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Discovery of carbon nanotubes. Sara ni carbon nanotube e

Abstract

This paper describes the following matters on carbon nanotubes (CNt): CNt is discovered in carbon deposits generated in the tip of a negative electrode during DC arc discharge between carbon electrodes. CNt has a construction in which cylinders made of normally several layers are superposed, based on cylindrical crystals in a single layer with six-member rings of carbon atoms laid out. Spiral arrangement of carbon six-member rings has been discovered in the single-layered crystals. Five-member rings exist in a location where the CNt tip is closed, and seven-member rings in a location where the CNt presents a saddle-like curve, without exceptions. It is introduced theoretically that the electronic structure of the single-layered CNt depends on the cylinder diameter and spiral pitch. Replacing part of the carbon negative electrode with iron, and vaporizing iron and carbon simultaneously through arc discharge can result in a single-layered CNt with a diameter of 1 nm. Heating the CNt deposited with metallic lead in an oxygen atmosphere can form CNt containing lead compounds. 19 refs., 9 figs.
Authors:
Publication Date:
Jan 20, 1994
Product Type:
Journal Article
Reference Number:
NEDO-94-910853; EDB-94-144981
Resource Relation:
Journal Name: Denki Gakkai Zasshi; (Japan); Journal Volume: 114:1
Subject:
36 MATERIALS SCIENCE; CARBON; ELECTRODES; MOLECULAR STRUCTURE; DEPOSITS; DIRECT CURRENT; ELECTRIC ARCS; CRYSTAL STRUCTURE; CYLINDERS; ELECTRONIC STRUCTURE; LATTICE PARAMETERS; MOLECULAR SIEVE PROCESS; SPIRAL CONFIGURATION; HEAT TREATMENTS; IRON; LEAD; SIZE; VAPOR DEPOSITED COATINGS; CHEMICAL REACTIONS; COATINGS; CONFIGURATION; CURRENTS; DESULFURIZATION; ELECTRIC CURRENTS; ELECTRIC DISCHARGES; ELEMENTS; METALS; NONMETALS; TRANSITION ELEMENTS; 360602* - Other Materials- Structure & Phase Studies; 360606 - Other Materials- Physical Properties- (1992-); 360601 - Other Materials- Preparation & Manufacture
OSTI ID:
6976218
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Journal ID: ISSN 0020-2878; CODEN: DGZAAW
Submitting Site:
NEDO
Size:
Pages: 33-37
Announcement Date:
Nov 01, 1994

Citation Formats

Iijima, S. Discovery of carbon nanotubes. Sara ni carbon nanotube e. Japan: N. p., 1994. Web.
Iijima, S. Discovery of carbon nanotubes. Sara ni carbon nanotube e. Japan.
Iijima, S. 1994. "Discovery of carbon nanotubes. Sara ni carbon nanotube e." Japan.
@misc{etde_6976218,
title = {Discovery of carbon nanotubes. Sara ni carbon nanotube e}
author = {Iijima, S}
abstractNote = {This paper describes the following matters on carbon nanotubes (CNt): CNt is discovered in carbon deposits generated in the tip of a negative electrode during DC arc discharge between carbon electrodes. CNt has a construction in which cylinders made of normally several layers are superposed, based on cylindrical crystals in a single layer with six-member rings of carbon atoms laid out. Spiral arrangement of carbon six-member rings has been discovered in the single-layered crystals. Five-member rings exist in a location where the CNt tip is closed, and seven-member rings in a location where the CNt presents a saddle-like curve, without exceptions. It is introduced theoretically that the electronic structure of the single-layered CNt depends on the cylinder diameter and spiral pitch. Replacing part of the carbon negative electrode with iron, and vaporizing iron and carbon simultaneously through arc discharge can result in a single-layered CNt with a diameter of 1 nm. Heating the CNt deposited with metallic lead in an oxygen atmosphere can form CNt containing lead compounds. 19 refs., 9 figs.}
journal = []
volume = {114:1}
journal type = {AC}
place = {Japan}
year = {1994}
month = {Jan}
}