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Sample records for al ca ar

  1. Xe and Ar nanobubbles in Al studied by photoemission spectroscopy...

    Office of Scientific and Technical Information (OSTI)

    Xe and Ar bombardment is observed by low energy electron diffraction, but this does not ... Road, Indore 452001, Madhya Pradesh (India) (India) Publication Date: 2008-03-01 OSTI ...

  2. Theoretical study of Al{sub n}V{sup +} clusters and their interaction with Ar

    SciTech Connect

    Fernndez, Eva Mara; Vega, Andrs; Balbs, Luis Carlos

    2013-12-07

    Recently, it has been experimentally elucidated whether a V impurity in Al{sub n}V{sup +} clusters occupies an external or an internal site by studying their interaction with argon as a function of cluster size [S. M. Lang, P. Claes, S. Neukermans, and E. Janssens, J. Am. Soc. Mass Spectrom. 22, 1508 (2011)]. In the work presented here we studied, by means of density functional theoretic calculations, the structural and electronic properties of Al{sub n}V{sup +} clusters with n = 1421 atoms, as well as the adsorption of a single Ar atom on them. For n < 17 the lowest energy structure of Al{sub n}V{sup +} is related to that of the pure Al {sub n+1}{sup +} cluster with the V atom substituting a surface Al atom. For n ? 17 the V impurity becomes embedded in the cluster, in agreement with the experimental results, and the clusters adopt a fcc-like structure instead of the icosahedral-like skeleton of pure Al {sub n+1}{sup +}. We have studied the binding energy per atom, the second energy difference, and the V and Al atom separation energies, in comparison with those of pure Al {sub n+1}{sup +}. We also studied the adsorption of atomic Ar on endohedral and exohedral V doped clusters. The optimized Ar adsorption geometries are formed with Ar on top of a surface atom (V for n < 17, and Al for n ? 17) without noticeable structural distortion of the host cluster. At the critical size (n = 17) of the exohedral-endohedral transition, the calculated Ar adsorption energy exhibits a drop and the Ar-cluster distance increases drastically, indicating that Ar becomes physisorbed rather than chemisorbed. All these results confirm the assumptions made by the experimentalists when interpreting their measurements.

  3. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOEpatents

    Marshall, Christopher D.; Payne, Stephen A.; Krupke, William F.

    1996-01-01

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  4. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOEpatents

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  5. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    DOE PAGES [OSTI]

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010]/χ[001] ≈ 3.5. A strong power-lawmore » divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.« less

  6. Ar-40/Ar-39 Age Constraints for the Jaramillo Normal Subchron...

    OpenEI (Open Energy Information) [EERE & EIA]

    oxygen isotope, climate record calibration of the astronomical timescale proposed by Johnson (1982) and Shackleton et al. (1990). Ar-40Ar-39 ages of a normally magnetized...

  7. Ca

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    P O. Box 3090 Ca rlsbad, New Mexico 88221 Mr. John Kieling , Acting Bureau Chief Hazardous Waste Bureau MAY 1 6 2012 New Mexico Environment Department 2905 E. Rodeo Park Drive, Bldg . 1 Santa Fe, New Mexico 87505-6303 Subject: Transmittal of the Waste Isolation Pilot Plant Revised Calendar Year 2005-2008 Culebra Potentiometric Surface Map Package Dear Mr. Kieling: On August 5 , 2011 , the New Mexico Environmental Department (NMED) approved the Groundwater Work Plan submitted as a condition to

  8. Inductively coupled plasmareactive ion etching of c- and a-plane AlGaN over the entire Al composition range: Effect of BCl{sub 3} pretreatment in Cl{sub 2}/Ar plasma chemistry

    SciTech Connect

    Shah, Amit P.; Laskar, Masihhur R.; Azizur Rahman, A.; Gokhale, Maheshwar R.; Bhattacharya, Arnab

    2013-11-15

    Inductively coupled plasma (ICP)reactive ion etching (RIE) patterning is a standard processing step for UV and optical photonic devices based on III-nitride materials. There is little research on ICP-RIE of high Al-content AlGaN alloys and for nonpolar nitride orientations. The authors present a comprehensive study of the ICP-RIE of c- and a-plane AlGaN in Cl{sub 2}/Ar plasma over the entire Al composition range. The authors find that the etch rate decreases in general with increasing Al content, with different behavior for c- and a-plane AlGaN. They also study the effect of BCl{sub 3} deoxidizing plasma pretreatment. An ICP deoxidizing BCl{sub 3} plasma with the addition of argon is more efficient in removal of surface oxides from Al{sub x}Ga{sub 1?x}N than RIE alone. These experiments show that Al{sub x}Ga{sub 1?x}N etching is affected by the higher binding energy of AlN and the higher affinity of oxygen to aluminum compared to gallium, with oxides on a-plane AlGaN more difficult to etch as compared to oxides on c-plane AlGaN, specifically for high Al composition materials. The authors achieve reasonably high etch rate (?350 nm/min) for high Al-content materials with a smooth surface morphology at a low DC bias of ??45 VDC.

  9. Characteristics of Al-doped ZnO thin films prepared in Ar + H{sub 2} atmosphere and their vacuum annealing behavior

    SciTech Connect

    Zhu, Bailin; Lü, Kun; Wang, Jun; Li, Taotao; Wu, Jun; Zeng, Dawen; Xie, Changsheng

    2013-11-15

    The microstructure and electrical–optical properties of Al-doped ZnO (AZO) films have been studied as a function of H{sub 2} flux in the magnetron sputtering process at 150 °C and postannealing temperature in vacuum. As H{sub 2} flux increases in the sputtering gas, the AZO films deposited have a (002) preferred orientation rather than the mixed (100) and (002) orientations, the grain size shows a tendency to first increase then decrease, and (002) diffraction peak position is inclined to shift to higher angles first then to lower angles. The resistivity of the films first decreases then increases with H{sub 2} flux, and the lowest resistivity of 4.02 × 10{sup −4}Ω cm is obtained at a H{sub 2} flux of 10 sccm. The average transmittance in the visible region shows little dependence on H{sub 2} flux. As a whole, the AZO films with higher values of figure of merit are obtained when the H{sub 2} flux is in the range of 6–12 sccm. The AZO films deposited in Ar and Ar + H{sub 2} exhibit different annealing behaviors. For the AZO film deposited in Ar, the grain size gradually increases, the stresses are relaxed, the resistivity first decreases then increases, and the average transmittance in the visible region is unchanged initially then somewhat decreased as annealing temperature is increased. The optimum annealing temperature for improving properties of AZO films deposited in Ar is 300 °C. For the AZO films deposited in Ar + H{sub 2}, annealing does not significantly change the microstructure but increases the resistivity of the films; the average transmittance in the visible region remains unchanged initially but greatly reduced with further increase in annealing temperature. The carrier transport in the as-deposited and annealed films appears to be controlled by a mechanism of grain boundary scattering, and the value of E{sub g} increases with the increase in carrier concentration due to Burstein–Moss effect.

  10. Progress in the material development of LiCaAlF sub 6 :Cr sup 3+ laser crystals

    SciTech Connect

    Michelle D. Shinn.; Chase, L.L.; Caird, J.A.; Payne, S.A.; Atherton, L.J.; Kway, W.L.

    1990-03-01

    High Cr{sup 3+} doping levels, up to 8 mole percent, and low losses have been obtained with the tunable solid-state laser material LiCaAlF{sub 6}:Cr{sup 3+} (Cr:LiCAF). Measurements and calculations show that high pumping and extraction efficiencies are possible with the improved material. 13 refs., 4 figs., 1 tab.

  11. Structural investigations of {beta}-CaAlF{sub 5} by coupling powder XRD, NMR, EPR and spectroscopic parameter calculations

    SciTech Connect

    Body, M. . E-mail: monique.body@univ-lemans.fr; Silly, G.; Legein, C.; Buzare, J.-Y.; Calvayrac, F.; Blaha, P.

    2005-12-15

    {beta}-CaAlF{sub 5} was synthesized by solid-state reaction. The precise structure was refined from X-ray powder diffraction data in the monoclinic space group P2{sub 1}/c with lattice constants a=5.3361A, b=9.8298A, c=7.3271A, and {beta}=109.91{sup o} (Z=4). The structure exhibits isolated chains of AlF{sub 6}{sup 3-} octahedra sharing opposite corners.{sup 19}F and {sup 27}Al solid state NMR spectra were recorded using MAS and SATRAS techniques. An EPR spectrum was recorded for {beta}-CaAlF{sub 5}:Cr{sup 3+}. The experimental spectra were simulated in order to extract the NMR and EPR parameter values. Five fluorine sites and one low symmetry aluminium site were found in agreement with the refined structure. These parameters were calculated using empirical and ab-initio methods. The agreement obtained between the calculated {sup 19}F chemical shift values, {sup 27}Al quadrupolar parameters, Cr{sup 3+} EPR fine structure parameters and the experimental results demonstrates the complementarity of XRD, magnetic resonance experiments and theoretical methodologies.

  12. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    SciTech Connect

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83μB/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ≈ 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility χ is anisotropic below 20 K, with a maximum ratio of χ[010][001] ≈ 3.5. A strong power-law divergence χ(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.

  13. Electronic study of Al substituted La{sub 0.7}Ca{sub 0.3}MnO{sub 3} using photoemission spectroscopy

    SciTech Connect

    Phase, D. M. Kumar, Manish Wadikar, A. D. Choudhary, R. J.

    2014-04-24

    Polycrystalline samples of La{sub 0.7}Ca{sub 0.3}Mn{sub 1−X}Al{sub X}O{sub 3} (X=0, 0.05, 0.15) are prepared using solid state reaction route. Photoemission spectroscopy measurements were performed on these samples to investigate their electronic properties. Al shows 3+ oxidation state in both Al doped samples while no effect of Al doping is found on the core level spectrum of La 4d and Ca 2p orbitals and they were found in 3{sup +} and 2{sup +} oxidation state respectively in all the samples . Mn 2p core level photoemission measurements indicates that for 5% Al doped sample (lower doping) Al ions replaces the Mn{sup 3+} ions while they substitute Mn{sup 4+} in 15 % Al doped sample ((higher doping)

  14. Phase-diagram study for the Al{sub 2}O{sub 3}-CaF{sub 2}-SiO{sub 2} system

    SciTech Connect

    Ueda, Shigeru; Maeda, Masafumi

    1999-10-01

    Phase relations for the Al{sub 2}O{sub 3}-CaF{sub 2}-SiO{sub 2} system were investigated from 1,673 to 1,723 K. The hot-filament technique was applied to observe a two-liquid region and liquidus for the ternary system. The liquidus saturated with SiO{sub 2} was investigated at 1673 K by using the hot-filament technique and the chemical equilibrium technique. In this system, the addition of Al{sub 2}O{sub 3} to the CaF{sub 2}-SiO{sub 2} system reduces the congruent temperature. A small substitution of Al{sub 2}O{sub 3} for CaF{sub 2} increases the solubility of SiO{sub 2}, namely, if the region of liquid phase could be enlarged. These results suggest that Al{sub 2}O{sub 3} would be an effective substitute of CaF{sub 2} in slag for steelmaking.

  15. The elastic and thermoelectric properties of the Zintl compound Ca{sub 5}Al{sub 2}Sb{sub 6} under high pressure

    SciTech Connect

    Yang, Gui; Cui, Haitao; Ma, Dongwei; He, Chaozheng

    2014-12-14

    The elastic and thermoelectric properties of Ca{sub 5}Al{sub 2}Sb{sub 6} under pressure are studied using ab initio calculation and semiclassical Boltzmann theory. The calculated elastic constants and minimum thermal conductivity indicate that Ca{sub 5}Al{sub 2}Sb{sub 6} exhibits an anisotropic structure and high thermoelectric performance. The size of the band gap shows a nonlinear change with increasing pressure. Based on the electronic structure, the calculated thermoelectric parameters show that the Seebeck coefficient has no obvious change under pressure, whereas the electrical conductivity improves with increasing pressure. Therefore, the power factor increases at an appropriate pressure of P = 2.6 GPa. P-type doping of Ca{sub 5}Al{sub 2}Sb{sub 6} may achieve better thermoelectric performance than n-type doping, in agreement with experiment. The anisotropic thermoelectric properties of Ca{sub 5}Al{sub 2}Sb{sub 6} indicate that the thermoelectric performance along the z-direction is superior to other directions. This is attributed to the combination of the large dispersion and high band degeneracy along the Γ-Z direction in the band structure.

  16. Al

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    on the way to the drip line .... 31 Al 28 Mg 32 Si 12 B + 18 O 30 Al* (-pn) 28 Mg 15 C + 18 O 33 Si* (-pn) 31 Al 16 N + 18 O 34 P* (-pn) 32 Si 15 C 10 7 s...

  17. AR-CITE

    Energy Science and Technology Software Center

    003796MLTPL00 AR-CITE: Analysis of Search Results for the Clarification and Identification of Technology Emergence

  18. The Aqueous Ca2+ System, in Comparison with Zn2+, Fe3+, and Al3+: An Ab Initio Molecular Dynamics Study

    SciTech Connect

    Bogatko, Stuart A.; Cauet, Emilie L.; Bylaska, Eric J.; Schenter, Gregory K.; Fulton, John L.; Weare, John H.

    2013-02-21

    Results of Ab Initio Molecular Dynamics (AIMD) simulations of a Ca2+ ion in an aqueous environment (64 waters, 38ps=5ps equilibration + 33ps data collection, 300K) are reported. The 1st hydration shell contains 6-7 waters with d(OH) = 0.97Å (identical to our bulk water estimate) and average tilt angle, I = 32º. The 1st maximum in the radial distribution function occurs at GCaO(r) = 2.45Å. Our results compare well with published experimental structural data from X-Ray Absorption (XAFS) and Neutron Diffraction. We also generate simulated XAFS spectra using a 1st principles MD-XAFS procedure and show quantitative agreement with experimental XAFS data from a 0.2m Ca(ClO4)2 aqueous solution. The Ca2+ 1st shell water dipole moment of 3.1D is identical to our bulk water estimate (3.1D). The structured 2nd hydration shell, composed of ~16.5 waters, has a maximum at GCaO(r) =4.6Å. The average 2nd shell dipole moment = 2.9D, is suppressed relative to bulk water values. Detailed H-bond analysis demonstrates the waters in this shell predominately coordinate 1st shell waters with a trigonally structured H-bond network. Two exchanges between the 1st hydration shell and the bulk were observed. These were consistent with a dissociative and dissociative interchange Eigen-Wilkins ligand exchange mechanism. Many transfers between the 2nd shell and bulk are detected for Ca2+ allowing an estimation of the 2nd shell mean residence time (MRT) of 4.6ps. Comparison of the Ca2+ hydration shell structure and dynamics with those of the recently reported Zn2+, Fe3+ and Al3+ cation species show that the 1st and 2nd hydration shell parameters, d(M-OI) distance, CNII, H-bond d(OI-OII) distance and %Tetrahedral structure are correlated with cation charge density, the ratio of cation charge (Z) and size (Rion). However, important exceptions are d(M-OII) and the 2nd shell Mean Residence Time (MRT). These differences are explained in terms of the 1st shell structure parameters (d(M-OI) distance

  19. Measurement and analysis of. cap alpha. particles emitted in reactions of /sup 12/C bombarding /sup 12/C, /sup 27/Al, and /sup nat/Ca

    SciTech Connect

    XIE Yuan-xiang; WU Guo-hua; ZHU Yong-tai; MIAO Rong-zhi; FONG En-pu; YIN Xu; MIAO He-bing; CAI Jing-xiang; SHEN Wen-qing; SUN Shu-ming

    1985-10-01

    The energy spectra and angular distributions of the ..cap alpha.. particles emitted in the reactions of 69.5 MeV /sup 12/C bombarding /sup 12/C, /sup 27/Al, and /sup nat/Ca have been measured and analyzed using the fast-particle exciton model. The contribution from the equilibrium and pre-equilibrium ..cap alpha.. emissions is calculated to be 89%, 81%, and 83% of the total ..cap alpha.. yields for the three reactions, respectively, where the pre-equilibrium ..cap alpha.. emissions are 11%, 14%, and 16%, respectively. A small contribution comes from other reaction mechanisms.

  20. Symmetry-dependent interfacial reconstruction to compensate polar discontinuity at perovskite oxide interfaces (LaAlO{sub 3}/SrTiO{sub 3} and LaAlO{sub 3}/CaTiO{sub 3})

    SciTech Connect

    Lee, Joohwi; Moon, Seon Young; Kim, Jin-Sang; Choi, Jung-Hae E-mail: almacore@kist.re.kr; Choi, Jong Kwon; Park, Jaehong; Hwang, Cheol Seong; Baek, Seung-Hyub; Chang, Hye Jung E-mail: almacore@kist.re.kr

    2015-02-16

    We report the crystal symmetry-dependency of the interfacial reconstruction to relieve the polar discontinuity at the complex oxide heterointerfaces. We chose LaAlO{sub 3}/SrTiO{sub 3} and LaAlO{sub 3}/CaTiO{sub 3} interfaces as model systems, where the neutral TiO{sub 2} and the positive LaO{sup +} layers form the polar discontinuity at the interface with TiO{sub 2}-terminated (001) cubic SrTiO{sub 3} and orthorhombic CaTiO{sub 3}. Using scanning transmission electron microscopy, we observed that the interlayer distance abnormally increased at the interface. We performed the first-principles calculations to understand the detailed atomic displacement at the interfaces having no oxygen vacancy and intermixing. Our results show that cations were reconstructed in different ways depending on the crystal symmetry through the octahedral tilts and atomic displacements to compensate the polar discontinuity at the interfaces. Our results imply that the interfacial reconstructions have to be considered along with the ionic compensation (intermixing) and electronic compensation (two dimensional electron gas) to fully understand the interfacial phenomena.

  1. Paleotemperatures at the lunar surfaces from open system behavior of cosmogenic 38Ar and radiogenic 40Ar

    DOE PAGES [OSTI]

    Shuster, David L.; Cassata, William S.

    2015-02-10

    The simultaneous diffusion of both cosmogenic 38Ar and radiogenic 40Ar from solid phases is controlled by the thermal conditions of rocks while residing near planetary surfaces. Combined observations of 38Ar/37Ar and 40Ar/39Ar ratios during stepwise degassing analyses of neutron-irradiated Apollo samples can distinguish between diffusive loss of Ar due to solar heating of the rocks and that associated with elevated temperatures during or following impact events; the data provide quantitative constraints on the durations and temperatures of each process. From sequentially degassed 38Ar/37Ar ratios can be calculated a spectrum of apparent 38Ar exposure ages versus the cumulative release fraction ofmore » 37Ar, which is particularly sensitive to conditions at the lunar surface typically over ~106–108 year timescales. Due to variable proportions of K- and Ca-bearing glass, plagioclase and pyroxene, with variability in the grain sizes of these phases, each sample will have distinct sensitivity to, and therefore different resolving power on, past near-surface thermal conditions. Furthermore, we present the underlying assumptions, and the analytical and numerical methods used to quantify the Ar diffusion kinetics in multi-phase whole-rock analyses that provide these constraints.« less

  2. Phase transformation of Ca{sub 4}[Al{sub 6}O{sub 12}]SO{sub 4} and its disordered crystal structure at 1073 K

    SciTech Connect

    Kurokawa, Daisuke; Takeda, Seiya; Colas, Maggy; Asaka, Toru; Thomas, Philippe; Fukuda, Koichiro

    2014-07-01

    The phase transformation of Ca{sub 4}[Al{sub 6}O{sub 12}]SO{sub 4} and the crystal structure of its high-temperature phase were investigated by differential thermal analysis, temperature-dependent Raman spectroscopy and high-temperature X-ray powder diffraction (CuKα{sub 1}). We determined the starting temperature of the orthorhombic-to-cubic transformation during heating (=711 K) and that of the reverse transformation during cooling (=742 K). The thermal hysteresis was negative (=−31 K), suggesting the thermoelasticity of the transformation. The space group of the high temperature phase is I4{sup ¯}3m with the unit-cell dimensions of a=0.92426(2) nm and V=0.78955(2) nm{sup 3} (Z=2) at 1073 K. The initial structural model was derived by the direct methods and further refined by the Rietveld method. The final structural model showed the orientational disordering of SO{sub 4} tetrahedra. The maximum-entropy method-based pattern fitting method was used to confirm the validity of the split-atom model, in which conventional structure bias caused by assuming intensity partitioning was minimized. At around the transformation temperature during heating, the vibrational spectra, corresponding to the Raman-active SO{sub 4} internal stretching mode, showed the continuous and gradual change in the slope of full width at half maximum versus temperature curve. This strongly suggests that the orthorhombic-to-cubic phase transformation would be principally accompanied by the statistical disordering in orientation of the SO{sub 4} tetrahedra, without distinct dynamical reorientation. - Graphical abstract: (Left) Three-dimensional electron-density distributions of the SO{sub 4} tetrahedron with the split-atom model, and (right) a bird's eye view of electron densities on the plane parallel to (111). - Highlights: • Crystal structure of Ca{sub 4}[Al{sub 6}O{sub 12}]SO{sub 4} at 1073 K is determined by powder XRD. • The atom arrangements are represented by the split-atom model

  3. A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} for near UV white light-emitting diodes

    SciTech Connect

    Yang, Zhigang; Zhao, Zhengyan; Shi, Yurong; Wang, Yuhua

    2013-10-15

    Graphical abstract: - Highlights: Novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was prepared by solid-state reaction. Excitation spectra suggested an obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited a red emission at 614 nm. Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white LEDs. - Abstract: A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was synthesized using a solid-state reaction method, and its luminescence characteristics and charge compensators effect (Li{sup +}, Na{sup +}, K{sup +}) were investigated. The excitation spectra showed a obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited an intense red emission at 614 nm. The Commission Internationale de lEclairage (CIE) chromaticity coordinates and quantum efficiency (QE) were (0.65, 0.35) and 62.3%, respectively. The good color saturation, high quantum efficiency and small thermal-quenching properties indicate that Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white light-emitting diodes.

  4. Synthesis, characterization of double perovskite Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr, Al) materials via sol–gel auto-combustion and their catalytic properties

    SciTech Connect

    Feraru, S.; Samoila, P.; Borhan, A.I.; Ignat, M.; Iordan, A.R.; Palamaru, M.N.

    2013-10-15

    Double perovskite-type oxide Ca{sub 2}MSbO{sub 6} materials, where M = Dy, Fe, Cr, and Al, were prepared by using the sol–gel auto-combustion method. The role of different B-site cations on their synthesis, structures, morphologies and catalytic properties was investigated. The progress of double-perovskite type structure formation and the disappearance of the organic phases were monitored by infrared absorption spectroscopy (FTIR). Double perovskite oxide structures were evaluated using X-ray diffraction (XRD), while the microstructure of obtained compounds was studied using scanning electron microscopy (SEM). Also, BET surface areas were measured at the liquid nitrogen temperature by nitrogen adsorption. Catalytic properties of the obtained compounds were evaluated by test reaction of hydrogen peroxide decomposition. - Highlights: • Ca{sub 2}MSbO{sub 6} double perovskites were obtained by sol–gel auto-combustion method. • Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr and Al) as catalysts in H{sub 2}O{sub 2} decomposition • Strong relationship between particles' shape, BET area and catalytic performance • Ca{sub 2}FeSbO{sub 6} spherical grains show superior catalytic activity.

  5. Growth of large-domain YBa{sub 2}Cu{sub 3}O{sub x} with new seeding crystals of CaNdAlO{sub 4} and SrLaGaO{sub 4}.

    SciTech Connect

    Shi, D.; Hull, J. R.; LeBlanc, D.; LeBlanc, M. A. R.; Dabkowski, A.; Chang, Y.; Jiang, Y.; Zhang, Z.; Fan, H.; Energy Technology; Univ. of Cincinnati; Univ. of Ottawa; McMaster Univ.; Chinese Academy of Sciences

    1995-05-10

    Single crystals of CaNdAlO{sub 4} and SrLaGaO{sub 4} were used as seeds to grow large domains of YBa{sub 2}Cu{sub 3}O{sub x} for levitation applications. These crystals have high melting temperatures (> 1500 C) and similar lattice structures to that of YBa{sub 2}Cu{sub 3}O{sub x}. In a seeded melt-texturing method developed previously, the single crystals of CaNdAlO{sub 4}, SrLaGaO{sub 4}, and NdBa{sub 2}Cu{sub 3}O{sub x} were used as seeds for comparison. After melt processing, scanning electron microscopy analysis did not reveal any major differences in all these seeded melt-textured samples. However, the levitation forces in the samples seeded with single crystals of CaNdAlO{sub 4} and SrLaGaO{sub 4} increased considerably compared to that of the sample seeded with NdBa{sub 2}Cu{sub 3}O{sub x}. A model is proposed to describe the domain growth mechanism during seeded melt processing.

  6. Ferromagnetism and magneto-transport properties of Mn{sub 0.92}Ca{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate

    SciTech Connect

    Dung, Dang Duc; Van Thiet, Duong; Anh Tuan, Duong; Cho, Sunglae; Feng, Wuwei

    2014-05-07

    The epitaxial Mn{sub 0.92}Ca{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 340 K was enhanced with the addition of Ca, compared to that of bulk MnAs (T{sub C} ∼ 318 K). The maxima magnetoresistance, ∼2.08% at 0.7 T, was observed near the critical magnetic transition temperature. Moreover, the giant magnetocaloric effect was found with the maximum magnetic entropy change, ∼200 J/kgK, around 330 K at 5 T.

  7. Soft X-ray absorption spectroscopy of La{sub 0.7}Ca{sub 0.3}Mn{sub 1−X}Al{sub X}O{sub 3} thin films

    SciTech Connect

    Kumar, Manish Choudhary, R. J. Phase, D. M.

    2014-04-24

    Epitaxial thin films of rare earth manganites have generated much attention recently due to their rich phase diagram. The electronic structure of these films is playing a very crucial role and demands a fundamental understanding prior to device fabrication. We have investigated the electronic structure of La{sub 0.7}Ca{sub 0.3}Mn{sub 1−X}Al{sub X}O{sub 3} (X=0, 0.15) epitaxial thin films by soft X-ray absorption spectroscopy technique using the surface sensitive total electron yield (TEY) mode.

  8. Agricultural Research Service (ARS) Research Participation Program...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Home About USDA ARS About ORISE Current Research Opportunities Site Map Contact ORISE Facebook Twitter Applicants Welcome to the Agricultural Research Service (ARS) Research...

  9. Phase Relations and Elemental Distribution Among Co-Existing Phases in the Ceramics of the Pseudobinary System CaZrTi{sub 2}O{sub 7}-LnAlO{sub 3} (Ln= Nd, Sm)

    SciTech Connect

    Mikhailenko, Natalia; Stefanovsky, Sergey

    2007-07-01

    In the ceramics in series (1-x) CaZrTi{sub 2}O{sub 7} - x NdAlO{sub 3} and (1-x) CaZrTi{sub 2}O{sub 7} - x SmAlO{sub 3} (x = 0.25, 0.5 and 0.75) produced by cold pressing and sintering at 1400, 1450 and 1500 deg. C zirconolite was found to be a major phase, perovskite was an extra phase and traces of residual baddeleyite occurred. At x = 0.75 the perovskite was major phase and zirconolite and cubic oxide of fianite or tazheranite type were extra phases. Major Nd and Sm host phase at x = 0.25 was found to be zirconolite (about 65% of total Nd{sub 2}O{sub 3} and 74% of total Sm{sub 2}O{sub 3}). With the x value increasing perovskite becomes major host phase for Nd and Sm accumulating of up to about 92% of total Nd and about 72% of total Sm. As follows from SEM/EDS data Nd and Sm contents in the zirconolite may reach {approx}1 formula unit (fu). (authors)

  10. Lattice constant grading in the Al.sub.y Ca.sub.1-y As.sub.1-x Sb.sub.x alloy system

    DOEpatents

    Moon, Ronald L.

    1981-01-01

    Liquid phase epitaxy is employed to grow a lattice matched layer of GaAsSb on GaAs substrates through the compositional intermediary of the III-V alloy system AlGaAsSb which acts as a grading layer. The Al constituent reaches a peak atomic concentration of about 6% within the first 2.5.mu.m of the transition layer, then decreases smoothly to about 1% to obtain a lattice constant of 5.74 A. In the same interval the equilibrium concentration of Sb smoothly increases from 0 to about 9 atomic percent to form a surface on which a GaAsSb layer having the desired energy bandgap of 1.1 ev for one junction of an optimized dual junction photovoltaic device. The liquid phase epitaxy is accomplished with a step cooling procedure whereby dislocation defects are more uniformly distributed over the surface of the growing layer.

  11. CaO-MgO-Al2O3-SiO2 (CMAS) corrosion of Gd2Zr2O7 and Sm2Zr2O7

    DOE PAGES [OSTI]

    Wang, Honglong; Bakal, Ahmet; Zhang, Xingxing; Tarwater, Emily; Sheng, Zhizhi; Fergus, Jeffrey W.

    2016-08-08

    Ceramic thermal barrier coatings are applied to superalloys used in gas turbine engineering to increase the operating temperature and the energy conversion efficiency. However, dust consisting of CaO-MgO-Al2O3-SiO2 (CMAS) from the air can be injected into the engines and corrode the thermal barrier coatings. Lanthanide zirconates are promising materials in thermal barrier coatings due to their low thermal conductivities, good phase stability and good corrosion resistance. However, the corrosion resistance mechanism of CMAS on lanthanide zirconates is still not clearly understood. In this work, the corrosion mechanism of Gd2Zr2O7 and Sm2Zr2O7 in CMAS is studied. Here, the results show thatmore » the CMAS can easily react with lanthanide zirconate thermal barrier coatings to form a dense layer, which can resist further corrosion« less

  12. Production of Ar{sup q+} ions with a tandem linear Paul trap

    SciTech Connect

    Higaki, H. Nagayasu, K.; Iwai, T.; Ito, K.; Okamoto, H.

    2015-06-29

    A tandem linear Paul trap was used to create highly charged Argon ions by electron impact ionizations. By improving the operation scheme, the production of Ar{sup 4+} ions was confirmed. Possible improvements for the future experiments with laser cooled Ca{sup +} ions are suggested.

  13. Experimental study of the beta-delayed proton precursors /sup 33/Ar and /sup 49/Fe

    SciTech Connect

    XU Xiao-ji; GUO Jun-sheng; GUO Ying-xiang; ZHAO Zhi-zheng; LUO Yi-xiao

    1985-01-01

    Beta-delayed proton precursors /sup 33/Ar and /sup 49/Fe have been produced via the (/sup 12/C,3n) reaction in 65-MeV carbon bombardments of /sup 24/Mg and /sup 40/Ca, respectively. The major proton peaks are at 3.28 +- 0.07 MeV for /sup 33/Ar and 1.98 +- 0.04 MeV for /sup 49/Fe. The corresponding cross section for /sup 33/Ar is 0.40 +- 0.08 ..mu..b, and for /sup 49/Fe 0.70 +- 0.14 ..mu..b. The half-life of /sup 33/Ar was determined to be 167 +- 24 ms.

  14. 244-AR Vault Interim Stabilization Project Plan

    SciTech Connect

    LANEY, T.

    2000-03-24

    The 244-AR Vault Facility, constructed between 1966 and 1968, was designed to provide lag storage and treatment for the Plutonium-Uranium Extraction Facility (PUREX) tank farm sludges. Tank farm personnel transferred the waste from the 244-AR Vault Facility to B Plant for recovery of cesium and strontium. B Plant personnel then transferred the treatment residuals back to the tank farms for storage of the sludge and liquids. The last process operations, which transferred waste supporting the cesium/strontium recovery mission, occurred in April 1978. After the final transfer in 1978, the 244-AR facility underwent a cleanout. However, 2,271 L (600 gal) of sludge were left in Tank 004AR from an earlier transfer from Tank 241-AX-104. When the cleanout was completed, the facility was placed in a standby status. The sludge had been transferred to Tank 004AR to support Pacific Northwest National Laboratory [PNNL] vitrification work. Documentation of waste transfers suggests that a portion of the sludge may have been moved from Tank 004AR to Tank 002AR in preparation for transfer back to the AX Tank Farm; however, quantities of the sludge that were moved to Tank 002AR from that transfer must be estimated.

  15. Ars Technica Visits GE's China Technology Center | GE Global...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Technica visits GE's China Technology Center Click to email this to a friend (Opens in new ... Ars Technica visits GE's China Technology Center Ars Technica visited GE's China ...

  16. Mueller Systems ArKion | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Mueller Systems ArKion Jump to: navigation, search Name: Mueller Systems (ArKion) Place: Middleboro, Massachusetts Zip: MA 02346 Product: Massachusetts-based energy management...

  17. Postcollision interactions in the Auger decay of the Ar L-shell

    SciTech Connect

    Samson, J.A.R.; Stolte, W.C.; He, Z.X.

    1997-04-01

    The photoionization cross sections for Ar{sup +} through Ar{sup 4+}, produced by the Auger decay of an inner shell 2p hole, have been measured between 242 eV and 253 eV on beamline 9.0.1 and 6.3.2. In this study the authors are interested in near threshold phenomenon involving postcollision interactions (PCI), which are related to the Auger decay of a vacancy in the Ar L-shell. During an Auger decay a postcollision interaction can occur causing the out-going photoelectron to be retarded thus losing a certain amount of energy. If the retardation is sufficiently large the photoelectron will not escape. This result produces a singly charged ion, which normally would not be present. Such evidence of electron capture by the PCI effect was first shown clearly by Eberhardt et al. and, with higher resolution, in the present work. However, capture of the photoelectron is expected to be 100% exactly at the L{sub 2,3} thresholds. Thus, from the authors results they would have expected the Ar{sup 2+} signal to be zero at threshold, but it was not? The authors can explain this anomoly on the basis that during the Auger decay the photoelectrons are captured into high lying excited states of Ar{sup +}, which subsequently decay through autoionization yielding Ar{sup 2+}. Future work in this area will seek experimental evidence to verify this prediction.

  18. Hazard evaluation for 244-AR vault facility

    SciTech Connect

    BRAUN, D.J.

    1999-08-25

    This document presents the results of a hazard identification and evaluation performed on the 244-AR Vault Facility to close a USQ (USQ No.TF-98-0785, Potential Inadequacy in Authorization Basis (PIAB): To Evaluate Miscellaneous Facilities Listed In HNF-2503 And Not Addressed In The TWRS Authorization Basis) that was generated as part of an evaluation of inactive TWRS facilities. A hazard evaluation for the Hanford Site 244-AR Vault Facility was performed. The process and results of the hazard evaluation are provided in this document. A previous hazard evaluation was performed for the 244-AR Vault Facility in 1996 in support of the Basis for Interim Operation (BIO) (HNF-SD-WM-BIO-001, 1998, Revision 1) of the Tank Waste Remediation System (TWRS). The results of that evaluation are provided in the BIO. Upon review of those results it was determined that hazardous conditions that could lead to the release of radiological and toxicological material from the 244-AR vaults due to flooding was not addressed in the original hazards evaluation. This supplemental hazard evaluation addresses this oversight of the original hazard evaluation. The results of the hazard evaluation were compared to the current TWRS BIO to identify any hazardous conditions where Authorization Basis (AB) controls may not be sufficient or may not exist. This document is not part of the AB and is not a vehicle for requesting changes to the AB. It is only intended to provide information about hazardous conditions associated with the condition and configuration of the 244-AR vault facility. The AB Control Decision process could be used to determine the applicability and adequacy of existing AB controls as well as any new controls that may be needed for the identified hazardous conditions associated with 244-AR vault flooding. This hazard evaluation does not constitute an accident analysis.

  19. ALS Spectrum

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Spectrum Print Begun in 2007, ALS Spectrum is a publication that encapsulates the same type of information contained in the ALS Activity Report but in a short, readable, ...

  20. ALS Spectrum

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Spectrum Print Begun in 2007, ALS Spectrum is a publication that encapsulates the same type of information contained in the ALS Activity Report but in a short, readable,...

  1. ALS Spectrum

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Spectrum Print Begun in 2007, ALS Spectrum is a publication that encapsulates the same type of information contained in the ALS Activity Report but in a short, readable, ...

  2. ALS@20

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    tribulations encountered during the construction of the ALS from former Director Jay Marx, current ALS Scientific Director Steve Kevan and Director Roger Falcone talked about...

  3. ALS Spectrum

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Spectrum Print Begun in 2007, ALS Spectrum is a publication that encapsulates the same type of information contained in the ALS Activity Report but in a short, readable,...

  4. DOE - Office of Legacy Management -- Berkeley CA Site - CA 03

    Office of Legacy Management (LM)

    Berkeley CA Site - CA 03 FUSRAP Considered Sites Berkeley, CA Alternate Name(s): University of California Gilman Hall, University of California CA.03-1 Location: Gilman Hall, University of California, Berkeley, California CA.03-1 Historical Operations: Performed research and development on the synthesis and production of plutonium, resulting in uranium, plutonium, cesium and americium contamination. CA.03-3 CA.03-5 Eligibility Determination: Eligible CA.03-1 CA.03-2 Radiological Survey(s):

  5. Category:Little Rock, AR | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    71 KB SVMediumOffice Little Rock AR Entergy Arkansas Inc.png SVMediumOffice Little ... 68 KB SVMidriseApartment Little Rock AR Entergy Arkansas Inc.png SVMidriseApartment Lit......

  6. ARS 12 - Courts and Civil Proceedings | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ARS 12 - Courts and Civil Proceedings Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 12 - Courts and Civil ProceedingsLegal...

  7. A.R.S. 11-801 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 11-801 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-801Legal Abstract County Planning: Definitions...

  8. A.R.S. 41-865 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-865Legal Published NA Year Signed or Took Effect 2015 Legal Citation A.R.S. ...

  9. A.R.S. 11-802 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 11-802 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-802Legal Abstract County Planning: County planning...

  10. A.R.S. 40-281 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 40-281 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-281Legal Abstract Power Plant and Transmission Line...

  11. A.R.S. 40-360 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 40-360 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-360Legal Published NA Year Signed or Took Effect...

  12. A.R.S. 40-282 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 40-282 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-282Legal Abstract Power Plant and Transmission Line...

  13. A.R.S. 9-462 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 9-462 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 9-462Legal Published NA Year Signed or Took Effect...

  14. MEIS1 functions as a potential AR negative regulator

    SciTech Connect

    Cui, Liang; Yang, Yutao; Hang, Xingyi; Cui, Jiajun; Gao, Jiangping

    2014-10-15

    The androgen receptor (AR) plays critical roles in human prostate carcinoma progression and transformation. However, the activation of AR is regulated by co-regulators. MEIS1 protein, the homeodomain transcription factor, exhibited a decreased level in poor-prognosis prostate tumors. In this study, we investigated a potential interaction between MEIS1 and AR. We found that overexpression of MEIS1 inhibited the AR transcriptional activity and reduced the expression of AR target gene. A potential proteinprotein interaction between AR and MEIS1 was identified by the immunoprecipitation and GST pull-down assays. Furthermore, MEIS1 modulated AR cytoplasm/nucleus translocation and the recruitment to androgen response element in prostate specific antigen (PSA) gene promoter sequences. In addition, MEIS1 promoted the recruitment of NCoR and SMRT in the presence of R1881. Finally, MEIS1 inhibited the proliferation and anchor-independent growth of LNCaP cells. Taken together, our data suggests that MEIS1 functions as a novel AR co-repressor. - Highlights: A potential interaction was identified between MEIS1 and AR signaling. Overexpression of MEIS1 reduced the expression of AR target gene. MEIS1 modulated AR cytoplasm/nucleus translocation. MEIS1 inhibited the proliferation and anchor-independent growth of LNCaP cells.

