National Library of Energy BETA

Sample records for ag io ir

  1. I/O Formats

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Formats I/O Formats Software I/O continues to be one of the main bottlenecks for scientific applications. Here are two software packages that many application developers use to manage input/output of heterogeneous types of binary application data used on many different platforms. HDF5 and NETCDF are both implemented on top of MPI-IO and have gained popularity as alternatives to basic POSIX API. HDF5 is a machine-independent and self-documenting file format. Each HDF5 file "looks" like

  2. I/O Resources

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    I/O Resources I/O Resources Motivation Many users must run jobs that read datasets that are too large to transfer to the /scratch directory. When large numbers of these jobs run simultaneously, it can have an adverse affect on the performance of the disks serving the data causing your jobs to run very inefficiently. We have configured a resource in the batch system that should help manage the amount of concurrent access. These are called IO resources, and they depend on the bandwidth available

  3. IO SUBSYSTEM 1 BETA

    Energy Science and Technology Software Center

    2002-08-21

    "IO Subsystem Ver. 1.0 Beta" uses standard object-oriented principles to minimize dependencies between the underlying input or output database format and the client code (i.e., Sierra) using the io subsystem. The interface and priciples are simolar to the Facade pattern described in the "Design Patterns" book by Gamma, et.al. The software uses data authentication algorithms to ensure data input/output is consistent with model being defined. "IO Subsystem Ver. 1.0 Beta" is a database independent input/outputmore » library for finite element analysis, preprocessing, post processing, and translation programs.« less

  4. PDSF I/O Monitoring

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    PDSF I/O Monitoring Last edited: 2016-04-29 11:34:41

  5. SC11-IO.pptx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    2 Tutorial Info & Presentations http://www.nersc.gov/users/training/nersc-training-events/ sc11/s10/ or http://tinyurl.com/sc11-s10 * Storage Systems and Parallel File Systems * High Level I/O Strategies * Data Access Patterns * Parallel I/O Interfaces * I/O using Lustre File Systems * Best Practices and Recommendations Outline 3 Getting bigger all the time * User I/O needs growing each year in scientific community * For our largest users I/O parallelism is mandatory * I/O remains a

  6. Palmer-IO.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Paige Terlip Paige Terlip Paige Terlip - Former Communicator, National Renewable Energy Laboratory Paige Terlip Paige Terlip is a former communicator at DOE's National Renewable Energy Laboratory. Most Recent Spruce Up Your Home for Spring and Summer May 6 Which Water Heater Is Right for You? March 5 Love Your Home and It'll Love You Back February 11

    IO Requirements for a Global Cloud Resolving Model Bruce Palmer Annette Koontz Karen Schuchardt Geodesic Grid Geodesic grids can be decomposed

  7. Cray IO COE

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    IO COE Performance of MPIIO on DVS+GPFS Yushu Yao Collaboration with: Mike Aamodt, Katie Antypas, Tina Butler, Mark Cruciani, Jason Hick, David Knaak, Rei Lee, Rose Olson, Mike Welcome 1 Wednesday, July 25, 12 WHY 2 Wednesday, July 25, 12 Scratch 35GB/S LSI 7900 OSS OSS OSS OSS OSS OSS ... ... LSI 7900 LSI 7900 ... ... LSI 7900 LSI 7900 ... ... DDN DDN DDN DDN PROJECT DVS DDN DDN DDN DDN GSCRATCH Data Analysis Visualization ... ... PNSD PNSD PNSD CMP CMP CMP ... CMP CMP CMP ... ... ... ...

  8. File storage and I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    File storage and IO File storage and IO Disk Quota Change Request Form Franklin File Systems The Franklin system has 4 different file systems mounted which provide different...

  9. Geodesic IO Library

    Energy Science and Technology Software Center

    2011-03-15

    GIO is an application programmer interface (API) or library for high performance IO that is designed for climate models that operate on a geodesic grid. GIO uses a combination of configuration files and API calls to define the mapping of internal model data to output variables in standard climate data formats. The mapping from model data to model output includes method of data slicing, aggregation, and linearization using a morton ordering approach. The data ismore » then persisted through a standard interface that can be implemented using several different high level parallel libraries. Both Parallel NetCDF and NetCDF4 interfaces are provided. GIO is designed to run on supercomputing systems or multi-processor clusters with parallel file systems.« less

  10. I/O Case Studies

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    (>10%) dealing IO related to the tecplot files Frequent OpenSeekClose uses lots of meta time Meta time is 50X of the actual write time Suggestion KEEP the file open saves 90%...

  11. Optimizing I/O performance on the Lustre file system

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    IO performance. File striping will primarily improve performance for codes doing serial IO from a single node or parallel IO from multiple nodes writing to a single shared...

  12. Introduction to Scientific I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Scientific I/O Show All | 1 2 3 4 5 6 | Next » Introduction to Scientific I/O Table of Contents Introduction to Scientific I/O The Lustre File System The HDF5 Library Parallel HDF5 Scientific I/O in HDF5 Optimizations for HDF5 on Lustre Introduction to Scientific I/O I/O is commonly used by scientific applications to achieve goals like: storing numerical output from simulations for later analysis; implementing 'out-of-core' techniques for algorithms that process more data than can fit in system

  13. Parallel I/O in Practice

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    art. This tutorial sheds light on the state-of-the-art in parallel IO and provides the knowledge necessary for attendees to best leverage IO resources available to them. We...

  14. Hopper File Storage and I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    File Storage and IO File Storage and IO Disk Quota Change Request Form Hopper File Systems Hopper has 5 user file systems which provide different degrees of storage, performance...

  15. File Storage and I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    File Storage and IO File Storage and IO Disk Quota Change Request Form Hopper File Systems Hopper has 5 user file systems which provide different degrees of storage, performance...

  16. I/O Statistics Last 30 Days

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    I/O Statistics Last 30 Days I/O Statistics Last 30 Days These plots show the daily statistics for the last 30 days for the storage systems at NERSC in terms of the amount of data transferred and the number of files transferred. Daily I/O Volume Daily I/O Count Last edited: 2016-10-21 11:56:2

  17. TOKIO: Total Knowledge of I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    TOKIO: Total Knowledge of I/O TOKIO: Total Knowledge of I/O The Total Knowledge of I/O (TOKIO) project is developing algorithms and a software framework that collects and correlates I/O workload data from production HPC resources at multiple system levels to provide a dramatically clearer view of system behavior, and the causes of behavior, to application scientists, facility operators and computer science researchers in the field. TOKIO is a collaboration between the Lawrence Berkeley and

  18. diod - distributed I/O daemon

    Energy Science and Technology Software Center

    2010-01-29

    diod is an I/O forwarding daemon used to improve scalability of file systems on large Linux clusters.

  19. Trilinos I/O Support (Trios)

    DOE PAGES [OSTI]

    Oldfield, Ron A.; Sjaardema, Gregory D.; Lofstead II, Gerald F.; Kordenbrock, Todd

    2012-01-01

    Trilinos I/O Support (Trios) is a new capability area in Trilinos that serves two important roles: (1) it provides and supports I/O libraries used by in-production scientific codes; (2) it provides a research vehicle for the evaluation and distribution of new techniques to improve I/O on advanced platforms. This paper provides a brief overview of the production-grade I/O libraries in Trios as well as some of the ongoing research efforts that contribute to the experimental libraries in Trios.

  20. Mili I/O Library

    Energy Science and Technology Software Center

    1996-08-23

    Mili is a high-level mesh I/O library and database developed to support computational analysis and post-processing on unstructured finite element meshes. Mili provides is self-describing database with high-level, finite element analysis-cognizant semantics, and cross-platform data portability. Mili provides analysis codes with the capability to completely describe and label the state data, which will be output do disk. Mili has both C and FORTRAN interfaces and provides for database portability by supporting both big-and little-endian binarymore » formats.« less

  1. I/O Resources for Scientific Applications at NERSC

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    IO Resources for Scientific Applications at NERSC IO Resources for Scientific Applications at NERSC Introduction NERSC provides a range of online resources to assist users...

  2. NUG_Parallel_IO_Oct2009.ppt

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    - We can treat this as "one big disk," but it may actually be a complex collection of disk arrays, IO servers, and networks. Terminology: Metadata * Data about data * File systems ...

  3. Special Inquiry: IO1HQ005 | Department of Energy

    Energy.gov [DOE] (indexed site)

    Review of the Yucca Mountain Project, IO1HQ005 Special Inquiry: IO1HQ005 More Documents & Publications Special Inquiry: I01HQ003 Inquiry Report: I01IG001 Special Inquiry: SI-11-2...

  4. IoT Interoperability at Bosch

    Energy.gov [DOE] (indexed site)

    Acquire d S oftwa re Innova tions , 2008 Bus ine s s proce s s ma na ge me nt Cloud-ba s e d IoT s olutions Acquiring P ros ys t (a nnounce d Fe brua ry 2015) P...

  5. FY06 I/O Integration Blueprint

    SciTech Connect

    Cupps, K; Fitzgerald, K; Gary, M; Shoopman, J; Hamilton, P; Loewe, B; Slavec, J; Smith, D; Fox, D; Southard, D; Wiltzuis, D; Allen, J; Bass, N; Boas, B; Connell, T; East, D; Gorda, B; Lawver, B; Louis, S; Quinn, T; Seager, M

    2006-04-06

    This document provides an understanding of the near and long term computing and I/O resources in the Secure Computing Facility (SCF) and Open Computing Facility (OCF). Requirements for data flows, storage capacities and transfer rates are determined. Recommendations are made for architectures, timeframes for major deliverables, and procurements for the next fiscal year.

  6. A brief parallel I/O tutorial.

    SciTech Connect

    Ward, H. Lee

    2010-03-01

    This document provides common best practices for the efficient utilization of parallel file systems for analysts and application developers. A multi-program, parallel supercomputer is able to provide effective compute power by aggregating a host of lower-power processors using a network. The idea, in general, is that one either constructs the application to distribute parts to the different nodes and processors available and then collects the result (a parallel application), or one launches a large number of small jobs, each doing similar work on different subsets (a campaign). The I/O system on these machines is usually implemented as a tightly-coupled, parallel application itself. It is providing the concept of a 'file' to the host applications. The 'file' is an addressable store of bytes and that address space is global in nature. In essence, it is providing a global address space. Beyond the simple reality that the I/O system is normally composed of a small, less capable, collection of hardware, that concept of a global address space will cause problems if not very carefully utilized. How much of a problem and the ways in which those problems manifest will be different, but that it is problem prone has been well established. Worse, the file system is a shared resource on the machine - a system service. What an application does when it uses the file system impacts all users. It is not the case that some portion of the available resource is reserved. Instead, the I/O system responds to requests by scheduling and queuing based on instantaneous demand. Using the system well contributes to the overall throughput on the machine. From a solely self-centered perspective, using it well reduces the time that the application or campaign is subject to impact by others. The developer's goal should be to accomplish I/O in a way that minimizes interaction with the I/O system, maximizes the amount of data moved per call, and provides the I/O system the most information about

  7. Microsoft PowerPoint - Franklin System IO

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    File Systems & IO Richard Gerber NERSC User Services RAGerber@lbl.gov NERSC Users Group Berkeley Lab Oakland, CA October 2, 2008 Oct. 2, 2008 NUG 2008, Berkeley Lab, NERSC Oakland Scientific Facility Outline * File Systems * System Layout * Best Practices * Details * Reference www.nersc.gov www.nersc.gov/nusers/systems/franklin Oct. 2, 2008 NUG 2008, Berkeley Lab, NERSC Oakland Scientific Facility Franklin File Systems Oct. 2, 2008 NUG 2008, Berkeley Lab, NERSC Oakland Scientific Facility

  8. Interface for Parallel I/O from Componentized Visualization Algorithms

    Energy Science and Technology Software Center

    2008-09-16

    The software is an interface layer over file I/O with features specifically designed for efficient parallel reads and writes. The interface provides multiple concrete implementations that easily allow the replacement of one interface with another. This feature allows a reader or writer implementation to work independently of whether parallel file I/O is available or desired. The software also contains extensions to some readers to allow it to use the file I/O functionality.

  9. Renewable Energy Engineering Consulting AG REECON AG | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Consulting AG REECON AG Jump to: navigation, search Name: Renewable Energy Engineering Consulting AG (REECON AG) Place: Heppenheim, Hessen, Germany Zip: D-64646 Sector: Solar...

  10. Antec Solar Energy AG formerly Oekologik Ecovest AG | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Antec Solar Energy AG formerly Oekologik Ecovest AG Jump to: navigation, search Name: Antec Solar Energy AG (formerly Oekologik Ecovest AG) Place: Arnstadt, Germany Zip: 99310...

  11. Abwicklungsgesellschaft Biogas I AG Formerly Schmack Biogas AG...

    OpenEI (Open Energy Information) [EERE & EIA]

    Abwicklungsgesellschaft Biogas I AG Formerly Schmack Biogas AG Jump to: navigation, search Name: Abwicklungsgesellschaft Biogas I AG (Formerly Schmack Biogas AG) Place: Schwandorf,...

  12. Reducing Configuration Complexity with Next Gen IoT Networks

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Reducing Configuration Complexity with Next Gen IoT Networks Orama Inc. November, 2015 1 Network Lighting Controls Low Penetration - Why? * Commissioning is very time-consuming & ...

  13. mira_boot_camp_2016_harms_io

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    on Mira and Challenges of Portable I/O with Best Practices Scaling Your Science 2016 Kevin Harms - harms@alcf.anl.gov Venkat Vishwanath Phil Carns Rob Latham Storage vs Computation Trend 2 ASC Sequoia 20 PF/s Compute 500GB/s Storage ASCI Red Mira Mira I/O Infrastructure Overview 3 Infiniband QDR SAN Cooley Compute I/O Node mira-fs0 (GPFS) mira-fs1 (GPFS) mira-home (GPFS) Infiniband FDR Cetus Storage resources Mira I/O Infrastructure 4 BG/Q Optical 2x16 Gbit/sec QDR InfiniBand 32 Gbit/sec Serial

  14. Livermore Random I/O Testbench

    Energy Science and Technology Software Center

    2012-09-01

    LRIOT is a test bench framework that is designed to generate sophisticated I/O rates that can stress high-performance memory and storage systems, such as non-volatile random access memories (NVRAM)and storage class memory. Furthermore, LRIOT provides the capabilities to mix multiple types of concurrency, namely threading and task parallelism, as well as distributed execution using Message Passing Interface (MPI) libraries. It will be used by algorithm designers to generate access patterns that mimic their application's behavior,more » and by system designers to test high-performance NVRAM storage.« less

  15. Requirements for Parallel I/O,

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Requirements for Parallel I/O, ! Visualization and Analysis Prabhat 1 , Q uincey K oziol 2 1 LBL/NERSC 2 The H DF G roup NERSC A SCR R equirements f or 2 017 January 1 5, 2 014 LBNL 1. Project Description! * m636 r epo * LBL V is B ase P rogram ( Bethel P I) [ PM: N owell] * Conduct f undamental a nd a pplied vis/analyEcs R &D t o address e xascale c hallenges * ExaHDF5 P roject ( Prabhat, Q uincey P Is) [ PM: Nowell] * Scale P arallel I /O, a nd d ata m anagement t echnologies f or current

  16. V-115: Apple iOS Bugs Let Local Users Gain Elevated Privileges...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    5: Apple iOS Bugs Let Local Users Gain Elevated Privileges V-115: Apple iOS Bugs Let Local Users Gain Elevated Privileges March 20, 2013 - 12:08am Addthis PROBLEM: Apple iOS Bugs...

  17. Parallel I/O Software Infrastructure for Large-Scale Systems

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Parallel IO Software Infrastructure for Large-Scale Systems Parallel IO Software Infrastructure for Large-Scale Systems Choudhary.png An illustration of how MPI---IO file domain...

  18. Multi-Purpose, Application-Centric, Scalable I/O Proxy Application

    Energy Science and Technology Software Center

    2015-06-15

    MACSio is a Multi-purpose, Application-Centric, Scalable I/O proxy application. It is designed to support a number of goals with respect to parallel I/O performance testing and benchmarking including the ability to test and compare various I/O libraries and I/O paradigms, to predict scalable performance of real applications and to help identify where improvements in I/O performance can be made within the HPC I/O software stack.

  19. Remote I/O : fast access to distant storage.

    SciTech Connect

    Foster, I.; Kohr, D., Jr.; Krishnaiyer, R.; Mogill, J.

    1997-12-17

    As high-speed networks make it easier to use distributed resources, it becomes increasingly common that applications and their data are not colocated. Users have traditionally addressed this problem by manually staging data to and from remote computers. We argue instead for a new remote I/O paradigm in which programs use familiar parallel I/O interfaces to access remote file systems. In addition to simplifying remote execution, remote I/O can improve performance relative to staging by overlapping computation and data transfer or by reducing communication requirements. However, remote I/O also introduces new technical challenges in the areas of portability, performance, and integration with distributed computing systems. We propose techniques designed to address these challenges and describe a remote I/O library called RIO that we have developed to evaluate the effectiveness of these techniques. RIO addresses issues of portability by adopting the quasi-standard MPI-IO interface and by defining a RIO device and RIO server within the ADIO abstract I/O device architecture. It addresses performance issues by providing traditional I/O optimizations such as asynchronous operations and through implementation techniques such as buffering and message forwarding to off load communication overheads. RIO uses the Nexus communication library to obtain access to configuration and security mechanisms provided by the Globus wide area computing tool kit. Microbenchmarks and application experiments demonstrate that our techniques achieve acceptable performance in most situations and can improve turnaround time relative to staging.

  20. ALCF I/O Data Repository (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Technical Report: ALCF IO Data Repository Citation Details In-Document Search Title: ALCF IO Data Repository You are accessing a document from the Department of Energy's (DOE) ...

  1. U-138: Cisco IOS IPSec IKE Unspecified Denial of Service Vulnerability |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy 38: Cisco IOS IPSec IKE Unspecified Denial of Service Vulnerability U-138: Cisco IOS IPSec IKE Unspecified Denial of Service Vulnerability April 2, 2012 - 7:00am Addthis PROBLEM: A vulnerability has been reported in Cisco IOS, which can be exploited by malicious people to cause a DoS (Denial of Service). PLATFORM: Cisco IOS XE 2.1.x Cisco IOS XE 2.2.x Cisco IOS XE 2.3.x Cisco IOS XE 2.4.x Cisco IOS XE 2.5.x Cisco IOS XE 2.6.x Cisco IOS XE 3.1.x Cisco IOS XE 3.3.x

  2. Hf-irJ

    Office of Legacy Management (LM)

    Hf-irJ jnj,4 States Governmen Department of Energy Inemorandum DOTE: DAY o 1S5a . 7 EPY TO F . O 0 NE-24 SUJEC': Authorization for Remedial Action of Residential Vicinity ...

  3. A Comprehensive Look at High Performance Parallel I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    A Comprehensive Look at High Performance Parallel I/O A Comprehensive Look at High Performance Parallel I/O Book Signing @ SC14! Nov. 18, 5 p.m. in Booth 1939 November 10, 2014 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov HighPerf Parallel IO In the 1990s, high performance computing (HPC) made a dramatic transition to massively parallel processors. As this model solidified over the next 20 years, supercomputing performance increased from gigaflops-billions of calculations per second-to

  4. A Comprehensive Look at High Performance Parallel I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    In this era of "big data," high performance parallel IO-the way disk drives efficiently read and write information on HPC systems-is extremely important. Yet the last book to ...

  5. Letter Report: IO1OP001 | Department of Energy

    Energy.gov [DOE] (indexed site)

    2 Department of Energy's Purchase Card programs and the lessons learned. Letter Report: IO1OP001 More Documents & Publications Audit Report: WR-B-02-03 Inspection Report:...

  6. Current parallel I/O limitations to scalable data analysis.

    SciTech Connect

    Mascarenhas, Ajith Arthur; Pebay, Philippe Pierre

    2011-07-01

    This report describes the limitations to parallel scalability which we have encountered when applying our otherwise optimally scalable parallel statistical analysis tool kit to large data sets distributed across the parallel file system of the current premier DOE computational facility. This report describes our study to evaluate the effect of parallel I/O on the overall scalability of a parallel data analysis pipeline using our scalable parallel statistics tool kit [PTBM11]. In this goal, we tested it using the Jaguar-pf DOE/ORNL peta-scale platform on a large combustion simulation data under a variety of process counts and domain decompositions scenarios. In this report we have recalled the foundations of the parallel statistical analysis tool kit which we have designed and implemented, with the specific double intent of reproducing typical data analysis workflows, and achieving optimal design for scalable parallel implementations. We have briefly reviewed those earlier results and publications which allow us to conclude that we have achieved both goals. However, in this report we have further established that, when used in conjuction with a state-of-the-art parallel I/O system, as can be found on the premier DOE peta-scale platform, the scaling properties of the overall analysis pipeline comprising parallel data access routines degrade rapidly. This finding is problematic and must be addressed if peta-scale data analysis is to be made scalable, or even possible. In order to attempt to address these parallel I/O limitations, we will investigate the use the Adaptable IO System (ADIOS) [LZL+10] to improve I/O performance, while maintaining flexibility for a variety of IO options, such MPI IO, POSIX IO. This system is developed at ORNL and other collaborating institutions, and is being tested extensively on Jaguar-pf. Simulation code being developed on these systems will also use ADIOS to output the data thereby making it easier for other systems, such as ours, to

  7. Campa AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Campa AG Jump to: navigation, search Name: Campa AG Place: Ochsenfurt, Germany Zip: 97199 Product: String representation "Campa AG is one ... on and trading." is too long....

  8. Eifelstrom AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Eifelstrom AG Place: Germany Sector: Solar Product: Holding company belonging to the family of Frank Asbeck, founder of Solar World AG. References: Eifelstrom AG1 This article...

  9. VWind AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    VWind AG Jump to: navigation, search Name: VWind AG Place: Germany Sector: Wind energy Product: Germany-based offshore wind installation company. References: VWind AG1 This...

  10. Altus AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Altus AG Jump to: navigation, search Name: Altus AG Place: Germany Sector: Renewable Energy Product: Germany-based renewable energy project developer. References: Altus AG1 This...

  11. WKV AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    WKV AG Place: Gutach, Baden-Wrttemberg, Germany Zip: 79261 Sector: Hydro Product: German-based hydro turbines manufacturer, Wasserkraft Volk AG (WKV AG) provides technology...

  12. Solarsquare AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solarsquare AG Jump to: navigation, search Name: Solarsquare AG Place: Switzerland Sector: Solar Product: Solar modules distributor. References: Solarsquare AG1 This article is a...

  13. Broadband enhancement of infrared absorption in microbolometers using Ag nanocrystals

    SciTech Connect

    Hyun, Jerome K.; Ahn, Chi Won; Kim, Woo Choong; Kim, Tae Hyun; Hyun, Moon Seop; Kim, Hee Yeoun E-mail: jhpark@nnfc.re.kr; Park, Jae Hong E-mail: jhpark@nnfc.re.kr; Lee, Won-Oh

    2015-12-21

    High performance microbolometers are widely sought for thermal imaging applications. In order to increase the performance limits of microbolometers, the responsivity of the device to broadband infrared (IR) radiation needs to be improved. In this work, we report a simple, quick, and cost-effective approach to modestly enhance the broadband IR response of the device by evaporating Ag nanocrystals onto the light entrance surface of the device. When irradiated with IR light, strong fields are built up within the gaps between adjacent Ag nanocrystals. These fields resistively generate heat in the nanocrystals and underlying substrate, which is transduced into an electrical signal via a resistive sensing element in the device. Through this method, we are able to enhance the IR absorption over a broadband spectrum and improve the responsivity of the device by ∼11%.

  14. Umwelt Management AG UMaAG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Management AG UMaAG Jump to: navigation, search Name: Umwelt Management AG (UMaAG) Place: Cuxhaven, Germany Zip: 27478 Sector: Wind energy Product: RE project developer, esp. wind...

  15. I/O Performance of Virtualized Cloud Environments

    SciTech Connect

    Ghoshal, Devarshi; Canon, Shane; Ramakrishnan, Lavanya

    2011-11-03

    The scientific community is exploring the suitability of cloud infrastructure to handle High Performance Computing (HPC) applications. The goal of Magellan, a project funded through DOE ASCR, is to investigate the potential role of cloud computing to address the computing needs of the Department of Energy?s Office of Science, especially for mid-range computing and data-intensive applications which are not served through existing DOE centers today. Prior work has shown that applications with significant communication orI/O tend to perform poorly in virtualized cloud environments. However, there is a limited understanding of the I/O characteristics in virtualized cloud environments. This paper will present our results in benchmarking the I/O performance over different cloud and HPC platforms to identify the major bottlenecks in existing infrastructure. We compare the I/O performance using IOR benchmark on two cloud platforms - Amazon and Magellan. We analyze the performance of different storage options available, different instance types in multiple availability zones. Finally, we perform large-scale tests in order to analyze the variability in the I/O patterns over time and region. Our results highlight the overhead and variability in I/O performance on both public and private cloud solutions. Our results will help applications decide between the different storage options enabling applications to make effective choices.

  16. I/O Performance of a Large-Scale, Interpreter-Driven Laser-Plasma...

    Office of Scientific and Technical Information (OSTI)

    Conference: IO Performance of a Large-Scale, Interpreter-Driven Laser-Plasma Interaction Code Citation Details In-Document Search Title: IO Performance of a Large-Scale, ...

  17. 01 Team Black_Presentation _LANL?s PaScalBB IO.pptx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    multiple 10-Gigabit Ethernet bonding Small-scale PaScalBB test bed and conduct a sequence of IO node performance tests. Discovery of enhanced IO node network...

  18. An Optimizing Compiler for Petascale I/O on Leadership Class Architectures

    SciTech Connect

    Choudhary, Alok; Kandemir, Mahmut

    2015-03-18

    In high-performance computing systems, parallel I/O architectures usually have very complex hierarchies with multiple layers that collectively constitute an I/O stack, including high-level I/O libraries such as PnetCDF and HDF5, I/O middleware such as MPI-IO, and parallel file systems such as PVFS and Lustre. Our project explored automated instrumentation and compiler support for I/O intensive applications. Our project made significant progress towards understanding the complex I/O hierarchies of high-performance storage systems (including storage caches, HDDs, and SSDs), and designing and implementing state-of-the-art compiler/runtime system technology that targets I/O intensive HPC applications that target leadership class machine. This final report summarizes the major achievements of the project and also points out promising future directions.

  19. IR Spot Weld Inspect

    Energy Science and Technology Software Center

    2014-01-01

    In automotive industry, destructive inspection of spot welds is still the mandatory quality assurance method due to the lack of efficient non-destructive evaluation (NDE) tools. However, it is costly and time-consuming. Recently at ORNL, a new NDE prototype system for spot weld inspection using infrared (IR) thermography has been developed to address this problem. This software contains all the key functions that ensure the NDE system to work properly: system input/output control, image acquisition, datamore » analysis, weld quality database generation and weld quality prediction, etc.« less

  20. T-611: Cisco IOS OCSP Revoked Certificate Security Issue

    Energy.gov [DOE]

    The PKI functionality in Cisco IOS 15.0 and 15.1 does not prevent permanent caching of certain public keys, which allows remote attackers to bypass authentication and have unspecified other impact by leveraging an IKE peer relationship in which a key was previously valid but later revoked, aka Bug ID CSCth82164, a different vulnerability than CVE-2010-4685.

  1. V-165: Cisco WebEx for iOS Certificate Validation Flaw Lets Remote Users

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Spoof the Server | Department of Energy 65: Cisco WebEx for iOS Certificate Validation Flaw Lets Remote Users Spoof the Server V-165: Cisco WebEx for iOS Certificate Validation Flaw Lets Remote Users Spoof the Server May 28, 2013 - 12:46am Addthis PROBLEM: Cisco WebEx for iOS Certificate Validation Flaw Lets Remote Users Spoof the Server PLATFORM: Cisco WebEx for iOS 4.1, Other versions may also be affected. ABSTRACT: A vulnerability was reported in Cisco WebEx for iOS. REFERENCE LINKS:

  2. Solarparc AG Former WindWelt AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: Solarparc AG (Former WindWelt AG) Place: Bonn, Germany Zip: 53115 Sector: Solar, Wind energy Product: Focused on planning, developing and operating wind and solar power...

  3. Tse AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Tse AG Jump to: navigation, search Name: tse.AG Place: Germany Product: Thenergo's German subsidiary. References: tse.AG1 This article is a stub. You can help OpenEI by expanding...

  4. Message Passage Interface Input/Output (MPI-IO Test) Version 1.0

    Energy Science and Technology Software Center

    2005-04-08

    Although there a host of existing file system and I/O test programs available, most were not designed with parallel I/O in mind and are not useful at the scale of our clusters. Los Alamos National Lab's MPI-IO test was written with I/O and scale in mind. The MPI-IO test is built on top of MPI's I/O calls and is used to gather timing information for reading from and writing to file(s) using a variety ofmore » I/O profiles; N processes writing to N files, N processes writing to one file, N processes sending data to m processes writing to m files, or n processes sending data to m processes to one file. A data aggregation capability is available and the user can pass down MPI-IO, ROMIO and some file system specific MPI hints. By default, the MPI-IO Test will write and specific pattern to a file, close the file, open the file for read, read the data, check for data integrity and close the file. Timing information is reported for file open, close, read and write data rates, and effective bandwidths. The MPI-IO Test can be used for performance benchmarking and, in some cases, to diagnost problems with file systems or I/O networks.« less

  5. Solarstocc AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Bad Zwischenahn, Germany Zip: 26160 Product: Designer and manufacturer of photovoltaic products and components. References: Solarstocc AG1 This article is a stub. You...

  6. Kopf AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: Kopf AG Place: Sulz-Bergfelden (DE), Germany Zip: 72172 Product: Focused on photovoltaic power systems, and energy and environmental technology. References: Kopf AG1 This...

  7. Evader AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Evader AG Place: Zug, Switzerland Product: Joint venture between Washington-based Evader Inc and the Schneider Group, in order to streamline...

  8. Solarvalue AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solarvalue AG Jump to: navigation, search Name: Solarvalue AG Place: Berlin, Berlin, Germany Zip: D-10719 Product: German manfuacturer of polysilicon made through metallurgical...

  9. Odersun AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Odersun AG Jump to: navigation, search Name: Odersun AG Place: Frankfurt, Germany Zip: 15236 Product: German manufacturer of copper indium disulphide on copper tape (CISCuT)...

  10. Varta AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Varta AG Jump to: navigation, search Name: Varta AG Place: Hanover, Germany Zip: 30419 Product: Headquartered in Hanover, concentrates on developing its global microbattery...

  11. ABIDAS AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ABIDAS AG Jump to: navigation, search Name: ABIDAS AG Place: Werder, Brandenburg, Germany Zip: 14542 Product: Local energy consultant and PV systems installer and integrator....

  12. ENRO AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: ENRO AG Place: Essen, Germany Zip: 45128 Sector: Biomass Product: Focuses on distributed energy supply concepts for local authorities and...

  13. Interstrom AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Interstrom AG Place: Bayreuth, Bavaria, Germany Zip: 95448 Sector: Solar Product: Germany-based electricity provider. The firm is...

  14. Solare AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Solare AG Place: Cologne, North Rhine-Westphalia, Germany Zip: 50678 Sector: Solar Product: Germany-based equipment manufacturer and developer...

  15. Inergetic AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Inergetic AG Jump to: navigation, search Name: Inergetic AG Place: Schwerin, Germany Zip: 19061 Sector: Biomass Product: Biomass power plant developer and operator. Actively...

  16. Solarcomplex AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solarcomplex AG Jump to: navigation, search Name: solarcomplex AG Place: Singen, Germany Zip: 78224 Sector: Renewable Energy, Solar Product: Regional solar energy company with the...

  17. Energieteam AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energieteam AG Jump to: navigation, search Name: Energieteam AG Place: Lichtenau, Germany Zip: D-33165 Sector: Wind energy Product: Wind farm developer. Has developed 904MW wind in...

  18. Solea AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Solea AG Place: Plattling, Germany Zip: 94447 Product: A Germany PV project developer and building contractor, who also manufactures its own...

  19. REON AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    REON AG Jump to: navigation, search Name: REON AG Place: Worpswede, Germany Zip: D-27726 Sector: Services Product: Specialists in technical and strategic advisory services for...

  20. Wattner AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    to: navigation, search Name: Wattner AG Place: Kln, Germany Zip: 50679 Product: German project finance arranger. References: Wattner AG1 This article is a stub. You can...

  1. Eutropa AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Eutropa AG Jump to: navigation, search Name: Eutropa AG Place: Munich, Bavaria, Germany Zip: 82008 Sector: Renewable Energy Product: Munich-based consultancy providing information...

  2. D0 Cryogenic System Superconducting Solenoid Platform I/O

    SciTech Connect

    Markley, D.; /Fermilab

    1997-10-09

    The Dzero detector is scheduled for a major upgrade between 1996 and 1999. This note describes the specifications and configuration of the physical Input/Output devices and instrumentation of the 2 Tesla Superconducting Solenoid. The Solenoid and the VLPC cryostats both reside on the detector platform and are cooled by the Dzero Helium Refrigerator. The cryogenic process control s for these two components will be an extension of the TI565 programmable logic controller system used for other Dzero cryogenic controls. Two Input/Output Bases will be installed on the Dzero detector platform near the cryo corner. These I/O bases will handle all the sensor input and process control output devices from the Solenoid and VLPC cryostats. Having the I/O bases installed on the detector platform makes the connecting cabl ing to the platform much easier . All the instruments are wired directly to the I/O base. The bases have only one communications network cabl e that must be routed off the platform to the South side of the Dzero building.

  3. OPAL: An Open-Source MPI-IO Library over Cray XT

    SciTech Connect

    Yu, Weikuan; Vetter, Jeffrey S; Canon, Richard Shane

    2007-01-01

    Parallel IO over Cray XT is supported by a vendor-supplied MPI-IO package. This package contains a proprietary ADIO implementation built on top of the sysio library. While it is reasonable to maintain a stable code base for application scientists' convenience, it is also very important to the system developers and researchers to analyze and assess the effectiveness of parallel IO software, and accordingly, tune and optimize the MPI-IO implementation. A proprietary parallel IO code base relinquishes such flexibilities. On the other hand, a generic UFS-based MPI-IO implementation is typically used on many Linux-based platforms. We have developed an open-source MPI-IO package over Lustre, referred to as OPAL (OPportunistic and Adaptive MPI-IO Library over Lustre). OPAL provides a single source-code base for MPI-IO over Lustre on Cray XT and Linux platforms. Compared to Cray implementation, OPAL provides a number of good features, including arbitrary specification of striping patterns and Lustre-stripe aligned file domain partitioning. This paper presents the performance comparisons between OPAL and Cray's proprietary implementation. Our evaluation demonstrates that OPAL achieves the performance comparable to the Cray implementation. We also exemplify the benefits of an open source package in revealing the underpinning of the parallel IO performance.

  4. VisIO: enabling interactive visualization of ultra-scale, time-series data via high-bandwidth distributed I/O systems

    SciTech Connect

    Mitchell, Christopher J; Ahrens, James P; Wang, Jun

    2010-10-15

    Petascale simulations compute at resolutions ranging into billions of cells and write terabytes of data for visualization and analysis. Interactive visuaUzation of this time series is a desired step before starting a new run. The I/O subsystem and associated network often are a significant impediment to interactive visualization of time-varying data; as they are not configured or provisioned to provide necessary I/O read rates. In this paper, we propose a new I/O library for visualization applications: VisIO. Visualization applications commonly use N-to-N reads within their parallel enabled readers which provides an incentive for a shared-nothing approach to I/O, similar to other data-intensive approaches such as Hadoop. However, unlike other data-intensive applications, visualization requires: (1) interactive performance for large data volumes, (2) compatibility with MPI and POSIX file system semantics for compatibility with existing infrastructure, and (3) use of existing file formats and their stipulated data partitioning rules. VisIO, provides a mechanism for using a non-POSIX distributed file system to provide linear scaling of 110 bandwidth. In addition, we introduce a novel scheduling algorithm that helps to co-locate visualization processes on nodes with the requested data. Testing using VisIO integrated into Para View was conducted using the Hadoop Distributed File System (HDFS) on TACC's Longhorn cluster. A representative dataset, VPIC, across 128 nodes showed a 64.4% read performance improvement compared to the provided Lustre installation. Also tested, was a dataset representing a global ocean salinity simulation that showed a 51.4% improvement in read performance over Lustre when using our VisIO system. VisIO, provides powerful high-performance I/O services to visualization applications, allowing for interactive performance with ultra-scale, time-series data.

  5. Application of a new coordination compound for the preparation of AgI nanoparticles

    SciTech Connect

    Mohandes, Fatemeh; Salavati-Niasari, Masoud

    2013-10-15

    Graphical abstract: Silver iodide nanoparticles have been sonochemically synthesized by using silver salicylate complex, [Ag(HSal)], as silver precursor. A series of control experiments were carried out to investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures. - Highlights: • Silver salicylate as a new precursor was applied to fabricate γ-AgI nanoparticles. • To further decrease the particle size of AgI, SDS was used as surfactant. • The effect of preparation parameters on the particle size of AgI was investigated. - Abstract: AgI nanoparticles have been sonochemically synthesized by using silver salicylate, [Ag(HSal)], as silver precursor. To investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures, several experiments were carried out. The products were characterized by SEM, TEM, XRD, TGA/DTA, UV–vis, and FT-IR. Based on the experimental findings in this research, it was found that the size of AgI nanoparticles was dramatically dependent on the silver precursor, sonochemical irradiation, and surfactant concentration. Sodium dodecyl sulfate (SDS) was applied as surfactant. When the concentration of SDS was 0.055 mM, very uniform sphere-like AgI nanoparticles with grain size of about 25–30 nm were obtained. These results indicated that the high concentration of SDS could prevent the aggregation between colloidal nanoparticles due to its steric hindrance effect.

  6. Synthesis of Ag{sub 2}S nanorods by biomimetic method in the lysozyme matrix

    SciTech Connect

    Qin, Dezhi Zhang, Li; He, Guoxu; Zhang, Qiuxia

    2013-09-01

    Graphical abstract: - Highlights: • Firstly, Ag{sub 2}S nanorods were synthesized by biomimetic method in the lysozyme solutions. • The study of the interaction between Ag{sup +} and the lysozyme. • Discussion of possible formation mechanism of Ag{sub 2}S nanorods. • The synthesis process of lyso-conjugated Ag{sub 2}S nanocrystals is facile, effective and environment friendly. - Abstract: Ag{sub 2}S nanorods were successfully synthesized by biomimetic route in the lysozyme solution at physiological temperature and atmospheric pressure. The transmission electron microscopy (TEM) images revealed that the prepared nanorods are uniform and monodisperse with homogeneous size about 50 nm in diameter and 150 nm in length. The optical property of Ag{sub 2}S nanocrystals was studied by the ultraviolet–visible (UV–vis) and photoluminescence (PL) spectroscopy, the results show that the products exhibit well-defined emission at 471 nm and 496 nm excited by 292 nm. The interaction of Ag{sup +}/Ag{sub 2}S with the lysozyme was investigated through Fourier transform infrared (FT-IR) spectroscopy, which shows that the cooperation effect of the lysozyme and Ag{sup +} could be responsible for the formation of as obtained Ag{sub 2}S nanorods.

  7. IR-2003- | Department of Energy

    Energy Saver

    IR-2003- (20.04 KB) More Documents & Publications Fact Sheet: Clean Coal Technology Ushers In New Era in Energy Fact Sheet: Clean Coal Technology Ushers In New Era in Energy ...

