National Library of Energy BETA

Sample records for biomass fast pyrolysis

  1. Catalytic fast pyrolysis of lignocellulosic biomass (Journal...

    Office of Scientific and Technical Information (OSTI)

    Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass ...

  2. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, ...

  3. Catalytic fast pyrolysis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

    2014-11-21

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  4. Specialists' workshop on fast pyrolysis of biomass

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    This workshop brought together most of those who are currently working in or have published significant findings in the area of fast pyrolysis of biomass or biomass-derived materials, with the goal of attaining a better understanding of the dominant mechanisms which produce olefins, oxygenated liquids, char, and tars. In addition, background papers were given in hydrocarbon pyrolysis, slow pyrolysis of biomass, and techniques for powdered-feedstock preparation in order that the other papers did not need to introduce in depth these concepts in their presentations for continuity. In general, the authors were requested to present summaries of experimental data with as much interpretation of that data as possible with regard to mechanisms and process variables such as heat flux, temperatures, partial pressure, feedstock, particle size, heating rates, residence time, etc. Separate abstracts have been prepared of each presentation for inclusion in the Energy Data Base. (DMC)

  5. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis,

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hydrotreating and Hydrocracking: A Design Case | Department of Energy Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case The goal of the U.S. Department of Energy's Bioenergy Technologies Office (BETO) is to enable the development of biomass technologies. PNNL-23053.pdf (0 B) More Documents & Publications Design

  6. Transportation fuels from biomass via fast pyrolysis and hydroprocessing

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2013-09-21

    Biomass is a renewable source of carbon, which could provide a means to reduce the greenhouse gas impact from fossil fuels in the transportation sector. Biomass is the only renewable source of liquid fuels, which could displace petroleum-derived products. Fast pyrolysis is a method of direct thermochemical conversion (non-bioconversion) of biomass to a liquid product. Although the direct conversion product, called bio-oil, is liquid; it is not compatible with the fuel handling systems currently used for transportation. Upgrading the product via catalytic processing with hydrogen gas, hydroprocessing, is a means that has been demonstrated in the laboratory. By this processing the bio-oil can be deoxygenated to hydrocarbons, which can be useful replacements of the hydrocarbon distillates in petroleum. While the fast pyrolysis of biomass is presently commercial, the upgrading of the liquid product by hydroprocessing remains in development, although it is moving out of the laboratory into scaled-up process demonstration systems.

  7. Upgrading of Biomass Fast Pyrolysis Oil (Bio-oil) Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Upgrading of Biomass Fast Pyrolysis Oil (Bio-oil) March 22, 2015 Bio-Oil Technology Area Review Principal Investigator : Zia Abdullah Organization: Battelle Memorial Institute 1 Goal Statement * 1,000 hrs. TOS * H/C product 30% blendable with ASTM petroleum fuels * Compatibility with petroleum refining unit operations * Fast Pyrolysis * In-situ catalytic fast pyrolysis * Ex-situ catalytic fast pyrolysis * Hydropyrolysis * Hydrothermal liquefaction * Solvent liquefaction Addresses all FOA-

  8. Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking

    SciTech Connect (OSTI)

    Jones, S. B.; Valkenburg, C.; Walkton, C. W.; Elliott, D. C.; Holladay, J. E.; Stevens, D. J.; Kinchin, C.; Czernik, S.

    2010-02-01

    The Biomass Program develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case is the first to establish detailed cost targest for the production of diesel and gasoline blendstock from biomass via a fast pyrolysis process.

  9. Effect of torrefaction on biomass structure and hydrocarbon production from fast pyrolysis

    DOE PAGES-Beta [OSTI]

    Neupane, Sneha; Adhikari, Sushil; Wang, Zhouhong; Ragauskas, Arthur; Pu, Yunqiao

    2015-01-27

    Torrefaction has been shown to improve the chemical composition of bio-oils produced from fast pyrolysis by lowering its oxygen content and enhancing the aromatic yield. A Py-GC/MS study was employed to investigate the effect of torrefaction temperatures (225, 250 and 275 °C) and residence times (15, 30 and 45 min) on product distribution from non-catalytic and H+ZSM-5 catalyzed pyrolysis of pinewood. During torrefaction, structural transformations in biomass constitutive polymers: hemicellulose, cellulose and lignin took place, which were evaluated using component analysis, solid state CP/MAS 13C NMR and XRD techniques. Torrefaction caused deacetylation and decomposition of hemicellulose, cleavage of aryl ethermore » linkages and demethoxylation of lignin, degradation of cellulose and an overall increase in aromaticity of biomass, all of which affected the product yield from pyrolysis of torrefied biomass. For non-catalytic pyrolysis, selectivity of phenolic compounds increased with an increase in torrefaction severity while that of furan compounds decreased. In the case of catalytic pyrolysis, the sample torrefied at 225 °C-30 min and 250 °C-15 min resulted in a significant increase in aromatic hydrocarbon (HC) and also total carbon yield (approx. 1.6 times higher) as compared to catalytic pyrolysis of non-torrefied pine. Cleavage of aryl ether linkages and demethoxylation in lignin due to torrefaction caused increased yield of phenolic compounds, which in the presence of a catalyst were dehydrated to form aromatic HC.« less

  10. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    SciTech Connect (OSTI)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-25

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed

  11. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    SciTech Connect (OSTI)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-28

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps

  12. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2011 State of Technology and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Male, Jonathan L.

    2012-02-01

    Review of the the status of DOE funded research for converting biomass to liquid transportation fuels via fast pyrolysis and hydrotreating for fiscal year 2011.

  13. Report - Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    SciTech Connect (OSTI)

    Jones, S. B.; Valkenburg, C.; Walton, C. W.; Elliott, D. C.; Holladay, J. E.; Stevens, D. J.; Kinchin, C.; Czernik, S.

    2009-02-01

    The purpose of this design case study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels.

  14. Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking

    Energy.gov [DOE]

    The Biomass Program develops design cases to understand the current state of conversiontechnologies and to determine where improvements need to take place in the future. The bestavailable bench and pilot-scale conversion data are integrated with detailed process flow andengineering models to identify technical barriers where research and development could leadto significant cost improvements and to calculate production costs. Past design cases focusedon finding pathways toward cost-competitive production of ethanol. This design case is thefirst to establish detailed cost targets for the production of diesel and gasoline blendstock frombiomass via a fast pyrolysis process.

  15. Norms, Standards, and Legislation for Fast Pyrolysis Bio-oils from Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Oasmaa, Anja; van de Beld, Bert; Saari, Pia; Elliott, Douglas C.; Solantausta, Yrjo

    2015-04-16

    Fast pyrolysis of woody biomass is close to full maturity, with first-of-its-kind commercial size installations for fuel production being commissioned in Finland (Fortum) and in The Netherlands (Empyro), and in the design phase in Brazil (Ensyn). In the industrial-scale combustion tests, the use of fast pyrolysis bio-oil (FPBO) has been demonstrated to be a viable option to replace heavy fuel oil in district heating applications. Commercially usable district heating boilers and burners suitable for FPBO are available. There is research on diesel-engine and gas-turbine applications but, so far, no proven demonstrations. FPBO is completely different from mineral oils; hence, standards are needed. Analytical methods have been systematically validated and modifications to the standards as well as completely new methods have been made. Two ASTM burner fuel standards already exist and European boiler fuel grades are being developed under CEN. The focus on CEN standardization is on boiler use, because of its commercial readiness.

  16. Fast pyrolysis of tropical biomass species and influence of water pretreatment on product distributions

    DOE PAGES-Beta [OSTI]

    Morgan, Trevor James; Turn, Scott Q.; Sun, Ning; George, Anthe; Gupta, Vijai

    2016-03-15

    Here, the fast pyrolysis behaviour of pretreated banagrass was examined at four temperatures (between 400 and 600 C) and four residence times (between ~1.2 and 12 s). The pretreatment used water washing/leaching to reduce the inorganic content of the banagrass. Yields of bio-oil, permanent gases and char were determined at each reaction condition and compared to previously published results from untreated banagrass. Comparing the bio-oil yields from the untreated and pretreated banagrass shows that the yields were greater from the pretreated banagrass by 4 to 11 wt% (absolute) at all reaction conditions. The effect of pretreatment (i.e. reducing the amountmore » of ash, and alkali and alkali earth metals) on pyrolysis products is: 1) to increase the dry bio-oil yield, 2) to decrease the amount of undetected material, 3) to produce a slight increase in CO yield or no change, 4) to slightly decrease CO2 yield or no change, and 5) to produce a more stable bio-oil (less aging). Char yield and total gas yield were unaffected by feedstock pretreatment. Four other tropical biomass species were also pyrolyzed under one condition (450°C and 1.4 s residence time) for comparison to the banagrass results. The samples include two hardwoods: leucaena and eucalyptus, and two grasses: sugarcane bagasse and energy-cane. A sample of pretreated energy-cane was also pyrolyzed. Of the materials tested, the best feedstocks for fast pyrolysis were sugarcane bagasse, pretreated energy cane and eucalyptus based on the yields of 'dry bio-oil', CO and CO2. On the same basis, the least productive feedstocks are untreated banagrass followed by pretreated banagrass and leucaena.« less

  17. Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials

    DOE Patents [OSTI]

    Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

    1993-08-10

    A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

  18. Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials

    DOE Patents [OSTI]

    Chum, Helena L.; Black, Stuart K.; Diebold, James P.; Kreibich, Roland E.

    1993-01-01

    A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

  19. Techno-Economic Analysis of Biomass Fast Pyrolysis to Transportation Fuels

    SciTech Connect (OSTI)

    Wright, M. M.; Satrio, J. A.; Brown, R. C.; Daugaard, D. E.; Hsu, D. D.

    2010-11-01

    This study develops techno-economic models for assessment of the conversion of biomass to valuable fuel products via fast pyrolysis and bio-oil upgrading. The upgrading process produces a mixture of naphtha-range (gasoline blend stock) and diesel-range (diesel blend stock) products. This study analyzes the economics of two scenarios: onsite hydrogen production by reforming bio-oil, and hydrogen purchase from an outside source. The study results for an nth plant indicate that petroleum fractions in the naphtha distillation range and in the diesel distillation range are produced from corn stover at a product value of $3.09/gal ($0.82/liter) with onsite hydrogen production or $2.11/gal ($0.56/liter) with hydrogen purchase. These values correspond to a $0.83/gal ($0.21/liter) cost to produce the bio-oil. Based on these nth plant numbers, product value for a pioneer hydrogen-producing plant is about $6.55/gal ($1.73/liter) and for a pioneer hydrogen-purchasing plant is about $3.41/gal ($0.92/liter). Sensitivity analysis identifies fuel yield as a key variable for the hydrogen-production scenario. Biomass cost is important for both scenarios. Changing feedstock cost from $50-$100 per short ton changes the price of fuel in the hydrogen production scenario from $2.57-$3.62/gal ($0.68-$0.96/liter).

  20. Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-oil to Produce Hydrocarbon Products

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Zacher, Alan H.

    2009-10-01

    Catalytic hydroprocessing has been applied to biomass fast pyrolysis liquid product (bio-oil) in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. The project was a cooperative research and development agreement among UOP LLC, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory (PNNL). This paper is focused on the process experimentation and product analysis undertaken at PNNL. The paper describes the experimental methods used and relates the results of the product analyses. A range of catalyst formulations were tested over a range of operating parameters including temperature, pressure, and flow-rate with bio-oil derived from several different biomass feedstocks. Effects of liquid hourly space velocity and catalyst bed temperature were assessed. Details of the process results were presented including mass and elemental balances. Detailed analysis of the products were provided including elemental composition, chemical functional type determined by mass spectrometry, and product descriptors such as density, viscosity and Total Acid Number (TAN). In summation, the paper provides an understanding of the efficacy of hydroprocessing as applied to bio-oil.

  1. Entrained-Flow, Fast Ablative Pyrolysis of Biomass - Annual Report, 1 December 1984 - 31 December 1985

    SciTech Connect (OSTI)

    Diebold, J. P.; Scahill, J. W.; Evans, R. J.

    1986-07-01

    The ablative, fast pyrolysis system was relocated to SERI's new, permanent Field Test Laboratory. Pyrolysis system modifications were made to increase the energy available to the vortex reactor and to enhance the collection efficiency of primary pyrolysis vapors. Mathematical modeling of the vapor cracker has resulted in the ability to accurately predict experimental results with respect to the thermal cracking of the primary vapors, the generation of noncondensible gases, and the gas composition. The computer algorithm of this model can be readily used to perform experimental simulation and/or reactor scale-up due to its fundamental nature. Preliminary screening tests with pure ZSM-5 zeolite catalyst, supplied by Mobil Research and Development Corporation, have shown promise for the conversion of primary pyrolysis oil vapors to aromatic hydrocarbons; i.e., gasoline.

  2. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    SciTech Connect (OSTI)

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFD–DAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting the reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.

  3. Coupling DAEM and CFD for simulating biomass fast pyrolysis in fluidized beds

    DOE PAGES-Beta [OSTI]

    Xiong, Qingang; Zhang, Jingchao; Wiggins, Gavin; Daw, C. Stuart; Xu, Fei

    2015-12-03

    We report results from computational simulations of an experimental, lab-scale bubbling bed biomass pyrolysis reactor that include a distributed activation energy model (DAEM) for the kinetics. In this study, we utilized multiphase computational fluid dynamics (CFD) to account for the turbulent hydrodynamics, and this was combined with the DAEM kinetics in a multi-component, multi-step reaction network. Our results indicate that it is possible to numerically integrate the coupled CFD–DAEM system without significantly increasing computational overhead. It is also clear, however, that reactor operating conditions, reaction kinetics, and multiphase flow dynamics all have major impacts on the pyrolysis products exiting themore » reactor. We find that, with the same pre-exponential factors and mean activation energies, inclusion of distributed activation energies in the kinetics can shift the predicted average value of the exit vapor-phase tar flux and its statistical distribution, compared to single-valued activation-energy kinetics. Perhaps the most interesting observed trend is that increasing the diversity of the DAEM activation energies appears to increase the mean tar yield, all else being equal. As a result, these findings imply that accurate resolution of the reaction activation energy distributions will be important for optimizing biomass pyrolysis processes.« less

  4. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some

  5. Distributed Reforming of Biomass Pyrolysis Oils (Presentation) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy Biomass Pyrolysis Oils (Presentation) Distributed Reforming of Biomass Pyrolysis Oils (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 06_nrel_distributed_reforming_biomass_pyrolysis_oils.pdf (301.5 KB) More Documents & Publications Distributed Bio-Oil Reforming Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis Bioenergy Technologies Office R&D

  6. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway

    SciTech Connect (OSTI)

    Jones, S.; Meyer, P.; Snowden-Swan, L.; Padmaperuma, A.; Tan, E.; Dutta, A.; Jacobson, J.; Cafferty, K.

    2013-11-01

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  7. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway

    SciTech Connect (OSTI)

    Jones, Susanne B.; Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Padmaperuma, Asanga B.; Tan, Eric; Dutta, Abhijit; Jacobson, Jacob; Cafferty, Kara

    2013-11-01

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  8. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    SciTech Connect (OSTI)

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in the mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.

  9. Modeling the impact of bubbling bed hydrodynamics on tar yield and its fluctuations during biomass fast pyrolysis

    DOE PAGES-Beta [OSTI]

    Xiong, Qingang; Ramirez, Emilio; Pannala, Sreekanth; Daw, C. Stuart; Xu, Fei

    2015-10-09

    The impact of bubbling bed hydrodynamics on temporal variations in the exit tar yield for biomass fast pyrolysis was investigated using computational simulations of an experimental laboratory-scale reactor. A multi-fluid computational fluid dynamics model was employed to simulate the differential conservation equations in the reactor, and this was combined with a multi-component, multi-step pyrolysis kinetics scheme for biomass to account for chemical reactions. The predicted mean tar yields at the reactor exit appear to match corresponding experimental observations. Parametric studies predicted that increasing the fluidization velocity should improve the mean tar yield but increase its temporal variations. Increases in themore » mean tar yield coincide with reducing the diameter of sand particles or increasing the initial sand bed height. However, trends in tar yield variability are more complex than the trends in mean yield. The standard deviation in tar yield reaches a maximum with changes in sand particle size. As a result, the standard deviation in tar yield increases with the increases in initial bed height in freely bubbling state, while reaches a maximum in slugging state.« less

  10. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Elliott, D.; Hart, T.; Neuenschwander, G.; Rotness, L.; Zacher, A. (2009). "Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-Oil to Produce Hydrocarbon Products." ...

  11. Experimental investigation into fast pyrolysis of biomass using an entrained-flow reactor

    SciTech Connect (OSTI)

    Bohn, M.; Benham, C.

    1981-02-01

    Pyrolysis experiments were performed using 30 and 90cm entrained-flow reactors, with steam as a carrier gas and two different feedstocks - wheat straw and powdered material drived from municipal solid waste (ECO-II TM). Reactor wall temperature was varied from 700/sup 0/ to 1400/sup 0/C. Gas composition data from the ECO-II tests were comparable to previously reported data but ethylene yield appeared to vary with reactor wall temperature and residence time. The important conclusion from the wheat straw tests is that olefin yields are about one half that obtained from ECO-II. Evidence was found that high olefin yields from ECO-II are due to the presence of plastics in the feedstock. Batch experiments were run on wheat straw using a Pyroprobe/sup TM/. The samples were heated at a high rate (20,000/sup 0/ C/sec) to 1000/sup 0/ and held at 1000/sup 0/C for a variable period of time from 0.05 to 4.95s. For times up to 0.15s volume fractions of ethylene, propylene, and methane increase while that of carbon dioxide decreases. Subsequently, only carbon monoxide and hydrogen are produced. The change may be related to poor thermal contact and suggests caution in using the Pyroprobe.

  12. Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels Conversion Pathway: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway "The 2017 Design Case"

    SciTech Connect (OSTI)

    Kevin L. Kenney; Kara G. Cafferty; Jacob J. Jacobson; Ian J. Bonner; Garold L. Gresham; J. Richard Hess; William A. Smith; David N. Thompson; Vicki S. Thompson; Jaya Shankar Tumuluru; Neal Yancey

    2014-01-01

    The U.S. Department of Energy promotes the production of liquid fuels from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass sustainable supply, logistics, conversion, and overall system sustainability. As part of its involvement in this program, Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. Between 2000 and 2012, INL quantified and the economics and sustainability of moving biomass from the field or stand to the throat of the conversion process using conventional equipment and processes. All previous work to 2012 was designed to improve the efficiency and decrease costs under conventional supply systems. The 2012 programmatic target was to demonstrate a biomass logistics cost of $55/dry Ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model.

  13. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels. Thermochemical Research Pathways with In Situ and Ex Situ Upgrading of Fast Pyrolysis Vapors

    SciTech Connect (OSTI)

    Dutta, Abhijit; Sahir, Asad; Tan, Eric; Humbird, David; Snowden-Swan, Lesley J.; Meyer, Pimphan; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John Lukas

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s efforts to enable the development of technologies for the production of infrastructurecompatible, cost-competitive liquid hydrocarbon fuels from biomass. Specifically, this report details two conceptual designs based on projected product yields and quality improvements via catalyst development and process integration. It is expected that these research improvements will be made within the 2022 timeframe. The two conversion pathways detailed are (1) in situ and (2) ex situ upgrading of vapors produced from the fast pyrolysis of biomass. While the base case conceptual designs and underlying assumptions outline performance metrics for feasibility, it should be noted that these are only two of many other possibilities in this area of research. Other promising process design options emerging from the research will be considered for future techno-economic analysis.

  14. Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing

    Energy.gov [DOE]

    In fast pyrolysis and hydrotreating, biomass is rapidly heated in a fluidized bed to create bio-oils, which can then be used to create hydrocarbon biofuel blendstocks.

  15. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis

    Energy.gov [DOE]

    The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils, which can be used to produce biofuel blendstocks.

  16. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis

    Energy.gov [DOE]

    In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks.

  17. Distributed Reforming of Biomass Pyrolysis Oils (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Working Group Meeting Presentation Guidance at a Glance Distributed Reforming of Biomass Pyrolysis Oils DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting November 6 and 7 2007 R. J. Evans, NREL D. M. Steward, NREL Innovation / Overview Biomass pyrolysis produces a liquid product, bio-oil, which contains a wide spectrum of components that can be efficiently, stored, and shipped, to a site for renewable hydrogen production and converted to H2 at moderate severity

  18. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility

    DOE PAGES-Beta [OSTI]

    Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David; Baddour, Frederick G.; Sahir, Asad

    2015-10-06

    Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design reportmore » led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition

  19. Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility

    SciTech Connect (OSTI)

    Dutta, Abhijit; Schaidle, Joshua A.; Humbird, David; Baddour, Frederick G.; Sahir, Asad

    2015-10-06

    Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this

  20. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Thermochemical Research Pathways with In Situ and Ex Situ Upgrading of Fast Pyrolysis Vapors

    SciTech Connect (OSTI)

    Dutta, Abhijit; Sahir, A. H.; Tan, Eric; Humbird, David; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from biomass. Specifically, this report details two conceptual designs based on projected product yields and quality improvements via catalyst development and process integration. It is expected that these research improvements will be made within the 2022 timeframe. The two conversion pathways detailed are (1) in situ and (2) ex situ upgrading of vapors produced from the fast pyrolysis of biomass. While the base case conceptual designs and underlying assumptions outline performance metrics for feasibility, it should be noted that these are only two of many other possibilities in this area of research. Other promising process design options emerging from the research will be considered for future techno-economic analysis. Both the in situ and ex situ conceptual designs, using the underlying assumptions, project MFSPs of approximately $3.5/gallon gasoline equivalent (GGE). The performance assumptions for the ex situ process were more aggressive with higher distillate (diesel-range) products. This was based on an assumption that more favorable reaction chemistry (such as coupling) can be made possible in a separate reactor where, unlike in an in situ upgrading reactor, one does not have to deal with catalyst mixing with biomass char and ash, which pose challenges to catalyst performance and maintenance. Natural gas was used for hydrogen production, but only when off gases from the process was not sufficient to meet the needs; natural gas consumption is insignificant in both the in situ and ex situ base cases. Heat produced from the burning of char, coke, and off-gases allows for the production of surplus electricity which is sold to the grid allowing a reduction of approximately 5¢/GGE in the MFSP.

  1. Supply Chain Sustainability Analysis of Fast Pyrolysis and Hydrotreati...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Supply Chain Sustainability Analysis of Fast Pyrolysis and Hydrotreating Bio-Oil to Produce Hydrocarbon Fuels Title Supply Chain Sustainability Analysis of Fast Pyrolysis and...

  2. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  3. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Energy.gov [DOE]

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  4. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  5. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  6. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2012 State of Technology and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Snowden-Swan, Lesley J.

    2013-08-27

    This report summarizes the economic impact of the work performed at PNNL during FY12 to improve fast pyrolysis oil upgrading via hydrotreating. A comparison is made between the projected economic outcome and the actual results based on experimental data. Sustainability metrics are also included.

  7. Biofuel from fast pyrolysis and catalytic hydrodeoxygenation.

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2015-09-04

    This review addresses recent developments in biomass fast pyrolysis bio-oil upgrading by catalytic hydrotreating. The research in the field has expanded dramatically in the past few years with numerous new research groups entering the field while existing efforts from others expand. The issues revolve around the catalyst formulation and operating conditions. Much work in batch reactor tests with precious metal catalysts needs further validation to verify long-term operability in continuous flow systems. The effect of the low level of sulfur in bio-oil needs more study to be better understood. Utilization of the upgraded bio-oil for feedstock to finished fuels is still in an early stage of understanding.

  8. Stabilization of Fast Pyrolysis Oil: Post Processing Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Lee, Suh-Jane; Hart, Todd R.

    2012-03-01

    UOP LLC, a Honeywell Company, assembled a comprehensive team for a two-year project to demonstrate innovative methods for the stabilization of pyrolysis oil in accordance with DOE Funding Opportunity Announcement (FOA) DE-PS36-08GO98018, Biomass Fast Pyrolysis Oil (Bio-oil) Stabilization. In collaboration with NREL, PNNL, the USDA Agricultural Research Service (ARS), Pall Fuels and Chemicals, and Ensyn Corporation, UOP developed solutions to the key technical challenges outlined in the FOA. The UOP team proposed a multi-track technical approach for pyrolysis oil stabilization. Conceptually, methods for pyrolysis oil stabilization can be employed during one or both of two stages: (1) during the pyrolysis process (In Process); or (2) after condensation of the resulting vapor (Post-Process). Stabilization methods fall into two distinct classes: those that modify the chemical composition of the pyrolysis oil, making it less reactive; and those that remove destabilizing components from the pyrolysis oil. During the project, the team investigated methods from both classes that were suitable for application in each stage of the pyrolysis process. The post processing stabilization effort performed at PNNL is described in this report. The effort reported here was performed under a CRADA between PNNL and UOP, which was effective on March 13, 2009, for 2 years and was subsequently modified March 8, 2011, to extend the term to December 31, 2011.

  9. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  10. Biomass Feedstocks for Renewable Fuel Production: A review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors

    SciTech Connect (OSTI)

    Daniel Carpenter; Stefan Czernik; Whitney Jablonski; Tyler L. Westover

    2014-02-01

    Renewable transportation fuels from biomass have the potential to substantially reduce greenhouse gas emissions and diversify global fuel supplies. Thermal conversion by fast pyrolysis converts up to 75% of the starting plant material (and its energy content) to a bio-oil intermediate suitable for upgrading to motor fuel. Woody biomass, by far the most widely-used and researched material, is generally preferred in thermochemical processes due to its low ash content and high quality bio-oil produced. However, the availability and cost of biomass resources, e.g. forest residues, agricultural residues, or dedicated energy crops, vary greatly by region and will be key determinates in the overall economic feasibility of a pyrolysis-to-fuel process. Formulation or blending of various feedstocks, combined with thermal and/or chemical pretreatment, could facilitate a consistent, high-volume, lower-cost biomass supply to an emerging biofuels industry. However, the impact of biomass type and pretreatment conditions on bio-oil yield and quality, and the potential process implications, are not well understood. This literature review summarizes the current state of knowledge regarding the effect of feedstock and pretreatments on the yield, product distribution, and upgradability of bio-oil.

  11. Environmental control technology for biomass flash pyrolysis

    SciTech Connect (OSTI)

    Harkness, J.B.L.; Doctor, R.D.; Seward, W.H.

    1980-01-01

    The rapid commercialization of biomass gasification and pyrolysis technologies will raise questions concerning the environmental impacts of these systems and the associated costs for appropriate control technologies. This study concentrates on characterizing the effluent emissions and control technologies for a dual fluid-bed pyrolysis unit run by Arizona State University, Tempe, Arizona. The ASU system produces a raw product gas that is passed through a catalytic liquefaction system to produce a fuel comparable to No. 2 fuel oil. Argonne National Laboratory is conducting a program that will survey several biomass systems to standardize the sampling techniques, prioritize standard analyses and develop a data base so that environmental issues later may be addressed before they limit or impede the commercialization of biomass gasification and pyrolysis technologies. Emissions will be related to both the current and anticipated emissions standards to generate material balances and set design parameters for effluent treatment systems. This will permit an estimate to be made of the capital and operating costs associated with these technologies.

  12. Methods for deoxygenating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Brandvold, Timothy A.

    2015-07-14

    Methods for deoxygenating a biomass-derived pyrolysis oil are provided. A method comprising the steps of diluting the biomass-derived pyrolysis oil with a phenolic-containing diluent to form a diluted pyoil-phenolic feed is provided. The diluted pyoil-phenolic feed is contacted with a deoxygenating catalyst in the presence of hydrogen at hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

  13. Methods for deoxygenating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-06-30

    Methods for deoxygenating a biomass-derived pyrolysis oil are provided. A method for deoxygenating a biomass-derived pyrolysis oil comprising the steps of combining a biomass-derived pyrolysis oil stream with a heated low-oxygen-pyoil diluent recycle stream to form a heated diluted pyoil feed stream is provided. The heated diluted pyoil feed stream has a feed temperature of about 150.degree. C. or greater. The heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a low-oxygen biomass-derived pyrolysis oil effluent.

  14. Fast Pyrolysis Conversion Tests of Forest Concepts' Crumbles™. Final Report

    SciTech Connect (OSTI)

    Santosa, Daniel M.; Zacher, Alan H.; Eakin, David E.

    2012-04-02

    The report describes the work done by PNNL on assessing Forest Concept's engineered feedstock using the bench-scale continuous fast pyrolysis system to produce liquid bio-oil, char and gas. Specifically, bio-oil from the following process were evaluated for its yield and quality to determine impact of varying feed size parameters. Furthermore, the report also describes the handling process of the biomass and the challenges of operating the system with above average particle size.

  15. INTEGRATED PYROLYSIS COMBINED CYCLE BIOMASS POWER SYSTEM CONCEPT DEFINITION

    SciTech Connect (OSTI)

    Eric Sandvig; Gary Walling; Robert C. Brown; Ryan Pletka; Desmond Radlein; Warren Johnson

    2003-03-01

    Advanced power systems based on integrated gasification/combined cycles (IGCC) are often presented as a solution to the present shortcomings of biomass as fuel. Although IGCC has been technically demonstrated at full scale, it has not been adopted for commercial power generation. Part of the reason for this situation is the continuing low price for coal. However, another significant barrier to IGCC is the high level of integration of this technology: the gas output from the gasifier must be perfectly matched to the energy demand of the gas turbine cycle. We are developing an alternative to IGCC for biomass power: the integrated (fast) pyrolysis/ combined cycle (IPCC). In this system solid biomass is converted into liquid rather than gaseous fuel. This liquid fuel, called bio-oil, is a mixture of oxygenated organic compounds and water that serves as fuel for a gas turbine topping cycle. Waste heat from the gas turbine provides thermal energy to the steam turbine bottoming cycle. Advantages of the biomass-fueled IPCC system include: combined cycle efficiency exceeding 37 percent efficiency for a system as small as 7.6 MW{sub e}; absence of high pressure thermal reactors; decoupling of fuel processing and power generation; and opportunities for recovering value-added products from the bio-oil. This report provides a technical overview of the system including pyrolyzer design, fuel clean-up strategies, pyrolysate condenser design, opportunities for recovering pyrolysis byproducts, gas turbine cycle design, and Rankine steam cycle. The report also reviews the potential biomass fuel supply in Iowa, provide and economic analysis, and present a summery of benefits from the proposed system.

  16. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  17. Low-order modeling of internal heat transfer in biomass particle pyrolysis

    DOE PAGES-Beta [OSTI]

    Wiggins, Gavin M.; Daw, C. Stuart; Ciesielski, Peter N.

    2016-05-11

    We present a computationally efficient, one-dimensional simulation methodology for biomass particle heating under conditions typical of fast pyrolysis. Our methodology is based on identifying the rate limiting geometric and structural factors for conductive heat transport in biomass particle models with realistic morphology to develop low-order approximations that behave appropriately. Comparisons of transient temperature trends predicted by our one-dimensional method with three-dimensional simulations of woody biomass particles reveal good agreement, if the appropriate equivalent spherical diameter and bulk thermal properties are used. Here, we conclude that, for particle sizes and heating regimes typical of fast pyrolysis, it is possible to simulatemore » biomass particle heating with reasonable accuracy and minimal computational overhead, even when variable size, aspherical shape, anisotropic conductivity, and complex, species-specific internal pore geometry are incorporated.« less

  18. Combustion Properties of Biomass Flash Pyrolysis Oils: Final Project Report

    SciTech Connect (OSTI)

    C. R. Shaddix; D. R. Hardesty

    1999-04-01

    Thermochemical pyrolysis of solid biomass feedstocks, with subsequent condensation of the pyrolysis vapors, has been investigated in the U.S. and internationally as a means of producing a liquid fuel for power production from biomass. This process produces a fuel with significantly different physical and chemical properties from traditional petroleum-based fuel oils. In addition to storage and handling difficulties with pyrolysis oils, concern exists over the ability to use this fuel effectively in different combustors. The report endeavors to place the results and conclusions from Sandia's research into the context of international efforts to utilize pyrolysis oils. As a special supplement to this report, Dr. Steven Gust, of Finland's Neste Oy, has provided a brief assessment of pyrolysis oil combustion research efforts and commercialization prospects in Europe.

  19. Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and...

    Energy.gov (indexed) [DOE]

    Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing (471.51 KB) More Documents & Publications Bioenergy Technologies Office R&D Pathways: In-Situ ...

  20. Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Fast Pyrolysis and Hydroprocessing DOEEE - 0808 * November 2012 Printed with a renewable-source ink on paper containing at least 50% wastepaper, including 10% post consumer waste. ...

  1. In-Situ Catalytic Fast Pyrolysis Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified. In-Situ Catalytic Fast Pyrolysis Technology Pathway...

  2. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  3. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  4. Methods and apparatuses for deoxygenating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-10-20

    Embodiments of methods and apparatuses for deoxygenating a biomass-derived pyrolysis oil are provided. In one example, a method comprises the steps of separating a low-oxygen biomass-derived pyrolysis oil effluent into a low-oxygen-pyoil organic phase stream and an aqueous phase stream. Phenolic compounds are removed from the aqueous phase stream to form a phenolic-rich diluent recycle stream. A biomass-derived pyrolysis oil stream is diluted and heated with the phenolic-rich diluent recycle stream to form a heated diluted pyoil feed stream. The heated diluted pyoil feed stream is contacted with a deoxygenating catalyst in the presence of hydrogen to deoxygenate the heated diluted pyoil feed stream.

