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ETDEWEB   /       /    Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide

Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide

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Abstract

Reactions of the title compound with different stoichiometries of KH/sub n/BL/sub 4-n/ (where n=1,2 and L=3,5-dimethylpyrazolyl) have been studied and the compounds UCl/sub 2/H/sub 2/BL/sub 2/ and UCl/sub 2/HBL/sub 3/ identified. The preparation of UCl/sub 2/H/sub 2/BL'/sub 2/py (L'=pyrazolyl, py=pyridine) is reported. The reactivity of UCl/sub 2/H/sub 2/BL'/sub 2/THF with sodium cyclopentadienide in tetrahydrofuran and toluene has been studied.
Authors:
Publication Date:
Aug 01, 1986
Product Type:
Conference
Report Number:
CONF-8509147-
Reference Number:
AIX-18-017573; EDB-87-047666
Resource Relation:
Journal Name: J. Less-Common Met.; (Switzerland); Journal Volume: 122; Conference: ACTINIDES '85, Aix-en-Provence, France, 1 Sep 1985
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; PYRAZOLES; CHEMICAL REACTIONS; TETRAHYDROFURAN; URANIUM CHLORIDES; URANIUM COMPLEXES; ABSORPTION SPECTROSCOPY; BORATES; CHEMICAL ANALYSIS; CYCLOPENTADIENE; INFRARED SPECTRA; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SODIUM COMPOUNDS; ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; ALKALI METAL COMPOUNDS; ALKENES; AZOLES; BORON COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; CYCLOALKENES; DIENES; FURANS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; POLYENES; RESONANCE; SPECTRA; SPECTROSCOPY; URANIUM COMPOUNDS; 400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials; 400102 - Chemical & Spectral Procedures
OSTI ID:
6870170
Research Organizations:
Laboratorio Nacional de Engenharia e Tecnologia Industrial, Sacavem, Portugal. Dept. de Quimica
Country of Origin:
Switzerland
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JCOMA
Submitting Site:
INIS
Size:
Pages: vp
Announcement Date:
May 13, 2001

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Citation Formats

Santos, I, Marques, N, and Pires de Matos, A. Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide. Switzerland: N. p., 1986. Web.
Santos, I, Marques, N, & Pires de Matos, A. Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide. Switzerland.
Santos, I, Marques, N, and Pires de Matos, A. 1986. "Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide." Switzerland.
@misc{etde_6870170,
title = {Reactions of UCl/sub 3/(THF)/sub x/ (THF=tetrahydrofuran) with poly(pyrazolyl) borates and sodium cyclopentadienide}
 author = {Santos, I, Marques, N, and Pires de Matos, A}
 abstractNote = {Reactions of the title compound with different stoichiometries of KH/sub n/BL/sub 4-n/ (where n=1,2 and L=3,5-dimethylpyrazolyl) have been studied and the compounds UCl/sub 2/H/sub 2/BL/sub 2/ and UCl/sub 2/HBL/sub 3/ identified. The preparation of UCl/sub 2/H/sub 2/BL'/sub 2/py (L'=pyrazolyl, py=pyridine) is reported. The reactivity of UCl/sub 2/H/sub 2/BL'/sub 2/THF with sodium cyclopentadienide in tetrahydrofuran and toluene has been studied.}
 journal = []
 volume = {122}
 place = {Switzerland}
 year = {1986}
 month = {Aug}
 }