Bryan Dairy - North-No. 2 100 LF $5.25 $525.00 Croy Dewatering 2 Bryan Dairy - North-No. 3 520 LF $5.25 $2,730.00 Croy Dewatering 4 Bryan Dairy - South

  4. Molecular dynamics study of interfacial confinement effects of aqueous NaCl brines in nanoporous carbon

    SciTech Connect

    Wander, M. C. F.; Shuford, K. L.

    2010-12-09

    In this paper, studies of aqueous electrolyte solutions in contact with a family of porous carbon geometries using classical molecular dynamics simulations are presented. These simulations provide an atomic scale depiction of ion transport dynamics in different environments to elucidate power of aqueous electrolyte supercapacitors. The electrolyte contains alkali metal and halide ions, which allow for the examination of size trends within specific geometries as well as trends in concentration. The electrode pores are modeled as planar graphite sheets and carbon nanotubes with interstices ranging from one to four nanometers. Ordered layers form parallel to the carbon surface, which facilitates focused ion motion under slightly confining conditions. As a result, the ions diffusivities are enhanced in the direction of the slit or pore. Further confining the system leads to decreased ion diffusivities. The ions are fully hydrated in all but the smallest slits and pores with those sizes showing increased ion pairing. There is strong evidence of charge separation perpendicular to the surface at all size scales, concentrations, and ion types, providing a useful baseline for examining differential capacitance behavior and future studies on energy storage. These systems show promise as high-power electrical energy storage devices.

  5. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT-STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect

    DUNCAN JB; COOKE GA; LOCKREM LL

    2009-07-20

    This report documents the effort to sequester technetium by the use of getters, reductants (tin(II) apatite and ferrous sulfate), sorbents (A530E and A532E ion exchange resins), and cementitious waste form. The pertechnetate form of technetium is highly soluble and mobile in aerobic (oxidizing) environments.

  6. Geochemistry of Bolivian salars, Lipez, southern Altiplano: Origin of solutes and brine evolution

    SciTech Connect

    Risacher, F. ); Fritz, B. )

    1991-03-01

    This paper focuses on poorly understood processes related to saline lakes, or salars, of the southern Bolivian Altiplano. A morphologic classification system is described, and the origin of solutes in the inflow waters is discussed. Next, the actual chemical evolution of these inflow waters is compared with their theoretical evolution based on thermodynamic equilibria. The water chemistry of a specific sequence of evaporating waters is then scrutinized to determine which processes are responsible for a significant discrepancy which is apparent between the measured and the calculated evolution.

  7. Experimental investigation of brine-CO2 flow through a natural...

    Office of Scientific and Technical Information (OSTI)

    ... A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Authors: Smith, M M ; ...

  8. Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California

    SciTech Connect

    Haizlip, J.R.; Truesdell, A.H.

    1988-01-01

    Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350 C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350 C). Within this pH range, liquid at 250 C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350 C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

  9. APPLIED PHYTO-REMEDIATION TECHNIQUES USING HALOPHYTES FOR OIL AND BRINE SPILL SCARS

    SciTech Connect

    M.L. Korphage; Bruce G. Langhus; Scott Campbell

    2003-03-01

    Produced salt water from historical oil and gas production was often managed with inadequate care and unfortunate consequences. In Kansas, the production practices in the 1930's and 1940's--before statewide anti-pollution laws--were such that fluids were often produced to surface impoundments where the oil would segregate from the salt water. The oil was pumped off the pits and the salt water was able to infiltrate into the subsurface soil zones and underlying bedrock. Over the years, oil producing practices were changed so that segregation of fluids was accomplished in steel tanks and salt water was isolated from the natural environment. But before that could happen, significant areas of the state were scarred by salt water. These areas are now in need of economical remediation. Remediation of salt scarred land can be facilitated with soil amendments, land management, and selection of appropriate salt tolerant plants. Current research on the salt scars around the old Leon Waterflood, in Butler County, Kansas show the relative efficiency of remediation options. Based upon these research findings, it is possible to recommend cost efficient remediation techniques for slight, medium, and heavy salt water damaged soil. Slight salt damage includes soils with Electrical Conductivity (EC) values of 4.0 mS/cm or less. Operators can treat these soils with sufficient amounts of gypsum, install irrigation systems, and till the soil. Appropriate plants can be introduced via transplants or seeded. Medium salt damage includes soils with EC values between 4.0 and 16 mS/cm. Operators will add amendments of gypsum, till the soil, and arrange for irrigation. Some particularly salt tolerant plants can be added but most planting ought to be reserved until the second season of remediation. Severe salt damage includes soil with EC values in excess of 16 mS/cm. Operators will add at least part of the gypsum required, till the soil, and arrange for irrigation. The following seasons more gypsum will be added and as the soil EC is reduced, plants can be introduced. If rapid remediation is required, a sufficient volume of topsoil, or sand, or manure can be added to dilute the local salinity, the bulk amendments tilled into the surface with added gypsum, and appropriate plants added. In this case, irrigation will be particularly important. The expense of the more rapid remediation will be much higher.

  10. Repetitive Regeneration of Media #1 after REE Sorption from Brine #1 at 70C

    SciTech Connect

    Gary Garland

    2015-07-23

    This dataset shows the ability of media #1 to be loaded with REE's, stripped of the REE's sequestered, regenerated, and reused over many cycles.

  11. Results of investigations at the Zunil geothermal field, Guatemala: Well logging and brine geochemistry

    SciTech Connect

    Adams, A.; Dennis, B.; Van Eeckhout, E.; Goff, F.; Lawton, R.; Trujillo, P.E.; Counce, D.; Archuleta, J. ); Medina, V. . Unidad de Desarollo Geotermico)

    1991-07-01

    The well logging team from Los Alamos and its counterpart from Central America were tasked to investigate the condition of four producing geothermal wells in the Zunil Geothermal Field. The information obtained would be used to help evaluate the Zunil geothermal reservoir in terms of possible additional drilling and future power plant design. The field activities focused on downhole measurements in four production wells (ZCQ-3, ZCQ-4, ZCQ-5, and ZCQ-6). The teams took measurements of the wells in both static (shut-in) and flowing conditions, using the high-temperature well logging tools developed at Los Alamos National Laboratory. Two well logging missions were conducted in the Zunil field. In October 1988 measurements were made in well ZCQ-3, ZCQ-5, and ZCQ-6. In December 1989 the second field operation logged ZCQ-4 and repeated logs in ZCQ-3. Both field operations included not only well logging but the collecting of numerous fluid samples from both thermal and nonthermal waters. 18 refs., 22 figs., 7 tabs.

  12. Galvanic corrosion of a copper alloy in lithium bromide heavy brine environments

    SciTech Connect

    Itzhak, D.; Greenberg, T.

    1999-08-01

    Galvanic corrosion of the copper alloy 84% Cu-15% Zn-1% Ni was studied in 55 wt% lithium bromide (LiBr) environments. The galvanic couples studied were: 84% Cu-15% Zn-1% Ni-Ti2, 84% Cu-15% Zn-1% Ni-Ti7, 84% Cu-15% Zn-1% Ni-30% Cu-70% Ni, 84% Cu-15% Zn-1% Ni-Pb, 84% Cu-15% Zn-1% Ni-Ag, and 84% Cu-15% Zn-1% Ni-Sn. Potentiodynamic polarization measurements, open-circuit potential (OCP), and weight change measurements were carried out to evaluate the galvanic effect. Results indicated that Ti alloys and 30% Cu-70% Ni were the most passive alloys tested, and they behaved as cathodes. Although galvanic corrosion was expected, a negligible effect was measured because of an effective passivation layer on the surface of Ti alloys and 30% Cu-70% Ni. Pb, Ag, and Sn showed anodic behavior as compared to 84% Cu-15% Zn-1% Ni. As a result of the galvanic coupling, significant weight loss of these metals was measured. Sn was the most effective anode as compared to the other tested alloys; it acted as a sacrificial anode. Sn provided effective cathodic protection to 84% Cu-15% Zn-1% Ni in 55 wt% LiBr environments at 140 C.

  13. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential

    Energy.gov [DOE]

    Utilizing EERE funds, ElectraTherm developed a geothermal technology that will generate electricity for less than $0.06 per kilowatt hour.

  14. The role of wellbore remediation on the evolution of groundwater quality from CO? and brine leakage

    SciTech Connect

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO? in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO? mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strong correlation between cumulative injected CO? mass and maximum plume pH volumes and a positive correlation between CO? flux, cumulative injected CO?, and plume recovery times, with secondary dependence on permeability.

