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Sample records for aquifers depleted fields

  1. Field Evaluation of the Restorative Capacity of the Aquifer Downgradie...

    Office of Scientific and Technical Information (OSTI)

    Mining Site Citation Details In-Document Search Title: Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site A ...

  2. Modeling CO2 Sequestration in Saline Aquifer and Depleted Oil Reservoir To Evaluate Regional CO2 Sequestration Potential of Ozark Plateau Aquifer System, South-Central Kansas

    SciTech Connect (OSTI)

    Watney, W. Lynn; Rush, Jason; Raney, Jennifer

    2014-09-30

    1. Drilled, cored, and logged three wells to the basement and collecting more than 2,700 ft of conventional core; obtained 20 mi2 of multicomponent 3D seismic imaging and merged and reprocessed more than 125 mi2 of existing 3D seismic data for use in modeling CO2- EOR oil recovery and CO2 storage in five oil fields in southern Kansas. 2. Determined the technical feasibility of injecting and sequestering CO2 in a set of four depleted oil reservoirs in the Cutter, Pleasant Prairie South, Eubank, and Shuck fields in southwest Kansas; of concurrently recovering oil from those fields; and of quantifying the volumes of CO2 sequestered and oil recovered during the process. 3. Formed a consortium of six oil operating companies, five of which own and operate the four fields. The consortium became part of the Southwest Kansas CO2-EOR Initiative for the purpose of sharing data, knowledge, and interest in understanding the potential for CO2-EOR in Kansas. 4. Built a regional well database covering 30,000 mi2 and containing stratigraphic tops from ~90,000 wells; correlated 30 major stratigraphic horizons; digitized key wells, including wireline logs and sample logs; and analyzed more than 3,000 drill stem tests to establish that fluid levels in deep aquifers below the Permian evaporites are not connected to the surface and therefore pressures are not hydrostatic. Connectivity with the surface aquifers is lacking because shale aquitards and impermeable evaporite layers consist of both halite and anhydrite. 5. Developed extensive web applications and an interactive mapping system that do the following: a. Facilitate access to a wide array of data obtained in the study, including core descriptions and analyses, sample logs, digital (LAS) well logs, seismic data, gravity and magnetics maps, structural and stratigraphic maps, inferred fault traces, earthquakes, Class I and II disposal wells, and surface lineaments. b. Provide real-time analysis of the project dataset, including

  3. Multidiscipline studies of the depletion behavior of the F23 Gas Field, offshore Sarawak, East Malaysia

    SciTech Connect (OSTI)

    Heijna, H.B.; Sin, S.L.M.; Ing, S.T.T.; Van Vliet, A.; Wong, K.; Hassan, W.M.W. )

    1994-07-01

    The F23 gas field is located 178 km north-northwest of Bintulu in the central Luconia province, offshore Sarawak. The accumulation consists of a late Miocene layered platform-type carbonate buildup 22 km[sup 2] and a maximum gas thickness of over 1000 ft. Eleven development wells and one observation well were completed in 1983, with initial gas delivery to Malaysia LNG in October 1983. Annual TDT surveys are conducted in the observation well to monitor the movement of the GWC in the central area of the field. As of April 1992, a cumulative rise of 25 ft was observed. This contrasts with material balance calculations predicted rise of some 60 ft based on Sgr of 50% inferred from core measurements. Among the potential explanations were irregular bottom-water encroachment, preferential flank water advance, or larger GIIP. As all had potentially important consequences to depletion strategy and ultimate reserves, multidiscipline studies were initiated. Time-lapse seismic data were used to better determine the existing fluid levels across the field and reservoir simulation studies were used to match observation well data and predict future reservoir behavior. Concurrent reservoir and simulation studies suggested that the material balance and observation well data could be reconciled by (1) a reduced aquifer, and/or increased GIIP, and/or a lower residual gas saturation, or (2) preferential flank water influx due to internal low-permeability layers. As (1) would not lead to early water breakthrough, the simulation effort was aimed to investigate (2), the possibility and implications of early edge water breakthrough via the flank zone.

  4. Use of natural radionuclides to predict the behavior of radwaste radionuclides in far-field aquifers

    SciTech Connect (OSTI)

    Hubbard, N.; Laul, J.C.; Perkins, R.W.

    1984-01-01

    In appropriate aquifers the natural radionuclides of the U and Th decay series are important sources of information about the behavior of radwaste radionuclides in far-field aquifers. The Wolfcamp Carbonate, Pennsylvanian Carbonate and Granite Wash aquifers in the Palo Duro Basin of the Texas Panhandle are prime examples of such aquifers. Sampling and analysis for key radionuclides in the ground waters of these aquifers are quite feasible and have been accomplished. Key early results are: (1) Ra does not appear to be retarded by sorption, (2) Th appears to be strongly sorbed, (3) kinetics seem to be different on time scales of days to months than on ones of hundreds of thousands of years, and (4) U and Th behave similarly when the time scales (half-lives) are similar, leading to the suggestion that uranium is in the +4 valence state in these aquifers. 10 references, 3 figures.

  5. Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of

    Office of Scientific and Technical Information (OSTI)

    a Uranium In-Situ Recovery Mining Site (Technical Report) | SciTech Connect Technical Report: Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site Citation Details In-Document Search Title: Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site A two-part field study was conducted in Smith Ranch-Highland in-situ recovery (ISR) near Douglas, Wyoming, to evaluate the

  6. U.S. Natural Gas Number of Underground Storage Depleted Fields Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    (Number of Elements) Depleted Fields Capacity (Number of Elements) U.S. Natural Gas Number of Underground Storage Depleted Fields Capacity (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 335 2000's 336 351 340 318 320 320 322 326 324 331 2010's 331 329 330 332 333 329 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date:

  7. U.S. Working Natural Gas Underground Storage Depleted Fields Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    (Million Cubic Feet) Depleted Fields Capacity (Million Cubic Feet) U.S. Working Natural Gas Underground Storage Depleted Fields Capacity (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 3,583,786 3,659,968 2010's 3,733,993 3,769,113 3,720,980 3,839,852 3,844,927 3,854,408 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date:

  8. ,"U.S. Natural Gas Number of Underground Storage Depleted Fields Capacity (Count)"

    U.S. Energy Information Administration (EIA) (indexed site)

    Depleted Fields Capacity (Count)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Natural Gas Number of Underground Storage Depleted Fields Capacity (Count)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  9. ,"U.S. Natural Gas Underground Storage Depleted Fields Capacity (MMcf)"

    U.S. Energy Information Administration (EIA) (indexed site)

    Depleted Fields Capacity (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Natural Gas Underground Storage Depleted Fields Capacity (MMcf)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  10. ,"U.S. Working Natural Gas Underground Storage Depleted Fields Capacity (MMcf)"

    U.S. Energy Information Administration (EIA) (indexed site)

    Depleted Fields Capacity (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Working Natural Gas Underground Storage Depleted Fields Capacity (MMcf)",1,"Annual",2015 ,"Release Date:","10/31/2016" ,"Next Release Date:","11/30/2016" ,"Excel File

  11. Modeling CO2 Sequestration in Saline Aquifer and Depleted Oil Reservoir To Evaluate Regional CO2 Sequestration Potential of Ozark Plateau Aquifer System, South-Central Kansas

    SciTech Connect (OSTI)

    Watney, W. Lynn

    2014-09-30

    1. Drilled, cored, and logged three wells to the basement and collecting more than 2,700 ft of conventional core; obtained 20 mi2 of multicomponent 3D seismic imaging and merged and reprocessed more than 125 mi2 of existing 3D seismic data for use in modeling CO2- EOR oil recovery and CO2 storage in five oil fields in southern Kansas. 2. Determined the technical feasibility of injecting and sequestering CO2 in a set of four depleted oil reservoirs in the Cutter, Pleasant Prairie South, Eubank, and Shuck fields in southwest Kansas; of concurrently recovering oil from those fields; and of quantifying the volumes of CO2 sequestered and oil recovered during the process. 3. Formed a consortium of six oil operating companies, five of which own and operate the four fields. The consortium became part of the Southwest Kansas CO2-EOR Initiative for the purpose of sharing data, knowledge, and interest in understanding the potential for CO2-EOR in Kansas. 4. Built a regional well database covering 30,000 mi2 and containing stratigraphic tops from ~90,000 wells; correlated 30 major stratigraphic horizons; digitized key wells, including wireline logs and sample logs; and analyzed more than 3,000 drill stem tests to establish that fluid levels in deep aquifers below the Permian evaporites are not connected to the surface and therefore pressures are not hydrostatic. Connectivity with the surface aquifers is lacking because shale aquitards and impermeable evaporite layers consist of both halite and anhydrite. 5. Developed extensive web applications and an interactive mapping system that do the following: a. Facilitate access to a wide array of data obtained in the study, including core descriptions and analyses, sample logs, digital (LAS) well logs, seismic data, gravity and magnetics maps, structural and stratigraphic maps, inferred fault traces, earthquakes, Class I and II disposal wells, and

  12. Modeling CO2 Sequestration in Saline Aquifer and Depleted Oil Reservoir To Evaluate Regional CO2 Sequestration Potential of Ozark Plateau Aquifer System, South-Central Kansas

    SciTech Connect (OSTI)

    Watney, W. Lynn

    2014-09-30

    1. Drilled, cored, and logged three wells to the basement and collecting more than 2,700 ft of conventional core; obtained 20 mi2 of multicomponent 3D seismic imaging and merged and reprocessed more than 125 mi2 of existing 3D seismic data for use in modeling CO2- EOR oil recovery and CO2 storage in five oil fields in southern Kansas. 2. Determined the technical feasibility of injecting and sequestering CO2 in a set of four depleted oil reservoirs in the Cutter, Pleasant Prairie South, Eubank, and Shuck fields in southwest Kansas; of concurrently recovering oil from those fields; and of quantifying the volumes of CO2 sequestered and oil recovered during the process. 3. Formed a consortium of six oil operating companies, five of which own and operate the four fields. The consortium became part of the Southwest Kansas CO2-EOR Initiative for the purpose of sharing data, knowledge, and interest in understanding the potential for CO2-EOR in Kansas. 4. Built a regional well database covering 30,000 mi2 and containing stratigraphic tops from ~90,000 wells; correlated 30 major stratigraphic horizons; digitized key wells, including wireline logs and sample logs; and analyzed more than 3,000 drill stem tests to establish that fluid levels in deep aquifers below the Permian evaporites are not connected to the surface and therefore pressures are not hydrostatic. Connectivity with the surface aquifers is lacking because shale aquitards and impermeable evaporite layers consist of both halite and anhydrite. 5. Developed extensive web applications and an interactive mapping system that do the following: a. Facilitate access to a wide array of data obtained in the study, including core descriptions and analyses, sample logs, digital (LAS) well logs, seismic data, gravity and magnetics maps, structural and stratigraphic maps, inferred fault traces, earthquakes, Class I and II disposal wells, and

  13. Field testing of a high-temperature aquifer thermal energy storage system

    SciTech Connect (OSTI)

    Sterling, R.L.; Hoyer, M.C.

    1989-03-01

    The University of Minnesota Aquifer Thermal Energy Storage (ATES) System has been operated as a field test facility for the past six years. Four short-term and two long-term cycles have been completed to data providing a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. A third long-term cycle is currently being planned to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact on the aquifer from heated waste storage cycles. The most critical activities in the preparation for the next cycle have proved to be the applications for the various permits and variances necessary to conduct the third cycle and the matching of the characteristics of the ATES system during heat recovery with a suitable adjacent building thermal load.

  14. U.S. Natural Gas Underground Storage Depleted Fields Capacity (Million

    U.S. Energy Information Administration (EIA) (indexed site)

    Cubic Feet) Depleted Fields Capacity (Million Cubic Feet) U.S. Natural Gas Underground Storage Depleted Fields Capacity (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 6,780,700 2000's 6,788,130 6,768,622 6,747,108 6,733,983 6,776,894 6,667,222 6,711,656 6,801,291 6,805,490 6,917,547 2010's 7,074,773 7,104,948 7,038,245 7,074,916 7,085,773 7,075,821 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  15. The University of Minnesota aquifer thermal energy storage (ATES) field test facility -- system description, aquifer characterization, and results of short-term test cycles

    SciTech Connect (OSTI)

    Walton, M.; Hoyer, M.C.; Eisenreich, S.J.; Holm, N.L.; Holm, T.R.; Kanivetsky, R.; Jirsa, M.A.; Lee, H.C.; Lauer, J.L.; Miller, R.T.; Norton, J.L.; Runke, H. )

    1991-06-01

    Phase 1 of the Aquifer Thermal Energy Storage (ATES) Project at the University of Minnesota was to test the feasibility, and model, the ATES concept at temperatures above 100{degrees}C using a confined aquifer for the storage and recovery of hot water. Phase 1 included design, construction, and operation of a 5-MW thermal input/output field test facility (FTF) for four short-term ATES cycles (8 days each of heat injection, storage, and heat recover). Phase 1 was conducted from May 1980 to December 1983. This report describes the FTF, the Franconia-Ironton-Galesville (FIG) aquifer used for the test, and the four short-term ATES cycles. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are all included. The FTF consists of monitoring wells and the source and storage well doublet completed in the FIG aquifer with heat exchangers and a fixed-bed precipitator between the wells of the doublet. The FIG aquifer is highly layered and a really anisotropic. The upper Franconia and Ironton-Galesville parts of the aquifer, those parts screened, have hydraulic conductivities of {approximately}0.6 and {approximately}1.0 m/d, respectively. Primary ions in the ambient ground water are calcium and magnesium bicarbonate. Ambient temperature FIG ground water is saturated with respect to calcium/magnesium bicarbonate. Heating the ground water caused most of the dissolved calcium to precipitate out as calcium carbonate in the heat exchanger and precipitator. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water, suggesting dissolution of some constituents of the aquifer during the cycles. Further work on the ground water chemistry is required to understand water-rock interactions.

  16. Comparison of Caprock Mineral Characteristics at Field Demonstration Sites for Saline Aquifer Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Griffith, C.A.; Lowry, G. (Carnegie Mellon University); Dzombak, D. (Carnegie Mellon University); Soong, Yee; Hedges, S.W.

    2008-10-01

    In 2003 the U.S Department of Energy initiated regional partnership programs to address the concern for rising atmospheric CO2. These partnerships were formed to explore regional and economical means for geologically sequestering CO2 across the United States and to set the stage for future commercial applications. Several options exist for geological sequestration and among these sequestering CO2 into deep saline aquifers is one of the most promising. This is due, in part, to the possibility of stabilized permanent storage through mineral precipitation from chemical interactions of the injected carbon dioxide with the brine and reservoir rock. There are nine field demonstration sites for saline sequestration among the regional partnerships in Phase II development to validate the overall commercial feasibility for CO2 geological sequestration. Of the nine sites considered for Phase II saline sequestration demonstration, seven are profiled in this study for their caprock lithologic and mineral characteristics.

  17. Field Evaluation of the Restorative Capacity of the Aquifer Downgradient of a Uranium In-Situ Recovery Mining Site

    SciTech Connect (OSTI)

    Reimus, Paul William

    2015-05-22

    A two-part field study was conducted in Smith Ranch-Highland in-situ recovery (ISR) near Douglas, Wyoming, to evaluate the restorative capacity of the aquifer downgradient (i.e., hydrologically downstream) of a Uranium ISR mining site with respect to the transport of uranium and other potential contaminants in groundwater after mining has ceased. The study was partially conducted by checking the Uranium content and the alkalinity of separate wells, some wells had been restored and others had not. A map and in-depth procedures of the study are included.

  18. Subsurface Biogeochemical Heterogeneity (Field-scale removal of U(VI) from groundwater in an alluvial aquifer by electron donor amendment)

    SciTech Connect (OSTI)

    Long, Philip E.; Lovley, Derek R.; N'Guessan, A. L.; Nevin, Kelly; Resch, C. T.; Arntzen, Evan; Druhan, Jenny; Peacock, Aaron; Baldwin, Brett; Dayvault, Dick; Holmes, Dawn; Williams, Ken; Hubbard, Susan; Yabusaki, Steve; Fang, Yilin; White, D. C.; Komlos, John; Jaffe, Peter

    2006-06-01

    Determine if biostimulation of alluvial aquifers by electron donor amendment can effectively remove U(VI) from groundwater at the field scale. Uranium contamination in groundwater is a significant problem at several DOE sites. In this project, the possibility of accelerating bioreduction of U(VI) to U(IV) as a means of decreasing U(VI) concentrations in groundwater is directly addressed by conducting a series of field-scale experiments. Scientific goals include demonstrating the quantitative linkage between microbial activity and U loss from groundwater and relating the dominant terminal electron accepting processes to the rate of U loss. The project is currently focused on understanding the mechanisms for unexpected long-term ({approx}2 years) removal of U after stopping electron donor amendment. Results obtained in the project successfully position DOE and others to apply biostimulation broadly to U contamination in alluvial aquifers.

  19. Modeling of horizontal well and lifting mechanisms to improve ultimate recovery in a depleted field in Lake Maracaibo, Venezuela

    SciTech Connect (OSTI)

    Saputelli, L.; Mata, T.; Jimenez, Z.

    1995-12-31

    Recovery of the remaining reserve of millions of oil barrels is inhibited by depleted reservoir pressures and existing exploitation policies in Lower Lagunillas Reservoir in Lake Maracaibo, Venezuela. Numerical simulation results indicated that proper production and reservoir management policies such as, controlled drawdown, producing wells at rates below the critical rates, low gas-oil-ratio production will promote efficient gravity segregation process, and subsequent optimum final recovery. Combination of infill horizontal wells and adequate lifting mechanisms yielded the recovery of additional reserves.

  20. Building Conceptual Models of Field-Scale Uranium Reactive Transport in a Dynamic Vadose Zone-Aquifer-River System

    SciTech Connect (OSTI)

    Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.

    2008-12-04

    Subsurface simulation is being used to build, test, and couple conceptual process models to better understand controls on a 0.4 km by 1.0 km uranium plume that has persisted above the drinking water standard in the groundwater of the Hanford 300 Area over the last 15 years. At this site, uranium-contaminated sediments in the vadose zone and aquifer are subject to significant variations in water levels and velocities driven by the diurnal, weekly, seasonal, and episodic Columbia River stage dynamics. Groundwater flow reversals typically occur twice a day with significant exchange of river water and groundwater in the near-river aquifer. Mixing of the dilute solution chemistry of the river with the groundwater complicates the uranium sorption behavior as the mobility of U(VI) has been shown experimentally to be a function of pH, carbonate, calcium, and uranium. Furthermore, uranium mass transfer between solid and aqueous phases has been observed to be rate-limited in the context of the high groundwater velocities resulting from the river stage fluctuations and the highly transmissive sediments (hydraulic conductivities ~1500 m/d). One- and two-dimensional vertical cross-sectional simulations of variably-saturated flow and reactive transport, based on laboratory-derived models of distributed rate mass transfer and equilibrium multicomponent surface complexation, are used to assess uranium transport at the dynamic vadose zone aquifer interface as well as changes to uranium mobility due to incursions of river water into the aquifer.

  1. A controlled in situ field evaluation of a new dynamic vacuum slug test method in unconfined aquifers

    SciTech Connect (OSTI)

    Lauctes, B.A.; Schleyer, C.A.

    1995-09-01

    Most ground water site characterizations require initial estimates of the ground water flow velocity and potential downgradient extent of ground water contamination. The fundamental aquifer property, hydraulic conductivity, must be determined to make these essential estimates. Highly contaminated ground water often precludes conducting multi-well aquifer tests to evaluate hydraulic conductivity due to potential human health risks and ground water storage/treatment/disposal costs and logistics. Consequently, single-well slug tests are often sued, but the widely used pressure slug test method is not suitable for water table monitoring wells. As a result, a new slug test method was developed by GCL for unconfined aquifers. The new method was benchmarked against the widely used solid slug test method in a series of rising-head and falling-head slug tests. A statistical evaluation indicated no statistical difference (alpha = 0.05) between hydraulic conductivity values calculated from each method. The new dynamic vacuum method, designed specifically for use in water table monitoring wells, uses a continuous vacuum to draw air through the well screen exposed above the water table. The vacuum induces upwelling as air pressure inside the well casing drops below atmospheric pressure. Once upwelling equilibrates with the applied vacuum, the vacuum is released allowing the water to recover and the air pressure inside the casing to return to atmospheric pressure.

  2. Carrier transport and collection in fully depleted semiconductors by a combined action of the space charge field and the field due to electrode voltages

    DOE Patents [OSTI]

    Rehak, P.; Gatti, E.

    1987-08-18

    A semiconductor charge transport device and method for making same are disclosed, characterized by providing a thin semiconductor wafer having rectifying junctions on its opposing major surfaces and including a small capacitance ohmic contact, in combination with bias voltage means and associated circuit means for applying a predetermined voltage to effectively deplete the wafer in regions thereof between the rectifying junctions and the ohmic contact. A charge transport device of the invention is usable as a drift chamber, a low capacitance detector, or a charge coupled device each constructed according to the methods of the invention for making such devices. Detectors constructed according to the principles of the invention are characterized by having significantly higher particle position indicating resolution than is attainable with prior art detectors, while at the same time requiring substantially fewer readout channels to realize such high resolution. 16 figs.

  3. Carrier transport and collection in fully depleted semiconductors by a combined action of the space charge field and the field due to electrode voltages

    DOE Patents [OSTI]

    Rehak, Pavel; Gatti, Emilio

    1987-01-01

    A semiconductor charge transport device and method for making same, characterized by providing a thin semiconductor wafer having rectifying junctions on its opposing major surfaces and including a small capacitance ohmic contact, in combination with bias voltage means and associated circuit means for applying a predetermined voltage to effectively deplete the wafer in regions thereof between the rectifying junctions and the ohmic contact. A charge transport device of the invention is usable as a drift chamber, a low capacitance detector, or a charge coupled device each constructed according to the methods of the invention for making such devices. Detectors constructed according to the principles of the invention are characterized by having significantly higher particle position indicating resolution than is attainable with prior art detectors, while at the same time requiring substantially fewer readout channels to realize such high resolution.

  4. Carrier transport and collection in fully depleted semiconductors by a combined action of the space charge field and the field due to electrode voltages

    DOE Patents [OSTI]

    Rehak, P.; Gatti, E.

    1984-02-24

    A semiconductor charge transport device and method for making same, characterized by providing a thin semiconductor wafer having rectifying functions on its opposing major surfaces and including a small capacitance ohmic contact, in combination with bias voltage means and associated circuit means for applying a predetermined voltage to effectively deplete the wafer in regions thereof between the rectifying junctions and the ohmic contact. A charge transport device of the invention is usable as a drift chamber, a low capacitance detector, or a charge coupled device each constructed according to the methods of the invention for making such devices. Detectors constructed according to the principles of the invention are characterized by having significantly higher particle position indicating resolution than is attainable with prior art detectors, while at the same time requiring substantially fewer readout channels to realize such high resolution.

  5. The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-compound DNAPLs with surfactant solutions: Phase 1 -- Laboratory and pilot field-scale testing and Phase 2 -- Solubilization test and partitioning and interwell tracer tests. Final report

    SciTech Connect (OSTI)

    1997-10-24

    Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). The field test was conducted in the alluvial aquifer which is located 20 to 30 meters beneath a vapor degreasing operation at Paducah Gaseous Diffusion Plant. This aquifer has become contaminated with TCE due to leakage of perhaps 40,000 liters of TCE, which has generated a plume of dissolved TCE extending throughout an area of approximately 3 km{sup 2} in the aquifer. Most of the TCE is believed to be present in the overlying lacustrine deposits and in the aquifer itself as a dense, non-aqueous phase liquid, or DNAPL. The objective of the field test was to assess the efficacy of the surfactant for in situ TCE solubilization. Although the test demonstrated that sorbitan monooleate was unsuitable as a solubilizer in this aquifer, the single-well test was demonstrated to be a viable method for the in situ testing of surfactants or cosolvents prior to proceeding to full-scale remediation.

  6. Field-Derived Hydraulic Properties for Perched-Water Aquifer Wells 299-E33-350 and 299-E33-351, Hanford Site B-Complex Area

    SciTech Connect (OSTI)

    Newcomer, Darrell R.

    2014-07-01

    During February and March 2014, Pacific Northwest National Laboratory conducted hydraulic (slug) tests at 200-DV-1 Operable Unit wells 299-E33-350 (C8914) and 299-E33-351 (C8915) as part of B-Complex Area Perched-Water characterization activities at the Hanford Site 200-East Area. During the construction/completion phase of each well, two overlapping depth intervals were tested within the unconfined perched-water aquifer contained in the silty-sand subunit of the Cold Creek Unit. The purpose of the slug-test characterization was to provide estimates of transmissivity and hydraulic conductivity for the perched-water aquifer at these selected well locations.

  7. Groundwater in the Regional Aquifer

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an ... August 1, 2013 Conceptual model of water movement and geology at Los Alamos National ...

  8. THE SNAKE RIVER PLAIN AQUIFER THE SNAKE RIVER PLAIN AQUIFER

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    aquifer THE INL & THE SNAKE RIVER PLAIN AQUIFER THE SNAKE RIVER PLAIN AQUIFER underneath the Idaho National Laboratory is one of the most productive groundwater resources in the U.S. Each year about 2 million acre-feet of water is drawn from the aquifer. Approximately 95 percent of the water withdrawn from the aquifer is used for irrigation, 3 per- cent for domestic water, and 2 percent for industrial purposes. The aquifer is the primary water source for more than 280,000 people in

  9. Tank depletion flow controller

    DOE Patents [OSTI]

    Georgeson, Melvin A.

    1976-10-26

    A flow control system includes two bubbler tubes installed at different levels within a tank containing such as radioactive liquid. As the tank is depleted, a differential pressure transmitter monitors pressure differences imparted by the two bubbler tubes at a remote, shielded location during uniform time intervals. At the end of each uniform interval, balance pots containing a dense liquid are valved together to equalize the pressures. The resulting sawtooth-shaped signal generated by the differential pressure transmitter is compared with a second sawtooth signal representing the desired flow rate during each time interval. Variations in the two signals are employed by a control instrument to regulate flow rate.

  10. Depleted uranium management alternatives

    SciTech Connect (OSTI)

    Hertzler, T.J.; Nishimoto, D.D.

    1994-08-01

    This report evaluates two management alternatives for Department of Energy depleted uranium: continued storage as uranium hexafluoride, and conversion to uranium metal and fabrication to shielding for spent nuclear fuel containers. The results will be used to compare the costs with other alternatives, such as disposal. Cost estimates for the continued storage alternative are based on a life-cycle of 27 years through the year 2020. Cost estimates for the recycle alternative are based on existing conversion process costs and Capital costs for fabricating the containers. Additionally, the recycle alternative accounts for costs associated with intermediate product resale and secondary waste disposal for materials generated during the conversion process.

  11. Field Test Report: Preliminary Aquifer Test Characterization Results for Well 299-W15-225: Supporting Phase I of the 200-ZP-1 Groundwater Operable Unit Remedial Design

    SciTech Connect (OSTI)

    Spane, Frank A.; Newcomer, Darrell R.

    2009-09-23

    This report examines the hydrologic test results for both local vertical profile characterization and large-scale hydrologic tests associated with a new extraction well (well 299-W15-225) that was constructed during FY2009 for inclusion within the future 200-West Area Groundwater Treatment System that is scheduled to go on-line at the end of FY2011. To facilitate the analysis of the large-scale hydrologic test performed at newly constructed extraction well 299-W15-225 (C7017; also referred to as EW-1 in some planning documents), the existing 200-ZP-1 interim pump-and-treat system was completely shut-down ~1 month before the performance of the large-scale hydrologic test. Specifically, this report 1) applies recently developed methods for removing barometric pressure fluctuations from well water-level measurements to enhance the detection of hydrologic test and pump-and-treat system effects at selected monitor wells, 2) analyzes the barometric-corrected well water-level responses for a preliminary determination of large-scale hydraulic properties, and 3) provides an assessment of the vertical distribution of hydraulic conductivity in the vicinity of newly constructed extraction well 299-W15-225. The hydrologic characterization approach presented in this report is expected to have universal application for meeting the characterization needs at other remedial action sites located within unconfined and confined aquifer systems.

  12. Working Gas Capacity of Depleted Fields

    Annual Energy Outlook

    296,096 311,096 335,396 349,296 364,296 364,296 2008-2014 Colorado 48,129 49,119 48,709 60,582 60,582 63,774 2008-2014 Illinois 51,418 87,368 87,368 87,368 11,768 11,768...

  13. Natural Gas Depleted Fields Storage Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    7,074,773 7,104,948 7,038,245 7,074,916 7,085,773 7,075,821 1999-2015 Alaska 83,592 83,592 83,592 2013-2015 Alabama 11,000 13,500 13,500 13,500 13,500 13,500 1999-2015 Arkansas 21,760 21,359 21,853 21,853 21,853 21,853 1999-2015 California 542,511 570,511 592,411 587,711 587,711 589,808 1999-2015 Colorado 105,768 105,858 124,253 122,086 130,186 130,186 1999-2015 Illinois 218,106 220,070 220,070 25,920 25,923 25,944 1999-2015 Indiana 30,003 30,003 30,003 30,003 30,003 30,003 1999-2015 Iowa 0 0 0

  14. Microsoft Word - S08542_Aquifer

    Office of Legacy Management (LM)

    Work Plan for the Enhanced Characterization of the Surficial Aquifer Riverton, Wyoming, Processing Site June 2012 LMS/RVT/S08542 This page intentionally left blank LMS/RVT/S08542 Work Plan for the Enhanced Characterization of the Surficial Aquifer Riverton, Wyoming, Processing Site June 2012 This page intentionally left blank U.S. Department of Energy Work Plan for the Enhanced Characterization of the Surficial Aquifer, Riverton, Wyoming June 2012 Doc. No. S08542 Page i Contents Abbreviations

  15. Depletion Aggregation > Batteries & Fuel Cells > Research > The...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Batteries & Fuel Cells In This Section Battery Anodes Battery Cathodes Depletion Aggregation Membranes Depletion Aggregation We are exploring a number of synthetic strategies to ...

  16. FEWA: a Finite Element model of Water flow through Aquifers

    SciTech Connect (OSTI)

    Yeh, G.T.; Huff, D.D.

    1983-11-01

    This report documents the implementation and demonstration of a Finite Element model of Water flow through Aquifers (FEWA). The particular features of FEWA are its versatility and flexibility to deal with as many real-world problems as possible. Point as well as distributed sources/sinks are included to represent recharges/pumpings and rainfall infiltrations. All sources/sinks can be transient or steady state. Prescribed hydraulic head on the Dirichlet boundaries and fluxes on Neumann or Cauchy boundaries can be time-dependent or constant. Source/sink strength over each element and node, hydraulic head at each Dirichlet boundary node, and flux at each boundary segment can vary independently of each other. Either completely confined or completely unconfined aquifers, or partially confined and partially unconfined aquifers can be dealt with effectively. Discretization of a compound region with very irregular curved boundaries is made easy by including both quadrilateral and triangular elements in the formulation. Large-field problems can be solved efficiently by including a pointwise iterative solution strategy as an optional alternative to the direct elimination solution method for the matrix equation approximating the partial differential equation of groundwater flow. FEWA also includes transient flow through confining leaky aquifers lying above and/or below the aquifer of interest. The model is verified against three simple cases to which analytical solutions are available. It is then demonstrated by two examples of how the model can be applied to heterogeneous and anisotropic aquifers with transient boundary conditions, time-dependent sources/sinks, and confining aquitards for a confined aquifer of variable thickness and for a free surface problem in an unconfined aquifer, respectively. 20 references, 25 figures, 8 tables.

  17. Anaerobic biodegradation of BTEX in aquifer material. Environmental research brief

    SciTech Connect (OSTI)

    Borden, R.C.; Hunt, M.J.; Shafer, M.B.; Barlaz, M.A.

    1997-08-01

    Laboratory and field experiments were conducted in two petroleum-contaminated aquifers to examine the anaerobic biodegradation of benzene, toluene, ethylbenzene and xylene isomers (BTEX) under ambient conditions. Aquifer material was collected from locations at the source, mid-plume and end-plume at both sites, incubated under ambient conditions, and monitored for disappearance of the test compounds. In the mid-plume location at the second site, in-situ column experiments were also conducted for comparison with the laboratory microscosm and field-scale results. In the end-plume microcosms, biodegradation was variable with extensive biodegradation in some microcosms and little or no biodegradation in others.

  18. Fully depleted back illuminated CCD

    DOE Patents [OSTI]

    Holland, Stephen Edward

    2001-01-01

    A backside illuminated charge coupled device (CCD) is formed of a relatively thick high resistivity photon sensitive silicon substrate, with frontside electronic circuitry, and an optically transparent backside ohmic contact for applying a backside voltage which is at least sufficient to substantially fully deplete the substrate. A greater bias voltage which overdepletes the substrate may also be applied. One way of applying the bias voltage to the substrate is by physically connecting the voltage source to the ohmic contact. An alternate way of applying the bias voltage to the substrate is to physically connect the voltage source to the frontside of the substrate, at a point outside the depletion region. Thus both frontside and backside contacts can be used for backside biasing to fully deplete the substrate. Also, high resistivity gaps around the CCD channels and electrically floating channel stop regions can be provided in the CCD array around the CCD channels. The CCD array forms an imaging sensor useful in astronomy.

  19. EIA - Natural Gas Pipeline Network - Aquifer Storage Reservoir...

    U.S. Energy Information Administration (EIA) (indexed site)

    Aquifer Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting ... Aquifer Underground Natural Gas Storage Reservoir Configuration Aquifer Underground ...

  20. Programmable nanometer-scale electrolytic metal deposition and depletion

    DOE Patents [OSTI]

    Lee, James Weifu; Greenbaum, Elias

    2002-09-10

    A method of nanometer-scale deposition of a metal onto a nanostructure includes the steps of: providing a substrate having thereon at least two electrically conductive nanostructures spaced no more than about 50 .mu.m apart; and depositing metal on at least one of the nanostructures by electric field-directed, programmable, pulsed electrolytic metal deposition. Moreover, a method of nanometer-scale depletion of a metal from a nanostructure includes the steps of providing a substrate having thereon at least two electrically conductive nanostructures spaced no more than about 50 .mu.m apart, at least one of the nanostructures having a metal disposed thereon; and depleting at least a portion of the metal from the nanostructure by electric field-directed, programmable, pulsed electrolytic metal depletion. A bypass circuit enables ultra-finely controlled deposition.

  1. Groundwater in the Regional Aquifer

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge http://farm3.staticflickr.com/2856/9804364405_b25f74cbb2_t.jpg En

  2. field

    National Nuclear Security Administration (NNSA)

    09%2A en Ten-Year Site Plans (TYSP) http:nnsa.energy.govaboutusouroperationsinfopsinfopstysp

    field field-type-text field-field-page-name">
  3. field

    National Nuclear Security Administration (NNSA)

    09%2A en Ten-Year Site Plans (TYSP) http:www.nnsa.energy.govaboutusouroperationsinfopsinfopstysp

    field field-type-text field-field-page-name">
  4. EOI: Offsite Depleted Uranium Metalworking | Y-12 National Security...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Offsite Depleted ... EOI: Offsite Depleted Uranium Metalworking Consolidated Nuclear ... of Depleted Uranium, for the Y-12 National Security Complex in Oak Ridge, Tennessee. ...

  5. EIA - Natural Gas Pipeline Network - Depleted Reservoir Storage...

    Gasoline and Diesel Fuel Update

    Depleted Reservoir Storage Configuration About U.S. Natural Gas Pipelines - Transporting ... Depleted Production Reservoir Underground Natural Gas Storage Well Configuration Depleted ...

  6. Depleted uranium disposal options evaluation

    SciTech Connect (OSTI)

    Hertzler, T.J.; Nishimoto, D.D.; Otis, M.D.

    1994-05-01

    The Department of Energy (DOE), Office of Environmental Restoration and Waste Management, has chartered a study to evaluate alternative management strategies for depleted uranium (DU) currently stored throughout the DOE complex. Historically, DU has been maintained as a strategic resource because of uses for DU metal and potential uses for further enrichment or for uranium oxide as breeder reactor blanket fuel. This study has focused on evaluating the disposal options for DU if it were considered a waste. This report is in no way declaring these DU reserves a ``waste,`` but is intended to provide baseline data for comparison with other management options for use of DU. To PICS considered in this report include: Retrievable disposal; permanent disposal; health hazards; radiation toxicity and chemical toxicity.

  7. Effect of uncertain hydraulic conductivity on the fate and transport of BTEX compounds at a field site

    SciTech Connect (OSTI)

    Lu, Guoping; Zheng, Chunmiao; Wolfsberg, Andrew

    2002-01-05

    A Monte Carlo analysis was conducted to investigate the effect of uncertain hydraulic conductivity on the fate and transport of BTEX compounds (benzene, toluene, ethyl benzene, and xylene) at a field site on Hill Air Force Base, Utah. Microbially mediated BTEX degradation has occurred at the site through multiple terminal electron-accepting processes, including aerobic respiration, denitrification, Fe(III) reduction, sulfate reduction, and methanogenesis degradation. Multiple realizations of the hydraulic conductivity field were generated and substituted into a multispecies reactive transport model developed and calibrated for the Hill AFB site in a previous study. Simulation results show that the calculated total BTEX masses (released from a constant-concentration source) that remain in the aquifer at the end of the simulation period statistically follow a lognormal distribution. In the first analysis (base case), the calculated total BTEX mass varies from a minimum of 12% less and a maximum of 60% more than that of the previously calibrated model. This suggests that the uncertainty in hydraulic conductivity can lead to significant uncertainties in modeling the fate and transport of BTEX. Geometric analyses of calculated plume configurations show that a higher BTEX mass is associated with wider lateral spreading, while a lower mass is associated with longer longitudinal extension. More BTEX mass in the aquifer causes either a large depletion of dissolved oxygen (DO) and NO{sub 3}{sup -}, or a large depletion of DO and a large production of Fe{sup 2+}, with moderately depleted NO{sub 3}{sup -}. In an additional analysis, the effect of varying degrees of aquifer heterogeneity and associated uncertainty is examined by considering hydraulic conductivity with different variances and correlation lengths. An increase in variance leads to a higher average BTEX mass in the aquifer, while an increase in correlation length results in a lower average. This observation is

  8. High-voltage-compatible, fully depleted CCDs

    SciTech Connect (OSTI)

    Holland, Stephen E.; Bebek, Chris J.; Dawson, Kyle S.; Emes, JohnE.; Fabricius, Max H.; Fairfield, Jessaym A.; Groom, Don E.; Karcher, A.; Kolbe, William F.; Palaio, Nick P.; Roe, Natalie A.; Wang, Guobin

    2006-05-15

    We describe charge-coupled device (CCD) developmentactivities at the Lawrence Berkeley National Laboratory (LBNL).Back-illuminated CCDs fabricated on 200-300 mu m thick, fully depleted,high-resistivity silicon substrates are produced in partnership with acommercial CCD foundry.The CCDs are fully depleted by the application ofa substrate bias voltage. Spatial resolution considerations requireoperation of thick, fully depleted CCDs at high substrate bias voltages.We have developed CCDs that are compatible with substrate bias voltagesof at least 200V. This improves spatial resolution for a given thickness,and allows for full depletion of thicker CCDs than previously considered.We have demonstrated full depletion of 650-675 mu m thick CCDs, withpotential applications in direct x-ray detection. In this work we discussthe issues related to high-voltage operation of fully depleted CCDs, aswell as experimental results on high-voltage-compatible CCDs.

  9. Beneficial Uses of Depleted Uranium

    SciTech Connect (OSTI)

    Brown, C.; Croff, A.G.; Haire, M. J.

    1997-08-01

    Naturally occurring uranium contains 0.71 wt% {sup 235}U. In order for the uranium to be useful in most fission reactors, it must be enriched the concentration of the fissile isotope {sup 235}U must be increased. Depleted uranium (DU) is a co-product of the processing of natural uranium to produce enriched uranium, and DU has a {sup 235}U concentration of less than 0.71 wt%. In the United States, essentially all of the DU inventory is in the chemical form of uranium hexafluoride (UF{sub 6}) and is stored in large cylinders above ground. If this co-product material were to be declared surplus, converted to a stable oxide form, and disposed, the costs are estimated to be several billion dollars. Only small amounts of DU have at this time been beneficially reused. The U.S. Department of Energy (DOE) has begun the Beneficial Uses of DU Project to identify large-scale uses of DU and encourage its reuse for the primary purpose of potentially reducing the cost and expediting the disposition of the DU inventory. This paper discusses the inventory of DU and its rate of increase; DU disposition options; beneficial use options; a preliminary cost analysis; and major technical, institutional, and regulatory issues to be resolved.

  10. AUTOMATED WATER LEVEL MEASUREMENTS IN SMALL-DIAMETER AQUIFER TUBES

    SciTech Connect (OSTI)

    PETERSEN SW; EDRINGTON RS; MAHOOD RO; VANMIDDLESWORTH PE

    2011-01-14

    Groundwater contaminated with hexavalent chromium, strontium-90, and uranium discharges into the Columbia River along approximately 16 km (10 mi) of the shoreline. Various treatment systems have and will continue to be implemented to eliminate the impact of Hanford Site contamination to the river. To optimize the various remediation strategies, it is important to understand interactions between groundwater and the surface water of the Columbia River. An automated system to record water levels in aquifer sampling tubes installed in the hyporheic zone was designed and tested to (1) gain a more complete understanding of groundwater/river water interactions based on gaining and losing conditions ofthe Columbia River, (2) record and interpret data for consistent and defensible groundwater/surface water conceptual models that may be used to better predict subsurface contaminant fate and transport, and (3) evaluate the hydrodynamic influence of extraction wells in an expanded pump-and-treat system to optimize the treatment system. A system to measure water levels in small-diameter aquifer tubes was designed and tested in the laboratory and field. The system was configured to allow manual measurements to periodically calibrate the instrument and to permit aquifer tube sampling without removing the transducer tube. Manual measurements were collected with an e-tape designed and fabricated especially for this test. Results indicate that the transducer system accurately records groundwater levels in aquifer tubes. These data are being used to refine the conceptual and numeric models to better understand interactions in the hyporheic zone of the Columbia River and the adjacent river water and groundwater, and changes in hydrochemistry relative to groundwater flux as river water recharges the aquifer and then drains back out in response to changes in the river level.