  8. ARM - Datastreams - goes7ir

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ir Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  9. T-676: Apple iOS Certificate Chain Validation Flaw Lets Certain Remote

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Users Access or Modify SSL/TLS Sessions | Department of Energy 6: Apple iOS Certificate Chain Validation Flaw Lets Certain Remote Users Access or Modify SSL/TLS Sessions T-676: Apple iOS Certificate Chain Validation Flaw Lets Certain Remote Users Access or Modify SSL/TLS Sessions July 26, 2011 - 1:06am Addthis PROBLEM: A vulnerability was reported in Apple iOS. A remote user with the ability to conduct a man-in-the-middle attack can access or modify SSL/TLS sessions. PLATFORM: iOS 4.2.5

  10. Effect of Ag nanoparticle concentration on the electrical and ferroelectric properties of Ag/P(VDF-TrFE) composite films

    DOE PAGES [OSTI]

    Paik, Haemin; Choi, Yoon -Young; Hong, Seungbum; No, Kwangsoo

    2015-09-04

    We investigated the effect of the Ag nanoparticles on the ferroelectric and piezoelectric properties of Ag/poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) composite films. We found that the remanent polarization and direct piezoelectric coefficient increased up to 12.14 μC/cm2 and 20.23 pC/N when the Ag concentration increased up to 0.005 volume percent (v%) and decreased down to 9.38 μC/cm2 and 13.45 pC/N when it increased up to 0.01 v%. Further increase in Ag concentration resulted in precipitation of Ag phase and significant leakage current that hindered any meaningful measurement of the ferroelectric and piezoelectric properties. 46% increase of the remanent polarization value and 27% increasemore » of the direct piezoelectric coefficient were observed in the film with the 0.005 v% of the Ag nanoparticles added without significant changes to the crystalline structure confirmed by both X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) experiments. The enhancements of both the ferroelectric and piezoelectric properties are attributed to the increase in the effective electric field induced by the reduction in the effective volume of P(VDF-TrFE) that results in more aligned dipoles.« less

  11. Effect of Ag nanoparticle concentration on the electrical and ferroelectric properties of Ag/P(VDF-TrFE) composite films

    SciTech Connect

    Paik, Haemin; Choi, Yoon -Young; Hong, Seungbum; No, Kwangsoo

    2015-09-04

    We investigated the effect of the Ag nanoparticles on the ferroelectric and piezoelectric properties of Ag/poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) composite films. We found that the remanent polarization and direct piezoelectric coefficient increased up to 12.14 μC/cm2 and 20.23 pC/N when the Ag concentration increased up to 0.005 volume percent (v%) and decreased down to 9.38 μC/cm2 and 13.45 pC/N when it increased up to 0.01 v%. Further increase in Ag concentration resulted in precipitation of Ag phase and significant leakage current that hindered any meaningful measurement of the ferroelectric and piezoelectric properties. 46% increase of the remanent polarization value and 27% increase of the direct piezoelectric coefficient were observed in the film with the 0.005 v% of the Ag nanoparticles added without significant changes to the crystalline structure confirmed by both X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) experiments. The enhancements of both the ferroelectric and piezoelectric properties are attributed to the increase in the effective electric field induced by the reduction in the effective volume of P(VDF-TrFE) that results in more aligned dipoles.

  12. Stadtwerke Mainz AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Mainz AG Jump to: navigation, search Name: Stadtwerke Mainz AG Place: Mainz, Germany Zip: 55118 Product: Utility in Mainz, Germany. References: Stadtwerke Mainz AG1 This article...

  13. Edison-IO-CUG2014-paper-Zhao

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Performance on Cray XC30 Zhengji Zhao 1) , Doug Petesch 2) , David Knaak 2) , and Tina Declerck 1) 1) National Energy Research Scientific Center, Berkeley, CA 2) Cray, Inc., St. Paul, MN Email: {zzhao, tmdeclerck}@lbl.gov; {dpetesch, knaak}@cray.com Abstract-Edison is NERSC's newest petascale Cray XC30 system. Edison has three Lustre file systems deploying the Cray Sonexion storage systems. During the Edison acceptance test period, we measured the system I/O performance on a dedicated system

  14. Developments in ROOT I/O and trees

    SciTech Connect

    Brun, R.; Canal, P.; Frank, M.; Kreshuk, A.; Linev, S.; Russo, P.; Rademakers, F.; /CERN

    2008-01-01

    For the last several months the main focus of development in the ROOT I/O package has been code consolidation and performance improvements. We introduced a new pre-fetch mechanism to minimize the number of transactions between client and server, hence reducing the effect of latency on the time it takes to read a file both locally and over wide are network. We will review the implementation and how well it works in different conditions (gain of an order of magnitude for remote file access). We will also briefly describe new utilities, including a faster implementation of Tree cloning (gain of an order of magnitude), a generic mechanism for object references, and a new entry list mechanism tuned both for small and large number of selections. In addition to reducing the coupling with the core module and becoming its owns library (libRIO) (as part of the general restructuring of the ROOT libraries), the I/O package has been enhanced in the area of XML and SQL support, thread safety, schema evolution, tree queries, and many other areas.

  15. Loremo AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Loremo AG Place: Mnchen, Bavaria, Germany Zip: 80807 Product: Designer of a 157 mpg light weight 2 cylinder Turbo-Diesel car. References: Loremo AG1 This article is a...

  16. ASP AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: ASP AG Place: Laupen, Switzerland Zip: CH-8637 Product: Manufacturer of inverters for PV systems and other off- and on-grid applications. References: ASP AG1 This...

  17. An Optimizing Compiler for Petascale I/O on Leadership-Class Architectures

    SciTech Connect

    Kandemir, Mahmut Taylan; Choudary, Alok; Thakur, Rajeev

    2014-03-01

    In high-performance computing (HPC), parallel I/O architectures usually have very complex hierarchies with multiple layers that collectively constitute an I/O stack, including high-level I/O libraries such as PnetCDF and HDF5, I/O middleware such as MPI-IO, and parallel file systems such as PVFS and Lustre. Our DOE project explored automated instrumentation and compiler support for I/O intensive applications. Our project made significant progress towards understanding the complex I/O hierarchies of high-performance storage systems (including storage caches, HDDs, and SSDs), and designing and implementing state-of-the-art compiler/runtime system technology that targets I/O intensive HPC applications that target leadership class machine. This final report summarizes the major achievements of the project and also points out promising future directions Two new sections in this report compared to the previous report are IOGenie and SSD/NVM-specific optimizations.

  18. Theoretical studies of Ir5Th and Ir5Ce nanoscale precipitates in Ir

    SciTech Connect

    Morris, James R; Averill, Frank; Cooper, Valentino R

    2014-01-01

    Experimentally, it is known that very small amounts of thorium and/or cerium added to iridium metal form a precipitate, Ir5Th / Ir5Ce, which improves the high temperature mechanical properties of the resulting alloys. We demonstrate that there are low-energy configurations for nano-scale precipitates of these phases in Ir, and that these coherent arrangements may assist in producing improved mechanical properties. One precipitate/matrix orientation gives a particularly low interfacial energy, and a low lattice misfit. Nanolayer precipitates with this orientation are found to be likely to form, with little driving force to coarsen. The predicted morphology of the precipitates and their orientation with the matrix phase provide a potential experiment that could be used to test these predictions.

  19. Edison-IO-CUG2014-presentation-final.pptx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    1) , Doug Petesch 2) , David Knaak 2) , and Tina Declerck 1)! ! 1) NERSC! 2) Cray, Inc! Cray User Group Meting! May 7, 2014 I/O Performance on Cray XC30 Acknowledgement * Mark S wan a t C ray f or t he L MT d ata e xtrac5ons * Steve Luzmoor, P atrick F arrell a t C ray w ho h elped r esolving t he bug 8 09189. * Marcus P etschlies, a N ERSC u ser, f or p roviding I OBUF t est d ata with a Q LUA c ode. * Harvey W asserman a t N ERSC f or v aluable d iscussion a nd h elp * Shane C anon a t N ERSC,

  20. Microsoft PowerPoint - Salishan-FY06-IO-Keynote-GGrider

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    HPC I/O and File Systems, is everyone out to get us? Gary Grider, LANL LA-UR-06-1122 02/2006 Salishan FY06 What drives us? *Provide reliable, easy-to-use, high-performance, scalable, and secure, I/O *Via standard and other interfaces *MPI-IO, POSIX, etc. Archive Site Backbone Past Gener- ation ASCI Platform Current Gener- ation ASCI Platform Disk Rich Supercomputer Disk Rich Supercomputer Balanced System Approach Disk Poor Clients Diskless Clients Object Archive cluster File System Gateways

  1. High temperature Ir segregation in Ir-B ceramics: Effect of oxygen presence on stability of IrB2 and other Ir-B phases

    DOE PAGES [OSTI]

    Xie, Zhilin; Terracciano, Anthony C.; Cullen, David A.; Blair, Richard G.; Orlovskaya, Nina

    2015-05-13

    The formation of IrB2, IrB1.35, IrB1.1 and IrB monoboride phases in the Ir–B ceramic nanopowder was confirmed during mechanochemical reaction between metallic Ir and elemental B powders. The Ir–B phases were analysed after 90 h of high energy ball milling and after annealing of the powder for 72 h at 1050°C in vacuo. The iridium monoboride (IrB) orthorhombic phase was synthesised experimentally for the first time and identified by powder X-ray diffraction. Additionally, the ReB2 type IrB2 hexagonal phase was also produced for the first time and identified by high resolution transmission electron microscope. Ir segregation along disordered domains ofmore » the boron lattice was found to occur during high temperature annealing. Furthermore, these nanodomains may have useful catalytic properties.« less

  2. Bosch Solar Energy AG former ErSol Solar Energy AG | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    AG former ErSol Solar Energy AG Jump to: navigation, search Name: Bosch Solar Energy AG (former ErSol Solar Energy AG) Place: Erfurt, Germany Zip: D-99099 Product: Germany-based...

  3. PV Crystalox Solar AG formerly PV Silicon AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    PV Crystalox Solar AG formerly PV Silicon AG Jump to: navigation, search Name: PV Crystalox Solar AG (formerly PV Silicon AG) Place: Abingdon, England, United Kingdom Zip: OX14 4SE...

  4. T-676: Apple iOS Certificate Chain Validation Flaw Lets Certain...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Remote Users Access or Modify SSLTLS Sessions T-676: Apple iOS Certificate Chain Validation Flaw Lets Certain Remote Users Access or Modify SSLTLS Sessions July 26, 2011 - ...

  5. BASIN BLAN CO BLAN CO S OT ERO IGNAC IO-BLANCO AZ TEC BALLAR

    Energy Information Administration (EIA) (indexed site)

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1- 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline AZ UT NM CO 1 2 Index Map for 2 Paradox-San Juan Panels 2001 Reserve Summary for All Paradox-San Juan Basin Fields Total Total Total Number Liquid Gas BOE of Reserves Reserves Reserves Fields (Mbbl) (MMcf) (Mbbl) Paradox-San Juan 250 174,193 20,653,622 3,616,464 Basin CO NM IGNAC IO-BLANCO IGNAC IO-BLANCO IGNAC IO-BLANCO IGNAC IO-BLANCO

  6. High-Performance I/O: HDF5 for Lattice QCD

    SciTech Connect

    Kurth, Thorsten; Pochinsky, Andrew; Sarje, Abhinav; Syritsyn, Sergey; Walker-Loud, Andre

    2015-01-01

    Practitioners of lattice QCD/QFT have been some of the primary pioneer users of the state-of-the-art high-performance-computing systems, and contribute towards the stress tests of such new machines as soon as they become available. As with all aspects of high-performance-computing, I/O is becoming an increasingly specialized component of these systems. In order to take advantage of the latest available high-performance I/O infrastructure, to ensure reliability and backwards compatibility of data files, and to help unify the data structures used in lattice codes, we have incorporated parallel HDF5 I/O into the SciDAC supported USQCD software stack. Here we present the design and implementation of this I/O framework. Our HDF5 implementation outperforms optimized QIO at the 10-20% level and leaves room for further improvement by utilizing appropriate dataset chunking.

  7. U-165: Apple iOS Bugs Let Remote Users Execute Arbitrary Code...

    Energy Saver

    iOS. A remote user can cause arbitrary code to be executed on the target user's system. ... A remote user can create a specially crafted file that, when loaded by the target user, ...

  8. Parabel AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: Parabel AG Place: Berlin-Pankow, Berlin, Germany Sector: Solar Product: Sells a thin-film roofing product using UniSolar laminates, and distributes and...

  9. Sunline AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Sector: Solar Product: German solar PV and thermal company active in planning and marketing solar installations. References: Sunline AG1 This article is a stub. You can help...

  10. Solarion AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Germany Zip: 4288 Sector: Solar Product: Focuses on the development, production and marketing of CIGS thin-film solar cells on flexible substrate. References: Solarion AG1 This...

  11. Ecodasa AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Berlin, Berlin, Germany Zip: 13435 Product: Ecodasa is an integrated biodiesel producer with a planned capacity of 774m litres biodiesel until 2008. References:...

  12. Solemaxx AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: Solemaxx AG Place: Zug, Switzerland Zip: CH-6300 Sector: Renewable Energy, Solar Product: Switzerland-based solar project developer and renewable energy...

  13. Meeco AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    navigation, search Name: meeco AG Place: Zug, Switzerland Zip: 6304 Sector: Renewable Energy Product: Switzerland-based company that offers engineering and management solutions in...

  14. Sunways AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Constance, Germany Zip: D-78467 Product: German manufacturer of PV cells, modules, inverters and integrated systems. References: Sunways AG1 This article is a stub. You can...

  15. Conergy AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: Conergy AG Place: Hamburg, Hamburg, Germany Zip: 20537 Sector: Biofuels, Biomass, Wind energy Product: PV and passive system integrator and inverter...

  16. Cowatec AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Cowatec AG Place: Burglengenfeld, Bavaria, Germany Zip: 93133 Product: Cowatec is a biogas plant turnkey provider, also offering financial and permission planning. References:...

  17. Ristma AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: Ristma AG Place: GlisVS, Switzerland Zip: 3902 Product: Swiss battery pack manufacturer primarily for the handheld cordless power tool market. It is laos...

  18. Gorlitz AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Sector: Services Product: Company providing products and services in energy data communication and processing. References: Gorlitz AG1 This article is a stub. You can help...

  19. Carpevigo AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Name: Carpevigo AG Place: Holzkirchen, Germany Zip: 83607 Product: Carpevigo is a German turnkey PV project developer that issues bonds to finance investments. References:...

  20. Solarpraxis AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Publishes technical journals and organises conferences in building services, the copper industry and solar technology. References: Solarpraxis AG1 This article is a stub....

  1. OpenMortar.io: An Extensible Sensing and Control Platform for Building Energy Management

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    OpenMortar.io: An Extensible Sensing and Control Platform for Building Energy Management 2014 Building Technologies Office Peer Review Anthony Rowe, agr@ece.cmu.edu Carnegie Mellon University Project Summary Timeline: Start date: November 2013 (New Project) Planned end date: November 2016 Key Milestones 1. Functional Requirement Analysis; 03/14 2. First Version of Mortar.io; 04/14 Key Partners: Bosch RTC Lutron Electronics 3. Benchtop HVAC, Lighting, CMEL Integration; 10/14 4. Deploy in Scaife

  2. GLEAN: Scalable In Situ Analysis and I/O Acceleration on Leadership

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Computing Systems | Argonne Leadership Computing Facility GLEAN: Scalable In Situ Analysis and I/O Acceleration on Leadership Computing Systems GLEAN is a flexible and extensible framework that takes application, analysis, and system characteristics into account to facilitate simulation-time data analysis and I/O acceleration. The GLEAN infrastructure hides significant details from the end user, while at the same time providing a flexible intterface to the fastest path for their data and

  3. Active Storage with Analytics Capabilities and I/O Runtime System for Petascale Systems

    SciTech Connect

    Choudhary, Alok

    2015-03-18

    Computational scientists must understand results from experimental, observational and computational simulation generated data to gain insights and perform knowledge discovery. As systems approach the petascale range, problems that were unimaginable a few years ago are within reach. With the increasing volume and complexity of data produced by ultra-scale simulations and high-throughput experiments, understanding the science is largely hampered by the lack of comprehensive I/O, storage, acceleration of data manipulation, analysis, and mining tools. Scientists require techniques, tools and infrastructure to facilitate better understanding of their data, in particular the ability to effectively perform complex data analysis, statistical analysis and knowledge discovery. The goal of this work is to enable more effective analysis of scientific datasets through the integration of enhancements in the I/O stack, from active storage support at the file system layer to MPI-IO and high-level I/O library layers. We propose to provide software components to accelerate data analytics, mining, I/O, and knowledge discovery for large-scale scientific applications, thereby increasing productivity of both scientists and the systems. Our approaches include 1) design the interfaces in high-level I/O libraries, such as parallel netCDF, for applications to activate data mining operations at the lower I/O layers; 2) Enhance MPI-IO runtime systems to incorporate the functionality developed as a part of the runtime system design; 3) Develop parallel data mining programs as part of runtime library for server-side file system in PVFS file system; and 4) Prototype an active storage cluster, which will utilize multicore CPUs, GPUs, and FPGAs to carry out the data mining workload.

  4. Bosch Solar Energy AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Bosch Solar Energy AG Jump to: navigation, search Logo: Bosch Solar Energy AG Name: Bosch Solar Energy AG Address: Wilhelm-Wolff-Strasse 23 Place: Arnstadt, Germany Product: solar...

  5. AG Land 5 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    5 Jump to: navigation, search Name AG Land 5 Facility AG Land 5 Sector Wind energy Facility Type Community Wind Facility Status In Service Owner AG Land Energy LLC Developer...

  6. ABO Wind AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: ABO Wind AG Place: Hessen, Germany Zip: 65193 Sector: Bioenergy, Wind energy Product: German developer of wind and bioenergy generation assets....

  7. Seeger Engineering AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Seeger Engineering AG Place: Hessisch Lichtenau, Hessen, Germany Zip: 37235 Sector: Biomass, Services Product: Services range from project...

  8. SITIZN Group Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SITIZN Group Holding AG Jump to: navigation, search Name: SITIZN Group Holding AG Place: Riederich, Germany Zip: 72585 Sector: Solar Product: Germany-based solar technology and...

  9. AG Solutions Inc | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    navigation, search Name: AG Solutions Inc. Place: Gladstone, Michigan Product: 10Mgpy biodiesel producer in Gladstone, Michigan. References: AG Solutions Inc.1 This article is a...

  10. EOP Biodiesel AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    EOP Biodiesel AG Jump to: navigation, search Name: EOP Biodiesel AG Place: Falkenhagen, Germany Zip: 16928 Product: German producer of biodiesel from rapeseed. References: EOP...

  11. Clean Mobile AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Munich, Bavaria, Germany Sector: Vehicles Product: Manufacturer of fuel cell-powered drives for small vehicles. References: Clean Mobile AG1 This article is a...

  12. ADM Hamburg AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ADM Hamburg AG Jump to: navigation, search Name: ADM Hamburg AG Place: Hamburg, Hamburg, Germany Zip: 21107 Product: Biodiesel producer with a capacity of 595m litresyear....

  13. Norddeutsche Affinerie AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Affinerie AG Jump to: navigation, search Name: Norddeutsche Affinerie AG Place: Hamburg, Germany Zip: 20539 Product: Producer and recycler of copper. Coordinates: 53.553345,...

  14. Centrosolar Group AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Group AG Jump to: navigation, search Name: Centrosolar Group AG Place: Munich, Germany Zip: 80807 Product: German holding company of various PV-related subsidiaries....

  15. ASSET LOGISTIC AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    LOGISTIC AG Jump to: navigation, search Name: ASSET@LOGISTIC AG Place: Hamburg, Hamburg, Germany Zip: 20148 Sector: Wind energy Product: Developer of 3 wind farms in Almeria,...

  16. Power PLUS Communications AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    PLUS Communications AG Jump to: navigation, search Name: Power PLUS Communications AG Place: Mannheim, Germany Zip: 68167 Product: String representation "Power Plus Comm ... nergy...

  17. Sonne Wind Beteiligungen AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Sonne+Wind Beteiligungen AG Place: Berlin, Germany Zip: 10715 Sector: Efficiency, Solar, Wind energy Product: Berlin-based VC firm...

  18. Solar Millennium AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: Solar Millennium AG Place: Erlangen, Bavaria, Germany Zip: D-91052 Sector: Solar Product: Bavaria-based solar project developer; provides...

  19. Nature Elements Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Holding AG Jump to: navigation, search Name: Nature Elements Holding AG Place: Baar, Switzerland Zip: CH-6340 Sector: Renewable Energy Product: Swiss developer of renewable energy...

  20. Centrotec Sustainable AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Sustainable AG Jump to: navigation, search Name: Centrotec Sustainable AG Place: Brilon, Germany Zip: D - 59929 Sector: Solar Product: Provides gas flue and climate systems for...

  1. Energie AG Oberoesterreich | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energie AG Oberoesterreich Jump to: navigation, search Name: Energie AG Oberoesterreich Place: Linz, Austria Zip: 4021 Product: Utility focused on Upper Austria. Coordinates:...

  2. AGO AG Energie Anlagen | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AGO AG Energie Anlagen Jump to: navigation, search Name: AGO AG Energie + Anlagen Place: Kulmbach, Baden-Wrttemberg, Germany Zip: 95326 Sector: Biomass Product: Project...

  3. Edisun Power AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Zurich, Switzerland Zip: 8006 Sector: Solar Product: Edisun Power Europe AG finances, acquires and operates solar power installations, and markets solar power....

  4. Bernried Erdwarme AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Bernried Erdwarme AG Jump to: navigation, search Name: Bernried Erdwarme AG Place: Germany Sector: Geothermal energy Product: Germany-based geothermal development company....

  5. SolarHybrid AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SolarHybrid AG Jump to: navigation, search Name: SolarHybrid AG Place: Germany Sector: Solar Product: Germany-based solar thermal hybrid product manufacturer References:...

  6. REpower Systems AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Systems AG Jump to: navigation, search Name: REpower Systems AG Place: Hamburg, Germany Zip: D-22297 Sector: Services, Wind energy Product: Wind turbine manufacturer with...

  7. In Trust AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Trust AG Jump to: navigation, search Name: in-Trust AG Place: Regensburg, Bavaria, Germany Zip: 93047 Product: Germany-based investment company focused mainly on investing in...

  8. SolarWorld AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SolarWorld AG Jump to: navigation, search Name: SolarWorld AG Place: Bonn, Germany Zip: 53113 Product: Vertically integrated PV manufacturer, with factories in Freiberg, Germany...

  9. Krass Capital Group AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Krass Capital Group AG Jump to: navigation, search Name: Krass Capital Group AG Place: Grfelfing, Bulgaria Zip: 82166 Sector: Renewable Energy Product: Grafelfing-based firm...

  10. Meyer Burger AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Meyer Burger AG Jump to: navigation, search Name: Meyer Burger AG Place: Steffisburg, Switzerland Zip: 3613 Sector: Solar Product: Manufactures wire saws for cutting and processing...

  11. ENRO Geothermie AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    ENRO Geothermie AG Jump to: navigation, search Name: ENRO Geothermie AG Place: Essen, North Rhine-Westphalia, Germany Zip: 45128 Sector: Geothermal energy Product: Geothermal...

  12. Offshore Ostsee Wind AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Ostsee Wind AG Jump to: navigation, search Name: Offshore Ostsee Wind AG Place: Brgerende, Mecklenburg-Western Pomerania, Germany Zip: 18211 Sector: Wind energy Product: Joint...

  13. American Ag Fuels LLC | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    American Ag Fuels LLC Jump to: navigation, search Name: American Ag Fuels LLC Place: Defiance, Ohio Zip: 43512 Product: Biodiesel producer in Defiance, Ohio. References: American...

  14. Swiss Wafers AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Wafers AG Jump to: navigation, search Name: Swiss Wafers AG Place: Weinfelden, Switzerland Zip: 8570 Sector: Services Product: Swiss-based manufacturer of mono and multicrystalline...

  15. Module Solar AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Module Solar AG Jump to: navigation, search Name: Module Solar AG Place: Baar, Switzerland Product: A Swiss PV module and materials supplier and developer Coordinates: 40.808083,...

  16. Huber and Suhner AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Suhner AG Jump to: navigation, search Name: Huber and Suhner AG Place: Pfaeffikon, Switzerland Zip: 8330 Sector: Solar Product: Huber and Suhner specialises in electrical and...

  17. Novel visible-light AgBr/Ag?PO? hybrids photocatalysts with surface plasma resonance effects

    SciTech Connect

    Wang, Yunfang Li, Xiuli; Wang, Yawen; Fan, Caimei

    2013-06-01

    Three kinds of AgBr/Ag?PO? hybrids were synthesised via an anion-exchange precipitation method and characterised by XRD, XPS, SEM, EDS, and UVvis. The results showed that AgBr/Ag?PO? hybrids displayed much higher photocatalytic activities than single Ag?PO? or AgBr under visible light (?>420 nm), and OH and h? were the major active species during the degradation process. Considering interstitial ions Ag?? on lattice gap of AgBr are easy to become sliver particle, we deduced the possible photocatalytic mechanism could be ascribed to the synergistic effects of the appropriate valence band position of Ag?PO? and AgBr, surface plasmon resonance effect of Ag?, reactive radical species Br?, and the Ag vacancy on the surface of catalysts. - Graphical abstract: The optical absorption and structural morphology of the as-prepared AgBr@Ag?PO? photocatalyst using an anion-exchange precipitation method are conductive to the photocatalytic degradation of organics in water. Highlights: Novel AgBr/Ag?PO? hybrids are synthesised by a facile method. AgBr/Ag?PO? hybrids show excellent photocatalytic activities under visible light. Interstitial ions are in favour of the formation of Ag particle. Surface plasmon resonance effect plays a key factor for light absorption. The photocatalytic mechanism for AgBr/Ag?PO? hybrids is studied.

  18. An evaluation of Java's I/O capabilities for high-performance computing.

    SciTech Connect

    Dickens, P. M.; Thakur, R.

    2000-11-10

    Java is quickly becoming the preferred language for writing distributed applications because of its inherent support for programming on distributed platforms. In particular, Java provides compile-time and run-time security, automatic garbage collection, inherent support for multithreading, support for persistent objects and object migration, and portability. Given these significant advantages of Java, there is a growing interest in using Java for high-performance computing applications. To be successful in the high-performance computing domain, however, Java must have the capability to efficiently handle the significant I/O requirements commonly found in high-performance computing applications. While there has been significant research in high-performance I/O using languages such as C, C++, and Fortran, there has been relatively little research into the I/O capabilities of Java. In this paper, we evaluate the I/O capabilities of Java for high-performance computing. We examine several approaches that attempt to provide high-performance I/O--many of which are not obvious at first glance--and investigate their performance in both parallel and multithreaded environments. We also provide suggestions for expanding the I/O capabilities of Java to better support the needs of high-performance computing applications.

  19. Understanding I/O workload characteristics of a Peta-scale storage system

    SciTech Connect

    Kim, Youngjae; Gunasekaran, Raghul

    2015-01-01

    Understanding workload characteristics is critical for optimizing and improving the performance of current systems and software, and architecting new storage systems based on observed workload patterns. In this paper, we characterize the I/O workloads of scientific applications of one of the world s fastest high performance computing (HPC) storage cluster, Spider, at the Oak Ridge Leadership Computing Facility (OLCF). OLCF flagship petascale simulation platform, Titan, and other large HPC clusters, in total over 250 thousands compute cores, depend on Spider for their I/O needs. We characterize the system utilization, the demands of reads and writes, idle time, storage space utilization, and the distribution of read requests to write requests for the Peta-scale Storage Systems. From this study, we develop synthesized workloads, and we show that the read and write I/O bandwidth usage as well as the inter-arrival time of requests can be modeled as a Pareto distribution. We also study the I/O load imbalance problems using I/O performance data collected from the Spider storage system.

  20. A novel polythreading Ag(I) coordination polymer with blue photoluminescence

    SciTech Connect

    Duan, Xian-Ying; Yao, Jing; Lu, Chang-Sheng; Meng, Qing-Jin

    2013-04-15

    One new compound, [Ag(p-bix)]{sub 3}[Ag(Hbtc){sub 2}]·2H{sub 2}O (H{sub 3}btc=1,2,4-benzenetricarboxylate, p-bix=1,4-bis(imidazol-1-ylmethyl)-benzene), has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, PXRD, luminescent analysis, and single-crystal X-ray diffraction. X-ray structural analysis revealed that 0-D unit [Ag(Hbtc){sub 2}]{sup 3−} and two kinds of 1-D linear chain [Ag(p-bix)]{sub ∞}{sup +}, can be found within the crystal structure. The combination of 0-D [Ag(Hbtc){sub 2}]{sup 3−} unit and 1-D undulated chain [Ag1(p{sub 1}-bix)]{sub ∞}{sup +} through weak Ag–O bond gave rise to 2-D anionic supramolecular doublelayer. Then the grids of the 2-D layer are threaded by 1-D linear cationic chain [Ag2(p{sub 2}-bix)]{sub ∞}{sup +} to generate entangled 3-D architecture with unusual poly(pseudo-rotaxane)-type arrangements. Luminescent properties of the title complex were also studied in this paper. - Graphical abstract: Novel 3D polythreading supramolecular architecture was constructed, in which 1D linear cationic chains [Ag(p{sub 2}-bix)]{sub ∞}{sup +} threaded into the grid of weak Ag–O bonded anionic 2D sheet. Highlights: ► Novel 1D{sup +}+2D{sup −}→3D polythreading coordination complex was reported. ► Diverse conformations of p-bix result in different 1D [Ag(p-bix)]{sub ∞}{sup +} chains. ► The title complex displayed blue photoluminescence at room temperature.

  1. Systaic AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Duesseldorf, North Rhine-Westphalia, Germany Zip: D-40213 Sector: Solar Product: Has developed and is installing a building-integrated PV roof, which can be used as...

  2. Sinosol AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solar Product: Buys PV modules and solar passive systems in China and sells them in Europe. References: Sinosol AG1 This article is a stub. You can help OpenEI by expanding...

  3. The parallel I/O architecture of the High Performance Storage System (HPSS)

    SciTech Connect

    Watson, R.W.; Coyne, R.A.

    1995-02-01

    Rapid improvements in computational science, processing capability, main memory sizes, data collection devices, multimedia capabilities and integration of enterprise data are producing very large datasets (10s-100s of gigabytes to terabytes). This rapid growth of data has resulted in a serious imbalance in I/O and storage system performance and functionality. One promising approach to restoring balanced I/O and storage system performance is use of parallel data transfer techniques for client access to storage, device-to-device transfers, and remote file transfers. This paper describes the parallel I/O architecture and mechanisms, Parallel Transport Protocol, parallel FIP, and parallel client Application Programming Interface (API) used by the High Performance Storage System (HPSS). Parallel storage integration issues with a local parallel file system are also discussed.

  4. High temperature Ir segregation in Ir-B ceramics: Effect of oxygen presence on stability of IrB2 and other Ir-B phases

    SciTech Connect

    Xie, Zhilin; Terracciano, Anthony C.; Cullen, David A.; Blair, Richard G.; Orlovskaya, Nina

    2015-05-13

    The formation of IrB2, IrB1.35, IrB1.1 and IrB monoboride phases in the Ir–B ceramic nanopowder was confirmed during mechanochemical reaction between metallic Ir and elemental B powders. The Ir–B phases were analysed after 90 h of high energy ball milling and after annealing of the powder for 72 h at 1050°C in vacuo. The iridium monoboride (IrB) orthorhombic phase was synthesised experimentally for the first time and identified by powder X-ray diffraction. Additionally, the ReB2 type IrB2 hexagonal phase was also produced for the first time and identified by high resolution transmission electron microscope. Ir segregation along disordered domains of the boron lattice was found to occur during high temperature annealing. Furthermore, these nanodomains may have useful catalytic properties.

  5. I/O values for determination of the origin of some indoor organic pollutants

    SciTech Connect

    Otson, R.; Zhu, J.

    1997-12-31

    To reduce human health risks resulting from exposure to toxic chemicals, it is important to determine the origin of such substances. The ratio (I/O) of indoor to outdoor concentrations of selected airborne vapor phase organic compounds (VPOC) was used to estimate the contribution of indoor sources to levels of the compounds in the air of 44 homes selected randomly in the Greater Toronto Area (GTA). Average I/O values for all of the homes were greater 1.5 for 10 of the 20 detected target compounds, and it could be concluded that indoor VPOC sources had a greater impact on indoor air quality than outdoor air in these instances. A significant finding, which aptly demonstrates the importance of indoor sources and pollution, was the overall I/O value of 5.2 for the 44 representative GTA homes. Possible indoor sources for most of the 10 compounds could be identified, based on information collected by means of a questionnaire, as well as from the scientific literature. However, possible sources for some compounds could not be determined as readily, probably because of the presence of multiple sources, and sources which had not been previously noted, such as foods and beverages. The sensitivity of I/O values to various factors (e.g., source strength, air exchange rates, precision of measurements, unanticipated sources), and the reliability of determining the origin of pollutants by use of I/O values alone were examined, with some examples. If used judiciously, the I/O value can be a useful tool for IAQ investigations.

  6. Extending the POSIX I/O interface: a parallel file system perspective.

    SciTech Connect

    Vilayannur, M.; Lang, S.; Ross, R.; Klundt, R.; Ward, L.; Mathematics and Computer Science; VMWare, Inc.; SNL

    2008-12-11

    The POSIX interface does not lend itself well to enabling good performance for high-end applications. Extensions are needed in the POSIX I/O interface so that high-concurrency HPC applications running on top of parallel file systems perform well. This paper presents the rationale, design, and evaluation of a reference implementation of a subset of the POSIX I/O interfaces on a widely used parallel file system (PVFS) on clusters. Experimental results on a set of micro-benchmarks confirm that the extensions to the POSIX interface greatly improve scalability and performance.

  7. Theoretical investigations of the IO,{sup q+} (q = 2, 3, 4) multi-charged ions: Metastability, characterization and spectroscopy

    SciTech Connect

    Hammami, H.; Yazidi, O.; Ben El Hadj Rhouma, M.; Al Mogren, M. M.; Hochlaf, M.

    2014-07-07

    Using ab initio methodology, we studied the IO{sup q+} (q = 2, 3, 4) multi-charged ions. Benchmark computations on the IO(X{sup 2}Π) neutral species allow validate the current procedure. For IO{sup 2+}, several potential wells were found on the ground and the electronic excited states potentials with potential barriers with respect to dissociation, where this dication can exist in the gas phase as long-lived metastable molecules. We confirm hence the recent observation of the dication by mass spectrometry. Moreover, we predict the existence of the metastable IO{sup 3+} trication, where a shallow potential well along the IO internuclear distance is computed. This potential well supports more than 10 vibrational levels. The IO{sup 3+} excited states are repulsive in nature, as well as the computed potentials for the IO{sup 4+} tetracation. For the bound states, we give a set of spectroscopic parameters including excitation transition energies, equilibrium distances, harmonic and anharmonic vibrational terms, and rotational constants. At the MRCI + Q/aug-cc-pV5Z(-PP) level, the adiabatic double and triple ionization energies of IO are computed to be ∼28.1 eV and ∼55.0 eV, respectively.

  8. Lake County Ag Park Greenhouse Low Temperature Geothermal Facility...

    OpenEI (Open Energy Information) [EERE & EIA]

    Ag Park Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Lake County Ag Park Greenhouse Low Temperature Geothermal Facility Facility Lake County Ag...

  9. Facile synthesis of pompon-like ZnO-Ag nanocomposites and their enhanced photocatalytic performance

    SciTech Connect

    Cheng, Yang; An, Liang; Lan, Jing; Gao, Fang; Tan, Ruiqin; Li, Xiao-min; Wang, Guang-hui

    2013-10-15

    Graphical abstract: - Highlights: • Pompon-like ZnO-Ag was prepared via heterothermal and photodeposition method. • Pompon-like ZnO-Ag is a excellent photocatalyst for degradation of azo dyes. • The photocatalytic and wetting properties were studied upon UV irradiation. • The discoloring efficiency of ZnO-Ag heterostructure toward to azo dyes is 99.1%. - Abstract: A series of pompon-like ZnO-Ag nanocomposites were prepared by hydrothermal method and photochemical deposition technique. Several characterizations indicated the successful deposition of Ag nanoparticles on ZnO. As a whole, the as-prepared composites present pompon-like nanostructures with a diameter of ∼10 μm. In detail, the nanostructural, chemical and optical properties were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), infrared spectroscopy (IR), ultra-visible spectra (UV). The photocatalytic degradation experiments under UV irradiation using Methyl Orange (MO) as a model dye were executed here. The relative results demonstrated that the pompon-like ZnO-Ag nanocomposite with a suitable content of Ag nanoparticles (about 4.82 wt%) has the highest photochemical activity, and the removal ratio of MO was 99.1% after 0.5 h adsorption and subsequent 2 h photodegradation processes. The excellent photocatalytic performance was attributed to the high surface areas of ZnO nanostructure and effectively separation of photo-generated charge on flower-like ZnO by employing Ag nanoparticles as a conductor.

  10. U-121: Apple iOS Bugs Let Remote Users Execute Arbitrary Code...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ID: 1026774 Apple Security Updates About the security content of iOS 5.1 Software Update CVE-2012-0641, CVE-2012-0642, CVE-2012-0643, CVE-2011-3453, CVE-2012-0644, CVE-2012-0585,...

  11. ARM - Datastreams - goes7ir8

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ir8 Documentation XDC documentation Data Quality Plots ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA....

  12. Sol e Suisse AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Suisse AG Jump to: navigation, search Name: Sol-e Suisse AG Place: Berne, Switzerland Zip: 25 Sector: Renewable Energy Product: Renewable energy division of BKW FMB Energy Ltd....

  13. Ag Fuels Ltd | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    to: navigation, search Name: Ag Fuels Ltd Place: Sealy, Texas Product: 3.6Mgpl (13.6Mlpy) biodiesel producer in Sealy, Texas. References: Ag Fuels Ltd1 This article is a stub....

  14. AgPro | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: AgPro Place: Massena, New York Product: Operator of biodiesel plant based on soy. References: AgPro1 This article is a stub. You can help OpenEI...

  15. MAN Ferrostaal AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Jump to: navigation, search Name: MAN Ferrostaal AG Place: Essen, Germany Zip: 45128 Sector: Solar Product: Germany-based firm that focuses on the development and realisation of...

  16. Payom Solar AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Payom Solar AG Jump to: navigation, search Name: Payom Solar AG Place: Merkendorf, Germany Zip: 91732 Product: Germany-based installer of roof-mounted PV plants, which also trades...

  17. SGL Carbon AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Carbon AG Jump to: navigation, search Name: SGL Carbon AG Place: Wiesbaden, Hessen, Germany Zip: 65203 Sector: Carbon Product: A Germany-based manufacturer of carbon-based products...

  18. Summary of the Optics, IR, Injection, Operations, Reliability...

    Office of Scientific and Technical Information (OSTI)

    Summary of the Optics, IR, Injection, Operations, Reliability and Instrumentation Working Group Citation Details In-Document Search Title: Summary of the Optics, IR, Injection, ...

  19. IR Spectral Bands and Performance | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    2013 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for IR Spectral Bands and Performance Citation Chris Douglass. IR Spectral Bands...

  20. AGS 20th anniversary celebration

    SciTech Connect

    Baggett, N.V.

    1980-05-22

    On May 22, 1980, a symposium was held at Brookhaven to celebrate the 20th birthday of the AGS, to recall its beginnings, and to review major discoveries that have been made with its beams. The talks at the symposium are recorded in this volume.

  1. U-165: Apple iOS Bugs Let Remote Users Execute Arbitrary Code and Spoof Address Bar URLs

    Energy.gov [DOE]

    Two vulnerabilities were reported in Apple iOS. A remote user can cause arbitrary code to be executed on the target user's system. A remote user can spoof the address bar URL.

  2. Preemptible I/O Scheduling of Garbage Collection for Solid State Drives

    SciTech Connect

    Lee, Junghee; Kim, Youngjae; Shipman, Galen M; Oral, H Sarp; Kim, Jongman

    2012-01-01

    Abstract Unlike hard disks, flash devices use out-of-update operations and they require a garbage collection (GC) process to reclaim invalid pages to create free blocks. This GC process is a major cause of performance degradation when running concurrently with other I/O operations as internal bandwidth is consumed to reclaim these invalid pages. The invocation of the GC process is generally governed by a low watermark on free blocks and other internal device metrics that different workloads meet at different intervals. This results in I/O performance that is highly dependent on workload characteristics. In this paper, we examine the GC process and propose a semi-preemptible GC scheme that allows GC processing to be preempted while pending I/O requests in the queue are serviced. Moreover, we further enhance flash performance by pipelining internal GC operations and merge them with pending I/O requests whenever possible. Our experimental evaluation of this semipreemptible GC scheme with realistic workloads demonstrate both improved performance and reduced performance variability. Write-dominant workloads show up to a 66.56% improvement in average response time with a 83.30% reduced variance in response time compared to the non-preemptible GC scheme. In addition, we explore opportunities of a new NAND flash device that supports suspend/resume commands for read, write and erase operations for fully preemptible GC. Our experiments with a fully preemptible GC enabled flash device show that request response time can be improved by up to 14.57% compared to semi-preemptible GC.

  3. Investigation and design of a network, I/O and storage SDC susceptibility analzer

    SciTech Connect

    Dubois, Andrew; Dubois, David; Michalak, Sarah

    2011-01-19

    This slide deck is intended for the Durmstrang Team Quarterly Review to be held January 25, 2011 in Baltimore, MD. The slides provide an overview of the Investigation and Design of a Network, I/O and Storage SDC Susceptibility Analyzer project. In addition, the slides provide the goals of the project, details of the work done to date and the project status and future work.