  5. Total Acid Value Titration of Hydrotreated Biomass Fast Pyrolysis Oil: Determination of Carboxylic Acids and Phenolics with Multiple End-Point Detection

    SciTech Connect (OSTI)

    Christensen, E.; Alleman, T. L.; McCormick, R. L.

    2013-01-01

    Total acid value titration has long been used to estimate corrosive potential of petroleum crude oil and fuel oil products. The method commonly used for this measurement, ASTM D664, utilizes KOH in isopropanol as the titrant with potentiometric end point determination by pH sensing electrode and Ag/AgCl reference electrode with LiCl electrolyte. A natural application of the D664 method is titration of pyrolysis-derived bio-oil, which is a candidate for refinery upgrading to produce drop in fuels. Determining the total acid value of pyrolysis derived bio-oil has proven challenging and not necessarily amenable to the methodology employed for petroleum products due to the different nature of acids present. We presented an acid value titration for bio-oil products in our previous publication which also utilizes potentiometry using tetrabutylammonium hydroxide in place of KOH as the titrant and tetraethylammonium bromide in place of LiCl as the reference electrolyte to improve the detection of these types of acids. This method was shown to detect numerous end points in samples of bio-oil that were not detected by D664. These end points were attributed to carboxylic acids and phenolics based on the results of HPLC and GC-MS studies. Additional work has led to refinement of the method and it has been established that both carboxylic acids and phenolics can be determined accurately. Use of pH buffer calibration to determine half-neutralization potentials of acids in conjunction with the analysis of model compounds has allowed us to conclude that this titration method is suitable for the determination of total acid value of pyrolysis oil and can be used to differentiate and quantify weak acid species. The measurement of phenolics in bio-oil is subject to a relatively high limit of detection, which may limit the utility of titrimetric methodology for characterizing the acidic potential of pyrolysis oil and products.

  6. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    DOE Patents [OSTI]

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  7. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  8. Flash pyrolysis and hydropyrolysis of biomass

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.

    1982-04-01

    Process chemistry data on the flash pyrolysis and hydropyrolysis of wood is being obtained in a 1'' downflow entrained tubular reactor. The data indicates that at residence times of <1 second, and 900 to 1000/sup 0/C and 500 psi pressure, the flash hydropyrolysis of wood yields mainly methane and water. As the residence time increases to >3 seconds, the products are methane and CO. Almost complete conversion of the carbon to methane and CO are obtained in these experiments. At lower temperatures, in the order of 800/sup 0/C, 500 psi and residence times <4 seconds, significant amounts of benzene and ethane are produced. The experimental process chemistry data have been used to design and evaluate two processes in a preliminary manner. One process converts wood to high BTU pipeline gas and the other to methanol and chemical feedstocks consisting of benzene and ethylene. Reasonable plant investments which compare favorably with coal conversion plant estimates are derived.

  9. Flash pyrolysis and hydropyrolysis of biomass

    SciTech Connect (OSTI)

    Not Available

    1982-08-01

    Process chemistry data on the flash pyrolysis and hydropyrolysis of wood is being obtained in a 1'' downflow entrained tubular reactor. The data indicates that at residence times of <1 second, and 900 to 1000/sup 0/C and 500 psi pressure, the flash hydropyrolysis of wood yields mainly methane and water. As the residence time increases to >3 seconds, the products are methane and CO. Almost complete conversion of the carbon to methane and CO are obtained in these experiments. At lower temperatures, in the order of 800/sup 0/C, 500 psi and residence times <4 seconds, significant amounts of benzene and ethane are produced. The experimental process chemistry data have been used to design and evaluate two processes in a preliminary manner. One process converts wood to high BTU pipeline gas and the other to methanol and chemical feedstocks consisting of benzene and ethylene. Reasonable plant investments which compare favorably with coal conversion plant estimates are derived.

  10. Apparatuses and methods for deoxygenating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Kalnes, Tom N.

    2015-12-29

    Apparatuses and methods for deoxygenating a biomass-derived pyrolysis oil are provided herein. In one example, the method comprises of dividing a feedstock stream into first and second feedstock portions. The feedstock stream comprises the biomass-derived pyrolysis oil and has a temperature of about 60.degree. C. or less. The first feedstock portion is combined with a heated organic liquid stream to form a first heated diluted pyoil feed stream. The first heated diluted pyoil feed stream is contacted with a first deoxygenating catalyst in the presence of hydrogen to form an intermediate low-oxygen pyoil effluent. The second feedstock portion is combined with the intermediate low-oxygen pyoil effluent to form a second heated diluted pyoil feed stream. The second heated diluted pyoil feed stream is contacted with a second deoxygenating catalyst in the presence of hydrogen to form additional low-oxygen pyoil effluent.

  11. Radiant flash pyrolysis of biomass using a xenon flashtube

    SciTech Connect (OSTI)

    Hopkins, M.W.; Antal, M.J. Jr.

    1984-06-01

    Biomass materials, including lignin, redwood, corn cob, Calotropis Procera, Leucaena wood, Kraft paper, newsprint, cow manure, D-glucose, and D-cellobiose, were pyrolyzed in vacuum by the visible radiant flux emitted from a Xenon flashtube. The flux density exceeded 8 kW/cm/sup 2/ during the 1 ms flash. Sirup yields were low (avg 25%), while the gas yield was high (avg 32%). The gaseous products were composed primarily of CO and CO/sub 2/. The high relative yields of CO establish the existence of a high temperature fragmentation pathway active during the flash pyrolysis of all biomass materials. 39 references, 2 figures, 5 tables.

  12. Flash pyrolysis and hydropyrolysis of biomass

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.

    1982-01-01

    Process chemical data on the flash pyrolysis and hydropyrolysis of sawdust for liquid and gaseous hydrocarbon-fuel production was obtained in a 1-inch downflow entrained tubular reactor. At residence times of less than 1 second, 90-100 degrees, and 500 psi, the flash hydropyrolysis of wood yields mainly CH/sub 4/ and H/sub 2/O. As the residence time increased to more than 3 seconds, the products are CH/sub 4/ and CO. Almost complete conversion of the C to CH/sub 4/ and CO is obtained in these experiments. At approximately 800 degrees, 500 psi, and residence times less than 4 seconds, significant amounts of C/sub 6/H/sub 6/ and C/sub 2/H/sub 6/ are produced. The experimental process chemical data were used to design and evaluate 2 processes. One process converts wood to a high-Btu pipeline gas and the other to MeOH and chemical feedstocks consisting of C/sub 6/H/sub 6/ and C/sub 2/H/sub 4/. Reasonable plant investments which compare favourably with coal conversion plant estimates are derived.

  13. Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil

    SciTech Connect (OSTI)

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-11-24

    Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

  14. Summary of Fast Pyrolysis and Upgrading GHG Analyses

    SciTech Connect (OSTI)

    Snowden-Swan, Lesley J.; Male, Jonathan L.

    2012-12-07

    by the rich dialogue and convergence around the energy content and GHG reduction of cellulosic ethanol (an example of these discussions can be found in Wang 2011). GHG analyses of fast pyrolysis technology routes are being developed and will require significant work to reach the levels of development and maturity of cellulosic ethanol models. This summary provides some of the first fast pyrolysis analyses and clarifies some of the reasons for differing results in an effort to begin the convergence on assumptions, discussion of quality of models, and harmonization.

  15. Predicting properties of gas and solid streams by intrinsic kinetics of fast pyrolysis of wood

    DOE PAGES-Beta [OSTI]

    Klinger, Jordan; Bar-Ziv, Ezra; Shonnard, David; Westover, Tyler; Emerson, Rachel

    2015-12-12

    Pyrolysis has the potential to create a biocrude oil from biomass sources that can be used as fuel or as feedstock for subsequent upgrading to hydrocarbon fuels or other chemicals. The product distribution/composition, however, is linked to the biomass source. This work investigates the products formed from pyrolysis of woody biomass with a previously developed chemical kinetics model. Different woody feedstocks reported in prior literature are placed on a common basis (moisture, ash, fixed carbon free) and normalized by initial elemental composition through ultimate analysis. Observed product distributions over the full devolatilization range are explored, reconstructed by the model, andmore » verified with independent experimental data collected with a microwave-assisted pyrolysis system. These trends include production of permanent gas (CO, CO2), char, and condensable (oil, water) species. Elementary compositions of these streams are also investigated. As a result, close agreement between literature data, model predictions, and independent experimental data indicate that the proposed model/method is able to predict the ideal distribution from fast pyrolysis given reaction temperature, residence time, and feedstock composition.« less

  16. Predicting properties of gas and solid streams by intrinsic kinetics of fast pyrolysis of wood

    SciTech Connect (OSTI)

    Klinger, Jordan; Bar-Ziv, Ezra; Shonnard, David; Westover, Tyler; Emerson, Rachel

    2015-12-12

    Pyrolysis has the potential to create a biocrude oil from biomass sources that can be used as fuel or as feedstock for subsequent upgrading to hydrocarbon fuels or other chemicals. The product distribution/composition, however, is linked to the biomass source. This work investigates the products formed from pyrolysis of woody biomass with a previously developed chemical kinetics model. Different woody feedstocks reported in prior literature are placed on a common basis (moisture, ash, fixed carbon free) and normalized by initial elemental composition through ultimate analysis. Observed product distributions over the full devolatilization range are explored, reconstructed by the model, and verified with independent experimental data collected with a microwave-assisted pyrolysis system. These trends include production of permanent gas (CO, CO2), char, and condensable (oil, water) species. Elementary compositions of these streams are also investigated. As a result, close agreement between literature data, model predictions, and independent experimental data indicate that the proposed model/method is able to predict the ideal distribution from fast pyrolysis given reaction temperature, residence time, and feedstock composition.

  17. Life Cycle Assessment of Gasoline and Diesel Produced via Fast Pyrolysis and Hydroprocessing

    SciTech Connect (OSTI)

    Hsu, D. D.

    2011-03-01

    In this work, a life cycle assessment (LCA) estimating greenhouse gas (GHG) emissions and net energy value (NEV) of the production of gasoline and diesel from forest residues via fast pyrolysis and hydroprocessing, from production of the feedstock to end use of the fuel in a vehicle, is performed. The fast pyrolysis and hydrotreating and hydrocracking processes are based on a Pacific Northwest National Laboratory (PNNL) design report. The LCA results show GHG emissions of 0.142 kg CO2-equiv. per km traveled and NEV of 1.00 MJ per km traveled for a process using grid electricity. Monte Carlo uncertainty analysis shows a range of results, with all values better than those of conventional gasoline in 2005. Results for GHG emissions and NEV of gasoline and diesel from pyrolysis are also reported on a per MJ fuel basis for comparison with ethanol produced via gasification. Although pyrolysis-derived gasoline and diesel have lower GHG emissions and higher NEV than conventional gasoline does in 2005, they underperform ethanol produced via gasification from the same feedstock. GHG emissions for pyrolysis could be lowered further if electricity and hydrogen are produced from biomass instead of from fossil sources.

  18. Fast pyrolysis of sweet soghum bagasse in a fluidized bed

    SciTech Connect (OSTI)

    Palm, M.; Peacocke, C.; Bridgewater, A.V.; Piskorz, J.; Scott, D.S.

    1993-12-31

    Samples of Italian sorghum bagasse were dried and ground and then pyrolyzed in the Waterloo Fast Pyrolysis bench scale reactor unit. Results were typical of agricultural grasses of this kind, and resembled those obtained from similar tests of sugar cane bagasse. A maximum liquid yield (dry feed basis) of 68% by weight of dry feed was achieved, with a corresponding char yield (ash included) of 16%. The high ash content of the bagasse (9.2%) gave a char with a very high ash content ({approx}50%), with calcium as the most abundant cation. Yields of hydroxyacetaldehyde were comparable to those obtained from softwoods. Deionized bagasse gave significant yields of anhydrosugars on pyrolysis. Sorghum bagasse appears to be a suitable feedstock, either for pyrolysis to yield an alternative fuel oil, or after pretreatment and pyrolysis, to yield a solution of fermentable sugars.

  19. Liquid products from the continuous flash pyrolysis of biomass

    SciTech Connect (OSTI)

    Scott, D.S.; Piskorz, J.; Radlein, D.

    1985-01-01

    A bench-scale continuous flash pyrolysis unit using a fluidized bed at atmospheric pressure has been employed to investigate conditions for maximum organic liquid yields from various biomass materials. Liquid yields for poplar-aspen were reported previously, and this work describes results for the flash pyrolysis of maple, poplar bark, bagasse, peat, wheat straw, corn stover, and a crude commercial cellulose. Organic liquid yields of 60-70% mf can be obtained from hardwoods and bagasse, and 40-50% from agricultural residues. Peat and bark with lower cellulose content give lower yields. The effects of the addition of lime and of a nickel catalyst to the fluid bed are reported also. A rough correlation exists between has content and maximum organic liquid yield, but the liquid yield correlates better with the alpha-cellulose content of the biomass. General relationships valid over all reaction conditions appear to exist among the ratios of final decomposition products also, and this correlation is demonstrated for the yields of methane and carbon monoxide.

  20. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    In-Situ Catalytic Fast Pyrolysis Technology Pathway Mary Biddy and Abhijit Dutta National Renewable Energy Laboratory Susanne Jones and Aye Meyer Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy under

  1. Radiant flash pyrolysis as a source of liquid syrups from biomass

    SciTech Connect (OSTI)

    Hofmann, L.; Antal, M.J.

    1981-01-01

    Continuing research at Princeton has identified compelling reasons for the use of solar heat to flash pyrolyze biomass materials. Recent efforts to design a solar fired reactor which selectively produces high yields of sugar related syrups from particulate biomass materials are described. To obtain a high yield of liquid syrups, the flash pyrolysis reactor must decouple the solid's temperature from the temperature of the gaseous environment within the reactor. This can be accomplished by using the intense flux of concentrated solar energy to rapidly heat opaque particles of biomass to high temperatures, while minimizing heat transfer losses from the particles to their gaseous environment. Under these conditions, volatile matter evolved by ablative pyrolysis of the biomass particles rapidly cools in the gaseous environment. This cooling occurs before subsequent gas phase pyrolysis destroys the integrity of the monomeric sugar units composing the volatile matter. The results of a numerical simulation which analyzes in detail the heat transfer phenomena occurring in a reactor are discussed.

  2. Co-pyrolysis of low rank coals and biomass: Product distributions

    SciTech Connect (OSTI)

    Soncini, Ryan M; Means, Nicholas C; Weiland, Nathan T

    2013-10-01

    Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

  3. Molecular-beam sampling/mass spectrometric studies of the primary pyrolysis mechanisms of biomass, fossil organic matter, and synthetic polymers

    SciTech Connect (OSTI)

    Evans, R.J.; Milne, T.A.; Soltys, M.N.

    1984-04-01

    To accomplish the determination of primary product composition, the flash pyrolysis of samples in 900/sup 0/C steam/He has been coupled with a molecular-beam sampling system for a mass spectrometer that permits real-time sampling and rapid quenching from ambient hot environments, while preserving reactive and condensible species. The major emphasis of this report is on the determination of the primary pyrolysis mechanisms of the fast pyrolysis of lignocellulosic biomass and its major constituents: cellulose, hemicellulose (particularly the pentoses, xylan and arabinan), and lignin. Other carbonaceous materials are also included for the purposes of comparison and demonstrating the technique, but pyrolysis mechanisms will not be discussed. These materials include Texas lignite, Pittsburgh number8 coal, Utah tar sand, Colorado oil shale, high-moor and low-moor peat, polyethylene, and polystyrene. The plastics are included because they are an important component of municipal solid waste and refuse-derived fuel.

  4. Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils

    DOE Patents [OSTI]

    Agblevor, Foster A.; Besler-Guran, Serpil

    2001-01-01

    A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

  5. The effect of temperature on liquid product composition from the fast pyrolysis of cellulose

    SciTech Connect (OSTI)

    Scott, D.S.; Piskorz, J.; Grinshpun, A.; Graham, R.G.

    1987-04-01

    In recent years, a good deal of attention has been focused on the thermal conversion of biomass to gases and liquids, and in particular, on the products obtainable from short time, high temperature pyrolysis of wood and other lignocellulosics. This flash pyrolysis is usually carried out at or near atmospheric pressures, while hydropyrolysis commonly employs hydrogen pressures to 20 MPa. Residence times of only a few seconds or less with reaction at high temperatures requires a reactor configuration capable of very high heating rates. Two of the most appropriate designs are the entrained flow reactor, and the fluidized bed reactor. Many flash pyrolysis studies have employed one or the other of these reactor types. In general, two approaches to flash pyrolysis of biomass have been used by various workers. One approach has the objective of producing a maximum yield of a desirable gas, which in atmospheric pressure non-catalytic pyrolysis processes is usually ethylene, or other olefins.

  6. Flash pyrolysis of biomass with reactive and nonreactive gases

    SciTech Connect (OSTI)

    Sundaram, M.S.; Steinberg, M.; Fallon, P.

    1982-10-01

    Studies were done on the flash pyrolysis of Douglas fir wood in the presence of reactive and nonreactive gases including hydrogen, methane, and helium. Pyrolysis and gasification of the wood particles was done in one step, without catalysts. Almost complete (98%) gasification of the carbon in Douglas fir wood was achieved at 1000/sup 0/C and 500-psi hydrogen pressure. The reaction products were methane, ethane, ethylene, carbon monoxide, BTX, and water. Flash hydropyrolysis produced a large yield of hydrocarbon gases (up to 78% C) comprising methane and ethane. High yields of ethylene (up to 21% C) and BTX (up to 12% C) were obtained via methane pyrolysis of fir wood; a free-radical mechanism is proposed to explain the enhanced yield of ethylene in a methane atmosphere.

  7. Design and operation of a solar fired biomass flash pyrolysis reactor

    SciTech Connect (OSTI)

    Antal, M.J.; Hofmann, L.; Brown, C.T.; Steenblick, R.

    1981-01-01

    The results of continuing research on the radiant flash pyrolysis of biomass as a source of fluid fuels, industrial feedstocks, and chemicals are described. Bench-scale sources of intense, visible radiant energy were used to simulate the concentrated solar flux available at the focus of solar towers. Windowed transport reactors were developed, which act as cavity receivers for the focused radiant energy and provide a means for direct use of the radiation to rapidly pyrolyze the entering biomass. Detailed result of both bench scale experiments and experiments using the Georgia Tech 400 kW (thermal) solar furnace are presented. These results suggest the use of concentrated radiant energy as a selective means for the production of either a hydrocarbon-rich synthesis gas or sugar related syrups from biomass by flash pyrolysis. Sawdust, ground corncobs, and powdered microcrystal cellulose were the biomass feedstocks in this work.

  8. Process for preparing phenolic formaldehyde resole resin products derived from fractionated fast-pyrolysis oils

    DOE Patents [OSTI]

    Chum, Helena L.; Kreibich, Roland E.

    1992-01-01

    A process for preparing phenol-formaldehyde resole resins and adhesive compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils.

  9. Experimental evaluation of a solar fired flash pyrolysis of biomass reactor

    SciTech Connect (OSTI)

    Antal, M.J. Jr.; Edwards, W.E.; Steenblik, R.A.; Brown, C.T.; Knight, J.A.; Elston, L.W.; Hurst, D.R.

    1981-01-01

    A Princeton-Georgia Institute of Technology flash pyrolysis of biomass test program was conducted at the DOE Advanced Components Test Facility (CTF) at Georgia Tech in August 1980. The 400 kWth solar thermal facility was used to provide a source of highly concentrated radiant energy for the flash pyrolysis of four types of biomass in a steam counterflow quartz reactor. The biomass materials were microcrystalline cellulose, hardwood sawdust, ground corn cob, and Kraft lignin. The experiments at Princeton and Georgia Tech suggest the use of concentrated radiant energy as a selective means for the production of either a hydrocarbon rich synthesis gas or sugar related syrups from biomass by flash pyrolysis. Experiments at Princeton have indicated that sugar related syrups are selectively produced when the biomass particles are rapidly heated by radiation in a cool gaseous environment. The gas temperatures in the reactor during the test program at Georgia Tech were relatively high, which selectively turned the chemistry toward the production of hydrocarbon rich synthesis gases.

  10. Investigations of the flash pyrolysis of biomass using simulated solar radiation

    SciTech Connect (OSTI)

    Hopkins, M.W.

    1982-09-01

    The purpose of this research was to demonstrate that flash pyrolysis has great potential as a technology for producing synthetic fuels and feedstocks from biomass. It was determined that the pursuit of faster and faster heating rates is not conducive to maximizing the yield of sirups from the pyrolysis of biomass. The consensus in the literature was that as heating rates increased, less char and more sirup would be formed. The implications of this finding are that three mechanisms compete to degrade the cellulose, instead of only two as was previously believed. The new branch of the decomposition mechanism is one which results primarily in the formation of low molecular weight gaseous products and char. This branch of the mechanism becomes important at the rapid heating rates seen in the flashlamp series of experiments. A summary of the spouted bed literature was presented with particular attention paid to the design of biomass pyrolysis reactors for use in conjunction with visible radiant heating. The combined results show that spouted beds have a place in pyrolysis research because they help realize several important goals. The use of clear spouted bed reactors makes possible the two temperature effect, the separation of gas phase and solid phase temperatures within a small region. This separation enables the high sirup yields, which result from rapid heating rates, to be preserved, and prohibits the cracking of these sirups to less valuable products.

  11. Large-Scale Pyrolysis Oil Production: A Technology Assessment and Economic Analysis

    SciTech Connect (OSTI)

    Ringer, M.; Putsche, V.; Scahill, J.

    2006-11-01

    A broad perspective of pyrolysis technology as it relates to converting biomass substrates to a liquid bio-oil product and a detailed technical and economic assessment of a fast pyrolysis plant.

  12. In-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical...

    Office of Scientific and Technical Information (OSTI)

    This technology pathway case investigates converting woody biomass using in-situ catalytic ... Sponsoring Org: USDOE Office of Energy Efficiency and Renewable Energy Biomass Program ...

  13. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway (Technical...

    Office of Scientific and Technical Information (OSTI)

    This technology pathway case investigates converting woody biomass using ex-situ catalytic ... Sponsoring Org: USDOE Office of Energy Efficiency and Renewable Energy Biomass Program ...

  14. MINIMIZING NET CO2 EMISSIONS BY OXIDATIVE CO-PYROLYSIS OF COAL / BIOMASS BLENDS

    SciTech Connect (OSTI)

    Todd Lang; Robert Hurt

    2001-12-23

    This study presents a set of thermodynamic calculations on the optimal mode of solid fuel utilization considering a wide range of fuel types and processing technologies. The technologies include stand-alone combustion, biomass/coal cofiring, oxidative pyrolysis, and straight carbonization with no energy recovery but with elemental carbon storage. The results show that the thermodynamically optimal way to process solid fuels depends strongly on the specific fuels and technologies available, the local demand for heat or for electricity, and the local baseline energy-production method. Burning renewable fuels reduces anthropogenic CO{sub 2} emissions as widely recognized. In certain cases, however, other processing methods are equally or more effective, including the simple carbonization or oxidative pyrolysis of biomass fuels.

  15. Renewable Hydrogen Production from Biomass Pyrolysis Aqueous Phase Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7, 2015 Thermochem Conversion Review PI: Abhijeet P. Borole, Ph.D. Oak Ridge National Laboratory Co:PI's & Collaborators: S. Pavlostathis, C. Tsouris, S. Yiacoumi, Georgia Tech; P. Ye, N. Labbe, University of Tennessee, Knoxville, R. Bhave, ORNL DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Renewable Hydrogen Production from Biomass Pyrolysis Aqueous Phase 2 Managed by UT-Battelle for the U.S. Department of Energy Presentation_name Goal Statement * Carbon, Hydrogen and

  16. Well-to-wheels analysis of fast pyrolysis pathways with the GREET model.

    SciTech Connect (OSTI)

    Han, J.; Elgowainy, A.; Palou-Rivera, I.; Dunn, J.B.; Wang, M.Q.

    2011-12-01

    The pyrolysis of biomass can help produce liquid transportation fuels with properties similar to those of petroleum gasoline and diesel fuel. Argonne National Laboratory conducted a life-cycle (i.e., well-to-wheels [WTW]) analysis of various pyrolysis pathways by expanding and employing the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The WTW energy use and greenhouse gas (GHG) emissions from the pyrolysis pathways were compared with those from the baseline petroleum gasoline and diesel pathways. Various pyrolysis pathway scenarios with a wide variety of possible hydrogen sources, liquid fuel yields, and co-product application and treatment methods were considered. At one extreme, when hydrogen is produced from natural gas and when bio-char is used for process energy needs, the pyrolysis-based liquid fuel yield is high (32% of the dry mass of biomass input). The reductions in WTW fossil energy use and GHG emissions relative to those that occur when baseline petroleum fuels are used, however, is modest, at 50% and 51%, respectively, on a per unit of fuel energy basis. At the other extreme, when hydrogen is produced internally via reforming of pyrolysis oil and when bio-char is sequestered in soil applications, the pyrolysis-based liquid fuel yield is low (15% of the dry mass of biomass input), but the reductions in WTW fossil energy use and GHG emissions are large, at 79% and 96%, respectively, relative to those that occur when baseline petroleum fuels are used. The petroleum energy use in all scenarios was restricted to biomass collection and transportation activities, which resulted in a reduction in WTW petroleum energy use of 92-95% relative to that found when baseline petroleum fuels are used. Internal hydrogen production (i.e., via reforming of pyrolysis oil) significantly reduces fossil fuel use and GHG emissions because the hydrogen from fuel gas or pyrolysis oil (renewable sources) displaces that from fossil fuel

  17. Jobs and Economic Development Impact (JEDI) User Reference Guide: Fast Pyrolysis Biorefinery Model

    SciTech Connect (OSTI)

    Zhang, Y.; Goldberg, M.

    2015-02-01

    This guide -- the JEDI Fast Pyrolysis Biorefinery Model User Reference Guide -- was developed to assist users in operating and understanding the JEDI Fast Pyrolysis Biorefinery Model. The guide provides information on the model's underlying methodology, as well as the parameters and data sources used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the JEDI Fast Pyrolysis Biorefinery Model estimates local (e.g., county- or state-level) job creation, earnings, and output from total economic activity for a given fast pyrolysis biorefinery. These estimates include the direct, indirect and induced economic impacts to the local economy associated with the construction and operation phases of biorefinery projects.Local revenue and supply chain impacts as well as induced impacts are estimated using economic multipliers derived from the IMPLAN software program. By determining the local economic impacts and job creation for a proposed biorefinery, the JEDI Fast Pyrolysis Biorefinery Model can be used to field questions about the added value biorefineries might bring to a local community.

  18. Catalytic Hydroprocessing of Fast Pyrolysis Bio-oil from Pine Sawdust

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.; Solantausta, Yrjo

    2012-06-01

    Catalytic hydroprocessing has been applied to the fast pyrolysis liquid product (bio-oil) from softwood biomass in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. This paper is focused on the process experimentation and product analysis. The paper describes the experimental methods used and relates the results of the product analyses. A range of operating parameters including temperature, and flow-rate were tested with bio-oil derived from pine wood as recovered and pyrolyzed in the pilot pyrolyzer of Metso Power in Tampere, Finland. Effects of time on stream and catalyst activity were assessed. Details of the process results were presented included product yields and hydrogen consumption. Detailed analysis of the products were provided including elemental composition and product descriptors such as density, viscosity and Total Acid Number (TAN). In summation, the paper provides an initial understanding of the efficacy of hydroprocessing as applied to the Finnish pine bio-oil.

  19. Radiant flash pyrolysis of biomass as a source of fuels and chemicals

    SciTech Connect (OSTI)

    Antal, M.J. Jr.; Hofman, L.; Moreira, J.R.

    1980-01-01

    Last year a team of US and French scientists using the Odeillo (France) 1MW/sub th/ solar furnace showed concentrated solar radiation to be an effective means for rapidly volatilizing biomass materials. The results of continuing research in the U.S. on radiant flash pyrolysis of biomass as a source of fluid fuels, industrial feedstocks and chemicals are described. Bench scale sources of intense, visible radiant energy have been used to simulate the concentrated solar flux available at the focus of solar towers. Windowed transport reactors are being developed, which act as cavity receivers for the focused radiant energy and provide a means for direct use of the radiation to rapidly pyrolyze the entering biomass. One of these reactors will be operated at the focus of the Georgia Tech 400kW/sub th/ solar furnace next August. Preliminary results from the bench scale reactor experiments, and plans for the Georgia Tech experiments are detailed.

  20. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.

    1982-06-01

    The rapid or flash pyrolysis of wood biomass is being studied in a 1'' downflow entrained tubular reactor with a capacity of approximately 1 lb/hr of wood. The process chemistry data is being obtained with the view of building a data base and ascertaining the value of producing synthetic fuels and chemical feedstocks by the flash pyrolysis method. Data is being obtained on the effect of non-reactive pyrolyzing gases and the effect of reactive gases, hydrogen for the flash hydropyrolysis of wood and methane for flash methanolysis of wood. Preliminary process design and analysis has been made. The yield of ethylene and benzene is especially attractive for the production of chemical feedstocks from the reaction of methane and wood in a flash methanolysis process.

  1. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  2. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE PAGES-Beta [OSTI]

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreatingmore » the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.« less

  3. Guidelines for Transportation, Handling, and Use of Fast Pyrolysis Bio-Oil. Part 1. Flammability and Toxicity

    SciTech Connect (OSTI)

    Oasmaa, Anja; Kalli, Anssi; Lindfors, Christian; Elliott, Douglas C.; Springer, David L.; Peacocke, Cordner; Chiaramonti, David

    2012-05-04

    An alternative sustainable fuel, biomass-derived fast pyrolysis oil or 'bio-oil', is coming into the market. Fast pyrolysis pilot and demonstration plants for fuel applications producing tonnes of bio-oil are in operation, and commercial plants are under design. There will be increasingly larger amounts of bio-oil transportation on water and by land, leading to a need for specifications and supporting documentation. Bio-oil is different from conventional liquid fuels, and therefore must overcome both technical and marketing hurdles for its acceptability in the fuels market. A comprehensive Material Safety Data Sheet (MSDS) is required, backed with independent testing and certification. In order to standardise bio-oil quality specifications are needed. The first bio-oil burner fuel standard in ASTM (D7544) was approved in 2009. CEN standardisation has been initiated in Europe. In the EU a new chemical regulation system, REACH (Registration, Evaluation and Authorisation of Chemicals) is being applied. Registration under REACH has to be made if bio-oil is produced or imported to the EU. In the USA and Canada, bio-oil has to be filed under TOSCA (US Toxic Substances Control Act). In this paper the state of the art on standardisation is discussed, and new data for the transportation guidelines is presented. The focus is on flammability and toxicity.

  4. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

    SciTech Connect (OSTI)

    Morgan, Trevor James; Turn, Scott Q.; George, Anthe

    2015-08-26

    A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amounts of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high

  5. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor

    DOE PAGES-Beta [OSTI]

    Morgan, Trevor James; Turn, Scott Q.; George, Anthe

    2015-08-26

    A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amountsmore » of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. In conclusion, the reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high

  6. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis and Catalytic Hydroconversion - Wastewater Cleanup by Catalytic Hydrothermal Gasification

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Olarte, Mariefel V.; Hart, Todd R.

    2015-06-19

    DOE-EE Bioenergy Technologies Office has set forth several goals to increase the use of bioenergy and bioproducts derived from renewable resources. One of these goals is to facilitate the implementation of the biorefinery. The biorefinery will include the production of liquid fuels, power and, in some cases, products. The integrated biorefinery should stand-alone from an economic perspective with fuels and power driving the economy of scale while the economics/profitability of the facility will be dependent on existing market conditions. UOP LLC proposed to demonstrate a fast pyrolysis based integrated biorefinery. Pacific Northwest National Laboratory (PNNL) has expertise in an important technology area of interest to UOP for use in their pyrolysis-based biorefinery. This CRADA project provides the supporting technology development and demonstration to allow incorporation of this technology into the biorefinery. PNNL developed catalytic hydrothermal gasification (CHG) for use with aqueous streams within the pyrolysis biorefinery. These aqueous streams included the aqueous phase separated from the fast pyrolysis bio-oil and the aqueous byproduct streams formed in the hydroprocessing of the bio-oil to finished products. The purpose of this project was to demonstrate a technically and economically viable technology for converting renewable biomass feedstocks to sustainable and fungible transportation fuels. To demonstrate the technology, UOP constructed and operated a pilot-scale biorefinery that processed one dry ton per day of biomass using fast pyrolysis. Specific objectives of the project were to: The anticipated outcomes of the project were a validated process technology, a range of validated feedstocks, product property and Life Cycle data, and technical and operating data upon which to base the design of a full-scale biorefinery. The anticipated long-term outcomes from successful commercialization of the technology were: (1) the replacement of a significant

  7. KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY

    SciTech Connect (OSTI)

    Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

    2013-10-29

    The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

  8. MINIMIZING NET CARBON DIOXIDE EMISSIONS BY OXIDATIVE CO-PYROLYSIS OF COAL/BIOMASS BLENDS

    SciTech Connect (OSTI)

    Robert Hurt; Todd Lang

    2001-06-25

    Solid fuels vary significantly with respect to the amount of CO{sub 2} directly produced per unit heating value. Elemental carbon is notably worse than other solid fuels in this regard, and since carbon (char) is an intermediate product of the combustion of almost all solid fuels, there is an opportunity to reduce specific CO{sub 2} emissions by reconfiguring processes to avoid char combustion wholly or in part. The primary goal of this one-year Innovative Concepts project is to make a fundamental thermodynamic assessment of three modes of solid fuel use: (1) combustion, (2) carbonization, and (3) oxidative pyrolysis, for a wide range of coal and alternative solid fuels. This period a large set of thermodynamic calculations were carried out to assess the potential of the three processes. The results show that the net carbon dioxide emissions and the relative ranking of the different processes depends greatly on the particular baseline fossil fuel being displaced by the new technology. As an example, in a baseline natural gas environment, it is thermodynamically more advantageous to carbonize biomass than to combust it, and even more advantageous to oxidatively pyrolyze the biomass.