  11. Preliminary formation analysis for compressed air energy storage in depleted natural gas reservoirs :

    SciTech Connect (OSTI)

    Gardner, William Payton

    2013-06-01

    The purpose of this study is to develop an engineering and operational understanding of CAES performance for a depleted natural gas reservoir by evaluation of relative permeability effects of air, water and natural gas in depleted natural gas reservoirs as a reservoir is initially depleted, an air bubble is created, and as air is initially cycled. The composition of produced gases will be evaluated as the three phase flow of methane, nitrogen and brine are modeled. The effects of a methane gas phase on the relative permeability of air in a formation are investigated and the composition of the produced fluid, which consists primarily of the amount of natural gas in the produced air are determined. Simulations of compressed air energy storage (CAES) in depleted natural gas reservoirs were carried out to assess the effect of formation permeability on the design of a simple CAES system. The injection of N2 (as a proxy to air), and the extraction of the resulting gas mixture in a depleted natural gas reservoir were modeled using the TOUGH2 reservoir simulator with the EOS7c equation of state. The optimal borehole spacing was determined as a function of the formation scale intrinsic permeability. Natural gas reservoir results are similar to those for an aquifer. Borehole spacing is dependent upon the intrinsic permeability of the formation. Higher permeability allows increased injection and extraction rates which is equivalent to more power per borehole for a given screen length. The number of boreholes per 100 MW for a given intrinsic permeability in a depleted natural gas reservoir is essentially identical to that determined for a simple aquifer of identical properties. During bubble formation methane is displaced and a sharp N2methane boundary is formed with an almost pure N2 gas phase in the bubble near the borehole. During cycling mixing of methane and air occurs along the boundary as the air bubble boundary moves. The extracted gas mixture changes as a

  12. An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

    SciTech Connect (OSTI)

    Jensen, E.J.

    1987-10-01

    During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides.

  13. Specification for the VERA Depletion Benchmark Suite

    SciTech Connect (OSTI)

    Kim, Kang Seog

    2015-12-17

    CASL-X-2015-1014-000 iii Consortium for Advanced Simulation of LWRs EXECUTIVE SUMMARY The CASL neutronics simulator MPACT is under development for the neutronics and T-H coupled simulation for the pressurized water reactor. MPACT includes the ORIGEN-API and internal depletion module to perform depletion calculations based upon neutron-material reaction and radioactive decay. It is a challenge to validate the depletion capability because of the insufficient measured data. One of the detoured methods to validate it is to perform a code-to-code comparison for benchmark problems. In this study a depletion benchmark suite has been developed and a detailed guideline has been provided to obtain meaningful computational outcomes which can be used in the validation of the MPACT depletion capability.

  14. EIA - Natural Gas Pipeline Network - Aquifer Storage Reservoir

    U.S. Energy Information Administration (EIA) (indexed site)

    Configuration Aquifer Storage Reservoir Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Aquifer Underground Natural Gas Storage Reservoir Configuration Aquifer Underground Natural Gas Well

  15. Depleted uranium: A DOE management guide

    SciTech Connect (OSTI)

    1995-10-01

    The U.S. Department of Energy (DOE) has a management challenge and financial liability in the form of 50,000 cylinders containing 555,000 metric tons of depleted uranium hexafluoride (UF{sub 6}) that are stored at the gaseous diffusion plants. The annual storage and maintenance cost is approximately $10 million. This report summarizes several studies undertaken by the DOE Office of Technology Development (OTD) to evaluate options for long-term depleted uranium management. Based on studies conducted to date, the most likely use of the depleted uranium is for shielding of spent nuclear fuel (SNF) or vitrified high-level waste (HLW) containers. The alternative to finding a use for the depleted uranium is disposal as a radioactive waste. Estimated disposal costs, utilizing existing technologies, range between $3.8 and $11.3 billion, depending on factors such as applicability of the Resource Conservation and Recovery Act (RCRA) and the location of the disposal site. The cost of recycling the depleted uranium in a concrete based shielding in SNF/HLW containers, although substantial, is comparable to or less than the cost of disposal. Consequently, the case can be made that if DOE invests in developing depleted uranium shielded containers instead of disposal, a long-term solution to the UF{sub 6} problem is attained at comparable or lower cost than disposal as a waste. Two concepts for depleted uranium storage casks were considered in these studies. The first is based on standard fabrication concepts previously developed for depleted uranium metal. The second converts the UF{sub 6} to an oxide aggregate that is used in concrete to make dry storage casks.

  16. EIA - Natural Gas Pipeline Network - Depleted Reservoir Storage

    U.S. Energy Information Administration (EIA) (indexed site)

    Configuration Depleted Reservoir Storage Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Depleted Production Reservoir Underground Natural Gas Storage Well Configuration Depleted Production Reservoir Storage

  17. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth...

    Energy.gov (indexed) [DOE]

    decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility ... cylinders; transportation of depleted uranium conversion products and waste materials ...

  18. DOE Extends Contract to Operate Depleted Uranium Hexafluoride...

    Office of Environmental Management (EM)

    Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants September 29, 2016 - ...

  19. DOE Awards Contract for the Operation of Depleted Uranium Hexafluoride...

    Office of Environmental Management (EM)

    Contract for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities DOE Awards Contract for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion ...

  20. Depleted Uranium Hexafluoride (DUF6) Fully Operational at the...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Depleted Uranium Hexafluoride (DUF6) Fully Operational at the Portsmouth and Paducah Gaseous Diffusion Sites Depleted Uranium Hexafluoride (DUF6) Fully Operational at the ...

  1. Record of Decision for Construction and Operation of a Depleted...

    Office of Environmental Management (EM)

    Record of Decision for Construction and Operation of a Depleted Uranium Hexafluoride ... Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the ...

  2. DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6...

    Energy Savers

    DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at Ohio and Kentucky Facilities DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at ...

  3. Enterprise Assessments Targeted Review of the Paducah Depleted...

    Energy.gov (indexed) [DOE]

    Targeted Review of the Fire Protection Program at the Paducah Depleted Uranium ... at the Paducah Depleted Uranium Hexafluoride Conversion Facility in Paducah, Kentucky. ...

  4. Disposition of Uranium Oxide From Conversion of Depleted Uranium...

    Energy Savers

    Disposition of Uranium Oxide From Conversion of Depleted Uranium Hexafluoride Disposition of Uranium Oxide From Conversion of Depleted Uranium Hexafluoride Disposition of Uranium ...

  5. Record of Decision for Construction and Operation of a Depleted...

    Office of Environmental Management (EM)

    ... Record of Decision for Construction and Operation of a Depleted Uranium Hexafluoride ... Construction and Operation of a Depleted Uranium Hexafluoride Conversion Facility at the ...

  6. VERA Core Simulator Methodology for PWR Cycle Depletion (Conference...

    Office of Scientific and Technical Information (OSTI)

    VERA Core Simulator Methodology for PWR Cycle Depletion Citation Details In-Document Search Title: VERA Core Simulator Methodology for PWR Cycle Depletion Authors: Kochunas, ...

  7. Number of Existing Natural Gas Depleted Fields Storage

    U.S. Energy Information Administration (EIA) (indexed site)

    331 329 330 332 333 329 1999-2015 Alaska 5 5 5 2013-2015 Alabama 1 1 1 1 1 1 1999-2015 Arkansas 2 2 2 2 2 2 1999-2015 California 13 13 14 13 13 13 1999-2015 Colorado 9 9 10 10 10 10 1999-2015 Illinois 11 11 11 9 9 9 1999-2015 Indiana 9 9 10 10 10 9 1999-2015 Kansas 18 18 18 18 17 17 1999-2015 Kentucky 20 20 20 20 21 21 1999-2015 Louisiana 8 8 7 8 8 8 1999-2015 Maryland 1 1 1 1 1 1 1999-2015 Michigan 43 43 43 43 43 42 1999-2015 Mississippi 6 6 6 6 6 6 1999-2015 Montana 5 5 5 5 5 5 1999-2015

  8. Neutral depletion and the helicon density limit

    SciTech Connect (OSTI)

    Magee, R. M.; Galante, M. E.; Carr, J. Jr.; Lusk, G.; McCarren, D. W.; Scime, E. E.

    2013-12-15

    It is straightforward to create fully ionized plasmas with modest rf power in a helicon. It is difficult, however, to create plasmas with density >10{sup 20} m{sup ?3}, because neutral depletion leads to a lack of fuel. In order to address this density limit, we present fast (1 MHz), time-resolved measurements of the neutral density at and downstream from the rf antenna in krypton helicon plasmas. At the start of the discharge, the neutral density underneath the antenna is reduced to 1% of its initial value in 15 ?s. The ionization rate inferred from these data implies that the electron temperature near the antenna is much higher than the electron temperature measured downstream. Neutral density measurements made downstream from the antenna show much slower depletion, requiring 14 ms to decrease by a factor of 1/e. Furthermore, the downstream depletion appears to be due to neutral pumping rather than ionization.

  9. Determination of the original-gas-in-place and aquifer properties in a water-drive reservoir by optimization technique

    SciTech Connect (OSTI)

    Chen, T.L.; Lin, Z.S.; Chen, Y.L.

    1995-10-01

    The purpose of this study was to estimate the original-gas-in-place (OGIP) of a water-drive reservoir using optimization algorithm for Port Arthur field, Texas, US. The properties of the associate aquifer were also obtained. The good agreement, between the results from this study and those from simulation study, would be demonstrated in this paper. In this study, material balance equation for a gas reservoir and van Everdingen-Hurst model for an aquifer were solved simultaneously to calculate cumulative gas production. The result was then compared with cumulative gas production measured in the field that observed at each pressure. The following parameters were manually adjusted to obtain: OGIP, thickness of the aquifer, water encroachment angle, ratio of aquifer to reservoir radius, and aquifer`s permeability. The procedure was then applied with simplex technique, an optimization algorithm, to adjust parameters automatically. When the difference between cumulative gas production calculated and observed was minimal, the parameters used in the model would be the results obtained. A water-drive gas reservoir, ``C`` sand gas reservoir in Port Arthur field, which had produced for about 12 years, was analyzed successfully. The results showed that the OGIP of 60.6 BCF estimated in this study was favorably compared with 56.2 BCF obtained by a numerical simulator in other study. In addition, the aquifer properties that were unavailable from the conventional plotting method can be estimated from this study. The estimated aquifer properties from this study were compared favorably with the core data.

  10. 30 TAC 213 - Edwards Aquifer | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    13 - Edwards Aquifer Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 30 TAC 213 - Edwards AquiferLegal Published NA Year...

  11. Depleted uranium hexafluoride: Waste or resource?

    SciTech Connect (OSTI)

    Schwertz, N.; Zoller, J.; Rosen, R.; Patton, S.; Bradley, C.; Murray, A.

    1995-07-01

    the US Department of Energy is evaluating technologies for the storage, disposal, or re-use of depleted uranium hexafluoride (UF{sub 6}). This paper discusses the following options, and provides a technology assessment for each one: (1) conversion to UO{sub 2} for use as mixed oxide duel, (2) conversion to UO{sub 2} to make DUCRETE for a multi-purpose storage container, (3) conversion to depleted uranium metal for use as shielding, (4) conversion to uranium carbide for use as high-temperature gas-cooled reactor (HTGR) fuel. In addition, conversion to U{sub 3}O{sub 8} as an option for long-term storage is discussed.

  12. Depleted uranium plasma reduction system study

    SciTech Connect (OSTI)

    Rekemeyer, P.; Feizollahi, F.; Quapp, W.J.; Brown, B.W.

    1994-12-01

    A system life-cycle cost study was conducted of a preliminary design concept for a plasma reduction process for converting depleted uranium to uranium metal and anhydrous HF. The plasma-based process is expected to offer significant economic and environmental advantages over present technology. Depleted Uranium is currently stored in the form of solid UF{sub 6}, of which approximately 575,000 metric tons is stored at three locations in the U.S. The proposed system is preconceptual in nature, but includes all necessary processing equipment and facilities to perform the process. The study has identified total processing cost of approximately $3.00/kg of UF{sub 6} processed. Based on the results of this study, the development of a laboratory-scale system (1 kg/h throughput of UF6) is warranted. Further scaling of the process to pilot scale will be determined after laboratory testing is complete.

  13. Assessment of Preferred Depleted Uranium Disposal Forms

    SciTech Connect (OSTI)

    Croff, A.G.; Hightower, J.R.; Lee, D.W.; Michaels, G.E.; Ranek, N.L.; Trabalka, J.R.

    2000-06-01

    The Department of Energy (DOE) is in the process of converting about 700,000 metric tons (MT) of depleted uranium hexafluoride (DUF6) containing 475,000 MT of depleted uranium (DU) to a stable form more suitable for long-term storage or disposal. Potential conversion forms include the tetrafluoride (DUF4), oxide (DUO2 or DU3O8), or metal. If worthwhile beneficial uses cannot be found for the DU product form, it will be sent to an appropriate site for disposal. The DU products are considered to be low-level waste (LLW) under both DOE orders and Nuclear Regulatory Commission (NRC) regulations. The objective of this study was to assess the acceptability of the potential DU conversion products at potential LLW disposal sites to provide a basis for DOE decisions on the preferred DU product form and a path forward that will ensure reliable and efficient disposal.

  14. The ultimate disposition of depleted uranium

    SciTech Connect (OSTI)

    Lemons, T.R.

    1991-12-31

    Depleted uranium (DU) is produced as a by-product of the uranium enrichment process. Over 340,000 MTU of DU in the form of UF{sub 6} have been accumulated at the US government gaseous diffusion plants and the stockpile continues to grow. An overview of issues and objectives associated with the inventory management and the ultimate disposition of this material is presented.

  15. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  16. Aquifer thermal energy storage. International symposium: Proceedings

    SciTech Connect (OSTI)

    1995-05-01

    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  17. Fluid Dynamics of Carbon Dioxide Disposal into Saline Aquifers

    SciTech Connect (OSTI)

    Garcia, Julio Enrique

    2003-12-18

    Injection of carbon dioxide (CO{sub 2}) into saline aquifers has been proposed as a means to reduce greenhouse gas emissions (geological carbon sequestration). Large-scale injection of CO{sub 2} will induce a variety of coupled physical and chemical processes, including multiphase fluid flow, fluid pressurization and changes in effective stress, solute transport, and chemical reactions between fluids and formation minerals. This work addresses some of these issues with special emphasis given to the physics of fluid flow in brine formations. An investigation of the thermophysical properties of pure carbon dioxide, water and aqueous solutions of CO{sub 2} and NaCl has been conducted. As a result, accurate representations and models for predicting the overall thermophysical behavior of the system CO{sub 2}-H{sub 2}O-NaCl are proposed and incorporated into the numerical simulator TOUGH2/ECO{sub 2}. The basic problem of CO{sub 2} injection into a radially symmetric brine aquifer is used to validate the results of TOUGH2/ECO2. The numerical simulator has been applied to more complex flow problem including the CO{sub 2} injection project at the Sleipner Vest Field in the Norwegian sector of the North Sea and the evaluation of fluid flow dynamics effects of CO{sub 2} injection into aquifers. Numerical simulation results show that the transport at Sleipner is dominated by buoyancy effects and that shale layers control vertical migration of CO{sub 2}. These results are in good qualitative agreement with time lapse surveys performed at the site. High-resolution numerical simulation experiments have been conducted to study the onset of instabilities (viscous fingering) during injection of CO{sub 2} into saline aquifers. The injection process can be classified as immiscible displacement of an aqueous phase by a less dense and less viscous gas phase. Under disposal conditions (supercritical CO{sub 2}) the viscosity of carbon dioxide can be less than the viscosity of the aqueous

  18. Depleted uranium human health risk assessment, Jefferson Proving Ground, Indiana

    SciTech Connect (OSTI)

    Ebinger, M.H.; Hansen, W.R.

    1994-04-29

    The risk to human health from fragments of depleted uranium (DU) at Jefferson Proving Ground (JPG) was estimated using two types of ecosystem pathway models. A steady-state, model of the JPG area was developed to examine the effects of DU in soils, water, and vegetation on deer that were hunted and consumed by humans. The RESRAD code was also used to estimate the effects of farming the impact area and consuming the products derived from the farm. The steady-state model showed that minimal doses to humans are expected from consumption of deer that inhabit the impact area. Median values for doses to humans range from about 1 mrem ({plus_minus}2.4) to 0.04 mrem ({plus_minus}0.13) and translate to less than 1 {times} 10{sup {minus}6} detriments (excess cancers) in the population. Monte Carlo simulation of the steady-state model was used to derive the probability distributions from which the median values were drawn. Sensitivity analyses of the steady-state model showed that the amount of DU in airborne dust and, therefore, the amount of DU on the vegetation surface, controlled the amount of DU ingested by deer and by humans. Human doses from the RESRAD estimates ranged from less than 1 mrem/y to about 6.5 mrem/y in a hunting scenario and subsistence fanning scenario, respectively. The human doses exceeded the 100 mrem/y dose limit when drinking water for the farming scenario was obtained from the on-site aquifer that was presumably contaminated with DU. The two farming scenarios were unrealistic land uses because the additional risk to humans due to unexploded ordnance in the impact area was not figured into the risk estimate. The doses estimated with RESRAD translated to less than 1 {times} 10{sup {minus}6} detriments to about 1 {times} 10{sup {minus}3} detriments. The higher risks were associated only with the farming scenario in which drinking water was obtained on-site.

  19. Number of Existing Natural Gas Aquifers Storage Fields

    Gasoline and Diesel Fuel Update

    Indiana 12 13 13 12 12 12 1999-2014 Iowa 4 4 4 4 4 4 1999-2014 Kentucky 3 3 3 3 3 2 1999-2014 Michigan 0 0 1999-2014 Minnesota 1 1 1 1 1 1 1999-2014 Missouri 1 1 1 1 1 1 1999-2014 ...

  20. University of Minnesota aquifer thermal energy storage (ATES) project report on the third long-term cycle

    SciTech Connect (OSTI)

    Hoyer, M.C.; Hallgren, J.P.; Uebel, M.H.; Delin, G.N.; Eisenreich, S.J.; Sterling, R.L.

    1994-12-01

    The University of Minnesota aquifer thermal energy storage (ATES) system has been operated as a field test facility (FTF) since 1982. The objectives were to design, construct, and operate the facility to study the feasibility of high-temperature ATES in a confined aquifer. Four short-term and two long-term cycles were previously conducted, which provided a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. The third long-term cycle (LT3) was conducted to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact that heated water storage had on the aquifer. For LT3, the source and storage wells were modified so that only the most permeable portion, the Ironton-Galesville part, of the Franconia-Ironton-Galesville aquifer was used for storage. This was expected to improve storage efficiency by reducing the surface area of the heated volume and simplify analysis of water chemistry results by reducing the number of aquifer-related variables which need to be considered. During LT3, a total volume of 63.2 {times} 10{sup 3} m {sup 3} of water was injected at a rate of 54.95 m{sup 3}/hr into the storage well at a mean temperature of 104.7{degrees}C. Tie-in to the reheat system of the nearby Animal Sciences Veterinary Medicine (ASVM) building was completed after injection was completed. Approximately 66 percent (4.13 GWh) of the energy added to the aquifer was recovered. Approximately 15 percent (0.64 GWh) of the usable (10 building. Operations during heat recovery with the ASVM building`s reheat system were trouble-free. Integration into more of the ASVM (or other) building`s mechanical systems would have resulted in significantly increasing the proportion of energy used during heat recovery.

  1. DOE Awards Contract for the Operation of Depleted Uranium Hexafluoride

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    (DUF6) Conversion Facilities | Department of Energy the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities DOE Awards Contract for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities September 29, 2016 - 1:00pm Addthis Media Contact: Lynette Chafin, 513-246-0461 Lynette.Chafin@emcbc.doe.gov Cincinnati -- The U.S. Department of Energy (DOE) today announced the award of a contract to Mid-America Conversion Services, LLC for the Operation of Depleted

  2. DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Plants | Department of Energy Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants September 29, 2016 - 1:00pm Addthis Media Contact: Brad Mitzelfelt, 859-219-4035 brad.mitzelfelt@lex.doe.gov LEXINGTON, Ky. - The U.S. Department of Energy's Office of Environmental Management (EM) today announced it is extending its contract for Operations of Depleted Uranium Hexafluoride (DUF6) Conversion

  3. DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Plants | Department of Energy Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants December 24, 2015 - 11:06am Addthis LEXINGTON, Ky. (Dec. 24, 2015) - The U.S. Department of Energy's Office of Environmental Management (EM) today announced it is extending its contract for Operations of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities at Paducah, Kentucky and Portsmouth, Ohio for a

  4. On parameterization of the inverse problem for estimating aquifer...

    Office of Scientific and Technical Information (OSTI)

    Title: On parameterization of the inverse problem for estimating aquifer properties using tracer data Authors: Kowalsky, M. B. ; Finsterle, S. ; Commer, M. ; Williams, K. H. ; ...

  5. Sole Source Aquifer Demonstration Program | Open Energy Information

    Open Energy Information (Open El) [EERE & EIA]

    Demonstration Program Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Sole Source Aquifer Demonstration ProgramLegal...

  6. Chemical and Isotopic Prediction of Aquifer Temperatures in the...

    Open Energy Information (Open El) [EERE & EIA]

    of Aquifer Temperatures in the Geothermal System at Long Valley, California Authors R.O. Fournier, Michael L. Sorey, Robert H. Mariner and Alfred H. Truesdell Published Journal...

  7. Gas generation matrix depletion quality assurance project plan

    SciTech Connect (OSTI)

    NONE

    1998-05-01

    The Los Alamos National Laboratory (LANL) is to provide the necessary expertise, experience, equipment and instrumentation, and management structure to: Conduct the matrix depletion experiments using simulated waste for quantifying matrix depletion effects; and Conduct experiments on 60 cylinders containing simulated TRU waste to determine the effects of matrix depletion on gas generation for transportation. All work for the Gas Generation Matrix Depletion (GGMD) experiment is performed according to the quality objectives established in the test plan and under this Quality Assurance Project Plan (QAPjP).

  8. DOE Extends Contract to Operate Depleted Uranium Hexafluoride...

    Energy.gov (indexed) [DOE]

    its contract for Operations of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities ... tons of DUF6 left over from decades of uranium enrichment at DOE's gaseous diffusion ...

  9. SFR with once-through depleted uranium breed & burn blanket ...

    Office of Scientific and Technical Information (OSTI)

    Title: SFR with once-through depleted uranium breed & burn blanket Authors: Zhang, Guanheng ; Greenspan, Ehud ; Jolodosky, Alejandra ; Vujic, Jasmina Publication Date: 2015-07-01 ...

  10. University of Michigan adds Depletion Capability to MPACT

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    of Michigan researchers Ben Collins, Ang Zhu, Brendan Kochunas, and Tom Downar. The numerical methods to implement nuclide point depletion and integrate a time dependent...

  11. Recovery of Depleted Uranium Fragments from Soil

    SciTech Connect (OSTI)

    Farr, C.P.; Alecksen, T.J.; Heronimus, R.S.; Simonds, M.H.; Farrar, D.R.; Baker, K.R.; Miller, M.L.

    2008-07-01

    A cost-effective method was demonstrated for recovering depleted uranium (DU) fragments from soil. A compacted clean soil pad was prepared adjacent to a pile of soil containing DU fragments. Soil from the contaminated pile was placed on the pad in three-inch lifts using conventional construction equipment. Each lift was scanned with an automatic scanning system consisting of an array of radiation detectors coupled to a detector positioning system. The data were downloaded into ArcGIS for data presentation. Areas of the pad exhibiting scaler counts above the decision level were identified as likely locations of DU fragments. The coordinates of these locations were downloaded into a PDA that was wirelessly connected to the positioning system. The PDA guided technicians to the locations where hand-held trowels and shovels were used to remove the fragments. After DU removal, the affected areas were re-scanned and the new data patched into the data base to replace the original data. This new data set along with soil sample results served as final status survey data. (authors)

  12. Aquifer thermal energy (heat and chill) storage

    SciTech Connect (OSTI)

    Jenne, E.A.

    1992-11-01

    As part of the 1992 Intersociety Conversion Engineering Conference, held in San Diego, California, August 3--7, 1992, the Seasonal Thermal Energy Storage Program coordinated five sessions dealing specifically with aquifer thermal energy storage technologies (ATES). Researchers from Sweden, The Netherlands, Germany, Switzerland, Denmark, Canada, and the United States presented papers on a variety of ATES related topics. With special permission from the Society of Automotive Engineers, host society for the 1992 IECEC, these papers are being republished here as a standalone summary of ATES technology status. Individual papers are indexed separately.

  13. Aquifer Sampling Tube Results for Fiscal Year 2003

    SciTech Connect (OSTI)

    Hartman, Mary J.; Peterson, Robert E.

    2003-10-27

    This report presents and discusses results of the fiscal year 2003 sampling event associated with aquifer tubes along the Columbia River in the northern Hanford Site. Aquifer tube data help define the extent of groundwater contamination near the river, determine vertical variations in contamination, monitor the performance of interim remedial actions near the river, and support impact studies.

  14. Estimating Plume Volume for Geologic Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Doughty, Christine

    2008-07-11

    Typically, when a new subsurface flow and transport problem is first being considered, very simple models with a minimal number of parameters are used to get a rough idea of how the system will evolve. For a hydrogeologist considering the spreading of a contaminant plume in an aquifer, the aquifer thickness, porosity, and permeability might be enough to get started. If the plume is buoyant, aquifer dip comes into play. If regional groundwater flow is significant or there are nearby wells pumping, these features need to be included. Generally, the required parameters tend to be known from pre-existing studies, are parameters that people working in the field are familiar with, and represent features that are easy to explain to potential funding agencies, regulators, stakeholders, and the public. The situation for geologic storage of carbon dioxide (CO{sub 2}) in saline aquifers is quite different. It is certainly desirable to do preliminary modeling in advance of any field work since geologic storage of CO{sub 2} is a novel concept that few people have much experience with or intuition about. But the parameters that control CO{sub 2} plume behavior are a little more daunting to assemble and explain than those for a groundwater flow problem. Even the most basic question of how much volume a given mass of injected CO{sub 2} will occupy in the subsurface is non-trivial. However, with a number of simplifying assumptions, some preliminary estimates can be made, as described below. To make efficient use of the subsurface storage volume available, CO{sub 2} density should be large, which means choosing a storage formation at depths below about 800 m, where pressure and temperature conditions are above the critical point of CO{sub 2} (P = 73.8 bars, T = 31 C). Then CO{sub 2} will exist primarily as a free-phase supercritical fluid, while some CO{sub 2} will dissolve into the aqueous phase.

  15. Method for isolating two aquifers in a single borehole

    DOE Patents [OSTI]

    Burklund, Patrick W.

    1985-10-22

    A method for isolating and individually instrumenting separate aquifers within a single borehole. A borehole is first drilled from the ground surface, through an upper aquifer, and into a separating confining bed. A casing, having upper and lower sections separated by a coupling collar, is lowered into the borehole. The borehole is grouted in the vicinity of the lower section of the casing. A borehole is then drilled through the grout plug and into a lower aquifer. After the lower aquifer is instrumented, the borehole is grouted back into the lower portion of the casing. Then the upper section of the casing is unscrewed via the coupling collar and removed from the borehole. Finally, instrumentation is added to the upper aquifer and the borehole is appropriately grouted. The coupling collar is designed to have upper right-hand screw threads and lower left-hand screw thread, whereby the sections of the casing can be readily separated.

  16. Method for isolating two aquifers in a single borehole

    DOE Patents [OSTI]

    Burklund, P.W.

    1984-01-20

    A method for isolating and individually instrumenting separate aquifers within a single borehole is disclosed. A borehole is first drilled from the ground surface, through an upper aquifer, and into a separating confining bed. A casing, having upper and lower sections separated by a coupling collar, is lowered into the borehole. The borehole is grouted in the vicinity of the lower section of the casing. A borehole is then drilled through the grout plug and into a lower aquifer. After the lower aquifer is instrumented, the borehole is grouted back into the lower portion of the casing. Then the upper section of the casing is unscrewed via the coupling collar and removed from the borehole. Finally, instrumentation is added to the upper aquifer and the borehole is appropriately grouted. The coupling collar is designed to have upper right-hand screw threads and lower left-hand screw thread, whereby the sections of the casing can be readily separated.

  17. Tracer advection by steady groundwater flow in a stratified aquifer

    SciTech Connect (OSTI)

    Sposito, Garrison; Weeks, Scott W.

    1997-01-02

    The perfectly stratified aquifer has often been investigated as a simple, tractable model for exploring new theoretical issues in subsurface hydrology. Adopting this approach, we show that steady groundwater flows in the perfectly stratified aquifer are always confined to a set of nonintersecting permanent surfaces, on which both streamlines and vorticity lines lie. This foliation of the flow domain exists as well for steady groundwater flows in any isotropic, spatially heterogeneous aquifer. In the present model example it is a direct consequence of the existence of a stream function, we then demonstrate that tracer plume advection by steady groundwater flow in a perfectly stratified aquifer is never ergodic, regardless of the initial size of the tracer plume. This nonergodicity, which holds also for tracer advection in any isotropic, spatially heterogeneous aquifer, implies that stochastic theories of purely advective tracer plume movement err in assuming ergodic behavior to simplify probabilistic calculations of plume spatial concentration moments.

  18. Thermophysical behavior of St. Peter sandstone: application to compressed air energy storage in an aquifer

    SciTech Connect (OSTI)

    Erikson, R.L.

    1983-12-01

    The long-term stability of a sandstone reservoir is of primary importance to the success of compressed air energy storage (CAES) in aquifers. The purpose of this study was to: develop experimental techniques for the operation of the CAES Porous Media Flow Loop (PMFL), an apparatus designed to study the stability of porous media in subsurface geologic environments, conduct experiments in the PMFL designed to determine the effects of temperature, stress, and humidity on the stability of candidate CAES reservoir materials, provide support for the CAES field demonstration project in Pittsfield, Illinois, by characterizing the thermophysical stability of Pittsfield reservoir sandstone under simulated field conditions.

  19. Water/rock interaction efficiency and seawater dolomitization in the Eocene Avon Park Formation, Floridan Aquifer

    SciTech Connect (OSTI)

    Cander, H.S. )

    1990-05-01

    The Floridan aquifer has often been proposed as a system of extensive meteoric carbonate diagenesis and mixing zone dolomitization. However, the dominance of marine isotope (C, O, {sup 87}Sr/{sup 86}Sr) and trace element (Sr, Fe, Mn) compositions in dolomites and limestones in the Eocene Avon Park Formation, Floridan aquifer, suggests that the very active low temperature meteoric groundwater system has, over the past 40 m.y., been an inefficient mechanism of diagenesis. {delta}{sup 18}O values of all but two replacement dolomites sampled range from +2.0 to +5.1 (PDB) with high Sr concentrations (90-325 ppm), indicating dolomitization by near-normal marine water involving no significant interaction with meteoric groundwater. The two {delta}{sup 18}O-depleted (0.0 {plus minus} 1) dolomites have low Sr concentrations ({approximately}100 ppm) suggesting limited recrystallization in meteoric water. Several dolomite samples have radiogenic {sup 87}Sr/{sup 86}Sr compositions (0.70810-0.70883 {plus minus} 2), but have heavy oxygen isotope compositions (> +2.0) and high Sr concentrations (<200 ppm) suggesting precipitation from cold Miocene age or younger seawater that circulated through the Florida platform. Most limestone stable isotope compositions cluster around marine values (({delta}{sup 18}O = {minus}1 to +1, PDB) {delta}{sup 13}C = +0.5 to +2.5) and have Eocene seawater {sup 87}Sr/{sup 86}Sr compositions (0.70775 {plus minus} 2 to 0.70779 {plus minus} 2) with 400 to 500 ppm Sr. Isotopic compositions of limestones from the east coast of Florida are all within these ranges. Only some limestones from central Florida and the west coast contain depleted stable isotopic compositions and low Sr concentrations. The sample with the most depleted stable isotope values has a radiogenic {sup 87}Sr/{sup 86}Sr composition (0.70870 {plus minus} 2), suggesting that diagenetic meteoric water migrated through post-Miocene strata.

  20. Optimizing multiphase aquifer remediation using ITOUGH2

    SciTech Connect (OSTI)

    Finsterle, S.; Pruess, K.

    1994-06-01

    The T2VOC computer model for simulating the transport of organic chemical contaminants in non-isothermal multiphase systems has been coupled to the ITOUGH2 code which solves parameter optimization problems. This allows one to use nonlinear programming and simulated annealing techniques to solve groundwater management problems, i.e. the optimization of multiphase aquifer remediation. This report contains three illustrative examples to demonstrate the optimization of remediation operations by means of simulation-minimization techniques. The code iteratively determines an optimal remediation strategy (e.g. pumping schedule) which minimizes, for instance, pumping and energy costs, the time for cleanup, and residual contamination. While minimizing the objective function is straightforward, the relative weighting of different performance measures--e.g. pumping costs versus cleanup time versus residual contaminant content--is subject to a management decision process. The intended audience of this report is someone who is familiar with numerical modeling of multiphase flow of contaminants, and who might actually use T2VOC in conjunction with ITOUGH2 to optimize the design of aquifer remediation operations.

  1. Energy Department Announces Agreement to Sell Depleted Uranium to be

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Enriched for Civil Nuclear Power | Department of Energy Agreement to Sell Depleted Uranium to be Enriched for Civil Nuclear Power Energy Department Announces Agreement to Sell Depleted Uranium to be Enriched for Civil Nuclear Power November 10, 2016 - 2:29pm Addthis News Media Contact 202-586-4940 DOENews@hq.doe.gov LEXINGTON -The Department of Energy (DOE) has agreed to sell depleted uranium to GE-Hitachi Global Laser Enrichment, LLC (GLE) over a 40-year period which would be enriched at a

  2. Radiochemical Analysis Methodology for uranium Depletion Measurements

    SciTech Connect (OSTI)

    Scatena-Wachel DE

    2007-01-09

    This report provides sufficient material for a test sponsor with little or no radiochemistry background to understand and follow physics irradiation test program execution. Most irradiation test programs employ similar techniques and the general details provided here can be applied to the analysis of other irradiated sample types. Aspects of program management directly affecting analysis quality are also provided. This report is not an in-depth treatise on the vast field of radiochemical analysis techniques and related topics such as quality control. Instrumental technology is a very fast growing field and dramatic improvements are made each year, thus the instrumentation described in this report is no longer cutting edge technology. Much of the background material is still applicable and useful for the analysis of older experiments and also for subcontractors who still retain the older instrumentation.

  3. Summary of three dimensional pump testing of a fractured rock aquifer in the western Siberian Basin

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.; Drozhko, E.G.; Glalolenko, Y.V.; Mokrov, Y.G.; Ivanov, I.A.; Glagolev, A.V.; Vasil`kova, N.A.

    1996-10-30

    A group of scientists from the Savannah River Technology Center and Russia successfully completed a 17 day field investigation of a fractured rock aquifer at the MAYAK PA nuclear production facility in Russia. The test site is located in the western Siberian Basin near the floodplain of the Mishelyak river. The fractured rock aquifer is composed of orphyrites, tuff, tuffbreccia and lava and is overlain by 0.5--12 meters of elluvial and alluvial sediments. A network of 3 uncased wells (176, 1/96, and 2/96) was used to conduct the tests. Wells 176 and 2/96 were used as observation wells and the centrally located well 1/96 was used as the pumping well. Six packers were installed and inflated in each of the observation wells at a depth of up to 85 meters. The use of 6 packers in each well resulted in isolating 7 zones for monitoring. The packers were inflated to different pressures to accommodate the increasing hydrostatic pressure. A straddle packer assembly was installed in the pumping well to allow testing of each of the individual zones isolated in the observation wells. A constant rate pumping test was run on each of the 7 zones. The results of the pumping tests are included in Appendix A. The test provided new information about the nature of the fractured rock aquifers in the vicinity of the Mishelyak river and will be key information in understanding the behavior of contaminants originating from process wastes discharged to Lake Karachi. Results from the tests will be analyzed to determine the hydraulic properties of different zones within the fractured rock aquifer and to determine the most cost effective clean-up approach for the site.

  4. DOE Selects Contractor for Depleted Hexafluoride Conversion Project...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    DOE Selects Contractor for Depleted Hexafluoride Conversion Project Support March 25, 2013 - 12:00pm Addthis Media Contact Bill Taylor, 803-952-8564 Bill.Taylor@srs.gov Cincinnati ...

  5. Attainable Burnup in a LIFE Engine Loaded with Depleted Uranium...

    Office of Scientific and Technical Information (OSTI)

    Title: Attainable Burnup in a LIFE Engine Loaded with Depleted Uranium The Laser Inertial Fusion-based Energy (LIFE) system uses a laser-based fusion source for electricity ...

  6. Disposition of DOE Excess Depleted Uranium, Natural Uranium,...

    Energy.gov (indexed) [DOE]

    U.S. Department of Energy (DOE) owns and manages an inventory of depleted uranium (DU), natural uranium (NU), and low-enriched uranium (LEU) that is currently stored in large ...

  7. Hyperspectral stimulated emission depletion microscopy and methods of use thereof

    SciTech Connect (OSTI)

    Timlin, Jerilyn A; Aaron, Jesse S

    2014-04-01

    A hyperspectral stimulated emission depletion ("STED") microscope system for high-resolution imaging of samples labeled with multiple fluorophores (e.g., two to ten fluorophores). The hyperspectral STED microscope includes a light source, optical systems configured for generating an excitation light beam and a depletion light beam, optical systems configured for focusing the excitation and depletion light beams on a sample, and systems for collecting and processing data generated by interaction of the excitation and depletion light beams with the sample. Hyperspectral STED data may be analyzed using multivariate curve resolution analysis techniques to deconvolute emission from the multiple fluorophores. The hyperspectral STED microscope described herein can be used for multi-color, subdiffraction imaging of samples (e.g., materials and biological materials) and for analyzing a tissue by Forster Resonance Energy Transfer ("FRET").

  8. Percentage depletion allowance alternative to Engle and Glass

    SciTech Connect (OSTI)

    Orbach, K.N.; Dickens, T.L.; Fields, K.T.

    1982-12-01

    Recently, the Seventh Circuit, reversing the Tax Court, held that advance royalties are eligible for percentage depletion even though no oil or gas is produced in the year of payment. In the appellate court's view, Internal Revenue Code Section 613A (c) is a limitation, rather than a prerequisite, to the deduction. The Tax Court, to the contrary, had held that advance royalties do not qualify for percentage depletion in the year of receipt unless there is actual production in such year attributable to the gross income. Likewise, the Tax Court has held that a lease bonus is not subject to percentage depletion. The purpose of this article is to analyze the positions of the Tax Court, Seventh Circuit, and, to a limited extent, the Internal Revenue Service with respect to the eligibility of percentage depletion for advance royalties and lease bonuses. (JMT)

  9. Modeling cross-hole slug tests in an unconfined aquifer

    DOE PAGES-Beta [OSTI]

    Malama, Bwalya; Kuhlman, Kristopher L.; Brauchler, Ralf; Bayer, Peter

    2016-06-28

    Cross-hole slug test date are analyzed with an extended version of a recently published unconfined aquifer model accounting for waterable effects using the linearized kinematic condition. The use of cross-hole slug test data to characterize aquifer heterogeneity and source/observation well oscillation parameters is evaluated. The data were collected in a series of multi-well and multi-level pneumatic slug tests conducted at a site in Widen, Switzerland. Furthermore, the tests involved source and observation well pairs separated by distances of up to 4 m, and instrumented with pressure transducers to monitor aquifer response in discrete intervals.

  10. Retrieval of buried depleted uranium from the T-1 trench

    SciTech Connect (OSTI)

    Burmeister, M.; Castaneda, N.; Greengard, T. |; Hull, C.; Barbour, D.; Quapp, W.J.

    1998-07-01

    The Trench 1 remediation project will be conducted this year to retrieve depleted uranium and other associated materials from a trench at Rocky Flats Environmental Technology Site. The excavated materials will be segregated and stabilized for shipment. The depleted uranium will be treated at an offsite facility which utilizes a novel approach for waste minimization and disposal through utilization of a combination of uranium recycling and volume efficient uranium stabilization.

  11. Energy Department Announces Agreement to Sell Depleted Uranium to be

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Enriched for Civil Nuclear Power | Department of Energy Announces Agreement to Sell Depleted Uranium to be Enriched for Civil Nuclear Power Energy Department Announces Agreement to Sell Depleted Uranium to be Enriched for Civil Nuclear Power November 10, 2016 - 12:00pm Addthis News Media Contact: (202) 586-4940 GE-Hitachi Global Laser Enrichment Evaluating Construction of $1 Billion Facility for Enrichment Bringing Hundreds of Jobs to Western Kentucky LEXINGTON, Ky.-The Department of Energy

  12. Stimulation Emission Depletion (STED) microscopy | The Ames Laboratory

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Stimulation Emission Depletion (STED) microscopy What is STED? Stimulation Emission Depletion (STED) microscopy is a super resolution microscopy tool that captures super resolution images on a nanometer scale. A donut-shaped red light switches off surrounding molecules, allowing only those in the center to fluoresce. At the nanoscale, light microscopes cannot tell features apart. Because light moves as waves and the particles of light are so close together, the lens used cannot focus all of the

  13. Use of natural radionuclides to predict the behavior of radwaste radionuclides in far-field aquifiers

    SciTech Connect (OSTI)

    Hubbard, N.; Laul, J.C.; Perkins, R.W.

    1983-10-01

    In appropriate aquifers the natural radionuclides of the U and Th decay series are important sources of information about the behavior of radwaste radionuclides in far-field aquifers. The Wolfcamp Carbonate, Pennsylvanian Carbonate and Granite Wash aquifers in the Palo Duro Basin of the Texas Panhandle are prime examples of such aquifers. Sampling and analysis for key radionuclides in the ground waters of these aquifers are quite feasible and have been accomplished. Key early results are: (1) Ra does not appear to be retarded by sorption, (2) Th appears to be strongly sorbed, (3) kinetics seem to be different on time scales of days to months than on ones of hundreds of thousands of years, and (4) U and Th behave similarily when the time scales (half-lives) are similar, leading to the suggestion that uranium is in the +4 valence state in these aquifers. 10 references, 9 figures.

  14. Underground helium travels to the Earth's surface via aquifers...

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Tweet EmailPrint Before it can put the party in party balloons, helium is carried from deep within the Earth's crust to the surface via aquifers, according to new research...

  15. Simulation analysis of the unconfined aquifer, Raft River Geothermal...

    Open Energy Information (Open El) [EERE & EIA]

    analysis of the unconfined aquifer, Raft River Geothermal Area, Idaho-Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Simulation analysis of the...