  4. Mortar.io - Open BAS Platform Electrical and Computer Engineering Department

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mortar.io - Open BAS Platform Electrical and Computer Engineering Department 1 Carnegie Mellon University Civil and Environmental Engineering Department 2 Carnegie Mellon University Anthony Rowe 1 , Mario Bérges 2 , Christopher Martin 3 Max Buevich 1 , Jingkun Gao 2 , Suman Giri 2 , Emre Kara 2 , Patrick Lazik 1 , Chris Palmer 1 , Niranjini Rajagopal 1 , Oliver Shih 1 Bosch Research and Technology Center 3 Sensor Andrew What's in a name? 3 Andrew Carnegie Andrew Mellon + Andrew File System

  5. Minimizing I/O Costs of Multi-Dimensional Queries with BitmapIndices

    SciTech Connect

    Rotem, Doron; Stockinger, Kurt; Wu, Kesheng

    2006-03-30

    Bitmap indices have been widely used in scientific applications and commercial systems for processing complex,multi-dimensional queries where traditional tree-based indices would not work efficiently. A common approach for reducing the size of a bitmap index for high cardinality attributes is to group ranges of values of an attribute into bins and then build a bitmap for each bin rather than a bitmap for each value of the attribute. Binning reduces storage costs,however, results of queries based on bins often require additional filtering for discarding it false positives, i.e., records in the result that do not satisfy the query constraints. This additional filtering,also known as ''candidate checking,'' requires access to the base data on disk and involves significant I/O costs. This paper studies strategies for minimizing the I/O costs for ''candidate checking'' for multi-dimensional queries. This is done by determining the number of bins allocated for each dimension and then placing bin boundaries in optimal locations. Our algorithms use knowledge of data distribution and query workload. We derive several analytical results concerning optimal bin allocation for a probabilistic query model. Our experimental evaluation with real life data shows an average I/O cost improvement of at least a factor of 10 for multi-dimensional queries on datasets from two different applications. Our experiments also indicate that the speedup increases with the number of query dimensions.

  6. 3S Industries AG Formerly 3S Swiss Solar Systems AG | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: 3S Industries AG (Formerly 3S Swiss Solar Systems AG) Place: Bern, Switzerland Zip: CH-3006 Product: Swiss-based manufacturer of manual and semi-automatic PV...

  7. TriWo AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    TriWo AG Place: Trier, Denmark Zip: 54290 Sector: Solar Product: Developer of solar photovoltaic electricity generation project in Germany. Coordinates: 49.757256, 6.636521...

  8. ASP Aton Sunpower AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zug, Switzerland Product: Zug-based project developer focused on the installaion of photovoltaic facilities. References: ASP Aton Sunpower AG1 This article is a stub. You can...

  9. Ag Processing Inc AGP | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Nebraska Zip: 68103-2047 Product: Cooperative engaged in the procurement, processing, marketing, and transportation of grains and grain products. References: Ag Processing Inc....

  10. Husker Ag LLC | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: Husker Ag LLC Place: Plainview, Nebraska Zip: 68769 Product: Bioethanol producer using corn as feedstock. Coordinates: 34.197675, -101.698139 Show Map...

  11. Getec AG Contracting | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: Getec AG Contracting Place: Magdeburg, Saxony-Anhalt, Germany Zip: 39108 Sector: Efficiency Product: German Efficiency Service Company....

  12. 3C Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    am Main, Germany Zip: 61118 Sector: Services Product: 3C Holding AG develops trading strategies for EU allowances, JICDM Projects and climate neutral events, products...

  13. Energiecontracting Heidelberg AG ECH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Baden-Wrttemberg, Germany Zip: 69126 Product: Consultancy specialised in local energy supply. References: Energiecontracting Heidelberg AG (ECH)1 This article is a...

  14. AG Plus Co operative | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Plus Co operative Jump to: navigation, search Name: AG Plus Co-operative Place: SE Kindred, North Dakota Zip: 58051 Product: Cooperative offering membership stock to agricultural...

  15. Unit Energy Europe AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Wind energy Product: Unit Energy develops and operates wind parks and hydroelectric power plants all across Europe. References: Unit Energy Europe AG1 This article is a stub....

  16. Inventux Technologies AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Steinhagen, Germany Zip: D-33803 Product: German manufacturer of micromorph tandem thin-film modules. Coordinates: 52.004606, 8.414257 Show Map Loading map......

  17. EnerVest AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: EnerVest AG Place: Mnchen, Germany Zip: 80538 Sector: Renewable Energy, Wind energy Product: EnerVest develops and manages renewable energy projects,...

  18. Denker Wulf AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    navigation, search Name: Denker & Wulf AG Place: Sehestedt, Germany Zip: 24814 Sector: Wind energy Product: Wind project developer, also provides innovative wind energy financing....

  19. EnergieKontor AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: EnergieKontor AG Place: Bremen, Bremen, Germany Zip: 28359 Sector: Wind energy Product: Bremen-based european wind project developer and wind farm operator....

  20. Bullith Batteries AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Batteries AG Place: Ismaning, Germany Zip: 85737 Product: Batteries producer using the lithium-polymer technology. Coordinates: 48.22727, 11.676305 Show Map Loading map......

  1. Solar Fabrik AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zip: 79111 Product: Freiburg-based manufacturer of wafers, PV cells, modules and inverters, largely through acquisitions. References: Solar Fabrik AG1 This article is a...

  2. MAMA Sustainable Incubation AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    for emerging green-markets such as renewable energy, sustainable architecture and water treatment. References: MAMA Sustainable Incubation AG1 This article is a stub. You...

  3. Centrotherm Photovoltaics AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Blaubeuren, Germany Zip: 89143 Sector: Services Product: Provides turnkey manufacturing equipment for crystalline silicon PV cells, and Siemens reactors and engineering...

  4. LEONI Studer AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Studer AG Place: Daniken, Switzerland Zip: 4658 Product: Switzerland-based cable manufacturing firm. The firm also produces PV junction boxes. Coordinates: 50.966671, 5.85...

  5. SolarMarkt AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    navigation, search Name: SolarMarkt AG Place: Freiburg, Germany Zip: 79114 Product: A German PV installation company for small to mid-sized projects and BIPV. References:...

  6. Enginion AG insolvent | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    (CHP) systems. The company's SteamCell product is targeted at the residential, automotive and portable power markets. References: Enginion AG (insolvent )1 This article is...

  7. BGZ Beteiligungsgesellschaft Zukunftsenergien AG | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Zukunftsenergien AG Place: Husum, Germany Zip: 25813 Sector: Solar, Wind energy Product: Finance and management holding, esp. for wind and solar projects....

  8. Pegasus Energietechnik AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG Place: Mhldorf am Inn, Germany Zip: 84453 Sector: Renewable Energy Product: Germany-based renewable energy developer assisting with projects in Europe. References:...

  9. Energiedienst Holding AG EDH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: Energiedienst Holding AG (EDH) Place: Laufenburg, Switzerland Zip: 5080 Product: Utility active in Switzerland and Germany. Coordinates:...

  10. Sunseeker Energy Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Jump to: navigation, search Name: Sunseeker Energy Holding AG Place: Schindellegi, Switzerland Zip: 8834 Sector: Solar Product: Switzerland-based company seeking to developing...

  11. Stangl Semiconductor Equipment AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    German manufacturer of wet chemistry systems for processing silicon and thin-film solar cells. References: Stangl Semiconductor Equipment AG1 This article is a stub. You...

  12. DB-Netz AG Offices

    Building Catalog

    Hamm, Germany The new office building for DB Netz AG was designed by the collaborative team of Architrav Architects and the Buildings Physics and Technical Building Services group of the University of Karlsruhe. The team developed an energy efficient building concept for the 64,304 sqft office building, located in Hamm, Germany. The design concept of the building is dominated by architectural solutions for ventilation, cooling and lighting. Use of HVAC and electric lighting is minimized as much as possible. 05/15/2015 - 10:35

  13. US-CERT Control System Center Input/Output (I/O) Conceputal Design

    SciTech Connect

    Not Available

    2005-02-01

    This document was prepared for the US-CERT Control Systems Center of the National Cyber Security Division (NCSD) of the Department of Homeland Security (DHS). DHS has been tasked under the Homeland Security Act of 2002 to coordinate the overall national effort to enhance the protection of the national critical infrastructure. Homeland Security Presidential Directive HSPD-7 directs the federal departments to identify and prioritize critical infrastructure and protect it from terrorist attack. The US-CERT National Strategy for Control Systems Security was prepared by the NCSD to address the control system security component addressed in the National Strategy to Secure Cyberspace and the National Strategy for the Physical Protection of Critical Infrastructures and Key Assets. The US-CERT National Strategy for Control Systems Security identified five high-level strategic goals for improving cyber security of control systems; the I/O upgrade described in this document supports these goals. The vulnerability assessment Test Bed, located in the Information Operations Research Center (IORC) facility at Idaho National Laboratory (INL), consists of a cyber test facility integrated with multiple test beds that simulate the nation's critical infrastructure. The fundamental mission of the Test Bed is to provide industry owner/operators, system vendors, and multi-agency partners of the INL National Security Division a platform for vulnerability assessments of control systems. The Input/Output (I/O) upgrade to the Test Bed (see Work Package 3.1 of the FY-05 Annual Work Plan) will provide for the expansion of assessment capabilities within the IORC facility. It will also provide capabilities to connect test beds within the Test Range and other Laboratory resources. This will allow real time I/O data input and communication channels for full replications of control systems (Process Control Systems [PCS], Supervisory Control and Data Acquisition Systems [SCADA], and components

  14. TIDAL HEATING IN A MAGMA OCEAN WITHIN JUPITER’S MOON Io

    SciTech Connect

    Tyler, Robert H.; Henning, Wade G.; Hamilton, Christopher W.

    2015-06-22

    Active volcanism observed on Io is thought to be driven by the temporally periodic, spatially differential projection of Jupiter's gravitational field over the moon. Previous theoretical estimates of the tidal heat have all treated Io as essentially a solid, with fluids addressed only through adjustment of rheological parameters rather than through appropriate extension of the dynamics. These previous estimates of the tidal response and associated heat generation on Io are therefore incomplete and possibly erroneous because dynamical aspects of the fluid behavior are not permitted in the modeling approach. Here we address this by modeling the partial-melt asthenosphere as a global layer of fluid governed by the Laplace Tidal Equations. Solutions for the tidal response are then compared with solutions obtained following the traditional solid-material approach. It is found that the tidal heat in the solid can match that of the average observed heat flux (nominally 2.25 W m{sup −2}), though only over a very restricted range of plausible parameters, and that the distribution of the solid tidal heat flux cannot readily explain a longitudinal shift in the observed (inferred) low-latitude heat fluxes. The tidal heat in the fluid reaches that observed over a wider range of plausible parameters, and can also readily provide the longitudinal offset. Finally, expected feedbacks and coupling between the solid/fluid tides are discussed. Most broadly, the results suggest that both solid and fluid tidal-response estimates must be considered in exoplanet studies, particularly where orbital migration under tidal dissipation is addressed.

  15. Synthesis, crystal structures and luminescent properties of two 4d-4f Ln-Ag heterometallic coordination polymers based on anion template

    SciTech Connect

    Fan, Le-Qing; Chen, Yuan; Wu, Ji-Huai; Huang, Yun-Fang

    2011-04-15

    Two new 4d-4f Ln-Ag heterometallic coordination polymers, {l_brace}[Ln{sub 3}Ag{sub 5}(IN){sub 10}(H{sub 2}O){sub 7}].4(ClO{sub 4}).4(H{sub 2}O){r_brace}{sub n} (Ln=Eu (1) and Sm (2), HIN=isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln{sub 2}O{sub 3}, AgNO{sub 3}, HIN and HClO{sub 4}, and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. It is proved that HClO{sub 4} not only adjusts the pH value of the reaction mixture, but also acts as anion template. The structure determination reveals that 1 and 2 are isostructural and feature a novel two-dimensional (2D) layered hetrometallic structure constructed from one-dimensional Ln-carboxylate chains and pillared Ag(IN){sub 2} units. The 2D layers are further interlinked through Ag...Ag and Ag...O(ClO{sub 4}{sup -}) multiple weak interactions, which form a rare Ag-ClO{sub 4} ribbon in lanthanide-transition metal coordination polymers, to give rise to a three-dimensional supramolecular architecture. Moreover, the luminescent properties of these two compounds have also been investigated at room temperature. -- Graphical abstract: Two new anion-templated 2D 4d-4f Ln-Ag heterometallic coordination polymers based on novel lanthanide-carboxylate chains and pillared Ag(IN){sub 2} units, {l_brace}[Ln{sub 3}Ag{sub 5}(IN){sub 10}(H{sub 2}O){sub 7}].4(ClO{sub 4}).4(H{sub 2}O){r_brace}{sub n} (Ln=Eu (1) and Sm (2), HIN=isonicotinic acid), have been hydrothermally synthesized and structurally characterized. 1 and 2 exhibit good luminescent properties. Display Omitted Research highlights: > Two 2D Eu (Sm)-Ag coordination polymers templated by perchlorate anion have been synthesized. > Polymers consist of novel 1D lanthanide-carboxylate chains. > In both structures, there are rare Ag...Ag and Ag...O(ClO{sub 4}{sup -}) multiple weak interactions. > Both compounds exhibit good luminescent properties.

  16. Three new Ag(I) coordination architectures based on mixed ligands: Syntheses, structures and photoluminescent properties

    SciTech Connect

    Li, Yamin; Xiao, Changyu; Li, Shu; Chen, Qi; Li, Beibei; Liao, Qian; Niu, Jingyang

    2013-04-15

    Three new silver (I) coordination complexes, [Ag{sub 2}(1,2-bdc)(phdat)]{sub n} (1), [Ag{sub 2}(NO{sub 2}-bdc)(phdat)]{sub n} (2), [Ag{sub 4}(nta){sub 3}(phdat)NO{sub 3}]{sub n} (3) (1,2-bdc=phthalic acid dianion, NO{sub 2}-bdc=5-nitro-1,3-benzenedicarboxylic acid dianion, nta=nicotinic acid anion, phdat=2,4-diamine-6-phenyl-1,3,5-triazine) have been hydrothermally synthesized by the reactions of silver nitrate and phdat with the homologous ligands 1,2-H{sub 2}bdc, NO{sub 2}-H{sub 2}bdc, and Hnta, respectively, and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses thermogravimetric analyses (TGA). The compound 1 exhibits a chiral 3D network with cbs/CrB self-dual topological net, which contains two kinds of single helical chains. For compound 2, the 3D network is comprised of two kinds of similar 2D sheets with the topological symbol of sql-type packed in AABBAA mode by Ag–N/O weakly contacts. And compound 3 has 2D double layer architecture, consisting of the 2D plane with hcb-type topological symbol connected by Ag–O weakly coordinations. The photoluminescent properties associated with the crystal structures of three compounds have also been measured. - Graphical abstract: Three new silver(I) coordination complexes 1–3 have been synthesized and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses, thermogravimetric analyses (TGA) and photoluminescent spectra. Highlights: ► The compound 1 exhibits a novel chiral 3D network with two kinds of single helical chains. ► 3D or 2D new Ag coordination complexes. ► The photoluminescent properties have been measured.

  17. Hopper:Improving I/O performance to GSCRATCH and PROJECT

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    GSCRATCH/PROJECT Performance Tuning on Hopper Hopper:Improving I/O performance to GSCRATCH and PROJECT What are GSCRATCH/PROJECT? GSCRATCH and PROJECT are two file systems at NERSC that one can access on most computational systems. They are both based on the IBM GPFS file system and have multiple racks of dedicated servers and disk arrays. How are GSCRATCH/PROJECT connected to Hopper? As shown in the figure below, GSCRATCH and PROJECT are each connected to several Private NSD Servers (PNSD; for

  18. Visible light driven photocatalysis and antibacterial activity of AgVO{sub 3} and Ag/AgVO{sub 3} nanowires

    SciTech Connect

    Singh, Anamika; Dutta, Dimple P.; Ballal, A.; Tyagi, A.K.; Fulekar, M.H.

    2014-03-01

    Graphical abstract: - Highlights: Ag/AgVO{sub 3} and pure AgVO{sub 3} nanowires synthesized by sonochemical process. Characterization done using XRD, SEM, TEM, EDX and BET analysis. Visible light degradation of RhB by Ag/AgVO{sub 3} within 45 min. Antibacterial activity of Ag/AgVO{sub 3} demonstrated. - Abstract: Ag/AgVO{sub 3} nanowires and AgVO{sub 3} nanorods were synthesized in aqueous media via a facile sonochemical route. The as-synthesized products were characterized by X-ray diffraction, BrunauerEmmettTeller surface area analysis, scanning electron microscopy together with an energy dispersion X-ray spectrum analysis, transmission electron microscopy and UVvis diffuse reflectance spectroscopy. The results revealed that inert atmosphere promotes the formation of Ag/AgVO{sub 3} nanowires. The photocatalytic studies revealed that the Ag/AgVO{sub 3} nanowires exhibited complete photocatalytic degradation of Rhodamine B within 45 min under visible light irradiation. The antibacterial activity of Ag/AgVO{sub 3} nanowires was tested against Escherechia coli and Bacillus subtilis. The minimum growth inhibitory concentration value was found to be 50 and 10 folds lower than for the antibiotic ciprofloxacin for E. coli and B. subtilis, respectively. The antibacterial properties of the ?-AgVO{sub 3} nanorods prove that in case of the Ag dispersed Ag/AgVO{sub 3} nanowires, the enhanced antibacterial action is also due to contribution from the AgVO{sub 3} support.

  19. Ag

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    ... Secretary or the Commission, 2 as appropriate, shall - (A) make a survey of the causes and extent of damage; and (B) expeditiously submit a report setting forth the results of ...

  20. RENERCO Renewable Energy Concepts AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    RENERCO Renewable Energy Concepts AG Jump to: navigation, search Name: RENERCO Renewable Energy Concepts AG Place: Munich, Germany Zip: D-80336 Sector: Renewable Energy Product:...

  1. Gamesa Energie Deutschland formerly EBV Management Holding AG...

    OpenEI (Open Energy Information) [EERE & EIA]

    Energie Deutschland formerly EBV Management Holding AG Jump to: navigation, search Name: Gamesa Energie Deutschland (formerly EBV Management Holding AG) Place: Oldenburg, Germany...

  2. Alpen Adria Energie AG AAE | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Alpen Adria Energie AG AAE Jump to: navigation, search Name: Alpen Adria Energie AG (AAE) Place: Ktschach Mauthen, Austria Zip: 9640 Sector: Renewable Energy Product: Utility...

  3. GATE Global Alternative Energy Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energy Holding AG Place: Wrzburg, Bavaria, Germany Zip: 97080 Product: Germany-based biodiesel producer. References: GATE Global Alternative Energy Holding AG1 This article...

  4. European Energy Exchange AG EEX | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energy Exchange AG EEX Jump to: navigation, search Name: European Energy Exchange AG (EEX) Place: Leipzig, Germany Zip: D-04109 Product: Germany's energy exchange, which aims to...

  5. Mepsolar AG aka Munich Energy Partners | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AG aka Munich Energy Partners Jump to: navigation, search Name: Mepsolar AG (aka Munich Energy Partners) Place: Munich, Germany Zip: 81829 Product: Develops utility scale PV...

  6. IO6490

    Office of Legacy Management (LM)

    - -Landfill, ' cleanup plan' is. expected by August peruneat OfEnergy tiy they hope mlxaamfaricclcanupplan for four radioactive oitcs m the puwn of Tonawanda by early...

  7. IO2566

    Office of Legacy Management (LM)

    566 ;;I: :.f;l -5 iii i: i:2 JOSEPH OALIBER, EBQ., RKCEIVKR 513-519 WKBT 20th STREET NEW YORK, NKU YORK April 1, 1993 Former Sites Restoration Division Director U.S. Department of...

  8. Standoff imaging of chemicals using IR spectroscopy

    SciTech Connect

    Senesac, Larry R; Thundat, Thomas George; Morales Rodriguez, Marissa E

    2011-01-01

    Here we report on a standoff spectroscopic technique for identifying chemical residues on surfaces. A hand-held infrared camera was used in conjunction with a wavelength tunable mid-IR quantum cascade laser (QCL) to create hyperspectral image arrays of a target with an explosive residue on its surface. Spectral signatures of the explosive residue (RDX) were extracted from the hyperspectral image arrays and compared with a reference spectrum. Identification of RDX was achieved for residue concentrations of 20 g per cm2 at a distance of 1.5 m, and for 5 g per cm2 at a distance of 15 cm.

  9. Gated IR Images of Shocked Surfaces

    SciTech Connect

    S. S. Lutz; W. D. Turley; P. M. Rightley; L. E. Primas

    2001-06-01

    Gated infrared (IR) images have been taken of a series of shocked surface geometries in tin. Metal coupons machined with steps and flats were mounted directly to the high explosive. The explosive was point-initiated and 500-ns to 1-microsecond-wide gated images of the target were taken immediately following shock breakout using a Santa Barbara Focalplane InSb camera (SBF-134). Spatial distributions of surface radiance were extracted from the images of the shocked samples and found to be non-single-valued. Several geometries were modeled using CTH, a two-dimensional Eulerian hydrocode.

  10. Spin orientations of the spin-half Ir4+ ions in Sr3NiIrO6, Sr2IrO4 and Na2IrO3: Density functional, perturbation theory and Madelung potential analyses

    DOE PAGES [OSTI]

    Gordon, Elijah E.; Xiang, Hongjun; Koehler, Jurgen; Whangbo, Myung -Hwan

    2016-03-01

    The spins of the low-spin Ir4+ (S = 1/2, d5) ions at the octahedral sites of the oxides Sr3NiIrO6, Sr2IrO4 and Na2IrO3 exhibit preferred orientations with respect to their IrO6 octahedra. We evaluated the magnetic anisotropies of these S = 1/2 ions on the basis of DFT calculations including spin-orbit coupling (SOC), and probed their origin by performing perturbation theory analyses with SOC as perturbation within the LS coupling scheme. The observed spin orientations of Sr3NiIrO6 and Sr2IrO4 are correctly predicted by DFT calculations, and are accounted for by the perturbation theory analysis. As for the spin orientation of Na2IrO3,more » both experimental studies and DFT calculations have not been unequivocal. Our analysis reveals that the Ir4+ spin orientation of Na2IrO3 should have nonzero components along the c- and a-axes directions. The spin orientations determined by DFT calculations are sensitive to the accuracy of the crystal structures employed, which is explained by perturbation theory analyses when interactions between adjacent Ir4+ ions are taken into consideration. There are indications implying that the 5d electrons of Na2IrO3 are less strongly localized compared with those of Sr3NiIrO6 and Sr2IrO4. This implication was confirmed by showing that the Madelung potentials of the Ir4+ ions are less negative in Na2IrO3 than in Sr3NiIrO6, Sr2IrO4. Most transition-metal S = 1/2 ions do have magnetic anisotropies because the SOC induces interactions among their crystal-field split d-states, and the associated mixing of the states modifies only the orbital parts of the states. This finding cannot be mimicked by a spin Hamiltonian because this model Hamiltonian lacks the orbital degree of freedom, thereby leading to the spin-half syndrome. As a result, the spin-orbital entanglement for the 5d spin-half ions Ir4+ is not as strong as has been assumed lately.« less

  11. Sputnik Engineering AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zip: CH-2502 Sector: Solar Product: Manufacturer of SolarMax grid tie inverters for photovoltaic applications. References: Sputnik Engineering AG1 This article is a stub. You can...

  12. SES 21 AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Place: OderdingPolling, Germany Zip: 82398 Sector: Solar Product: A distributor of photovoltaic and solar thermal systems in Germany. References: SES 21 AG1 This article is a...

  13. SolarTec AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SolarTec AG Place: Munich, Bavaria, Germany Product: Developing a technology it calls Sol*Con- 700x Fresnel concentrators for use with gallium arsenide or germanium cells, also...

  14. Bos ten AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Place: Regensburg-Westenviertel, Germany Zip: 93049 Sector: Solar Product: Partner of Beck Energy in development of a 3.2MW solar PV plant. References: Bos.ten AG1 This article...

  15. Multi Contact AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    firm in the field of renewable energy, produces Solarline - connector systems for photovoltaics. References: Multi-Contact AG1 This article is a stub. You can help OpenEI by...

  16. AG Land 1 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.145531, -93.432161 Show Map Loading map... "minzoom":false,"mappings...

  17. AG Land 4 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.206397, -93.325714 Show Map Loading map... "minzoom":false,"mappings...

  18. AG Land 2 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 41.904231, -93.354864 Show Map Loading map... "minzoom":false,"mappings...

  19. AG Land 3 | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    LLC Developer AG Land Energy LLC Energy Purchaser Alliant Energy Location Story County IA Coordinates 42.146061, -93.428028 Show Map Loading map... "minzoom":false,"mappings...

  20. City Solar AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    services for large-scale PV power plants, also has a division called City Solar Invest to develop its own plants. References: City Solar AG1 This article is a stub. You...

  1. Solar Power Partners AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solar Product: Small Solar project developer with projects located in South Africa and France. References: Solar Power Partners AG1 This article is a stub. You can help OpenEI by...

  2. E ON AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    E.ON AG Place: Dusseldorf, North Rhine-Westphalia, Germany Zip: 40479 Sector: Renewable Energy Product: Dusseldorf-based company that operates as a public utility in the...

  3. Purple Level - 1 Milestone Review Committee I/O and Archive Follow-up Demonstration

    SciTech Connect

    Gary, M R

    2006-12-05

    On July 7th 2006, the Purple Level-1 Review Committee convened and was presented with evidence of the completion of Level-2 Milestone 461 (Deploy First Phase of I/O Infrastructure for Purple) which was performed in direct support of the Purple Level-1 milestone. This evidence included a short presentation and the formal documentation of milestone No.461 (see UCRL-TR-217288). Following the meeting, the Committee asked for the following additional evidence: (1) Set a speed measurement/goal/target assuming a number of files that the user needs to get into the archives. Then redo the benchmark using whatever tool(s) the labs prefer (HTAR, for example). Document how long the process takes. (2) Develop a test to read files back to confirm that what the user gets out of the archive is what the user put into the archive. This evidence has been collected and is presented here.

  4. Ir-based alloys for ultra-high temperature applications

    DOEpatents

    Liu, Chain T.; George, Easo P.; Bloom, Everett E.

    2006-01-03

    An alloy composition includes, in atomic percent: about 1 to about 10% of at least one element selected from the group consisting of Zr and Hf, balance Ir.

  5. Summary of the Optics, IR, Injection, Operations, Reliability...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Summary of the Optics, IR, Injection, Operations, Reliability and Instrumentation Working Group Citation Details In-Document Search Title: Summary of the Optics, ...

  6. X-ray transient absorption and picosecond IR spectroscopy of...

    Office of Scientific and Technical Information (OSTI)

    X-ray transient absorption and picosecond IR spectroscopy of fulvalene(tetracarbonyl)diruthenium on photoexcitation Citation Details In-Document Search Title: X-ray transient ...

  7. Microsoft Word - IR-mnt Apr 2009.doc

    Office of Legacy Management (LM)

    ... Publications IR039 U. S. Department of Energy, Grand Junction Projects Office Roundup, a Monthly Site Newsletter, May 19, 1992. "Geotech Donates Money for Ambulance Garage". ...

  8. NEAR-IR TWO PHOTON MICROSCOPY IMAGING OF SILICA NANOPARTICLES...

    Office of Scientific and Technical Information (OSTI)

    NANOPARTICLES FUNCTIONALIZED WITH ISOLATED SENSITIZED Yb(III) CENTERS Citation Details In-Document Search Title: NEAR-IR TWO PHOTON MICROSCOPY IMAGING OF SILICA NANOPARTICLES ...

  9. Graphene-silicon layered structures on single-crystalline Ir...

    Office of Scientific and Technical Information (OSTI)

    Accepted Manuscript: Graphene-silicon layered structures on single-crystalline Ir(111) thin films Prev Next Title: Graphene-silicon layered structures on single-crystalline...

  10. PIA - Form EIA-475 A/G Residential Energy Consumption Survey...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Form EIA-475 AG Residential Energy Consumption Survey PIA - Form EIA-475 AG Residential Energy Consumption Survey PIA - Form EIA-475 AG Residential Energy Consumption Survey PIA ...

  11. Ag on Si(111) from basic science to application

    SciTech Connect

    Belianinov, Aleksey

    2012-04-04

    In our work we revisit Ag and Au adsorbates on Si(111)-7x7, as well as experiment with a ternary system of Pentacene, Ag and Si(111). Of particular interest to us is the Si(111)-({radical}3x{radical}3)R30{degree}Ag (Ag-Si-{radical}3 hereafter). In this thesis I systematically e plore effects of Ag deposition on the Ag-Si-{radical}3 at different temperatures, film thicknesses and deposition fluxes. The generated insight of the Ag system on the Si(111) is then applied to generate novel methods of nanostructuring and nanowire growth. I then extend our expertise to the Au system on the Ag-Si(111) to gain insight into Au-Si eutectic silicide formation. Finally we explore behavior and growth modes of an organic molecule on the Ag-Si interface.

  12. Photocatalytic performances and activities of Ag-doped CuFe{sub 2}O{sub 4} nanoparticles

    SciTech Connect

    Zhu, Zhengru; Li, Xinyong; Zhao, Qidong; Li, Yonghua; Sun, Caizhi; Cao, Yongqiang

    2013-08-01

    Graphical abstract: - Highlights: CuFe{sub 2}O{sub 4} nanocrystals were synthesized by a co-precipitation method. Ag/CuFe{sub 2}O{sub 4} catalyst was prepared by the wetness impregnation strategy. The structural properties of Ag/CuFe{sub 2}O{sub 4} were investigated by XRD, TEM, DRS, and XPS techniques. Ag/CuFe{sub 2}O{sub 4} has higher photocatalytic activity. - Abstract: In this work, CuFe{sub 2}O{sub 4} nanoparticles were synthesized by a chemical co-precipitation route. The Ag/CuFe{sub 2}O{sub 4} catalyst was prepared based on the CuFe{sub 2}O{sub 4} nanoparticles by the incipient wetness impregnation strategy, which showed excellent photoelectric property and catalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction (XRD), transmission electronic microscopy (TEM), UVvis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR) techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage (SPV) measurement. The photocatalytic degradation of 4-CP by the Ag/CuFe{sub 2}O{sub 4} and CuFe{sub 2}O{sub 4} samples were comparatively studied under xenon lamp irradiation. The results indicate that the Ag/CuFe{sub 2}O{sub 4} sample exhibited the higher efficiency for the degradation of 4-CP.

  13. IR keeps coal miners safe and reduces downtime

    SciTech Connect

    Massey, L.G.

    2009-01-15

    Infrared (IR) cameras can inspect the direct current trolley system that powers mantrips and locomotives that transport men and supplies to an underground mine. If trolley insulators become shorted or electrically leaky they can heat the roof and cause a fire or cave-in. The article explains how IR inspection works and describes typical problems that can be identified by thermograms. 8 figs.

  14. Template synthesis of Ag/AgCl microrods and their efficient visible light-driven photocatalytic performance

    SciTech Connect

    Chen, Hua; Xiao, Liang; Huang, Jianhua

    2014-09-15

    Highlights: Preparation ofAg/AgCl microrods by reaction of Ag{sub 2}WO{sub 4} microrods with NaCl solution. Generation of metallic Ag is induced by the ambient light in the synthesis process. Ag/AgCl shows excellent visible light-driven photodegradation of organic dyes. - Abstract: Ag/AgCl microrods, aggregated by nanoparticles with a diameter ranging from 100 nm to 2 ?m, were prepared by an ion-exchange reaction at 80 C between Ag{sub 2}WO{sub 4} template and NaCl solution. The existence of metallic Ag species was confirmed by XRD, DRS and XPS measurements. Ag/AgCl microrods showed excellent photocatalytic activity for the degradation of rhodamine B and methylene blue under visible light irradiation. The degradation rate constants of rhodamine B and methylene blue are 0.176 and 0.114 min{sup ?1}, respectively. The cycling photodegradation experiments suggest that Ag/AgCl microds could be employed as stable plasmonic photocatalysts for the degradation of organic dyes under visible light irradiation.

  15. NaIrO3A Pentavalent Post-perovskite

    SciTech Connect

    M Bremholm; S Dutton; P Stephens; R Cava

    2011-12-31

    Sodium iridium (V) oxide, NaIrO{sub 3}, was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides.

  16. Simultaneous multi-beam planar array IR (pair) spectroscopy

    DOEpatents

    Elmore, Douglas L.; Rabolt, John F.; Tsao, Mei-Wei

    2005-09-13

    An apparatus and method capable of providing spatially multiplexed IR spectral information simultaneously in real-time for multiple samples or multiple spatial areas of one sample using IR absorption phenomena requires no moving parts or Fourier Transform during operation, and self-compensates for background spectra and degradation of component performance over time. IR spectral information and chemical analysis of the samples is determined by using one or more IR sources, sampling accessories for positioning the samples, optically dispersive elements, a focal plane array (FPA) arranged to detect the dispersed light beams, and a processor and display to control the FPA, and display an IR spectrograph. Fiber-optic coupling can be used to allow remote sensing. Portability, reliability, and ruggedness is enhanced due to the no-moving part construction. Applications include determining time-resolved orientation and characteristics of materials, including polymer monolayers. Orthogonal polarizers may be used to determine certain material characteristics.

  17. A Lightweight, High-performance I/O Management Package for Data-intensive Computing

    SciTech Connect

    Wang, Jun

    2011-06-22

    Our group has been working with ANL collaborators on the topic ??bridging the gap between parallel file system and local file system? during the course of this project period. We visited Argonne National Lab -- Dr. Robert Ross??s group for one week in the past summer 2007. We looked over our current project progress and planned the activities for the incoming years 2008-09. The PI met Dr. Robert Ross several times such as HEC FSIO workshop 08, SC??08 and SC??10. We explored the opportunities to develop a production system by leveraging our current prototype to (SOGP+PVFS) a new PVFS version. We delivered SOGP+PVFS codes to ANL PVFS2 group in 2008.We also talked about exploring a potential project on developing new parallel programming models and runtime systems for data-intensive scalable computing (DISC). The methodology is to evolve MPI towards DISC by incorporating some functions of Google MapReduce parallel programming model. More recently, we are together exploring how to leverage existing works to perform (1) coordination/aggregation of local I/O operations prior to movement over the WAN, (2) efficient bulk data movement over the WAN, (3) latency hiding techniques for latency-intensive operations. Since 2009, we start applying Hadoop/MapReduce to some HEC applications with LANL scientists John Bent and Salman Habib. Another on-going work is to improve checkpoint performance at I/O forwarding Layer for the Road Runner super computer with James Nuetz and Gary Gridder at LANL. Two senior undergraduates from our research group did summer internships about high-performance file and storage system projects in LANL since 2008 for consecutive three years. Both of them are now pursuing Ph.D. degree in our group and will be 4th year in the PhD program in Fall 2011 and go to LANL to advance two above-mentioned works during this winter break. Since 2009, we have been collaborating with several computer scientists (Gary Grider, John bent, Parks Fields, James Nunez

  18. Ag@AgHPW as a plasmonic catalyst for visible-light photocatalytic degradation of environmentally harmful organic pollutants

    SciTech Connect

    Zhou, Wenhui; Cao, Minhua Li, Na; Su, Shuangyue; Zhao, Xinyu; Wang, Jiangqiang; Li, Xianghua; Hu, Changwen

    2013-06-01

    Graphical abstract: Ag@Ag{sub x}H{sub 3?x}PW12O40 (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant, which show a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation. - Highlights: A new visible-light driven photocatalyst Ag@Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} was designed. The photocatalyst shows a high activity for the degradation of methyl blue. The high activity can be ascribed to the synergy of photoexcited AgHPW and Ag. - Abstract: Ag@Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} (Ag@AgHPW) nanoparticles (NPs), a new visible-light driven plasmonic photocatalyst, are prepared by a green photoreduction strategy without the addition of any surfactant. They show strong absorption in the visible region because of the localized surface plasmon resonance (LSPR) of Ag NPs. This plasmonic photocatalyst shows a high activity and stability for the degradation of methyl blue (MB) under visible light irradiation, which could be attributed to the highly synergy of photoexcited Ag{sub x}H{sub 3?x}PW{sub 12}O{sub 40} (AgHPW) and plasmon-excited Ag NPs and the confinement effects at interfaces between polyoxometalates (POMs) and silver. POM anions have redox ability and high photocatalytic activity, whereas Ag NPs could effectively accelerate the separation of electrons and holes, both of which contribute to their high activity.

  19. AgFe Management Ltd | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    AgFe Management Ltd Jump to: navigation, search Name: AgFe Management Ltd Place: London, England, United Kingdom Zip: W11 1QF Product: London-based, Financial Asset Management and...

  20. SiC Processing AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    SiC Processing AG Jump to: navigation, search Name: SiC Processing AG Place: Hirschau, Germany Zip: 92242 Sector: Solar Product: Offers management and recycling of slurry for solar...

  1. E ON Energy from Waste AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    from Waste AG Jump to: navigation, search Name: E.ON Energy from Waste AG Place: Helmstedt, Lower Saxony, Germany Zip: 38350 Product: Lower Saxony-based E.ON subsidiary is the...

  2. S R Biogas Energiesysteme AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Energiesysteme AG Jump to: navigation, search Name: S&R Biogas Energiesysteme AG Place: Frankfurt am Main, Hessen, Germany Zip: 60598 Product: S&R Biogas Energiesysteme is a biogas...

  3. Organic pollutant photodecomposition by Ag/KNbO3 nanocomposites...

    Office of Scientific and Technical Information (OSTI)

    In this study, Ag nanoparticles supported on well-defined perovskite orthorhombic KNbO3 ... slab models of KNbO3 (101) are employed to mimic large supportedmore Ag nanoparticles. ...

  4. The BNL AGS accelerator complex status and future plans

    SciTech Connect

    Tanaka, Mitsuyoshi

    1997-05-01

    This paper describes the present performance and capability of the BNL AGS accelerator complex and possible future intensity upgrade plans. In 1995, the AGS reached its design upgrade goal of 6.0 x 10(exp 13) ppp with the Booster. The AGS with a new fast extracted beam (FEB) system is able to perform single bunch multiple extraction at 30 Hz per AGS cycle for the g-2 experiment and for RHIC injection.

  5. EA-261 UBS AG, London Branch | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    1 UBS AG, London Branch EA-261 UBS AG, London Branch Order authorizing UBS AG, London Branch to export electric energy to Mexico. EA-261 UBS AG, London Branch (24.57 KB) More Documents & Publications EA-184 Morgan Stanley Capital Group Inc. EA-167 PG&E Energy Trading-Power, L.P EA-181 H.Q Energy Services (U.S

  6. IRS Announces New Tribal Economic Development Bond Allocation Guidance

    Energy.gov [DOE]

    Treasury and the IRS published new guidance today allocating Tribal Economic Development Bonds (TEDBs) for Tribes that have projects that are in the final stages of going to the market to receive financing.

  7. ARM - Field Campaign - IR Cloud Camera Feasibility Study

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    govCampaignsIR Cloud Camera Feasibility Study ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send...

  8. The Use of Microscopes and Telescopes in IR Imaging (Conference...

    Office of Scientific and Technical Information (OSTI)

    working in a research environment, where applications can vary from week to week. ... In these cases, the thermographer must rely on an IR microscope for close-up work with a ...

  9. Wet Chemical Compositional and Near IR Spectra Data Sets for...

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Find More Like This Return to Search Wet Chemical Compositional and Near IR Spectra Data ... Wet chemical compositional data and NIR spectra exist for the following types of biomass ...

  10. New IRS Rules for Small and Medium Wind Turbines

    Energy.gov [DOE]

    The Small Wind Certification Council (SWCC) will host a webinar on how certification is being used to meet the new Internal Revenue Service (IRS) requirements for small and medium wind turbines...

  11. DWEA Webinar: IRS Guidance for Small Wind Turbines

    Energy.gov [DOE]

    The U.S. Internal Revenue Service (IRS) has issued Notice 2015-4 providing new performance and quality standards of small wind turbines – defined as having a nameplate capacity of up to 100 kW – in...

  12. IRS Parking Facility Lighting Retrofit Reduces Annual Energy...

    Office of Environmental Management (EM)

    The retrofit resulted in annual energy savings of 2 million kWh, annual cost savings of over 122,000, and a simple payback of 2.5 years. Download the IRS parking facility case ...

  13. Energy Efficient Clothes Dryer with IR Heating and Electrostatic

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Precipitator | Department of Energy Clothes Dryer with IR Heating and Electrostatic Precipitator Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator This project seeks to demonstrate a ventless residential dryer with an energy factor greater than 4.04.<br /> Photo credit: GE Global Research This project seeks to demonstrate a ventless residential dryer with an energy factor greater than 4.04. Photo credit: GE Global Research Project team members left to right

  14. High intensity proton operation at the Brookhaven AGS accelerator complex

    SciTech Connect

    Ahrens, L.A.; Blaskiewicz, M.; Bleser, E.; Brennan, J.M.; Gardner, C.; Glenn, J.W.; Onillon, E.; Reece, R.K.; Roser, T.; Soukas, A.

    1994-08-01

    With the completion of the AGS rf upgrade, and the implementation of a transition {open_quotes}jump{close_quotes}, all of accelerator systems were in place in 1994 to allow acceleration of the proton intensity available from the AGS Booster injector to AGS extraction energy and delivery to the high energy users. Beam commissioning results with these new systems are presented. Progress in identifying and overcoming other obstacles to higher intensity are given. These include a careful exploration of the stopband strengths present on the AGS injection magnetic porch, and implementation of the AGS single bunch transverse dampers throughout the acceleration cycle.

