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Electrical properties of V205-ZnO-TeO2 glasses. V205-ZnO-TeO2 kei garasu no denki dendo

Abstract

It is known that glasses contained Transition Metal Oxide (TMO) such as V2O5 show a semi-conductivity, those conductive mechanism has been understood according to the Small Polaron Hopping (SPH) theory developed by Mott and Austin. Authors investigated the glass formation regions, de-conductivity([sigma]) and the conductive mechanism for V2O5-Bi2O3-TeO2 glasses as a tellurite glass containing the TMO. It was clarified that the adiabatic SPH and the non-adiabatic SPH are satisfied for the glasses with V2O5>50 mol% and V2O5<50 mol%, respectively. In this study, the electrical properties of V2O5-ZnO-TeO2 glasses were investigated, and the SPH conductions were considered from the standpoints of the polaron band width J, carrier mobility [mu], carrier density Nc. The conductive mechanism and dependence of V2O5 density on Seebeck coefficients Q were clarified in which a formation region of V2O5 is from 30 to 60 mol%. 40 refs., 9 figs., 2 tabs.
Authors:
Mori, H; Igarashi, J; Sakata, H [1] 
  1. Tokai Univ., Tokyo (Japan). Faculty of Engineering
Publication Date:
Dec 01, 1993
Product Type:
Journal Article
Reference Number:
NEDO-94-910079; EDB-94-081971
Resource Relation:
Journal Name: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi (Journal of the Ceramic Society of Japan); (Japan); Journal Volume: 101:1180
Subject:
36 MATERIALS SCIENCE; ELECTRICAL PROPERTIES; TRANSITION ELEMENTS; GLASS; TELLURIUM OXIDES; VANADIUM OXIDES; ZINC OXIDES; POLARONS; BAND THEORY; CARRIER DENSITY; CARRIER MOBILITY; SEEBECK EFFECT; THERMOELECTRICITY; CHALCOGENIDES; ELECTRICITY; ELEMENTS; METALS; MOBILITY; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; QUASI PARTICLES; TELLURIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS; ZINC COMPOUNDS; 360204* - Ceramics, Cermets, & Refractories- Physical Properties
OSTI ID:
7207468
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Journal ID: ISSN 0914-5400; CODEN: NSKRE2
Submitting Site:
NEDO
Size:
Pages: 1351-1357
Announcement Date:
Jun 15, 1994

Citation Formats

Mori, H, Igarashi, J, and Sakata, H. Electrical properties of V205-ZnO-TeO2 glasses. V205-ZnO-TeO2 kei garasu no denki dendo. Japan: N. p., 1993. Web.
Mori, H, Igarashi, J, &amp; Sakata, H. Electrical properties of V205-ZnO-TeO2 glasses. V205-ZnO-TeO2 kei garasu no denki dendo. Japan.
Mori, H, Igarashi, J, and Sakata, H. 1993. "Electrical properties of V205-ZnO-TeO2 glasses. V205-ZnO-TeO2 kei garasu no denki dendo." Japan.
@misc{etde_7207468,
title = {Electrical properties of V205-ZnO-TeO2 glasses. V205-ZnO-TeO2 kei garasu no denki dendo}
author = {Mori, H, Igarashi, J, and Sakata, H}
abstractNote = {It is known that glasses contained Transition Metal Oxide (TMO) such as V2O5 show a semi-conductivity, those conductive mechanism has been understood according to the Small Polaron Hopping (SPH) theory developed by Mott and Austin. Authors investigated the glass formation regions, de-conductivity([sigma]) and the conductive mechanism for V2O5-Bi2O3-TeO2 glasses as a tellurite glass containing the TMO. It was clarified that the adiabatic SPH and the non-adiabatic SPH are satisfied for the glasses with V2O5>50 mol% and V2O5<50 mol%, respectively. In this study, the electrical properties of V2O5-ZnO-TeO2 glasses were investigated, and the SPH conductions were considered from the standpoints of the polaron band width J, carrier mobility [mu], carrier density Nc. The conductive mechanism and dependence of V2O5 density on Seebeck coefficients Q were clarified in which a formation region of V2O5 is from 30 to 60 mol%. 40 refs., 9 figs., 2 tabs.}
journal = []
volume = {101:1180}
journal type = {AC}
place = {Japan}
year = {1993}
month = {Dec}
}