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Complexes of Zn(2) and Cd(2) with 2-methyl-benzimidazole

Abstract

Coordination compounds of Zn(2) and Cd(2) salts with 2-methyl-benzimidazole (MBI) of 2MBIxMeX/sub 2/ composition, where Me is Zn (2), Cd (2); X is NO/sub 3//sup -/, CH/sub 3/COO/sup -/, CL/sup -/, Br/sup -/, I/sup -/, 1/2SO/sub 4//sup -2/, as well as acid compounds of (MBIH)/sub 2/(CdX/sub 4/) composition, where X is Cl/sup -/, Br/sup -/, I/sup -/, have been obtained and investigated. The synthetized compounds are of white colour, they are stable in air, soluble in alcohols, decomposed by water. Decomposition temperatures for most of the Cd(2) compounds lie above 250 deg C. Infrared spectra and diffractograms of these compounds have been studied. From the curves of radial distribution of atomic density, the ionic nature of the bonding of halide groups in the complexes has been established.
Publication Date:
Jul 01, 1978
Product Type:
Journal Article
Reference Number:
AIX-10-432482; EDB-79-083921
Resource Relation:
Journal Name: Ukr. Khim. Zh.; (USSR); Journal Volume: 44:7
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CADMIUM COMPLEXES; CHEMICAL PREPARATION; ZINC COMPLEXES; BENZIMIDAZOLES; CHEMICAL BONDS; CHEMICAL PROPERTIES; INFRARED SPECTRA; PYROLYSIS; AZOLES; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; HETEROCYCLIC COMPOUNDS; IMIDAZOLES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SPECTRA; SYNTHESIS; THERMOCHEMICAL PROCESSES; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6295696
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: UKZHA
Submitting Site:
INIS
Size:
Pages: 687-689
Announcement Date:
May 01, 1979

Citation Formats

Slyusarenko, K F, Artemenko, M V, Pokhodnya, G A, and Kononenko, O.M. (Kievskij Tekhnologicheskij Inst. Pishchevoj Promyshlennosti (Ukrainian SSR)). Complexes of Zn(2) and Cd(2) with 2-methyl-benzimidazole. USSR: N. p., 1978. Web.
Slyusarenko, K F, Artemenko, M V, Pokhodnya, G A, & Kononenko, O.M. (Kievskij Tekhnologicheskij Inst. Pishchevoj Promyshlennosti (Ukrainian SSR)). Complexes of Zn(2) and Cd(2) with 2-methyl-benzimidazole. USSR.
Slyusarenko, K F, Artemenko, M V, Pokhodnya, G A, and Kononenko, O.M. (Kievskij Tekhnologicheskij Inst. Pishchevoj Promyshlennosti (Ukrainian SSR)). 1978. "Complexes of Zn(2) and Cd(2) with 2-methyl-benzimidazole." USSR.
@misc{etde_6295696,
title = {Complexes of Zn(2) and Cd(2) with 2-methyl-benzimidazole}
author = {Slyusarenko, K F, Artemenko, M V, Pokhodnya, G A, and Kononenko, O.M. (Kievskij Tekhnologicheskij Inst. Pishchevoj Promyshlennosti (Ukrainian SSR))}
abstractNote = {Coordination compounds of Zn(2) and Cd(2) salts with 2-methyl-benzimidazole (MBI) of 2MBIxMeX/sub 2/ composition, where Me is Zn (2), Cd (2); X is NO/sub 3//sup -/, CH/sub 3/COO/sup -/, CL/sup -/, Br/sup -/, I/sup -/, 1/2SO/sub 4//sup -2/, as well as acid compounds of (MBIH)/sub 2/(CdX/sub 4/) composition, where X is Cl/sup -/, Br/sup -/, I/sup -/, have been obtained and investigated. The synthetized compounds are of white colour, they are stable in air, soluble in alcohols, decomposed by water. Decomposition temperatures for most of the Cd(2) compounds lie above 250 deg C. Infrared spectra and diffractograms of these compounds have been studied. From the curves of radial distribution of atomic density, the ionic nature of the bonding of halide groups in the complexes has been established.}
journal = []
volume = {44:7}
journal type = {AC}
place = {USSR}
year = {1978}
month = {Jul}
}