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Kinetic investigation of heterogeneous catalytic reactions by means of the kinetic isotope method

Journal Article:

Abstract

The application of the kinetic isotope method to heterogeneous catalytic processes is possible for surface compounds by using the steady-state relation. However, the characterization of intermediate products becomes ambiguous if sorption rates are of the same order of magnitude as surface reactions rates. The isotopic exchange reaction renders possible the estimation of sorption rates.
Authors:
Bauer, F; Dermietzel, J [1] 
  1. Akademie der Wissenschaften der DDR, Leipzig. Zentralinstitut fuer Isotopen- und Strahlenforschung
Publication Date:
Sep 01, 1978
Product Type:
Journal Article
Reference Number:
AIX-09-416665; EDB-79-043755
Resource Relation:
Journal Name: Isotopenpraxis; (German Democratic Republic); Journal Volume: 14:9
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBON 14; ISOTOPIC EXCHANGE; ADSORPTION; CARBON 14 COMPOUNDS; CATALYSIS; CHEMICAL REACTION KINETICS; DESORPTION; ISOMERIZATION; SURFACES; TRACER TECHNIQUES; XYLENES; AROMATICS; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CARBON ISOTOPES; CHEMICAL REACTIONS; EVEN-EVEN NUCLEI; HYDROCARBONS; ISOTOPE APPLICATIONS; ISOTOPES; KINETICS; LABELLED COMPOUNDS; LIGHT NUCLEI; NUCLEI; ORGANIC COMPOUNDS; RADIOISOTOPES; REACTION KINETICS; SORPTION; YEARS LIVING RADIOISOTOPES; 400303* - Organic Chemistry- Isotope Exchange & Isotope Separation- (-1987)
OSTI ID:
6486119
Country of Origin:
Germany
Language:
German
Other Identifying Numbers:
Journal ID: CODEN: IPRXA
Submitting Site:
INIS
Size:
Pages: 300-303
Announcement Date:
Feb 01, 1979

Journal Article:

Citation Formats

Bauer, F, and Dermietzel, J. Kinetic investigation of heterogeneous catalytic reactions by means of the kinetic isotope method. Germany: N. p., 1978. Web.
Bauer, F, & Dermietzel, J. Kinetic investigation of heterogeneous catalytic reactions by means of the kinetic isotope method. Germany.
Bauer, F, and Dermietzel, J. 1978. "Kinetic investigation of heterogeneous catalytic reactions by means of the kinetic isotope method." Germany.
@misc{etde_6486119,
title = {Kinetic investigation of heterogeneous catalytic reactions by means of the kinetic isotope method}
author = {Bauer, F, and Dermietzel, J}
abstractNote = {The application of the kinetic isotope method to heterogeneous catalytic processes is possible for surface compounds by using the steady-state relation. However, the characterization of intermediate products becomes ambiguous if sorption rates are of the same order of magnitude as surface reactions rates. The isotopic exchange reaction renders possible the estimation of sorption rates.}
journal = {Isotopenpraxis; (German Democratic Republic)}
volume = {14:9}
journal type = {AC}
place = {Germany}
year = {1978}
month = {Sep}
}