  15. Enhanced thermal stability of Ag nanorods through capping

    SciTech Connect

    Bachenheimer, Lou; Elliott, Paul; Stagon, Stephen; Huang, Hanchen

    2014-11-24

    Ag nanorods may serve as sensors in the detection of trace amounts of chemical agents, even single molecules, through surface enhanced Raman spectroscopy (SERS). However, thermal coarsening of Ag nanorods near room temperature limits their applications. This letter proposes the use of a thin oxide capping layer to enhance the thermal stability of Ag nanorods beyond 100?C. Using electron microscopy characterization and SERS tests, the authors show that the proposed method is effective in stabilizing both morphology and sensitivity of Ag nanorods. The results of this work extend the applicability of Ag nanorods as chemical sensors to higher temperatures.

  16. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOEpatents

    Johnson, C.C.; Taylor, L.T.

    1985-01-04

    A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  17. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOEpatents

    Johnson, Charles C.; Taylor, Larry T.

    1986-01-01

    A zero dead volume (ZDV) microbore high performance liquid chromatography (.mu.HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a .mu.HPLC column end fitting to minimize the transfer volume of the effluents exiting the .mu.HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF.sub.2), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  18. Tidal dissipation in a homogeneous spherical body. II. Three examples: Mercury, Io, and Kepler-10 b

    SciTech Connect

    Makarov, Valeri V.; Efroimsky, Michael E-mail: michael.efroimsky@usno.navy.mil

    2014-11-01

    In Efroimsky and Makarov (Paper I), we derived from the first principles a formula for the tidal heating rate in a homogeneous sphere, compared it with the previously used formulae, and noted the differences. Now we present case studies: Mercury, Kepler-10 b, and a triaxial Io. A sharp frequency dependence of k {sub 2}/Q near spin-orbit resonances yields a sharp dependence of k {sub 2}/Q (and, therefore, of tidal heating) upon the spin rate. Thereby physical libration plays a major role in tidal heating of synchronously rotating planets. The magnitude of libration in the spin rate being defined by the planet's triaxiality, the latter becomes a factor determining the dissipation rate. Other parameters equal, a strongly triaxial synchronized body generates more heat than a similar body of a more symmetrical shape. After an initially triaxial object melts and loses its triaxiality, dissipation becomes less intensive; the body can solidify, with the tidal bulge becoming a new figure with triaxiality lower than the original. We derive approximate expressions for the dissipation rate in a Maxwell planet with the Maxwell time longer than the inverse tidal frequency. The expressions derived pertain to the 1:1 and 3:2 resonances and a nonresonant case; so they are applicable to most close-in super-Earths detected. In these planets, the heating outside synchronism is weakly dependent on the eccentricity and obliquity, provided both these parameters's values are moderate. According to our calculation, Kepler-10 b could hardly survive the intensive tidal heating without being synchronized, circularized, and reshaped through a complete or partial melt-down.

  19. Quasi-two-dimensional Ag nanoparticle formation in silica by Xe ion irradiation and subsequent Ag ion implantation

    SciTech Connect

    Wang, Jun; Jia, Guangyi; Mu, Xiaoyu; Liu, Changlong

    2013-04-01

    Ag nanoparticles were fabricated in silica by Xe ion irradiation and subsequent Ag ion implantation, which distributed in a depth range from 4.8 to 14.3 nm, rather than dispersed from surface to a depth of 24.7 nm when no irradiation was made in advance. In addition, the suppression of Ag implants' sputtering loss was also evidenced by a greatly increased Ag content in the prepared sample. These results are mainly due to the defect-enhanced in-beam particle growth. Further, formation of polycrystalline Ag nanoparticles was revealed, whose effect on optical absorption was discussed according to the electron mean-free-path mode.

  20. EXPLORING IO'S ATMOSPHERIC COMPOSITION WITH APEX: FIRST MEASUREMENT OF {sup 34}SO{sub 2} AND TENTATIVE DETECTION OF KCl

    SciTech Connect

    Moullet, A.; Lellouch, E.; Moreno, R.; Gurwell, M.; Black, J. H; Butler, B.

    2013-10-10

    The composition of Io's tenuous atmosphere is poorly constrained. Only the major species SO{sub 2} and a handful of minor species have been positively identified, but a variety of other molecular species should be present, based on thermochemical equilibrium models of volcanic gas chemistry and the composition of Io's environment. This paper focuses on the spectral search for expected yet undetected molecular species (KCl, SiO, S{sub 2}O) and isotopes ({sup 34}SO{sub 2}). We analyze a disk-averaged spectrum of a potentially line-rich spectral window around 345 GHz, obtained in 2010 at the APEX 12 m antenna. Using different models assuming either extended atmospheric distributions or a purely volcanically sustained atmosphere, we tentatively measure the KCl relative abundance with respect to SO{sub 2} and derive a range of 4 × 10{sup –4}-8 × 10{sup –3}. We do not detect SiO or S{sub 2}O and present new upper limits on their abundances. We also present the first measurement of the {sup 34}S/{sup 32}S isotopic ratio in gas phase on Io, which appears to be twice as high as the Earth and interstellar medium reference values. Strong lines of SO{sub 2} and SO are also analyzed to check for longitudinal variations of column density and relative abundance. Our models show that, based on their predicted relative abundance with respect to SO{sub 2} in volcanic plumes, both the tentative KCl detection and SiO upper limit are compatible with a purely volcanic origin for these species.

  1. Superconducting and magnetic properties of Sr?Ir?Sn??

    DOE PAGES [OSTI]

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    Magnetization and muon spin relaxation or rotation (SR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field SR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field SR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ?? with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap valuemoreof 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.less

  2. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition

    SciTech Connect

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.

    2010-11-01

    The flux of atomic oxygen generated in a electron cyclotron resonance (ECR) microwave plasma source was quantified by two different methods. The commonly applied approach of monitoring the frequency change of a silver-coated quartz crystal microbalance (QCM) deposition rate monitor as the silver is oxidized was found to underestimate the atomic oxygen flux by an order of magnitude compared to a more direct deposition approach. In the mixed-phase Ag/Ag2O deposition method, silver films were deposited in the presence of the plasma such that the films were partially oxidized to Ag2O; x-ray photoelectron spectroscopy (XPS) was utilized for quantification of the oxidized fraction. The inaccuracy of the QCM oxidation method was tentatively attributed to efficient catalytic recombination of O atoms on the silver surface.

  3. Double dumbbell shaped AgNi alloy by pulsed electrodeposition

    SciTech Connect

    Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy; Narayanan, V. Stephen, A.

    2014-01-28

    Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

  4. Low Dose IR Creates an Oncogenic Microenvironment by Inducing Premature

    SciTech Connect

    Yuan, Zhi-Min

    2013-04-28

    Introduction Much of the work addressing ionizing radiation-induced cellular response has been carried out mainly with the traditional cell culture technique involving only one cell type, how cellular response to IR is influenced by the tissue microenvironment remains elusive. By use of a three-dimensional (3D) co-culture system to model critical interactions of different cell types with their neighbors and with their environment, we recently showed that low-dose IR-induced extracellular signaling via the tissue environment affects profoundly cellular responses. This proposal aims at determining the response of mammary epithelial cells in a tissue-like setting.

  5. Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using...

    Office of Scientific and Technical Information (OSTI)

    Conference: Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using Low Dose In Situ Liquid STEM. Citation Details In-Document Search Title: Monitoring Galvanic ...

  6. High intensity performance and upgrades at the Brookhaven AGS...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 43 PARTICLE ACCELERATORS; BEAM EMITTANCE; BEAM OPTICS; BROOKHAVEN AGS; GEV RANGE; LINEAR ACCELERATORS; MEV RANGE; ...

  7. Solaxis GmbH Regetec Handels AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zip: 47475 Sector: Solar Product: Distributor and installer of photovoltaic modules and solar heating systems. References: Solaxis GmbH (Regetec Handels AG)1 This article is a...

  8. Schnell Z ndstrahlmotoren AG Co KG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zndstrahlmotoren is specialized on the production of dual fuel engines (CHPs) for biogas, dump and sewage gas. References: Schnell Zndstrahlmotoren AG & Co. KG1 This...

  9. EnviTec Biogas AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    EnviTec Biogas AG Place: Saerbeck, North Rhine-Westphalia, Germany Zip: 48369 Product: Plans, finances, installs and commissions biogas systems including technical and biological...

  10. Theoretical study of Ag- and Au-filled skutterudites. | Department...

    Energy.gov [DOE] (indexed site)

    theoretical values of thermoelectric properties for Ag-filled skutterudites. stoica.pdf (3.05 MB) More Documents & Publications Thermoelectric Generator Development for ...

  11. EPURON GmbH formerly Voltwerk AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    EPURON GmbH (formerly Voltwerk AG) Place: Hamburg, Germany Zip: 20537 Sector: Solar, Wind energy Product: Develops, finances, implements and operates solar, wind and biogas...

  12. On-Line Weld NDE with IR Thermography | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    On-Line Weld NDE with IR Thermography On-Line Weld NDE with IR Thermography 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting lm054_warren_2012_o.pdf (1.94 MB) More Documents & Publications On-Line Weld NDE with IR Thermography Vehicle Technologies Office Merit Review 2014: On-Line Weld NDE with IR Thermography Online Weld Quality NDE & Control with IR Thermography

  13. IRS Parking Facility Lighting Retrofit Reduces Annual Energy Use by 76% |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy IRS Parking Facility Lighting Retrofit Reduces Annual Energy Use by 76% IRS Parking Facility Lighting Retrofit Reduces Annual Energy Use by 76% IRS Parking Facility Lighting Retrofit Reduces Annual Energy Use by 76% Document provides an overview of how the IRS and MC Realty Group, its property management firm, achieved a 76% reduction in lighting energy use at an IRS facility parking garage in Kansas City, Missouri. The retrofit resulted in annual energy savings of 2

  14. METAL MEDIA FILTERS, AG-1 SECTION FI

    SciTech Connect

    Adamson, D.

    2012-05-23

    One application of metal media filters is in various nuclear air cleaning processes including applications for protecting workers, the public and the environment from hazardous and radioactive particles. To support this application the development of the ASME AG-1 FI Standard on Metal Media has been under way for more than ten years. Development of the proposed section has required resolving several difficult issues associated with operating conditions (media velocity, pressure drop, etc.), qualification testing, and quality acceptance testing. Performance characteristics of metal media are dramatically different than the glass fiber media with respect to parameters like differential pressures, operating temperatures, media strength, etc. These differences make existing data for a glass fiber media inadequate for qualifying a metal media filter for AG-1. In the past much work has been conducted on metal media filters at facilities such as Lawrence Livermore National Laboratory (LLNL) and Savannah River National Laboratory (SRNL) to qualify the media as High Efficiency Particulate Air (HEPA) Filters. Particle retention testing has been conducted at Oak Ridge Filter Test Facility and at Air Techniques International (ATI) to prove that the metal media meets or exceeds the 99.97% particle retention required for a HEPA Filter. Even with his testing, data was lacking to complete an AG-1 FI Standard on metal media. With funding secured by Mississippi State University (MSU) from National Nuclear Security Administration (NNSA), a research test stand is being designed and fabricated at MSU's Institute for Clean Energy Technology (ICET) Facility to obtain qualification data on metal media. This in turn will support required data needed for the FI Standard. The paper will discuss in detail how the test stand at MSU will obtain the necessary data to complete the FI Standard.

  15. Disproportionation of Ag+ by pressure-and heat-induced Xe insertion into Ag-natrolite

    DOE PAGES [OSTI]

    Seoung, Donghoon; Cynn, Hyunchae; Park, Changyong; Choi, Kwang -Yong; Blom, Douglas A.; Evans, William J.; Kao, Chi -Chang; Vogt, Thomas; Lee, Yongjae

    2011-12-27

    In this study, pressure can drastically alter chemical and physical properties of materials and allow structural phase transitions and chemical reactions to occur that defy much of our understanding gained at ambient conditions. The observation and prediction of new exotic binary phases of sodium chlorides (1) and the auto-dissociat ions of XeF2 and NO2 at high pressures suggests new chemistry is within reach (2). Particularly exciting is the high-pressure chemistry of Xenon, which has been found to react with ice (3) and hydrogen (4) and predicted to form stable Mg-Xe compounds (5) under pressure. We show that Ag16Al16Si24O80 · 16H2Omore » inserts Xe at 1.7 GPa and 250 ° C and Ag+ disproportionates to metallic Ag and Ag2+ which is retained together with Xe within the pores after pressure release. This represents the first case of Xe acting as a chemical mediator based on its adduct forming capabilities within small pores.« less

  16. Sr2IrO4: Gateway to cuprate superconductivity?

    DOE PAGES [OSTI]

    Mitchell, J. F.

    2015-06-05

    High temperature superconductivity in cuprates remains a defining challenge in condensed matter physics. Recently, a new set of related compounds based on Ir rather than Cu has been discovered that may be on the verge of superconductivity themselves or be able to shed new light on the underlying interactions responsible for superconductivity in the cuprates.

  17. Microsoft Word - AG Chapter 6 1 Nov 2010 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    AG Chapter 6 1 Nov 2010 Microsoft Word - AG Chapter 6 1 Nov 2010 PDF icon Microsoft Word - AG Chapter 6 1 Nov 2010 More Documents & Publications Competition Requirements AcqGuide ...

  18. EECH Group AG formerly European Energy Consult Holding P T Technology...

    OpenEI (Open Energy Information) [EERE & EIA]

    EECH Group AG formerly European Energy Consult Holding P T Technology AG Jump to: navigation, search Name: EECH Group AG (formerly European Energy Consult Holding, P&T Technology...

  19. Ag/AgBr/g-C{sub 3}N{sub 4}: A highly efficient and stable composite photocatalyst for degradation of organic contaminants under visible light

    SciTech Connect

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Graphical abstract: Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed excellent photocatalytic activities on the degradation of methyl orange (MO) under visible light. The improved photocatalytic performance and stability of Ag/AgBr/g-C{sub 3}N{sub 4} originated from the synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. O{sub 2}?, one of the reactive species, was responsible for the photodegradation of MO compared to H+ and OH. - Highlights: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalyst was reported. Ag/AgBr/g-C{sub 3}N{sub 4} had novel energy band combination between AgBr and g-C{sub 3}N{sub 4}. Synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. Electron trapping role of metallic Ag dominated the stability of Ag/AgBr/g-C{sub 3}N{sub 4}. - Abstract: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts were constructed via depositionprecipitation method and extensively characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UVvis diffuse reflectance spectroscopy (DRS). Under visible light (? > 420 nm), Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed much higher photocatalytic activities than those of Ag/AgBr and g-C{sub 3}N{sub 4} for degradation of methyl orange (MO). 50% Ag/AgBr/g-C{sub 3}N{sub 4} presented the best photocatalytic performance, which was mainly attributed to the synergistic effects of AgBr/g-C{sub 3}N{sub 4} interface and the in situ metallic Ag nanoparticles for efficiently separating electronhole pairs. Furthermore, Ag/AgBr/g-C{sub 3}N{sub 4} remained good photocatalytic activity through 5 times of cycle experiments. Additionally, the radical scavengers experiment indicated that O{sub 2}{sup ?} was the main reactive species for the MO degradation under visible light.

  20. Phoenix Solar AG formerly Phoenix SonnenStrom | Open Energy Informatio...

    OpenEI (Open Energy Information) [EERE & EIA]

    Solar AG formerly Phoenix SonnenStrom Jump to: navigation, search Name: Phoenix Solar AG (formerly Phoenix SonnenStrom) Place: Sulzemoos, Germany Zip: 85254 Product: Develops...

  1. Intruder states in odd-mass Ag isotopes

    SciTech Connect

    Rogowski, J.; Alstad, J.; Brant, S.; Daniels, W.R.; De Frenne, D.; Heyde, K.; Jacobs, E.; Kaffrell, N.; Paar, V.; Skarnemark, G.; Trautmann, N. (Institut fuer Kernchemie, Universitaet Mainz, D-6500 Mainz (Federal Republic of Germany) Department of Chemistry, University of Oslo, N-0315 Oslo (Norway) Prirodoslovno-matematicki fakultet, University of Zagreb, 41000 Zagreb (Yugoslavia) Los Alamos National Laboratory, Los Alamos, NM (USA) Laboratorium voor Kernfysica, Proeftuinstraat 86, B-9000 Gent (Belgium) Department of Nuclear Chemistry, Chalmers University of Technology, S-41296 Goeteborg (Sweden))

    1990-12-01

    The information on the coexistence of deformed intruder states and normal spherical hole-core coupled states in odd-mass Ag nuclei has been extended to the neutron-rich isotopes {sup 113}Ag{sub 66} and {sup 115}Ag{sub 68}. Data have been obtained from an investigation of the {gamma} rays following the {beta}{sup {minus}} decay of the {sup 113,115}Pd precursors. A minimum for the excitation energy of the intruder states occurs in {sup 113}Ag{sub 66}, exactly at neutron midshell. The properties of the intruder states in {sup 109,111,113,115}Ag are discussed and a description in the framework of the interacting-boson-fermion model is presented.

  2. Synthesis and photocatalytic performance of an efficient Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} composite photocatalyst under visible light

    SciTech Connect

    Liang, Yinghua; Lin, Shuanglong; Liu, Li; Hu, Jinshan; Cui, Wenquan

    2014-08-15

    Highlights: The plasmatic Ag@AgBr sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts. Ag@AgBr greatly increased visible light absorption for K{sub 2}Ti{sub 4}O{sub 9}. The plamonic photocatalysts exhibited enhanced activity for the degradation of RhB. - Abstract: Ag@AgBr nanoparticle-sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts (Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9}) were prepared by a facile precipitationphotoreduction method. The photocatalytic activities of the Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} nanocomposites were evaluated for photocatalytic degradation of (RhB) under visible light irradiation. The composites exhibited excellent visible light absorption, which was attributable to the surface plasmon effect of Ag nanoparticles. The Ag@AgBr was uniformly scattered on the surface of K{sub 2}Ti{sub 4}O{sub 9} and possessed sizes in the range of 2050 nm. The loading amount of Ag@AgBr was also studied, and was found to influence the absorption spectra of the resulting composites. Approximately 95.9% of RhB was degraded by Ag@AgBr (20 wt.%)/K{sub 2}Ti{sub 4}O{sub 9} after irradiation for 1 h. The stability of the material was also investigated by performing consecutive runs. Additionally, studies performed using radical scavengers indicated that O{sub 2}{sup ?} and Br{sup 0} acted as the main reactive species. Based on the experimental results, a photocatalytic mechanism for organics degradation over Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} photocatalysts was proposed.

  3. Relative Infrared (IR) and Terahertz (THz) Signatures of Common Explosives

    SciTech Connect

    Sharpe, Steven W.; Johnson, Timothy J.; Sheen, David M.; Atkinson, David A.

    2006-11-13

    Pacific Northwest National Laboratory (PNNL) has recently recorded the infrared (IR) and far-infrared (sometimes called the terahertz, THz) spectral signatures of four common explosives, in the condensed phase. The signatures of RDX, PETN, TNT and Tetryl were recorded both in the infrared and the THz domains, using Fourier transform infrared (FTIR) spectroscopy. Samples consisted of thin films and were made by depositing and subsequent evaporation of an acetone-explosive mixture. The complete spectrum spanned the range from 4,000 to 8 cm-1 at 2.0 cm-1 spectral resolution. Preliminary results in the infrared agree with those of previous workers, while the THz signatures are one order of magnitude weaker than the strongest IR bands.

  4. IR OPTICS MEASUREMENT WITH LINEAR COUPLING'S ACTION-ANGLE PARAMETERIZATION.

    SciTech Connect

    LUO, Y.; BAI, M.; PILAT, R.; SATOGATA, T.; TRBOJEVIC, D.

    2005-05-16

    A parameterization of linear coupling in action-angle coordinates is convenient for analytical calculations and interpretation of turn-by-turn (TBT) beam position monitor (BPM) data. We demonstrate how to use this parameterization to extract the twiss and coupling parameters in interaction regions (IRs), using BPMs on each side of the long IR drift region. The example of TBT BPM analysis was acquired at the Relativistic Heavy Ion Collider (RHIC), using an AC dipole to excite a single eigenmode. Besides the full treatment, a fast estimate of beta*, the beta function at the interaction point (IP), is provided, along with the phase advance between these BPMs. We also calculate and measure the waist of the beta function and the local optics.

  5. First lasing of the IR upgrade FEL at Jefferson lab

    SciTech Connect

    Christopher Behre; Stephen Benson; George Biallas; James Boyce; Christopher Curtis; David Douglas; H. Dylla; L. Dillon-townes; Richard Evans; Albert Grippo; Joseph Gubeli; David Hardy; John Heckman; Carlos Hernandez-Garcia; Tommy Hiatt; Kevin Jordan; Nikolitsa Merminga; George Neil; Joseph Preble; Harvey Rutt; Michelle D. Shinn; Timothy Siggins; Hiroyuki Toyokawa; David W. Waldman; Richard Walker; Neil Wilson; Byung Yunn; Shukui Zhang

    2004-08-01

    We report initial lasing results from the IR Upgrade FEL at Jefferson Lab[1]. The electron accelerator was operated with low average current beam at 80 MeV. The time structure of the beam was 120 pC bunches at 4.678 MHz with up to 750 {micro}sec pulses at 2Hz. Lasing was established over the entire wavelength range of the mirrors (5.5-6.6 {micro}m). The detuning curve length, turn-on time, and power were in agreement with modeling results assuming a 1 psec FWHM micropulse. The same model predicts over 10 kW of power output with 10 mA of beam and 10% output coupling, which is the ultimate design goal of the IR Upgrade FEL. The behavior of the laser while the dispersion section strength was varied was found to qualitatively match predictions. Initial CW lasing results also will be presented.

  6. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    SciTech Connect

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A. [and others

    1998-01-01

    Uncooled pyroelectric IR imaging systems, such as night vision goggles, offer important strategic advantages in battlefield scenarios and reconnaissance surveys. Until now, the current technology for fabricating these devices has been limited by low throughput and high cost which ultimately limit the availability of these sensor devices. We have developed and fabricated an alternative design for pyroelectric IR imaging sensors that utilizes a multilayered thin film deposition scheme to create a monolithic thin film imaging element on an active silicon substrate for the first time. This approach combines a thin film pyroelectric imaging element with a thermally insulating SiO{sub 2} aerogel thin film to produce a new type of uncooled IR sensor that offers significantly higher thermal, spatial, and temporal resolutions at a substantially lower cost per unit. This report describes the deposition, characterization and optimization of the aerogel thermal isolation layer and an appropriate pyroelectric imaging element. It also describes the overall integration of these components along with the appropriate planarization, etch stop, adhesion, electrode, and blacking agent thin film layers into a monolithic structure. 19 refs., 8 figs., 6 tabs.

  7. Sub-picosecond IR study of the reactive intermediate in an alkane...

    Office of Scientific and Technical Information (OSTI)

    Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2 Citation Details In-Document Search Title: Sub-picosecond IR study of ...

  8. The IR-resummed Effective Field Theory of Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    IR-resummed Effective Field Theory of Large Scale Structures Citation Details In-Document Search Title: The IR-resummed Effective Field Theory of Large Scale Structures We present a ...

  9. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches Data for a number of ...

  10. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: ...

  11. Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers

    SciTech Connect

    Ran, Xing-Rui; Wang, Ning; Xie, Wei-Ping; Xiong, Yan-Ju; Cheng, Qian; Long, Yi; Yue, Shan-Tang; Liu, Ying-Liang

    2015-05-15

    By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, ([Ln{sup III}Ag{sup I}(na)(ina)(ox)]·2(H{sub 2}O)){sub n} [Ln=Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Ho(6), Y(7), Yb(8)], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. - Graphical abstract: Series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction which are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. - Highlights: • Complexes 1–8 are first built by three kinds of organic ligands based on nicotinic acid and isonicotinic acid. • PCPs 1–8 are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. • The total solvent-accessible volume of PCP 2 comprises 11.6% of the crystal volume after dislodging the free water molecules. • Complexes 2 and 4 exhibit characteristic lanthanide-centered luminescence, while compounds 3 and 5 show antiferromagnetic behaviors.

  12. A new architecture as transparent electrodes for solar and IR applications based on photonic structures via soft lithography

    SciTech Connect

    Kuang, Ping

    2011-05-15

    Transparent conducting electrodes with the combination of high optical transmission and good electrical conductivity are essential for solar energy harvesting and electric lighting devices. Currently, indium tin oxide (ITO) is used because ITO offers relatively high transparency (>80%) to visible light and low sheet resistance (R{sub s} = 10 ohms/square ({Omega}#2;/?)) for electrical conduction. However, ITO is costly due to limited indium reserves, and it is brittle. These disadvantages have motivated the search for other conducting electrodes with similar or better properties. There has been research on a variety of electrode structures involving carbon nanotube networks, graphene films, nanowire and nanopatterned meshes and grids. Due to their novel characteristics in light manipulation and collection, photonic crystal structures show promise for further improvement. Here, we report on a new architecture consisting of nanoscale high aspect ratio metallic photonic structures as transparent electrodes fabricated via a combination of processes. For (Au) and silver (Ag) structures, the visible light transmission can reach as high as 80%, and the sheet resistance of the structure can be as low as 3.2{Omega}#2;/?. The optical transparency of the high aspect ratio metal structures at visible wavelength range is comparable to that of ITO glass, while their sheet resistance is more than 3 times lower, which indicates a much higher electrical conductivity of the metal structures. Furthermore, the high aspect ratio metal structures have very high infrared (IR) reflection (90%) for the transverse magnetic (TM) mode, which can lead to the development of fabrication of metallic structures as IR filters for heat control applications. Investigations of interdigitated structures based on the high aspect ratio metal electrodes are ongoing to study the feasibility in smart window applications in light transmission modulation.

  13. Carbon-Supported IrNi Core-Shell Nanoparticles: Synthesis Characterization and Catalytic Activity

    SciTech Connect

    K Sasaki; K Kuttiyiel; L Barrio; D Su; A Frenkel; N Marinkovic; D Mahajan; R Adzic

    2011-12-31

    We synthesized carbon-supported IrNi core-shell nanoparticles by chemical reduction and subsequent thermal annealing in H{sub 2}, and verified the formation of Ir shells on IrNi solid solution alloy cores by various experimental methods. The EXAFS analysis is consistent with the model wherein the IrNi nanoparticles are composed of two-layer Ir shells and IrNi alloy cores. In situ XAS revealed that the Ir shells completely protect Ni atoms in the cores from oxidation or dissolution in an acid electrolyte under elevated potentials. The formation of Ir shell during annealing due to thermal segregation is monitored by time-resolved synchrotron XRD measurements, coupled with Rietveld refinement analyses. The H{sub 2} oxidation activity of the IrNi nanoparticles was found to be higher than that of a commercial Pt/C catalyst. This is predominantly due to Ni-core-induced Ir shell contraction that makes the surface less reactive for IrOH formation, and the resulting more metallic Ir surface becomes more active for H{sub 2} oxidation. This new class of core-shell nanoparticles appears promising for application as hydrogen anode fuel cell electrocatalysts.

  14. Work Function Reduction by BaO: Growth of Crystalline Barium Oxide on Ag(001) and Ag(111) Surfaces

    SciTech Connect

    Droubay, Timothy C.; Kong, Lingmei; Chambers, Scott A.; Hess, Wayne P.

    2015-02-01

    Ultrathin films of barium oxide were grown on Ag(001) and Ag(111) using the evaporation of Ba metal in an O2 atmosphere by molecular beam epitaxy. Ultraviolet photoemission spectroscopy reveals that films consisting of predominantly BaO or BaO2 result in Ag(001) work function reductions of 1.74 eV and 0.64 eV, respectively. On the Ag(001) surface, Ba oxide growth is initiated by two-dimensional nucleation of epitaxial BaO, followed by a transition to three-dimensional dual-phase nucleation of epitaxial BaO and BaO2. Three-dimensional islands of primarily BaO2(111) nucleate epitaxially on the Ag(111) substrate leaving large patches of Ag uncovered. We find no indication of chemical reaction or charge transfer between the films and the Ag substrates. These data suggest that the origin of the observed work function reduction is largely due to a combination of BaO surface relaxation and an electrostatic compressive effect.

  15. EA-263 UBS AG, London Branch | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Mexico. EA-263 UBS AG, London Branch (35.25 KB) More Documents & Publications EA-232 OGE Energy Resources Inc EA-249 Exelon Generation Company LLC EA-122-A Dynegy Power Marketing,

  16. PVA TePla AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    search Name: PVA TePla AG Place: Asslar, Germany Zip: 35614 Product: Supplier of plants and equipment for vacuum systems, crystal-growing systems and plasma systems, some of...

  17. Otter Tail Ag Enterprises LLC | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Enterprises LLC Jump to: navigation, search Name: Otter Tail Ag Enterprises LLC Place: Fergua Falls, Minnesota Zip: 56537-7518 Product: Developed a 55m gallon ethanol facility in...

  18. SFC Smart Fuel Cell AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Zip: D-85649 Product: Smart Fuel Cell designs, develops and manufactures direct methanol fuel cell systems. References: SFC Smart Fuel Cell AG1 This article is a stub. You...

  19. IR Spectrometer Using 90-degree Off-axis Parabolic Mirrors

    SciTech Connect

    Robert M. Malone, Richard, G. Hacking, Ian J. McKenna, and Daniel H. Dolan

    2008-09-02

    A gated spectrometer has been designed for real-time, pulsed infrared (IR) studies at the National Synchrotron Light ource at the Brookhaven National Laboratory. A pair of 90-degree, off-axis parabolic mirrors are used to relay the light from an entrance slit to an output IR recording camera. With an initial wavelength range of 1500–4500 nm required, gratings could not be used in the spectrometer because grating orders would overlap. A magnesium oxide prism, placed between these parabolic mirrors, serves as the dispersion element. The spectrometer is doubly telecentric. With proper choice of the air spacing between the prism and the second parabolic mirror, any spectral region of interest within the InSb camera array’s sensitivity region can be recorded. The wavelengths leaving the second parabolic mirror are collimated, thereby relaxing the camera positioning tolerance. To set up the instrument, two different wavelength (visible) lasers are introduced at the entrance slit and made collinear with the optical axis via flip mirrors. After dispersion by the prism, these two laser beams are directed to tick marks located on the outside housing of the gated IR camera. This provides first-order wavelength calibration for the instrument. Light that is reflected off the front prism face is coupled into a high-speed detector to verify steady radiance during the gated spectral imaging. Alignment features include tick marks on the prism and parabolic mirrors. This instrument was designed to complement singlepoint pyrometry, which provides continuous time histories of a small collection of spots from shock-heated targets.

  20. MULTI-TUBE POWER LEADS TOWER FOR BEPCII IR MAGNETS.

    SciTech Connect

    JIA,L.X.; ZHANG,X.B.; WANG,L.; WANG,T.H.; YAO,Z.L.

    2004-05-11

    A power lead tower containing the multi-tube power leads is designed and under fabrication for the superconducting IR quadrupole magnets in the Beijing Electron Position Collider Upgrade (BEPCII). The lead tower consists of six pairs of gas-cooled leads for seven superconducting coils at various operating currents. The power lead is designed in a modular fashion, which can be easily applied to suit different operating current. The end copper block of the tube lead has a large cold mass that provide a large time constant in case of cooling flow interruption. A novel cryogenic electrical isolator is used for the leads.

  1. Commissioning of the new AGS MMPS transformers

    SciTech Connect

    Bajon,E.; Badea, V. S.; Bannon, M.; Bonati, R.; Marneris, I. M.; Porqueddu, r.; Roser, T.; Sandberg, J.; Savatteri, S.

    2009-05-04

    The Brookhaven AGS Main Magnet Power Supply (MMPS) is a thyristor control supply rated at 5500 Amps. +/-9000 Volts. The peak magnet power is 50 MWatts. The power supply is fed from a motor/generator manufactured by Siemens. During rectify and invert operation the P Bank power supplies are used. During the flattops the F Bank power supplies are used. The P Bank power supplies are fed from two 23 MVA transformers and the F Bank power supplies are fed from two 5.3 MYA transformers. The fundamental frequency of the F Bank power supplies is 1440 Hz, however the fundamental frequency of the P banks was 720 Hz. It was very important to reduce the ripple during rectify to improve polarized proton operations. For this reason and also because the original transformers were 45 years old we replaced these transformers with new ones and we made the fundamental frequency of both P and F banks 1440 Hz. This paper will highlight the major hurdles that were involved during the installation of the new transformers. It will present waveforms while running at different power levels up to 6MW full load. It will show the transition from the F-Bank power supplies to the P-Banks and also show the improvements in ripple made on the P-Bank power supplies.

  2. Phase diagrams of the Tb-Ag-In and Dy-Ag-In systems at 870 K

    SciTech Connect

    Demchyna, M.; Belan, B.; Manyako, M.; Pietraszko, A.; Kalychak, Ya.

    2012-08-15

    The phase equilibria of Tb-Ag-In and Dy-Ag-In ternary systems have been studied at 870 K in the whole concentration range by means of X-ray powder, single crystal X-ray diffraction and EDX analyses. Isothermal sections of Tb-Ag-In and Dy-Ag-In phase diagrams at this temperature have been constructed. Both systems are characterized by formation of three ternary compounds: REAg{sub 3}In{sub 3} (YbAg{sub 2}In{sub 4}-type, space group Im-3), REAg{sub 2}In (MnCu{sub 2}Al-type, space group Fm-3m) and RE{sub 2}AgIn{sub 3} (CaIn{sub 2}-type, space group P6{sub 3}/mmc) RE=Tb, Dy. Homogeneity ranges of the ternary phases with CaIn{sub 2} structure type lies from 35 to 60 at% of In for Tb-containing phase and from 39 to 50 at% of In for Dy-containing phase. The existence of solid solutions based on REAg (CsCl-type, space group Pm-3m) binary compounds up to 30 at% of In and REIn{sub 3} (AuCu{sub 3}-type, space group Pm-3 m) binary compounds up to 5 at% of Ag has been found. - Graphical Abstract: Phase relations in the ternary systems Tb-Ag-In and Dy-Ag-In have been established for the isothermal section at T=870 K based on X-ray powder and single crystal diffraction analyses. The existence of three ternary compounds in each system were observed. Highlights: Black-Right-Pointing-Pointer Isothermal section of Tb-Ag-In system at T=870 K was constructed. Black-Right-Pointing-Pointer Isothermal section of Dy-Ag-In system at T=870 K was constructed. Black-Right-Pointing-Pointer Three ternary compounds and two solid solutions in each system were detected.

  3. Qualification tests for {sup 192}Ir sealed sources

    SciTech Connect

    Iancso, Georgeta Iliescu, Elena Iancu, Rodica

    2013-12-16

    This paper describes the results of qualification tests for {sup 192}Ir sealed sources, available in Testing and Nuclear Expertise Laboratory of National Institute for Physics and Nuclear Engineering 'Horia Hulubei' (I.F.I.N.-HH), Romania. These sources had to be produced in I.F.I.N.-HH and were tested in order to obtain the authorization from The National Commission for Nuclear Activities Control (CNCAN). The sources are used for gammagraphy procedures or in gammadefectoscopy equipments. Tests, measurement methods and equipments used, comply with CNCAN, AIEA and International Quality Standards and regulations. The qualification tests are: 1. Radiological tests and measurements: dose equivalent rate at 1 m; tightness; dose equivalent rate at the surface of the transport and storage container; external unfixed contamination of the container surface. 2. Mechanical and climatic tests: thermal shock; external pressure; mechanic shock; vibrations; boring; thermal conditions for storage and transportation. Passing all tests, it was obtained the Radiological Security Authorization for producing the {sup 192}Ir sealed sources. Now IFIN-HH can meet many demands for this sealed sources, as the only manufacturer in Romania.

  4. Infrared (IR) photon-sensitive spectromicroscopy in a cryogenic environment

    DOEpatents

    Pereverzev, Sergey

    2016-06-14

    A system designed to suppress thermal radiation background and to allow IR single-photon sensitive spectromicroscopy of small samples by using both absorption, reflection, and emission/luminescence measurements. The system in one embodiment includes: a light source; a plurality of cold mirrors configured to direct light along a beam path; a cold or warm sample holder in the beam path; windows of sample holder (or whole sample holder) are transparent in a spectral region of interest, so they do not emit thermal radiation in the same spectral region of interest; a cold monochromator or other cold spectral device configured to direct a selected fraction of light onto a cold detector; a system of cold apertures and shields positioned along the beam path to prevent unwanted thermal radiation from arriving at the cold monochromator and/or the detector; a plurality of optical, IR and microwave filters positioned along the beam path and configured to adjust a spectral composition of light incident upon the sample under investigation and/or on the detector; a refrigerator configured to maintain the detector at a temperature below 1.0K; and an enclosure configured to: thermally insulate the light source, the plurality of mirrors, the sample holder, the cold monochromator and the refrigerator.

  5. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Universit de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  6. Preparation, characterization and photocatalytic activity of visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites

    SciTech Connect

    Li, Xiaojuan Tang, Duanlian; Tang, Fan; Zhu, Yunyan; He, Changfa; Liu, Minghua Lin, Chunxiang; Liu, Yifan

    2014-08-15

    Highlights: A plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst has been successfully synthesized. Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibit high visible light photocatalytic activity. Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst is stable and magnetically separable. - Abstract: A visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has been successfully synthesized via a depositionprecipitation and photoreduction through a novel one-pot process. X-ray diffraction spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and UVvis diffuse reflectance spectroscopy were employed to investigate the crystal structure, chemical composition, morphology, and optical properties of the as-prepared nanocomposites. The photocatalytic activities of the nanocomposites were evaluated by photodegradation of Rhodamine B (RhB) and phenol under visible light. The results demonstrated that the obtained Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibited higher photocatalytic activity as compared to pure ZnFe{sub 2}O{sub 4}. In addition, the sample photoreduced for 20 min and calcined at 500 C achieved the highest photocatalytic activity. Furthermore, the Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has high stability under visible light irradiation and could be conveniently separated by using an external magnetic field.

  7. EDDY CURRENT EFFECT OF THE BNL-AGS VACUUM CHAMBER ON THE OPTICS OF THE BNL-AGS SYNCHROTRON.

    SciTech Connect

    TSOUPAS,N.; AHRENS,L.; BROWN,K.A.; GLENN,J.W.; GARDNER,K.

    1999-03-29

    During the acceleration cycle of the AGS synchrotron, eddy currents are generated within the walls of the vacuum chambers of the AGS main magnets. The vacuum chambers have elliptical cross section, are made of inconel material with a wall thickness of 2 mm and are placed within the gap of the combined-function main magnets of the AGS synchrotron. The generation of the eddy currents in the walls of the vacuum chambers, creates various magnetic multipoles, which affect the optics of the AGS machine. In this report these magnetic multipoles are calculated for various time interval starting at the acceleration cycle, where the magnetic field of the main magnet is {approx}0.1 T, and ending before the beam extraction process, where the magnetic field of the main magnet is almost constant at {approx}1.1 T. The calculations show that the magnetic multipoles generated by the eddy-currents affect the optics of the AGS synchrotron during the acceleration cycle and in particular at low magnetic fields of the main magnet. Their effect is too weak to affect the optics of the AGS machine during beam extraction at the nominal energies.

  8. Half-life determination for {sup 108}Ag and {sup 110}Ag

    SciTech Connect

    Zahn, Guilherme S.; Genezini, Frederico A.

    2014-11-11

    In this work, the half-life of the short-lived silver radionuclides {sup 108}Ag and {sup 110}Ag were measured by following the activity of samples after they were irradiated in the IEA-R1 reactor. The results were then fitted using a non-paralizable dead time correction to the regular exponential decay and the individual half-life values obtained were then analyzed using both the Normalized Residuals and the Rajeval techniques, in order to reach the most exact and precise final values. To check the validity of dead-time correction, a second correction method was also employed by means of counting a long-lived {sup 60}Co radioactive source together with the samples as a livetime chronometer. The final half-live values obtained using both dead-time correction methods were in good agreement, showing that the correction was properly assessed. The results obtained are partially compatible with the literature values, but with a lower uncertainty, and allow a discussion on the last ENSDF compilations' values.

  9. Evidence for hybrid surface metallic band in (4??4) silicene on Ag(111)

    SciTech Connect

    Tsoutsou, D. Xenogiannopoulou, E.; Golias, E.; Tsipas, P.; Dimoulas, A.

    2013-12-02

    The electronic band structure of monolayer (4??4) silicene on Ag(111) is imaged by angle resolved photoelectron spectroscopy. A dominant hybrid surface metallic band is observed to be located near the bulk Ag sp-band which is also faintly visible. The two-dimensional character of the hybrid band has been distinguished against the bulk character of the Ag(111) sp-band by means of photon energy dependence experiments. The surface band exhibits a steep linear dispersion around the K{sup }{sub Ag} point and has a saddle point near the M{sup }{sub Ag} point of Ag(111) resembling the ?-band dispersion in graphene.