  15. Bulk modulus and specific heat of B-site doped (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1−x}B{sub x}O{sub 3} (B=Fe, Cr, Ru, Al, Ga)

    SciTech Connect

    Srivastava, Archana; Thakur, Rasna; Gaur, N. K.

    2014-04-24

    Specific heat (C{sub p}) thermal expansion (α) and Bulk modulus (B{sub T}) of lightly doped Rare Earth manganites (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1−x}B{sub x}O{sub 3} (B{sup 3+} = Fe{sup 3+},Cr{sup 3+},Ga{sup 3+},Al{sup 3+},Ru4+); (0.3Ca{sub 0.35}Mn{sub 0.97}Fe{sub 0.03}O{sub 3} as a function of temperature (10K≤T≤ 200K) is found to be in agreement with the published data. The trend of variation of Debye temperature with B-site cationic radius is predicted probably for the first time for the B-site doped rare earth manganites.

  16. Industry @ ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Researchers from IBM's forward-thinking Spintronic Science and Applications Center (SpinAps) recently used the ALS to gain greater insight into vanadium dioxide's unusual phase ...

  17. ALS Spectrum

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    encapsulates the same type of information contained in the ALS Activity Report but in a short, readable, newsletter-like format. Featured scientific and facility developments are...

  18. Bimodal Energy Distributions in the Scattering of Ar+ Ions from...

    Office of Scientific and Technical Information (OSTI)

    Bimodal Energy Distributions in the Scattering of Ar+ Ions from Modified Surfaces at Hyperthermal Energies Citation Details In-Document Search Title: Bimodal Energy Distributions ...

  19. http://www.ars.usda.gov/research/publications/Publications.htm...

    National Nuclear Security Administration (NNSA)

    - Ed Wagner, Larry Tatarko, John Publications Publications Related National Programs Air Quality (203) Soil Resource Management (202) Page 1 of 2 ARS | Publication request:...

  20. Beta decay of 32Ar for fundamental tests

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Beta decay of 32 Ar for fundamental tests Chris Wrede University of Washington Argonne-ATLAS user meeting August 8 th , 2009 Outline * 1999 measurement of positron-neutrino correlation in 32 Ar(e + nu e ): ISOL facility (CERN-ISOLDE) * 2008 measurement the ft value for superallowed 32 Ar(e + nu e ) decay to test isospin symmetry breaking corrections: fragmentation facility (MSU-NSCL) * Where does ATLAS fit in to this? A bridge from stability to 32 Ar! Detecting scalar currents in weak decays n e

  1. Development of electrically insulating CaO coatings

    SciTech Connect

    Natesan, K.; Reed, C.B.; Uz, M.; Rink, D.L.

    1998-09-01

    A systematic study has been initiated to develop electrically insulating CaO coatings by vapor phase transport and by in-situ formation in a liquid Li environment. Several experiments were conducted in vapor transport studies with variations in process temperature, time, specimen location, specimen surface preparation, and pretreatment. Several of the coatings obtained by the method exhibited Ca concentration in the range of 60--95 wt.% on the surface. However, coating thickness has not been very uniform among several samples exposed in the same run or even within the same sample. The coatings developed in these early tests degraded after 24 h exposure to Li at 500 C. Additional experiments are underway to develop better-adhering and more dense coatings by this method. A program to develop in-situ CaO coatings in Li has been initiated, and the first set of capsule tests at 800 C in three different Li-Ca mixtures will be completed in early July. Specimens included in the run are bare V-4Cr-4Ti alloy, specimens with a grit-blasted surface and O-precharged in 99.999% Ar, polished specimens precharged in a 99.999% Ar and 5000 ppm O{sub 2}-N{sub 2} mixture, and prealuminized V-5Cr-5Ti alloy preoxidized in a 5000 ppm O{sub 2}-N{sub 2} mixture. Additional experiments at lower temperatures are planned.

  2. ALS Visitors

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... September 2012 Congressman Steve Womack (R-Arkansas) toured the ALS on September 25, along ... Womack, a freshman member of Congress is Vice Chairman of the House Energy and Water ...

  3. ARS 41-1072 Licensing Time Frames | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    1-1072 Licensing Time Frames Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 41-1072 Licensing Time FramesLegal Abstract...

  4. A.R.S. 11-804 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-804Legal Abstract This section authorizes counties to develop and adopt...

  5. A.R.S. 41-841 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-841Legal Abstract Archaeological Discoveries Published NA Year Signed or Took...

  6. A.R.S. 41-842 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-842Legal Abstract Discusses the requirement of prior authorization in order to...

  7. A.R.S. 41-861 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-861Legal Abstract This section discusses agency responsibility for the...

  8. A.R.S. 41-843 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-843Legal Abstract Prohibits the unnecessary defacing of an archaeological and...

  9. 49 A.R.S. 201: Definitions | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 201: DefinitionsLegal Abstract This section contains definitions that relate to water...

  10. A.R.S. 11-811 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-811Legal Abstract This section authorizes counties to adopt zoning ordinances....

  11. ARS 41-1092 Uniform Administrative Hearing Procedures | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    92 Uniform Administrative Hearing Procedures Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 41-1092 Uniform Administrative...

  12. ARS 40 - Public Utilities and Carriers | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    StatuteStatute: ARS 40 - Public Utilities and CarriersLegal Abstract This title sets forth the statutes for public utilities and carriers in Arizona. Published NA Year Signed...

  13. NEW OF SCHWINGER VARIATIONAL PRINCIPLE FOR K-SHELL EXCITATION OF CA{sup 18+} (1S{sup 2}) IONS BY IMPACT OF VARIOUS ATOMS AT 8.6 MeV/amu

    SciTech Connect

    Lasri, B.; Hanssen, J.

    2011-10-27

    A new variational impact parameter approach to the process of direct electronic excitation of atoms by impact of ions at intermediate velocities regimes was shown to be very successful in predicting the saturation of cross sections when the projectile charge is increased [1-4]. In our approach, this new procedure is based on the fractional form of the Schwinger variational principle and applied to study K-shell excitation of Ca{sup 18+} (1s{sup 2}) ions impinging at 8.6 MeV/amu on various gases (H{sub 2}, He, N{sub 2}, O{sub 2}, Ne, Ar, Kr, Xe). The excitation cross sections are compared with another theoretical approaches, like Born approximation. All obtained results stay in good agreement with experimental data of Xiang-Yuan Xu et al.[5].

  14. Combined U-Th/He and 40Ar/39Ar geochronology of post-shield lavas from the Mauna Kea and Kohala volcanoes, Hawaii

    SciTech Connect

    Aciego, S.M.; Jourdan, F.; DePaolo, D.J.; Kennedy, B.M.; Renne, P.R.; Sims, K.W.W.

    2009-10-01

    Late Quaternary, post-shield lavas from the Mauna Kea and Kohala volcanoes on the Big Island of Hawaii have been dated using the {sup 40}Ar/{sup 39}Ar and U-Th/He methods. The objective of the study is to compare the recently demonstrated U-Th/He age method, which uses basaltic olivine phenocrysts, with {sup 40}Ar/{sup 39}Ar ages measured on groundmass from the same samples. As a corollary, the age data also increase the precision of the chronology of volcanism on the Big Island. For the U-Th/He ages, U, Th and He concentrations and isotopes were measured to account for U-series disequilibrium and initial He. Single analyses U-Th/He ages for Hamakua lavas from Mauna Kea are 87 {+-} 40 ka to 119 {+-} 23 ka (2{sigma} uncertainties), which are in general equal to or younger than {sup 40}Ar/{sup 39}Ar ages. Basalt from the Polulu sequence on Kohala gives a U-Th/He age of 354 {+-} 54 ka and a {sup 40}Ar/{sup 39}Ar age of 450 {+-} 40 ka. All of the U-Th/He ages, and all but one spurious {sup 40}Ar/{sup 39}Ar ages conform to the previously proposed stratigraphy and published {sup 14}C and K-Ar ages. The ages also compare favorably to U-Th whole rock-olivine ages calculated from {sup 238}U - {sup 230}Th disequilibria. The U-Th/He and {sup 40}Ar/{sup 39}Ar results agree best where there is a relatively large amount of radiogenic {sup 40}Ar (>10%), and where the {sup 40}Ar/{sup 36}Ar intercept calculated from the Ar isochron diagram is close to the atmospheric value. In two cases, it is not clear why U-Th/He and {sup 40}Ar/{sup 39}Ar ages do not agree within uncertainty. U-Th/He and {sup 40}Ar/{sup 39}Ar results diverge the most on a low-K transitional tholeiitic basalt with abundant olivine. For the most alkalic basalts with negligible olivine phenocrysts, U-Th/He ages were unattainable while {sup 40}Ar/{sup 39}Ar results provide good precision even on ages as low as 19 {+-} 4 ka. Hence, the strengths and weaknesses of the U-Th/He and {sup 40}Ar/{sup 39}Ar methods are

  15. Influence of Fe-doped Graphite Electrode Characteristics on Ar-H2 Carbon Arc Plasma and SWCNT Formation

    SciTech Connect

    Huczko, A.; Lange, H.; Bystrzejewski, M.; Ando, Y.; Zhao, X.; Inoue, S.

    2005-09-27

    Two Fe-doped (ca. 1 at.%) homogeneous graphite electrodes (different graphite microcrystals, degree of graphitization and, thereby, electrical conductivities) electrodes were used in the process of production of single-walled carbon nanotubes in Ar-H2 arc plasma under pressure 26 kPa. The C2 content (namely carbon vapor pressure) and temperature distributions in the arc plasma were determined using optical emission spectroscopy. The mechanism of CNT formation based on carbon dimers as the building blocks seems to be at least questionable.

  16. Characterizing Fluorocarbon Assisted Atomic Layer Etching of Si Using Cyclic Ar/C4F8 and Ar/CHF3 Plasma

    DOE PAGES [OSTI]

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L; Joseph, Eric A; Oehrlein, Gottlieb S

    2016-09-08

    With the increasing interest in establishing directional etching methods capable of atomic scale resolution for fabricating highly scaled electronic devices, the need for development and characterization of atomic layer etching (ALE) processes, or generally etch processes with atomic layer precision, is growing. In this work, a flux-controlled cyclic plasma process is used for etching of SiO2 and Si at the Angstrom-level. This is based on steady-state Ar plasma, with periodic, precise injection of a fluorocarbon (FC) precursor (C4F8 and CHF3), and synchronized, plasma-based Ar+ ion bombardment [D. Metzler et al., J Vac Sci Technol A 32, 020603 (2014), and D.more » Metzler et al., J Vac Sci Technol A 34, 01B101 (2016)]. For low energy Ar+ ion bombardment conditions, physical sputter rates are minimized, whereas material can be etched when FC reactants are present at the surface. This cyclic approach offers a large parameter space for process optimization. Etch depth per cycle, removal rates, and self-limitation of removal, along with material dependence of these aspects, were examined as a function of FC surface coverage, ion energy, and etch step length using in situ real time ellipsometry. The deposited FC thickness per cycle is found to have a strong impact on etch depth per cycle of SiO2 and Si, but is limited with regard to control over material etching selectivity. Ion energy over the 20 to 30 eV range strongly impacts material selectivity. The choice of precursor can have a significant impact on the surface chemistry and chemically enhanced etching. CHF3 has a lower FC deposition yield for both SiO2 and Si, and also exhibits a strong substrate dependence of FC deposition yield, in contrast to C4F8. The thickness of deposited FC layers using CHF3 is found to be greater for Si than for SiO2. X-ray photoelectron spectroscopy was used to study surface chemistry. When thicker FC films of 11 Å are employed, strong changes of FC film chemistry during a cycle are

  17. Ca rlsbad Field Office

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    En ergy Ca rlsbad Field Office P. O . Box 3090 Carlsbad , New Mexico 88221 AUG 2 9 2013 Mr. John E. Kieling , Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, New Mexico 87505-6303 Subject: Notification of Class 1 Permit Modification to the Waste Isolation Pilot Plant Hazardous Waste Facility Permit Number: NM4890139088-TSDF Dear Mr. Kieling: Enclosed is a Class 1 Permit Modification Notification for the fo ll owing items: * Revise a

  18. ALS Communications Group

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Communications Group Print From left: Ashley White, Lori Tamura, Keri Troutman, and Carina Braun. The ALS Communications staff maintain the ALS Web site; write and edit all...

  19. About the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and science. You can also view ALS visitors and award recipients. Strategic Plan Roadmap for the renewal of ALS facility and scientific programs. Organization ALS...

  20. Interatomic scattering in energy dependent photoelectron spectra of Ar clusters

    SciTech Connect

    Patanen, M.; Benkoula, S.; Nicolas, C.; Goel, A.; Antonsson, E.; Neville, J. J.; Miron, C.

    2015-09-28

    Soft X-ray photoelectron spectra of Ar 2p levels of atomic argon and argon clusters are recorded over an extended range of photon energies. The Ar 2p intensity ratios between atomic argon and clusters’ surface and bulk components reveal oscillations similar to photoelectron extended X-ray absorption fine structure signal (PEXAFS). We demonstrate here that this technique allows us to analyze separately the PEXAFS signals from surface and bulk sites of free-standing, neutral clusters, revealing a bond contraction at the surface.

  1. Structural, magnetic, and superconducting properties of pulsed-laser-deposition-grown La1.85 Sr0.15 CuO4 / La2/3 Ca1/3 MnO3 superlattices on (001)-oriented LaSrAlO4 substrates

    DOE PAGES [OSTI]

    Das, S.; Sen, K.; Marozau, I.; Uribe-Laverde, M. A.; Biskup, N.; Varela, M.; Khaydukov, Y.; Soltwedel, O.; Keller, T.; Döbeli, M.; et al

    2014-03-12

    Epimore » taxial La1.85 Sr0.15 CuO4 / La2/3 Ca1/3 MnO3 (LSCO/LCMO) superlattices (SL) on (001)- oriented LaSrAlO4 substrates have been grown with pulsed laser deposition (PLD) technique. Their structural, magnetic and superconducting properties have been determined with in-situ reflection high energy electron diffraction (RHEED), x-ray diffraction, specular neutron reflectometry, scanning transmission electron microscopy (STEM), electric transport, and magnetization measurements. We find that despite the large mismatch between the in-plane lattice parameters of LSCO (a = 0.3779 nm) and LCMO (a = 0.387 nm) these superlattices can be grown epitaxially and with a high crystalline quality. While the first LSCO layer remains clamped to the LSAO substrate, a sizeable strain relaxation occurs already in the first LCMO layer. The following LSCO and LCMO layers adopt a nearly balanced state in which the tensile and compressive strain effects yield alternating in-plane lattice parameters with an almost constant average value. No major defects are observed in the LSCO layers, while a significant number of vertical antiphase boundaries are found in the LCMO layers. The LSCO layers remain superconducting with a relatively high superconducting onset temperature of Tconset ≈ 36 K. The macroscopic superconducting response is also evident in the magnetization data due to a weak diamagnetic signal below 10 K for H ∥ ab and a sizeable paramagnetic shift for H ∥ c that can be explained in terms of a vortex-pinning-induced flux compression. The LCMO layers maintain a strongly ferromagnetic state with a Curie temperature of TCurie ≈ 190 K and a large low-temperature saturation moment of about 3.5 (1) μB. These results suggest that the LSCO/LCMO superlattices can be used to study the interaction between the antagonistic ferromagnetic and superconducting orders and, in combination with previous studies on YBCO/LCMO superlattices, may allow one to identify the relevant

  2. New Rydberg-Rydberg transitions of the ArH and ArD molecules: Bands involving the 4f complex of ArD

    SciTech Connect

    Dabrowski, I.; Tokaryk, D.; Watson, J.K.G.; Lipson, R.H.

    1995-12-31

    The 4f {r_arrow} 5s transition of ArD is observed in Ar/D{sub 2} discharges as a band near 4830 {Angstrom}1 (v{sub 00} = 20682 cm{sup -1}) with O, Q and S-form branches. On the basis of a preliminary rotational analysis of this band, the transitions 4f {r_arrow} 3d{sigma}, 4f {r_arrow} 3d{pi}, and 4f {r_arrow} 3d{delta} to the three components of the 3d complex could be assigned to bands at 4371, 7666 and 6045 cm{sup -1}, respectively. These bands give information on components of the 4f complex not seen in the 4f {r_arrow} 5s band. The 4f complex is found to be a good example of Hund`s case (d), with R = 0 splittings that are predominantly of second-rank tensor type with the coefficient of {lambda}{sup 2} equal to 16.5 cm{sup -1}. A number of small perturbations are probably due to vibrational levels of other electronic states, but two larger perturbations near R = 11 and R = 24 are attributed to v = 0 of the 4d{delta} and 4d{sigma} states, respectively. The quantum defects of the 4f and other states will be discussed in terms of the properties of the ArH{sup +} or ArD{sup +} core, including the I-mixing effects of the core electric dipole moment.

  3. Precision angle-resolved autoionization resonances in Ar and Ne

    SciTech Connect

    Berrah, N.; Langer, B.; Gorczyca, T.W.

    1997-04-01

    Theoretical work has shown that the electron angular distribution and the shape of the autoionization resonances are crucial to the understanding of certain types of electron-electron correlation. Autoionization resonances in Ne (Ar) result from the decay of the excited discrete state Ne{sup *} 2s2p{sup 6} np (Ar{sup *} 3s3p{sup 6} np) into the continuum state Ne{sup +} 2s{sup 2}2p{sup 5} + e{sup {minus}} (ks,kd) (Ar{sup +} 3s{sup 2}3p{sup 5} + e{sup {minus}} (ks,kd)). Since the continuum can also be reached by direct photoionization, both paths add coherently, giving rise to interferences that produce the characteristic Beutler-Fano line shape. In this work, the authors report on quantitative angle-resolved electron spectrometry studies of (a) the Ne 2s{sup 2}2p{sup 6} {r_arrow} 2s2p{sup 6} np (n=3-5) autoionizing resonances and the 2s{sup 2}2p{sup 6} {r_arrow} 2p{sup 4}3s3p doubly excited resonance, (b) the Ar 3s{sup 2}3p{sup 6} {r_arrow} 3s3p{sup 6} np (n=4-9) autoionization resonances and extended R-matrix calculations of the angular-distribution parameters for both Ne and Ar measurements. Their results are compared with previous theoretical work by Taylor.

  4. TOUGH2/EOS7CA

    Energy Science and Technology Software Center

    003504MLTPL00 EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

  5. sup 40 Ar- sup 39 Ar and K-Ar dating of K-rich rocks from the Roccamonfina volcano, Roman Comagmatic Region, Italy

    SciTech Connect

    Di Brozolo, F.R.; Di Girolamo, P.; Turi, B.; Oddone, M. )

    1988-06-01

    Roccamonfina is the northernmost Volcano of the Campanian area of the K-rich Roman comagmatic Region of Italy. It erupted a huge amount of pyroclastics and lavas belonging to both the Leucite-Basanite and Leucitite Series (LBLS) and the Shoshonite Series (SS), spread over an area of about 300 km{sup 2}. The above series correspond to the High-K Series (HKS) and Low-K Series (LKS) of Appleton (1971), respectively. {sup 40}Ar-{sup 39}Ar and K-Ar dating of samples from both series gave ages ranging from 0.656 to 0.096 Ma for the SS and from 1.03( ) to 0.053 Ma for the LBLS. These results indicate that the products of the two series were outpoured together at least between 0.7 and 0.1 Ma age, i.e. during both the so-called pre-caldera phase and the post-caldera phase of activity. The latest products of the volcanism at Roccamonfina were erupted just before the deposition of the Grey Campanian Ignimbrite, which erupted from vents located about 50 km to the south in the Phlegrean Fields near Naples and has an age of about 33,000 years. Taking into account all the available all the available radiometric data the authors conclude that Roccamonfina was active between 1.5 and 0.05 Ma ago, in excellent agreement with the stratigraphic evidence. In this same time span is concentrated the activity of all the centers of the Roman Region north of Naples.

  6. 41 A.R.S. 1092 et seq.: Uniform Administrative Hearing Procedures...

    OpenEI (Open Energy Information) [EERE & EIA]

    A.R.S. 1092 et seq.: Uniform Administrative Hearing Procedures Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 41 A.R.S. 1092 et...

  7. VA VT CT RI MT WY CO ID UT OR NV CA AZ NM WA TN WV NC AR OK

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2 1 Locations of Smart Grid Demonstration and Large-Scale Energy Storage Projects NH 32 Awards Support Projects in 24 States 6 11 MA

  8. VA VT CT RI MT WY CO ID UT OR NV CA AZ NM WA TN WV NC AR OK

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2 1 Locations of Smart Grid Demonstration and Large-Scale Energy Storage Projects NH 32 Awards Support Projects in 24 States 6 11 MA

  9. VA VT CT RI MT WY CO ID UT OR NV CA AZ NM WA TN WV NC AR OK

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2 1 Smart Grid Demonstration Project Locations NH MA 16 Awards Support Projects in 21 States

  10. VA VT CT RI MT WY CO ID UT OR NV CA AZ NM WA TN WV NC AR OK

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7 2 1 Energy Storage Demonstration Project Locations NH 16 Awards Support Projects in 9 States MA

  11. ALS Chemistry Lab

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for ...

  12. OSTI Announces Alert Service for arXiv Patrons | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information Announces Alert Service for arXiv Patrons Back to the OSTI News Listing for 2005 Now arXiv patrons can receive automatic notification of the latest information posted on arXiv, as well as other e-print sources in OSTI's E-print Network

  13. ALS Communications Group

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Communications Group Print From left: Ashley White, Lori Tamura, Keri Troutman, and Carina Braun. The ALS Communications staff maintain the ALS Web site; write and edit all print...

  14. ALS Users' Association Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Awards: David A. Shirley Award for Outstanding Scientific Achievement at the ALS Klaus Halbach Award for Innovative Instrumentation at the ALS Tim Renner User Services Award for...

  15. ALS User Meeting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    User Meeting ALS User Meeting web banner ALS User Meeting: October 5-7, 2015 Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User...

  16. ALS User Meeting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS User Meeting Print web banner ALS User Meeting: October 5-7, 2015 Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User Meeting...

  17. ALS Users' Association Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Source (ALS) at the Lawrence Berkeley Laboratory (LBL) for their research and the ALS management, as well as to provide a channel for communication with other synchrotron...

  18. High resolution rotational spectroscopy of weakly bound ionic clusters: ArH/sub 3//sup +/, ArD/sub 3//sup +/

    SciTech Connect

    Bogey, M.; Bolvin, H.; Demuynck, C.; Destombes, J.L.

    1987-03-09

    The first high-resolution study of weakly bound cluster ions is reported. The millimeter- and submillimeter-wave rotational spectra of ArH/sub 3/ /sup +/ and ArD/sub 3/ /sup +/ have been observed in a magnetically confined, liquid-nitrogen--cooled glow discharge and a partial molecular structure has been derived from their analysis. ArH/sub 3/ /sup +/ appears to be planar, with the Ar atom lying on a symmetry axis of the H/sub 3/ /sup +/ equilateral triangle, 2.38 A from the H/sub 3/ /sup +/ centroid. SPlitting of some of the lines is strong evidence for tunneling motion.

  19. Southern CA Area | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    CA Area Jump to: navigation, search Contents 1 Clean Energy Clusters in the Southern CA Area 1.1 Products and Services in the Southern CA Area 1.2 Research and Development...

  20. Dusty Plasma in He-Ar Glow Discharge

    SciTech Connect

    Maiorov, S. A.; Ramazanov, T. S.; Dzhumagulova, K. N.; Dosbolayev, M. K.; Jumabekov, A. N.

    2008-09-07

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for He-Ar mixture. It is shown that under the conventional conditions of the experiments with dusty structures in plasma, the choice of light and heavy gases for the mixture suppresses electron heating in electric field and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths and gas pressures.

  1. TI--CR--AL--O thin film resistors

    DOEpatents

    Jankowski, Alan F.; Schmid, Anthony P.

    2000-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  2. ALS Chemistry Lab

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for ...

  3. An international land-biosphere model benchmarking activity for the IPCC Fifth Assessment Report (AR5)

    SciTech Connect

    Hoffman, Forrest M [ORNL; Randerson, James T [ORNL; Thornton, Peter E [ORNL; Bonan, Gordon [National Center for Atmospheric Research (NCAR); Erickson III, David J [ORNL; Fung, Inez [University of California, Berkeley

    2009-12-01

    The need to capture important climate feedbacks in general circulation models (GCMs) has resulted in efforts to include atmospheric chemistry and land and ocean biogeochemistry into the next generation of production climate models, called Earth System Models (ESMs). While many terrestrial and ocean carbon models have been coupled to GCMs, recent work has shown that such models can yield a wide range of results (Friedlingstein et al., 2006). This work suggests that a more rigorous set of global offline and partially coupled experiments, along with detailed analyses of processes and comparisons with measurements, are needed. The Carbon-Land Model Intercomparison Project (C-LAMP) was designed to meet this need by providing a simulation protocol and model performance metrics based upon comparisons against best-available satellite- and ground-based measurements (Hoffman et al., 2007). Recently, a similar effort in Europe, called the International Land Model Benchmark (ILAMB) Project, was begun to assess the performance of European land surface models. These two projects will now serve as prototypes for a proposed international land-biosphere model benchmarking activity for those models participating in the IPCC Fifth Assessment Report (AR5). Initially used for model validation for terrestrial biogeochemistry models in the NCAR Community Land Model (CLM), C-LAMP incorporates a simulation protocol for both offline and partially coupled simulations using a prescribed historical trajectory of atmospheric CO2 concentrations. Models are confronted with data through comparisons against AmeriFlux site measurements, MODIS satellite observations, NOAA Globalview flask records, TRANSCOM inversions, and Free Air CO2 Enrichment (FACE) site measurements. Both sets of experiments have been performed using two different terrestrial biogeochemistry modules coupled to the CLM version 3 in the Community Climate System Model version 3 (CCSM3): the CASA model of Fung, et al., and the carbon

  4. AmeriFlux US-AR1 ARM USDA UNL OSU Woodward Switchgrass 1 (Dataset) | Data

    Office of Scientific and Technical Information (OSTI)

    Explorer AR1 ARM USDA UNL OSU Woodward Switchgrass 1 Title: AmeriFlux US-AR1 ARM USDA UNL OSU Woodward Switchgrass 1 This is the AmeriFlux version of the carbon flux data for the site US-AR1 ARM USDA UNL OSU Woodward Switchgrass 1. Site Description - The ARM USDA UNL OSU Woodward Switchgrass 1 tower is located on public land owned by the USDA-ARS Southern Plains Range Research Station in Woodward, Oklahoma. The site is on a former native prairie that is in the process of changing to

  5. AmeriFlux US-AR2 ARM USDA UNL OSU Woodward Switchgrass 2 (Dataset) | Data

    Office of Scientific and Technical Information (OSTI)

    Explorer AR2 ARM USDA UNL OSU Woodward Switchgrass 2 Title: AmeriFlux US-AR2 ARM USDA UNL OSU Woodward Switchgrass 2 This is the AmeriFlux version of the carbon flux data for the site US-AR2 ARM USDA UNL OSU Woodward Switchgrass 2. Site Description - The ARM USDA UNL OSU Woodward Switchgrass 2 tower is located on public land owned by the USDA-ARS Southern Plains Range Research Station in Woodward, Oklahoma. The site is on a former wheat field that is in the process of changing to

  6. Ca

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    James Bearzi, Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, New Mexico 87505-6303 April 27, 2010 Subject:...

  7. Ca

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    consistent with Groundwater Permit Modification Work Plan (work plan) for Calendar ... of the Culebra behavior in the vicinity surounding the WIPP site (Kuhlman, 2010). ...

  8. Ca

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    John Kieling , Acting Bureau Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Bldg. 1 Santa Fe, NM 87505-6303 FEB 2 3 2012 Subject: Transmittal of the Final Audit Report for SRS/CCP Certification Audit A-1 2-04 Dear Mr. Kieling : This letter transmits the Final Audit Report for Carlsbad Field Office Audit A-12-04 of the Savannah River Site Central Chara cterization Project (SRS/CCP) processes performed to characterize and certify waste , as required by

  9. Ca

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    James Bearzi, Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, New Mexico 87505-6303 April 27, 2010 Subject: Notification of Sampling Line Loss, Waste Isolation Pilot Plant Permit Number NM4890139088-TSDF Dear Mr. Bearzi: The purpose of this letter is to transmit notification to the New Mexico Environment Department (NMED) of the loss of a hydrogen and methane monitoring sampling line and the results of the associated evaluation as

  10. Improved thermoelectric performance of n-type Ca and Ca-Ce filled skutterudites

    DOE PAGES [OSTI]

    Thompson, Daniel R.; Liu, Chang; Ellison, Nicole D.; Salvador, James R.; Meyer, Martin S.; Haddad, Daad B.; Wang, Hsin; Cai, W.

    2014-12-28

    Thermoelectric (TE) technology for use in automotive waste heat recovery is being advanced by General Motors with support from the US Department of Energy. Skutterudites are a very promising material for this application of TE technology due to their superior mechanical properties and good TE performance. Double-filled YbxBayCo4Sb12 with ZT values around 1.1 at 750K are the best performing n-type skutterudites produced on a large scale using an economically viable approach of melt spinning (MS) in conjunction with spark plasma sintering (SPS). Another economical production method on the tons scale, the melt quench annealing (MQA) technique, has been recently claimedmore » by Treibacher Industrie AG, further information is available [G. Rogl et al., Acta Mater. 76, 434-448 (2014)]. A possible hurdle to commercial implementation of these materials is the use of rare earths as the fillers to reduce thermal conductivity and improve the electrical transport properties. It will be shown herein that skutterudites double-filled with Ca and Ce, both of which are lower-cost fillers, display markedly different TE properties depending on whether they are produced by MQA or MS + SPS synthesis techniques. Finally, Ca and Ce double-filled skutterudites prepared by MS + SPS have TE properties that are superior to the same compositions prepared by MQA and that are comparable to the best performing Yb and Ba filled materials. Furthermore, the results of this study suggest that the unusually poor transport properties of MQA Ca-filled skutterudites can be ascribed to deleterious secondary phases, which is contrary to reports in the literature attempting to explain these irregularities via band structure features.« less

  11. Improved thermoelectric performance of n-type Ca and Ca-Ce filled skutterudites

    SciTech Connect

    Thompson, Daniel R.; Liu, Chang; Ellison, Nicole D.; Salvador, James R.; Meyer, Martin S.; Haddad, Daad B.; Wang, Hsin; Cai, W.

    2014-12-28

    Thermoelectric (TE) technology for use in automotive waste heat recovery is being advanced by General Motors with support from the US Department of Energy. Skutterudites are a very promising material for this application of TE technology due to their superior mechanical properties and good TE performance. Double-filled Yb{sub x}Ba{sub y}Co{sub 4}Sb{sub 12} with ZT values around 1.1 at 750 K are the best performing n-type skutterudites produced on a large scale using an economically viable approach of melt spinning (MS) in conjunction with spark plasma sintering (SPS). Another economical production method on the tons scale, the melt quench annealing (MQA) technique, has been recently claimed by Treibacher Industrie AG, further information is available [G. Rogl et al., Acta Mater. 76, 434–448 (2014)]. A possible hurdle to commercial implementation of these materials is the use of rare earths as the fillers to reduce thermal conductivity and improve the electrical transport properties. It will be shown herein that skutterudites double-filled with Ca and Ce, both of which are lower-cost fillers, display markedly different TE properties depending on whether they are produced by MQA or MS + SPS synthesis techniques. Ca and Ce double-filled skutterudites prepared by MS + SPS have TE properties that are superior to the same compositions prepared by MQA and that are comparable to the best performing Yb and Ba filled materials. Furthermore, the results of this study suggest that the unusually poor transport properties of MQA Ca-filled skutterudites can be ascribed to deleterious secondary phases, which is contrary to reports in the literature attempting to explain these irregularities via band structure features.

  12. Improved thermoelectric performance of n-type Ca and Ca-Ce filled skutterudites

    SciTech Connect

    Thompson, Daniel R.; Liu, Chang; Ellison, Nicole D.; Salvador, James R.; Meyer, Martin S.; Haddad, Daad B.; Wang, Hsin; Cai, W.

    2014-12-28

    Thermoelectric (TE) technology for use in automotive waste heat recovery is being advanced by General Motors with support from the US Department of Energy. Skutterudites are a very promising material for this application of TE technology due to their superior mechanical properties and good TE performance. Double-filled YbxBayCo4Sb12 with ZT values around 1.1 at 750K are the best performing n-type skutterudites produced on a large scale using an economically viable approach of melt spinning (MS) in conjunction with spark plasma sintering (SPS). Another economical production method on the tons scale, the melt quench annealing (MQA) technique, has been recently claimed by Treibacher Industrie AG, further information is available [G. Rogl et al., Acta Mater. 76, 434-448 (2014)]. A possible hurdle to commercial implementation of these materials is the use of rare earths as the fillers to reduce thermal conductivity and improve the electrical transport properties. It will be shown herein that skutterudites double-filled with Ca and Ce, both of which are lower-cost fillers, display markedly different TE properties depending on whether they are produced by MQA or MS + SPS synthesis techniques. Finally, Ca and Ce double-filled skutterudites prepared by MS + SPS have TE properties that are superior to the same compositions prepared by MQA and that are comparable to the best performing Yb and Ba filled materials. Furthermore, the results of this study suggest that the unusually poor transport properties of MQA Ca-filled skutterudites can be ascribed to deleterious secondary phases, which is contrary to reports in the literature attempting to explain these irregularities via band structure features.

  13. DOE - Office of Legacy Management -- Stauffer-Temescal Co - CA...

    Office of Legacy Management (LM)

    CA.12-1 CA.12-2 CA.12-3 Location: 1201 South 47th Street , Richmond , California CA.12-1 ... CA.12-1 - Report; Trip Report to Stauffer Metals Company, Richmond California on April 4 ...

  14. Uv-preionized ArF and KrF excimer lasers

    SciTech Connect

    Cheng, S.; Cailai, Y.; Alrong, Y.C.D.

    1981-11-01

    Experimental investigations of UV-preionized ArF and KrF excimer lasers are reported. The output laser energies of 105 mJ for ArF and 185 mJ for KrF are obtained. Effects of various parameters on the laser characteristics are discussed.

  15. Design Analysis Report for 244-AR Interim Stabilization Exhaust Ventilation Ducting

    SciTech Connect

    RUTHERFORD, J.

    2002-11-21

    This report documents the design analysis performed for the exhaust ducting associated with the 244-AR Interim Stabilization Project. The exhaust ducting connects portable exhausters PORO5 and PORO6 to the existing east dog house of the 291-AR filter vault and the vessel ventilation system. This analysis examines loads on the ductwork and ductwork supports.

  16. Alignment of Ar{sup +} [{sup 3}P]4p{sup 2}P{sup 0}{sub 3/2} satellite state from the polarization analysis of fluorescent radiation after photoionization

    SciTech Connect

    Yenen, O.; McLaughlin, K.W.; Jaecks, D.H.

    1997-04-01

    The measurement of the polarization of radiation from satellite states of Ar{sup +} formed after the photoionization of Ar provides detailed information about the nature of doubly excited states, magnetic sublevel cross sections and partial wave ratios of the photo-ejected electrons. Since the formation of these satellite states is a weak process, it is necessary to use a high flux beam of incoming photons. In addition, in order to resolve the many narrow doubly excited Ar resonances, the incoming photons must have a high resolution. The characteristics of the beam line 9.0.1 of the Advanced Light Source fulfill these requirements. The authors determined the polarization of 4765 {Angstrom} fluorescence from the Ar{sup +} [{sup 3}P] 4p {sup 2}P{sub 3/2}{sup 0} satellite state formed after photoionization of Ar by photons from the 9.0.1 beam line of ALS in the 35.620-38.261 eV energy range using a resolution of approximately 12,700. This is accomplished by measuring the intensities of the fluorescent light polarized parallel (I{parallel}) and perpendicular (I{perpendicular}) to the polarization axis of the incident synchrotron radiation using a Sterling Optics 105MB polarizing filter. The optical system placed at 90{degrees} with respect to the polarization axis of the incident light had a narrow band interference filter ({delta}{lambda}=0.3 nm) to isolate the fluorescent radiation.

  17. ALS Chemistry Lab

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE controls are employed in...

  18. Science DMZ for ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU ...

  19. Access to the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS User Services Office and take safety training (see Complete Safety Training ) before ... the User Office in advance and have all their online forms completed before their arrival. ...

  20. 2013 ALS User Meeting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    3 ALS User Meeting banner Home Agenda Awards Exhibitors Lodging Posters Registration T-Shirt Contest Transportation Workshops Contact Us User Meeting Archives Users' Executive...

  1. 2013 ALS User Meeting

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2013 ALS User Meeting Print banner Home Agenda Awards Exhibitors Lodging Posters Registration T-Shirt Contest Transportation Workshops Contact Us User Meeting Archives Users'...

  2. Excellent Passivation and Low Reflectivity Al2O3/TiO2 Bilayer Coatings for n-Wafer Silicon Solar Cells: Preprint

    SciTech Connect

    Lee, B. G.; Skarp, J.; Malinen, V.; Li, S.; Choi, S.; Branz, H. M.

    2012-06-01

    A bilayer coating of Al2O3 and TiO2 is used to simultaneously achieve excellent passivation and low reflectivity on p-type silicon. This coating is targeted for achieving high efficiency n-wafer Si solar cells, where both passivation and anti-reflection (AR) are needed at the front-side p-type emitter. It could also be valuable for front-side passivation and AR of rear-emitter and interdigitated back contact p-wafer cells. We achieve high minority carrier lifetimes {approx}1 ms, as well as a nearly 2% decrease in absolute reflectivity, as compared to a standard silicon nitride AR coating.

  3. NEW ACCURATE MEASUREMENT OF {sup 36}ArH{sup +} AND {sup 38}ArH{sup +} RO-VIBRATIONAL TRANSITIONS BY HIGH RESOLUTION IR ABSORPTION SPECTROSCOPY

    SciTech Connect

    Cueto, M.; Herrero, V. J.; Tanarro, I.; Doménech, J. L.; Cernicharo, J.; Barlow, M. J.; Swinyard, B. M.