  16. DOE Announces Transfer of Depleted Uranium to Advance the U.S...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Transfer of Depleted Uranium to Advance the U.S. National Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant DOE Announces Transfer of Depleted Uranium to ...

  17. Analysis of Sweet Lake geopressured-geothermal aquifer

    SciTech Connect (OSTI)

    Andrade, M.; Rago, F.M.; Ohkuma, H.; Sepehrnoori, K.; Peters, E.; Dorfman, M.

    1983-01-01

    The Sweet Lake geopressured-geothermal aquifer, located southeast of Lake Charles, Louisiana, is an aquifer modeled by a two-dimensional geopressured-geothermal simulator. This aquifer is a sandstone within the Frio formation at depths between 15,000 to 15,640 ft with a net porous thickness of 250 ft, a calculated in-situ permeability (from drawdown data) of 17 md, an estimated porosity of 24 percent, a uniaxial compaction coefficient of 4.5 x 10/sup -7/ psi/sup -1/ and a solution gas-water ratio of 11 SCF/STB all at the initial reservoir pressure of 12,060 psi. These parameters are typically pressure sensitive in geopressured-geothermal aquifers and are critically important to aquifer performance. Several simulation experiments are conducted which investigate the effects of varying initial values for these parameters with the experimentally determined values as means. The simulations give both optimistic and pessimistic expectations for aquifer performance. The expected life of the geopressured-geothermal well is reported for each simulation.

  18. Total Natural Gas Underground Storage Capacity

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Storage Capacity Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working...

  19. Natural Gas Underground Storage Capacity (Summary)

    U.S. Energy Information Administration (EIA) (indexed site)

    Salt Caverns Storage Capacity Aquifers Storage Capacity Depleted Fields Storage Capacity Total Working Gas Capacity Working Gas Capacity of Salt Caverns Working Gas Capacity of ...

  20. Effect of Shim Arm Depletion in the NBSR

    SciTech Connect (OSTI)

    Hanson A. H.; Brown N.; Diamond, D.J.

    2013-02-22

    The cadmium shim arms in the NBSR undergo burnup during reactor operation and hence, require periodic replacement. Presently, the shim arms are replaced after every 25 cycles to guarantee they can maintain sufficient shutdown margin. Two prior reports document the expected change in the 113Cd distribution because of the shim arm depletion. One set of calculations was for the present high-enriched uranium fuel and the other for the low-enriched uranium fuel when it was in the COMP7 configuration (7 inch fuel length vs. the present 11 inch length). The depleted 113Cd distributions calculated for these cores were applied to the current design for an equilibrium low-enriched uranium core. This report details the predicted effects, if any, of shim arm depletion on the shim arm worth, the shutdown margin, power distributions and kinetics parameters.

  1. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, C.W.

    1998-11-03

    A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

  2. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, Charles W.

    1998-01-01

    A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

  3. Bicarbonate Impact on U(VI) Bioreduction in a Shallow Alluvial Aquifer

    SciTech Connect (OSTI)

    Long, Philip E.; Williams, Kenneth H.; Davis, James A.; Fox, Patricia M.; Wilkins, Michael J.; Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.; Berman, Elena S.; Gupta, Manish; Chandler, Darrell P.; Murray, Christopher J.; Peacock, Aaron D.; Giloteaux, L.; Handley, Kim M.; Lovley, Derek R.; Banfield, Jillian F.

    2015-02-01

    Field-scale biostimulation and desorption tracer experiments conducted in a uranium (U) contaminated, shallow alluvial aquifer have provided insight into the coupling of microbiology, biogeochemistry, and hydrogeology that control U mobility in the subsurface. Initial experiments successfully tested the concept that Fe-reducing bacteria such as Geobacter sp. could enzymatically reduce soluble U(VI) to insoluble U(IV) during in situ electron donor amendment (Anderson et al. 2003, Williams et al. 2011). In parallel, in situ desorption tracer tests using bicarbonate amendment demonstrated rate-limited U(VI) desorption (Fox et al. 2012). These results and prior laboratory studies underscored the importance of enzymatic U(VI)-reduction and suggested the ability to combine desorption and bioreduction of U(VI). Here we report the results of a new field experiment in which bicarbonate-promoted uranium desorption and acetate amendment were combined and compared to an acetate amendment-only experiment in the same experimental plot. Results confirm that bicarbonate amendment to alluvial aquifer desorbs U(VI) and increases the abundance of Ca-uranyl-carbonato complexes. At the same time, that the rate of acetate-promoted enzymatic U(VI) reduction was greater in the presence of added bicarbonate in spite of the increased dominance of Ca-uranyl-carbonato aqueous complexes. A model-simulated peak rate of U(VI) reduction was ~3.8 times higher during acetate-bicarbonate treatment than under acetate-only conditions. Lack of consistent differences in microbial community structure between acetate-bicarbonate and acetate-only treatments suggest that a significantly higher rate of U(VI) reduction the bicarbonate-impacted sediment may be due to a higher intrinsic rate of microbial reduction induced by elevated concentrations of the bicarbonate oxyanion. The findings indicate that bicarbonate amendment may be useful in improving the engineered bioremediation of uranium in aquifers.

  4. Second Generation Monolithic Full-depletion Radiation Sensor with Integrated CMOS Circuitry

    SciTech Connect (OSTI)

    Segal, J.D.; Kenney, C.J.; Parker, S.I.; Aw, C.H.; Snoeys, W.J.; Wooley, B.; Plummer, J.D.; /Stanford U., Elect. Eng. Dept.

    2011-05-20

    A second-generation monolithic silicon radiation sensor has been built and characterized. This pixel detector has CMOS circuitry fabricated directly in the high-resistivity floatzone substrate. The bulk is fully depleted from bias applied to the backside diode. Within the array, PMOS pixel circuitry forms the first stage amplifiers. Full CMOS circuitry implementing further amplification as well as column and row logic is located in the periphery of the pixel array. This allows a sparse-field readout scheme where only pixels with signals above a certain threshold are readout. We describe the fabrication process, circuit design, system performance, and results of gamma-ray radiation tests.

  5. Analysis of Sweet Lake geopressured-geothermal aquifer

    SciTech Connect (OSTI)

    Andrade, M.; Rago, F.; Ohkuma, H.; Sepehrnoori, K.; Peters, E.; Dorfman, M.

    1982-01-01

    The Sweet Lake geopressured-geothermal aquifer, located southeast of Lake Charles, Louisiana, is modeled by a two-dimensional geopressured-geothermal simulator. This aquifer is a sandstone within the Frio formation at depths between 15,000 to 15,640 ft with a net porous thickness of 250 ft, a calculated in-situ permeability (from drawdown data) of 17 md, an estimated porosity of 24%, a uniaxial compaction coefficient of 4.5 x 10/sup -7/ psi/sup -1/ and a solution gas-water ratio of 11 SCF/STB all at the initial reservoir pressure of 12,060 psi. These parameters are typically pressure sensitive in geopressured-geothermal aquifers and are critically important to aquifer performance. Several simulation experiments are conducted which investigate the effects of varying initial values for these parameters with the experimentally determined values as means. The simulations give both optimistic and pessimistic expectations for aquifer performance. The expected life of the geopressured-geothermal well is reported for each simulation.

  6. FEMA: a Finite Element Model of Material Transport through Aquifers

    SciTech Connect (OSTI)

    Yeh, G.T.; Huff, D.D.

    1985-01-01

    This report documents the construction, verification, and demonstration of a Finite Element Model of Material Transport through Aquifers (FEMA). The particular features of FEMA are its versatility and flexibility to deal with as many real-world problems as possible. Mechanisms included in FEMA are: carrier fluid advection, hydrodynamic dispersion and molecular diffusion, radioactive decay, sorption, source/sinks, and degradation due to biological, chemical as well as physical processes. Three optional sorption models are embodied in FEMA. These are linear isotherm and Freundlich and Langmuir nonlinear isotherms. Point as well as distributed source/sinks are included to represent artificial injection/withdrawals and natural infiltration of precipitation. All source/sinks can be transient or steady state. Prescribed concentration on the Dirichlet boundary, given gradient on the Neumann boundary segment, and flux at each Cauchy boundary segment can vary independently of each other. The aquifer may consist of as many formations as desired. Either completely confined or completely unconfined or partially confined and partially unconfined aquifers can be dealt with effectively. FEMA also includes transient leakage to or from the aquifer of interest through confining beds from or to aquifers lying below and/or above.

  7. EIS-0269: Long-Term Management of Depleted Uranium Hexaflouride

    Energy.gov [DOE]

    The U.S. Department of Energy (DOE) prepared this programmatic environmental impact statement to assess the potential impacts of alternative management strategies for depleted uranium hexafluoride currently stored at three DOE sites: Paducah site near Paducah, Kentucky; Portsmouth site near Portsmouth, Ohio; and K-25 site on the Oak Ridge Reservation in Oak Ridge, Tennessee.

  8. Legal and regulatory issues affecting aquifer thermal energy storage

    SciTech Connect (OSTI)

    Hendrickson, P.L.

    1981-10-01

    This document updates and expands the report with a similar title issued in October 1980. This document examines a number of legal and regulatory issues that potentially can affect implementation of the aquifer thermal energy storage (ATES) concept. This concept involves the storage of thermal energy in an underground aquifer until a later date when it can be effectively utilized. Either heat energy or chill can be stored. Potential end uses of the energy include district space heating and cooling, industrial process applications, and use in agriculture or aquaculture. Issues are examined in four categories: regulatory requirements, property rights, potential liability, and issues related to heat or chill delivery.

  9. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  10. CRDIAC: Coupled Reactor Depletion Instrument with Automated Control

    SciTech Connect (OSTI)

    Steven K. Logan

    2012-08-01

    When modeling the behavior of a nuclear reactor over time, it is important to understand how the isotopes in the reactor will change, or transmute, over that time. This is especially important in the reactor fuel itself. Many nuclear physics modeling codes model how particles interact in the system, but do not model this over time. Thus, another code is used in conjunction with the nuclear physics code to accomplish this. In our code, Monte Carlo N-Particle (MCNP) codes and the Multi Reactor Transmutation Analysis Utility (MRTAU) were chosen as the codes to use. In this way, MCNP would produce the reaction rates in the different isotopes present and MRTAU would use cross sections generated from these reaction rates to determine how the mass of each isotope is lost or gained. Between these two codes, the information must be altered and edited for use. For this, a Python 2.7 script was developed to aid the user in getting the information in the correct forms. This newly developed methodology was called the Coupled Reactor Depletion Instrument with Automated Controls (CRDIAC). As is the case in any newly developed methodology for modeling of physical phenomena, CRDIAC needed to be verified against similar methodology and validated against data taken from an experiment, in our case AFIP-3. AFIP-3 was a reduced enrichment plate type fuel tested in the ATR. We verified our methodology against the MCNP Coupled with ORIGEN2 (MCWO) method and validated our work against the Post Irradiation Examination (PIE) data. When compared to MCWO, the difference in concentration of U-235 throughout Cycle 144A was about 1%. When compared to the PIE data, the average bias for end of life U-235 concentration was about 2%. These results from CRDIAC therefore agree with the MCWO and PIE data, validating and verifying CRDIAC. CRDIAC provides an alternative to using ORIGEN-based methodology, which is useful because CRDIAC's depletion code, MRTAU, uses every available isotope in its depletion

  11. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Annual Report FY09

    SciTech Connect (OSTI)

    Wolery, T; Aines, R; Hao, Y; Bourcier, W; Wolfe, T; Haussman, C

    2009-11-25

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine is reinjected into the formation at net volume reduction, such that the volume of fresh water extracted balances the volume of CO{sub 2} injected into the formation. This process provides additional CO{sub 2} storage capacity in the aquifer, reduces operational risks (cap-rock fracturing, contamination of neighboring fresh water aquifers, and seismicity) by relieving overpressure in the formation, and provides a source of low-cost fresh water to offset costs or operational water needs. This multi-faceted project combines elements of geochemistry, reservoir engineering, and water treatment engineering. The range of saline formation waters is being identified and analyzed. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations. Computer modeling is being used to evaluate processes in the storage aquifer, including the evolution of the pressure field. Water treatment costs are being evaluated by comparing the necessary process facilities to those in common use for seawater RO. There are presently limited brine composition data available for actual CCS sites by the site operators including in the U.S. the seven regional Carbon Sequestration Partnerships (CSPs). To work around this, we are building a 'catalog' of compositions representative of 'produced' waters (waters produced in the course of seeking or producing oil and gas), to which we are adding data from actual CCS sites as they become available. Produced waters comprise the most common examples of saline

  12. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Interim Progress Report

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Hao, Y; Bourcier, W L

    2009-07-22

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including nanofiltration (NF) and reverse osmosis (RO). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine would be reinjected into the formation at net volume reduction. This process provides additional storage space (capacity) in the aquifer, reduces operational risks by relieving overpressure in the aquifer, and provides a source of low-cost fresh water to offset costs or operational water needs. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations for brines typical of CCS sites. Computer modeling is being used to evaluate processes in the aquifer, including the evolution of the pressure field. This progress report deals mainly with our geochemical modeling of high-salinity brines and covers the first six months of project execution (September, 2008 to March, 2009). Costs and implementation results will be presented in the annual report. The brines typical of sequestration sites can be several times more concentrated than seawater, requiring specialized modeling codes typical of those developed for nuclear waste disposal calculations. The osmotic pressure developed as the brines are concentrated is of particular concern, as are precipitates that can cause fouling of reverse osmosis membranes and other types of membranes (e.g., NF). We have now completed the development associated with tasks (1) and (2) of the work plan. We now have a contract with Perlorica, Inc., to provide support to the cost analysis and nanofiltration evaluation. We have also conducted several preliminary analyses of the pressure effect in the reservoir in order to confirm that reservoir

  13. Porous media experience applicable to field evaluation for compressed air energy storage

    SciTech Connect (OSTI)

    Allen, R.D.; Gutknecht, P.J.

    1980-06-01

    A survey is presented of porous media field experience that may aid in the development of a compressed air energy storage field demonstration. Work done at PNL and experience of other groups and related industries is reviewed. An overall view of porous media experience in the underground storage of fluids is presented. CAES experience consists of site evaluation and selection processes used by groups in California, Kansas, and Indiana. Reservoir design and field evaluation of example sites are reported. The studies raised questions about compatibility with depleted oil and gas reservoirs, storage space rights, and compressed air regulations. Related experience embraces technologies of natural gas, thermal energy, and geothermal and hydrogen storage. Natural gas storage technology lends the most toward compressed air storage development, keeping in mind the respective differences between stored fluids, physical conditions, and cycling frequencies. Both fluids are injected under pressure into an aquifer to form a storage bubble confined between a suitable caprock structure and partially displaced ground water. State-of-the-art information is summarized as the necessary foundation material for field planning. Preliminary design criteria are given as recommendations for basic reservoir characteristics. These include geometric dimensions and storage matrix properties such as permeability. Suggested ranges are given for injection air temperature and reservoir pressure. The second step in developmental research is numerical modeling. Results have aided preliminary design by analyzing injection effects upon reservoir pressure, temperature and humidity profiles. Results are reported from laboratory experiments on candidate sandstones and caprocks. Conclusions are drawn, but further verification must be done in the field.

  14. DOE Extends Contract to Operate Depleted Uranium Hexafluoride Conversion Plants

    Energy.gov [DOE]

    LEXINGTON, Ky. – The U.S. Department of Energy’s Office of Environmental Management (EM) today announced it is extending its contract for Operations of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities at Paducah, Kentucky and Portsmouth, Ohio for a period of up to nine months. The contract period for the current contractor, BWXT Conversion Services LLC (BWCS), had been scheduled to expire on January 1, 2016.

  15. 1,2,3-D Diffusion Depletion Multi-Group

    Energy Science and Technology Software Center (OSTI)

    1992-04-20

    CITATION is designed to solve problems using the finite difference representation of neutron diffusion theory, treating up to three space dimensions with arbitrary group to group scattering. X-y-z, theta-r-z, hexagonal z, and triagonal z geometries may be treated. Depletion problems may be solved and fuel managed for multi-cycle analysis. Extensive first order perturbation results may be obtained given microscopic data and nuclide concentrations. Statics problems may be solved and perturbation results obtained with microscopic data.

  16. High-voltage compatible, full-depleted CCD

    DOE Patents [OSTI]

    Holland, Stephen Edward

    2007-09-18

    A charge coupled device for detecting electromagnetic and particle radiation is described. The device includes a high-resistivity semiconductor substrate, buried channel regions, gate electrode circuitry, and amplifier circuitry. For good spatial resolution and high performance, especially when operated at high voltages with full or nearly full depletion of the substrate, the device can also include a guard ring positioned near channel regions, a biased channel stop, and a biased polysilicon electrode over the channel stop.

  17. Background Fact Sheet Transfer of Depleted Uranium and Subsequent Transactions

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Background Fact Sheet Transfer of Depleted Uranium and Subsequent Transactions At the direction of Energy Secretary Steven Chu, over many months, the Energy Department (DOE) has been working closely with Energy Northwest (ENW), the Tennessee Valley Authority (TVA), and USEC Inc. (USEC) to develop a plan to address the challenges at USEC's Paducah Gaseous Diffusion Plant (GDP) that advances America's national security interests, protects taxpayers, and provides benefits for TVA and the Bonneville

  18. Transport and biogeochemical reaction of metals in a physically and chemically heterogeneous aquifer

    SciTech Connect (OSTI)

    Scheibe, Timothy D.; Fang, Yilin; Murray, Christopher J; Roden, Eric E; Chen, Jinsong; Chien, Yi-Ju; Brooks, Scott C; Hubbard, Susan S

    2006-01-01

    Biologically mediated reductive dissolution and precipitation of metals and radionuclides play key roles in their subsurface transport. Physical and chemical properties of natural aquifer systems, such as reactive iron-oxide surface area and hydraulic conductivity, are often highly heterogeneous in complex ways that can exert significant control on transport, natural attenuation, and active remediation processes. Typically, however, few data on the detailed distribution of these properties are available for incorporation into predictive models. In this study, we integrate field-scale geophysical, hydrologic, and geochemical data from a well-characterized site with the results of laboratory batch-reaction studies to formulate two-dimensional numerical models of reactive transport in a heterogeneous granular aquifer. The models incorporate several levels of coupling, including effects of ferrous iron sorption onto (and associated reduction of reactive surface area of) ferric iron surfaces, microbial growth and transport dynamics, and cross-correlation between hydraulic conductivity and initial ferric iron surface area. These models are then used to evaluate the impacts of physical and chemical heterogeneity on transport of trace levels of uranium under natural conditions, as well as the effectiveness of uranium reduction and immobilization upon introduction of a soluble electron donor (a potential biostimulation remedial strategy).

  19. Transport and biogeochemical reaction of metals in a physically and chemically heterogeneous aquifer

    SciTech Connect (OSTI)

    Scheibe, Timothy D.; Fang, Yilin; Murray, Christopher J.; Roden, Eric E.; Chen, Jinsong; Chien, Yi-Ju; Brooks, Scott C.; Hubbard, Susan S.

    2006-06-01

    Biologically-mediated reductive dissolution and precipitation of metals and radionuclides plays a key role in their subsurface transport. Physical and chemical properties of natural aquifer systems, such as reactive iron oxide surface area and hydraulic conductivity, are often highly heterogeneous in complex ways that can exert significant control on transport, natural attenuation, and active remediation processes. Typically, however, few data on the detailed distribution of these properties are available for incorporation into predictive models. In this study, we integrate field-scale geophysical, hydrologic, and geochemical data from a well-characterized site with the results of laboratory batch reaction studies to formulate numerical models of reactive transport in a heterogeneous granular aquifer. The models incorporate several levels of coupling, including effects of ferrous iron sorption onto (and associated reduction of reactive surface area of) ferric iron surfaces, microbial growth and transport dynamics, and cross-correlation between hydraulic conductivity and initial ferric iron surface area. These models are then used to evaluate the impacts of physical and chemical heterogeneity on transport of trace levels of uranium under natural conditions, as well as the effectiveness of uranium reduction and immobilization upon introduction of a soluble electron donor (a potential biostimulation remedial strategy).

  20. Alignment of gold nanorods by angular photothermal depletion

    SciTech Connect (OSTI)

    Taylor, Adam B.; Chow, Timothy T. Y.; Chon, James W. M.

    2014-02-24

    In this paper, we demonstrate that a high degree of alignment can be imposed upon randomly oriented gold nanorod films by angular photothermal depletion with linearly polarized laser irradiation. The photothermal reshaping of gold nanorods is observed to follow quadratic melting model rather than the threshold melting model, which distorts the angular and spectral hole created on 2D distribution map of nanorods to be an open crater shape. We have accounted these observations to the alignment procedures and demonstrated good agreement between experiment and simulations. The use of multiple laser depletion wavelengths allowed alignment criteria over a large range of aspect ratios, achieving 80% of the rods in the target angular range. We extend the technique to demonstrate post-alignment in a multilayer of randomly oriented gold nanorod films, with arbitrary control of alignment shown across the layers. Photothermal angular depletion alignment of gold nanorods is a simple, promising post-alignment method for creating future 3D or multilayer plasmonic nanorod based devices and structures.

  1. Accounting for Depletion of Oil and Gas Resources in Malaysia

    SciTech Connect (OSTI)

    Othman, Jamal Jafari, Yaghoob

    2012-12-15

    Since oil and gas are non-renewable resources, it is important to identify the extent to which they have been depleted. Such information will contribute to the formulation and evaluation of appropriate sustainable development policies. This paper provides an assessment of the changes in the availability of oil and gas resources in Malaysia by first compiling the physical balance sheet for the period 2000-2007, and then assessing the monetary balance sheets for the said resource by using the Net Present Value method. Our findings show serious reduction in the value of oil reserves from 2001 to 2005, due to changes in crude oil prices, and thereafter the depletion rates decreased. In the context of sustainable development planning, albeit in the weak sustainability sense, it will be important to ascertain if sufficient reinvestments of the estimated resource rents in related or alternative capitals are being attempted by Malaysia. For the study period, the cumulative resource rents were to the tune of RM61 billion. Through a depletion or resource rents policy, the estimated quantum may guide the identification of a reinvestment threshold (after considering needed capital investment for future development of the industry) in light of ensuring the future productive capacity of the economy at the time when the resource is exhausted.

  2. OrigenArp Primer: How to Perform Isotopic Depletion and Decay Calculations with SCALE/ORIGEN

    SciTech Connect (OSTI)

    Bowman, Stephen M; Gauld, Ian C

    2010-08-01

    The SCALE (Standardized Computer Analyses for Licensing Evaluation) computer software system developed at Oak Ridge National Laboratory is widely used and accepted around the world for nuclear analyses. ORIGEN-ARP is a SCALE isotopic depletion and decay analysis sequence used to perform point-depletion calculations with the well-known ORIGEN-S code using problem-dependent cross sections. Problem-dependent cross-section libraries are generated using the ARP (Automatic Rapid Processing) module using an interpolation algorithm that operates on pre-generated libraries created for a range of fuel properties and operating conditions. Methods are provided in SCALE to generate these libraries using one-, two-, and three-dimensional transport codes. The interpolation of cross sections for uranium-based fuels may be performed for the variables burnup, enrichment, and water density. An option is also available to interpolate cross sections for mixed-oxide (MOX) fuels using the variables burnup, plutonium content, plutonium isotopic vector, and water moderator density. This primer is designed to help a new user understand and use ORIGEN-ARP with the OrigenArp Windows graphical user interface in SCALE. It assumes that the user has a college education in a technical field. There is no assumption of familiarity with nuclear depletion codes in general or with SCALE/ORIGEN-ARP in particular. The primer is based on SCALE 6 but should be applicable to earlier or later versions of SCALE. Information is included to help new users, along with several sample problems that walk the user through the different input forms and menus and illustrate the basic features. References to related documentation are provided. The primer provides a starting point for the nuclear analyst who uses SCALE/ORIGEN-ARP. Complete descriptions are provided in the SCALE documentation. Although the primer is self-contained, it is intended as a companion volume to the SCALE documentation. The SCALE Manual is

  3. Geochemical detection of carbon dioxide in dilute aquifers

    SciTech Connect (OSTI)

    Carroll, S; Hao, Y; Aines, R

    2009-03-27

    Carbon storage in deep saline reservoirs has the potential to lower the amount of CO{sub 2} emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO{sub 2} gas leak into dilute groundwater are important measures for the potential release of CO{sub 2} to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO{sub 2} storage reservoir. Specifically, we address the relationships between CO{sub 2} flux, groundwater flow, detection time and distance. The CO{sub 2} flux ranges from 10{sup 3} to 2 x 10{sup 6} t/yr (0.63 to 1250 t/m{sup 2}/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.

  4. Death Valley Lower Carbonate Aquifer Monitoring Program Wells Down gradient of the Proposed Yucca Mountain Nuclear Waste Repository

    SciTech Connect (OSTI)

    Inyo County

    2006-07-26

    Inyo County has participated in oversight activities associated with the Yucca Mountain Nuclear Waste Repository since 1987. The overall goal of these studies are the evaluation of far-field issues related to potential transport, by ground water, or radionuclides into Inyo County, including Death Valley, and the evaluation of a connection between the Lower Carbonate Aquifer (LCA) and the biosphere. Our oversight and completed Cooperative Agreement research, and a number of other investigators research indicate that there is groundwater flow between the alluvial and carbonate aquifers both at Yucca Mountain and in Inyo County. In addition to the potential of radionuclide transport through the LCA, Czarnecki (1997), with the US Geological Survey, research indicate potential radionuclide transport through the shallower Tertiary-age aquifer materials with ultimate discharge into the Franklin Lake Playa in Inyo County. The specific purpose of this Cooperative Agreement drilling program was to acquire geological, subsurface geology, and hydrologic data to: (1) establish the existence of inter-basin flow between the Amargosa Basin and Death Valley Basin; (2) characterize groundwater flow paths in the LCA through Southern Funeral Mountain Range, and (3) Evaluation the hydraulic connection between the Yucca Mountain repository and the major springs in Death Valley through the LCA.

  5. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    SciTech Connect (OSTI)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F.

    1991-12-01

    The technical feasibility of high-temperature [>100{degrees}C (>212{degrees}F)] aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota`s St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  6. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    SciTech Connect (OSTI)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F. )

    1991-12-01

    The technical feasibility of high-temperature (>100{degrees}C (>212{degrees}F)) aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota's St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  7. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  8. Water geochemistry and hydrogeology of the shallow aquifer at Roosevelt Hot Springs, southern Utah: A hot dry rock prospect

    SciTech Connect (OSTI)

    Vuataz, F.D.; Goff, F.

    1987-12-01

    On the western edge of the geothermal field, three deep holes have been drilled that are very hot but mostly dry. Two of them (Phillips 9-1 and Acord 1-26 wells) have been studied by Los Alamos National Laboratory for the Hot Dry Rock (HDR) resources evaluation program. A review of data and recommendations have been formulated to evaluate the HDR geothermal potential at Roosevelt. The present report is directed toward the study of the shallow aquifer of the Milford Valley to determine if the local groundwater would be suitable for use as make-up water in an HDR system. This investigation is the result of a cooperative agreement between Los Alamos and Phillips Petroleum Co., formerly the main operator of the Roosevelt Hot Springs Unit. The presence of these hot dry wells and the similar setting of the Roosevelt area to the prototype HDR site at Fenton Hill, New Mexico, make Roosevelt a very good candidate site for creation of another HDR geothermal system. This investigation has two main objectives: to assess the water geochemistry of the valley aquifer, to determine possible problems in future make-up water use, such as scaling or corrosion in the wells and surface piping, and to assess the hydrogeology of the shallow groundwaters above the HDR zone, to characterize the physical properties of the aquifer. These two objectives are linked by the fact that the valley aquifer is naturally contaminated by geothermal fluids leaking out of the hydrothermal reservoir. In an arid region where good-quality fresh water is needed for public water supply and irrigation, nonpotable waters would be ideal for an industrial use such as injection into an HDR energy extraction system. 50 refs., 10 figs., 10 tabs.

  9. Development stategy for a mature oil field in Lake Maracaibo, Venezuela - an integrated study in petroleum engineering

    SciTech Connect (OSTI)

    Rondon, L.; Coll, C.; Cordova, P.; Gamero, H.

    1996-12-31

    The results from a 3-D , 3-Phase numerical simulation model of Lower Lagunillas reservoir in Block IV Lake Maracaibo, indicate the possibility of additional recovery from this mature field by drilling infill horizontal wells. The simulation model was the final outcome of an integrated work effort by a team of specialists. The field has produced approximately 920 MMSTB or 43% of OOIP to date and the remaining reserves are estimated to be 270 MMSTB. The reservoir pressure has declined from 4200 psi to 1400 psi, well below the bubble point pressure of 4000 psi. The objectives of an integrated reservoir study were to understand the reservoir heterogeneity and dynamics, evaluate the efficiency of the gas injection started in 1966 and the strength of the active acquifer as pressure support mechanisms. The new model shows the presence of layers with bypassed oil and higher pressures between layers that show greater pressure depletion and high GOR This situation demonstrates the need to formulate a new development strategy for efficiently recovering the remaining reserves. The study indicates that the drilling of horizontal wells or infill deviated wells in some of these layers offers the best solution for maximizing recovery from this reservoir taking full advantage of the reservoir heterogeneity aquifer support and secondary gas cap to optimize well locations.

  10. Development stategy for a mature oil field in Lake Maracaibo, Venezuela - an integrated study in petroleum engineering

    SciTech Connect (OSTI)

    Rondon, L.; Coll, C.; Cordova, P.; Gamero, H. )

    1996-01-01

    The results from a 3-D , 3-Phase numerical simulation model of Lower Lagunillas reservoir in Block IV Lake Maracaibo, indicate the possibility of additional recovery from this mature field by drilling infill horizontal wells. The simulation model was the final outcome of an integrated work effort by a team of specialists. The field has produced approximately 920 MMSTB or 43% of OOIP to date and the remaining reserves are estimated to be 270 MMSTB. The reservoir pressure has declined from 4200 psi to 1400 psi, well below the bubble point pressure of 4000 psi. The objectives of an integrated reservoir study were to understand the reservoir heterogeneity and dynamics, evaluate the efficiency of the gas injection started in 1966 and the strength of the active acquifer as pressure support mechanisms. The new model shows the presence of layers with bypassed oil and higher pressures between layers that show greater pressure depletion and high GOR This situation demonstrates the need to formulate a new development strategy for efficiently recovering the remaining reserves. The study indicates that the drilling of horizontal wells or infill deviated wells in some of these layers offers the best solution for maximizing recovery from this reservoir taking full advantage of the reservoir heterogeneity aquifer support and secondary gas cap to optimize well locations.

  11. Source Term Modeling for Evaluating the Potential Impacts to Groundwater of Fluids Escaping from a Depleted Oil Reservoir Used for Carbon Sequestration

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Brown, Christopher F.

    2014-06-13

    In recent years depleted oil reservoirs have received special interest as carbon storage reservoirs because of their potential to offset costs through collaboration with enhanced oil recovery projects. Modeling is currently being conducted to evaluate potential risks to groundwater associated with leakage of fluids from depleted oil reservoirs used for storage of CO2. Modeling results reported here focused on understanding how toxic organic compounds found in oil will distribute between the various phases within a storage reservoir after introduction of CO2, understanding the migration potential of these compounds, and assessing potential groundwater impacts should leakage occur. Two model scenarios were conducted to evaluate how organic components in oil will distribute among the phases of interest (oil, CO2, and brine). The first case consisted of 50 wt.% oil and 50 wt.% water; the second case was 90 wt.% CO2 and 10 wt.% oil. Several key organic compounds were selected for special attention in this study based upon their occurrence in oil at significant concentrations, relative toxicity, or because they can serve as surrogate compounds for other more highly toxic compounds for which required input data are not available. The organic contaminants of interest (COI) selected for this study were benzene, toluene, naphthalene, phenanthrene, and anthracene. Partitioning of organic compounds between crude oil and supercritical CO2 was modeled using the Peng-Robinson equation of state over temperature and pressure conditions that represent the entire subsurface system (from those relevant to deep geologic carbon storage environments to near surface conditions). Results indicate that for a typical set of oil reservoir conditions (75°C, and 21,520 kPa) negligible amounts of the COI dissolve into the aqueous phase. When CO2 is introduced into the reservoir such that the final composition of the reservoir is 90 wt.% CO2 and 10 wt.% oil, a significant fraction of the oil

  12. Postmidnight depletion of the high-energy tail of the quiet plasmasphere

    DOE PAGES-Beta [OSTI]

    Sarno-Smith, Lois K.; Liemohn, Michael W.; Katus, Roxanne M.; Skoug, Ruth M.; Larsen, Brian A.; Thomsen, Michelle F.; Wygant, John R.; Moldwin, Mark B.

    2015-03-06

    The Van Allen Probes Helium Oxygen Proton Electron (HOPE) instrument measures the high energy tail of the thermal plasmasphere allowing study of topside ionosphere and inner magnetosphere coupling. We statistically analyze a 22 month period of HOPE data, looking at quiet times with a Kp index of less than 3. We investigate the high energy range of the plasmasphere, which consists of ions at energies between 1-10 eV and contains approximately 5% of total plasmaspheric density. Both the fluxes and partial plasma densities over this energy range show H+ is depleted the most in the post-midnight sector (1-4 MLT), followedmore » by O+ and then He+. The relative depletion of each species across the post-midnight sector is not ordered by mass, which reveals ionospheric influence. We compare our results with keV energy electron data from HOPE and the Van Allen Probes Electric Fields and Waves (EFW) instrument spacecraft potential to rule out spacecraft charging. Our conclusion is that the post-midnight ion disappearance is due to diurnal ionospheric temperature variation and charge exchange processes« less

  13. Postmidnight depletion of the high-energy tail of the quiet plasmasphere

    SciTech Connect (OSTI)

    Sarno-Smith, Lois K.; Liemohn, Michael W.; Katus, Roxanne M.; Skoug, Ruth M.; Larsen, Brian A.; Thomsen, Michelle F.; Wygant, John R.; Moldwin, Mark B.

    2015-03-06

    The Van Allen Probes Helium Oxygen Proton Electron (HOPE) instrument measures the high energy tail of the thermal plasmasphere allowing study of topside ionosphere and inner magnetosphere coupling. We statistically analyze a 22 month period of HOPE data, looking at quiet times with a Kp index of less than 3. We investigate the high energy range of the plasmasphere, which consists of ions at energies between 1-10 eV and contains approximately 5% of total plasmaspheric density. Both the fluxes and partial plasma densities over this energy range show H+ is depleted the most in the post-midnight sector (1-4 MLT), followed by O+ and then He+. The relative depletion of each species across the post-midnight sector is not ordered by mass, which reveals ionospheric influence. We compare our results with keV energy electron data from HOPE and the Van Allen Probes Electric Fields and Waves (EFW) instrument spacecraft potential to rule out spacecraft charging. Our conclusion is that the post-midnight ion disappearance is due to diurnal ionospheric temperature variation and charge exchange processes

  14. Accelerated Depletion: Assessing Its Impacts on Domestic Oil and Natural Gas Prices and Production

    Reports and Publications

    2000-01-01

    Analysis of the potential impacts of accelerated depletion on domestic oil and natural gas prices and production.

  15. Design and Implementation of a C02 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells in a Shallow Shelf Carbonate Approaching Waterflood Depletion

    SciTech Connect (OSTI)

    1997-08-01

    The objective is to utilize reservoir characteristics and advanced technologies to optimize the design of a carbon dioxide (CO2) project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. Also the project seeks to demonstrate the performance and economic viability of the project in the field.

  16. Inhibition of lytic infection of pseudorabies virus by arginine depletion

    SciTech Connect (OSTI)

    Wang, H.-C. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Kao, Y.-C. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Chang, T-J. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Wong, M.-L. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China)]. E-mail: mlwong@dragon.nchu.edu.tw

    2005-08-26

    Pseudorabies virus (PRV) is a member of Alphahepesviruses; it is an enveloped virus with a double-stranded DNA genome. Polyamines (such as spermine and spermidine) are ubiquitous in animal cells and participate in cellular proliferation and differentiation. Previous results of our laboratory showed that the PRV can accomplish lytic infection either in the presence of exogenous spermine (or spermidine) or depletion of cellular polyamines. The amino acid arginine is a precursor of polyamine biosynthesis. In this work, we investigated the role of arginine in PRV infection. It was found that the plaque formation of PRV was inhibited by arginase (enzyme catalyzing the conversion of arginine into ornithine and urea) treatment whereas this inhibition can be reversed by exogenous arginine, suggesting that arginine is essential for PRV proliferation. Western blotting was conducted to study the effect of arginine depletion on the levels of structural proteins of PRV in virus-infected cells. Four PRV structural proteins (gB, gE, UL47, and UL48) were chosen for examination, and results revealed that the levels of viral proteins were obviously reduced in long time arginase treatment. However, the overall protein synthesis machinery was apparently not influenced by arginase treatment either in mock or PRV-infected cells. Analyzing with native gel, we found that arginase treatment affected the mobility of PRV structural proteins, suggesting the conformational change of viral proteins by arginine depletion. Heat shock proteins, acting as molecular chaperons, participate in protein folding and translocation. Our results demonstrated that long time arginase treatment could reduce the expression of cellular heat shock proteins 70 (hsc70 and hsp70), and transcriptional suppression of heat shock protein 70 gene promoter was one of the mechanisms involved in this reduced expression.

  17. Depleted uranium storage and disposal trade study: Summary report

    SciTech Connect (OSTI)

    Hightower, J.R.; Trabalka, J.R.

    2000-02-01

    The objectives of this study were to: identify the most desirable forms for conversion of depleted uranium hexafluoride (DUF6) for extended storage, identify the most desirable forms for conversion of DUF6 for disposal, evaluate the comparative costs for extended storage or disposal of the various forms, review benefits of the proposed plasma conversion process, estimate simplified life-cycle costs (LCCs) for five scenarios that entail either disposal or beneficial reuse, and determine whether an overall optimal form for conversion of DUF6 can be selected given current uncertainty about the endpoints (specific disposal site/technology or reuse options).

  18. Aquifer thermal energy storage reference manual: seasonal thermal energy storage program

    SciTech Connect (OSTI)

    Prater, L.S.

    1980-01-01

    This is the reference manual of the Seasonal Thermal Energy Storage (STES) Program, and is the primary document for the transfer of technical information of the STES Program. It has been issued in preliminary form and will be updated periodically to include more technical data and results of research. As the program progresses and new technical data become available, sections of the manual will be revised to incorporate these data. This primary document contains summaries of: the TRW, incorporated demonstration project at Behtel, Alaska, Dames and Moore demonstration project at Stony Brook, New York, and the University of Minnesota demonstration project at Minneapolis-St. Paul, Minnesota; the technical support programs including legal/institutional assessment; economic assessment; environmental assessment; field test facilities; a compendia of existing information; numerical simulation; and non-aquifer STES concepts. (LCL)

  19. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric open aquifer and closed aquifer approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with open and/or closed approaches) and through flow modeling. These examples show that the open aquifer CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the closed aquifer estimates are a closer approximation to the flow-model derived capacity. An analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the closed aquifer approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.

  20. Geophysical Monitoring of Ground Surface Deformation Associated with a Confined Aquifer Storage and Recovery Operation

    DOE PAGES-Beta [OSTI]

    Bonneville, Alain; Heggy, Essam; Strickland, Christopher E.; Normand, Jonathan; Dermond, Jeffrey A.; Fang, Yilin; Sullivan, E. C.

    2015-08-11

    A main issue in the storage of large volumes of fluids, mainly water and CO2, in the deep subsurface is to determine their field-scale-induced displacements and consequences on the mechanical behavior of the storage reservoir and surroundings. A quantifiable estimation of displacement can be made by combining the robust, cost-effective, and repeatable geophysical techniques of micro-gravimetry, differential global positioning system (DGPS), and differential synthetic aperture radar interferometry (DInSAR). These techniques were field tested and evaluated in an active large-volume aquifer storage and recovery (ASR) project in Pendleton, Oregon, USA, where three ASR wells are injecting up to 1.9 million m3/yr-1more » into basalt aquifers to a depth of about 150 m. Injection and recovery of water at the wells was accompanied by significant gravity anomalies and vertical deformation of the ground surface localized to the immediate surroundings of the injection wells as evidenced by DGPS and gravity measurements collected in 2011. At a larger scale, and between 2011 and 2013, DInSAR monitoring of the Pendleton area suggests the occurrence of sub-centimetric deformation in the western part of the city and close to the injection locations associated with the ASR cycle. A numerical simulation of the effect of the water injection gives results in good agreement with the observations and confirms the validity of the approach, which could be deployed in similar geological contexts to look at the mechanical effects of water and gas injections. The gravity signal reflects deep phenomena and gives additional insight into the repartition of fluids in the subsurface.« less

  1. Geophysical Monitoring of Ground Surface Deformation Associated with a Confined Aquifer Storage and Recovery Operation

    SciTech Connect (OSTI)

    Bonneville, Alain; Heggy, Essam; Strickland, Christopher E.; Normand, Jonathan; Dermond, Jeffrey A.; Fang, Yilin; Sullivan, E. C.

    2015-08-11

    A main issue in the storage of large volumes of fluids, mainly water and CO2, in the deep subsurface is to determine their field-scale-induced displacements and consequences on the mechanical behavior of the storage reservoir and surroundings. A quantifiable estimation of displacement can be made by combining the robust, cost-effective, and repeatable geophysical techniques of micro-gravimetry, differential global positioning system (DGPS), and differential synthetic aperture radar interferometry (DInSAR). These techniques were field tested and evaluated in an active large-volume aquifer storage and recovery (ASR) project in Pendleton, Oregon, USA, where three ASR wells are injecting up to 1.9 million m3/yr-1 into basalt aquifers to a depth of about 150 m. Injection and recovery of water at the wells was accompanied by significant gravity anomalies and vertical deformation of the ground surface localized to the immediate surroundings of the injection wells as evidenced by DGPS and gravity measurements collected in 2011. At a larger scale, and between 2011 and 2013, DInSAR monitoring of the Pendleton area suggests the occurrence of sub-centimetric deformation in the western part of the city and close to the injection locations associated with the ASR cycle. A numerical simulation of the effect of the water injection gives results in good agreement with the observations and confirms the validity of the approach, which could be deployed in similar geological contexts to look at the mechanical effects of water and gas injections. The gravity signal reflects deep phenomena and gives additional insight into the repartition of fluids in the subsurface.

