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Direct atomic spectrometric analysis by slurry atomisation: Pt. 7. Analysis of coal using inductively coupled plasma mass spectrometry

Conference:

Abstract

The application of slurry atomisation - inductively coupled plasma mass spectrometry (ICP-MS) to major, minor and trace element determination in coals has been investigated. Eight certified reference material (CRM) coals have been ground by the bottle and bead method and analysed using both rapid scan semi-quantitative analysis, employing a single rhodium internal standard, and full quantitative analysis using simple aqueous standards for calibration. The semi-quantitative mode, which determines the concentration using the mass-response curve for 68 elements against the single internal standard, produced values which were within a factor of two of the certified reference value, in most instances. The full quantitative determination gave excellent agreement with the certified reference material coals for a large number of elemental constituents. The results from the determination of 16 elements of interest are discussed including the effects of polyatomic interferents and isotope sensitivity.
Publication Date:
Sep 01, 1988
Product Type:
Conference
Report Number:
CONF-880108-
Reference Number:
GB-88-001977; EDB-89-000123
Resource Relation:
Journal Name: J. Anal. At. Spectrom.; (United Kingdom); Journal Volume: 3:6; Conference: Winter conference on plasma spectrochemistry, San Diego, CA, United States, 3 Jan 1988
Subject:
01 COAL, LIGNITE, AND PEAT; COAL; ATOMIZATION; MASS SPECTROSCOPY; QUANTITATIVE CHEMICAL ANALYSIS; SLURRIES; ELEMENTS; TRACE AMOUNTS; CARBONACEOUS MATERIALS; CHEMICAL ANALYSIS; DISPERSIONS; ENERGY SOURCES; FOSSIL FUELS; FUELS; MATERIALS; MIXTURES; SPECTROSCOPY; SUSPENSIONS; 010600* - Coal, Lignite, & Peat- Properties & Composition
OSTI ID:
6662751
Research Organizations:
Plymouth Polytechnic (GB). Dept. of Environmental Sciences; VG Elemental, Winsford (GB)
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JASPE
Submitting Site:
GB
Size:
Pages: 753-761
Announcement Date:

Conference:

Citation Formats

Ebdon, Les, Foulkes, M E, Parry, H G.M., and Tye, C T. Direct atomic spectrometric analysis by slurry atomisation: Pt. 7. Analysis of coal using inductively coupled plasma mass spectrometry. United Kingdom: N. p., 1988. Web.
Ebdon, Les, Foulkes, M E, Parry, H G.M., & Tye, C T. Direct atomic spectrometric analysis by slurry atomisation: Pt. 7. Analysis of coal using inductively coupled plasma mass spectrometry. United Kingdom.
Ebdon, Les, Foulkes, M E, Parry, H G.M., and Tye, C T. 1988. "Direct atomic spectrometric analysis by slurry atomisation: Pt. 7. Analysis of coal using inductively coupled plasma mass spectrometry." United Kingdom.
@misc{etde_6662751,
title = {Direct atomic spectrometric analysis by slurry atomisation: Pt. 7. Analysis of coal using inductively coupled plasma mass spectrometry}
author = {Ebdon, Les, Foulkes, M E, Parry, H G.M., and Tye, C T}
abstractNote = {The application of slurry atomisation - inductively coupled plasma mass spectrometry (ICP-MS) to major, minor and trace element determination in coals has been investigated. Eight certified reference material (CRM) coals have been ground by the bottle and bead method and analysed using both rapid scan semi-quantitative analysis, employing a single rhodium internal standard, and full quantitative analysis using simple aqueous standards for calibration. The semi-quantitative mode, which determines the concentration using the mass-response curve for 68 elements against the single internal standard, produced values which were within a factor of two of the certified reference value, in most instances. The full quantitative determination gave excellent agreement with the certified reference material coals for a large number of elemental constituents. The results from the determination of 16 elements of interest are discussed including the effects of polyatomic interferents and isotope sensitivity.}
journal = {J. Anal. At. Spectrom.; (United Kingdom)}
volume = {3:6}
place = {United Kingdom}
year = {1988}
month = {Sep}
}