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Crown ether complexes of lanthanoid and actinoid elements. Crystal and molecular structure of Nd(NO/sub 3/)/sub 3/(18-crown-6)

Abstract

Nd(NO/sub 3/)/sub 3/.18-Crown-6 crystallizes in the orthorhombic system, space group Pbca with eight molecules in a cell of dimensions a = 15.512(9), b = 21.662(1), c = 12.141(6) A. The structure has been determined by Patterson heavy-atom methods and refined by full-matrix least squares to R = 0.038. The neodymium atom is coordinated by 6 oxygen atoms of the 18-crown-6 unit and by three bidentate nitrate groups; one on the more hindered side of the ring and two on the opposite side.
Authors:
Bombieri, G; De Paoli, G; Benetollo, F; [1]  Cassol, A [2] 
  1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
  2. Padua Univ. (Italy)
Publication Date:
Jan 01, 1980
Product Type:
Journal Article
Reference Number:
AIX-12-577227; EDB-81-046900
Resource Relation:
Journal Name: J. Inorg. Nucl. Chem.; (United Kingdom); Journal Volume: 42:10
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; NEODYMIUM COMPLEXES; LATTICE PARAMETERS; ORTHORHOMBIC LATTICES; COORDINATION NUMBER; MOLECULAR STRUCTURE; NEODYMIUM NITRATES; POLYETHYLENE GLYCOLS; SPACE GROUPS; X-RAY DIFFRACTION; ALCOHOLS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; GLYCOLS; HYDROXY COMPOUNDS; NEODYMIUM COMPOUNDS; NITRATES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; POLYMERS; RARE EARTH COMPLEXES; RARE EARTH COMPOUNDS; SCATTERING; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6869759
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JINCA
Submitting Site:
INIS
Size:
Pages: 1417-1422
Announcement Date:
Feb 01, 1981

Citation Formats

Bombieri, G, De Paoli, G, Benetollo, F, and Cassol, A. Crown ether complexes of lanthanoid and actinoid elements. Crystal and molecular structure of Nd(NO/sub 3/)/sub 3/(18-crown-6). United Kingdom: N. p., 1980. Web. doi:10.1016/0022-1902(80)80107-2.
Bombieri, G, De Paoli, G, Benetollo, F, & Cassol, A. Crown ether complexes of lanthanoid and actinoid elements. Crystal and molecular structure of Nd(NO/sub 3/)/sub 3/(18-crown-6). United Kingdom. https://doi.org/10.1016/0022-1902(80)80107-2
Bombieri, G, De Paoli, G, Benetollo, F, and Cassol, A. 1980. "Crown ether complexes of lanthanoid and actinoid elements. Crystal and molecular structure of Nd(NO/sub 3/)/sub 3/(18-crown-6)." United Kingdom. https://doi.org/10.1016/0022-1902(80)80107-2.
@misc{etde_6869759,
title = {Crown ether complexes of lanthanoid and actinoid elements. Crystal and molecular structure of Nd(NO/sub 3/)/sub 3/(18-crown-6)}
author = {Bombieri, G, De Paoli, G, Benetollo, F, and Cassol, A}
abstractNote = {Nd(NO/sub 3/)/sub 3/.18-Crown-6 crystallizes in the orthorhombic system, space group Pbca with eight molecules in a cell of dimensions a = 15.512(9), b = 21.662(1), c = 12.141(6) A. The structure has been determined by Patterson heavy-atom methods and refined by full-matrix least squares to R = 0.038. The neodymium atom is coordinated by 6 oxygen atoms of the 18-crown-6 unit and by three bidentate nitrate groups; one on the more hindered side of the ring and two on the opposite side.}
doi = {10.1016/0022-1902(80)80107-2}
journal = []
volume = {42:10}
journal type = {AC}
place = {United Kingdom}
year = {1980}
month = {Jan}
}