  2. Stormwater runoff policy on the Spokane/Rathdrum Prairie Aquifer

    SciTech Connect (OSTI)

    Hale, E.O.

    1990-01-01

    The Panhandle Health District, in conjunction with the Idaho Department of Water Resources, is developing a stormwater runoff control program under the US EPA Wellhead Protection Program. The goal of the project is to protect the Spokane Valley/Rathdrum Prairie Aquifer from widespread subsurface disposal of stormwater runoff via shallow injection wells. Studies conducted by the health district in 1976 and 1977 established that areas downgradient from urban land uses had elevated nitrate level sand that the aquifer is vulnerable to contamination from surface activities. The stormwater runoff controls are being developed in conjunction with similar programs, such as chemical storage and use, solid waste and subsurface sewage disposal. The expected result will be a groundwater management system that protects the resource by preventing contamination rather than a program that responds to poor water quality with costly remedial action.

  3. Including environmental concerns in management strategies for depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Goldberg, M.; Avci, H.I.; Bradley, C.E.

    1995-12-31

    One of the major programs within the Office of Nuclear Energy, Science, and Technology of the US Department of Energy (DOE) is the depleted uranium hexafluoride (DUF{sub 6}) management program. The program is intended to find a long-term management strategy for the DUF{sub 6} that is currently stored in approximately 46,400 cylinders at Paducah, KY; Portsmouth, OH; and Oak Ridge, TN, USA. The program has four major components: technology assessment, engineering analysis, cost analysis, and the environmental impact statement (EIS). From the beginning of the program, the DOE has incorporated the environmental considerations into the process of strategy selection. Currently, the DOE has no preferred alternative. The results of the environmental impacts assessment from the EIS, as well as the results from the other components of the program, will be factored into the strategy selection process. In addition to the DOE`s current management plan, other alternatives continued storage, reuse, or disposal of depleted uranium, will be considered in the EIS. The EIS is expected to be completed and issued in its final form in the fall of 1997.

  4. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  5. VERA Core Simulator Methodology for PWR Cycle Depletion

    SciTech Connect (OSTI)

    Kochunas, Brendan; Collins, Benjamin S; Jabaay, Daniel; Kim, Kang Seog; Graham, Aaron; Stimpson, Shane; Wieselquist, William A; Clarno, Kevin T; Palmtag, Scott; Downar, Thomas; Gehin, Jess C

    2015-01-01

    This paper describes the methodology developed and implemented in MPACT for performing high-fidelity pressurized water reactor (PWR) multi-cycle core physics calculations. MPACT is being developed primarily for application within the Consortium for the Advanced Simulation of Light Water Reactors (CASL) as one of the main components of the VERA Core Simulator, the others being COBRA-TF and ORIGEN. The methods summarized in this paper include a methodology for performing resonance self-shielding and computing macroscopic cross sections, 2-D/1-D transport, nuclide depletion, thermal-hydraulic feedback, and other supporting methods. These methods represent a minimal set needed to simulate high-fidelity models of a realistic nuclear reactor. Results demonstrating this are presented from the simulation of a realistic model of the first cycle of Watts Bar Unit 1. The simulation, which approximates the cycle operation, is observed to be within 50 ppm boron (ppmB) reactivity for all simulated points in the cycle and approximately 15 ppmB for a consistent statepoint. The verification and validation of the PWR cycle depletion capability in MPACT is the focus of two companion papers.

  6. Relationship of regional water quality to aquifer thermal energy storage

    SciTech Connect (OSTI)

    Allen, R.D.

    1983-11-01

    Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to counter these potential geochemical and lithologic problems were also identified through the literature search. Regional hydrology summaries and other sources were used in reviewing aquifers of 19 drainage regions in the US to determine generic geochemical characteristics for analysis. Numerical modeling techniques were used to perform geochemical analyses of water quality from 67 selected aquifers. Candidate water resources regions were then identified for exploration and development of ATES. This study identified six principal mechanisms by which ATES reservoir permeability may be impaired: (1) particulate plugging, (2) chemical precipitation, (3) liquid-solid reactions, (4) formation disaggregation, (5) oxidation reactions, and (6) biological activity. Specific proven countermeasures to reduce or eliminate these effects were found. Of the hydrologic regions reviewed, 10 were identified as having the characteristics necessary for ATES development: (1) Mid-Atlantic, (2) South-Atlantic Gulf, (3) Ohio, (4) Upper Mississippi, (5) Lower Mississippi, (6) Souris-Red-Rainy, (7) Missouri Basin, (8) Arkansas-White-Red, (9) Texas-Gulf, and (10) California.

  7. Draft Supplement Analysis for Location(s) to Dispose of Depleted Uranium Oxide Conversion Product Generated from DOE'S Inventory of Depleted Uranium Hexafluoride

    Office of Environmental Management (EM)

    DRAFT SUPPLEMENT ANALYSIS FOR LOCATION(S) TO DISPOSE OF DEPLETED URANIUM OXIDE CONVERSION PRODUCT GENERATED FROM DOE'S INVENTORY OF DEPLETED URANIUM HEXAFLUORIDE (DOE/EIS-0359-SA1 AND DOE/EIS-0360-SA1) March 2007 March 2007 i CONTENTS NOTATION........................................................................................................................... iv 1 INTRODUCTION AND BACKGROUND ................................................................. 1 1.1 Why DOE Has Prepared This

  8. Ground-Water Table and Chemical Changes in an Alluvial Aquifer During

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells | Department of Energy Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the

  9. Preliminary potentiometric map and flow dynamic characteristics for the upper-basalt confined aquifer system

    SciTech Connect (OSTI)

    Spane, F.A. Jr.; Raymond, R.G.

    1993-09-01

    This report presents the first comprehensive Hanford Site-wide potentiometric map for the upper-basalt confined aquifer system (i.e., the upper Saddle Mountains Basalt). In constructing the potentiometric map, over forty on-site and off-site monitoring wells and boreholes were used. The potentiometric map developed for the upper-basalt confined aquifer is consistent with the areal head pattern indicated for the Mabton interbed, which is a deeper and more areally extensive confined aquifer underlying the Hanford Site. Salient features for the upper-basalt confined aquifer system potentiometric map are described.

  10. Investigation of breached depleted UF{sub 6} cylinders

    SciTech Connect (OSTI)

    Barber, E.J.; Butler, T.R.; DeVan, J.H.; Googin, J.M.; Taylor, M.S.; Dyer, R.H.; Russell, J.R.

    1991-09-01

    In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton steel cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. Both holes, concealed by UF{sub 4} reaction products identical in color to the cylinder coating, were similarly located near the front stiffening ring. The UF{sub 4} appeared to have self-sealed the holes, thus containing nearly all of the uranium contents. Martin Marietta Energy Systems, Inc., Vice President K.W. Sommerfeld immediately formed an investigation team to: (1) identify the most likely cause of failure for the two breached cylinders, (2) determine the impact of these incidents on the three-site inventory, and (3) provide recommendations and preventive measures. This document discusses the results of this investigation.

  11. Investigation of breached depleted UF sub 6 cylinders

    SciTech Connect (OSTI)

    Barber, E.J.; Butler, T.R.; DeVan, J.H.; Googin, J.M.; Taylor, M.S.; Dyer, R.H.; Russell, J.R.

    1991-09-01

    In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton steel cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. Both holes, concealed by UF{sub 4} reaction products identical in color to the cylinder coating, were similarly located near the front stiffening ring. The UF{sub 4} appeared to have self-sealed the holes, thus containing nearly all of the uranium contents. Martin Marietta Energy Systems, Inc., Vice President K.W. Sommerfeld immediately formed an investigation team to: (1) identify the most likely cause of failure for the two breached cylinders, (2) determine the impact of these incidents on the three-site inventory, and (3) provide recommendations and preventive measures. This document discusses the results of this investigation.

  12. Enterprise Assessments Targeted Review of the Paducah Depleted Uranium Hexafluoride Conversion Facility Fire Protection Program – September 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    Targeted Review of the Fire Protection Program at the Paducah Depleted Uranium Hexafluoride Conversion Facility

  13. Potential Risks of Freshwater Aquifer Contamination with Geosequestration

    SciTech Connect (OSTI)

    Jackson, Robert

    2013-09-30

    Substantial leakage of CO{sub 2} from deep geological strata to shallow potable aquifers is likely to be rare, but chemical detection of potential leakage nonetheless remains an integral component of any safe carbon capture and storage system. CO{sub 2} that infiltrates an unconfined freshwater aquifer will have an immediate impact on water chemistry by lowering pH in most cases and by altering the concentration of total dissolved solids. Chemical signatures in affected waters provide an important opportunity for early detection of leaks. In the presence of CO{sub 2}, trace elements such as Mn, Fe, and Ca can increase by an order of magnitude or more above control concentrations within 100 days. Therefore, these and other elements should be monitored along with pH as geochemical markers of potential CO{sub 2} leaks. Dissolved inorganic carbon and alkalinity can also be rapidly responsive to CO{sub 2} and are stable indicators of a leak. Importantly, such changes may be detectable long before direct changes in CO{sub 2} are observed. The experimental results also suggest that the relative severity of the impact of leaks on overlying drinking-water aquifers should be considered in the selection of CO{sub 2} sequestration sites. One primary selection criteria should be metal and metalloid availability, such as uranium and arsenic abundance, to carefully monitor chemical species that could trigger changes above maximum contaminant levels (MCLs). Overall, the risks of leakage from underground CO{sub 2} storage are real but appear to be manageable if systems are closely monitored.

  14. Appendix B Surface Infiltration and Aquifer Test Data

    Office of Legacy Management (LM)

    B Surface Infiltration and Aquifer Test Data This page intentionally left blank Infiltration Tests This page intentionally left blank 0 50 100 150 200 250 300 350 400 450 TIME (MIN) 200 250 TIME (MIN) 0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 TIME (MIN) zoo 800 1000 TIME (MIN) 0 150 300 450 600 750 , 900 1050 1200 1350 1500 1650 1800 TIME (MIN) TIME (MIN) 0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 TIME (MIN) INF-8 TEST I 300 400 TIME (MIN) INF-8 TEST 2 200 250

  15. DOE Issues Final Request for Proposal for the Operation of Depleted...

    Energy.gov (indexed) [DOE]

    (RFP), for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities ... inventory at Paducah and Portsmouth to uranium oxide at design throughput of the ...

  16. EIS-0329: Proposed Construction, Operation, Decontamination/Decommissioning of Depleted Uranium Hexafluoride Conversion Facilities

    Energy.gov [DOE]

    This EIS analyzes DOE's proposal to construct, operate, maintain, and decontaminate and decommission two depleted uranium hexafluoride (DUF 6) conversion facilities, at Portsmouth, Ohio, and Paducah, Kentucky.

  17. Top-gate organic depletion and inversion transistors with doped channel and injection contact

    SciTech Connect (OSTI)

    Liu, Xuhai; Kasemann, Daniel Leo, Karl

    2015-03-09

    Organic field-effect transistors constitute a vibrant research field and open application perspectives in flexible electronics. For a commercial breakthrough, however, significant performance improvements are still needed, e.g., stable and high charge carrier mobility and on-off ratio, tunable threshold voltage, as well as integrability criteria such as n- and p-channel operation and top-gate architecture. Here, we show pentacene-based top-gate organic transistors operated in depletion and inversion regimes, realized by doping source and drain contacts as well as a thin layer of the transistor channel. By varying the doping concentration and the thickness of the doped channel, we control the position of the threshold voltage without degrading on-off ratio or mobility. Capacitance-voltage measurements show that an inversion channel can indeed be formed, e.g., an n-doped channel can be inverted to a p-type inversion channel with highly p-doped contacts. The Cytop polymer dielectric minimizes hysteresis, and the transistors can be biased for prolonged cycles without a shift of threshold voltage, indicating excellent operation stability.

  18. A ground state depleted laser in neodymium doped yttrium orthosilicate

    SciTech Connect (OSTI)

    Beach, R.; Albrecht, G.; Solarz, R.; Krupke, W.; Comaskey, B.; Mitchell, S.; Brandle, C.; Berkstresser, G.

    1990-01-16

    A ground state depleted (GSD){sup 1,2} laser has been demonstrated in the form of a Q-switched oscillator operating at 912 nm. Using Nd{sup 3+} as the active ion and Y{sub 2}SiO{sub 5} as the host material, the laser transition is from the lowest lying stark level of the Nd{sup 3t}F{sub 3/2} level to a stark level 355 cm{sup {minus}1} above the lowest lying one in the {sup 4}I{sub 9/2} manifold. The necessity of depleting the ground {sup 4}I{sub 9/2} manifold is evident for this level scheme as transparency requires a 10% inversion. To achieve the high excitation levels required for the efficient operation of this laser, bleach wave pumping using an alexandrite laser at 745 nm has been employed. The existence of a large absorption feature at 810 nm also allows for the possibility of AlGaAs laser diode pumping. Using KNbO{sub 3}, noncritical phase matching is possible at 140{degree}C using d{sub 32} and has been demonstrated. The results of Q-switched laser performance and harmonic generation in KNbO{sub 3} will be presented. Orthosilicate can be grown in large boules of excellent optical quality using a Czochralski technique. Because of the relatively small 912 nm emission cross section of 2-3 {times} 10{sup {minus}20} cm{sup 2} (orientation dependent) fluences of 10-20 J/cm{sup 2} must be circulated in the laser cavity for the efficient extraction of stored energy. This necessitates very aggressive laser damage thresholds. Results from the Reptile laser damage facility at Lawrence Livermore National Laboratory (LLNL) will be presented showing Y{sub 2}SiO{sub 5} bulk and AR sol-gel coated surface damage thresholds of greater than 40 J/cm{sup 2} for 10 nsec, 10 Hz, 1.06 {mu} pulses. 16 refs., 18 figs., 6 tabs.

  19. Application of thermal depletion model to geothermal reservoirs...

    Open Energy Information (Open El) [EERE & EIA]

    method are presented, and possible application to the Salton Sea Geothermal Field, the Raft River System, and to reinjection of supersaturated fluids is discussed. Authors...

  20. Effects of surfactants on the desorption of organic contaminants from aquifer materials. Doctoral thesis

    SciTech Connect (OSTI)

    Brickell, J.L.

    1989-08-01

    The efficiency of removing organic contaminants from groundwater aquifers by the pump and treat process is adversely affected by the retardation of the contaminant's mobility due to adsorption onto aquifer material. The use of surfactants in conjunction with the pump and treat process has the potential for improving contaminant mobility by solubilizing the adsorbed contaminant.

  1. Regional assessment of aquifers for thermal-energy storage. Volume 2. Regions 7 through 12

    SciTech Connect (OSTI)

    Not Available

    1981-06-01

    This volume contains information on the geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the following regions of the US: Unglaciated Central Region; Glaciated Appalachians, Unglaciated Appalachians; Coastal Plain; Hawaii; and Alaska. (LCL)

  2. Regional assessment of aquifers for thermal energy storage. Volume 1. Regions 1 through 6

    SciTech Connect (OSTI)

    Not Available

    1981-06-01

    This volume contains information on the geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the following regions of the US: the Western Mountains; Alluvial Basins; Columbia LAVA Plateau; Colorado Plateau; High Plains; and Glaciated Central Region. (LCL)

  3. Using complex resistivity imaging to infer biogeochemical processes associated with bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Orozco, A. Flores; Williams, K.H.; Long, P.E.; Hubbard, S.S.; Kemna, A.

    2011-04-01

    Experiments at the Department of Energy's Rifle Integrated Field Research Challenge (IFRC) site near Rifle, Colorado (USA) have demonstrated the ability to remove uranium from groundwater by stimulating the growth and activity of Geobacter species through acetate amendment. Prolonging the activity of these strains in order to optimize uranium bioremediation has prompted the development of minimally-invasive and spatially-extensive monitoring methods diagnostic of their in situ activity and the end products of their metabolism. Here we demonstrate the use of complex resistivity imaging for monitoring biogeochemical changes accompanying stimulation of indigenous aquifer microorganisms during and after a prolonged period (100+ days) of acetate injection. A thorough raw-data statistical analysis of discrepancies between normal and reciprocal measurements and incorporation of a new power-law phase-error model in the inversion were used to significantly improve the quality of the resistivity phase images over those obtained during previous monitoring experiments at the Rifle IRFC site. The imaging results reveal spatiotemporal changes in the phase response of aquifer sediments, which correlate with increases in Fe(II) and precipitation of metal sulfides (e.g., FeS) following the iterative stimulation of iron and sulfate reducing microorganism. Only modest changes in resistivity magnitude were observed over the monitoring period. The largest phase anomalies (>40 mrad) were observed hundreds of days after halting acetate injection, in conjunction with accumulation of Fe(II) in the presence of residual FeS minerals, reflecting preservation of geochemically reduced conditions in the aquifer - a prerequisite for ensuring the long-term stability of immobilized, redox-sensitive contaminants, such as uranium.

  4. Using complex resistivity imaging to infer biogeochemical processes associated with bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Flores-Orozco, Adrian; Williams, Kenneth H.; Long, Philip E.; Hubbard, Susan S.; Kemna, Andreas

    2011-07-07

    Experiments at the Department of Energys Rifle Integrated Field Research Challenge (IFRC) site near Rifle, Colorado (USA) have demonstrated the ability to remove uranium from groundwater by stimulating the growth and activity of Geobacter species through acetate amendment. Prolonging the activity of these strains in order to optimize uranium bioremediation has prompted the development of minimally-invasive and spatially-extensive monitoring methods diagnostic of their in situ activity and the end products of their metabolism. Here we demonstrate the use of complex resistivity imaging for monitoring biogeochemical changes accompanying stimulation of indigenous aquifer microorganisms during and after a prolonged period (100+ days) of acetate injection. A thorough raw-data statistical analysis of discrepancies between normal and reciprocal measurements and incorporation of a new power-law phase-error model in the inversion were used to significantly improve the quality of the resistivity phase images over those obtained during previous monitoring experiments at the Rifle IRFC site. The imaging results reveal spatiotemporal changes in the phase response of aquifer sediments, which correlate with increases in Fe(II) and precipitation of metal sulfides (e.g., FeS) following the iterative stimulation of iron and sulfate reducing microorganism. Only modest changes in resistivity magnitude were observed over the monitoring period. The largest phase anomalies (>40 mrad) were observed hundreds of days after halting acetate injection, in conjunction with accumulation of Fe(II) in the presence of residual FeS minerals, reflecting preservation of geochemically reduced conditions in the aquifer a prerequisite for ensuring the long-term stability of immobilized, redox-sensitive contaminants, such as uranium.

  5. Investigation of breached depleted UF{sub 6} cylinders

    SciTech Connect (OSTI)

    DeVan, J.H.

    1991-12-31

    In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. An investigation team was immediately formed to determine the cause of the failures and their impact on future storage procedures and to recommend corrective actions. Subsequent investigation showed that the failures most probably resulted from mechanical damage that occurred at the time that the cylinders had been placed in the storage yard. In both cylinders evidence pointed to the impact of a lifting lug of an adjacent cylinder near the front stiffening ring, where deflection of the cylinder could occur only by tearing the cylinder. The impacts appear to have punctured the cylinders and thereby set up corrosion processes that greatly extended the openings in the wall and obliterated the original crack. Fortunately, the reaction products formed by this process were relatively protective and prevented any large-scale loss of uranium. The main factors that precipitated the failures were inadequate spacing between cylinders and deviations in the orientations of lifting lugs from their intended horizontal position. After reviewing the causes and effects of the failures, the team`s principal recommendation for remedial action concerned improved cylinder handling and inspection procedures. Design modifications and supplementary mechanical tests were also recommended to improve the cylinder containment integrity during the stacking operation.

  6. Kr Ion Irradiation Study of the Depleted-Uranium Alloys

    SciTech Connect (OSTI)

    J. Gan; D. Keiser; B. Miller; M. Kirk; J. Rest; T. Allen; D. Wachs

    2010-12-01

    Fuel development for the Reduced Enrichment Research and Test Reactor program is tasked with the development of new low-enriched uranium nuclear fuels that can be employed to replace existing highly enriched uranium fuels currently used in some research reactors throughout the world. For dispersion-type fuels, radiation stability of the fuel/cladding interaction product has a strong impact on fuel performance. Three depleted uranium alloys are cast for the radiation stability studies of the fuel/cladding interaction product using Kr ion irradiation to investigate radiation damage from fission products. SEM analysis indicates the presence of the phases of interest: U(Si, Al)3, (U, Mo)(Si, Al)3, UMo2Al20, U6Mo4Al43, and UAl4. Irradiations of TEM disc samples were conducted with 500 keV Kr ions at 200C to ion doses up to 2.5 1015 ions/cm2 (~ 10 dpa) with an Kr ion flux of 1012 ions/cm2-sec (~ 4.0 10-3 dpa/sec). Microstructural evolution of the phases relevant to fuel-cladding interaction products was investigated using transmission electron microscopy.

  7. Neutronic and depletion analysis of the Pb-AHTR

    SciTech Connect (OSTI)

    Fratoni, Massimiliano; Greenspan, Ehud; Peterson, Per F.

    2007-07-01

    The PB-AHTR is a Pebble Bed Advanced High Temperature Reactor that is cooled with the liquid salt flibe (LiF-BeF{sub 2}) rather than helium. This study presents a preliminary neutronic and depletion analysis for the PBAHTR. The attainable burnup is determined as a function of uranium loading per pebble, power density and core dimensions. It is found that the optimal design for a 425 {mu}m UC{sub 0.5}O{sub 1.5} fuel kernel diameter, 10% enriched uranium, features a graphite-to-heavy metal ratio of {approx}360 and its reactivity coefficients are all negative. A comparison with the helium-cooled pebble-bed reactor and with a prismatic-fuel reactor that is cooled with either flibe or helium is also presented. It is found that the PB-AHTR offers similar discharge burnup as the other three designs. As compared to the gas-cooled pebble bed, the PB-AHTR uranium loading and energy generated per pebble are {approx}2.5 times higher. (authors)

  8. Design and Implementation of a CO(2) Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells in Shallow Shelf Carbonate Approaching Waterflood Depletion

    SciTech Connect (OSTI)

    Harpole, K.J.; Dollens, K.B.; Durrett, E.G.; Bles, J.S

    1997-10-31

    The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide (CO) project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. All work this quarter falls within the demonstration project.

  9. Depletion at Solid-Liquid Interfaces under Shear: Flowing Hexadecane on Functionalized Surfaces

    SciTech Connect (OSTI)

    Guttfreund, Philipp; Wolff, Max; Maccarini, Marco; Gerth, Stefan; Ankner, John Francis; Browning, Jim; Halbert, Candice E; Wacklin, Hanna; Zabel, Hartmut

    2011-01-01

    We present a neutron reflectivity study on the interface of flowing hexadecane, which is known to exhibit surface slip on functionalized solid surfaces. The single crystalline silicon substrates are either chemically cleaned or covered by octadecyl-trichlorosilane (OTS) which result in different interfacial energies in respect to hexadecane. The liquid is in situ sheared and the reflectivities are compared to the static case. Moreover, the temperature dependence is recorded. For both types of interface, density depleted layers are observed, but shear affects them differently. Whereas at the attractive surface the depletion is enhanced by shear, the low interfacial energy leads to a diminishment of the depleted layer when applying shear. This systematic change of the depletion layer indicates different structural rearrangements under shear load. Finally, the possible link of the depletion layer with surface slip is discussed.

  10. Metallothionein deficiency aggravates depleted uranium-induced nephrotoxicity

    SciTech Connect (OSTI)

    Hao, Yuhui; Huang, Jiawei; Gu, Ying; Liu, Cong; Li, Hong; Liu, Jing; Ren, Jiong; Yang, Zhangyou; Peng, Shuangqing; Wang, Weidong; Li, Rong

    2015-09-15

    Depleted uranium (DU) has been widely used in both civilian and military activities, and the kidney is the main target organ of DU during acute high-dose exposures. In this study, the nephrotoxicity caused by DU in metallothionein-1/2-null mice (MT −/−) and corresponding wild-type (MT +/+) mice was investigated to determine any associations with MT. Each MT −/− or MT +/+ mouse was pretreated with a single dose of DU (10 mg/kg, intraperitoneal injection) or an equivalent volume of saline. After 4 days of DU administration, kidney changes were assessed. After DU exposure, serum creatinine and serum urea nitrogen in MT −/− mice significantly increased than in MT +/+ mice, with more severe kidney pathological damage. Moreover, catalase and superoxide dismutase (SOD) decreased, and generation of reactive oxygen species and malondialdehyde increased in MT −/− mice. The apoptosis rate in MT −/− mice significantly increased, with a significant increase in both Bax and caspase 3 and a decrease in Bcl-2. Furthermore, sodium-glucose cotransporter (SGLT) and sodium-phosphate cotransporter (NaPi-II) were significantly reduced after DU exposure, and the change of SGLT was more evident in MT −/− mice. Finally, exogenous MT was used to evaluate the correlation between kidney changes induced by DU and MT doses in MT −/− mice. The results showed that, the pathological damage and cell apoptosis decreased, and SOD and SGLT levels increased with increasing dose of MT. In conclusion, MT deficiency aggravated DU-induced nephrotoxicity, and the molecular mechanisms appeared to be related to the increased oxidative stress and apoptosis, and decreased SGLT expression. - Highlights: • MT −/− and MT +/+ mice were used to evaluate nephrotoxicity of DU. • Renal damage was more evident in the MT −/− mice after exposure to DU. • Exogenous MT also protects against DU-induced nephrotoxicity. • MT deficiency induced more ROS and apoptosis after exposure to

  11. Dupoly process for treatment of depleted uranium and production of beneficial end products

    SciTech Connect (OSTI)

    Kalb, Paul D.; Adams, Jay W.; Lageraaen, Paul R.; Cooley, Carl R.

    2000-02-29

    The present invention provides a process of encapsulating depleted uranium by forming a homogenous mixture of depleted uranium and molten virgin or recycled thermoplastic polymer into desired shapes. Separate streams of depleted uranium and virgin or recycled thermoplastic polymer are simultaneously subjected to heating and mixing conditions. The heating and mixing conditions are provided by a thermokinetic mixer, continuous mixer or an extruder and preferably by a thermokinetic mixer or continuous mixer followed by an extruder. The resulting DUPoly shapes can be molded into radiation shielding material or can be used as counter weights for use in airplanes, helicopters, ships, missiles, armor or projectiles.

  12. Evaluating Impacts of CO2 Intrusion into an Unconsolidated Aquifer: II. Modeling Results

    SciTech Connect (OSTI)

    Zheng, Liange; Qafoku, Nikolla; Lawter, Amanda R.; Wang, Guohui; Shao, Hongbo; Brown, Christopher F.

    2015-08-04

    Large scale deployment of CO2 geological sequestration requires the assessment of the risks. One of the potential risks is the impact of CO2 leakage on shallow groundwater overlying the sequestration site.The understanding of the key chemical processes and parameters are critical for building numerical models for risk assessment. Model interpretation of laboratory and field tests is an effective way to enhance such understanding. Column experiments in which CO2 charged synthetic groundwater flowed through a column packed with material from High Plains aquifer was conducted and concentration of several constituents in the effluent water was analyzed. In this paper, reactive transport model was developed to interpret the observed concentration changes, attempting to shed light on the chemical reactions and key parameters that control the concentration changes of these constituents. The reactive transport model catches the concentration changes of pH, Ca, Mg, Ba, Sr, Cs, As and Pb fairly well. Calcite dissolution and Ca-driven cation exchange reactions are the major drivers for the concentration changes of Ca, Ba, Sr, and Cs. The pH-driven adsorption/desorption reactions lead to a concentration increase of As and Pb. The volume fraction and reactive surface area of calcite, CEC and sorption capacity are key parameters in determining the magnitude of concentration increase. Model results also show that the dissolution of calcite with Ba impurity could be an alternative explanation of the increase in Ba concentration.

  13. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  14. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  15. Generalized thickness and configuration of the top of the intermediate aquifer, West-Central Florida

    SciTech Connect (OSTI)

    Corral, M.A. Jr.; Wolansky, R.M.

    1984-01-01

    The water-bearing units of the intermediate aquifer consist of discontinuous sand, gravel, shell, and limestone and dolomite beds in the Tamiami Formation of late Miocene age and the Hawthorn Formation of middle Miocene age. Within parts of Polk, Manatee, Hardee, De Soto, Sarasota, and Charlotte Counties, sand and clay beds within the Tampa Limestone that are hydraulically connected to the Hawthorn Formation are also included in the intermediate aquifer. 15 refs.

  16. DOE Announces Transfer of Depleted Uranium to Advance the U.S. National

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant | Department of Energy Transfer of Depleted Uranium to Advance the U.S. National Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant DOE Announces Transfer of Depleted Uranium to Advance the U.S. National Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant May 15, 2012 - 4:00pm Addthis News Media Contact (202) 386-4940 WASHINGTON - The Department of Energy - in collaboration

  17. Accelerated cellular senescence phenotype of GAPDH-depleted human lung carcinoma cells

    SciTech Connect (OSTI)

    Phadke, Manali; Krynetskaia, Natalia; Mishra, Anurag; Krynetskiy, Evgeny; Jayne Haines Center for Pharmacogenomics, Temple University School of Pharmacy, Philadelphia, PA 19140

    2011-07-29

    Highlights: {yields} We examined the effect of glyceraldehyde 3-phosphate (GAPDH) depletion on proliferation of human carcinoma A549 cells. {yields} GAPDH depletion induces accelerated senescence in tumor cells via AMPK network, in the absence of DNA damage. {yields} Metabolic and genetic rescue experiments indicate that GAPDH has regulatory functions linking energy metabolism and cell cycle. {yields} Induction of senescence in LKB1-deficient lung cancer cells via GAPDH depletion suggests a novel strategy to control tumor cell proliferation. -- Abstract: Glyceraldehyde 3-phosphate dehydrogenase (GAPDH) is a pivotal glycolytic enzyme, and a signaling molecule which acts at the interface between stress factors and the cellular apoptotic machinery. Earlier, we found that knockdown of GAPDH in human carcinoma cell lines resulted in cell proliferation arrest and chemoresistance to S phase-specific cytotoxic agents. To elucidate the mechanism by which GAPDH depletion arrests cell proliferation, we examined the effect of GAPDH knockdown on human carcinoma cells A549. Our results show that GAPDH-depleted cells establish senescence phenotype, as revealed by proliferation arrest, changes in morphology, SA-{beta}-galactosidase staining, and more than 2-fold up-regulation of senescence-associated genes DEC1 and GLB1. Accelerated senescence following GAPDH depletion results from compromised glycolysis and energy crisis leading to the sustained AMPK activation via phosphorylation of {alpha} subunit at Thr172. Our findings demonstrate that GAPDH depletion switches human tumor cells to senescent phenotype via AMPK network, in the absence of DNA damage. Rescue experiments using metabolic and genetic models confirmed that GAPDH has important regulatory functions linking the energy metabolism and the cell cycle networks. Induction of senescence in LKB1-deficient non-small cell lung cancer cells via GAPDH depletion suggests a novel strategy to control tumor cell proliferation.

  18. Comparative Analysis of Depleted Uranium Oxide Films (Conference) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Conference: Comparative Analysis of Depleted Uranium Oxide Films Citation Details In-Document Search Title: Comparative Analysis of Depleted Uranium Oxide Films Authors: Santiago Cordoba, Miguel A. [1] ; Beaux, Miles Frank [1] ; Holesinger, Terry George [1] ; Scott, Brian Lindley [1] ; Vodnik, Douglas R. [1] ; Usov, Igor Olegovich [1] ; Bauer, Eve [2] ; King, Graham [2] + Show Author Affiliations Los Alamos National Laboratory Former LANL employee Publication Date: 2016-11-08 OSTI

  19. Optimization of Depletion Modeling and Simulation for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Betzler, Benjamin R; Ade, Brian J; Chandler, David; Ilas, Germina; Sunny, Eva E

    2015-01-01

    Monte Carlo based depletion tools used for the high-fidelity modeling and simulation of the High Flux Isotope Reactor (HFIR) come at a great computational cost; finding sufficient approximations is necessary to make the use of these tools feasible. The optimization of the neutronics and depletion model for the HFIR is based on two factors: (i) the explicit representation of the involute fuel plates with sets of polyhedra and (ii) the treatment of depletion mixtures and control element position during depletion calculations. A very fine representation (i.e., more polyhedra in the involute plate approximation) does not significantly improve simulation accuracy. The recommended representation closely represents the physical plates and ensures sufficient fidelity in regions with high flux gradients. Including the fissile targets in the central flux trap of the reactor as depletion mixtures has the greatest effect on the calculated cycle length, while localized effects (e.g., the burnup of specific isotopes or the power distribution evolution over the cycle) are more noticeable consequences of including a critical control element search or depleting burnable absorbers outside the fuel region.

  20. Fresh Water Generation from Aquifer-Pressured Carbon Storage

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Bourcier, W L; Wolfe, T; Haussmann, C

    2010-02-19

    Can we use the pressure associated with sequestration to make brine into fresh water? This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). Possible products are: Drinking water, Cooling water, and Extra aquifer space for CO{sub 2} storage. The conclusions are: (1) Many saline formation waters appear to be amenable to largely conventional RO treatment; (2) Thermodynamic modeling indicates that osmotic pressure is more limiting on water recovery than mineral scaling; (3) The use of thermodynamic modeling with Pitzer's equations (or Extended UNIQUAC) allows accurate estimation of osmotic pressure limits; (4) A general categorization of treatment feasibility is based on TDS has been proposed, in which brines with 10,000-85,000 mg/L are the most attractive targets; (5) Brines in this TDS range appear to be abundant (geographically and with depth) and could be targeted in planning future CCS operations (including site selection and choice of injection formation); and (6) The estimated cost of treating waters in the 10,000-85,000 mg/L TDS range is about half that for conventional seawater desalination, due to the anticipated pressure recovery.

  1. Depletion of cellular poly (A) binding protein prevents protein synthesis and leads to apoptosis in HeLa cells

    SciTech Connect (OSTI)

    Thangima Zannat, Mst.; Bhattacharjee, Rumpa B.; Bag, Jnanankur

    2011-05-13

    Highlights: {yields} Depletion of cellular PABP level arrests mRNA translation in HeLa cells. {yields} PABP knock down leads to apoptotic cell death. {yields} PABP depletion does not affect transcription. {yields} PABP depletion does not lead to nuclear accumulation of mRNA. -- Abstract: The cytoplasmic poly (A) binding protein (PABP) is important in mRNA translation and stability. In yeast, depletion of PABP leads to translation arrest. Similarly, the PABP gene in Drosophila is important for proper development. It is however uncertain, whether mammalian PABP is essential for mRNA translation. Here we showed the effect of PABP depletion on mRNA metabolism in HeLa cells by using a small interfering RNA. Our results suggest that depletion of PABP prevents protein synthesis and consequently leads to cell death through apoptosis. Interestingly, no detectable effect of PABP depletion on transcription, transport and stability of mRNA was observed.

  2. Stochastic interactions of two Brownian hard spheres in the presence of depletants

    SciTech Connect (OSTI)

    Karzar-Jeddi, Mehdi; Fan, Tai-Hsi; Tuinier, Remco; Taniguchi, Takashi

    2014-06-07

    A quantitative analysis is presented for the stochastic interactions of a pair of Brownian hard spheres in non-adsorbing polymer solutions. The hard spheres are hypothetically trapped by optical tweezers and allowed for random motion near the trapped positions. The investigation focuses on the long-time correlated Brownian motion. The mobility tensor altered by the polymer depletion effect is computed by the boundary integral method, and the corresponding random displacement is determined by the fluctuation-dissipation theorem. From our computations it follows that the presence of depletion layers around the hard spheres has a significant effect on the hydrodynamic interactions and particle dynamics as compared to pure solvent and uniform polymer solution cases. The probability distribution functions of random walks of the two interacting hard spheres that are trapped clearly shift due to the polymer depletion effect. The results show that the reduction of the viscosity in the depletion layers around the spheres and the entropic force due to the overlapping of depletion zones have a significant influence on the correlated Brownian interactions.

  3. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the

  4. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the

  5. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    DOE PAGES-Beta [OSTI]

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnershipmore » Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However

  6. Two-phase convective CO2 dissolution in saline aquifers

    DOE PAGES-Beta [OSTI]

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlyingmore » two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.« less

  7. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 2

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A.

    1995-06-30

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation.

  8. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 1

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A.

    1995-06-30

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation. These Appendices contain the Federal Register Notice, comments on evaluation factors, independent technical reviewers resumes, independent technical reviewers manual, and technology information packages.

  9. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    DOE PAGES-Beta [OSTI]

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric “open aquifer” and “closed aquifer” approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with “open” and/or “closed” approaches) and through flow modeling. These examples show that the “open aquifer” CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the “closed aquifer” estimates are a closer approximation to the flow-model derived capacity. Anmore » analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the “closed aquifer” approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.« less

  10. Water Influx, and Its Effect on Oil Recovery: Part 1. Aquifer Flow, SUPRI TR-103

    SciTech Connect (OSTI)

    Brigham, William E.

    1999-08-09

    Natural water encroachment is commonly seen in many oil and gas reservoirs. In fact, overall, there is more water than oil produced from oil reservoirs worldwide. Thus it is clear that an understanding of reservoir/aquifer interaction can be an important aspect of reservoir management to optimize recovery of hydrocarbons. Although the mathematics of these processes are difficult, they are often amenable to analytical solution and diagnosis. Thus this will be the ultimate goal of a series of reports on this subject. This first report deals only with aquifer behavior, so it does not address these important reservoir/aquifer issues. However, it is an important prelude to them, for the insight gained gives important clues on how to address reservoir/aquifer problems. In general when looking at aquifer flow, there are two convenient inner boundary conditions that can be considered; constant pressure or constant flow rate. There are three outer boundary conditions that are convenient to consider; infinite, closed and constant pressure. And there are three geometries that can be solved reasonably easily; linear, radial and spherical. Thus there are a total of eighteen different solutions that can be analyzed.

  11. Utah Underground Natural Gas Storage Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    Show Data By: Data Series Area 2010 2011 2012 2013 2014 2015 View History Total Storage ... Aquifers 939 939 948 948 948 992 2008-2015 Depleted Fields 51,250 53,950 53,950 53,950 ...

  12. Transient effects and pump depletion in stimulated Raman scattering. [Para-hydrogen

    SciTech Connect (OSTI)

    Carlsten, J.L.; Wenzel, R.G.; Druehl, K.

    1983-01-01

    Stimulated rotational Raman scattering in a 300-K multipass cell filled with para-H/sub 2/ with a single-mode CO/sub 2/-pumped laser is studied using a frequency-narrowed optical parametric oscillator (OPO) as a probe laser at the Stokes frequency for the S/sub 0/(O) transition. Amplification and pump depletion are examined as a function of incident pump energy. The pump depletion shows clear evidence of transient behavior. A theoretical treatment of transient stimulated Raman scattering, including effects of both pump depletion and medium saturation is presented. In a first approximation, diffraction effects are neglected, and only plane-wave interactions are considered. The theoretical results are compared to the experimental pulse shapes.

  13. DANDE: a linked code system for core neutronics/depletion analysis

    SciTech Connect (OSTI)

    LaBauve, R.J.; England, T.R.; George, D.C.; MacFarlane, R.E.; Wilson, W.B.

    1985-06-01

    This report describes DANDE - a modular neutronics, depletion code system for reactor analysis. It consists of nuclear data processing, core physics, and fuel depletion modules, and allows one to use diffusion and transport methods interchangeably in core neutronics calculations. This latter capability is especially important in the design of small modular cores. Additional unique features include the capability of updating the nuclear data file during a calculation; a detailed treatment of depletion, burnable poisons as well as fuel; and the ability to make geometric changes such as control rod repositioning and fuel relocation in the course of a calculation. The detailed treatment of reactor fuel burnup, fission-product creation and decay, as well as inventories of higher-order actinides is a necessity when predicting the behavior of reactor fuel under increased burn conditions. The operation of the code system is made clear in this report by following a sample problem.

  14. Parametric Analysis of PWR Spent Fuel Depletion Parameters for Long-Term-Disposal Criticality Safety

    SciTech Connect (OSTI)

    DeHart, M.D.

    1999-08-01

    Utilization of burnup credit in criticality safety analysis for long-term disposal of spent nuclear fuel allows improved design efficiency and reduced cost due to the large mass of fissile material that will be present in the repository. Burnup-credit calculations are based on depletion calculations that provide a conservative estimate of spent fuel contents (in terms of criticality potential), followed by criticality calculations to assess the value of the effective neutron multiplication factor (k(sub)eff) for the a spent fuel cask or a fuel configuration under a variety of probabilistically derived events. In order to ensure that the depletion calculation is conservative, it is necessary to both qualify and quantify assumptions that can be made in depletion models.

  15. Summary of the engineering analysis report for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W., Rahm-Crites, L.

    1997-09-01

    The Department of Energy (DOE) is reviewing ideas for the long-term management and use of its depleted uranium hexafluoride. DOE owns about 560,000 metric tons (over a billion pounds) of depleted uranium hexafluoride. This material is contained in steel cylinders located in storage yards near Paducah, Kentucky; Portsmouth, Ohio; and at the East Tennessee Technology Park (formerly the K-25 Site) in Oak Ridge, Tennessee. On November 10, 1994, DOE announced its new Depleted Uranium Hexafluoride Management Program by issuing a Request for Recommendations and an Advance Notice of Intent in the Federal Register (59 FR 56324 and 56325). The first part of this program consists of engineering, costs and environmental impact studies. Part one will conclude with the selection of a long-term management plan or strategy. Part two will carry out the selected strategy.

  16. Monopolistic recycling of oil revenue and intertemporal bias in oil depletion and trade

    SciTech Connect (OSTI)

    Hillman, A.L.; Long, N.V.

    1985-08-01

    This paper investigates oil depletion and trade when monopolistic oil producers also exercise monopoly power in the capital market. A two-period model views collusively organized oil producers with an initial trade surplus and a subsequent deficit. When monopoly power in the capital market is applied to the disadvantage of borrowers, less oil is initially made available to oil importers than if the interest rate had been competitively determined. This depletion bias, however, is reversed if, because of incentives for capital accumulation, it is to the advantage of the oil producers to subsidize lending to the oil importers. In either case the bias in oil depletion due to monopolistic recycling of oil revenue is greater, the more vulnerable are oil importer's incomes to a curtailment of oil supplies. 25 references.

