Abstract
Over 30 metal oxides and chlorides were tested for their catalytic activity and selectivity for the liquid-phase conversion of 0.2 mole of phenol with 0.8 mole of ammonia in a 100 ml autoclave. Best results were obtained with stannic and stannous chloride, which yielded an optimum of 56% of aniline (59% conversion, 95% selectivity) at 340/sup 0/C and three hours of reaction time. The reaction was inhibited by sodium hydroxide and by water. An acid-catalyzed mechanism is discussed.
Citation Formats
Hamada, H, Matsuzaki, T, and Wakabayashi, K.
Liquid-phase ammonolysis of phenols with metal chloride catalysts.
Japan: N. p.,
1980.
Web.
Hamada, H, Matsuzaki, T, & Wakabayashi, K.
Liquid-phase ammonolysis of phenols with metal chloride catalysts.
Japan.
Hamada, H, Matsuzaki, T, and Wakabayashi, K.
1980.
"Liquid-phase ammonolysis of phenols with metal chloride catalysts."
Japan.
@misc{etde_6462162,
title = {Liquid-phase ammonolysis of phenols with metal chloride catalysts}
author = {Hamada, H, Matsuzaki, T, and Wakabayashi, K}
abstractNote = {Over 30 metal oxides and chlorides were tested for their catalytic activity and selectivity for the liquid-phase conversion of 0.2 mole of phenol with 0.8 mole of ammonia in a 100 ml autoclave. Best results were obtained with stannic and stannous chloride, which yielded an optimum of 56% of aniline (59% conversion, 95% selectivity) at 340/sup 0/C and three hours of reaction time. The reaction was inhibited by sodium hydroxide and by water. An acid-catalyzed mechanism is discussed.}
journal = []
volume = {4}
journal type = {AC}
place = {Japan}
year = {1980}
month = {Apr}
}
title = {Liquid-phase ammonolysis of phenols with metal chloride catalysts}
author = {Hamada, H, Matsuzaki, T, and Wakabayashi, K}
abstractNote = {Over 30 metal oxides and chlorides were tested for their catalytic activity and selectivity for the liquid-phase conversion of 0.2 mole of phenol with 0.8 mole of ammonia in a 100 ml autoclave. Best results were obtained with stannic and stannous chloride, which yielded an optimum of 56% of aniline (59% conversion, 95% selectivity) at 340/sup 0/C and three hours of reaction time. The reaction was inhibited by sodium hydroxide and by water. An acid-catalyzed mechanism is discussed.}
journal = []
volume = {4}
journal type = {AC}
place = {Japan}
year = {1980}
month = {Apr}
}