  15. Draft Test Plan for Brine Migration Experimental Studies in Run-of-Mine Salt Backfill

    SciTech Connect

    Jordan, Amy B.; Stauffer, Philip H.; Reed, Donald T.; Boukhalfa, Hakim; Caporuscio, Florie Andre; Robinson, Bruce Alan

    2015-02-02

    The primary objective of the experimental effort described here is to aid in understanding the complex nature of liquid, vapor, and solid transport occurring around heated nuclear waste in bedded salt. In order to gain confidence in the predictive capability of numerical models, experimental validation must be performed to ensure that (a) hydrological and physiochemical parameters and (b) processes are correctly simulated. The experiments proposed here are designed to study aspects of the system that have not been satisfactorily quantified in prior work. In addition to exploring the complex coupled physical processes in support of numerical model validation, lessons learned from these experiments will facilitate preparations for larger-scale experiments that may utilize similar instrumentation techniques.

  16. The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

    DOE PAGES [OSTI]

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

  17. EERE Success Story-Nevada: Geothermal Brine Brings Low-Cost Power...

    Energy.gov [DOE] (indexed site)

    Utilizing a 1 million EERE investment, heat from geothermal fluids-a byproduct of gold mining-will be generating electricity this year for less than 0.06 per kilowatt hour with ...

  18. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    Produced Gas Composition 2.4 The IGT Bubble Test 2.4.1 Physical Phenomena That Cause the Bubble 2.4.2 The Febuary 1 I , 1986 Bubble Test 2.4.3 The April 14, 1987 Bubble Test 2.4.4 ...

  19. Repetitive Regeneration of Media #1 in a Dynamic Column Extraction using Brine #1

    SciTech Connect

    Gary Garland

    2015-10-14

    This data is from a regeneration study from a dynamic column extraction experiment where we ran a solution of REE's through a column of media #1 then stripped the REE's off the media using 2M HNO3 solution. We then re-equilibrated the media and repeated the process of running a REE solution through the column and stripping the REE's off the media and comparing the two runs.

  20. Gas content of Gladys McCall reservoir brine (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    ... However, observed small transients in EthaneMethane and PropaneMethane ratios indicate that some free gas was produced from the near wellbore region. These results suggest that ...

  1. Staff | Energy Systems Integration | NREL

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Staff NREL's Energy Systems Integration directorate includes the Power Systems Engineering Center, Computational Science Center, Cyber-Physical Systems Security and Resilience Center, and Energy Systems Integration Facility operations staff. Photo of Bryan Hannegan Bryan Hannegan Associate Lab Director, Energy Systems Integration Dr. Bryan Hannegan leads the lab's global initiative to optimize links among electricity, fuel, thermal, water, and communication networks to enable a more sustainable

  2. Bryant Polzin | Argonne National Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Bryan Long (Acting) About Us Bryan Long (Acting) - Deputy CIO for Enterprise Operations & Shared Services Mr. Bryan K. Long is the (Acting) Deputy Chief Information Officer (OCIO) for Enterprise Operations and Shared Services at the United States Department of Energy (DOE). In this position, he is responsible for providing reliable, secure, and cost-effective information technology support services that satisfy business needs. With more than 30 years of technical implementation and

  3. Appliance Standards and Building Codes

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Team Lead - Test Procedures and Certification, Compliance, and Enforcement Ashley Armstrong, (202) 586-6590 * Lucas Adin, (202) 287-1317 * Bryan Berringer, (202) 586-0371 * Josh ...

  4. NREL to Advance Technologies for Microgrid Projects - News Releases...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    such as wind and solar energy, combined heat and power, energy storage, and demandresponse," NREL's Associate Director for Energy Systems Integration Bryan Hannegan said. ...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Sok, Devin ; Laserson, Uri ; Laserson, Jonathan ; Liu, Yi ; Vigneault, Francois ; Julien, Jean- Philippe ; Briney, Bryan ; Ramos, Alejandra ; Saye, Karen F. ; Le, Khoa ; et al ...

  6. Mr. Fred Cartwright Executive Director, Clemson University Internation...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    for Automotive Research Mr. Bryan Dods Executive & Chief Engineer GE Power & Water Mr. Tom Elswick Director of Business Development - Products & Systems Siemens Industry USA Mr. ...

  7. EIA - Energy Conferences & Presentations.

    Annual Energy Outlook

    (EIA) Speakers: Denise Bode (American Wind Energy Association) Bryan Hannegan ... University in 1995. Denise Bode, American Wind Energy Association U.S. Wind Industry: On ...

  8. Microsoft Word - Data Classification Security Framework V5.doc

    Energy.gov [DOE] (indexed site)

    2007 Security Framework for Control System Data Classification and Protection Bryan T. ... Security Framework for Control System Data Classification and Protection 2 Issued by ...

  9. "Conflict Between Economic Growth and Environmental Protection...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    9, 2012, 4:15pm Colloquia MBG Auditorium "Conflict Between Economic Growth and Environmental Protection", Dr. Bryan Czech, resident, Center for the Advancement of the Steady State...

  10. A MICROFLUIDIC PLATFORM FOR THE FLUIDIC ISOLATION AND OBSERVATION...

    Office of Scientific and Technical Information (OSTI)

    Authors: Moorman, Matthew Wallace ; James, Conrad D. ; Carson, Bryan D. ; Manginell, Ronald Paul ; Branda, Catherine 1 ; Renzi, Ronald F. 1 ; Singh, Anup K. 1 ; Martino, ...

  11. Sandia National Laboratories: News: Publications: Lab News

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    December 12, 2014 Turning biological cells to stone improves cancer and stem cell research Sandia researchers Bryan Kaehr (1815) and Kristin Meyer (1815) analyze a silicized...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Victoria (3) Iversen, Colleen M (2) Norby, Richard (2) Sullivan, Patrick F. (2) Allen, Michael F. (1) Brooks, Jonathan (1) Childs, Joanne (1) Curtis, Bryan (1) Eissenstat, David...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... channels Herbst, Daniel C. ; Witten, Thomas A. ; Tsai, Tsung-Han ; Coughlin, E. Bryan ... ; Chen, Lang ; Pasquarella, Joseph R. ; Holmes, Kathryn V. ; Li, Fang ; UMM) July 2013 ...

  14. Charles County, Maryland: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Bryans Road, Maryland Hughesville, Maryland Indian Head, Maryland La Plata, Maryland Port Tobacco Village, Maryland Potomac Heights, Maryland St. Charles, Maryland Waldorf,...

  15. Microsoft PowerPoint - SWL NERC status june 2009.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Sandra Spence * SPA Gary Cox * SWD Sherman Jones * NWD Karl Bryan * MVD Jeff Artman 5 COE Status of NERC Compliance * Current Level of USACE compliance varies per District. ...

  16. Structural basis for bifunctional peptide recognition at human...

    Office of Scientific and Technical Information (OSTI)

    Raimund ; Fromme, Petra ; Tourw, Dirk ; Schiller, Peter W. ; Roth, Bryan L. ; Ballet, Steven ; Katritch, Vsevolod ; Stevens, Raymond C. ; Cherezov , Vadim 1 ; UNC) 2 ;...

  17. Engineer develops 'leap forward' with 3D-printer | National Nuclear...

    National Nuclear Security Administration (NNSA)

    NNSA Blog Lawrence Livermore Laboratory engineer Bryan Moran won an award last month for his 3D printing innovation. It could revolutionize additive manufacturing. Lawrence ...

  18. Microsoft Word - Data Classification Security Framework V5.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    888P Unlimited Release Printed July 2007 Security Framework for Control System Data Classification and Protection Bryan T. Richardson and John Michalski Prepared by Sandia National ...

  19. Microsoft Word - S08557_PhI

    Office of Legacy Management (LM)

    Office of Legacy Management Mound, Ohio, Site Phase I Groundwater Monitoring Report ... left blank LMSMNDS08557 Office of Legacy Management Mound, Ohio, Site Phase I ...

  20. Preliminary laboratory study of plutonium-238 dissolution from Mound soil by means of the ACT*DE*CON{sup SM} process

    SciTech Connect

    Brown, K.A.; Heinrich, R.R.; Johnson, D.O.; Edgar, D.E.

    1992-04-01

    The treatment of contaminated soil presents a significant technical problem. Soil-washing and chemical-extraction methods have proven to be effective for specific applications, but a process with more comprehensive treatment properties that is both cost-effective and environmentally propitious is needed. Bradtec, Inc., has developed a process, the ACT*DE*CON{sup SM} process, that has been tested on soil contaminated with plutonium. The process effectively extracted Pu-238 after three washes, reducing the contamination levels from approximately 20 Bq/g to 1.6--1.9 Bq/g and yielding a decontamination factor ranging from 11 to 13. By using four or more ACT*DE*CON{sup SM} washes or a continuous-flow process with ACT*DE*CON{sup SM} solvents on a pilot-scale test, a target decontamination level of 0.93 Bq/g might be achievable.