  17. 1,2 or 3-D Few-Group Diffusion Depletion

    Energy Science and Technology Software Center (OSTI)

    1982-12-01

    The PDQ series of programs is designed to solve the neutron diffusion-depletion problem in one, two or three dimensions. The three-dimensional spatial calculation may be either explicit or discontinuous trial function synthesis. Up to five lethargy groups are permitted. Adjoint, fixed source, one iteration, additive fixed source, eigenvalue, and boundary value calculations may be performed. The programs utilize the HARMONY system for time-dependent representation of cross section variation and generalized depletion chain solutions. Geometries availablemore » include rectangular, cylindrical, spherical, and hexagonal. All allow variable mesh in all dimensions. Various control searches as well as temperature and xenon feedback are provided.« less

  18. Electron depletion via cathode spot dispersion of dielectric powder into an overhead plasma

    SciTech Connect (OSTI)

    Gillman, Eric D.; Foster, John E.

    2013-11-15

    The effectiveness of cathode spot delivered dielectric particles for the purpose of plasma depletion is investigated. Here, cathode spot flows kinetically entrain and accelerate dielectric particles originally at rest into a background plasma. The time variation of the background plasma density is tracked using a cylindrical Langmuir probe biased approximately at electron saturation. As inferred from changes in the electron saturation current, depletion fractions of up to 95% are observed. This method could be exploited as a means of communications blackout mitigation for manned and unmanned reentering spacecraft as well as any high speed vehicle enveloped by a dense plasma layer.

  19. Hydrologic transport of depleted uranium associated with open air dynamic range testing at Los Alamos National Laboratory, New Mexico, and Eglin Air Force Base, Florida

    SciTech Connect (OSTI)

    Becker, N.M.; Vanta, E.B.

    1995-05-01

    Hydrologic investigations on depleted uranium fate and transport associated with dynamic testing activities were instituted in the 1980`s at Los Alamos National Laboratory and Eglin Air Force Base. At Los Alamos, extensive field watershed investigations of soil, sediment, and especially runoff water were conducted. Eglin conducted field investigations and runoff studies similar to those at Los Alamos at former and active test ranges. Laboratory experiments complemented the field investigations at both installations. Mass balance calculations were performed to quantify the mass of expended uranium which had transported away from firing sites. At Los Alamos, it is estimated that more than 90 percent of the uranium still remains in close proximity to firing sites, which has been corroborated by independent calculations. At Eglin, we estimate that 90 to 95 percent of the uranium remains at test ranges. These data demonstrate that uranium moves slowly via surface water, in both semi-arid (Los Alamos) and humid (Eglin) environments.

  20. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  1. Apparatus and method for extraction of chemicals from aquifer remediation effluent water

    DOE Patents [OSTI]

    McMurtrey, Ryan D.; Ginosar, Daniel M.; Moor, Kenneth S.; Shook, G. Michael; Moses, John M.; Barker, Donna L.

    2002-01-01

    An apparatus and method for extraction of chemicals from an aquifer remediation aqueous effluent are provided. The extraction method utilizes a critical fluid for separation and recovery of chemicals employed in remediating aquifers contaminated with hazardous organic substances, and is particularly suited for separation and recovery of organic contaminants and process chemicals used in surfactant-based remediation technologies. The extraction method separates and recovers high-value chemicals from the remediation effluent and minimizes the volume of generated hazardous waste. The recovered chemicals can be recycled to the remediation process or stored for later use.

  2. FORIG: a modification of the ORIGEN2 isotope-generation and depletion code for fusion problems

    SciTech Connect (OSTI)

    Blink, J.A.

    1982-03-03

    This report describes how to use the FORIG computer code to solve isotope-generation and depletion problems in fusion and fission reactors. FORIG is an adaptation of ORIGEN2 to run on a Cray-1 computer, and to accept more extensive activation cross sections.

  3. DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at Ohio and Kentucky Facilities

    Energy.gov [DOE]

    Cincinnati -- The U.S. Department of Energy (DOE) today issued a Draft Request for Proposal (RFP) seeking a contractor to perform Depleted Uranium Hexafluoride (DUF6) Operations at the two DUF6 conversion facilities at Portsmouth, Ohio, and Paducah, Kentucky.

  4. DOE Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services

    Office of Energy Efficiency and Renewable Energy (EERE)

    Cincinnati – The U.S. Department of Energy (DOE) today issued a Request for Quotation (RFQ) for engineering and operations technical services to support the Portsmouth Paducah Project Office and the oversight of operations of the Depleted Uranium Hexafluoride (DUF6) Conversion Project located in Paducah KY, and Portsmouth OH.

  5. Running Out Of and Into Oil. Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, David L.; Hopson, Janet L.; Li, Jia

    2003-10-01

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value.

  6. Verification of a Depletion Method in SCALE for the Advanced High Temperature Reactor

    SciTech Connect (OSTI)

    KELLY, RYAN; Ilas, Dan

    2013-01-01

    This study describes a new approach employing the Dancoff correction method to model the TRISO-based fuel form used by the Advanced High-Temperature Reactor (AHTR) reactor design concept. The Dancoff correction method is used to perform isotope depletion analysis using the TRITON sequence of SCALE and is verified by code-to-code comparisons. The current AHTR fuel design has TRISO particles concentrated along the edges of a slab fuel element. This geometry prevented the use of the DOUBLEHET treatment, previously developed in SCALE to model spherical and cylindrical fuel. The new method permits fuel depletion on complicated geometries that traditionally can be handled only by continuous energy based depletion code systems. The method was initially tested on a fuel configuration typical of the Next Generation Nuclear Plant (NGNP), where DOUBLEHET treatment is possible. A confirmatory study was performed on the AHTR reference core geometry using the VESTA code, which uses the continuous energy MCNP5 code as a transport solver and ORIGEN2.2 code for depletion calculations. Comparisons of the results indicate good agreement of whole core characteristics, such as the multiplication factor and the isotopics, including their spatial distribution. Key isotopes analyzed included 235U, 239Pu, 240Pu, and 241Pu. The results from this study indicate that the Dancoff factor method can generate estimates of core characteristics with reasonable precision for scoping studies of configurations where DOUBLEHET treatment cannot be performed.

  7. Verification of a Depletion Method in SCALE for the Advanced High Temperature Reactor

    SciTech Connect (OSTI)

    KELLY, RYAN; Ilas, Dan

    2012-01-01

    This study describes a new method utilizing the Dancoff factor to model a non-standard TRISO fuel form characteristic of the AHTR reactor design concept for depletion analysis using the TRITON sequence of SCALE and the validation of this method by code-to-code comparisons. The fuel used in AHTR has the TRISO particles concentrated along the edges of a slab fuel element. This particular geometry prevented the use of a standard DOUBLEHET treatment, previously developed in SCALE to handle NGNP-designed fuel. The new method permits fuel depletion on complicated geometries that traditionally can be handled only by continuous energy based depletion code systems. The method was initially tested on a fuel design typical of the NGNP, where the DOUBLEHET treatment is available. A more comprehensive study was performed using the VESTA code that uses the continuous energy MCNP5 code as a transport solver and ORIGEN2.2 code for depletion calculations. Comparisons of the results indicate good agreement of whole core characteristics, such as the multiplication factor, and the isotopics, including their spatial distribution. Key isotopes analyzed included 235U, 239Pu, 240Pu and 241Pu. The results from this study indicate that the Dancoff factor method can generate estimates of core characteristics with reasonable precision for scoping studies of configurations where the DOUBLEHET treatment is unavailable.

  8. Comparison of nitrogen depletion and repletion on lipid production in yeast and fungal species

    DOE PAGES-Beta [OSTI]

    Yang, Shihui; Wang, Wei; Wei, Hui; Van Wychen, Stefanie; Pienkos, Philip T.; Zhang, Min; Himmel, Michael E.

    2016-08-29

    Although it is well known that low nitrogen stimulates lipid accumulation, especially for algae and some oleaginous yeast, few studies have been conducted in fungal species, especially on the impact of different nitrogen deficiency strategies. In this study, we use two promising consolidated bioprocessing (CBP) candidates to examine the impact of two nitrogen deficiency strategies on lipid production, which are the extensively investigated oleaginous yeast Yarrowia lipolytica, and the commercial cellulase producer Trichoderma reesei. We first utilized bioinformatics approaches to reconstruct the fatty acid metabolic pathway and demonstrated the presence of a triacylglycerol (TAG) biosynthesis pathway in Trichoderma reesei. Wemore » then examined the lipid production of Trichoderma reesei and Y. lipomyces in different media using two nitrogen deficiency strategies of nitrogen natural repletion and nitrogen depletion through centrifugation. Our results demonstrated that nitrogen depletion was better than nitrogen repletion with about 30% lipid increase for Trichoderma reesei and Y. lipomyces, and could be an option to improve lipid production in both oleaginous yeast and filamentous fungal species. The resulting distinctive lipid composition profiles indicated that the impacts of nitrogen depletion on yeast were different from those for fungal species. Under three types of C/N ratio conditions, C16 and C18 fatty acids were the predominant forms of lipids for both Trichoderma reesei and Y. lipolytica. In addition, while the overall fatty acid methyl ester (FAME) profiles of Trichoderma reesei were similar, the overall FAME profiles of Y. lipolytica observed a shift. The fatty acid metabolic pathway reconstructed in this work supports previous reports of lipid production in T. reesei, and provides a pathway for future omics studies and metabolic engineering efforts. Further investigation to identify the genetic targets responsible for the effect of nitrogen depletion

  9. Review and problem definition of water/rock reactions associated with injection of spent geothermal fluids from a geothermal plant into aquifers

    SciTech Connect (OSTI)

    Elders, W.A.

    1986-07-01

    Among the technical problems faced by the burgeoning geothermal industry is the disposal of spent fluids from power plants. Except in unusual circumstances the normal practice, especially in the USA, is to pump these spent fluids into injection wells to prevent contamination of surface waters, and possibly in some cases, to reduce pressure drawdown in the producing aquifers. This report is a survey of experience in geothermal injection, emphasizing geochemical problems, and a discussion of approaches to their possible mitigation. The extraction of enthalpy from geothermal fluid in power plants may cause solutions to be strongly supersaturated in various dissolved components such as silica, carbonates, sulfates, and sulfides. Injection of such supersaturated solutions into disposal wells has the potential to cause scaling in the well bores and plugging of the aquifers, leading to loss of injectivity. Various aspects of the geochemistry of geothermal brines and their potential for mineral formation are discussed, drawing upon a literature survey. Experience of brine treatment and handling, and the economics of mineral extraction are also addressed in this report. Finally suggestions are made on future needs for possible experimental, field and theoretical studies to avoid or control mineral scaling.

  10. A quantitative analysis of hydraulic interaction processes in stream-aquifer systems

    DOE PAGES-Beta [OSTI]

    Wang, Wenke; Dai, Zhenxue; Zhao, Yaqian; Li, Junting; Duan, Lei; Wang, Zhoufeng; Zhu, Lin

    2016-01-28

    The hydraulic relationship between the stream and aquifer can be altered from hydraulic connection to disconnection when the pumping rate exceeds the maximum seepage flux of the streambed. This study proposes to quantitatively analyze the physical processes of stream-aquifer systems from connection to disconnection. A free water table equation is adopted to clarify under what conditions a stream starts to separate hydraulically from an aquifer. Both the theoretical analysis and laboratory tests have demonstrated that the hydraulic connectedness of the stream-aquifer system can reach a critical disconnection state when the horizontal hydraulic gradient at the free water surface is equalmore » to zero and the vertical is equal to 1. A boundary-value problem for movement of the critical point of disconnection is established for an analytical solution of the inverted water table movement beneath the stream. The result indicates that the maximum distance or thickness of the inverted water table is equal to the water depth in the stream, and at a steady state of disconnection, the maximum hydraulic gradient at the streambed center is 2. In conclusion, this study helps us to understand the hydraulic phenomena of water flow near streams and accurately assess surface water and groundwater resources.« less

  11. Evaluating the impact of aquifer layer properties on geomechanical response during CO2 geological sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Lin, Guang; Fang, Yilin

    2013-04-01

    Numerical models play an essential role in understanding the facts of carbon dioxide (CO2) geological sequestration in the life cycle of a storage reservoir. We present a series of test cases that reflect a broad and realistic range of aquifer reservoir properties to systematically evaluate and compare the impacts on the geomechanical response to CO2 injection. In this study, a coupled hydro-mechanical model was introduced to simulate the sequestration process, and a quasi-Monte Carlo sampling method was introduced to efficiently sample the value of aquifer properties and geometry parameters. Aquifer permeability was found to be of significant importance to the geomechanical response to the injection. To study the influence of uncertainty of the permeability distribution in the aquifer, an additional series of tests is presented, based on a default permeability distribution site sample with various distribution deviations generated by the Monte Carlo sampling method. The results of the test series show that different permeability distributions significantly affect the displacement and possible failure zone.

  12. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Bacon, Diana H.; Qafoku, Nikolla; Dai, Zhenxue; Keating, Elizabeth; Brown, Christopher F.

    2016-01-01

    Multiphase, reactive transport modeling was used to identify the mechanisms controlling trace metal release under elevated CO2 conditions from a well-characterized carbonate aquifer. Modeling was conducted for two experimental scenarios: batch experiments to simulate sudden, fast, and short-lived release of CO2 as would occur in the case of well failure during injection, and column experiments to simulate more gradual leaks such as those occurring along undetected faults, fractures, or well linings. Observed and predicted trace metal concentrations are compared to groundwater concentrations from this aquifer to determine the potential for leaking CO2 to adversely impact drinking water quality. Finally, a three-dimensional multiphase flow and reactive-transport simulation of CO2 leakage from an abandoned wellbore into a generalized model of the shallow, unconfined portion of the aquifer is used to determine potential impacts on groundwater quality. As a measure of adverse impacts on groundwater quality, both the EPAs MCL limits and the maximum trace metal concentration observed in the aquifer were used as threshold values.

  13. Design and implementation of a CO{sub 2} flood utilizing advanced reservoir characterization and horizontal injection wells in a shallow shelf carbonate approaching waterflood depletion. Technical progress report

    SciTech Connect (OSTI)

    Chimahusky, J.S.

    1996-04-19

    The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a CO{sub 2} project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. This report includes work on the reservoir characterization and project design objective and the demonstration project objective.

  14. Design and implementation of a CO{sub 2} flood utilizing advanced reservoir characterization and horizontal injection wells in a shallow shelf carbonate approaching waterflood depletion. Quarterly report, July 1 - September 30, 1996

    SciTech Connect (OSTI)

    Chimahusky, J.S.

    1996-10-01

    The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second object is to demonstrate the performance and economic viability of the project in the field. The report include work on the reservoir characterization and project design objective and demonstration project objective.

  15. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and

  16. Evaluating Impacts of CO2 Intrusion into an Unconsolidated Aquifer. I. Experimental Data

    SciTech Connect (OSTI)

    Lawter, Amanda R.; Qafoku, Nikolla; Wang, Guohui; Shao, Hongbo; Brown, Christopher F.

    2015-08-04

    Capture and deep subsurface sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Batch and column experiments combined with wet chemical extractions were conducted to evaluate these risks to groundwater quality and to understand effects of CO2 leakage on aquifer chemistry and mineralogy. Sediments from the High Plains aquifer in Kansas, a confined sandstone aquifer, were used to study time-dependent release of major, minor and trace elements when exposed to CO2 gas. Results showed that Ca, Ba, Si, Mg, Sr, Na, and K increased either instantaneously or followed nonlinear increasing trends with time, indicating dissolution and/or desorption reactions controlled their release. Other elements, such as Mn and Fe, were also released from all sediments, creating a potential for redox reactions to occur. Results from acid extractions confirmed sediments had appreciable amounts of contaminants that may potentially be released into the aqueous phase. However, results from the batch and column experiments demonstrated that only a few trace elements (e.g., As, Cu, Cr, Pb) were released, indicating the risk of groundwater quality degradation due to exposure to leakage of sequestered CO2 is low. Concentrations of Mo were consistently higher in the control experiments (absence of CO2) and were below detection in the presence of CO2 indicating a possible benefit of CO2 in groundwater aquifers. These investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  17. Potential Impacts of Leakage from Black Rock Reservoir on the Hanford Site Unconfined Aquifer: Initial Hypothetical Simulations of Flow and Contaminant Transport

    SciTech Connect (OSTI)

    Freedman, Vicky L.

    2008-01-30

    Initial scoping calculations of the unconfined aquifer at the Hanford Site were carried out for the U.S. Bureau of Reclamation (USBR) to investigate the potential impacts on the Hanford unconfined aquifer that would result from leakage from the proposed Black Rock Reservoir to the west. Although impacts on groundwater flow and contaminant transport were quantified based on numerical simulation results, the investigation represented a qualitative assessment of the potential lateral recharge that could result in adverse effects on the aquifer. Because the magnitude of the potential leakage is unknown, hypothetical bounding calculations were performed. When a quantitative analysis of the magnitude of the potential recharge from Black Rock Reservoir is obtained, the hydrologic impacts analysis will be revisited. The analysis presented in this report represents initial bounding calculations. A maximum lateral recharge (i.e., upland flux) was determined in the first part of this study by executing steady-state flow simulations that raised the water table no higher than the elevation attained in the Central Plateau during the Hanford operational period. This metric was selected because it assumed a maximum remobilization of contaminants that existed under previous fully saturated conditions. Three steady-state flow fields were then used to analyze impacts to transient contaminant transport: a maximum recharge (27,000 acre-ft/yr), a no additional flux (365 acre-ft/yr), and an intermediate recharge case (16,000 acre-ft/yr). The transport behavior of four radionuclides was assessed for a 300 year simulation period with the three flow fields. The four radionuclides are tritium, iodine-129, technetium-99, and uranium-238. Transient flow and transport simulations were used to establish hypothetical concentration distributions in the subsurface. Using the simulated concentration distributions in 2005 as initial conditions for steady-state flow runs, simulations were executed to

  18. Potential Impacts of Leakage from Black Rock Reservoir on the Hanford Site Unconfined Aquifer: Initial Hypothetical Simulations of Flow and Contaminant Transport

    SciTech Connect (OSTI)

    Freedman, Vicky L.

    2007-03-09

    Initial scoping calculations of the unconfined aquifer at the Hanford Site were carried out for the U.S. Bureau of Reclamation (USBR) to investigate the potential impacts on the Hanford unconfined aquifer that would result from leakage from the proposed Black Rock Reservoir to the west. Although impacts on groundwater flow and contaminant transport were quantified based on numerical simulation results, the investigation represented a qualitative assessment of the potential lateral recharge that could result in adverse effects on the aquifer. Because the magnitude of the potential leakage is unknown, hypothetical bounding calculations were performed. When a quantitative analysis of the magnitude of the potential recharge from Black Rock Reservoir is obtained, the hydrologic impacts analysis will be revisited. The analysis presented in this report represent initial bounding calculations. A maximum lateral recharge (i.e., upland flux) was determined in the first part of this study by executing steady-state flow simulations that raised the water table no higher than the elevation attained in the Central Plateau during the Hanford operational period. This metric was selected because it assumed a maximum remobilization of contaminants that existed under previous fully saturated conditions. Three steady-state flow fields were then used to analyze impacts to transient contaminant transport: a maximum recharge (27,000 acre-ft/yr), a no additional flux (365 acre-ft/yr), and an intermediate recharge case (16,000 acre-ft/yr). The transport behavior of four radionuclides was assessed for a 300 year simulation period with the three flow fields. The four radionuclides are current contaminants of concern (COCs) in the Central Plateau and include tritium, iodine-129, technetium-99, and uranium-238. Transient flow and transport simulations were used to establish hypothetical concentration distributions in the subsurface. Using the simulated concentration distributions in 2005 as

  19. In Situ Reduction of Aquifer Sediments to Create a Permeable Reactive Barrier to Remediate Chromate (CrO4 2-): BenchScale Tests to Determine Barrier Longevity

    SciTech Connect (OSTI)

    Szecsody, Jim E.; Fruchter, Jonathan S.; Vermeul, Vince R.; Williams, Mark D.; Devary, Brooks J.

    2005-01-02

    Laboratory tests were conducted to determine sediment geochemical properties needed to develop a design for implementation of the in-situ oxidation–reduction (redox) manipulation (ISRM) technology for chromate (CrO42–) remediation at a Superfund site and three other sites. A generalized hydrogeologic description of the Superfund site consist of a silty clay upper confining layer to a depth of ~6.71 m, the A1 unit from ~6.71 m to ~8.23 m, the A2 unit from ~8.23 m to ~10.67 m, and the A3 unit from ~10.67 m to ~12.19 m below ground surface. The A/B aquitard was encountered at a depth of ~12.19 m. The A1, A2, and A3 hydrostratigraphic units are all sandy gravels, but with considerable difference in fines content and subsequently, hydraulic conductivity. Hydraulic tests conducted in pilot test site monitoring wells indicate that the A1 unit has a 10 times lower hydraulic conductivity than the A2 unit, while the A3 unit hydraulic conductivity is significantly higher than that observed in the A2 unit (i.e., a trend of increasing permeability with depth). Calculated hydraulic conductivities, based on sieve analysis, show this same spatial trend. Results from a tracer injection test and electromagnetic borehole flow meter tests conducted at the site indicate a relatively high degree of formation heterogeneity. Laboratory experiments showed that chemical reduction yielded a redox capacity (0.26% iron(II)) that falls within the range of values observed in sediments analyzed from sites where field-scale deployment of the ISRM technology is currently in progress or being considered (0.1% Hanford 100D area, 0.24% Ft Lewis, 0.4% Moffett Federal Airfield). There was relatively little spatial variability in reducible iron (Fe) content between the three aquifer units. This mass of reducible Fe represents a sufficient quantity for a treatment zone emplaced to remain anoxic for 430 pore volumes, which would be expected to last tens of years, depending on aquifer flow rates and the

  20. A method for including external feed in depletion calculations with CRAM and implementation into ORIGEN

    DOE PAGES-Beta [OSTI]

    Isotalo, Aarno E.; Wieselquist, William A.

    2015-05-15

    A method for including external feed with polynomial time dependence in depletion calculations with the Chebyshev Rational Approximation Method (CRAM) is presented and the implementation of CRAM to the ORIGEN module of the SCALE suite is described. In addition to being able to handle time-dependent feed rates, the new solver also adds the capability to perform adjoint calculations. Results obtained with the new CRAM solver and the original depletion solver of ORIGEN are compared to high precision reference calculations, which shows the new solver to be orders of magnitude more accurate. Lastly, in most cases, the new solver is upmore » to several times faster due to not requiring similar substepping as the original one.« less

  1. Summary of the Preliminary Analysis of Savannah River Depleted Uranium Trioxide

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2010-10-13

    This report summarizes a preliminary special analysis of the Savannah River Depleted Uranium Trioxide waste stream (SVRSURANIUM03, Revision 2). The analysis is considered preliminary because a final waste profile has not been submitted for review. The special analysis is performed to determine the acceptability of the waste stream for shallow land burial at the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada National Security Site (NNSS). The Savannah River Depleted Uranium Trioxide waste stream requires a special analysis because the waste stream’s sum of fractions exceeds one. The 99Tc activity concentration is 98 percent of the NNSS Waste Acceptance Criteria and the largest single contributor to the sum of fractions.

  2. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L. ); Koss, T.C. . Office of Environmental Guidance)

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  3. Performance upgrades to the MCNP6 burnup capability for large scale depletion calculations

    SciTech Connect (OSTI)

    Fensin, M. L.; Galloway, J. D.; James, M. R.

    2015-04-11

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. With the merger of MCNPX and MCNP5, MCNP6 combined the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. The new MCNP6 depletion capability was first showcased at the International Congress for Advancements in Nuclear Power Plants (ICAPP) meeting in 2012. At that conference the new capabilities addressed included the combined distributive and shared memory parallel architecture for the burnup capability, improved memory management, physics enhancements, and new predictability as compared to the H.B Robinson Benchmark. At Los Alamos National Laboratory, a special purpose cluster named tebow, was constructed such to maximize available RAM per CPU, as well as leveraging swap space with solid state hard drives, to allow larger scale depletion calculations (allowing for significantly more burnable regions than previously examined). As the MCNP6 burnup capability was scaled to larger numbers of burnable regions, a noticeable slowdown was realized.This paper details two specific computational performance strategies for improving calculation speedup: (1) retrieving cross sections during transport; and (2) tallying mechanisms specific to burnup in MCNP. To combat this slowdown new performance upgrades were developed and integrated into MCNP6 1.2.

  4. Potential hazards of compressed air energy storage in depleted natural gas reservoirs.

    SciTech Connect (OSTI)

    Cooper, Paul W.; Grubelich, Mark Charles; Bauer, Stephen J.

    2011-09-01

    This report is a preliminary assessment of the ignition and explosion potential in a depleted hydrocarbon reservoir from air cycling associated with compressed air energy storage (CAES) in geologic media. The study identifies issues associated with this phenomenon as well as possible mitigating measures that should be considered. Compressed air energy storage (CAES) in geologic media has been proposed to help supplement renewable energy sources (e.g., wind and solar) by providing a means to store energy when excess energy is available, and to provide an energy source during non-productive or low productivity renewable energy time periods. Presently, salt caverns represent the only proven underground storage used for CAES. Depleted natural gas reservoirs represent another potential underground storage vessel for CAES because they have demonstrated their container function and may have the requisite porosity and permeability; however reservoirs have yet to be demonstrated as a functional/operational storage media for compressed air. Specifically, air introduced into a depleted natural gas reservoir presents a situation where an ignition and explosion potential may exist. This report presents the results of an initial study identifying issues associated with this phenomena as well as possible mitigating measures that should be considered.

  5. Performance upgrades to the MCNP6 burnup capability for large scale depletion calculations

    DOE PAGES-Beta [OSTI]

    Fensin, M. L.; Galloway, J. D.; James, M. R.

    2015-04-11

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. With the merger of MCNPX and MCNP5, MCNP6 combined the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. The new MCNP6 depletion capability was first showcased at the International Congress for Advancements in Nuclear Power Plants (ICAPP) meeting in 2012. At that conference the new capabilities addressed included the combined distributive and shared memory parallel architecture for the burnup capability, improved memory management, physics enhancements, and newmore » predictability as compared to the H.B Robinson Benchmark. At Los Alamos National Laboratory, a special purpose cluster named “tebow,” was constructed such to maximize available RAM per CPU, as well as leveraging swap space with solid state hard drives, to allow larger scale depletion calculations (allowing for significantly more burnable regions than previously examined). As the MCNP6 burnup capability was scaled to larger numbers of burnable regions, a noticeable slowdown was realized.This paper details two specific computational performance strategies for improving calculation speedup: (1) retrieving cross sections during transport; and (2) tallying mechanisms specific to burnup in MCNP. To combat this slowdown new performance upgrades were developed and integrated into MCNP6 1.2.« less

  6. Micelle-induced depletion interaction and resultant structure in charged colloidal nanoparticle system

    SciTech Connect (OSTI)

    Ray, D.; Aswal, V. K.; Kohlbrecher, J.

    2015-04-28

    The evolution of the interaction and the resultant structure in the mixed system of anionic silica nanoparticles (Ludox LS30) and non-ionic surfactant decaethylene glycol monododecylether (C12E10), undergoing phase separation, have been studied using small-angle neutron scattering and dynamic light scattering. The measurements have been carried out for a fixed concentration of nanoparticle (1?wt.?%) with varying concentration of surfactant (0 to 1?wt.?%), in the absence and presence of an electrolyte. It is found that the micelles of non-ionic surfactant adsorb on the nanoparticle in the absence of electrolyte (form stable system), whereas these micelles become non-adsorbing in the presence of electrolyte (show phase separation). The phase separation arises because of C12E10 micelles, causing depletion interaction between nanoparticles and leading to their aggregation. The interaction is modeled by double Yukawa potential accounting for attractive depletion as well as repulsive electrostatic forces. Both the interactions (attraction and repulsion) are found to be of long-range. The nanoparticle aggregation (phase separation) is governed by the increase in the magnitude and the range of the depletion attraction with the increase in the surfactant concentration. The nanoparticle aggregates formed are quite large in size (order of micron) and are characterized by the surface fractal having simple cubic packing of nanoparticles within the aggregates.

  7. Performance upgrades to the MCNP6 burnup capability for large scale depletion calculations

    SciTech Connect (OSTI)

    Fensin, M. L.; Galloway, J. D.; James, M. R.

    2015-04-11

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. With the merger of MCNPX and MCNP5, MCNP6 combined the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. The new MCNP6 depletion capability was first showcased at the International Congress for Advancements in Nuclear Power Plants (ICAPP) meeting in 2012. At that conference the new capabilities addressed included the combined distributive and shared memory parallel architecture for the burnup capability, improved memory management, physics enhancements, and new predictability as compared to the H.B Robinson Benchmark. At Los Alamos National Laboratory, a special purpose cluster named “tebow,” was constructed such to maximize available RAM per CPU, as well as leveraging swap space with solid state hard drives, to allow larger scale depletion calculations (allowing for significantly more burnable regions than previously examined). As the MCNP6 burnup capability was scaled to larger numbers of burnable regions, a noticeable slowdown was realized.This paper details two specific computational performance strategies for improving calculation speedup: (1) retrieving cross sections during transport; and (2) tallying mechanisms specific to burnup in MCNP. To combat this slowdown new performance upgrades were developed and integrated into MCNP6 1.2.

  8. Semiconductor-based photoelectrochemical water splitting at the limit of very wide depletion region

    SciTech Connect (OSTI)

    Liu, Mingzhao; Lyons, John L.; Yan, Danhua H.; Hybertsen, Mark S.

    2015-11-23

    In semiconductor-based photoelectrochemical (PEC) water splitting, carrier separation and delivery largely relies on the depletion region formed at the semiconductor/water interface. As a Schottky junction device, the trade-off between photon collection and minority carrier delivery remains a persistent obstacle for maximizing the performance of a water splitting photoelectrode. Here, it is demonstrated that the PEC water splitting efficiency for an n-SrTiO3 (n-STO) photoanode is improved very significantly despite its weak indirect band gap optical absorption (α < 10⁴ cm⁻¹), by widening the depletion region through engineering its doping density and profile. Graded doped n-SrTiO3 photoanodes are fabricated with their bulk heavily doped with oxygen vacancies but their surface lightly doped over a tunable depth of a few hundred nanometers, through a simple low temperature re-oxidation technique. The graded doping profile widens the depletion region to over 500 nm, thus leading to very efficient charge carrier separation and high quantum efficiency (>70%) for the weak indirect transition. As a result, this simultaneous optimization of the light absorption, minority carrier (hole) delivery, and majority carrier (electron) transport by means of a graded doping architecture may be useful for other indirect band gap photocatalysts that suffer from a similar problem of weak optical absorption.

  9. Power distributions in fresh and depleted LEU and HEU cores of the MITR reactor.

    SciTech Connect (OSTI)

    Wilson, E.H.; Horelik, N.E.; Dunn, F.E.; Newton, T.H., Jr.; Hu, L.; Stevens, J.G.

    2012-04-04

    The Massachusetts Institute of Technology Reactor (MITR-II) is a research reactor in Cambridge, Massachusetts designed primarily for experiments using neutron beam and in-core irradiation facilities. It delivers a neutron flux comparable to current LWR power reactors in a compact 6 MW core using Highly Enriched Uranium (HEU) fuel. In the framework of its non-proliferation policies, the international community presently aims to minimize the amount of nuclear material available that could be used for nuclear weapons. In this geopolitical context, most research and test reactors both domestic and international have started a program of conversion to the use of Low Enriched Uranium (LEU) fuel. A new type of LEU fuel based on an alloy of uranium and molybdenum (UMo) is expected to allow the conversion of U.S. domestic high performance reactors like the MITR-II reactor. Toward this goal, core geometry and power distributions are presented. Distributions of power are calculated for LEU cores depleted with MCODE using an MCNP5 Monte Carlo model. The MCNP5 HEU and LEU MITR models were previously compared to experimental benchmark data for the MITR-II. This same model was used with a finer spatial depletion in order to generate power distributions for the LEU cores. The objective of this work is to generate and characterize a series of fresh and depleted core peak power distributions, and provide a thermal hydraulic evaluation of the geometry which should be considered for subsequent thermal hydraulic safety analyses.

  10. Semiconductor-based photoelectrochemical water splitting at the limit of very wide depletion region

    DOE PAGES-Beta [OSTI]

    Liu, Mingzhao; Lyons, John L.; Yan, Danhua H.; Hybertsen, Mark S.

    2015-11-23

    In semiconductor-based photoelectrochemical (PEC) water splitting, carrier separation and delivery largely relies on the depletion region formed at the semiconductor/water interface. As a Schottky junction device, the trade-off between photon collection and minority carrier delivery remains a persistent obstacle for maximizing the performance of a water splitting photoelectrode. Here, it is demonstrated that the PEC water splitting efficiency for an n-SrTiO3 (n-STO) photoanode is improved very significantly despite its weak indirect band gap optical absorption (α < 10⁴ cm⁻¹), by widening the depletion region through engineering its doping density and profile. Graded doped n-SrTiO3 photoanodes are fabricated with their bulkmore » heavily doped with oxygen vacancies but their surface lightly doped over a tunable depth of a few hundred nanometers, through a simple low temperature re-oxidation technique. The graded doping profile widens the depletion region to over 500 nm, thus leading to very efficient charge carrier separation and high quantum efficiency (>70%) for the weak indirect transition. As a result, this simultaneous optimization of the light absorption, minority carrier (hole) delivery, and majority carrier (electron) transport by means of a graded doping architecture may be useful for other indirect band gap photocatalysts that suffer from a similar problem of weak optical absorption.« less

  11. DUSCOBS - a depleted-uranium silicate backfill for transport, storage, and disposal of spent nuclear fuel

    SciTech Connect (OSTI)

    Forsberg, C.W.; Pope, R.B.; Ashline, R.C.; DeHart, M.D.; Childs, K.W.; Tang, J.S.

    1995-11-30

    A Depleted Uranium Silicate COntainer Backfill System (DUSCOBS) is proposed that would use small, isotopically-depleted uranium silicate glass beads as a backfill material inside storage, transport, and repository waste packages containing spent nuclear fuel (SNF). The uranium silicate glass beads would fill all void space inside the package including the coolant channels inside SNF assemblies. Based on preliminary analysis, the following benefits have been identified. DUSCOBS improves repository waste package performance by three mechanisms. First, it reduces the radionuclide releases from SNF when water enters the waste package by creating a local uranium silicate saturated groundwater environment that suppresses (1) the dissolution and/or transformation of uranium dioxide fuel pellets and, hence, (2) the release of radionuclides incorporated into the SNF pellets. Second, the potential for long-term nuclear criticality is reduced by isotopic exchange of enriched uranium in SNF with the depleted uranium (DU) in the glass. Third, the backfill reduces radiation interactions between SNF and the local environment (package and local geology) and thus reduces generation of hydrogen, acids, and other chemicals that degrade the waste package system. In addition, the DUSCOBS improves the integrity of the package by acting as a packing material and ensures criticality control for the package during SNF storage and transport. Finally, DUSCOBS provides a potential method to dispose of significant quantities of excess DU from uranium enrichment plants at potential economic savings. DUSCOBS is a new concept. Consequently, the concept has not been optimized or demonstrated in laboratory experiments.

  12. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  13. Geostatistical Simulation of Hydrofacies Heterogeneity of the West Thessaly Aquifer Systems in Greece

    SciTech Connect (OSTI)

    Modis, K. Sideri, D.

    2013-06-15

    Integrating geological properties, such as relative positions and proportions of different hydrofacies, is of highest importance in order to render realistic geological patterns. Sequential indicator simulation (SIS) and Plurigaussian simulation (PS) are alternative methods for conceptual and deterministic modeling for the characterization of hydrofacies distribution. In this work, we studied the spatial differentiation of hydrofacies in the alluvial aquifer system of West Thessaly basin in Greece. For this, we applied both SIS and PS techniques to an extensive set of borehole data from that basin. Histograms of model versus experimental hydrofacies proportions and indicative cross sections were plotted in order to validate the results. The PS technique was shown to be more effective in reproducing the spatial characteristics of the different hydrofacies and their distribution across the study area. In addition, the permeability differentiations reflected in the PS model are in accordance to known heterogeneities of the aquifer capacity.

  14. Optimization of Geological Environments for Carbon Dioxide Disposan in Saline Aquifers in the United States

    SciTech Connect (OSTI)

    Hovorka, Susan

    1999-02-01

    Recent research and applications have demonstrated technologically feasible methods, defined costs, and modeled processes needed to sequester carbon dioxide (CO{sub 2}) in saline-water-bearing formations (aquifers). One of the simplifying assumptions used in previous modeling efforts is the effect of real stratigraphic complexity on transport and trapping in saline aquifers. In this study we have developed and applied criteria for characterizing saline aquifers for very long-term sequestration of CO{sub 2}. The purpose of this pilot study is to demonstrate a methodology for optimizing matches between CO{sub 2} sources and nearby saline formations that can be used for sequestration. This project identified 14 geologic properties used to prospect for optimal locations for CO{sub 2} sequestration in saline-water-bearing formations. For this demonstration, we digitized maps showing properties of saline formations and used analytical tools in a geographic information system (GIS) to extract areas that meet variably specified prototype criteria for CO{sub 2} sequestration sites. Through geologic models, realistic aquifer properties such as discontinuous sand-body geometry are determined and can be used to add realistic hydrologic properties to future simulations. This approach facilitates refining the search for a best-fit saline host formation as our understanding of the most effective ways to implement sequestration proceeds. Formations where there has been significant drilling for oil and gas resources as well as extensive characterization of formations for deep-well injection and waste disposal sites can be described in detail. Information to describe formation properties can be inferred from poorly known saline formations using geologic models in a play approach. Resulting data sets are less detailed than in well-described examples but serve as an effective screening tool to identify prospects for more detailed work.

  15. Surfactant-enhanced aquifer remediation at the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Jackson, R.E.; Londergan, J.T.; Pickens, J.F.

    1995-10-01

    Many DOE facilities are situated in areas of sand and gravel which have become polluted with dense, non-aqueous phase liquids or DNAPLs, such as chlorinated solvents, from the various industrial operations at these facilities. The presence of such DNAPLs in sand and gravel aquifers is now recognized as the principal factor in the failure of standard ground-water remediation methods. The principal objective of this study, as stated in the Statement of Work of the contract (DE-AC21-92MC29111), is to demonstrate that multi-component DNAPLs can be readily solubilized in sand and gravel aquifers by dilute surfactant solutions. The specific objectives of the contract are: to identify dilute surfactants or blends of surfactants in the laboratory that will efficiently extract multi-component DNAPLs from sand and gravel aquifers by micellar solubilization (Phase 1); 2. to test the efficacy of the identified surfactants or blends of surfactants to solubilize in situ perchloroethylene (PCE) and trichloroethylene (TCE) DNAPLs by the injection and the subsequent extraction through an existing well or wells at a government-owned contaminated site (Phase 1); and 3. to demonstrate the full-scale operation of this remedial technology at a government-owned contaminated site (Phase 2). Specific objective number 1 has been completed and reported to DOE. However, the results of the test referred to in specific objective number 2, conducted at Paducah Gaseous Diffusion Plant in 1994, were inconclusive. Following this first test, it was decided by DOE and INTERA to move the test site elsewhere due to difficulties with obtaining core samples of the sand and gravel aquifer containing the DNAPL and with ascertaining the location of the DNAPL relative to the injection well. The solubilization test at the Portsmouth Gaseous Diffusion Plant (PORTS) will constitute the second test of Phase 1 of this contract.

  16. Underground Thermal Energy Storage (UTES) Via Borehole and Aquifer Thermal Energy Storage (BTES/ATES) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Underground Thermal Energy Storage (UTES) Via Borehole and Aquifer Thermal Energy Storage (BTES/ATES) Systems Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 3-4, 2015 Houston, TX Presented By: Chuck Hammock, PE, CGD, LEED AP BD+C, Andrews, Hammock & Powell, Inc. Consulting Engineers Macon, GA www.ahpengr.com * "Direct-Use" (American) Geothermal Heat Pump (GHP) architecture vs. Geothermal designed for true Thermal Energy Storage (mostly European applications)

  17. Water-supply potential of the Upper Floridan aquifer in the vicinity of Savannah, Georgia

    SciTech Connect (OSTI)

    Garza, R.; Krause, R.E. )

    1993-03-01

    The Upper Floridan aquifer is the primary source of freshwater in coastal Georgia. Groundwater withdrawal in the area of Savannah and in the adjacent coastal areas in Georgia and South Carolina has resulted in large regional water-level declines and a reversal of the hydraulic gradient that existed prior to development. Changes in gradient and decreasing water levels are causing lateral encroachment of seawater into the Upper Floridan aquifer at the northern end of Hilton Head Island, SC, and vertical intrusion of saltwater into the Upper and Lower Floridan aquifers in the Brunswick, GA., area. Concerns about future water-supply demands prompted the US Geological Survey and the Chatham County-Savannah Metropolitan Planning Commission to undertake a cooperative study to evaluate the ground-water resources in the Savannah, GA, area. A numerical ground-water flow model was developed and used in conjunction with other previously calibrated models in the coastal areas of Georgia and South Carolina to simulate the effects of additional ground-water withdrawal on water levels. Based on model simulations and the constraint of preventing additional water-level declines at the locations of encroachment and intrusion, the potential of the Upper Floridan aquifer to supply additional water in the Savannah area is limited under present hydrologic conditions. The potential for additional withdrawal in the vicinity of Savannah, GA, ranges from less than 1 million gallons per day (Mgal/d) to about 5 Mgal/d. Because of the limited water-supply potential, hypothetical alternatives of ground-water withdrawal were simulated to determine the effects on water levels. These simulations indicate that reduction and redistribution of ground-water withdrawal would not adversely affect water levels at the locations of encroachment and intrusion.

  18. Flow and Transport in the Hanford 300 Area Vadose Zone-Aquifer-River System

    SciTech Connect (OSTI)

    Waichler, Scott R.; Yabusaki, Steven B.

    2005-07-13

    Contaminant migration in the 300 Area unconfined aquifer is strongly coupled to fluctuations in the Columbia River stage. To better understand the interaction between the river, aquifer, and vadose zone, a 2-D saturated-unsaturated flow and transport model was developed for a vertical cross-section aligned west-east across the Hanford Site 300 Area, nearly perpendicular to the river. The model was used to investigate water flow and tracer transport in the vadose zone-aquifer-river flow system, in support of the ongoing study of the 300 Area uranium plume. The STOMP simulator was used to model 1-year from 3/1/92 to 2/28/93, a period when hourly data were available for both groundwater and river levels. Net water flow to the river (per 1-meter width of shoreline) was 182 m3/y in the base case, but the cumulative exchange or total flow back and forth across the riverbed was 30 times greater. The low river case had approximately double the net water and Groundwater tracer flux into the river as compared to the base case.

