Abstract
The employment of isotopic tracers is a useful technique for gaining insight into the rate controlling steps of a complex chemical reaction such as is frequently encountered in heterogeneous catalysis. An effective procedure has been to superpose tracer transfer on a reaction which is occurring under steady state conditions. If tracer transfer is employed in this fashion it is often possible to assess the individual step velocities in an assumed reaction mechanism. If transient transfer of tracer is now introduced it is possible in addition to estimate surface concentrations of chemisorbed species. The purpose of the present paper is to present the mathematical relationships involved when transfer of the tracer is not differential in the investigation. For this purpose a simple example is chosen to illustrate the various possibilities involved.
Happel, J
[1]
- Columbia Univ., New York (USA). Dept. of Chemical Engineering
Citation Formats
Happel, J.
Rate equations for tracer studies in recirculating reactors.
Japan: N. p.,
1974.
Web.
Happel, J.
Rate equations for tracer studies in recirculating reactors.
Japan.
Happel, J.
1974.
"Rate equations for tracer studies in recirculating reactors."
Japan.
@misc{etde_7142562,
title = {Rate equations for tracer studies in recirculating reactors}
author = {Happel, J}
abstractNote = {The employment of isotopic tracers is a useful technique for gaining insight into the rate controlling steps of a complex chemical reaction such as is frequently encountered in heterogeneous catalysis. An effective procedure has been to superpose tracer transfer on a reaction which is occurring under steady state conditions. If tracer transfer is employed in this fashion it is often possible to assess the individual step velocities in an assumed reaction mechanism. If transient transfer of tracer is now introduced it is possible in addition to estimate surface concentrations of chemisorbed species. The purpose of the present paper is to present the mathematical relationships involved when transfer of the tracer is not differential in the investigation. For this purpose a simple example is chosen to illustrate the various possibilities involved.}
journal = []
volume = {22:3}
journal type = {AC}
place = {Japan}
year = {1974}
month = {Oct}
}
title = {Rate equations for tracer studies in recirculating reactors}
author = {Happel, J}
abstractNote = {The employment of isotopic tracers is a useful technique for gaining insight into the rate controlling steps of a complex chemical reaction such as is frequently encountered in heterogeneous catalysis. An effective procedure has been to superpose tracer transfer on a reaction which is occurring under steady state conditions. If tracer transfer is employed in this fashion it is often possible to assess the individual step velocities in an assumed reaction mechanism. If transient transfer of tracer is now introduced it is possible in addition to estimate surface concentrations of chemisorbed species. The purpose of the present paper is to present the mathematical relationships involved when transfer of the tracer is not differential in the investigation. For this purpose a simple example is chosen to illustrate the various possibilities involved.}
journal = []
volume = {22:3}
journal type = {AC}
place = {Japan}
year = {1974}
month = {Oct}
}