  1. Preliminary laboratory study of plutonium-238 dissolution from Mound soil by means of the ACT*DE*CON sup SM process

    SciTech Connect

    Brown, K.A.; Heinrich, R.R.; Johnson, D.O.; Edgar, D.E. )

    1992-04-01

    The treatment of contaminated soil presents a significant technical problem. Soil-washing and chemical-extraction methods have proven to be effective for specific applications, but a process with more comprehensive treatment properties that is both cost-effective and environmentally propitious is needed. Bradtec, Inc., has developed a process, the ACT*DE*CON{sup SM} process, that has been tested on soil contaminated with plutonium. The process effectively extracted Pu-238 after three washes, reducing the contamination levels from approximately 20 Bq/g to 1.6--1.9 Bq/g and yielding a decontamination factor ranging from 11 to 13. By using four or more ACT*DE*CON{sup SM} washes or a continuous-flow process with ACT*DE*CON{sup SM} solvents on a pilot-scale test, a target decontamination level of 0.93 Bq/g might be achievable.

  2. EA-0821: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio

    Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to use an existing glass melter thermal treatment unit (also known as a Penberthy Pyro-Converter joule-heated glass furnace) for the...

  3. Alteration Behavior of High Burnup Spent Fuel in Salt Brine Under Hydrogen Overpressure and in Presence of Bromide

    SciTech Connect

    Loida, Andreas; Metz, Volker; Kienzler, Bernhard

    2007-07-01

    Recent studies have shown that in the presence of H2 overpressure, which forms due to the corrosion of the Fe based container, the dissolution rate of the spent fuel matrix is slowed down by a factor of about 10, associated with a distinct decrease of concentrations of important radionuclides. However, in a natural salt environment as well as in geological formations with chloride rich groundwater the presence of radiation chemically active impurities such as bromide must be taken in consideration. Bromide is known to react with {beta}/{gamma} radiolysis products, thus counteracting the protective H{sub 2} effect. In the present experiments using high burnup spent fuel, it is observed that during 212 days the matrix dissolution rate was enhanced by a factor of about 10 in the presence of up to 10{sup -3} M bromide and 3.2 bar H{sub 2} overpressure. However, concentrations of matrix bound actinides were found at the same level or below as found under identical conditions, but in the absence of bromide. In the long-term it is expected that the effect of bromide becomes less important, because the decrease of {beta}/{gamma}-activity results in a decrease of oxidative radicals, which react with bromide, while a-activity will dominate the radiation field. (authors)

  4. RealGasBrine v1.0 option of TOUGH+ v1.5 () | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Guide; Sample Problem Input Data; 1 CD-ROM Software CPU: MLTPL Open Source: No Source Code Available: Yes Research Org: Lawrence Berkeley National Laboratory Sponsoring Org: ...

  5. EIS-0302: Notice of Intent to Prepare an Environmental Impact Statement

    Office of Energy Efficiency and Renewable Energy (EERE)

    Transfer of the Heat Source / Radioisotope Themoelectric Generator Assembly and Test Operations From the Mound Site

  6. Microsoft Word - N01535_B100 Plume Delin Rpt

    Office of Legacy Management (LM)

    Building 100 Off-Site Plume Delineation South of Bryan Dairy Road Data Report for Rally Stores Property November 2010 LMS/PIN/N01535 This page intentionally left blank LMS/PIN/N01535 Pinellas Environmental Restoration Project Building 100 Area Off-Site Plume Delineation South of Bryan Dairy Road Data Report for Rally Stores Property November 2010 This page intentionally left blank U.S. Department of Energy Building 100 Area Off-Site Plume Delineation South of Bryan Dairy Road November 2010 Doc.

  7. Feasibility report on alternative methods for cooling cavern oils at the U.S. Strategic Petroleum Reserve.

    SciTech Connect

    Levin, Bruce L.; Lord, David L.; Hadgu, Teklu

    2005-06-01

    Oil caverns at the U.S. Strategic Petroleum Reserve (SPR) are subjected to geothermal heating from the surrounding domal salt. This process raises the temperature of the crude oil from around 75 F upon delivery to SPR to as high as 130 F after decades of storage. While this temperature regime is adequate for long-term storage, it poses challenges for offsite delivery, with warm oil evolving gases that pose handling and safety problems. SPR installed high-capacity oil coolers in the mid-1990's to mitigate the emissions problem by lowering the oil delivery temperature. These heat exchanger units use incoming raw water as the cooling fluid, and operate only during a drawdown event where incoming water displaces the outgoing oil. The design criteria for the heat exchangers are to deliver oil at 100 F or less under all drawdown conditions. Increasing crude oil vapor pressures due in part to methane intrusion in the caverns is threatening to produce sufficient emissions at or near 100 F to cause the cooled oil to violate delivery requirements. This impending problem has initiated discussion and analysis of alternative cooling methods to bring the oil temperature even lower than the original design basis of 100 F. For the study described in this report, two alternative cooling methods were explored: (1) cooling during a limited drawdown, and (2) cooling during a degas operation. Both methods employ the heat exchangers currently in place, and do not require extra equipment. An analysis was run using two heat transfer models, HEATEX, and CaveMan, both developed at Sandia National Laboratories. For cooling during a limited drawdown, the cooling water flowrate through the coolers was varied from 1:1 water:oil to about 3:1, with an increased cooling capacity of about 3-7 F for the test cavern Bryan Mound 108 depending upon seasonal temperature effects. For cooling in conjunction with a degas operation in the winter, cavern oil temperatures for the test cavern Big Hill 102 were

  8. Sensible Solar Fueling Energy Revolution in Georgia | Department...

    Energy.gov [DOE] (indexed site)

    Bryan says the future of American energy lies in greater usage of renewables. "Solar PV has no emissions of any kind, doesn't use water, doesn't create noise, has no waste and has ...

  9. Microsoft Word - 11-0632 Better Business Forms Data Report.doc

    Office of Legacy Management (LM)

    by Better Business Forms at 10950 Belcher Road in April 2011. The purpose of this ... on the Young - Rainey STAR Center south across Bryan Dairy Road onto private property. ...

  10. Ex Parte Memorandum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Tuesday, May 4, 2010, Kit Kennedy and Kate Houren of the Natural Resources Defense Council (NRDC) initiated a telephone call with Daniel Cohen and Bryan Miller of the Department of ...

  11. Los Alamos National Security LLC Selected to Manage Los Alamos...

    Energy Saver

    ... This is the first time since its creation that operation of the laboratory has been open to competition. Media contact(s): Anne Womack Kolton, 202586-4940 Bryan Wilkes, 202...

  12. The November WINDExchange Webinar: Offshore Wind Market Update

    Energy.gov [DOE]

    Aaron Smith, an energy analyst at the National Renewable Energy Laboratory, will present an overview and update of the U.S. offshore wind market. Stacy Tingley and Bryan Wilson of Deepwater Wind...

  13. CX-014634: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Section of Bryan Hill 36-Inch Crude Oil Pipeline at Hillebrandt Bayou CX(s) Applied: B1.3Date: 12/22/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  14. User Science Images

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    in the Pegasus Toroidal Experiment at the University of Wisconsin-Madison Author(s): John O'Bryan and Carl Sovinnec | Category: Fusion Energy | URL: http:www.cptc.wisc.edu...

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    O'Shea, Brian W. (2) Oishi, Jeffrey S. (2) Smith, Britton D. (2) Bordner, James (1) Bryan, ... Skillman, Samuel W. ; O'Shea, Brian W. ; Smith, Britton D., E-mail: stephen.skory@colorad...

  16. ENZO: AN ADAPTIVE MESH REFINEMENT CODE FOR ASTROPHYSICS (Journal...

    Office of Scientific and Technical Information (OSTI)

    Authors: Bryan, Greg L. ; Turk, Matthew J. 1 ; Norman, Michael L. ; Bordner, James ; Xu, Hao ; Kritsuk, Alexei G. 2 ; O'Shea, Brian W. ; Smith, Britton 3 ; Abel, Tom ; Wang, ...

  17. BCS Fuel Cells | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    BCS Fuel Cells Jump to: navigation, search Name: BCS Fuel Cells Place: Bryan, Texas Zip: TX 77801 Product: A privately held corporation from Texas, BCS is a developer of PEM fuel...

