Abstract
Vanadium exists in heavy oil as a chelate with mesoporphiline methyl ester, and the combustion ash of the oil may contain up to 80 percent of its oxides. Air is sampled in a standard way and to each 50 ml of the sample and blank solutions, add 5 ml of phosphoric acid and 2 ml of 10 percent ammonium sulfamate solution. After 10 min, the solution is titrated with potassium permanganate until it becomes purple. Two ml of hydrochloric acid and 10 ml of N-benzoylphenylhydroxylamine benzene solution are added and shaken for 30 sec. The benzene layer is washed with several portions of 2 ml HCl until no coloration of the HCl solution is visible. The benzene layer is transferred to a colorimetric tube and dried with granular calcium chloride. The absorbance is measured near 530 nm and the concentration is determined from a calibration curve previously prepared.
Citation Formats
Yoneyama, E, Sugano, S, and Fukui, S.
Air pollution test methods.
Japan: N. p.,
1974.
Web.
Yoneyama, E, Sugano, S, & Fukui, S.
Air pollution test methods.
Japan.
Yoneyama, E, Sugano, S, and Fukui, S.
1974.
"Air pollution test methods."
Japan.
@misc{etde_7077615,
title = {Air pollution test methods}
author = {Yoneyama, E, Sugano, S, and Fukui, S}
abstractNote = {Vanadium exists in heavy oil as a chelate with mesoporphiline methyl ester, and the combustion ash of the oil may contain up to 80 percent of its oxides. Air is sampled in a standard way and to each 50 ml of the sample and blank solutions, add 5 ml of phosphoric acid and 2 ml of 10 percent ammonium sulfamate solution. After 10 min, the solution is titrated with potassium permanganate until it becomes purple. Two ml of hydrochloric acid and 10 ml of N-benzoylphenylhydroxylamine benzene solution are added and shaken for 30 sec. The benzene layer is washed with several portions of 2 ml HCl until no coloration of the HCl solution is visible. The benzene layer is transferred to a colorimetric tube and dried with granular calcium chloride. The absorbance is measured near 530 nm and the concentration is determined from a calibration curve previously prepared.}
journal = []
volume = {20:3}
journal type = {AC}
place = {Japan}
year = {1974}
month = {Jun}
}
title = {Air pollution test methods}
author = {Yoneyama, E, Sugano, S, and Fukui, S}
abstractNote = {Vanadium exists in heavy oil as a chelate with mesoporphiline methyl ester, and the combustion ash of the oil may contain up to 80 percent of its oxides. Air is sampled in a standard way and to each 50 ml of the sample and blank solutions, add 5 ml of phosphoric acid and 2 ml of 10 percent ammonium sulfamate solution. After 10 min, the solution is titrated with potassium permanganate until it becomes purple. Two ml of hydrochloric acid and 10 ml of N-benzoylphenylhydroxylamine benzene solution are added and shaken for 30 sec. The benzene layer is washed with several portions of 2 ml HCl until no coloration of the HCl solution is visible. The benzene layer is transferred to a colorimetric tube and dried with granular calcium chloride. The absorbance is measured near 530 nm and the concentration is determined from a calibration curve previously prepared.}
journal = []
volume = {20:3}
journal type = {AC}
place = {Japan}
year = {1974}
month = {Jun}
}