  10. A UV to mid-IR study of AGN selection

    SciTech Connect

    Chung, Sun Mi; Kochanek, Christopher S.; Assef, Roberto; Brown, Michael J. I.; Stern, Daniel; Jannuzi, Buell T.; Gonzalez, Anthony H.; Hickox, Ryan C.; Moustakas, John

    2014-07-20

    We classify the spectral energy distributions (SEDs) of 431,038 sources in the 9 deg{sup 2} Boötes field of the NOAO Deep Wide-Field Survey (NDWFS). There are up to 17 bands of data available per source, including ultraviolet (GALEX), optical (NDWFS), near-IR (NEWFIRM), and mid-infrared (IRAC and MIPS) data, as well as spectroscopic redshifts for ∼20,000 objects, primarily from the AGN and Galaxy Evolution Survey. We fit galaxy, active galactic nucleus (AGN), stellar, and brown dwarf templates to the observed SEDs, which yield spectral classes for the Galactic sources and photometric redshifts and galaxy/AGN luminosities for the extragalactic sources. The photometric redshift precision of the galaxy and AGN samples are σ/(1 + z) = 0.040 and σ/(1 + z) = 0.169, respectively, with the worst 5% outliers excluded. On the basis of the χ{sub ν}{sup 2} of the SED fit for each SED model, we are able to distinguish between Galactic and extragalactic sources for sources brighter than I = 23.5 mag. We compare the SED fits for a galaxy-only model and a galaxy-AGN model. Using known X-ray and spectroscopic AGN samples, we confirm that SED fitting can be successfully used as a method to identify large populations of AGNs, including spatially resolved AGNs with significant contributions from the host galaxy and objects with the emission line ratios of 'composite' spectra. We also use our results to compare with the X-ray, mid-IR, optical color, and emission line ratio selection techniques. For an F-ratio threshold of F > 10, we find 16,266 AGN candidates brighter than I = 23.5 mag and a surface density of ∼1900 AGN deg{sup –2}.

  11. The AGS Ggamma Meter and Calibrating the Gauss Clock

    SciTech Connect

    Ahrens, Leif

    2014-03-31

    During AGS Polarized Proton acceleration periods, one output from the AGS Ggamma Meter, namely the energy (or Ggamma) calculated from the magnetic field in the AGS main magnets and the beam radius- both measured in particular instant, is used to figure out the times in the AGS magnet acceleration cycle when the beam passes through a particular set of depolarizing resonances. The resonance set occur whenever a particle’s Ggamma (energy*(G/m) becomes nearly equal to n*Qx (i.e. any integer multiplied by the horizontal betatron tune). This deliverable is why the machinery is referred to as the ''Ggamma Meter'' rather than the AGS energy meter. The Ggamma Meter takes as inputs a set of measurements of frequency (F(t)), radius (r(t)), and gauss clock counts (GCC(t)). The other energy (GgammaBr) assumes the field when the gauss clock starts counting is known. The change in field to time t is given by the measured accumulated gauss clock counts multiplied by the gauss clock calibration (gauss/GCC). In order to deal with experimental data, this calibration factor gets an added ad hoc complication, namely a correction dependent on the rate of change the counting rate. The Ggamma meter takes GCC(t) and together with the past history for this cycle calculates B(t).

  12. Progress and status of the AGS Booster project

    SciTech Connect

    Weng, W.T. )

    1989-01-01

    New physics opportunities, such as: rare K-decay, neutrino and heavy ion physics demand that a rapid-cycling high vacuum and high intensity Booster be built for the AGS at Brookhaven National Laboratory. The circumference of the Booster ring is one-quarter that of the AGS. Three modes of operation for various particles are envisioned. For unpolarized protons, four Booster pulses would be injected at a 7.5 Hz repetition rate within a 400 ms flat bottom of the AGS, enabling the present 1.5 {times} 10{sup 13} ppp to be increased to 6 {times} 10{sup 13} ppp. The protons would be accelerated to 1.5 GeV although the bending capability provided for heavy ions would eventually allow protons to be accelerated to 2.5 GeV. For heavy ions the rep rates is about 1 Hz and only one pulse would be injected into the AGS. For polarized protons 20 or so pulses can be stored in the Booster ring before injecting them into the AGS. Provisions for mixed modes of operation into a super cycle has been provided for future needs. In this paper, the lattice design and magnet characteristics will be briefly reviewed and major design issues will be discussed and design choices explained. Finally, the construction status and schedule will be presented. 9 refs., 3 figs.

  13. Complexation and phase evolution at dimethylformamide-Ag(111) interfaces

    DOE PAGES [OSTI]

    Song, Wentao; Leung, Kevin; Shao, Qian; Gaskell, Karen J.; Reutt-Robey, Janice E.

    2016-09-15

    The interaction of solvent molecules with metallic surfaces impacts many interfacial chemical processes. We investigate the chemical and structure evolution that follows adsorption of the polar solvent dimethylformamide (DMF) on Ag(111). An Ag(DMF)2 coordination complex forms spontaneously by DMF etching of Ag(111), yielding mixed films of the complexes and DMF. Utilizing ultrahigh vacuum scanning tunneling microscopy (UHV-STM), in combination with X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) computations, we map monolayer phases from the 2-D gas regime, consisting of a binary mixture of DMF and Ag(DMF)2, through the saturation monolayer limit, in which these two chemical species phasemore » separate into ordered islands. Structural models for the near-square DMF phase and the chain-like Ag(DMF)2 phase are presented and supported by DFT computation. Interface evolution is summarized in a surface pressure-composition phase diagram, which allows structure prediction over arbitrary experimental conditions. In conclusion, this work reveals new surface coordination chemistry for an important electrolyte-electrode system, and illustrates how surface pressure can be used to tune monolayer phases.« less

  14. Fabrication, characterization and photocatalytic properties of Ag/AgI/BiOI heteronanostructures supported on rectorite via a cation-exchange method

    SciTech Connect

    Chen, Yunfang; Fang, Jianzhang; Lu, Shaoyou; Wu, Yan; Chen, Dazhi; Huang, Liyan; Xu, Weicheng; Zhu, Ximiao; Fang, Zhanqiang

    2015-04-15

    Highlights: • Ag/AgI/BiOI-rectorite was prepared by twice cation-exchange process. • Ag/AgI/BiOI-rectorite photocatalyst possessed SPR and adsorption capacity. • Ag/AgI/BiOI-rectorite exhibited highly photocatalytic activity. • Trapped holes and ·O{sub 2}{sup −} were formed active species in the photocatalytic system. - Abstract: In this work, a new plasmonic photocatalyst Ag/AgI/BiOI-rectorite was prepared via a cation exchange process. The photocatalyst had been characterized by X-ray powder diffraction (XRD), Raman spectra, nitrogen sorption (BET), field-emission scanning electron microscope (FE-SEM), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity, which was evaluated by degradation of rhodamine B (RhB) and bisphenol A (BPA) under visible light irradiation, was enhanced significantly by loading Ag/AgI/BiOI nanoparticles onto rectorite. The photogenerated holes and superoxide radical (·O{sub 2}{sup −}) were both formed as active species for the photocatalytic reactions under visible light irradiation. The existence of metallic Ag particles, which possess the surface plasmon resonance effect, acted as an indispensable role in the photocatalytic reaction.

  15. Epitaxial growth of iridate pyrochlore Nd2Ir2O7 films

    DOE PAGES [OSTI]

    Gallagher, J. C.; Esser, B. D.; Morrow, R.; Dunsiger, S. R.; Williams, R. E. A.; Woodward, P. M.; McComb, D. W.; Yang, F. Y.

    2016-02-29

    Epitaxial films of the pyrochlore Nd2Ir2O7 have been grown on (111)-oriented yttria-stabilized zirconia (YSZ) substrates by off-axis sputtering followed by post-growth annealing. X-ray diffraction (XRD) results demonstrate phase-pure epitaxial growth of the pyrochlore films on YSZ. Scanning transmission electron microscopy (STEM) investigation of an Nd2Ir2O7 film with a short post-annealing provides insight into the mechanism for crystallization of Nd2Ir2O7 during the post-annealing process. STEM images reveal clear pyrochlore ordering of Nd and Ir in the films. As a result, the epitaxial relationship between the YSZ and Nd2Ir2O7 is observed clearly while some interfacial regions show a thin region with polycrystallinemore » Ir nanocrystals.« less

  16. FT-IR microscopical analysis with synchrotron radiation: The microscope optics and system performance

    SciTech Connect

    Reffner, J.A.; Martoglio, P.A.; Williams, G.P.

    1995-01-01

    When a Fourier transform infrared (FT-IR) microspectrometer was first interfaced with the National Synchrotron Light Source (NSLS) in September 1993, there was an instant realization that the performance at the diffraction limit had increased 40-100 times. The synchrotron source transformed the IR microspectrometer into a true IR microprobe, providing high-quality IR spectra for probe diameters at the diffraction limit. The combination of IR microspectroscopy and synchrotron radiation provides a powerful new tool for molecular spectroscopy. The ability to perform IR microspectroscopy with synchrotron radiation is still under development at Brookhaven National Laboratory, but several initial studies have been completed that demonstrate the broad-ranging applications of this technology and its potential for materials characterization.

  17. Phthalocyanine adsorption to graphene on Ir(111): Evidence for decoupling from vibrational spectroscopy

    SciTech Connect

    Endlich, M. Gozdzik, S.; Néel, N.; Kröger, J.; Rosa, A. L. da; Frauenheim, T.; Wehling, T. O.

    2014-11-14

    Phthalocyanine molecules have been adsorbed to Ir(111) and to graphene on Ir(111). From a comparison of scanning tunneling microscopy images of individual molecules adsorbed to the different surfaces alone it is difficult to discern potential differences in the molecular adsorption geometry. In contrast, vibrational spectroscopy using inelastic electron scattering unequivocally hints at strong molecule deformations on Ir(111) and at a planar adsorption geometry on graphene. The spectroscopic evidence for the different adsorption configurations is supported by density functional calculations.

  18. IR Imaging Using Arrays of SiO2 Micromechanical Detectors (Journal...

    Office of Scientific and Technical Information (OSTI)

    Each detector element incorporates an optical resonant cavity layer in the IR absorbing region of the sensing element. The simplified microfabrication process requires only four ...

  19. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches

    Energy.gov [DOE]

    Data for a number of regulated emissions and ethanol using the SESAM FT-IR compare favorably with standard emissions analyzers.

  20. On Loops in Inflation II: IR Effects in Single Clock Inflation...

    Office of Scientific and Technical Information (OSTI)

    Title: On Loops in Inflation II: IR Effects in Single Clock Inflation Authors: Senatore, Leonardo ; Stanford U., ITP KIPAC, Menlo Park ; Zaldarriaga, Matias ; Princeton, Inst. ...

  1. Structure and magnetic properties of the pyrochlore iridate Y2Ir2O7...

    Office of Scientific and Technical Information (OSTI)

    Structure and magnetic properties of the pyrochlore iridate Y2Ir2O7 Citation Details ... Sponsoring Org: USDOE Country of Publication: United States Language: English Word Cloud ...

  2. Oxygen Reduction at Very Low Overpotential on Nanoporous Ag Catalysts

    DOE PAGES [OSTI]

    Zhou, Yang; Lu, Qi; Zhuang, Zhongbin; Hutchings, Gregory S.; Kattel, Shyam; Yan, Yushan; Chen, Jingguang G.; Xiao, John Q.; Jiao, Feng

    2015-05-07

    Here we report a monolithic nanoporous Ag (np-Ag) material, synthesized using the dealloying method, as high-performance catalysts for ORR in alkaline media. As shown in Scheme 1, when there is insufficient potential input, the O2 molecules are more likely to rebound off from a planar electrode surface (i.e. bulk polycrystalline metal, films made from nanoparticles or nanowires) before they could be reduced. In contrast, they are more likely to be trapped inside the monolithic nanoporous structure, contacting with catalytic surface for multiple time, which greatly enhances the chance for them to be fully reduced. As a result, the np-Ag catalystmore » is able to achieve an equivalent or better ORR performance than the state-of the-art Pt/C catalyst at low overpotentials, which is most desired in electrochemical energy applications for maximizing efficiency.« less

  3. Oxygen Reduction at Very Low Overpotential on Nanoporous Ag Catalysts

    SciTech Connect

    Zhou, Yang; Lu, Qi; Zhuang, Zhongbin; Hutchings, Gregory S.; Kattel, Shyam; Yan, Yushan; Chen, Jingguang G.; Xiao, John Q.; Jiao, Feng

    2015-05-07

    Here we report a monolithic nanoporous Ag (np-Ag) material, synthesized using the dealloying method, as high-performance catalysts for ORR in alkaline media. As shown in Scheme 1, when there is insufficient potential input, the O2 molecules are more likely to rebound off from a planar electrode surface (i.e. bulk polycrystalline metal, films made from nanoparticles or nanowires) before they could be reduced. In contrast, they are more likely to be trapped inside the monolithic nanoporous structure, contacting with catalytic surface for multiple time, which greatly enhances the chance for them to be fully reduced. As a result, the np-Ag catalyst is able to achieve an equivalent or better ORR performance than the state-of the-art Pt/C catalyst at low overpotentials, which is most desired in electrochemical energy applications for maximizing efficiency.

  4. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOEpatents

    Anderson, I.E.; Yost, F.G.; Smith, J.F.; Miller, C.M.; Terpstra, R.L.

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217 C and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid ``mushy`` zone) relative to the eutectic melting temperature (e.g. up to 15 C above the eutectic melting temperature). 5 figs.

  5. Field-induced quantum criticality in YbAgGe

    SciTech Connect

    Bud'ko, S.; Canfield, P.

    2008-01-01

    YbAgGe is one of the very few stoichiometric, Yb-based, heavy fermion materials that exhibit field-induced quantum criticality. We will present an overview of thermodynamic and transport measurements in YbAgGe single crystals. Moderate magnetic field (45-90 kOe, depending on orientation) suppresses long range magnetic order, giving rise to non-Fermi-liquid behavior followed at higher field by a crossover to a heavy Fermi-liquid. Given the more accessible temperature and field scales, a non-Fermi liquid region rather than point for T {yields} 0 K may be detected.

  6. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOEpatents

    Anderson, Iver E.; Yost, Frederick G.; Smith, John F.; Miller, Chad M.; Terpstra, Robert L.

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217.degree. C. and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid "mushy" zone) relative to the eutectic melting temperature (e.g. up to 15.degree. C. above the eutectic melting temperature).

  7. Wacker Chemie AG formerly Wacker GmbH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Wacker Chemie AG formerly Wacker GmbH Jump to: navigation, search Name: Wacker Chemie AG (formerly Wacker GmbH) Place: Munich, Germany Zip: 81737 Sector: Solar Product: German...

  8. Solar World USA not SolarWorld AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    World USA not SolarWorld AG Jump to: navigation, search Name: Solar World USA (not SolarWorld AG) Place: Colorado Springs, Colorado Zip: 80907 Sector: Solar Product: Solar World...

  9. Deutsche Solar AG formerly Bayer Solar GmbH | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    Solar AG formerly Bayer Solar GmbH Jump to: navigation, search Name: Deutsche Solar AG (formerly Bayer Solar GmbH) Place: FreibergSachsen, Germany Zip: 9599 Sector: Solar Product:...

  10. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine ...

  11. Bull Solar GmbH Bull Holding AG | Open Energy Information

    OpenEI (Open Energy Information) [EERE & EIA]

    (Bull Holding AG) Place: North Rhine-Westphalia, Germany Sector: Solar Product: German solar installer. References: Bull Solar GmbH (Bull Holding AG)1 This article is a stub....

  12. Origin of Novel Diffusions of Cu and Ag in Semiconductors: The...

    Office of Scientific and Technical Information (OSTI)

    Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe Prev Next Title: Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe ...

  13. Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) with a two-dimensional square lattice of Ag 2+ ions (Ag=silver, Pyz-pyrdzine, S2O8=sulfate)

    SciTech Connect

    Singleton, John; Mc Donald, R; Sengupta, P; Cox, S; Manson, J; Southerland, H; Warter, M; Stone, K; Stephens, P; Lancaster, T; Steele, A; Blundell, S; Baker, P; Pratt, F; Lee, C; Whangbo, M

    2009-01-01

    X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz){sub 2}(S{sub 2}O{sub 8}) consists of 2D square nets of Ag{sup 2+} ions resulting from the corner-sharing of axially elongated AgN{sub 4}O{sub 2} octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, {mu}{sup +}Sr measurements indicate that Ag(pyz){sub 2}(S{sub 2}O{sub 8}) undergoes 3D magnetic ordering below 7.8(3) K.

  14. Enhanced oxygen evolution activity of IrO2 and RuO2 (100) surfaces...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Enhanced oxygen evolution activity of IrO2 and RuO2 (100) surfaces Citation Details In-Document Search ... Here we report that the (100) surface of IrO2 and RuO2 is ...

  15. NaIrO{sub 3}-A pentavalent post-perovskite

    SciTech Connect

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-03-15

    Sodium iridium (V) oxide, NaIrO{sub 3,} was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO{sub 3}, synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO{sub 3} post-perovskite. Research highlights: {yields} NaIrO{sub 3} post-perovskite stabilized by pressure. {yields} First example of a pentavalent oxide post-perovskite. {yields} Non-metallic and non-magnetic behavior of NaIrO{sub 3}.

  16. The AGS Booster main ring power supply system

    SciTech Connect

    Soukas, A.; Hughes, K.; Sandberg, J.; Toldo, F.; Zhang, S.Y. )

    1989-01-01

    The AGS Booster is being designed as a very versatile particle accelerator. Its primary function is to be a high quality injector to the currently operating Alternating Gradient Synchrotron (AGS). The Booster/AGS combination will produce proton intensities greater than 5 {times} 10{sup 13}protons per pulse (ppp), and accelerate heavy ions, with mass up to 200, to a maximum energy of 15 GeV per atomic mass unit (GeV/amu). The power supply for the Booster Main Ring (BMRPS) has to accommodate a wide range of cycles and a wide range of operating parameters. The cycles range from storage for several seconds to rapid cycling at 7.5 Hz. The peak output power is 18 MW. This paper will describe the AGS Booster machine powering requirements, the choice of power supply, the a.c. circuit tie-in and its associated problems and some of the details of the design of the BMRPS. 9 refs., 2 figs.

  17. Water dissociation on Mn(1×1)/Ag(100)

    DOE PAGES [OSTI]

    Arble, Chris; Tong, Xiao; Giordano, Livia; Ferrari, Anna Maria; Newberg, John T.

    2016-08-19

    In this work we utilize experimental and simulation techniques to examine the molecular level interaction of water with a MnO(1×1) thin film deposited onto Ag(100). The formation of MnO(1×1)/Ag(100) was characterized by low energy electron diffraction and scanning tunneling microscopy. Density functional theory (DFT) shows MnO(1×1) is thermodynamically more stable than MnO(2×1) by –0.4 eV per MnO. Upon exposure to 2.5 Torr water vapor at room temperature, X-ray photoemission spectroscopy results show extensive surface hydroxylation attributed to reactivity at MnO(1×1) terrace sites. DFT calculations of a water monomer on MnO(1×1)/Ag(100) show the dissociated form is energetically more favorable than molecularmore » adsorption, with a hydroxylation activation barrier 0.4 eV per H2O. Lastly, these results are discussed and contrasted with previous studies of MgO/Ag(100) which show a stark difference in behavior for water dissociation.« less

  18. Beam energy evolution of HBT systematics at the AGS

    SciTech Connect

    Best, D.; Ajitanand, N.N.; Alexander, J.M.; Anderson, M.; Brady,F.P.; Case, T.; Caskey, W.; Cebra, D.; Chance, J.L.; Chung, P.; Cole, B.; Crowe, K.; Das, A.C.; Draper, J.E.; Gilkes, M.L.; Gushue, S.; Heffner,M.; Hirsch, A.S.; Hjort, E.L.; Huo, L.; Justice, M.; Kaplan, M.; Keane,D.; Kintner, J.C.; Klay, J.; Krofcheck, D.; Lacey, R.A.; Lisa, M.A.; Liu,H.; Liu, Y.M.; McGrath, R.; Milosevich, Z.; Odyniec, G.; Olson, D.L.; Panitkin, S.Y.; Pinkenburg, C.; Porile, N.T.; Rai, G.; Ritter, H.G.; Romero, J.L.; Scharenberg, R.P.; Schroeder, L.S.; Srivastava, B.; Stone,N.T.B.; Symons, T.J.M.; Wang, S.; Wells, R.; Whitfield, J.; Wienold, T.; Witt, R.; Wood, L.; Yang, X.; Zhang, W.; Zhang, Y.; E895 Collaboration

    1999-07-31

    We present preliminary results of the first pi interferometry (HBT) excitation function at intermediate AGS energies. The beam energy evolution of the correlations' dependence on mr:centrality, and emission angle with respect to the reaction I,lane are discussed. Comparisons with predictions of the RQMD cascade model are made.

  19. The development of in-situ calibration method for divertor IR thermography in ITER

    SciTech Connect

    Takeuchi, M.; Sugie, T.; Ogawa, H.; Takeyama, S.; Itami, K.

    2014-08-21

    For the development of the calibration method of the emissivity in IR light on the divertor plate in ITER divertor IR thermography system, the laboratory experiments have been performed by using IR instruments. The calibration of the IR camera was performed by the plane black body in the temperature of 100–600 degC. The radiances of the tungsten heated by 280 degC were measured by the IR camera without filter (2.5–5.1 μm) and with filter (2.95 μm, 4.67 μm). The preliminary data of the scattered light of the laser of 3.34 μm that injected into the tungsten were acquired.

  20. EFG IO?-90)

    Office of Legacy Management (LM)

    ... Luckey, Ohio, site on land purchased by the Defense Plant Corporation (U.S. Government). ... (successor to the Defense Plant Corporation) to the U.S. Government (Ref. a, f). ...

  1. IO235U

    Office of Legacy Management (LM)

    35U 93 -256 Deoart ent of E e ay *akYhlgs FWdnOfLe DATE : March 25, 1993 REPLY TO AWN OF: EW-93:Hartman SUBJECT: CATEGORICAL EXCLUSION (CX) D~ERMINATION - REMOVAL ACTION AT THE GRANITE CITY SITE TO: Carol M. Borgstrom, Director, Office of NEPA Oversight, FORS, EH-25 Attached is a categorical exclusion (CX) determination describing the proposed removal and disposal of radiologically contaminated materials at the Granite City, Illinois, site. Removal action at this site is being undertaken as part

  2. I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    The New Computing Infrastructure In this issue Things you should know.........................1 Consultants' Corner...................2 Software and Tool News.........................4 Machine News.....................7 HPC-Behind the Scenes....................9 Quarterly Stats........16 Current Machines- a snapshot in time........17 LA-UR-15-26501 Things you should know... Standard service features: The Integrated Computing Network (ICN) Consulting Team provides user support on a wide variety

  3. I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Trinity Issue In this issue Things you should know........................1 Consultants' Corner...................2 Software and Tool News.........................3 Machines News.....................5 HPC-Behind the Scenes.....................8 Quarterly Stats.......10 Current Machines- a snapshot in time.......11 LA-UR-14-27892 Things you should know............ Standard service features The Integrated Computing Network (ICN) Consulting Team provides user support on a wide variety of HPC

  4. I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    In this issue Things you should know........................1 Consultants Corner...................2 Software and Tool News.........................4 Machines News.....................6 HPC-Behind the Scenes.....................8 Quarterly Stats.......12 Current Machines- a snapshot in time.......13 LA-UR-14-25322 Things you should know............ Standard service features The Integrated Computing Network (ICN) Consulting Team provides user support on a wide variety of HPC topics: *

  5. I/O

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ... Figure 1: The diagram is a notional diagram of the future open computing environment in the 2014-2017 timeframe. 8 Quarterly Statistics 9 HPC user Highlight MPAS-Ocean (Model for ...

  6. I/O Libraries

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Help Staff Blogs Request Repository Mailing List Need Help? Out-of-hours Status and Password help Call operations: 1-800-66-NERSC, option 1 or 510-486-6821 Account Support ...

  7. Synchrotron IR microspectroscopy for protein structure analysis: Potential and questions

    DOE PAGES [OSTI]

    Yu, Peiqiang

    2006-01-01

    Synchrotron radiation-based Fourier transform infrared microspectroscopy (S-FTIR) has been developed as a rapid, direct, non-destructive, bioanalytical technique. This technique takes advantage of synchrotron light brightness and small effective source size and is capable of exploring the molecular chemical make-up within microstructures of a biological tissue without destruction of inherent structures at ultra-spatial resolutions within cellular dimension. To date there has been very little application of this advanced technique to the study of pure protein inherent structure at a cellular level in biological tissues. In this review, a novel approach was introduced to show the potential of the newly developed, advancedmore » synchrotron-based analytical technology, which can be used to localize relatively “pure“ protein in the plant tissues and relatively reveal protein inherent structure and protein molecular chemical make-up within intact tissue at cellular and subcellular levels. Several complex protein IR spectra data analytical techniques (Gaussian and Lorentzian multi-component peak modeling, univariate and multivariate analysis, principal component analysis (PCA), and hierarchical cluster analysis (CLA) are employed to relatively reveal features of protein inherent structure and distinguish protein inherent structure differences between varieties/species and treatments in plant tissues. By using a multi-peak modeling procedure, RELATIVE estimates (but not EXACT determinations) for protein secondary structure analysis can be made for comparison purpose. The issues of pro- and anti-multi-peaking modeling/fitting procedure for relative estimation of protein structure were discussed. By using the PCA and CLA analyses, the plant molecular structure can be qualitatively separate one group from another, statistically, even though the spectral assignments are not known. The synchrotron-based technology provides a new approach for protein structure research in

  8. Measuring Broadband IR Irradiance in the Direct Solar Beam (Poster)

    SciTech Connect

    Reda, I.; Konings, J.; Xie, Y.; Dooraghi, M.; Sengupta, M.

    2015-03-01

    Solar and atmospheric science radiometers, e.g. pyranometers, pyrheliometers, and photovoltaic cells are calibrated with traceability to a consensus reference, which is maintained by Absolute Cavity Radiometers (ACRs). The ACR is an open cavity with no window, developed to measure extended broadband direct solar irradiance beyond the ultraviolet and infrared bands below and above 0.2 micrometers and 50 micrometers, respectively. On the other hand, pyranometers and pyrheliometers are developed to measure broadband shortwave irradiance from approximately 0.3 micrometers to 3 micrcometers, while the present photovoltaic cells are limited to approximately 0.3 micrometers to 1 micrometers. The broadband mismatch of ACR versus such radiometers causes discrepancy in radiometers' calibration methods that has not been discussed or addressed in the solar and atmospheric science literature. Pyrgeometers are also used for solar and atmospheric science applications and calibrated with traceability to consensus reference, yet calibrated during nighttime only, because no consensus reference has yet been established for the daytime longwave irradiance. This poster shows a method to measure the broadband IR irradiance in the direct solar beam from 3 micrometers to 50 micrometers, as first step that might be used to help develop calibration methods to address the mismatch between broadband ACR and shortwave radiometers, and the lack of a daytime reference for pyrgeometers. The irradiance was measured from sunrise to sunset for 5 days when the sun disk was cloudless; the irradiance varied from approximately 1 Wm-2 to 16 Wm-2 for solar zenith angle from 80 degres to 16 degrees respectively; estimated uncertainty is 1.5 Wm-2.

  9. Measuring Broadband IR Irradiance in the Direct Solar Beam (Presentation)

    SciTech Connect

    Reda, I.

    2015-03-01

    Solar and atmospheric science radiometers, e.g. pyranometers, pyrheliometers, and photovoltaic cells are calibrated with traceability to a consensus reference, which is maintained by Absolute Cavity Radiometers (ACRs). The ACR is an open cavity with no window, developed to measure extended broadband direct solar irradiance beyond the ultraviolet and infrared bands below and above 0.2 um and 50 um, respectively. On the other hand, pyranometers and pyrheliometers are developed to measure broadband shortwave irradiance from approximately 0.3 um to 3 um, while the present photovoltaic cells are limited to approximately 0.3 um to 1 um. The broadband mismatch of ACR versus such radiometers causes discrepancy in radiometers' calibration methods that has not been discussed or addressed in the solar and atmospheric science literature. Pyrgeometers are also used for solar and atmospheric science applications and are calibrated with traceability to consensus reference, yet are calibrated during nighttime only, because no consensus reference has yet been established for the daytime longwave irradiance. This poster shows a method to measure the broadband IR irradiance in the direct solar beam from 3 um to 50 um, as a first step that might be used to help develop calibration methods to address the mismatch between broadband ACR and shortwave radiometers, and the lack of a daytime reference for pyrgeometers. The irradiance was measured from sunrise to sunset for 5 days when the sun disk was cloudless; the irradiance varied from approximately 1 Wm-2 to 16 Wm-2 for solar zenith angle from 80 degrees to 16 degrees respectively; estimated uncertainty is 1.5 Wm-2.

  10. Characterization and device performance of (AgCu)(InGa)Se2 absorber layers

    SciTech Connect

    Hanket, Gregory; Boyle, Jonathan H.; Shafarman, William N.

    2009-06-08

    The study of (AgCu)(InGa)Se2 absorber layers is of interest in that Ag-chalcopyrites exhibit both wider bandgaps and lower melting points than their Cu counterparts. (AgCu)(InGa)Se2 absorber layers were deposited over the composition range 0 < Ag/(Ag+Cu) < 1 and 0.3 < Ga/(In+Ga) < 1.0 using a variety of elemental co-evaporation processes. Films were found to be singlephase over the entire composition range, in contrast to prior studies. Devices with Ga content 0.3 < Ga/(In+Ga) <0.5 tolerated Ag incorporation up to Ag/(Ag+Cu) = 0.5 without appreciable performance loss. Ag-containing films with Ga/(In+Ga) = 0.8 showed improved device characteristics over Cu-only control samples, in particular a 30-40% increase in short-circuit current. An absorber layer with composition Ag/(Ag+Cu) = 0.75 and Ga/(In+Ga) = 0.8 yielded a device with VOC = 890 mV, JSC = 20.5mA/cm2, fill factor = 71.3%, and ? = 13.0%.

  11. NGC 7538 IRS 1 - Subarcsecond resolution recombination line and (N-15)H3 maser observations

    SciTech Connect

    Gaume, R.A.; Johnston, K.J.; Nguyen, H.A.; Wilson, T.L.; Dickel, H.R. Max-Planck-Inst. fuer Radioastronomie, Bonn Illinois Univ., Urbana )

    1991-08-01

    The present imaging of the NGC 7538 IRS 1-associated (N-15)H3 (J, K) = (3, 3) maser emission with 0.2-arcsec resolution shows the strongest such masers, which may be amplifying the strong double-lobe radio continuum core of the IRS 1 H II region, to be concentrated in two regions separated by about 0.2 arcsec. Observations of several hydrogen recombination line transitions indicate that the velocity of the IRS H II region is similar to that of the ambient molecular cloud. 23 refs.

  12. In search of the elusive IrB2: Can mechanochemistry help?

    DOE PAGES [OSTI]

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; Cullen, David A.; Lapidus, Saul H.; Kata, Dariusz; Rutkowski, Paweł; Lis, Jerzy

    2015-10-20

    We produced hexagonal ReB2-type IrB2 diboride and orthorhombic IrB monoboride phases, that were previously unknown and saw them produced by mechanochemical syntheses. High energy ball milling of elemental Ir and B powder for 30 h, followed by annealing of the powder at 1050 °C for 48 h, resulted in the formation of the desired phases. Both traditional laboratory and high resolution synchrotron X-ray diffraction (XRD) analyses were used for phase identification of the synthesized powder. Additionally, scanning electron microscopy and transmission electron microscopy were employed, along with XRD, to further characterize the microstructure of the phases produced.

  13. Injection and acceleration of Au31+ in the BNL AGS.

    SciTech Connect

    Fischer,W.; Ahrens, L.; Brown, K.; Gardner, C.; Glenn, W.; Huang, H.; Mapes, M.; Smart, L.; Thieberger, P.; Tsoupas, N.; Zhang, S.Y.; Zeno, K.; Omet, C.; Spiller, P.

    2008-06-23

    Injection and acceleration of ions in a lower charge state reduces space charge effects, and, if further elcctron stripping is needed, may allow elimination of a stripping stage and the associated beam losses. The former is of interest to the accelerators in the GSI FAIR complex, the latter for BNL RHIC collider operation at energies lower than the current injection energy. Lower charge state ions, however, have a higher likelihood of electron stripping which can lead to dynamic pressures rises and subsequent beam losses. We report on experiments in the AGS where Au{sup 31+} ions were injected and accelerated instead of the normally used Au{sup 77+} ions. Beam intensities and the average pressure in the AGS ring are recorded, and compared with calculations for dynamic pressures and beam losses. The experimental results will be used to benchmark the StrahlSim dynamic vacuum code and will be incorporated in the GSI FAIR SIS100 design.

  14. CONTINUOUS EXTRACTED BEAM IN THE AGS FAST EXTERNAL BEAM LINE.

    SciTech Connect

    GLENN,J.W.; TSOUPAS,N.; BROWN,K.A.; BIRYUKOV,V.M.

    2001-06-18

    A method to split off a few percent of the 6 x 10{sup 13} AGS beam delivered to the Slow External Beam (SEB) lines and send it down the Fast External Beam line (FEB) has been developed. The mission is to feed a counter experiment off the FEB that directly measures the neutrino mass using the muon storage ring. The use of normal thin septum splitters would have an excessive loss overhead and been optically difficult. The AGS Slow Extraction uses a third integer resonance with sextuple strength so the resonance width is a few percent of the beam width. This results in a low density tail which will be clipped by a bent crystal and deflected into the FEB channel. This clipping off of the tail should reduce losses in the SEB transport line. Details of modeled orbits, particle distribution and extraction trajectories into and out off the crystal will be given.

  15. IR Imaging Using Arrays of SiO2 Micromechanical Detectors

    SciTech Connect

    Grbovic, Dragoslav; Lavrik, Nickolay V; Rajic, Slobodan; Datskos, Panos G; Hunter, Scott Robert

    2012-01-01

    In this letter, we describe the fabrication of an array of bimaterial detectors for infrared (IR) imaging that utilize SiO2 as a structural material. All the substrate material underneath the active area of each detector element was removed. Each detector element incorporates an optical resonant cavity layer in the IR absorbing region of the sensing element. The simplified microfabrication process requires only four photolithographic steps with no wet etching or sacrificial layers. The thermomechanical deflection sensitivity was 7.9 10-3 rad/K which corresponds to a noise equivalent temperature difference (NETD) of 2.9 mK. In the present work the array was used to capture IR images while operating at room temperature and atmospheric pressure and no need for vacuum packaging. The average measured NETD of our IR detector system was approximately 200 mK but some sensing elements exhibited an NETD of 50 mK.

  16. New insulating antiferromagnetic quaternary iridates MLa10Ir4O24...

    Office of Scientific and Technical Information (OSTI)

    The canonical example is the Ruddlesden-Popper compound Sr2IrO4, which has been suggested as a potential route to a new class of high temperature superconductor due to the formal ...

  17. Structure symmetry determination and magnetic evolution in Sr2Ir1...

    Office of Scientific and Technical Information (OSTI)

    evolution in Sr2Ir1-xRhxO4 This content will become publicly available on November 23, 2016 Prev Next Title: Structure symmetry determination and magnetic evolution in ...

  18. IRS Issues New Tax Credit Guidance for Owners of Small Wind Turbines |

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    Department of Energy IRS Issues New Tax Credit Guidance for Owners of Small Wind Turbines IRS Issues New Tax Credit Guidance for Owners of Small Wind Turbines February 19, 2015 - 10:02am Addthis Homeowners who install small wind turbines similar to these can qualify for tax credits. | Photo courtesy of Wind Utility Consulting Homeowners who install small wind turbines similar to these can qualify for tax credits. | Photo courtesy of Wind Utility Consulting Patrick Gilman Program Manager for

  19. Syntheses, crystal structures and fluorescent properties of Cd(II), Hg(II) and Ag(I) coordination polymers constructed from 1H-1,2,4-triazole-1-acetic acid

    SciTech Connect

    Ding Degang; Xie Lixia; Fan Yaoting; Hou Hongwei; Xu Yan

    2009-06-15

    Three new d{sup 10} coordination polymers, namely [Cd(taa)Cl]{sub n}1, [Hg(taa)Cl]{sub n}2, and [Ag{sub 1.5}(taa)(NO{sub 3}){sub 0.5}]{sub n}3 (taa=1H-1,2,4-triazole-1-acatate anion) have been prepared and characterized by elemental analysis, IR, and single crystal X-ray diffraction. Compound 1 consists of two-dimensional layers constructed by carboxyl-linked helical chains, which are further linked through carboxyl group to generate a unique 3D open framework. Topological analysis reveals that the structure of 1 can be classified as an unprecedented (3,8)-connected network with the Schlaefli symbol (4.5{sup 2}){sub 2}(4{sup 2}.5{sup 8}.6{sup 14}.7{sup 3}.8). Compound 2 manifests a doubly interpenetrated decorated alpha-polonium cubic network with the Schlaefli symbol of (4{sup 10}.6{sup 2}.8{sup 3}). Compound 3 consists of 2D puckered layers made up of Ag centers and taa{sup -} bridges. In addition, all of these compounds are photoluminescent in the solid state with spectra that closely resemble those of the ligand precursor. - Graphical abstract: Three new compounds based on 1H-1,2,4-triazole-1-acetic acid and Cd(II), Hg(II) and Ag(I) salts display luminescent properties and may be potential candidates for luminescent materials.

  20. Thermal stability and transport studies of (100 - 2x)TeO{sub 2}-xAg{sub 2}O-xWO{sub 3} (7.5 {<=} x {<=} 30) glass system

    SciTech Connect

    Upender, G.; Ramesh, Ch.; Mouli, V. Chandra

    2011-02-15

    Graphical abstract: Typical modulated DSC (NRHF and C{sub p}) results during a heating scan in the 85TeO{sub 2}-7.5Ag{sub 2}O-7.5WO{sub 3} glass sample. Research highlights: {yields} The addition of equal mol% of WO{sub 3} and Ag{sub 2}O to TeO{sub 2} increases the thermal stability. {yields} The 55TeO{sub 2}-22.5WO{sub 3}-22.5Ag{sub 2}O shows the highest thermal stability ({Delta}T = 237 {sup o}C). {yields} These glasses are more useful for drawing of optical fibers. {yields} The present glass system shows higher conductivity. -- Abstract: Differential scanning calorimetry (DSC), infrared (IR) and direct current (DC) conductivity studies have been carried out on (100 - 2x)TeO{sub 2}-xAg{sub 2}O-xWO{sub 3} (7.5 {<=} x {<=} 30) glass system. The IR studies show that the structure of glass network consists of [TeO{sub 4}], [TeO{sub 3}]/[TeO{sub 3+1}], [WO{sub 4}] units. Thermal properties such as the glass transition (T{sub g}), onset crystallization (T{sub o}), thermal stability ({Delta}T), glass transition width ({Delta}T{sub g}), heat capacities in the glassy and liquid state (C{sub pg} and C{sub pl}), heat capacity change ({Delta}C{sub p}) and ratios C{sub pl}/C{sub pg} of the glass systems were calculated. The highest thermal stability (237 {sup o}C) obtained in 55TeO{sub 2}-22.5Ag{sub 2}O-22.5WO{sub 3} glass suggests that this new glass may be a potentially useful candidate material host for rare earth doped optical fibers. The DC conductivity of glasses was measured in temperature region 27-260 {sup o}C, the activation energy (E{sub act}) values varied from 1.393 to 0.272 eV and for the temperature interval 170-260 {sup o}C, the values of conductivity ({sigma}) of glasses varied from 8.79 x 10{sup -9} to 1.47 x 10{sup -6} S cm{sup -1}.

  1. LENS MODELS OF HERSCHEL-SELECTED GALAXIES FROM HIGH-RESOLUTION NEAR-IR OBSERVATIONS

    SciTech Connect

    Calanog, J. A.; Cooray, A.; Ma, B.; Casey, C. M.; Fu, Hai; Wardlow, J.; Amber, S.; Baker, A. J.; Baes, M.; Bock, J.; Bourne, N.; Dye, S.; Bussmann, R. S.; Chapman, S. C.; Clements, D. L.; Conley, A.; Dannerbauer, H.; Dunne, L.; Eales, S.; and others

    2014-12-20

    We present Keck-Adaptive Optics and Hubble Space Telescope high resolution near-infrared (IR) imaging for 500 ?m bright candidate lensing systems identified by the Herschel Multi-tiered Extragalactic Survey and Herschel Astrophysical Terahertz Large Area Survey. Out of 87 candidates with near-IR imaging, 15 (?17%) display clear near-IR lensing morphologies. We present near-IR lens models to reconstruct and recover basic rest-frame optical morphological properties of the background galaxies from 12 new systems. Sources with the largest near-IR magnification factors also tend to be the most compact, consistent with the size bias predicted from simulations and previous lensing models for submillimeter galaxies (SMGs). For four new sources that also have high-resolution submillimeter maps, we test for differential lensing between the stellar and dust components and find that the 880 ?m magnification factor (?{sub 880}) is ?1.5 times higher than the near-IR magnification factor (?{sub NIR}), on average. We also find that the stellar emission is ?2 times more extended in size than dust. The rest-frame optical properties of our sample of Herschel-selected lensed SMGs are consistent with those of unlensed SMGs, which suggests that the two populations are similar.