  18. FRED User Group

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Fuel Reliability: U.S. Leaker Status Courtesy: Mike Reitmeyer (Exelon) ... NextEra Energy 6. Security-Bryan Hanson, Exelon 7. Training-Randy Edington, APS 8. Work ...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Keith (1) Bryan Huff (1) Christina D,Moon (1) Christopher G,Knight (1) Christopher M,Thomas (1) David Williams (1) David,Harris (1) Douglas G. Patchen (1) Elizabeth,Saunders...

  20. U.S. Department of Energy N N E E W W S S For Immediate Release...

    National Nuclear Security Administration (NNSA)

    N N E E W W S S For Immediate Release Media Contact: Bryan Wilkes December 12, 2002 (202) 586-7371 Brooks Names New Diversity and Outreach Manager New diversity director hired for...

  1. Probabilistic Performance Assessment: SCC of SNF Interim Storage...

    Office of Scientific and Technical Information (OSTI)

    Probabilistic Performance Assessment: SCC of SNF Interim Storage Canisters C. Bryan1, C. ... Effect of Initial Heat Load Two alternative cases run, with 4 kW and 10 kW heat ...

  2. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Fundamental study of CO2-H2O-mineral interactions for carbon sequestration, with emphasis on the nature of the supercritical fluid-mineral interface.","Bryan, Charles R.; Dewers,...

  3. engineering

    National Nuclear Security Administration (NNSA)

    an award last month for his 3D printing innovation. It could revolutionize additive manufacturing.

    Lawrence Livermore Lab engineer Bryan Moran wasn't necessarily...

  4. additive manufacturuing

    National Nuclear Security Administration (NNSA)

    an award last month for his 3D printing innovation. It could revolutionize additive manufacturing.

    Lawrence Livermore Lab engineer Bryan Moran wasn't necessarily...

  5. EC Publications

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Sampling, Crack Growth Modeling and Experimental PlansBryan admin 2016-04-18T20:58:24+00:00 Popular Downloads Solar Energy Grid Integration Systems: Final Report of ...

  6. BPA-2014-00537-FOIA Request

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Act must be signed and, therefore, cannot be submitted on this form. Name Bryan Edwards Email Orga nizati on Mailin g Addre ss City State Phon C FAX Ex. xxx-xxx-xxxx...

  7. Document: 1095-0005 Actionee: Dorothy Riehie * Document Date...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    E. GANO JOHN K. JOHNSEN FAX (509) 453-6874 BRYAN G. EVENSON (1946-1993) SHAWN M. MURPHY MICHAEL J. THORNIER BRUCE P. HANSONOUFIENMR MEGAN K MURPHY (1922-2006)OUFIENMR 1095-0005...

  8. engineering | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Engineer develops 'leap forward' with 3D-printer Lawrence Livermore Laboratory engineer Bryan Moran won an award last month for his 3D printing innovation. It could revolutionize ...

  9. Triangle Universities Nuclear Laboratory : 2011

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Make a left onto TowerView Road and then make another left at the first stop light onto Science Dr; You should park in the Bryan Center parking Garage which is located on the...

  10. SREL Reprint #3252

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    populations from three regions of the American continent Cynthia Martins Villar1, Albert Lawrence Bryan Jr.2, Stacey Lyn Lance2, Erika Martins Braga3, Carlos Congrains1, and...

  11. SREL Reprint #3299

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    9 Precipitation influences on uptake of a global pollutant by a coastal avian species Albert L. Bryan Jr.1, Joel W. Snodgrass2, Heather A. Brant1, Christopher S. Romanek1, Charles...

  12. Sandia Energy - Nanoscale Effects on Heterojunction Electron...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    in GaNAlGaN CoreShell Nanowires" published in Nano Letters, Sandia scientist Bryan M. Wong, and EFRC scientists Franois Lonard, Qiming Li, and George T. Wang, present a...

  13. Sandia Energy - Alyssa Christy

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    in GaNAlGaN CoreShell Nanowires" published in Nano Letters, Sandia scientist Bryan M. Wong, and EFRC scientists Franois Lonard, Qiming Li, and George T. Wang, present a...

  14. Biomass Program Monthly News Blast: June

    Energy.gov [DOE] (indexed site)

    Meeting Summary, Paul Bryan, May 10, 2011 Update your subscriptions, modify your password or e-mail address, or stop subscriptions at any time on your Subscriber Preferences Page. ...

  15. Alumni | Photosynthetic Antenna Research Center

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Alumni Alumni Chi Zhao Alumnus Read more about Chi Zhao Srinivasa Rao Allu Alumnus Read more about Srinivasa Rao Allu Ran Zhang Alumnus Read more about Ran Zhang Claire Mai Read more about Claire Mai Talia Rubnitz Alumna Read more about Talia Rubnitz Bryan Fry Alumnus Read more about Bryan Fry Peter Rosenquist Alumnus Read more about Peter Rosenquist Christine Ajinjeru Alumna Read more about Christine Ajinjeru Alicia Lohman Alumna Read more about Alicia Lohman Sudipa Ghimire-Rijal Alumna Read

  16. News Item

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    , 2016 Time: 11:00 am Speaker: Bryan Huey, University of Connecticut Title: Nanoscale Investigations of Solar Cell Performance Location: 67-3111 Chemla Room Biography: Associate Professor Bryan Huey's research group develops and applies novel variations of Atomic Force Microscopy. Research projects include: Tomographic AFM Switching dynamics in ferroelectric and multiferroic materials. Piezoactuation of novel Piezoelectrics. In-situ imaging of Micro-Electro-Mechanical-Systems Nanoscale

  17. Microsoft Word - N01628_Sitewide semiannual Dec-May 2011

    Office of Legacy Management (LM)

    A Building 100 Area South Plume Data Reports Pinellas Environmental Restoration Project Building 100 Off-Site Plume Delineation South of Bryan Dairy Road Data Report for Rally Stores Property November 2010 LMS/PIN/N01535 This page intentionally left blank LMS/PIN/N01535 Pinellas Environmental Restoration Project Building 100 Area Off-Site Plume Delineation South of Bryan Dairy Road Data Report for Rally Stores Property November 2010 This page intentionally left blank U.S. Department of Energy

  18. Management Overview

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SPECTROSCOPIC ON-LINE MONITORING OF RADIOCHEMICAL STREAMS NEET Review September 17, 2014 Sam Bryan, Tatiana Levitskaia, and Amanda Casella sam.bryan@pnnl.gov Pacific Northwest National Laboratory Process Monitoring Can Be Achieved Throughout the Flowsheet Global vision: Process monitoring/control at various points in flowsheet Every flowsheet contains Raman and/or UV-vis-NIR active species Coriolis and conductivity instruments can be used on all process streams Monitoring Is Not Flowsheet

  19. Management Overview

    Office of Environmental Management (EM)

    SPECTROSCOPIC ON-LINE MONITORING OF RADIOCHEMICAL STREAMS NEET Review September 17, 2014 Sam Bryan, Tatiana Levitskaia, and Amanda Casella sam.bryan@pnnl.gov Pacific Northwest National Laboratory Process Monitoring Can Be Achieved Throughout the Flowsheet Global vision: Process monitoring/control at various points in flowsheet Every flowsheet contains Raman and/or UV-vis-NIR active species Coriolis and conductivity instruments can be used on all process streams Monitoring Is Not Flowsheet

  20. January

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    January January We are your source for reliable, up-to-date news and information; our scientists and engineers can provide technical insights on our innovations for a secure nation. Steven Conradson and Bryan Henson, new Fellows of the Chemistry Division of the American Association for the Advancement of Science (AAAS) Conradson and Henson named AAAS Fellows Steven Conradson and Bryan Henson are new Fellows of the Chemistry Division of the American Association for the Advancement of Science. -

  1. H2 @ Scale … A Potential Opportunity Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    @SCALE : Deeply Decarbonizing our Energy System U.S. Department of Energy Fuel Cell Technologies Office July 28 th , 2016 Presenter: Bryan Pivovar : National Renewable Energy Laboratory DOE Host: Erika Gupta : Fuel Cell Technologies Office 2 | Fuel Cell Technologies Office eere.energy.gov Question and Answer * Please type your questions into the question box 2 H2 at Scale FCTO Webinar July 28, 2016 3 July 28, 2016 Webinar H 2 at Scale: Deeply Decarbonizing our Energy System Presented by Bryan

  2. CX-006107: Categorical Exclusion Determination

    Energy.gov [DOE]

    Texas-City-Flower Mound, Town ofCX(s) Applied: A9, B2.5, B5.1Date: 07/11/2011Location(s): Flower Mound, TexasOffice(s): Energy Efficiency and Renewable Energy

  3. Program Update: 1st Quarter 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    Inside this update: Successful Transition from Mound Site to Mound Business Park Continues; Second Five-Year Plan to Address Uranium Contamination in the Navajo Nation; Nuclear Weapons Program...

