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Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A

Abstract

The kinetics of NFA leaching of a hydrothermal treated Y zeolite was determined by using AAS, IR and NMR techniques. It was observed first order with respect to NFA onto intra crystalline volume. The transformation of octahedral Aluminium into mainly tetrahedral species was observed at the first contact with the fluorinated reagent,being leached as NM{sub 4} Al F{sub 4} and, in a less amount, as (N H{sub 4}){sub 3} Al F{sub 6}. (author) 4 refs., 5 figs., 1 tab.
Authors:
Martins, Ruth L; Camorim, Vera L.D.D.; Menezes, Sonia M.C. de [1] 
  1. PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas
Publication Date:
Dec 31, 1991
Product Type:
Miscellaneous
Report Number:
CONF-9105459-
Reference Number:
SCA: 665100; 664200; 400101; PA: AIX-29:045907; EDB-98:091417; SN: 98001998985
Resource Relation:
Conference: 3. meeting of nuclear magnetic resonance users, 3. Encontro de usuarios de ressonancia magnetica nuclear, Buzios (Brazil), 14-18 May 1991; Other Information: DN: 4 refs., 5 figs., 1 tab.; PBD: 1991; Related Information: Is Part Of Proceedings of the 3. Meeting of nuclear magnetic resonance users; PB: 425 p.; Anais do 3. encontro de usuarios de ressonancia magnetica nuclear
Subject:
66 PHYSICS; 40 CHEMISTRY; ABSORPTION SPECTROSCOPY; INFRARED RADIATION; INFRARED THERMOGRAPHY; NUCLEAR MAGNETIC RESONANCE; SILICATE MINERALS; ZEOLITES
OSTI ID:
636801
Research Organizations:
Associacao de Usuarios de Ressonancia Magnetica Nuclear, Rio de Janeiro, RJ (Brazil)
Country of Origin:
Brazil
Language:
Portuguese
Other Identifying Numbers:
TRN: BR98E1462045907
Availability:
Available from the Library of the Brazilian Nuclear Energy Commission, Rio de Janeiro
Submitting Site:
BRN
Size:
pp. 363-368
Announcement Date:
Jan 24, 2004

Citation Formats

Martins, Ruth L, Camorim, Vera L.D.D., and Menezes, Sonia M.C. de. Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A. Brazil: N. p., 1991. Web.
Martins, Ruth L, Camorim, Vera L.D.D., & Menezes, Sonia M.C. de. Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A. Brazil.
Martins, Ruth L, Camorim, Vera L.D.D., and Menezes, Sonia M.C. de. 1991. "Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A." Brazil.
@misc{etde_636801,
title = {Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A}
author = {Martins, Ruth L, Camorim, Vera L.D.D., and Menezes, Sonia M.C. de}
abstractNote = {The kinetics of NFA leaching of a hydrothermal treated Y zeolite was determined by using AAS, IR and NMR techniques. It was observed first order with respect to NFA onto intra crystalline volume. The transformation of octahedral Aluminium into mainly tetrahedral species was observed at the first contact with the fluorinated reagent,being leached as NM{sub 4} Al F{sub 4} and, in a less amount, as (N H{sub 4}){sub 3} Al F{sub 6}. (author) 4 refs., 5 figs., 1 tab.}
place = {Brazil}
year = {1991}
month = {Dec}
}