  9. Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids

    SciTech Connect (OSTI)

    Oyama, Ted; Agblevor, Foster; Battaglia, Francine; Klein, Michael

    2013-01-18

    The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

  10. U.S., Canada, and Finland Pyrolysis Collaborations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    , Canada, and Finland Pyrolysis Collaborations U.S., Canada, and Finland Pyrolysis Collaborations Jonathan Male, PNNL, presentation at the December 5, 2012, Biomass Program-hosted International webinar on U.S., Canada, and Finland pyrolysis collaborations. male_2012_webinar.pdf (837.26 KB) More Documents & Publications Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading 2013 Peer Review Presentations-Bio-oil Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and

  11. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1984-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gases He and N/sub 2/ is being determined in an 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the ethylene yield based on pine wood carbon conversion is 27%, for benzene it is 25% and for CO the yield is 39%, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood. The yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, thus indicating a free radical reaction between CH/sub 4/ and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicate an economically competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 7 references, 13 figures, 1 table.

  12. Flash pyrolysis of biomass with reactive and non-reactive gases

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1985-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gases He and N/sub 2/ is being determined in a 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 30% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH/sub 4/ and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates an economically competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 8 refs., 18 figs., 1 tab.

  13. The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1990-02-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

  14. Oil production by entrained pyrolysis of biomass and processing of oil and char

    DOE Patents [OSTI]

    Knight, James A.; Gorton, Charles W.

    1990-01-02

    Entrained pyrolysis of lignocellulosic material proceeds from a controlled pyrolysis-initiating temperature to completion of an oxygen free environment at atmospheric pressure and controlled residence time to provide a high yield recovery of pyrolysis oil together with char and non-condensable, combustible gases. The residence time is a function of gas flow rate and the initiating temperature is likewise a function of the gas flow rate, varying therewith. A controlled initiating temperature range of about 400.degree. C. to 550.degree. C. with corresponding gas flow rates to maximize oil yield is disclosed.

  15. Flash pyrolysis of biomass with reactive and non-reactive gases. Summary report, March 1982-March 1983

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1983-03-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H/sub 2/ and CH/sub 4/ and with the non-reactive gas He is being determined in a 1'' downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000/sup 0/C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol production. With methane, flash methanolysis of wood, leads to high yields of ethylene, benzene and CO which can be used for the production of valuable feedstocks and methanol fuel. At reactor conditions of 50 psi and 1000/sup 0/C and approximately 1 sec residence time, the ethylene yield based on wood carbon converted is 22%, benzene 12% and the CO yield is 48%. The yield of ethylene is 2.2 times higher with methane than with helium, thus indicating a free radical rection between CH/sub 4/ and the pyrolyzed wood. A preliminary process analysis indicates an economically competitive process for the production of ethylene, benzene and methanol based on the methanolysis of wood. It is recommended to further develop the data base for the flash pyrolysis of wood and other biomass materials with methane as well as with other reactive gases (e.g. CO and CO/sub 2/) and determine the role of the hemi-cellulose and lignin in the formation of these valuable fuels and feedstocks.

  16. Computational Pyrolysis Consortium

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    reduce oxygen content, corrosivity, viscosity and increase stability) with vapor and ... and CFD Hemicellulose Cellulose Example dynamic simulation of biomass pyrolysis in a 0.1 ...

  17. Demonstration of Pyrolysis Biorefinery Concept for Biopower,...

    Energy.gov (indexed) [DOE]

    Office (BETO) Project Peer Review Demonstration of Pyrolysis Biorefinery Concept for ... plants * Product development and demonstration *4 Biomass Prep and Handling Pyrolysis ...

  18. Phenolic compounds containing/neutral fractions extract and products derived therefrom from fractionated fast-pyrolysis oils

    DOE Patents [OSTI]

    Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

    1993-06-29

    A process is described for preparing phenol-formaldehyde novolak resins and molding compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils. The fractionation consists of a neutralization stage which can be carried out with aqueous solutions of bases or appropriate bases in the dry state, followed by solvent extraction with an organic solvent having at least a moderate solubility parameter and good hydrogen bonding capacity. Phenolic compounds-containing/neutral fractions extracts obtained by fractionating fast-pyrolysis oils from a lignocellulosic material, is such that the oil is initially in the pH range of 2-4, being neutralized with an aqueous bicarbonate base, and extracted into a solvent having a solubility parameter of approximately 8.4-9.11 [cal/cm[sup 3

  19. Fast Pyrolysis and Hydrotreating: 2014 State of Technology R&D and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

    2015-03-20

    This report documents the technical targets and modeled costs associated with the Bioenergy Technologies Office 2014 fiscal year research related to pyrolysis oil upgrading to hydrocarbons.

  20. Acetylene from the co-pyrolysis of biomass and waste tires or coal in the H{sub 2}/Ar plasma

    SciTech Connect (OSTI)

    Bao, W.; Cao, Q.; Lv, Y.; Chang, L.

    2008-07-01

    Acetylene from carbon-containing materials via plasma pyrolysis is not only simple but also environmentally friendly. In this article, the acetylene produced from co-pyrolyzing biomass with waste tire or coal under the conditions of H{sub 2}/Ar DC arc plasma jet was investigated. The experimental results showed that the co-pyrolysis of mixture with biomass and waste tire or coal can improve largely the acetylene relative volume fraction (RVF) in gaseous products and the corresponding yield of acetylene. The change trends for the acetylene yield of plasma pyrolysis from mixture with raw sample properties were the same as relevant RVF. But the yield change trend with feeding rate is different from its RVF. The effects of the feeding rate of raw materials and the electric current of plasmatron on acetylene formation are also discussed.

  1. New applications of X-ray tomography in pyrolysis of biomass: Biochar imaging

    DOE PAGES-Beta [OSTI]

    Jones, Keith; Ramakrishnan, Girish; Uchimiya, Minori; Orlov, Alexander

    2015-01-30

    We report on the first ever use of non-destructive micrometer-scale synchrotron-computed microtomography (CMT) for biochar material characterization as a function of pyrolysis temperature. This innovative approach demonstrated an increase in micron-sized marcropore fraction of the Cotton Hull (CH) sample, resulting in up to 29% sample porosity. We have also found that initial porosity development occurred at low temperatures (below 350°C) of pyrolysis, consistent with chemical composition of CH. This innovative technique can be highly complementary to traditional BET measurements, considering that Barrett–Joyner–Halenda (BJH) analysis of pore size distribution cannot detect these macropores. Such information can be of substantial relevance tomore » environmental applications, given that water retention by biochars added to soils is controlled by macropore characteristic among the other factors. In addition, complementing our data with SEM, EDX, and XRF characterization techniques allowed us to develop a better understanding of evolution of biochar properties during its production, such presence of metals and initial morphological features of biochar before pyrolysis. These results have significant implications for using biochar as a soil additive and for clarifying the mechanisms of biofuel production by pyrolysis.« less

  2. New applications of X-ray tomography in pyrolysis of biomass: Biochar imaging

    SciTech Connect (OSTI)

    Jones, Keith; Ramakrishnan, Girish; Uchimiya, Minori; Orlov, Alexander

    2015-01-30

    We report on the first ever use of non-destructive micrometer-scale synchrotron-computed microtomography (CMT) for biochar material characterization as a function of pyrolysis temperature. This innovative approach demonstrated an increase in micron-sized marcropore fraction of the Cotton Hull (CH) sample, resulting in up to 29% sample porosity. We have also found that initial porosity development occurred at low temperatures (below 350°C) of pyrolysis, consistent with chemical composition of CH. This innovative technique can be highly complementary to traditional BET measurements, considering that Barrett–Joyner–Halenda (BJH) analysis of pore size distribution cannot detect these macropores. Such information can be of substantial relevance to environmental applications, given that water retention by biochars added to soils is controlled by macropore characteristic among the other factors. In addition, complementing our data with SEM, EDX, and XRF characterization techniques allowed us to develop a better understanding of evolution of biochar properties during its production, such presence of metals and initial morphological features of biochar before pyrolysis. These results have significant implications for using biochar as a soil additive and for clarifying the mechanisms of biofuel production by pyrolysis.

  3. Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis/Hydrotreating Pathway

    SciTech Connect (OSTI)

    Howe, Daniel T.; Westover, Tyler; Carpenter, Daniel; Santosa, Daniel M.; Emerson, Rachel; Deutch, Steve; Starace, Anne; Kutnyakov, Igor V.; Lukins, Craig D.

    2015-05-21

    Feedstock composition can affect final fuel yields and quality for the fast pyrolysis and hydrotreatment upgrading pathway. However, previous studies have focused on individual unit operations rather than the integrated system. In this study, a suite of six pure lignocellulosic feedstocks (clean pine, whole pine, tulip poplar, hybrid poplar, switchgrass, and corn stover) and two blends (equal weight percentages whole pine/tulip poplar/switchgrass and whole pine/clean pine/hybrid poplar) were prepared and characterized at Idaho National Laboratory. These blends then underwent fast pyrolysis at the National Renewable Energy Laboratory and hydrotreatment at Pacific Northwest National Laboratory. Although some feedstocks showed a high fast pyrolysis bio-oil yield such as tulip poplar at 57%, high yields in the hydrotreater were not always observed. Results showed overall fuel yields of 15% (switchgrass), 18% (corn stover), 23% (tulip poplar, Blend 1, Blend 2), 24% (whole pine, hybrid poplar) and 27% (clean pine). Simulated distillation of the upgraded oils indicated that the gasoline fraction varied from 39% (clean pine) to 51% (corn stover), while the diesel fraction ranged from 40% (corn stover) to 46% (tulip poplar). Little variation was seen in the jet fuel fraction at 11 to 12%. Hydrogen consumption during hydrotreating, a major factor in the economic feasibility of the integrated process, ranged from 0.051 g/g dry feed (tulip poplar) to 0.070 g/g dry feed (clean pine).

  4. Molybdenum carbides, active and in situ regenerable catalysts in hydroprocessing of fast pyrolysis bio-oil

    DOE PAGES-Beta [OSTI]

    Choi, Jae -Soon; Zacher, Alan; Wang, Huamin; Olarte, Mariefel V.; Armstrong, Beth L.; Meyer, III, Harry M.; Schwartz, Viviane; Soykal, I. Ilgaz

    2016-05-19

    This paper describes properties of molybdenum carbides as a potential catalyst for fast pyrolysis bio-oil hydroprocessing. Currently, high catalyst cost, short catalyst lifetime, and lack of effective regeneration methods are hampering the development of this otherwise attractive renewable hydrocarbon technology. A series of metal-doped bulk Mo carbides were synthesized, characterized, and evaluated in sequential low-temperature stabilization and high-temperature deoxygenation of a pine-derived bio-oil. During a typical 60 h run, Mo carbides were capable of upgrading raw bio-oil to a level suitable for direct insertion into the current hydrocarbon infrastructure with residual oxygen content and total acid number of upgraded oilsmore » below 2 wt % and 0.01 mg KOH g–1, respectively. The performance was shown to be sensitive to the type of metal dopant, Ni-doped Mo carbides outperforming Co-, Cu-, or Ca-doped counterparts; a higher Ni loading led to a superior catalytic performance. No bulk oxidation or other significant structural changes were observed. Besides the structural robustness, another attractive property of Mo carbides was in situ regenerability. The effectiveness of regeneration was demonstrated by successfully carrying out four consecutive 60 h runs with a reductive decoking between two adjacent runs. These results strongly suggest that Mo carbides are a good catalyst candidate which could lead to a significant cost reduction in hydroprocessing bio-oils. Furthermore, we highlight areas for future research which will be needed to further understand carbide structure–function relationships and help design practical bio-oil upgrading catalysts based on Mo carbides.« less

  5. Lignin pyrolysis in heated grid apparatus: Experiment and theory

    SciTech Connect (OSTI)

    Avni, L.; Coughlin, R.W.; King, H.H.; Solomon, P.R.

    1983-01-01

    The study of lignin pyrolysis has a vital importance since all lignin conversion processes, namely; combustion, liquefaction and gasification, are initiated by this step. Lignin, a major component of biomass is a potential source of aromatic chemicals through the pyrolysis process. This paper considers the application of a recently developed pyrolysis model of coal pyrolysis applied to a heated grid as well as an entrained flow reactor, to the pyrolysis of lignin. Flash pyrolysis as well as slow heating rate pyrolysis was carried out in a heated grid, in which on-line, in-situ gas and tar analysis is performed by Fourier Transform Infrared (FT-IR) Spectroscopy. The model has proved to be successful in simulating the results of vacuum flash pyrolysis and slow heating rate pyrolysis for a variety of lignins. The experiments have shown that lignin pyrolysis kinetics are insensitive to lignin source or extracting process. Theory and experiment agree well for both slow and fast heating rates, using the given model parameters. The lignin parameters of the model are related to the functional group composition of the lignin.

  6. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis, Catalytic Hydroconversion and Co-processing with Vacuum Gas Oil

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis, Catalytic Hydroconversion and Co-processing with Vacuum Gas Oil Raymond G. Wissinger Manager, Renewable Energy & Chemicals Development UOP, LLC This presentation does not contain any proprietary, confidential, or otherwise restricted information © Copyright 2015 UOP LLC, a Honeywell Company 2 File Number Goal Statement * Demonstrate a technically and economically viable approach for converting

  7. Phenolic compounds containing/neutral fractions extract and products derived therefrom from fractionated fast-pyrolysis oils

    DOE Patents [OSTI]

    Chum, Helena L.; Black, Stuart K.; Diebold, James P.; Kreibich, Roland E.

    1993-01-01

    A process for preparing phenol-formaldehyde novolak resins and molding compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils. The fractionation consists of a neutralization stage which can be carried out with aqueous solutions of bases or appropriate bases in the dry state, followed by solvent extraction with an organic solvent having at least a moderate solubility parameter and good hydrogen bonding capacity. Phenolic compounds-containing/neutral fractions extracts obtained by fractionating fast-pyrolysis oils from a lignocellulosic material, is such that the oil is initially in the pH range of 2-4, being neutralized with an aqueous bicarbonate base, and extracted into a solvent having a solubility parameter of approximately 8.4-9.11 [cal/cm.sup.3 ].sup.1/2 with polar components in the 1.8-3.0 range and hydrogen bonding components in the 2-4.8 range and the recovery of the product extract from the solvent with no further purification being needed for use in adhesives and molding compounds. The product extract is characterized as being a mixture of very different compounds having a wide variety of chemical functionalities, including phenolic, carbonyl, aldehyde, methoxyl, vinyl and hydroxyl. The use of the product extract on phenol-formaldehyde thermosetting resins is shown to have advantages over the conventional phenol-formaldehyde resins.

  8. Methods and apparatuses for preparing upgraded pyrolysis oil

    DOE Patents [OSTI]

    Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

    2013-10-01

    Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

  9. Biomass

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Transportation Energy Co-Evolution of Biofuels Lignocellulosic Biomass Microalgae ... HomeBiomass Permalink One-Pot-to-Prep Biomass for Biofuels Biofuels, Biomass, Energy, ...

  10. Proceedings of the Biomass Pyrolysis Oil Properties and Combustion Meeting, 26-28 September 1994, Estes Park, Colorado

    SciTech Connect (OSTI)

    Milne, T.

    1995-01-01

    The increasing scale-up of fast pyrolysis in North America and Europe, as well as the exploration and expansion of markets for the energy use of biocrude oils that now needs to take place, suggested that it was timely to convene an international meeting on the properties and combustion behavior of these oils. A common understanding of the state-of-the-art and technical and other challenges which need to be met during the commercialization of biocrude fuel use, can be achieved. The technical issues and understanding of combustion of these oils are rapidly being advanced through R&D in the United States. Canada, Europe and Scandinavia. It is obvious that for the maximum economic impact of biocrude, it will be necessary to have a common set of specifications so that oils can be used interchangeably with engines and combustors which require minimal modification to use these renewable fuels. Fundamental and applied studies being pursued in several countries are brought together in this workshop so that we can arrive at common strategies. In this way, both the science and the commercialization are advanced to the benefit of all, without detracting from the competitive development of both the technology and its applications. This United States-Canada-Finland collaboration has led to the two and one half day specialists meeting at which the technical basis for advances in biocrude development is discussed. The goal is to arrive at a common agenda on issues that cross national boundaries in this area. Examples of agenda items are combustion phenomena, the behavior of trace components of the oil (N, alkali metals), the formation of NOx in combustion, the need for common standards and environmental safety and health issues in the handling, storage and transportation of biocrudes.

  11. Fast Pyrolysis and Hydrotreating 2013 State of Technology R&D and Projections to 2017

    SciTech Connect (OSTI)

    Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

    2014-04-16

    This report documents the FY13 modeled costs and experimental basis for those costs for fast pyrolyis and hydrotreating to liquid fuels. The report also documents the projected costs to 2013.

  12. Biomass Thermochemical Conversion Program. 1983 Annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1984-08-01

    Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

  13. Fundamentals of thermochemical biomass conversion

    SciTech Connect (OSTI)

    Overend, R.P.; Milne, T.A.; Mudge, L.

    1985-01-01

    The contents of this book are: Wood and biomass ultrastructure; Cellulose, hemicellulose and extractives; Lignin; Pretreatment of biomass for thermochemical biomass conversion; A kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquefaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics; Influence of alkali carbonates on biomass volatilization; Flash pyrolysis of biomass with reactive and non-reactive gases; Pyrolytic reactions and biomass; Product formation in the pyrolysis of large wood particles; The pyrolysis under vacuum of aspen poplar; Simulation of kraft lignin pyrolysis; and Kinetics of wood gasification by carbon dioxide and steam.

  14. Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-09-01

    Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

  15. Flash vacuum pyrolysis of lignin model compounds

    SciTech Connect (OSTI)

    Cooney, M.J.; Britt, P.F.; Buchanan, A.C. III

    1997-03-01

    Despite the extensive research into the pyrolysis of lignin, the underlying chemical reactions that lead to product formation are poorly understood. Detailed mechanistic studies on the pyrolysis of biomass and lignin under conditions relevant to current process conditions could provide insight into utilizing this renewable resource for the production of chemicals and fuel. Currently, flash or fast pyrolysis is the most promising process to maximize the yields of liquid products (up to 80 wt %) from biomass by rapidly heating the substrate to moderate temperatures, typically 500{degrees}C, for short residence times, typically less than two seconds. To provide mechanistic insight into the primary reaction pathways under process relevant conditions, we are investigating the flash vacuum pyrolysis (FVP) of lignin model compounds that contain a {beta}-ether. linkage and {alpha}- or {gamma}-alcohol, which are key structural elements in lignin. The dominant products from the FVP of PhCH{sub 2}CH{sub 2}OPh (PPE), PhC(OH)HCH{sub 2}OPh, and PhCH{sub 2}CH(CH{sub 2}OH)OPh at 500{degrees}C can be attributed to homolysis of the weakest bond in the molecule (C-O bond) or 1,2-elimination. Surprisingly, the hydroxy-substituent dramatically increases the decomposition of PPE. It is proposed that internal hydrogen bonding is accelerating the reaction.

  16. Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils. Final Report

    SciTech Connect (OSTI)

    George W. Huber; Upadhye, Aniruddha A.; Ford, David M.; Bhatia, Surita R.; Badger, Phillip C.

    2012-10-19

    This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8m were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments

  17. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED...

    Office of Scientific and Technical Information (OSTI)

    One factor limiting the development of commercial biomass pyrolysis is challenges related ... This improvement also results in lower liquid yield and high hydrogen consumption. Biomass ...

  18. Process for fractionating fast-pyrolysis oils, and products derived therefrom

    DOE Patents [OSTI]

    Chum, Helena L.; Black, Stuart K.

    1990-01-01

    A process is disclosed for fractionating lignocellulosic materials fast-prolysis oils to produce phenol-containing compositions suitable for the manufacture of phenol-formaldehyde resins. The process includes admixing the oils with an organic solvent having at least a moderate solubility parameter and good hydrogen The United States Government has rights in this invention under Contract No. DE-AC02-83CH10093 between the United States Department of Energy and the Solar Energy Research Institute, a Division of the Midwest Research Institute.

  19. Flash Vacuum Pyrolysis of Lignin Model Compounds: Reaction Pathways of Aromatic Methoxy Groups

    SciTech Connect (OSTI)

    Britt, P.F.; Buchanan, A.C., III; Martineau, D.R.

    1999-03-21

    Currently, there is interest in utilizing lignin, a major constituent of biomass, as a renewable source of chemicals and fuels. High yields of liquid products can be obtained from the flash or fast pyrolysis of biomass, but the reaction pathways that lead to product formation are not understood. To provide insight into the primary reaction pathways under process relevant conditions, we are investigating the flash vacuum pyrolysis (FVP) of lignin model compounds at 500 C. This presentation will focus on the FVP of {beta}-ether linkages containing aromatic methoxy groups and the reaction pathways of methoxy-substituted phenoxy radicals.

  20. Formate-assisted pyrolysis

    SciTech Connect (OSTI)

    DeSisto, William Joseph; Wheeler, Marshall Clayton; van Heiningen, Adriaan R. P.

    2015-03-17

    The present invention provides, among other thing, methods for creating significantly deoxygenated bio-oils form biomass including the steps of providing a feedstock, associating the feedstock with an alkali formate to form a treated feedstock, dewatering the treated feedstock, heating the dewatered treated feedstock to form a vapor product, and condensing the vapor product to form a pyrolysis oil, wherein the pyrolysis oil contains less than 30% oxygen by weight.

  1. Techno-economic and uncertainty analysis of in situ and ex situ fast pyrolysis for biofuel production

    SciTech Connect (OSTI)

    Li, Boyan; Ou, Longwen; Dang, Qi; Meyer, Pimphan A.; Jones, Susanne B.; Brown, Robert C.; Wright, Mark

    2015-11-01

    This study evaluates the techno-economic uncertainty in cost estimates for two emerging biorefinery technologies for biofuel production: in situ and ex situ catalytic pyrolysis. Stochastic simulations based on process and economic parameter distributions are applied to calculate biorefinery performance and production costs. The probability distributions for the minimum fuel-selling price (MFSP) indicate that in situ catalytic pyrolysis has an expected MFSP of $4.20 per gallon with a standard deviation of 1.15, while the ex situ catalytic pyrolysis has a similar MFSP with a smaller deviation ($4.27 per gallon and 0.79 respectively). These results suggest that a biorefinery based on ex situ catalytic pyrolysis could have a lower techno-economic risk than in situ pyrolysis despite a slightly higher MFSP cost estimate. Analysis of how each parameter affects the NPV indicates that internal rate of return, feedstock price, total project investment, electricity price, biochar yield and bio-oil yield are significant parameters which have substantial impact on the MFSP for both in situ and ex situ catalytic pyrolysis.

  2. NREL: Biomass Research - Projects

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Spectrometer analyzes vapors during the gasification and pyrolysis processes. NREL's biomass projects are designed to advance the production of liquid transportation fuels from...

  3. Design Case Summary: Production of Gasoline and Diesel from Biomass...

    Energy.gov (indexed) [DOE]

    Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing Bioenergy Technologies ...

  4. Update of Hydrogen from Biomass - Determination of the Delivered Cost of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hydrogen: Milestone Completion Report | Department of Energy Update of Hydrogen from Biomass - Determination of the Delivered Cost of Hydrogen: Milestone Completion Report Update of Hydrogen from Biomass - Determination of the Delivered Cost of Hydrogen: Milestone Completion Report Milestone report summarizing the economic feasibility of producing hydrogen from biomass via (1) gasification/reforming of the resulting syngas and (2) fast pyrolysis/reforming of the resulting bio-oil. 33112.pdf

  5. CONVERTING PYROLYSIS OILS TO RENEWABLE TRANSPORT FUELS: PROCESSING CHALLENGES & OPPORTUNITIES

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Nair, Prabhakar N.; Elliott, Douglas C.; Bain, Richard; Marinangelli, Richard

    2008-03-11

    To enable a sustained supply of biomass-based transportation fuels, the capability to process feedstocks outside the food chain must be developed. Significant industry efforts are underway to develop these new technologies, such as converting cellulosic wastes to ethanol. UOP, in partnership with U.S. Government labs, NREL and PNNL, is developing an alternate route using cellulosic feedstocks. The waste biomass is first subjected to a fast pyrolysis operation to generate pyrolysis oil (pyoil for short). Current efforts are focused on developing a thermochemical platform to convert pyoils to renewable gasoline, diesel and jet fuel. The fuels produced will be indistinguishable from their fossil fuel counterparts and, therefore, will be compatible with existing transport and distribution infrastructure.

  6. Steam reforming of fast pyrolysis-derived aqueous phase oxygenates over Co, Ni, and Rh metals supported on MgAl2O4

    DOE PAGES-Beta [OSTI]

    Xing, Rong; Dagle, Vanessa Lebarbier; Flake, Matthew; Kovarik, Libor; Albrecht, Karl O.; Deshmane, Chinmay; Dagle, Robert A.

    2016-02-03

    In this paper we examine the feasibility of steam reforming the mixed oxygenate aqueous fraction derived from fast pyrolysis bio-oils. Catalysts selective towards hydrogen formation and resistant to carbon formation utilizing feeds with relatively low steam-to-carbon (S/C) ratios are desired. Rh (5 wt%), Pt (5 wt%), Ru (5 wt%), Ir (5 wt%), Ni (15 wt%), and Co (15 wt%) metals supported on MgAl2O4 were evaluated for catalytic performance at 500 °C and 1 atm using a complex feed mixture comprising acids, polyols, cycloalkanes, and phenolic compounds. The Rh catalyst was found to be the most active and resistant to carbonmore » formation. The Ni and Co catalysts were found to be more active than the other noble metal catalysts investigated (Pt, Ru, and Ir).« less

  7. Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-04-01

    Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling

  8. CORROSIVITY AND COMPOSITION OF RAW AND TREATED PYROLYSIS OILS

    SciTech Connect (OSTI)

    Keiser, Jim; Howell, Michael; Connatser, Raynella M.; Lewis, Sam; Elliott, Douglas C.

    2012-10-14

    Fast pyrolysis offers a relatively low cost method of processing biomass to produce a liquid product that has the potential for conversion to several types of liquid fuels. The liquid product of fast pyrolysis, known as pyrolysis oil or bio-oil, contains a high oxygen content primarily in the form of water, carboxylic acids, phenols, ketones and aldehydes. These oils are typically very acidic with a Total Acid Number that is often in the range of 50 to 100, and previous studies have shown this material to be quite corrosive to common structural materials. Removal of at least some of the oxygen and conversion of this oil to a more useful product that is considerably less corrosive can be accomplished through a hydrogenation process. The product of such a treatment is considered to have the potential for blending with crude oil for processing in petroleum refineries. Corrosion studies and chemical analyses have been conducted using as produced bio-oil samples as well as samples that have been subjected to different levels of oxygen removal. Chemical analyses show treatment affected the concentrations of carboxylic acids contained in the oil, and corrosion studies showed a positive benefit of the oxygen removal. Results of these studies will be presented in this paper.

  9. NREL: Biomass Research - Publications

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    biofuels Biomass process and sustainability analyses. ... For information on biomass policy, read congressional ... on the Yield and Product Distribution of Fast ...

  10. FAST

    Energy Science and Technology Software Center (OSTI)

    002363MLTPL00 FAST - A Framework for Agile Software Testing v. 2.0 https://software.sandia.gov/trac/fast

  11. Biomass conversion processes for energy and fuels

    SciTech Connect (OSTI)

    Sofer, S.S.; Zaborsky, O.R.

    1981-01-01

    The book treats biomass sources, promising processes for the conversion of biomass into energy and fuels, and the technical and economic considerations in biomass conversion. Sources of biomass examined include crop residues and municipal, animal and industrial wastes, agricultural and forestry residues, aquatic biomass, marine biomass and silvicultural energy farms. Processes for biomass energy and fuel conversion by direct combustion (the Andco-Torrax system), thermochemical conversion (flash pyrolysis, carboxylolysis, pyrolysis, Purox process, gasification and syngas recycling) and biochemical conversion (anaerobic digestion, methanogenesis and ethanol fermentation) are discussed, and mass and energy balances are presented for each system.

  12. Biomass Resources and Technology Options

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Bio-Oil From Pyrolysis Biomass Power Current Commercial Technology * Almost all systems are combustion steam turbine * Most are grate stokers but FBC increasingly used * 1-110 MW ...

  13. Charcoal from the pyrolysis of rapeseed plant straw-stalk

    SciTech Connect (OSTI)

    Karaosmanoglu, F.; Tetik, E.

    1999-07-01

    Charcoal is an important product of pyrolysis of biomass sources. Charcoal can be used for domestic, agricultural, metallurgical, and chemical purposes. In this study different characteristics of charcoal, one of the rape seed plant straw-stalk pyrolysis product, was researched and presented as candidates.

  14. Corrosivity Of Pyrolysis Oils

    SciTech Connect (OSTI)

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  15. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

    SciTech Connect (OSTI)

    Wang, Huamin; Male, Jonathan L.; Wang, Yong

    2013-05-01

    There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

  16. Design Case Summary: Production of Gasoline and Diesel from Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    The Pyrolysis Design Case Cost targets for converting biomass to renewable gasoline and ... technologies and to determine where improvements need to take place in the future. ...

  17. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  18. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    SciTech Connect (OSTI)

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-10-07

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  19. Numberical studies of the radiant flash pyrolysis of cellulose

    SciTech Connect (OSTI)

    Kothari, V.; Antal, M.J. Jr.

    1983-01-01

    When biomass particles are heated very rapidly (>1000/sup 0/ C/s) in an oxygen free environment, they undergo pyrolysis with the formation of little or no char. If concentrated solar energy is used to rapidly heat the particles their temperature may exceed that of the surrounding gaseous environment by several hundred degrees Celsius when pyrolysis occurs. This ''two temperature'' effect gives rise to the formation of high yields of syrups from the pyrolyzing biomass. Numberical exploration of the combined effects of heat and mass transfer on the radiative flash pyrolysis phenonmena are described in this paper. (5 tables, 8 figs, 12 refs.)

  20. Numerical studies of the radiant flash pyrolysis of cellulose

    SciTech Connect (OSTI)

    Kothari, V.; Antal, M.J. Jr.

    1983-01-01

    When biomass particles are heated very rapidly (temperatures greater than 1000 degrees/s) in an oxygen free environment, they undergo pyrolysis with the formation of little or no char. If concentrated solar energy is used to rapidly heat the particles their temperature may exceed that of the surrounding gaseous environment by several hundred degrees Celsius when pyrolysis occurs. This two temperature effect gives rise to the formation of high yields of syrups from the pyrolyzing biomass. Numerical exploration of the combined effects of heat and mass transfer on the radiative flash pyrolysis phenonmena are described in this paper. 12 references.

  1. Hydrothermal Liquefaction of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with

  2. Hydropyrolysis of biomass

    SciTech Connect (OSTI)

    Kobayashi, Atsushi; Steinberg, M.

    1992-01-01

    The pyrolysis and hydropyrolysis of biomass was investigated. Experimental runs using the biomass (Poplar wood sawdust) were performed using a tubular reactor of dimensions 1 inch inside diameter and 8 feet long heated at a temperature of 800 C and pressures between 450 and 750 psig. At low heat-up rate the reaction precedes in two steps. First pyrolysis takes place at temperatures of 300 to 400 c and subsequent hydropyrolysis takes place at 700 C and above. This is also confirmed by pressurized thermogravimetric analysis (PTGA). Under conditions of rapid heat-up at higher temperatures and higher hydrogen pressure gasification and hydrogasification of biomass is especially effective in producing carbon monoxide and methane. An overall conversion of 88 to 90 wt % of biomass was obtained. This value is in agreement with the previous work of flash pyrolysis and hydropyrolysis of biomass for rapid heat-up and short residence time. Initial rates of biomass conversion indicate that the rate increases significantly with increase in hydrogen pressure. At 800 C and 755 psig the initial rate of biomass conversion to gases is 0.92 1/min.

  3. Numerical studies of the radiant flash pyrolysis of cellulose

    SciTech Connect (OSTI)

    Kothari, V.; Antal, M.J.

    1983-01-01

    When biomass particles are heated very rapidly (>1000/sup 0/C/s) in an oxygen free environment, they undergo pyrolysis with the formation of little or no char. If concentrated solar energy is used to rapidly heat the particles, their temperature may exceed that of the surrounding gaseous environment by several hundred degrees Celsius when pyrolysis occurs. This ''two temperature'' effect gives rise to the formation of high yields of sirups from the pyrolyzing biomass. Interest in the selective formation of sirups during the radiative flash pyrolysis of biomass caused the authors to initiate numerical explorations of the combined effects of heat and mass transfer on the radiative flash pyrolysis phenomena. These explorations are described in this paper.