  4. Other Stakeholders

    Office of Legacy Management (LM)

    Mound Science and Energy Museum (MSEM) 1075 Mound Road Miamisburg, Ohio 45342-6714 Website: http:www.moundmuseum.com (937) 353-4457 E-mail: msern0l @clearwire.net Mr. ...

  5. Microsoft Word - S07963_MND 5yr

    Office of Legacy Management (LM)

    blank U.S. Department of Energy Mound, Ohio, Third Five-Year Review September 2011 Doc. ... Mound, Ohio, Third Five-Year Review U.S. Department of Energy Doc. No. ...

  6. Puna Geothermal Venture 8MW Expantion | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    potential brine in a state-of-the-art binary plant, development of highly reliable brine pH monitoring and control system, and brine injection management in a high energy resource....

  7. EA-0821: Finding of No Significant Impact

    Energy.gov [DOE]

    Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio

  8. Innovative Approach Cuts Cleanup Time in Half, Potentially Saving $6

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Million | Department of Energy Cuts Cleanup Time in Half, Potentially Saving $6 Million Innovative Approach Cuts Cleanup Time in Half, Potentially Saving $6 Million October 31, 2016 - 12:05pm Addthis DOE and Mound Site personnel view an emulsified oil injection, part of SRNL's enhanced attenuation groundwater treatment approach at Mound. DOE and Mound Site personnel view an emulsified oil injection, part of SRNL's enhanced attenuation groundwater treatment approach at Mound. MIAMISBURG, Ohio

  9. EA-1438: Finding of No Significant Impact

    Energy.gov [DOE]

    Future Location of the Heat Source/Radioisotope Power System Assembly and Test Operations at the Mound Site, Miamisburg, Ohio

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... marine boundary layer (1) thorium (1) transmutation (1) transuranium ...

  11. DOE-HDBK-1079-94; Primer on Tritium Safe Handling Practices

    Office of Environmental Management (EM)

    previously developed by DOE sites (Savannah River, Rocky Flats, and Mound) and is intended ... . . . . . . 17 Bioassay and Internal Dosimetry . . . . . . . . . . . . . . . . . . . ...

  12. Experimental Study of Porosity Changes in Shale Caprocks Exposed to CO2-Saturated Brines I: Evolution of Mineralogy, Pore Connectivity, Pore Size Distribution, and Surface Area

    DOE PAGES [OSTI]

    Mouzakis, Katherine M.; Navarre-Sitchler, Alexis K.; Rother, Gernot; Bañuelos, José Leobardo; Wang, Xiuyu; Kaszuba, John P.; Heath, Jason E.; Miller, Quin R. S.; Alvarado, Vladimir; McCray, John E.

    2016-07-18

    Carbon capture, utilization, and storage, one proposed method of reducing anthropogenic emissions of CO2, relies on low permeability formations, such as shales, above injection formations to prevent upward migration of the injected CO2. Porosity in caprocks evaluated for sealing capacity before injection can be altered by geochemical reactions induced by dissolution of injected CO2 into pore fluids, impacting long-term sealing capacity. Therefore, long-term performance of CO2 sequestration sites may be dependent on both initial distribution and connectivity of pores in caprocks, and on changes induced by geochemical reaction after injection of CO2, which are currently poorly understood. This paper presentsmore » results from an experimental study of changes to caprock porosity and pore network geometry in two caprock formations under conditions relevant to CO2 sequestration. Pore connectivity and total porosity increased in the Gothic Shale; while total porosity increased but pore connectivity decreased in the Marine Tuscaloosa. Gothic Shale is a carbonate mudstone that contains volumetrically more carbonate minerals than Marine Tuscaloosa. Carbonate minerals dissolved to a greater extent than silicate minerals in Gothic Shale under high CO2 conditions, leading to increased porosity at length scales <~200 nm that contributed to increased pore connectivity. In contrast, silicate minerals dissolved to a greater extent than carbonate minerals in Marine Tuscaloosa leading to increased porosity at all length scales, and specifically an increase in the number of pores >~1 μm. Mineral reactions also contributed to a decrease in pore connectivity, possibly as a result of precipitation in pore throats or hydration of the high percentage of clays. Finally, this study highlights the role that mineralogy of the caprock can play in geochemical response to CO2 injection and resulting changes in sealing capacity in long-term CO2 storage projects.« less

  13. EFFECT OF QUARTZ/MULLITE BLEND CERAMIC ADDITIVE ON IMPROVING RESISTANCE TO ACID OF SODIUM SILICATE-ACTIVATED SLAG CEMENT. CELCIUS BRINE.

    SciTech Connect

    SUGAMA, T.; BROTHERS, L.E.; VAN DE PUTTE, T.R.

    2006-06-01

    We evaluated the usefulness of manufactured quartz/mullite blend (MQMB) ceramic powder in increasing the resistance to acid of sodium silicate-activated slag (SSAS) cementitious material for geothermal wells. A 15-day exposure to 90{sup o} CO{sub 2}-laden H{sub 2}SO{sub 4} revealed that the MQMB had high potential as an acid-resistant additive for SSAS cement. Two factors, the appropriate ratio of slag/MQMB and the autoclave temperature, contributed to better performance of MQMB-modified SSAS cement in abating its acid erosion. The most effective slag/MQMB ratio in minimizing the loss in weight by acid erosion was 70/30 by weight. For autoclave temperature, the loss in weight of 100 C autoclaved cement was a less than 2%, but at 300 C it was even lower. Before exposure to acid, the cement autoclaved at 100 C was essentially amorphous; increasing the temperature to 200 C led to the formation of crystalline analcime in the zeolitic mineral family during reactions between the mullite in MQMB and the Na from sodium silicate. In addition, at 300 C, crystal of calcium silicate hydrate (1) (CSH) was generated in reactions between the quartz in MQMB and the activated slag. These two crystalline phases (CSH and analcime) were responsible for densifying the autoclaved cement, conveying improved compressive strength and minimizing water permeability. The CSH was susceptible to reactions with H{sub 2}SO{sub 4}, forming two corrosion products, bassanite and ionized monosilicic acid. However, the uptake of ionized monosilicic acid by Mg dissociated from the activated slag resulted in the formation of lizardite as magnesium silicate hydrate. On the other hand, the analcime was barely susceptible to acid if at all. Thus, the excellent acid resistance of MQMB-modified SSAS cement was due to the combined phases of lizardite and analcime.

  14. Modeling CO{sub 2}-Brine-Rock Interaction Including Mercury and H{sub 2}S Impurities in the Context of CO{sub 2} Geologic Storage

    SciTech Connect

    Spycher, N.; Oldenburg, C.M.

    2014-01-01

    This study uses modeling and simulation approaches to investigate the impacts on injectivity of trace amounts of mercury (Hg) in a carbon dioxide (CO{sub 2}) stream injected for geologic carbon sequestration in a sandstone reservoir at ~2.5 km depth. At the range of Hg concentrations expected (7-190 ppbV, or ~ 0.06-1.6 mg/std.m{sup 3}CO{sub 2}), the total volumetric plugging that could occur due to complete condensation of Hg, or due to complete precipitation of Hg as cinnabar, results in a very small porosity change. In addition, Hg concentration much higher than the concentrations considered here would be required for Hg condensation to even occur. Concentration of aqueous Hg by water evaporation into CO{sub 2} is also unlikely because the higher volatility of Hg relative to H{sub 2}O at reservoir conditions prevents the Hg concentration from increasing in groundwater as dry CO{sub 2} sweeps through, volatilizing both H{sub 2}O and Hg. Using a model-derived aqueous solution to represent the formation water, batch reactive geochemical modeling show that the reaction of the formation water with the CO{sub 2}-Hg mixture causes the pH to drop to about 4.7 and then become buffered near 5.2 upon reaction with the sediments, with a negligible net volume change from mineral dissolution and precipitation. Cinnabar (HgS(s)) is found to be thermodynamically stable as soon as the Hg-bearing CO{sub 2} reacts with the formation water which contains small amounts of dissolved sulfide. Liquid mercury (Hg(l)) is not found to be thermodynamically stable at any point during the simulation. Two-dimensional radial reactive transport simulations of CO{sub 2} injection at a rate of 14.8 kg/s into a 400 m-thick formation at isothermal conditions of 106°C and average pressure near 215 bar, with varying amounts of Hg and H{sub 2}S trace gases, show generally that porosity changes only by about ±0.05% (absolute, i.e., new porosity = initial porosity ±0.0005) with Hg predicted to readily precipitate from the CO{sub 2} as cinnabar in a zone mostly matching the single-phase CO{sub 2} plume. The precipitation of minerals other than cinnabar, however, dominates the evolution of porosity. Main reactions include the replacement of primarily Fe-chlorite by siderite, of calcite by dolomite, and of K-feldspar by muscovite. Chalcedony is also predicted to precipitate from the dissolution of feldspars and quartz. Although the range of predicted porosity change is quite small, the amount of dissolution and precipitation predicted for these individual minerals is not negligible. These reactive transport simulations assume that Hg gas behaves ideally. To examine effects of non-ideality on these simulations, approximate calculations of the fugacity coefficient of Hg in CO{sub 2} were made. Results suggest that Hg condensation could be significantly overestimated when assuming ideal gas behavior, making our simulation results conservative with respect to impacts on injectivity. The effect of pressure on Henry’s constant for Hg is estimated to yield Hg solubilities about 10% lower than when this effect is not considered, a change that is considered too small to affect the conclusions of this report. Although all results in this study are based on relatively mature data and modeling approaches, in the absence of experimental data and more detailed site-specific information, it is not possible to fully validate the results and conclusions.