  19. Metabolic interdependencies between phylogenetically novel fermenters and respiratory organisms in an unconfined aquifer

    SciTech Connect (OSTI)

    Wrighton, Kelly C.; Castelle, Cindy; Wilkins, Michael J.; Hug, Laura A.; Sharon, I.; Thomas, Brian C.; Handley, Kim M.; Mullin, Sean W.; Nicora, Carrie D.; Singh, Andrea; Lipton, Mary S.; Long, Philip E.; Williams, Kenneth H.; Banfield, Jillian F.

    2014-07-08

    Fermentation-based metabolism is an important ecosystem function often associated with environments rich in organic carbon, such as wetlands, sewage sludge, and the mammalian gut. The diversity of microorganisms and pathways involved in carbon and hydrogen cycling in sediments and aquifers and the impacts of these processes on other biogeochemical cycles remain poorly understood. Here we used metagenomics and proteomics to characterize microbial communities sampled from an aquifer adjacent to the Colorado River at Rifle, Colorado, USA, and document interlinked microbial roles in geochemical cycling. The organic carbon content in the aquifer was elevated via two acetate-based biostimulation treatments. Samples were collected at three time points, with the objective of extensive genome recovery to enable metabolic reconstruction of the community. Fermentative community members include genomes from a new phylum (ACD20), phylogenetically novel members of the Chloroflexi and Bacteroidetes, as well as candidate phyla genomes (OD1, BD1-5, SR1, WWE3, ACD58, TM6, PER, and OP11). These organisms have the capacity to produce hydrogen, acetate, formate, ethanol, butyrate, and lactate, activities supported by proteomic data. The diversity and expression of hydrogenases suggests the importance of hydrogen currency in the subsurface. Our proteogenomic data further indicate the consumption of fermentation intermediates by Proteobacteria can be coupled to nitrate, sulfate, and iron reduction. Thus, fermentation carried out by previously unstudied members of sediment microbial communities may be an important driver of diverse subsurface biogeochemical cycles.

  20. Exposure of a food crop to trichloroethylene from a contaminated aquifer. Master's thesis

    SciTech Connect (OSTI)

    Baringer, R.G.

    1994-09-01

    This research developed a methodology for assessment of the exposure of a mature corn crop to trichloroethylene from a contaminated aquifer. The methodology was then applied to the case of Hill AFB to determine the ability of the methodology to provide information about a specific exposure. Current procedures sample for food contamination but do not attempt to predict exposure problems. A review of the potential exposure pathways from the aquifer to the crop was conducted. Based on this review, the exposures due to soil gas and irrigation were modeled. Empirical estimated were used to approximate the expected flux of soil gas vaporizing directly from the aquifer. On the basis of this approximation, the exposure the air of the crop canopy was mathematically estimated. Analytical models were developed to simulate the amount of the contaminant reaching the crop from two different means of irrigation. The subsequent exposure once the contaminated irrigation water had reached the crop was modeled both in the air of the crop canopy and the soil phase near the root system. The methodology provided insights into which exposure pathways are more important than others and which environmental parameters most influence the amount of exposure.

  1. The exploration for a deep aquifer in the Hadhramaut, Yemen

    SciTech Connect (OSTI)

    Bauman, P.

    1996-11-01

    The Hadhramaut province of Yemen, an area with a population of more than half a million inhabitants, is presently facing a serious water crisis. A groundwater exploration project is presently drilling 23 exploration wells widely spaced over the Masila Block, an oil exploration lease are within the province. The main target is the Cretaceous Mukalla Formation, a 300 m thick highly permeable sandstone. Field reconnaissance was integrated with satellite images; geologic, hydrogeologic, geophysical, topographic maps; and local socioeconomic and political information to choose the well locations. Studying available seismic reflection data was particularly useful for choosing drilling locations over grabens buried in wadi fill. The various pieces of information were integrated in a geographic information system (GIS). To date, eight wells have been drilled and completed. Borehole geophysical logging has played an important role in all phases of well completion. All completed boreholes have tested from 200 to over 1,000 imperial gallons per minute.

  2. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    SciTech Connect (OSTI)

    Zoback, Mark D.; Kovscek, Anthony R.; Wilcox, Jennifer

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  3. All-optical depletion of dark excitons from a semiconductor quantum dot

    SciTech Connect (OSTI)

    Schmidgall, E. R.; Schwartz, I.; Cogan, D.; Gershoni, D.; Gantz, L.; Heindel, T.; Reitzenstein, S.

    2015-05-11

    Semiconductor quantum dots are considered to be the leading venue for fabricating on-demand sources of single photons. However, the generation of long-lived dark excitons imposes significant limits on the efficiency of these sources. We demonstrate a technique that optically pumps the dark exciton population and converts it to a bright exciton population, using intermediate excited biexciton states. We show experimentally that our method considerably reduces the dark exciton population while doubling the triggered bright exciton emission, approaching thereby near-unit fidelity of quantum dot depletion.

  4. Partial depletion region collapse and its impact on transient capacitance measurements

    SciTech Connect (OSTI)

    Lips, K.; Unold, T.; Xu, Y.; Crandall, R.S.

    1996-12-31

    The authors investigate capacitance transients under various experimental conditions on a number of different amorphous silicon Schottky barrier device structures. The samples differ mainly in their back contact configuration, which is non-ohmic for one type of sample and ohmic for the second type of samples. Anomalous transients can be observed for all samples regardless of the back contact if the depletion region is only partially collapsed by partial voltage pulsing. The authors find that samples without an ohmic back contact show a slowly rising capacitance during the filling pulse. These samples show anomalous capacitance transients for short filling pulses.

  5. Depleted and Recyclable Uranium in the United States: Inventories and Options

    SciTech Connect (OSTI)

    Schneider, Erich; Scopatza, Anthony; Deinert, Mark

    2007-07-01

    International consumption of uranium currently outpaces production by nearly a factor of two. Secondary supplies from dismantled nuclear weapons, along with civilian and governmental stockpiles, are being used to make up the difference but supplies are limited. Large amounts of {sup 235}U are contained in spent nuclear fuel as well as in the tails left over from past uranium enrichment. The usability of these inhomogeneous uranium supplies depends on their isotopics. We present data on the {sup 235}U content of spent nuclear fuel and depleted uranium tails in the US and discuss the factors that affect its marketability and alternative uses. (authors)

  6. VERA Modeling and Simulation of the AP1000 PWR Cycle 1 Depletion

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    CASL-U-2015-0302-000 VERA Modeling and Simulation of the AP1000 PWR Cycle 1 Depletion L3:VMA.AMA.P11.06 David Salazar, Westinghouse Fausto Franceschini, Westinghouse September 30, 2015 L3:VMA.AMA.P11.06 Official Use Only ii Protected under CASL Master NDA CASL-U-2015-0302-000 REVISION LOG Revision Date Affected Pages Revision Description 0 09/30/2015 All Initial issuance Document pages that are: Export Controlled ____________No______________________________________ IP/Proprietary/NDA

  7. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2

  8. Depleted uranium oxides and silicates as spent nuclear fuel waste package fill materials

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1996-09-10

    A new repository waste package (WP) concept for spent nuclear fuel (SNF) is being investigated that uses depleted uranium (DU) to improve performance and reduce the uncertainties of geological disposal of SNF. The WP would be filled with SNF and then filled with depleted uranium (DU) ({approximately}0.2 wt % {sup 235}U) dioxide (UO{sub 2}) or DU silicate-glass beads. Fission products and actinides can not escape the SNF UO{sub 2} crystals until the UO{sub 2} dissolves or is transformed into other chemical species. After WP failure, the DU fill material slows dissolution by three mechanisms: (1) saturation of AT groundwater with DU and suppression of SNF dissolution, (2) maintenance of chemically reducing conditions in the WP that minimize SNF solubility by sacrificial oxidation of DU from the +4 valence state, and (3) evolution of DU to lower-density hydrated uranium silicates. The fill expansion seals the WP from water flow. The DU also isotopically exchanges with SNF uranium as the SNF degrades to reduce long-term nuclear-criticality concerns.

  9. The Modeling of Advanced BWR Fuel Designs with the NRC Fuel Depletion Codes PARCS/PATHS

    DOE PAGES-Beta [OSTI]

    Ward, Andrew; Downar, Thomas J.; Xu, Y.; March-Leuba, Jose A; Thurston, Carl; Hudson, Nathanael H.; Ireland, A.; Wysocki, A.

    2015-04-22

    The PATHS (PARCS Advanced Thermal Hydraulic Solver) code was developed at the University of Michigan in support of U.S. Nuclear Regulatory Commission research to solve the steady-state, two-phase, thermal-hydraulic equations for a boiling water reactor (BWR) and to provide thermal-hydraulic feedback for BWR depletion calculations with the neutronics code PARCS (Purdue Advanced Reactor Core Simulator). The simplified solution methodology, including a three-equation drift flux formulation and an optimized iteration scheme, yields very fast run times in comparison to conventional thermal-hydraulic systems codes used in the industry, while still retaining sufficient accuracy for applications such as BWR depletion calculations. Lastly, themore » capability to model advanced BWR fuel designs with part-length fuel rods and heterogeneous axial channel flow geometry has been implemented in PATHS, and the code has been validated against previously benchmarked advanced core simulators as well as BWR plant and experimental data. We describe the modifications to the codes and the results of the validation in this paper.« less

  10. Packaging and Disposal of a Radium-beryllium Source using Depleted Uranium Polyethylene Composite Shielding

    SciTech Connect (OSTI)

    Keith Rule; Paul Kalb; Pete Kwaschyn

    2003-02-11

    Two, 111-GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from the Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (depleted uranium and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  11. Effects of Bismuth on Wide-Depletion-Width GaInNAs Solar Cells

    SciTech Connect (OSTI)

    Ptak, A. J.; France, R.; Jiang, C.-S.; Reedy, R. C.

    2008-05-01

    GaInNAs solar cells could be useful in next-generation multijunction solar cells if issues surrounding low photocurrents and photovoltages are surmounted. Wide-depletion-width devices generate significant photocurrent using a p-i-n structure grown by molecular beam epitaxy, but these depletion widths are only realized in a region of parameter space that leads to rough surface morphologies. Here, bismuth is explored as a surfactant for the growth of GaInNAs solar cells. Very low fluxes of Bi are effective at maintaining smooth surfaces, even at high growth temperatures and In contents. However, Bi also increases the net donor concentration in these materials, manifested in our n-on-p device structures as a pn-junction that moves deeper into the base layer with increasing Bi fluxes. Quantum efficiency modeling and scanning kelvin probe microscopy measurements confirm the type conversion of the base layer from p type to n type. Bi incorporation in GaAsBi samples shows signs of surface segregation, leading to a finite buildup time, and this effect may lead to slow changes in the electrical properties of the GaInNAs(Bi) devices. Bi also appears to create a defect level, although this defect level is not deleterious enough to increase the dark current in the devices.

  12. The Modeling of Advanced BWR Fuel Designs with the NRC Fuel Depletion Codes PARCS/PATHS

    SciTech Connect (OSTI)

    Ward, Andrew; Downar, Thomas J.; Xu, Y.; March-Leuba, Jose A; Thurston, Carl; Hudson, Nathanael H.; Ireland, A.; Wysocki, A.

    2015-04-22

    The PATHS (PARCS Advanced Thermal Hydraulic Solver) code was developed at the University of Michigan in support of U.S. Nuclear Regulatory Commission research to solve the steady-state, two-phase, thermal-hydraulic equations for a boiling water reactor (BWR) and to provide thermal-hydraulic feedback for BWR depletion calculations with the neutronics code PARCS (Purdue Advanced Reactor Core Simulator). The simplified solution methodology, including a three-equation drift flux formulation and an optimized iteration scheme, yields very fast run times in comparison to conventional thermal-hydraulic systems codes used in the industry, while still retaining sufficient accuracy for applications such as BWR depletion calculations. Lastly, the capability to model advanced BWR fuel designs with part-length fuel rods and heterogeneous axial channel flow geometry has been implemented in PATHS, and the code has been validated against previously benchmarked advanced core simulators as well as BWR plant and experimental data. We describe the modifications to the codes and the results of the validation in this paper.

  13. Dynamics of Microbial Community Composition and Function during In Situ Bioremediation of a Uranium-Contaminated Aquifer

    SciTech Connect (OSTI)

    Van Nostrand, Dr. Joy D.; Wu, Liyou; Wu, Weimin; Huang, Zhijian; Gentry, Terry J; Deng, Ye; Carley, Jack M; Carroll, Sue L; He, Zhili; Gu, Baohua; Luo, Jian; Criddle, Craig; Watson, David B; Jardine, Philip M; Marsh, Terence; Tiedje, James; Hazen, Terry; Zhou, Jizhong

    2011-01-01

    A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter 1). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process.

  14. Dynamics of microbial community composition and function during in-situ bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Nostrand, J.D. Van; Wu, L.; Wu, W.M.; Huang, A.; Gentry, T.J.; Deng, Y.; Carley, J.; Carrol, S.; He, Z.; Gu, B.; Luo, J.; Criddle, C.S.; Watson, D.B.; Jardine, P.M.; Marsh, T.L.; Tiedje, J.M.; Hazen, T.C.; Zhou, J.

    2010-08-15

    A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter{sup -1}). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process.

  15. Issues Related to Seismic Activity Induced by the Injection of CO2 in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Sminchak, Joel; Gupta, Neeraj; Byrer, Charles; Bergman, Perry

    2001-05-31

    Case studies, theory, regulation, and special considerations regarding the disposal of carbon dioxide (CO2) into deep saline aquifers were investigated to assess the potential for induced seismic activity. Formations capable of accepting large volumes of CO2 make deep well injection of CO2 an attractive option. While seismic implications must be considered for injection facilities, induced seismic activity may be prevented through proper siting, installation, operation, and monitoring. Instances of induced seismic activity have been documented at hazardous waste disposal wells, oil fields, and other sites. Induced seismic activity usually occurs along previously faulted rocks and may be investigated by analyzing the stress conditions at depth. Seismic events are unlikely to occur due to injection in porous rocks unless very high injection pressures cause hydraulic fracturing. Injection wells in the United States are regulated through the Underground Injection Control (UIC) program. UIC guidance requires an injection facility to perform extensive characterization, testing, and monitoring. Special considerations related to the properties of CO2 may have seismic ramifications to a deep well injection facility. Supercritical CO2 liquid is less dense than water and may cause density-driven stress conditions at depth or interact with formation water and rocks, causing a reduction in permeability and pressure buildup leading to seismic activity. Structural compatibility, historical seismic activity, cases of seismic activity triggered by deep well injection, and formation capacity were considered in evaluating the regional seismic suitability in the United States. Regions in the central, midwestern, and southeastern United States appear best suited for deep well injection. In Ohio, substantial deep well injection at a waste disposal facility has not caused seismic events in a seismically active area. Current

  16. Influence of Carbon and Microbial Community Priming on the Attenuation of Uranium in a Contaminated Floodplain Aquifer

    SciTech Connect (OSTI)

    Mouser, Paula J.; N'Guessan, A. Lucie; Qafoku, Nikolla; Sinha, M.; Williams, K. H.; Dangelmayr, M.; Resch, Charles T.; Peacock, Aaron D.; Wang, Zheming; Figueroa, Linda A.; Long, P. E.

    2015-07-01

    The capacity for subsurface sediments to sequester metal contaminants, such as uranium (U), and retain them after bioremediation efforts are completed is critical to site stewardship. Sediments enriched in natural organic matter are capable of sequestering significant quantities of U, but may also serve as sources to the aquifer, contributing to plume persistence. Two types of sediments were compared to better understand the mechanisms contributing to the sequestration and release of U in the presence of organic matter. Artificially bioreduced sediments were retrieved from a field experimental plot previously stimulated with acetate while naturally bioreduced sediments were collected from a location enriched in organic matter but never subject to acetate amendment. Batch incubations demonstrated that the artificially bioreduced sediments were primed to rapidly remove uranium from the groundwater whereas naturally bioreduced sediments initially released a sizeable portion of sediment U before U(VI)-removal commenced. Column experiments confirmed that U release persisted for 65 pore volumes in naturally bioreduced sediments, demonstrating the sink-source behavior of this sediment. Acetate addition to artificially bioreduced sediments shifted the microbial community from one dominated by sulfate-reducing bacteria within Desulfobacteraceae to the iron-reducing family Geobacteraceae and Firmicutes during U(VI) reduction. In contrast, initial Geobacteraceae communities innaturally reduced sediments were replaced by clone sequences with similarity to opportunistic Pseudomonas spp. during U release, while U(VI) removal occurred concurrent with enrichment of Firmicutes. These investigations stress the importance of characterizing zones with heterogeneous carbon pools at U contaminated sites prior to the determination of a remedial strategy.

  17. Computer program for predicting surface subsidence resulting from pressure depletion in geopressured wells: subsidence prediction for the DOW test well No. 1, Parcperdue, Louisiana

    SciTech Connect (OSTI)

    Janssen, J.C.; Carver, D.R.; Bebout, D.G.; Bachman, A.L.

    1981-01-01

    The nucleus-of-strain concept is used to construct a computer program for predicting surface subsidence due to pressure reduction in geopressured reservoirs. Numerical integration allows one to compute the vertical displacement of the ground surface directly above and beyond the aquifer boundaries which results from the pressure reduction in each of the small finite volumes into which the aquifer is partitioned. The program treats depth (measured from the surface to the mean thickness of the aquifer) as a constant. Variation in aquifer thickness is accounted for by linear interpolation from one boundary to its opposite. In this simple model, subsidence is proportional to the pressure reduction (considered constant in this presentation) and to but one physical parameter, Cm(1-..nu..), in which Cm is its coefficient of uniaxial compaction, and ..nu.. is Poisson's ratio.

  18. D0 Decomissioning : Storage of Depleted Uranium Modules Inside D0 Calorimeters after the Termination of D0 Experiment

    SciTech Connect (OSTI)

    Sarychev, Michael; /Fermilab

    2011-09-21

    Dzero liquid Argon calorimeters contain hadronic modules made of depleted uranium plates. After the termination of DO detector's operation, liquid Argon will be transferred back to Argon storage Dewar, and all three calorimeters will be warmed up. At this point, there is no intention to disassemble the calorimeters. The depleted uranium modules will stay inside the cryostats. Depleted uranium is a by-product of the uranium enrichment process. It is slightly radioactive, emits alpha, beta and gamma radiation. External radiation hazards are minimal. Alpha radiation has no external exposure hazards, as dead layers of skin stop it; beta radiation might have effects only when there is a direct contact with skin; and gamma rays are negligible - levels are extremely low. Depleted uranium is a pyrophoric material. Small particles (such as shavings, powder etc.) may ignite with presence of Oxygen (air). Also, in presence of air and moisture it can oxidize. Depleted uranium can absorb moisture and keep oxidizing later, even after air and moisture are excluded. Uranium oxide can powder and flake off. This powder is also pyrographic. Uranium oxide may create health problems if inhaled. Since uranium oxide is water soluble, it may enter the bloodstream and cause toxic effects.

  19. The depletion of Interleukin-8 causes cell cycle arrest and increases the efficacy of docetaxel in breast cancer cells

    SciTech Connect (OSTI)

    Shao, Nan; Chen, Liu-Hua; Ye, Run-Yi; Lin, Ying; Wang, Shen-Ming

    2013-02-15

    Highlights: ► IL-8 depletion affects cell cycle distribution. ► Intrinsic IL-8 mediates breast cancer cell migration and invasion. ► IL-8 siRNA down regulates key factors that control survival and metastatic pathway. ► IL-8 depletion reduces integrin β3 expression. ► IL-8 depletion increases the chemosensitivity to docetaxel. -- Abstract: IL-8 is a multi-functional pro-inflammatory chemokine, which is highly expressed in cancers, such as ER-negative breast cancer. The present study demonstrates the pervasive role of IL-8 in the malignant progression of ER-negative breast cancer. IL-8 siRNA inhibited proliferation and delayed the G1 to S cell cycle progression in MDA-MB-231 and BT549 cells. IL-8 silencing resulted in the upregulation of the CDK inhibitor p27, the downregulation of cyclin D1, and the reduction of phosphorylated-Akt and NF-κB activities. IL-8 depletion also increased the chemosensitivity to docetaxel. These results indicate a role for IL-8 in promoting tumor cell survival and resistance to docetaxel and highlight the potential therapeutic significance of IL-8 depletion in ER-negative breast cancer patients.

  20. Electrodic voltages accompanying stimulated bioremediation of a uranium-contaminated aquifer

    SciTech Connect (OSTI)

    Williams, K.H.; N'Guessan, A.L.; Druhan, J.; Long, P.E.; Hubbard, S.S.; Lovley, D.R.; Banfield, J.F.

    2009-11-15

    The inability to track the products of subsurface microbial activity during stimulated bioremediation has limited its implementation. We used spatiotemporal changes in electrodic potentials (EP) to track the onset and persistence of stimulated sulfate-reducing bacteria in a uranium-contaminated aquifer undergoing acetate amendment. Following acetate injection, anomalous voltages approaching -900 mV were measured between copper electrodes within the aquifer sediments and a single reference electrode at the ground surface. Onset of EP anomalies correlated in time with both the accumulation of dissolved sulfide and the removal of uranium from groundwater. The anomalies persisted for 45 days after halting acetate injection. Current-voltage and current-power relationships between measurement and reference electrodes exhibited a galvanic response, with a maximum power density of 10 mW/m{sup 2} during sulfate reduction. We infer that the EP anomalies resulted from electrochemical differences between geochemically reduced regions and areas having higher oxidation potential. Following the period of sulfate reduction, EP values ranged from -500 to -600 mV and were associated with elevated concentrations of ferrous iron. Within 10 days of the voltage decrease, uranium concentrations rebounded from 0.2 to 0.8 {mu}M, a level still below the background value of 1.5 {mu}M. These findings demonstrate that EP measurements provide an inexpensive and minimally invasive means for monitoring the products of stimulated microbial activity within aquifer sediments and are capable of verifying maintenance of redox conditions favorable for the stability of bioreduced contaminants, such as uranium.

  1. Sleuthing the Fate of Water in Ancient Aquifers and Ice Cores | U.S. DOE

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    Office of Science (SC) Sleuthing the Fate of Water in Ancient Aquifers and Ice Cores Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information » 10.01.12 Sleuthing the Fate of

  2. Application of three aquifer test methods for estimating hydraulic properties within the 100-N Area

    SciTech Connect (OSTI)

    Gilmore, T.J.; Spane, F.A. Jr.; Newcomer, D.R.; Sherwood, C.R.

    1992-12-01

    The purpose if this study was to better define the range of saturated horizontal hydraulic conductivities in the 100-N Area of the Hanford Site in southeastern Washington for use in a numerical groundwater model. Three methods were used for determining aquifer properties and are discussed within this report (1) reanalysis of past pumping test data using a pressure derivative method to identify the data in the radial flow regime for analysis by traditional graphical techniques, (2) sinusoidal analysis techniques described in Ferris that utilize water-table responses to river-level variations, and (3) the basic flow equation for groundwater.

  3. Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

    SciTech Connect (OSTI)

    Bencini, A.; Ercolanelli, R.; Sbaragli, A.

    1993-11-01

    Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

  4. Geostatistical analysis of potentiometric data in Wolfcamp aquifer of the Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Harper, W.V.; Furr, J.M.

    1986-04-01

    This report details a geostatistical analysis of potentiometric data from the Wolfcamp aquifer in the Palo Duro Basin, Texas. Such an analysis is a part of an overall uncertainty analysis for a high-level waste repository in salt. Both an expected potentiometric surface and the associated standard error surface are produced. The Wolfcamp data are found to be well explained by a linear trend with a superimposed spherical semivariogram. A cross-validation of the analysis confirms this. In addition, the cross-validation provides a point-by-point check to test for possible anomalous data.

  5. Prickett and Lonnquist aquifer simulation program for the Apple II minicomputer

    SciTech Connect (OSTI)

    Hull, L.C.

    1983-02-01

    The Prickett and Lonnquist two-dimensional groundwater model has been programmed for the Apple II minicomputer. Both leaky and nonleaky confined aquifers can be simulated. The model was adapted from the FORTRAN version of Prickett and Lonnquist. In the configuration presented here, the program requires 64 K bits of memory. Because of the large number of arrays used in the program, and memory limitations of the Apple II, the maximum grid size that can be used is 20 rows by 20 columns. Input to the program is interactive, with prompting by the computer. Output consists of predicted lead values at the row-column intersections (nodes).

  6. Analysis of shear banding in Armco IF iron, tungsten alloy, and depleted uranium

    SciTech Connect (OSTI)

    Barta, R.C.; Kim, C.H.

    1992-03-01

    We study the problem of the initiation and growth of shear bands in three materials by analyzing the thermomechanical deformations of a block of nonuniform thickness undergoing overall simple shearing deformations. Each of these materials is assumed to obey the Johnson-Cook law. It is found that, for each material, the deformations of the block have become nonhomogeneous by the time the shear stress attains its maximum value. For Armco IF iron, a narrow band at the center develops when the shear stress there has dropped to 85% of its peak value, and the same occurs for the tungsten alloy when the shear stress at the specimen center equals 80% of the maximum value. For the depleted uranium satisfactory results could be computed only till the shear stress dropped to 99% of the peak value.

  7. Theophylline prevents NAD{sup +} depletion via PARP-1 inhibition in human pulmonary epithelial cells

    SciTech Connect (OSTI)

    Moonen, Harald J.J. . E-mail: h.moonen@grat.unimaas.nl; Geraets, Liesbeth; Vaarhorst, Anika; Bast, Aalt; Wouters, Emiel F.M.; Hageman, Geja J.

    2005-12-30

    Oxidative DNA damage, as occurs during exacerbations in chronic obstructive pulmonary disease (COPD), highly activates the nuclear enzyme poly(ADP-ribose)polymerase-1 (PARP-1). This can lead to cellular depletion of its substrate NAD{sup +}, resulting in an energy crisis and ultimately in cell death. Inhibition of PARP-1 results in preservation of the intracellular NAD{sup +} pool, and of NAD{sup +}-dependent cellular processes. In this study, PARP-1 activation by hydrogen peroxide decreased intracellular NAD{sup +} levels in human pulmonary epithelial cells, which was found to be prevented in a dose-dependent manner by theophylline, a widely used compound in the treatment of COPD. This enzyme inhibition by theophylline was confirmed in an ELISA using purified human PARP-1 and was found to be competitive by nature. These findings provide new mechanistic insights into the therapeutic effect of theophylline in oxidative stress-induced lung pathologies.

  8. Conclusions of the Capstone Depleted Uranium Aerosol Characterization and Risk Assessment Study

    SciTech Connect (OSTI)

    Parkhurst, MaryAnn; Guilmette, Raymond A.

    2009-02-26

    The rationale for the Capstone Depleted Uranium (DU) Aerosol Characterization and Risk Assessment Program and its results and applications have been examined in the previous 13 articles of this special issue. This paper summarizes the results and discusses its successes and lessons learned. The robust data from the Capstone DU Aerosol Study have provided a sound basis for assessing the inhalation exposure to DU aerosols and the dose and risk to personnel in combat vehicles at the time of perforation and to those entering immediately after perforation. The Human Health Risk Assessment provided a technically sound process for evaluating chemical and radiological doses and risks from DU aerosol exposure using well-accepted biokinetic and dosimetric models innovatively applied. An independent review of the study process and results is summarized, and recommendations for possible avenues of future study by the authors and by other major reviews of DU health hazards are provided.

  9. Multi-images deconvolution improves signal-to-noise ratio on gated stimulated emission depletion microscopy

    SciTech Connect (OSTI)

    Castello, Marco; Diaspro, Alberto; Vicidomini, Giuseppe

    2014-12-08

    Time-gated detection, namely, only collecting the fluorescence photons after a time-delay from the excitation events, reduces complexity, cost, and illumination intensity of a stimulated emission depletion (STED) microscope. In the gated continuous-wave- (CW-) STED implementation, the spatial resolution improves with increased time-delay, but the signal-to-noise ratio (SNR) reduces. Thus, in sub-optimal conditions, such as a low photon-budget regime, the SNR reduction can cancel-out the expected gain in resolution. Here, we propose a method which does not discard photons, but instead collects all the photons in different time-gates and recombines them through a multi-image deconvolution. Our results, obtained on simulated and experimental data, show that the SNR of the restored image improves relative to the gated image, thereby improving the effective resolution.

  10. Strategy for Characterizing Transuranics and Technetium Contamination in Depleted UF{sub 6} Cylinders

    SciTech Connect (OSTI)

    Hightower, J.R.

    2000-10-26

    This report summarizes results of a study performed to develop a strategy for characterization of low levels of radioactive contaminants [plutonium (Pu), neptunium (Np), americium (Am), and technetium (Tc)] in depleted uranium hexafluoride (DUF{sub 6}) cylinders at the gaseous diffusion plants in Oak Ridge, Tennessee; Paducah, Kentucky; and Piketon, Ohio. In these gaseous diffusion plants, this radioactivity came from enriching recycled uranium (the so-called ''reactor returns'') from Savannah River, South Carolina, and Hanford, Washington, reactors. Results of this study will be used to support a request for proposals to design, build, and operate facilities to convert the DUF{sub 6} to more chemically stable forms. These facilities would need to be designed to handle any transuranic contaminants that might be present in order to (1) protect the workers' health and safety and (2) protect the public and the environment.

  11. Revenue ruling 73-538: the service's assault on percentage depletion for ''D'' miners

    SciTech Connect (OSTI)

    Barnes, D.A.

    1983-01-01

    In this article, the author examines the Internal Revenue Service's ruling that storage and loading for shipment at the mine site are nonmining processes for ores and minerals described in section 613(c)(4)(D) of the Internal Revenue Code. He explains the tax consequences of the ruling and discusses the correctness of the position taken by the Internal Revenue Service in light of the relevant case law and the language and legislative history of the statute. The effect of the ruling is to reduce the percentage depletion deduction available to many miners of ores and minerals described in section 613(c)(4)(D), including miners of lead, zinc, copper, gold, silver, uranium, fluorspar, potash, soda ash, garnet and tungsten. (JMT)

  12. Manufacturing Process Development to Produce Depleted Uranium Wire for EBAM Feedstock

    SciTech Connect (OSTI)

    Alexander, David John; Clarke, Kester Diederik; Coughlin, Daniel Robert; Scott, Jeffrey E.

    2015-06-30

    Wire produced from depleted uranium (DU) is needed as feedstock for the Electron-Beam Additive Manufacturing (EBAM) process. The goal is to produce long lengths of DU wire with round or rectangular cross section, nominally 1.5 mm (0.060 inches). It was found that rolling methods, rather than swaging or drawing, are preferable for production of intermediate quantities of DU wire. Trials with grooveless rolling have shown that it is suitable for initial reductions of large stock. Initial trials with grooved rolling have been successful, for certain materials. Modified square grooves (square round-bottom vee grooves) with 12.5 % reduction of area per pass have been selected for the reduction process.

  13. {sup 1}H NMR relaxometry as an indicator of setting and water depletion during cement hydration

    SciTech Connect (OSTI)

    Wang, Biyun; Faure, Paméla; Thiéry, Mickaël; Baroghel-Bouny, Véronique

    2013-03-15

    Proton nuclear magnetic resonance relaxometry has been used to detect setting and microstructure evolution during cement hydration. NMR measurements were performed since casting, during setting and until hardening (from 0 to 3 days). The mobility of water molecules was assessed by an analysis focused on the diagram of longitudinal relaxation time T{sub 1} generated by an Inversion Recovery sequence. The initial stiffening of the solid network was identified by an analysis of the relaxation rate 1/T{sub 1}. The kinetics of water depletion was investigated by using a simple one-pulse acquisition sequence. In parallel, conventional techniques (Vicat needle and temperature monitoring), as well as numerical simulations of hydration, were used to complement and validate these NMR results. Cement pastes and mortars with different water-to-cement ratios made of grey or white OPCs were tested. Furthermore, the effects of the addition of sand, super-plasticizer and silica fume on the hydration kinetics were investigated.

  14. Using Hydro-Cutting to Aid in Remediation of a Firing Range Contaminated with Depleted Uranium

    SciTech Connect (OSTI)

    Styvaert, Michael S.; Conley, Richard D.; Watters, David J.

    2003-02-24

    This paper describes the challenges encountered in decommissioning a firing range that had been used to test fire depleted uranium rounds in the late 1950's and early 1960's. The paper details the operational challenges and innovative solutions involved in remediating and decommissioning a firing range bullet catcher once unexploded ordnance was discovered. It also discusses how the Army dealt with an intertwining web of regulatory and permit issues that arose in treating and disposing of multiple waste streams. The paper will show how the use of a Resource Conservation and Recovery Act (RCRA) Temporary Authorization allowed the Army to deal with the treatment of a variety of waste streams and how hydro-cutting process was used to demilitarize the potentially unexploded rounds.

  15. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update

    Capacity Definitions Key Terms Definition Aquifer Storage Field A sub-surface facility for storing natural gas, consisting of water-bearing sands topped by an impermeable cap rock. Depleted Reservoir Storage Field A sub-surface natural geological reservoir, usually a depleted gas or oil field, used for storing natural gas. Natural Gas A gaseous mixture of hydrocarbon compounds, the primary one being methane. Salt Dome Storage Field (Salt Cavern) A storage facility that is a cavern hollowed out

  16. Environmental acceptability of high-performance alternatives for depleted uranium penetrators

    SciTech Connect (OSTI)

    Kerley, C.R.; Easterly, C.E.; Eckerman, K.F.

    1996-08-01

    The Army`s environmental strategy for investigating material substitution and management is to measure system environmental gains/losses in all phases of the material management life cycle from cradle to grave. This study is the first in a series of new investigations, applying material life cycle concepts, to evaluate whether there are environmental benefits from increasing the use of tungsten as an alternative to depleted uranium (DU) in Kinetic Energy Penetrators (KEPs). Current military armor penetrators use DU and tungsten as base materials. Although DU alloys have provided the highest performance of any high-density alloy deployed against enemy heavy armor, its low-level radioactivity poses a number of environmental risks. These risks include exposures to the military and civilian population from inhalation, ingestion, and injection of particles. Depleted uranium is well known to be chemically toxic (kidney toxicity), and workplace exposure levels are based on its renal toxicity. Waste materials containing DU fragments are classified as low-level radioactive waste and are regulated by the Nuclear Regulatory Commission. These characteristics of DU do not preclude its use in KEPs. However, long-term management challenges associated with KEP deployment and improved public perceptions about environmental risks from military activities might be well served by a serious effort to identify, develop, and substitute alternative materials that meet performance objectives and involve fewer environmental risks. Tungsten, a leading candidate base material for KEPS, is potentially such a material because it is not radioactive. Tungsten is less well studied, however, with respect to health impacts and other environmental risks. The present study is designed to contribute to the understanding of the environmental behavior of tungsten by synthesizing available information that is relevant to its potential use as a penetrator.

  17. Cadmium Depletion Impacts on Hardening Neutron6 Spectrum for Advanced Fuel Testing in ATR

    SciTech Connect (OSTI)

    Gray S. Chang

    2011-05-01

    For transmuting long-lived isotopes contained in spent nuclear fuel into shorter-lived fission products effectively is in a fast neutron spectrum reactor. In the absence of a fast spectrum test reactor in the United States of America (USA), initial irradiation testing of candidate fuels can be performed in a thermal test reactor that has been modified to produce a test region with a hardened neutron spectrum. A test region is achieved with a Cadmium (Cd) filter which can harden the neutron spectrum to a spectrum similar (although still somewhat softer) to that of the liquid metal fast breeder reactor (LMFBR). A fuel test loop with a Cd-filter has been installed within the East Flux Trap (EFT) of the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL). A detailed comparison analyses between the cadmium (Cd) filter hardened neutron spectrum in the ATR and the LMFBR fast neutron spectrum have been performed using MCWO. MCWO is a set of scripting tools that are used to couple the Monte Carlo transport code MCNP with the isotope depletion and buildup code ORIGEN-2.2. The MCWO-calculated results indicate that the Cd-filter can effectively flatten the Rim-Effect and reduce the linear heat rate (LHGR) to meet the advanced fuel testing project requirements at the beginning of irradiation (BOI). However, the filtering characteristics of Cd as a strong absorber quickly depletes over time, and the Cd-filter must be replaced for every two typical operating cycles within the EFT of the ATR. The designed Cd-filter can effectively depress the LHGR in experimental fuels and harden the neutron spectrum enough to adequately flatten the Rim Effect in the test region.

  18. Evaluation of the Acceptability of Potential Depleted Uranium Hexafluoride Conversion Products at the Envirocare Disposal Site

    SciTech Connect (OSTI)

    Croff, A.G.

    2001-01-11

    The purpose of this report is to review and document the capability of potential products of depleted UF{sub 6} conversion to meet the current waste acceptance criteria and other regulatory requirements for disposal at the facility in Clive, Utah, owned by Envirocare of Utah, Inc. The investigation was conducted by identifying issues potentially related to disposal of depleted uranium (DU) products at Envirocare and conducting an initial analysis of them. Discussions were then held with representatives of Envirocare, the state of Utah (which is a NRC Agreement State and, thus, is the cognizant regulatory authority for Envirocare), and DOE Oak Ridge Operations. Provisional issue resolution was then established based on the analysis and discussions and documented in a draft report. The draft report was then reviewed by those providing information and revisions were made, which resulted in this document. Issues that were examined for resolution were (1) license receipt limits for U isotopes; (2) DU product classification as Class A waste; (3) use of non-DOE disposal sites for disposal of DOE material; (4) historical NRC views; (5) definition of chemical reactivity; (6) presence of mobile radionuclides; and (7) National Environmental Policy Act coverage of disposal. The conclusion of this analysis is that an amendment to the Envirocare license issued on October 5, 2000, has reduced the uncertainties regarding disposal of the DU product at Envirocare to the point that they are now comparable with uncertainties associated with the disposal of the DU product at the Nevada Test Site that were discussed in an earlier report.

  19. Preconceptual design studies and cost data of depleted uranium hexafluoride conversion plants

    SciTech Connect (OSTI)

    Jones, E

    1999-07-26

    One of the more important legacies left with the Department of Energy (DOE) after the privatization of the United States Enrichment Corporation is the large inventory of depleted uranium hexafluoride (DUF6). The DOE Office of Nuclear Energy, Science and Technology (NE) is responsible for the long-term management of some 700,000 metric tons of DUF6 stored at the sites of the two gaseous diffusion plants located at Paducah, Kentucky and Portsmouth, Ohio, and at the East Tennessee Technology Park in Oak Ridge, Tennessee. The DUF6 management program resides in NE's Office of Depleted Uranium Hexafluoride Management. The current DUF6 program has largely focused on the ongoing maintenance of the cylinders containing DUF6. However, the long-term management and eventual disposition of DUF6 is the subject of a Programmatic Environmental Impact Statement (PEIS) and Public Law 105-204. The first step for future use or disposition is to convert the material, which requires construction and long-term operation of one or more conversion plants. To help inform the DUF6 program's planning activities, it was necessary to perform design and cost studies of likely DUF6 conversion plants at the preconceptual level, beyond the PEIS considerations but not as detailed as required for conceptual designs of actual plants. This report contains the final results from such a preconceptual design study project. In this fast track, three month effort, Lawrence Livermore National Laboratory and Bechtel National Incorporated developed and evaluated seven different preconceptual design cases for a single plant. The preconceptual design, schedules, costs, and issues associated with specific DUF6 conversion approaches, operating periods, and ownership options were evaluated based on criteria established by DOE. The single-plant conversion options studied were similar to the dry-conversion process alternatives from the PEIS. For each of the seven cases considered, this report contains information on

  20. Microscale depletion of high abundance proteins in human biofluids using IgY14 immunoaffinity resin: Analysis of human plasma and cerebrospinal fluid

    DOE PAGES-Beta [OSTI]

    Hyung, Seok Won; Piehowski, Paul D.; Moore, Ronald J.; Orton, Daniel J.; Schepmoes, Athena A.; Clauss, Therese R.; Chu, Rosalie K.; Fillmore, Thomas L.; Brewer, Heather M.; Liu, Tao; et al

    2014-09-06

    Removal of highly abundant proteins in plasma is often carried out using immunoaffinity depletion to extend the dynamic range of measurements to lower abundance species. While commercial depletion columns are available for this purpose, they generally are not applicable to limited sample quantities (<20 µL) due to low yields stemming from losses caused by nonspecific binding to the column matrix. Additionally, the cost of the depletion media can be prohibitive for larger scale studies. Modern LC-MS instrumentation provides the sensitivity necessary to scale-down depletion methods with minimal sacrifice to proteome coverage, which makes smaller volume depletion columns desirable for maximizingmore » sample recovery when samples are limited, as well as for reducing the expense of large scale studies. We characterized the performance of a 346 µL column volume micro-scale depletion system, using four different flow rates to determine the most effective depletion conditions for ~6 μL injections of human plasma proteins and then evaluated depletion reproducibility at the optimum flow rate condition. Depletion of plasma using a commercial 10 mL depletion column served as the control. Results showed depletion efficiency of the micro-scale column increased as flow rate decreased, and that our micro-depletion was reproducible. We found, in an initial application, a 600 µL sample of human cerebral spinal fluid (CSF) pooled from multiple sclerosis patients was depleted and then analyzed using reversed phase liquid chromatography-mass spectrometry to demonstrate the utility of the system for this important biofluid where sample quantities are more commonly limited.« less

  1. Total Reducing Capacity in Aquifer Minerals and Sediments: Quantifying the Potential to Attenuate Cr(VI) in Groundwater

    SciTech Connect (OSTI)

    Sisman, S. Lara

    2015-07-20

    Hexavalent chromium, Cr(VI), is present in the environment as a byproduct of industrial processes. Due to its mobility and toxicity, it is crucial to attenuate or remove Cr(VI) from the environment. The objective of this investigation was to quantify potential natural attenuation, or reduction capacity, of reactive minerals and aquifer sediments. Samples of reduced-iron containing minerals such as ilmenite, as well as Puye Formation sediments representing a contaminated aquifer in New Mexico, were reacted with chromate. The change in Cr(VI) during the reaction was used to calculate reduction capacity. This study found that minerals that contain reduced iron, such as ilmenite, have high reducing capacities. The data indicated that sample history may impact reduction capacity tests due to surface passivation. Further, this investigation identified areas for future research including: a) refining the relationships between iron content, magnetic susceptibility and reduction capacity, and b) long term kinetic testing using fresh aquifer sediments.

