Abstract
A study is made to determine the catalytic actions and changes in grain size and surface area of various iron compound catalysts used for hydrogenation of phenanthrene. Effects of oxygen-containing compounds on the reaction are also investigated. Reactions of phenanthrene or CLB samples are performed in decalin or 1-methylnaphthalene as solvent. The solid reaction residue, including the catalyst used, is filtered and washed in acetone to provide specimens for SEM, surface area measurement (BET) and XRD. Three of the iron catalysts examined, CGS, FE(CO)/sub 5/ and FeS/sub 2/, are found to be highly effective for both phenanthrene hydrogenation and CLB decomposition, while Fe/sub 3/C does not work effectively for either of them. Fe (zero valene) and Fe/sub 2/O/sub 3/ are found effective for phenanthrene hydrogenation but not for CLB decomposition. (7 tabs)
Citation Formats
Tamura, Tomoyuki, Ogata, Eisuke, and Kamiya, Yoshio.
Studies of coal liquefaction (50). Catalysis of iron compounds.
Japan: N. p.,
1956.
Web.
Tamura, Tomoyuki, Ogata, Eisuke, & Kamiya, Yoshio.
Studies of coal liquefaction (50). Catalysis of iron compounds.
Japan.
Tamura, Tomoyuki, Ogata, Eisuke, and Kamiya, Yoshio.
1956.
"Studies of coal liquefaction (50). Catalysis of iron compounds."
Japan.
@misc{etde_7969190,
title = {Studies of coal liquefaction (50). Catalysis of iron compounds}
author = {Tamura, Tomoyuki, Ogata, Eisuke, and Kamiya, Yoshio}
abstractNote = {A study is made to determine the catalytic actions and changes in grain size and surface area of various iron compound catalysts used for hydrogenation of phenanthrene. Effects of oxygen-containing compounds on the reaction are also investigated. Reactions of phenanthrene or CLB samples are performed in decalin or 1-methylnaphthalene as solvent. The solid reaction residue, including the catalyst used, is filtered and washed in acetone to provide specimens for SEM, surface area measurement (BET) and XRD. Three of the iron catalysts examined, CGS, FE(CO)/sub 5/ and FeS/sub 2/, are found to be highly effective for both phenanthrene hydrogenation and CLB decomposition, while Fe/sub 3/C does not work effectively for either of them. Fe (zero valene) and Fe/sub 2/O/sub 3/ are found effective for phenanthrene hydrogenation but not for CLB decomposition. (7 tabs)}
place = {Japan}
year = {1956}
month = {Oct}
}
title = {Studies of coal liquefaction (50). Catalysis of iron compounds}
author = {Tamura, Tomoyuki, Ogata, Eisuke, and Kamiya, Yoshio}
abstractNote = {A study is made to determine the catalytic actions and changes in grain size and surface area of various iron compound catalysts used for hydrogenation of phenanthrene. Effects of oxygen-containing compounds on the reaction are also investigated. Reactions of phenanthrene or CLB samples are performed in decalin or 1-methylnaphthalene as solvent. The solid reaction residue, including the catalyst used, is filtered and washed in acetone to provide specimens for SEM, surface area measurement (BET) and XRD. Three of the iron catalysts examined, CGS, FE(CO)/sub 5/ and FeS/sub 2/, are found to be highly effective for both phenanthrene hydrogenation and CLB decomposition, while Fe/sub 3/C does not work effectively for either of them. Fe (zero valene) and Fe/sub 2/O/sub 3/ are found effective for phenanthrene hydrogenation but not for CLB decomposition. (7 tabs)}
place = {Japan}
year = {1956}
month = {Oct}
}