You need JavaScript to view this

Sensitive method for continuous air monitoring for /sup 14/C and /sup 3/H. Empfindliches verfahren zur koninuierlichen C-14 und H-3 luftueberwachung

Abstract

In the monitoring of air for /sup 14/C and /sup 3/H the necessary sensitivity cannot be achieved by direct measurement, but only through continuous sampling and scintillation spectroscopy. The two radionuclides are separated from each other at the time of sampling. In addition, by a catalytic reaction over CuO at 600/sup 0/C, a differentiation is achieved between tritiated atmospheric water vapor (HTO), /sup 14/CO/sub 2/ and other isotopically labeled substances contained in the air. Tritium is obtained in the form of water and /sup 14/C as Na/sub 2//sup 14/CO/sub 3/. Radioactivity is measured in a scintillation spectrometer. For tritium this method has a detection limit of 0.8 pCi/m/sup 3/ or air, and for C/sup 14/ 0.6 pCi/m/sup 3/ of air. These values correspond to 15 to 30% of the mean background concentration for HTO and /sup 14/CO/sub 2/ observed up to the present.
Publication Date:
Jul 01, 1976
Product Type:
Miscellaneous
Report Number:
MLM-2441(TR)
Reference Number:
ERA-02-057374; NTS-77-000041; EDB-77-128748
Resource Relation:
Related Information: TN: Translated from the German journal article Atomwirtschaft, Vol. 21, No. 9-10, pp 485-488, 1976. CODEN: AWAKA, Country of intellectual origin: Germany, Federal Republic of. Translation funded by US ERDA, Mound Laboratory
Subject:
54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CARBON 14; RADIATION MONITORING; SURFACE AIR; TRITIUM; LOW DOSE IRRADIATION; RADIOACTIVITY; SCINTILLATION COUNTERS; SPECTROSCOPY; AIR; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CARBON ISOTOPES; EVEN-EVEN NUCLEI; FLUIDS; GASES; HYDROGEN ISOTOPES; IRRADIATION; ISOTOPES; LIGHT NUCLEI; MEASURING INSTRUMENTS; MONITORING; NUCLEI; ODD-EVEN NUCLEI; RADIATION DETECTORS; RADIOISOTOPES; YEARS LIVING RADIOISOTOPES; 500300* - Environment, Atmospheric- Radioactive Materials Monitoring & Transport- (-1989); 400103 - Radiometric & Radiochemical Procedures- (-1987)
OSTI ID:
8181341
Research Organizations:
Institute for Environmental Physics, Univ. of Heidelberg (Germany)
Country of Origin:
Germany
Language:
English
Contract Number:
EY-76-C-04-0053
Submitting Site:
TIC
Size:
16 pages
Announcement Date:
Oct 01, 1977

Citation Formats

Rudolph, J., and Weiss, W. Sensitive method for continuous air monitoring for /sup 14/C and /sup 3/H. Empfindliches verfahren zur koninuierlichen C-14 und H-3 luftueberwachung. Germany: N. p., 1976. Web.
Rudolph, J., & Weiss, W. Sensitive method for continuous air monitoring for /sup 14/C and /sup 3/H. Empfindliches verfahren zur koninuierlichen C-14 und H-3 luftueberwachung. Germany.
Rudolph, J., and Weiss, W. 1976. "Sensitive method for continuous air monitoring for /sup 14/C and /sup 3/H. Empfindliches verfahren zur koninuierlichen C-14 und H-3 luftueberwachung." Germany.
@misc{etde_8181341,
title = {Sensitive method for continuous air monitoring for /sup 14/C and /sup 3/H. Empfindliches verfahren zur koninuierlichen C-14 und H-3 luftueberwachung}
author = {Rudolph, J., and Weiss, W.}
abstractNote = {In the monitoring of air for /sup 14/C and /sup 3/H the necessary sensitivity cannot be achieved by direct measurement, but only through continuous sampling and scintillation spectroscopy. The two radionuclides are separated from each other at the time of sampling. In addition, by a catalytic reaction over CuO at 600/sup 0/C, a differentiation is achieved between tritiated atmospheric water vapor (HTO), /sup 14/CO/sub 2/ and other isotopically labeled substances contained in the air. Tritium is obtained in the form of water and /sup 14/C as Na/sub 2//sup 14/CO/sub 3/. Radioactivity is measured in a scintillation spectrometer. For tritium this method has a detection limit of 0.8 pCi/m/sup 3/ or air, and for C/sup 14/ 0.6 pCi/m/sup 3/ of air. These values correspond to 15 to 30% of the mean background concentration for HTO and /sup 14/CO/sub 2/ observed up to the present.}
place = {Germany}
year = {1976}
month = {Jul}
}