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Studies on the electrochemical behaviour of iron by the use of radio-tracer technique, 1. Studies on the electrodeposition and dissolution of iron by the use of radio-tracer technique

Journal Article:

Abstract

To investigate whether radio-tracer techniques can augment conventional electrochemical techniques, offering useful information about the electrochemical behaviour of iron, the current efficiency of the electrodeposition of iron and the corrosion rate of metallic iron were measured by the radio-tracer method and the results were compared with the results measured by gravimetry and absorption photometry. Major conclusions obtained by the experiments are summarized as: 1) Between ordinary Fe and /sup 59/Fe, no isotope effect was observed. 2) Radiation from /sup 59/Fe had no effect on the electrode reaction. 3) While the use of a Ge semiconductor detector is undoubtedly preferable, Geiger-Mueller counter or NaI(Tl) scintillation counter gave fully satisfactory results. 4) Electrodeposited iron corrodes several times more rapidly than the iron base metal. These results suggests many other interesting applications of the radio-tracer technique when it is desired to obtain more detailed information on the electrochemical behaviour of iron. (author).
Publication Date:
Dec 01, 1984
Product Type:
Journal Article
Reference Number:
AIX-17-012934; EDB-86-024727
Resource Relation:
Journal Name: Denki Kagaku Oyobi Kogyo Butsuri Kagaku; (Japan); Journal Volume: 52:12
Subject:
36 MATERIALS SCIENCE; IRON; ELECTRODEPOSITION; IRON 59; USES; DISSOLUTION; ELECTROLYSIS; IRON CHLORIDES; TRACER TECHNIQUES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHLORIDES; CHLORINE COMPOUNDS; DAYS LIVING RADIOISOTOPES; DEPOSITION; ELEMENTS; EVEN-ODD NUCLEI; HALIDES; HALOGEN COMPOUNDS; INTERMEDIATE MASS NUCLEI; IRON COMPOUNDS; IRON ISOTOPES; ISOTOPE APPLICATIONS; ISOTOPES; LYSIS; METALS; NUCLEI; RADIOISOTOPES; SURFACE COATING; TRANSITION ELEMENT COMPOUNDS; TRANSITION ELEMENTS; 360101* - Metals & Alloys- Preparation & Fabrication
OSTI ID:
6450123
Research Organizations:
Kyoto Univ., Japan. Faculty of Engineering
Country of Origin:
Japan
Language:
Japanese
Other Identifying Numbers:
Journal ID: CODEN: DKOKA
Submitting Site:
HEDB
Size:
Pages: 820-824
Announcement Date:

Journal Article:

Citation Formats

Moritani, Kimikazu, Ito, Yasuhiko, Kamata, Masahiro, and Oishi, Jun. Studies on the electrochemical behaviour of iron by the use of radio-tracer technique, 1. Studies on the electrodeposition and dissolution of iron by the use of radio-tracer technique. Japan: N. p., 1984. Web.
Moritani, Kimikazu, Ito, Yasuhiko, Kamata, Masahiro, & Oishi, Jun. Studies on the electrochemical behaviour of iron by the use of radio-tracer technique, 1. Studies on the electrodeposition and dissolution of iron by the use of radio-tracer technique. Japan.
Moritani, Kimikazu, Ito, Yasuhiko, Kamata, Masahiro, and Oishi, Jun. 1984. "Studies on the electrochemical behaviour of iron by the use of radio-tracer technique, 1. Studies on the electrodeposition and dissolution of iron by the use of radio-tracer technique." Japan.
@misc{etde_6450123,
title = {Studies on the electrochemical behaviour of iron by the use of radio-tracer technique, 1. Studies on the electrodeposition and dissolution of iron by the use of radio-tracer technique}
author = {Moritani, Kimikazu, Ito, Yasuhiko, Kamata, Masahiro, and Oishi, Jun}
abstractNote = {To investigate whether radio-tracer techniques can augment conventional electrochemical techniques, offering useful information about the electrochemical behaviour of iron, the current efficiency of the electrodeposition of iron and the corrosion rate of metallic iron were measured by the radio-tracer method and the results were compared with the results measured by gravimetry and absorption photometry. Major conclusions obtained by the experiments are summarized as: 1) Between ordinary Fe and /sup 59/Fe, no isotope effect was observed. 2) Radiation from /sup 59/Fe had no effect on the electrode reaction. 3) While the use of a Ge semiconductor detector is undoubtedly preferable, Geiger-Mueller counter or NaI(Tl) scintillation counter gave fully satisfactory results. 4) Electrodeposited iron corrodes several times more rapidly than the iron base metal. These results suggests many other interesting applications of the radio-tracer technique when it is desired to obtain more detailed information on the electrochemical behaviour of iron. (author).}
journal = {Denki Kagaku Oyobi Kogyo Butsuri Kagaku; (Japan)}
volume = {52:12}
journal type = {AC}
place = {Japan}
year = {1984}
month = {Dec}
}