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Photometric determination of zirconium in phosphorites by reaction with arsenazo III

Abstract

The reaction between zirconium and arsenazo III has been studied over a wide range of hydrochloric acid concentration and under different conditions. 6 and 9 M HCl solutions are optimal for determining zirconium; the least effect of phosphate ions and color stability in time are observed in this case. The determination of zirconium should be carried out using 10-fold reagent excess and in 15-20 min after adding the reagent. The interference of phosphate ions has been estimated. A procedure has been developed for photometric determination of zirconium in phosphorites with prior acid separation of soluble impurities.
Publication Date:
May 01, 1976
Product Type:
Journal Article
Reference Number:
AIX-08-309512; EDB-77-101084
Resource Relation:
Journal Name: Zh. Anal. Khim.; (USSR); Journal Volume: 31:5; Other Information: 2 refs., 5 figs., 2 tables; for English translation see the journal I. Anal. Chem. USSR
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ZIRCONIUM; SPECTROPHOTOMETRY; ABSORPTION SPECTRA; ARSENAZO; CHEMICAL PREPARATION; HYDROCHLORIC ACID; PHOSPHATES; PHOSPHORITES; ZIRCONIUM COMPLEXES; AROMATICS; ARSENIC COMPOUNDS; ARSONIC ACIDS; AZO COMPOUNDS; COMPLEXES; ELEMENTS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; INORGANIC ACIDS; METALS; MINERALS; ORGANIC ACIDS; ORGANIC ARSENIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHENOLS; PHOSPHORUS COMPOUNDS; POLYPHENOLS; REAGENTS; ROCKS; SEDIMENTARY ROCKS; SPECTRA; SULFONIC ACIDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS; 400104* - Spectral Procedures- (-1987)
OSTI ID:
7311324
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZAKHA
Submitting Site:
INIS
Size:
Pages: 892-896
Announcement Date:
Jun 01, 1977

Citation Formats

Nikol'skaya, I V, and Maksimov, A V. Photometric determination of zirconium in phosphorites by reaction with arsenazo III. USSR: N. p., 1976. Web.
Nikol'skaya, I V, & Maksimov, A V. Photometric determination of zirconium in phosphorites by reaction with arsenazo III. USSR.
Nikol'skaya, I V, and Maksimov, A V. 1976. "Photometric determination of zirconium in phosphorites by reaction with arsenazo III." USSR.
@misc{etde_7311324,
title = {Photometric determination of zirconium in phosphorites by reaction with arsenazo III}
author = {Nikol'skaya, I V, and Maksimov, A V}
abstractNote = {The reaction between zirconium and arsenazo III has been studied over a wide range of hydrochloric acid concentration and under different conditions. 6 and 9 M HCl solutions are optimal for determining zirconium; the least effect of phosphate ions and color stability in time are observed in this case. The determination of zirconium should be carried out using 10-fold reagent excess and in 15-20 min after adding the reagent. The interference of phosphate ions has been estimated. A procedure has been developed for photometric determination of zirconium in phosphorites with prior acid separation of soluble impurities.}
journal = []
volume = {31:5}
journal type = {AC}
place = {USSR}
year = {1976}
month = {May}
}