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Adsorption and catalytic properties of skeleton nickel alloyed by tantalum

Abstract

Adsorption properties are studied of Ni-Ta-catalysts composed of 20-50% Ni, 0-30% Ta, 50% Al with respect to hydrogen; their activity in a number of reactions has been tested. The adsorption capacity is characterized with respect to H/sub 2/ by the methods of thermodesorption and conductometry. It is shown that three forms to hydrogen (..beta.., ..gamma.., sigma) adsorb onto the surface of the alloyed catalysts, whose desorption peaks overlap because of their high mobility and interchangeability. Variation of activity, selectivity and isomerizing capacity of the catalysts correlates with the content of a weakly adsorbed mobile form of H/sub 2/.
Publication Date:
Feb 01, 1977
Product Type:
Journal Article
Reference Number:
AIX-08-336915; EDB-77-146778
Resource Relation:
Journal Name: Zh. Fiz. Khim.; (USSR); Journal Volume: 51:2
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM ALLOYS; SORPTIVE PROPERTIES; NICKEL ALLOYS; TANTALUM ALLOYS; ADSORBENTS; CATALYSTS; CATALYTIC EFFECTS; HYDROGEN; ALLOYS; CRYOGENIC FLUIDS; ELEMENTS; FLUIDS; NONMETALS; SURFACE PROPERTIES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
7214896
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZFKHA
Submitting Site:
INIS
Size:
Pages: 424-428
Announcement Date:
Oct 01, 1977

Citation Formats

Erzhanova, M S, Sokol'skii, D V, Popov, N I, and Kondratenko, V I. Adsorption and catalytic properties of skeleton nickel alloyed by tantalum. USSR: N. p., 1977. Web.
Erzhanova, M S, Sokol'skii, D V, Popov, N I, & Kondratenko, V I. Adsorption and catalytic properties of skeleton nickel alloyed by tantalum. USSR.
Erzhanova, M S, Sokol'skii, D V, Popov, N I, and Kondratenko, V I. 1977. "Adsorption and catalytic properties of skeleton nickel alloyed by tantalum." USSR.
@misc{etde_7214896,
title = {Adsorption and catalytic properties of skeleton nickel alloyed by tantalum}
author = {Erzhanova, M S, Sokol'skii, D V, Popov, N I, and Kondratenko, V I}
abstractNote = {Adsorption properties are studied of Ni-Ta-catalysts composed of 20-50% Ni, 0-30% Ta, 50% Al with respect to hydrogen; their activity in a number of reactions has been tested. The adsorption capacity is characterized with respect to H/sub 2/ by the methods of thermodesorption and conductometry. It is shown that three forms to hydrogen (..beta.., ..gamma.., sigma) adsorb onto the surface of the alloyed catalysts, whose desorption peaks overlap because of their high mobility and interchangeability. Variation of activity, selectivity and isomerizing capacity of the catalysts correlates with the content of a weakly adsorbed mobile form of H/sub 2/.}
journal = []
volume = {51:2}
journal type = {AC}
place = {USSR}
year = {1977}
month = {Feb}
}