  2. New insulating antiferromagnetic quaternary iridates MLa10Ir4O24 (M=Sr, Ba)

    DOE PAGES [OSTI]

    Zhao, Qingbiao; Han, Fei; Stoumpos, Constantinos C.; Han, Tian -Heng; Li, Hao; Mitchell, J. F.

    2015-07-01

    Recently, oxides of Ir4+ have received renewed attention in the condensed matter physics community, as it has been reported that certain iridates have a strongly spin-orbital coupled (SOC) electronic state, Jeff = ½, that defines the electronic and magnetic properties. The canonical example is the Ruddlesden-Popper compound Sr2IrO4, which has been suggested as a potential route to a new class of high temperature superconductor due to the formal analogy between Jeff = ½ and the S = ½ state of the cuprate superconductors. The quest for other iridium oxides that present tests of the underlying SOC physics is underway. Inmore » this spirit, here we report the synthesis and physical properties of two new quaternary tetravalent iridates, MLa10Ir4O24 (M = Sr, Ba). The crystal structure of both compounds features isolated IrO6 octahedra in which the electronic configuration of Ir is d5. As a result, both compounds order antiferromagnetically despite the lack of obvious superexchange pathways, and resistivity measurement shows that SrLa10Ir4O24 is an insulator.« less

  3. Planar Hall effect in Y{sub 3}Fe{sub 5}O{sub 12}/IrMn films

    SciTech Connect

    Zhang, X. Zou, L. K.

    2014-12-29

    The planar Hall effect of IrMn on an yttrium iron garnet (YIG = Y{sub 3}Fe{sub 5}O{sub 12}) was measured in the magnetic field rotating in the film plane. The magnetic field angular dependence of planar Hall resistance (PHR) was observed in YIG/IrMn bilayer at different temperatures, while the Gd{sub 3}Ga{sub 5}O{sub 12}/IrMn film shows constant PHR for different magnetic field angles at both 10 K and 300 K. This provides evidence that IrMn has interfacial spins which can be led by ferrimagnetic layer in YIG/IrMn structure. A hysteresis can be observed in PHR-magnetic field angle loop of YIG/IrMn film at 10 K, indicative of the irreversible switching of IrMn interfacial spins at low temperature.

  4. W{sub 18}O{sub 49} nanorods decorated with Ag/AgCl nanoparticles as highly-sensitive gas-sensing material and visible-light-driven photocatalyst

    SciTech Connect

    Sun Shibin; Chang Xueting; Dong Lihua; Zhang Yidong; Li Zhenjiang; Qiu Yanyan

    2011-08-15

    A novel gas-sensing material and photocatalyst was successfully obtained by decorating Ag/AgCl nanoparticles on the W{sub 18}O{sub 49} nanorods through a clean photochemical route. The as-prepared samples were characterized using combined techniques of X-ray diffractometry, electron microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy. Gas-sensing measurements indicate that the Ag/AgCl/W{sub 18}O{sub 49} NRs sensors exhibit superior reducing gas-sensing properties to those of bare W{sub 18}O{sub 49} NRs, and they are highly selective and sensitive to NH{sub 3}, acetone, and H{sub 2}S with short response and recovery times. The Ag/AgCl/W{sub 18}O{sub 49} NRs photocatlysts also possess higher photocatalytic performance than bare W{sub 18}O{sub 49} NRs for degradation of methyl orange under simulated sunlight irradiation. Possible mechanisms concerning the enhancement of gas-sensing and photocatalytic activities of the Ag/AgCl/W{sub 18}O{sub 49} NRs composite were proposed. - Graphical Abstract: The Ag/AgCl nanoparticles adhered well to the W{sub 18}O{sub 49} nanorod. The Ag could act as transfer center of the photoexcited carriers, prohibiting their recombinations in both W{sub 18}O{sub 49} and AgCl. Highlights: > Ag/AgCl/W{sub 18}O{sub 49} NRs were successfully obtained via a clean photochemical route. > The Ag/AgCl nanoparticles decorated on the W{sub 18}O{sub 49} NRs possessed cladding structure. > The Ag/AgCl/W{sub 18}O{sub 49} NRs exhibited excellent gas-sensing and photocatalytic properties.

  5. Surface-supported Ag islands stabilized by a quantum size effect: Their interaction with small molecules relevant to ethylene epoxidation

    SciTech Connect

    Shao, Dahai

    2013-05-15

    This dissertation focuses on how QSE-stabilized, surface-supported Ag nanoclusters will interact with ethylene or oxygen. Experiments are performed to determine whether the QSE-mediated Ag islands react differently toward adsorption of ethylene or oxygen, or whether the adsorption of these small molecules will affect the QSE-mediated stability of Ag islands. Studies of the interaction of oxygen with Ag/Si(111)-77 were previously reported, but these studies were performed at a low Ag coverage where 3D Ag islands were not formed. So the study of such a system at a higher Ag coverage will be a subject of this work. The interaction of ethylene with Ag/Si(111)-77, as well as the interaction of oxygen with Ag/NiAl(110) are also important parts of this study.

  6. AG490 inhibits NFATc1 expression and STAT3 activation during RANKL induced osteoclastogenesis

    SciTech Connect

    Li, Chang-hong; Zhao, Jin-xia; Sun, Lin; Yao, Zhong-qiang; Deng, Xiao-li; Liu, Rui; Liu, Xiang-yuan

    2013-06-14

    Highlights: AG490 inhibits RANKL-induced osteoclastogenesis in RAW264.7 cells. AG490 affects cell proliferation and cell cycle distribution. AG490 reduces NFATc1 expression during RANKL-induced osteoclastogenesis. AG490 disrupts the activation of RANKL-mediated JAK2/STAT3 signaling pathway. STAT3 depletion partly mimics the effect of AG490 on RANKL-induced osteoclastogenesis. -- Abstract: Commonly, JAK/STAT relays cytokine signals for cell activation and proliferation, and recent studies have shown that the elevated expression of JAK/STAT is associated with the immune rejection of allografts and the inflammatory processes of autoimmune disease. However, the role which JAK2/STAT3 signaling plays in the receptor activator of nuclear factor-?B ligand (RANKL)-mediated osteoclastogenesis is unknown. In this study, we investigated the effects of AG490, specific JAK2 inhibitor, on osteoclast differentiation in vitro. AG490 significantly inhibited osteoclastogenesis in murine osteoclast precursor cell line RAW264.7 induced by RANKL. AG490 suppressed cell proliferation and delayed the G1 to S cell cycle transition. Furthermore, AG490 also suppressed the expression of nuclear factor of activated T cells (NFAT) c1 but not c-Fos in RAW264.7. Subsequently, we investigated various intracellular signaling components associated with osteoclastogenesis. AG490 had no effects on RANKL-induced activation of Akt, ERK1/2. Interestingly, AG490 partly inhibited RANKL-induced phosphorylation of Ser{sup 727} in STAT3. Additionally, down-regulation of STAT3 using siRNA resulted in suppression of TRAP, RANK and NFATc1 expression. In conclusion, we demonstrated that AG490 inhibited RANKL-induced osteoclastogenesis by suppressing NFATc1 production and cell proliferation via the STAT3 pathway. These results suggest that inhibition of JAK2 may be useful for the treatment of bone diseases characterized by excessive osteoclastogenesis.

  7. Spin glass in semiconducting KFe1.05Ag0.88Te2 single crystals

    DOE PAGES [OSTI]

    Ryu, H.; Lei, H.; Klobes, B.; Warren, J. B.; Hermann, R. P.; Petrovic, C.

    2015-05-26

    We report discovery of KFe1.05Ag0.88Te2 single crystals with semiconducting spin glass ground state. Composition and structure analysis suggest nearly stoichiometric I4/mmm space group but allow for the existence of vacancies, absent in long range semiconducting antiferromagnet KFe1.05Ag0.88Te2. The subtle change in stoichometry in Fe/Ag sublattice changes magnetic ground state but not conductivity, giving further insight into the semiconducting gap mechanism.

  8. NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts

    Energy.gov [DOE]

    DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3

  9. Organic pollutant photodecomposition by Ag/KNbO3 nanocomposites: A combined experimental and theoretical study

    DOE PAGES [OSTI]

    Zhang, Tingting; Liu, Ping; Lei, Wanying; Rodriguez, J. A.; Yu, Jiaguo; Qi, Yang; Liu, Gang; Liu, Minghua

    2016-01-12

    In this study, Ag nanoparticles supported on well-defined perovskite orthorhombic KNbO3 nanowires are synthesized via facile photoreduction and systematically characterized by XRD, Raman, DRUV–vis, XPS, PL, TEM, HRTEM, and HAADF-STEM. The photoreactivity of Ag/KNbO3 nanocomposites as a function of Ag contents (0.4–2.8 wt %) is assessed toward aqueous rhodamine B degradation under UV- and visible-light, respectively. It is found that the UV-induced photoreactivity initially increases and then decreases with increasing Ag contents. At an optimal Ag content (ca. 1.7 wt %), the greatest photoreactivity is achieved under UV light, with the photocatalytic reaction rate of 1.7 wt % Ag/KNbO3 exceedingmore » that of pristine KNbO3 by a factor of ca. 13. In contrast, visible light-induced photoreactivity monotonically increases with increasing Ag contents in the range of 0.4–2.8 wt %. On the basis of the detected active species and intermediate products in the photocatalytic processes, conjugated structure cleavage and N-deethylation are revealed to be the respective predominant pathway under UV and visible-light illumination. To gain an insight into the observed photoreactivity, the electronic properties of Ag/KNbO3 have been investigated using spin-polarized DFT calculations. Herein, Ag extended adlayers (1–4 ML) on the slab models of KNbO3 (101) are employed to mimic large supported Ag nanoparticles. A Bader analysis of the electron density shows a small net charge transfer (ca. 0.1 e) from KNbO3 to Ag. The electron localization function of Ag/KNbO3 (101) illustrates that Ag adlayers with thickness larger than 2 ML are essentially metallic, and weak polarization occurs at the interface. In addition, the metallic Ag adlayers generate a continuum of Ag bandgap states, which play a key role in determining different Ag content-dependent behavior between UV and visible-light illumination.« less

  10. NuCellSys GmbH formerly Ballard AG formerly XCellsis | Open Energy...

    OpenEI (Open Energy Information) [EERE & EIA]

    Germany Product: Focused on developing and manufacturing fuel cell systems for automotive applications. References: NuCellSys GmbH (formerly Ballard AG, formerly XCellsis)1...

  11. Spectral investigation of nonlinear local field effects in Ag nanoparticles

    SciTech Connect

    Sato, Rodrigo Takeda, Yoshihiko; Ohnuma, Masato; Oyoshi, Keiji

    2015-03-21

    The capability of Ag nanoparticles to modulate their optical resonance condition, by optical nonlinearity, without an external feedback system was experimentally demonstrated. These optical nonlinearities were studied in the vicinity of the localized surface plasmon resonance (LSPR), using femtosecond pump-and-probe spectroscopy with a white-light continuum probe. Transient transmission changes ΔT/T exhibited strong photon energy and particle size dependence and showed a complex and non-monotonic change with increasing pump light intensity. Peak position and change of sign redshift with increasing pump light intensity demonstrate the modulation of the LSPR. These features are discussed in terms of the intrinsic feedback via local field enhancement.

  12. Copper intercalation at the interface of graphene and Ir(111) studied by scanning tunneling microscopy

    SciTech Connect

    Sicot, M. Fagot-Revurat, Y.; Kierren, B.; Vasseur, G.; Malterre, D.

    2014-11-10

    We report on the intercalation of a submonolayer of copper at 775?K underneath graphene epitaxially grown on Ir(111) studied by means of low energy electron diffraction (LEED) and scanning tunneling microscopy (STM) at 77?K. Nucleation and growth dynamics of Cu below graphene have been investigated, and, most importantly, the intercalation mechanism has been identified. First, LEED patterns reveal the pseudomorphic growth of Cu on Ir under the topmost graphene layer resulting in a large Cu in-plane lattice parameter expansion of about 6% compared to Cu(111). Second, large-scale STM topographs as a function of Cu coverage show that Cu diffusion on Ir below graphene exhibits a low energy barrier resulting in Cu accumulation at Ir step edges. As a result, the graphene sheet undergoes a strong edges reshaping. Finally, atomically-resolved STM images reveal a damaged graphene sheet at the atomic scale after metal intercalation. Point defects in graphene were shown to be carbon vacancies. According to these results, a Cu penetration path beneath graphene is proposed to occur via metal aided defect formation with no or poor self healing of the graphene sheet. This work illustrates the fact that Cu intercalation is harmful for graphene grown on Ir(111) at the atomic scale.

  13. Elastic, magnetic and electronic properties of iridium phosphide Ir2P

    DOE PAGES [OSTI]

    Wang, Pei; Wang, Yonggang; Wang, Liping; Zhang, Xinyu; Yu, Xiaohui; Zhu, Jinlong; Wang, Shanmin; Qin, Jiaqian; Leinenweber, Kurt; Chen, Haihua; et al

    2016-02-24

    Cubic (space group: Fm3¯m) iridium phosphide, Ir2P, has been synthesized at high pressure and high temperature. Angle-dispersive synchrotron X-ray diffraction measurements on Ir2P powder using a diamond-anvil cell at room temperature and high pressures (up to 40.6 GPa) yielded a bulk modulus of B0 = 306(6) GPa and its pressure derivative B0' = 6.4(5). Such a high bulk modulus attributed to the short and strongly covalent Ir-P bonds as revealed by first – principles calculations and three-dimensionally distributed [IrP4] tetrahedron network. Indentation testing on a well–sintered polycrystalline sample yielded the hardness of 11.8(4) GPa. Relatively low shear modulus of ~64more » GPa from theoretical calculations suggests a complicated overall bonding in Ir2P with metallic, ionic, and covalent characteristics. Additionally, a spin glass behavior is indicated by magnetic susceptibility measurements.« less

  14. Elastic, magnetic and electronic properties of iridium phosphide Ir2P

    DOE PAGES [OSTI]

    Wang, Pei; Wang, Yonggang; Wang, Liping; Zhang, Xinyu; Yu, Xiaohui; Zhu, Jinlong; Wang, Shanmin; Qin, Jiaqian; Leinenweber, Kurt; Chen, Haihua; et al

    2016-02-24

    Cubic (space group: Fm3¯m) iridium phosphide, Ir2P, has been synthesized at high pressure and high temperature. Angle-dispersive synchrotron X-ray diffraction measurements on Ir2P powder using a diamond-anvil cell at room temperature and high pressures (up to 40.6 GPa) yielded a bulk modulus of B0 = 306(6) GPa and its pressure derivative B0'= 6.4(5). Such a high bulk modulus attributed to the short and strongly covalent Ir-P bonds as revealed by first – principles calculations and three-dimensionally distributed [IrP4] tetrahedron network. Indentation testing on a well–sintered polycrystalline sample yielded the hardness of 11.8(4) GPa. Relatively low shear modulus of ~64 GPamore » from theoretical calculations suggests a complicated overall bonding in Ir2P with metallic, ionic, and covalent characteristics. Additionally, a spin glass behavior is indicated by magnetic susceptibility measurements.« less

  15. Modulated IR radiometry for determining thermal properties and basic characteristics of titanium thin films

    SciTech Connect

    Apreutesei, Mihai; Lopes, Claudia; Vaz, Filipe; Macedo, Francisco; Borges, Joel

    2014-07-01

    Titanium thin films of different thicknesses were prepared by direct current magnetron sputtering to study modulated infrared (IR) radiometry as a tool for analyzing film thickness. Thickness was varied by regularly increasing the deposition time, keeping all the other deposition parameters constant. The influence of film thickness on morphological, structural, and electrical properties of the titanium coatings also was investigated. The experimental results revealed a systematic grain growth with increasing film thickness, along with enhanced film crystallinity, which led to increased electrical conductivity. Using the results obtained by modulated IR radiometry, the thickness of each thin film was calculated. These thickness values were then compared with the coating thickness measurements obtained by scanning electron microscopy. The values confirmed the reliability of modulated IR radiometry as an analysis tool for thin films and coatings, and for determining thicknesses in the micrometer range, in particular.

  16. Vortexlike excitations in the heavy-fermion superconductor CeIrIn5

    DOE PAGES [OSTI]

    Luo, Yongkang; Rosa, P. F. S.; Bauer, E. D.; Thompson, J. D.

    2016-05-05

    Here, we report a systematic study of temperature- and field-dependent charge (ρ) and entropy (S) transport in the heavy-fermion superconductor CeIrIn5. Its large positive thermopower Sxx is typical of Ce-based Kondo lattice systems, and strong electronic correlations play an important role in enhancing the Nernst signal Sxy. By separating the off-diagonal Peltier coefficient αxy from Sxy, we find that αxy becomes positive and greatly enhanced at temperatures well above the bulk Tc. Compared with the nonmagnetic analog LaIrIn5, these results suggest vortexlike excitations in a precursor state to unconventional superconductivity in CeIrIn5. This study sheds light on the similarity ofmore » heavy-fermion and cuprate superconductors and on the possibility of states not characterized by the amplitude of an order parameter.« less

  17. In search of the elusive IrB2: Can mechanochemistry help?

    SciTech Connect

    Xie, Zhilin; Blair, Richard G.; Orlovskaya, Nina; Cullen, David A.; Lapidus, Saul H.; Kata, Dariusz; Rutkowski, Paweł; Lis, Jerzy

    2015-10-20

    We produced hexagonal ReB2-type IrB2 diboride and orthorhombic IrB monoboride phases, that were previously unknown and saw them produced by mechanochemical syntheses. High energy ball milling of elemental Ir and B powder for 30 h, followed by annealing of the powder at 1050 °C for 48 h, resulted in the formation of the desired phases. Both traditional laboratory and high resolution synchrotron X-ray diffraction (XRD) analyses were used for phase identification of the synthesized powder. Additionally, scanning electron microscopy and transmission electron microscopy were employed, along with XRD, to further characterize the microstructure of the phases produced.

  18. Determination of partial (n,xngamma) cross-sections in 193-Ir

    SciTech Connect

    Talou, P; Chadwick, M B; Nelson, R; Fotiades, N; Devlin, M; Garrett, P E; Younes, W; Becker, J A

    2003-10-15

    The {sup 193}Ir(n,n'){sup 193m}Ir cross section for the production of the 80-keV isomer in {sup 193}Ir is evaluated using a combination of experimental data and nuclear reaction modeling, from threshold to about 20 MeV. Four discrete {gamma} lines feeding the isomer were recently observed with the GEANIE {gamma}-ray detector at LANSCE. Theoretical calculations of the nuclear reaction mechanisms in play are then carried out to evaluate the contributions not accounted for in the experimental setup (direct population; fraction of {gamma}-lines not observed in the experiment; etc). Experiment and modeling are then combined to provide a total cross section for the production of the Iridium isomer. We finally compare our result with activation measurement data available for a few energy points.

  19. Observations of Ag diffusion in ion implanted SiC

    DOE PAGES [OSTI]

    Gerczak, Tyler J.; Leng, Bin; Sridharan, Kumar; Jerry L. Hunter, Jr.; Giordani, Andrew J.; Allen, Todd R.

    2015-03-17

    The nature and magnitude of Ag diffusion in SiC has been a topic of interest in connection with the performance of tristructural isotropic (TRISO) coated particle fuel for high temperature gas-cooled nuclear reactors. Ion implantation diffusion couples have been revisited to continue developing a more complete understanding of Ag fission product diffusion in SiC. Ion implantation diffusion couples fabricated from single crystal 4H-SiC and polycrystalline 3C-SiC substrates and exposed to 1500–1625°C, were investigated in this study by transmission electron microscopy and secondary ion mass spectrometry (SIMS). The high dynamic range of SIMS allowed for multiple diffusion régimes to be investigated,more » including enhanced diffusion by implantation-induced defects and grain boundary (GB) diffusion in undamaged SiC. Lastly, estimated diffusion coefficients suggest GB diffusion in bulk SiC does not properly describe the release observed from TRISO fuel.« less

  20. SIMULATIONS OF THE AGS MMPS STORING ENERGY IN CAPACITOR BANKS

    SciTech Connect

    MARNERIS,I.; BADEA, V.S.; BONATI, R.; ROSER, T.; SANDBERG, J.

    2007-06-25

    The Brookhaven AGS Main Magnet Power Supply (MMPS) is a thyristor control supply rated at 5500 Amps, +/-9000 Volts. The peak magnet power is 50 MWatts. The power supply is fed from a motor/generator manufactured by Siemens. The generator is 3 phase 7500 Volts rated at 50 MVA. The peak power requirements come from the stored energy in the rotor of the motor/generator. The motor generator is about 45 years old, made by Siemens and it is not clear if companies will be manufacturing similar machines in the future. We are therefore investigating different ways of storing energy for future AGS MMPS operations. This paper will present simulations of a power supply where energy is stored in capacitor banks. Two dc to dc converters will be presented along with the control system of the power section. The switching elements will be IGCT's made by ABB. The simulation program used is called PSIM version 6.1. The average power from the local power authority into the power supply will be kept constant during the pulsing of the magnets at +/-50 MW. The reactive power will also be kept constant below 1.5 MVAR. Waveforms will be presented.

  1. Robust Ag nanoplate ink for flexible electronics packaging

    SciTech Connect

    Li, Ruo -Zhou; Hu, Anming; Bridges, Denzel; Oakes, Ken D.; Peng, Rui; Tumuluri, Uma; Wu, Zili; Feng, Zhili; Zhang, Tong

    2015-03-24

    Nanoinks are currently a topic of heightened interest with respect to low temperature bonding processes and printable electronics. We have developed an innovative polyvinylpyrrolidone (PVP)-stabilized Ag nanoplate ink amenable to very strong low temperature packaging, and investigated the relationship between bonding strength and electrical conductivity post-bonding. PVP shell plastic deformations observed in failure microcracks with the formation of PVP nanofibers, revealed bonding strength at low temperatures (<250 °C) was primarily due to adhesive bonding. It is found that, utilizing photonic sintering, ~70 °C reduction of transformation temperature from adhesive to metallic bonding was achieved compared to that of thermal sintering. A numerical simulation was developed to better understand the influences of the light-induced heat generation, which demonstrated near-infrared light can facilitate sintering. Bonding strengths of 27 MPa were achieved at room temperatures, and 29.4 MPa at 210 °C with photonic sintering. Moreover, the anisotropic resistivity was observed with different thermal dependences. Furthermore, these results demonstrate Ag nanoplate inks have potential for low temperature 3D interconnections in lead-free microcircuits, flexible electronic packaging, and diverse sensing applications.

  2. Robust Ag nanoplate ink for flexible electronics packaging

    DOE PAGES [OSTI]

    Li, Ruo -Zhou; Hu, Anming; Bridges, Denzel; Oakes, Ken D.; Peng, Rui; Tumuluri, Uma; Wu, Zili; Feng, Zhili; Zhang, Tong

    2015-03-24

    Nanoinks are currently a topic of heightened interest with respect to low temperature bonding processes and printable electronics. We have developed an innovative polyvinylpyrrolidone (PVP)-stabilized Ag nanoplate ink amenable to very strong low temperature packaging, and investigated the relationship between bonding strength and electrical conductivity post-bonding. PVP shell plastic deformations observed in failure microcracks with the formation of PVP nanofibers, revealed bonding strength at low temperatures (<250 °C) was primarily due to adhesive bonding. It is found that, utilizing photonic sintering, ~70 °C reduction of transformation temperature from adhesive to metallic bonding was achieved compared to that of thermal sintering.more » A numerical simulation was developed to better understand the influences of the light-induced heat generation, which demonstrated near-infrared light can facilitate sintering. Bonding strengths of 27 MPa were achieved at room temperatures, and 29.4 MPa at 210 °C with photonic sintering. Moreover, the anisotropic resistivity was observed with different thermal dependences. Furthermore, these results demonstrate Ag nanoplate inks have potential for low temperature 3D interconnections in lead-free microcircuits, flexible electronic packaging, and diverse sensing applications.« less

  3. Structure symmetry determination and magnetic evolution in Sr2Ir1–xRhxO4

    DOE PAGES [OSTI]

    Ye, Feng; Wang, Xiaoping; Hoffmann, Christina; Wang, Jinchen; Chi, Songxue; Matsuda, Masaaki; Chakoumakos, Bryan C.; Fernandez-Baca, Jaime A.; Cao, Gang

    2015-11-23

    We use single-crystal neutron diffraction to determine the crystal structure symmetry and to study the magnetic evolution in the rhodium doped iridates Sr2Ir1–xRhxO4 (0 ≤ x ≤ 0.16). Throughout this doping range, the crystal structure retains a tetragonal symmetry (space group I41/a) with two distinct magnetic Ir sites in the unit cell forming staggered IrO6 rotation. Upon Rh doping, the magnetic order is suppressed and the magnetic moment of Ir4+ is reduced from 0.21 μB/Ir for x = 0 to 0.18 μB/Ir for x = 0.12. As a result, the magnetic structure at x = 0.12 is different from thatmore » of the parent compound while the moments remain in the basal plane.« less

  4. The Synthesis of Ag-Doped Mesoporous TiO2

    SciTech Connect

    Li, Xiaohong S.; Fryxell, Glen E.; Wang, Chong M.; Engelhard, Mark H.

    2008-04-15

    Ag-doped mesoporous titanium oxide was prepared using non-ionic surfactants and easily handled titanium precursors, under mild reaction conditions. In contrast to the stabilizing effect of Cd-doping on mesoporous TiO2, Ag-doping was found to significantly destabilize the mesoporous structure.

  5. Preparation and photocatalytic properties of AgISnO{sub 2} nano-composites

    SciTech Connect

    Wen, Biao; Wang, Xiao-Hui; Lu, Juan; Cao, Jia-Lei; Wang, Zuo-Shan

    2013-05-15

    Highlights: ? AgISnO{sub 2} nano-composites have been successfully synthesized. ? As-prepared AgISnO{sub 2} nano-composites own the excellent visible light photocatalytic activity. ? As-prepared AgISnO{sub 2} nano-composites own the excellent stability. - Abstract: AgI doped SnO{sub 2} nano-composites were prepared by the chemical coprecipitation method and were characterized by the X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Results showed that main of the I{sup ?} ions remained in the AgI lattice which is highly dispersed in the system. The photo-catalytic experiments performed under visible light irradiation using methylene blue as the pollutant revealed that not only the photo-catalytic activity but also the stability of SnO{sub 2} based photocatalyst could be improved by introduction of an appropriate amount of AgI, and the result was further supported by the UVVis diffuse reflection spectra and the electron spin-resonance spectra. Among all of the samples, AgISnO{sub 2} nano-composite with 2At% AgI exhibited the best catalytic efficiency and stability.

  6. Handling collision debris in quad- and dipole-first LHC IR options

    SciTech Connect

    Mokhov, N.V.; Rakhno, I.L.; /Fermilab

    2006-12-01

    Detailed MARS15 Monte Carlo energy deposition calculations are performed for two main designs of the LHC interaction regions (IR) capable to achieve a luminosity of 10{sup 35} cm{sup -2} s{sup -1}: a traditional quadrupole-first scheme and the one with a dual-bore inner triplet with separation dipoles placed in front of the quadrupoles. It is shown that with the appropriate design of the Nb3Sn magnets, IR layout and a number of protective measures implemented, both schemes are feasible for the LHC luminosity upgrade up to 10{sup 35} cm{sup -2} s{sup -1}.

  7. Mechanism of Efficient Anti-Markovnikov Olefin Hydroarylation Catalyzed by Homogeneous Ir(III) Complexes

    SciTech Connect

    Bhalla, Gaurav; Bischof, Steven M; Ganesh, Somesh K; Liu, Xiang Y; Jones, C J; Borzenko, Andrey; Tenn, William J; Ess, Daniel H; Hashiguchi, Brian G; Lokare, Kapil S; Leung, Chin Hin; Oxgaard, Jonas; Goddard, William A; Periana, Roy A

    2011-01-01

    The mechanism of the hydroarylation reaction between unactivated olefins (ethylene, propylene, and styrene) and benzene catalyzed by [(R)Ir(?-acac-O,O,C{sup 3})-(acac-O,O){sub 2}]{sub 2} and [R-Ir(acac-O,O){sub 2}(L)] (R = acetylacetonato, CH{sub 3}, CH{sub 2}CH{sub 3}, Ph, or CH{sub 2}CH{sub 2}Ph, and L = H{sub 2}O or pyridine) Ir(III) complexes was studied by experimental methods. The system is selective for generating the anti-Markovnikov product of linear alkylarenes (61:39 for benzene + propylene and 98:2 for benzene + styrene). The reaction mechanism was found to follow a rate law with first-order dependence on benzene and catalyst, but a non-linear dependence on olefin. {sup 13}C-labelling studies with CH{sub 3}{sup 13}CH{sub 2}-Ir-Py showed that reversible ?-hydride elimination is facile, but unproductive, giving exclusively saturated alkylarene products. The migration of the {sup 13}C-label from the ? to ?-positions was found to be slower than the CH activation of benzene (and thus formation of ethane and Ph-d{sub 5}-Ir-Py). Kinetic analysis under steady state conditions gave a ratio of the rate constants for CH activation and ?-hydride elimination (k{sub CH}: k{sub ?}) of ~0.5. The comparable magnitude of these rates suggests a common rate determining transition state/intermediate, which has been shown previously with B3LYP density functional theory (DFT) calculations. Overall, the mechanism of hydroarylation proceeds through a series of pre-equilibrium dissociative steps involving rupture of the dinuclear species or the loss of L from Ph-Ir-L to the solvento, 16-electron species, Ph-Ir(acac-O,O){sub 2}-Sol (where Sol refers to coordinated solvent). This species then undergoes trans to cisisomerization of the acetylacetonato ligand to yield the pseudo octahedral species cis-Ph-Ir-Sol, which is followed by olefin insertion (the regioselective and rate determining step), and then activation of the CH bond of an incoming benzene to generate the product and

  8. Filamentation of IR and UV femtosecond pulses upon focusing in air

    SciTech Connect

    Dergachev, A A; Ionin, Andrei A; Kandidov, V P; Seleznev, L V; Sinitsyn, D V; Sunchugasheva, E S; Shlenov, Svyatoslav A

    2013-01-31

    The filamentation of IR and UV laser pulses has been studied numerically and experimentally for different initial beam focusing geometries, and linear electron density profiles along the plasma channel of filaments have been obtained. The results demonstrate that changes in laser beam focusing have a stronger effect on filament and plasma channel parameters for UV radiation than for IR radiation. Focusing causes individual high fluence regions produced by refocusing to merge to form a continuous extended filament with a continuous plasma channel. (nonlinear optical phenomena)

  9. Preparation of Ag/AgCl/BiMg{sub 2}VO{sub 6} composite and its visible-light photocatalytic activity

    SciTech Connect

    Guo, Rui; Zhang, Gaoke; Liu, Jiu

    2013-05-15

    Graphical abstract: - Abstract: A novel composite photocatalyst Ag/AgCl/BiMg{sub 2}VO{sub 6} was synthesized by depositing Ag/AgCl nanoparticles on BiMg{sub 2}VO{sub 6} substrate via a precipitation–photoreduction method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDXA), X-ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectrophotometer (UV–vis DRS). The photocatalyst showed high and stable photocatalytic activity for photocatalytic degradation of acid red G under visible-light irradiation (λ > 420 nm). In addition, the active ·O{sub 2}{sup −} and h{sup +}, as main reactive species, played the major roles during the reaction process. The high photocatalytic activity of the composite may be related to the efficient electron–hole pairs separation at the photocatalyst interfaces, as well as the surface plasmon resonance of Ag nanoparticles formed on AgCl particles in the degradation reaction.

  10. Joint contributions of Ag ions and oxygen vacancies to conducting filament evolution of Ag/TaO{sub x}/Pt memory device

    SciTech Connect

    Chung, Yu-Lung; Cheng, Wen-Hui; Chen, Wei-Chih; Jhan, Sheng-An; Chen, Jen-Sue; Jeng, Jiann-Shing

    2014-10-28

    The electroforming and resistive switching behaviors in the Ag/TaO{sub x}/Pt trilayer structure are investigated under a continual change of temperatures between 300 K and 100 K to distinguish the contributions of Ag ions and oxygen vacancies in developing of conducting filaments. For either electroforming or resistive switching, a significantly higher forming/set voltages is needed as the device is operated at 100 K, as compared to that observed when operating at 300 K. The disparity in forming/set voltages of Ag/TaO{sub x}/Pt operating at 300 K and 100 K is attributed to the contribution of oxygen vacancies, in addition to Ag atoms, in formation of conducting filament at 100 K since the mobilities of oxygen vacancies and Ag ions become comparable at low temperature. The presence of oxygen vacancy segment in the conducting filament also modifies the reset current from a gradually descending behavior (at 300 K) to a sharp drop (at 100 K). Furthermore, the characteristic set voltage and reset current are irreversible as the operation temperature is brought from 100 K back to 300 K, indicating the critical role of filament constituents on the switching behaviors of Ag/oxide/Pt system.

  11. Low-temperature ferromagnetic properties in Co-doped Ag{sub 2}Se nanoparticles

    SciTech Connect

    Yang, Fengxia E-mail: xia9020@hust.edu.cn; Yu, Gen; Han, Chong; Liu, Tingting; Zhang, Duanming; Xia, Zhengcai E-mail: xia9020@hust.edu.cn

    2014-01-06

    β-Ag{sub 2}Se is a topologically nontrivial insulator. The magnetic properties of Co-doped Ag{sub 2}Se nanoparticles with Co concentrations up to 40% were investigated. The cusp of zero-field-cooling magnetization curves and the low-temperature hysteresis loops were observed. With increasing concentration of Co{sup 2+} ions mainly substituting Ag{sub I} sites in the Ag{sub 2}Se structure, the resistivity, Curie temperature T{sub c}, and magnetization increased. At 10 T, a sharp drop of resistance near T{sub c} was detected due to Co dopants. The ferromagnetic behavior in Co-doped Ag{sub 2}Se might result from the intra-layer ferromagnetic coupling and surface spin. This magnetic semiconductor is a promising candidate in electronics and spintronics.

  12. Optical and quantum efficiency analysis of (Ag,Cu)(In,Ga)Se2 absorber layers

    SciTech Connect

    Boyle, Jonathan; Hanket, Gregory; Shafarman, William

    2009-06-09

    (Ag,Cu)(In,Ga)Se2 thin films have been deposited by elemental co-evaporation over a wide range of compositions and their optical properties characterized by transmission and reflection measurements and by relative shift analysis of quantum efficiency device measurements. The optical bandgaps were determined by performing linear fits of (?h?)2 vs. h?, and the quantum efficiency bandgaps were determined by relative shift analysis of device curves with fixed Ga/(In+Ga) composition, but varying Ag/(Cu+Ag) composition. The determined experimental optical bandgap ranges of the Ga/(In+Ga) = 0.31, 0.52, and 0.82 groups, with Ag/(Cu+Ag) ranging from 0 to 1, were 1.19-1.45 eV, 1.32-1.56 eV, and 1.52-1.76 eV, respectively. The optical bowing parameter of the different Ga/(In+Ga) groups was also determined.

  13. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer

    2013-07-15

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with μ{sub eff}=7.87(1) μ{sub B}/Eu atom and θ{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of −9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  14. Nature of the insulating ground state of the5d postperovskite CaIrO?

    DOE PAGES [OSTI]

    Kim, Sun -Woo; Liu, Chen; Kim, Hyun -Jung; Lee, Jun -Ho; Yao, Yongxin; Ho, Kai -Ming; Cho, Jun -Hyung

    2015-08-26

    In this study, the insulating ground state of the 5d transition metal oxide CaIrO3 has been classified as a Mott-type insulator. Based on a systematic density functional theory (DFT) study with local, semilocal, and hybrid exchange-correlation functionals, we reveal that the Ir t2g states exhibit large splittings and one-dimensional electronic states along the c axis due to a tetragonal crystal field. Our hybrid DFT calculation adequately describes the antiferromagnetic (AFM) order along the c direction via a superexchange interaction between Ir4+ spins. Furthermore, the spin-orbit coupling (SOC) hybridizes the t2g states to open an insulating gap. These results indicate thatmoreCaIrO3 can be represented as a spin-orbit Slater insulator, driven by the interplay between a long-range AFM order and the SOC. Such a Slater mechanism for the gap formation is also demonstrated by the DFT + dynamical mean field theory calculation, where the metal-insulator transition and the paramagnetic to AFM phase transition are concomitant with each other.less

  15. Overview and status of first 25 MW(e) IR-CFB boiler in India

    SciTech Connect

    Kavidass, S.; Bakshi, V.K.; Diwakar, K.K.

    1997-12-31

    The Babcock and Wilcox (B and W) internal recirculation CFB (IR-CFB) boiler is unique in design. Worldwide, B and W offers IR-CFB boilers up to 150 MW(e) both reheat and non-reheat, and is pursuing units up to 300 MW(e). This paper discusses an overview and status of the construction, commissioning, initial start-up operation and milestones of the ongoing 25 MW(e) IR-CFB boiler project at Kanoria Chemicals and Industries Ltd., Renukoot, India. This IR-CFB boiler is designed, supplied and installed by Thermax Babcock and Wilcox Ltd. (TBW), a joint venture company of the B and W and Thermax in India. The boiler parameters are, steam flow of 29.2 kg/s (23,420 lbs/hr), 6.4 MPa (925 psig), and 485 C (905 F) with feedwater temperature of 180 C (356 F). The boiler will utilize high-ash content (> 45%), subbituminous coal with a heating value of 3,500 KCal/kg (6,300 Btu/lb). This paper also discusses the various aspects of the boiler design, performance, auxiliary equipment, advantages and initial start-up operating performance.

  16. Update of operating experience of B and W IR-CFB coal-fired boilers

    SciTech Connect

    Belin, F.; Kavidass, S.; Maryamchik, M.; Walker, D.J.; Mandal, A.K.; Price, C.E.

    1999-07-01

    This paper updates the operating experience of two Babcock and Wilcox (B and W) coal-fired, internal recirculation circulating fluidized-bed (IR-CFB) boilers. The first boiler is located at Southern Illinois University (SIU) in Carbondale, Illinois, USA, and is designed for 35 MW{sub th} output for cogeneration application, utilizing high sulfur, low ash Illinois coal. The second boiler is located at Kanoria Chemicals and Industries in Renukoot, India, and is designed for 81 MW{sub th} output for captive power requirement, firing high ash, low sulfur coal. This boiler was supplied by Thermax B and W Ltd., a joint venture company of B and W and Thermax of India. The choice of CFB technology was based on its fuel flexibility, cost effectiveness and environmental benefits for solid fuels. Based on the broad experience in designing utility and industrial boilers for operation worldwide, B and W has developed a cost effective and compact atmospheric pressure IR-CFB boiler. The B and W IR-CFB boiler design is distinctive in its use of U-beam particle separators. Worldwide, B and W offers IF-CFB boilers up to 175 MW{sub th}, both reheat and non-reheat, and is pursuing units up to 350 MW{sub th}. This paper reviews the general description of each IR-CFB boiler, design and performance aspects, as well as overall operating experiences. The boiler availabilities including maintenance aspects and emissions data will be presented.

  17. Temperature dependence of anisotropic magnetoresistance in antiferromagnetic Sr{sub 2}IrO{sub 4}

    SciTech Connect

    Wang, C.; Seinige, H.; Tsoi, M.; Cao, G.; Zhou, J.-S.; Goodenough, J. B.

    2015-05-07

    Temperature-dependent magnetotransport properties of the antiferromagnetic semiconductor Sr{sub 2}IrO{sub 4} are investigated with point-contact devices. The point-contact technique allows to probe very small volumes and, therefore, to look for electronic transport on a microscopic scale. Point-contact measurements with single crystals of Sr{sub 2}IrO{sub 4} were intended to see whether the additional local resistance associated with a small contact area between a sharpened Cu tip and the antiferromagnet shows magnetoresistance (MR) such as that seen in bulk crystals. Point-contact measurements at liquid nitrogen temperature revealed large MRs (up to 28%) for modest magnetic fields (250 mT) applied within an IrO{sub 2} (ab) plane with angular dependence showing a crossover from four-fold to two-fold symmetry with an increasing magnetic field. Point contact measurement exhibits distinctive anisotropic magnetoresistance (AMR) in comparison to a bulk experiment, imposing intriguing questions about the mechanism of AMR in this material. Temperature-dependent MR measurements show that the MR falls to zero at the Neel temperature, but the temperature dependence of the MR ratio differs qualitatively from that of the resistivity. This AMR study helps to unveil the entanglement between electronic transport and magnetism in Sr{sub 2}IrO{sub 4} while the observed magnetoresistive phenomena can be potentially used to sense the antiferromagnetic order parameter in spintronic applications.

