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Rhodium trichloride as a homogeneous catalyst for isotopic hydrogen exchange. Comparison with heterogeneous rhodium in the deuteriation of aromatic compounds and alkanes

Journal Article:

Abstract

The use of rhodium trichloride as a homogeneous catalyst for the exchange of aromatic compounds and alkanes is described; comparison of the results with corresponding data from heterogeneous rhodium metal and other homogeneous systems, e.g., platinum and iridium, supports the proposal that specific type of ..pi..-complex mechanisms are common to all such exchange systems.
Authors:
Blake, M R; Garnett, J L; Gregor, I K; Hannan, W; Hoa, K; Long, M A [1] 
  1. New South Wales Univ., Kensington (Australia)
Publication Date:
Dec 03, 1975
Product Type:
Journal Article
Reference Number:
AIX-07-236084; EDB-76-092822
Resource Relation:
Journal Name: J. Chem. Soc. (London), Chem. Commun.; (United Kingdom); Journal Volume: 23
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DEUTERIUM; ISOTOPIC EXCHANGE; RHODIUM CHLORIDES; CATALYTIC EFFECTS; ALKANES; AROMATICS; CATALYSIS; CATALYSTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DEUTERIUM COMPOUNDS; HYDROGEN; CHLORIDES; CHLORINE COMPOUNDS; CRYOGENIC FLUIDS; ELEMENTS; FLUIDS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NONMETALS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; REACTION KINETICS; RHODIUM COMPOUNDS; STABLE ISOTOPES; TRANSITION ELEMENT COMPOUNDS; 400303* - Organic Chemistry- Isotope Exchange & Isotope Separation- (-1987)
OSTI ID:
7152598
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JCCCA
Submitting Site:
INIS
Size:
Pages: 930-932
Announcement Date:
Aug 01, 1976

Journal Article:

Citation Formats

Blake, M R, Garnett, J L, Gregor, I K, Hannan, W, Hoa, K, and Long, M A. Rhodium trichloride as a homogeneous catalyst for isotopic hydrogen exchange. Comparison with heterogeneous rhodium in the deuteriation of aromatic compounds and alkanes. United Kingdom: N. p., 1975. Web.
Blake, M R, Garnett, J L, Gregor, I K, Hannan, W, Hoa, K, & Long, M A. Rhodium trichloride as a homogeneous catalyst for isotopic hydrogen exchange. Comparison with heterogeneous rhodium in the deuteriation of aromatic compounds and alkanes. United Kingdom.
Blake, M R, Garnett, J L, Gregor, I K, Hannan, W, Hoa, K, and Long, M A. 1975. "Rhodium trichloride as a homogeneous catalyst for isotopic hydrogen exchange. Comparison with heterogeneous rhodium in the deuteriation of aromatic compounds and alkanes." United Kingdom.
@misc{etde_7152598,
title = {Rhodium trichloride as a homogeneous catalyst for isotopic hydrogen exchange. Comparison with heterogeneous rhodium in the deuteriation of aromatic compounds and alkanes}
author = {Blake, M R, Garnett, J L, Gregor, I K, Hannan, W, Hoa, K, and Long, M A}
abstractNote = {The use of rhodium trichloride as a homogeneous catalyst for the exchange of aromatic compounds and alkanes is described; comparison of the results with corresponding data from heterogeneous rhodium metal and other homogeneous systems, e.g., platinum and iridium, supports the proposal that specific type of ..pi..-complex mechanisms are common to all such exchange systems.}
journal = {J. Chem. Soc. (London), Chem. Commun.; (United Kingdom)}
volume = {23}
journal type = {AC}
place = {United Kingdom}
year = {1975}
month = {Dec}
}