    2014-03-01

    The protonated argon ion, {sup 36}ArH{sup +}, was recently identified in the Crab Nebula from Herschel spectra. Given the atmospheric opacity at the frequency of its J = 1-0 and J = 2-1 rotational transitions (617.5 and 1234.6 GHz, respectively), and the current lack of appropriate space observatories after the recent end of the Herschel mission, future studies on this molecule will rely on mid-infrared observations. We report on accurate wavenumber measurements of {sup 36}ArH{sup +} and {sup 38}ArH{sup +} rotation-vibration transitions in the v = 1-0 band in the range 4.1-3.7 μm (2450-2715 cm{sup –1}). The wavenumbers of the R(0) transitions of the v = 1-0 band are 2612.50135 ± 0.00033 and 2610.70177 ± 0.00042 cm{sup –1} (±3σ) for {sup 36}ArH{sup +} and {sup 38}ArH{sup +}, respectively. The calculated opacity for a gas thermalized at a temperature of 100 K and with a linewidth of 1 km s{sup –1} of the R(0) line is 1.6 × 10{sup –15} × N({sup 36}ArH{sup +}). For column densities of {sup 36}ArH{sup +} larger than 1 × 10{sup 13} cm{sup –2}, significant absorption by the R(0) line can be expected against bright mid-IR sources.

  4. Geochronology of the Porgera gold deposit, Papua New Guinea: Resolving the effects of excess argon on K-Ar and sup 40 Ar/ sup 39 Ar age estimates for magmatism and mineralization

    SciTech Connect

    Richards, J.P.; McDougall, I. )

    1990-05-01

    Mesothermal/epithermal gold mineralization at Porgera in the highlands of Papua New Guinea (PNG), occurs in structurally controlled veins and disseminations, which overprint and cross-cut a suite of shallow-level, comagmatic, mafic alkaline stocks and dykes and their sedimentary host rocks. Conventional K-Ar apparent ages of twelve hornblende separates from eight different intrusions scatter between 7 and 14 Ma, but four biotite separates are concordant at 6.02 {plus minus} 0.29 Ma (2{sigma}). {sup 40}Ar/{sup 39}Ar step-heating experiments on six of the hornblende separates reveal saddle-shaped age spectra, which indicate the presence of excess {sup 40}Ar. One of these samples yields a well-defined plateau with an apparent age of 5.96 {plus minus} 0.25 Ma (2{sigma}). Conventional K-Ar analyses of six separates of hydrothermal illite and roscoelite associated with gold mineralization yield apparent ages of between 5.1 and 6.1 Ma and indicate that ore deposition occurred within 1 Ma of magmatism at Porgera. Evidence for the evolution of a magmatic volatile phase, and the presence of excess {sup 40}Ar both in the intrusives and in hydrothermal fluids associated with the orebody, suggest that magmatic fluids may have had some involvement in metallogenesis, but the exact nature of this involvement is not yet clear. Late Miocene magmatism and mineralization at Porgera are thought to have occurred shortly prior to or during the initiation of continent/arc collision and to pre-date associated Pliocene uplift and foreland deformation in the highlands.

  5. New Rydberg-Rydberg transitions of the ArH and ArD molecules: Bands involving s, p and d electronic states

    SciTech Connect

    Darbrowski, I.; Tokaryk, D.; Watson, J.K.G.

    1995-12-31

    8The previous analyses of the spectra of ArH and ArD are extended to other transitions between s, p and d complexes, using a case (d) Hamiltonian in which the rotational and centrifugal energies are expressed in powers of R{sup 2}. While l is not a perfect quantum number, it provides convenient labels for the states. The present analysis of bands involving the lowest bound state (5s) is restricted to ArD because the corresponding state of ArH is strongly predissociated. The bands 5p {r_arrow} 5s and 6p {r_arrow} 5s have been observed, but analysis of the former is hampered by interference by D{sub 3} emission. These bands show that the small {sigma} - {pi} separation found in the 4p complex is accidental. For example, 6p{sigma} - 6p{pi} is 69.9 cm{sup -1} (from the R = 0 Hamiltonian), whereas the corresponding separation in 4p is 2.0 cm{sup -1}. Observation of the 3d{delta} {r_arrow} 4p band completes the 3d complex, whose wide splitting ({sigma}, {pi} and {delta} components at 16311, 13016, and 14637 m{sup -1} relative to 5s in ArD) corresponds to an almost pure fourth-rank tensor pattern. The bands 6s {r_arrow} 4p and 8s {r_arrow} 4p have also been analysed.

  6. GAS AND DUST ABSORPTION IN THE DoAr 24E SYSTEM

    SciTech Connect

    Kruger, Andrew J.; Richter, Matthew J.; Seifahrt, Andreas; Carr, John S.; Najita, Joan R.; Moerchen, Margaret M.; Doppmann, Greg W.

    2012-11-20

    We present findings for DoAr 24E, a binary system that includes a classical infrared companion. We observed the DoAr 24E system with the Spitzer Infrared Spectrograph (IRS), with high-resolution, near-infrared spectroscopy of CO vibrational transitions, and with mid-infrared imaging. The source of high extinction toward infrared companions has been an item of continuing interest. Here we investigate the disk structure of DoAr 24E using the column densities, temperature, and velocity profiles of two CO absorption features seen toward DoAr 24Eb. We model the spectral energy distributions found using T-ReCS imaging and investigate the likely sources of extinction toward DoAr 24Eb. We find the lack of silicate absorption and small CO column density toward DoAr 24Eb suggest that the mid-infrared continuum is not as extinguished as the near-infrared, possibly due to the mid-infrared originating from an extended region. This, along with the velocity profile of the CO absorption, suggests that the source of high extinction is likely due to a disk or disk wind associated with DoAr 24Eb.

  7. Nonadiabatic molecular collisions. II. A further trajectory-surface-hopping study of the ArH2(+) system

    SciTech Connect

    Chapman, S.

    1985-05-01

    The nonadiabatic molecular processes of charge exchange and chemical reaction in the species Ar(+) + H2, Ar + H2(+), and Ar + D2(+) are characterized theoretically in three-dimensional space using the trajectory-surface-hopping model of Tully and Preston (1971) and the diatomics-in-molecules hypersurfaces of Kuntz and Roach (1972). The results are presented in tables, graphs, and diagrams and shown to be in good general agreement with experimental data. Findings reported include the direct nature of the reactions, the stripping process involved in the reaction Ar(+) + H2 yields ArH(+) + H, the high rotational temperature of the product ArH(+), and the sensitive dependence of Ar + H2(+) and Ar + D2(+) cross sections on the vibrational state of the reactants. 38 references.

  8. Access to the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    are required to register with the ALS User Services Office and take safety training (see Complete Safety Training ) before they are issued a Berkeley Lab ID badge and granted...

  9. ALS Users' Association Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    facility. Thorough discussion with users of current projects, as well as plans for the future, will place ALS management in a better position to evaluate the needs of users and...

  10. ALS in the News

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    the ALS is well represented) New Lithium-Ion Battery Discovery Contradicts ... of water-no deeper than a few molecules-to the surface of a barium fluoride crystal. ...

  11. ALS Staff Photo

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    On May 14, 2013, members of ALS staff posed for a group photo in front of the dome. A hi-res version can be downloaded here. The last staff photo was taken in 2006. 2013 staff...

  12. ALS Users' Association Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    users and will enable users to plan more efficiently the utilization of the facility. The role of the ALSUA shall be to advise the ALS Director on matters of concern to users....

  13. ALS Communications Group

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    organize bi-monthly Science Cafs, create conference and workshop Web sites and publicity, and coordinate ALS participation in Lab-wide events such as the Berkeley Lab Open...

  14. ALS Staff Photo

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Print On May 14, 2013, members of ALS staff posed for a group photo in front of the dome. A hi-res version can be downloaded here. The last staff photo was taken in 2006. 2013...

  15. Anodic reactions in the Ca/CaCrO/sub 4/ thermal battery

    SciTech Connect

    Guidotti, R.A.; Reinhardt, F.W.

    1985-09-01

    The reaction of Ca with a CaCrO/sub 4/-(LiCl-KCl eutectic) solution at temperatures of 400/sup 0/C to 500/sup 0/C was studied to better understand the nature of the chemical reactions and electrochemical processes that occur in the Ca/CaCrO/sub 4/ thermal battery at the anode during activation and discharge. Limited tests also were conducted with a CaCrO/sub 4/-(CaCl/sub 2/-NaCl-KCl eutectic) solution at 550/sup 0/C. Ca/CaCrO/sub 4/ and CaLi/sub 2//CaCrO/sub 4/ single cells were tested to observe the relative performance differences of Ca and CaLi/sub 2/ anodes. The discharged cells were analyzed by optical microscopy, electron microprobe, Auger electron spectroscopy, and secondary-ion mass spectroscopy. These analytical data were used in conjunction with the results of chemical-reaction experiments to propose a discharge mechanism for the Ca/CaCrO/sub 4/ thermal battery, consistent with experimental observations.

  16. File:NREL-ar-80m.pdf | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    File Edit with form History File:NREL-ar-80m.pdf Jump to: navigation, search File File history File usage Arkansas Annual Average Wind Speed at 80 Meters Size of this preview: 463...

  17. A.R.S. 37-102: State Land Department - Powers and Duties ...

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 37-102: State Land Department - Powers and DutiesLegal Abstract This section...

  18. 49 A.R.S. 255 et seq.: Arizona Pollutant Discharge Elimination...

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 255 et seq.: Arizona Pollutant Discharge Elimination System ProgramLegal Abstract...

  19. 49 A.R.S. 321 et seq.: Water Quality Appeals | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 321 et seq.: Water Quality AppealsLegal Abstract This section governs appeals to the...

  20. ARS Title 49-200 Water Quality Control | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    -200 Water Quality Control Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS Title 49-200 Water Quality ControlLegal Abstract...

  1. Title 32 CFR 651 Environmental Analysis of Army Actions (AR 200...

    OpenEI (Open Energy Information) [EERE & EIA]

    of Army Actions (AR 200-2) Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 32 CFR 651...

  2. Ion chemistry in H{sub 2}-Ar low temperature plasmas

    SciTech Connect

    Sode, M.; Schwarz-Selinger, T.; Jacob, W.

    2013-08-14

    A rate equation model is devised to study the ion composition of inductively coupled H{sub 2}-Ar plasmas with different H{sub 2}-Ar mixing ratios. The model is applied to calculate the ion densities n{sub i}, the wall loss probability of atomic hydrogen β{sub H}, and the electron temperature T{sub e}. The calculated n{sub i}'s of Ar{sup +}, H{sup +}, H{sub 2}{sup +}, H{sub 3}{sup +}, and ArH{sup +} are compared with experimental results. Calculations were made for a total gas pressure of 1.0 Pa. The production and loss channels of all ions are presented and discussed in detail. With the production and loss rates, the density dependence of each ion on the plasma parameters is explained. It is shown that the primary ions H{sub 2}{sup +} and Ar{sup +} which are produced by ionization of the background gas by electron collisions are effectively converted into H{sub 3}{sup +} and ArH{sup +}. The high density of ArH{sup +} and Ar{sup +} is attributed to the low loss to the walls compared to hydrogen ions. It is shown that the H{sup +}/H{sub 2}{sup +} density ratio is strongly correlated to the H/H{sub 2} density ratio. The dissociation degree is around 1.7%. From matching the calculated to the measured atomic hydrogen density n{sub H}, the wall loss probability of atomic hydrogen on stainless steel β{sub H} was determined to be β{sub H}=0.24. The model results were compared with recently published experimental results. The calculated and experimentally obtained data are in fair agreement.

  3. OSTI Announces Alert Service for arXiv Patrons | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information March 2005 Oak Ridge, TN - The Office of Scientific and Technical Information (OSTI) is pleased to announce implementation of an Alert Service that serves patrons of arXiv, a source in the fields of physics, mathematics, non-linear science, computer science, and quantitative biology. ArXiv, a service of Cornell University Library System, is one of the sources included in OSTI's E-print Network. Through this Alert Service, patrons can subscribe

  4. Microsoft Word - Household Energy Use CA

    Energy Information Administration (EIA) (indexed site)

    0 20 40 60 80 100 US PAC CA Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US PAC CA Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 2,000 4,000 6,000 8,000 10,000 12,000 US PAC CA Site Consumption kilowatthours $0 $250 $500 $750 $1,000 $1,250 $1,500 US PAC CA Expenditures dollars ELECTRICITY ONLY average per household  California households use 62 million Btu of energy per home, 31% less than the U.S. average. The lower than average site

  5. Hanford Site's Data Packages in the Administrative Record (AR) and Public Information Repository (PIR)

    DOE Data Explorer

    In 1989, the Department of Energy joined with the Washington State Department of Ecology and the U.S. Environmental Protection Agency in signing the Hanford Federal Facility Agreement and Consent Order more commonly known as the Tri-Party Agreement (TPA). The TPA outlines legally enforceable milestones for Hanford cleanup over the next several decades. The AR is the body of documents and information that is considered or relied upon to arrive at a final decision for remedial action or hazardous waste management. An AR is established for each operable unit (OU); treatment, storage, or disposal unit (TSD); or Expedited Response Action (ERA) group and will contain all documents having information considered in arriving at a Record of Decision or permit. Documents become part of the AR after they have been designated as an AR by the TPA or after EPA, DOE, or other official parties have identified a document or set of documents for inclusion. Furthermore, AR documents are to be kept in a Public Information Repository (PIR).Thousands of data packages that support the AR documents are available to the public in the Hanford PIR.

  6. Theoretical potential curves for excited states of ArH and the rate of collisional quenching of metastable Ar by H

    SciTech Connect

    Vance, R.L.; Gallup, G.A.

    1980-07-15

    Energy curves for the ground state and the first seven excited states of ArH have been calculated using the multiconfiguration valence bond (MCVB) method. Important features of the excited curves include two distinct avoided crossings between the lowest Ar*H and the highest ArH* potential energy curves. Using these curves we have made a theoretical analysis of quenching of metastable Ar by collision with H at room temperature. Application of the Massey criterion indicates that the separation of the potential curves in the region of the crossing and the acceleration produced by the fall of the reactant channel potential curve from its asymptotic level combine to produce a relatively high probability for curve switching. A more quantitative estimate of the curve switching probability is given with the Landau--Zener formula and leads to a theoretical value of the quenching rate approximately ten times the experimental. In light of the many approximations involved this qualitative agreement is satisfactory and provides a rationale to explain the anomalously high rate constant for the quenching reaction. Structural features of the interacting potential curves are discussed in terms of the diabatic states involved.

  7. The novel HDAC inhibitor AR-42-induced anti-colon cancer cell activity is associated with ceramide production

    SciTech Connect

    Xu, Weihong; Xu, Bin; Yao, Yiting; Yu, Xiaoling; Shen, Jie

    2015-08-07

    In the current study, we investigated the potential activity of AR-42, a novel histone deacetylase (HDAC) inhibitor, against colon cancer cells. Our in vitro results showed that AR-42 induced ceramide production, exerted potent anti-proliferative and pro-apoptotic activities in established (SW-620 and HCT-116 lines) and primary human colon cancer cells. Exogenously-added sphingosine 1-phosphate (S1P) suppressed AR-42-induced activity, yet a cell-permeable ceramide (C4) facilitated AR-42-induced cytotoxicity against colon cancer cells. In addition, AR-42-induced ceramide production and anti-colon cancer cell activity were inhibited by the ceramide synthase inhibitor fumonisin B1, but were exacerbated by PDMP, which is a ceramide glucosylation inhibitor. In vivo, oral administration of a single dose of AR-42 dramatically inhibited SW-620 xenograft growth in severe combined immunodeficient (SCID) mice, without inducing overt toxicities. Together, these results show that AR-42 dramatically inhibits colon cancer cell proliferation in vitro and in vivo, and ceramide production might be the key mechanism responsible for its actions. - Highlights: • AR-42 is anti-proliferative against primary/established colon cancer cells. • AR-42 induces significant apoptotic death in primary/established colon cancer cells. • Ceramide production mediates AR-42-induced cytotoxicity in colon cancer cells. • AR-42 oral administration potently inhibits SW-620 xenograft growth in SCID mice.

  8. Data Management at the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Data Management at the ALS Print Users of the ALS are responsible for meeting their data management obligations to their home institutions and granting agencies. Except as noted ...

  9. AL PRO | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: AL-PRO Place: Grossheide, Lower Saxony, Germany Zip: 26532 Sector: Wind energy Product: AL-PRO is an inndependent expert office for wind forecasts, wind...

  10. AL2007-08.doc

    Energy.gov [DOE] (indexed site)

    Assessment Tool, IEEE Standard 1680-2006 for Environmental Assessment of Personal Computer Products. When is this Acquisition Letter (AL) Effective? This AL is effective...

  11. 2012 ALS User Meeting Awards

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2012 ALS User Meeting Awards Print Recipients of the 2012 Users' Executive Committee awards and Student Poster Competition were announced Tuesday, October 9, at the ALS User...

  12. 2012 ALS User Meeting Awards

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2 ALS User Meeting Awards Recipients of the 2012 Users' Executive Committee awards and Student Poster Competition were announced Tuesday, October 9, at the ALS User Meeting. David...

  13. Transparent conductive Al-doped ZnO thin films grown at room temperature

    SciTech Connect

    Wang Yuping; Lu Jianguo; Bie Xun; Gong Li; Li Xiang; Song Da; Zhao Xuyang; Ye Wenyi; Ye Zhizhen

    2011-05-15

    Aluminum-doped ZnO (ZnO:Al, AZO) thin films were prepared on glass substrates by dc reactive magnetron sputtering from a Zn-Al alloy target at room temperature. The effects of the Ar-to-O{sub 2} partial pressure ratios on the structural, electrical, and optical properties of AZO films were studied in detail. AZO films grown using 100:4 to 100:8 Ar-to-O{sub 2} ratio result in acceptable quality films with c-axis orientated crystals, uniform grains, 10{sup -3} {Omega} cm resistivity, greater than 10{sup 20} cm{sup -3} electron concentration, and high transmittance, 90%, in the visible region. The lowest resistivity of 4.11x10{sup -3} {Omega} cm was obtained under the Ar-to-O{sub 2} partial pressure ratio of 100:4. A relatively strong UV emission at {approx}3.26 eV was observed in the room-temperature photoluminescence spectrum. X-ray photoelectron spectroscopy analysis confirmed that Al was introduced into ZnO and substitutes for Zn and doped the film n-type.

  14. KCAT, Xradia, ALS and APS Performance Summary

    SciTech Connect

    Waters, A; Martz, H; Brown, W

    2004-09-30

    At Lawrence Livermore National Laboratory (LLNL) particular emphasis is being placed on the nondestructive characterization (NDC) of components, subassemblies and assemblies of millimeter-size extent with micrometer-size features (mesoscale). These mesoscale objects include materials that vary widely in composition, density, geometry and embedded features. Characterizing these mesoscale objects is critical for corroborating the physics codes that underlie LLNL's Stockpile Stewardship mission. In this report we present results from our efforts to quantitatively characterize the performance of several x-ray systems in an effort to benchmark existing systems and to determine which systems may have the best potential for our mesoscale imaging needs. Several different x-ray digital radiography (DR) and computed tomography (CT) systems exist that may be applicable to our mesoscale object characterization requirements, including microfocus and synchrotron systems. The systems we have benchmarked include KCAT (LLNL developed) and Xradia {mu}XCT (Xradia, Inc., Concord, CA), both microfocus systems, and Beamline 1-ID at the Advance Photon Source (APS) and the Tomography Beamline at the Advanced Light Source (ALS), both synchrotron based systems. The ALS Tomography Beamline is a new installation, and the data presented and analyzed here is some of the first to be acquired at the facility. It is important to note that the ALS system had not yet been optimized at the time we acquired data. Results for each of these systems has been independently documented elsewhere. In this report we summarize and compare the characterization results for these systems.

  15. Simulation of an Ar/NH{sub 3} low pressure magnetized direct current discharge

    SciTech Connect

    Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physiccal Science and Technical College, Dalian University, Dalian 116622 (China)

    2013-01-15

    A two-dimensional fluid model has been used to investigate the properties of plasma in an Ar/NH{sub 3} low pressure magnetized direct current discharge. We compared the simulation results with the theoretical and experimental results of the other gas discharge in which the magnetic field is considered. Results that obtained using this method are in good agreement with literature. The simulation results show that the positive ammonia ion density follows the positive argon ion density. The Ar{sub 2}{sup +} density is slightly higher than the Ar{sup +} density at 100 mTorr. The largest ammonia ion is NH{sub 3}{sup +} ion, followed by NH{sub 2}{sup +}, NH{sub 4}{sup +}, and NH{sup +} ions. The contribution of NH{sup +} ions to the density of the positive ammonia ions is marginal. The influence of pressure on the plasma discharge has been studied by simulation, and the mechanisms have been discussed. The average plasma density increases as pressure increased. The plasma density appears to be more inhomogeneous than that at the lower pressure. The ratio of charge particles changed as pressure increased. The Ar{sup +} density is slightly higher than the Ar{sub 2}{sup +} density as the pressure increased. It makes NH{sub 4}{sup +} ratio increase as pressure increased. It shows that the electron temperature drops with rising pressure by numerical calculation.

  16. ACS National Meeting (San Diego, CA) - JCAP

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ACS National Meeting (San Diego, CA) ACS National Meeting (San Diego, CA) Sun, Mar 13, 2016 7:00am 07:00 Thu, Mar 17, 2016 5:00pm 17:00 San Diego Convention Center 111 W Harbor Dr San Diego, CA 92101 Harry Atwater, "Artificial Photosynthesis: Progress, Science Prospects and Technology Outlook" Abstract: The design of highly efficient, non-biological energy conversion system that generate fuels directly from sunlight, water and carbon dioxide is both a formidable challenge and an

  17. Ion mass spectrometry investigations of the discharge during reactive high power pulsed and direct current magnetron sputtering of carbon in Ar and Ar/N{sub 2}

    SciTech Connect

    Schmidt, S.; Greczynski, G.; Jensen, J.; Hultman, L.; Czigany, Zs.

    2012-07-01

    Ion mass spectrometry was used to investigate discharges formed during high power impulse magnetron sputtering (HiPIMS) and direct current magnetron sputtering (DCMS) of a graphite target in Ar and Ar/N{sub 2} ambient. Ion energy distribution functions (IEDFs) were recorded in time-averaged and time-resolved mode for Ar{sup +}, C{sup +}, N{sub 2}{sup +}, N{sup +}, and C{sub x}N{sub y}{sup +} ions. An increase of N{sub 2} in the sputter gas (keeping the deposition pressure, pulse width, pulse frequency, and pulse energy constant) results for the HiPIMS discharge in a significant increase in C{sup +}, N{sup +}, and CN{sup +} ion energies. Ar{sup +}, N{sub 2}{sup +}, and C{sub 2}N{sup +} ion energies, in turn, did not considerably vary with the changes in working gas composition. The HiPIMS process showed higher ion energies and fluxes, particularly for C{sup +} ions, compared to DCMS. The time evolution of the plasma species was analyzed for HiPIMS and revealed the sequential arrival of working gas ions, ions ejected from the target, and later during the pulse-on time molecular ions, in particular CN{sup +} and C{sub 2}N{sup +}. The formation of fullerene-like structured CN{sub x} thin films for both modes of magnetron sputtering is explained by ion mass-spectrometry results and demonstrated by transmission electron microscopy as well as diffraction.

  18. Melt processing of the Bi[sub 2]Sr[sub 2]CaCu[sub 2]O[sub y] superconductor in oxygen and argon atmospheres

    SciTech Connect

    Holesinger, T.G.; Miller, D.J. ); Chumbley, L.S. )

    1992-08-01

    Solidification and subsequent annealing of Bi[sub 2]Sr[sub 2]CaCu[sub 2]O[sub y] (2212) in oxygen and argon atmospheres were investigated in order to identify alternative processing routes for controlling microstructures and superconducting properties. In addition to 2212, several other phases formed on cooling in O[sub 2] and did not disappear upon subsequent annealing. Crystallization in Ar resulted in a divorced eutetic structure of Bi[sub 2]Sr[sub 3-x]Ca[sub x]O[sub y] and Cu[sub 2]O/CuO. The superconductor was formed on subsequent anneals. Samples melted in Ar and then annealed generally possessed a more uniform microstructure compared with samples that were melted in oxygen and annealed. Compositional measurements of the 2212 phase suggest that CaO segregation in the melt may be minimized with an overall composition such as Bi[sub 2.15]Sr[sub 2]Ca[sub 0.85]Cu[sub 2]O[sub y].

  19. Melt processing of the Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y} superconductor in oxygen and argon atmospheres

    SciTech Connect

    Holesinger, T.G.; Miller, D.J.; Chumbley, L.S.

    1992-08-01

    Solidification and subsequent annealing of Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub y} (2212) in oxygen and argon atmospheres were investigated in order to identify alternative processing routes for controlling microstructures and superconducting properties. In addition to 2212, several other phases formed on cooling in O{sub 2} and did not disappear upon subsequent annealing. Crystallization in Ar resulted in a divorced eutetic structure of Bi{sub 2}Sr{sub 3-x}Ca{sub x}O{sub y} and Cu{sub 2}O/CuO. The superconductor was formed on subsequent anneals. Samples melted in Ar and then annealed generally possessed a more uniform microstructure compared with samples that were melted in oxygen and annealed. Compositional measurements of the 2212 phase suggest that CaO segregation in the melt may be minimized with an overall composition such as Bi{sub 2.15}Sr{sub 2}Ca{sub 0.85}Cu{sub 2}O{sub y}.

  20. Fluorocarbon assisted atomic layer etching of SiO2 and Si using cyclic Ar/C4F8 and Ar/CHF3 plasma

    DOE PAGES [OSTI]

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L.; Joseph, Eric A.; Oehrlein, Gottlieb S.

    2015-11-11

    The need for atomic layer etching (ALE) is steadily increasing as smaller critical dimensions and pitches are required in device patterning. A flux-control based cyclic Ar/C4F8 ALE based on steady-state Ar plasma in conjunction with periodic, precise C4F8 injection and synchronized plasma-based low energy Ar+ ion bombardment has been established for SiO2.1 In this work, the cyclic process is further characterized and extended to ALE of silicon under similar process conditions. The use of CHF3 as a precursor is examined and compared to C4F8. CHF3 is shown to enable selective SiO2/Si etching using a fluorocarbon (FC) film build up. Othermore »critical process parameters investigated are the FC film thickness deposited per cycle, the ion energy, and the etch step length. Etching behavior and mechanisms are studied using in situ real time ellipsometry and X-ray photoelectron spectroscopy. Silicon ALE shows less self-limitation than silicon oxide due to higher physical sputtering rates for the maximum ion energies used in this work, ranged from 20 to 30 eV. The surface chemistry is found to contain fluorinated silicon oxide during the etching of silicon. As a result, plasma parameters during ALE are studied using a Langmuir probe and establish the impact of precursor addition on plasma properties.« less

  1. Fluorocarbon assisted atomic layer etching of SiO2 and Si using cyclic Ar/C4F8 and Ar/CHF3 plasma

    DOE PAGES [OSTI]

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L.; Joseph, Eric A.; Oehrlein, Gottlieb S.

    2015-11-11

    The need for atomic layer etching (ALE) is steadily increasing as smaller critical dimensions and pitches are required in device patterning. A flux-control based cyclic Ar/C4F8 ALE based on steady-state Ar plasma in conjunction with periodic, precise C4F8 injection and synchronized plasma-based low energy Ar+ ion bombardment has been established for SiO2.1 In this work, the cyclic process is further characterized and extended to ALE of silicon under similar process conditions. The use of CHF3 as a precursor is examined and compared to C4F8. CHF3 is shown to enable selective SiO2/Si etching using a fluorocarbon (FC) film build up. Othermore » critical process parameters investigated are the FC film thickness deposited per cycle, the ion energy, and the etch step length. Etching behavior and mechanisms are studied using in situ real time ellipsometry and X-ray photoelectron spectroscopy. Silicon ALE shows less self-limitation than silicon oxide due to higher physical sputtering rates for the maximum ion energies used in this work, ranged from 20 to 30 eV. The surface chemistry is found to contain fluorinated silicon oxide during the etching of silicon. As a result, plasma parameters during ALE are studied using a Langmuir probe and establish the impact of precursor addition on plasma properties.« less

  2. HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF LANTHANUM IN Ar DISCHARGE IN THE NEAR-INFRARED

    SciTech Connect

    Güzelçimen, F.; Başar, Gö.; Tamanis, M.; Kruzins, A.; Ferber, R.; Windholz, L.; Kröger, S. E-mail: sophie.kroeger@htw-berlin.de

    2013-10-01

    A high-resolution spectrum of lanthanum has been recorded by a Fourier Transform spectrometer in the wavelength range from 833 nm to 1666 nm (6000 cm{sup –1} to 12,000 cm{sup –1}) using as light source a hollow cathode lamp operated with argon as the discharge carrier gas. In total, 2386 spectral lines were detected in this region, of which 555 lines could be classified as La I transitions and 10 lines as La II transitions. All La II transitions and 534 of these La I transitions were classified for the first time, and 6 of the La II transitions and 433 of the classified La I transitions appear to be new lines, which could not be found in the literature. The corresponding energy level data of classified lines are given. Additionally, 430 lines are assigned as Ar I lines and 394 as Ar II lines, of which 179 and 77, respectively, were classified for the first time. All 77 classified Ar II transitions as well as 159 of the classified Ar I transitions are new lines. Furthermore, the wavenumbers of 997 unclassified spectral lines were determined, 235 of which could be assigned as La lines, because of their hyperfine pattern. The remaining 762 lines may be either unclassified Ar lines or unresolved and unclassified La lines with only one symmetrical peak with an FWHM in the same order of magnitude as the Ar lines. The accuracy of the wavenumber for the classified lines with signal-to-noise-ratio higher than four is better than 0.006 cm{sup –1} which corresponds to an accuracy of 0.0004 nm at 830 nm and 0.0017 nm at 1660 nm, respectively.

  3. Materials Data on Ca4Al6WO16 (SG:217) by Materials Project

    SciTech Connect

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in...

    Office of Scientific and Technical Information (OSTI)

    Chimica Fisica, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy). E-mail: cfmet@chimica.unige.it Dipartimento di Chimica e Chim. Ind., Sezione di Chimica Fisica, ...

  5. Materials Data on CaScAlSiO6 (SG:14) by Materials Project

    SciTech Connect

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on Ca3Al7Ag2 (SG:166) by Materials Project

    DOE Data Explorer

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Modeling of inductively coupled plasma SF{sub 6}/O{sub 2}/Ar plasma discharge: Effect of O{sub 2} on the plasma kinetic properties

    SciTech Connect

    Pateau, Amand; Rhallabi, Ahmed Fernandez, Marie-Claude; Boufnichel, Mohamed; Roqueta, Fabrice

    2014-03-15

    A global model has been developed for low-pressure, inductively coupled plasma (ICP) SF{sub 6}/O{sub 2}/Ar mixtures. This model is based on a set of mass balance equations for all the considered species, coupled with the discharge power balance equation and the charge neutrality condition. The present study is an extension of the kinetic global model previously developed for SF{sub 6}/Ar ICP plasma discharges [Lallement et al., Plasma Sources Sci. Technol. 18, 025001 (2009)]. It is focused on the study of the impact of the O{sub 2} addition to the SF{sub 6}/Ar gas mixture on the plasma kinetic properties. The simulation results show that the electron density increases with the %O{sub 2}, which is due to the decrease of the plasma electronegativity, while the electron temperature is almost constant in our pressure range. The density evolutions of atomic fluorine and oxygen versus %O{sub 2} have been analyzed. Those atomic radicals play an important role in the silicon etching process. The atomic fluorine density increases from 0 up to 40% O{sub 2} where it reaches a maximum. This is due to the enhancement of the SF{sub 6} dissociation processes and the production of fluorine through the reactions between SF{sub x} and O. This trend is experimentally confirmed. On the other hand, the simulation results show that O(3p) is the preponderant atomic oxygen. Its density increases with %O{sub 2} until reaching a maximum at almost 40% O{sub 2}. Over this value, its diminution with O{sub 2}% can be justified by the high increase in the loss frequency of O(3p) by electronic impact in comparison to its production frequency by electronic impact with O{sub 2}.

  8. Microsoft Word - Household Energy Use CA

    Gasoline and Diesel Fuel Update

    ... None Yes Yes No No 0% 20% 40% 60% 80% 100% US CA No Car CAR IS PARKED WITHIN 20 FT OF ELECTRICAL OUTLET More highlights from RECS on housing characteristics and energy-related ...

  9. XeCl Avalanche discharge laser employing Ar as a diluent

    DOEpatents

    Sze, Robert C.

    1981-01-01

    A XeCl avalanche discharge exciplex laser which uses a gaseous lasing starting mixture of: (0.2%-0.4% chlorine donor/2.5%-10% Xe/97.3%-89.6% Ar). The chlorine donor normally comprises HCl but can also comprise CCl.sub.4 BCl.sub.3. Use of Ar as a diluent gas reduces operating pressures over other rare gas halide lasers to near atmospheric pressure, increases output lasing power of the XeCl avalanche discharge laser by 30% to exceed KrF avalanche discharge lasing outputs, and is less expensive to operate.

  10. XeCl avalanche discharge laser employing Ar as a diluent

    DOEpatents

    Sze, R.C.

    1979-10-10

    A XeCl avalanche discharge exciplex laser which uses a gaseous lasing starting mixture of: 0.2 to 0.4% chlorine donor/2.5% to 10% Xe/97.3% to 89.6% Ar) is provided. The chlorine donor normally comprises HCl but can also comprise CCl/sub 4/ BCl/sub 3/. Use of Ar as a diluent gas reduces operating pressures over other rare gas halide lasers to near atmospheric pressure, increases output lasing power of the XeCl avalanche discharge laser by 30% to exceed KrF avalanche discharge lasing outputs, and is less expensive to operate.

  11. Radioactive air emissions notice of construction, use of a portable exhauster on 244-AR vault

    SciTech Connect

    Allen, C.P., Fluor Daniel Hanford

    1997-02-11

    This document serves as a notice of construction (NOC), pursuant to the requirements of Washington Administrative Code (WAC) 246-247- 060, and as a request for approval to construct pursuant to 40 Code of Federal Regulations (CFR) 61.96, for the use of a portable exhauster at the 244-AR Vault during transfers or movement of radioactive waste as part of pumping of secondary containment, tank stabilization/pumping, and other activities (i.e., transfer or pumping of radioactive waste using established procedures, entries for maintenance and inspections) within the 244-AR Vault.

  12. Process for producing Ti-Cr-Al-O thin film resistors

    DOEpatents

    Jankowski, Alan F.; Schmid, Anthony P.

    2001-01-01

    Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  13. Flat panel display using Ti-Cr-Al-O thin film

    DOEpatents

    Jankowski, Alan F.; Schmid, Anthony P.

    2002-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  14. Nonadiabatic molecular collisions. II. A further trajectory-surface-hopping study of the ArH/sup +//sub 2/ system

    SciTech Connect

    Chapman, S.

    1985-05-01

    Both charge transfer and chemical reaction are studied for the reactants Ar/sup +/+H/sub 2/, Ar+H/sup +//sub 2/, and Ar+D/sup +//sub 2/, using the trajectory-surface-hopping model with diatomics-in-molecules /sup 2/A' surfaces for ArH/sup +//sub 2/. Results are compared with a number of recent experiments. Agreement with experiment is generally satisfactory. The reactions are direct. The Ar/sup +/+H/sub 2/ ..-->.. ArH/sup +/+H reaction is well characterized as a stripping process. Charge transfer occurs predominantly by long-range electron jump. The Ar+H/sup +//sub 2/ and Ar+D/sup +//sub 2/ cross sections depend sensitively on reactant vibration, rising sharply from v = 0 to v = 1, and falling gradually for v> or =2. The ArH/sup +/ product is rotationally hot. Points of disagreement with experiment are discussed in the light of the approximations in the surface and the TSH model.

  15. DOE - Office of Legacy Management -- Arthur D Little Co - CA...

    Office of Legacy Management (LM)

    Designated Name: Not Designated Alternate Name: Merrill Company CA.01-1 Location: San Francisco , California CA.01-2 Evaluation Year: 1986 CA.01-1 Site Operations: Performed ...

  16. Emission Regulations Reduced Impact of Climate Change in CA

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Emission Regulations Reduced Impact of Climate Change in CA Emission Regulations Reduced Impact of Climate Change in CA Study shows clean diesel programs slashed black carbon, a ...

  17. EA-1798: Abengoa Solar's Mojave Solar Project near Barstow, CA...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8: Abengoa Solar's Mojave Solar Project near Barstow, CA EA-1798: Abengoa Solar's Mojave Solar Project near Barstow, CA July 1, 2011 EA-1798: Final Environmental Assessment Loan ...

  18. California Climate Exchange CaCX | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    CaCX Jump to: navigation, search Name: California Climate Exchange (CaCX) Place: California Product: Aims to reducte CO2 emission in California. References: California Climate...

  19. DOE - Office of Legacy Management -- Electro Circuits Inc - CA...

    Office of Legacy Management (LM)

    Designated Name: Not Designated Alternate Name: None Location: 401 East Green Street , Pasadena , California CA.08-1 Evaluation Year: 1994 CA.08-2 Site Operations: Conducted ...

  20. San Diego, CA Liquefied Natural Gas Exports to Mexico (Dollars...

    Energy Information Administration (EIA) (indexed site)

    San Diego, CA Liquefied Natural Gas Exports to Mexico (Dollars per Thousand Cubic Feet) San Diego, CA Liquefied Natural Gas Exports to Mexico (Dollars per Thousand Cubic Feet) ...

  1. CALiPER Application Summary Report 17. LED AR111 and PAR36 Lamps

    SciTech Connect

    none,

    2012-08-01

    Report 17 analyzes the performance of a group of six LED products labeled as AR111 lamps. Results indicate that this product category lags behind other types of directional LED lamps but may perform acceptably in some applications and provide some energy savings.

  2. Heavy ion beam induced charge transfer in Ar-Cs mixtures

    SciTech Connect

    Murnick, D.E.; Gernhauser, R.; Ulrich, A.; Krotz, W.; Wieser, J.

    1993-12-01

    In situ production of target ions in cold, dense matter by heavy ion collisions and subsequent selective charge transfer may provide an effective pumping scheme for heavy ion beam pumped lasers. Charge transfer from cesium atoms to doubly charged argon ions was used for selective population of 4d-levels in Ar II. The argon ions were produced in an argon-cesium gas target by a pulsed beam of 100 MeV {sup 32}S{sup 8+} ions from the Munich Tandem van de Graaff accelerator. The ion beam of 12 {times} 10{sup 6} ions/pulse had a pulse width of 2 ns and a repetition rate of 32 kHz. The argon pressure was typically 250 mbar. The cesium partial pressure was adjusted by heating the gas target, including a cesium reservoir, to temperatures between 250 and 500{degrees}C. Time resolved wavelength spectra showed large intensity increases corresponding to 4d {sup 4}D and 4d {sup 4}F to 4p transitions in Ar II in the ultraviolet wavelength region between 300 and 400 nm. This is interpreted as a resonant charge transfer of outer electrons of cesium to 4d levels in Ar II in Cs{sup 0} + Ar{sup 2+} collisions.

  3. Properties of steady discharge in Ar-Kr-F2 gas mixture

    SciTech Connect

    Chengen, Z.

    1981-11-01

    Some properties of Ar-Kr-F/sub 2/ laser gas mixture plasma under steady discharge conditions are computed and discussed. Both the excitation rate of the discharging electrons and the distribution of the discharge energy are discussed. The effects of fluoride gas content and impurity gas content on the discharge property are studied.