  15. Development of bushings and bearings for use in hot-brine pumps. Quarterly technical progress report No. 6, March 1-June 1, 1981

    SciTech Connect

    Not Available

    1981-06-01

    The nature of the problems associated with premature failures of downhole line shaft bearings, especially those tested in the Imperial Valley, was studied. Problem Definition is complete. Phase II, 100-hour Screening Tests, is 80 percent completed with promising results. Significant testing procedure modifications have been made and are presented.

  16. More Information on Economic Development

    Office of Legacy Management (LM)

    Mound Advanced Technology Center (MATC) is a business and scientific technology park at the Mound Site. MATC site - http://mound.com/ More Information on Economic Development at MATC: * Comprehensive Reuse Plan (future document) * Marketing Plan (future document) * Brochures (future documents) * Annual Reports (future document) * Miscellaneous Fact Sheets (future document)

  17. Passive injection: A strategy for mitigating reservoir pressurization...

    Office of Scientific and Technical Information (OSTI)

    induced seismicity and brine migration in geologic CO2 storage Citation Details ... induced seismicity and brine migration in geologic CO2 storage Authors: ...

  18. Coupled Model for Heat and Water Transport in a High Level Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    and dissolutionprecipitation of the salt in the brine inclusion are simulated; effects of initial inclusion size and temperature gradient on the brine behavior are investigated. ...

  19. Did the Mississippian Lodgepole buildup at Dickinson Field (North Dakota) form as a gas seep ({open_quotes}vent{close_quotes}) community?

    SciTech Connect

    Longman, M.W.

    1996-10-01

    The Lower Mississippian Lodgepole carbonate buildup reservoir at Dickinson Field in Stark County, North Dakota, has been widely reported as being a Waulsortian (or Waulsortian-like) mound. The term {open_quotes}Waulsortian mound{close_quotes} is used for a variety of Early Mississippian carbonate buildups that share a number of features including an abundance of carbonate mud, a {open_quotes}framework{close_quotes} of organisms such as fenestrate bryozoans and crinoids that tended to trap or baffle sediment, and a general absence of marine-cemented reef framework. Although the age of the Lodgepole mound at Dickinson Field qualifies it to be a Waulsortian mound, petrographic study of cores reveals that the reservoir rocks are quite unlike those in true Waulsortian mounds. Instead of being dominated by carbonate mud, the Lodgepole mound core is dominated by marine cement. Furthermore, ostracods and microbial limestones are common in the mound core where they occur with crinoid debris and small amounts of bryozoan, coral, and brachiopod debris. The abundant microbial limestones and marine cement indicate that the Dickinson mound formed as a lithified reef on the sea floor rather than as a Waulsortian mud mound. The microbial limestones, marine cement, and common ostracods in the mount core, and the fact that the mound nucleated almost directly o top of the Bakken Shale, suggest that the Dickinson Lodgepole mound formed at the site of a submarine spring and gas seep.

  20. ORISE receives its 12th DOE Star of Excellence Award for safety

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ORISE receives its 12th DOE Star of Excellence Award for safety FOR IMMEDIATE RELEASE October 4, 2016 FY16-50 Bryan Campbell, Brenda Longmire, Tom Wantland and Brad Davy Employees (L to R) Bryan Campbell, Brenda Longmire and Tom Wantland received DOE's Star of Excellence Award from Brad Davy (far right), DOE's director for the Office of Worker Safety and Health Assistance. Click image for full resolution version. OAK RIDGE, Tenn.-The Oak Ridge Institute for Science and Education (ORISE), which

  1. Alkaline Membrane Fuel Cell Workshop Welcome and OverviewInnovation

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Alkaline Membrane Fuel Cell Workshop Welcome and Overview Innovation for Our Energy Future Bryan Pivovar National Renewable Energy Laboratory AMFC Workshop May 8, 2011 Innovation for Our Energy Future 2 Welcome - Your participation is appreciated - Date of Workshop Innovation for Our Energy Future 3 Meeting Location Innovation for Our Energy Future Workshop Agenda SUNDAY, MAY 8, 2011 1:00 pm - 1:15 pm Welcome and Opening Remarks (Salon H) 1:15 pm - 1:45 pm Workshop Overview: Dr. Bryan Pivovar,

  2. SRS Reaches Milestone by Finishing Ash Basin Cleanup's First Phase |

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Department of Energy SRS Reaches Milestone by Finishing Ash Basin Cleanup's First Phase SRS Reaches Milestone by Finishing Ash Basin Cleanup's First Phase November 16, 2016 - 12:30pm Addthis Workers add the geosynthetic layer to the protective mound capping the dirt and coal ash landfill. Workers add the geosynthetic layer to the protective mound capping the dirt and coal ash landfill. Several layers make up the protected mound capping the landfill containing coal ash and dirt. Several

  3. Microsoft Word - S07535_2010_GW_Mon

    Office of Legacy Management (LM)

    Mound Site Phase I Groundwater Monitoring Report Calendar Year 2010 March 2011 LMS/MND/S07535 This page intentionally left blank LMS/MND/S07535 Mound Site Phase I Groundwater Monitoring Report Calendar Year 2010 March 2011 This page intentionally left blank U.S. Department of Energy Mound Site Phase I Groundwater Monitoring Report-CY 2010 March 2011 Doc. No. S07535 Page i Contents Abbreviations

  4. Microsoft Word - S08562_6_7_8_GW_021512

    Office of Legacy Management (LM)

    Mound, Ohio, Site Parcel 6, 7, and 8 Groundwater Monitoring Report Calendar Year 2011 September 2012 LMS/MND/S08562 This page intentionally left blank LMS/MND/S08562 Mound, Ohio, Site Parcel 6, 7, and 8 Groundwater Monitoring Report Calendar Year 2011 September 2012 This page intentionally left blank U.S. Department of Energy Mound, Ohio, Parcel 6, 7, and 8 Groundwater Monitoring Report CY 2011 September 2012 Doc. No. S08562 Page i Contents Abbreviations

  5. Microsoft Word - S10173_2013_Annual_IC.docx

    Office of Legacy Management (LM)

    Institutional Controls at the Mound Site Miamisburg, Ohio June 2013 LMS/MND/S10173 This page intentionally left blank LMS/MND/S10173 Annual Assessment of the Effectiveness of Institutional Controls at the Mound Site Miamisburg, Ohio June 2013 This page intentionally left blank U.S. Department of Energy Annual Assessment of the Effectiveness of Sitewide Institutional Controls, Mound Site June 2013 Doc. No. S10173 Page i Contents Abbreviations

  6. TITLEPG.PDF

    Office of Legacy Management (LM)

    Mound's Land Transfer Process December 1999 Developed by: Department of Energy -- Miamisburg Environmental Management Project, in coordination with: the United States Environmental Protection Agency, the Ohio Environmental Protection Agency, and the Miamisburg-Mound Community Improvement Corporation 1 DOE-Mound's Land Transfer Process: Supplemental Text INTRODUCTION This document provides a description of the land transfer process developed by the Department of Energy-Miamisburg Environmental

  7. Consortium for Advanced Simulation of Light Water Reactors (CASL...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    that have included management of CERCLA and RCRA remediation projects at the INL, Rocky Flats, and Mound laboratories, management of special nuclear materials at the INL, and...

