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Moessbauer study of iron(III) salicylates

Journal Article:

Abstract

Moessbauer infrared and magnetic studies of different basic salicylates of iron(III) are reported. Comparison of observed isomer shift and quadrupole splitting with the earlier work allows to assign the trinuclear chain structure to the complexes wherein the central iron atom in the chain is considered to be octahedrally coordinated in case of salicylate and 4-aminosalicylate derivatives, and pentacoordinated for the thiosalicylate with the terminal iron atom in tetrahedral symmetry. The Moessbauer parameters and ..mu..sub(eff)-value indicate the high spin state of the central iron atom and low spin state for the terminal ones.
Authors:
Mahesh, K; Sharma, N D; Gupta, D C; [1]  Puri, D M [2] 
  1. Kurukshetra Univ. (India). Dept. of Physics
  2. Kurukshetra Univ. (India). Dept. of Chemistry
Publication Date:
Jul 01, 1979
Product Type:
Journal Article
Reference Number:
AIX-11-553529; EDB-81-069242
Resource Relation:
Journal Name: Proc. Indian Natl. Sci. Acad., Part A; (India); Journal Volume: 45:4
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBOXYLIC ACID SALTS; ISOMER SHIFT; IRON 57; MOESSBAUER EFFECT; SALICYLIC ACID; INFRARED SPECTRA; IRON COMPLEXES; LIGANDS; MOLECULAR STRUCTURE; QUADRUPOLE MOMENTS; SPIN; STRUCTURAL CHEMICAL ANALYSIS; ANGULAR MOMENTUM; CARBOXYLIC ACIDS; COMPLEXES; EVEN-ODD NUCLEI; HYDROXY ACIDS; INTERMEDIATE MASS NUCLEI; IRON ISOTOPES; ISOTOPES; NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; PARTICLE PROPERTIES; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6448159
Country of Origin:
India
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: PIPSB
Submitting Site:
INIS
Size:
Pages: 277-283
Announcement Date:
Oct 01, 1980

Journal Article:

Citation Formats

Mahesh, K, Sharma, N D, Gupta, D C, and Puri, D M. Moessbauer study of iron(III) salicylates. India: N. p., 1979. Web.
Mahesh, K, Sharma, N D, Gupta, D C, & Puri, D M. Moessbauer study of iron(III) salicylates. India.
Mahesh, K, Sharma, N D, Gupta, D C, and Puri, D M. 1979. "Moessbauer study of iron(III) salicylates." India.
@misc{etde_6448159,
title = {Moessbauer study of iron(III) salicylates}
author = {Mahesh, K, Sharma, N D, Gupta, D C, and Puri, D M}
abstractNote = {Moessbauer infrared and magnetic studies of different basic salicylates of iron(III) are reported. Comparison of observed isomer shift and quadrupole splitting with the earlier work allows to assign the trinuclear chain structure to the complexes wherein the central iron atom in the chain is considered to be octahedrally coordinated in case of salicylate and 4-aminosalicylate derivatives, and pentacoordinated for the thiosalicylate with the terminal iron atom in tetrahedral symmetry. The Moessbauer parameters and ..mu..sub(eff)-value indicate the high spin state of the central iron atom and low spin state for the terminal ones.}
journal = {Proc. Indian Natl. Sci. Acad., Part A; (India)}
volume = {45:4}
journal type = {AC}
place = {India}
year = {1979}
month = {Jul}
}