  18. Nature of the insulating ground state of the 5d postperovskite CaIrO3

    DOE PAGES [OSTI]

    Kim, Sun -Woo; Liu, Chen; Kim, Hyun -Jung; Lee, Jun -Ho; Yao, Yongxin; Ho, Kai -Ming; Cho, Jun -Hyung

    2015-08-26

    In this study, the insulating ground state of the 5d transition metal oxide CaIrO3 has been classified as a Mott-type insulator. Based on a systematic density functional theory (DFT) study with local, semilocal, and hybrid exchange-correlation functionals, we reveal that the Ir t2g states exhibit large splittings and one-dimensional electronic states along the c axis due to a tetragonal crystal field. Our hybrid DFT calculation adequately describes the antiferromagnetic (AFM) order along the c direction via a superexchange interaction between Ir4+ spins. Furthermore, the spin-orbit coupling (SOC) hybridizes the t2g states to open an insulating gap. These results indicate thatmore » CaIrO3 can be represented as a spin-orbit Slater insulator, driven by the interplay between a long-range AFM order and the SOC. Such a Slater mechanism for the gap formation is also demonstrated by the DFT + dynamical mean field theory calculation, where the metal-insulator transition and the paramagnetic to AFM phase transition are concomitant with each other.« less

  19. Thermodynamics and superconductivity of Th7(Fe, Ru, Os, Co, Rh, Ir)3 system

    SciTech Connect

    Smith, James L; Lashley, Jason C; Volz, Heather M; Fisher, Robert A

    2008-01-01

    Expanding the temperature range of previous specific-heat measurements on the Th7(Fe, Ru, Os, Co, Rh, Ir)3 system, we measure the effect of transition-metal substitution on total entropy (S{sub 298 k}), electronic specific heat ({gamma}), and Debye temperature ({Theta}D). In addition we measure the pressure dependence, up to 10 kbar, of the superconducting transition.

  20. Effect of Ag addition to L1{sub 0} FePt and L1{sub 0} FePd films grown by molecular beam epitaxy

    SciTech Connect

    Tokuoka, Y.; Seto, Y.; Kato, T.; Iwata, S.

    2014-05-07

    L1{sub 0} ordered FePt-Ag (5?nm) and FePd-Ag (5?nm) films were grown on MgO (001) substrate at temperatures of 250400?C by using molecular beam epitaxy method, and their crystal and surface structures, perpendicular magnetic anisotropies and Curie temperatures were investigated. In the case of FePt-Ag, Ag addition with the amount of 1020 at.?% was effective to promote L1{sub 0} ordering and granular growth, resulting in the increase of the perpendicular magnetic anisotropy and coercivity of the FePt-Ag films. On the other hand, in the case of FePd-Ag, Ag addition changed the surface morphology from island to continuous film associated with the reductions of its coercivity and perpendicular anisotropy. The variations of lattice constants and Curie temperature with Ag addition were significantly different between FePt-Ag and FePd-Ag. For FePd-Ag, the c and a axes lattice spacings and Curie temperature gradually changed with increasing Ag content, while they unchanged for FePt-Ag. These results suggest the possibility of the formation of FePdAg alloy in FePd-Ag, while Ag segregation in FePt-Ag.

  1. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect

    Mei, Donghai; Lebarbier, Vanessa M.; Rousseau, Roger; Glezakou, Vassiliki-Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matt; Dagle, Robert A.

    2013-06-07

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850°C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR

  2. Intermediate hearth repair technique at Thyssen Stahl AG

    SciTech Connect

    Kowalski, W.; Bachhofen, H.J.; Ruether, P.; Ballewski, T.

    1996-12-31

    Nowadays various techniques for the fastest possible intermediate repair and/or emplacement of refractory materials above the tuyere level allow a significant extension of furnace campaign life. The latter are hence now exclusively determined by the service life of the hearth. The improvement of hearth monitoring and the estimation of residual brick strength of the refractory lining on the basis of temperature measurements in the hearth enable the location of individual zones of premature wear. These measurement methods, which were developed by Thyssen Stahl AG, aid the decision to undertake selective repair of the hearth. Three areas of repair are differentiated: taphole zone; hearth wall, localized; and hearth wall, extensive. This hearth repair method is described in this report using the example of hearth refurbishing blast furnace 8, Hamborn.

  3. Optimization of the AGS superconducting helical partial snake strength.

    SciTech Connect

    Lin,F.; Huang, H.; Luccio, A.U.; Roser, T.

    2008-06-23

    Two helical partial snakes, one super-conducting (a.k.a cold snake) and one normal conducting (a.k.a warm snake), have preserved the polarization of proton beam up to 65% in the Brookhaven Alternating Gradient Synchrotron (AGS) at the extraction energy from 85% at injection. In order to overcome spin resonances, stronger partial snakes would be required. However, the stronger the partial snake, the more the stable spin direction tilted producing a stronger horizontal intrinsic resonance. The balance between increasing the spin tune gap generated by the snakes and reducing the tilted stable spin direction has to be considered to maintain the polarization. Because the magnetic field of the warm snake has to be a constant, only the cold snake with a maximum 3T magnetic field can be varied to find out the optimum snake strength. This paper presents simulation results by spin tracking with different cold snake magnetic fields. Some experimental data are also analyzed.

  4. AGS tune jump power supply design and test

    SciTech Connect

    Mi, J.; Glenn, J.W.; Huang, H.; Marneris, I.; Rosas, P.; Sandberg, J.; Tan, Y.; Zhang, W.

    2011-03-28

    A horizontal tune jump system has been installed to overcome the horizontal intrinsic spin resonances, which requires jumping the horizontal tune 0.04 units 82 times, 41 up and 41 down. Two quadruple magnets have been installed in AGS ring to perform this. The pulsed magnet current ranges from about 140A near injection to about 1400A later. The current pulse rise and fall time are around 100uS and flat tops time is around 4mS. These quadruples have separated supplies. This tune jump pulse power supply employees all semiconductor parts as well as the main switches. During dummy load and magnet testing, the test results showed that the power supply could meet the specification. This article will describe some details of power supply simulation, design and testing. Some test waveforms and pictures are presented in this paper.

  5. Recent development of Bi(2223)/Ag tapes for practical applications

    SciTech Connect

    Grasso, G.; Siri, A.S.; Marti, F.; Huang, Y.; Fluekiger, R.; Caracino, P.; Martini, L.

    1999-04-20

    In this paper the authors report about some of the major developments of Ag sheathed Bi(2223) tapes that are actually under study in view of a possible practical application of these conductors. Efforts on improving the tape behavior in presence of alternating currents and high magnetic fields have to be done together with a severe optimization of the Powder-In-Tube method. A clear reduction of the magnetic AC losses is observed by AC susceptibility measurements performed on twisted Bi(2223) tapes prepared at the University of Geneva, with a resistive barrier capable of reducing the coupling losses between filaments. Finally, the authors report on multifilamentary tapes developed with a special configuration that can be of great interest when a magnetic field is applied to the tape at a significant angle with respect to the a-b planes of the superconductor.

  6. Transverse impedance measurement in RHIC and the AGS

    SciTech Connect

    Biancacci, Nicolo; Blaskiewicz, M.; Dutheil, Y.; Liu, C.; Mernick, M.; Minty, M.; White, S. M.

    2014-05-12

    The RHIC luminosity upgrade program aims for an increase of the polarized proton luminosity by a factor 2. To achieve this goal a significant increase in the beam intensity is foreseen. The beam coupling impedance could therefore represent a source of detrimental effects for beam quality and stability at high bunch intensities. For this reason it is essential to quantify the accelerator impedance budget and the major impedance sources, and possibly cure them. In this MD note we summarize the results of the 2013 transverse impedance measurements in the AGS and RHIC. The studies have been performed measuring the tune shift as a function of bunch intensity and deriving the total accelerator machine transverse impedance. For RHIC, we could obtain first promising results of impedance localization measurements as well.

  7. GaSb substrates with extended IR wavelength for advanced space based applications

    SciTech Connect

    Allen, Lisa P.; Flint, Patrick; Dallas, Gordon; Bakken, Daniel; Blanchat, Kevin; Brown, Gail J.; Vangala, Shivashankar R.; Goodhue, William D.; Krishnaswami, Kannan

    2009-05-01

    GaSb substrates have advantages that make them attractive for implementation of a wide range of infrared (IR) detectors with higher operating temperatures for stealth and space based applications. A significant aspect that would enable widespread commercial application of GaSb wafers for very long wavelength IR (VLWIR) applications is the capability for transmissivity beyond 15 m. Due largely to the GaSb (antisite) defect and other point defects in undoped GaSb substrates, intrinsic GaSb is still slightly p-type and strongly absorbs in the VLWIR. This requires backside thinning of the GaSb substrate for IR transmissivity. An extremely low n-type GaSb substrate is preferred to eliminate thinning and provide a substrate solution for backside illuminated VLWIR devices. By providing a more homogeneous radial distribution of the melt solute to suppress GaSb formation and controlling the cooling rate, ultra low doped n:GaSb has been achieved. This study examines the surface properties and IR transmission spectra of ultra low doped GaSb substrates at both room and low temperatures. Atomic force microscopy (AFM), homoepitaxy by MBE, and infrared Fourier transform (FTIR) analysis was implemented to examine material quality. As compared with standard low doped GaSb, the ultra low doped substrates show over 50% transmission and consistent wavelength transparency past 23 m with improved %T at low temperature. Homoepitaxy and AFM results indicate the ultra low doped GaSb has a low thermal desorbtion character and qualified morphology. In summary, improvements in room temperature IR transmission and extended wavelength characteristics have been shown consistently for ultra low doped n:GaSb substrates.

  8. Hierarchical Ag/ZnO micro/nanostructure: Green synthesis and enhanced photocatalytic performance

    SciTech Connect

    Gao, Shuyan; Jia, Xiaoxia; Yang, Shuxia; Li, Zhengdao; Jiang, Kai

    2011-04-15

    Ag/ZnO metal-semiconductor nanocomposites with hierarchical micro/nanostructure have been prepared by the hydrothermal synthesis in the presence of bovine serum albumin (BSA). The results suggest that this biomolecule-assisted hydrothermal method is an efficient route for the fabrication of Ag/ZnO nanocomposites by using BSA both a shape controller and a reducing agent of Ag{sup +} ions. Moreover, Ag nanoparticles on the ZnO act as electron sinks, improving the separation of photogenerated electrons and holes, increasing the surface hydroxyl contents of ZnO, facilitating trapping the photoinduced electrons and holes to form more active hydroxyl radicals, and thus, enhancing the photocatalytic efficiency of ZnO. This is a good example for the organic combination of green chemistry and functional materials. -- Graphical Abstract: A green strategy is report to construct Ag/ZnO metal-semiconductor nanocomposites with hierarchical micro/nanostructure and enhanced photocatalytic activity. Display Omitted Research highlights: > Hierarchical micro/nanostructured Ag/ZnO nanocomposites have been prepared via a green route. > Ag nanoparticles improve the separation of photogenerated electrons and holes. > This facilitates trapping the photoinduced electrons and holes to form more hydroxyl radicals. Therefore, it enhances the photocatalytic efficiency of ZnO.

  9. Light-dependent controlled synthesis and photocatalytic properties of stable Ag{sub 3} nanocrystals

    SciTech Connect

    Wang, Jian-Dong; Liu, Jin-Ku; Luo, Chong-Xiao; Yang, Xiao-Hong

    2014-12-15

    The silver phosphate (Ag{sub 3}PO{sub 4}) is applied in organic matter photodegradation as a novel catalyst materials, however, its instability reduces the photocatalytic life and limits its further applications. In this work, a series of Ag{sub 3}PO{sub 4} crystalline nanoparticle clusters have been synthesized by a photocontrol method. By comparing their sunlight photocatalytic properties, the Ag{sub 3}PO{sub 4} nanoparticles with dominant (2 2 0) facets have a lower surface energy (1.05 J m{sup ?2}) than existing Ag{sub 3}PO{sub 4} crystals which can offer a longer catalyst service life. The photodegradation rate of the Ag{sub 3}PO{sub 4} nanoparticles is about 3 times that of common Ag{sub 3}PO{sub 4} bulk materials and the sunlight is used as the power source instead of high cost artificial visible light sources in this catalytic system. An effective continuous photodegradation reactor using Ag{sub 3}PO{sub 4} nanoparticles is successfully fabricated to degrade rhodamine B solution. At the same time, this work provides an example for how oxidation photocatalyst works without extra adding sacrificial reagent.

  10. A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface

    SciTech Connect

    Erikat, I. A.; Hamad, B. A.

    2013-11-07

    We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75 ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir–C and Ir–Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

  11. An overview of Booster and AGS polarized proton operation during Run 15

    SciTech Connect

    Zeno, K.

    2015-10-20

    This note is an overview of the Booster and AGS for the 2015 Polarized Proton RHIC run from an operations perspective. There are some notable differences between this and previous runs. In particular, the polarized source intensity was expected to be, and was, higher this year than in previous RHIC runs. The hope was to make use of this higher input intensity by allowing the beam to be scraped down more in the Booster to provide a brighter and smaller beam for the AGS and RHIC. The RHIC intensity requirements were also higher this run than in previous runs, which caused additional challenges because the AGS polarization and emittance are normally intensity dependent.

  12. Longitudinal emittance measurements in the Booster and AGS during the 2014 RHIC gold run

    SciTech Connect

    Zeno, K.

    2014-08-18

    This note describes longitudinal emittance measurements that were made in the Booster and AGS during the 2014 RHIC Gold run. It also contains an overview of the longitudinal aspects of their setup during this run. Each bunch intended for RHIC is composed of beam from 4 Booster cycles, and there are two of them per AGS cycle. For each of the 8 Booster cycles required to produce the 2 bunches in the AGS, a beam pulse from EVIS is injected into the Booster and captured in four h=4 buckets. Then those bunches are accelerated to a porch where they are merged into 2 bunches and then into 1 bunch.

  13. Effect of Ag doping and annealing on thermoelectric properties of PbTe

    SciTech Connect

    Bala, Manju Tripathi, T. S.; Avasthi, D. K.; Asokan, K.; Gupta, Srashti

    2015-06-24

    The present study reveals that annealing Ag doped PbTe thin films enhance thermoelectric properties. Phase formation was identified by using X-ray diffraction measurement. Annealing increases the crystallinity of both undoped and Ag doped PbTe. Electrical resistivity and thermoelectric power measurements are done using four probe and bridge method respectively. The increase in thermoelectric power of Ag doped PbTe is 29 % in comparison to undoped PbTe and it further increases to 34 % after annealing at 250{sup o} C for 1 hour whereas thermoelectric power increases by 14 % on annealing undoped PbTe thin films at same temperature.

  14. Nanoscale structure in AgSbTe2 determined by diffuse elastic neutron scattering

    SciTech Connect

    Specht, Eliot D [ORNL; Ma, Jie [ORNL; Delaire, Olivier A [ORNL; Budai, John D [ORNL; May, Andrew F [ORNL; Karapetrova, Evguenia A. [Argonne National Laboratory (ANL)

    2015-01-01

    Diffuse elastic neutron scattering measurements confirm that AgSbTe2 has a hierarchical structure, with defects on length scales from nanometers to microns. While scattering from mesoscale structure is consistent with previously-proposed structures in which Ag and Sb order on a NaCl lattice, more diffuse scattering from nanoscale structure suggests a structural rearrangement in which hexagonal layers form a combination of (ABC), (ABA), and (AAB) stacking sequences. The AgCrSe2 structure is the best-fitting model for the local atomic arrangements.

  15. Current-perpendicular-to-the-plane giant magnetoresistance in spin-valves with AgSn alloy spacers

    SciTech Connect

    Read, J. C.; Nakatani, T. M.; Smith, Neil; Choi, Y.-S.; York, B. R.; Brinkman, E.; Childress, J. R.

    2015-07-28

    We investigate the use of AgSn alloys as the spacer layer in current-perpendicular-to-the-plane magnetoresistance devices. Alloying with Sn increases resistivity but results in a reasonably long (>10 nm) spin-diffusion length, so large magnetoresistance can be achieved with thin AgSn spacers. Compared to Ag thin films, AgSn forms smaller grain sizes, reduced roughness, and exhibits less interdiffusion upon annealing, resulting in decreased interlayer magnetic coupling in exchange biased spin-valves. AgSn also shows improved corrosion resistance compared to Ag, which is advantageous for nanofabrication, including magnetic recording head sensors. Combining a AgSn spacer with Co-based Heusler alloy ferromagnet in an exchange biased, polycrystalline trilayer thinner than 12 nm results in magnetoresistance values up to 15% at room temperature.

  16. Microwave assisted hydrothermal synthesis of Ag/AgCl/WO{sub 3} photocatalyst and its photocatalytic activity under simulated solar light

    SciTech Connect

    Adhikari, Rajesh; Gyawali, Gobinda; Sekino, Tohru; Wohn Lee, Soo

    2013-01-15

    Simulated solar light responsive Ag/AgCl/WO{sub 3} composite photocatalyst was synthesized by microwave assisted hydrothermal process. The synthesized powders were characterized by X-Ray Diffraction (XRD) spectroscopy, X-Ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Diffuse Reflectance Spectroscopy (UV-Vis DRS), and BET surface area analyzer to investigate the crystal structure, morphology, chemical composition, optical properties and surface area of the composite photocatalyst. This photocatalyst exhibited higher photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation. Dye degradation efficiency of composite photocatalyst was found to be increased significantly as compared to that of the commercial WO{sub 3} nanopowder. Increase in photocatalytic activity of the photocatalyst was explained on the basis of surface plasmon resonance (SPR) effect caused by the silver nanoparticles present in the composite photocatalyst. Highlights: Black-Right-Pointing-Pointer Successful synthesis of Ag/AgCl/WO{sub 3} nanocomposite. Black-Right-Pointing-Pointer Photocatalytic experiment was performed under simulated solar light. Black-Right-Pointing-Pointer Nanocomposite photocatalyst was very active as compared to WO{sub 3} commercial powder. Black-Right-Pointing-Pointer SPR effect due to Ag nanoparticles enhanced the photocatalytic activity.

  17. Platinum-monolayer Electrocatalysts: Palladium Interlayer on IrCo Alloy Core Improves Activity in Oxygen-reduction Reaction

    SciTech Connect

    Gong, K.; Chen, W.-F.; Sasaki, K.; Su, D.; Vukmirovic, M.B.; Zhou, W.; Izzo, E.L.; Perez-Acosta, C.; Hirunsit, P.; Balbuena, P.B.; Adzic, R.R.

    2010-11-15

    We describe the synthesis and electrocatalytic properties of a new low-Pt electrocatalyst consisting of an IrCo core, a Pd interlayer, and a surface Pt monolayer, emphasizing the interlayer's role in improving electrocatalytic activity for the oxygen-reduction reaction on Pt in HClO{sub 4} solution. We prepared the IrCo alloys by decomposing, at 800 C, hexacyanometalate, KCoIr(CN){sub 6}, adsorbed on the carbon surfaces. The synthesis of Ir{sub 3}Co/C involved heating a mix of metal salts and carbon in hydrogen at 500 C. Thereafter, we placed a palladium and/or platinum monolayer on them via the galvanic displacement of an underpotentially deposited copper monolayer. The electrocatalysts were characterized using structural- and electrochemical-techniques. For PtML/PdML/IrCo/C, we observed a Pt mass activity of 1.18 A/mg{sub (Pt)} and the platinum-group-metals mass of 0.16 A/mg{sub (Pt, Pd, Ir)}. In comparison, without a Pd interlayer, i.e., Pt{sub ML}/IrCo/C, the activities of 0.15 A/mg{sub (Pt)} and 0.036 A/mg{sub (Pt, Pd, Ir)} were considerably lower. We consider that the palladium interlayer plays an essential role in achieving high catalytic activity by adjusting the electronic interaction of the platinum monolayer with the IrCo core, so that it accelerates the kinetics of adsorption and desorption of the intermediates of oxygen reduction. A similar trend was observed for Pt{sub ML}/Pd{sub ML} and Pt{sub ML} deposited on Ir{sub 3}Co/C alloy core. We used density functional theory to interpret the observed phenomena.

  18. ZnO/Ag composite nanorod arrays for surface-plasmon-enhanced emission study

    SciTech Connect

    Pal, Anil Kumar E-mail: d.bharathimohan@gmail.com; Mohan, D. Bharathi E-mail: d.bharathimohan@gmail.com

    2014-04-24

    The surface plasmon resonance enhanced emission through coupling of surface plasmons and exciton band energies is studied in hybrid ZnO/Ag nanostructure. The catalytic growth of ZnO nanorods is controlled in seed mediated growth by altering size distribution of Ag nanoislands. X-ray diffraction shows a predominant (002) crystal plane confirming the preferential growth of ZnO nanorods on as-deposited Ag. Increase of surface roughness in Ag film by post deposition annealing process enhances the light emission due to momentum matching between surface plasmons and excitons as well as a red shift of 32 meV occurs due to multi phonon and phonon-exciton interaction.

  19. Ternary eutectic growth of nanostructured thermoelectric Ag-Pb-Te materials

    SciTech Connect

    Wu, Hsin-jay; Chen, Sinn-wen; Foo, Wei-jian; Jeffrey Snyder, G.

    2012-07-09

    Nanostructured Ag-Pb-Te thermoelectric materials were fabricated by unidirectionally solidifying the ternary Ag-Pb-Te eutectic and near-eutectic alloys using the Bridgeman method. Specially, the Bridgman-grown eutectic alloy exhibited a partially aligned lamellar microstructure, which consisted of Ag{sub 5}Te{sub 3} and Te phases, with additional 200-600 nm size particles of PbTe. The self-assembled interfaces altered the thermal and electronic transport properties in the bulk Ag-Pb-Te eutectic alloy. Presumably due to phonon scattering from the nanoscale microstructure, a low thermal conductivity ({kappa} = 0.3 W/mK) was achieved of the eutectic alloy, leading to a zT peak of 0.41 at 400 K.

  20. DEPARTlIiIENT OF ENERGY EERE PROJECT MAN AG EMENT CENTER NEPA...

    Office of Energy Efficiency and Renewable Energy (EERE) (indexed site)

    lAUIl) u.s. DEPARTlIiIENT OF ENERGY EERE PROJECT MAN AG EMENT CENTER NEPA DETERMINATION RECIPIENT:Ocean Engineering and Energy Systems Intemational, Inc. (OCEES) Page lof3 STATE: ...

  1. Feasible voltage-tap based quench detection in a Ag/Bi-2212 coil...

    Office of Scientific and Technical Information (OSTI)

    Small insert solenoids have been built using a commercial AgBi-2212 multifilamentary round wire, insulated with a new thin TiO2 - polymer coating insulation (thickness in 20 m ...

  2. Influence of Ag doping concentration on structural and optical properties of CdS thin film

    SciTech Connect

    Kumar, Pragati; Saxena, Nupur; Gupta, Vinay; Agarwal, Avinash

    2015-05-15

    This work shows the influence of Ag concentration on structural properties of pulsed laser deposited nanocrystalline CdS thin film. X-ray photoelectron spectroscopy (XPS) studies confirm the dopant concentration in CdS films and atomic concentration of elements. XPS studies show that the samples are slightly sulfur deficient. GAXRD scan reveals the structural phase transformation from cubic to hexagonal phase of CdS without appearance of any phase of CdO, Ag{sub 2}O or Ag{sub 2}S suggesting the substitutional doping of Ag ions. Photoluminescence studies illustrate that emission intensity increases with increase in dopant concentration upto 5% and then decreases for higher dopant concentration.

  3. Partial gamma-ray cross section measurements in 109Ag(n, x n...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Partial gamma-ray cross section measurements in 109Ag(n, x n y p gamma) reactions Citation Details In-Document Search Title: Partial gamma-ray cross section ...

  4. The U5+ compound Ba9Ag10U4S24: Synthesis, structure, and electronic...

    Office of Scientific and Technical Information (OSTI)

    The U5+ compound Ba9Ag10U4S24: Synthesis, structure, and electronic properties This ... Sponsoring Org: USDOE Country of Publication: United States Language: English Word Cloud ...

  5. Curing the UV/IR mixing for field theories with translation-invariant star products

    SciTech Connect

    Tanasa, Adrian; Vitale, Patrizia

    2010-03-15

    The ultraviolet/infrared (UV/IR) mixing of noncommutative field theories has been recently shown to be a generic feature of translation-invariant associative products. In this paper we propose to take into account the quantum corrections of the model to modify in this way the noncommutative action. This idea was already used to cure the UV/IR mixing for theories on Moyal space. We show that in the present framework also, this proposal proves successful for curing the mixing. We achieve this task by explicit calculations of one and higher loops Feynman amplitudes. For the sake of completeness, we compute the form of the new action in the matrix base for the Wick-Voros product.

  6. Practical Analysis of materials with depth varying compositions using FT-IR photoacoustic spectroscopy (PAS)

    SciTech Connect

    J.F. McClelland; R.W. Jones; Siquan Luo

    2004-09-30

    FT-IR photoacoustic spectroscopy (PAS) is discussed as a nondestructive method to probe the molecular composition of materials versus depth on the basis of the analysis of layers of experimentally controllable thickness, which are measured from the sample surface to depths of some tens of micrometers, depending on optical and thermal properties. Computational methods are described to process photoacoustic amplitude and phase spectra for both semi-quantitative and quantitative depth analyses. These methods are demonstrated on layered and gradient samples.

  7. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for

  8. Improved ARM-SGP TOA OLR Fluxes from GOES-8 IR Radiances Based on CERES Data

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    ARM-SGP TOA OLR Fluxes from GOES-8 IR Radiances Based on CERES Data D. R. Doelling and M. M. Khaiyer Analytical Services and Materials, Inc. Hampton, Virginia P. Minnis National Aeronautics and Space Administration Langley Research Center Hampton, Virginia Introduction The radiation budget at the top of the atmosphere (TOA) is a quantity of fundamental importance to the Atmospheric Radiation Measurement (ARM) Program. Thus, it is necessary to measure the radiation budget components, broadband

  9. HIGH ENERGY PULSED POWER SYSTEM FOR AGS SUPER NEUTRINO FOCUSING HORN.

    SciTech Connect

    ZHANG, S.Y.; SANDBERG, J.; WENG, W.-T.

    2005-05-16

    This paper present a preliminary design of a 300 kA, 2.5 Hz pulsed power system. This system will drive the focusing horn of proposed Brookhaven AGS Neutrino Super Beam Facility for Very Long Baseline Neutrino Oscillation Experiment. The peak output power of the horn pulsed power system will reach Giga-watts, and the upgraded AGS will be capable of delivering 1 MW in beam power.

  10. Non-toxic silver iodide (AgI) quantum dots sensitized solar cells

    SciTech Connect

    Moosakhani, S.; Sabbagh Alvani, A.A.; Sarabi, A.A.; Sameie, H.; Salimi, R.; Kiani, S.; Ebrahimi, Y.

    2014-12-15

    Highlights: • We have demonstrated AgI sensitized solar cell for the first time. • Obtained mesoporous titania powders possessed small crystallite size, high purity and surface area, and developed mesopores with a narrow pore size distribution. • Photovoltaic measurements revealed the electron injection from AgI to TiO{sub 2}. • The assembled AgI-QD solar cells yielded a power conversion efficiency of 0.64% under one sun illumination. • AgI may be a suitable candidate material for use as a non-toxic sensitizer in QDSSC. - Abstract: The present study reports the performance of a new photosensitizer -AgI quantum dots (QDs)- and mesoporous titania (TiO{sub 2}) nanocrystals synthesized by sol–gel (SG) method for solar cells. Furthermore, the effects of n-heptane on the textural properties of TiO{sub 2} nanocrystals were comprehensively investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), N{sub 2} adsorption–desorption measurements, and UV–vis spectroscopy. TiO{sub 2} powders exhibited an anatase-type mesoporous structure with a high surface area of 89.7 m{sup 2}/g. Afterwards, the QDs were grown on mesoporous TiO{sub 2} surface to fabricate a TiO{sub 2}/AgI electrode by a successive ionic layer adsorption and reaction (SILAR) deposition route. Current–voltage characteristics and electrochemical impedance spectroscopy (EIS) data demonstrated that the injection of photoexcited electrons from AgI QDs into the TiO{sub 2} matrix produces photocurrents. The assembled AgI-QD solar cells yielded a power conversion efficiency of 0.64% and a short-circuit current of 2.13 mA/cm{sup 2} under one sun illumination.

  11. Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler

    SciTech Connect

    James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

    1999-05-31

    This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

  12. NGC 7538 IRS. 1. Interaction of a polarized dust spiral and a molecular outflow

    SciTech Connect

    Wright, M. C. H.; Hull, Charles L. H.; Pillai, Thushara; Zhao, Jun-Hui; Sandell, Göran

    2014-12-01

    We present dust polarization and CO molecular line images of NGC 7538 IRS 1. We combined data from the Submillimeter Array, the Combined Array for Research in Millimeter-wave Astronomy, and the James Clerk Maxwell Telescope to make images with ∼2.''5 resolution at 230 and 345 GHz. The images show a remarkable spiral pattern in both the dust polarization and molecular outflow. These data dramatically illustrate the interplay between a high infall rate onto IRS 1 and a powerful outflow disrupting the dense, clumpy medium surrounding the star. The images of the dust polarization and the CO outflow presented here provide observational evidence for the exchange of energy and angular momentum between the infall and the outflow. The spiral dust pattern, which rotates through over 180° from IRS 1, may be a clumpy filament wound up by conservation of angular momentum in the infalling material. The redshifted CO emission ridge traces the dust spiral closely through the MM dust cores, several of which may contain protostars. We propose that the CO maps the boundary layer where the outflow is ablating gas from the dense gas in the spiral.

  13. The first photometric analysis of the near contact binary IR Cas

    SciTech Connect

    Li, Kai; Hu, S.-M.; Guo, D.-F.; Jiang, Y.-G.; Gao, D.-Y.; Chen, X. E-mail: likai@ynao.ac.cn E-mail: difu@sdu.edu.cn

    2014-11-01

    The first photometric analysis of IR Cas was carried out based on the new observed BVRI light curves. The symmetric light curves and nearly flat secondary minimum indicate that very precise photometric results can be determined. We found that IR Cas is a near contact binary with the primary component filling its Roche lobe. An analysis of the O – C diagram based on all available times of minimum light reveals evidence for a periodic change with a semi-amplitude of 0.0153 days and a period of 39.7 yr superimposed on a secular decrease at a rate of dp/dt = –1.28(± 0.09) × 10{sup –7} days yr{sup –1}. The most reasonable explanation for the periodic change is the light time-travel effect due to a third body. The period decrease may be caused by mass transfer from the primary component to the secondary. With the decreasing period, IR Cas would eventually evolve into a contact system.

  14. An industrial FT-IR process gas analyzer for stack gas cems analysis

    SciTech Connect

    Welch, G.M.; Herman, B.E.

    1995-12-31

    This paper describes utilizing Fourier Transform Infrared (FT-IR) technology to meet and exceed EPA requirements to Continuously Monitor Carbon Monoxide (CO) and Sulfur Dioxide (SO){sub 2} in an oil refinery. The application consists of Continuous Emission Monitoring (CEMS) of two stacks from a Fluid Catalytic Cracking unit (FCCU). The discussion will follow the project from initial specifications, installation, start-up, certification results (RATA, 7 day drift), Cylinder Gas Audit (CGA) and the required maintenance. FT-IR is a powerful analytical tool suitable for measurement of stack component gases required to meet CEMS regulations, and allows simultaneous multi-component analysis of complex stack gas streams with a continuous sample stream flow through the measurement cell. The Michelson Interferometer in a unique {open_quotes}Wishbone{close_quotes} design and with a special alignment control enables standardized configuration of the analyzer for flue gas analysis. Normal stack gas pollutants: NO{sub x}, SO{sub 2}, and CO; as well as water soluble pollutants such as NH{sub 3} and HCI may be accurately determined and reported even in the presence of 0-31 Vol % water vapor concentrations (hot and wet). This FT-IR analyzer has been operating with EPA Certification in an oil refinery environment since September 1994.

  15. Energetics of the formation of Cu-Ag core–shell nanoparticles

    SciTech Connect

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of core–shell Cu-Ag nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a core–shell structure from two previously distinct, non-interacting nanoparticles. In most cases, the core–shell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a core–shell structure forms. In general, it was found that the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a core–shell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a Cu–Ag interfacial energy, which is always smaller.

  16. Energetics of the formation of CuAg coreshell nanoparticles

    DOE PAGES [OSTI]

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of coreshell CuAg nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a coreshell structure from two previously distinct, non-interacting nanoparticles. In most cases, the coreshell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a coreshell structure forms. In general, it was foundmorethat the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a coreshell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a CuAg interfacial energy, which is always smaller.less

  17. Effect of carbon ion irradiation on Ag diffusion in SiC

    SciTech Connect

    Leng, Bin; Ko, Hyunseok; Gerczak, Tyler J.; Deng, Jie; Giordani, Andrew J.; Hunter, Jerry L.; Morgan, Dane; Szlufarska, Izabela; Sridharan, Kumar

    2015-11-14

    Transport of Ag fission product through the silicon-carbide (SiC) diffusion barrier layer in TRISO fuel particles is of considerable interest given the application of this fuel type in high temperature gas-cooled reactor (HTGR) and other future reactor concepts. The reactor experiments indicate that radiation may play an important role in release of Ag; however so far the isolated effect of radiation on Ag diffusion has not been investigated in controlled laboratory experiments. In this study, we investigate the diffusion couples of Ag and polycrystalline 3C–SiC, as well as Ag and single crystalline 4H–SiC samples before and after irradiation with C2+ ions. The diffusion couple samples were exposed to temperatures of 1500 °C, 1535 °C, and 1569 °C, and the ensuing diffusion profiles were analyzed by secondary ion mass spectrometry (SIMS). We found that diffusion coefficients calculated from these measurements indicate that Ag diffusion was greatly enhanced by carbon irradiation due to a combined effect of radiation damage on diffusion and the presence of grain boundaries in polycrystalline SiC samples.

  18. Effect of carbon ion irradiation on Ag diffusion in SiC

    DOE PAGES [OSTI]

    Leng, Bin; Ko, Hyunseok; Gerczak, Tyler J.; Deng, Jie; Giordani, Andrew J.; Hunter, Jerry L.; Morgan, Dane; Szlufarska, Izabela; Sridharan, Kumar

    2015-11-14

    Transport of Ag fission product through the silicon-carbide (SiC) diffusion barrier layer in TRISO fuel particles is of considerable interest given the application of this fuel type in high temperature gas-cooled reactor (HTGR) and other future reactor concepts. The reactor experiments indicate that radiation may play an important role in release of Ag; however so far the isolated effect of radiation on Ag diffusion has not been investigated in controlled laboratory experiments. In this study, we investigate the diffusion couples of Ag and polycrystalline 3C–SiC, as well as Ag and single crystalline 4H–SiC samples before and after irradiation with C2+more » ions. The diffusion couple samples were exposed to temperatures of 1500 °C, 1535 °C, and 1569 °C, and the ensuing diffusion profiles were analyzed by secondary ion mass spectrometry (SIMS). We found that diffusion coefficients calculated from these measurements indicate that Ag diffusion was greatly enhanced by carbon irradiation due to a combined effect of radiation damage on diffusion and the presence of grain boundaries in polycrystalline SiC samples.« less

  19. Energetics of the formation of Cu-Ag core–shell nanoparticles

    DOE PAGES [OSTI]

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of core–shell Cu-Ag nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a core–shell structure from two previously distinct, non-interacting nanoparticles. In most cases, the core–shell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a core–shell structure forms. In general, it was foundmore » that the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a core–shell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a Cu–Ag interfacial energy, which is always smaller.« less

  20. Simulations of Merging Helion Bunches on the AGS Injection Porch

    SciTech Connect

    Gardner, C. J.

    2014-08-29

    During the setup of helions for the FY2014 RHIC run it was discovered that the standard scheme for merging bunches on the AGS injection porch required an injection kicker pulse shorter than what was available. To overcome this difficulty, K. Zeno proposed and developed an interesting and unusual alternative which uses RF harmonic numbers 12, 4, 2 (rather than the standard 8, 4, 2) to merge 8 helion bunches into 2. In this note we carry out simulations that illustrate how the alternative scheme works and how it compares with the standard scheme. This is done in Sections 13 and 14. A scheme in which 6 bunches are merged into 1 is simulated in Section 15. This may be useful if more helions per merged bunch are needed in future runs. General formulae for the simulations are given in Sections 9 through 12. For completeness, Sections 1 through 8 give a derivation of the turn-by-turn equations of longitudinal motion at constant magnetic field. The derivation is based on the work of MacLachlan. The reader may wish to skip over these Sections and start with Section 9.

  1. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible

  2. Synthesis and anti-bacterial activity of Cu, Ag and Cu-Ag alloy nanoparticles: A green approach

    SciTech Connect

    Valodkar, Mayur; Modi, Shefaly; Pal, Angshuman; Thakore, Sonal

    2011-03-15

    Research highlights: {yields} Synthesis of novel nanosized copper-silver alloys of different compositions. {yields} Completely green approach for synthesis of water soluble bimetallic nanoparticle. {yields} Interesting anti-bacterial activity of as synthesized metal and alloy nanoparticle. -- Abstract: Metallic and bimetallic nanoparticles of copper and silver in various proportions were prepared by microwave assisted chemical reduction in aqueous medium using the biopolymer, starch as a stabilizing agent. Ascorbic acid was used as the reducing agent. The silver and copper nanoparticles exhibited surface plasmon absorption resonance maxima (SPR) at 416 and 584 nm, respectively; while SPR for the Cu-Ag alloys appeared in between depending on the alloy composition. The SPR maxima for bimetallic nanoparticles changes linearly with increasing copper content in the alloy. Transmission electron micrograph (TEM) showed monodispersed particles in the range of 20 {+-} 5 nm size. Both silver and copper nanoparticles exhibited emission band at 485 and 645 nm, respectively. The starch-stabilized nanoparticles exhibited interesting antibacterial activity with both gram positive and gram negative bacteria at micromolar concentrations.

  3. THE AGS-BASED SUPER NEUTRINO BEAM FACILITY CONCEPTUAL DESIGN REPORT

    SciTech Connect

    WENG,W.T.; DIWAN,M.; RAPARIA,D.

    2004-10-08

    After more than 40 years of operation, the AGS is still at the heart of the Brookhaven hadron accelerator complex. This system of accelerators presently comprises a 200 MeV linac for the pre-acceleration of high intensity and polarized protons, two Tandem Van der Graaffs for the pre-acceleration of heavy ion beams, a versatile Booster that allows for efficient injection of all three types of beams into the AGS and, most recently, the two RHIC collider rings that produce high luminosity heavy ion and polarized proton collisions. For several years now, the AGS has held the world intensity record with more than 7 x 10{sup 13} protons accelerated in a single pulse. The requirements for the proton beam for the super neutrino beam are summarized and a schematic of the upgraded AGS is shown. Since the present number of protons per fill is already close to the required number, the upgrade is based on increasing the repetition rate and reducing beam losses (to avoid excessive shielding requirements and to maintain activation of the machine components at workable level). It is also important to preserve all the present capabilities of the AGS, in particular its role as injector to RHIC. The AGS Booster was built not only to allow the injection of any species of heavy ion into the AGS but to allow a fourfold increase of the AGS intensity. It is one-quarter the circumference of the AGS with the same aperture. However, the accumulation of four Booster loads in the AGS takes about 0.6 s, and is therefore not well suited for high average beam power operation. To minimize the injection time to about 1 ms, a 1.2 GeV linac will be used instead. This linac consists of the existing warm linac of 200 MeV and a new superconducting linac of 1.0 GeV. The multi-turn H{sup -} injection from a source of 30 mA and 720 {micro}s pulse width is sufficient to accumulate 9 x 10{sup 13} particle per pulse in the AGS[10]. The minimum ramp time of the AGS to full energy is presently 0.5 s; this must

  4. Mid-IR laser action in the H{sub 3} Rydberg molecule and some possible astrophysical implications

    SciTech Connect

    Saykally, Richard J.

    2015-01-22

    Mid-IR lasing has been observed in supersonic plasmas and assigned to d to p transitions in tri-atomic hydrogen Rydberg states. Possible astrophysical implications are discussed.

  5. Progress in Solving the Elusive Ag Transport Mechanism in TRISO Coated Particles: What is new?

    SciTech Connect

    Isabella Van Rooyen

    2014-10-01

    The TRISO particle for HTRs has been developed to an advanced state where the coating withstands internal gas pressures and retains fission products during irradiation and under postulated accidents. However, one exception is Ag that has been found to be released from high quality TRISO coated particles when irradiated and can also during high temperature accident heating tests. Although out- of- pile laboratory tests have never hither to been able to demonstrate a diffusion process of Ag in SiC, effective diffusion coefficients have been derived to successfully reproduce measured Ag-110m releases from irradiated HTR fuel elements, compacts and TRISO particles It was found that silver transport through SiC does not proceed via bulk volume diffusion. Presently grain boundary diffusion that may be irradiation enhanced either by neutron bombardment or by the presence of fission products such as Pd, are being investigated. Recent studies of irradiated AGR-1 TRISO fuel using scanning transmission electron microscopy (STEM), transmission kukuchi diffraction (TKD) patterns and high resolution transmission electron microscopy (HRTEM) have been used to further the understanding of Ag transport through TRISO particles. No silver was observed in SiC grains, but Ag was identified at triple-points and grain boundaries of the SiC layer in the TRISO particle. Cadmium was also found in some of the very same triple junctions, but this could be related to silver behavior as Ag-110m decays to Cd-110. Palladium was identified as the main constituent of micron-sized precipitates present at the SiC grain boundaries and in most SiC grain boundaries and the potential role of Pd in the transport of Ag will be discussed.