  8. Preliminary Notice of Violation, Babcock & Wilcox of Ohio, Inc- EA-98-12

    Office of Energy Efficiency and Renewable Energy (EERE)

    Issued to Babcock & Wilcox of Ohio, Inc., related to Radiological Work Controls and Bioassay Program Deficiencies at the Mound Site, November 16, 1998 (EA-98-12)

  9. Listing of Defense Nuclear Facilities

    Energy Saver

    Listing of Defense Nuclear Facilities The facilities listed below are considered DOE defense nuclear facilities for purposes of Section 3161. Kansas City Plant Pinellas Plant Mound ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... August 2009 Thorium Energy Futures Peggs, Stephen ; Roser, Thomas ; Parks, G ; Lindroos, ...

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Advanced Burner Reactor with Breed-and-Burn Thorium Blankets for Improved Economics and ...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... reactor (4) bwr (4) lwr (4) nestle (4) thorium (4) Filter by Author Powers, Jeffrey J ...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Self-Sustaining Thorium Boiling Water Reactors Greenspan, Ehud ; Gorman, Phillip M. ; ...

  14. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Production of Actinium-225 via High Energy Proton Induced Spallation of Thorium-232 ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Thorium based power systems and relevant safeguards considerations Fane, Brian M ; Murphy, ...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... rods (5) reactivity (5) simulation (5) thorium (5) thorium oxides (5) control (4) mixed ...

  17. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... scenarios are typically envisioned for thorium fuel cycles: 'open' cycles based on ...

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Fission-suppressed fusion breeder on the thorium cycle and nonproliferation Moir, R. W. ...

  19. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... reactors and associated plants (1) thorium (1) thorium reactors (1) uranium (1) ...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... and associated plants (2) spectra (2) thorium (2) uranium tetrafluoride (2) void ...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Filter Results Filter by Subject fuel cycle (3) nuclear (3) thorium (3) design (2) doe (2) ...

  2. What we know today.ai

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... radioactive materials like uranium and thorium * Naturally radioactive materials are ... The short-term change maps better display the intricacies of the mound decay (blues ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Have feedback or suggestions for a way to improve these results? Thorium Energy Futures ...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... physics (2) radioactive ion beams (2) thorium (2) accelerator facilities (1) actinide ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... physics and radiation physics (2) thorium (2) vacuum (2) actinide targets (1) ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Thorium Energy Futures Peggs, Stephen ; Roser, Thomas ; Parks, G ; Lindroos, Mats ; ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... (5) fuel cycle (3) nuclear fuels (3) thorium (3) accelerator driven transmutation (2) ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... January 2008 Thorium Energy Futures Peggs, Stephen ; Roser, Thomas ; Parks, G ; Lindroos, ...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Full Text Available August 2004 Thorium Energy Futures Peggs, Stephen ; Roser, Thomas ; ...

  10. Search for: All records | SciTech Connect

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... of radioactive elements, uranium and thorium in particular, presents new challenges. ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... reactors and associated plants (1) thorium (1) transmutation (1) transuranium ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... are intended for high uranium or thorium utilization, produce fissile material ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... Filter Results Filter by Subject fuel cycle (2) nuclear (2) thorium (2) depletion (1) doe ...

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    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... and activity in the uranium and thorium decay chains - inconsequential to ...

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    Office of Scientific and Technical Information (OSTI)

    ... Center, Morgantown, WV (United States) Mound Area Office, Miamisburg, OH (United ... This report details these findings. less Full Text Available May 2014 Thorium Energy ...

  17. Microsoft Word - readingroom.docx

    Office of Legacy Management (LM)

    9/2011 Mound Public Reading Room The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Administrative Record (AR) Database will continue to be available in the Mound Public Reading Room, now located at the Mound Science and Energy Museum, located at 1075 Mound Road, Miamisburg, Ohio, 45342. The museum is open from 9:00 a.m. to 12:00 p.m. on Saturdays. You may contact the museum at (937) 353-4457 or at msern0l @clearwire.net to make an appointment to use the reading

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... States) Mound Plant, Miamisburg, OH (United States) NE-75, USDOE Office of Space and Defense Power Systems NNSA Kansas City Site Office (United States) National Energy ...

  19. Microsoft PowerPoint - Triay - EM Program Update

    Office of Environmental Management (EM)

    ... Accelerator Laboratory 8 M *Nevada Test Site 44 M *Energy Technology Engineering Center 54 M *Mound 20 M *12 States, 17 Sites UraniumThorium 69 M Management & ...

  20. Modern Geothermal Features | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    seeps (fumaroles) or pure fluid manifestations (geysers and hot springs) causing spectacular mineral formations (e.g. sinter terraces, tufa mounds). These types of...

  1. I

    National Nuclear Security Administration (NNSA)

    ... White River National Forest Terry Reetz, Black Hills National Forest Doug Schleusner, ... or earth mounds) that produce an integrated whole reflecting a primary cultural activity. ...

  2. MHK Technologies/Tidal Lagoons | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    to shape the output curve in order to dispatch power in response to demand price signals. The impoundment structure is a conventional rubble mound breakwater (loose rock,...

  3. Holt County, Missouri: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Missouri Corning, Missouri Craig, Missouri Forest City, Missouri Fortescue, Missouri Maitland, Missouri Mound City, Missouri Oregon, Missouri Retrieved from "http:en.openei.org...

  4. Preliminary Notice of Violation, EG&G Incorporated- EA-97-10

    Office of Energy Efficiency and Renewable Energy (EERE)

    Isued to EG&G Incorporated, related to Bioassay and Internal Dosimetry Program Deficiencies at the Mound Plant, (EA-97-10)

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    of Energy's (DOE) Nuclear Energy (NE) Radioisotope Power Systems (RPS) Program ... Mound Plant, Miamisburg, OH (United States) NE-75, USDOE Office of Space and Defense Power ...

  6. Madison Parish, Louisiana: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zone Subtype A. Places in Madison Parish, Louisiana Delta, Louisiana Mound, Louisiana Richmond, Louisiana Tallulah, Louisiana Retrieved from "http:en.openei.orgw...

  7. Microsoft Word - salescontract2008.docx

    Office of Legacy Management (LM)

    Sales Contract by and between the United States Department of Energy and the Miamisburg Mound Community Improvement Corporation (August 28, 2008) has been removed from the LM ...

  8. Ohio's 3rd congressional district: Energy Resources | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Institute Registered Energy Companies in Ohio's 3rd congressional district Edison Material Technology Center EMTEC JatroDiesel Miamisburg Mound Community Improvement Corp...

  9. FY 2011 Budget Request

    Energy.gov [DOE] (indexed site)

    ... Those former contractor workers are associated with the following sites: Rocky Flats, Fernald, Mound, Pinellas, Grand Junction, Portsmouth and Paducah. Under LM oversight, the ...

  10. Higher Power Energy LLC | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Higher Power Energy LLC Jump to: navigation, search Name: Higher Power Energy, LLC Place: Flower Mound, Texas Zip: 78028 Sector: Renewable Energy, Wind energy Product: Higher Power...

  11. From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits- Mound Science and Energy Museum Programs Cover a Wide Range of Topics From Hydrogen Fuel Cells to ...

  12. http://emdev.apps.em.doe.gov/EMDEV/Pages/groundwaterReport.aspx

    Office of Environmental Management (EM)

    Mound Plume Remediation Contractor: Unknown Report Last Updated: 2009 Contaminants Halogenated VOCsSVOCs Present? Yes VOC Name Concentration (ppb) Regulatory Driver Cleanup...

  13. Audit Report: IG-0501 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    and Closure of the Miamisburg Environmental Management Project With the end of the cold war, the Miamisburg Environmental Management Project (MEMP), formerly known as the Mound...

  14. Microsoft Word - S10184_GW.docx

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Sitewide Groundwater Monitoring Report, ... Groundwater Monitoring Report, CY 2012, Mound, Ohio U.S. Department of Energy Doc. No. ...

  15. 2011 Annual IC Assessment Report

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Annual Assessment of the Effectiveness of ... of Sitewide Institutional Controls, Mound Site U.S. Department of Energy Doc. No. ...

  16. SR0605

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Until recently, these drums were covered with mounds of earth at SRSs central waste management facility. The drums were generated during decades of nuclear operations at SRS. ...

  17. Tarrant County, Texas: Energy Resources | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Benbrook, Texas Blue Mound, Texas Briar, Texas Burleson, Texas Colleyville, Texas Crowley, Texas Dalworthington Gardens, Texas Edgecliff Village, Texas Euless, Texas Everman,...

