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KCeSe[sub 4]: A new solid-state lanthanide polychalcogenide

Abstract

Cerium and molten potassium selenide flux provide access to KCeSe[sub 4]. The structure of this novel lanthanide polychalcogenide is related to the CuAl[sub 2] structure, and Ce and Se form anionic layers with K[sup +] ions in the cavities. Each Ce[sup 3+] ion is surrounded by eight Se[sub 2][sup 2-] units in a square antiprismatic arrangement (structure shown on the right). (orig.).
Authors:
Sutorik, A C; Kanatzidis, M G [1] 
  1. Michigan State Univ., East Lansing, MI (United States). Dept. of Chemistry and Center for Fundamental Materials Research
Publication Date:
Dec 01, 1992
Product Type:
Journal Article
Reference Number:
DEN-93-003964; EDB-93-059614
Resource Relation:
Journal Name: Angewandte Chemie. International Edition in English; (Germany); Journal Volume: 31:12
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CERIUM SELENIDES; MAGNETIC SUSCEPTIBILITY; SOLID SOLUTIONS; CHEMICAL PREPARATION; POTASSIUM SELENIDES; SOLIDS; STRUCTURAL CHEMICAL ANALYSIS; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0000-0013 K; TEMPERATURE RANGE 0013-0065 K; TEMPERATURE RANGE 0065-0273 K; ALKALI METAL COMPOUNDS; CERIUM COMPOUNDS; CHALCOGENIDES; DISPERSIONS; MAGNETIC PROPERTIES; MIXTURES; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; RARE EARTH COMPOUNDS; SELENIDES; SELENIUM COMPOUNDS; SOLUTIONS; SYNTHESIS; TEMPERATURE RANGE; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6673752
Country of Origin:
Germany
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0570-0833; CODEN: ACIEAY
Submitting Site:
DEN
Size:
Pages: 1594-1596
Announcement Date:
May 15, 1993

Citation Formats

Sutorik, A C, and Kanatzidis, M G. KCeSe[sub 4]: A new solid-state lanthanide polychalcogenide. Germany: N. p., 1992. Web. doi:10.1002/anie.199215941.
Sutorik, A C, & Kanatzidis, M G. KCeSe[sub 4]: A new solid-state lanthanide polychalcogenide. Germany. https://doi.org/10.1002/anie.199215941
Sutorik, A C, and Kanatzidis, M G. 1992. "KCeSe[sub 4]: A new solid-state lanthanide polychalcogenide." Germany. https://doi.org/10.1002/anie.199215941.
@misc{etde_6673752,
title = {KCeSe[sub 4]: A new solid-state lanthanide polychalcogenide}
author = {Sutorik, A C, and Kanatzidis, M G}
abstractNote = {Cerium and molten potassium selenide flux provide access to KCeSe[sub 4]. The structure of this novel lanthanide polychalcogenide is related to the CuAl[sub 2] structure, and Ce and Se form anionic layers with K[sup +] ions in the cavities. Each Ce[sup 3+] ion is surrounded by eight Se[sub 2][sup 2-] units in a square antiprismatic arrangement (structure shown on the right). (orig.).}
doi = {10.1002/anie.199215941}
journal = []
volume = {31:12}
journal type = {AC}
place = {Germany}
year = {1992}
month = {Dec}
}