Abstract
Recently some uranium tetrachloride adducts with N-(hydroxyphenyl)-salicylaldimine and N-(methoxyphenyl)salicylaldimine have been prepared (Doretti et al., J. Inorg. Nucl. Chem., (in press)): the study has now extended to the complexes of Uranium(IV) and Thorium(IV) with N,N'-Ethylenebis(salicylideneimine), H/sub 2/salen, and N,N'-Propylenebis(salicylideneimine), H/sub 2/salpropen, with the aim to prepare fully substituted complexes, mixed complexes containing both chloride and Schiff base groups and adducts of tetrachlorides with free Schiff bases. This paper reports the preparation and properties of the compounds MCl/sub 4/(H/sub 2/salen), MCl/sub 4/(H/sub 2/salpropen), M(salen)Cl/sub 2/, M(salen)/sub 2/ and M(salpropen)/sub 2/, where M = U or Th. These compounds have been characterized by elemental analyses and their IR spectra are reported and discussed.
Doretti, L;
Madalosso, F;
Sitran, S;
Faleschini, S
[1]
- Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
Citation Formats
Doretti, L, Madalosso, F, Sitran, S, and Faleschini, S.
Mixed complexes of uranium(IV) and thorium(IV) with N,N'-ethylenebis(salicylideneimine) and N,N'-propylenebis(salicylideneimine).
United Kingdom: N. p.,
1976.
Web.
doi:10.1016/0020-1650(76)80073-6.
Doretti, L, Madalosso, F, Sitran, S, & Faleschini, S.
Mixed complexes of uranium(IV) and thorium(IV) with N,N'-ethylenebis(salicylideneimine) and N,N'-propylenebis(salicylideneimine).
United Kingdom.
https://doi.org/10.1016/0020-1650(76)80073-6
Doretti, L, Madalosso, F, Sitran, S, and Faleschini, S.
1976.
"Mixed complexes of uranium(IV) and thorium(IV) with N,N'-ethylenebis(salicylideneimine) and N,N'-propylenebis(salicylideneimine)."
United Kingdom.
https://doi.org/10.1016/0020-1650(76)80073-6.
@misc{etde_7321464,
title = {Mixed complexes of uranium(IV) and thorium(IV) with N,N'-ethylenebis(salicylideneimine) and N,N'-propylenebis(salicylideneimine)}
author = {Doretti, L, Madalosso, F, Sitran, S, and Faleschini, S}
abstractNote = {Recently some uranium tetrachloride adducts with N-(hydroxyphenyl)-salicylaldimine and N-(methoxyphenyl)salicylaldimine have been prepared (Doretti et al., J. Inorg. Nucl. Chem., (in press)): the study has now extended to the complexes of Uranium(IV) and Thorium(IV) with N,N'-Ethylenebis(salicylideneimine), H/sub 2/salen, and N,N'-Propylenebis(salicylideneimine), H/sub 2/salpropen, with the aim to prepare fully substituted complexes, mixed complexes containing both chloride and Schiff base groups and adducts of tetrachlorides with free Schiff bases. This paper reports the preparation and properties of the compounds MCl/sub 4/(H/sub 2/salen), MCl/sub 4/(H/sub 2/salpropen), M(salen)Cl/sub 2/, M(salen)/sub 2/ and M(salpropen)/sub 2/, where M = U or Th. These compounds have been characterized by elemental analyses and their IR spectra are reported and discussed.}
doi = {10.1016/0020-1650(76)80073-6}
journal = []
volume = {12:10}
journal type = {AC}
place = {United Kingdom}
year = {1976}
month = {Jan}
}
title = {Mixed complexes of uranium(IV) and thorium(IV) with N,N'-ethylenebis(salicylideneimine) and N,N'-propylenebis(salicylideneimine)}
author = {Doretti, L, Madalosso, F, Sitran, S, and Faleschini, S}
abstractNote = {Recently some uranium tetrachloride adducts with N-(hydroxyphenyl)-salicylaldimine and N-(methoxyphenyl)salicylaldimine have been prepared (Doretti et al., J. Inorg. Nucl. Chem., (in press)): the study has now extended to the complexes of Uranium(IV) and Thorium(IV) with N,N'-Ethylenebis(salicylideneimine), H/sub 2/salen, and N,N'-Propylenebis(salicylideneimine), H/sub 2/salpropen, with the aim to prepare fully substituted complexes, mixed complexes containing both chloride and Schiff base groups and adducts of tetrachlorides with free Schiff bases. This paper reports the preparation and properties of the compounds MCl/sub 4/(H/sub 2/salen), MCl/sub 4/(H/sub 2/salpropen), M(salen)Cl/sub 2/, M(salen)/sub 2/ and M(salpropen)/sub 2/, where M = U or Th. These compounds have been characterized by elemental analyses and their IR spectra are reported and discussed.}
doi = {10.1016/0020-1650(76)80073-6}
journal = []
volume = {12:10}
journal type = {AC}
place = {United Kingdom}
year = {1976}
month = {Jan}
}