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Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze

Journal Article:

Abstract

Methods for synthesis and separation in solid state of the rhenium(5) and molybdenum(5) onium complexes with diaza-18-crown-6(L), the content of which according to the data of elementary analysis, IRS in the close and remote areas, thermogravimetry, conductometry and potentiometry corresponds to the (H[sub 2]L)[EOX[sub 5]], where E = Re, Mo; X = Cl[sup -], Br[sup -]. Thermotransformation of onium compounds is studied by methods of thermal methods (TG-DTG-DTA combined study). Their avility to be affected by solid-phase dehydrohalogenization, e.i. anderson regrouping. The thermolysis products, corresponding to the general formula (EOLX[sub 3]), are separated and studied.
Authors:
Ashurova, N Kh; Yakubov, K G [1] 
  1. Tadzhikskij Gosudarstvennyj Univ., Dushanbe (Tajikistan)
Publication Date:
Nov 01, 1992
Product Type:
Journal Article
Reference Number:
AIX-24-049053; EDB-93-092613
Resource Relation:
Journal Name: Zhurnal Neorganicheskoj Khimii; (USSR); Journal Volume: 37:11
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLYBDENUM COMPLEXES; CHEMICAL PREPARATION; PYROLYSIS; RHENIUM COMPLEXES; CHEMICAL COMPOSITION; CHEMICAL REACTION YIELD; CRYSTALS; ELECTRIC CONDUCTIVITY; HALIDES; HETEROCYCLIC COMPOUNDS; INFRARED SPECTRA; POLYETHYLENE GLYCOLS; ALCOHOLS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; ELECTRICAL PROPERTIES; GLYCOLS; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; PHYSICAL PROPERTIES; POLYMERS; SPECTRA; SYNTHESIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPLEXES; YIELDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6487212
Country of Origin:
Russian Federation
Language:
Russian
Other Identifying Numbers:
Journal ID: ISSN 0044-457X; CODEN: ZNOKAQ
Submitting Site:
INIS
Size:
Pages: 2500-2506
Announcement Date:
Aug 01, 1993

Journal Article:

Citation Formats

Ashurova, N Kh, and Yakubov, K G. Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze. Russian Federation: N. p., 1992. Web.
Ashurova, N Kh, & Yakubov, K G. Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze. Russian Federation.
Ashurova, N Kh, and Yakubov, K G. 1992. "Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze." Russian Federation.
@misc{etde_6487212,
title = {Thermal transformations of oxohalide complexes of rhenium(5) and molybdenum(5) with diazo-18-crown-6 in solid phase. Termicheskie prevrashcheniya oksogalogenidnykh kompleksov reniya(5) i molibdena(5) s diaza-18-kraun-6 v tverdoj faze}
author = {Ashurova, N Kh, and Yakubov, K G}
abstractNote = {Methods for synthesis and separation in solid state of the rhenium(5) and molybdenum(5) onium complexes with diaza-18-crown-6(L), the content of which according to the data of elementary analysis, IRS in the close and remote areas, thermogravimetry, conductometry and potentiometry corresponds to the (H[sub 2]L)[EOX[sub 5]], where E = Re, Mo; X = Cl[sup -], Br[sup -]. Thermotransformation of onium compounds is studied by methods of thermal methods (TG-DTG-DTA combined study). Their avility to be affected by solid-phase dehydrohalogenization, e.i. anderson regrouping. The thermolysis products, corresponding to the general formula (EOLX[sub 3]), are separated and studied.}
journal = {Zhurnal Neorganicheskoj Khimii; (USSR)}
volume = {37:11}
journal type = {AC}
place = {Russian Federation}
year = {1992}
month = {Nov}
}