  4. Hypothetical AlF{sub 3} crystal structures

    SciTech Connect

    Le Bail, Armel . E-mail: alb@cristal.org; Calvayrac, Florent . E-mail: Florent.Calvayrac@univ-lemans.fr

    2006-10-15

    Applying a structure prediction computer programme (GRINSP=Geometrically Restrained INorganic Structure Prediction), the occurrence of 6-connected 3D networks was investigated, through AlF{sub 6} octahedra exclusive corner sharing. The five known AlF{sub 3} varieties were reproduced ({alpha}-, {beta}-, {eta}-, {kappa}- and {tau}-AlF{sub 3}) and seven hypothetical models were predicted. Among these still to be synthesized AlF{sub 3} phases, one can recognize two known structure t (TlCa{sub 2}Ta{sub 5}O{sub 15}, Ba{sub 4}CoTa{sub 10}O{sub 30}) and some easy to imagine intergrowths; however, a few others are completely unexpected, though simple. A comparison of the ab initio total energies of all the structures is provided, leading to the conclusion that the virtual models could well be viable. - Graphical abstract: Hypothetical AlF{sub 3} structure with a dense packing of corner-sharing AlF{sub 6} octahedra packed in tetrahedral blocks.

  5. Charge states of Ca atoms in {beta}-dicalcium silicate

    SciTech Connect

    Mori, Kazuhiro . E-mail: kmori@rri.kyoto-u.ac.jp; Kiyanagi, Ryoji; Yonemura, Masao; Iwase, Kenji; Sato, Takashi; Itoh, Keiji; Sugiyama, Masaaki; Kamiyama, Takashi; Fukunaga, Toshiharu

    2006-11-15

    In order to study the crystal structure of {beta}-bar Ca{sub 2}SiO{sub 4}, time-of-flight neutron powder diffraction experiments were carried out at temperatures between room temperature (RT) and 600 deg. C. Rietveld refinement at RT has shown that {beta}-bar Ca{sub 2}SiO{sub 4} is monoclinic based on P2{sub 1}/n symmetry and two different types of Ca sites, Ca(1) and Ca(2). All interatomic distances within 3A were calculated, with the valences of Ca(1) with seven Ca-O bonds and Ca(2) with eight were estimated to be 1.87+ and 2+ by the Zachariasen-Brown-Altermatt formula (bond valence sum). Applying charge neutrality the two charge states of Ca in {beta}-bar Ca{sub 2}SiO{sub 4} are [Ca(1)SiO{sub 4}]{sup 2-} and Ca(2){sup 2+}, respectively. Furthermore, the [Ca(1)SiO{sub 4}]{sup 2-} unit has the shortest Ca-O distance, and its length kept constant at 2.23A at all temperatures. In the short-range structure analysis at RT, the shortest Ca-O bond was also observed in a radial distribution function. These results imply that the [Ca(1)SiO{sub 4}]{sup 2-} unit has covalency on the shortest Ca-O in addition to Si-O.

  6. Characterization of cathodic corrosion products in the Ca/CaCrO/sub 4/ thermal battery

    SciTech Connect

    Guidotti, R.A.; Reinhardt, F.W.; Venturini, E.L.; Rogers, J.W. Jr.; Cathey, W.N.

    1985-05-01

    Using thermal analysis techniques, we investigated the corrosion process resulting from the reaction of iron, nickel, and stainless steel (used as current collectors in Ca/CaCrO/sub 4/ thermal batteries) with CaCrO/sub 4/ dissolved in LiCl-KCl eutectic. The reaction product for iron was synthesized in bulk external to the battery and was characterized by chemical analysis, X-ray diffraction, Moessbauer spectroscopy, X-ray photoelectron spectroscopy, static magnetization, and electrical conductivity. This characterization provides a better understanding of the cathodic corrosion processes that occur in the Ca/CaCrO/sub 4/ thermal battery, and how the properties of the reaction layer at the catholyte-current collector interface influence battery performance.

  7. Materials compatibility during the chlorination of molten CaCl/sub 2/. CaO salts. [CaCl/sub 2/. CaO salt

    SciTech Connect

    Rense, C.E.C.; Fife, K.W.; Bowersox, D.F.; Ferran, M.D.

    1987-01-01

    As part of our effort to develop a semicontinuous PuO/sub 2/ reduction process, we are investigating promising materials for containing a 900/sup 0/C molten CaCl/sub 2/ . CaO chlorination reaction. We want the material to contain this reaction and to be reusable. We tested candidate materials in a simulated salt (no plutonium) using anhydrous HCl as the chlorinating agent. Data are presented on the performance of 36 metals and alloys, 9 ceramics, and 3 coatings.

  8. DOE CYBER SECURITY EBK: CORE COMPETENCY TRAINING REQUIREMENTS: CA

    Energy.gov [DOE]

    DOE CYBER SECURITY EBK: CORE COMPETENCY TRAINING REQUIREMENTS. Key Cyber Security Role: Certification Agent (CA)

  9. Chemical stability and Ce doping of LiMgAlF6 neutron scintillator

    DOE PAGES [OSTI]

    Du, M. H.

    2014-11-13

    We perform density functional calculations to investigate LiMgAlF6 as a potential neutron scintillator material. The calculations of enthalpy of formation and phase diagram show that single-phase LiMgAlF6 can be grown but it should be more difficult than growing LiCaAlF6 and LiSrAlF6. Moreover, the formation energy calculations for substitutional Ce show that the concentration of Ce on the Al site is negligible but a high concentration (>1 at.%) of Ce on the Mg site is attainable provided that the Fermi level is more than 5 eV lower than the conduction band minimum. Acceptor doping should promote Ce incorporation in LiMgAlF6.

  10. Chemical stability and Ce doping of LiMgAlF6 neutron scintillator

    SciTech Connect

    Du, M. H.

    2014-11-13

    We perform density functional calculations to investigate LiMgAlF6 as a potential neutron scintillator material. The calculations of enthalpy of formation and phase diagram show that single-phase LiMgAlF6 can be grown but it should be more difficult than growing LiCaAlF6 and LiSrAlF6. Moreover, the formation energy calculations for substitutional Ce show that the concentration of Ce on the Al site is negligible but a high concentration (>1 at.%) of Ce on the Mg site is attainable provided that the Fermi level is more than 5 eV lower than the conduction band minimum. Acceptor doping should promote Ce incorporation in LiMgAlF6.

  11. AmeriFlux US-AR2 ARM USDA UNL OSU Woodward Switchgrass 2

    DOE Data Explorer

    Billesbach, Dave [University of Nebraska; Bradford, James [U.S. Department of Agriculture

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-AR2 ARM USDA UNL OSU Woodward Switchgrass 2. Site Description - The ARM USDA UNL OSU Woodward Switchgrass 2 tower is located on public land owned by the USDA-ARS Southern Plains Range Research Station in Woodward, Oklahoma. The site is on a former wheat field that is in the process of changing to switchgrass. A companion site (ARM USDA UNL OSU Woodward Switchgrass 1) is on a former native prairie. Previous wheat was planted in Fall 2008. In Spring 2009, herbicide was applied to kill the wheat prior to switchgrass planting. Later in the year, the site was sprayed with post-emergence herbicide. In 2010, fertilization occurred before herbicide was sprayed for broadleaf control.

  12. AmeriFlux US-AR1 ARM USDA UNL OSU Woodward Switchgrass 1

    SciTech Connect

    Billesbach, Dave; Bradford, James

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-AR1 ARM USDA UNL OSU Woodward Switchgrass 1. Site Description - The ARM USDA UNL OSU Woodward Switchgrass 1 tower is located on public land owned by the USDA-ARS Southern Plains Range Research Station in Woodward, Oklahoma. The site is on a former native prairie that is in the process of changing to switchgrass. A second companion site (ARM USDA UNL OSU Woodward Switchgrass 2) is on a former wheat field. In Spring 2009, the former native prairie site was burned, cattle were put on the pasture to graze down emergent grass, and broadleaf herbicide was sprayed. In Summer 2009, the cattle were removed from the pasture, and the site was sprayed with herbicide to kill all grass. In Spring 2010, prior to the planting of switchgrass, final herbicide was sprayed to kill cheat grass and to control broadleaf plants.

  13. ALS Evidence Confirms Combustion Theory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

  14. ALS Collaborative Postdoctoral Fellowship Program

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    the National Center of Electron Microscopy, and the National Energy Research Scientific Computing Center. ALS Collaborative Postdoctoral Fellowships normally provide only partial...

  15. ALS Collaborative Postdoctoral Fellowship Program

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    who will collaborate closely with ALS staff and users in new and emerging scientific and engineering research fields. The program will provide advanced training for careers paths...

  16. AL2007-05.doc

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL 2007-05 Acquisition Regulation Date 03292007 ACQUISITION LETTER This Acquisition ... LETTERS REMAINING IN EFFECT NUMBER DATE SUBJECT 93-4 040793 Displaced Workers ...

  17. ALS Collaborative Postdoctoral Fellowship Program

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    scientists) to discuss possible projects and to identify external sources of matching funds. Applicants must then submit a completed ALS Collaborative Postdoctoral...

  18. ALS Scientific Advisory Committee Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    It acts as a "board of directors" to advise the Laboratory on current and future ALS operations, allocation of facility resources, strategic planning, budget development, and...

  19. Investigation of plasma-dust structures in He-Ar gas mixture

    SciTech Connect

    Maiorov, S. A.; Ramazanov, T. S.; Dzhumagulova, K. N.; Jumabekov, A. N.; Dosbolayev, M. K.

    2008-09-15

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for a He-Ar mixture. It is shown that the choice of light and heavy gases for the mixture suppresses ion heating in electric field under the conventional conditions of experiments and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths, and gas pressures.

  20. Material-dependent amorphization and epitaxial crystallization in ion-implanted AlAs/GaAs layer structures

    SciTech Connect

    Cullis, A.G.; Chew, N.G.; Whitehouse, C.R. ); Jacobson, D.C.; Poate, J.M.; Pearton, S.J.

    1989-09-18

    When AlAs/GaAs layer samples are subjected to Ar{sup +} ion bombardment at liquid-nitrogen temperature, it is shown that very different damage structures are produced in the two materials. While the GaAs is relatively easily amorphized, the AlAs is quite resistant to damage accumulation and remains crystalline for the ion doses employed in these investigations. Epitaxial regrowth of buried amorphous GaAs layers of thicknesses up to 150 nm can be induced by rapid thermal annealing. It is demonstrated that differences in the initial damage state have a strong influence upon the nature of lattice defects produced by annealing.

  1. Isotopic Constraints on the Chemical Evolution of Geothermal Fluids, Long Valley, CA

    SciTech Connect

    Brown, Shaun; Kennedy, Burton; DePaolo, Donald; Evans, William

    2008-08-01

    A spatial survey of the chemical and isotopic composition of fluids from the Long Valley hydrothermal system was conducted. Starting at the presumed hydrothermal upwelling zone in the west moat of the caldera, samples were collected from the Casa Diablo geothermal field and a series of monitoring wells defining a nearly linear, ~;;14 km long, west-to-east trend along the proposed fluid flow path (Sorey et al., 1991). Samples were analyzed for the isotopes of water, Sr, Ca, and noble gases, the concentrations of major cations and anions and total CO2. Our data confirm earlier models in which the variations in water isotopes along the flow path reflect mixing of a single hydrothermal fluid with local groundwater. Variations in Sr data are poorly constrained and reflect fluid mixing, multiple fluid-pathways or water-rock exchange along the flow path as suggested by Goff et al. (1991). Correlated variations among total CO2, noble gases and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO2, noble gases) driving calcite precipitation as the fluid flows west-to-east across the caldera. This is the first evidence that Ca isotopes may trace and provide definitive evidence of calcite precipitation along fluid flow paths in geothermal systems.

  2. Microsoft Word - Cd-CA.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The First Cadmium Enzyme - Carbonic Anhydrase 2 from the marine diatom Thalassiosira weissflogii Todd W. Lane 1 , Mak A. Saito 2 , Graham N. George 3 , Ingrid J. Pickering 3 , Roger C. Prince 4 and François M.M. Morel 5 1 Biosystems Research Department, Sandia National Labs, Livermore, CA 2 Marine Chemistry and Geochemistry Department, Woods Hole Oceanographic Institution, Woods Hole, MA 3 Department of Geological Sciences, University of Saskatchewan, Saskatoon, Canada 4 ExxonMobil Research

  3. A.R.S. 37-461: Grants of Rights-of-Way and Site for Public...

    OpenEI (Open Energy Information) [EERE & EIA]

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 37-461: Grants of Rights-of-Way and Site for Public UsesLegal Abstract This...

  4. Synthesis of c-axis oriented AlN thin films on different substrates: A review

    SciTech Connect

    Iriarte, G.F.

    2010-09-15

    Highly c-axis oriented AlN thin films have been deposited by reactive sputtering on different substrates. The crystallographic properties of layered film structures consisting of a piezoelectric layer, aluminum nitride (AlN), synthesized on a variety of substrates, have been examined. Aluminum nitride thin films have been deposited by reactive pulsed-DC magnetron sputtering using an aluminum target in an Ar/N{sub 2} gas mixture. The influence of the most critical deposition parameters on the AlN thin film crystallography has been investigated by means of X-ray diffraction (XRD) analysis of the rocking curve Full-Width at Half Maximum (FWHM) of the AlN-(0 0 0 2) peak. The relationship between the substrate, the synthesis parameters and the crystallographic orientation of the AlN thin films is discussed. A guide is provided showing how to optimize these conditions to obtain highly c-axis oriented AlN thin films on substrates of different nature.

  5. EIS-0439: Rice Solar Energy Project in Riverside County, CA ...

    Energy Saver

    9: Rice Solar Energy Project in Riverside County, CA EIS-0439: Rice Solar Energy Project in Riverside County, CA March 29, 2010 EIS-0439: Notice of Intent to Prepare an ...

  6. EIS-0455: Genesis Solar Energy Project in Riverside County, CA...

    Office of Environmental Management (EM)

    5: Genesis Solar Energy Project in Riverside County, CA EIS-0455: Genesis Solar Energy Project in Riverside County, CA December 17, 2010 EIS-0455: Notice of Adoption of an ...

  7. Metropolitan Water District of S CA | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Metropolitan Water District of S CA Jump to: navigation, search Name: Metropolitan Water District of S CA Place: California Phone Number: (213) 217-6000 Website: www.mwdh2o.com...

  8. File:Ca1.pdf | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Ca1.pdf Jump to: navigation, search File File history File usage Metadata File:Ca1.pdf Size of this preview: 463 599 pixels. Other resolution: 464 600 pixels. Go to page 1 2...

  9. Capacity Needs Diagnostics for Renewable Energies (CaDRE) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    here: Handbook Toolbox Four Levels of CaDRE CaDRE is based on the idea that a governing body can successfully develop in the renewable energy sector when the following...

  10. Effects of porosity on leaching of Ca from hardened ordinary...

    Office of Scientific and Technical Information (OSTI)

    Effects of porosity on leaching of Ca from hardened ordinary Portland cement paste Citation Details In-Document Search Title: Effects of porosity on leaching of Ca from hardened ...

  11. Current Collector Corrosion in Ca-Ion Batteries - Joint Center...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    May 23, 2015, Research Highlights Current Collector Corrosion in Ca-Ion Batteries C45 ... Ca-ion batteries, but it should not be a roadblock to practical implementation. ...

  12. Distinctive plume formation in atmospheric Ar and He plasmas in microwave frequency band and suitability for biomedical applications

    SciTech Connect

    Lee, H. Wk.; Kang, S. K.; Won, I. H.; Kim, H. Y.; Kwon, H. C.; Sim, J. Y.; Lee, J. K.

    2013-12-15

    Distinctive discharge formation in atmospheric Ar and He plasmas was observed in the microwave frequency band using coaxial transmission line resonators. Ar plasmas formed a plasma plume whereas He formed only confined plasmas. As the frequency increased from 0.9 GHz to 2.45 GHz, the Ar plasma exhibited contraction and filamentation, and the He plasmas were constricted. Various powers and gas flow rates were applied to identify the effect of the electric field and gas flow rate on plasma plume formation. The He plasmas were more strongly affected by the electric field than the Ar plasmas. The breakdown and sustain powers yielded opposite results from those for low-frequency plasmas (?kHz). The phenomena could be explained by a change in the dominant ionization process with increasing frequency. Penning ionization and the contribution of secondary electrons in sheath region reduced as the frequency increased, leading to less efficient ionization of He because its ionization and excitation energies are higher than those of Ar. The emission spectra showed an increase in the NO and N{sub 2} second positive band in both the Ar and He plasmas with increasing frequency whereas the hydroxyl radical and atomic O peaks did not increase with increasing frequency but were highest at particular frequencies. Further, the frequency effect of properties such as the plasma impedance, electron density, and device efficiency were presented. The study is expected to be helpful for determining the optimal conditions of plasma systems for biomedical applications.

  13. Financial Statement: IG-FS-CA-06-04

    Energy.gov [DOE]

    Review of Actions to Correct Financial Control and Reporting Weaknesses; Audit Report No: OAS-FS/CA-06-04

  14. West Flank Coso, CA FORGE Seismic Reflection

    DOE Data Explorer

    Doug Blankenship

    2016-05-16

    PDFs of seismic reflection profiles 101,110, 111 local to the West Flank FORGE site. 45 line kilometers of seismic reflection data are processed data collected in 2001 through the use of vibroseis trucks. The initial analysis and interpretation of these data was performed by Unruh et al. (2001). Optim processed these data by inverting the P-wave first arrivals to create a 2-D velocity structure. Kirchhoff images were then created for each line using velocity tomograms (Unruh et al., 2001).

  15. ALS 20th Anniversary Celebration

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The 20th anniversary of the ALS was celebrated on Friday, October 4, with style, good humor, lots of stories, and a very large cake. More important, however, was the large number...

  16. Scott Taylor, ALS Safety Manager

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    for safety inspections. There weren't division safety coordinators back in those days, Taylor explains. Joining the ALS reminds Taylor of his early days at the Lab, when he felt...

  17. ALS Scientific Advisory Committee Charter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The SAC will meet as often as necessary but no less than twice a year. The deliberations of the SAC will be confidential to the extent legally possible. The ALS Director andor ...

  18. ALS Doctoral Fellowship in Residence

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    and technological research. As the world's first third-generation synchrotron radiation source, the ALS offers outstanding performance in the VUV-soft x-ray energy range and...

  19. ALS 20th Anniversary Celebration

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    20th Anniversary Celebration Print The 20th anniversary of the ALS was celebrated on Friday, October 4, with style, good humor, lots of stories, and a very large cake. More...

  20. STM Images of Atomic-Scale Carbon Nanotube Defects Produced by Ar+ Irradiation

    SciTech Connect

    Osvath, Z.; Vertesy, G.; Tapaszto, L.; Weber, F.; Horvath, Z.E.; Gyulai, J.; Biro, L.P.

    2005-09-27

    Multi-wall carbon nanotubes (MWCNTs) dispersed on graphite (HOPG) substrate were irradiated with Ar+ ions of 30 keV, using a low-dose of D 5x1011 ions/cm2. The irradiated samples were investigated by scanning tunneling microscopy (STM) under ambient conditions. Atomic resolution STM images reveal individual nanotube defects, which appear as hillocks of 1-2 angstroms in height, due to the locally changed electronic structure. After annealing at 450 deg. C in nitrogen atmosphere, the irradiated MWCNTs were investigated again by STM. The effect of the heat treatment on the irradiation-induced nanotube defects is also discussed.

  1. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  2. Ionization of large homogeneous and heterogeneous clusters generated in acetylene-Ar expansions: Cluster ion polymerization

    SciTech Connect

    Kocisek, J.; Lengyel, J.; Farnik, M.

    2013-03-28

    Pure acetylene and mixed Ar-acetylene clusters are formed in supersonic expansions of acetylene/argon mixtures and analysed using reflectron time-of-flight mass spectrometer with variable electron energy ionization source. Acetylene clusters composed of more than a hundred acetylene molecules are generated at the acetylene concentration of Almost-Equal-To 8%, while mixed species are produced at low concentrations ( Almost-Equal-To 0.7%). The electron energy dependence of the mass spectra revealed the ionization process mechanisms in clusters. The ionization above the threshold for acetylene molecule of 11.5 eV results in the main ionic fragment progression (C{sub 2}H{sub 2}){sub n}{sup +}. At the electron energies Greater-Than-Or-Slanted-Equal-To 21.5 eV above the CH+CH{sup +} dissociative ionization limit of acetylene the fragment ions nominally labelled as (C{sub 2}H{sub 2}){sub n}CH{sup +}, n Greater-Than-Or-Slanted-Equal-To 2, are observed. For n Less-Than-Or-Slanted-Equal-To 7 these fragments correspond to covalently bound ionic structures as suggested by the observed strong dehydrogenation [(C{sub 2}H{sub 2}){sub n}-k Multiplication-Sign H]{sup +} and [(C{sub 2}H{sub 2}){sub n}CH -k Multiplication-Sign H]{sup +}. The dehydrogenation is significantly reduced in the mixed clusters where evaporation of Ar instead of hydrogen can stabilize the nascent molecular ion. The C{sub 3}H{sub 3}{sup +} ion was previously assigned to originate from the benzene molecular ion; however, the low appearance energy of Almost-Equal-To 13.7 eV indicates that a less rigid covalently bound structure of C{sub 6}H{sub 6}{sup +} ion must also be formed upon the acetylene cluster electron ionization. The appearance energy of Ar{sub n}(C{sub 2}H{sub 2}){sup +} fragments above Almost-Equal-To 15.1 eV indicates that the argon ionization is the first step in the fragment ion production, and the appearance energy of Ar{sub n{>=}2}(C{sub 2}H{sub 2}){sub m{>=}2}{sup +} at Almost-Equal-To 13

  3. Dust Successive Generations in Ar/SiH{sub 4} : Dust Cloud Dynamics

    SciTech Connect

    Cavarroc, M.; Mikikian, M.; Tessier, Y.; Boufendi, L.

    2008-09-07

    Silane-based plasmas are widely used to deposit nanostructured silicon thin films or to synthesize silicon nanoparticles. Dust particle formation in Ar/SiH{sub 4} plasmas is a continuous phenomenon: as long as silane precursors are provided, new dust generations are formed. Successive generations can be monitored thanks to various electrical (V{sub dc}/3H) and optical (OES, video imaging) diagnostics. Experiments presented in this paper have been performed in a capacitively-coupled radiofrequency discharge, at low pressure (12 Pa) in an Argon/Silane mixture (92:8)

  4. Structure and Magnetic Properties of Ce3(Ni/Al/Ga)11„A New Phase with the La3Al11 Structure Type

    Office of Scientific and Technical Information (OSTI)

    Crystals 2015, 5, 1-8; doi:10.3390/cryst5010001 crystals ISSN 2073-4352 www.mdpi.com/journal/crystals Article Structure and Magnetic Properties of Ce 3 (Ni/Al/Ga) 11 -A New Phase with the La 3 Al 11 Structure Type Oliver Janka 1,2,†, *, Tian Shang 3,4,† , Ryan E. Baumbach 3,5,† , Eric D. Bauer 3,† , Joe D. Thompson 3,† and Susan M. Kauzlarich 1,†, * 1 Department of Chemistry, University of California, Davis, CA 95616, USA 2 Institut für Anorganische und Analytische Chemie,

  5. Fusion of {sup 48}Ca+{sup 48}Ca Far Below the Barrier

    SciTech Connect

    Scarlassara, F.; Montagnoli, G.; Mason, P.; Stefanini, A. M.; Silvestri, R.; Corradi, L.; Fioretto, E.; Guiot, B.; Courtin, S.; Haas, F.; Lebhertz, D.; Szilner, S.

    2009-08-26

    In recent years, a puzzling pattern has been observed in fusion cross sections well below the Coulomb barrier, characterized as a departure from the exponential-like behavior predicted by standard coupled-channels models, known as fusion hindrance. We report on recent fusion measurements performed at the Laboratori Nazionali di Legnaro, in particular the {sup 48}Ca+{sup 48}Ca reaction down to the level of 0.6 {mu}b. Unlike most recent results in this field, we do not observe the typical divergent behavior of the logarithmic derivative; but rather a sort of saturation, albeit at a larger value than predicted with a standard nucleus-nucleus potential.

  6. Quantitative determination of mass-resolved ion densities in H{sub 2}-Ar inductively coupled radio frequency plasmas

    SciTech Connect

    Sode, M.; Schwarz-Selinger, T.; Jacob, W.

    2013-03-07

    Inductively coupled H{sub 2}-Ar plasmas are characterized by an energy-dispersive mass spectrometer (plasma monitor), a retarding field analyzer, optical emission spectroscopy, and a Langmuir probe. A procedure is presented that allows determining quantitatively the absolute ion densities of Ar{sup +}, H{sup +}, H{sub 2}{sup +}, H{sub 3}{sup +}, and ArH{sup +} from the plasma monitor raw signals. The calibration procedure considers the energy and mass-dependent transmission of the plasma monitor. It is shown that an additional diagnostic like a Langmuir probe or a retarding field analyzer is necessary to derive absolute fluxes with the plasma monitor. The conversion from fluxes into densities is based on a sheath and density profile model. Measurements were conducted for a total gas pressure of 1.0 Pa. For pure H{sub 2} plasmas, the dominant ion is H{sub 3}{sup +}. For mixed H{sub 2}-Ar plasmas, the ArH{sup +} molecular ion is the most dominant ion species in a wide parameter range. The electron density, n{sub e}, is around 3 Multiplication-Sign 10{sup 16} m{sup -3} and the electron temperature, T{sub e}, decreases from 5 to 3 eV with increasing Ar content. The dissociation degree was measured by actinometry. It is around 1.7% nearly independent on Ar content. The gas temperature, estimated by the rotational distribution of the Q-branch lines of the H{sub 2} Fulcher-{alpha} diagonal band (v Prime =v Double-Prime =2) is estimated to (540 {+-} 50) K.

  7. Mode transition in CF{sub 4} + Ar inductively coupled plasma

    SciTech Connect

    Liu, Wei; Gao, Fei; Zhao, Shu-Xia; Li, Xue-Chun; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-12-15

    The E to H mode transitions are studied by a hairpin probe and optical emission spectroscopy in inductively coupled CF{sub 4} + Ar plasmas. Electron density, optical emission intensity of Ar, and the voltage and current are measured during the E to H mode transitions. It is found that the electron density and plasma emission intensity increase continuously at low pressure during the E to H mode transition, while they jump up discontinuously at high pressure. Meanwhile, the transition threshold power and ?P (the power interval between E and H mode) increase by increasing the pressure. When the ratio of CF{sub 4} increases, the E to H mode transition happens at higher applied power, and meanwhile, the ?P also significantly increases. Besides, the effects of CF{sub 4} gas ratio on the plasma properties and the circuit electrical properties in both pure E and H modes were also investigated. The electron density and plasma emission intensity both decrease upon increasing the ratio of CF{sub 4} at the two modes, due to the stronger electrons loss scheme. The applied voltages at E and H modes both increase as increasing the CF{sub 4} gas ratio, however the applied current at two modes behave just oppositely with the gas ratio.

  8. Effects of Ar plasma treatment for deposition of ruthenium film by remote plasma atomic layer deposition

    SciTech Connect

    Park, Taeyong; Lee, Jaesang; Park, Jingyu; Jeon, Heeyoung; Jeon, Hyeongtag; Lee, Ki-Hoon; Cho, Byung-Chul; Kim, Moo-Sung; Ahn, Heui-Bok

    2012-01-15

    Ruthenium thin films were deposited on argon plasma-treated SiO{sub 2} and untreated SiO{sub 2} substrates by remote plasma atomic layer deposition using bis(ethylcyclopentadienyl)ruthenium [Ru(EtCp){sub 2}] as a Ru precursor and ammonia plasma as a reactant. The results of in situ Auger electron spectroscopy (AES) analysis indicate that the initial transient region of Ru deposition was decreased by Ar plasma treatment at 400 deg. C, but did not change significantly at 300 deg. C The deposition rate exhibited linearity after continuous film formation and the deposition rates were about 1.7 A/cycle and 0.4 A/cycle at 400 deg. C and 300 deg. C, respectively. Changes of surface energy and polar and dispersive components were measured by the sessile drop test. The quantity of surface amine groups was measured from the surface nitrogen concentration with AES. Furthermore, the Ar plasma-treated SiO{sub 2} contained more amine groups and less hydroxyl groups on the surface than on untreated SiO{sub 2}. Auger spectra exhibited chemical shifts by Ru-O bonding, and larger shifts were observed on untreated substrates due to the strong adhesion of Ru films.

  9. Near- and sub-barrier fusion of {sup 6}He+{sup 40}Ar

    SciTech Connect

    Hinnefeld, J.D.; Kolata, J.J.; Belbot, M.; Lamkin, K.; Zahar, M.; Santi, P.; Kugi, J.

    1993-10-01

    A measurement of the fusion cross section for {sup 6}He + {sup 40}Ar near and below the Coulomb barrier has been performed using a {sup 6}He beam from the UND/Um radioactive beam facility. The {sup 6}He nucleus is thought to have a neutron skin surrounding a {sup 6}He core. If this is the case, then Coulomb polarization of the core relative to the halo might result in neutron flow along a neck, and therefore to a large enhancement of the sub-barrier fusion cross section. {sup 6}He nuclei, of incident energy 10.05 {+-} 0.44 MeV, were directed into a segmented ionization counter (MUSIC) filled with P10 at 40 torr. The {sup 40}Ar in the detector gas served also as the target nuclei. {sup 6}He energies in the 50-cm active length of the detector varied from 7.75 MeV down to 3.05 MeV. Calculations indicate that fusion events should be distinguishable from most non-fusion events on the basis of energy deposition patterns in the ten MUSIC detector segments. For some large-angle scattering events a more elaborate analysis involving detailed Monte Carlo simulation of the various reactions is necessary.

  10. Ablation and cone formation mechanism on CR-39 by ArF laser irradiation

    SciTech Connect

    Shakeri Jooybari, B. E-mail: hafarideh@aut.ac.ir; Afarideh, H. E-mail: hafarideh@aut.ac.ir; Lamehi-Rachti, M.; Ghergherehchi, M.

    2015-03-07

    In this work, chemical properties, surface modification, and micro structures formation on ablated polyallyl di-glycol carbonate (CR-39) polymer by ArF laser irradiation (λ = 193 nm) at various fluences and pulse number were investigated. CR-39 samples have been irradiated with an ArF laser (193 nm) at a repetition rate of 1 Hz. Threshold fluence of ablation and effective absorption coefficient of CR-39 were determined. Conical microstructures (Taylor cone) formed on laser-ablated CR-39 exhibit: smooth, Taylor cone shape walls and sharp tips together with interference and well defined fringe-structure with a period of 230 nm, around cone base. Mechanism of cone formation and cone evolution of CR-39 ablated surface were investigated by change of fluences (at a given pulse number) and pulse number (at a given fluence). Cone height, cone base, and region of interface were increased in micrometer steps by increasing the total fluence. Depression on the base of the cone and the circular fringe were simulated. FTIR spectra were measured and energy dispersive x-ray analysis of irradiated and un-irradiated samples was performed.

  11. Numerical analysis of a mixture of Ar/NH{sub 3} microwave plasma chemical vapor deposition reactor

    SciTech Connect

    Li Zhi [School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); Zhao Zhen [Chemistry Department, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Physical Science and Technical College, Dalian University, Dalian 116622 (China)

    2012-06-01

    A two-dimensional fluid model has been used to investigate the properties of plasma in Ar/NH{sub 3} microwave electron cyclotron resonance discharge at low pressure. The electromagnetic field model solved by the three-dimensional Simpson method is coupled to a fluid plasma model. The finite difference method was employed to discrete the governing equations. 40 species (neutrals, radicals, ions, and electrons) are consisted in the model. In total, 75 electron-neutral, 43 electron-ion, 167 neutral-neutral, 129 ion-neutral, 28 ion-ion, and 90 3-body reactions are used in the model. According to the simulation, the distribution of the densities of the considered plasma species has been showed and the mechanisms of their variations have been discussed. It is found that the main neutrals (Ar*, Ar**, NH{sub 3}{sup *}, NH, H{sub 2}, NH{sub 2}, H, and N{sub 2}) are present at high densities in Ar/NH{sub 3} microwave electron cyclotron resonance discharge when the mixing ratio of Ar/NH{sub 3} is 1:1 at 20 Pa. The density of NH is more than that of NH{sub 2} atom. And NH{sub 3}{sup +} are the most important ammonia ions. But the uniformity of the space distribution of NH{sub 3}{sup +} is lower than the other ammonia ions.

  12. Mapping the Ionization State of Laser-Irradiated Ar Gas Jets With Multi-Wavelength Monochromatic X-Ray Imaging

    SciTech Connect

    Kugland, N L; Doppner, T; Kemp, A; Schaeffer, D; Glenzer, S H; Niemann, C

    2010-04-08

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultra-high intensity (10{sup 19} W/cm{sup 2}, 200 fs) Ti:Sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {micro}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {micro}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry, which images in one dimension, indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {micro}m along the laser axis.

  13. Mapping the ionization state of laser-irradiated Ar gas jets with multiwavelength monochromatic x-ray imaging

    SciTech Connect

    Kugland, N. L.; Niemann, C.; Doeppner, T.; Kemp, A.; Glenzer, S. H.; Schaeffer, D.

    2010-10-15

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx_equal}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultrahigh intensity (10{sup 19} W/cm{sup 2}, 50 TW) Ti:sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {mu}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {mu}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {mu}m along the laser axis.

  14. Microsoft Word - AL2006-11.doc

    Energy.gov [DOE] (indexed site)

    Guide Chapter 7.1, Acquisition Planning Acquisition Guide Chapter 42.5, Contract Management Planning When is this Acquisition Letter (AL) Effective? This AL is effective...

  15. ALS Ceramics Materials Research Advances Engine Performance

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics...

  16. ALS@20 Kick-Off Celebration

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    tribulations encountered during the construction of the ALS from former Director Jay Marx, current ALS Scientific Director Steve Kevan and Director Roger Falcone talked about...

  17. Site-related near-infrared luminescence in MAl{sub 12}O{sub 19} (M = Ca, Sr, Ba):Fe{sup 3+} phosphors

    SciTech Connect

    Li, Y.J.; Ma, Y.Y.; Ye, S.; Hu, G.P.; Zhang, Q.Y.

    2014-03-01

    Graphical abstract: - Highlights: • Intense 700–850 nm NIR emissions in MAl{sub 12}O{sub 19} (M = Ca, Sr, Ba):1%Fe{sup 3+} has been obtained. • The NIR emissions can be ascribed to the octahedral Fe{sup 3+} sites. • The site symmetry of Fe{sup 3+} in CA{sub 6} and SA{sub 6} may be lower than that in BA{sub 6}. • The phosphors may be potentially applied in the high-resolution bioimaging. - Abstract: Intense and broad near-infrared (NIR) photoluminescence (PL) peaks locating at 777, 808 and 810 nm is observed for BaAl{sub 12}O{sub 19} (BA{sub 6}):1%Fe{sup 3+}, CaAl{sub 12}O{sub 19} (CA{sub 6}):1%Fe{sup 3+} and SrAl{sub 12}O{sub 19} (SA{sub 6}):1%Fe{sup 3+}, respectively. Electron paramagnetic resonance (EPR) spectra show that Fe{sup 3+} ions substitute for the different types of Al{sup 3+} sites simultaneously. Meanwhile, the luminescence of Fe{sup 3+} in MAl{sub 12}O{sub 19} (M = Ca, Sr and Ba) are ascribed to octahedral Fe{sup 3+}. In addition, the site symmetry of Fe{sup 3+} in CA{sub 6}/SA{sub 6} is lower compared with BA{sub 6}, deduced from the photoluminescence excitation (PLE), EPR and Fourier-transform infrared (FT-IR) spectra. These phosphors can be considered as good candidates for the applications in the field of high-resolution bioimaging.

  18. NRELs e-Ca Test

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    NREL's e ---Ca T est Energy Innova5on Portal Webinar Arrelaine A . Dameron March 2 7, 2 012 2 Characteriza5on o f W ater P ermea5on B arriers Barrier Ambient E nvironment Sensi*ve C omponents Vapor a dsorbs a nd dissolves i nto barrier Vapor d iffuses Vapor d esorbs/ outgasses * Barrier m anufacturers need a c haracteriza5on method t hat i s: - Reproducible - Highly s ensi*ve - Easy t o u se - Scalable 3 1 F ood P ackaging 0.1 L CDs 0.01 T FTs 10 ---3 C dTe / Thin F ilm 10 ---4 C IGS 10 ---5 10

  19. Ab initio energies and tunneling lifetimes of the doubly charged AH{sup 2+} (A = Mg-Ar) diatomics

    SciTech Connect

    Nefedova, V.V.; Boldyrev, A.I.; Simons, J.

    1995-09-15

    Potential energy curves for the ground and low-lying excited states of the AH{sup 2+} (A = Mg-Ar) dications have been calculated using high-level ab initio methods with large atomic orbital basis sets. Quasi-bound potential energy curves with local minima and deprotonation barriers have been found for most of the dications studied. The energies, tunneling lifetimes, and widths of the quasi-bound states have been calculated by numerical solution of the radial Schroedinger equation using the Numeov method. All these dications except ArH{sup 2+} have low-lying states which support quasi-bound vibrational states. The ArH{sup 2+} dication has a {sup 2}{Pi}{sub i} potential energy curve with a minimum so shallow that it does not support any quasi-bound vibrational states. Results of our calculations are compared with previous ab initio calculations and available experimental data. 24 refs., 8 figs., 12 tabs.

  20. INTERPRETING ERUPTIVE BEHAVIOR IN NOAA AR 11158 VIA THE REGION'S MAGNETIC ENERGY AND RELATIVE-HELICITY BUDGETS

    SciTech Connect

    Tziotziou, Kostas; Georgoulis, Manolis K.; Liu Yang

    2013-08-01

    In previous works, we introduced a nonlinear force-free method that self-consistently calculates the instantaneous budgets of free magnetic energy and relative magnetic helicity in solar active regions (ARs). Calculation is expedient and practical, using only a single vector magnetogram per computation. We apply this method to a time series of 600 high-cadence vector magnetograms of the eruptive NOAA AR 11158 acquired by the Helioseismic and Magnetic Imager on board the Solar Dynamics Observatory over a five-day observing interval. Besides testing our method extensively, we use it to interpret the dynamical evolution in the AR, including eruptions. We find that the AR builds large budgets of both free magnetic energy and relative magnetic helicity, sufficient to power many more eruptions than the ones it gave within the interval of interest. For each of these major eruptions, we find eruption-related decreases and subsequent free-energy and helicity budgets that are consistent with the observed eruption (flare and coronal mass ejection (CME)) sizes. In addition, we find that (1) evolution in the AR is consistent with the recently proposed (free) energy-(relative) helicity diagram of solar ARs, (2) eruption-related decreases occur before the flare and the projected CME-launch times, suggesting that CME progenitors precede flares, and (3) self terms of free energy and relative helicity most likely originate from respective mutual terms, following a progressive mutual-to-self conversion pattern that most likely stems from magnetic reconnection. This results in the non-ideal formation of increasingly helical pre-eruption structures and instigates further research on the triggering of solar eruptions with magnetic helicity firmly placed in the eruption cadre.

