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Modified aluminoplatinum catalysts for the reaction of cyclotrimerization of ethylene

Abstract

The influence of additions of various metals (Sc, Zr, Sn, and Re) on the dispersity of Pt particles on an Al-Pt catalyst for the reaction of ethylene cyclotrimerization was studied. It was shown that introduction of additives of different natures and concentrations, employment of different conditions for H/sub 2/ reduction and thermal treatment of the catalyst, and other things allow the dispersity of the Pt on the catalyst to be varied within the range 0.06-1 GAMMA (GAMMA - the fraction of Pt accessible for reaction on the surface of the support). For most of the studied catalysts a symbiotic relation between the dispersity of the Pt particles and the activity of the A1-Pt catalyst in the studied reaction is observed.
Publication Date:
Jan 01, 1981
Product Type:
Journal Article
Reference Number:
EDB-83-043413
Resource Relation:
Journal Name: Izv. Akad. Nauk SSSR, Ser. Khim.; (USSR); Journal Volume: 9
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM; CATALYTIC EFFECTS; CATALYSTS; ADDITIVES; ETHYLENE; POLYMERIZATION; PLATINUM; RHENIUM; SCANDIUM; TEMPERATURE EFFECTS; TIN; ZIRCONIUM; ALKENES; CHEMICAL REACTIONS; ELEMENTS; HYDROCARBONS; METALS; ORGANIC COMPOUNDS; PLATINUM METALS; TRANSITION ELEMENTS; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987); 400201 - Chemical & Physicochemical Properties
OSTI ID:
6799852
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: IASKA
Submitting Site:
HEDB
Size:
Pages: 1958-1961
Announcement Date:
Oct 01, 1982

Citation Formats

Vasina, T V, Bragin, O V, Lutovinova, V N, Preobrazhenskii, A V, and Savostin, Yu A. Modified aluminoplatinum catalysts for the reaction of cyclotrimerization of ethylene. USSR: N. p., 1981. Web.
Vasina, T V, Bragin, O V, Lutovinova, V N, Preobrazhenskii, A V, & Savostin, Yu A. Modified aluminoplatinum catalysts for the reaction of cyclotrimerization of ethylene. USSR.
Vasina, T V, Bragin, O V, Lutovinova, V N, Preobrazhenskii, A V, and Savostin, Yu A. 1981. "Modified aluminoplatinum catalysts for the reaction of cyclotrimerization of ethylene." USSR.
@misc{etde_6799852,
title = {Modified aluminoplatinum catalysts for the reaction of cyclotrimerization of ethylene}
author = {Vasina, T V, Bragin, O V, Lutovinova, V N, Preobrazhenskii, A V, and Savostin, Yu A}
abstractNote = {The influence of additions of various metals (Sc, Zr, Sn, and Re) on the dispersity of Pt particles on an Al-Pt catalyst for the reaction of ethylene cyclotrimerization was studied. It was shown that introduction of additives of different natures and concentrations, employment of different conditions for H/sub 2/ reduction and thermal treatment of the catalyst, and other things allow the dispersity of the Pt on the catalyst to be varied within the range 0.06-1 GAMMA (GAMMA - the fraction of Pt accessible for reaction on the surface of the support). For most of the studied catalysts a symbiotic relation between the dispersity of the Pt particles and the activity of the A1-Pt catalyst in the studied reaction is observed.}
journal = []
volume = {9}
journal type = {AC}
place = {USSR}
year = {1981}
month = {Jan}
}