  18. Corrosion Resistances of Iron-Based Amorphous Metals with Yttrium and Tungsten Additions in Hot Calcium Chloride Brine & Natural Seawater: Fe48Mo14Cr15Y2C15B6 and W-Containing Variants

    SciTech Connect

    Farmer, J C; Haslam, J; Day, S; Lian, T; Saw, C; Hailey, P; Choi, J; Yang, N; Blue, C; Peter, W; Payer, J; Branagan, D J

    2006-10-20

    Yttrium-containing SAM1651 (Fe{sub 48.0}Cr{sub 15.0}Mo{sub 14.0}B{sub 6.0}C{sub 15.0}Y{sub 2.0}), has a critical cooling rate (CCR) of approximately 80 Kelvin per second, while SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) with no yttrium has a higher critical cooling rate of approximately 600 Kelvin per second. SAM1651's low CCR enables it to be rendered as a completely amorphous material in practical materials processes. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The passive film stability of these Fe-based amorphous metal formulations have been found to be superior to that of conventional stainless steels, and comparable to that of Ni-based alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates.

  19. CX-010404: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks, Government Furnished Equipment CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  20. CX-010401: Categorical Exclusion Determination

    Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    fuel cycle and fuel materials (2) radioactive wastes (2) sensitivity (2) simulation (2) water (2) arsenic (1) bentonite (1) boom clay (1) brine leakage (1) brines (1) buffers (1)...

  2. Column Sorption Uptake and Regeneration Study; Rare Earth Element Sorbent Uptake and Sorbent Stripping

    SciTech Connect

    Tim Lanyk

    2015-12-18

    Study of rare earth element (REE) uptake from geothermal brine simulant by column loading, metal recovery through stripping, and regeneration of column for re-loading. Simulated brine testing.

  3. Geochemical engineering reference manual

    SciTech Connect

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  4. Operating Experience Summary, 2014-04

    Energy.gov [DOE] (indexed site)

    that store brine used to displace stored crude oil when the oil is withdrawn from underground caverns. The brine tanks must be repaired and repainted every 3 to 5 years to...

  5. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) Increased fracture ...

  6. The Viability of Sustainable, Self-Propping Shear Zones in Ehanced...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) 7 | US DOE Geothermal Office ...

  7. Long Term Innovative Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Long Term Innovative Technologies Long Term Innovative Technologies Presentation by Bryan Pivovar on DOE's Hydrogen and Fuel Cell Technologies, Fuel Cell Presolicitation Workshop - Lakewood, CO March 16, 2010 fuelcell_pre-solicitation_wkshop_mar10_pivovar.pdf (1.2 MB) More Documents & Publications Resonance-Stabilized Anion Exchange Polymer Electrolytes Advanced Cathode Catalysts 2016 Alkaline Membrane Fuel Cell Workshop

  8. Q&A With Byron Washom of the University of California at San Diego

    Office of Energy Efficiency and Renewable Energy (EERE)

    Bryan Washom was setting world records for efficiency in solar power long before it was cool. And now, as the Director of Strategic Initiatives at the University of California at San Diego, he's using that drive to bring clean energy technology to the marketplace.

  9. FIA-12-0001- In the Matter of Kevin Leary

    Energy.gov [DOE]

    OHA issued a decision denying a FOIA appeal filed by Kevin Leary of a final determination issued by the DOE Richland Operations Office (RO). Mr. Leary requested copies of e-mails, the associated metadata, and instant messages for Margot Voogd, Larry Romine and Bryan Foley, from August 1, 2005, through January 31, 2009.

  10. FIA-12-0001- In the Matter of Kevin Leary

    Energy.gov [DOE]

    OHA issued a decision denying a FOIA appeal filed by Kevin Leary of a final determination issued by the DOE Richland Operations Office (RO). Mr. Leary requested copies of e-mails, the associated metadata, and instant messages for Margot Voogd, Larry Romine and Bryan Foley, from August 1, 2005, through January 31, 2009. RO informed Mr. Leary that no documents existed.

  11. CX-100599 Categorical Exclusion Determination

    Energy.gov [DOE]

    Fleet Services EV Charging Station Installation, Richard H. Bryan State Office Building Award Number: DE-EE0006992 CX(s) Applied: B5.23 Weatherization & Intergovernmental Programs Office (SEP) Date: 03/31/2016 Location(s): NV Office(s): Golden Field Office

  12. A Downtown Denver Law Firm Leverages Tenant Improvement Funds to Cut Operating Expenses

    SciTech Connect

    2013-03-01

    Bryan Cave HRO (formerly Holme Roberts & Owen LLP, headquartered in Denver, Colorado), an international law firm, partnered with the U.S Department of Energy (DOE) to develop and implement solutions to retrofit existing buildings to reduce annual energy consumption by at least 30% versus pre-retrofit energy use as part of DOE’s Commercial Building Partnership (CBP) program.

  13. EA-1482: Finding of No Significant Impact

    Energy.gov [DOE]

    Pilot Experiment for Geological Sequestration of Carbon Dioxide in Saline Aquifer Brine Formations, Frio Formation, Liberty County, Texas

  14. Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources

    Energy.gov [DOE]

    Project objectives: Demonstrate a 1 megawatt Variable Phase Turbine and Variable Phase Cycle with low temperature brine.

  15. Management Overview

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... * Insignificant groundwater abundance and mobility (nominal) * Brine saturation (esp. human intrusion) Engineered Barriers * Backfill and seals * Robust containment ...

  16. Microsoft PowerPoint - Adams - American Recovery and Reinvestment...

    Office of Environmental Management (EM)

    211,775,000 211,775,000 1,325,505 Moab 108,350,000 108,350,000 6,365,420 Mound ... 309 1,491 9 Los Alamos (NM) 706 82 16 98 1 Moab (UT) 2,363 37 130 167 0 Mound (OH) 0 28 0 ...

  17. Norm removal from frac water

    DOEpatents

    Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

    2014-11-18

    A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

  18. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    SciTech Connect

    Not Available

    1991-01-01

    The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

  19. Where is the lower Leonard shelf A depositional model for the Blalock Lake Southeast and Powell 8300 fields, Glasscock County, Texas

    SciTech Connect

    Highsmith, D.L. ); Taylor, L.H. )

    1992-04-01

    Lithofacies and microfacies analysis of reservoir rocks from the Blalock Lake Southeast field indicate in-situ mound and intermound facies. Mounds grew on remnant Strawn paleohighs across a broad carbonate ramp. Two-dimensional seismic sequence stratigraphy does not confirm a well-defined shelf margin. Rocks from the Powell 8300 field are grainstone and debris-flow facies sourced from the adjacent mounds of the Blalock Lake Southeast field. The authors recognize six major lateral facies in the two field areas: the mound facies, a flanking crinoid mudstone, apron talus, intermound peloidal mudstones, capping grainstones, and downdip grainstone and debris flows. This depositional model also includes a globally documented eustatic sea level fall in the overall transgressive upper Wolfcamp - lower Leonard cycle. The perpendicular depositional trends of the mound facies and the grainstone-debris-flow facies are useful tools that can be applied to exploratory and development efforts.

  20. Evaluation of the corrosivity of dust deposited on waste packages at Yucca Mountain, Nevada.

    SciTech Connect

    Wolery, Thomas J.; Bryan, Charles R.; Barr, Deborah; Jarek, Russell L.; Hardin, Ernest L.; Shields, David R.; Sutton, Mark A.

    2005-08-01

    Potentially corrosive brines can form during post-closure by deliquescence of salt minerals in dust deposited on the surface of waste packages at Yucca Mountain during operations and the pre-closure ventilation period. Although thermodynamic modeling and experimental studies of brine deliquescence indicates that brines are likely to form, they will be nitrate-rich and noncorrosive. Processes that modify the brines following deliquescence are beneficial with respect to inhibition of corrosion. For example, acid degassing (HCl, HNO{sub 3}) could dry out brines, but kinetic limitations are likely to limit the effect to increasing their passivity by raising the pH and increasing the NO{sub 3}/Cl ratio. Predicted dust quantities and maximum brine volumes on the waste package surface are small, and physical isolation of salt minerals in the dust may inhibit formation of eutectic brines and decrease brine volumes. If brines do contact the WP surface, small droplet volumes and layer thicknesses do not support development of diffusive gradients necessary for formation on separate anodic-cathodic zones required for localized corrosion. Finally, should localized corrosion initiate, corrosion product buildup will stifle corrosion, by limiting oxygen access to the metal surface, by capillary retention of brine in corrosion product porosity, or by consumption of brine components (Cl{sup -}).