  2. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE PAGES-Beta [OSTI]

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  3. CRC DEPLETION CALCULATIONS FOR THE RODDED ASSEMBLIES IN BATCHES 1, 2, 3, AND 1X OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-09-03

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain rodded fuel assemblies from batches 1, 2, 3, and 1X of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A rodded assembly is one that contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) for some period of time during its irradiation history. The objective of this analysis is to provide SAS2H calculated isotopic compositions of depleted fuel and depleted burnable poison for each fuel assembly to be used in subsequent CRC reactivity calculations containing the fuel assemblies.

  4. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 1, 2, AND 3 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-29

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 1, 2, and 3 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  5. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 4 AND 5 OF CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Kenneth D. Wright

    1997-07-30

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 4 and 5 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  6. CRC DEPLETION CALCULATIONS FOR THE NON-RODDED ASSEMBLIES IN BATCHES 8 AND 9 CRYSTAL RIVER UNIT 3

    SciTech Connect (OSTI)

    Michael L. Wilson

    2001-02-08

    The purpose of this design analysis is to document the SAS2H depletion calculations of certain non-rodded fuel assemblies from batches 8 and 9 of the Crystal River Unit 3 pressurized water reactor (PWR) that are required for Commercial Reactor Critical (CRC) evaluations to support the development of the disposal criticality methodology. A non-rodded assembly is one which never contains a control rod assembly (CRA) or an axial power shaping rod assembly (APSRA) during its irradiation history. The objective of this analysis is to provide SAS2H generated isotopic compositions for each fuel assembly's depleted fuel and depleted burnable poison materials. These SAS2H generated isotopic compositions are acceptable for use in CRC benchmark reactivity calculations containing the various fuel assemblies.

  7. Design and implementation of a CO{sub 2} flood utilizing advanced reservoir characterization and horizontal injection wells in a shallow shelf carbonate approaching waterflood depletion. [Quarterly report], October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    1996-03-21

    The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a CO{sub 2} project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. This report includes work on the reservoir characterization and project design objective. In addition the initiation of the demonstration project objective includes work done in November and December, 1995.

  8. Analysis of temperatures and water levels in wells to estimatealluvial aquifer hydraulic conductivities

    SciTech Connect (OSTI)

    Su, Grace W.; Jasperse, James; Seymour, Donald; Constantz, Jim

    2003-06-19

    Well water temperatures are often collected simultaneously with water levels; however, temperature data are generally considered only as a water quality parameter and are not utilized as an environmental tracer. In this paper, water levels and seasonal temperatures are used to estimate hydraulic conductivities in a stream-aquifer system. To demonstrate this method, temperatures and water levels are analyzed from six observation wells along an example study site, the Russian River in Sonoma County, California. The range in seasonal ground water temperatures in these wells varied from <0.28C in two wells to {approx}88C in the other four wells from June to October 2000. The temperature probes in the six wells are located at depths between 3.5 and 7.1 m relative to the river channel. Hydraulic conductivities are estimated by matching simulated ground water temperatures to the observed ground water temperatures. An anisotropy of 5 (horizontal to vertical hydraulic conductivity) generally gives the best fit to the observed temperatures. Estimated conductivities vary over an order of magnitude in the six locations analyzed. In some locations, a change in the observed temperature profile occurred during the study, most likely due to deposition of fine-grained sediment and organic matter plugging the streambed. A reasonable fit to this change in the temperature profile is obtained by decreasing the hydraulic conductivity in the simulations. This study demonstrates that seasonal ground water temperatures monitored in observation wells provide an effective means of estimating hydraulic conductivities in alluvial aquifers.

  9. Chlorinated degreasing solvents: Physical-chemical properties affecting aquifer contamination and remediation

    SciTech Connect (OSTI)

    Jackson, R.E.; Dwarakanath, V.

    1999-09-30

    Chlorinated degreasing solvents are multicomponent liquids containing not only the chlorinated hydrocarbons with which their name is associated (e.g., trichloroethylene or [TCE], perchloroethylene or [PCE], 1,1,1-trichloroethane [TCA]) but also a number of organic additives included as corrosion inhibitors and antioxidants. The additives, such as 1,4-dioxane, are likely to be of significant public-health importance as ground water contaminants due to their toxicity, solubility, and mobility. Following their use in vapor degreasing systems by industry, chlorinated degreasing solvents will also contain about 25% solubilized oil and grease. A number of physical-chemical properties become especially important in the light of the multicomponent nature of these solvents. First, the higher aqueous solubility and lower sorption of the additives makes it reasonable to expect that faster moving plumes of these solvent additives will precede plumes of the chlorinated hydrocarbons. Second, due to high losses of chlorinated hydrocarbons by volatilization from vapor degreasers during years in the middle of the century, it is probable that background concentrations of these hydrocarbons are present in ground water flow systems due to their downwind washout. Finally, the solubilized oil and grease may cause profound changes to the wettability of aquifer materials contacted by the solvents during their subsurface migration. It is argued, therefore, that the wettability of aquifer materials contaminated by chlorinated degreasing solvents needs to be experimentally determined before remediation of DNAPL at each site, rather than being simply assumed as water wet.

  10. The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-component DNAPLS with surfactant solutions. Topical report

    SciTech Connect (OSTI)

    1995-01-01

    Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Laboratory studies were conducted at the State University of New York at Buffalo (SUNY) while numerical simulation and field work were undertaken by INTERA Inc. in collaboration with Martin Marietta Energy Systems Inc. at the Paducah Gaseous Diffusion Plant (PGDP) in Kentucky. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). Ten of these were capable of solubilizing TCE to concentrations greater than 15,000 mg/L, compared to its aqueous solubility of 1,100 mg/L. Four surfactants were identified as good solubilizers of all three chlorinated solvents. Of these, a secondary alcohol ethoxylate was the first choice for in situ testing because of its excellent solubilizing ability and its low propensity to sorb. However, this surfactant did not meet the Commonwealth of Kentucky`s acceptance criteria. Consequently, it was decided to use a surfactant approved for use by the Food and Drug Administration as a food-grade additive. As a 1% micellar-surfactant solution, this sorbitan monooleate has a solubilization capacity of 16,000 mg TCE/L, but has a higher propensity to sorb to clays than has the alcohol ethoxylate.

  11. Horizontal-well pilot waterflood tests shallow, abandoned field

    SciTech Connect (OSTI)

    McAlpine, J.L. ); Joshi, S.D. )

    1991-08-05

    This paper reports on the suitability of using horizontal wells in a waterflood of shallow, partially depleted sands which will be tested in the Jennings field in Oklahoma. The vertical wells drilled in the Jennings field intersect several well-known formations such as Red Fork, Misner, and Bartlesville sand. Most of these formations have been produced over a number of years, and presently no wells are producing in the field. In the 1940s, 1950s, and 1960s, wells were drilled on 10-acre spacing, and the last well was plugged in 1961. The field was produced only on primary production and produced approximately 1 million bbl of oil. Because the field was not waterflooded, a large potential exists to produce from the field using secondary methods. To improve the economics for the secondary process, a combination of horizontal and vertical wells was considered.

  12. West Virginia Underground Natural Gas Storage Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    531,480 524,324 524,324 524,337 528,637 528,837 1988-2015 Salt Caverns 0 0 0 1999-2015 Aquifers 200 2015-2015 Depleted Fields 531,480 524,324 524,324 524,337 528,637 528,637 1999-2015 Total Working Gas Capacity 260,744 256,692 256,643 258,056 262,305 259,381 2008-2015 Salt Caverns 0 0 0 2012-2015 Aquifers 66 2015-2015 Depleted Fields 260,744 256,692 256,643 258,056 262,305 259,315 2008-2015 Total Number of Existing Fields 32 30 30 30 30 31 1989-2015 Aquifers 1 2015-2015 Depleted Fields 32 30 30

  13. DOE Issues Final Request for Proposal for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities

    Office of Energy Efficiency and Renewable Energy (EERE)

    Cincinnati -- The U.S. Department of Energy (DOE) today issued a Final Request for Proposal (RFP), for the Operation of Depleted Uranium Hexafluoride (DUF6) Conversion Facilities at Paducah, Kentucky and Portsmouth, Ohio. A cost-plus award fee and firm-fixed-price contract line item contract will be awarded from this Final RFP.

  14. Field Sampling Plan for the Distler Brickyard Superfund Site, Hardin County, Kentucky

    SciTech Connect (OSTI)

    J. P. Martin; L. N. Peterson; C. J. Taylor

    1999-08-01

    This plan describes the field and analytical activities to be conducted at the Distler Brickyard Superfund Site, Hardin County, Kentucky, in order to evaluate natural attenuation processes within the aquifer system. Sampling will consist of a single round to take place in October 1999. Analytes will consist of the contaminants of concern (chlorinated aliphatic hydrocarbons), electron donors (non-chlorinated organic compounds), oxidation-reduction indicators, and water quality parameters. These activities are conducted in order to evaluate the water quality parameters. These activities are conducted in order to evaluate the extent to which natural attenuation processes, in the form of anaerobic reductive dechlorination, may be taking place in the aquifer system. These data will then be used to select the appropriate remediation technology for this site.

  15. Field-effect P-N junction

    DOE Patents [OSTI]

    Regan, William; Zettl, Alexander

    2015-05-05

    This disclosure provides systems, methods, and apparatus related to field-effect p-n junctions. In one aspect, a device includes an ohmic contact, a semiconductor layer disposed on the ohmic contact, at least one rectifying contact disposed on the semiconductor layer, a gate including a layer disposed on the at least one rectifying contact and the semiconductor layer and a gate contact disposed on the layer. A lateral width of the rectifying contact is less than a semiconductor depletion width of the semiconductor layer. The gate contact is electrically connected to the ohmic contact to create a self-gating feedback loop that is configured to maintain a gate electric field of the gate.

  16. Assessment of microorganisms from Indonesian Oil Fields

    SciTech Connect (OSTI)

    Kadarwati, S.; Udiharto, M.; Rahman, M.; Jasjfi, E.; Legowo, E.H.

    1995-12-31

    Petroleum resources have been the mainstay of the national development in Indonesia. However, resources are being depleted after over a century of exploitation, while the demand continues to grow with the rapid economic development of the country. In facing the problem, EOR has been applied in Indonesia, such as the steamflooding project in Duri field, but a more energy efficient technology would be preferable. Therefore, MEOR has been recommended as a promising solution. Our study, aimed at finding indigenous microorganisms which can be developed for application in MEOR, has isolated microbes from some oil fields of Indonesia. These microorganisms have been identified, their activities studied, and the effects of their metabolisms examined. This paper describes the research carried out by LEMIGAS in this respect, giving details on the methods of sampling, incubation, identification, and activation of the microbes as well as tests on the effects of their metabolites, with particular attention to those with potential for application in MEOR.

  17. Proceedings of a workshop on uses of depleted uranium in storage, transportation and repository facilities

    SciTech Connect (OSTI)

    1997-12-31

    A workshop on the potential uses of depleted uranium (DU) in the repository was organized to coordinate the planning of future activities. The attendees, the original workshop objective and the agenda are provided in Appendices A, B and C. After some opening remarks and discussions, the objectives of the workshop were revised to: (1) exchange information and views on the status of the Department of Energy (DOE) activities related to repository design and planning; (2) exchange information on DU management and planning; (3) identify potential uses of DU in the storage, transportation, and disposal of high-level waste and spent fuel; and (4) define the future activities that would be needed if potential uses were to be further evaluated and developed. This summary of the workshop is intended to be an integrated resource for planning of any future work related to DU use in the repository. The synopsis of the first day`s presentations is provided in Appendix D. Copies of slides from each presenter are presented in Appendix E.

  18. Modulated Tool-Path Chip Breaking For Depleted Uranium Machining Operations

    SciTech Connect (OSTI)

    Barkman, W. E.; Babelay Jr., E. F.; Smith, K. S.; Assaid T. S.; McFarland, J. T.; Tursky, D. A.

    2010-04-15

    Turning operations involving depleted uranium frequently generate long, stringy chips that present a hazard to both the machinist and the machine tool. While a variety of chip-breaking techniques are available, they generally depend on a mechanism that increases the bending of the chip or the introduction of a one dimensional vibration that produces an interrupted cutting pattern. Unfortunately, neither of these approaches is particularly effective when making a 'light depth-of-cut' on a contoured workpiece. The historical solution to this problem has been for the machinist to use long-handled tweezers to 'pull the chip' and try to keep it submerged in the chip pan; however, this approach is not practical for all machining operations. This paper discusses a research project involving the Y-12 National Security Complex and the University of North Carolina at Charlotte in which unique, oscillatory part programs are used to continuously create an interrupted cut that generates pre-defined, user-selectable chip lengths.

  19. PACKAGING AND DISPOSAL OF A RADIUM BERYLLIUM SOURCE USING DEPLETED URANIUM POLYETHYLENE COMPOSITE SHIELDING.

    SciTech Connect (OSTI)

    RULE,K.; KALB,P.; KWASCHYN,P.

    2003-02-23

    Two, 111 GBq (3 Curie) radium-beryllium (RaBe) sources were in underground storage at the Brookhaven National Laboratory (BNL) since 1988. These sources originated from Princeton Plasma Physics Laboratory (PPPL) where they were used to calibrate neutron detection diagnostics. In 1999, PPPL and BNL began a collaborative effort to expand the use of an innovative pilot-scale technology and bring it to full-scale deployment to shield these sources for eventual transport and burial at the Hanford Burial site. The transport/disposal container was constructed of depleted uranium oxide encapsulated in polyethylene to provide suitable shielding for both gamma and neutron radiation. This new material can be produced from recycled waste products (DU and polyethylene), is inexpensive, and can be disposed with the waste, unlike conventional lead containers, thus reducing exposure time for workers. This paper will provide calculations and information that led to the initial design of the shielding. We will also describe the production-scale processing of the container, cost, schedule, logistics, and many unforeseen challenges that eventually resulted in the successful fabrication and deployment of this shield. We will conclude with a description of the final configuration of the shielding container and shipping package along with recommendations for future shielding designs.

  20. DEPLETION OF MOLECULAR GAS BY AN ACCRETION OUTBURST IN A PROTOPLANETARY DISK

    SciTech Connect (OSTI)

    Banzatti, A.; Pontoppidan, K. M.; Muzerolle, J. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Bruderer, S. [Max-Planck-Institut fr Extraterrestrische Physik, Giessenbachstr. 1, D-85748 Garching bei Mnchen (Germany); Meyer, M. R., E-mail: banzatti@stsci.edu [ETH Zrich, Institut fr Astronomie, Wolfgang-Pauli-Strasse 27, CH-8093 Zrich (Switzerland)

    2015-01-01

    We investigate new and archival 3-5 ?m high-resolution (?3 km s{sup 1}) spectroscopy of molecular gas in the inner disk of the young solar-mass star EX Lupi, taken during and after the strong accretion outburst of 2008. The data were obtained using the CRIRES spectrometer at the European Southern Observatory Very Large Telescope in 2008 and 2014. In 2008, emission lines from CO, H{sub 2}O, and OH were detected with broad profiles tracing gas near and within the corotation radius (0.02-0.3 AU). In 2014, the spectra display marked differences. The CO lines, while still detected, are much weaker, and the H{sub 2}O and OH lines have disappeared altogether. At 3 ?m a veiled stellar photospheric spectrum is observed. Our analysis finds that the molecular gas mass in the inner disk has decreased by an order of magnitude since the outburst, matching a similar decrease in the accretion rate onto the star. We discuss these findings in the context of a rapid depletion of material accumulated beyond the disk corotation radius during quiescent periods, as proposed by models of episodic accretion in EXor-type young stars.

  1. Imaging the Solar Cell P-N Junction and Depletion Region Using Secondary Electron Contrast

    SciTech Connect (OSTI)

    Heath, J. T.; Jiang, C. S.; Al-Jassim, M. M.

    2011-01-01

    We report on secondary electron (SE) images of cross-sectioned multicrystalline Si and GaAs/GaInP solar cell devices, focusing on quantifying the relationship between the apparent n{sup +}-p contrast and characteristic electronic features of the device. These samples allow us to compare the SE signal from devices which have very different physical characteristics: differing materials, diffused junction versus abrupt junction, heterojunction versus homojunction. Despite these differences, we find that the SE image contrast for both types of sample, and as a function of reverse bias across the diode, closely agrees with PC1D simulations of the bulk electrostatic potential in the device, accurately yielding the depletion edge and width. A spatial derivative of the SE data shows a local maximum at the metallurgical junction. Such data are valuable, for example, in studying the conformity of a diffused junction to the textured surface topography. These data also extend our understanding of the origin of the SE contrast.

  2. Analysis of mineral trapping for CO{sub 2} disposal in deep aquifers

    SciTech Connect (OSTI)

    Xu, Tianfu; Apps, John A.; Pruess, Karsten

    2001-07-20

    CO{sub 2} disposal into deep aquifers has been suggested as a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO{sub 2} disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO{sub 2} injection, we have analyzed the impact of CO{sub 2} immobilization through carbonate precipitation. A survey of all major classes of rock-forming minerals, whose alteration would lead to carbonate precipitation, indicated that very few minerals are present in sufficient quantities in aquifer host rocks to permit significant sequestration of CO{sub 2}. We performed batch reaction modeling of the geochemical evolution of three different aquifer mineralogies in the presence of CO{sub 2} at high pressure. Our modeling considered (1) redox processes that could be important in deep subsurface environments, (2) the presence of organic matter, (3) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, and (4) CO{sub 2} solubility dependence on pressure, temperature and salinity of the system. The geochemical evolution under both natural background and CO{sub 2} injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO{sub 2} sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO{sub 2} that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO{sub 2} dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of ferric mineral precursors such as glauconite, which in turn is dependent on the reactivity of associated organic material. The accumulation of carbonates in

  3. Possible Impacts of Global Warming on Hydrology of the Ogallala Aquifer Region

    SciTech Connect (OSTI)

    Rosenberg, Norman J. ); Epstein, Daniel J. ); Wang, Dahong; Vail, Lance W. ); Srinivasan, Ragahvan; Arnold, J G.

    1998-12-01

    The Ogallala or High Plains aquifer provides water for about 20% of the irrigated land in the United States. About 20 km{sup 3} (16.6 million acre-feet) of water are withdrawn annually from this aquifer. In general, recharge has not compensated for withdrawals since major irrigation development began in this region in the 1940s. The mining of the Ogallala has been pictured as an analogue to climate change in that many GCMs predict a warmer and drier future for this region. We anticipate the possible impacts of climate change on the sustainability of the aquifer as a source of water for irrigation and other purposes in the region. We have applied HUMUS, the Hydrologic Unit Model of the U.S. to the Missouri and Arkansas-White-Red water resource regions that overlie the Ogallala. We have imposed three general circulation model (GISS, UKTR and BMRC) projections of future climate change on this region and simulated the changes that may be induced in water yields (runoff plus lateral flow) and ground water recharge. Each GCM was applied to HUMUS at three levels of global mean temperature (GMT) to represent increasing severity of climate change (a surrogate for time). HUMUS was also run at three levels of atmospheric CO2 concentration (hereafter denoted by[CO2]) in order to estimate the impacts of direct CO2 effects on photosynthesis and evapotranspiration. Since the UKTR and GISS GCMs project increased precipitation in the Missouri basin, water yields increase there. The BMRC GCM predicts sharply decreased precipitation and, hence, reduced water yields. Precipitation reductions are even greater in the Arkansas basin under BMRC as are the consequent water yield losses. GISS and UKTR climates lead to only moderate yield losses in the Arkansas. CO2-fertilization reverses these losses and yields increase slightly. CO2 fertilization increases recharge in the base (no climate change) case in both basins. Recharge is reduced under all three GCMs and severities of climate change.

  4. Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivity values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.

  5. Determining flow, recharge, and vadose zonedrainage in anunconfined aquifer from groundwater strontium isotope measurements, PascoBasin, WA

    SciTech Connect (OSTI)

    mjsingleton@lbl.gov

    2004-06-29

    Strontium isotope compositions (87Sr/86Sr) measured in groundwater samples from 273 wells in the Pasco Basin unconfined aquifer below the Hanford Site show large and systematic variations that provide constraints on groundwater recharge, weathering rates of the aquifer host rocks, communication between unconfined and deeper confined aquifers, and vadose zone-groundwater interaction. The impact of millions of cubic meters of wastewater discharged to the vadose zone (103-105 times higher than ambient drainage) shows up strikingly on maps of groundwater 87Sr/86Sr. Extensive access through the many groundwater monitoring wells at the site allows for an unprecedented opportunity to evaluate the strontium geochemistry of a major aquifer, hosted primarily in unconsolidated sediments, and relate it to both long term properties and recent disturbances. Groundwater 87Sr/86Sr increases systematically from 0.707 to 0.712 from west to east across the Hanford Site, in the general direction of groundwater flow, as a result of addition of Sr from the weathering of aquifer sediments and from diffuse drainage through the vadose zone. The lower 87Sr/86Sr groundwater reflects recharge waters that have acquired Sr from Columbia River Basalts. Based on a steady-state model of Sr reactive transport and drainage, there is an average natural drainage flux of 0-1.4 mm/yr near the western margin of the Hanford Site, and ambient drainage may be up to 30 mm/yr in the center of the site assuming an average bulk rock weathering rate of 10-7.5 g/g/yr.

  6. Detection of hexavalent uranium with inline and field-portable immunosensors

    SciTech Connect (OSTI)

    Melton, Scott J.; Yu, Haini; Ali, Mehnaaz F.; Williams, Kenneth H; Wilkins, Michael J.; Long, Philip E.; Blake, Diane A.

    2008-10-02

    An antibody that recognizes a chelated form of hexavalent uranium was used in the development of two different immunosensors for uranium detection. Specifically, these sensors were utilized for the analysis of groundwater samples collected during a 2007 field study of in situ bioremediation in a aquifer located at Rifle, CO. The antibody-based sensors provided data comparable to that obtained using Kinetic Phosphorescence Analysis (KPA). Thus, these novel instruments and associated reagents should provide field researchers and resource managers with valuable new tools for on-site data acquisition.

  7. Contaminant transport in unconfined aquifer, input to low-level tank waste interim performance assessment

    SciTech Connect (OSTI)

    Lu, A.H., Westinghouse Hanford

    1996-08-14

    This report describes briefly the Hanford sitewide groundwater model and its application to the Low-Level Tank Waste Disposal (LLTWD) interim Performance Assessment (PA). The Well Intercept Factor (WIF) or dilution factor from a given areal flux entering the aquifer released from the LLTWD site are calculated for base case and various sensitivity cases. In conjunction with the calculation for released fluxes through vadose zone transport,the dose at the compliance point can be obtained by a simple multiplication. The relative dose contribution from the upstream sources was also calculated and presented in the appendix for an equal areal flux at the LLTWD site. The results provide input for management decisions on remediation action needed for reduction of the released fluxes from the upstream facilities to the allowed level to meet the required dose criteria.

  8. Abiotic/Biotic Degradation and Mineralization of N-Nitrosodimethylamine in Aquifer Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; McKinley, James P.; Breshears, Andrew T.; Crocker, Fiona H.

    2008-10-14

    The N-nitrosodimethylamine (NDMA) degradation rate and mineralization rate were measured in two aquifer sediments that received treatments to create oxic, reducing, and sequential reducing/oxic environments. Chemically reduced sediments rapidly abiotically degraded NDMA to nontoxic dimethylamine (DMA) to parts per trillion levels, then degraded to further products. NDMA was partially mineralized in reduced sediments (6 to 28 percent) at a slow rate (half-life 3,460 h) by an unknown abiotic/biotic pathway. In contrast, NDMA was mineralized more rapidly (half-life 342 h) and to a greater extent (30 to 81 percent) in oxic sediments with propane addition, likely by a propane monooxygenase pathway. NDMA mineralization in sequential reduced sediment followed by oxic sediment treatment did result in slightly more rapid mineralization and a greater mineralization extent relative to reduced systems. These increases were minor, so aerobic NDMA mineralization with oxygen and propane addition was the most viable in situ NDMA mineralization strategy.

  9. Running Out of and Into Oil: Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, D.L.

    2003-11-14

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value. Probability distributions are produced for the year in which conventional oil production peaks for the world as a whole and the year of peak production from regions outside the Middle East. Recent estimates of world oil resources by the United States Geological Survey (USGS), the International Institute of Applied Systems Analysis (IIASA), the World Energy Council (WEC) and Dr. C. Campbell provide alternative views of the extent of ultimate world oil resources. A model of oil resource depletion and expansion for twelve world regions is combined with a market equilibrium model of conventional and unconventional oil supply and demand to create a World Energy Scenarios Model (WESM). The model does not make use of Hubbert curves but instead relies on target reserve-to-production ratios to determine when regional output will begin to decline. The authors believe that their analysis has a bias toward optimism about oil resource availability because it does not attempt to incorporate political or environmental constraints on production, nor does it explicitly include geologic constraints on production rates. Global energy scenarios created by IIASA and WEC provide the context for the risk analysis. Key variables such as the quantity of undiscovered oil and rates of technological progress are treated as probability distributions, rather than constants. Analyses based on the USGS and IIASA resource assessments indicate that conventional oil production outside the Middle East is likely to peak sometime between 2010 and 2030. The most important determinants of the date are the quantity of undiscovered oil, the rate at

  10. System-Scale Model of Aquifer, Vadose Zone, and River Interactions for the Hanford 300 Area - Application to Uranium Reactive Transport

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Bacon, Diana H.; Freedman, Vicky L.; Parker, Kyle R.; Waichler, Scott R.; Williams, Mark D.

    2013-10-01

    This report represents a synthesis and integration of basic and applied research into a system-scale model of the Hanford 300 Area groundwater uranium plume, supported by the U.S. Department of Energy’s Richland Operations (DOE-RL) office. The report integrates research findings and data from DOE Office of Science (DOE-SC), Office of Environmental Management (DOE-EM), and DOE-RL projects, and from the site remediation and closure contractor, Washington Closure Hanford, LLC (WCH). The three-dimensional, system-scale model addresses water flow and reactive transport of uranium for the coupled vadose zone, unconfined aquifer, and Columbia River shoreline of the Hanford 300 Area. The system-scale model of the 300 Area was developed to be a decision-support tool to evaluate processes of the total system affecting the groundwater uranium plume. The model can also be used to address “what if” questions regarding different remediation endpoints, and to assist in design and evaluation of field remediation efforts. For example, the proposed cleanup plan for the Hanford 300 Area includes removal, treatment, and disposal of contaminated sediments from known waste sites, enhanced attenuation of uranium hot spots in the vadose and periodically rewetted zone, and continued monitoring of groundwater with institutional controls. Illustrative simulations of polyphosphate infiltration were performed to demonstrate the ability of the system-scale model to address these types of questions. The use of this model in conjunction with continued field monitoring is expected to provide a rigorous basis for developing operational strategies for field remediation and for defining defensible remediation endpoints.

  11. Barriers and Issues Related to Achieving Final Disposition of Depleted Uranium

    SciTech Connect (OSTI)

    Gillas, D. L.; Chambers, B. K.

    2002-02-26

    Approximately 750,000 metric tons (MT) of surplus depleted uranium (DU) in various chemical forms are stored at several Department of Energy (DOE) sites throughout the United States. Most of the DU is in the form of DU hexafluoride (DUF6) that resulted from uranium enrichment operations over the last several decades. DOE plans to convert the DUF6 to ''a more stable form'' that could be any one or combination of DU tetrafluoride (DUF4 or green salt), DU oxide (DUO3, DUO2, or DU3O8), or metal depending on the final disposition chosen for any given quantity. Barriers to final disposition of this material have existed historically and some continue today. Currently, the barriers are more related to finding uses for this material versus disposing as waste. Even though actions are beginning to convert the DUF6, ''final'' disposition of the converted material has yet to be decided. Unless beneficial uses can be implemented, DOE plans to dispose of this material as waste. This expresses the main barrier to DU disposition; DOE's strategy is to dispose unless uses can be found while the strategy should be only dispose as a last resort and make every effort to find uses. To date, only minimal research programs are underway to attempt to develop non-fuel uses for this material. Other issues requiring resolution before these inventories can reach final disposition (uses or disposal) include characterization, disposal of large quantities, storage (current and future), and treatment options. Until final disposition is accomplished, these inventories must be managed in a safe and environmentally sound manner; however, this is becoming more difficult as materials and facilities age. The most noteworthy final disposition technical issues include the development of reuse and treatment options.

  12. Impacts of Humic Injection Experiments on the South Oyster Field Research Site

    SciTech Connect (OSTI)

    John F. McCarthy

    2004-04-27

    A closure plan for the South Oyster Focus Area (SOFA) is being implemented to assess the impacts of a series of experimental injections of microorganisms, tracers and chemical amendments on the chemical and physical properties of the aquifer. The proposed research addresses environmental monitoring of humic substances injected into the aquifer, as described in the Site Closure Plan for the South Oyster Field Research Site. The goal of the research is to demonstrate that the dissolved organic matter (DOM) in the groundwater at and downgradient from the injection site has returned to a pre-injection �baseline� conditions with respect to either the concentration or chemical composition of the DOM. For clarity, the humic solution injected during the experiment will be referred to as �humic injectate.� The term �DOM� will refer to the organic material recovered in the groundwater, which includes the autochthonous groundwater DOM as well as any of the humic injectate remaining in the groundwater. Specific objectives include: � Estimate the amount of humic material remaining in the aquifer at the completion of the push-pull experiment and the potential for environmental impacts due to release of humics retained on the sediments. � Monitor the DOM concentrations in groundwater over time at the injection well and at sampling locations within the potential downgradient plume of the injected tracers. � Evaluate the chemical composition of the DOM to determine whether the injection experiment had an impact of the chemical properties of the aquifer. The product of this research will be a contribution to the Site Closure Report documenting the impact of the humic experiments on the aquifer. Return of the aquifer to a �baseline� conditions will be achieved if the DOM concentrations in the groundwater are determined over the course of the research to have decreased to the pre-injection level, or if the chemical properties of

  13. Effects of magnetic fields on lithium evolution in F and G stars

    SciTech Connect (OSTI)

    Li, T. D.; Bi, S. L.; Yang, W. M.; Liu, K.; Tian, Z. J.; Ge, Z. S., E-mail: litanda@mail.bnu.edu.cn, E-mail: bisl@bnu.edu.cn [Astronomy Department, Beijing Normal University, Beijing 100875 (China)

    2014-02-01

    To study the effects of magnetic fields on lithium depletion and to explain the characteristics of lithium evolution in F- and G-type stars in open clusters, we construct a stellar model that includes a Tayler-Spruit dynamo-type field. Through examining the features of extra-mixing caused by magnetic fields in stellar interiors and the relationship between lithium depletion and the input parameters (i.e., mass, metallicity, and the initial rotational condition), we find that the magnetic model produces extra-mixing processes different from other models. During pre-main sequence, the model exhibits very efficient extra-mixing, resulting in strong lithium depletion. As a star evolves, the efficiency of extra-mixing rapidly decreases and lithium depletion slows down at old ages. By setting up different initial rotating conditions, the model predicts dispersions of lithium abundance in both main sequence and pre-main sequence stages. The dispersion begins when a radiative core forms in the interior. The number sees a rapid growth afterward, reaching 0.1-0.5 dex at zero age main sequence in G and late-F stars. The increase of dispersion continues in the main sequence, which is slight in G and late-F stars while significant in mid-F stars. Finally, a comparison is carried out between the theoretical results and the observed data in four open clusters. Good agreements are obtained.

  14. Geology of Ziliujing gas field - The gas field developed earliest in the world

    SciTech Connect (OSTI)

    Ding, Chuanbai )

    1991-03-01

    Ziliujing gas field, located in Zigong municipality, Sichuan, is an asymmetric anticline, and well depth is generally less than 1,300 m. There are eight gas- and brine-producing intervals. Tc-3 of the Lower Triassic is the main gas-producing horizon, which is a carbonate with a combination of fracture and intergranular porosities. As early as 1,500 years ago, the production of brine and natural gas was started; over 13,000 wells were drilled of which over 1,000 wells were gas wells. The total area of different producing zones is about 22 km{sup 2}. The distribution and production of natural gas are controlled by structural faults. The gas sources supplied are beyond the limit of the structure. Tc-3 reservoir is a typical fissured reservoir, and most of the wells have the characteristics of (1) high initial production rate; (2) rapid depletion; and (3) long producing life. Owing to the favorable geological conditions; the great number of wells; outstanding ancient technologies in drilling, production, and transportation; comprehensive utilization; and very long production history, tremendous success is achieved in the development of gas fields. The total cumulative gas production by the end of 1985 was 33 billion cubic meters in which 17.2 billion cubic meters were contributed by Tc-3 reservoir; maximum gas and brine recoveries have been achieve. So far the gas reservoirs have not been depleted and new discoveries have been found in recent years. The brilliant achievements of the ancestors remain.

  15. Nuclear Data Uncertainty Propagation in Depletion Calculations Using Cross Section Uncertainties in One-group or Multi-group

    SciTech Connect (OSTI)

    Díez, C.J.; Cabellos, O.; Martínez, J.S.

    2015-01-15

    Several approaches have been developed in last decades to tackle nuclear data uncertainty propagation problems of burn-up calculations. One approach proposed was the Hybrid Method, where uncertainties in nuclear data are propagated only on the depletion part of a burn-up problem. Because only depletion is addressed, only one-group cross sections are necessary, and hence, their collapsed one-group uncertainties. This approach has been applied successfully in several advanced reactor systems like EFIT (ADS-like reactor) or ESFR (Sodium fast reactor) to assess uncertainties on the isotopic composition. However, a comparison with using multi-group energy structures was not carried out, and has to be performed in order to analyse the limitations of using one-group uncertainties.

  16. FORIG: a computer code for calculating radionuclide generation and depletion in fusion and fission reactors. User's manual

    SciTech Connect (OSTI)

    Blink, J.A.

    1985-03-01

    In this manual we describe the use of the FORIG computer code to solve isotope-generation and depletion problems in fusion and fission reactors. FORIG runs on a Cray-1 computer and accepts more extensive activation cross sections than ORIGEN2 from which it was adapted. This report is an updated and a combined version of the previous ORIGEN2 and FORIG manuals. 7 refs., 15 figs., 13 tabs.

  17. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  18. Relationship of the percentage depletion allowance and the dividends received deduction: a disagreement with the tax court

    SciTech Connect (OSTI)

    Orbach, K.N.

    1983-09-01

    Arguments against the Tax Court's holding in Lastarmo, Inc. v. Commissioner review the equations for solving the percentage depletion deduction (PD) and dividends received deduction (DRD) interrelationship to determine whether a corporate taxpayer has had a net operating loss (NOL). The Tax Court sought to fill a perceived gap in Internal Revenue Service statutory framework which the author considers invalid because of the calculations used to prove NOL. His calculations show that none existed. 48 references. (DCK)

  19. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  20. Use of depleted uranium silicate glass to minimize release of radionuclides from spent nuclear fuel waste packages

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1996-01-20

    A Depleted Uranium Silicate Container Backfill System (DUSCOBS) is proposed that would use small, isotopically-depleted uranium silicate glass beads as a backfill material inside repository waste packages containing spent nuclear fuel (SNF). The uranium silicate glass beads would fill the void space inside the package including the coolant channels inside SNF assemblies. Based on preliminary analysis, the following benefits have been identified. DUSCOBS improves repository waste package performance by three mechanisms. First, it reduces the radionuclide releases from SNF when water enters the waste package by creating a local uranium silicate saturated groundwater environment that suppresses (a) the dissolution and/or transformation of uranium dioxide fuel pellets and, hence, (b) the release of radionuclides incorporated into the SNF pellets. Second, the potential for long-term nuclear criticality is reduced by isotopic exchange of enriched uranium in SNF with the depleted uranium (DU) in the glass. Third, the backfill reduces radiation interactions between SNF and the local environment (package and local geology) and thus reduces generation of hydrogen, acids, and other chemicals that degrade the waste package system. Finally, DUSCOBS provides a potential method to dispose of significant quantities of excess DU from uranium enrichment plants at potential economic savings. DUSCOBS is a new concept. Consequently, the concept has not been optimized or demonstrated in laboratory experiments.

  1. Diffraction barrier breakthrough in coherent anti-Stokes Raman scattering microscopy by additional probe-beam-induced phonon depletion

    SciTech Connect (OSTI)

    Liu Wei; Niu Hanben

    2011-02-15

    We provide an approach to significantly break the diffraction limit in coherent anti-Stokes Raman scattering (CARS) microscopy via an additional probe-beam-induced photon depletion (APIPD). The additional probe beam, whose profile is doughnut shaped and whose wavelength is different from the Gaussian probe beam, depletes the phonons to yield an unwanted anti-Stokes signal within a certain bandwidth at the rim of the diffraction-limited spot. When the Gaussian probe beam that follows immediately arrives, no anti-Stokes signal is generated in this region, resembling stimulated emission depletion (STED) microscopy, and the spot-generating useful anti-Stokes signals by this beam are substantially suppressed to a much smaller dimension. Scanning the spot renders three-dimensional, label-free, and chemically selective CARS images with subdiffraction resolution. Also, resolution-enhanced images of the molecule, specified by its broadband even-total CARS spectral signals not only by one anti-Stokes signal for its special chemical bond, can be obtained by employing a supercontinuum source.

  2. IAEA Coordinated Research Project on HTGR Reactor Physics, Thermal-hydraulics and Depletion Uncertainty Analysis

    SciTech Connect (OSTI)

    Strydom, Gerhard; Bostelmann, F.

    2015-09-01

    The continued development of High Temperature Gas Cooled Reactors (HTGRs) requires verification of HTGR design and safety features with reliable high fidelity physics models and robust, efficient, and accurate codes. The predictive capability of coupled neutronics/thermal-hydraulics and depletion simulations for reactor design and safety analysis can be assessed with sensitivity analysis (SA) and uncertainty analysis (UA) methods. Uncertainty originates from errors in physical data, manufacturing uncertainties, modelling and computational algorithms. (The interested reader is referred to the large body of published SA and UA literature for a more complete overview of the various types of uncertainties, methodologies and results obtained). SA is helpful for ranking the various sources of uncertainty and error in the results of core analyses. SA and UA are required to address cost, safety, and licensing needs and should be applied to all aspects of reactor multi-physics simulation. SA and UA can guide experimental, modelling, and algorithm research and development. Current SA and UA rely either on derivative-based methods such as stochastic sampling methods or on generalized perturbation theory to obtain sensitivity coefficients. Neither approach addresses all needs. In order to benefit from recent advances in modelling and simulation and the availability of new covariance data (nuclear data uncertainties) extensive sensitivity and uncertainty studies are needed for quantification of the impact of different sources of uncertainties on the design and safety parameters of HTGRs. Only a parallel effort in advanced simulation and in nuclear data improvement will be able to provide designers with more robust and well validated calculation tools to meet design target accuracies. In February 2009, the Technical Working Group on Gas-Cooled Reactors (TWG-GCR) of the International Atomic Energy Agency (IAEA) recommended that the proposed Coordinated Research Program (CRP) on

  3. Optimal pulsed pumping for aquifer remediation when contaminant transport is affected by rate-limited sorption: A calculus of variation approach. Master's thesis

    SciTech Connect (OSTI)

    Hartman, R.T.

    1994-09-01

    The remediation of groundwater contamination continues to persist as a social and economic problem due to increased governmental regulations and public health concerns. Additionally, the geochemistry of the aquifer and the contaminant transport within the aquifer complicates the remediation process to restore contaminated aquifers to conditions compatible with health-based standards. Currently, the preferred method for aquifer cleanup (pump-and-treat) has several limitations including, the persistence of sorbed chemicals on soil matrix and the long term operation and maintenance expense. The impetus of this research was to demonstrate that a calculus of variations approach could be applied to a pulsed pumping aquifer remediation problem where contaminant transport was affected by rate-limited sorption and generalized to answer several management objectives. The calculus of variation approach produced criteria for when the extraction pump is turned on and off. Additionally, the analytic solutions presented in this research may be useful in verifying numerical codes developed to solve optimal pulsed pumping aquifer remediation problems under conditions of rate-limited sorption.

  4. In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental Study

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

    2015-09-15

    In situ arsenic removal from groundwater by an iron coating method has great potential to be a cost effective and simple groundwater remediation technique, especially in rural and remote areas where groundwater is used as the main source of drinking water. The in situ arsenic removal technique was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions., Its effectiveness was then evaluated in an actual high-arsenic groundwater environment. The mechanism of arsenic removal by the iron coating was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, an electron microprobe, and Fourier transformation infrared spectroscopy. A 4-step alternative cycle aquifer iron coating method was developed. A continuous injection of 5 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 hours can create a uniform coating of crystalline goethite on the surface of quartz sand in the columns without causing clogging. At a flow rate of 0.45 cm/min of the injection reagents (vi), the time for arsenic (as Na2HAsO4) to pass through the iron-coated quartz sand column was approximately 35 hours, which was much longer than that for tracer fluorescein sodium (approximately 2 hours). The retardation factor of arsenic was 23, and its adsorption capacity was 0.11 mol As per mol Fe, leading to an excellent arsenic removal. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As (V) and Fe (II) reagents. When the arsenic content in the groundwater was 233 ?g/L, the aqueous phase arsenic was completely removed with an arsenic adsorption of 0.05 mol As per mol Fe. Arsenic fixation resulted from a process of adsorption/co-precipitation, in which arsenic and iron likely formed the arsenic-bearing iron mineral phases with poor crystallinity by way of bidentate binuclear complexes. Thus, the high arsenic removal efficiency of the technique likely resulted from the

  5. Internal split field generator

    DOE Patents [OSTI]

    Thundat; Thomas George; Van Neste, Charles W.; Vass, Arpad Alexander

    2012-01-03

    A generator includes a coil of conductive material. A stationary magnetic field source applies a stationary magnetic field to the coil. An internal magnetic field source is disposed within a cavity of the coil to apply a moving magnetic field to the coil. The stationary magnetic field interacts with the moving magnetic field to generate an electrical energy in the coil.

  6. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  7. Guidelines for conceptual design and evaluation of aquifer thermal energy storage

    SciTech Connect (OSTI)

    Meyer, C.F.; Hauz, W.