  4. Biomass Derivatives Competitive with Heating Oil Costs. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Derivatives Competitive with Heating Oil Costs. Biomass Derivatives Competitive with Heating Oil Costs. Presentation at the May 9, 2012, Pyrolysis Oil Workship on biomass derivatives competitive with heating oil costs. pyrolysis_levine.pdf (733.32 KB) More Documents & Publications Challenge # 1. Feedstock & Production Thermochemical Conversion Proceeses to Aviation Fuels A Review of DOE Biofuels Program

  5. Scrap tire pyrolysis: Experiment and modelling

    SciTech Connect (OSTI)

    Napoli, A.; Soudais, Y.; Lecomte, D.; Castillo, S.

    1997-12-01

    Pyrolysis of waste, usually organic solids like tires, plastics or composite materials, is an alternative thermal waste treatment technology. Three main physical and chemical mechanisms - i.e.: chemical kinetics, internal heat transfer and external heat transfer - have to be considered when modelling the degradation of solid waste particles. Because of the lack of physical properties for wastes most of the models described in the literature use basic data obtained on the pyrolysis of coal, wood and biomass. In this work, the authors report basic information on the thermal degradation of tire samples at small scale: Thermogravimetric analyser (TGA) and differential scanning calorimeter (DSC), as well as direct and indirect measurements of thermal and physical properties (thermal conductivity of the tire and of the char, porosity, density, specific heat). Pyrolysis experiments on tire samples are performed in an imaging furnace. The experimental results are compared to theoretical values deduced from models that take into account physical property measurements.

  6. Catalytic pyrolysis using UZM-44 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-04-29

    A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  7. Catalytic pyrolysis using UZM-44 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christopher P; Boldingh, Edwin P

    2013-12-17

    A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  8. Fundamental Pyrolysis Studies

    SciTech Connect (OSTI)

    Milne, T. A.; Evans, R. J.; Soltys, M. N.

    1983-03-01

    Progress on the direct mass spectrometric sampling of pyrolysis products from wood and its constituents is described for the period from June 1982 to February 1983. A brief summary and references to detailed reports, of the qualitative demonstration of our approach to the study of the separated processes of primary and secondary pyrolysis is presented. Improvements and additions to the pyrolysis and data acquisition systems are discussed and typical results shown. Chief of these are a heated-grid pyrolysis system for controlled primary pyrolysis and a sheathed flame arrangement for secondary cracking studies. Qualitative results of the secondary cracking of cellulose, lignin, and wood are shown as are comparisons with the literature for the pyrolysis spectra of cellulose, lignin, and levoglucosan. 'Fingerprints' for a number of materials are shown, with spectra taken under carefully controlled conditions so that sensitivity calibrations for different compounds, now being determined, can be applied.

  9. Distributed Reforming of Biomass Pyrolysis Oils (Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    forecourt assumptions Catalyst Experimental Results -Rhodium catalyst closest to equilibrium, but system did not include added water CH 3 OH % conversion CO wt. % C CO 2 wt. % C ...

  10. Biomass Direct Liquefaction Options. TechnoEconomic and Life Cycle Assessment

    SciTech Connect (OSTI)

    Tews, Iva J.; Zhu, Yunhua; Drennan, Corinne; Elliott, Douglas C.; Snowden-Swan, Lesley J.; Onarheim, Kristin; Solantausta, Yrjo; Beckman, David

    2014-07-31

    The purpose of this work was to assess the competitiveness of two biomass to transportation fuel processing routes, which were under development in Finland, the U.S. and elsewhere. Concepts included fast pyrolysis (FP), and hydrothermal liquefaction (HTL), both followed by hydrodeoxygenation, and final product refining. This work was carried out as a collaboration between VTT (Finland), and PNNL (USA). The public funding agents for the work were Tekes in Finland and the Bioenergy Technologies Office of the U.S. Department of Energy. The effort was proposed as an update of the earlier comparative technoeconomic assessment performed by the IEA Bioenergy Direct Biomass Liquefaction Task in the 1980s. New developments in HTL and the upgrading of the HTL biocrude product triggered the interest in reinvestigating this comparison of these biomass liquefaction processes. In addition, developments in FP bio-oil upgrading had provided additional definition of this process option, which could provide an interesting comparison.

  11. Biomass thermal conversion research at SERI

    SciTech Connect (OSTI)

    Milne, T. A.; Desrosiers, R. E.; Reed, T. B.

    1980-09-01

    SERI's involvement in the thermochemical conversion of biomass to fuels and chemicals is reviewed. The scope and activities of the Biomass Thermal Conversion and Exploratory Branch are reviewed. The current status and future plans for three tasks are presented: (1) Pyrolysis Mechanisms; (2) High Pressure O/sub 2/ Gasifier; and (3) Gasification Test Facility.

  12. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  13. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  14. Rapid Solar-Thermal Conversion of Biomass to Syngas - Energy Innovation

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Rapid Solar-Thermal Conversion of Biomass to Syngas Production of synthesis gas or hydrogen by gasification or pyrolysis of biological feedstocks using solar-thermal energy. University of Colorado Contact CU About This Technology Technology Marketing Summary The invention provides processes that perform biomass gasification or pyrolysis for production of hydrogen, synthesis gas, liquid fuels, or other

  15. Pyrolysis with cyclone burner

    DOE Patents [OSTI]

    Green, Norman W.; Duraiswamy, Kandaswamy; Lumpkin, Robert E.

    1978-07-25

    In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue and separating out the fines.

  16. Pyrolysis with staged recovery

    DOE Patents [OSTI]

    Green, Norman W.; Duraiswamy, Kandaswamy; Lumpkin, Robert E.; Winter, Bruce L.

    1979-03-20

    In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source fed over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue.

  17. Effect of temperature on pyrolysis product of empty fruit bunches

    SciTech Connect (OSTI)

    Rahman, Aizuddin Abdul; Sulaiman, Fauziah; Abdullah, Nurhayati

    2015-04-24

    Pyrolysis of empty fruit bunches (EFB) was performed in a fixed bed reactor equipped with liquid collecting system. Pyrolysis process was conducted by varying the terminal pyrolysis temperature from 300 to 500°C under heating rate of 10°C/min for at least 2 hours. Char yield was obtained highest at 300°C around 55.88 wt%, and started to decrease as temperature increase. The maximum yield of pyrolysis liquid was obtained around 54.75 wt% as pyrolysis temperature reach 450°C. For gas yield percentage, the yield gained as temperature was increased from 300 to 500°C, within the range between 8.44 to 19.32 wt%. The char obtained at 400°C has great potential as an alternative solid fuel, due to its high heating value of 23.37 MJ/kg, low in volatile matter and ash content which are approximately around 40.32 and 11.12 wt%, respectively. The collected pyrolysis liquid within this temperature range found to have high water content of around 16.15 to 18.20 wt%. The high aqueous fraction seemed to cause the pyrolysis liquid to have low HHV which only ranging from 10.81 to 12.94 MJ/kg. These trends of results showed that necessary enhancement should be employ either on the raw biomass or pyrolysis products in order to approach at least the minimum quality of common hydrocarbon solid or liquid fuel. For energy production, both produced bio-char and pyrolysis liquid are considered as sustainable sources of bio-energy since they contained low amounts of nitrogen and sulphur, which are considered as environmental friendly solid and liquid fuel.

  18. A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2014-02-21

    The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H{sub 2}Bioil) using supplementary hydrogen (H{sub 2}) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H{sub 2} is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H{sub 2}Bioil process for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygenation were constructed, completing Task A. These reactors were capable of operation under a wide-range of conditions; enabling process studies that lead to identification of optimum process conditions. Model compounds representing biomass pyrolysis products were studied, completing Task B. These studies were critical in identifying and developing HDO catalysts to target specific oxygen functional groups. These process and model compound catalyst studies enabled identification of catalysts that achieved 100% deoxygenation of the real biomass feedstock, sorghum, to form hydrocarbons in high yields as part of Task C. The work completed during this grant has identified and validated the novel and commercially scalable H2Bioil process for production of hydrocarbon fuels from biomass. Studies on model compounds as well as real biomass

  19. 90 Seconds of Discovery: Fast Pyrolysis

    ScienceCinema (OSTI)

    Weber, Robert; Elliot, Douglas

    2014-06-13

    Fossil fuels have provided a time-proven, energy-dense fuel for more than a century. The challenge facing America today is developing alternatives that work within our existing infrastructure; to decrease environmental impact; and to increase energy security.

  20. 90 Seconds of Discovery: Fast Pyrolysis

    SciTech Connect (OSTI)

    Weber, Robert; Elliot, Douglas

    2013-01-08

    Fossil fuels have provided a time-proven, energy-dense fuel for more than a century. The challenge facing America today is developing alternatives that work within our existing infrastructure; to decrease environmental impact; and to increase energy security.

  1. Polycyclic aromatic hydrocarbons (PAH) formation from the pyrolysis of different municipal solid waste fractions

    SciTech Connect (OSTI)

    Zhou, Hui; Wu, Chunfei; Onwudili, Jude A.; Meng, Aihong; Zhang, Yanguo; Williams, Paul T.

    2015-02-15

    Highlights: • PAH from pyrolysis of 9 MSW fractions was investigated. • Pyrolysis of plastics released more PAH than that of biomass. • Naphthalene was the most abundant PAH in the tar. • The mechanism of PAH release from biomass and plastics was proposed. - Abstract: The formation of 2–4 ring polycyclic aromatic hydrocarbons (PAH) from the pyrolysis of nine different municipal solid waste fractions (xylan, cellulose, lignin, pectin, starch, polyethylene (PE), polystyrene (PS), polyvinyl chloride (PVC), and polyethylene terephthalate (PET)) were investigated in a fixed bed furnace at 800 °C. The mass distribution of pyrolysis was also reported. The results showed that PS generated the most total PAH, followed by PVC, PET, and lignin. More PAH were detected from the pyrolysis of plastics than the pyrolysis of biomass. In the biomass group, lignin generated more PAH than others. Naphthalene was the most abundant PAH, and the amount of 1-methynaphthalene and 2-methynaphthalene was also notable. Phenanthrene and fluorene were the most abundant 3-ring PAH, while benzo[a]anthracene and chrysene were notable in the tar of PS, PVC, and PET. 2-ring PAH dominated all tar samples, and varied from 40 wt.% to 70 wt.%. For PS, PET and lignin, PAH may be generated directly from the aromatic structure of the feedstock.

  2. DOE Technical Targets for Hydrogen Production from Biomass Gasification |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Biomass Gasification DOE Technical Targets for Hydrogen Production from Biomass Gasification These tables list the U.S. Department of Energy (DOE) technical targets and example cost contributions for hydrogen production from biomass gasification. More information about targets can be found in the Hydrogen Production section of the Fuel Cell Technologies Office's Multi-Year Research, Development, and Demonstration Plan. Technical Targets: Biomass Gasification/Pyrolysis

  3. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R.; Gregg, David W.

    1983-01-01

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  4. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1998-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  5. Pyrolysis process and apparatus

    DOE Patents [OSTI]

    Lee, Chang-Kuei

    1983-01-01

    This invention discloses a process and apparatus for pyrolyzing particulate coal by heating with a particulate solid heating media in a transport reactor. The invention tends to dampen fluctuations in the flow of heating media upstream of the pyrolysis zone, and by so doing forms a substantially continuous and substantially uniform annular column of heating media flowing downwardly along the inside diameter of the reactor. The invention is particularly useful for bituminous or agglomerative type coals.

  6. NO reduction in decoupling combustion of biomass and biomass-coal blend

    SciTech Connect (OSTI)

    Li Dong; Shiqiu Gao; Wenli Song; Jinghai Li; Guangwen Xu

    2009-01-15

    Biomass is a form of energy that is CO{sub 2}-neutral. However, NOx emissions in biomass combustion are often more than that of coal on equal heating-value basis. In this study, a technology called decoupling combustion was investigated to demonstrate how it reduces NO emissions in biomass and biomass-coal blend combustion. The decoupling combustion refers to a two-step combustion method, in which fuel pyrolysis and the burning of char and pyrolysis gas are separated and the gas burns out during its passage through the burning-char bed. Tests in a quartz dual-bed reactor demonstrated that, in decoupling combustion, NO emissions from biomass and biomass-coal blends were both less than those in traditional combustion and that NO emission from combustion of blends of biomass and coal decreased with increasing biomass percentage in the blend. Co-firing rice husk and coal in a 10 kW stove manufactured according to the decoupling combustion technology further confirmed that the decoupling combustion technology allows for truly low NO emission as well as high efficiency for burning biomass and biomass-coal blends, even in small-scale stoves and boilers. 22 refs., 6 figs., 1 tab.

  7. Controlled catalystic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1994-01-01

    A process of using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents.

  8. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1994-06-14

    A process is described using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents. 68 figs.

  9. Pyrolysis of polystyrene - polyphenylene oxide to recover styrene and useful products

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1995-01-01

    A process of using fast pyrolysis in a carrier gas to convert a polystyrene and polyphenylene oxide plastic waste to a given polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components therein comprising: selecting a first temperature range to cause pyrolysis of given polystyrene and polyphenylene oxide and its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and a support and treating the feed stream with the catalyst to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of high value monomeric constituent of styrene from polystyrene and polyphenylene oxide in the first temperature range; differentially heating the feed stream at a heat rate within the first temperature range to provide differential pyrolysis for selective recovery of the high value monomeric constituent of styrene from polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components; separating the high value monomer constituent of styrene; selecting a second higher temperature range to cause pyrolysis to a different derived high value product of polyphenylene oxide from the plastic waste and differentially heating the feed stream at the higher temperature range to cause pyrolysis of the plastic into a polyphenylene oxide derived product; and separating the different derived high value polyphenylene oxide product.

  10. Catalytic Upgrading of Pyrolysis Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Office (BETO) 2015 Project Peer Review Catalytic Upgrading of Pyrolysis Products March 24 th , 2015 Thermochemical Conversion Josh Schaidle NREL This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 2.3.1.314 Goal Statement The goal of this project is to design and develop scalable and cost-effective next generation catalysts for ex-situ catalytic fast pyrolysis (CFP) to improve the fuel quality and stability of the resulting bio-oil by reducing

  11. Chapter 8: Pyrolysis Mechanisms of Lignin Model Compounds Using a Heated Micro-Reactor

    SciTech Connect (OSTI)

    Robichaud, David J.; Nimlos, Mark R.; Ellison, G. Barney

    2015-10-03

    Lignin is an important component of biomass, and the decomposition of its thermal deconstruction products is important in pyrolysis and gasification. In this chapter, we investigate the unimolecular pyrolysis chemistry through the use of singly and doubly substituted benzene molecules that are model compounds representative of lignin and its primary pyrolysis products. These model compounds are decomposed in a heated micro-reactor, and the products, including radicals and unstable intermediates, are measured using photoionization mass spectrometry and matrix isolation infrared spectroscopy. We show that the unimolecular chemistry can yield insight into the initial decomposition of these species. At pyrolysis and gasification severities, singly substituted benzenes typically undergo bond scission and elimination reactions to form radicals. Some require radical-driven chain reactions. For doubly substituted benzenes, proximity effects of the substituents can change the reaction pathways.

  12. Aromatics and phenols from catalytic pyrolysis of Douglas fir pellets in microwave with ZSM-5 as a catalyst

    SciTech Connect (OSTI)

    Wang, Lu; Lei, Hanwu; Ren, Shoujie; Bu, Quan; Liang, Jing; Wei, Yi; Liu, Yupeng; Lee, Guo-Shuh J.; Chen, Shulin; Tang, Juming; Zhang, Qin; Ruan, Roger

    2012-11-04

    Microwave assisted catalytic pyrolysis was investigated to convert Douglas fir pellets to bio-oils by a ZSM-5 Zeolite catalyst. A central composite experimental design (CCD) was used to optimize the catalytic pyrolysis process. The effects of reaction time, temperature and catalyst to biomass ratio on the bio-oil, syngas, and biochar yields were determined. GC/MS analysis results showed that the bio-oil contained a series of important and useful chemical compounds. Phenols, guaiacols, and aromatic hydrocarbons were the most abundant compounds which were about 50-82 % in bio-oil depending on the pyrolysis conditions. Comparison between the bio-oils from microwave pyrolysis with and without catalyst showed that the catalyst increased the content of aromatic hydrocarbons and phenols. A reaction pathway was proposed for microwave assisted catalyst pyrolysis of Douglas fir pellets.

  13. Catalyst specificities in high pressure hydroprocessing of pyrolysis and gasification tars

    SciTech Connect (OSTI)

    Soltes, E.J.; Lin, S.C.K.; Sheu, Y.H.E.

    1987-04-01

    Over a period of several years, the Department of Forest Science at Texas A and M University has been conducting studies in the hydroprocessing (catalytic high pressure hydrotreating or hydrodeoxygenation accompanied by hydrocracking) of pyrolytic tars produced in biomass pyrolysis and gasification. Upgrading through hydroprocessing results in good yields of volatile hydrocarbon and phenolic products. This paper compares the performance of twenty different catalysts selected for hydroprocessing of a pine pyrolysis oil, describes the use of noble metal catalysts with tars produced from nine different biomass feedstocks (oil from pine pyrolysis and the tars from pine wood chip, pine plywood trim, pecan shell, peanut shell, sugarcane bagasse, corncob, rice hull, and cottonseed hull gasification), and compares the use of several catalysts in a trickle bed reactor for kinetic studies of the hyroprocessing reaction.

  14. Yields and composition of syrups resulting from the flash pyrolysis of cellulosic materials using radiant energy

    SciTech Connect (OSTI)

    De Jenga, C.I.; Antal, M.J. Jr.; Jones, M. Jr.

    1982-11-01

    Cellulosic materials have been flash pyrolyzed using concentrated solar energy. The syrups obtained were composed mainly of levoglucosan. Radiant flash pyrolysis has thus been identified as a potentially attractive means of selectively degrading biomass material into good yields of relatively few products. The techniques and equipment employed to determine the composition of the pyrolyzates are described.

  15. Technical and economic analyses of hydrogen production via indirectly heated gasification and pyrolysis

    SciTech Connect (OSTI)

    Mann, M.K.

    1995-09-01

    Technoeconomic analyses have been conducted on two processes to produce hydrogen from biomass: indirectly-heated gasification of biomass followed by steam reforming of the syngas, and biomass pyrolysis followed by steam reforming of the pyrolysis oil. The analysis of the gasification-based process was highly detailed, including a process flowsheet, material and energy balances calculated with a process simulation program, equipment cost estimation, and the determination of the necessary selling price of hydrogen. The pyrolysis-based process analysis was of a less detailed nature, as all necessary experimental data have not been obtained; this analysis is a follow-up to the preliminary economic analysis presented at the 1994 Hydrogen Program Review. A coproduct option in which pyrolysis oil is used to produce hydrogen and a commercial adhesive was also studied for economic viability. Based on feedstock availability estimates, three plant sizes were studied: 907 T/day, 272 T/day, and 27 T/day. The necessary selling price of hydrogen produced by steam reforming syngas from the Battelle Columbus Laboratories indirectly heated biomass gasifier falls within current market values for the large and medium size plants within a wide range of feedstock costs. Results show that the small scale plant does not produce hydrogen at economically competitive prices, indicating that if gasification is used as the upstream process to produce hydrogen, local refueling stations similar to current gasoline stations, would probably not be feasible.

  16. Cellulose Pyrolysis A Literature, Review.

    Office of Scientific and Technical Information (OSTI)

    Pyrolysis A Literature, Review. - - pacific N o r t h ... I ' I . - " 1- jl, . .' , . - --h 1 , i b - . "I 1.- . . ... probably act primarily by physical means (e.g., borax), 2) ...

  17. Biomass Rapid Analysis Network (BRAN)

    SciTech Connect (OSTI)

    Not Available

    2003-10-01

    Helping the emerging biotechnology industry develop new tools and methods for real-time analysis of biomass feedstocks, process intermediates and The Biomass Rapid Analysis Network is designed to fast track the development of modern tools and methods for biomass analysis to accelerate the development of the emerging industry. The network will be led by industry and organized and coordinated through the National Renewable Energy Lab. The network will provide training and other activities of interest to BRAN members. BRAN members will share the cost and work of rapid analysis method development, validate the new methods, and work together to develop the training for the future biomass conversion workforce.

  18. Biomass pretreatment

    DOE Patents [OSTI]

    Hennessey, Susan Marie; Friend, Julie; Elander, Richard T; Tucker, III, Melvin P

    2013-05-21

    A method is provided for producing an improved pretreated biomass product for use in saccharification followed by fermentation to produce a target chemical that includes removal of saccharification and or fermentation inhibitors from the pretreated biomass product. Specifically, the pretreated biomass product derived from using the present method has fewer inhibitors of saccharification and/or fermentation without a loss in sugar content.

  19. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethylene-terephthalate and polyethylene to sequentially recover [monomers

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1998-10-13

    A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feed stream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

  20. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals

    DOE Patents [OSTI]

    Chum, H.L.; Evans, R.J.

    1992-08-04

    A process is described for using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent. 11 figs.

  1. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals

    DOE Patents [OSTI]

    Chum, Helena L.; Evans, Robert J.

    1992-01-01

    A process of using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent.

  2. Biomass Logistics

    SciTech Connect (OSTI)

    J. Richard Hess; Kevin L. Kenney; William A. Smith; Ian Bonner; David J. Muth

    2015-04-01

    Equipment manufacturers have made rapid improvements in biomass harvesting and handling equipment. These improvements have increased transportation and handling efficiencies due to higher biomass densities and reduced losses. Improvements in grinder efficiencies and capacity have reduced biomass grinding costs. Biomass collection efficiencies (the ratio of biomass collected to the amount available in the field) as high as 75% for crop residues and greater than 90% for perennial energy crops have also been demonstrated. However, as collection rates increase, the fraction of entrained soil in the biomass increases, and high biomass residue removal rates can violate agronomic sustainability limits. Advancements in quantifying multi-factor sustainability limits to increase removal rate as guided by sustainable residue removal plans, and mitigating soil contamination through targeted removal rates based on soil type and residue type/fraction is allowing the use of new high efficiency harvesting equipment and methods. As another consideration, single pass harvesting and other technologies that improve harvesting costs cause biomass storage moisture management challenges, which challenges are further perturbed by annual variability in biomass moisture content. Monitoring, sampling, simulation, and analysis provide basis for moisture, time, and quality relationships in storage, which has allowed the development of moisture tolerant storage systems and best management processes that combine moisture content and time to accommodate baled storage of wet material based upon “shelf-life.” The key to improving biomass supply logistics costs has been developing the associated agronomic sustainability and biomass quality technologies and processes that allow the implementation of equipment engineering solutions.

  3. YEAR 2 BIOMASS UTILIZATION

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke

    2004-11-01

    This Energy & Environmental Research Center (EERC) Year 2 Biomass Utilization Final Technical Report summarizes multiple projects in biopower or bioenergy, transportation biofuels, and bioproducts. A prototype of a novel advanced power system, termed the high-temperature air furnace (HITAF), was tested for performance while converting biomass and coal blends to energy. Three biomass fuels--wood residue or hog fuel, corn stover, and switchgrass--and Wyoming subbituminous coal were acquired for combustion tests in the 3-million-Btu/hr system. Blend levels were 20% biomass--80% coal on a heat basis. Hog fuel was prepared for the upcoming combustion test by air-drying and processing through a hammer mill and screen. A K-Tron biomass feeder capable of operating in both gravimetric and volumetric modes was selected as the HITAF feed system. Two oxide dispersion-strengthened (ODS) alloys that would be used in the HITAF high-temperature heat exchanger were tested for slag corrosion rates. An alumina layer formed on one particular alloy, which was more corrosion-resistant than a chromia layer that formed on the other alloy. Research activities were completed in the development of an atmospheric pressure, fluidized-bed pyrolysis-type system called the controlled spontaneous reactor (CSR), which is used to process and condition biomass. Tree trimmings were physically and chemically altered by the CSR process, resulting in a fuel that was very suitable for feeding into a coal combustion or gasification system with little or no feed system modifications required. Experimental procedures were successful for producing hydrogen from biomass using the bacteria Thermotoga, a deep-ocean thermal vent organism. Analytical procedures for hydrogen were evaluated, a gas chromatography (GC) method was derived for measuring hydrogen yields, and adaptation culturing and protocols for mutagenesis were initiated to better develop strains that can use biomass cellulose. Fly ash derived from

  4. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE CONDITIONS WITH SPECIAL CONSIDERATION TO PIPELINE SHIPMENT

    SciTech Connect (OSTI)

    Bunting, Bruce G; Boyd, Alison C

    2012-01-01

    One factor limiting the development of commercial biomass pyrolysis is challenges related to the transportation of the produced pyrolysis oil. The oil has different chemical and physical properties than crude oil, including more water and oxygen and has lower H/C ratio, higher specific gravity and density, higher acidity, and lower energy content. These differences could limit its ability to be transported by existing petroleum pipelines. Pyrolysis oil can also be treated, normally by catalytic hydrodeoxygenation, and approaches crude oil and petroleum condensates at higher severity levels. This improvement also results in lower liquid yield and high hydrogen consumption. Biomass resources for pyrolysis are expected to become plentiful and widely distributed in the future, mainly through the use of crop residuals and growing of energy crops such as perennial grasses, annual grasses, and woody crops. Crude oil pipelines are less well distributed and, when evaluated on a county level, could access about 18% of the total biomass supply. States with high potential include Texas, Oklahoma, California, and Louisiana. In this study, published data on pyrolysis oil was compiled into a data set along with bio-source source material, pyrolysis reactor conditions, and upgrading conditions for comparison to typical crude oils. Data of this type is expected to be useful in understanding the properties and chemistry and shipment of pyrolysis oil to refineries, where it can be further processed to fuel or used as a source of process heat.

  5. Biomass One Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleBiomassOneBiomassFacility&oldid397204" Feedback Contact needs updating Image needs...

  6. Chemical Characterization and Water Content Determination of Bio-Oils Obtained from Various Biomass Species using 31P NMR Spectroscopy

    SciTech Connect (OSTI)

    David, K.; Ben, H.; Muzzy, J.; Feik, C.; Iisa, K.; Ragauskas, A.

    2012-03-01

    Pyrolysis is a promising approach to utilize biomass for biofuels. One of the key challenges for this conversion is how to analyze complicated components in the pyrolysis oils. Water contents of pyrolysis oils are normally analyzed by Karl Fischer titration. The use of 2-chloro-4,4,5,5,-tetramethyl-1,3,2-dioxaphospholane followed by {sup 31}P NMR analysis has been used to quantitatively analyze the structure of hydroxyl groups in lignin and whole biomass. Results: {sup 31}P NMR analysis of pyrolysis oils is a novel technique to simultaneously characterize components and analyze water contents in pyrolysis oils produced from various biomasses. The water contents of various pyrolysis oils range from 16 to 40 wt%. The pyrolysis oils obtained from Loblolly pine had higher guaiacyl content, while that from oak had a higher syringyl content. Conclusion: The comparison with Karl Fischer titration shows that {sup 31}P NMR could also reliably be used to measure the water content of pyrolysis oils. Simultaneously with analysis of water content, quantitative characterization of hydroxyl groups, including aliphatic, C-5 substituted/syringyl, guaiacyl, p-hydroxyl phenyl and carboxylic hydroxyl groups, could also be provided by {sup 31}P NMR analysis.

  7. Vacuum pyrolysis of used tires

    SciTech Connect (OSTI)

    Roy, C.; Darmstadt, H.; Benallal, B.; Chaala, A.; Schwerdtfeger, A.E.

    1995-11-01

    The vacuum pyrolysis of used tires enables the recovery of useful products, such as pyrolytic oil and pyrolytic carbon black (CB{sub P}). The light part of the pyrolytic oil contains dl-limonene which has a high price on the market. The naphtha fraction can be used as a high octane number component for gasoline. The middle distillate demonstrated mechanical and lubricating properties similar to those of the commercial aromatic oil Dutrex R 729. The heavy oil was tested as a feedstock for the production of needle coke. It was found that the surface morphology of CB{sub P} produced by vacuum pyrolysis resembles that of commercial carbon black. The CB{sub P} contains a higher concentration of inorganic compounds (especially ZnO and S) than commercial carbon black. The pyrolysis process feasibility looks promising. One old tire can generate upon vacuum pyrolysis, incomes of at least $2.25 US with a potential of up to $4.83 US/tire upon further product improvement. The process has been licensed to McDermott Marketing Servicing Inc. (Houston) for its exploitation in the US.

  8. Hydrogen production from switchgrass via a hybrid pyrolysis-microbial electrolysis process

    SciTech Connect (OSTI)

    Lewis, Alex J.; Ren, Shoujie; Ye, Philip; Kim, Pyoungchung; Labbe, Niki; Borole, Abhijeet P.

    2015-06-30

    A new approach to hydrogen production using a hybrid pyrolysis-microbial electrolysis process is described. The aqueous stream generated during pyrolysis of switchgrass was used as a substrate for hydrogen production in a microbial electrolysis cell, achieving a maximum hydrogen production rate of 4.3 L H2/L-day at a loading of 10 g COD/L-anode-day. Hydrogen yields ranged from 50 3.2% to76 0.5% while anode coulombic efficiency ranged from 54 6.5% to 96 0.21%, respectively. Significant conversion of furfural, organic acids and phenolic molecules was observed under both batch and continuous conditions. The electrical and overall energy efficiency ranged from 149-175% and 48-63%, respectively. The results demonstrate the potential of the pyrolysis-microbial electrolysis process as a sustainable and efficient route for production of renewable hydrogen with significant implications for hydrocarbon production from biomass.

  9. Hydrogen production from switchgrass via a hybrid pyrolysis-microbial electrolysis process

    SciTech Connect (OSTI)

    Lewis, Alex J; Ren, Shoujie; Ye, Philip; Kim, Pyoungchung; Labbe, Niki; Borole, Abhijeet P

    2015-01-01

    A new approach to hydrogen production using a hybrid pyrolysis-microbial electrolysis process is described. The aqueous stream generated during pyrolysis of switchgrass was used as a substrate for hydrogen production in a microbial electrolysis cell, achieving a maximum hydrogen production rate of 4.3 L H2/L-day at a loading of 10 g COD/L-anode-day. Hydrogen yields ranged from 50 3.2% to76 0.5% while anode coulombic efficiency ranged from 54 6.5% to 96 0.21%, respectively. Significant conversion of furfural, organic acids and phenolic molecules was observed under both batch and continuous conditions. The electrical and overall energy efficiency ranged from 149-175% and 48-63%, respectively. The results demonstrate the potential of the pyrolysis-microbial electrolysis process as a sustainable and efficient route for production of renewable hydrogen with significant implications for hydrocarbon production from biomass.

  10. Biomass and Waste-to-Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Anaerobic Digestion & Biogas: Industry Perspectives ... waste and manure, and municipal commercial food waste. ... Production of Gasoline and Diesel from Biomass via Fast ...

  11. Reforming Pyrolysis Aqueous Waste Streams to Process Hydrogen and Hydrocarbons Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1: Reforming Pyrolysis Aqueous Waste Streams to Process Hydrogen and Hydrocarbons March 27, 2015 Kim Magrini 2 | Bioenergy Technologies Office eere.energy.gov Program Mission: Transform our renewable biomass resources into commercially viable, high-performance biofuels, bioproducts, and biopower through targeted research, development, demonstration, and deployment supported through public and private partnerships. Task Goal: Develop, evaluate and characterize reforming and upgrading catalysts

  12. Past, Present, and Future Production of Bio-oil (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Bio-oil is a liquid product produced by fast pyrol-ysis of biomass. The fast pyrolysis is performed by heating the biomass rapidly (2 sec) at temperatures ranging from 350 to 650 ...

  13. Methods for pretreating biomass

    DOE Patents [OSTI]

    Balan, Venkatesh; Dale, Bruce E; Chundawat, Shishir; Sousa, Leonardo

    2015-03-03

    A method of alkaline pretreatment of biomass, in particular, pretreating biomass with gaseous ammonia.

  14. A Review on Biomass Torrefaction Process and Product Properties

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Shahab Sokhansanj; Christopher T. Wright; J. Richard Hess; Richard D. Boardman

    2011-08-01

    Biomass Torrefaction is gaining attention as an important preprocessing step to improve the quality of biomass in terms of physical properties and chemical composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of approximately 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-280 C. Thus, the process can be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, which produces a final product that will have a lower mass but a higher heating value. The present review work looks into (a) torrefaction process and different products produced during the process and (b) solid torrefied material properties which include: (i) physical properties like moisture content, density, grindability, particle size distribution and particle surface area and pelletability; (ii) chemical properties like proximate and ultimate composition; and (iii) storage properties like off-gassing and spontaneous combustion.

