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Investigation into chemism of multivalent element ions reactions with organic reagents. XXXII. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine

Abstract

Spectrophotometric investigations have been made in to the interaction of indium with alizarin red S (alizarin-3-sulphonic acid) when extracting it with chloroform. The complex is extracted as an ion association with diphenylguanidine, in which the ratio In:Aliz:DPG = 1:3:3. The central ion In/sup 3 +/ substitutes three protons in three particles of the ligand. The structure of the complex being extracted is discussed. Molar absorbancy index of the complex in the chloroform extract (2.8x10/sup 4/) is twice as great as in the aqueous solution. The effect of the pH value on the formation of the indium complexes extracted is studied.
Authors:
Biryuk, E A; Nazarenko, V A; [1]  AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii)
  1. AN Ukrainskoj SSR, Kiev. Inst. Obshchej i Neorganicheskoj Khimii
Publication Date:
Sep 01, 1975
Product Type:
Journal Article
Reference Number:
AIX-07-272291; EDB-77-031336
Resource Relation:
Journal Name: Zh. Anal. Khim.; (USSR); Journal Volume: 30:9; Other Information: For English translation see the journal J. Anal. Chem. USSR
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; INDIUM; SOLVENT EXTRACTION; INDIUM COMPLEXES; ALIZARIN; ANTHRAQUINONES; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; CHLOROFORM; GUANIDINES; INDIUM COMPOUNDS; MOLECULAR STRUCTURE; PH VALUE; SPECTROPHOTOMETRY; SULFONIC ACIDS; AROMATICS; CARBONIC ACID DERIVATIVES; CHLORINATED ALIPHATIC HYDROCARBONS; COMPLEXES; DYES; ELEMENTS; EXTRACTION; HALOGENATED ALIPHATIC HYDROCARBONS; HYDROXY COMPOUNDS; KINETICS; METALS; ORGANIC ACIDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; QUINONES; REACTION KINETICS; REAGENTS; SEPARATION PROCESSES; 400105* - Separation Procedures
OSTI ID:
7326914
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZAKHA
Submitting Site:
INIS
Size:
Pages: 1720-1723
Announcement Date:
Dec 01, 1976

Citation Formats

Biryuk, E A, Nazarenko, V A, and AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii). Investigation into chemism of multivalent element ions reactions with organic reagents. XXXII. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine. USSR: N. p., 1975. Web.
Biryuk, E A, Nazarenko, V A, & AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii). Investigation into chemism of multivalent element ions reactions with organic reagents. XXXII. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine. USSR.
Biryuk, E A, Nazarenko, V A, and AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii). 1975. "Investigation into chemism of multivalent element ions reactions with organic reagents. XXXII. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine." USSR.
@misc{etde_7326914,
title = {Investigation into chemism of multivalent element ions reactions with organic reagents. XXXII. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine}
author = {Biryuk, E A, Nazarenko, V A, and AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii)}
abstractNote = {Spectrophotometric investigations have been made in to the interaction of indium with alizarin red S (alizarin-3-sulphonic acid) when extracting it with chloroform. The complex is extracted as an ion association with diphenylguanidine, in which the ratio In:Aliz:DPG = 1:3:3. The central ion In/sup 3 +/ substitutes three protons in three particles of the ligand. The structure of the complex being extracted is discussed. Molar absorbancy index of the complex in the chloroform extract (2.8x10/sup 4/) is twice as great as in the aqueous solution. The effect of the pH value on the formation of the indium complexes extracted is studied.}
journal = []
volume = {30:9}
journal type = {AC}
place = {USSR}
year = {1975}
month = {Sep}
}