    1980-10-01

    Guidelines are presented for use as a tool by those considering application of a new technology, aquifer thermal energy storage (ATES). The guidelines will assist utilities, municipalities, industries, and other entities in the conceptual design and evaluation of systems employing ATES. The potential benefits of ATES are described, an overview is presented of the technology and its applications, and rules of thumb are provided for quickly judging whether a proposed project has sufficient promise to warrant detailed conceptual design and evaluation. The characteristics of sources and end uses of heat and chill which are seasonally mismatched and may benefit from ATES (industrial waste heat, cogeneration, solar heat, and winter chill, for space heating and air conditioning) are discussed. Storage and transport subsystems and their expected performance and cost are described. A 10-step methodology is presented for conceptual design of an ATES system and evaluation of its technical and economic feasibility in terms of energy conservation, cost savings, fuel substitution, improved dependability of supply, and abatement of pollution, with examples, and the methodology is applied to a hypothetical proposed ATES system, to illustrate its use.

  8. Fractured rock aquifer tests in the Western Siberian Basin, Ozyorsk, Russia

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.

    1997-10-01

    A series of multi-zone pumping tests was conducted in a contaminated fractured rock aquifer in the Western Siberian Basin, Ozyorsk, Russia. The tests were conducted adjacent to the Mishelyak River floodplain in fractured Paleozoic porphyrites, tufts, tuff breccia, and lava typical of the Ural mountain complex. Geophysical logs, borehole photography, core samples, and results from previous borehole contamination studies were used to identify the zones to be tested. A network of three uncased wells was tested using a system of inflatable packers, pressure transducers and data loggers. Seven zones were isolated and monitored in two of the uncased wells. A straddle packer assembly was used to isolate individual zones within the pumping well. Eight constant rate pumping tests were conducted. Results of the testing indicate that shallow groundwater migrates primarily in two intervals that are separated by an interval with low lateral conductivity. The water bearing intervals have moderate to high specific capacities (1.3 and 30 L/min/m). Several processes are responsible for fracturing present in the lower interval. The network of compound fractures produced a complex array of fracture intersections yielding a fractured media with hydraulic behavior similar to porous media. Models used for the analysis of pumping tests in porous media provide a good estimation of the hydraulic response of the lower interval to pumping. Future work will include more complex analysis of the data to determine hydraulic conductivity ellipses.

  9. Single-cell genomics reveal metabolic strategies for microbial growth and survival in an oligotrophic aquifer

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Kennedy, David W.; Castelle, Cindy; Field, Erin; Stepanauskas, Ramunas; Fredrickson, Jim K.; Konopka, Allan

    2014-02-01

    Bacteria from the genus Pedobacter are a major component of microbial assemblages at Hanford Site and have been shown to significantly change in abundance in response to the subsurface intrusion of Columbia River water. Here we employed single cell genomics techniques to shed light on the physiological niche of these microorganisms. Analysis of four Pedobacter single amplified genomes (SAGs) from Hanford Site sediments revealed a chemoheterotrophic lifestyle, with the potential to exist under both aerobic and microaerophilic conditions via expression of both aa3?type and cbb3-type cytochrome c oxidases. These SAGs encoded a wide-range of both intra-and extra-cellular carbohydrate-active enzymes, potentially enabling the degradation of recalcitrant substrates such as xylan and chitin, and the utilization of more labile sugars such as mannose and fucose. Coupled to these enzymes, a diversity of transporters and sugar-binding molecules were involved in the uptake of carbon from the extracellular local environment. The SAGs were enriched in TonB-dependent receptors (TBDRs), which play a key role in uptake of substrates resulting from degradation of recalcitrant carbon. CRISPR-Cas mechanisms for resisting viral infections were identified in all SAGs. These data demonstrate the potential mechanisms utilized for persistence by heterotrophic microorganisms in a carbon-limited aquifer, and hint at potential linkages between observed Pedobacter abundance shifts within the 300 Area subsurface and biogeochemical shifts associated with Columbia River water intrusion.

  10. Petrology of lower and middle Eocene carbonate rocks, Floridan aquifer, central Florida

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1984-09-01

    Study of cores from a US Geological Survey test well near Polk City, Florida, indicates that the Avon Park-Lake City (Claibornian) and Oldsmar (Sabinian) Limestones, which comprise most of the Floridan aquifer in central Florida, can be divided into six microfacies: foraminiferal mudstone, foraminiferal wackestone-packstone, foraminiferal grainstone, nodular anhydrite, laminated dolomicrite, and replacement dolomite. Dolomite containing variable amounts of nodular anhydrite forms more than 90% of the Avon Park-Lake city interval, whereas thte Oldsmar is chiefly limestone. Several episodes of dolomite formation are recognized. Laminated dolomicrite formed syngenetically in a supratidal-sabhka environment. Crystalline dolomite with nodular anhydrite formed early by replacement of limestone through reflux of dense, magnesium-rich brines. Replacement dolomite not associated with evaporites and containing limpid crystals probably formed later by a mixed-water process in the subsurface environment. Late diagenetic processes affecting crystalline dolomites include hydration of anhydrite to gypsum, partial dissolution of gypsum, minor alteration of gypsum to calcite, and dissolution of calcian dolomite cores in stoichiometric crystals. Crystalline dolomite and grainstone are the only rock types that have high enough porosities and permeabilities to provide significant yields of water. Medium and finely crystalline dolomites show best values of porosity and permeability because they have high percentages of intercrystal and moldic pores that are well connected. Filling of pores by anhydrite or gypsum can significantly reduce porosity and permeability.

  11. An example of mixing-zone dolomite, Middle Eocene Avon Park Formation, Floridan aquifer system

    SciTech Connect (OSTI)

    Cander, H.S. )

    1994-07-01

    A late-formed dolomite cement in a core of the Middle Eocene Avon Park Formation, peninsular Florida, provides an example of dolomite cement from a mixing zone and illustrates how dolomite textural alteration and stabilization can occur at earth-surface conditions. The Avon Park Formation is a pervasively dolomitized peritidal platform carbonate 400 m thick in the Florida aquifer system. Typical Avon Park dolomite is inclusion-rich, fine-grained (< 40 mm), noncathodoluminescent, highly porous (average, 20%), and formed during the Eocene by normal to hypersaline seawater ([delta][sup 18]O = + 3.7[per thousand] PDB; [delta][sup 13]C = + 2.0[per thousand]; [sup 87]Sr/[sup 86]Sr = 0.70778; Sr = 167 ppm). In a 20 m interval in a core from southwest Florida, inclusion-free, cathodoluminescent dolomite overgrows the early-formed noncathodoluminescent marine dolomite. The cathodoluminescent dolomite cement profoundly alters the texture of Avon Park dolomite from typical Cenozoic-like porous, poorly crystalline dolomite to hard, dense, low-porosity, highly crystalline Paleozoic-like dolomite. The dolomite cement is not a replacement of limestone but an overgrowth of early-formed marine dolomite and pore-occluding cement. This study demonstrates that: (1) dolomite precipitated from a 75% seawater mixing-zone fluid that was both calcite saturated and sulfate-rich, and (2) dramatic textural maturation and stabilization in dolomite can occur in the near surface environment, without elevated temperature and burial conditions.

  12. Mobilization of trace elements in aquifers by biodegradation of hydrocarbon contaminants. Master Thesis

    SciTech Connect (OSTI)

    Kearney, S.L.

    1997-12-01

    This study had two objectives: (1) to determine the extent of metal mobility within petroleum-contaminated aquifers, (2) to determine if biodegradation of petroleum hydrocarbons can explain metal mobility. The approach reviewed analytical results from 2305 groundwater sampling events, taken from 958 wells, located at 136 sites found at 53 Air Force installations. The study showed that high levels of metals are present at petroleum hydrocarbon sites where metals would not generally be expected. Of the metals with drinking water maximum contaminant levels (MCLs), mercury and silver were detected the least frequently. Barium and copper were detected at the sites, but fewer than 2.5 percent of the samples exceeded their MCLs. All other metals exceeded their MCLs in at least 2.5 percent of the samples, with antimony and lead exceeding their MCLs in 19 percent and 10 percent of samples, respectively. Higher concentrations of barium and manganese were most strongly correlated with petroleum hydrocarbon contamination, and relatively strong correlations also existed for aluminum, arsenic, iron, and lead. Major cations such as calcium, magnesium, sodium and potassium were least affected by petroleum hydrocarbons concentrations.

  13. H. R. 4670: a bill to amend the Internal Revenue Code of 1954 to increase the depletion allowance for oil and natural gas, and to allow percentage depletion for stripper well production of integrated producers. Introduced in the House of Representatives, Ninety-Ninth Congress, Second Session, April 23, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    An amendment to the Internal Revenue Code of 1954 increases the depletion allowance for oil and natural gas and allows percentage depletion for stripper well production of integrated producers. The bill was referred to the House Committee on Ways and Means after its introduction.

  14. U.S. Partners with Canada to Renew Funding for World's Largest International CO2 Storage Project in Depleted Oil Fields

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy and Natural Resources Canada announced today a total of $5.2 million has been committed by the two governments to bring a benchmark carbon dioxide injection project to successful conclusion in 2011.

  15. Review of corrosion in 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders

    SciTech Connect (OSTI)

    Lykins, M.L.

    1995-08-01

    A literature review was conducted to determine the type, extent and severity of corrosion found in the 10- and 14-ton mild steel depleted UF{sub 6} storage cylinders. Also discussed in this review is corrosion found in the valves and plugs used in the cylinders. Corrosion of the cylinders is a gradual process which occurs slowly over time. Understanding corrosion of the cylinders is an important concern for long term storage of the UF{sub 6} in the cylinder yards, as well as the final disposition of the depleted UF{sub 6} tails inventory in the future. The following conclusions are made from the literature review: (1) The general external corrosion rate of the cylinders is about 1 to 2 mils per year (1 mil = 0.001{double_prime}). The highest general external corrosion rate was over 5 mpy on the 48G type cylinders. (2) General internal corrosion from the depleted UF{sub 6} is negligible under normal storage conditions. Crevice corrosion can occur at the cylinder/saddle interface from the retention of water in this area. Crevice corrosion can occur at the cylinder/skirt interface on the older skirted cylinders due to the lack of water drainage in this area. Crevice corrosion can occur on cylinders that have been in ground contact. Crevice corrosion and galvanic corrosion can occur where the stainless steel I.D. nameplates are attached to the cylinder. The packing nuts on the bronze one-inch valves used in the cylinders are susceptible to stress corrosion cracking (SCC). Mechanical damage from routine handling can lead to a breach in a cylinder with subsequent accelerated corrosion of the mild steel due to attack from HF and other UF{sub 6} hydrolysis by-products.

  16. Synthetic drill-in fluid for gravel packing depleted sands and pressured shale

    SciTech Connect (OSTI)

    Ali, S.; Griffith, G.; Jones, T.; Hinojosa, R.; Smejkal, K.

    1999-03-01

    Weighted synthetic- or oil-base drill-in fluids offer an excellent solution to the problem of reactive, pressured shale. However, some operators remain uneasy about drilling into a reservoir with an invert emulsion drill-in fluid. This apprehension is partly due to the possibility of creating emulsion blocks or changing the rock matrix wettability. Either of these conditions may reduce the crude`s mobility by restricting flow. This formation damage is avoided with water-base drill-in fluids, but the borehole stability problem remains an issue. A synthetic drill-in fluid`s ability to stabilize reactive shales is well documented. There remains a concern that once reactive shales are exposed to completion brine, the inhibition imparted by a synthetic fluid is lost. If lost, the shale particles could spall (slough) freely into the wellbore, plugging the screens and resulting in an incomplete gravel placement. Another concern is the effective displacement of the synthetic fluid to the completion brine without creating undesirable emulsions and damaging the integrity of the synthetic-fluid filter cake. The key appears to be selecting a spacer system that prevents formation of viscous emulsions at the interfaces and would not aggressively attack the wellbore filter cake. The paper describes laboratory evaluation, simulated core tests, test results, a field case history in the South Timbalier field offshore Louisiana, and lessons learned.

  17. Characterization of options and their analysis requirements for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W.; Rosen, R.S.; Zoller, J.N.; Harri, J.W.; Schwertz, N.L.

    1995-12-01

    The Department of Energy (DOE) is examining alternative strategies for the long-term management of depleted uranium hexafluoride (UF{sub 6}) currently stored at the gaseous diffusion plants at Portsmouth, Ohio, and Paducah, Kentucky, and on the Oak Ridge Reservation in Oak Ridge, Tennessee. This paper describes the methodology for the comprehensive and ongoing technical analysis of the options being considered. An overview of these options, along with several of the suboptions being considered, is presented. The long-term management strategy alternatives fall into three broad categories: use, storage, or disposal. Conversion of the depleted UF6 to another form such as oxide or metal is needed to implement most of these alternatives. Likewise, transportation of materials is an integral part of constructing the complete pathway between the current storage condition and ultimate disposition. The analysis of options includes development of pre-conceptual designs; estimates of effluents, wastes, and emissions; specification of resource requirements; and preliminary hazards assessments. The results of this analysis will assist DOE in selecting a strategy by providing the engineering information necessary to evaluate the environmental impacts and costs of implementing the management strategy alternatives.

  18. Two-phase convective CO2 dissolution in saline aquifers

    SciTech Connect (OSTI)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlying two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.

  19. A preliminary sub-basin scale evaluation framework of site suitability for onshore aquifer-based CO{sub 2} storage in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Wang, Ying; Dahowski, Robert T; Davidson, Casie L; Bromhal, Grant S

    2013-01-01

    Development of a reliable, broadly applicable framework for the identification and suitability evaluation of potential CO{sub 2} storage sites is essential before large-scale deployment of carbon dioxide capture and geological storage (CCS) can commence. In this study, a sub-basin scale evaluation framework was developed to assess the suitability of potential onshore deep saline aquifers for CO{sub 2} storage in China. The methodology, developed in consultation with experts from the academia and the petroleum industry in China, is based on a multi-criteria analysis (MCA) framework that considers four objectives: (1) storage optimization, in terms of storage capacity and injectivity; (2) risk minimization and storage security; (3) environmental restrictions regarding surface and subsurface use; and (4) economic considerations. The framework is designed to provide insights into both the suitability of potential aquifer storage sites as well as the priority for early deployment of CCS with existing CO{sub 2} sources. Preliminary application of the framework, conducted using GIS-based evaluation tools revealed that 18% of onshore aquifer sites with a combined CO{sub 2} storage capacity of 746 gigatons are considered to exhibit very high suitability, and 11% of onshore aquifer sites with a total capacity of 290 gigatons exhibit very high priority opportunities for implementation. These onshore aquifer sites may provide promising opportunities for early large-scale CCS deployment and contribute to CO{sub 2} mitigation in China for many decades.

  20. A preliminary sub-basin scale evaluation framework of site suitability for onshore aquifer-based CO2 storage in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Wang, Ying; Dahowski, Robert T.; Davidson, Casie L.; Bromhal, Grant

    2013-01-30

    Development of a reliable, broadly applicable framework for the identification and suitability evaluation of potential CO2 storage sites is essential before large scale deployment of carbon dioxide capture and geological storage (CCS) can commence. In this study, a sub-basin scale evaluation framework was developed to assess the suitability of potential onshore deep saline aquifers for CO2 storage in China. The methodology, developed in consultation with experts from the academia and the petroleum industry in China, is based on a multi-criteria analysis (MCA) framework that considers four objectives: (1) storage optimization, in terms of storage capacity and injectivity; (2) risk minimization and storage security; (3) environmental restrictions regarding surface and subsurface use; and (4) economic considerations. The framework is designed to provide insights into both the suitability of potential aquifer storage sites as well as the priority for early deployment of CCS with existing CO2 sources. Preliminary application of the framework, conducted using GIS-based evaluation tools revealed that 18% of onshore aquifer sites with a combined CO2 storage capacity of 746 gigatons are considered to exhibit very high suitability, and 11% of onshore aquifer sites with a total capacity of 290 gigatons exhibit very high priority opportunities for implementation. These onshore aquifer sites may provide promising opportunities for early large-scale CCS deployment and contribute to CO2 mitigation in China for many decades.

  1. Self-excited dust-acoustic waves in an electron-depleted nanodusty plasma

    SciTech Connect (OSTI)

    Tadsen, Benjamin Greiner, Franko; Groth, Sebastian; Piel, Alexander

    2015-11-15

    A dust density wave field is observed in a cloud of nanodust particles confined in a radio frequency plasma. Simultaneous measurements of the dust properties, grain size and density, as well as the wave parameters, frequency and wave number, allow for an estimate of the ion density, ion drift velocity, and the dust charge using a hybrid model for the wave dispersion. It appears that the charge on the dust grains in the cloud is drastically reduced to tens of elementary charges compared with isolated dust particles in a plasma. The charge is much higher at the cloud's periphery, i.e., towards the void in the plasma center and also towards the outer edge of the cloud.

  2. ZPR-3 Assembly 11 : A cylindrical sssembly of highly enriched uranium and depleted uranium with an average {sup 235}U enrichment of 12 atom % and a depleted uranium reflector.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D.; Tsiboulia, A.; Rozhikhin, Y.; National Security; Inst. of Physics and Power Engineering

    2010-09-30

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 11 (ZPR-3/11) was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 12 at.% and a depleted uranium reflector. Approximately 79.7% of the total fissions in this assembly occur above 100 keV, approximately 20.3% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 8 in the Cross Section Evaluation Working Group

  3. External split field generator

    DOE Patents [OSTI]

    Thundat, Thomas George; Van Neste, Charles W.; Vass, Arpad Alexander

    2012-02-21

    A generator includes a coil disposed about a core. A first stationary magnetic field source may be disposed on a first end portion of the core and a second stationary magnetic field source may be disposed on a second end portion of core. The first and second stationary magnetic field sources apply a stationary magnetic field to the coil. An external magnetic field source may be disposed outside the coil to apply a moving magnetic field to the coil. Electrical energy is generated in response to an interaction between the coil, the moving magnetic field, and the stationary magnetic field.

  4. livermore field office

    National Nuclear Security Administration (NNSA)

    donation to those in need.

    Livermore Field Office sets core values as part of continuous improvement process http:nnsa.energy.govbloglivermore-field-office-sets-cor...

  5. Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquife

    SciTech Connect (OSTI)

    Campbell, K M; K Kukkadapu, R K; Qafoku, N P; Peacock, A D; Lesher, E; Williams, K H; Bargar, J R; Wilkins, M J; Figueroa, L; Ranville, J; Davis, J A; Long, P E

    2012-05-23

    Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology and redox processes that occur in these zones, several cores from a region of naturally occurring reducing conditions in a U-contaminated aquifer (Rifle, CO) were examined. Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for U and Fe content, oxidation state, and mineralogy; reduced S phases; and solid-phase organic C content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase U concentrations were higher in the naturally reduced zone, with a high proportion of the U present as U(IV). The sediments were also elevated in reduced S phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and SO4 reduction has occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentrations of solid-phase organic C and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic C concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic C for maintaining reducing conditions and U immobilization.

  6. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2003-10-21

    Field and laboratory investigations of naturally occurring CO{sub 2}-reservoirs are being conducted to determine the characteristics of potential seal and reservoir units and the extent of the interactions that occur between the host rocks and the CO{sub 2} charged fluids. Efforts have focused on the Farnham Dome field, located in central Utah, and the Springerville-St. Johns field in Arizona and New Mexico. The Springerville-St. Johns field is particularly significant because of the presence of extensive travertine deposits that document release of CO{sub 2} to the atmosphere. CO{sub 2} accumulations at both fields occur in sedimentary rocks typical of CO{sub 2} reservoirs occurring on the Colorado Plateau. The main achievements during this quarter were: (1) a soil gas flux survey at the Springerville-St Johns field, (2) collection of some soil gas for chemical and isotopic analysis from this field, and (3) collection of travertine samples from an elevation range of over 1000 feet (330 m) for dating the time span of carbonate-saturated spring outflow at this field. Analytical results and interpretations are still in progress. When available they will allow contrast with soil gas measurements from Farnham Dome natural CO{sub 2} field in central Utah, which were reported in the previous quarterly report.

  7. An Advanced Fracture Characterization and Well Path Navigation System for Effective Re-Development and Enhancement of Ultimate Recovery from the Complex Monterey Reservoir of South Ellwood Field, Offshore California

    SciTech Connect (OSTI)

    Steve Horner

    2006-01-31

    Venoco Inc, intends to re-develop the Monterey Formation, a Class III basin reservoir, at South Ellwood Field, Offshore Santa Barbara, California. Well productivity in this field varies significantly. Cumulative Monterey production for individual wells has ranged from 260 STB to 8,700,000 STB. Productivity is primarily affected by how well the well path connects with the local fracture system and the degree of aquifer support. Cumulative oil recovery to date is a small percentage of the original oil in place. To embark upon successful re-development and to optimize reservoir management, Venoco intends to investigate, map and characterize field fracture patterns and the reservoir conduit system. State of the art borehole imaging technologies including FMI, dipole sonic and cross-well seismic, interference tests and production logs will be employed to characterize fractures and micro faults. These data along with the existing database will be used for construction of a novel geologic model of the fracture network. Development of an innovative fracture network reservoir simulator is proposed to monitor and manage the aquifer's role in pressure maintenance and water production. The new fracture simulation model will be used for both planning optimal paths for new wells and improving ultimate recovery. In the second phase of this project, the model will be used for the design of a pilot program for downhole water re-injection into the aquifer simultaneously with oil production. Downhole water separation units attached to electric submersible pumps will be used to minimize surface fluid handling thereby improving recoveries per well and field economics while maintaining aquifer support. In cooperation with the DOE, results of the field studies as well as the new models developed and the fracture database will be shared with other operators. Numerous fields producing from the Monterey and analogous fractured reservoirs both onshore and offshore will benefit from the

  8. AN ADVANCED FRACTURE CHARACTERIZATION AND WELL PATH NAVIGATION SYSTEM FOR EFFECTIVE RE-DEVELOPMENT AND ENHANCEMENT OF ULTIMATE RECOVERY FROM THE COMPLEX MONTEREY RESERVOIR OF SOUTH ELLWOOD FIELD, OFFSHORE CALIFORNIA

    SciTech Connect (OSTI)

    Steve Horner

    2005-08-01

    Venoco Inc, intends to re-develop the Monterey Formation, a Class III basin reservoir, at South Ellwood Field, Offshore Santa Barbara, California. Well productivity in this field varies significantly. Cumulative Monterey production for individual wells has ranged from 260 STB to 8,700,000 STB. Productivity is primarily affected by how well the well path connects with the local fracture system and the degree of aquifer support. Cumulative oil recovery to date is a small percentage of the original oil in place. To embark upon successful re-development and to optimize reservoir management, Venoco intends to investigate, map and characterize field fracture patterns and the reservoir conduit system. State of the art borehole imaging technologies including FMI, dipole sonic and cross-well seismic, interference tests and production logs will be employed to characterize fractures and micro faults. These data along with the existing database will be used for construction of a novel geologic model of the fracture network. Development of an innovative fracture network reservoir simulator is proposed to monitor and manage the aquifer's role in pressure maintenance and water production. The new fracture simulation model will be used for both planning optimal paths for new wells and improving ultimate recovery. In the second phase of this project, the model will be used for the design of a pilot program for downhole water re-injection into the aquifer simultaneously with oil production. Downhole water separation units attached to electric submersible pumps will be used to minimize surface fluid handling thereby improving recoveries per well and field economics while maintaining aquifer support. In cooperation with the DOE, results of the field studies as well as the new models developed and the fracture database will be shared with other operators. Numerous fields producing from the Monterey and analogous fractured reservoirs both onshore and offshore will benefit from the

  9. Stratigraphy of the unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory, Idaho

    SciTech Connect (OSTI)

    Anderson, S.R.; Liszewski, M.J.

    1997-08-01

    The unsaturated zone and the Snake River Plain aquifer at and near the Idaho National Engineering Laboratory (INEL) are made up of at least 178 basalt-flow groups, 103 sedimentary interbeds, 6 andesite-flow groups, and 4 rhyolite domes. Stratigraphic units identified in 333 wells in this 890-mile{sup 2} area include 121 basalt-flow groups, 102 sedimentary interbeds, 6 andesite-flow groups, and 1 rhyolite dome. Stratigraphic units were identified and correlated using the data from numerous outcrops and 26 continuous cores and 328 natural-gamma logs available in December 1993. Basalt flows make up about 85% of the volume of deposits underlying the area.

  10. /sup 234/U//sup 230/Th ratio as an indicator of redox state, and U, Th and Ra behavior in briney aquifers

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1985-06-01

    The /sup 234/U//sup 230/Th ratio serves as an in-situ indicator of the redox state in groundwater aquifers. The higher this ratio, the more U there is in the +6 state and thus a lesser reducing environment. Radium is retarded in the shallow aquifer and its sorption is dependent on the CaSO/sub 4/ content and redox state. Relative to Ra, U and Th are highly sorbed. The total retardation factor for Th is approx.1400 and mean sorption time for /sup 228/Th is approx.10 days in the shallow zone. The desorption rate of Ra is significantly slower in the shallow than in the deep aquifer. There is no effect of colloids in brines. 6 refs., 5 figs., 2 tabs.

  11. /sup 234/U//sup 230/Th ratio as an indicator of redox state, and U/sub 2/, Th, and Ra behavior in Briney aquifers

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1986-01-01

    The /sup 234/U//sup 230/Th ratio serves as an in-situ indicator of the redox state in groundwater aquifers. The higher this ratio, the more U there is in the +6 valance state and thus a less reducing environment. Radium sorption is retarded in the shallow aquifer and is dependent on the CaSO/sub 4/ content and the redox state. Relative to Ra, U and Th are highly sorbed. The total retardation factor for Th is approx. 1400 and mean sorption time for /sup 228/Th is approx. 10 days in the shallow zone. The desorption rate of Ra is significantly slower in the shallow than in the deep aquifer. There is no effect of colloids in brines.

  12. Activation of RAS/ERK alone is insufficient to inhibit RXRα function and deplete retinoic acid in hepatocytes

    SciTech Connect (OSTI)

    Wang, Ai-Guo Song, Ya-Nan; Chen, Jun; Li, Hui-Ling; Dong, Jian-Yi; Cui, Hai-Peng; Yao, Liang; Li, Xue-Feng; Gao, Wen-Ting; Qiu, Ze-Wen; Wang, Fu-Jin; Wang, Jing-Yu

    2014-09-26

    Highlights: • The activation of RAS/ERK is insufficient to inhibit RXRα function and deplete RA. • The retinoid metabolism-related genes are down-regulated by ras oncogene. • The atRA has no effect on preventing hepatic tumorigenesis or curing the developed hepatic nodules. - Abstract: Activation of RAS/ERK signaling pathway, depletion of retinoid, and phosphorylation of retinoid X receptor alpha (RXRα) are frequent events found in liver tumors and thought to play important roles in hepatic tumorigenesis. However, the relationships among them still remained to be elucidated. By exploring the transgenic mouse model of hepatic tumorigenesis induced by liver-specific expression of H-ras12V oncogene, the activation of RAS/ERK, the mRNA expression levels of retinoid metabolism-related genes, the contents of retinoid metabolites, and phosphorylation of RXRα were determined. RAS/ERK signaling pathway was gradually and significantly activated in hepatic tumor adjacent normal liver tissues (P) and hepatic tumor tissues (T) of H-ras12V transgenic mice compared with normal liver tissues (Wt) of wild type mice. On the contrary, the mRNA expression levels of retinoid metabolism-related genes were significantly reduced in P and T compared with Wt. Interestingly, the retinoid metabolites 9-cis-retinoic acid (9cRA) and all-trans-retinoic acid (atRA), the well known ligands for nuclear transcription factor RXR and retinoic acid receptor (RAR), were significantly decreased only in T compared with Wt and P, although the oxidized polar metabolite of atRA, 4-keto-all-trans-retinoic-acid (4-keto-RA) was significantly decreased in both P and T compared with Wt. To our surprise, the functions of RXRα were significantly blocked only in T compared with Wt and P. Namely, the total protein levels of RXRα were significantly reduced and the phosphorylation levels of RXRα were significantly increased only in T compared with Wt and P. Treatment of H-ras12V transgenic mice at 5-week

  13. Field Campaign Guidelines

    SciTech Connect (OSTI)

    Voyles, J. W.; Chapman, L. A.

    2015-12-01

    This document establishes a common set of guidelines for the Atmospheric Radiation Measurement (ARM) Climate Research Facility for planning, executing, and closing out field campaigns. The steps that guide individual field campaigns are described in the Field Campaign Tracking System and are specifically tailored to meet the scope of each field campaign.

  14. Arkansas Underground Natural Gas Storage Capacity

    U.S. Energy Information Administration (EIA) (indexed site)

    21,760 21,359 21,853 21,853 21,853 21,853 1988-2015 Salt Caverns 0 0 0 1999-2015 Aquifers 0 0 0 1999-2015 Depleted Fields 21,760 21,359 21,853 21,853 21,853 21,853 1999-2015 Total Working Gas Capacity 13,898 12,036 12,178 12,178 12,178 12,178 2008-2015 Salt Caverns 0 0 0 2012-2015 Aquifers 0 0 0 2012-2015 Depleted Fields 13,898 12,036 12,178 12,178 12,178 12,178 2008-2015 Total Number of Existing Fields 2 2 2 2 2 2 1989-2015 Depleted Fields 2 2 2 2 2 2

  15. Analysis of Aquifer Response, Groundwater Flow, and PlumeEvolution at Site OU 1, Former Fort Ord, California

    SciTech Connect (OSTI)

    Jordan, Preston D.; Oldenburg, Curtis M.; Su, Grace W.

    2005-02-24

    This report presents a continuation from Oldenburg et al. (2002) of analysis of the hydrogeology, In-Situ Permeable Flow Sensor (ISPFS) results, aquifer response, and changes in the trichloroethylene (TCE) groundwater plume at Operational Unit 1 (OU 1) adjacent to the former Fritzsche Army Airfield at the former Fort Ord Army Base, located on Monterey Bay in northern Monterey County. Fuels and solvents were burned on a portion of OU 1 called the Fire Drill Area (FDA) during airport fire suppression training between 1962 and 1985. This activity resulted in soil and groundwater contamination in the unconfined A-aquifer. In the late 1980's, soil excavation and bioremediation were successful in remediating soil contamination at the site. Shortly thereafter, a groundwater pump, treat, and recharge system commenced operation. This system has been largely successful at remediating groundwater contamination at the head of the groundwater plume. However, a trichloroethylene (TCE) groundwater plume extends approximately 3000 ft (900 m) to the northwest away from the FDA. In the analyses presented here, we augment our prior work (Oldenburg et al., 2002) with new information including treatment-system totalizer data, recent water-level and chemistry data, and data collected from new wells to discern trends in contaminant migration and groundwater flow that may be useful for ongoing remediation efforts. Some conclusions from the prior study have been modified based on these new analyses, and these are pointed out clearly in this report.

  16. MOSRC Field Definitions 01202016 MOSRC Field Definitions

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    MOSRC Field Definitions 01202016 MOSRC Field Definitions 1/5 1/20/2016 Field Name Definition Prime Contract Procurement Instrument Identifier The unique Prime Contractor identifier as it is recorded on the original (or base) contract in FPDS-NG. This must be a valid DOE M&O PIID, as recorded in FPDS-NG. Prime Contract DUNS Number The Prime Contractor's Dun and Bradstreet Data Universal Numbering System (DUNS) as it is recorded on the prime contract in FPDS-NG. Subcontract DUNS Number The

  17. Neutronics and Depletion Methods for Parametric Studies of Fluoride Salt Cooled High Temperature Reactors with Slab Fuel Geometry and Multi-Batch Fuel Management Schemes

    SciTech Connect (OSTI)

    Cisneros, Anselmo T.; Ilas, Dan

    2012-01-01

    The Advanced High Temperature Reactor (AHTR) is a 3400 MWth fluoride salt cooled high temperature reactor (FHR) that uses TRISO particle fuel compacted into slabs rather than spherical fuel pebbles or cylindrical fuel compacts. Simplified methods are required for parametric design studies such that analyzing the entire feasible design space for an AHTR is tractable. These simplifications include fuel homogenization techniques to increase the speed of neutron transport calculations in depletion analysis and equilibrium depletion analysis methods to analyze systems with multi-batch fuel management schemes. This paper presents three elements of significant novelty. First, the reactivity-equivalent physical transformation (RPT) methodology usually applied in systems with coated particle fuel in cylindrical and spherical geometries was extended to slab geometries. Secondly, based on this newly developed RPT method for slab geometries, a methodology that uses Monte Carlo depletion approaches was further developed to search for the maximum discharge burnup in a multi-batch system by iteratively estimating the beginning of equilibrium cycle composition and sampling different discharge burnups. This iterative equilibrium depletion search (IEDS) method fully defines an equilibrium fuel cycle (keff, power, flux and composition evolutions across space and time), but is computationally demanding, although feasible on single-processor workstations. Finally, an analytical method, the non-linear reactivity model, was developed by expanding the linear reactivity model to include an arbitrary number of higher order terms to extrapolate single-batch depletion results to estimate the maximum discharge burnup and BOEC keff in systems with multi-batch fuel management schemes. Results from this method were benchmarked against equilibrium depletion analysis results using the IEDS.

  18. Neutronics and Depletion Methods for Parametric Studies of Fluoride Salt Cooled High Temperature Reactors with Slab Fuel Geometry and Multi-Batch Fuel Management Schemes

    SciTech Connect (OSTI)

    Cisneros, Anselmo T.; Ilas, Dan

    2013-01-01

    The Advanced High-Temperature Reactor (AHTR) is a 3400 MWth fluoride-salt-cooled high-temperature reactor (FHR) that uses TRISO particle fuel compacted into slabs rather than spherical or cylindrical fuel compacts. Simplified methods are required for parametric design studies such that analyzing the entire feasible design space for an AHTR is tractable. These simplifications include fuel homogenization techniques to increase the speed of neutron transport calculations in depletion analysis and equilibrium depletion analysis methods to analyze systems with multi-batch fuel management schemes. This paper presents three elements of significant novelty. First, the Reactivity-Equivalent Physical Transformation (RPT) methodology usually applied in systems with coated-particle fuel in cylindrical and spherical geometries has been extended to slab geometries. Secondly, based on this newly developed RPT method for slab geometries, a methodology that uses Monte Carlo depletion approaches was further developed to search for the maximum discharge burnup in a multi-batch system by iteratively estimating the beginning of equilibrium cycle (BOEC) composition and sampling different discharge burnups. This Iterative Equilibrium Depletion Search (IEDS) method fully defines an equilibrium fuel cycle (keff, power, flux, and composition evolutions) but is computationally demanding, although feasible on single-processor workstations. Finally, an analytical method, the Non-Linear Reactivity Model, was developed by expanding the linear reactivity model to include an arbitrary number of higher order terms so that single-batch depletion results could be extrapolated to estimate the maximum discharge burnup and BOEC keff in systems with multi-batch fuel management schemes. Results from this method were benchmarked against equilibrium depletion analysis results using the IEDS.

  19. Washington Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    39,210 41,309 43,673 46,900 46,900 46,900 1988-2014 Aquifers 39,210 41,309 43,673 46,900 46,900 46,900 1999-2014 Depleted Fields 0 0 1999-2014 Total Working Gas Capacity 23,514...

  20. Oregon Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    29,565 29,565 29,565 28,750 29,565 29,565 1989-2014 Salt Caverns 0 0 1999-2014 Aquifers 0 0 1999-2014 Depleted Fields 29,565 29,565 29,565 28,750 29,565 29,565 1999-2014 Total...

  1. Tennessee Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    1,200 0 NA NA 1998-2014 Salt Caverns 0 0 1999-2014 Aquifers 0 0 1999-2014 Depleted Fields 1,200 0 0 1999-2014 Total Working Gas Capacity 860 0 0 2008-2014 Salt Caverns 0 0...

  2. Mississippi Underground Natural Gas Storage Capacity

    Annual Energy Outlook

    187,251 210,128 235,638 240,241 289,416 303,522 1988-2013 Salt Caverns 62,424 62,301 82,411 90,452 139,627 153,733 1999-2013 Aquifers 0 1999-2012 Depleted Fields 124,827 147,827...

  3. Ohio Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    580,380 580,380 580,380 577,944 577,944 577,944 1988-2014 Salt Caverns 0 0 1999-2014 Aquifers 0 0 1999-2014 Depleted Fields 580,380 580,380 580,380 577,944 577,944 577,944...

  4. Texas Underground Natural Gas Storage Capacity

    Annual Energy Outlook

    740,477 766,768 783,579 812,394 831,190 842,072 1988-2013 Salt Caverns 160,786 182,725 196,140 224,955 246,310 253,220 1999-2013 Aquifers 0 1999-2012 Depleted Fields 579,691...

  5. New York Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    245,579 245,579 245,579 245,579 245,779 245,779 1988-2014 Salt Caverns 2,340 2,340 2,340 0 2,340 2,340 1999-2014 Aquifers 0 0 1999-2014 Depleted Fields 243,239 243,239 243,239...

  6. Louisiana Underground Natural Gas Storage Capacity

    Annual Energy Outlook

    15,858 651,968 670,880 690,295 699,646 733,939 1988-2013 Salt Caverns 88,806 123,341 142,253 161,668 297,020 213,039 1999-2013 Aquifers 0 1999-2012 Depleted Fields 527,051 528,626...

  7. New Mexico Underground Natural Gas Storage Capacity

    Annual Energy Outlook

    80,000 80,000 84,300 84,300 89,100 89,100 1988-2013 Salt Caverns 0 1999-2012 Aquifers 0 1999-2012 Depleted Fields 80,000 80,000 84,300 84,300 89,100 89,100 1999-2013 Total Working...

  8. Oklahoma Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    371,338 371,338 372,838 370,838 370,535 375,935 1988-2014 Salt Caverns 0 0 1999-2014 Aquifers 170 170 170 1999-2014 Depleted Fields 371,338 371,338 372,838 370,668 370,365 375,765 ...

  9. Kansas Underground Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update

    82,300 284,821 284,731 284,905 283,974 282,984 1988-2014 Salt Caverns 931 931 931 931 0 1999-2014 Aquifers 0 0 1999-2014 Depleted Fields 281,370 283,891 283,800 283,974 283,974...

  10. Pre-test geological and geochemical evaluation of the Caprock, St. Peter Sandstone and formation fluids, Yakley Field, Pike County, Illinois

    SciTech Connect (OSTI)

    Not Available

    1983-03-01

    The goal of these studies is to ensure long-term stable containment of air in the underground reservoirs used in conjunction with compressed air energy storage (CAES) plants. The specific objective is to develop stability criteria and engineering guidelines for designing CAES reservoirs in each of the three major reservoir types, including aquifers, salt cavities, and mined hard rock caverns. This document characterizes the geologic nature of porous media constituents native to the aquifer field test site near Pittsfield, Illinois. The geologic samples were subjected to geochemical evaluations to determine anticipated responses to cyclic air injection, heating and moisture - conditions typical of an operating CAES reservoir. This report documents the procedures used and results obtained from these analyses.

  11. Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

    2014-10-01

    High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

  12. HIGHLY DEPLETED ETHANE AND MILDLY DEPLETED METHANOL IN COMET 21P/GIACOBINI-ZINNER: APPLICATION OF A NEW EMPIRICAL {nu}{sub 2}-BAND MODEL FOR CH{sub 3}OH NEAR 50 K

    SciTech Connect (OSTI)

    DiSanti, M. A.; Bonev, B. P.; Villanueva, G. L.; Mumma, M. J.

    2013-01-20

    We obtained infrared spectra of Comet 21P/Giacobini-Zinner (hereafter 21P/GZ) using NIRSPEC at Keck II on UT 2005 June 3, approximately one month before perihelion, that simultaneously sampled H{sub 2}O, C{sub 2}H{sub 6}, and CH{sub 3}OH. Our production rate for H{sub 2}O (3.885 {+-} 0.074 Multiplication-Sign 10{sup 28} molecules s{sup -1}) was consistent with that measured during other apparitions of 21P/GZ as retrieved from optical, infrared, and radio observations. Our analysis also provided values for rotational temperature (T {sub rot} = 51 {+-} 3 K) and the abundance ratio of ortho and para spin populations for water (OPR = 2.99 {+-} 0.23, implying a spin temperature exceeding 50 K). Six Q-branches in the {nu}{sub 7} band of C{sub 2}H{sub 6} provided a production rate (5.27 {+-} 0.90 Multiplication-Sign 10{sup 25} s{sup -1}) that corresponded to an abundance ratio of 0.136 {+-} 0.023 Multiplication-Sign 10{sup -2} relative to H{sub 2}O, confirming the previously reported strong depletion of C{sub 2}H{sub 6} from IR observations during the 1998 apparition, and in qualitative agreement with the depletion of C{sub 2} known from optical studies of 21P/GZ. For CH{sub 3}OH, we applied our recently published quantum model for the {nu}{sub 3} band to obtain a rotational temperature (48{sup +10}/{sub -7} K) consistent with that obtained for H{sub 2}O. In addition, we developed a new empirical model for the CH{sub 3}OH {nu}{sub 2} band, based on observations of Comet 8P/Tuttle with NIRSPEC. The application of our {nu}{sub 2} model to 21P/GZ yielded a production rate in agreement with that obtained from the {nu}{sub 3} band. Combining results from both {nu}{sub 2} and {nu}{sub 3} bands provided a production rate (47.5 {+-} 4.4 Multiplication-Sign 10{sup 25} s{sup -1}) that corresponded to an abundance ratio of 1.22 {+-} 0.11 Multiplication-Sign 10{sup -2} relative to H{sub 2}O in 21P/GZ, indicating mild depletion of CH{sub 3}OH. Together with observations of 21P/GZ in

  13. Field Campaign Guidelines

    U.S. Department of Energy (DOE) all webpages (Extended Search)

    ... provided in Appendix B. 3.3.1 General Guidelines for Field Campaign Data ARM-sponsored ... the field, if at all possible * Timely release to collaborating science teams and ...

  14. Covariant Noncommutative Field Theory

    SciTech Connect (OSTI)

    Estrada-Jimenez, S.; Garcia-Compean, H.; Obregon, O.; Ramirez, C.

    2008-07-02

    The covariant approach to noncommutative field and gauge theories is revisited. In the process the formalism is applied to field theories invariant under diffeomorphisms. Local differentiable forms are defined in this context. The lagrangian and hamiltonian formalism is consistently introduced.

  15. Nevada Field Office

    National Nuclear Security Administration (NNSA)

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