  15. An economic analysis of mobile pyrolysis for northern New Mexico forests.

    SciTech Connect (OSTI)

    Brady, Patrick D.; Brown, Alexander L.; Mowry, Curtis Dale; Borek, Theodore Thaddeus, III

    2011-12-01

    In the interest of providing an economically sensible use for the copious small-diameter wood in Northern New Mexico, an economic study is performed focused on mobile pyrolysis. Mobile pyrolysis was selected for the study because transportation costs limit the viability of a dedicated pyrolysis plant, and the relative simplicity of pyrolysis compared to other technology solutions lends itself to mobile reactor design. A bench-scale pyrolysis system was used to study the wood pyrolysis process and to obtain performance data that was otherwise unavailable under conditions theorized to be optimal given the regional problem. Pyrolysis can convert wood to three main products: fixed gases, liquid pyrolysis oil and char. The fixed gases are useful as low-quality fuel, and may have sufficient chemical energy to power a mobile system, eliminating the need for an external power source. The majority of the energy content of the pyrolysis gas is associated with carbon monoxide, followed by light hydrocarbons. The liquids are well characterized in the historical literature, and have slightly lower heating values comparable to the feedstock. They consist of water and a mix of hundreds of hydrocarbons, and are acidic. They are also unstable, increasing in viscosity with time stored. Up to 60% of the biomass in bench-scale testing was converted to liquids. Lower ({approx}550 C) furnace temperatures are preferred because of the decreased propensity for deposits and the high liquid yields. A mobile pyrolysis system would be designed with low maintenance requirements, should be able to access wilderness areas, and should not require more than one or two people to operate the system. The techno-economic analysis assesses fixed and variable costs. It suggests that the economy of scale is an important factor, as higher throughput directly leads to improved system economic viability. Labor and capital equipment are the driving factors in the viability of the system. The break

  16. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1994-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  17. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1994-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  18. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1993-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  19. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1994-10-25

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

  20. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1994-04-05

    A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 87 figures.

  1. Desulfurized gas production from vertical kiln pyrolysis

    DOE Patents [OSTI]

    Harris, Harry A.; Jones, Jr., John B.

    1978-05-30

    A gas, formed as a product of a pyrolysis of oil shale, is passed through hot, retorted shale (containing at least partially decomposed calcium or magnesium carbonate) to essentially eliminate sulfur contaminants in the gas. Specifically, a single chambered pyrolysis vessel, having a pyrolysis zone and a retorted shale gas into the bottom of the retorted shale zone and cleaned product gas is withdrawn as hot product gas near the top of such zone.

  2. Apparatus for entrained coal pyrolysis

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy

    1982-11-16

    This invention discloses a process and apparatus for pyrolyzing particulate coal by heating with a particulate solid heating media in a transport reactor. The invention tends to dampen fluctuations in the flow of heating media upstream of the pyrolysis zone, and by so doing forms a substantially continuous and substantially uniform annular column of heating media flowing downwardly along the inside diameter of the reactor. The invention is particularly useful for bituminous or agglomerative type coals.

  3. Thermochemical Conversion of Woody Biomass to Fuels and Chemicals Final Report

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2015-09-30

    Maine and its industries identified more efficient utilization of biomass as a critical economic development issue. In Phase I of this implementation project, a research team was assembled, research equipment was implemented and expertise was demonstrated in pyrolysis, hydrodeoxygenation of pyrolysis oils, catalyst synthesis and characterization, and reaction engineering. Phase II built upon the infrastructure to innovate reaction pathways and process engineering, and integrate new approaches for fuels and chemical production within pulp and paper and other industries within the state. This research cluster brought together chemists, engineers, physicists and students from the University of Maine, Bates College, and Bowdoin College. The project developed collaborations with Oak Ridge National Laboratory and Brookhaven National Laboratory. The specific research projects within this proposal were of critical interest to the DoE - in particular the biomass program within EERE and the catalysis/chemical transformations program within BES. Scientific and Technical Merit highlights of this project included: (1) synthesis and physical characterization of novel size-selective catalyst/supports using engineered mesoporous (1-10 nm diameter pores) materials, (2) advances in fundamental knowledge of novel support/ metal catalyst systems tailored for pyrolysis oil upgrading, (3) a microcalorimetric sensing technique, (4) improved methods for pyrolysis oil characterization, (5) production and characterization of woody biomass-derived pyrolysis oils, (6) development of two new patented bio oil pathways: thermal deoxygenation (TDO) and formate assisted pyrolysis (FASP), and (7) technoeconomics of pyrolysis of Maine forest biomass. This research cluster has provided fundamental knowledge to enable and assess pathways to thermally convert biomass to hydrocarbon fuels and chemicals.

  4. Controlled catalystic and thermal sequential pyrolysis and hydrolysis...

    Office of Scientific and Technical Information (OSTI)

    range to cause pyrolysis of a given polymer to its high value monomeric constituents ... temperature; range; pyrolysis; polymer; value; monomeric; constituents; prior; ...

  5. FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds Breakout Session 2: Frontiers and Horizons ...

  6. Lyonsdale Biomass LLC Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Biomass Facility Jump to: navigation, search Name Lyonsdale Biomass LLC Biomass Facility Facility Lyonsdale Biomass LLC Sector Biomass Location Lewis County, New York...

  7. Biomass One LP Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LP Biomass Facility Jump to: navigation, search Name Biomass One LP Biomass Facility Facility Biomass One LP Sector Biomass Location Jackson County, Oregon Coordinates 42.334535,...

  8. Biomass Feed and Gasification

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    the feeding and conversion of biomass and coal-biomass mixtures as essential upstream ... Activities support research for handling and processing of coal-biomass mixtures, ensuring ...

  9. Star Biomass | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Jump to: navigation, search Name: Star Biomass Place: India Sector: Biomass Product: Plans to set up biomass projects in Rajasthan. References: Star Biomass1 This article...

  10. Lignocellulosic Biomass

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Lignocellulosic Biomass - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  11. Flash pyrolysis products from beech wood

    SciTech Connect (OSTI)

    Beaumont, O.

    1985-04-01

    Flash pyrolysis products from beech wood obtained in an original pyrolysis apparatus were analyzed. The analytical procedure is described, and the composition of pyrolytic oil presented with more than 50 compounds. Comparison of pyrolytic products of cellulose, hemicellulose, and wood indicates the origin of each product. 19 references.

  12. Life-Cycle Assessment of Pyrolysis Bio-Oil Production*

    SciTech Connect (OSTI)

    Steele, Philip; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

    2012-07-01

    As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

  13. The Influence of Process Conditions on the Chemical Composition of Pine Wood Catalytic Pyrolysis Oils

    DOE PAGES-Beta [OSTI]

    Pereira, J.; Agblevor, F. A.; Beis, S. H.

    2012-01-01

    Pine wood samples were used as model feedstock to study the properties of catalytic fast pyrolysis oils. The influence of two commercial zeolite catalysts (BASF and SudChem) and pretreatment of the pine wood with sodium hydroxide on pyrolysis products were investigated. The pyrolysis oils were first fractionated using column chromatography and characterized using GC-MS. Long chain aliphatic hydrocarbons, levoglucosan, aldehydes and ketones, guaiacols/syringols, and benzenediols were the major compounds identified in the pyrolysis oils. The catalytic pyrolysis increased the polycyclic hydrocarbons fraction. Significant decreases in phthalate derivatives using SudChem and long chain aliphatics using BASF catalyst were observed. Significant amountsmore » of aromatic heterocyclic hydrocarbons and benzene derivatives were formed, respectively, using BASF and SudChem catalysts. Guaiacyl/syringyl and benzenediols derivatives were partly suppressed by the zeolite catalysts, while the sodium hydroxide treatment enriched phenolic derivatives. Zeolite catalyst and sodium hydroxide were employed together; they showed different results for each catalyst.« less

  14. Tracy Biomass Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    NEEDS 2006 Database Retrieved from "http:en.openei.orgwindex.php?titleTracyBiomassBiomassFacility&oldid398234" Feedback Contact needs updating Image needs...

  15. Biomass shock pretreatment

    DOE Patents [OSTI]

    Holtzapple, Mark T.; Madison, Maxine Jones; Ramirez, Rocio Sierra; Deimund, Mark A.; Falls, Matthew; Dunkelman, John J.

    2014-07-01

    Methods and apparatus for treating biomass that may include introducing a biomass to a chamber; exposing the biomass in the chamber to a shock event to produce a shocked biomass; and transferring the shocked biomass from the chamber. In some aspects, the method may include pretreating the biomass with a chemical before introducing the biomass to the chamber and/or after transferring shocked biomass from the chamber.

  16. Environmental impacts of thermochemical biomass conversion. Final report

    SciTech Connect (OSTI)

    Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; McKinney, M.D.; Norton, M.V.; Abrams, C.W.

    1995-06-01

    Thermochemical conversion in this study is limited to fast pyrolysis, upgrading of fast pyrolysis oils, and gasification. Environmental impacts of all types were considered within the project, but primary emphasis was on discharges to the land, air, and water during and after the conversion processes. The project discussed here is divided into five task areas: (1) pyrolysis oil analysis; (2) hydrotreating of pyrolysis oil; (3) gas treatment systems for effluent minimization; (4) strategic analysis of regulatory requirements; and (5) support of the IEA Environmental Systems Activity. The pyrolysis oil task was aimed at understanding the oil contaminants and potential means for their removal. The hydrotreating task was undertaken to better define one potential means for both improving the quality of the oil but also removing contaminants from the oil. Within Task 3, analyses were done to evaluate the results of gasification product treatment systems. Task 4 was a review and collection of regulatory requirements which would be applicable to the subject processes. The IEA support task included input to and participation in the IEA Bioenergy activity which directly relates to the project subject. Each of these tasks is described along with the results. Conclusions and recommendations from the overall project are given.

  17. Waste tire recycling by pyrolysis

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This project examines the City of New Orleans' waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans' waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city's limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city's waste tire problem. Pending state legislation could improve the city's ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

  18. Biomass Conversion

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Feedstocks to Final Products To efficiently convert algae, diverse types of cellulosic biomass, and emerging feedstocks into renewable fuels, the U.S. Department of Energy (DOE) supports research, development, and demonstration of technologies. This research will help ensure that these renewable fuels are compatible with today's vehicles and infrastructure. Advanced biofuels are part of the United States' "all-of-the-above" energy strategy to develop domestic energy resources and win

  19. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  20. ©2013 Catalysis Center for Energy Innovation * University of...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    biomass sources and feed them directly into their process, Catalytic Fast Pyrolysis (CFP). Within the reactor, particles of biomass are rapidly heated within seconds to 900 F, ...

  1. Coal liquefaction with subsequent bottoms pyrolysis

    DOE Patents [OSTI]

    Walchuk, George P.

    1978-01-01

    In a coal liquefaction process wherein heavy bottoms produced in a liquefaction zone are upgraded by coking or a similar pyrolysis step, pyrolysis liquids boiling in excess of about 1000.degree. F. are further reacted with molecular hydrogen in a reaction zone external of the liquefaction zone, the resulting effluent is fractionated to produce one or more distillate fractions and a bottoms fraction, a portion of this bottoms fraction is recycled to the reaction zone, and the remaining portion of the bottoms fraction is recycled to the pyrolysis step.

  2. Biomass Thermochemical Conversion Program. 1984 annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1985-01-01

    The objective of the program is to generate scientific data and conversion process information that will lead to establishment of cost-effective process for converting biomass resources into clean fuels. The goal of the program is to develop the data base for biomass thermal conversion by investigating the fundamental aspects of conversion technologies and by exploring those parameters that are critical to the conversion processes. The research activities can be divided into: (1) gasification technology; (2) liquid fuels technology; (3) direct combustion technology; and (4) program support activities. These activities are described in detail in this report. Outstanding accomplishments during fiscal year 1984 include: (1) successful operation of 3-MW combustor/gas turbine system; (2) successful extended term operation of an indirectly heated, dual bed gasifier for producing medium-Btu gas; (3) determination that oxygen requirements for medium-Btu gasification of biomass in a pressurized, fluidized bed gasifier are low; (4) established interdependence of temperature and residence times on biomass pyrolysis oil yields; and (5) determination of preliminary technical feasibility of thermally gasifying high moisture biomass feedstocks. A bibliography of 1984 publications is included. 26 figs., 1 tab.

  3. 1982 annual report: Biomass Thermochemical Conversion Program

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1983-01-01

    This report provides a brief overview of the Thermochemical Conversion Program's activities and major accomplishments during fiscal year 1982. The objective of the Biomass Thermochemical Conversion Program is to generate scientific data and fundamental biomass converison process information that, in the long term, could lead to establishment of cost effective processes for conversion of biomass resources into clean fuels and petrochemical substitutes. The goal of the program is to improve the data base for biomass conversion by investigating the fundamental aspects of conversion technologies and exploring those parameters which are critical to these conversion processes. To achieve this objective and goal, the Thermochemical Conversion Program is sponsoring high-risk, long-term research with high payoff potential which industry is not currently sponsoring, nor is likely to support. Thermochemical conversion processes employ elevated temperatures to convert biomass materials into energy. Process examples include: combustion to produce heat, steam, electricity, direct mechanical power; gasification to produce fuel gas or synthesis gases for the production of methanol and hydrocarbon fuels; direct liquefaction to produce heavy oils or distillates; and pyrolysis to produce a mixture of oils, fuel gases, and char. A bibliography of publications for 1982 is included.

  4. BIOMASS TO BIO-OIL BY LIQUEFACTION

    SciTech Connect (OSTI)

    Wang, Huamin; Wang, Yong

    2013-01-10

    Significant efforts have been devoted to develop processes for the conversion of biomass, an abundant and sustainable source of energy, to liquid fuels and chemicals, in order to replace diminishing fossil fuels and mitigate global warming. Thermochemical and biochemical methods have attracted the most attention. Among the thermochemical processes, pyrolysis and liquefaction are the two major technologies for the direct conversion of biomass to produce a liquid product, often called bio-oil. This chapter focuses on the liquefaction, a medium-temperature and high-pressure thermochemical process for the conversion of biomass to bio-oil. Water has been most commonly used as a solvent and the process is known as hydrothermal liquefaction (HTL). Fundamentals of HTL process, key factors determining HTL behavior, role of catalyst in HTL, properties of produced bio-oil, and the current status of the technology are summarized. The liquefaction of biomass by using organic solvents, a process called solvolysis, is also discussed. A wide range of biomass feedstocks have been tested for liquefaction including wood, crop residues, algae, food processing waste, and animal manure.

  5. Waste tire recycling by pyrolysis

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This project examines the City of New Orleans` waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans` waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city`s limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city`s waste tire problem. Pending state legislation could improve the city`s ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

  6. Pyrolysis of waste tyres: A review

    SciTech Connect (OSTI)

    Williams, Paul T.

    2013-08-15

    Graphical abstract: - Highlights: Pyrolysis of waste tyres produces oil, gas and char, and recovered steel. Batch, screw kiln, rotary kiln, vacuum and fluidised-bed are main reactor types. Product yields are influenced by reactor type, temperature and heating rate. Pyrolysis oils are complex and can be used as chemical feedstock or fuel. Research into higher value products from the tyre pyrolysis process is reviewed. - Abstract: Approximately 1.5 billion tyres are produced each year which will eventually enter the waste stream representing a major potential waste and environmental problem. However, there is growing interest in pyrolysis as a technology to treat tyres to produce valuable oil, char and gas products. The most common reactors used are fixed-bed (batch), screw kiln, rotary kiln, vacuum and fluidised-bed. The key influence on the product yield, and gas and oil composition, is the type of reactor used which in turn determines the temperature and heating rate. Tyre pyrolysis oil is chemically very complex containing aliphatic, aromatic, hetero-atom and polar fractions. The fuel characteristics of the tyre oil shows that it is similar to a gas oil or light fuel oil and has been successfully combusted in test furnaces and engines. The main gases produced from the pyrolysis of waste tyres are H{sub 2}, C{sub 1}C{sub 4} hydrocarbons, CO{sub 2}, CO and H{sub 2}S. Upgrading tyre pyrolysis products to high value products has concentrated on char upgrading to higher quality carbon black and to activated carbon. The use of catalysts to upgrade the oil to a aromatic-rich chemical feedstock or the production of hydrogen from waste tyres has also been reported. Examples of commercial and semi-commercial scale tyre pyrolysis systems show that small scale batch reactors and continuous rotary kiln reactors have been developed to commercial scale.

  7. Biomass Feedstock and Conversion Supply System Design and Analysis

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Mohammad S. Roni; Patrick Lamers; Kara G. Cafferty

    2014-09-01

    Idaho National Laboratory (INL) supports the U.S. Department of Energy’s bioenergy research program. As part of the research program INL investigates the feedstock logistics economics and sustainability of these fuels. A series of reports were published between 2000 and 2013 to demonstrate the feedstock logistics cost. Those reports were tailored to specific feedstock and conversion process. Although those reports are different in terms of conversion, some of the process in the feedstock logistic are same for each conversion process. As a result, each report has similar information. A single report can be designed that could bring all commonality occurred in the feedstock logistics process while discussing the feedstock logistics cost for different conversion process. Therefore, this report is designed in such a way that it can capture different feedstock logistics cost while eliminating the need of writing a conversion specific design report. Previous work established the current costs based on conventional equipment and processes. The 2012 programmatic target was to demonstrate a delivered biomass logistics cost of $55/dry ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model. The goal of the 2017 Design Case is to enable expansion of biofuels production beyond highly productive resource areas by breaking the reliance of cost-competitive biofuel production on a single, low-cost feedstock. The 2017 programmatic target is to supply feedstock to the conversion facility that meets the in-feed conversion process quality specifications at a total logistics cost of $80/dry T. The $80/dry T. target encompasses total delivered feedstock cost, including both grower payment and logistics costs, while meeting all conversion in-feed quality targets

  8. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, Robert J.; Chum, Helena L.

    1994-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  9. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1994-10-25

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

  10. Consider upgrading pyrolysis oils into renewable fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Holmgren, Jennifer; Marinangelli, Richard; nair, Prabhakar; Bain, Richard

    2008-09-01

    New research is identifying processing routes to convert cellulosic biomass into transportation fuels

  11. Biomass torrefaction mill

    DOE Patents [OSTI]

    Sprouse, Kenneth M.

    2016-05-17

    A biomass torrefaction system includes a mill which receives a raw biomass feedstock and operates at temperatures above 400 F (204 C) to generate a dusty flue gas which contains a milled biomass product.

  12. Biomass to Gasoline and DIesel Using Integrated Hydropyrolysis and Hydroconversion

    SciTech Connect (OSTI)

    Marker, Terry; Roberts, Michael; Linck, Martin; Felix, Larry; Ortiz-Toral, Pedro; Wangerow, Jim; Tan, Eric; Gephart, John; Shonnard, David

    2013-01-02

    Cellulosic and woody biomass can be directly converted to hydrocarbon gasoline and diesel blending components through the use of integrated hydropyrolysis plus hydroconversion (IH2). The IH2 gasoline and diesel blending components are fully compatible with petroleum based gasoline and diesel, contain less than 1% oxygen and have less than 1 total acid number (TAN). The IH2 gasoline is high quality and very close to a drop in fuel. The DOE funding enabled rapid development of the IH2 technology from initial proof-of-principle experiments through continuous testing in a 50 kg/day pilot plant. As part of this project, engineering work on IH2 has also been completed to design a 1 ton/day demonstration unit and a commercial-scale 2000 ton/day IH2 unit. These studies show when using IH2 technology, biomass can be converted directly to transportation quality fuel blending components for the same capital cost required for pyrolysis alone, and a fraction of the cost of pyrolysis plus upgrading of pyrolysis oil. Technoeconomic work for IH2 and lifecycle analysis (LCA) work has also been completed as part of this DOE study and shows IH2 technology can convert biomass to gasoline and diesel blending components for less than $2.00/gallon with greater than 90% reduction in greenhouse gas emissions. As a result of the work completed in this DOE project, a joint development agreement was reached with CRI Catalyst Company to license the IH2 technology. Further larger-scale, continuous testing of IH2 will be required to fully demonstrate the technology, and funding for this is recommended. The IH2 biomass conversion technology would reduce U.S. dependence on foreign oil, reduce the price of transportation fuels, and significantly lower greenhouse gas (GHG) emissions. It is a breakthrough for the widespread conversion of biomass to transportation fuels.

  13. Science Activities in Biomass

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    concern plant growth and the environment, byproducts of biomass, and energy contained in different types of biomass. Provided by the Department of Energy's National Renewable...

  14. NREL: Biomass Research - Facilities

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Facilities At NREL's state-of-the-art biomass research facilities, researchers design and optimize processes to convert renewable biomass feedstocks into transportation fuels and...

  15. NREL: Biomass Research - Capabilities

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    is then separated, purified, and recovered for use as a transportation fuel. NREL biomass researchers and scientists have strong capabilities in many facets of biomass...

  16. Biomass Analytical Library

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    diversity and performance, The chemical and physical properties of biomass and biomass feedstocks are characterized as they move through the supply chain to various conversion...

  17. Sources of biomass feedstock variability and the potential impact on biofuels production

    SciTech Connect (OSTI)

    Williams, C. Luke; Westover, Tyler L.; Emerson, Rachel M.; Tumuluru, Jaya Shankar; Li, Chenlin

    2015-11-23

    In this study, terrestrial lignocellulosic biomass has the potential to be a carbon neutral and domestic source of fuels and chemicals. However, the innate variability of biomass resources, such as herbaceous and woody materials, and the inconsistency within a single resource due to disparate growth and harvesting conditions, presents challenges for downstream processes which often require materials that are physically and chemically consistent. Intrinsic biomass characteristics, including moisture content, carbohydrate and ash compositions, bulk density, and particle size/shape distributions are highly variable and can impact the economics of transforming biomass into value-added products. For instance, ash content increases by an order of magnitude between woody and herbaceous feedstocks (from ~0.5 to 5 %, respectively) while lignin content drops by a factor of two (from ~30 to 15 %, respectively). This increase in ash and reduction in lignin leads to biofuel conversion consequences, such as reduced pyrolysis oil yields for herbaceous products as compared to woody material. In this review, the sources of variability for key biomass characteristics are presented for multiple types of biomass. Additionally, this review investigates the major impacts of the variability in biomass composition on four conversion processes: fermentation, hydrothermal liquefaction, pyrolysis, and direct combustion. Finally, future research processes aimed at reducing the detrimental impacts of biomass variability on conversion to fuels and chemicals are proposed.

  18. Sources of biomass feedstock variability and the potential impact on biofuels production

    DOE PAGES-Beta [OSTI]

    Williams, C. Luke; Westover, Tyler L.; Emerson, Rachel M.; Tumuluru, Jaya Shankar; Li, Chenlin

    2015-11-23

    In this study, terrestrial lignocellulosic biomass has the potential to be a carbon neutral and domestic source of fuels and chemicals. However, the innate variability of biomass resources, such as herbaceous and woody materials, and the inconsistency within a single resource due to disparate growth and harvesting conditions, presents challenges for downstream processes which often require materials that are physically and chemically consistent. Intrinsic biomass characteristics, including moisture content, carbohydrate and ash compositions, bulk density, and particle size/shape distributions are highly variable and can impact the economics of transforming biomass into value-added products. For instance, ash content increases by anmore » order of magnitude between woody and herbaceous feedstocks (from ~0.5 to 5 %, respectively) while lignin content drops by a factor of two (from ~30 to 15 %, respectively). This increase in ash and reduction in lignin leads to biofuel conversion consequences, such as reduced pyrolysis oil yields for herbaceous products as compared to woody material. In this review, the sources of variability for key biomass characteristics are presented for multiple types of biomass. Additionally, this review investigates the major impacts of the variability in biomass composition on four conversion processes: fermentation, hydrothermal liquefaction, pyrolysis, and direct combustion. Finally, future research processes aimed at reducing the detrimental impacts of biomass variability on conversion to fuels and chemicals are proposed.« less

  19. The direct observation of alkali vapor species in biomass combustion and gasification

    SciTech Connect (OSTI)

    French, R.J.; Dayton, D.C.; Milne, T.A.

    1994-01-01

    This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

  20. Biomass Program Overview

    SciTech Connect (OSTI)

    2010-01-01

    This document provides an overview of the Biomass Program's mission, strategic goals, and research approach.

  1. Biomass Webinar Presentation Slides

    Office of Energy Efficiency and Renewable Energy (EERE)

    Download presentation slides for the DOE Office of Indian Energy webinar on biomass renewable energy.

  2. Biomass treatment method

    DOE Patents [OSTI]

    Friend, Julie; Elander, Richard T.; Tucker, III; Melvin P.; Lyons, Robert C.

    2010-10-26

    A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

  3. Opportunities for Biomass-Based Fuels and Products in a Refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy Opportunities for Biomass-Based Fuels and Products in a Refinery Opportunities for Biomass-Based Fuels and Products in a Refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Corinne Valkenburg, Staff Engineer, Pacific Northwest National Laboratory biomass13_male_2-d.pdf (891.45 KB) More Documents & Publications FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds 2013

  4. Pyrolysis kinetics for the Bakken shale

    SciTech Connect (OSTI)

    Burnham, A.K.

    1992-01-01

    Pyrolysis kinetics are reported and compared for rapid open pyrolysis experiments: Py-TG-FTIR, Py-FID, and Py-MS. Where the type of information obtained overlapped, the results were very similar. The principal activation energy for total hydrocarbon generation using a parallel reaction model is 52 kcal/mol. As with most petroleum source rocks, carbon dioxide generation tends to lead oil formation while ethene and methane generation tend to lag oil generation. The midpoint of oil generation for a geological heating rate of 3 {degrees}C/m.y. is predicted to be between 130 and 140{degrees}C. 5 refs., 4 figs., 1 tab.

  5. Biomass Feed and Gasification

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass Feed and Gasification The Biomass Feed and Gasification Key Technology will advance scientific knowledge of the feeding and conversion of biomass and coal-biomass mixtures as essential upstream steps for production of liquid transportation fuels with a lower net GHG emissions than conventional oil refining. Activities support research for handling and processing of coal-biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on

  6. Hydrogen production from switchgrass via a hybrid pyrolysis-microbial electrolysis process

    DOE PAGES-Beta [OSTI]

    Lewis, Alex J.; Ren, Shoujie; Ye, Philip; Kim, Pyoungchung; Labbe, Niki; Borole, Abhijeet P.

    2015-06-30

    A new approach to hydrogen production using a hybrid pyrolysis-microbial electrolysis process is described. The aqueous stream generated during pyrolysis of switchgrass was used as a substrate for hydrogen production in a microbial electrolysis cell, achieving a maximum hydrogen production rate of 4.3 L H2/L-day at a loading of 10 g COD/L-anode-day. Hydrogen yields ranged from 50 3.2% to76 0.5% while anode coulombic efficiency ranged from 54 6.5% to 96 0.21%, respectively. Significant conversion of furfural, organic acids and phenolic molecules was observed under both batch and continuous conditions. The electrical and overall energy efficiency ranged from 149-175% and 48-63%,more » respectively. The results demonstrate the potential of the pyrolysis-microbial electrolysis process as a sustainable and efficient route for production of renewable hydrogen with significant implications for hydrocarbon production from biomass.« less

  7. Processes for converting lignocellulosics to reduced acid pyrolysis oil

    DOE Patents [OSTI]

    Kocal, Joseph Anthony; Brandvold, Timothy A

    2015-01-06

    Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.

  8. Calvin Mukarakate | Bioenergy | NREL

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Mukarakate Calvin Mukarakate Senior Scientist Calvin.Mukarakate@nrel.gov | 303-384-7724 Research Interests Production of transportation fuels from biomass pyrolysis vapors Selective conversion of biomass pyrolysis vapors to form monomers for renewable polymers Production of hydrogen and chemical intermediates from pyrolysis aqueous waste streams Areas of Expertise Catalyst fast pyrolysis of biomass to produce transportation fuels and chemicals Reforming pyrolysis aqueous waste streams to process

  9. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more

  10. Corrosion considerations for thermochemical biomass liquefaction process systems in biofuel production

    SciTech Connect (OSTI)

    Brady, Michael P.; Keiser, James R.; Leonard, Donovan N.; Whitmer, Lysle; Thomson, Jeffery K.

    2014-11-11

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oils to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 °C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. Lastly, this paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.

  11. Corrosion considerations for thermochemical biomass liquefaction process systems in biofuel production

    DOE PAGES-Beta [OSTI]

    Brady, Michael P.; Keiser, James R.; Leonard, Donovan N.; Whitmer, Lysle; Thomson, Jeffery K.

    2014-11-11

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oilsmore » to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 °C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. Lastly, this paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.« less

  12. Research Summary: Corrosion Considerations for Thermochemical Biomass Liquefaction Process Systems in Biofuel Production

    DOE PAGES-Beta [OSTI]

    Brady, Michael P; Keiser, James R; Leonard, Donovan N; Whitmer, Lysle; Thomson, Jeffery K

    2014-01-01

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oilsmore » to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. This paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.« less

  13. Research Summary: Corrosion Considerations for Thermochemical Biomass Liquefaction Process Systems in Biofuel Production

    SciTech Connect (OSTI)

    Brady, Michael P; Keiser, James R; Leonard, Donovan N; Whitmer, Lysle; Thomson, Jeffery K

    2014-01-01

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oils to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. This paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.

  14. FAST | NISAC

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    FAST v8 Offers New Modeling and Analysis Features FAST v8 Offers New Modeling and Analysis Features May 11, 2016 - 5:34pm Addthis Researchers at NREL recently released version 8.15 of FAST (FAST v8), an open-source, multiphysics engineering software tool used to design and analyze wind turbines. FAST v8 is also an open-source modular platform for creating, testing, and demonstrating new modeling and analysis capabilities. The new features in FAST v8 include: The ability to model advanced

  15. AGCO Biomass Solutions: Biomass 2014 Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AGCO Biomass Solutions: Biomass 2014 Presentation AGCO Biomass Solutions: Biomass 2014 Presentation Plenary IV: Advances in Bioenergy Feedstocks-From Field to Fuel AGCO Biomass Solutions: Biomass 2014 Presentation Glenn Farris, Marketing Manager Biomass, AGCO Corporation farris_biomass_2014.pdf (2.11 MB) More Documents & Publications High Level Overview of DOE Biomass Logistics II Project Activities 2013 Peer Review Presentations-Feedstock Supply and Logistics Feedstock Supply and

  16. Process development for biomass liquefaction

    SciTech Connect (OSTI)

    Elliott, D.C.

    1980-01-01

    The biomass liquefaction processes (Bureau of Mines and LBL) in use at DOE's experimental facility in Albany, Oregon are described. The chemical composition of the distillate fractions is given. An economic analysis of the 2 processes showed that the LBL process requires less capital investment but the operational costs are very similar. When considered for use as a substitute fuel oil, wood oil as produced at Albany by the LBL process appears qualitatively to fall somewhere between petroleum derived number 6 Fuel Oil and the synthetic oil derived from the Occidental Flash Pyrolysis process. Wood oil falls nearly half way between the other two oils in nearly all categories except that wood oil is very low in sulfur content. This comparison is valid on a chemical basis, however, the use of wood oil purely as a substitute fuel is not currently economically attractive. Despite the large amount of resources already expended on research of this process, it remains in a developmental stage and new technology could have a significant impact on the process economics. The alternate use of wood oil as a chemical feedstock is also being studied.

  17. Dual Layer Monolith ATR of Pyrolysis Oil for Distributed Synthesis Gas Production

    SciTech Connect (OSTI)

    Lawal, Adeniyi

    2012-09-29

    We have successfully demonstrated a novel reactor technology, based on BASF dual layer monolith catalyst, for miniaturizing the autothermal reforming of pyrolysis oil to syngas, the second and most critical of the three steps for thermochemically converting biomass waste to liquid transportation fuel. The technology was applied to aged as well as fresh samples of pyrolysis oil derived from five different biomass feedstocks, namely switch-grass, sawdust, hardwood/softwood, golden rod and maple. Optimization of process conditions in conjunction with innovative reactor system design enabled the minimization of carbon deposit and control of the H2/CO ratio of the product gas. A comprehensive techno-economic analysis of the integrated process using in part, experimental data from the project, indicates (1) net energy recovery of 49% accounting for all losses and external energy input, (2) weight of diesel oil produced as a percent of the biomass to be ~14%, and (3) for a demonstration size biomass to Fischer-Tropsch liquid plant of ~ 2000 daily barrels of diesel, the price of the diesel produced is ~$3.30 per gallon, ex. tax. However, the extension of catalyst life is critical to the realization of the projected economics. Catalyst deactivation was observed and the modes of deactivation, both reversible and irreversible were identified. An effective catalyst regeneration strategy was successfully demonstrated for reversible catalyst deactivation while a catalyst preservation strategy was proposed for preventing irreversible catalyst deactivation. Future work should therefore be focused on extending the catalyst life, and a successful demonstration of an extended (> 500 on-stream hours) catalyst life would affirm the commercial viability of the process.

  18. Indirect heating pyrolysis of oil shale

    DOE Patents [OSTI]

    Jones, Jr., John B.; Reeves, Adam A.

    1978-09-26

    Hot, non-oxygenous gas at carefully controlled quantities and at predetermined depths in a bed of lump oil shale provides pyrolysis of the contained kerogen of the oil shale, and cool non-oxygenous gas is passed up through the bed to conserve the heat

  19. Research on the pyrolysis of hardwood in an entrained bed process development unit

    SciTech Connect (OSTI)

    Kovac, R.J.; Gorton, C.W.; Knight, J.A.; Newman, C.J.; O'Neil, D.J. . Research Inst.)