  1. Effective defect diffusion lengths in Ar-ion bombarded 3C-SiC

    DOE PAGES [OSTI]

    Bayu Aji, L. B.; Wallace, J. B.; Shao, L.; Kucheyev, S. O.

    2016-04-14

    Above room temperature, SiC exhibits pronounced processes of diffusion and interaction of radiation-generated point defects. Here, we use the recently developed pulsed ion beam method to measure effective defect diffusion lengths in 3C-SiC bombarded in the temperature range of 25–200 °C with 500 keV Ar ions. Results reveal a diffusion length of ~10 nm, which exhibits a weak temperature dependence, changing from 9 to 13 nm with increasing temperature. Lastly, these results have important implications for understanding and predicting radiation damage in SiC and for the development of radiation-resistant materials via interface-mediated defect reactions.

  2. Ionization of He, Ne, Ar, Kr, and Xe by impact of He{sup +} ions

    SciTech Connect

    Miraglia, J. E.; Gravielle, M. S.

    2010-04-15

    In this article we report ionization cross sections of neutral He, Ne, Ar, Kr, and Xe by impact of He{sup +} ions with energies ranging from 25 to 1000 keV/amu. A general theory to deal with dressed projectiles is developed in the context of the Continuum-Distorted-Wave Eikonal-Initial-State approximation. The strategy is based on the use of an effective charge defined in terms of the momentum transfer extracted from the first Born approximation and extensively used in the local plasma approximation to deal with ions in solids. The difference between the actual potential of the projectile and the Coulombic effective one used in the distorted wave functions is treated in first perturbative order. Our results show that the proposed approach gives a very good account of available experiments.

  3. Etching mechanism of niobium in coaxial Ar/Cl2 radio frequency plasma

    SciTech Connect

    Upadhyay, Janardan; Im, Do; Popovic, Svetozar; Valente-Feliciano, Anne -Marie; Phillips, H. Larry; Vuskovic, Leposova

    2015-03-18

    The understanding of the Ar/Cl2 plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl2 concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. Furthermore, to understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate.

  4. In-Beam Gamma-ray Spectroscopy in the sdpf {sup 37}Ar Nucleus

    SciTech Connect

    Silveira, M. A. G.; Medina, N. H.; Seale, W. A.; Ribas, R. V.; Oliveira, J. R. B. de; Zilio, S.; Lenzi, S. M.; Napoli, D. R.; Marginean, N.; Vedova, F. Della; Farnea, E.; Ionescu-Bujor, M.; Iordachescu, A.

    2007-10-26

    The nucleus {sup 37}Ar has been studied with {gamma}-ray spectroscopy in the {sup 24}Mg({sup 16}O,2pn) reaction at a beam energy of 70 MeV. Twenty two new excited states up to an excitation energy of 13 MeV have been observed. We compare the first negative and positive parity yrast states with large-scale-shell-model calculations using the Antoine code and the SDPF interaction, considering the excitation of the 1d{sub 5/2},2s{sub 1/2} and 1d{sub 3/2} nucleons to 1f{sub 7/2} and 2p{sub 3/2} in the sdpf valence space.

  5. AR-CITE: Analysis of Search Results for the Clarification and Identification of Technology Emergence

    Energy Science and Technology Software Center

    2012-06-15

    The Analysis of Search Results for the Clarification and Identification of Technology Emergence (AR-CITE) computer code examines a scientometric model that tracks the emergence of an identified technology from initial discovery (via original scientific and conference literature), through critical discoveries (via original scientific, conference literature and patents), transitioning through Technology Readiness Levels (TRLs) and ultimately on to commercial currency of citations, collaboration indicators, and on-line news patterns are identified. The combinations of four distinct andmore » separate searchable on-line networked sources (i.e. scholarly publications and citation, world patents, news archives, and on-line mapping networks) are assembled to become one collective network (a dataset for analysis of relations). This established network becomes the basis from which to quickly analyze the temporal flow of activity (searchable events) for the subject domain to be clarified and identified.« less

  6. Oestrogen directly inhibits the cardiovascular L-type Ca{sup 2+} channel Ca{sub v}1.2

    SciTech Connect

    Ullrich, Nina D. . E-mail: ullrich@pyl.unibe.ch; Koschak, Alexandra; MacLeod, Kenneth T.

    2007-09-21

    Oestrogen can modify the contractile function of vascular smooth muscle and cardiomyocytes. The negative inotropic actions of oestrogen on the heart and coronary vasculature appear to be mediated by L-type Ca{sup 2+} channel (Ca{sub v}1.2) inhibition, but the underlying mechanisms remain elusive. We tested the hypothesis that oestrogen directly inhibits the cardiovascular L-type Ca{sup 2+} current, I {sub CaL}. The effect of oestrogen on I {sub CaL} was measured in Ca{sub v}1.2-transfected HEK-293 cells using the whole-cell patch-clamp technique. The current revealed typical activation and inactivation profiles of nifedipine- and cadmium-sensitive I {sub CaL}. Oestrogen (50 {mu}M) rapidly reduced I {sub CaL} by 50% and shifted voltage-dependent activation and availability to more negative potentials. Furthermore, oestrogen blocked the Ca{sup 2+} channel in a rate-dependent way, exhibiting higher efficiency of block at higher stimulation frequencies. Our data suggest that oestrogen inhibits I {sub CaL} through direct interaction of the steroid with the channel protein.

  7. Development and quality assessments of commercial heat production of ATF FeCrAl tubes

    SciTech Connect

    Yamamoto, Yukinori

    2015-09-01

    Development and quality assessment of the 2nd generation ATF FeCrAl tube production with commercial manufacturers were conducted. The manufacturing partners include Sophisticated Alloys, Inc. (SAI), Butler, PA for FeCrAl alloy casting via vacuum induction melting, Oak Ridge National Laboratory (ORNL) for extrusion process to prepare the master bars/tubes to be tube-drawn, and Rhenium Alloys, Inc. (RAI), North Ridgeville, OH, for tube-drawing process. The masters bars have also been provided to Los Alamos National Laboratory (LANL) who works with Century Tubes, Inc., (CTI), San Diego, CA, as parallel tube production effort under the current program.

  8. MAGNETIC ENERGY PARTITION BETWEEN THE CORONAL MASS EJECTION AND FLARE FROM AR 11283

    SciTech Connect

    Feng, L.; Li, Y. P.; Gan, W. Q.; Wiegelmann, T.; Inhester, B.; Su, Y.; Sun, X. D.

    2013-03-01

    On 2011 September 6, an X-class flare and a halo coronal mass ejection (CME) were observed from Earth erupting from the same active region AR 11283. The magnetic energy partition between them has been investigated. SDO/HMI vector magnetograms were used to obtain the coronal magnetic field using the nonlinear force-free field (NLFFF) extrapolation method. The free magnetic energies before and after the flare were calculated to estimate the released energy available to power the flare and the CME. For the flare energetics, thermal and nonthermal energies were derived using the RHESSI and GOES data. To obtain the radiative output, SDO/EVE data in the 0.1-37 nm waveband were utilized. We have reconstructed the three-dimensional (3D) periphery of the CME from the coronagraph images observed by STEREO-A, B, and SOHO. The mass calculations were then based on a more precise Thomson-scattering geometry. The subsequent estimate of the kinetic and potential energies of the CME took advantage of the more accurate mass, and the height and speed in a 3D frame. The released free magnetic energy resulting from the NLFFF model is about 6.4 Multiplication-Sign 10{sup 31} erg, which has a possible upper limit of 1.8 Multiplication-Sign 10{sup 32} erg. The thermal and nonthermal energies are lower than the radiative output of 2.2 Multiplication-Sign 10{sup 31} erg from SDO/EVE for this event. The total radiation covering the whole solar spectrum is probably a few times larger. The sum of the kinetic and potential energy of the CME could go up to 6.5 Multiplication-Sign 10{sup 31} erg. Therefore, the free energy is able to power the flare and the CME in AR 11283. Within the uncertainty, the flare and the CME may consume a similar amount of free energy.

  9. A=17Al (1993TI07)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Al (1993TI07) (Not observed) See (1983ANZQ, 1988WA18, 1992AV03).

  10. Machine Safeguarding (AL-131) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Machine Safeguarding (AL-131) Event Type: Training Date: 11/17/2016 - 15

  11. Andre Al Haddad | Argonne National Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Andre Al Haddad Visiting Scholar Telephone (630) 252-5913 E-mail aalhaddad

  12. RAPID/Roadmap/4-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us State Exploration Process (4-CA-a) 04CAAExploration.pdf...

  13. File:INL-geothermal-ca.pdf | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ca.pdf Jump to: navigation, search File File history File usage California Geothermal Resources Size of this preview: 439 599 pixels. Other resolution: 439 600 pixels. Full...

  14. RAPID/Roadmap/19-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Water Access and Water Rights (19-CA-a) California has a hybrid water law system, containing...

  15. RAPID/Roadmap/15-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Air Quality Permit - Authority to Construct (15-CA-a) A developer seeking to construct,...

  16. RAPID/Roadmap/15-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Air Quality Permit - Operating Permit (15-CA-b) A developer operating a facility that...

  17. California Fuel Cell Partnership CaFCP | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    fuel cell vehicles under real driving conditions and to assist in the development of a hydrogen infrastructure. References: California Fuel Cell Partnership (CaFCP)1 This...

  18. RAPID/Roadmap/7-CA-f | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap7-CA-f < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  19. RAPID/Roadmap/18-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap18-CA-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  20. RAPID/Roadmap/6-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    CA-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  1. RAPID/Roadmap/13-CA-c | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap13-CA-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  2. RAPID/Roadmap/14-CA-d | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap14-CA-d < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  3. RAPID/Roadmap/13-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Help Apps Datasets Community Login | Sign Up Search Page Edit with form History RAPIDRoadmap13-CA-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and...

  4. RAPID/Roadmap/3-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap3-CA-b < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  5. RAPID/Roadmap/6-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    CA-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  6. RAPID/Roadmap/8-CA-c | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    CA-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools...

  7. RAPID/Roadmap/11-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPIDRoadmap11-CA-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  8. 06-14-2010 CA-B-10-0081

    National Nuclear Security Administration (NNSA)

    CA-B-10-0081 Sandia National LaboratoriesCalifornia proposes to continue development and ... Site Office Neutron Scatter Camera Measurements Sandia National Laboratories - California

  9. RAPID/Roadmap/9-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us State Environmental Review Process (9-CA-a) The...

  10. RAPID/Roadmap/14-CA-c | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Geothermal Hydropower Solar Tools Contribute Contact Us Underground Injection Control Permit (14-CA-c) The injection of spent (cooled) geothermal fluids and in some cases...

  11. RAPID/Roadmap/14-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Contact Us Nonpoint Source Pollution (14-CA-a) The California State Water Resources Control Board (SWRCB) and the California Coastal Commission (CCC), in coordination with the...

  12. RAPID/Roadmap/12-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us California Fish and Game Process (12-CA-a) California protects certain species and habitat beyond the...

  13. RAPID/Roadmap/1-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Land Use Planning (1-CA-a) Land...

  14. Corrosion resistance of weldable Fe-Al alloys in reducing environments

    SciTech Connect

    Banovic, S.W.; DuPont, J.N.; Marder, A.R.

    1999-11-01

    Low aluminum Fe-Al alloys are being investigated for use as protective coatings in reducing environments. Intermetallic compositions have already demonstrated excellent high temperature corrosion resistance in both oxidation and sulfidation environments, however, they are limited in use due to low room temperature ductility and poor weldability arising from hydrogen embrittlement. Using Gas Tungsten Arc and Gas Metal Arc Welding process without the use of pre-heat and post weld heat treatments, a weldability regime below approximately 10 wt% Al in the overlay has been found. The high temperature sulfidation behavior of alloys located near this crack/no crack boundary (5 to 12.5 wt% Al) was examined using a thermogravimetric balance in a reducing gas mixture of O.l% H{sub 2}-1.0% H{sub 2}S-balance Ar gas at 700 C. Light optical microscopy, scanning electron microscopy, and energy dispersive spectroscopy were used to analyze the surface and cross-sectional morphologies. It was seen that the Fe-Al alloys exhibited lower weight gains than bare water wall tubes (carbon steel) and 309 stainless steel. Aluminum additions to the iron were found to extrinsically affect the iron sulfide reaction product morphology. Low carbon steel, with no aluminum, formed a continuous, and somewhat dense, iron sulfide scale that provided some protection. Small additions of aluminum (5--7.5 wt% Al) resulted in the growth of iron sulfide as nodules or a porous surface scale. Larger additions (above 10 wt%) were found to limit the growth of iron sulfide and significantly reduce corrosion rates. These results indicate that Fe-Al claddings containing 5 to 10 wt% Al show potential promise for applications requiring a combination of weldability and sulfidation resistance in moderately reducing environments.

  15. Microsoft Word - AL2008-05.doc

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy No. AL 2008-05 Acquisition Regulation Date 04/03/2008 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject: Environmental, Energy, and Transportation Management References: Executive Order 13423, dated January 24, 2007 Implementing Instructions, dated March 28, 2007 When is this Acquisition Letter (AL) effective? This AL is effective upon issuance. When does this AL Expire? This AL remains in effect

  16. Multiple ionization of Ar by F{sup -} impact: Projectile-electron-loss and direct-ionization collision channels

    SciTech Connect

    Sant'Anna, M. M.; Zappa, F.; Santos, A. C. F.; Coelho, L. F. S.; Wolff, W.; Barros, A. L. F. de; Castro Faria, N. V. de

    2006-08-15

    We have measured single- and multiple-target ionization cross sections for the F{sup -}+Ar collision system. Measurements of the final target and projectile charge states were performed in coincidence, separating the collision channels for single-, double-, and triple-projectile-electron loss and for direct ionization. The studied velocity region extends from v=0.46 to v=1.45 atomic units. Results are compared with existing H{sup -}+Ar data as well as with Ar multiple ionization by protons, electrons, and antiprotons. For the direct-ionization channel, ratios for multiple-to-single target ionization are similar to those found for H{sup +}+Ar collisions. For this channel multiple ionization is well described by independent single-ionization events by a frozen projectile. For the projectile-electron-loss collision channels, on the other hand, the correlation between projectile electrons and target electrons plays an important role. Our data show that the average final charge state of the target, , increases steeply with the final charge state of the projectile, while an independent-particle model (neglecting two-center electron-electron correlation) only accounts for small variations of .

  17. Synthesis of AlN/Al Polycrystals along with Al Nanoparticles Using Thermal Plasma Route

    SciTech Connect

    Kanhe, Nilesh S.; Nawale, A. B.; Kulkarni, N. V.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2011-07-15

    This paper for the first time reports the (200) oriented growth of hexagonal Aluminum nitride crystals during synthesis of aluminum nanoparticles in dc transferred arc thermal plasma reactor by gas phase condensation in nitrogen plasma. The structural and morphological study of as synthesized AlN crystal and aluminium nanoparticles was done by using the x-ray diffraction method, scanning electron microscopy and transmission electron microscopy.

  18. Ca cofactor of the water-oxidation complex: Evidence for a Mn/Ca heteronuclear cluster

    SciTech Connect

    Cinco, Roehl M.; Robblee, John H.; Messinger, Johannes; Fernandez, Carmen; McFarlane, Karen L.; Pizarro, Shelly A.; Sauer, Ken; Yachandra, Vittal K.

    2001-07-25

    Calcium and chloride are necessary cofactors for the proper function of the oxygen-evolving complex (OEC) of Photosystem II (PS II). Located in the thylakoid membranes of green plants, cyanobacteria and algae, PS II and the OEC catalyze the light-driven oxidation of water into dioxygen (released into the biosphere), protons and electrons for carbon fixation. The actual chemistry of water oxidation is performed by a cluster of four manganese atoms, along with the requisite cofactors Ca{sup 2+} and Cl{sup -}. While the Mn complex has been extensively studied by X-ray absorption techniques, comparatively less is known about the Ca{sup 2+} cofactor. The fewer number of studies on the Ca{sup 2+} cofactor have sometimes relied on substituting the native cofactor with strontium or other metals, and have stirred some debate about the structure of the binding site. past efforts using Mn EXAFS on Sr-substituted PSII are suggestive of a close link between the Mn cluster and Sr, within 3.5 {angstrom}. The most recent published study using Sr EXAFS on similar samples confirms this finding of a 3.5 {angstrom} distance between Mn and Sr. This finding was base3d on a second Fourier peak (R {approx} 3 {angstrom}) in the Sr EXAFS from functional samples, but is absent from inactive, hydroxylamine-treated PS II. This Fourier peak II was found to fit best to two Mn at 3.5 {angstrom} rather than lighter atoms (carbon). Nevertheless, other experiments have given contrary results. They wanted to extend the technique by using polarized Sr EXAFS on layered Sr-substituted samples, to provide important angle information. Polarized EXAFS involves collecting spectra for different incident angles ({theta}) between the membrane normal of the layered sample and the X-ray electric field vector. Dichroism in the EXAFS can occur, depending on how the particular absorber-backscatterer (A-B) vector is aligned with the electric field. Through analysis of the dichroism, they extract the average number

  19. Ab initio modeling of zincblende AlN layer in Al-AlN-TiN multilayers

    DOE PAGES [OSTI]

    Yadav, S. K.; Wang, J.; Liu, X. -Y.

    2016-06-13

    An unusual growth mechanism of metastable zincblende AlN thin film by diffusion of nitrogen atoms into Al lattice is established. Using first-principles density functional theory, we studied the possibility of thermodynamic stability of AlN as a zincblende phase due to epitaxial strains and interface effect, which fails to explain the formation of zincblende AlN. We then compared the formation energetics of rocksalt and zincblende AlN in fcc Al through direct diffusion of nitrogen atoms to Al octahedral and tetrahedral interstitials. Furthermore, the formation of a zincblende AlN thin film is determined to be a kinetically driven process, not a thermodynamicallymore » driven process.« less

  20. CA_OPPUSST - Cantera OPUS Steady State

    Energy Science and Technology Software Center

    2005-03-01

    The Cantera Opus Steady State (ca-opusst) applications solves steady reacting flow problems in opposed-flow geometries. It is a 1-0 application that represents axisymmetnc 3-0 physical systems that can be reduced via a similarity transformation to a 1-0 mathematical representation. The code contain solutions of the general dynamic equations for the particle distribution functions using a sectional model to describe the particle distribution function. Operators for particle nucleation, coagulation, condensation (i.e., growth/etching via reactions with themore » gas ambient), internal particle reactions. particle transport due to convection and due to molecular transport, are included in the particle general dynamics equation. Heat transport due to radiation exchange of the environment with particles in local thermal equilibrium to the surrounding gas will be included in the enthalpy conservation equation that is solved for the coupled gas! particle system in an upcoming version of the code due in June 2005. The codes use Cantera , a C++ Cal Tech code, for determination of gas phase species transport, reaction, and thermodynamics physical properties and source terms. The Codes use the Cantera Aerosol Dynamics Simulator (CADS) package, a general library for aerosol modeling, to calculate properties and source terms for the aerosol general dynamics equation, including particle formation from gas phase reactions, particle surface chemistry (growth and oxidation), bulk particle chemistry, particle transport by Brownian diffusion, thermophoresis, and diffusiophoresis, and thermal radiative transport involving particles. Also included are post-processing programs, cajost and cajrof, to extract ascii data from binary output files to produce plots.« less

  1. ANALOG I/O MODULE TEST SYSTEM BASED ON EPICS CA PROTOCOL AND ACTIVEX CA INTERFACE

    SciTech Connect

    YENG,YHOFF,L.

    2003-10-13

    Analog input (ADC) and output (DAC) modules play a substantial role in device level control of accelerator and large experiment physics control system. In order to get the best performance some features of analog modules including linearity, accuracy, crosstalk, thermal drift and so on have to be evaluated during the preliminary design phase. Gain and offset error calibration and thermal drift compensation (if needed) may have to be done in the implementation phase as well. A natural technique for performing these tasks is to interface the analog VO modules and GPIB interface programmable test instruments with a computer, which can complete measurements or calibration automatically. A difficulty is that drivers of analog modules and test instruments usually work on totally different platforms (vxworks VS Windows). Developing new test routines and drivers for testing instruments under VxWorks (or any other RTOS) platform is not a good solution because such systems have relatively poor user interface and developing such software requires substantial effort. EPICS CA protocol and ActiveX CA interface provide another choice, a PC and LabVIEW based test system. Analog 110 module can be interfaced from LabVIEW test routines via ActiveX CA interface. Test instruments can be controlled via LabVIEW drivers, most of which are provided by instrument vendors or by National Instruments. Labview also provides extensive data analysis and process functions. Using these functions, users can generate powerful test routines very easily. Several applications built for Spallation Neutron Source (SNS) Beam Loss Monitor (BLM) system are described in this paper.

  2. Spectroscopy diagnostic of dual-frequency capacitively coupled CHF{sub 3}/Ar plasma

    SciTech Connect

    Liu, Wen-Yao; Du, Yong-Quan [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); Liu, Yong-Xin; Liu, Jia; Zhao, Tian-Liang; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Xu, Yong; Li, Xiao-Song; Zhu, Ai-Min [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China) [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-11-15

    A combined spectroscopic method of absorption, actinometry, and relative optical emission intensity is employed to determine the absolute CF{sub 2} density, the relative F and H densities, H atom excitation temperature and the electron density in dual-frequency (60/2 MHz) capacitively coupled CHF{sub 3}/Ar plasmas. The effects of different control parameters, such as high-frequency (HF) power, low-frequency (LF) power, gas pressure, gap length and content of CHF{sub 3}, on the concentration of radical CF{sub 2}, F, and H and excitation temperature are discussed, respectively. It is found that the concentration of CF{sub 2} is strongly dependent on the HF power, operating pressure and the proportion of CHF{sub 3} in feed gas, while it is almost independent of the LF power and the gap length. A higher concentration ratio of F to CF{sub 2} could be obtained in dual-frequency discharge case. Finally, the generation and decay mechanisms of CF{sub 2} and F were also discussed.

  3. Ordered InP nanostructures fabricated by Ar{sup +}-ion irradiation

    SciTech Connect

    Mohanta, S.K.; Soni, R.K.; Tripathy, S.; Chua, S.J.

    2006-01-23

    In this letter, we report fabrication of ordered InP nanostructures using 50 keV Ar{sup +}-ion irradiation at normal incidence. The structural and optical properties of these nanodots as a function of ion dose have been investigated. Scanning electron microscopy investigations reveal that the average sizes of the InP nanodots vary from 50 nm to 90 nm as the ion dose increases from 1x10{sup 17} to 1x10{sup 18} cm{sup -2}. Furthermore, an increase in ion dose results in a wider dot size distribution. Apart from the bulk InP band-edge photoluminescence (PL), the surface nanostructuring leads to the observation of an additional PL band at 1.98 eV. Such a blueshifted PL peak could arise due to a combined effect of carrier confinement in the surface nanodots and radiative recombination associated with surface states. The room-temperature micro-Raman investigation of InP nanodots reveals optical phonon softening due to phonon confinement in the surface nanodots.

  4. Structural modifications in InP nanostructures prepared by Ar{sup +}-ion irradiation

    SciTech Connect

    Mohanta, S. K.; Soni, R. K.; Gosvami, N. N.; Vajpeyi, A. P.; Tripathy, S.

    2007-10-01

    The evolution of nanopatterned InP surfaces by low-energy Ar{sup +}-ion irradiation and their dependence on incidence angle were investigated by field emission scanning electron microscopy, atomic force microscopy, and Raman scattering. Ordered surface nanodots of high aspect ratio were created. At large ion incidence angle the dot density decreases and the size varies in the range of 65-130 nm with height of around 25-30 nm. Rapid thermal annealing of the patterned surface shows cluster formation at annealing temperatures of 400 deg. C and above, with some micro-cracks at ion incidence angle of 45 deg. C . With increasing ion incidence angle, the optical phonon Raman modes display systematic downward shift and large asymmetric broadening associated with increased contribution of disorder activated LO and TO modes from the patterned surface. The lowering of phonon frequencies, induced by the phonon wave function confinement, signifies the presence of embedded nanocrystallites in the large sized nanodot patterned surface. The surface damage recovery is achieved by rapid thermal annealing of the samples as reflected in the increased optical phonon frequencies and reduced line shape broadening with annealing temperature. For large ion incident angle, the strain relaxation in the irradiated surface region leads to micro-crack formation in the patterned surface and further hardening of the phonon frequencies.

  5. SUCCESSIVE SOLAR FLARES AND CORONAL MASS EJECTIONS ON 2005 SEPTEMBER 13 FROM NOAA AR 10808

    SciTech Connect

    Liu Chang; Wang Haimin; Lee, Jeongwoo; Karlicky, Marian; Choudhary, Debi Prasad; Deng Na E-mail: haimin@flare.njit.ed E-mail: karlicky@asu.cas.c E-mail: na.deng@csun.ed

    2009-09-20

    We present a multiwavelength study of the 2005 September 13 eruption from NOAA AR 10808 that produced total four flares and two fast coronal mass ejections (CMEs) within {approx}1.5 hr. Our primary attention is paid to the fact that these eruptions occurred in close succession in time, and that all of them were located along an S-shaped magnetic polarity inversion line (PIL) of the active region. In our analysis, (1) the disturbance created by the first flare propagated southward along the PIL to cause a major filament eruption that led to the first CME and the associated second flare underneath. (2) The first CME partially removed the overlying magnetic fields over the northern delta spot to allow the third flare and the second CME. (3) The ribbon separation during the fourth flare would indicate reclosing of the overlying field lines opened by the second CME. It is thus concluded that these series of flares and CMEs are interrelated to each other via magnetic reconnections between the expanding magnetic structure and the nearby magnetic fields. These results complement previous works made on this event with the suggested causal relationship among the successive eruptions.

  6. Heat- and light-induced transformations of Yb trapping sites in an Ar matrix

    SciTech Connect

    Tao, L.-G.; Lambo, R. Zhou, X.-G.; Hu, S.-M.; Kleshchina, N. N.; Bezrukov, D. S.; Buchachenko, A. A.

    2015-11-07

    The low-lying electronic states of Yb isolated in a solid Ar matrix grown at 4.2 K are characterized through absorption and emission spectroscopy. Yb atoms are found to occupy three distinct thermally stable trapping sites labeled “red,” “blue,” and “violet” according to the relative positions of the absorption features they produce. Classical simulations of the site structure and relative stability broadly reproduced the experimentally observed matrix-induced frequency shifts and thus identified the red, blue, and violet sites as due to respective single substitutional (SS), tetravacancy (TV), and hexavacancy (HV) occupation. Prolonged excitation of the {sup 1}S → {sup 1}P transition was found to transfer the Yb population from HV sites into TV and SS sites. The process showed reversibility in that annealing to 24 K predominantly transferred the TV population back into HV sites. Population kinetics were used to deduce the effective rate parameters for the site transformation processes. Experimental observations indicate that the blue and violet sites lie close in energy, whereas the red one is much less stable. Classical simulations identify the blue site as the most stable one.

  7. Identification of weak autoionizing resonances observed through fluorescence from the satellite states of Ar{sup +}

    SciTech Connect

    McLaughlin, K.W.; Yenen, O.; Samson, J.A.R.

    1997-04-01

    Photoionization accompanied by excitation of the residual ionic state violates an independent electron model since, according to QED, photons interact only with individual electrons. By allowing measurements at a threshold event with high resolution, the observation of the fluorescence from the decay of these excited states (satellite states) is a sensitive method in the study of electron-electron interactions, providing complementary information to photoelectron spectroscopy. In the measurements reported here, an atomic beam of argon has been photoionized with 34 to 39 eV synchrotron radiation at beamline 9.0.1 of the Advanced Light Source. This energy range encompasses the 3p{sup 4} [{sup 3}P] 4p {sup 4}P, {sup 2}P, and {sup 2}D as well as the [{sup 1}D]4p {sup 2}F satellite states of Ar{sup +}. By observing the fine-structure resolved fluorescence from these satellite states, new Rydberg series and extensions of previously known series have been resolved with an energy resolution of 3 meV. With the high photon flux available from the high resolution monochromator of beamline 9.0.1, even the weakly excited [{sup 3}P] 4p ({sup 2}S) ns,d autoionizing structure has been observed for the first time.

  8. Scaling behavior studies of Ar{sup +} ion irradiated ripple structured mica surfaces

    SciTech Connect

    Metya, Amaresh Ghose, Debabrata

    2014-04-24

    We have studied scaling behavior of ripple structured mica surfaces. Clean mica (001) surface is sputtered by 500 eV Ar{sup +} ion beam at 40° incidence angle for different time ranging from 28 minutes to 245 minutes to form ripples on it. The scaling of roughness of sputtered surface characterized by AFM is observed into two regime here; one is super roughening which is for above the crossover bombardment time (i.e, t{sub x} ≥ 105 min) with the scaling exponents α = α{sub s} = 1.45 ± 0.03, α{sub local} = 0.87 ± 0.03, β = 1.81 ± 0.01, β{sub local} = 1.67 ± 0.07 and another is a new type of scaling dynamics for t{sub x} ≤ 105 min with the scaling exponents α = 0.95 (calculated), α{sub s} = 1.45 ± 0.03, α{sub local} = 0.87 ± 0.03, β = 1.81 ± 0.01, β{sub local} = 1.67 ± 0.07. In the super roughening scaling dynamics, two types of power law dependency is observed on spatial frequency of morphology (k): for higher k values PSD ∼ k{sup −4} describing diffusion controlled smoothening and for lower k values PSD ∼ k{sup −2} reflecting kinetic roughening.

  9. Reversal of the asymmetry in a cylindrical coaxial capacitively coupled Ar/Cl2 plasma

    DOE PAGES [OSTI]

    Upadhyay, Janardan; Im, Do; Popović, Svetozar; Vušković, Leposava; Valente-Feliciano, Anne -Marie; Phillips, Larry

    2015-10-08

    The reduction of the asymmetry in the plasma sheath voltages of a cylindrical coaxial capacitively coupled plasma is crucial for efficient surface modification of the inner surfaces of concave three-dimensional structures, including superconducting radio frequency cavities. One critical asymmetry effect is the negative dc self-bias, formed across the inner electrode plasma sheath due to its lower surface area compared to the outer electrode. The effect on the self-bias potential with the surface enhancement by geometric modification on the inner electrode structure is studied. The shapes of the inner electrodes are chosen as cylindrical tube, large and small pitch bellows, andmore » disc-loaded corrugated structure (DLCS). The dc self-bias measurements for all these shapes were taken at different process parameters in Ar/Cl2 discharge. Lastly, the reversal of the negative dc self-bias potential to become positive for a DLCS inner electrode was observed and the best etch rate is achieved due to the reduction in plasma asymmetry.« less

  10. Effect Of Preparation Methods On The Performance Of Co/Al2O3 Catalysts For Dry Reforming Of Methane

    SciTech Connect

    Ewbank, Jessica L.; Kovarik, Libor; Kenvin, Christian C.; Sievers, Carsten

    2014-01-06

    Two methods, dry impregnation (DI) and controlled adsorption (CA), are used for the preparation of Co/ Al2O3 catalysts for methane dry reforming reactions. Point of zero charge (PZC) measurements, pH-precipitation studies, and adsorption isotherms are used to develop a synthesis procedure in which deposition of Co2+ takes place in a more controlled manner than metal deposition during drying in synthesis by dry impregnation. The possible adsorption phenomena that occur during preparation of Co/Al2O3 catalysts by controlled adsorption are discussed. H2 chemisorption and TEM show that catalysts prepared by CA have smaller average particle sizes and higher dispersions. TPR studies show that for the sample prepared by CA a higher amount of cobalt is reduced to its metallic state and that more CoAl2O4 spinel species are present relative to DI samples. The catalyst prepared by CA shows higher activity and slower deactivation for methane dry reforming than the catalyst prepared by DI. XPS and C, H, N analysis on spent catalysts confirm two types of carbonaceous deposits are formed depending on the preparation method.

  11. Al Corn Clean Fuel | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Corn Clean Fuel Jump to: navigation, search Name: Al-Corn Clean Fuel Place: Claremont, North Dakota Product: Al-Corn is an ethanol plant located in Claremont, North Dakota, which...

  12. Promising Magnesium Battery Research at ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Promising Magnesium Battery Research at ALS Promising Magnesium Battery Research at ALS Print Wednesday, 23 January 2013 16:59 toyota battery a) Cross-section of the in situ ...

  13. ALS Operating Schedule on Google Calendar

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ALS Operating Schedule on Google Calendar Print ALS Operating Schedule Your browser does not appear to support JavaScript, but this page needs to use JavaScript to display...

  14. Category:Montgomery, AL | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Montgomery, AL Jump to: navigation, search Go Back to PV Economics By Location Media in category "Montgomery, AL" The following 16 files are in this category, out of 16 total....

  15. Materials Data on Ca2AlH10ClO8 (SG:15) by Materials Project

    DOE Data Explorer

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Materials Data on Ca3Ti2AlSi3O14F (SG:2) by Materials Project

    SciTech Connect

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. Materials Data on Ca3TiAl2Si3O13F2 (SG:2) by Materials Project

    SciTech Connect

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Materials Data on CaAl4Si2(HO6)2 (SG:9) by Materials Project

    DOE Data Explorer

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. AL2002-01.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    2-01.pdf AL2002-01.pdf PDF icon AL2002-01.pdf More Documents & Publications AL2002-04.pdf AL2002-08.pdf AL2002-06...

  20. AL2002-04.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4.pdf AL2002-04.pdf PDF icon AL2002-04.pdf More Documents & Publications AL2004-01r2.pdf AL2002-01.pdf AL2002-08...

  1. Aluminium distribution in ZSM-5 revisited: The role of Al-Al interactions

    SciTech Connect

    Ruiz-Salvador, A. Rabdel; Grau-Crespo, Ricardo; Gray, Aileen E.; Lewis, Dewi W.

    2013-02-15

    We present a theoretical study of the distribution of Al atoms in zeolite ZSM-5 with Si/Al=47, where we focus on the role of Al-Al interactions rather than on the energetics of Al/Si substitutions at individual sites. Using interatomic potential methods, we evaluate the energies of the full set of symmetrically independent configurations of Al siting in a Si{sub 94}Al{sub 2}O{sub 192} cell. The equilibrium Al distribution is determined by the interplay of two factors: the energetics of the Al/Si substitution at an individual site, which tends to populate particular T sites (e.g., the T14 site), and the Al-Al interaction, which at this Si/Al maximises Al-Al distances in general agreement with Dempsey's rule. However, it is found that the interaction energy changes approximately as the inverse of the square of the distance between the two Al atoms, rather than the inverse of the distance expected if this were merely charge repulsion. Moreover, we find that the anisotropic nature of the framework density plays an important role in determining the magnitude of the interactions, which are not simply dependent on Al-Al distances. - Graphical abstract: Role of Al-Al interactions in high silica ZSM-5 is shown to be anisotropic in nature and not dependent solely on Coulombic interactions. Highlights: Black-Right-Pointing-Pointer Si-Al distribution in ZSM-5 is revisited, stressing the role of the Al-Al interaction. Black-Right-Pointing-Pointer Coulomb interactions are not the key factors controlling the Al siting. Black-Right-Pointing-Pointer Anisotropy of the framework is identified as a source of departure from Dempsey's rule.

  2. Emission Regulations Reduced Impact of Climate Change in CA

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Emission Regulations Reduced Impact of Climate Change in CA Emission Regulations Reduced Impact of Climate Change in CA Study shows clean diesel programs slashed black carbon, a powerful short-term contributor to global warming June 13, 2013 Jon Weiner 510-486-4014 jrweiner@lbl.gov CA-BC-graphic.jpg Sacramento - Reductions in emissions of black carbon since the late 1980s, mostly from diesel engines as a result of air quality programs, have resulted in a measurable reduction of concentrations of

  3. 229th Electrochemical Society (ECS) Meeting (San Diego, CA) - JCAP

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    229th Electrochemical Society (ECS) Meeting (San Diego, CA) 229th Electrochemical Society (ECS) Meeting (San Diego, CA) Sun, May 29, 2016 12:00pm 12:00 Thu, Jun 2, 2016 1:00pm 13:00 San Diego, CA USA Joel A. Haber, "Development of Solar Fuels Photoanodes through Combinatorial Integration of Ni-La-Co-Ce Oxide and Ni-Fe-Co-Ce Oxide Catalysts on BiVO4" The development of an efficient photoanode remains the primary materials challenge in the establishment of a scalable technology for solar

  4. Microsoft Word - Ca-DTPA Insert_2 Pages.doc

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    calcium trisodium injection contains the sodium salt of calcium diethylenetriaminepentaacetate. Pentetate calcium trisodium is also known as trisodium calcium diethylenetriaminepentaacetate and is commonly referred to as Ca-DTPA. It has a molecular formula of Na3CaC14H18N3O10 and a molecular weight of 497.4 Daltons. It is represented by the following struc tural formula: Ca-DTPA is supplied as a clear, colorless, hyperosmolar (1260 mOsmol/kg) solution in a colorless ampoule containing 5 mL. The

  5. Hydrogen isotope trapping in Al-Cu binary alloys

    SciTech Connect

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high; for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.

  6. Hydrogen isotope trapping in Al-Cu binary alloys

    DOE PAGES [OSTI]

    Chao, Paul; Karnesky, Richard A.

    2016-01-01

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high;more » for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.« less

  7. Ca{sub 2}Pd{sub 3}Ge, a new fully ordered ternary Laves phase structure

    SciTech Connect

    Doverbratt, Isa; Ponou, Simeon; Lidin, Sven

    2013-01-15

    The title compound, Ca{sub 2}Pd{sub 3}Ge, was prepared as a part of a systematic investigation of the Ca-Pd-Ge ternary phase diagram. The structure was determined and refined from single-crystal X-ray diffraction data. It is a new fully ordered ternary Laves phase with the space group R-3m, Z=3, a=5.6191 (5) A, c=12.1674 (7) A, wR{sub 2}=0.054 (all data) and is isostructural to Mg{sub 2}Ni{sub 3}Si (Noreus et al., 1985 [17]) but due to the larger size of all elements in Ca{sub 2}Pd{sub 3}Ge, the cell axes are approximately 10% longer. The compound may formally be considered as a Zintl compound, with [Pd{sub 3}Ge]{sup 4-} forming a poly-anionic network and divalent Ca cations located in truncated tetrahedral interstices. The electronic structure and chemical bonding of Ca{sub 2}Pd{sub 3}Ge is discussed in terms of LMTO band structure calculations and compared with CaPd{sub 2} (MgCu{sub 2}-type). - Graphical abstract: The title compound, Ca{sub 2}Pd{sub 3}Ge is a new fully ordered ternary Laves phase which may formally be considered as a Zintl compound, with [Pd{sub 3}Ge]{sup 4-} forming a poly-anionic network and divalent Ca cations located in truncated tetrahedral interstices. The structure is composed of Kagome net layers, consisting of Pd atoms only, which are stacked in an ABC sequence. Band structure calculations show that the Fermi level is located at a local minimum of the DOS (pseudo-gap) indicating that the charge is roughly optimized in the structure. Highlights: Black-Right-Pointing-Pointer Site specific segregation in a Laves phase that is also a Zintl phase. Black-Right-Pointing-Pointer Pseudo-gap at the Fermi level in a Laves phase. Black-Right-Pointing-Pointer Distorted Frank-Kasper polyhedron.

