Abstract
Following previously reported work (Peterson et al. J. Phys. Chem.; 71: 4506 (1967)) on the radiolysis of triphenyl stibine in benzene from which it was concluded that the energy is absorbed by benzene and excited benzene molecules transfer their energy to the metal phenyl which does not decompose due to quenching and since benzene is a protective agent for cyclohexane against ..gamma.. radiation, a system consisting of benzene, cyclohexane and triphenyl stibine has been used to study the energy transfer processes and the nature of protection. It was found that /sup 60/C0 ..gamma.. radiolysis of cyclohexane in presence of 1 x 10/sup -2/M triphenyl stibine formed two isomers of pentane and hexane and hexene, methylcyclopentane, benzene and cyclohexene. G values of these products, except those of hexene and methylcyclopentane are negligible. All products except these two are eliminated in the radiolysis of this system in presence of benzene. G values of these products are reduced considerably. The mechanism of formation of these compounds and a sponge type protection have been postulated to explain the results.
Citation Formats
Nazir, S B, and Rai, R S.
Radiation chemistry of a mixture of benzene and cyclohexane in presence of triphenyl stibine.
United Kingdom: N. p.,
1976.
Web.
doi:10.1016/0020-708X(76)90067-3.
Nazir, S B, & Rai, R S.
Radiation chemistry of a mixture of benzene and cyclohexane in presence of triphenyl stibine.
United Kingdom.
https://doi.org/10.1016/0020-708X(76)90067-3
Nazir, S B, and Rai, R S.
1976.
"Radiation chemistry of a mixture of benzene and cyclohexane in presence of triphenyl stibine."
United Kingdom.
https://doi.org/10.1016/0020-708X(76)90067-3.
@misc{etde_7326758,
title = {Radiation chemistry of a mixture of benzene and cyclohexane in presence of triphenyl stibine}
author = {Nazir, S B, and Rai, R S}
abstractNote = {Following previously reported work (Peterson et al. J. Phys. Chem.; 71: 4506 (1967)) on the radiolysis of triphenyl stibine in benzene from which it was concluded that the energy is absorbed by benzene and excited benzene molecules transfer their energy to the metal phenyl which does not decompose due to quenching and since benzene is a protective agent for cyclohexane against ..gamma.. radiation, a system consisting of benzene, cyclohexane and triphenyl stibine has been used to study the energy transfer processes and the nature of protection. It was found that /sup 60/C0 ..gamma.. radiolysis of cyclohexane in presence of 1 x 10/sup -2/M triphenyl stibine formed two isomers of pentane and hexane and hexene, methylcyclopentane, benzene and cyclohexene. G values of these products, except those of hexene and methylcyclopentane are negligible. All products except these two are eliminated in the radiolysis of this system in presence of benzene. G values of these products are reduced considerably. The mechanism of formation of these compounds and a sponge type protection have been postulated to explain the results.}
doi = {10.1016/0020-708X(76)90067-3}
journal = []
volume = {27:8}
journal type = {AC}
place = {United Kingdom}
year = {1976}
month = {Aug}
}
title = {Radiation chemistry of a mixture of benzene and cyclohexane in presence of triphenyl stibine}
author = {Nazir, S B, and Rai, R S}
abstractNote = {Following previously reported work (Peterson et al. J. Phys. Chem.; 71: 4506 (1967)) on the radiolysis of triphenyl stibine in benzene from which it was concluded that the energy is absorbed by benzene and excited benzene molecules transfer their energy to the metal phenyl which does not decompose due to quenching and since benzene is a protective agent for cyclohexane against ..gamma.. radiation, a system consisting of benzene, cyclohexane and triphenyl stibine has been used to study the energy transfer processes and the nature of protection. It was found that /sup 60/C0 ..gamma.. radiolysis of cyclohexane in presence of 1 x 10/sup -2/M triphenyl stibine formed two isomers of pentane and hexane and hexene, methylcyclopentane, benzene and cyclohexene. G values of these products, except those of hexene and methylcyclopentane are negligible. All products except these two are eliminated in the radiolysis of this system in presence of benzene. G values of these products are reduced considerably. The mechanism of formation of these compounds and a sponge type protection have been postulated to explain the results.}
doi = {10.1016/0020-708X(76)90067-3}
journal = []
volume = {27:8}
journal type = {AC}
place = {United Kingdom}
year = {1976}
month = {Aug}
}