    1991-08-01

    An atmospheric flash pyrolysis process, the Georgia Tech Entrained Flow Pyrolysis Process, for the production of liquid biofuels from oak hardwood is described. The development of the process began with bench-scale studies and a conceptual design in the 1978--1981 timeframe. Its development and successful demonstration through research on the pyrolysis of hardwood in an entrained bed process development unit (PDU), in the period of 1982--1989, is presented. Oil yields (dry basis) up to 60% were achieved in the 1.5 ton-per-day PDU, far exceeding the initial target/forecast of 40% oil yields. Experimental data, based on over forty runs under steady-state conditions, supported by material and energy balances of near-100% closures, have been used to establish a process model which indicates that oil yields well in excess of 60% (dry basis) can be achieved in a commercial reactor. Experimental results demonstrate a gross product thermal efficiency of 94% and a net product thermal efficiency of 72% or more; the highest values yet achieved with a large-scale biomass liquefaction process. A conceptual manufacturing process and an economic analysis for liquid biofuel production at 60% oil yield from a 200-TPD commercial plant is reported. The plant appears to be profitable at contemporary fuel costs of $21/barrel oil-equivalent. Total capital investment is estimated at under $2.5 million. A rate-of-return on investment of 39.4% and a pay-out period of 2.1 years has been estimated. The manufacturing cost of the combustible pyrolysis oil is $2.70 per gigajoule. 20 figs., 87 tabs.

  20. Fast Ignition

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    fast ignition Fast Ignition Researchers Study Fast Ignition University of California at San Diego researchers participate in experiments on the Titan laser at LLNL's Jupiter Laser Facility to study fast ignition. The approach being taken by the National Ignition Facility to achieve thermonuclear ignition and burn is called the "central hot spot" scenario. This technique relies on simultaneous compression and ignition of a spherical fuel capsule in an implosion, roughly like in a diesel

  1. Theoretical Study of the Thermal Decomposition of Carboxylic Acids at Pyrolysis Temperature

    SciTech Connect (OSTI)

    Clark, J. M.; Robichaud, D. J.; Nimlos, M. R.

    2013-01-01

    Carboxylic acids are important in the processing of biomass into renewable fuels and chemicals. They are formed from the pretreatment and pyrolysis of hemicellulose biopolymers and are released from the decomposition of sugars. They result from the deconstruction of polyhydroxyalkanoates (bacterial carbon storage polymers) from fatty acids derived from algae, bacteria, and oil crops. The thermal deoxygenation of carboxylic acids is an important step in the conversion of biomass into aliphatic hydrocarbons suitable for use in renewable biofuels and as petrochemical replacements. Decarboxylation, a primary decomposition pathway under pyrolysis conditions, represents an ideal conversion process, because it eliminates two atoms of oxygen for every carbon atom removed. Problematically, additional deoxygenation processes exist (e.g. dehydration) that are in direct competition with decarboxylation and result in the formation of reactive and more fragmented end products. To better understand the competition between decarboxylation and other deoxygenation processes and to gain insight into possible catalysts that would favor decarboxylation, we have investigated the mechanisms and thermochemistry of the various unimolecular and bimolecular deoxygenation pathways for a family of C1-C4 organic acids using electronic structure calculations at the M06-2X/6-311++G(2df,p) level of theory.

  2. Russell Biomass | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Place: Massachusetts Sector: Biomass Product: Russell Biomass, LLC is developing a 50MW biomass to energy project at the former Westfield Paper Company site in Russell,...

  3. Biomass for Electricity Generation

    Reports and Publications

    2002-01-01

    This paper examines issues affecting the uses of biomass for electricity generation. The methodology used in the National Energy Modeling System to account for various types of biomass is discussed, and the underlying assumptions are explained.

  4. Biomass 2014 Draft Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Biomass 2014 Draft Agenda All topics and times are tentative and subject to change. Page | 1 BIOMASS 2014: Growing the Future Bioeconomy July 29-30, 2014, Washington Convention ...

  5. Reprint of: Pyrolysis technologies for municipal solid waste: A review

    SciTech Connect (OSTI)

    Chen, Dezhen; Yin, Lijie; Wang, Huan; He, Pinjing

    2015-03-15

    Highlights: • MSW pyrolysis reactors, products and environmental impacts are reviewed. • MSW pyrolysis still has to deal with flue gas emissions and products’ contamination. • Definition of standardized products is suggested to formalize MSW pyrolysis technology. • Syngas is recommended to be the target product for single MSW pyrolysis technology. - Abstract: Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO{sub 2} and NH{sub 3}, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.

  6. Pyrolysis technologies for municipal solid waste: A review

    SciTech Connect (OSTI)

    Chen, Dezhen; Yin, Lijie; Wang, Huan; He, Pinjing

    2014-12-15

    Highlights: • MSW pyrolysis reactors, products and environmental impacts are reviewed. • MSW pyrolysis still has to deal with flue gas emissions and products’ contamination. • Definition of standardized products is suggested to formalize MSW pyrolysis technology. • Syngas is recommended to be the target product for single MSW pyrolysis technology. - Abstract: Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO{sub 2} and NH{sub 3}, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.

  7. Pretreated densified biomass products

    DOE Patents [OSTI]

    Dale, Bruce E; Ritchie, Bryan; Marshall, Derek

    2014-03-18

    A product comprising at least one densified biomass particulate of a given mass having no added binder and comprised of a plurality of lignin-coated plant biomass fibers is provided, wherein the at least one densified biomass particulate has an intrinsic density substantially equivalent to a binder-containing densified biomass particulate of the same given mass and h a substantially smooth, non-flakey outer surface. Methods for using and making the product are also described.

  8. Biomass Characterization | Bioenergy | NREL

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Extractability, Bioenergy Research (2016) Compositional Analysis of Biomass Reference Materials: Results from an Interlaboratory Study, Bioenergy Research (2015) View all ...

  9. Biomass Program Biopower Factsheet

    SciTech Connect (OSTI)

    2010-03-01

    Generating electricity and thermal energy from biomass has the potential to help meet national goals for renewable energy. The forest products industry has used biomass for power and heat for many decades, yet widespread use of biomass to supply electricity to the U.S. power grid and other applications is relatively recent.

  10. Small Modular Biomass Systems

    SciTech Connect (OSTI)

    2002-12-01

    This fact sheet provides information about modular biomass systems. Small modular biomass systems can help supply electricity to rural areas, businesses, and the billions of people who live without power worldwide. These systems use locally available biomass fuels such as wood, crop waste, animal manures, and landfill gas.

  11. Biomass gasification at the focus of the Odeillo (France 1-MW (thermal) solar furnace

    SciTech Connect (OSTI)

    Antal, M.J. Jr.; Royere, C.; Vialaron, A.

    1980-01-01

    Experiments described in this paper were undertaken to explore the use of concentrated solar radiation for the flash pyrolysis of biomass. Biomass materials (powdered, microcrystalline cellulose and ground corn cob material) have been successfully gasified in a windowed chemical reactor operating at the focus of the Odeillo 1 MW/sub th/ solar furnace. The quartz window survived radiant flux levels in excess of 1000 W/cm/sup 2/; however impurities carried by the steam flow into the reactor ultimately clouded the window. Pyrolytic char yields of the Odeillo experimetns were quite low: ranging between one and four percent. Gas yields were also relatively low, but condensible yields were high. These results reflect the important role played by the gas phase chemistry (largely unaffected by the high solar flux) in the production of permanent gases from biomass. A consideration of the characteristic times for chemical kinetic and heat transfer phenomenon within a rapidly pyrolyzing particle indicate that heat transfer (not chemical kinetics) is the rate limiting step. However, the thermochemical and optical properties of biomass materials are poorly understood and much more experimental work must be completed before definitive conclusions in this important area can be made. Because the use of concentrated solar radiation for direct gasification of biomass materials results in the formation of little or no char without reliance on the water gas or Boudourad reactions, solar flash pyrolysis of biomass holds unusual promise for the economical production of liquid and gaseous fuels from renewable resources.

  12. Effects of torrefaction and densification on switchgrass pyrolysis products

    SciTech Connect (OSTI)

    Yang, Zixu; Sarkar, Madhura; Kumar, Ajay; Tumuluru, Jaya Shankar; Huhnke, Raymond L.

    2014-12-01

    Abstract The pyrolysis behaviors of four types of pretreated switchgrass (torrefied at 230 and 270 °C, densification, and torrefaction at 270 ºC followed by densification) were studied at three temperatures (500, 600, 700 ºC) using a pyroprobe attached to a gas chromatogram mass spectroscopy (Py-GC/MS). The torrefaction of switchgrass improved its oxygen to carbon ratio and energy content. Contents of anhydrous sugars and phenols in pyrolysis products of torrefied switchgrass were higher than those in pyrolysis products of raw switchgrass. As the torrefaction temperature increased from 230 to 270 °C, the contents of anhydrous sugars and phenols in pyrolysis products increased whereas content of guaiacols decreased. High pyrolysis temperature (600 and 700 °C as compared to 500 °C) enhanced decomposition of lignin and anhydrous sugars, leading to increase in phenols, aromatics and furans. Densification enhanced depolymerization of cellulose and hemicellulose during pyrolysis.

  13. Effects of torrefaction and densification on switchgrass pyrolysis products

    SciTech Connect (OSTI)

    Yang, Zixu; Sarkar, Madhura; Kumar, Ajay; Tumuluru, Jaya Shankar; Huhnke, Raymond L.

    2014-12-01

    Abstract The pyrolysis behaviors of four types of pretreated switchgrass (torrefied at 230 and 270 C, densification, and torrefaction at 270 C followed by densification) were studied at three temperatures (500, 600, 700 C) using a pyroprobe attached to a gas chromatogram mass spectroscopy (Py-GC/MS). The torrefaction of switchgrass improved its oxygen to carbon ratio and energy content. Contents of anhydrous sugars and phenols in pyrolysis products of torrefied switchgrass were higher than those in pyrolysis products of raw switchgrass. As the torrefaction temperature increased from 230 to 270 C, the contents of anhydrous sugars and phenols in pyrolysis products increased whereas content of guaiacols decreased. High pyrolysis temperature (600 and 700 C as compared to 500 C) enhanced decomposition of lignin and anhydrous sugars, leading to increase in phenols, aromatics and furans. Densification enhanced depolymerization of cellulose and hemicellulose during pyrolysis.

  14. Chemical Analysis of Soot Using Thermal Desorption/Pyrolysis Gas

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Chromatography/Mass Spectrometry | Department of Energy Analysis of Soot Using Thermal Desorption/Pyrolysis Gas Chromatography/Mass Spectrometry Chemical Analysis of Soot Using Thermal Desorption/Pyrolysis Gas Chromatography/Mass Spectrometry A new method of soot analysis using thermal/pyrolysis GS-MS has provided a faster, more efficient analytical method to understand the surface chemistry of the soot. p-15_lewis.pdf (450.33 KB) More Documents & Publications Accelerated Extraction of

  15. Understanding Biomass Feedstock Variability

    SciTech Connect (OSTI)

    Kevin L. Kenney; William A. Smith; Garold L. Gresham; Tyler L. Westover

    2013-01-01

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that due to inherent species variabilities, production conditions, and differing harvest, collection, and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture, and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  16. Understanding Biomass Feedstock Variability

    SciTech Connect (OSTI)

    Kevin L. Kenney; Garold L. Gresham; William A. Smith; Tyler L. Westover

    2013-01-01

    If the singular goal of biomass logistics and the design of biomass feedstock supply systems is to reduce the per-ton supply cost of biomass, these systems may very well develop with ultimate unintended consequences of highly variable and reduced quality biomass feedstocks. This paper demonstrates that, due to inherent species variabilities, production conditions and differing harvest, collection and storage practices, this is a very real scenario that biomass producers and suppliers as well as conversion developers should be aware of. Biomass feedstock attributes of ash, carbohydrates, moisture and particle morphology will be discussed. We will also discuss specifications for these attributes, inherent variability of these attributes in biomass feedstocks, and approaches and solutions for reducing variability for improving feedstock quality.

  17. NREL: Biomass Research - Biomass Characterization Capabilities

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass Characterization Capabilities A photo of a man wearing a white lab coat and looking into a large microscope. A researcher uses an Atomic Force Microscope to image enzymes...

  18. Process for minimizing solids contamination of liquids from coal pyrolysis

    DOE Patents [OSTI]

    Wickstrom, Gary H.; Knell, Everett W.; Shaw, Benjamin W.; Wang, Yue G.

    1981-04-21

    In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

  19. Technical Information Exchange on Pyrolysis Oil: Potential for...

    Energy Savers

    renewable heating oil substitution Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution Two-day agenda from the workshop: Technical ...

  20. Applications of Modern Pyrolysis Gas Chromatography for the Study...

    Office of Scientific and Technical Information (OSTI)

    Publisher: Advances in Gas Chromatography, Applications of Modern Pyrolysis Gas ... Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, ...

  1. Applications of Modern Pyrolysis Gas Chromatography for the Study...

    Office of Scientific and Technical Information (OSTI)

    Publisher: Advances in Gas Chromatography, Applications of Modern Pyrolysis Gas ... States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

  2. Polycyclic aromatic hydrocarbons (PAH) formation from the pyrolysis...

    Office of Scientific and Technical Information (OSTI)

    the pyrolysis of different municipal solid waste fractions Citation Details In-Document ... Resource Relation: Journal Name: Waste Management; Journal Volume: 36; Other ...

  3. Complex pendulum biomass sensor

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Perrenoud, Ben C.

    2007-12-25

    A complex pendulum system biomass sensor having a plurality of pendulums. The plurality of pendulums allow the system to detect a biomass height and density. Each pendulum has an angular deflection sensor and a deflector at a unique height. The pendulums are passed through the biomass and readings from the angular deflection sensors are fed into a control system. The control system determines whether adjustment of machine settings is appropriate and either displays an output to the operator, or adjusts automatically adjusts the machine settings, such as the speed, at which the pendulums are passed through the biomass. In an alternate embodiment, an entanglement sensor is also passed through the biomass to determine the amount of biomass entanglement. This measure of entanglement is also fed into the control system.

  4. NREL: Biomass Research - Webmaster

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    to reply. Your name: Your email address: Your message: Send Message Printable Version Biomass Research Home Capabilities Projects Facilities Research Staff Working with Us Data &...

  5. Biomass Processing Photolibrary

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Research related to bioenergy is a major focus in the U.S. as science agencies, universities, and commercial labs seek to create new energy-efficient fuels. The Biomass Processing Project is one of the funded projects of the joint USDA-DOE Biomass Research and Development Initiative. The Biomass Processing Photolibrary has numerous images, but there are no accompanying abstracts to explain what you are seeing. The project website, however, makes available the full text of presentations and publications and also includes an exhaustive biomass glossary that is being developed into an ASAE Standard.

  6. Biomass: Wood as Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Coordinator USDA Forest Service State & Private Forestry ... habitat and forest health Modern Woody Biomass ... Requires manual fuel delivery & stoking Pellets Meter ...

  7. Process for treating biomass

    DOE Patents [OSTI]

    Campbell, Timothy J.; Teymouri, Farzaneh

    2015-08-11

    This invention is directed to a process for treating biomass. The biomass is treated with a biomass swelling agent within the vessel to swell or rupture at least a portion of the biomass. A portion of the swelling agent is removed from a first end of the vessel following the treatment. Then steam is introduced into a second end of the vessel different from the first end to further remove swelling agent from the vessel in such a manner that the swelling agent exits the vessel at a relatively low water content.

  8. Process for treating biomass

    DOE Patents [OSTI]

    Campbell, Timothy J; Teymouri, Farzaneh

    2015-11-04

    This invention is directed to a process for treating biomass. The biomass is treated with a biomass swelling agent within the vessel to swell or rupture at least a portion of the biomass. A portion of the swelling agent is removed from a first end of the vessel following the treatment. Then steam is introduced into a second end of the vessel different from the first end to further remove swelling agent from the vessel in such a manner that the swelling agent exits the vessel at a relatively low water content.

  9. Biomass | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    technologies that are used for biomass thermal and combined heat and power (CHP) plants are direct combustion and gasification systems. Direct combustion systems are the...

  10. Biomass Indirect Liquefaction Workshop

    Energy.gov [DOE]

    To support research and development (R&D) planning efforts within the Thermochemical Conversion Program, the Bioenergy Technologies Office hosted the Biomass Indirect Liquefaction (IDL)...

  11. Overview of biomass technologies

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The biomass overview of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  12. Co-firing biomass

    SciTech Connect (OSTI)

    Hunt, T.; Tennant, D.

    2009-11-15

    Concern about global warming has altered the landscape for fossil-fuel combustion. The advantages and challenges of co-firing biomass and coal are discussed. 2 photos.

  13. Biomass Feasibility Analysis Report

    SciTech Connect (OSTI)

    Lipscomb, Brian

    2015-03-30

    Feasibility study to determine technical and economic viability of a co-generation biomass fuel power plant for the Confederated Salish and Kootenai Tribes.

  14. Major Biomass Conference

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Top Scientists, Industry and Government Leaders to Gather for Major Biomass Conference International gathering to focus on business successes, technology updates, facility tours ...

  15. Biomass: Biogas Generator

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    BIOGAS GENERATOR Curriculum: Biomass Power (organic chemistry, chemicalcarbon cycles, plants, energy resourcestransformations) Grade Level: Middle School (6-8) Small groups (3 to ...

  16. Gasification-based biomass

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The gasification-based biomass section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  17. Biomass Energy Basics | NREL

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass Energy Basics We have used biomass energy, or "bioenergy"-the energy from plants and plant-derived materials-since people began burning wood to cook food and keep warm. Wood is still the largest biomass energy resource today, but other sources of biomass can also be used. These include food crops, grassy and woody plants, residues from agriculture or forestry, oil-rich algae, and the organic component of municipal and industrial wastes. Even the fumes from landfills (which are

  18. Direct-fired biomass

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The direct-fired biomass section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  19. Wheelabrator Westchester Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Westchester Biomass Facility Jump to: navigation, search Name Wheelabrator Westchester Biomass Facility Facility Wheelabrator Westchester Sector Biomass Facility Type Municipal...

  20. Kevin L Kenney*

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    SB, Valkenburg C, Walton CW et al. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case. Pacific Northwest National...

  1. Pyrolysis reactor and fluidized bed combustion chamber

    DOE Patents [OSTI]

    Green, Norman W.

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  2. Better Biomass Conversion with Recyclable GVL Solvent - Energy Innovation

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Portal Better Biomass Conversion with Recyclable GVL Solvent Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary To recover useful carbohydrates locked in biomass, molecular bonds must be broken while avoiding further reaction of the resulting glucose and xylose sugars. This is a challenge because glucose can degrade quicker than it is produced. Fast, hot reactions try to minimize such degradation, but are impractical. Expensive catalysts

  3. Florida Biomass Energy LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    LLC Jump to: navigation, search Name: Florida Biomass Energy, LLC Place: Florida Sector: Biomass Product: Florida-based biomass project developer. References: Florida Biomass...

  4. Atlantic Biomass Conversions Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Conversions Inc Jump to: navigation, search Name: Atlantic Biomass Conversions Inc Place: Frederick, Maryland Sector: Biomass Product: Atlantic Biomass Conversions is...

  5. Biomass Power Association (BPA) | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Summary LAUNCH TOOL Name: Biomass Power Association (BPA) AgencyCompany Organization: Biomass Power Association Sector: Energy Focus Area: Biomass, - Biomass Combustion, -...

  6. Colusa Biomass Energy Corporation | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Energy Corporation Jump to: navigation, search Name: Colusa Biomass Energy Corporation Place: Colusa, California Zip: 95932 Sector: Biomass Product: Colusa Biomass Energy...

  7. Biomass Research Program

    ScienceCinema (OSTI)

    Kenney, Kevin; Wright, Christopher; Shelton-Davis, Colleen

    2013-05-28

    INL's mission is to achieve DOE's vision of supplying high-quality raw biomass; preprocessing biomass into advanced bioenergy feedstocks; and delivering bioenergy commodities to biorefineries. You can learn more about research like this at the lab's facebook site http://www.facebook.com/idahonationallaboratory.

  8. NREL: Biomass Research - Projects in Biomass Process and Sustainabilit...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Projects in Biomass Process and Sustainability Analyses Researchers at NREL use biomass process and sustainability analyses to understand the economic, technical, and global ...

  9. NREL: Biomass Research - Capabilities in Biomass Process and...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Capabilities in Biomass Process and Sustainability Analyses A photo of a woman and four ... A team of NREL researchers uses biomass process and sustainability analyses to bridge the ...

  10. Energy from biomass and wastes V. Proceedings of the fifth symposium, Lake Buena Vista, FL, January 26-30, 1981

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    Papers are presented in the areas of biomass production and procurement, biomass and waste combustion, gasification processes, liquefaction processes, environmental effects and government programs. Specific topics include a water hyacinth wastewater treatment system with biomass production, the procurement of wood as an industrial fuel, the cofiring of densified refuse-derived fuel and coal, the net energy production in anaerobic digestion, photosynthetic hydrogen production, the steam gasification of manure in a fluidized bed, and biomass hydroconversion to synthetic fuels. Attention is also given to the economics of deriving alcohol for power applications from grain, ethanol fermentation in a yeast-immobilized column fermenter, a solar-fired biomass flash pyrolysis reactor, particulate emissions from controlled-air modular incinerators, and the DOE program for energy recovery from urban wastes.

  11. Biomass Torrefaction Process Review and Moving Bed Torrefaction System Model Development

    SciTech Connect (OSTI)

    Jaya Shakar Tumuluru; Shahab Sokhansanj; Christopher T. Wright

    2010-08-01

    Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300°C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200–230ºC and 270–280ºC. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, producing a final product that will have a lower mass but a higher heating value. An important aspect of research is to establish a degree of torrefaction where gains in heating value offset the loss of mass. There is a lack of literature on torrefaction reactor designs and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed for different capacities, designing the heat loads and gas flow rates, and developing an interactive excel sheet where the user can define design specifications. In this report, 25–1000 kg/hr are used in equations for the design of the torrefier, examples of calculations, and specifications for the torrefier.

  12. Biomass Torrefaction Process Review and Moving Bed Torrefaction System Model Development

    SciTech Connect (OSTI)

    Jaya Shakar Tumuluru; Shahab Sokhansanj; Christopher T. Wright; Richard D. Boardman

    2010-08-01

    Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-230 C and 270-280 C. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, producing a final product that will have a lower mass but a higher heating value. An important aspect of research is to establish a degree of torrefaction where gains in heating value offset the loss of mass. There is a lack of literature on torrefaction reactor designs and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes (a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and (b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed for different capacities, designing the heat loads and gas flow rates, and developing an interactive excel sheet where the user can define design specifications. In this report, 25-1000 kg/hr are used in equations for the design of the torrefier, examples of calculations, and specifications for the torrefier.

  13. NREL: Biomass Research - Research Staff

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Thomas.Foust@nrel.gov Bratis, Adam Management, Biomass Laboratory Program Manager Adam.Bratis@nrel.gov Chum, Helena Management, Biomass Fellow Helena.Chum@nrel.gov Pienkos,...

  14. NREL: Biomass Research Home Page

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Photo of a technician completing a laboratory procedure Biomass Compositional Analysis Find laboratory analytical procedures for standard biomass analysis. Photo of the Integrated...

  15. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Investigating and Using Biomass Gases Grades: 9-12 Topic: Biomass Authors: Eric Benson and Melissa Highfill Owner: National Renewable Energy Laboratory This educational material is...

  16. Fast valve

    DOE Patents [OSTI]

    Van Dyke, William J.

    1992-01-01

    A fast valve is disclosed that can close on the order of 7 milliseconds. It is closed by the force of a compressed air spring with the moving parts of the valve designed to be of very light weight and the valve gate being of wedge shaped with O-ring sealed faces to provide sealing contact without metal to metal contact. The combination of the O-ring seal and an air cushion create a soft final movement of the valve closure to prevent the fast air acting valve from having a harsh closing.

  17. Fast valve

    DOE Patents [OSTI]

    Van Dyke, W.J.

    1992-04-07

    A fast valve is disclosed that can close on the order of 7 milliseconds. It is closed by the force of a compressed air spring with the moving parts of the valve designed to be of very light weight and the valve gate being of wedge shaped with O-ring sealed faces to provide sealing contact without metal to metal contact. The combination of the O-ring seal and an air cushion create a soft final movement of the valve closure to prevent the fast air acting valve from having a harsh closing. 4 figs.

  18. Pyrolysis reaction networks for lignin model compounds: unraveling thermal deconstruction of β-O-4 and α-O-4 compounds

    SciTech Connect (OSTI)

    Choi, Yong S.; Singh, Rahul; Zhang, Jing; Balasubramanian, Ganesh; Sturgeon, Matthew R.; Katahira, Rui; Chupka, Gina; Beckham, Gregg T.; Shanks, Brent H.

    2016-01-01

    Although lignin is one of the main components of biomass, its pyrolysis chemistry is not well understood due to complex heterogeneity. To gain insights into this chemistry, the pyrolysis of seven lignin model compounds (five ..beta..-O-4 and two ..alpha..-O-4 linked molecules) was investigated in a micropyrolyzer connected to GC-MS/FID. According to quantitative product mole balance for the reaction networks, concerted retro-ene fragmentation and homolytic dissociation were strongly suggested as the initial reaction step for ..beta..-O-4 compounds and ..alpha..-O-4 compounds, respectively. The difference in reaction pathway between compounds with different linkages was believed to result from thermodynamics of the radical initiation. The rate constants for the different reaction pathways were predicted from ab initio density functional theory calculations and pre-exponential literature values. The computational findings were consistent with the experiment results, further supporting the different pyrolysis mechanisms for the ..beta..-ether linked and ..alpha..-ether linked compounds. A combination of the two pathways from the dimeric model compounds was able to describe qualitatively the pyrolysis of a trimeric lignin model compound containing both ..beta..-O-4 and ..alpha..-O-4 linkages.

  19. Vacuum pyrolysis of waste tires with basic additives

    SciTech Connect (OSTI)

    Zhang Xinghua; Wang Tiejun Ma Longlong; Chang Jie

    2008-11-15

    Granules of waste tires were pyrolyzed under vacuum (3.5-10 kPa) conditions, and the effects of temperature and basic additives (Na{sub 2}CO{sub 3}, NaOH) on the properties of pyrolysis were thoroughly investigated. It was obvious that with or without basic additives, pyrolysis oil yield increased gradually to a maximum and subsequently decreased with a temperature increase from 450 deg. C to 600 deg. C, irrespective of the addition of basic additives to the reactor. The addition of NaOH facilitated pyrolysis dramatically, as a maximal pyrolysis oil yield of about 48 wt% was achieved at 550 deg. C without the addition of basic additives, while a maximal pyrolysis oil yield of about 50 wt% was achieved at 480 deg. C by adding 3 wt% (w/w, powder/waste tire granules) of NaOH powder. The composition analysis of pyrolytic naphtha (i.b.p. (initial boiling point) {approx}205 deg. C) distilled from pyrolysis oil showed that more dl-limonene was obtained with basic additives and the maximal content of dl-limonene in pyrolysis oil was 12.39 wt%, which is a valuable and widely-used fine chemical. However, no improvement in pyrolysis was observed with Na{sub 2}CO{sub 3} addition. Pyrolysis gas was mainly composed of H{sub 2}, CO, CH{sub 4}, CO{sub 2}, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}. Pyrolytic char had a surface area comparable to commercial carbon black, but its proportion of ash (above 11.5 wt%) was much higher.

  20. Catalytic pyrolysis of plastic wastes - Towards an economically viable process

    SciTech Connect (OSTI)

    McIntosh, M.J.; Arzoumanidis, G.G.; Brockmeier, F.E.

    1996-07-01

    The ultimate goal of our project is an economically viable pyrolysis process to recover useful fuels and/or chemicals from plastics- containing wastes. This paper reports the effects of various promoted and unpromoted binary oxide catalysts on yields and compositions of liquid organic products, as measured in a small laboratory pyrolysis reactor. On the basis of these results, a commercial scale catalytic pyrolysis reactor was simulated by the Aspen software and rough costs were estimated. The results suggest that such a process has potential economic viability.

  1. Pyrolysis of carbonaceous materials with solvent quench recovery

    DOE Patents [OSTI]

    Green, Norman W.; Duraiswamy, Kandaswamy; Lumpkin, Robert E.; Knell, Everett W.; Mirza, Zia I.; Winter, Bruce L.

    1978-04-18

    In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue. Apparatus useful for practicing this process are disclosed.

  2. Method for preventing plugging in the pyrolysis of agglomerative coals

    DOE Patents [OSTI]

    Green, Norman W.

    1979-01-23

    To prevent plugging in a pyrolysis operation where an agglomerative coal in a nondeleteriously reactive carrier gas is injected as a turbulent jet from an opening into an elongate pyrolysis reactor, the coal is comminuted to a size where the particles under operating conditions will detackify prior to contact with internal reactor surfaces while a secondary flow of fluid is introduced along the peripheral inner surface of the reactor to prevent backflow of the coal particles. The pyrolysis operation is depicted by two equations which enable preselection of conditions which insure prevention of reactor plugging.

  3. Computational Analysis of the Pyrolysis of ..beta..-O4 Lignin Model Compounds: Concerted vs. Homolytic Fragmentation

    SciTech Connect (OSTI)

    Clark, J. M.; Robichaud, D. J.; Nimlos, M. R.

    2012-01-01

    The thermochemical conversion of biomass to liquid transportation fuels is a very attractive technology for expanding the utilization of carbon neutral processes and reducing dependency on fossil fuel resources. As with all such emerging technologies, biomass conversion through gasification or pyrolysis has a number of obstacles that need to be overcome to make these processes cost competitive with the refining of fossil fuels. Our current efforts have focused on the investigation of the thermochemistry of the linkages between lignin units using ab initio calculations on dimeric lignin model compounds. All calculations were carried out using M062X density functional theory at the 6-311++G(d,p) basis set. The M062X method has been shown to be consistent with the CBS-QB3 method while being significantly less computationally expensive. To date we have only completed the study on the b-O4 compounds. The theoretical calculations performed in the study indicate that concerted elimination pathways dominate over bond homolysis reactions under typical pyrolysis conditions. However, this does not mean that concerted elimination will be the dominant loss process for lignin. Bimolecular radical chemistry could very well dwarf the unimolecular pathways investigated in this study. These concerted pathways tend to form stable, reasonably non-reactive products that would be more suited producing a fungible bio-oil for the production of liquid transportation fuels.

  4. Biomass Basics Webinar

    Energy.gov [DOE]

    The Bioenergy Technologies Office (BETO) is hosting a Biomass Basics Webinar on August 27, 2015, from 4:00-4:40pm EDT. This webinar will provide high school students and teachers with background...

  5. NREL: Biomass Research - News

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    News Below are news stories related to NREL biomass research. Subscribe to the RSS feed RSS . Learn about RSS. June 3, 2015 NREL Cyanobacteria Ramps Up Photosynthesis-and New...

  6. The ultimate biomass refinery

    SciTech Connect (OSTI)

    Bungay, H.R. )

    1988-01-01

    Bits and pieces of refining schemes and both old and new technology have been integrated into a complete biomass harvesting, processing, waste recycle, and marketing complex. These choices are justified with economic estimates and technology assessments.

  7. Biomass Energy Production Incentive

    Office of Energy Efficiency and Renewable Energy (EERE)

    In 2007 South Carolina enacted the Energy Freedom and Rural Development Act, which provides production incentives for certain biomass-energy facilities. Eligible systems earn $0.01 per kilowatt-h...

  8. Biomass 2014 Poster Session

    Energy.gov [DOE]

    The U.S. Department of Energy’s Bioenergy Technologies Office (BETO) invites students, researchers, public and private organizations, and members of the general public to submit poster abstracts for consideration for the annual Biomass Conference Poster Session. The Biomass 2014 conference theme focuses on topics that are advancing the growth of the bioeconomy, such as improvements in feedstock logistics; promising, innovative pathways for advanced biofuels; and market-enabling co-products.

  9. Biomass Basics Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    August 27, 2015 Biomass Basics Alexis Martin Fellow, Bioenergy Technologies Office Department of Energy 2 | Bioenergy Technologies Office Agenda * Overview of Bioenergy * Biomass to Biofuels Life Cycle * Importance of Bioenergy * 2016 BioenergizeME Infographic Challenge 3 | Bioenergy Technologies Office Questions and Comments Please record any questions and comments you may have during the webinar and send them to BioenergizeME@ee.doe.gov As a follow-up to the webinar, the presenter(s) will

  10. Flash hydrogenation of biomass

    SciTech Connect (OSTI)

    Steinberg, M

    1980-01-01

    It is proposed to obtain process chemistry information on the rapid hydrogenation of biomass (wood and other agricultural products) to produce light liquid and gaseous hydrocarbon fuels and feedstocks. The process is referred to as Flash Hydropyrolysis. The information will be of use in the design and evaluation of processes for the conversion of biomass to synthetic fuels and petrochemical feedstocks. Results obtained in an initial experiment are discussed.

  11. 2007 Biomass Program Overview

    SciTech Connect (OSTI)

    none,

    2009-10-27

    The Biomass Program is actively working with public and private partners to meet production and technology needs. With the corn ethanol market growing steadily, researchers are unlocking the potential of non-food biomass sources, such as switchgrass and forest and agricultural residues. In this way, the Program is helping to ensure that cost-effective technologies will be ready to support production goals for advanced biofuels.

