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Electrolyte for niobium coating deposition. Ehlektrolit dlya osazhdeniya niobievykh pokrytij

Abstract

Electrolyte composition is devised, which permits to increase by an order (as compared with the known compositions) current efficiency in the process of niobium coating electrodeposition. The following ratio of the electrolyte components, g/l, is recommended: dicyclopentadienylniobiumdichloride 5-10, sodium perchlorate - 10-50, dimethylformamide or its mixture with methanol (4:1-20:1) - to 1 l. The process of electrodeposition is realized at the temperature 20-40 deg C and cathode current density 0.05 A/dmS for 0.25-2 h. The cathode potential has the value 0.9-1.5 V (as to relatively saturated mercurous chloride electrode). Copper, platinum, graphite were used as the cathode materials, graphite - as the anode one. The results obtained are substantiated. 1 table.
Publication Date:
Jul 07, 1982
Product Type:
Patent
Report Number:
SU 1181337; A
Reference Number:
EDB-87-133681
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; NIOBIUM; ELECTRODEPOSITION; AMIDES; CHEMICAL COMPOSITION; CHLORIDES; CURRENT DENSITY; CYCLOALKENES; DIENES; ELECTRIC POTENTIAL; ELECTRODES; ELECTROLYTES; METHANOL; NIOBIUM COMPLEXES; SODIUM PERCHLORATES; ALCOHOLS; ALKALI METAL COMPOUNDS; ALKENES; CHLORINE COMPOUNDS; COMPLEXES; DEPOSITION; ELECTROLYSIS; ELEMENTS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; HYDROXY COMPOUNDS; LYSIS; METALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PERCHLORATES; POLYENES; SODIUM COMPOUNDS; SURFACE COATING; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS; 400400* - Electrochemistry
OSTI ID:
6292976
Country of Origin:
USSR
Language:
Russian
Submitting Site:
HEDB
Size:
Pages: 4
Announcement Date:
Aug 01, 1987

Citation Formats

Mikshis, Yu I, Kentra, P P, Knizhnikov, B A, and Ol'dekop, Yu A. Electrolyte for niobium coating deposition. Ehlektrolit dlya osazhdeniya niobievykh pokrytij. USSR: N. p., 1982. Web.
Mikshis, Yu I, Kentra, P P, Knizhnikov, B A, & Ol'dekop, Yu A. Electrolyte for niobium coating deposition. Ehlektrolit dlya osazhdeniya niobievykh pokrytij. USSR.
Mikshis, Yu I, Kentra, P P, Knizhnikov, B A, and Ol'dekop, Yu A. 1982. "Electrolyte for niobium coating deposition. Ehlektrolit dlya osazhdeniya niobievykh pokrytij." USSR.
@misc{etde_6292976,
title = {Electrolyte for niobium coating deposition. Ehlektrolit dlya osazhdeniya niobievykh pokrytij}
author = {Mikshis, Yu I, Kentra, P P, Knizhnikov, B A, and Ol'dekop, Yu A}
abstractNote = {Electrolyte composition is devised, which permits to increase by an order (as compared with the known compositions) current efficiency in the process of niobium coating electrodeposition. The following ratio of the electrolyte components, g/l, is recommended: dicyclopentadienylniobiumdichloride 5-10, sodium perchlorate - 10-50, dimethylformamide or its mixture with methanol (4:1-20:1) - to 1 l. The process of electrodeposition is realized at the temperature 20-40 deg C and cathode current density 0.05 A/dmS for 0.25-2 h. The cathode potential has the value 0.9-1.5 V (as to relatively saturated mercurous chloride electrode). Copper, platinum, graphite were used as the cathode materials, graphite - as the anode one. The results obtained are substantiated. 1 table.}
place = {USSR}
year = {1982}
month = {Jul}
}