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Analysis of paper machine process waters; Paperikoneen prosessivesianalytiikka - MPKT 09

Abstract

The closure of paper machine circuits demands a better knowledge of the chemical structures and behaviour of organic compounds in pulp mill process waters. Nonionic or negatively charged detrimental substances (anionic trash) which will eventually cause runnability. Paper quality problems are of special interest. The main purpose of the project was to develop routine `fingerprint` analytical procedures to study various process waters. Our major interest was focused on low molecular weight carboxylic acids, carbohydrates and lignin based material. The `fingerprints` (chromatograms and electropherograms) can be used to differentiate various process waters or to find out changes between the composition of organic compounds in various stages of the papermaking process. Until now the most characteristic `fingerprints` were obtained by capillary zone electrophoresis (CZE) and by pyrolysis - gas chromatography - mass spectrometry (Py-GC/MS). Examples of using these techniques are briefly discussed. (orig.)
Publication Date:
Dec 31, 1998
Product Type:
Technical Report
Report Number:
NEI-FI-362
Reference Number:
SCA: 320303; 400102; PA: FI-99:003387; SN: 99002156294
Resource Relation:
Other Information: PBD: 1998; Related Information: Is Part Of CACTUS technology programme. Yearbook 1998; Alakangas, E. [ed.]; PB: 300 p.
Subject:
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 40 CHEMISTRY; PAPER INDUSTRY; PAPER; PRODUCTION; WATER; CARBOXYLIC ACIDS; CARBOHYDRATES; LIGNIN; QUANTITATIVE CHEMICAL ANALYSIS; CAPILLARIES; ELECTROPHORESIS; GAS CHROMATOGRAPHY; MASS SPECTROSCOPY; COLLOIDS; BENCH-SCALE EXPERIMENTS
OSTI ID:
703389
Research Organizations:
VTT Energy, Jyvaeskylae (Finland)
Country of Origin:
Finland
Language:
Finnish
Other Identifying Numbers:
Other: ON: DE99771568; TRN: FI9903387
Availability:
OSTI as DE99771568
Submitting Site:
FI
Size:
pp. 139-149
Announcement Date:
Jan 25, 2004

Citation Formats

Knuutinen, J, Alen, R, Harjula, P, Kilpinen, J, Pallonen, R, and Jurvela, V. Analysis of paper machine process waters; Paperikoneen prosessivesianalytiikka - MPKT 09. Finland: N. p., 1998. Web.
Knuutinen, J, Alen, R, Harjula, P, Kilpinen, J, Pallonen, R, & Jurvela, V. Analysis of paper machine process waters; Paperikoneen prosessivesianalytiikka - MPKT 09. Finland.
Knuutinen, J, Alen, R, Harjula, P, Kilpinen, J, Pallonen, R, and Jurvela, V. 1998. "Analysis of paper machine process waters; Paperikoneen prosessivesianalytiikka - MPKT 09." Finland.
@misc{etde_703389,
title = {Analysis of paper machine process waters; Paperikoneen prosessivesianalytiikka - MPKT 09}
author = {Knuutinen, J, Alen, R, Harjula, P, Kilpinen, J, Pallonen, R, and Jurvela, V}
abstractNote = {The closure of paper machine circuits demands a better knowledge of the chemical structures and behaviour of organic compounds in pulp mill process waters. Nonionic or negatively charged detrimental substances (anionic trash) which will eventually cause runnability. Paper quality problems are of special interest. The main purpose of the project was to develop routine `fingerprint` analytical procedures to study various process waters. Our major interest was focused on low molecular weight carboxylic acids, carbohydrates and lignin based material. The `fingerprints` (chromatograms and electropherograms) can be used to differentiate various process waters or to find out changes between the composition of organic compounds in various stages of the papermaking process. Until now the most characteristic `fingerprints` were obtained by capillary zone electrophoresis (CZE) and by pyrolysis - gas chromatography - mass spectrometry (Py-GC/MS). Examples of using these techniques are briefly discussed. (orig.)}
place = {Finland}
year = {1998}
month = {Dec}
}