  12. Algae Biomass Summit

    Energy.gov [DOE]

    The 9th annual Algae Biomass Summit will be hosted at the Washington Marriot Wardman Park in Washington D.C., September 29 – October 2, 2015. The event will gather leaders in algae biomass from all sectors. U.S. Department of Energy Undersecretary Franklin Orr will give a keynote address at the conference, and Bioenergy Technologies Office (BETO) Director Jonathan, Algae Program Manager Alison Goss Eng, and the BETO Algae Team will be in attendance.

  13. A Pyrolysis and Primary Migration Model

    Energy Science and Technology Software Center (OSTI)

    1993-08-11

    PMOD-Version 1.6 is a copyrighted computer program for simulating oil generation, cracking, and other chemical reactions occurring during the pyrolysis of petroleum source rocks over a specified history of temperature and either depth or hydrostatic pressure. The chemical reaction mechanism is defined by the user and, within limits, can be as simple or complex as desired. The model also simulates compaction of the source rock and expulsion of a liquid water phase and a liquidmore » hydrocarbon phase. The expulsion is done by either a simple, constant-fluid-density model or by a more rigorous model using a modified Redlich-Kwong-Soave equation of state. The latter model also calculates overpressuring. An auxiliary program, PLOTPMOD, permits graphical display and hardcopy of the results, as well as preparation of ASCII-file subsets of the results for use with a spreadsheet or other graphics program.« less

  14. Inhibition of coke formation in pyrolysis furnaces

    SciTech Connect (OSTI)

    Tong, Y.; Poindexter, M.K.; Rowe, C.T.

    1995-12-31

    Coke formation in pyrolysis furnaces, which thermally convert hydrocarbons to ethylene as well as other useful products, adversely affects product yields, causes furnace down time for coke removal, and shortens furnace coil life. A phosphorus-based chemical treatment program was developed to inhibit the coke formation. The anticoking performance of the phosphorus-based treatment program was studied using a bench scale coking rate measurement apparatus. The programs`s influence on coke morphology and reactor surface was addressed using SEM/EDX surface characterization techniques. For comparison, similar studies were carried out with sulfur-containing species which are conventionally used in industrial practice as furnace additives. The present work demonstrated that the phosphorus-based treatment program provided an efficient and durable surface passivation against coke formation.

  15. Feedstock effects in coal flash pyrolysis

    SciTech Connect (OSTI)

    Tatterson, D.F.; Robinson, K.K.; Guercio, R.; Marker, T.L.

    1990-10-01

    In this paper the impact of lower rank coals on yields and product qualities is examined in a large- scale flash pyrolysis reactor capable of achieving heating rates of 10{sup 6}{degrees}C/s and reactor times of 10 ms. A Montana lignite and a Minnesota peat were pyrolyzed and the results compared to those for Illinois No. 6 bituminous coal. The peat was found to be more reactive than the Illinois No. 6 coal and the lignite less reactive. Relatively high liquid yields were also obtained from the peat. This result demonstrates that high oxygen content in a feedstock does not necessarily correlate with low production of liquids. At high reactor severity, the peat is an excellent source of aromatics (benzene, toulene, and xylenes) and medium Btu gas, which could be converted to other chemical feedstocks.

  16. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y.; Cha, Chang Y.; Merriam, Norman W.

    1992-01-01

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  17. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  18. Biomass 2011 Conference Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1 Conference Agenda Biomass 2011 Conference Agenda Biomass 2011 Conference Agenda bio2011_full_agenda.pdf (620.42 KB) More Documents & Publications Biomass 2009 Conference Agenda Biomass 2010 Conference Agenda Biomass 2012

  19. Northeast Regional Biomass Program

    SciTech Connect (OSTI)

    Lusk, P.D.

    1992-12-01

    The Northeast Regional Biomass Program has been in operation for a period of nine years. During this time, state managed programs and technical programs have been conducted covering a wide range of activities primarily aim at the use and applications of wood as a fuel. These activities include: assessments of available biomass resources; surveys to determine what industries, businesses, institutions, and utility companies use wood and wood waste for fuel; and workshops, seminars, and demonstrations to provide technical assistance. In the Northeast, an estimated 6.2 million tons of wood are used in the commercial and industrial sector, where 12.5 million cords are used for residential heating annually. Of this useage, 1504.7 mw of power has been generated from biomass. The use of wood energy products has had substantial employment and income benefits in the region. Although wood and woodwaste have received primary emphasis in the regional program, the use of municipal solid waste has received increased emphasis as an energy source. The energy contribution of biomass will increase as potentia users become more familiar with existing feedstocks, technologies, and applications. The Northeast Regional Biomass Program is designed to support region-specific to overcome near-term barriers to biomass energy use.

  20. Biological Pyrolysis Oil Upgrading Presentation for BETO 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Pyrolysis Oil Upgrading WBS 2.3.2.301 2015 DOE BioEnergy Technologies Office (BETO) ... * Tt-J Catalytic Upgrading of Bio-Oil Intermediates to Fuels and Chemicals ...

  1. Technical Information Exchange on Pyrolysis Oil: Potential for...

    Energy Savers

    Renewab;e Heating Oil Substation Fuel in New England Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England This ...

  2. Biomass cogeneration. A business assessment

    SciTech Connect (OSTI)

    Skelton, J.C.

    1981-11-01

    This guide serves as an overview of the biomass cogeneration area and provides direction for more detailed analysis. The business assessment is based in part on discussions with key officials from firms that have adopted biomass cogeneration systems and from organizations such as utilities, state and federal agencies, and banks that would be directly involved in a biomass cogeneration project. The guide is organized into five chapters: biomass cogeneration systems, biomass cogeneration business considerations, biomass cogeneration economics, biomass cogeneration project planning, and case studies.

  3. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    SciTech Connect (OSTI)

    Roberts, Michael; Marker, Terry; Ortiz-Toral, Pedro; Linck, Martin; Felix, Larry; Wangerow, Jim; Swanson, Dan; McLeod, Celeste; Del Paggio, Alan; Urade, Vikrant; Rao, Madhusudhan; Narasimhan, Laxmi; Gephart, John; Starr, Jack; Hahn, John; Stover, Daniel; Parrish, Martin; Maxey, Carl; Shonnard, David; Handler, Robert; Fan, Jiquig

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  4. Indirectly heated fluidized bed biomass gasification using a latent heat ballast

    SciTech Connect (OSTI)

    Pletka, R.; Brown, R.; Smeenk, J.

    1998-12-31

    The objective of this study is to improve the heating value of gas produced during gasification of biomass fuels using an indirectly heated gasifier based on latent heat ballasting. The latent heat ballast consists of lithium fluoride salt encased in tubes suspended in the reactor. The lithium fluoride has a melting point that is near the desired gasification temperature. With the ballast a single reactor operating in a cyclic mode stores energy during a combustion phase and releases it during a pyrolysis phase. Tests were carried out in a fluidized bed reactor to evaluate the concept. The time to cool the reactor during the pyrolysis phase from 1,172 K (1,650 F) to 922 K (1,200 F) increased 102% by use of the ballast system. This extended pyrolysis time allowed 33% more biomass to be gasified during a cycle. Additionally, the total fuel fraction pyrolyzed to produce useful gas increased from 74--80%. Higher heating values of 14.2 to 16.6 MJ/Nm{sup 3} (382--445 Btu/scf) on a dry basis were obtained from the ballasted gasifier.

  5. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  6. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  7. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    SciTech Connect (OSTI)

    Solak, Agnieszka; Rutkowski, Piotr

    2014-02-15

    Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  8. Validation Results for Core-Scale Oil Shale Pyrolysis

    SciTech Connect (OSTI)

    Staten, Josh; Tiwari, Pankaj

    2015-03-01

    This report summarizes a study of oil shale pyrolysis at various scales and the subsequent development a model for in situ production of oil from oil shale. Oil shale from the Mahogany zone of the Green River formation was used in all experiments. Pyrolysis experiments were conducted at four scales, powdered samples (100 mesh) and core samples of 0.75”, 1” and 2.5” diameters. The batch, semibatch and continuous flow pyrolysis experiments were designed to study the effect of temperature (300°C to 500°C), heating rate (1°C/min to 10°C/min), pressure (ambient and 500 psig) and size of the sample on product formation. Comprehensive analyses were performed on reactants and products - liquid, gas and spent shale. These experimental studies were designed to understand the relevant coupled phenomena (reaction kinetics, heat transfer, mass transfer, thermodynamics) at multiple scales. A model for oil shale pyrolysis was developed in the COMSOL multiphysics platform. A general kinetic model was integrated with important physical and chemical phenomena that occur during pyrolysis. The secondary reactions of coking and cracking in the product phase were addressed. The multiscale experimental data generated and the models developed provide an understanding of the simultaneous effects of chemical kinetics, and heat and mass transfer on oil quality and yield. The comprehensive data collected in this study will help advance the move to large-scale in situ oil production from the pyrolysis of oil shale.

  9. Effects of torrefaction and densification on switchgrass pyrolysis products

    DOE PAGES-Beta [OSTI]

    Yang, Zixu; Sarkar, Madhura; Kumar, Ajay; Tumuluru, Jaya Shankar; Huhnke, Raymond L.

    2014-12-01

    Abstract The pyrolysis behaviors of four types of pretreated switchgrass (torrefied at 230 and 270 °C, densification, and torrefaction at 270 ºC followed by densification) were studied at three temperatures (500, 600, 700 ºC) using a pyroprobe attached to a gas chromatogram mass spectroscopy (Py-GC/MS). The torrefaction of switchgrass improved its oxygen to carbon ratio and energy content. Contents of anhydrous sugars and phenols in pyrolysis products of torrefied switchgrass were higher than those in pyrolysis products of raw switchgrass. As the torrefaction temperature increased from 230 to 270 °C, the contents of anhydrous sugars and phenols in pyrolysis productsmore » increased whereas content of guaiacols decreased. High pyrolysis temperature (600 and 700 °C as compared to 500 °C) enhanced decomposition of lignin and anhydrous sugars, leading to increase in phenols, aromatics and furans. Densification enhanced depolymerization of cellulose and hemicellulose during pyrolysis.« less

  10. Cheap carbon sorbents produced from lignite by catalytic pyrolysis

    SciTech Connect (OSTI)

    Kuznetsov, B.N.; Schchipko, M.L.

    1995-12-01

    Some data are presented describing the new technology of carbon sorbent production from powdered lignite in the installation with fluidized bed of catalyst. It was shown the different types of char products with extended pore structure and high sorption ability can be produced from cheap and accessible lignite of Kansk-Achinsk coal pit in pilot installation with fluidized bed of Al-Cu-Cr oxide catalyst or catalytically active slag materials. In comparison with the conventional technologies of pyrolysis the catalytic pyrolysis allows to increase by 3-5 times the process productivity and to decrease significantly the formation of harmful compounds. The latter is accomplished by complete oxidation of gaseous pyrolysis products in the presence of catalysts and by avoiding the formation of pyrolysis tars - the source of cancerogenic compounds. The technology of cheap powdered sorbent production from lignites makes possible to obtain from lignite during the time of pyrolysis only a few seconds char products with porosity up to 0.6 cm{sup 3} /g, and specific surface area more than 400 m{sup 3} /g. Some methods of powdered chars molding into carbon materials with the different shape were proved for producing of firmness sorbents. Cheap carbon sorbents obtained by thermocatalytic pyrolysis can be successfully used in purification of different industrial pollutants as one-time sorbent or as adsorbents of long-term application with periodic regeneration.

  11. Review on Biomass Torrefaction Process and Product Properties and Design of Moving Bed Torrefaction System Model Development

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Christopher T. Wright; Shahab Sokhansanj

    2011-08-01

    A Review on Torrefaction Process and Design of Moving Bed Torrefaction System for Biomass Processing Jaya Shankar Tumuluru1, Shahab Sokhansanj2 and Christopher T. Wright1 Idaho National Laboratory Biofuels and Renewable Energy Technologies Department Idaho Falls, Idaho 83415 Oak Ridge National Laboratory Bioenergy Resource and Engineering Systems Group Oak Ridge, TN 37831 Abstract Torrefaction is currently developing as an important preprocessing step to improve the quality of biomass in terms of physical properties, and proximate and ultimate composition. Torrefaction is a slow heating of biomass in an inert or reduced environment to a maximum temperature of 300 C. Torrefaction can also be defined as a group of products resulting from the partially controlled and isothermal pyrolysis of biomass occurring in a temperature range of 200-230 C and 270-280 C. Thus, the process can also be called a mild pyrolysis as it occurs at the lower temperature range of the pyrolysis process. At the end of the torrefaction process, a solid uniform product with lower moisture content and higher energy content than raw biomass is produced. Most of the smoke-producing compounds and other volatiles are removed during torrefaction, which produces a final product that will have a lower mass but a higher heating value. There is a lack of literature on the design aspects of torrefaction reactor and a design sheet for estimating the dimensions of the torrefier based on capacity. This study includes (a) conducting a detailed review on the torrefaction of biomass in terms of understanding the process, product properties, off-gas compositions, and methods used, and (b) to design a moving bed torrefier, taking into account the basic fundamental heat and mass transfer calculations. Specific objectives include calculating the dimensions like diameter and height of the moving packed bed torrefier for different capacities ranging from 25-1000 kg/hr, designing the heat loads and gas flow rates, and

  12. Biomass Crop Assistance Program (BCAP) | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    United States Department of Agriculture Partner: Farm Service Agency Sector: Energy, Land Focus Area: Biomass, - Biomass Combustion, - Biomass Gasification, - Biomass...

  13. Optimization of the pyrolysis process of empty fruit bunch (EFB) in a fixed-bed reactor through a central composite design (CCD)

    SciTech Connect (OSTI)

    Mohamed, Alina Rahayu; Hamzah, Zainab; Daud, Mohamed Zulkali Mohamed

    2014-07-10

    The production of crude palm oil from the processing of palm fresh fruit bunches in the palm oil mills in Malaysia hs resulted in a huge quantity of empty fruit bunch (EFB) accumulated. The EFB was used as a feedstock in the pyrolysis process using a fixed-bed reactor in the present study. The optimization of process parameters such as pyrolysis temperature (factor A), biomass particle size (factor B) and holding time (factor C) were investigated through Central Composite Design (CCD) using Stat-Ease Design Expert software version 7 with bio-oil yield considered as the response. Twenty experimental runs were conducted. The results were completely analyzed by Analysis of Variance (ANOVA). The model was statistically significant. All factors studied were significant with p-values < 0.05. The pyrolysis temperature (factor A) was considered as the most significant parameter because its F-value of 116.29 was the highest. The value of R{sup 2} was 0.9564 which indicated that the selected factors and its levels showed high correlation to the production of bio-oil from EFB pyrolysis process. A quadratic model equation was developed and employed to predict the highest theoretical bio-oil yield. The maximum bio-oil yield of 46.2 % was achieved at pyrolysis temperature of 442.15 °C using the EFB particle size of 866 μm which corresponded to the EFB particle size in the range of 710–1000 μm and holding time of 483 seconds.

  14. Two-stage dilute acid prehydrolysis of biomass

    DOE Patents [OSTI]

    Grohmann, Karel; Torget, Robert W.

    1992-01-01

    A two-stage dilute acid prehydrolysis process on xylan containing hemicellulose in biomass is effected by: treating feedstock of hemicellulosic material comprising xylan that is slow hydrolyzable and xylan that is fast hydrolyzable under predetermined low temperature conditions with a dilute acid for a residence time sufficient to hydrolyze the fast hydrolyzable xylan to xylose; removing said xylose from said fast hydrolyzable xylan and leaving a residue; and treating said residue having a slow hydrolyzable xylan with a dilute acid under predetermined high temperature conditions for a residence time required to hydrolyze said slow hydrolyzable xylan to xylose.

  15. Research into the pyrolysis of pure cellulose, lignin, and birch wood flour in the China Lake entrained-flow reactor

    SciTech Connect (OSTI)

    Diebold, J.

    1980-06-01

    This experimental program used the China Lake entrained-flow pyrolysis reactor to briefly investigate the pyrolysis of pure cellulose, pure lignin, and birch wood flour. The study determined that the cellulose and wood flour do pyrolyze to produce primarily gaseous products containing significant amounts of ethylene and other useful hydrocarbons. During attempts to pyrolyze powdered lignin, the material melted and bubbled to block the reactor entrance. The pure cellulose and wood flour produced C/sub 2/ + yields of 12% to 14% by weight, which were less than yields from an organic feedstock derived from processed municipal trash. The char yields were 0.1% by weight from cellulose and 1.5% from birch wood flour - one to two orders of magnitude less than were produced from the trash-derived feedstock. In scanning electron microscope photographs, most of the wood flour char had a sintered and agglomerated appearance, although some particles retained the gross cell characteristics of the wood flour. The appearance of the char particles indicated that the material had once been molten and possibly vapor before it formed spheroidal particles about 1 ..mu..m diameter which agglomerated to form larger char particles. The ability to completely melt or vaporize lignocellulosic materials under conditions of high heating rates has now been demonstrated in a continuous flow reactor and promises new techniques for fast pyrolysis. This char was unexpectedly attracted by a magnet, presumably because of iron contamination from the pyrolysis reactor tube wall. The production of water-insoluble tars was negligible compared to the tars produced from trash-derived feedstock. The production of water-soluble organic materials was fairly low and qualitatively appeared to vary inversely with temperature. This study was of a preliminary nature and additional studies are necessary to optimize ethylene production from these feedstocks.

  16. Sustainable Biomass Supply Systems

    SciTech Connect (OSTI)

    Erin Searcy; Dave Muth; Erin Wilkerson; Shahab Sokansanj; Bryan Jenkins; Peter Titman; Nathan Parker; Quinn Hart; Richard Nelson

    2009-04-01

    The U.S. Department of Energy (DOE) aims to displace 30% of the 2004 gasoline use (60 billion gal/yr) with biofuels by 2030 as outlined in the Energy Independence and Security Act of 2007, which will require 700 million tons of biomass to be sustainably delivered to biorefineries annually. Lignocellulosic biomass will make an important contribution towards meeting DOEs ethanol production goals. For the biofuels industry to be an economically viable enterprise, the feedstock supply system (i.e., moving the biomass from the field to the refinery) cannot contribute more that 30% of the total cost of the biofuel production. The Idaho National Laboratory in collaboration with Oak Ridge National Laboratory, University of California, Davis and Kansas State University are developing a set of tools for identifying economical, sustainable feedstocks on a regional basis based on biorefinery siting.

  17. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  18. Fixed Bed Biomass Gasifier

    SciTech Connect (OSTI)

    Carl Bielenberg

    2006-03-31

    The report details work performed by Gazogen to develop a novel biomass gasifier for producimg electricity from commercially available hardwood chips. The research conducted by Gazogen under this grant was intended to demonstrate the technical and economic feasibility of a new means of producing electricity from wood chips and other biomass and carbonaceous fuels. The technical feasibility of the technology has been furthered as a result of the DOE grant, and work is expected to continue. The economic feasibility can only be shown when all operational problems have been overocme. The technology could eventually provide a means of producing electricity on a decentralized basis from sustainably cultivated plants or plant by-products.

  19. Method for pretreating lignocellulosic biomass

    DOE Patents [OSTI]

    Kuzhiyil, Najeeb M.; Brown, Robert C.; Dalluge, Dustin Lee

    2015-08-18

    The present invention relates to a method for pretreating lignocellulosic biomass containing alkali and/or alkaline earth metal (AAEM). The method comprises providing a lignocellulosic biomass containing AAEM; determining the amount of the AAEM present in the lignocellulosic biomass; identifying, based on said determining, the amount of a mineral acid sufficient to completely convert the AAEM in the lignocellulosic biomass to thermally-stable, catalytically-inert salts; and treating the lignocellulosic biomass with the identified amount of the mineral acid, wherein the treated lignocellulosic biomass contains thermally-stable, catalytically inert AAEM salts.

  20. A REVIEW ON BIOMASS DENSIFICATION TECHNOLOGIE FOR ENERGY APPLICATION

    SciTech Connect (OSTI)

    JAYA SHANKAR TUMULURU; CHRISTOPHER T. WRIGHT

    2010-08-01

    The world is currently facing challenges to reduce the dependence on fossil fuels and to achieve a sustainable renewable supply. Renewable energies represent a diversity of energy sources that can help to maintain the equilibrium of different ecosystems. Among the various sources of renewable energy, biomass is finding more uses as it is considered carbon neutral since the carbondioxide released during its use is already part of the carbon cycle (Arias et al., 2008). Increasing the utilization of biomass for energy can help to reduce the negative CO2 impact on the environment and help to meet the targets established in the Kyoto Protocol (UN, 1998). Energy from biomass can be produced from different processes like thermochemical (combustion, gasification, and pyrolysis), biological (anaerobic digestion, fermentation) or chemical (esterification) where direct combustion can provide a direct near-term energy solution (Arias et al., 2008). Some of the inherent problems with raw biomass materials, like low bulk density, high moisture content, hydrophilic nature and low calorific value, limit the ease of use of biomass for energy purposes (Arias et al., 2008). In fact, due to its low energy density compared to fossil fuels, high volumes of biomass will be needed; adding to problems associated with storage, transportation and feed handling at a cogeneration plant. Furthermore, grinding biomass pulverizes, can be very costly and in some cases impractical. All of these drawbacks have given rise to the development of new technologies in order to increase the quality of biomass fuels. The purpose of the work is mainly in four areas 1) Overview of the torrefaction process and to do a literature review on i) Physical properties of torrefied raw material and torrefaction gas composition. 2) Basic principles in design of packed bed i) Equations governing the flow of material in packed bed ii) Equations governing the flow of the gases in packed bed iii) Effect of physical

  1. Biofuels - Biomass Feedstock - Energy Innovation Portal

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Biofuels - Biomass Feedstock Idaho National Laboratory Contact INL About This Technology Technology ...

  2. Randolph Electric Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Facility Jump to: navigation, search Name Randolph Electric Biomass Facility Facility Randolph Electric Sector Biomass Facility Type Landfill Gas Location Norfolk County,...

  3. Berlin Gorham Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Gorham Biomass Facility Jump to: navigation, search Name Berlin Gorham Biomass Facility Facility Berlin Gorham Sector Biomass Location Coos County, New Hampshire Coordinates...

  4. Westchester Landfill Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Landfill Biomass Facility Jump to: navigation, search Name Westchester Landfill Biomass Facility Facility Westchester Landfill Sector Biomass Facility Type Landfill Gas Location...

  5. Shasta 2 Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    2 Biomass Facility Jump to: navigation, search Name Shasta 2 Biomass Facility Facility Shasta 2 Sector Biomass Owner Wheelabrator Location Anderson, California Coordinates...

  6. Biodyne Pontiac Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Pontiac Biomass Facility Jump to: navigation, search Name Biodyne Pontiac Biomass Facility Facility Biodyne Pontiac Sector Biomass Facility Type Non-Fossil Waste Location...

  7. San Marcos Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Marcos Biomass Facility Jump to: navigation, search Name San Marcos Biomass Facility Facility San Marcos Sector Biomass Facility Type Landfill Gas Location San Diego County,...

  8. Hebei Jiantou Biomass Power | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jiantou Biomass Power Jump to: navigation, search Name: Hebei Jiantou Biomass Power Place: Jinzhou, Hebei Province, China Zip: 50000 Sector: Biomass Product: A company engages in...

  9. Okeelanta 2 Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    2 Biomass Facility Jump to: navigation, search Name Okeelanta 2 Biomass Facility Facility Okeelanta 2 Sector Biomass Owner Florida Crystals Location South Bay, Florida Coordinates...

  10. Florida Biomass Energy Consortium | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Consortium Jump to: navigation, search Name: Florida Biomass Energy Consortium Place: Florida Sector: Biomass Product: Association of biomass energy companies. References: Florida...

  11. Sunset Farms Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Farms Biomass Facility Jump to: navigation, search Name Sunset Farms Biomass Facility Facility Sunset Farms Sector Biomass Facility Type Landfill Gas Location Travis County, Texas...

  12. East Bridgewater Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Bridgewater Biomass Facility Jump to: navigation, search Name East Bridgewater Biomass Facility Facility East Bridgewater Sector Biomass Facility Type Landfill Gas Location...

  13. Biodyne Lyons Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Lyons Biomass Facility Jump to: navigation, search Name Biodyne Lyons Biomass Facility Facility Biodyne Lyons Sector Biomass Facility Type Landfill Gas Location Cook County,...

  14. Reliant Conroe Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Conroe Biomass Facility Jump to: navigation, search Name Reliant Conroe Biomass Facility Facility Reliant Conroe Sector Biomass Facility Type Landfill Gas Location Montgomery...

  15. Plummer Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Plummer Biomass Facility Jump to: navigation, search Name Plummer Biomass Facility Facility Plummer Sector Biomass Owner Wood Power Location Plummer, Idaho Coordinates...

  16. Otay Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Otay Biomass Facility Jump to: navigation, search Name Otay Biomass Facility Facility Otay Sector Biomass Facility Type Landfill Gas Location San Diego County, California...

  17. Florida Biomass Energy Group | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Group Jump to: navigation, search Name: Florida Biomass Energy Group Place: Gulf Breeze, Florida Zip: 32561 Sector: Biomass Product: Florida Biomass Energy Group is a Florida...

  18. SPI Sonora Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Sonora Biomass Facility Jump to: navigation, search Name SPI Sonora Biomass Facility Facility SPI Sonora Sector Biomass Owner Sierra Pacific Industries Location Sonora, California...

  19. Wheelabrator Saugus Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Saugus Biomass Facility Jump to: navigation, search Name Wheelabrator Saugus Biomass Facility Facility Wheelabrator Saugus Sector Biomass Facility Type Municipal Solid Waste...

  20. Biodyne Peoria Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Peoria Biomass Facility Jump to: navigation, search Name Biodyne Peoria Biomass Facility Facility Biodyne Peoria Sector Biomass Facility Type Landfill Gas Location Peoria County,...

  1. Zilkha Biomass Energy LLC | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zilkha Biomass Energy LLC Jump to: navigation, search Logo: Zilkha Biomass Energy LLC Name: Zilkha Biomass Energy LLC Address: 1001 McKinney Place: Houston, Texas Zip: 77002...

  2. Mecca Plant Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Plant Biomass Facility Jump to: navigation, search Name Mecca Plant Biomass Facility Facility Mecca Plant Sector Biomass Location Riverside County, California Coordinates...

  3. Biodyne Springfield Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Springfield Biomass Facility Jump to: navigation, search Name Biodyne Springfield Biomass Facility Facility Biodyne Springfield Sector Biomass Facility Type Landfill Gas Location...

  4. Biomass Feedstock Composition and Property Database () | Data...

    Office of Scientific and Technical Information (OSTI)

    Biomass Feedstock Composition and Property Database Title: Biomass Feedstock Composition and Property Database The Office of Energy Efficiency and Renewable Energy's Biomass ...

  5. Kiefer Landfill Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Kiefer Landfill Biomass Facility Jump to: navigation, search Name Kiefer Landfill Biomass Facility Facility Kiefer Landfill Sector Biomass Facility Type Landfill Gas Location...

  6. Biomass Boiler for Food Processing Applications | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Biomass Boiler for Food Processing Applications Biomass Boiler for Food Processing Applications Biomass Boiler Uses a Combination of Wood Waste and Tire-Derived Fuel In 2011, the ...

  7. Pyrolysis of Municipal Solid Waste for Syngas Production by Microwave Irradiation

    SciTech Connect (OSTI)

    Gedam, Vidyadhar V.; Regupathi, Iyyaswami

    2012-03-15

    In the present study, we discuss the application of microwave-irradiated pyrolysis of municipal solid waste (MSW) for total recovery of useful gases and energy. The MSW pyrolysis under microwave irradiation highly depends on the process parameters, like microwave power, microwave absorbers, and time of irradiation. The thoroughness of pyrolysis and product recovery were studied by changing the abovesaid variables. Pyrolysis of MSW occurs in the power rating range of 450-850 W-outside this power rating range, pyrolysis is not possible. Experiments were carried out using various microwave absorbers (i.e., graphite, charcoal, and iron) to enhance the pyrolysis even at lower power rating. The results show that the pyrolysis of MSW was possible even at low power ratings. The major composition of the pyrolysis gaseous product were analyzed with GC-MS which includes CO{sub 2}, CO, CH{sub 4}, etc.

  8. Biomass Program Factsheet

    SciTech Connect (OSTI)

    2010-03-01

    The emerging U.S. bioindustry is using a range of biomass resources to provide a secure and growing supply of transportation fuels and electric power. Displacing an increasing portion of our imported oil with renewable, domestic bioenergy will provide clear benefits:Reduced greenhouse gas (GHG) emissions; A cleaner, more secure energy future; Sustainable transportation fuels; Opportunities for economic growth

  9. Biomass Scenario Model

    SciTech Connect (OSTI)

    2015-09-01

    The Biomass Scenario Model (BSM) is a unique, carefully validated, state-of-the-art dynamic model of the domestic biofuels supply chain which explicitly focuses on policy issues, their feasibility, and potential side effects. It integrates resource availability, physical/technological/economic constraints, behavior, and policy. The model uses a system dynamics simulation (not optimization) to model dynamic interactions across the supply chain.

  10. Enzymes for improved biomass conversion

    DOE Patents [OSTI]

    Brunecky, Roman; Himmel, Michael E.

    2016-02-02

    Disclosed herein are enzymes and combinations of the enzymes useful for the hydrolysis of cellulose and the conversion of biomass. Methods of degrading cellulose and biomass using enzymes and cocktails of enzymes are also disclosed.

  11. NREL: Learning - Biomass Energy Basics

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass Energy Basics Photo of a farmer standing in a field and inspecting corn crops. We have used biomass energy, or "bioenergy"-the energy from plants and plant-derived...

  12. Scrap tires: a resource and technology evaluation of tire pyrolysis and other selected alternate technologies

    SciTech Connect (OSTI)

    Dodds, J.; Domenico, W.F.; Evans, D.R.; Fish, L.W.; Lassahn, P.L.; Toth, W.J.

    1983-11-01

    The results of a technical and economic evaluation of scrap tire pyrolysis are presented and some other alternative uses for scrap tires are discussed. A scrap tire, by definition in this report, is one for which there is no economic end use. Information is presented on the scrap tire resource, pyrolysis processes, pyrolysis products (char, oil, and gas), markets for these products, and the economics of tire pyrolysis. A discussion is presented on alternative ideas for using scrap tires as an energy resource.

  13. Biomass Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Education & Workforce Development » Resources » Biomass Basics Biomass Basics Biomass is an energy resource derived from organic matter, which includes wood, agricultural waste, and other living-cell material that can be burned to produce heat energy. It also includes algae, sewage, and other organic substances that may be used to make energy through chemical processes. Biomass currently supplies about 3% of total U.S. energy consumption in the form of electricity, process heat, and

  14. Biomass Feedstocks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Research & Development » Biomass Feedstocks Biomass Feedstocks An alternate text version of this video is available online. A feedstock is defined as any renewable, biological material that can be used directly as a fuel, or converted to another form of fuel or energy product. Biomass feedstocks are the plant and algal materials used to derive fuels like ethanol, butanol, biodiesel, and other hydrocarbon fuels. Examples of biomass feedstocks include corn starch, sugarcane juice, crop

  15. Reburn system with feedlot biomass

    DOE Patents [OSTI]

    Annamalai, Kalyan; Sweeten, John M.

    2005-12-13

    The present invention pertains to the use of feedlot biomass as reburn fuel matter to reduce NO.sub.x emissions. According to one embodiment of the invention, feedlot biomass is used as the reburn fuel to reduce NO.sub.x. The invention also includes burners and boiler in which feedlot biomass serves a reburn fuel.

  16. Biomass 2009 Conference Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    09 Conference Agenda Biomass 2009 Conference Agenda Biomass 2009 Conference Agenda bio2009_full_agenda.pdf (323.99 KB) More Documents & Publications Biomass 2010 Conference Agenda Biomass 2011 Conference Agenda ICAM Workshop

  17. Biomass 2010 Conference Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    0 Conference Agenda Biomass 2010 Conference Agenda Biomass 2010 Conference Agenda bio2010_full_agenda.pdf (299 KB) More Documents & Publications Biomass 2009 Conference Agenda Biomass 2011 Conference Agenda QTR Cornerstone Workshop 2014

  18. Eccleshall Biomass Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Eccleshall Biomass Ltd Jump to: navigation, search Name: Eccleshall Biomass Ltd Place: Eccleshall, United Kingdom Zip: ST21 6JL Sector: Biomass Product: Developing a 2.2MW biomass...

  19. ESD Biomass Ltd | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    ESD Biomass Ltd Jump to: navigation, search Name: ESD Biomass Ltd Place: Neston, United Kingdom Zip: SN13 9TZ Sector: Biomass Product: Acts as advisor to firms developing biomass...

  20. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  1. Use of an Apple IIe microcomputer for pyrolysis data acquisition

    SciTech Connect (OSTI)

    Not Available

    1988-02-01

    An Apple IIe microcomputer is being used to collect data and to control a pyrolysis system. Pyrolysis data for bitumen and kerogen are widely used to estimate source rock maturity. For a detailed analysis of kinetic parameters, however, data must be obtained more precisely than for routine pyrolysis. The authors discuss the program which controls the temperature ramp of the furnace that heats the sample, and collects data from a thermocouple in the furnace and from the flame ionization detector measuring evolved hydrocarbons. These data are stored on disk for later use by programs that display the results of the experiment or calculate kinetic parameters. The program is written in Applesoft BASIC with subroutines in Apple assembler for speed and efficiency.

