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Solvent effect on the rate and equilibrium of reaction between 10-phenylphenoxarsine and methyl iodide. Vliyanie rastvoritelya na skorost' i ravnovesie reaktsii 10-fenilfenoksarsina s iodistym metilom

Journal Article:

Abstract

Effect of solvent nature on nucleophilic capacity of three-coordinated arsenic and the equilibrium state of 10-phenylphenoxarsine (PA) reaction with methyl iodide are studied. Kinetic investigations are carried out by the conductometry at 24,35,45 deg C. It is established that quaternization of PA with methyl iodide when substituting a solvent (ketone for alcohol) increases 3-14 times with simultaneous growth of the activation energy value. When transforming from aprotic solvents to protic ones PA interaction equilibrium with methyl iodide shifts to the side of arsonic salt formation.
Authors:
Gavrilov, V I; Gumerov, N S; Rakhmatullin, R R [1] 
  1. Kazanskij Khimiko-Tekhnologicheskij Inst., Kazan (USSR)
Publication Date:
Feb 01, 1990
Product Type:
Journal Article
Reference Number:
AIX-22-002304; EDB-91-004319
Resource Relation:
Journal Name: Zhurnal Obshchej Khimii; (USSR); Journal Volume: 60:2
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; METHYL IODIDE; CHEMICAL REACTIONS; ACTIVATION ENERGY; CHEMICAL REACTION KINETICS; ENTHALPY; ENTROPY; EQUILIBRIUM; MEDIUM TEMPERATURE; ORGANIC ARSENIC COMPOUNDS; ORGANIC SOLVENTS; ARSENIC COMPOUNDS; ENERGY; HALOGENATED ALIPHATIC HYDROCARBONS; IODINATED ALIPHATIC HYDROCARBONS; KINETICS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC IODINE COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLVENTS; THERMODYNAMIC PROPERTIES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6381895
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: ISSN 0044-460X; CODEN: ZOKHA
Submitting Site:
INIS
Size:
Pages: 381-385
Announcement Date:

Journal Article:

Citation Formats

Gavrilov, V I, Gumerov, N S, and Rakhmatullin, R R. Solvent effect on the rate and equilibrium of reaction between 10-phenylphenoxarsine and methyl iodide. Vliyanie rastvoritelya na skorost' i ravnovesie reaktsii 10-fenilfenoksarsina s iodistym metilom. USSR: N. p., 1990. Web.
Gavrilov, V I, Gumerov, N S, & Rakhmatullin, R R. Solvent effect on the rate and equilibrium of reaction between 10-phenylphenoxarsine and methyl iodide. Vliyanie rastvoritelya na skorost' i ravnovesie reaktsii 10-fenilfenoksarsina s iodistym metilom. USSR.
Gavrilov, V I, Gumerov, N S, and Rakhmatullin, R R. 1990. "Solvent effect on the rate and equilibrium of reaction between 10-phenylphenoxarsine and methyl iodide. Vliyanie rastvoritelya na skorost' i ravnovesie reaktsii 10-fenilfenoksarsina s iodistym metilom." USSR.
@misc{etde_6381895,
title = {Solvent effect on the rate and equilibrium of reaction between 10-phenylphenoxarsine and methyl iodide. Vliyanie rastvoritelya na skorost' i ravnovesie reaktsii 10-fenilfenoksarsina s iodistym metilom}
author = {Gavrilov, V I, Gumerov, N S, and Rakhmatullin, R R}
abstractNote = {Effect of solvent nature on nucleophilic capacity of three-coordinated arsenic and the equilibrium state of 10-phenylphenoxarsine (PA) reaction with methyl iodide are studied. Kinetic investigations are carried out by the conductometry at 24,35,45 deg C. It is established that quaternization of PA with methyl iodide when substituting a solvent (ketone for alcohol) increases 3-14 times with simultaneous growth of the activation energy value. When transforming from aprotic solvents to protic ones PA interaction equilibrium with methyl iodide shifts to the side of arsonic salt formation.}
journal = {Zhurnal Obshchej Khimii; (USSR)}
volume = {60:2}
journal type = {AC}
place = {USSR}
year = {1990}
month = {Feb}
}