  8. Happenings @ AL Month | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Happenings @ AL Month Happenings @ AL Month November 2016 « Prev Next » Event Type - Any - Audit/Review Holiday Lab Wide Retirement Speaker/Demo Training Visitors Apply Sun Mon Tue Wed Thu Fri Sat 30 31 1 2 3 4 5 6 7 8 9 10 11 12 4th Japan-US Bilateral Meeting on Rare Metals Spedding A/B 8:00am to 5:00pm General Employee Training (AL-001) 140 TASF 9:00am Spill Prevention, Control & Countermeasures (AL-218) 140 TASF 10:00am Sprains & Strains Prevention (AL-183) 140 TASF 2:00pm Aerial

  9. THE KINEMATICS AND PLASMA PROPERTIES OF A SOLAR SURGE TRIGGERED BY CHROMOSPHERIC ACTIVITY IN AR11271

    SciTech Connect

    Kayshap, P.; Srivastava, Abhishek K. [Aryabhatta Research Institute of Observational Sciences (ARIES), Manora Peak, Nainital 263 129 (India)] [Aryabhatta Research Institute of Observational Sciences (ARIES), Manora Peak, Nainital 263 129 (India); Murawski, K., E-mail: kmur@kft.umcs.lublin.pl [Group of Astrophysics, UMCS, ul. Radziszewskiego 10, 20-031 Lublin (Poland)

    2013-01-20

    We observe a solar surge in NOAA AR11271 using the Solar Dynamics Observatory (SDO) Atmospheric Imaging Assembly 304 A image data on 2011 August 25. The surge rises vertically from its origin up to a height of Almost-Equal-To 65 Mm with a terminal velocity of Almost-Equal-To 100 km s{sup -1}, and thereafter falls and fades gradually. The total lifetime of the surge was Almost-Equal-To 20 minutes. We also measure the temperature and density distribution of the observed surge during its maximum rise and find an average temperature and a density of 2.0 MK and 4.1 Multiplication-Sign 10{sup 9} cm{sup -3}, respectively. The temperature map shows the expansion and mixing of cool plasma lagging behind the hot coronal plasma along the surge. Because SDO/HMI temporal image data do not show any detectable evidence of significant photospheric magnetic field cancellation for the formation of the observed surge, we infer that it is probably driven by magnetic-reconnection-generated thermal energy in the lower chromosphere. The radiance (and thus the mass density) oscillations near the base of the surge are also evident, which may be the most likely signature of its formation by a reconnection-generated pulse. In support of the present observational baseline of the triggering of the surge due to chromospheric heating, we devise a numerical model with conceivable implementation of the VAL-C atmosphere and a thermal pulse as an initial trigger. We find that the pulse steepens into a slow shock at higher altitudes which triggers plasma perturbations exhibiting the observed features of the surge, e.g., terminal velocity, height, width, lifetime, and heated fine structures near its base.

  10. RAPID/Roadmap/8-CA-b | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    in a timely manner and not wait until the last day of the open window. GIDAP Best Management Practice, section 3.5. 8-CA-b.7 - Hold Scoping Meeting Within five (5) Business...

  11. Field Projects: Cañon City, Colorado

    Energy.gov [DOE]

    In June 2000, Cotter Corporation installed a PRB at its uranium ore processing millsite in Cañon City, Colorado. The PRB contains zero-valent iron (ZVI) that treated molybdenum and uranium...

  12. RAPID/Roadmap/17-CA-a | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Tools Contribute Contact Us State Aesthetic Concerns (17-CA-a) Page Does Not Exist.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  13. 11-03-2010 CA-B-10-0135

    National Nuclear Security Administration (NNSA)

    1-03-2010 CA-B-10-0135 Sandia National LaboratoriesCalifornia proposes to establish a university partnership LDRD to support a fellowship student whose project, titled ...

  14. RAPID/Roadmap/7-CA-e | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    see: Green arrow.PNG 9-FD-a: BLM NEPA Process 7-CA-e.8 - Conduct Environmental, Reliability, and Mitigation Assessments At the same time that the BLM is conducting the Project...

  15. Calexico, CA Natural Gas Pipeline Exports to Mexico (Million...

    Energy Information Administration (EIA) (indexed site)

    Million Cubic Feet) Calexico, CA Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 565 544 592 557 600 586 592 ...

  16. Ogilby Mesa, CA Natural Gas Pipeline Imports From Mexico (Million...

    Energy Information Administration (EIA) (indexed site)

    Million Cubic Feet) Ogilby Mesa, CA Natural Gas Pipeline Imports From Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 78 376 2013 16 7 - No ...

  17. Otay Mesa, CA Natural Gas Pipeline Imports from Mexico (Million...

    Energy Information Administration (EIA) (indexed site)

    from Mexico (Million Cubic Feet) Otay Mesa, CA Natural Gas Pipeline Imports from Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 236 86 93 110 ...

  18. Proceedings of the Seventh Annual Conference on Fossil Energy Materials. Fossil Energy AR and TD Materials Program

    SciTech Connect

    Cole, N.C.; Judkins, R.R.

    1993-07-01

    Objective of the AR&TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The 37 papers are arranged into 3 sessions: ceramics, new alloys/intermetallics, and new alloys/advanced austenitics. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  19. Rotational and angular distributions of NO products from NO-Rg(Rg = He, Ne, Ar) complex photodissociation

    DOE PAGES [OSTI]

    Heather L. Holmes-Ross; Hall, Gregory E.; Valenti, Rebecca J.; Yu, Hua -Gen; Lawrance, Warren D.

    2016-01-29

    In this study, we present the results of an investigation into the rotational and angular distributions of the NO A~ state fragment following photodissociation of the NO-He, NO-Ne and NO-Ar van der Waals complexed excited via the A~ ← X~ transition. For each complex the dissociation is probed for several values of Ea, the available energy above the dissociation threshold.

  20. EA-1638: Solyndra, Inc. Photovoltaic Manufacturing Facility in Fremont, CA

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    | Department of Energy 8: Solyndra, Inc. Photovoltaic Manufacturing Facility in Fremont, CA EA-1638: Solyndra, Inc. Photovoltaic Manufacturing Facility in Fremont, CA March 2, 2009 EA-1638: Final Environmental Assessment Loan Guarantee to Solyndra, Inc. for Construction of A Photovoltaic Manufacturing Facility and Leasing of an Existing Commercial Facility in Fremont, California March 31, 2009 EA-1638: Finding of No Significant Impact Loan Guarantee to Solyndra, Inc. for Construction of a

  1. EA-1798: Abengoa Solar's Mojave Solar Project near Barstow, CA |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy 8: Abengoa Solar's Mojave Solar Project near Barstow, CA EA-1798: Abengoa Solar's Mojave Solar Project near Barstow, CA July 1, 2011 EA-1798: Final Environmental Assessment Loan Guarantee to Mojave Solar, LLC for the Abengoa Mojave Solar Project near Barstow, California July 8, 2011 EA-1798: Finding of No Significant Impact Loan Guarantee to Mojave Solar, LLC for the Abengoa Mojave Solar Project near Barstow, California March 17, 2011 Abengoa Mojave Final Biological

  2. Climate Action Champions: Blue Lake Rancheria Tribe, CA | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy Blue Lake Rancheria Tribe, CA Climate Action Champions: Blue Lake Rancheria Tribe, CA The Blue Lake Rancheria, California, a federally recognized Native American tribal Government and community, is located on over 100 acres of land spanning the scenic Mad River in northwestern California. In its operational strategy, the Tribe has implemented the ‘seven generations’ philosophy, where actions taken today will have a positive impact for seven generations to come. This results

  3. Climate Action Champions: San Francisco, CA | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    San Francisco, CA Climate Action Champions: San Francisco, CA To meet the challenge of climate change, San Francisco is working with residents, businesses, community organizations, and state and federal agencies to create innovative programs and policies. To meet the challenge of climate change, San Francisco is working with residents, businesses, community organizations, and state and federal agencies to create innovative programs and policies. Climate Action Progress and Plans San Francisco

  4. NUG Meeting June 24-25, 2004 (Berkeley, CA)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    NUG Meeting June 24-25, 2004 (Berkeley, CA) Dates June 24-25, 2004 Location Lawrence Berkeley National Laboratory 1 Cyclotron Road Building 54, Conference Room 130 (Perseverance Hall) Berkeley, CA Presentations Agenda NERSC User Group (NUG) Meeting June 24-25, 2004 at Berkeley Lab The Spring 2004 NUG Meeting took place on Thursday, June 24 (training day) and Friday, June 25 (business meeting), in Building 54, Conference Room 130 (Perseverance Hall). Training Day Lecture Materials Time Title

  5. ERSUG Meeting: January 28-29, 1997 (Berkeley, CA)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ERSUG Meeting: January 28-29, 1997 (Berkeley, CA) Dates January 28-29, 1997 Location Lawerence Berkeley Nantional Laboratory Perserverence Hall 1 Cyclotron Road Berkeley, CA 94720 Presentations Agenda ERSUG Business Meeting Special Special Pre-ERSUG-meeting Training Day: Monday, January 27, 1997 ERSUG Meeting (Day 1) January 28th Tuesday, Perseverance Hall Time Topic Speaker 8:30 Pickup from Hotel 9:00 Welcome Klaus Berkner - Associate Laboratory Director, Berkeley Lab 9:10 Agenda Review Ricky

  6. ERSUG Meeting: January 8-9, 1996 (Berkeley, CA)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ERSUG Meeting: January 8-9, 1996 (Berkeley, CA) Dates January 8-9, 1996 Location Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley, CA 94720 Attendee List Minutes ERSUG Meeting Minutes - January 8,9, 1996 Lawrence Berkeley LaboratoryJanuary 8-9, 1996Kirby Fong (NERSC, LLNL), Dave Stevens (LBL), Ricky A. Kendall (PNNL,ExERSUG Vice-Chair) Opening Remarks From the Berkeley Laboratory This ERSUG meeting, originally planned for Princeton, New Jersey, was rescheduled at the Lawrence

  7. ERSUG Meeting: June 13 - 14, 1995 (Livermore, CA)

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ERSUG Meeting: June 13 - 14, 1995 (Livermore, CA) Dates ERSUG Meeting: June 13 & 14, 1995 Location Lawrence Livermore National Laboratory Livermore, CA Minutes Summary of ERSUG Meeting June 13 - 14, 1995, Livermore, California The Energy Research Supercomputer Users Group (ERSUG) June 1995 meeting was hosted by the National Energy Research Supercomputer Center (NERSC) at the Lawrence Livermore National Laboratory (LLNL). Some of the talks are summarized below. Welcome The meeting opened

  8. Electrochemistry Gordon Research Seminar/Conference (Ventura, CA) - JCAP

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Electrochemistry Gordon Research Seminar/Conference (Ventura, CA) Electrochemistry Gordon Research Seminar/Conference (Ventura, CA) Sat, Jan 9, 2016 2:30pm 14:30 Fri, Jan 15, 2016 3:30pm 15:30 Sonja Francis, "Catalyst Screening for Electrochemical Carbon Dioxide Reduction" Co-authors: Daniel Torelli, Bruce Brunschwig, Nate Lewis October 11 2015 Electrochemical Energy Summit at the 228th ECS Meeting (Phoenix, AZ) February 28 Renewable Energy: Solar Fuels - Gordon Research Conference

  9. Effect of 200 keV Ar{sup +} implantation on optical and electrical properties of polyethyleneterepthalate (PET)

    SciTech Connect

    Kumar, Rajiv Goyal, Meetika Sharma, Ambika; Aggarwal, Sanjeev; Sharma, Annu; Kanjilal, D.

    2015-05-15

    In the present paper we have discussed the effect of 200 keV Ar{sup +} ions on the electrical and optical properties of PET samples. PET samples were implanted with 200 keV Ar{sup +} ions to various doses ranging from 1×10{sup 15} to 1×10{sup 17} Ar{sup +} cm{sup 2}. The changes in the electrical and optical properties of pristine and implanted PET specimens have been studied by using Keithley electrometer and UV-Visible absorption spectroscopy. The electrical conductivity has found to be increased with increasing ion dose. The optical studies have revealed the drastic alterations in optical band gap from 3.63 eV to 1.48 eV and also increase in number of carbon atoms per cluster from 215 to 537. Further, the change in the electrical conductivity and optical band gap has also been correlated with the formation of conductive islands in the implanted layers of PET.

  10. Ar{sup +}-irradiation-induced damage in hydride vapor-phase epitaxy GaN films

    SciTech Connect

    Nakano, Yoshitaka Ogawa, Daisuke; Nakamura, Keiji; Kawakami, Retsuo; Niibe, Masahito

    2015-07-15

    The authors have investigated the electrical characteristics of hydride vapor-phase epitaxy GaN films exposed to Ar{sup +} irradiation, employing Schottky barrier diodes. The Ar{sup +} irradiation tends to largely increase the effective carrier concentration in the near surface region of GaN up to ∼25 nm, due to the generation of donor-type N vacancy defects, compared to the original value before the irradiation. More interestingly, acceptor-type deep-level defects are found to be formed at ∼2.1, ∼2.9, and ∼3.2 eV below the conduction band in the subsequently deeper region, in which Ga vacancies introduced by the Ar{sup +} irradiation are considered to be in-diffused and immediately combined with hydrogen. These N vacancies and hydrogenated Ga vacancies formed are dominantly responsible for changing the depth profiles of the effective carrier concentration via the carrier generation, the carrier trapping, and/or carrier compensation.

  11. Role of excited state photoionization in the 852.1 nm Cs laser pumped by Cs-Ar photoassociation

    SciTech Connect

    Hewitt, J. D.; Houlahan, T. J. Jr.; Eden, J. G.; Gallagher, J. E.; Perram, G. P.; Carroll, D. L.; Palla, A. D.; Verdeyen, J. T.

    2013-03-18

    Photoionization of Cs (6p {sup 2}P{sub 3/2}) atoms during the operation of a Cs D{sub 2} line (852.1 nm: 6p {sup 2}P{sub 3/2}{yields}6s {sup 2}S{sub 1/2}) laser, pumped by free{yields}free transitions of thermal Cs-Ar ground state pairs, has been investigated experimentally and computationally. Photoexcitation of Cs vapor/Ar mixtures through the blue satellite of the D{sub 2} transition (peaking at 836.7 nm) selectively populates the {sup 2}P{sub 3/2} upper laser level by the dissociation of the CsAr excited complex. Comparison of laser output energy data, for instantaneous pump powers up to 3 MW, with the predictions of a numerical model sets an upper bound of 8 Multiplication-Sign 10{sup -26} cm{sup 4} W{sup -1} on the Cs (6p {sup 2}P{sub 3/2}) two photon ionization cross-section at 836.7 nm which corresponds to a single photon cross-section of 2.4 Multiplication-Sign 10{sup -19} cm{sup 2} for a peak pump intensity of 3 MW cm{sup -2}.

  12. Revisiting the Al/Al2O3 Interface: Coherent Interfaces and Misfit

    Office of Scientific and Technical Information (OSTI)

    Accommodation (Journal Article) | DOE PAGES Revisiting the Al/Al2O3 Interface: Coherent Interfaces and Misfit Accommodation Title: Revisiting the Al/Al2O3 Interface: Coherent Interfaces and Misfit Accommodation We report the coherent and semi-coherent Al/α-Al2O3 interfaces using molecular dynamics simulations with a mixed, metallic-ionic atomistic model. For the coherent interfaces, both Al-terminated and O-terminated nonstoichiometric interfaces have been studied and their relative

  13. Spatial distribution of electrical properties for Al-doped ZnO films deposited by dc magnetron sputtering using various inert gases

    SciTech Connect

    Sato, Yasushi; Ishihara, Keita; Oka, Nobuto; Shigesato, Yuzo

    2010-07-15

    Spatial distribution of electrical properties of Al-doped ZnO (AZO) films deposited by magnetron sputtering was investigated. To adjust the intensity of bombardment by high-energy particles, the AZO films were deposited using Ar, Kr, or Xe gas with varying plasma impedance. The spatial distribution of the electrical properties clearly depends on the sputtering gas. In the case of using Kr or Xe, the resistivity of the films in front of the target center and erosion areas was significantly enhanced, in contrast with Ar. This was attributed to an enhancement in bombardment damage due to the increased sputtering voltages required for Kr or Xe discharges. The increase in plasma impedance was due to the smaller coefficients for secondary-electron emission of the target surface by Kr or Xe impingements, which leads to the larger sputtering voltage.

  14. Phase equilibria in Ca-Co-O system

    SciTech Connect

    Sedmidubsky, D.; Jakes, V.; Jankovsky, O.; Leitner, J.; Sofer, Z.; Hejtmanek, J.

    2012-10-15

    The phase equilibria in the ternary Ca-Co-O system have been studied by thermal analysis (DSC/DTA, TGA), X-ray diffraction of quenched samples and low temperature heat capacity measurements. These experimental data were combined with the data available in literature and used to assess the thermodynamic quantities of the involved phases. A particular focus was put on the misfit cobaltite Ca{sub 3}Co{sub 3.93}O{sub 9.36} as a potential candidate for high temperature thermoelectric conversion whose observed nonstoichiometry was described in terms of compound energy formalism. The phase diagram was mapped using FactSage program. - Graphical abstract: Heat capacity and decomposition behavior of misfit layer cobaltite, Ca{sub 3}Co{sub 3.93+x}O{sub 9+{delta}}. Highlights: Black-Right-Pointing-Pointer Thermodynamic properties of phases involved in the Ca-Co-O system were assessed. Black-Right-Pointing-Pointer The misfit layer cobaltite Ca{sub 3}Co{sub 3.93+x}O{sub 9+d} was described using compound energy formalism. Black-Right-Pointing-Pointer The phase diagram of the Ca-Co-O system was calculated.

  15. DOE Zero Energy Ready Home Case Study: KB Home, Lancaster, CA...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    KB Home, Lancaster, CA DOE Zero Energy Ready Home Case Study: KB Home, Lancaster, CA Case study of a DOE Zero Energy Ready home in Lancaster, CA, that achieved a HERS 43 without PV ...

  16. Growth and stress-induced transformation of zinc blende AlN layers in Al-AlN-TiN multilayers

    DOE PAGES [OSTI]

    Li, Nan; Yadav, Satyesh K.; Wang, Jian; Liu, Xiang -Yang; Misra, Amit

    2015-12-18

    We report that AlN nanolayers in sputter deposited {111}Al/AlN/TiN multilayers exhibit the metastable zinc-blende-structure (z-AlN). Based on density function theory calculations, the growth of the z-AlN is ascribed to the kinetically and energetically favored nitridation of the deposited aluminium layer. In situ nanoindentation of the as-deposited {111}Al/AlN/TiN multilayers in a high-resolution transmission electron microscope revealed the z-AlN to wurzite AlN phase transformation through collective glide of Shockley partial dislocations on every two {111} planes of the z-AlN.

  17. IBM Probes Material Capabilities at the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Researchers from IBM's forward-thinking Spintronic Science and Applications Center (SpinAps) recently used the ALS to gain greater insight into vanadium dioxide's unusual phase ...

  18. Al Turi Biomass Facility | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    NEEDS 2006 Database Retrieved from "http:en.openei.orgwindex.php?titleAlTuriBiomassFacility&oldid397128" Feedback Contact needs updating Image needs updating...

  19. Microsoft Word - AL2005-03.doc

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL 2005-03 Acquisition Regulation Date 100804 ACQUISITION LETTER This Acquisition Letter is issued under the authority of the DOE and NNSA Procurement Executives. Subject:...

  20. April 27, 2015-Special ALS Colloquium

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Years Janos Kirz, ALS Abstract Rntgen's great discovery became an instant public sensation. Fascination with the "new kind of rays" that could reveal the structure of opaque...

  1. Al Tayyar Energy | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: Al Tayyar Energy Place: Abu Dhabi, United Arab Emirates Sector: Renewable Energy Product: Provides development capital and equity investments...

  2. Microsoft Word - al2006-12.doc

    Energy.gov [DOE] (indexed site)

    AL-2006-12 (092906) 7 III. What Procedures Ensure Effective Audit Management? Some strategies for managing required audit activity include: 1. Contracting officers should...

  3. Crystallographic Consulting Brings Research to the ALS

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    of the participating research team (PRT) members at the Berkeley Center for Structural Biology (BCSB), which operates five ALS beamlines. As PRT members, companies are...

  4. Al Furat Petroleum Company | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Furat Petroleum Company Name: Al Furat Petroleum Company Place: Damascus, Syria Product: oil and hydrocarbon gas Year Founded: 1985 Phone Number: 00963-11- (6183333) Website:...

  5. Microsoft Word - Final MR AL.doc

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy No. AL 2009-01 Acquisition Regulation Date: 10062008 ACQUISITION ... Subject: Management Reserve and Contingency References: FAR Subpart 15.4 Contract Pricing ...

  6. Revision of Army regulation (AR) 200-2, environmental effects of Army actions, and the application of total quality mangement (TQM) principles

    SciTech Connect

    Merkel, H,K.; Robitaille, P.

    1995-12-01

    AR 200-2 is the Army`s implementing regulation to the National Environmental Policy Act (NEPA) and DoD`s NEPA Directive DoDD 6050.1. AR 200-2 was last revised in the late 1980s and since then the scope of Army NEPA compliance activities have significantly increased, and NEPA practice and case law are continually changing. The purpose of revising AR 200-2 is to provide Army personel with clear and Concise guidance on how to meet their NEPA compliance requirements. The revision process included reviewing the current AR 200-2 to identify areas and topics needing clarification or modification; conferring with Army NEPA personnel to obtain views on NEPA compliance practices and procedures; conducting a review and analysis of significant, recent developments in NEPA case law; reviewing other federal NEPA implementing regulations to identify useful, transferrable concepts; preparing a {open_quotes}strawman{close_quotes} version of AR 200-2 to use as a starting point in the revision process; coordinating and consolidating input from the AR 200-2 Revisions Steering Committee; and responding to review comments. A draft version of AR 200-2 has been completed and informal Army-wide comments have been addressed. Some of the issues that the AR 200-2 Revisions Steering Committee considered during the revision effort included expanding the list of categorical exclusions, determining the appropriate length for the public comment period for environmental assessments prior to approval of the finding of no significant impact, determining the appropriate level of analysis for Army actions abroad, and determining whether Comprehensive Environmental Response Compensation Liability Act (CERCLA) or Resource Conservation and Recovery Act (RCRA) actions should be addressed under NEPA. Total Quality Management (TQM) principles were applied during the revision process. GroupSystems{trademark} software was used as a vehicle to enhance total group participation from managers to practitioners.

  7. Fluorocarbon assisted atomic layer etching of SiO2 and Si using cyclic Ar/C4F8 and Ar/CHF3 plasma

    SciTech Connect

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L.; Joseph, Eric A.; Oehrlein, Gottlieb S.

    2015-11-11

    The need for atomic layer etching (ALE) is steadily increasing as smaller critical dimensions and pitches are required in device patterning. A flux-control based cyclic Ar/C4F8 ALE based on steady-state Ar plasma in conjunction with periodic, precise C4F8 injection and synchronized plasma-based low energy Ar+ ion bombardment has been established for SiO2.1 In this work, the cyclic process is further characterized and extended to ALE of silicon under similar process conditions. The use of CHF3 as a precursor is examined and compared to C4F8. CHF3 is shown to enable selective SiO2/Si etching using a fluorocarbon (FC) film build up. Other critical process parameters investigated are the FC film thickness deposited per cycle, the ion energy, and the etch step length. Etching behavior and mechanisms are studied using in situ real time ellipsometry and X-ray photoelectron spectroscopy. Silicon ALE shows less self-limitation than silicon oxide due to higher physical sputtering rates for the maximum ion energies used in this work, ranged from 20 to 30 eV. The surface chemistry is found to contain fluorinated silicon oxide during the etching of silicon. As a result, plasma parameters during ALE are studied using a Langmuir probe and establish the impact of precursor addition on plasma properties.

  8. AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT Acquisition Letters (AL)...

  9. AL2010-01.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1.pdf AL2010-01.pdf PDF icon AL2010-01.pdf More Documents & Publications G Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all sections.doc Microsoft Word - AL-Consolidated Approps...

  10. AL2007-09.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7-09.pdf AL2007-09.pdf PDF icon AL2007-09.pdf More Documents & Publications AL2007-04.pdf RL-2007OMCPIA.pdf AL2007-06.pdf...

  11. AL2007-04.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    4.pdf AL2007-04.pdf PDF icon AL2007-04.pdf More Documents & Publications Preliminary Notice of Violation, BWXT Y-12 LLC - EA-2007-04 AL2007-05.doc&0; AL2007-09...

  12. AL2007-06.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    6.pdf AL2007-06.pdf PDF icon AL2007-06.pdf More Documents & Publications AL2007-04.pdf AL2007-09.pdf RL-2007OMCPIA...

  13. Microsoft Word - AL2006-08.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    8.doc Microsoft Word - AL2006-08.doc PDF icon Microsoft Word - AL2006-08.doc More Documents & Publications AL2007-05.doc&0; Microsoft Word - AL2005-14.doc Microsoft Word - ...

  14. Microsoft Word - AL2005-03.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5-03.doc Microsoft Word - AL2005-03.doc PDF icon Microsoft Word - AL2005-03.doc More Documents & Publications Microsoft Word - AL2005-01.doc Microsoft Word - AL2006-08.doc ...

  15. Microsoft Word - AL2008-05.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Microsoft Word - AL2008-05.doc Microsoft Word - AL2008-05.doc Microsoft Word - AL2008-05.doc More Documents & Publications Microsoft Word - AL 2010-07 Acquistion Letters Remaining...

  16. Microsoft Word - al2005-04.doc | Department of Energy

    Energy Saver

    al2005-04.doc Microsoft Word - al2005-04.doc PDF icon Microsoft Word - al2005-04.doc More Documents & Publications AL2005-04ClassDeviation.pdf Microsoft Word - Matrixpart2.doc...

  17. Microsoft Word - AL2004-02.doc | Department of Energy

    Energy.gov [DOE] (indexed site)

    Microsoft Word - AL2004-02.doc More Documents & Publications Microsoft Word - AL2005-02.doc Microsoft Word - al2005-04.doc Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all...

  18. Microsoft Word - al2004-03.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    al2004-03.doc Microsoft Word - al2004-03.doc PDF icon Microsoft Word - al2004-03.doc More Documents & Publications Acquisition Letter: AL2005-08 OPAM Policy Acquisition Guides ...

  19. Microsoft Word - AL2005-10.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2005-10.doc Microsoft Word - AL2005-10.doc Microsoft Word - AL2005-10.doc (133.11 KB) More Documents & Publications Microsoft Word - AL2005-16.doc Audit Report: IG-0860 Microsoft ...

  20. Modeling of plasma chemistry in an atmospheric pressure Ar/NH{sub 3} cylindrical dielectric barrier discharge described using the one-dimensional fluid model

    SciTech Connect

    Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physical Science and Technical College, Dalian University, Dalian 116622 (China)

    2013-01-15

    The keynote of our research is to study the gas phase chemistry in an atmospheric pressure Ar/NH{sub 3} cylindrical dielectric barrier discharge, which is very important to produce the iron-nitride magnetic fluid. For this purpose, a home-made one dimensional fluid model with the Scharfetter-Gummel method has been developed. The equations solved are the particle balances, assuming a drift-diffusion approximation for the fluxes, and the electron energy equation. The self-consistent electric field is obtained by the simultaneous solution of Poisson's equation. The simulations were carried out for the different ammonia concentrations (2%, 3.5%, and 7%), at a voltage of 1 kV, and a driving frequency of 20 kHz. It concluded that the major ion products of Ar are Ar{sup +} and Ar{sub 2}{sup +}. Ar{sup +} is the most important positive ions, followed by Ar{sub 2}{sup +}. It is shown that the NH{sup +} density is smaller than that of the other ammonia ions. The density of NH{sub 4}{sup +} is more than that of the other ammonia ions when the ammonia concentration increased. The diffuse mode can be established after the discharge was ignited, and the mode changes to filamentary mode with an increase in ammonia concentration.

  1. sup 40 Ar/ sup 39 laser-probe dating by step heating and spot fusion of phengites from the Dora Maira nappe of the western Alps, Italy

    SciTech Connect

    Scaillet, S.; Feraud, G. ); Lagabrielle, Y. ); Ballevre, M.; Ruffet, G. )

    1990-08-01

    {sup 40}Ar/{sup 39}Ar laser-probe dating of phengitic micas has been carried out by step-heating and spot-fusion procedures. These micas represent successive deformation stages in the structural evolution of the internal Dora Maira nappe, western Alps. Single phengites from a gneiss affected by a single ductile strain under retrogressive conditions (sample 99.1) display complete isotopic resetting with nearly homogeneous intracrystalline Ar distribution and yield plateau ages of about 40 Ma. Small clusters of phengites from an earlier foliation were selected from a polydeformed mica schist (sample PTX3). They show a partial isotopic resetting in response to overprinting during the retrogressive deformation stage with a concentric age zoning from 68 Ma on the rim to 87 Ma in the core one cleavage plane. This zonation is fully consistent with the laser-derived discordant age spectrum, which ranges from 40 to 90 Ma from low to high temperatures. According to the deformation history of both samples, these preliminary data suggest a deformation control on Ar migration during recrystallization processes, and they are consistent with the timing of the collisional evolution previously reported for southern Dora Maira units. This study shows that the {sup 40}Ar/{sup 39}Ar continuous laser-probe dating technique produces data accurate enough to discriminate several tectonometamorphic episodes recorded in single hand samples.

  2. Ca and S K-edge XANES studies of calcite-acid mine water interactions

    SciTech Connect

    Myneni, S.C.B.; Perera, R.C.C.

    1997-04-01

    Heavy metal-rich acidic waters (SO{sub 4}{sup 2{minus}}, AsO{sub 4}{sup 3{minus}}, SeO{sub 4}{sup 2{minus}}, Fe{sup 2+}, Fe{sup 3+}, Al{sup 3+}, Cu{sup 2+}, Zn{sup 2+}, Cd{sup 2+}) and related ochreous coatings are common around abandoned sulfide and coal mine sites. This is mainly caused by the natural weathering of pyrite (FeS{sub 2}), arsenopyrite (FeAsS), and other metal sulfide containing shales. Acid generation in the case of pyrite can be explained by a general reaction: FeS{sub 2} + 3.5 O{sub 2} + H{sub 2}O {leftrightarrow} Fe{sup 2+} + SO{sub 4}{sup 2{minus}} + 2H{sup +}. Also, these low pH waters interact with the soils, and mobilize their soluble elements. One of the common remediation strategies is to allow these acid waters to react with limestone (CaCO{sub 3}-rich rock) and neutralize the pH and precipitate out soluble metals. Yet, the associated problem is the precipitation of Fe and Al oxides and hydroxy sulfate coatings on limestone surfaces, which block calcite reactive sites, and make them ineffective a few hours after initiation of treatment. The main objectives of this research are to examine: (1) the chemistry of limestone surface coatings, and (2) their toxic metal uptake and the conditions that inhibit their formation. Previous molecular studies using X-ray diffraction, and vibrational spectroscopy on limestone surface coatings (sampled from Athens, OH) indicate that the surface-most layer (the layer in contact with water) is composed of schwertmannite (Fe(III)-hydroxy sulfate) like phases. However, white, X-ray amorphous; Al-, sulfate- and carbonate-rich; and Ca-poor phases appeared at the interface between the limestone and the iron oxide coatings. The structure, morphology, and coordination chemistry of component major and trace elements of these white precipitate phases have not previously been examined.

  3. Silicon etch using SF{sub 6}/C{sub 4}F{sub 8}/Ar gas mixtures

    SciTech Connect

    Bates, Robert L.; Stephan Thamban, P. L.; Goeckner, Matthew J.; Overzet, Lawrence J.

    2014-07-01

    While plasmas using mixtures of SF{sub 6}, C{sub 4}F{sub 8}, and Ar are widely used in deep silicon etching, very few studies have linked the discharge parameters to etching results. The authors form such linkages in this report. The authors measured the optical emission intensities of lines from Ar, F, S, SF{sub x}, CF{sub 2}, C{sub 2}, C{sub 3}, and CS as a function of the percentage C{sub 4}F{sub 8} in the gas flow, the total gas flow rate, and the bias power. In addition, the ion current density and electron temperature were measured using a floating Langmuir probe. For comparison, trenches were etched of various widths and the trench profiles (etch depth, undercut) were measured. The addition of C{sub 4}F{sub 8} to an SF{sub 6}/Ar plasma acts to reduce the availability of F as well as increase the deposition of passivation film. Sulfur combines with carbon in the plasma efficiently to create a large optical emission of CS and suppress optical emissions from C{sub 2} and C{sub 3}. At low fractional flows of C{sub 4}F{sub 8}, the etch process appears to be controlled by the ion flux more so than by the F density. At large C{sub 4}F{sub 8} fractional flows, the etch process appears to be controlled more by the F density than by the ion flux or deposition rate of passivation film. CF{sub 2} and C{sub 2} do not appear to cause deposition from the plasma, but CS and other carbon containing molecules as well as ions do.

  4. Site Environmental Report for 2014 SNL/CA

    SciTech Connect

    Larsen, Barbara L.

    2015-06-01

    Sandia National Laboratories, California (SNL/CA) is a government-owned/contractoroperated laboratory. Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, manages and operates the laboratory for the Department of Energy’s National Nuclear Security Administration (NNSA). The NNSA Sandia Field Office administers the contract and oversees contractor operations at the site. This Site Environmental Report for 2014 was prepared in accordance with DOE Order 231.1B, Environment, Safety and Health Reporting (DOE 2011d). The report provides a summary of environmental monitoring information and compliance activities that occurred at SNL/CA during calendar year 2014. General site and environmental program information is also included.

  5. Response function of the magnetic spectrometer PRISMA for the multinucleon transfer reaction {sup 40}Ar+{sup 208}Pb

    SciTech Connect

    Mijatovic, T.; Szilner, S.; Corradi, L.; Courtin, S.; Farnea, E.; Fioretto, E.; Gadea, A.; Goasduff, A.; Haas, F.; Jelavic-Malenica, D.; Lunardi, S.; Mengoni, D.; Montagnoli, G.; Montanari, D.; Pollarolo, G.; Recchia, F.; Sahin, E.; Scarlassara, F.; Soic, N.; Stefanini, A. M.; and others

    2012-10-20

    Multinucleon transfer reaction {sup 40}Ar+{sup 208}Pb has been investigated with the PRISMA-CLARA experimental setup in LNL, INFN, Italy. The experimental differential cross sections have been obtained for different transfer channels by measuring more than {Delta}{theta}{sub lab} = 20 Degree-Sign covered by three angular settings of PRISMA. Results have been compared with the semiclassical calculation GRAZING. Since the understanding of the reaction mechanism depends strongly on the determination of absolute cross section, effect of transport of ions through PRISMA has been studied via a Monte Carlo simulation code.

  6. {sup 39}Ar Detection at the 10{sup -16} Isotopic Abundance Level with Atom Trap Trace Analysis

    SciTech Connect

    Jiang, W.; Williams, W.; Bailey, K.; O'Connor, T. P.; Mueller, P.; Davis, A. M.; Hu, S.-M.; Sun, Y. R.; Lu, Z.-T.; Purtschert, R.; Sturchio, N. C.

    2011-03-11

    Atom trap trace analysis, a laser-based atom counting method, has been applied to analyze atmospheric {sup 39}Ar (half-life=269 yr), a cosmogenic isotope with an isotopic abundance of 8x10{sup -16}. In addition to the superior selectivity demonstrated in this work, the counting rate and efficiency of atom trap trace analysis have been improved by 2 orders of magnitude over prior results. The significant applications of this new analytical capability lie in radioisotope dating of ice and water samples and in the development of dark matter detectors.

  7. Experimental investigations of electron density and ion energy distributions in dual-frequency capacitively coupled plasmas for Ar/CF{sub 4} and Ar/O{sub 2}/CF{sub 4} discharges

    SciTech Connect

    Liu, Jia; Liu, Yong-Xin; Gao, Fei; Wang, You-Nian, E-mail: ynwang@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Bi, Zhen-Hua [School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China)

    2014-01-07

    The electron density and ion energy distribution (IED) are investigated in low-pressure dual-frequency capacitively coupled Ar/CF{sub 4} (90%/10%) and Ar/O{sub 2}/CF{sub 4} (80%/10%/10%) plasmas. The relations between controllable parameters, such as high-frequency (HF) power, low-frequency (LF) power and gas pressure, and plasma parameters, such as electron density and IEDs, are studied in detail by utilizing a floating hairpin probe and an energy resolved quadrupole mass spectrometer, respectively. In our experiment, the electron density is mainly determined by the HF power and slightly influenced by the LF power. With increasing gas pressure, the electron density first goes up rapidly to a maximum value and then decreases at various HF and LF powers. The HF power also plays a considerable role in affecting the IEDs under certain conditions and the ion energy independently controlled by the LF source is discussed here. For clarity, some numerical results obtained from a two-dimensional fluid model are presented.

  8. Time-dependent quantum wave packet study of the Ar+H{sub 2}{sup +}{yields}ArH{sup +}+H reaction on a new ab initio potential energy surface for the ground electronic state (1{sup 2}A Prime )

    SciTech Connect

    Hu Mei; Liu Xinguo; Tan Ruishan; Li Hongzheng; Xu Wenwu

    2013-05-07

    A new global potential energy surface for the ground electronic state (1{sup 2}A Prime ) of the Ar+H{sub 2}{sup +}{yields}ArH{sup +}+H reaction has been constructed by multi-reference configuration interaction method with Davidson correction and a basis set of aug-cc-pVQZ. Using 6080 ab initio single-point energies of all the regions for the dynamics, a many-body expansion function form has been used to fit these points. The quantum reactive scattering dynamics calculations taking into account the Coriolis coupling (CC) were carried out on the new potential energy surface over a range of collision energies (0.03-1.0 eV). The reaction probabilities and integral cross sections for the title reaction were calculated. The significance of including the CC quantum scattering calculation has been revealed by the comparison between the CC and the centrifugal sudden approximation calculation. The calculated cross section is in agreement with the experimental result at collision energy 1.0 eV.

  9. DOE - Office of Legacy Management -- Burris Park Field Station - CA 10

    Office of Legacy Management (LM)

    Burris Park Field Station - CA 10 FUSRAP Considered Sites Site: Burris Park Field Station (CA.10 ) Post-closure maintenance is managed as an Other FUSRAP site. Designated Name: Burris Park, California, Site Alternate Name: Burris Park Field Station Location: Kingsburg , California CA.10-1 Evaluation Year: 1987 CA.10-2 Site Operations: The U.S Atomic Energy Commission contracted with the University of California to conduct experiments on decontamination of soils containing Strontium-90. CA.10-1

  10. Synthesis of BiPbSrCaCuO superconductor

    DOEpatents

    Hults, W.L.; Kubat-Martin, K.A.; Salazar, K.V.; Phillips, D.S.; Peterson, D.E.