  2. FY12 Biomass Program Congressional Budget Request

    SciTech Connect (OSTI)

    none,

    2011-02-01

    FY12 budget and funding for the Biomass Program biomass and biorefinery systems research development and deployment.

  3. Metro Wastewater Reclamation District Biomass Facility | Open...

    Open Energy Information (Open El) [EERE & EIA]

    Wastewater Reclamation District Biomass Facility Jump to: navigation, search Name Metro Wastewater Reclamation District Biomass Facility Facility Metro Wastewater Reclamation...

  4. NREL: Biomass Research - Thermochemical Conversion Capabilities

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    and commercialization of biomass gasification is the integration of the gasifier with downstream syngas processing. ... Biomass Characterization Biochemical Conversion Thermochemical ...

  5. Third world applications of pyrolysis of agricultural and forestry wastes

    SciTech Connect (OSTI)

    Tatom, J.W.; Wellborn, H.W.; Harahap, F.; Sasmojo, S.

    1980-01-01

    The development of an appropriate technology for the conversion of agricultural and wood wastes into fuels in underdeveloped nations is discussed. Low temperature pyrolysis offers a promising means of conversion since the char and oil products are storable and easily transportable. The steady-flow, vertical packed bed, partial oxidation pyrolysis process is described and the appropriate technology pyrolytic converter basic design concept is presented. The current status of program in the US and in Papua New Guinea is described. The operation, test results, and economics of the converter are discussed.

  6. Microsoft PowerPoint - CCEIHighlight-Pyrolysis-Dec2011

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    10 -10 10 -5 10 0 10 5 10 10 10 -4 10 -2 10 0 10 2 10 4 Pyrolysis Number [-] Biot Number [-] 1m 10m 100m 1mm 10mm 0.1m isothermal convection-limited conduction-limited conduction-limited kinetically-limited A Revealing Pyrolysis Chemistry of Cellulose  Design a system to eliminate internal and external heat transfer and mass transfer  Heat Characteristic Length < 10 microns  Develop analytics to quantify >90% of carbon 5 microns 0.1 1 10 100 0.1 1 10 100 Yield, powder [%]

  7. Clean fractionation of biomass

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    The US Department of Energy (DOE) Alternative Feedstocks (AF) program is forging new links between the agricultural community and the chemicals industry through support of research and development (R & D) that uses `green` feedstocks to produce chemicals. The program promotes cost-effective industrial use of renewable biomass as feedstocks to manufacture high-volume chemical building blocks. Industrial commercialization of such processes would stimulate the agricultural sector by increasing the demand of agricultural and forestry commodities. New alternatives for American industry may lie in the nation`s forests and fields. The AF program is conducting ongoing research on a clean fractionation process. This project is designed to convert biomass into materials that can be used for chemical processes and products. Clean fractionation separates a single feedstock into individual components cellulose, hemicellulose, and lignin.

  8. Biomass 2012 Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2 Agenda Biomass 2012 Agenda Detailed agenda from the July 10-11, 2012, Biomass conference--Biomass 2012: Confronting Challenges, Creating Opportunities - Sustaining a Commitment to Bioenergy. bio2012_final_agenda.pdf (340.96 KB) More Documents & Publications Biomass 2013 Agenda Biomass 2011 Conference Agenda Biomass 2010

  9. Biomass 2013 Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    3 Agenda Biomass 2013 Agenda This agenda outlines the sessions and events for Biomass 2013 in Washington, D.C., July 31-August 1. biomass_2013_agenda.pdf (322.3 KB) More Documents & Publications Biomass 2010 Conference Agenda Biomass 2012 Agenda Biomass 2009

  10. Pyrolytic oil of banana (Musa spp.) pseudo-stem via fast process

    SciTech Connect (OSTI)

    Abdullah, Nurhayati; Sulaiman, Fauziah; Taib, Rahmad Mohd; Miskam, Muhamad Azman

    2015-04-24

    This study was an attempt to produce bio-oil from banana pseudo-stem, a waste of banana cultivation, using fast pyrolysis technology. The compositions were determined and the thermal degradation behaviour of the raw material was analyzed using Perkin-Elmer Simultaneous Thermal Analyzer (STA) 6000. A 300 g/h fluidized bed bench scale fast pyrolysis unit, assembled with double screw feeders and cyclones, operating at atmospheric pressure, was used to obtain the pyrolysis liquid. The study involves the impact of the following key variables; the reactor temperature in the range of 450–650 °C, and the residence time in the range of 1.00–3.00 s. The particle size was set at 224-400 µm. The properties of the liquid product were analyzed for calorific heating value, pH value, conductivity, water and char content. The basic functional groups of the compositions were also determined using FTIR. The properties of the liquid product were compared with other wood derived bio-oil. The pyrolysis liquids derived from banana pseudo-stem were found to be in an aqueous phase.

  11. DOE 2014 Biomass Conference

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2014 Biomass Conference Jim Williams Senior Manager American Petroleum Institute July 29, 2014 DRAFT 7/28/14 Let's Agree with the Chicken Developing & Implementing Fuels & Vehicle Standards * Let Free Markets Work - Mandates and subsidies distort the free market - Must meet consumers' needs - Follow automobile company recommendations as found in owner's manuals - Changes must be compatible with transportation fuel infrastructure * Use Sound Science - Adopt a systems approach, addressing

  12. Hydrolysis of biomass material

    DOE Patents [OSTI]

    Schmidt, Andrew J.; Orth, Rick J.; Franz, James A.; Alnajjar, Mikhail

    2004-02-17

    A method for selective hydrolysis of the hemicellulose component of a biomass material. The selective hydrolysis produces water-soluble small molecules, particularly monosaccharides. One embodiment includes solubilizing at least a portion of the hemicellulose and subsequently hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A second embodiment includes solubilizing at least a portion of the hemicellulose and subsequently enzymatically hydrolyzing the solubilized hemicellulose to produce at least one monosaccharide. A third embodiment includes solubilizing at least a portion of the hemicellulose by heating the biomass material to greater than 110.degree. C. resulting in an aqueous portion that includes the solubilized hemicellulose and a water insoluble solids portion and subsequently separating the aqueous portion from the water insoluble solids portion. A fourth embodiment is a method for making a composition that includes cellulose, at least one protein and less than about 30 weight % hemicellulose, the method including solubilizing at least a portion of hemicellulose present in a biomass material that also includes cellulose and at least one protein and subsequently separating the solubilized hemicellulose from the cellulose and at least one protein.

  13. Pyrolysis kinetics of scrap tire rubbers. 1: Using DTG and TGA

    SciTech Connect (OSTI)

    Kim, S.; Park, J.K.; Chun, H.D.

    1995-07-01

    Tire pyrolysis kinetics was investigated to explore an economically viable design for the pyrolysis process. Derivative thermogravimetry (DTG) and thermogravimetric analysis (TGA) were found to provide valuable information on pyrolysis kinetics and mechanisms of a heterogeneous compound like scrap tire rubbers. Kinetic parameters of each compositional compound were obtained by analyzing DTG and TGA results with a series of mathematical methods proposed in this study. The pyrolysis kinetics of the scrap tire rubbers tested was well accounted for by the first-order irreversible independent reactions of three compositional compounds. The sidewall and tread rubber exhibited different thermal degradation patterns, suggesting a compositional difference between them. Isothermal pyrolysis results showed that the sidewall rubber would hardly be degraded at low temperature regions (<600 K), whereas it would be more rapidly degraded than the tread rubber at higher temperatures ({>=}746 K). Because of the shorter pyrolysis time, the higher isothermal pyrolysis temperature appeared to be more economically favorable.

  14. Co-pyrolysis of coal with organic solids

    SciTech Connect (OSTI)

    Straka, P.; Buchtele, J.

    1995-12-01

    The co-pyrolysis of high volatile A bituminous coal with solid organic materials (proteins, cellulose, polyisoprene, polystyrene, polyethylene-glycolterephtalate-PEGT) at a high temperature conditions was investigated. Aim of the work was to evaluate, firstly, the changes of the texture and of the porous system of solid phase after high temperature treatment in presence of different types of macromolecular solids, secondly, properties and composition of the tar and gas. Considered organic solids are important waste components. During their co-pyrolysis the high volatile bituminous coal acts as a hydrogen donor in the temperature rank 220-480{degrees}C. In the rank 500- 1000{degrees}C the solid phase is formed. The co-pyrolysis was carried out at heating rate 3 K/min. It was found that an amount of organic solid (5-10%) affects important changes in the optical texture forms of solid phase, in the pore distribution and in the internal surface area. Transport large pores volume decreases in presence of PEGT, polystyrene and cellulose and increases in presence of proteins and polyisoprene. (image analysis measurements show that the tendency of coal to create coarse pores during co-pyrolysis is very strong and increases with increasing amount of organic solid in blend). An addition of considered materials changes the sorption ability (methylene blue test, iodine adsorption test), moreover, the reactivity of the solid phase.

  15. US EPA biomass fuel analytical laboratory. Report for January-April 1997

    SciTech Connect (OSTI)

    Baskin, E.; Lee, C.W.; Natschke, D.F.

    1997-01-01

    The paper describes the U.S. EPA`s biomass fuel analytical laboratory at its Environmental Research Center in Research Triangle Park, NC. There is increasing interest in utlizing biomass-based fuels in thermal energy systems as an effective means for global warming remediation. The laboratory is examining biomass fuels and the variation in products of incomplete combustion (PICs) with combustion conditions. The objectives are to evaluate the kinetics of combustion and emission characteristics (e.g., structure and composition) of representative samples of relevant types of biomass fuels by studying (1) the local pyrolysis and combustion processes and products, and (2) the overall degradation rate as influenced by heat transmission. Biomass fuel samples will be examined by thermogravimetric analysis with an on-line Fourier transform infrared spectrometer (TGA-FTIR). EPA has built a prototype TGA, capable of handling a 100 g sample with 1 microgram resolution for this laboratory. This instrument is capable of heating the sample to 1200 C. Samples can be pyrolyzed and combusted sequentially by automated gas switching.

  16. Upgrading liquid products: Notes from the workshop at the international conference research in thermochemical biomass conversion

    SciTech Connect (OSTI)

    Elliott, D.C.

    1988-07-01

    A workshop was held at the International Energy Agency conference, Research in Thermochemical Biomass Conversion, on the subject of upgrading liquid products. The workshop discussion focused on the two prominent methods of liquids upgrading, catalytic hydroprocessing and catalytic cracking. Catalytic hydroprocessing as applied to biomass liquids relies heavily on petroleum developed technology; similar catalysts and operating conditions are used, although lower space velocities are typical. The need for stabilization of the pyrolytic products prior to hydroprocessing was also discussed. Catalytic cracking of biomass liquids also relies heavily on petroleum processing technology. Zeolite catalyst development has focused on the ZSM-5 of Mobil and its application to pyrolysis products. Significant olefinic gas yields are obtained in the zeolitic processing of biomass pyrolyzates and the conversion of these to liquid fuels is a primary research goal. Aromatic gasoline is the primary product in both catalytic processes. A general conclusion of the workshop participants was that the cost of liquid fuels for internal combustion engines would be higher in the foreseeable future. Due to the high cost of initial biomass liquefaction plants (including upgrading) a more likely near-term product would be aromatic chemicals produced under constrained economic circumstances. 16 refs.

  17. Biomass process handbook

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    Descriptions are given of 42 processes which use biomass to produce chemical products. Marketing and economic background, process description, flow sheets, costs, major equipment, and availability of technology are given for each of the 42 processes. Some of the chemicals discussed are: ethanol, ethylene, acetaldehyde, butanol, butadiene, acetone, citric acid, gluconates, itaconic acid, lactic acid, xanthan gum, sorbitol, starch polymers, fatty acids, fatty alcohols, glycerol, soap, azelaic acid, perlargonic acid, nylon-11, jojoba oil, furfural, furfural alcohol, tetrahydrofuran, cellulose polymers, products from pulping wastes, and methane. Processes include acid hydrolysis, enzymatic hydrolysis, fermentation, distillation, Purox process, and anaerobic digestion.

  18. A technical economic analysis of direct biomass liquefaction

    SciTech Connect (OSTI)

    Elliott, D.C.; Baker, E.G.; Oestman, A.; Gevert, S.B.; Beckman, D.; Solantausta, Y.; Hoernell, C.; Kjellstroem, B.

    1989-02-01

    This paper is based on the results of a technoeconomic assessment of direct biomass liquefaction processes converting wood and peat to gasoline and diesel fuels. The assessment was carried out by the Working Group of the International Energy Agency, Direct Biomass Liquefaction Activity, in which Canada, Finland, Sweden, and the United States participated. The processes chosen for detailed analysis were Atmospheric Flash Pyrolysis (AFP) and Liquefaction In Pressurized Solvent (LIPS). The assessment covered three steps for each process from feed to final product: primary liquefaction to a crude oil product; catalytic hydrotreating to upgrade the crude product to a deoxygenated product oil; and refining the deoxygenated product to gasoline and diesel fuel. Present technology cases and potential future technology cases were evaluated. A consistent analytical basis was used throughout to allow comparison of the processes. This assessment shows that AFP is more economical than LIPS both for the production of boiler fuel oil as the primary liquefaction product and for the production of gasoline and diesel fuel products. The potential for future cost reduction through research and development is also clearly demonstrated. 23 refs., 14 figs., 7 tabs.

  19. International Biomass Conference and Expo

    Energy.gov [DOE]

    The International Biomass Conference and Expo will be held April 11–14, 2016, in Charlotte, North Carolina, and will gather bioeconomy experts across the supply chain. Bioenergy Technologies Office Technology Manager Elliott Levine will be moderating a panel titled, “The Near-Term Opportunity for Biomass as a Low-Carbon Coal Supplement or Replacement.” The panel will focus on the technological challenges and opportunities in the potential for biomass to replace coal.

  20. Biomass Burning Observation Project Specifically,

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Pacific Northwest region and in the vicinity of Memphis, Tennessee, as part of the Biomass Burning Observation Project (BBOP). The aircraft will fly through smoke plumes from...

  1. New model for thermal volatilization of solid particles undergoing flash-pyrolysis

    SciTech Connect (OSTI)

    Villermaux, J.; Antoine, B.; Lede, J.; Soulignac, F.

    1983-01-01

    Many industrial processes involve the consumption of solid particles immersed in a reacting medium. Among these, the gasification of coal and biomass in fixed, fluidized or moving beds is of special interest. A great number of models describing gas-solid reactions can be found in the literature. Models dealing with the thermal volatilization of a solid controlled by heat transfer between the surrounding medium and the inner volume of the particle are more scarce. In addition, existing models often rely on the concept of a surface reaction, which is questionable, because deeper layers also contribute to the reaction as heat penetrates into the solid. A new model is proposed describing the volatilization of a solid by thermal penetration. This model was initially imagined for interpreting flash-pyrolysis of sawdust particles. Actually, it could be applied to any kind of solid reactions where volatilization is controlled by heat conduction from the outer surface. Only a few preliminary but significant results are presented in this paper. (Refs. 6)>

  2. New model for thermal volatilization of solid particles undergoing flash-pyrolysis

    SciTech Connect (OSTI)

    Villermaux, J.; Antoine, B.; Lede, J.; Soulignac, F.

    1983-01-01

    Many industrial processes involve the consumption of solid particles immersed in a reacting medium. Among these, the gasification of coal and biomass in fixed, fluidized or moving beds is of special interest. A great number of models describing gas-solid reactions can be found in the literature. Models dealing with the thermal volatilization of a solid controlled by heat transfer between the surrounding medium and the inner volume of the particle are more scarce. In addition, existing models often rely on the concept of a ''surface reaction'', which is questionable, because deeper layers also contribute to the reaction as heat penetrates into the solid. A new model is proposed describing the volatilization of a solid by thermal penetration. This model was initially imagined for interpreting flash-pyrolysis of sawdust particles. Actually, it could be applied to any kind of solid reactions where volatilization is controlled by heat conduction from the outer surface. Only a few preliminary but significant results are presented in this paper. (6 figs., 6 refs.)

  3. Clean fractionation of biomass

    SciTech Connect (OSTI)

    1995-09-01

    The US DOE Alternative Feedstocks (AF) program is forging new links between the agricultural community and the chemicals industry through support of research and development (R&D) that uses green feedstocks to produce chemicals. The program promotes cost-effective industrial use of renewable biomass as feedstocks to manufacture high-volume chemical building blocks. Industrial commercialization of such processes would stimulate the agricultural sector by increasing the demand of agricultural and forestry commodities. A consortium of five DOE national laboratories has been formed with the objectives of providing industry with a broad range of expertise and helping to lower the risk of new process development through federal cost sharing. The AF program is conducting ongoing research on a clean fractionation process, designed to convert biomass into materials that can be used for chemical processes and products. The focus of the clean fractionation research is to demonstrate to industry that one technology can successfully separate all types of feedstocks into predictable types of chemical intermediates.

  4. System and process for biomass treatment

    DOE Patents [OSTI]

    Dunson, Jr., James B; Tucker, III, Melvin P; Elander, Richard T; Lyons, Robert C

    2013-08-20

    A system including an apparatus is presented for treatment of biomass that allows successful biomass treatment at a high solids dry weight of biomass in the biomass mixture. The design of the system provides extensive distribution of a reactant by spreading the reactant over the biomass as the reactant is introduced through an injection lance, while the biomass is rotated using baffles. The apparatus system to provide extensive assimilation of the reactant into biomass using baffles to lift and drop the biomass, as well as attrition media which fall onto the biomass, to enhance the treatment process.

  5. Biomass Webinar Text Version | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Text Version Biomass Webinar Text Version Dowload the text version of the audio from the DOE Office of Indian Energy webinar on biomass. DOE Office of Indian Energy Foundational Course Webinar on Biomass: Text Version (153.94 KB) More Documents & Publications Biomass Webinar Presentation Slides Assessing Energy Resources Webinar Text Version Transcript: Biomass Clean Cities Webinar - Workforce Development

  6. Process for concentrated biomass saccharification

    DOE Patents [OSTI]

    Hennessey, Susan M.; Seapan, Mayis; Elander, Richard T.; Tucker, Melvin P.

    2010-10-05

    Processes for saccharification of pretreated biomass to obtain high concentrations of fermentable sugars are provided. Specifically, a process was developed that uses a fed batch approach with particle size reduction to provide a high dry weight of biomass content enzymatic saccharification reaction, which produces a high sugars concentration hydrolysate, using a low cost reactor system.

  7. Mobile Biomass Pelletizing System

    SciTech Connect (OSTI)

    Thomas Mason

    2009-04-16

    This grant project examines multiple aspects of the pelletizing process to determine the feasibility of pelletizing biomass using a mobile form factor system. These aspects are: the automatic adjustment of the die height in a rotary-style pellet mill, the construction of the die head to allow the use of ceramic materials for extreme wear, integrating a heat exchanger network into the entire process from drying to cooling, the use of superheated steam for adjusting the moisture content to optimum, the economics of using diesel power to operate the system; a break-even analysis of estimated fixed operating costs vs. tons per hour capacity. Initial development work has created a viable mechanical model. The overall analysis of this model suggests that pelletizing can be economically done using a mobile platform.

  8. Catalytic Hydrothermal Gasification of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2008-05-06

    A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

  9. Conditioning biomass for microbial growth

    DOE Patents [OSTI]

    Bodie, Elizabeth A; England, George

    2015-03-31

    The present invention relates to methods for improving the yield of microbial processes that use lignocellulose biomass as a nutrient source. The methods comprise conditioning a composition comprising lignocellulose biomass with an enzyme composition that comprises a phenol oxidizing enzyme. The conditioned composition can support a higher rate of growth of microorganisms in a process. In one embodiment, a laccase composition is used to condition lignocellulose biomass derived from non-woody plants, such as corn and sugar cane. The invention also encompasses methods for culturing microorganisms that are sensitive to inhibitory compounds in lignocellulose biomass. The invention further provides methods of making a product by culturing the production microorganisms in conditioned lignocellulose biomass.

  10. Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    bio-oil that's turned into fuel, thereby lessening the impact of biomass production on food supplies while creating a more efficient, cost-effective alternative to traditional...

  11. Evaluating the effect of potassium on cellulose pyrolysis reaction...

    Office of Scientific and Technical Information (OSTI)

    GrantContract Number: AC36-08-GO28308 Type: Publisher's Accepted Manuscript Journal Name: Biomass and Bioenergy Additional Journal Information: Journal Volume: 74; Journal Issue: ...

  12. Treatment of biomass to obtain fermentable sugars

    DOE Patents [OSTI]

    Dunson, Jr., James B.; Tucker, Melvin; Elander, Richard; Hennessey, Susan M.

    2011-04-26

    Biomass is pretreated using a low concentration of aqueous ammonia at high biomass concentration. Pretreated biomass is further hydrolyzed with a saccharification enzyme consortium. Fermentable sugars released by saccharification may be utilized for the production of target chemicals by fermentation.

  13. NREL: Energy Analysis - Biomass Technology Analysis

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... Biomass-fired integrated gasification combined-cycle system using a biomass energy crop Pulverized coal boiler representing an average U.S. coal-fired power plant Cofiring biomass ...

  14. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K.; Brown, Michael D.; Wilcox, Wayne A.; Baker, Eddie G.

    1989-01-01

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  15. Pyrolysis of epoxies used for thermal-battery headers

    SciTech Connect (OSTI)

    Guidotti, R.A.; Thornberg, S.M.; Campbell-Domme, B.

    1995-08-01

    Thermally activated batteries use an epoxy for encapsulation of the electrical feedthroughs in the header of the battery. When the thermal battery is thermally abused, the encapsulant can pyrolyze and generate large internal pressures. This causes the battery to vent in extreme cases. The nature of these gases has never been adequately documented. Therefore, a study was undertaken to address this deficiency. The pyrolysis of various encapsulants that have been used, or are being considered for use, in thermally activated batteries was studied over a temperature range of 155 to 455 C. The composition of the pyrolysis decomposition products was determined by gas chromatography/mass spectrometry (GS/MS). This determination is helpful in assessing the potential environmental and health effect for personnel exposed to such gases. In addition, the thermal stability of the various epoxies was measured by thermogravimetric analysis (TGA).

  16. Quality improvement of pyrolysis oil from waste rubber by adding sawdust

    SciTech Connect (OSTI)

    Wang, Wen-liang; Chang, Jian-min; Cai, Li-ping; Shi, Sheldon Q.

    2014-12-15

    Highlights: • Rubber-pyrolysis oil is difficult to be fuel due to high proportion of PAHs. • The efficiency of pyrolysis was increased as the percentage of sawdust increased. • The adding of sawdust improved pyrolysis oil quality by reducing the PAHs content. • Adding sawdust reduced nitrogen/sulfur in oil and was easier to convert to diesel. - Abstract: This work was aimed at improving the pyrolysis oil quality of waste rubber by adding larch sawdust. Using a 1 kg/h stainless pyrolysis reactor, the contents of sawdust in rubber were gradually increased from 0%, 50%, 100% and 200% (wt%) during the pyrolysis process. Using a thermo-gravimetric (TG) analyzer coupled with Fourier transform infrared (FTIR) analysis of evolving products (TG–FTIR), the weight loss characteristics of the heat under different mixtures of sawdust/rubber were observed. Using the pyrolysis–gas chromatography (GC)–mass spectrometry (Py–GC/MS), the vapors from the pyrolysis processes were collected and the compositions of the vapors were examined. During the pyrolysis process, the recovery of the pyrolysis gas and its composition were measured in-situ at a reaction temperature of 450 °C and a retaining time of 1.2 s. The results indicated that the efficiency of pyrolysis was increased and the residual carbon was reduced as the percentage of sawdust increased. The adding of sawdust significantly improved the pyrolysis oil quality by reducing the polycyclic aromatic hydrocarbons (PAHs) and nitrogen and sulfur compounds contents, resulting in an improvement in the combustion efficiency of the pyrolysis oil.

  17. Biomass Resource Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Biomass Resource Basics Biomass Resource Basics August 14, 2013 - 1:22pm Addthis Biomass resources that are used directly as a fuel, or converted to another form or energy product that are available on a renewable basis are commonly referred to as feedstocks. Biomass Feedstocks Biomass feedstocks include dedicated energy crops, agricultural crops, forestry residues, algae, biomass processing residues, municipal waste, and animal waste. Dedicated Energy Crops Dedicated energy crops are non-food

  18. Pore Scale Analysis of Oil Shale/Sands Pyrolysis

    SciTech Connect (OSTI)

    Lin, Chen-Luh; Miller, Jan

    2011-03-01

    There are important questions concerning the quality and volume of pore space that is created when oil shale is pyrolyzed for the purpose of producing shale oil. In this report, 1.9 cm diameter cores of Mahogany oil shale were pyrolyzed at different temperatures and heating rates. Detailed 3D imaging of core samples was done using multiscale X-ray computed tomography (CT) before and after pyrolysis to establish the pore structure. The pore structure of the unreacted material was not clear. Selected images of a core pyrolyzed at 400oC were obtained at voxel resolutions from 39 microns (❍m) to 60 nanometers (nm). Some of the pore space created during pyrolysis was clearly visible at these resolutions and it was possible to distinguish between the reaction products and the host shale rock. The pore structure deduced from the images was used in Lattice Boltzmann simulations to calculate the permeability in the pore space. The permeabilities of the pyrolyzed samples of the silicate-rich zone were on the order of millidarcies, while the permeabilities of the kerogen-rich zone after pyrolysis were very anisotropic and about four orders of magnitude higher.

  19. WeBiomass Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Zip: 05701 Region: Greater Boston Area Sector: Biomass Product: Commercial Biomass Boiler Systems Website: www.webiomass.com Coordinates: 43.58070919775, -72.971301209182...

  20. BSCL Use Plan: Solving Biomass Recalcitrance

    SciTech Connect (OSTI)

    Himmel, M.; Vinzant, T.; Bower, S.; Jechura, J.

    2005-08-01

    Technical report describing NREL's new Biomass Surface Characterization Laboratory (BSCL). The BSCL was constructed to provide the most modern commercial surface characterization equipment for studying biomass surfaces.

  1. Biomass Indirect Liquefaction Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Presentation Biomass Indirect Liquefaction Presentation TRI Technology Update & IDL R&D ... ClearFuels-Rentech Pilot-Scale Biorefinery Biomass Indirect Liquefaction Presentation ...

  2. Vanadium catalysts break down biomass for fuels

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    break down biomass into useful components Due to diminishing petroleum reserves, non-food biomass (lignocellulose) is an attractive alternative as a feedstock for the...

  3. Biomass Scenario Model Scenario Library: Definitions, Construction...

    Office of Scientific and Technical Information (OSTI)

    S. 09 BIOMASS FUELS; 59 BASIC BIOLOGICAL SCIENCES; 29 ENERGY PLANNING, POLICY AND ECONOMY BIOMASS; BIOFUEL; BSM; SYSTEM DYNAMICS; BIOFUEL INCENTIVES; SCENARIOS; Bioenergy;...

  4. Biomass 2013: Welcome | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Welcome Biomass 2013: Welcome Welcome and Introductory Keynotes Valerie Reed, Acting ... September 2014 Monthly News Blast BETO Monthly News Blast, August 2013r Biomass 2012 ...

  5. ARM - Biomass Burning Observation Project (BBOP)

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    March 2013 BNL BBOP Website Contacts Larry Kleinman, Lead Scientist Arthur Sedlacek Biomass Burning Observation Project (BBOP) Biomass Burning Plants, trees, grass, brush, and...

  6. NREL: Biomass Research - What Is a Biorefinery?

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    What Is a Biorefinery? A biorefinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power, and chemicals from biomass. The biorefinery...

  7. Bamboo: An Overlooked Biomass Resource? (Technical Report) |...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 09 BIOMASS FUELS; 01 COAL, LIGNITE, AND PEAT; AGRICULTURAL WASTES; ASH CONTENT; BAMBOO; BIOMASS; ENERGY RECOVERY ...

  8. Providing the Resource: Biomass Feedstocks & Logistics

    SciTech Connect (OSTI)

    2010-03-01

    A summary of Biomass Program resource assessment activities, feedstock trials, and harvest, storage, handling, and transport activities to support biomass feedstock development and use.

  9. Huntington Resource Recovery Facility Biomass Facility | Open...

    Open Energy Information (Open El) [EERE & EIA]

    Resource Recovery Facility Biomass Facility Jump to: navigation, search Name Huntington Resource Recovery Facility Biomass Facility Facility Huntington Resource Recovery Facility...

  10. Conditioning biomass for microbial growth (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Conditioning biomass for microbial growth Title: Conditioning biomass for microbial growth You are accessing a document from the Department of Energy's (DOE) DOE Patents. This ...

  11. Biomass Indirect Liquefaction Strategy Workshop: Summary Report...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Report Biomass Indirect Liquefaction Strategy Workshop: Summary Report This report is based on the proceedings of the U.S. DOE's Bioenergy Technologies Office Biomass Indirect ...

  12. Genetic manipulation of lignocellulosic biomass for bioenergy...

    Office of Scientific and Technical Information (OSTI)

    biomass for bioenergy Citation Details In-Document Search This content will become publicly available on September 7, 2017 Title: Genetic manipulation of lignocellulosic biomass ...

  13. Bioware Biomass Thermoconversion Technologies | Open Energy Informatio...

    Open Energy Information (Open El) [EERE & EIA]

    Bioware Biomass Thermoconversion Technologies Jump to: navigation, search Name: Bioware - Biomass Thermoconversion Technologies Place: Campinas, Brazil Zip: 13084-971 Product: The...

  14. Rocklin Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    References USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleRocklinBiomassFacility&oldid398013" Categories: Energy Generation Facilities Stubs...

  15. California Biomass Collaborative Energy Cost Calculators | Open...

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Collaborative Energy Cost Calculators Jump to: navigation, search Tool Summary LAUNCH TOOL Name: California Biomass Collaborative Energy Cost Calculators AgencyCompany...

  16. Prairie City Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titlePrairieCityBiomassFacility&oldid397964" Feedback Contact needs updating Image needs updating...

  17. Chateaugay Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleChateaugayBiomassFacility&oldid397318" Feedback Contact needs updating Image needs updating...

  18. Riddle Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleRiddleBiomassFacility&oldid398000" Feedback Contact needs updating Image needs updating...

  19. Bieber Plant Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleBieberPlantBiomassFacility&oldid397188" Feedback Contact needs updating Image needs updating...

  20. Bayport Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleBayportBiomassFacility&oldid397176" Feedback Contact needs updating Image needs updating...

  1. Tracy Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Facility Jump to: navigation, search Name Tracy Biomass Facility Facility Tracy Sector Biomass Owner US Renewables Group Location Tracy, California Coordinates 37.7396513,...

  2. St. Paul Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleSt.PaulBiomassFacility&oldid398161" Feedback Contact needs updating Image needs updating...

  3. SPI Anderson Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleSPIAndersonBiomassFacility&oldid398041" Feedback Contact needs updating Image needs updating...

  4. Alexandria Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleAlexandriaBiomassFacility&oldid397132" Feedback Contact needs updating Image needs updating...

  5. Biomass Combustion Systems Inc | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass Combustion Systems Inc Retrieved from "http:en.openei.orgwindex.php?titleBiomassCombustionSystemsInc&oldid768602" Feedback Contact needs updating Image...

  6. Mendota Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleMendotaBiomassFacility&oldid397757" Feedback Contact needs updating Image needs updating...

  7. Baton Rogue Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleBatonRogueBiomassFacility&oldid397172" Feedback Contact needs updating Image needs updating...

  8. Madera Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleMaderaBiomassFacility&oldid397721" Feedback Contact needs updating Image needs updating...

  9. Okeelanta 1 Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleOkeelanta1BiomassFacility&oldid397873" Feedback Contact needs updating Image needs updating...

  10. New Meadows Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Jump to: navigation, search Name New Meadows Biomass Facility Facility New Meadows Sector Biomass Owner Tamarack Energy Location New Meadows, Idaho Coordinates 44.9712808,...

  11. Oroville Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleOrovilleBiomassFacility&oldid397894" Feedback Contact needs updating Image needs updating...

  12. Multitrade Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleMultitradeBiomassFacility&oldid397817" Feedback Contact needs updating Image needs updating...

  13. Biomass Energy Resources | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Resources Jump to: navigation, search Name: Biomass Energy Resources Place: Dallas, Texas Product: A start up fuel processing technology References: Biomass Energy Resources1...

  14. Ashland Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleAshlandBiomassFacility&oldid397156" Feedback Contact needs updating Image needs updating...

  15. Chowchilla Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleChowchillaBiomassFacility&oldid397324" Feedback Contact needs updating Image needs updating...

  16. Biomass Scenario Model | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    National Renewable Energy Laboratory Partner: Department of Energy (DOE) Office of the Biomass Program Sector: Energy Focus Area: Biomass Phase: Determine Baseline Topics:...

  17. Greenville Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleGreenvilleBiomassFacility&oldid397531" Feedback Contact needs updating Image needs updating...

  18. NREL: Learning - Student Resources on Biomass Energy

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Biomass Energy The following resources can provide you with more information on biomass energy. Alternative Fuels Data Center U.S. Department of Energy's Office of Energy...

  19. Duluth Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleDuluthBiomassFacility&oldid397416" Feedback Contact needs updating Image needs updating...

  20. Delano Biomass Facility | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    USA Biomass National Map Retrieved from "http:en.openei.orgwindex.php?titleDelanoBiomassFacility&oldid397390" Feedback Contact needs updating Image needs updating...