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Ruthenium (3) coordination compounds with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid

Abstract

In the process of interaction of K/sub 2/Ru(H/sub 2/O)Cl/sub 5/ with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid (H/sub 8/EDTP) Ru/sup 3/ mono-, bi- and trinuclear complexonates are synthesized. On the basis of IR and X-ray electron spectroscopy and potentiometry suppositions are made on the way of ligand (EDTP, Cl/sup -/, H/sub 2/O) coordination. Ru/sup 3/ complexonates are characterized using spectrophotometry, polarography, conductometry. Thermal decomposition of the complexonates is studied.
Publication Date:
Dec 01, 1987
Product Type:
Journal Article
Reference Number:
AIX-19-071353; EDB-88-141473
Resource Relation:
Journal Name: Zh. Neorg. Khim.; (USSR); Journal Volume: 32:12
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; RUTHENIUM COMPLEXES; CHEMICAL PREPARATION; AMINES; CHELATES; CHLORIDES; COORDINATION VALENCES; ELECTRON SPECTRA; HYDRATES; INFRARED SPECTRA; MOLECULAR STRUCTURE; PHOSPHONATES; PYROLYSIS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DECOMPOSITION; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; SPECTRA; SYNTHESIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPLEXES; VALENCE; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6909162
Research Organizations:
AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZNOKA
Submitting Site:
INIS
Size:
Pages: 3011-3016
Announcement Date:
Aug 01, 1988

Citation Formats

Ezerskaya, N A, Ki, Buj Kuang, and Shubochkin, L K. Ruthenium (3) coordination compounds with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid. USSR: N. p., 1987. Web.
Ezerskaya, N A, Ki, Buj Kuang, & Shubochkin, L K. Ruthenium (3) coordination compounds with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid. USSR.
Ezerskaya, N A, Ki, Buj Kuang, and Shubochkin, L K. 1987. "Ruthenium (3) coordination compounds with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid." USSR.
@misc{etde_6909162,
title = {Ruthenium (3) coordination compounds with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid}
author = {Ezerskaya, N A, Ki, Buj Kuang, and Shubochkin, L K}
abstractNote = {In the process of interaction of K/sub 2/Ru(H/sub 2/O)Cl/sub 5/ with ethylenediamine-N,N,N',N'-tetramethylphosphonic acid (H/sub 8/EDTP) Ru/sup 3/ mono-, bi- and trinuclear complexonates are synthesized. On the basis of IR and X-ray electron spectroscopy and potentiometry suppositions are made on the way of ligand (EDTP, Cl/sup -/, H/sub 2/O) coordination. Ru/sup 3/ complexonates are characterized using spectrophotometry, polarography, conductometry. Thermal decomposition of the complexonates is studied.}
journal = []
volume = {32:12}
journal type = {AC}
place = {USSR}
year = {1987}
month = {Dec}
}