    1994-04-05

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi[sub a]Pb[sub b]Sr[sub c]Ca[sub d]Cu[sub e]O[sub f] wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10[+-]z by reacting a mixture of Bi[sub 4]Sr[sub 3]Ca[sub 3]Cu[sub 4]O[sub 16[+-]z], an alkaline earth metal cuprate, e.g., Sr[sub 9]Ca[sub 5]Cu[sub 24]O[sub 41], and an alkaline earth metal plumbate, e.g., Ca[sub 2[minus]x]Sr[sub x]PbO[sub 4] wherein x is about 0.5, is disclosed.

  11. Synthesis of BiPbSrCaCuO superconductor

    DOEpatents

    Hults, William L.; Kubat-Martin, Kimberly A.; Salazar, Kenneth V.; Phillips, David S.; Peterson, Dean E.

    1994-01-01

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi.sub.a Pb.sub.b Sr.sub.c Ca.sub.d Cu.sub.e O.sub.f wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10.+-.z by reacting a mixture of Bi.sub.4 Sr.sub.3 Ca.sub.3 Cu.sub.4 O.sub.16.+-.z, an alkaline earth metal cuprate, e.g., Sr.sub.9 Ca.sub.5 Cu.sub.24 O.sub.41, and an alkaline earth metal plumbate, e.g., Ca.sub.2-x Sr.sub.x PbO.sub.4 wherein x is about 0.5, is disclosed.

  12. Otay Mesa, CA Liquefied Natural Gas Exports to Mexico (Million...

    Energy Information Administration (EIA) (indexed site)

    Million Cubic Feet) Otay Mesa, CA Liquefied Natural Gas Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 28.552 20.095 25.827 18.229 ...

  13. Ogilby, CA Natural Gas Pipeline Exports to Mexico (Million Cubic...

    Energy Information Administration (EIA) (indexed site)

    Million Cubic Feet) Ogilby, CA Natural Gas Pipeline Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,249 5,761 5,912 5,065 6,188 ...

  14. Proceedings of the sixth annual conference on fossil energy materials. Fossil Energy AR and TD Mateials Program

    SciTech Connect

    Cole, N.C.; Judkins, R.R.

    1992-07-01

    The Sixth Annual Conference on Fossil Energy Materials was held in Oak Ridge, Tennessee, on May 12--14, 1992. The meeting was sponsored by the US Department of Energy`s Office of Fossil Energy through the Advanced Research and Technology Development (AR&TD) Materials Program, and ASM International. The objective of the AR&TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The management of the Program has been decentralized to the DOE Field Office, Oak Ridge with Oak Ridge National Laboratory (ORNL) as the technical support contractor. The research is performed by staff members at ORNL and by a substantial number of researchers at other national laboratories, universities, and in private industry. The work is divided into the following categories: (1) ceramics, (2) development and corrosion resistance of iron aluminide, advanced austenitic and chromium-niobium alloys, and (3) technology assessment and technology transfer. This conference is held each year to review the work on all of the projects of the Program. The agenda for the meeting is given in Appendix A, and a list of attendees is presented in Appendix B. ASM International cosponsored the conference, for which we are especially grateful.

  15. Radioactive air emissions notice of construction use of a portable exhauster at 244-AR vault. Revision 2

    SciTech Connect

    Carrell, D.J.

    1997-12-17

    This document serves as a notice of construction (NOC), pursuant to the requirements of Washington Administrative Code (WAC) 246-247-060, and as a request for approval to construct, pursuant to 40 Code of Federal Regulations (CFR) 61.96, a portable exhauster at the 244-AR Vault. The exhauster would be used during air jetting of accumulated liquids from the cell sumps into the tanks and to make transfers among the tanks within the vault when needed. The 244-AR Vault is considered to be a double-contained receiver tank (OCRT) based on its functional characteristics, although it is not listed as one of the five designated DCRTs in the 200 Area Tank Farm systems. Process operations at the vault have been inactive since 1978 and the vault`s two stacks have not operated since 1993. Since cessation of vault operations an extremely large amount of rain water and snow melt have accumulated in the cell sumps. The water level in the sumps is substantially above their respective operating levels and there is concern for leakage to the environment through containment failure due to corrosion from backed-up sump liquid. Active ventilation is required to provide contamination control during air jetting operations within the vault. It has been determined that it would not be cost effective to repair the existing exhaust systems to an operational condition; thus, a portable exhauster will be used to support the intermittent operations.

  16. Development of the sputtering yields of ArF photoresist after the onset of argon ion bombardment

    SciTech Connect

    Takeuchi, Takuya; Ishikawa, Kenji; Kondo, Hiroki; Takeda, Keigo; Sekine, Makoto; Hori, Masaru; Corbella, Carles; Grosse-Kreul, Simon; Keudell, Achim von

    2013-01-07

    Modification of an advanced ArF excimer lithographic photoresist by 400 eV Ar ion irradiation was observed in situ in real time using both infrared spectroscopy and a quartz microbalance sensor. The photoresist sputtering yields had a characteristic behavior; the sputtering yields were higher than unity at the beginning, until an ion dose of 2 Multiplication-Sign 10{sup 16} ions cm{sup -2}. Thereafter, the yields decreased immediately to almost zero and remained constant with the yield at zero until a dose of approximately 4 Multiplication-Sign 10{sup 16} ions cm{sup -2} was reached. At larger doses, the yields increased again and reached a steady-state value of approximately 0.6. This development of the sputtering yield after the onset of ion bombardment is explained by an ion-induced modification of the photoresist that includes preferential sputtering of individual groups, argon ion implantation and the generation of voids. All these effects must be taken into account to assess line-edge-roughness on a photoresist subjected to highly energetic ion irradiation.

  17. Interfacial reactions in epitaxial Al/TiN(111) model diffusion barriers: Formation of an impervious self-limited wurtzite-structure AIN(0001) blocking layer

    SciTech Connect

    Chun, J.-S.; Desjardins, P.; Lavoie, C.; Shin, C.-S.; Cabral, C.; Petrov, I.; Greene, J. E.

    2001-06-15

    Single-crystal TiN(111) layers, 45 nm thick, were grown on MgO(111) by ultrahigh vacuum reactive magnetron sputter deposition in pure N{sub 2} discharges at T{sub s}=700{degree}C. Epitaxial Al(111) overlayers, 160 nm thick, were then deposited at T{sub s}=100{degree}C in Ar without breaking vacuum. Interfacial reactions and changes in bilayer microstructure due to annealing at 620 and 650{degree}C were investigated using x-ray diffraction and transmission electron microscopy (TEM). The interfacial regions of samples annealed at 620{degree}C consist of continuous {approx_equal}7-nm-thick epitaxial wurtzite-structure AlN(0001) layers containing a high density of stacking faults, with {approx_equal}22 nm thick tetragonal Al{sub 3}Ti(112) overlayers. Surprisingly, samples annealed at the higher temperature are more stable against Al{sub 3}Ti formation. TEM analyses of bilayers annealed at 650{degree}C (10{degree}C below the Al melting point!) reveal only the self-limited growth of an {approx_equal}3-nm-thick interfacial layer of perfect smooth epitaxial wurtzite-structure AlN(0001) which serves as an extremely effective deterrent for preventing further interlayer reactions. {copyright} 2001 American Institute of Physics.

  18. Thermodynamic studies of CaLaFe??O??(s)

    SciTech Connect

    Rakshit, S.K.; Parida, S.C.; Lilova, Kristina; Navrotsky, Alexandra

    2013-05-01

    Thermodynamic studies on CaLaFe??O??(s) were carried out using Knudsen effusion mass spectrometry and calorimetry, viz. differential scanning calorimetry and high temperature oxide melt solution calorimetry. Standard molar Gibbs free energy of formation (?{sub f}G?{sub m}), enthalpy of formation and heat capacity (C?{sub ?,m}) of the compound were calculated as a function of temperature for the first time. C?{sub ?,m}(CaLaFe??O??) was determined and used for second law analysis, from which enthalpy and entropy of formation of the compound were calculated and the respective values are: ?{sub f}H?{sub m}(298.15 K)/kJ mol?=-6057(8) and S?{sub m}(298.15 K)/J K? mol?=427(5). ?{sub f}H?{sub m}(298.15 K)/kJ mol?: -6055(6) was also calculated using oxide melt solution calorimetry, which is in close agreement with the second law value. A heat capacity anomaly was also observed at T=684 K. A table of thermodynamic data from 298.15 K to 1000 K for CaLaFe??O??(s) was also constructed to represent an optimized set of data. - graphical abstract: Variation of standard molar heat capacities of CaLaF??O??(s) and MFe??O??(s) (M=Sr, Ba and Pb) as a function of temperature. Highlights: Thermodynamic studies on CaLaFe??O??(s) were performed using KEQMS and solution calorimetry. It was synthesized using gel combustion route and characterized by XRD technique. The compound is magnetic in nature and shows a heat capacity anomaly at 684 K. Thermodynamic table was constructed from 298 K to 1000 K.

  19. Acquisition Letters (AL) Remaining in Effect | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    (AL) Remaining in Effect Acquisition Letters (AL) Remaining in Effect DATE: November 8, 2016 TO: Procurement Directors Heads of Contracting Activities FROM: Chief Contract and Financial Assistance Policy Division Office of Policy Office of Acquisition Management SUBJECT: Acquisition Letters (AL) Remaining in Effect SUMMARY: The attached AL identifies ALs currently in effect and discontinued ALs, along with the reason why an AL is discontinued. Questions concerning this policy flash should be

  20. Summary Slides of ALS Science Highlights

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Summary Slides of ALS Science Highlights Print No. Slide ... Vol. 356 294 Graphene's 3D Counterpart 10.0.1 ... 06.27.2007 Vol. 277 142 Laser-Seeded CSR 1.4.3 04.25.2007 ...

  1. ALS History: The First 20 Years

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    History: The First 20 Years Print Below is an interactive timeline covering highlights of the first 20 years of ALS history. By no means exhaustive, it is meant to provide a broad ...

  2. Summary Slides of ALS Industry Highlights

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Print No. Slide Beamline Full Web Highlight ALSNews Volume 17 Takeda Advances Diabetes Research at ALS 5.0.2, 5.0.3 06.02.2015 Vol. 364 16 Metrology for Next-Generation...

  3. Footprinting Technique Gives ALS Users New Insights

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    formation. The ALS XFP experts at Beamline 5.3.1. From left: Research Scientist Sayan Gupta, Beamline 5.3.1 Scientist Rich Celestre, and BCSB Head Corie Ralston. XFP, a powerful...

  4. Microsoft Word - Maeder et al.doc

    Office of Scientific and Technical Information (OSTI)

    ... molecular nitrogen (Bomar and Knoll 1985; Lobo and Zinder 1988). 73 They also adapt to ... Syst. Appl. Microbiol. 7: 293-299. 494 Lobo, A.L. and S.H. Zinder. 1988. Diazotrophy and ...

  5. Western Baldwin County, AL Grid Interconnection Project

    SciTech Connect

    Thomas DeBell

    2011-09-30

    The Objective of this Project was to provide an additional supply of electricity to the affected portions of Baldwin County, AL through the purchase, installation, and operation of certain substation equipment.

  6. ALS Reveals New State of Matter

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of...

  7. Al Husseini Amelio JV | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solar Product: JV company to develop a 1GW solar plant in Jordan and an integrated 200MW thin-film module factory. References: Al-Husseini & Amelio JV1 This article is a stub....

  8. Microsoft Word - AL2005-11.doc

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    appropriate reviews; and (5) ensure they pay only for what they negotiated. AL 2005-11 (071505) - 2 - Background DEAR 970.3102-3-70 DOE Policy is based on the assumption...

  9. Aromatic nitration with ion radical pairs (ArH/sup +/,NO/sub 2/) as reactive intermediates. Time-resolved studies of charge-transfer activation of dialkoxybenzenes

    SciTech Connect

    Sankararaman, S.; Haney, W.A.; Kochi, J.K.

    1987-08-19

    Aromatic nitrations carried out both under electrophilic conditions and by charge-transfer activation afford the same yields and isomer distributions of nitration products from a common series of aromatic ethers (ArH). Time-resolved spectroscopy establishes the charge-transfer nitration to proceed via the ion radical pair (ArH/sup +/,NO/sub 2/), generated by the deliberate excitation of the electron donor-acceptor or ..pi.. complex of the arene with C(NO/sub 2/)/sub 4/. Laser flash photolysis of the charge-transfer band defines the evolution of the arene cation radical ArH/sup +/ and allows its decay kinetics to be delineated in various solvents and with added salts. The internal trapping of ArH/sup +/ is examined in the substituted p-dimethoxybenzenes CH/sub 3/OC/sub 6/H/sub 4/OCH/sub 2/X with X = CO/sub 2/H, CO/sub 2//sup -/, CO/sub 2/Et, and CH/sub 2/OH as the pendant functional groups. The mechanistic relevance of the collapse of (ArH/sup +/, NO/sub 2/) to the Wheland intermediate is discussed in the context of electrophilic aromatic nitrations.

  10. 17th Annual ALS Users' Association Meeting

    SciTech Connect

    Robinson, Art; Tamura, Lori

    2004-11-29

    It's not exactly Russian roulette, but scheduling October events outdoors is not risk-free, even in usually sunny California. An overflow crowd of more than 400 registered users, ALS staff, and vendors enjoyed a full indoor program featuring science highlights and workshops spread over two and a half days from October 18 to October 20. However, a major storm, heralding the onset of the San Francisco Bay Area rainy season, posed a few weather challenges for the events on the ALS patio.

  11. Metastability in the MgAl2O4-Al2O3 System

    DOE PAGES [OSTI]

    Wilkerson, Dr. Kelley R.; Smith, Jeffrey D; Hemrick, James Gordon

    2014-01-01

    Aluminum oxide must take a spinel form ( -Al2O3) at elevated temperatures in order for extensive solid solution to form between MgAl2O4 and -Al2O3. The solvus line between MgAl2O4 and Al2O3 has been dened at 79.6 wt% Al2O3 at 1500C, 83.0 wt% Al2O3 at 1600C, and 86.5 wt% Al2O3 at 1700C. A metastable region has been dened at temperatures up to 1700C which could have signicant implications for material processing and properties. Additionally, initial processing could have major implications on nal chemistry. The spinel solid solution region has been extended to form an innite solid solution with Al2O3 at elevatedmore » temperatures. A minimum in melting at 1975C and a chemistry of 96 wt% Al2O3 rather than a eutectic is present, resulting in no eutectic crystal formation during solidication.« less

  12. Structural, magnetic, and superconducting properties of pulsed-laser-deposition-grown La1.85 Sr0.15 CuO4 / La2/3 Ca1/3 MnO3 superlattices on (001)-oriented LaSrAlO4 substrates

    SciTech Connect

    Das, S.; Sen, K.; Marozau, I.; Uribe-Laverde, M. A.; Biskup, N.; Varela, M.; Khaydukov, Y.; Soltwedel, O.; Keller, T.; Döbeli, M.; Schneider, C. W.; Bernhard, C.

    2014-03-12

    Epitaxial La1.85 Sr0.15 CuO4 / La2/3 Ca1/3 MnO3 (LSCO/LCMO) superlattices (SL) on (001)- oriented LaSrAlO4 substrates have been grown with pulsed laser deposition (PLD) technique. Their structural, magnetic and superconducting properties have been determined with in-situ reflection high energy electron diffraction (RHEED), x-ray diffraction, specular neutron reflectometry, scanning transmission electron microscopy (STEM), electric transport, and magnetization measurements. We find that despite the large mismatch between the in-plane lattice parameters of LSCO (a = 0.3779 nm) and LCMO (a = 0.387 nm) these superlattices can be grown epitaxially and with a high crystalline quality. While the first LSCO layer remains clamped to the LSAO substrate, a sizeable strain relaxation occurs already in the first LCMO layer. The following LSCO and LCMO layers adopt a nearly balanced state in which the tensile and compressive strain effects yield alternating in-plane lattice parameters with an almost constant average value. No major defects are observed in the LSCO layers, while a significant number of vertical antiphase boundaries are found in the LCMO layers. The LSCO layers remain superconducting with a relatively high superconducting onset temperature of Tconset ≈ 36 K. The macroscopic superconducting response is also evident in the magnetization data due to a weak diamagnetic signal below 10 K for H ∥ ab and a sizeable paramagnetic shift for H ∥ c that can be explained in terms of a vortex-pinning-induced flux compression. The LCMO layers maintain a

  13. Cathode encapsulation of organic light emitting diodes by atomic layer deposited Al{sub 2}O{sub 3} films and Al{sub 2}O{sub 3}/a-SiN{sub x}:H stacks

    SciTech Connect

    Keuning, W.; Weijer, P. van de; Lifka, H.; Kessels, W. M. M.; Creatore, M. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Philips Research Laboratories, High Tech Campus 4, P.O. Box WAG12, 5656 AE Eindhoven (Netherlands); Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2012-01-15

    Al{sub 2}O{sub 3} thin films synthesized by plasma-enhanced atomic layer deposition (ALD) at room temperature (25 deg. C) have been tested as water vapor permeation barriers for organic light emitting diode devices. Silicon nitride films (a-SiN{sub x}:H) deposited by plasma-enhanced chemical vapor deposition served as reference and were used to develop Al{sub 2}O{sub 3}/a-SiN{sub x}:H stacks. On the basis of Ca test measurements, a very low intrinsic water vapor transmission rate of {<=} 2 x 10{sup -6} g m{sup -2} day{sup -1} and 4 x 10{sup -6} g m{sup -2} day{sup -1} (20 deg. C/50% relative humidity) were found for 20-40 nm Al{sub 2}O{sub 3} and 300 nm a-SiN{sub x}:H films, respectively. The cathode particle coverage was a factor of 4 better for the Al{sub 2}O{sub 3} films compared to the a-SiN{sub x}:H films and an average of 0.12 defects per cm{sup 2} was obtained for a stack consisting of three barrier layers (Al{sub 2}O{sub 3}/a-SiN{sub x}:H/Al{sub 2}O{sub 3}).

  14. Modeling Precipitation and Sorption of Al, U and Co-contaminants during Titration of Acidic Sediments in Recirculation Flow-Through Experiments

    SciTech Connect

    Tang, Guoping; Luo, Wensui; Brooks, Scott C; Watson, David B; Gu, Baohua

    2013-01-01

    We conducted batch and recirculating column titration tests with contaminated acidic sediments with controlled CO2 in the headspace, and extended the geochemical model by Gu et al. (2003, GCA) to better understand and quantify the reactions governing trace metal fate in the subsurface. The sediment titration curve showed slow pH increase due to strong buffering by Al precipitation and CO2 uptake. Assuming precipitation of basaluminite at low saturation index (SI=-4), and decreasing cation exchange selectivity coefficient (kNa\\Al=0.3), the predictions are close to the observed pH and Al; and the model explains 1) the observed Ca, Mg, and Mn concentration decrease by cation exchange with sorbed Al, and 2) the decrease of U by surface complexation with Fe hydroxides at low pH, and precipitation as liebigite (Ca2UO2(CO3)3:10H2O) at pH>5.5. Without further adjustment geochemical parameters, the model describes reasonably well previous sediment and column titration tests without CO2 in the headspace, as well as the new large column test. The apparent inhibition of U and Ni decrease in the large column can be explained by formation of aqueous carbonate complexes and/or competition with carbonate for surface sites. These results indicated that ignoring labile solid phase Al would underestimate base requirement in titration of acidic aquifers.

  15. AL2000-10Attach.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2000-10Attach.pdf AL2000-10Attach.pdf PDF icon AL2000-10Attach.pdf More Documents & Publications AL2000-10R.pdf AL2004-01r2.pdf Consent Order, Fluor Federal Services - EA-2000-10...

  16. Microsoft Word - AL2003-04.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2003-04.doc Microsoft Word - AL2003-04.doc Microsoft Word - AL2003-04.doc (254.1 KB) More Documents & Publications AL2004-01r2.pdf City of Tulare Renewable Biogas Fuel Cell Project Microsoft Word - AL2006-08.doc

  17. Microsoft Word - AL2000-05.doc | Department of Energy

    Energy Saver

    .doc Microsoft Word - AL2000-05.doc PDF icon Microsoft Word - AL2000-05.doc More Documents & Publications al99-06.doc&0; Microsoft Word - AL2000-05Attachment.doc AL2004-01r2.pdf...

  18. Microsoft Word - al2005-06.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    al2005-06.doc Microsoft Word - al2005-06.doc Microsoft Word - al2005-06.doc (139.24 KB) More Documents & Publications Microsoft Word - AL2006-01.doc OPAM Policy Acquisition Guides Acquisition Letter: AL2005-08

  19. Microsoft Word - al2007-11.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    al2007-11.doc Microsoft Word - al2007-11.doc Microsoft Word - al2007-11.doc (62.82 KB) More Documents & Publications Acquisition Guide Chapter 19 Update Acquisition Letter: AL2005-08 Microsoft Word - al2004-03

  20. Ca(OH).sub.2 -treated ceramic microsphere

    DOEpatents

    Sugama, Toshifumi

    1990-01-01

    Geothermal wells with lost circulation problems are treated with a lightweight, high temperature (i.e. 350.degree. C.) cement slurry which incorporates pressure resistant hollow microspheres into the slurry wherein the spheres have been pretreated with an alkali compound such as Ca(OH).sub.2 for up to 20 hours and at 100.degree.-300.degree. C. Preferably, the alkali solution is a saturated aqueous solution and the treatment is for 10 hours.

  1. Ca(OH).sub.2 -treated ceramic microsphere

    DOEpatents

    Sugama, Toshifumi

    1989-01-01

    Geothermal wells with lost circulation problems are treated with a lightweight, high temperature (i.e. 350.degree. C.) cement slurry which incorporates pressure resistant hollow microspheres into the slurry wherein the spheres have been pretreated with an alkali compound such as Ca(OH).sub.2 for up to 20 hours and at 100.degree.-300.degree. C. Preferably, the alkali solution is a saturated aqueous solution and the treatment is for 10 hours.

  2. Ca(OH)[sub 2]-treated ceramic microsphere

    DOEpatents

    Sugama, Toshifumi.

    1989-04-18

    Geothermal wells with lost circulation problems are treated with a lightweight, high temperature (i.e. 350 C) cement slurry which incorporates pressure resistant hollow microspheres into the slurry wherein the spheres have been pretreated with an alkali compound such as Ca(OH)[sub 2] for up to 20 hours and at 100--300 C. Preferably, the alkali solution is a saturated aqueous solution and the treatment is for 10 hours. 2 figs.

  3. Ca(OH)[sub 2]-treated ceramic microsphere

    DOEpatents

    Sugama, Toshifumi.

    1990-06-26

    Geothermal wells with lost circulation problems are treated with a lightweight, high temperature (i.e. 350 C) cement slurry which incorporates pressure resistant hollow microspheres into the slurry wherein the spheres have been pretreated with an alkali compound such as Ca(OH)[sub 2] for up to 20 hours and at 100--300 C. Preferably, the alkali solution is a saturated aqueous solution and the treatment is for 10 hours. 2 figs.

  4. Concentration of Ca in blood of amateur runners using NAA

    SciTech Connect

    Kovacs, L.; Zamboni, C. B.; Metairon, S.; Nunes, L. A. S.; Lourenco, T. F.; Macedo, D. V.

    2013-05-06

    In this study the Ca levels were determined in amateur runners blood at LABEX (Laboratorio de Bioquimica do Exercicio - UNICAMP, Brazil), using Neutron Activation Analyses (NAA) technique. The range established at rest (162 - 410 mgL{sup -1}) when compared with control group (51 - 439 mgL{sup -1}) suggests that there is a dependency of these limits in the function of the adopted physical training.

  5. Role of CA Utility Programs in Addressing MELS

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Role of CA Utility Programs in addressing MELS Mangesh Basarkar, Emerging Technologies, PG&E DOE MELS Workshop Pacific Energy Center, San Francisco, June 3, 2016 OVERVIEW  Growing realization for utilities on the impact of miscellaneous electric loads (MELS) in buildings  Lot of ongoing data collection activities in support of products, programs and services for addressing MELS  Data collection activities primarily happens in the:  Emerging Technologies Programs  Codes and

  6. Fourier-transform microwave spectroscopy and determination of the three dimensional potential energy surface for ArCS

    SciTech Connect

    Niida, Chisato; Nakajima, Masakazu; Endo, Yasuki; Sumiyoshi, Yoshihiro; Ohshima, Yasuhiro; Kohguchi, Hiroshi

    2014-03-14

    Pure rotational transitions of the ArCS van der Waals complex have been observed by Fourier Transform Microwave (FTMW) and FTMW-millimeter wave double resonance spectroscopy. Rotational transitions of v{sub s} = 0, 1, and 2 were able to be observed for normal CS, together with those of C{sup 34}S in v{sub s} = 0, where v{sub s} stands for the quantum number of the CS stretching vibration. The observed transition frequencies were analyzed by a free rotor model Hamiltonian, where rovibrational energies were calculated as dynamical motions of the three nuclei on a three-dimensional potential energy surface, expressed by analytical functions with 57 parameters. Initial values for the potential parameters were obtained by high-level ab initio calculations. Fifteen parameters were adjusted among the 57 parameters to reproduce all the observed transition frequencies with the standard deviation of the fit to be 0.028 MHz.

  7. Observation of a periodic runaway in the reactive Ar/O{sub 2} high power impulse magnetron sputtering discharge

    SciTech Connect

    Shayestehaminzadeh, Seyedmohammad E-mail: shayesteh@mch.rwth-aachen.de; Arnalds, Unnar B.; Magnusson, Rögnvaldur L.; Olafsson, Sveinn

    2015-11-15

    This paper reports the observation of a periodic runaway of plasma to a higher density for the reactive discharge of the target material (Ti) with moderate sputter yield. Variable emission of secondary electrons, for the alternating transition of the target from metal mode to oxide mode, is understood to be the main reason for the runaway occurring periodically. Increasing the pulsing frequency can bring the target back to a metal (or suboxide) mode, and eliminate the periodic transition of the target. Therefore, a pulsing frequency interval is defined for the reactive Ar/O{sub 2} discharge in order to sustain the plasma in a runaway-free mode without exceeding the maximum power that the magnetron can tolerate.

  8. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  9. Mathematical simulation of the amplification of 1790-nm laser radiation in a nuclear-excited He Ar plasma containing nanoclusters of uranium compounds

    SciTech Connect

    Kosarev, V A; Kuznetsova, E E

    2014-02-28

    The possibility of applying dusty active media in nuclearpumped lasers has been considered. The amplification of 1790-nm radiation in a nuclear-excited dusty He Ar plasma is studied by mathematical simulation. The influence of nanoclusters on the component composition of the medium and the kinetics of the processes occurring in it is analysed using a specially developed kinetic model, including 72 components and more than 400 reactions. An analysis of the results indicates that amplification can in principle be implemented in an active laser He Ar medium containing 10-nm nanoclusters of metallic uranium and uranium dioxide. (lasers)

  10. AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT AL 2014-06 ACQUISITION LETTERS REMAINING IN EFFECT Acquisition Letters (AL) that remain in effect are identified below. All other...

  11. AL2001-04.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1-04.pdf AL2001-04.pdf PDF icon AL2001-04.pdf More Documents & Publications FAL2001-04.pdf FAL2001-03.pdf AL2001-01...

  12. AL2001-01.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1-01.pdf AL2001-01.pdf PDF icon AL2001-01.pdf More Documents & Publications FAL2001-03.pdf FAL2001-02.pdf AL2001-04...

  13. AL2006-05.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5.pdf AL2006-05.pdf PDF icon AL2006-05.pdf More Documents & Publications 2006 EMAB Recommendation Summary Microsoft Word - AL2006-08.doc DOEECRReport2006(2).pdf...

  14. Microsoft Word - AL2005-07.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7.doc Microsoft Word - AL2005-07.doc PDF icon Microsoft Word - AL2005-07.doc More Documents & Publications Microsoft Word - AL2006-07.doc OPAM Policy Acquisition Guides Initial ...

  15. Microsoft Word - al95-14.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    al95-14.doc Microsoft Word - al95-14.doc PDF icon Microsoft Word - al95-14.doc More Documents & Publications Cooperation with the New Independent States of the Former Soviet Union ...

  16. Microsoft Word - AL2005-01.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1.doc Microsoft Word - AL2005-01.doc PDF icon Microsoft Word - AL2005-01.doc More Documents & Publications Microsoft Word - AL2006-08.doc Acquisition Letter Archive listing ...

  17. Microsoft Word - AL2006-01.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1.doc Microsoft Word - AL2006-01.doc PDF icon Microsoft Word - AL2006-01.doc More Documents & Publications Microsoft Word - al2005-06.doc Chapter 19 - Small Business Programs OPAM...

  18. Microsoft Word - AL2005-16.doc | Department of Energy

    Office of Environmental Management (EM)

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  19. Microsoft Word - AL2000-01.doc | Department of Energy

    Office of Environmental Management (EM)

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  20. Microsoft Word - AL2005-02.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5-02.doc Microsoft Word - AL2005-02.doc PDF icon Microsoft Word - AL2005-02.doc More Documents & Publications Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all sections.doc...

  1. Microsoft Word - AL2002-03.doc | Department of Energy

    Office of Environmental Management (EM)

    2-03.doc Microsoft Word - AL2002-03.doc PDF icon Microsoft Word - AL2002-03.doc More Documents & Publications Microsoft Word - AL2005-01.doc Microsoft Word - FAL2004-01.doc...

  2. Microsoft Word - AL2008-06.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2008-06.doc Microsoft Word - AL2008-06.doc PDF icon Microsoft Word - AL2008-06.doc More Documents & Publications Chapter 9 - Contracting Qualifications Microsoft Word - PART...

  3. Microsoft Word - AL2006-02.doc | Department of Energy

    Energy Saver

    2.doc Microsoft Word - AL2006-02.doc PDF icon Microsoft Word - AL2006-02.doc More Documents & Publications Microsoft Word - AL2006-03.doc Archived Financial Assistance Letters...

  4. Microsoft Word - AL2006-03.doc | Department of Energy

    Energy Saver

    3.doc Microsoft Word - AL2006-03.doc PDF icon Microsoft Word - AL2006-03.doc More Documents & Publications Microsoft Word - AL2006-02.doc Archived Financial Assistance Letters...

  5. Microsoft Word - AL-ARRASafetyALREDO3 | Department of Energy

    Energy Saver

    ARRASafetyALREDO3 Microsoft Word - AL-ARRASafetyALREDO3 PDF icon Microsoft Word - AL-ARRASafetyALREDO3 More Documents & Publications Microsoft Word - AL-ARRASafetyALREDO3.doc...

  6. Microsoft Word - AL2005-14.doc | Department of Energy

    Office of Environmental Management (EM)

    4.doc Microsoft Word - AL2005-14.doc PDF icon Microsoft Word - AL2005-14.doc More Documents & Publications Microsoft Word - AL-Omnibus FY 2009 Apr 22 2009 all sections.doc...

  7. al99-06attachment.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    attachment.doc&0; al99-06attachment.doc&0; PDF icon al99-06attachment.doc&0; More Documents & Publications Microsoft Word - AL2000-05Attachment.doc Microsoft Word - NSRC...

  8. Microsoft Word - AL2006-11.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2006-11.doc Microsoft Word - AL2006-11.doc PDF icon Microsoft Word - AL2006-11.doc More Documents & Publications Subject: Cost and Price Analysis Subject: Cost and Price Analysis...

  9. Microsoft Word - AL2008-05.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL2008-05.doc Microsoft Word - AL2008-05.doc PDF icon Microsoft Word - AL2008-05.doc More Documents & Publications Acquisition Letters Remaining In Effect Acquisition Letters ...

  10. G I E Al Wahdoui | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    I E Al Wahdoui Jump to: navigation, search Name: G.I.E. Al Wahdoui Place: Morocco Zip: BP 131 Sector: Solar Product: GIE Al Wahdoui is developing a solar project in Plage, Morocco....

  11. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE PAGES [OSTI]

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore » diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  12. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE PAGES [OSTI]

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  13. Acquisition Letter No. AL-2017-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7-01 Acquisition Letter No. AL-2017-01 DATE: November 8, 2016 TO: Procurement Directors Heads of Contracting Activities FROM: Chief Contract and Financial Assistance Policy Division Office of Policy Office of Acquisition Management SUBJECT: Acquisition Letters (AL) Remaining in Effect SUMMARY: The attached AL identifies ALs currently in effect and discontinued ALs, along with the reason why an AL is discontinued. Questions concerning this policy flash should be directed to Mike Dombrowski at

  14. (Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor

    SciTech Connect

    Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C.; Han, W.; Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J.; Ning, F. L.; Munsie, T. J. S.; Medina, T.; Luke, G. M.; Carlo, J. P.; Munevar, J.; Zhang, G. M.; Jin, C. Q.

    2014-10-28

    Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?

  15. DOE Zero Energy Ready Home Case Study: KB Home, Lancaster, CA...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Dorado Hill, CA DOE Zero Energy Ready Home Case Study: KB Home, San Marcos, CA, Production Home DOE Zero Energy Ready Home Case Study: Palo Duro Homes, Via del Cielo, Santa Fe, NM

  16. File:08-CA-b - CAISO Interconnection Request Process.pdf | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    8-CA-b - CAISO Interconnection Request Process.pdf Jump to: navigation, search File File history File usage Metadata File:08-CA-b - CAISO Interconnection Request Process.pdf Size...

  17. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation...

    Office of Scientific and Technical Information (OSTI)

    Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex ...

  18. File:08-CA-d - CPCN for Transmission Projects (2).pdf | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

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  19. File:08-CA-f - Permit to Construct.pdf | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

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  20. File:07-CA-e - BLM-CEC Joint Siting Process.pdf | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    07-CA-e - BLM-CEC Joint Siting Process.pdf Jump to: navigation, search File File history File usage Metadata File:07-CA-e - BLM-CEC Joint Siting Process.pdf Size of this preview:...

  1. Acquisitlon Letter No. AL 2008-06 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AL 2008-06 Acquisitlon Letter No. AL 2008-06 Subject: Domestic and Foreign Procurement Preference Requirements References: FAR Part 25 - Foreign Acquisition DEAR Part 925 - Foreign ...

  2. Field Mapping At Chena Geothermal Area (Waring, Et Al., 1917...

    OpenEI (Open Energy Information) [EERE & EIA]

    Waring, Et Al., 1917) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Chena Geothermal Area (Waring, Et Al., 1917) Exploration...

  3. Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) | Open...

    OpenEI (Open Energy Information) [EERE & EIA]

    Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Radiometrics At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity...

  4. Observation Wells At Lightning Dock Area (Warpinski, Et Al.,...

    OpenEI (Open Energy Information) [EERE & EIA]

    Area (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Observation Wells At Lightning Dock Area (Warpinski, Et Al., 2004)...

  5. ALS "Workhorse" Endstation Retires after 22 Years of Service

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    "Workhorse" Endstation Retires after 22 Years of Service ALS "Workhorse" Endstation Retires after 22 Years of Service Print Following a career spanning over two decades, ALS ...

  6. Acquisition Letter No. AL 2012-05 | Department of Energy

    Energy.gov [DOE] (indexed site)

    and Project Management SUBJECT: Reissuance of Acquisition Letter on Meal Costs in Management and Operation Contracts SUMMARY: This AL is a reissuance (under the new AL...

  7. Microsoft Word - AL2005-12.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    PDF icon Microsoft Word - AL2005-12.doc More Documents & Publications Microsoft Word - AL2005-11.doc OPAM Policy Acquisition Guides Chapter 31 - Contract Cost Principles...

  8. Moore Foundation Funds ALS Researchers for Promising New Technique...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Moore Foundation Funds ALS Researchers for Promising New Technique for Studying Materials Moore Foundation Funds ALS Researchers for Promising New Technique for Studying Materials...

  9. Fluid Inclusion Analysis At Geysers Area (Moore, Et Al., 2001...

    OpenEI (Open Energy Information) [EERE & EIA]

    Area (Moore, Et Al., 2001) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Fluid Inclusion Analysis At Geysers Area (Moore, Et Al., 2001)...

  10. Field Mapping At Dixie Valley Geothermal Area (Smith, Et Al....

    OpenEI (Open Energy Information) [EERE & EIA]

    Smith, Et Al., 2001) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Dixie Valley Geothermal Area (Smith, Et Al., 2001)...

  11. Microsoft Word - al2006-12.doc | Department of Energy

    Energy.gov [DOE] (indexed site)

    Microsoft Word - al2006-12.doc More Documents & Publications Acquisition Letter No. AL 2008-02 Department of Energy Special Report: DOEIG-0934...

  12. The mechanical properties of FeAl

    SciTech Connect

    Baker, I.; George, E.P.

    1996-12-31

    Only in the last few years has progress been made in obtaining reproducible mechanical properties data for FeAl. Two sets of observations are the foundation of this progress. The first is that the large vacancy concentrations that exist in FeAl at high temperature are easily retained at low temperature and that these strongly affect the low-temperature mechanical properties. The second is that RT ductility is adversely affected by water vapor. Purpose of this paper is not to present a comprehensive overview of the mechanical properties of FeAl but rather to highlight our understanding of key phenomena and to show how an understanding of the factors which control the yield strength and fracture behavior has followed the discovery of the above two effects. 87 refs, 9 figs.

  13. High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O

    DOEpatents

    Ginley, David S.; Hietala, Vincent M.; Hohenwarter, Gert K. G.; Martens, Jon S.; Plut, Thomas A.; Tigges, Chris P.; Vawter, Gregory A.; Zipperian, Thomas E.

    1994-10-25

    A process for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO.sub.3 crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O.sub.3, followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry.

  14. High temperature superconductor step-edge Josephson junctions using Ti-Ca-Ba-Cu-O

    DOEpatents

    Ginley, D.S.; Hietala, V.M.; Hohenwarter, G.K.G.; Martens, J.S.; Plut, T.A.; Tigges, C.P.; Vawter, G.A.; Zipperian, T.E.

    1994-10-25

    A process is disclosed for formulating non-hysteretic and hysteretic Josephson junctions using HTS materials which results in junctions having the ability to operate at high temperatures while maintaining high uniformity and quality. The non-hysteretic Josephson junction is formed by step-etching a LaAlO[sub 3] crystal substrate and then depositing a thin film of TlCaBaCuO on the substrate, covering the step, and forming a grain boundary at the step and a subsequent Josephson junction. Once the non-hysteretic junction is formed the next step to form the hysteretic Josephson junction is to add capacitance to the system. In the current embodiment, this is accomplished by adding a thin dielectric layer, LaA1O[sub 3], followed by a cap layer of a normal metal where the cap layer is formed by first depositing a thin layer of titanium (Ti) followed by a layer of gold (Au). The dielectric layer and the normal metal cap are patterned to the desired geometry. 8 figs.

