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Binary and ternary chelates of scandium (III), Yttrium (III) and lanthanum (III) with ethyleneglycol-bis(. beta. -aminoethylether)-tetraacetic acid as primary and substituted salicylic acids as secondary ligands

Abstract

Formation constants of binary and ternary complexes of the systems of the type: M-L and M-egta-L (M = scandium(III), yttrium(III) and lanthanum(III), egta = ethylene glycol-bis(..beta..-aminoethylether)-tetra acetic acid, L = o-cresotic acid (o-ca), m-cresotic acid (m-ca), 5-chlorosalicyclic acid(csa), and 3,5-dibromosalicylic acid (dbsa)) have been determined pH-metrically at 25deg and ..mu.. = 0.1M (KNO/sub 3/) in 50% (v/v) aqueous-ethanol medium. The order of stabilities of ternary complexes has been compared with those of corresponding binary complexes, and results discussed on the basis of coulombic interactions.
Authors:
Pandey, A K; Chandra, M; Agarwala, B V; Dey, A K [1] 
  1. Allahabad Univ. (India). Chemical Labs.
Publication Date:
Jan 01, 1980
Product Type:
Journal Article
Reference Number:
AIX-12-575010; EDB-81-010962
Resource Relation:
Journal Name: J. Indian Chem. Soc.; (India); Journal Volume: 57:1
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; LANTHANUM COMPLEXES; STABILITY; SCANDIUM COMPLEXES; YTTRIUM COMPLEXES; CHELATES; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; PH VALUE; COMPLEXES; KINETICS; RARE EARTH COMPLEXES; REACTION KINETICS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6862599
Country of Origin:
India
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JICSA
Submitting Site:
INIS
Size:
Pages: 32-34
Announcement Date:
Jan 01, 1981

Citation Formats

Pandey, A K, Chandra, M, Agarwala, B V, and Dey, A K. Binary and ternary chelates of scandium (III), Yttrium (III) and lanthanum (III) with ethyleneglycol-bis(. beta. -aminoethylether)-tetraacetic acid as primary and substituted salicylic acids as secondary ligands. India: N. p., 1980. Web.
Pandey, A K, Chandra, M, Agarwala, B V, & Dey, A K. Binary and ternary chelates of scandium (III), Yttrium (III) and lanthanum (III) with ethyleneglycol-bis(. beta. -aminoethylether)-tetraacetic acid as primary and substituted salicylic acids as secondary ligands. India.
Pandey, A K, Chandra, M, Agarwala, B V, and Dey, A K. 1980. "Binary and ternary chelates of scandium (III), Yttrium (III) and lanthanum (III) with ethyleneglycol-bis(. beta. -aminoethylether)-tetraacetic acid as primary and substituted salicylic acids as secondary ligands." India.
@misc{etde_6862599,
title = {Binary and ternary chelates of scandium (III), Yttrium (III) and lanthanum (III) with ethyleneglycol-bis(. beta. -aminoethylether)-tetraacetic acid as primary and substituted salicylic acids as secondary ligands}
author = {Pandey, A K, Chandra, M, Agarwala, B V, and Dey, A K}
abstractNote = {Formation constants of binary and ternary complexes of the systems of the type: M-L and M-egta-L (M = scandium(III), yttrium(III) and lanthanum(III), egta = ethylene glycol-bis(..beta..-aminoethylether)-tetra acetic acid, L = o-cresotic acid (o-ca), m-cresotic acid (m-ca), 5-chlorosalicyclic acid(csa), and 3,5-dibromosalicylic acid (dbsa)) have been determined pH-metrically at 25deg and ..mu.. = 0.1M (KNO/sub 3/) in 50% (v/v) aqueous-ethanol medium. The order of stabilities of ternary complexes has been compared with those of corresponding binary complexes, and results discussed on the basis of coulombic interactions.}
journal = []
volume = {57:1}
journal type = {AC}
place = {India}
year = {1980}
month = {Jan}
}