  6. Atomic-scale investigation of interface-facilitated deformation twinning in severely deformed Ag-Cu nanolamellar composites

    SciTech Connect

    An, X. H. E-mail: xiaozhou.liao@sydenye.edu.au; Cao, Y.; Liao, X. Z. E-mail: xiaozhou.liao@sydenye.edu.au; Zhu, S. M.; Nie, J. F.; Kawasaki, M.; Ringer, S. P.; Langdon, T. G.; Zhu, Y. T.

    2015-07-06

    We report an atomic-scale investigation of interface-facilitated deformation twinning behaviour in Ag-Cu nanolamellar composites. Profuse twinning activities in Ag supply partial dislocations to directly transmit across the Ag-Cu lamellar interface that promotes deformation twinning in the neighbouring Cu lamellae although the interface is severely deformed. The trans-interface twin bands change the local structure at the interface. Our analysis suggests that the orientation relationship and interfacial structure between neighbouring Ag-Cu lamellae play a crucial role in such special interface-facilitated twinning behaviour.

  7. Characterization of Na+- beta-Zeolite Supported Pd and Pd Ag Bimetallic Catalysts using EXAFS, TEM and Flow Reactor

    SciTech Connect

    Huang,W.; Lobo, R.; Chen, J.

    2008-01-01

    Flow reactor studies of the selective hydrogenation of acetylene in the presence of ethylene have been performed on Na+ exchanged {beta}-zeolite supported Pd, Ag and PdAg catalysts, as an extension of our previous batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. Results from flow reactor studies show that the PdAg/Na+-{beta}-zeolite bimetallic catalyst has lower activity than Pd/Na+-{beta}-zeolite monometallic catalyst, while Ag/Na+-{beta}-zeolite does not show any activity for acetylene hydrogenation. However, the selectivity for the PdAg bimetallic catalyst is much higher than that for either the Pd catalyst or Ag catalyst. The selectivity to byproduct (ethane) is greatly inhibited on the PdAg bimetallic catalyst as well. The results from the current flow reactor studies confirmed the pervious results from batch reactor studies [W. Huang, J.R. McCormick, R.F. Lobo, J.G. Chen, J. Catal. 246 (2007) 40-51]. In addition, we used transmission electron microscope (TEM), extended X-ray absorption fine structure (EXAFS), and FTIR of CO adsorption to confirm the formation of Pd-Ag bimetallic alloy in the PdAg/Na+-{beta}-zeolite catalyst.

  8. Role of the antiferromagnetic pinning layer on spin wave properties in IrMn/NiFe based spin-valves

    SciTech Connect

    Gubbiotti, G. Tacchi, S.; Del Bianco, L.; Bonfiglioli, E.; Giovannini, L.; Spizzo, F.; Zivieri, R.; Tamisari, M.

    2015-05-07

    Brillouin light scattering (BLS) was exploited to study the spin wave properties of spin-valve (SV) type samples basically consisting of two 5 nm-thick NiFe layers (separated by a Cu spacer of 5 nm), differently biased through the interface exchange coupling with an antiferromagnetic IrMn layer. Three samples were investigated: a reference SV sample, without IrMn (reference); one sample with an IrMn underlayer (10 nm thick) coupled to the bottom NiFe film; one sample with IrMn underlayer and overlayer of different thickness (10 nm and 6 nm), coupled to the bottom and top NiFe film, respectively. The exchange coupling with the IrMn, causing the insurgence of the exchange bias effect, allowed the relative orientation of the NiFe magnetization vectors to be controlled by an external magnetic field, as assessed through hysteresis loop measurements by magneto-optic magnetometry. Thus, BLS spectra were acquired by sweeping the magnetic field so as to encompass both the parallel and antiparallel alignment of the NiFe layers. The BLS results, well reproduced by the presented theoretical model, clearly revealed the combined effects on the spin dynamic properties of the dipolar interaction between the two NiFe films and of the interface IrMn/NiFe exchange coupling.

  9. Metal insulator transitions in perovskite SrIrO{sub 3} thin films

    SciTech Connect

    Biswas, Abhijit; Jeong, Yoon Hee; Kim, Ki-Seok

    2014-12-07

    Understanding of metal insulator transitions in a strongly correlated system, driven by Anderson localization (disorder) and/or Mott localization (correlation), is a long standing problem in condensed matter physics. The prevailing fundamental question would be how these two mechanisms contrive to accomplish emergent anomalous behaviors. Here, we have grown high quality perovskite SrIrO{sub 3} thin films, containing a strong spin orbit coupled 5d element Ir, on various substrates such as GdScO{sub 3} (110), DyScO{sub 3} (110), SrTiO{sub 3} (001), and NdGaO{sub 3} (110) with increasing lattice mismatch, in order to carry out a systematic study on the transport properties. We found that metal insulator transitions can be induced in this system; by either reducing thickness (on best lattice matched substrate) or changing degree of lattice strain (by lattice mismatch between film and substrates) of films. Surprisingly these two pathways seek two distinct types of metal insulator transitions; the former falls into disorder driven Anderson type whereas the latter turns out to be of unconventional Mott-Anderson type with the interplay of disorder and correlation. More interestingly, in the metallic phases of SrIrO{sub 3}, unusual non-Fermi liquid characteristics emerge in resistivity as Δρ ∝ T{sup ε} with ε evolving from 4/5 to 1 to 3/2 with increasing lattice strain. We discuss theoretical implications of these phenomena to shed light on the metal insulator transitions.

  10. Transition from the infalling envelope to the Keplerian disk around L1551 IRS 5

    SciTech Connect

    Chou, Ti-Lin [Department of Physics, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan (China); Takakuwa, Shigehisa; Yen, Hsi-Wei; Ohashi, Nagayoshi; Ho, Paul T. P., E-mail: tlchou@asiaa.sinica.edu.tw [Academia Sinica Institute of Astronomy and Astrophysics, P. O. Box 23-141, Taipei 10617, Taiwan (China)

    2014-11-20

    We present combined Submillimeter Array (SMA) +Atacama Submillimeter Telescope Experiment (ASTE) images of the Class I protobinary L1551 IRS 5 in the CS (J = 7-6) line, the submillimeter images of L1551 IRS 5 with the most complete spatial sampling ever achieved (0.''9-36''). The SMA image of L1551 IRS 5 in the 343 GHz dust-continuum emission is also presented, which shows an elongated feature along the northwest to southeast direction (?160 AU 80 AU), perpendicular to the associated radio jets. The combined SMA+ASTE images show that the high-velocity (?1.5 km s{sup 1}) CS emission traces the structure of the dust component and shows a velocity gradient along the major axis, which is reproduced by a geometrically thin Keplerian-disk model with a central stellar mass of ?0.5 M {sub ?}. The low-velocity (?1.3 km s{sup 1}) CS emission shows an extended (?1000 AU) feature that exhibits slight south (blueshifted) to north (redshifted) emission offsets, which is modeled with a rotating and infalling envelope with a conserved angular momentum. The rotational motion of the envelope connects smoothly to the inner Keplerian rotation at a radius of ?64 AU. The infalling velocity of the envelope is ?three times lower than the free-fall velocity toward the central stellar mass of 0.5 M {sub ?}. These results demonstrate transition from the infalling envelope to the Keplerian disk, consistent with the latest theoretical studies of disk formation. We suggest that sizable (r ? 50-200 AU) Keplerian disks are already formed when the protostars are still deeply embedded in the envelopes.

  11. Phase-matched generation of coherent soft and hard X-rays using IR lasers

    DOEpatents

    Popmintchev, Tenio V.; Chen, Ming-Chang; Bahabad, Alon; Murnane, Margaret M.; Kapteyn, Henry C.

    2013-06-11

    Phase-matched high-order harmonic generation of soft and hard X-rays is accomplished using infrared driving lasers in a high-pressure non-linear medium. The pressure of the non-linear medium is increased to multi-atmospheres and a mid-IR (or higher) laser device provides the driving pulse. Based on this scaling, also a general method for global optimization of the flux of phase-matched high-order harmonic generation at a desired wavelength is designed.

  12. Radiation from Ag high energy density Z-pinch plasmas and applications to lasing

    SciTech Connect

    Weller, M. E. Safronova, A. S.; Kantsyrev, V. L.; Esaulov, A. A.; Shrestha, I.; Stafford, A.; Keim, S. F.; Shlyaptseva, V. V.; Osborne, G. C.; Petkov, E. E.; Apruzese, J. P.; Giuliani, J. L.; Chuvatin, A. S.

    2014-03-15

    Silver (Ag) wire arrays were recently introduced as efficient x-ray radiators and have been shown to create L-shell plasmas that have the highest electron temperature (>1.8?keV) observed on the Zebra generator so far and upwards of 30?kJ of energy output. In this paper, results of single planar wire arrays and double planar wire arrays of Ag and mixed Ag and Al that were tested on the UNR Zebra generator are presented and compared. To further understand how L-shell Ag plasma evolves in time, a time-gated x-ray spectrometer was designed and fielded, which has a spectral range of approximately 3.55.0?. With this, L-shell Ag as well as cold L{sub ?} and L{sub ?} Ag lines was captured and analyzed along with photoconducting diode (PCD) signals (>0.8?keV). Along with PCD signals, other signals, such as filtered XRD (>0.2?keV) and Si-diodes (SiD) (>9?keV), are analyzed covering a broad range of energies from a few eV to greater than 53?keV. The observation and analysis of cold L{sub ?} and L{sub ?} lines show possible correlations with electron beams and SiD signals. Recently, an interesting issue regarding these Ag plasmas is whether lasing occurs in the Ne-like soft x-ray range, and if so, at what gains? To help answer this question, a non-local thermodynamic equilibrium (LTE) kinetic model was utilized to calculate theoretical lasing gains. It is shown that the Ag L-shell plasma conditions produced on the Zebra generator at 1.7 maximum current may be adequate to produce gains as high as 6?cm{sup ?1} for various 3p???3s transitions. Other potential lasing transitions, including higher Rydberg states, are also included in detail. The overall importance of Ag wire arrays and plasmas is discussed.

  13. I/O impedance controller

    DOEpatents

    Ruesch, Rodney; Jenkins, Philip N.; Ma, Nan

    2004-03-09

    There is disclosed apparatus and apparatus for impedance control to provide for controlling the impedance of a communication circuit using an all-digital impedance control circuit wherein one or more control bits are used to tune the output impedance. In one example embodiment, the impedance control circuit is fabricated using circuit components found in a standard macro library of a computer aided design system. According to another example embodiment, there is provided a control for an output driver on an integrated circuit ("IC") device to provide for forming a resistor divider network with the output driver and a resistor off the IC device so that the divider network produces an output voltage, comparing the output voltage of the divider network with a reference voltage, and adjusting the output impedance of the output driver to attempt to match the output voltage of the divider network and the reference voltage. Also disclosed is over-sampling the divider network voltage, storing the results of the over sampling, repeating the over-sampling and storing, averaging the results of multiple over sampling operations, controlling the impedance with a plurality of bits forming a word, and updating the value of the word by only one least significant bit at a time.

  14. SC11-IO.pptx

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    sharing of files as persistent storage over a network. * Network File System (protocol) (NFS) - Widely used and available, but not developed as a standard for high- performance...

  15. I/O Library List

    U.S. Department of Energy (DOE) - all webpages (Extended Search)

    Help Staff Blogs Request Repository Mailing List Need Help? Out-of-hours Status and Password help Call operations: 1-800-66-NERSC, option 1 or 510-486-6821 Account Support ...

  16. Determination of Desorbed Species During Heating of AgI-Mordenite Provided by ORNL

    SciTech Connect

    Croes, Kenneth James; Garino, Terry J.; Mowry, Curtis D.; Nenoff, Tina M.

    2015-12-15

    This study is focused on describing the desorbed off gases due to heating of the AgIMordenite (MOR) produced at ORNL for iodine (I2) gas capture from nuclear fuel aqueous reprocessing. In particular, the interest is for the incorporation of the AgI-MOR into a waste form, which might be the Sandia developed, low temperature sintering, Bi-Si oxide based, Glass Composite Material (GCM). The GCM has been developed as a waste form for the incorporation any oxide based getter material. In the case where iodine may be released during the sintering process of the GCM, additional Ag flake is added as further insurance in total iodine capture and retention. This has been the case for the incorporated ORNL developed AgIMOR. Thermal analysis studies were carried out to determine off gasing processes of ORNL AgIMOR. Independent of sample size, ~7wt% of total water is desorbed by 225°C. This includes both bulk surface and occluded water, and are monitored as H2O and OH. Of that total, ~5.5wt% is surface water which is removed by 125°C, and 1.5wt% is occluded (in zeolite pore) water. Less than ~1 wt% total water continues to desorb, but is completely removed by 500°C. Above 300°C, the detectable remaining desorbing species observed are iodine containing compounds, including I and I2.

  17. Sonic IR crack detection of aircraft turbine engine blades with multi-frequency ultrasound excitations

    SciTech Connect

    Zhang, Ding; Han, Xiaoyan; Newaz, Golam

    2014-02-18

    Effectively and accurately detecting cracks or defects in critical engine components, such as turbine engine blades, is very important for aircraft safety. Sonic Infrared (IR) Imaging is such a technology with great potential for these applications. This technology combines ultrasound excitation and IR imaging to identify cracks and flaws in targets. In general, failure of engine components, such as blades, begins with tiny cracks. Since the attenuation of the ultrasound wave propagation in turbine engine blades is small, the efficiency of crack detection in turbine engine blades can be quite high. The authors at Wayne State University have been developing the technology as a reliable tool for the future field use in aircraft engines and engine parts. One part of the development is to use finite element modeling to assist our understanding of effects of different parameters on crack heating while experimentally hard to achieve. The development has been focused with single frequency ultrasound excitation and some results have been presented in a previous conference. We are currently working on multi-frequency excitation models. The study will provide results and insights of the efficiency of different frequency excitation sources to foster the development of the technology for crack detection in aircraft engine components.

  18. Graphene oxide/carbon nanoparticle thin film based IR detector: Surface properties and device characterization

    SciTech Connect

    Chowdhury, Farzana Aktar; Hossain, Mohammad Abul; Uchida, Koji; Tamura, Takahiro; Sugawa, Kosuke; Mochida, Tomoaki; Otsuki, Joe; Mohiuddin, Tariq; Boby, Monny Akter; Alam, Mohammad Sahabul

    2015-10-15

    This work deals with the synthesis, characterization, and application of carbon nanoparticles (CNP) adorned graphene oxide (GO) nanocomposite materials. Here we mainly focus on an emerging topic in modern research field presenting GO-CNP nanocomposite as a infrared (IR) radiation detector device. GO-CNP thin film devices were fabricated from liquid phase at ambient condition where no modifying treatments were necessary. It works with no cooling treatment and also for stationary objects. A sharp response of human body IR radiation was detected with time constants of 3 and 36 sec and radiation responsivity was 3 mAW{sup −1}. The current also rises for quite a long time before saturation. This work discusses state-of-the-art material developing technique based on near-infrared photon absorption and their use in field deployable instrument for real-world applications. GO-CNP-based thin solid composite films also offer its potentiality to be utilized as p-type absorber material in thin film solar cell, as well.

  19. Laser separation of nitrogen isotopes by the IR+UV dissociation of ammonia molecules

    SciTech Connect

    Apatin, V M; Klimin, S A; Laptev, V B; Lokhman, V N; Ogurok, D D; Pigul'skii, S V; Ryabov, E A

    2008-08-31

    The separation of nitrogen isotopes is studied upon successive single-photon IR excitation and UV dissociation of ammonia molecules. The excitation selectivity was provided by tuning a CO{sub 2} laser to resonance with {sup 14}NH{sub 3} molecules [the 9R(30) laser line] or with {sup 15}NH{sub 3} molecules [the 9R(10) laser line]. Isotopic mixtures containing 4.8% and 0.37% (natural content) of the {sup 15}NH isotope were investigated. The dependences of the selectivity and the dissociation yield for each isotopic component on the buffer gas pressure (N{sub 2}, O{sub 2}, Ar) and the ammonia pressure were obtained. In the limit of low NH{sub 3} pressures (0.5-2 Torr), the dissociation selectivity {alpha}(15/14) for {sup 15}N was 17. The selectivity mechanism of the IR+UV dissociation is discussed and the outlook is considered for the development of the nitrogen isotope separation process based on this approach. (laser isotope separation)

  20. Observation of second spin reorientation transition within ultrathin region in Fe films on Ag(001) surface

    SciTech Connect

    Khim, T.-Y.; Shin, M.; Lee, H. E-mail: jhp@postech.ac.kr; Park, B.-G.; Park, J.-H. E-mail: jhp@postech.ac.kr

    2014-06-21

    We acquired direct measurements for in-plane and perpendicular-to-plane magnetic moments of Fe films using an x-ray magnetic circular dichroism technique with increase of the Fe thickness (up to 40 Å) on the Ag(001) surface. Epitaxial Fe/Ag(001) films were grown in situ with the thickness varying from 2 Å to 40 Å, and the magnetic anisotropy was carefully investigated as a function of the film thickness. We found re-entrance of the in-plane magnetic anisotropy of the Fe film in ultrathin region. The results manifest that the epitaxial Fe/Ag(001) film undergoes two distinct spin reorientation transitions from in-plane to out-of-plane at the film thickness t ≈ 9 Å and back to in-plane at t ≈ 18 Å as t increases.

  1. Formation mechanism and properties of CdS-Ag2S nanorod superlattices

    SciTech Connect

    Wang, Lin-Wang; Demchenko, Denis O.; Robinson, Richard D.; Sadtler, Bryce; Erdonmez, Can K.; Alivisatos, A. Paul; Wang, Lin-Wang

    2008-08-11

    The mechanism of formation of recently fabricated CdS-Ag{sub 2}S nanorod superlattices is considered and their elastic properties are predicted theoretically based on experimental structural data. We consider different possible mechanisms for the spontaneous ordering observed in these 1D nanostructures, such as diffusion-limited growth and ordering due to epitaxial strain. A simplified model suggests that diffusion-limited growth partially contributes to the observed ordering, but cannot account for the full extent of the ordering alone. The elastic properties of bulk Ag{sub 2}S are predicted using a first principles method and are fed into a classical valence force field (VFF) model of the nanostructure. The VFF results show significant repulsion between Ag{sub 2}S segments, strongly suggesting that the interplay between the chemical interface energy and strain due to the lattice mismatch between the two materials drives the spontaneous pattern formation.

  2. Simulations of the infrared, Raman, and 2D-IR photon echo spectra of water in nanoscale silica pores

    DOE PAGES [OSTI]

    Burris, Paul C.; Laage, Damien; Thompson, Ward H.

    2016-05-20

    Vibrational spectroscopy is frequently used to characterize nanoconfined liquids and probe the effect of the confining framework on the liquid structure and dynamics relative to the corresponding bulk fluid. However, it is still unclear what molecular-level information can be obtained from such measurements. In this Paper, we address this question by using molecular dynamics (MD) simulations to reproduce the linear infrared (IR), Raman, and two-dimensional IR (2D-IR) photon echo spectra for water confined within hydrophilic (hydroxyl-terminated) silica mesopores. To simplify the spectra the OH stretching region of isotopically dilute HOD in D2O is considered. An empirical mapping approach is usedmore » to obtain the OH vibrational frequencies, transition dipoles, and transition polarizabilities from the MD simulations. The simulated linear IR and Raman spectra are in good general agreement with measured spectra of water in mesoporous silica reported in the literature. The key effect of confinement on the water spectrum is a vibrational blueshift for OH groups that are closest to the pore interface. The blueshift can be attributed to the weaker hydrogen bonds (H-bonds) formed between the OH groups and silica oxygen acceptors. Non-Condon effects greatly diminish the contribution of these OH moieties to the linear IR spectrum, but these weaker H-bonds are readily apparent in the Raman spectrum. The 2D-IR spectra have not yet been measured and thus the present results represent a prediction. Lastly, the simulated spectra indicate that it should be possible to probe the slower spectral diffusion of confined water compared to the bulk liquid by analysis of the 2D-IR spectra.« less

  3. Ag-Pd-Cu alloy inserted transparent indium tin oxide electrodes for organic solar cells

    SciTech Connect

    Kim, Hyo-Joong; Seo, Ki-Won; Kim, Han-Ki; Noh, Yong-Jin; Na, Seok-In

    2014-09-01

    The authors report on the characteristics of Ag-Pd-Cu (APC) alloy-inserted indium tin oxide (ITO) films sputtered on a glass substrate at room temperature for application as transparent anodes in organic solar cells (OSCs). The effect of the APC interlayer thickness on the electrical, optical, structural, and morphological properties of the ITO/APC/ITO multilayer were investigated and compared to those of ITO/Ag/ITO multilayer electrodes. At the optimized APC thickness of 8 nm, the ITO/APC/ITO multilayer exhibited a resistivity of 8.55 × 10{sup −5} Ω cm, an optical transmittance of 82.63%, and a figure-of-merit value of 13.54 × 10{sup −3} Ω{sup −1}, comparable to those of the ITO/Ag/ITO multilayer. Unlike the ITO/Ag/ITO multilayer, agglomeration of the metal interlayer was effectively relieved with APC interlayer due to existence of Pd and Cu elements in the thin region of the APC interlayer. The OSCs fabricated on the ITO/APC/ITO multilayer showed higher power conversion efficiency than that of OSCs prepared on the ITO/Ag/ITO multilayer below 10 nm due to the flatness of the APC layer. The improved performance of the OSCs with ITO/APC/ITO multilayer electrodes indicates that the APC alloy interlayer prevents the agglomeration of the Ag-based metal interlayer and can decrease the thickness of the metal interlayer in the oxide-metal-oxide multilayer of high-performance OSCs.

  4. In-situ TEM study of Cu-Ag nanoparticle thermal interaction. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Conference: In-situ TEM study of Cu-Ag nanoparticle thermal interaction. Citation Details In-Document Search Title: In-situ TEM study of Cu-Ag nanoparticle thermal interaction. Abstract not provided. Authors: Lu, Ping Publication Date: 2013-10-01 OSTI Identifier: 1113336 Report Number(s): SAND2013-8356C 476492 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the Rio Grande symposium held October 7, 2013

  5. Synthesis of highly efficient antibacterial agent Ag doped ZnO nanorods: Structural, Raman and optical properties

    SciTech Connect

    Jan, Tariq; Iqbal, Javed; Ismail, Muhammad; Mahmood, Arshad

    2014-04-21

    Here, synthesis, structural, morphological, Raman, optical properties and antibacterial activity of undoped and Ag doped ZnO nanorods by chemical co-precipitation technique have been reported. Structural analysis has revealed that Ag doping cannot deteriorate the structure of ZnO and wurtzite phase is maintained. Lattice constants are found to be decreased with the Ag doping. Fourier transform infrared and Raman spectroscopy also confirm the X-ray diffraction results. Scanning electron microscopy results have demonstrated the formation of ZnO nanorods with average diameter and length of 96 nm and 700 nm, respectively. Raman spectroscopy results suggest that the Ag doping enhances the number of defects in ZnO crystal. It has been found from optical study that Ag doping results in positional shift of band edge absorption peak. This is attributed to the successful incorporation of Ag dopant into ZnO host matrix. The antibacterial activity of prepared nanorods has been determined by two different methods and compared to that of undoped ZnO nanorods. Ag doped ZnO nanorods exhibit excellent antibacterial activity as compared to that of undoped ZnO nanorods. This excellent antibacterial activity may be attributed to the presence of oxygen vacancies and Zn{sup 2+} interstitial defects. Our preliminary findings suggest that Ag doped ZnO nanorods can be used externally to control the spreading of infections related with tested bacterial strains.

  6. Thermoelectric properties of p-type PbTe/Ag{sub 2}Te bulk composites by extrinsic phase mixing

    SciTech Connect

    Lee, Min Ho; Rhyee, Jong-Soo

    2015-12-15

    We investigated the thermoelectric properties of PbTe/Ag{sub 2}Te bulk composites, synthesized by hand milling, mixing, and hot press sintering. From x-ray diffraction and energy dispersive x-ray spectroscopy measurements, we observed Ag{sub 2}Te phase separation in the PbTe matrix without Ag atom diffusion. In comparison with previously reported pseudo-binary (PbTe){sub 1−x}(Ag{sub 2}Te){sub x} composites, synthesized by high temperature phase separation, the PbTe/Ag{sub 2}Te bulk composites fabricated with a low temperature phase mixing process give rise to p-type conduction of carriers with significantly decreased electrical conductivity. This indicates that Ag atom diffusion in the PbTe matrix changes the sign of the Seebeck coefficient to n-type and also increases the carrier concentration. Effective p-type doping with low temperature phase separation by mixing and hot press sintering can enhance the thermoelectric performance of PbTe/Ag{sub 2}Te bulk composites, which can be used as a p-type counterpart of n-type (PbTe){sub 1−x}(Ag{sub 2}Te){sub x} bulk composites.

  7. Element-specific study of epitaxial NiO/Ag/CoO/Fe films grown on vicinal Ag(001) using photoemission electron microscopy

    SciTech Connect

    Meng, Y.; Li, J.; Tan, A.; Jin, E.; Son, J.; Park, J. S.; Doran, A.; Young, A. T.; Scholl, A.; Arenholz, E.; Wu, J.; Hwang, C.; Zhao, H. W.; Qiu, Z. Q.

    2011-01-10

    NiO/Ag/CoO/Fe single crystalline films are grown epitaxially on a vicinal Ag(001) substrate using molecular beam epitaxy and investigated by photoemission electron microscopy. We find that after zero-field cooling, the in-plane Fe magnetization switches from parallel to perpendicular direction of the atomic steps of the vicinal surface at thinner CoO thickness but remains in its original direction parallel to the steps at thicker CoO thickness. CoO and NiO domain imaging result shows that both CoO/Fe and NiO/CoO spins are perpendicularly coupled, suggesting that the Fe magnetization switching may be associated with the rotatable-frozen spin transition of the CoO film.

  8. Thermoelectric transport of Se-rich Ag{sub 2}Se in normal phases and phase transitions

    SciTech Connect

    Mi, Wenlong; Lv, Yanhong; Qiu, Pengfei; Shi, Xun E-mail: cld@mail.sic.ac.cn; Chen, Lidong E-mail: cld@mail.sic.ac.cn; Zhang, Tiansong

    2014-03-31

    Small amount of Se atoms are used to tune the carrier concentrations (n{sub H}) and electrical transport in Ag{sub 2}Se. Significant enhancements in power factor and thermoelectric figure of merit (zT) are observed in the compositions of Ag{sub 2}Se{sub 1.06} and Ag{sub 2}Se{sub 1.08}. The excessive Se atoms do not change the intrinsically electron-conducting character in Ag{sub 2}Se. The detailed analysis reveals the experiment optimum carrier concentration in Ag{sub 2}Se is around 5 × 10{sup 18} cm{sup −3}. We also investigate the temperature of maximum zT and the thermoelectric transport during the first order phase transitions using the recently developed measurement system.

  9. New Mid-IR Lasers Based on Rare-Earth-Doped Sulfide and Chloride Materials

    SciTech Connect

    Nostrand, M

    2000-09-01

    Applications in remote-sensing and military countermeasures have driven a need for compact, solid-state mid-IR lasers. Due to multi-phonon quenching, non-traditional hosts are needed to extend current solid-state, room-temperature lasing capabilities beyond {approx} 4 {micro}m. Traditional oxide and fluoride hosts have effective phonon energies in the neighborhood of 1000 cm{sup -1} and 500 cm{sup -1}, respectively. These phonons can effectively quench radiation above 2 and 4 {micro}m, respectively. Materials with lower effective phonon energies such as sulfides and chlorides are the logical candidates for mid-IR (4-10 {micro}m) operation. In this report, laser action is demonstrated in two such hosts, CaGa{sub 2}S{sub 4} and KPb{sub 2}Cl{sub 5}. The CaGa{sub 2}S{sub 4}:Dy{sup 3+} laser operating at 4.3 {micro}m represents the first sulfide laser operating beyond 2 {micro}m. The KPb{sub 2}Cl{sub 5}:Dy{sup 3+} laser operating at 2.4 {micro}m represents the first operation of a chloride-host laser in ambient conditions. Laser action is also reported for CaGa{sub 2}S{sub 4}:Dy{sup 3+} at 2.4 {micro}m, CaGa{sub 2}S{sub 4}:Dy{sup 3+} at 1.4 {micro}m, and KPb{sub 2}Cl{sub 5}:Nd{sup 3+} at 1.06 {micro}m. Both host materials have been fully characterized, including lifetimes, absorption and emission cross sections, radiative branching ratios, and radiative quantum efficiencies. Radiative branching ratios and radiative quantum efficiencies have been determined both by the Judd-Ofelt method (which is based on absorption measurements), and by a novel method described herein which is based on emission measurements. Modeling has been performed to predict laser performance, and a new method to determine emission cross section from slope efficiency and threshold data is developed. With the introduction and laser demonstration of rare-earth-doped CaGa{sub 2}S{sub 4} and KPb{sub 2}Cl{sub 5}, direct generation of mid-IR laser radiation in a solid-state host has been demonstrated. In

  10. On the Relative Utility of Infrared (IR) versus Terahertz (THz) for Optical Sensors

    SciTech Connect

    Johnson, Timothy J.; Valentine, Nancy B.; Gassman, Paul L.; Atkinson, David A.; Sharpe, Steven W.; Williams, Stephen D.

    2007-11-30

    Pacific Northwest National Laboratory (PNNL) has active programs investigating the optical absorption strengths of several types of molecules including toxic industrial chemicals (TICs), microbiological threats such as bacteria, as well as explosives such as RDX, PETN and TNT. While most of our work has centered on the mid-infrared domain (600 to 6,500 cm-1), more recent work has also included work in the far-infrared, also called the terahertz (THz) region (500 to ~8 cm-1). Using Fourier transform infrared spectroscopy, we have been able to compare the relative, and in some cases absolute, IR/THz cross sections of a number of species in the solid and liquid phases. The relative band strengths of a number of species of interest are discussed in terms of both experimental and computational results.

  11. Graphene-silicon layered structures on single-crystalline Ir(111) thin films

    SciTech Connect

    Que, Yande D.; Tao, Jing; Zhang, Yong; Wang, Yeliang L.; Wu, Lijun J.; Zhu, Yimei M.; Kim, Kisslinger; Weinl, Michael; Schreck, Matthias; Shen, Chengmin M.; Du, Shixuan X.; Liu, Yunqi Q.; Gao, H. -J.; Huang, Li; Xu, Wenyan Y.

    2015-01-20

    Epitaxial growth of graphene on transition metal crystals, such as Ru,⁽¹⁻³⁾ Ir,⁽⁴⁻⁶⁾ and Ni,⁽⁷⁾ provides large-area, uniform graphene layers with controllable defect density, which is crucial for practical applications in future devices. To decrease the high cost of single-crystalline metal bulks, single-crystalline metal films are strongly suggested as the substrates for epitaxial growth large-scale high-quality graphene.⁽⁸⁻¹⁰⁾ Moreover, in order to weaken the interactions of graphene with its metal host, which may result in a suppression of the intrinsic properties of graphene,⁽¹¹ ¹²⁾ the method of element intercalation of semiconductors at the interface between an epitaxial graphene layer and a transition metal substrate has been successfully realized.⁽¹³⁻¹⁶⁾

  12. Graphene-silicon layered structures on single-crystalline Ir(111) thin films

    DOE PAGES [OSTI]

    Que, Yande D.; Tao, Jing; Zhang, Yong; Wang, Yeliang L.; Wu, Lijun J.; Zhu, Yimei M.; Kim, Kisslinger; Weinl, Michael; Schreck, Matthias; Shen, Chengmin M.; et al

    2015-01-20

    Epitaxial growth of graphene on transition metal crystals, such as Ru,⁽¹⁻³⁾ Ir,⁽⁴⁻⁶⁾ and Ni,⁽⁷⁾ provides large-area, uniform graphene layers with controllable defect density, which is crucial for practical applications in future devices. To decrease the high cost of single-crystalline metal bulks, single-crystalline metal films are strongly suggested as the substrates for epitaxial growth large-scale high-quality graphene.⁽⁸⁻¹⁰⁾ Moreover, in order to weaken the interactions of graphene with its metal host, which may result in a suppression of the intrinsic properties of graphene,⁽¹¹ ¹²⁾ the method of element intercalation of semiconductors at the interface between an epitaxial graphene layer and a transitionmore » metal substrate has been successfully realized.⁽¹³⁻¹⁶⁾« less

  13. DESIGN AND CONSTRUCTION OF A 15 T, 120 MM BORE IR QUADRUPOLE MAGNET FOR LARP

    SciTech Connect

    Caspi, S.; Cheng, D.; Dietderich, D.; Felice, H.; Ferracin, P.; Hafalia, R.; Hannaford, R.; Sabbi, G. S.; Anerella, M.; Ghosh, A.; Schmalzle, J.; Wanderer, P.; Ambrosio, G.; Bossert, R.; Kashikhin, V.; Pasholk, D.; Zlobin, A.

    2009-05-04

    Pushing accelerator magnets beyond 10 T holds a promise of future upgrades to machines like the Large Hadron Collider (LHC) at CERN. Nb{sub 3}Sn conductor is at the present time the only practical superconductor capable of generating fields beyond 10 T. In support of the LHC Phase-II upgrade, the US LHC Accelerator Research Program (LARP) is developing a large bore (120 mm) IR quadrupole (HQ) capable of reaching 15 T at its conductor peak field and a peak gradient of 219 T/m at 1.9 K. While exploring the magnet performance limits in terms of gradient, forces and stresses the 1 m long two-layer coil will demonstrate additional features such as alignment and accelerator field quality. In this paper we summarize the design and report on the magnet construction progress.

  14. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  15. Effect of Field Errors in Muon Collider IR Magnets on Beam Dynamics

    SciTech Connect

    Alexahin, Y.; Gianfelice-Wendt, E.; Kapin, V.V.; /Fermilab

    2012-05-01

    In order to achieve peak luminosity of a Muon Collider (MC) in the 10{sup 35} cm{sup -2}s{sup -1} range very small values of beta-function at the interaction point (IP) are necessary ({beta}* {le} 1 cm) while the distance from IP to the first quadrupole can not be made shorter than {approx}6 m as dictated by the necessity of detector protection from backgrounds. In the result the beta-function at the final focus quadrupoles can reach 100 km making beam dynamics very sensitive to all kind of errors. In the present report we consider the effects on momentum acceptance and dynamic aperture of multipole field errors in the body of IR dipoles as well as of fringe-fields in both dipoles and quadrupoles in the ase of 1.5 TeV (c.o.m.) MC. Analysis shows these effects to be strong but correctable with dedicated multipole correctors.

  16. In Situ Diffuse Reflectance IR Spectroscopy and X-ray Absorption Spectroscopy for Fast Catalytic Processes

    SciTech Connect

    N Marinkovic; Q Wang; A Frenkel

    2011-12-31

    A new instrument for synchronous in situ investigations of catalytic materials by IR and X-ray absorption spectroscopies was designed and built at the X18A beamline of the National Synchrotron Light Source of Brookhaven National Laboratory. It provides analytical tools for solving structural, electronic and kinetic problems in catalysis science by two complementary methods. Among the features attractive for catalysis research are the broad range of catalytically active elements that can be investigated (starting with Ni and beyond), the wide range of reaction conditions (temperatures up to 873 K, various reactive gases) and time scales (starting from tens of seconds). The results of several representative experiments that illustrate the attractive capabilities of the new set-up are discussed.

  17. Interaction of mineral surfaces with simple organci molecules by diffuse reflectance IR spectroscopy (DRIFT)

    SciTech Connect

    Joan Thomas; Michael Kelley

    2007-06-18

    Diffuse reflectance Fourier-transform infrared spectroscopy (DRIFTS) was used to characterize multi-layers of lysine, glutamic acid and salicylic acid on ?-alumina and kaolinite surfaces. The results agreed well with those previously obtained by ATR-IR in aqueous media where available, indicating that DRIFT may be regarded as effectively an in-situ spectroscopy for these materials. In the case of salicylic acid adsorption onto ?-alumina, DRIFTS was used to identify monolayer coverage and to detect molecules down to coverage of 3% of a monolayer. The spectroscopic results as to coverage were confirmed by analysis of the solutions used for treatment. The spectra obtained allowed identification of changes in the bonding environment with increasing surface coverage. DRIFTS, offers several advantages in terms of materials, experimental technique and data treatment, motivating further investigations.

  18. Synthesis, phase relationship and crystal structure of the new binary compound Ir{sub 13}Al{sub 45}

    SciTech Connect

    Bostroem, Magnus . E-mail: bostroem@cpfs.mpg.de; Niewa, Rainer; Prots, Yurii; Grin, Yuri

    2005-01-15

    The new phase Ir{sub 13}Al{sub 45} was synthesized in equilibrium with an aluminum-rich melt. Its crystal structure was established from single-crystal diffraction data. The compound crystallizes in the space group Pnma and represents a novel structure type (Pearson symbol oP232, a=16.760(2)A, b=12.321(1)A, c=17.425(2)A). The structure can essentially be described as a simple hexagonal column packing of pseudopentagonal columns formed by irregular Al polyhedra centered by Ir atoms. Ir{sub 13}Al{sub 45} forms peritectically at 895 deg. C and exists in equilibrium with the melt in a narrow temperature interval of 19 deg. C.

  19. Structure symmetry determination and magnetic evolution in Sr2Ir1–xRhxO4

    SciTech Connect

    Ye, Feng; Wang, Xiaoping; Hoffmann, Christina; Wang, Jinchen; Chi, Songxue; Matsuda, Masaaki; Chakoumakos, Bryan C.; Fernandez-Baca, Jaime A.; Cao, Gang

    2015-11-23

    We use single-crystal neutron diffraction to determine the crystal structure symmetry and to study the magnetic evolution in the rhodium doped iridates Sr2Ir1–xRhxO4 (0 ≤ x ≤ 0.16). Throughout this doping range, the crystal structure retains a tetragonal symmetry (space group I41/a) with two distinct magnetic Ir sites in the unit cell forming staggered IrO6 rotation. Upon Rh doping, the magnetic order is suppressed and the magnetic moment of Ir4+ is reduced from 0.21 μB/Ir for x = 0 to 0.18 μB/Ir for x = 0.12. As a result, the magnetic structure at x = 0.12 is different from that of the parent compound while the moments remain in the basal plane.

  20. Spitzer mid-IR spectroscopy of powerful 2Jy and 3CRR radio galaxies. II. AGN power indicators and unification

    SciTech Connect

    Dicken, D.; Tadhunter, C.; Morganti, R.; Axon, D.; Robinson, A.; Magagnoli, M.; Kharb, P.; Ramos Almeida, C.; Hardcastle, M.; Nesvadba, N. P. H.; Singh, V.; Kouwenhoven, M. B. N.; Rose, M.; Spoon, H.; Inskip, K. J.; Holt, J.

    2014-06-20

    It remains uncertain which continuum and emission line diagnostics best indicate the bolometric powers of active galactic nuclei (AGNs), especially given the attenuation caused by the circumnuclear material and the possible contamination by components related to star formation. Here we use mid-IR spectra along with multiwavelength data to investigate the merit of various diagnostics of AGN radiative power, including the mid-IR [Ne III] ?25.89 ?m and [O IV] ?25.89 ?m fine-structure lines, the optical [O III] ?5007 forbidden line, and mid-IR 24 ?m, 5 GHz radio, and X-ray continuum emission, for complete samples of 46 2Jy radio galaxies (0.05 < z < 0.7) and 17 3CRR FRII radio galaxies (z < 0.1). We find that the mid-IR [O IV] line is the most reliable indicator of AGN power for powerful radio-loud AGNs. By assuming that the [O IV] is emitted isotropically, and comparing the [O III] and 24 ?m luminosities of the broad- and narrow-line AGNs in our samples at fixed [O IV] luminosity, we show that the [O III] and 24 ?m emission are both mildly attenuated in the narrow-line compared to the broad-line objects by a factor of ?2. However, despite this attenuation, the [O III] and 24 ?m luminosities are better AGN power indicators for our sample than either the 5 GHz radio or the X-ray continuum luminosities. We also detect the mid-IR 9.7 ?m silicate feature in the spectra of many objects but not ubiquitously: at least 40% of the sample shows no clear evidence for these features. We conclude that, for the majority of powerful radio galaxies, the mid-IR lines are powered by AGN photoionization.