  15. Assessment of LED Technology in Ornamental Post-Top Luminaires. Sacramento, CA

    SciTech Connect

    Tuenge, J. R.; Bryan, M. M.; Bisbee, D. A.

    2011-12-01

    GATEWAY program report on a demonstration of LED ornamental post-top luminaires in a residential part of Sacramento, CA.

  16. EIS-0455: Genesis Solar Energy Project in Riverside County, CA | Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    of Energy 5: Genesis Solar Energy Project in Riverside County, CA EIS-0455: Genesis Solar Energy Project in Riverside County, CA December 17, 2010 EIS-0455: Notice of Adoption of an Environmental Impact Statement Genesis Solar Energy Project, Riverside County, CA August 27, 2010 EIS-0455: Final Environmental Impact Statement Genesis Solar Energy Project, Riverside County, CA September 1, 2011 EIS-0455: Record of Decision Genesis Solar Energy Project, Riverside County, California

  17. GA-AL-SC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    GA-AL-SC GA-AL-SC October 1, 2012 ALA-1-N Wholesale Power Rate Schedule Area: PowerSouth Energy Cooperative System: Georgia-Alabama-South Carolina October 1, 2012 Duke-1-E Wholesale Power Rate Schedule Area: Duke On-System System: Georgia-Alabama-South Carolina October 1, 2012 Duke-2-E Wholesale Power Rate Schedule Area: Central System: Georgia-Alabama-South Carolina October 1, 2012 Duke-3-E Wholesale Power Rate Schedule Area: None System: Georgia-Alabama-South Carolina October 1, 2012 Duke-4-E

  18. Electronic circuits having NiAl and Ni.sub.3 Al substrates

    DOEpatents

    Deevi, Seetharama C.; Sikka, Vinod K.

    1999-01-01

    An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  19. Alloy inhomogeneity and carrier localization in AlGaN sections and AlGaN/AlN nanodisks in nanowires with 240350?nm emission

    SciTech Connect

    Himwas, C.; Hertog, M. den; Dang, Le Si; Songmuang, R.; Monroy, E.

    2014-12-15

    We present structural and optical studies of AlGaN sections and AlGaN/AlN nanodisks (NDs) in nanowires grown by plasma-assisted molecular beam epitaxy. The Al-Ga intermixing at Al(Ga)N/GaN interfaces and the chemical inhomogeneity in AlGaN NDs evidenced by scanning transmission electron microscopy are attributed to the strain relaxation process. This interpretation is supported by the three-dimensional strain distribution calculated by minimizing the elastic energy in the structure. The alloy inhomogeneity increases with the Al content, leading to enhanced carrier localization signatures in the luminescence characteristics, i.e., red shift of the emission, s-shaped temperature dependence, and linewidth broadening. Despite these effects, the emission energy of AlGaN/AlN NDs can be tuned in the 240350?nm range with internal quantum efficiencies around 30%.

  20. Anorthite sputtering by H+ and Arq+ (q = 1-9) at solar wind velocities

    SciTech Connect

    Hijazi, Hussein Dib; Bannister, Mark E.; Meyer, III, Harry M.; Rouleau, Christopher M.; Barghouty, A. F.; Rickman, D. L.; Meyer, Fred W.

    2014-10-16

    Here, we report sputtering measurements of anorthite-like material, taken to be representative of soils found in the lunar highlands, impacted by singly and multicharged ions representative of the solar wind. The ions investigated include protons, as well as singly and multicharged Ar ions (as proxies for the nonreactive heavy solar wind constituents), in the charge state range +1 to +9, at fixed solar wind-relevant impact velocities of 165 and 310 km/s (0.25 keV/amu and 0.5 keV/amu). A quartz microbalance approach (QCM) for determination of total sputtering yields was used. The goal of the measurements was to determine the sputtering contribution of the heavy, multicharged minority solar wind constituents in comparison to that due to the dominant H+ fraction. The QCM results show a yield increase of a factor of about 80 for Ar+ versus H+ sputtering and an enhancement by a factor of 1.67 between Ar9+ and Ar+, which is a clear indication of a potential sputtering effect.

  1. Comment on ``Effect of electron temperature on negative hydrogen ion production in a low-pressure Ar discharge plasma with methane`` [Appl. Phys. Lett. 63, 1619 (1993)

    SciTech Connect

    Pinnaduwage, L.A. |

    1995-08-14

    The author proposes a mechanism for the efficient production of negative Hydrogen ions in a low{minus}pressure Ar discharge plasma with methane using a novel pin{minus}hollow cathode as reported in Appl. Phys. Lett. 63, 1619 (1993). (AIP) {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

  2. Ternary Dy-Er-Al magnetic refrigerants

    DOEpatents

    Gschneidner, Jr., Karl A.; Takeya, Hiroyuki

    1995-07-25

    A ternary magnetic refrigerant material comprising (Dy.sub.1-x Er.sub.x)Al.sub.2 for a magnetic refrigerator using the Joule-Brayton thermodynamic cycle spanning a temperature range from about 60K to about 10K, which can be adjusted by changing the Dy to Er ratio of the refrigerant.

  3. Ternary Dy-Er-Al magnetic refrigerants

    DOEpatents

    Gschneidner, K.A. Jr.; Takeya, Hiroyuki

    1995-07-25

    A ternary magnetic refrigerant material comprising (Dy{sub 1{minus}x}Er{sub x})Al{sub 2} for a magnetic refrigerator using the Joule-Brayton thermodynamic cycle spanning a temperature range from about 60K to about 10K, which can be adjusted by changing the Dy to Er ratio of the refrigerant. 29 figs.

  4. Fuel Cell Power Plants Biofuel Case Study - Tulare, CA

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    clean Fuel Cell Power Plants Biofuel Case Study - Tulare, CA DOE-NREL Workshop Golden, CO June 11-13, 2012 FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. Integrated Fuel Cell Company 2 Manufacture Sell (direct & via partners) Install Services 1.4 MW plant at a municipal building 2.4 MW plant owned by an Independent power producer 600 kW plant at a food processor 11.2 MW plant - largest fuel cell park

  5. ,"CA, State Offshore Proved Nonproducing Reserves"

    Energy Information Administration (EIA) (indexed site)

    Proved Nonproducing Reserves" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","CA, State Offshore Proved Nonproducing Reserves",5,"Annual",2014,"6/30/1996" ,"Release Date:","11/19/2015" ,"Next Release Date:","12/31/2016" ,"Excel File

  6. Otay Mesa, CA Liquefied Natural Gas Exports (Million Cubic Feet)

    Energy Information Administration (EIA) (indexed site)

    (Million Cubic Feet) Otay Mesa, CA Liquefied Natural Gas Exports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 3 5 2014 6 7 7 8 7 7 9 8 9 8 9 6 2015 8 7 8 8 8 9 9 7 7 7 5 5 2016 6 8 7 6 7 6 5 5 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 10/31/2016 Next Release Date: 11/30/2016 Referring Pages: U.S.

  7. Hazardous Waste Generator Training (AL-073) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Hazardous Waste Generator Training (AL-073) Event Type: Training Date: 11/17/2016 - 14

  8. Hoisting & Rigging (AL-014) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Hoisting & Rigging (AL-014) Event Type: Training Date: 11/09/2016 - 11

  9. AL2007-02.doc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    7-02.doc&#0; AL2007-02.doc&#0; AL2007-02.doc&#0; (19.72 KB) More Documents & Publications Department of Energy Acquisition Letter 2013-04 on Executive Compensation Acquisition Letter No. AL 2013-04 Acquisition Letter No. AL 2014-07

  10. Al2000-12.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Al2000-12.pdf Al2000-12.pdf PDF icon Al2000-12.pdf More Documents & Publications AL2007-02.doc&0; Audit Report: OAS-L-07-17 Audit Report: OAS-L-07-18...

  11. Aerial Lift Training (AL-179) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Aerial Lift Training (AL-179) Event Type: Training Date: 11/09

  12. General Employee Training (AL-001) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    General Employee Training (AL-001) Event Type: Training Date: 11/08/2016 - 09

  13. Spill Prevention, Control & Countermeasures (AL-218) | The Ames Laboratory

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Spill Prevention, Control & Countermeasures (AL-218) Event Type: Training Date: 11/08/2016 - 10

  14. A limited role for carbonic anhydrase in C4 photosynthesis as revealed by a ca1ca2 double mutant in maize.

    DOE PAGES [OSTI]

    Studer, Anthony J.; Gandin, Anthony; Kolbe, Allison R.; Wang, Lin; Cousins, Asaph B.; Brutnell, Thomas P.

    2014-04-04

    Carbonic anhydrase (CA) catalyzes the first biochemical step of the carbon concentrating mechanism of C4 plants, and in C4 monocots, it has been suggested that CA activity is near limiting for photosynthesis. Here, we test this hypothesis through the characterization of transposon induced mutant alleles of Ca1 and Ca2 in Zea mays. In addition, these two isoforms account for more than 85% of the CA transcript pool. A significant change in isotopic discrimination is observed in mutant plants, which have as little as 3% of wild-type CA activity, but surprisingly, photosynthesis is not reduced under current or elevated pCO2. However,more » growth and rates of photosynthesis under sub-ambient pCO2 are significantly impaired in the mutants. These findings suggest, that while CA is not limiting for C4 photosynthesis in Z. mays at current pCO2, it likely maintains high rates of photosynthesis when CO2 availability is reduced. Current atmospheric CO2 levels now exceed 400 ppm (~40.53 Pa) and contrast the low CO2 partial pressure (pCO2) conditions under which C4 plants expanded their range ~10 million years ago when the global atmospheric CO2 was below 300 ppm (~30.40 Pa). Thus, as CO2 levels continue to rise, selective pressures for high levels of CA may be limited to arid climates where stomatal closure reduces CO2 availability to the leaf.« less

  15. Indirect synthesis of Al{sub 2}O{sub 3}via radiation- or photochemical formation of its hydrated precursors

    SciTech Connect

    Barta, Jan Pospisil, Milan; Cuba, Vaclav

    2014-01-01

    Graphical abstract: - Highlights: Al{sub 2}O{sub 3} precursors were produced by UV/e-beam irradiation of aqueous solutions. Depending on the aluminium salt (Cl{sup ?} or NO{sub 3}{sup ?}), either ?-AlOOH or Al(OH){sub 3} is formed. The mechanism involved strongly depends on the presence of formate anion. Prepared mesoporous solid phase has high specific surface area (<190 m{sup 2} g{sup ?1}). Calcination of the precursor leads to the formation of ?-/?-, ?- and ?-Al{sub 2}O{sub 3}. - Abstract: ?-, ?- and ?-modifications of aluminium oxide (alumina) were successfully prepared by calcination of precursor solid phase obtained by irradiation of clear aqueous solutions by UV light or electron beam. For the precipitate to form, formate anion must be present in the solution in sufficient concentration. According to X-ray diffraction, the precipitate was found to consist of ?-AlOOH or a mixture of ?- and ?-Al(OH){sub 3}, when aluminium chloride or aluminium nitrate was used, respectively. The addition of hydrogen peroxide as a OH radical source and sensitizer markedly improved the efficiency of the preparation. Some hints for the apparently very complex mechanism involved were listed and discussed. Calcination of the dried precipitate at 500800 C produced highly porous ?-alumina with high specific surface area (ca. 150 m{sup 2} g{sup ?1}). Mixture of ?- and ?-transition aluminas was obtained at 1000 C and pure, stable corundum ?-Al{sub 2}O{sub 3} formed at 1200 C. Samples were further investigated by means of scanning electron microscopy and specific surface area or porosity measurement. According to N{sub 2} adsorption isotherm, the precipitate contains mostly mesopores with average pore size 7 nm with specific surface area of ca. 100 m{sup 2} g{sup ?1}. Possible applications of the material as sorbent or catalyst as well as a pure matrix for thermoluminescence dosimetry were briefly contemplated. Strong light-induced thermoluminescence was observed in both

  16. Acquisition Letters No. AL 2013-05 | Department of Energy

    Energy Saver

    7 Acquisition Letter No. AL 2015-07 DATE: July 07, 2015 TO: Procurement Directors/Contracting Officers FROM: Director Contract and Financial Assistance Policy Division Office of Policy Office of Acquisition Management SUBJECT: Acquisition Letter No. AL 2015-07, Performance of Inherently Governmental and Critical Functions SUMMARY: Attached is revised Acquisition Letter (AL) No. AL 2015-07, Performance of Inherently Governmental and Critical Functions, dated July 07, 2015. This AL provides

  17. Theoretical investigation of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe)

    SciTech Connect

    Gao, Kunqi; Sheng, Li

    2015-04-14

    The equilibrium geometries, harmonic frequencies, and dissociation energies of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe) were investigated using the following method: Becke-3-parameter-Lee-Yang-Parr (B3LYP), Boese-Matrin for Kinetics (BMK), second-order Mller-Plesset perturbation theory (MP2), and coupled-cluster with single and double excitations as well as perturbative inclusion of triples (CCSD(T)). The results indicate that HHeNH{sub 3}{sup +}, HArNH{sub 3}{sup +}, HKrNH{sub 3}{sup +}, and HXeNH{sub 3}{sup +} ions are metastable species that are protected from decomposition by high energy barriers, whereas the HNeNH{sub 3}{sup +} ion is unstable because of its relatively small energy barrier for decomposition. The bonding nature of noble-gas atoms in HNgNH{sub 3}{sup +} was also analyzed using the atoms in molecules approach, natural energy decomposition analysis, and natural bond orbital analysis.

  18. Characteristics of oligosaccharides from rat parotid (RP) N-linked glycoproteins (GP) after. beta. -adrenoreceptor (. beta. -AR) stimulation

    SciTech Connect

    Baum, B.J.; Yeh, C.K.; Kousvelari, E.E.

    1987-05-01

    The authors have shown that ..beta..-AR stimulation of RP cells leads to marked enhancement of N-linked glycosylation in 4 secretory GP (Mrapprox.220Kd, HMW;approx.32-38Kd, MMW;approx.17Kd, LMW). To characterize oligosaccharides in GP, cells were incubated 60 min +/- isoproterenol (ISO) and analyzed 2 ways. First, cell extracts were subjected to SDS-PAGE and Western blotting with peroxidase-conjugated Con A or wheat germ agglutinin (WGA). Second, double-labeled (/sup 3/H) man//sup 14/C leu) extracts were chromatographed on G200 followed by analysis of GP on Con A-Sepharose. HMW from control (CON) and ISO cells were Endo H insensitive, Endo F sensitive, altered by incubation with deoxynojirimycin (dNM), and bound both Con A and WGA conjugates. Similar findings were observed with LMW while MMW were sensitive to Endo H and Endo F, unaffected by dNM, bound Con A (strongly) and WGA (weakly). MMW and LMW were primarily eluted from Con A-Sepharose with 0.5M ..cap alpha..-methyl mannoside (..cap alpha..-MM) while HMW were eluted sequentially with 10 mM ..cap alpha..-methyl glucoside and ..cap alpha..-MM. HMW, MMW, and LMW had approx.4 fold higher /sup 3/H//sup 14/C ratios after ISO. These results suggest HMW and LMW likely contain biantennary complex and hybrid oligosaccharides while MMW contain only high mannose oligosaccharide types.

  19. Reversal of the asymmetry in a cylindrical coaxial capacitively coupled Ar/Cl2 plasma

    SciTech Connect

    Upadhyay, Janardan; Im, Do; Popović, Svetozar; Vušković, Leposava; Valente-Feliciano, Anne -Marie; Phillips, Larry

    2015-10-08

    The reduction of the asymmetry in the plasma sheath voltages of a cylindrical coaxial capacitively coupled plasma is crucial for efficient surface modification of the inner surfaces of concave three-dimensional structures, including superconducting radio frequency cavities. One critical asymmetry effect is the negative dc self-bias, formed across the inner electrode plasma sheath due to its lower surface area compared to the outer electrode. The effect on the self-bias potential with the surface enhancement by geometric modification on the inner electrode structure is studied. The shapes of the inner electrodes are chosen as cylindrical tube, large and small pitch bellows, and disc-loaded corrugated structure (DLCS). The dc self-bias measurements for all these shapes were taken at different process parameters in Ar/Cl2 discharge. Lastly, the reversal of the negative dc self-bias potential to become positive for a DLCS inner electrode was observed and the best etch rate is achieved due to the reduction in plasma asymmetry.

  20. Complete direct sequencing of the entire AR gene in 45 unrelated patients with androgen insensitivity syndrome: Mutations identified in 32 patients (18 novel mutations), no mutation detected in 13 other patients (29%)

    SciTech Connect

    Mebarki, F.; Forest, M.G.; Josso, N.

    1994-09-01

    The androgen insensivity syndrome (AIS) is a recessive X-linked disorder resulting from a deficient function of the androgen receptor (AR). The human AR gene has 3 functional domains: N-terminal encoded by exon 1, DNA-binding domain encoded by exons 2 and 3, and androgen-binding domain encoded by exons 4 to 8. In order to characterize the molecular defects of the AR gene in AIS, the entire coding regions and the intronic bording sequences of the AR gene were amplified by PCR before automatic direct sequencing in 45 patients. Twenty seven different point mutations were found in 32 unrelated AIS patients: 18 with a complete form (CAIS), 14 with a partial form (PAIS); 18 of these mutations are novel mutations, not published to date. Only 3 mutations were repeatedly found: R804H in 3 families; M780I in 3 families and R774C in 2 families. For 26 patients out of the 32 found to have a mutation, maternal DNA was collected and sequenced: 6 de novo mutations were detected (i.e. 23% of the cases). Finally, no mutation was detected in 13 patients (29%): 7 with CAIS and 6 familial severe PAIS. The latter all presented with perineal hypospadias, micropenis, 4 out of 6 being raised as girl. Diagnosis of AIS in these 13 families in whom no mutation was detected is supported by the following criteria: clinical data, familial history (2 or 3 index cases in the same family), familial segregation of the polymorphic CAG repeat of the AR gene. Mutations in intronic regions or the promoter of the AR gene could not explain all cases of AIS without mutations in the AR coding regions, because AR binding (performed in 9 out of 13) was normal in 6, suggesting the synthesis of an AR protein. This situation led us to speculate that another X-linked factor associated with the AR could be implicated in some cases of AIS.

  1. Electronic transport through Al/InN nanowire/Al junctions (Journal...

    Office of Scientific and Technical Information (OSTI)

    Report Number(s): SAND2016-0883J Journal ID: ISSN 0003-6951; APPLAB; 619001 GrantContract Number: AC04-94AL85000 Type: Accepted Manuscript Journal Name: Applied Physics Letters ...

  2. The impact of argon admixture on the c-axis oriented growth of direct current magnetron sputtered Sc{sub x}Al{sub 1?x}N thin films

    SciTech Connect

    Mayrhofer, P. M.; Bittner, A.; Schmid, U.; Eisenmenger-Sittner, C.; Stger-Pollach, M.

    2014-05-21

    The piezoelectric properties of wurtzite aluminium nitride (w-AlN) are enhanced by alloying with scandium (Sc), thus offering superior properties for applications in micro electro-mechanical systems devices. Sc{sub x}Al{sub 1?x}N thin films have been prepared by DC reactive magnetron sputtering on Si (100) substrates from a single target. When targeting a concentration range from x?=?0 up to x?=?0.15, the preparation conditions have been optimized by varying the Ar/N{sub 2} ratio in the sputtering gas. To incorporate an increasing Sc concentration, a higher Ar/N{sub 2} ratio has to be applied during the deposition process. Hence, the argon concentration in the sputtering gas becomes a crucial parameter for microstructure-related parameters. To determine phase purity, degree of c-axis orientation, lattice parameter, and grain size, the Sc{sub x}Al{sub 1?x}N thin films were investigated by techniques, such as scanning electron microscopy, transmission electron microscopy, and X-ray diffraction.

  3. Ni{sub 3}Al technology transfer

    SciTech Connect

    Sikka, V.K.; Viswanathan, S.; Santella, M.L.

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  4. OP-AL-0002-001.PDF

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Doc. ID: OP-AL-0002-001.doc Caretaker Date: 2000/08/03 This authorized list is effective 08/03/2000 and specifies those individuals who have been authorized for Caretaker Operation 1. Aigeldinger, Georg 2. Bucher, Stephanie 3. Choi, Jaewu 4. Koch, Kevin 5. Lian, Kun 6. Ling, Zhong Geng 7. Manohara, Harish 8. Morikawa, Eizi 9. Palshin, Vadim 10. Rupp, Louis 11. Schoonmaker, Mike 12. Scott, John 13. Sprunger, Phil 14. Tittsworth, Roland 15. Xu, Jie Authorization: ________________ ________

  5. OP-AL-0003-001.PDF

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Doc. ID: OP-AL-0003-001.doc Accelerator Operators Date: 2000/08/03 This document is effective 08/4/2000 and specifies those individuals who are authorized to operate the Electron Accelerators at CAMD. 1. Ben Craft 2. Larry Oliszwesky 3. Paul Jines 4. Don Patterson 5. Yongzhang Huang Authorization: ____________________ ________ ____________________ ________ F. Josef Hormes Date Benjamin Craft III Date ____________________ ________ Lorraine Marceau-Day

  6. Smoothing single-crystalline SiC surfaces by reactive ion etching using pure NF{sub 3} and NF{sub 3}/Ar mixture gas plasmas

    SciTech Connect

    Tasaka, Akimasa; Kotaka, Yuki; Oda, Atsushi; Saito, Morihiro; Tojo, Tetsuro; Inaba, Minoru

    2014-09-01

    In pure NF{sub 3} plasma, the etching rates of four kinds of single-crystalline SiC wafer etched at NF{sub 3} pressure of 2 Pa were the highest and it decreased with an increase in NF{sub 3} pressure. On the other hand, they increased with an increase in radio frequency (RF) power and were the highest at RF power of 200 W. A smooth surface was obtained on the single-crystalline 4H-SiC after reactive ion etching at NF{sub 3}/Ar gas pressure of 2 Pa and addition of Ar to NF{sub 3} plasma increased the smoothness of SiC surface. Scanning electron microscopy observation revealed that the number of pillars decreased with an increase in the Ar-concentration in the NF{sub 3}/Ar mixture gas. The roughness factor (R{sub a}) values were decreased from 51.5 nm to 25.5 nm for the As-cut SiC, from 0.25 nm to 0.20 nm for the Epi-SiC, from 5.0 nm to 0.7 nm for the Si-face mirror-polished SiC, and from 0.20 nm to 0.16 nm for the C-face mirror-polished SiC by adding 60% Ar to the NF{sub 3} gas. Both the R{sub a} values of the Epi- and the C-face mirror-polished wafer surfaces etched using the NF{sub 3}/Ar (40:60) plasma were similar to that treated with mirror polishing, so-called the Catalyst-Referred Etching (CARE) method, with which the lowest roughness of surface was obtained among the chemical mirror polishing methods. Etching duration for smoothing the single-crystalline SiC surface using its treatment was one third of that with the CARE method.

  7. Nucleation of metastable aragonite CaCO3 in seawater

    DOE PAGES [OSTI]

    Sun, Wenhao; Jayaraman, Saivenkataraman; Chen, Wei; Persson, Kristin A.; Ceder, Gerbrand

    2015-03-04

    Predicting the conditions in which a compound adopts a metastable structure when it crystallizes out of solution is an unsolved and fundamental problem in materials synthesis, and one which, if understood and harnessed, could enable the rational design of synthesis pathways toward or away from metastable structures. Crystallization of metastable phases is particularly accessible via low-temperature solution-based routes, such as chimie douce and hydrothermal synthesis, but although the chemistry of the solution plays a crucial role in governing which polymorph forms, how it does so is poorly understood. Here, we demonstrate an ab initio technique to quantify thermodynamic parameters ofmoresurfaces and bulks in equilibrium with an aqueous environment, enabling the calculation of nucleation barriers of competing polymorphs as a function of solution chemistry, thereby predicting the solution conditions governing polymorph selection. We apply this approach to resolve the long-standing calcitearagonite problemthe observation that calcium carbonate precipitates as the metastable aragonite polymorph in marine environments, rather than the stable phase calcitewhich is of tremendous relevance to biomineralization, carbon sequestration, paleogeochemistry, and the vulnerability of marine life to ocean acidification. We identify a direct relationship between the calcite surface energy and solution MgCa ion concentrations, showing that the calcite nucleation barrier surpasses that of metastable aragonite in solutions with Mg:Ca ratios consistent with modern seawater, allowing aragonite to dominate the kinetics of nucleation. The ability to quantify how solution parameters distinguish between polymorphs marks an important step toward the ab initio prediction of materials synthesis pathways in solution.less

  8. Nucleation of metastable aragonite CaCO3 in seawater

    DOE PAGES [OSTI]

    Sun, Wenhao; Jayaraman, Saivenkataraman; Chen, Wei; Persson, Kristin A.; Ceder, Gerbrand

    2015-03-04

    Predicting the conditions in which a compound adopts a metastable structure when it crystallizes out of solution is an unsolved and fundamental problem in materials synthesis, and one which, if understood and harnessed, could enable the rational design of synthesis pathways toward or away from metastable structures. Crystallization of metastable phases is particularly accessible via low-temperature solution-based routes, such as chimie douce and hydrothermal synthesis, but although the chemistry of the solution plays a crucial role in governing which polymorph forms, how it does so is poorly understood. Here, we demonstrate an ab initio technique to quantify thermodynamic parameters ofmore » surfaces and bulks in equilibrium with an aqueous environment, enabling the calculation of nucleation barriers of competing polymorphs as a function of solution chemistry, thereby predicting the solution conditions governing polymorph selection. We apply this approach to resolve the long-standing “calcite–aragonite problem”––the observation that calcium carbonate precipitates as the metastable aragonite polymorph in marine environments, rather than the stable phase calcite––which is of tremendous relevance to biomineralization, carbon sequestration, paleogeochemistry, and the vulnerability of marine life to ocean acidification. We identify a direct relationship between the calcite surface energy and solution Mg–Ca ion concentrations, showing that the calcite nucleation barrier surpasses that of metastable aragonite in solutions with Mg:Ca ratios consistent with modern seawater, allowing aragonite to dominate the kinetics of nucleation. Our ability to quantify how solution parameters distinguish between polymorphs marks an important step toward the ab initio prediction of materials synthesis pathways in solution.« less

  9. AR03-04

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... the fulfillment of an oil-indus- try quest that goes ... deeper and more complex extraction techniques have become ... P) and flight-test three prototypes at White Sands Missile ...

  10. FY06 AR

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... The novel fi eld kit employs a heated diode sensor (commonly used to fi nd refrigerant leaks) to detect halogenated volatile organic compounds in soil and water at a sensitivity ...

  11. Long-term behavior of CaO-based pellets supported by calcium aluminate cements in a long series of CO{sub 2} capture cycles

    SciTech Connect

    Manovic, V.; Anthony, E.J.

    2009-10-15

    A series of carbonation/calcination tests consisting of 1000 cycles was performed with CaO-based pellets prepared using hydrated lime and calcium aluminate cement. The change in CO{sub 2} carrying capacity of the sorbent was investigated in a thermogravimetric analyzer (TGA) apparatus and the morphology of residues after those cycles in the TGA was examined by scanning electron microscopy (SEM). Larger quantities of sorbent pellets underwent 300 carbonation/calcination cycles in a tube furnace (TF), and their properties were examined by nitrogen physisorption tests (BET and BJH). The crushing strength of the pellets before and after the CO{sub 2} cycles was determined by means of a custom-made strength testing apparatus. The results showed high CO{sub 2} carrying capacity in long series of cycles with an extremely high residual activity of the order of 28%. This superior performance is a result of favorable morphology due to the existence of large numbers of nanosized pores suitable for carbonation. This morphology is relatively stable during cycles due to the presence of mayenite (Ca{sub 12}Al{sub 14}O{sub 33}) in the CaO structure. However, the crushing tests showed that pellets lost strength after 300 carbonation/calcination cycles, and this appears to be due to the cracks formed in the pellets. This effect was not observed in smaller particles suitable for use in fluidized bed (FBC) systems.

  12. Evaluation of cloud fraction and its radiative effect simulated by IPCC AR4 global models against ARM surface observations

    SciTech Connect

    Qian, Yun; Long, Charles N.; Wang, Hailong; Comstock, Jennifer M.; McFarlane, Sally A.; Xie, Shaocheng

    2012-02-17

    Cloud Fraction (CF) is the dominant modulator of radiative fluxes. In this study, we evaluate CF simulations in the IPCC AR4 GCMs against ARM ground measurements, with a focus on the vertical structure, total amount of cloud and its effect on cloud shortwave transmissivity, for both inter-model deviation and model-measurement discrepancy. Our intercomparisons of three CF or sky-cover related dataset reveal that the relative differences are usually less than 10% (5%) for multi-year monthly (annual) mean values, while daily differences are quite significant. The results also show that the model-observation and the inter-model deviations have a similar magnitude for the total CF (TCF) and the normalized cloud effect, and they are twice as large as the surface downward solar radiation and cloud transmissivity. This implies that the other cloud properties, such as cloud optical depth and height, have a similar magnitude of disparity to TCF among the GCMs, and suggests that a better agreement among the GCMs in solar radiative fluxes could be the result of compensating errors in either cloud vertical structure, cloud optical depth or cloud fraction. Similar deviation pattern between inter-model and model-measurement suggests that the climate models tend to generate larger bias against observations for those variables with larger inter-model deviation. The simulated TCF from IPCC AR4 GCMs are very scattered through all seasons over three ARM sites: Southern Great Plains (SGP), Manus, Papua New Guinea and North Slope of Alaska (NSA). The GCMs perform better at SGP than at Manus and NSA in simulating the seasonal variation and probability distribution of TCF; however, the TCF in these models is remarkably underpredicted and cloud transmissivity is less susceptible to the change of TCF than the observed at SGP. Much larger inter-model deviation and model bias are found over NSA than the other sites in estimating the TCF, cloud transmissivity and cloud-radiation interaction

  13. Spectral shapes of Ar-broadened HCl lines in the fundamental band by classical molecular dynamics simulations and comparison with experiments

    SciTech Connect

    Tran, H.; Domenech, J.-L.

    2014-08-14

    Spectral shapes of isolated lines of HCl perturbed by Ar are investigated for the first time using classical molecular dynamics simulations (CMDS). Using reliable intermolecular potentials taken from the literature, these CMDS provide the time evolution of the auto-correlation function of the dipole moment, whose Fourier-Laplace transform leads to the absorption spectrum. In order to test these calculations, room temperature spectra of various lines in the fundamental band of HCl diluted in Ar are measured, in a large pressure range, with a difference-frequency laser spectrometer. Comparisons between measured and calculated spectra show that the CMDS are able to predict the large Dicke narrowing effect on the shape of HCl lines and to satisfactorily reproduce the shapes of HCl spectra at different pressures and for various rotational quantum numbers.

  14. Three-dimensional magnetic restructuring in two homologous solar flares in the seismically active NOAA AR 11283

    SciTech Connect

    Liu, Chang; Deng, Na; Lee, Jeongwoo; Wang, Haimin; Wiegelmann, Thomas; Jiang, Chaowei; Dennis, Brian R.; Su, Yang; Donea, Alina

    2014-11-10

    We carry out a comprehensive investigation comparing the three-dimensional magnetic field restructuring, flare energy release, and the helioseismic response of two homologous flares, the 2011 September 6 X2.1 (FL1) and September 7 X1.8 (FL2) flares in NOAA AR 11283. In our analysis, (1) a twisted flux rope (FR) collapses onto the surface at a speed of 1.5 km s{sup –1} after a partial eruption in FL1. The FR then gradually grows to reach a higher altitude and collapses again at 3 km s{sup –1} after a fuller eruption in FL2. Also, FL2 shows a larger decrease of the flux-weighted centroid separation of opposite magnetic polarities and a greater change of the horizontal field on the surface. These imply a more violent coronal implosion with corresponding more intense surface signatures in FL2. (2) The FR is inclined northward and together with the ambient fields, it undergoes a southward turning after both events. This agrees with the asymmetric decay of the penumbra observed in the peripheral regions. (3) The amounts of free magnetic energy and nonthermal electron energy released during FL1 are comparable to those of FL2 within the uncertainties of the measurements. (4) No sunquake was detected in FL1; in contrast, FL2 produced two seismic emission sources S1 and S2 both lying in the penumbral regions. Interestingly, S1 and S2 are connected by magnetic loops, and the stronger source S2 has a weaker vertical magnetic field. We discuss these results in relation to the implosion process in the low corona and the sunquake generation.

  15. STUDY OF THE RECURRING DIMMING REGION DETECTED AT AR 11305 USING THE CORONAL DIMMING TRACKER (CoDiT)

    SciTech Connect

    Krista, Larisza D.; Reinard, Alysha

    2013-01-10

    We present a new approach to coronal dimming detection using the COronal DImming Tracker tool (CODIT), which was found to be successful in locating and tracking multiple dimming regions. This tool, an extension of a previously developed coronal hole tracking software, allows us to study the properties and the spatial evolution of dimming regions at high temporal and spatial cadence from the time of their appearance to their disappearance. We use Solar Dynamics Observatory/Atmospheric Imaging Assembly 193 A wavelength observations and Helioseismic and Magnetic Imager magnetograms to study dimmings. As a demonstration of the detection technique we analyzed six recurrences of a dimming observed near AR 11305 between 2011 September 29 and October 2. The dimming repeatedly appeared and formed in a similar way, first expanding then shrinking and occasionally stabilizing in the same location until the next eruption. The dimming areas were studied in conjunction with the corresponding flare magnitudes and coronal mass ejection (CME) masses. These properties were found to follow a similar trend during the observation period, which is consistent with the idea that the magnitude of the eruption and the CME mass affect the relative sizes of the consecutive dimmings. We also present a hypothesis to explain the evolution of the recurrent single dimming through interchange reconnection. This process would accommodate the relocation of quasi-open magnetic field lines and hence allow the CME flux rope footpoint (the dimming) to expand into quiet-Sun regions. By relating the properties of dimmings, flares, and CMEs we improve our understanding of the magnetic field reconfiguration caused by reconnection.

  16. Parametric study of atmospheric pressure microwave-induced Ar/O{sub 2} plasmas and the ambient air effect on the plasma

    SciTech Connect

    Moon, Se Youn; Choe, W.

    2006-10-15

    A torch type microwave-induced afterglow plasma was produced at atmospheric pressure using an open-ended fused silica concentric double tube assisted by Ar and O{sub 2} supply gases. The plasma emerged from the end of the discharge tube and was exposed to ambient air. A parametric study of the plasma characteristics was performed by measuring the temperature, density, and plasma volume as the operational parameters such as microwave power, gas flow rate, and its composition were varied. The excitation temperature (T{sub exc}) obtained from the Ar I emission spectrum ranged from 3010 to 4350 K and the rotational temperature (T{sub rot}) measured from the OH and O{sub 2} diatomic molecular spectra ranged from 2250 to 3550 K. The electron density (n{sub e}) from the H{sub {beta}} Stark broadening width at the plasma core was in the range of 6.6 to 7.6x10{sup 14} cm{sup -3}. The two-dimensional distribution of T{sub exc} and T{sub rot} was also obtained. Experiments while varying the Ar and O{sub 2} gas flow rate and the O{sub 2}/Ar ratio showed that n{sub e} was reduced but T{sub exc} was increased as the O{sub 2} flow rate was increased. Using an additional dielectric tube for shielding the plasma from the ambient air demonstrated a significantly enlarged plasma length and lower T{sub rot} due to the nitrogen entrainment, as compared to the unshielded case.

  17. Simulations of Ar gas-puff Z-pinch radiation sources with double shells and central jets on the Z generator

    DOE PAGES [OSTI]

    Tangri, V.; Harvey-Thompson, Adam James; Giuliani, J. L.; Thornhill, J. W.; Velikovich, A. L.; Apruzese, J. P.; Quart, N. D.; DasGupta, A.; Jones, Brent M.; Jennings, Christopher Ashley

    2016-10-19

    Radiation-magnetohydrodynamic simulations using the non-LTE Mach2-TCRE code in (r,z) geometry are performed for two pairs of recent Ar gas-puff Z-pinch experiments on the refurbished Z generator with an 8 cm diameter nozzle. One pair of shots had an outer-to-inner shell mass ratio of 1:1.6 and a second pair had a ratio of 1:1.

  18. EIS-0439: Rice Solar Energy Project in Riverside County, CA | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Energy 9: Rice Solar Energy Project in Riverside County, CA EIS-0439: Rice Solar Energy Project in Riverside County, CA March 29, 2010 EIS-0439: Notice of Intent to Prepare an Environmental Impact Statement Proposed Construction and Operation of the Rice Solar Energy Project, Riverside County, CA October 22, 2010 EIS-0439: EPA Notice of Availability of the Draft Environmental Impact Statement Rice Solar Energy Project, Riverside County, California October 22, 2010 EIS-0439: Draft

  19. Analysis of natural gases, AL, AR, FL, GA, IL, IN, IA, KY, LA, MD, MI, MS, MO, NJ, NY, NC, OH, PA, TN, VA, and WV; 1951-1991 (for microcomputers). Data file

    SciTech Connect

    Not Available

    1991-01-01

    The U.S. Bureau of Mines diskette contains analysis and related source data for 2,357 natural gas samples collected from miscellaneous states, which include the following states: Alabama, Arkansas (except Arkoma Basin), Florida, Georgia, Illinois, Indiana, Iowa, Kentucky, Louisiana, Maryland, Michigan, Mississippi, Missouri, New Jersey, New York, North Carolina, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. All samples were obtained and analyzed as part of the Bureau's investigations of occurrences of helium in natural gases of countries with free market economies. The survey has been conducted since 1917. The analysis contained on the diskette contain the full range of component analysis data. Five files are on the diskette: READ.ME, MISC.TXT, MISC.DBF, USHEANAL.DBF, and BASINCDE.TXT.

  20. Magnetic order and heavy fermion behavior in CePd{sub 1+x}Al{sub 6-x}: Synthesis, structure, and physical properties

    SciTech Connect

    Tobash, Paul H., E-mail: ptobash@lanl.go [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Ronning, Filip; Thompson, J.D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bobev, Svilen [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bauer, Eric D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2010-03-15

    The physical properties including magnetic susceptibility, specific heat, and electrical resistivity of single crystals are reported for the compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) which crystallizes in the tetragonal SrAu{sub 2}Ga{sub 5}-type structure (space group P4/mmm). The compound was grown from an excess of molten Al flux from the respective elements and the crystal structure was established from single-crystal X-ray diffraction. Anomalies in the low temperature specific heat C{sub p}(T) and electrical resistivity rho(T) show that the compound undergoes ferromagnetic order at T{sub C}=2.8 K. In the ordered state, CePd{sub 1.5}Al{sub 5.5} displays heavy fermion behavior with a Sommerfeld coefficient of ca. 500 mJ/mol-K{sup 2}. - Graphical abstract: The compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) has been synthesized and structurally characterized by single-crystal X-ray diffraction. The measured physical properties of temperature and field dependent magnetic susceptibility, specific heat, and electrical resistivity suggests that the compound undergoes ferromagnetic order at ca. 2.8 K and further exhibits relatively heavy fermion behavior with a Sommerfeld coefficient of 500 mJ/mol-K2.