Abstract
By electron spectroscopy accurate values have been determined for the neon 1s ionization potential (870.312 +- .017 eV) and the neon Auger (/sup 1/D/sub 2/) kinetic energy (804.557 +- .017 eV). Using these together with the neon 2s ionization potential for calibration, 1s ionization potentials have been determined for CF/sub 4/ (C = 301.96, F = 695.57), CO/sub 2/ (C = 297.71, O = 541.32), N/sub 2/ (N = 409.93) and ionization potentials for Ar (2s = 326.37, 2p/sub /sup 3///sub 2// = 248.60, 2p/sub /sup 1///sub 2// = 250.70). These are known with an accuracy of 0.05 eV. The results are in good agreement with those of other measurements but have significantly smaller uncertainties. Comparison is made between experimental and theoretical ionization potentials. The value for neon is quite close to a recently reported theoretical value of 870.0 eV. The relativistic corrections for a cylindrical mirror analyzer, which are much smaller at low energies than would be expected from an approximate formula, are discussed.
Citation Formats
Thomas, T D, and Shaw, Jr, R W.
Accurate core ionization potentials and photoelectron kinetic energies for light elements.
Netherlands: N. p.,
1974.
Web.
doi:10.1016/0368-2048(74)85066-8.
Thomas, T D, & Shaw, Jr, R W.
Accurate core ionization potentials and photoelectron kinetic energies for light elements.
Netherlands.
https://doi.org/10.1016/0368-2048(74)85066-8
Thomas, T D, and Shaw, Jr, R W.
1974.
"Accurate core ionization potentials and photoelectron kinetic energies for light elements."
Netherlands.
https://doi.org/10.1016/0368-2048(74)85066-8.
@misc{etde_7313733,
title = {Accurate core ionization potentials and photoelectron kinetic energies for light elements}
author = {Thomas, T D, and Shaw, Jr, R W}
abstractNote = {By electron spectroscopy accurate values have been determined for the neon 1s ionization potential (870.312 +- .017 eV) and the neon Auger (/sup 1/D/sub 2/) kinetic energy (804.557 +- .017 eV). Using these together with the neon 2s ionization potential for calibration, 1s ionization potentials have been determined for CF/sub 4/ (C = 301.96, F = 695.57), CO/sub 2/ (C = 297.71, O = 541.32), N/sub 2/ (N = 409.93) and ionization potentials for Ar (2s = 326.37, 2p/sub /sup 3///sub 2// = 248.60, 2p/sub /sup 1///sub 2// = 250.70). These are known with an accuracy of 0.05 eV. The results are in good agreement with those of other measurements but have significantly smaller uncertainties. Comparison is made between experimental and theoretical ionization potentials. The value for neon is quite close to a recently reported theoretical value of 870.0 eV. The relativistic corrections for a cylindrical mirror analyzer, which are much smaller at low energies than would be expected from an approximate formula, are discussed.}
doi = {10.1016/0368-2048(74)85066-8}
journal = []
volume = {5}
journal type = {AC}
place = {Netherlands}
year = {1974}
month = {Jan}
}
title = {Accurate core ionization potentials and photoelectron kinetic energies for light elements}
author = {Thomas, T D, and Shaw, Jr, R W}
abstractNote = {By electron spectroscopy accurate values have been determined for the neon 1s ionization potential (870.312 +- .017 eV) and the neon Auger (/sup 1/D/sub 2/) kinetic energy (804.557 +- .017 eV). Using these together with the neon 2s ionization potential for calibration, 1s ionization potentials have been determined for CF/sub 4/ (C = 301.96, F = 695.57), CO/sub 2/ (C = 297.71, O = 541.32), N/sub 2/ (N = 409.93) and ionization potentials for Ar (2s = 326.37, 2p/sub /sup 3///sub 2// = 248.60, 2p/sub /sup 1///sub 2// = 250.70). These are known with an accuracy of 0.05 eV. The results are in good agreement with those of other measurements but have significantly smaller uncertainties. Comparison is made between experimental and theoretical ionization potentials. The value for neon is quite close to a recently reported theoretical value of 870.0 eV. The relativistic corrections for a cylindrical mirror analyzer, which are much smaller at low energies than would be expected from an approximate formula, are discussed.}
doi = {10.1016/0368-2048(74)85066-8}
journal = []
volume = {5}
journal type = {AC}
place = {Netherlands}
year = {1974}
month = {Jan}
}