Abstract
The time-course of absorption changes of oxygen-saturated solutions of bovine-liver catalase after pulse radiolysis have been studied. The rate constant of formation of Compound I due to the reaction of catalase with hydrogen peroxide has been estimated to be 2.0 x 10/sup 7/ dm/sup 3/ mol/sup -1/s/sup -1/. Radiation generated super-oxide radicals reduce Compound I to Compound II with a rate constant of 5.0 x 10/sup 6/ dm/sup 3/ mol/sup -1/s/sup -1/. The formation of Compound III in the direct reaction of O/sub 2//sup -/ with catalase has also been observed.
Citation Formats
Gebicka, Lidia, Metodiewa, Diana, and Gebicki, J L.
Pulse radiolysis of catalase in solution: Pt. 1. Reactions of O/sub 2//sup -/ with catalase and its Compound I.
United Kingdom: N. p.,
1989.
Web.
doi:10.1080/09553008914550051.
Gebicka, Lidia, Metodiewa, Diana, & Gebicki, J L.
Pulse radiolysis of catalase in solution: Pt. 1. Reactions of O/sub 2//sup -/ with catalase and its Compound I.
United Kingdom.
https://doi.org/10.1080/09553008914550051
Gebicka, Lidia, Metodiewa, Diana, and Gebicki, J L.
1989.
"Pulse radiolysis of catalase in solution: Pt. 1. Reactions of O/sub 2//sup -/ with catalase and its Compound I."
United Kingdom.
https://doi.org/10.1080/09553008914550051.
@misc{etde_6267671,
title = {Pulse radiolysis of catalase in solution: Pt. 1. Reactions of O/sub 2//sup -/ with catalase and its Compound I}
author = {Gebicka, Lidia, Metodiewa, Diana, and Gebicki, J L}
abstractNote = {The time-course of absorption changes of oxygen-saturated solutions of bovine-liver catalase after pulse radiolysis have been studied. The rate constant of formation of Compound I due to the reaction of catalase with hydrogen peroxide has been estimated to be 2.0 x 10/sup 7/ dm/sup 3/ mol/sup -1/s/sup -1/. Radiation generated super-oxide radicals reduce Compound I to Compound II with a rate constant of 5.0 x 10/sup 6/ dm/sup 3/ mol/sup -1/s/sup -1/. The formation of Compound III in the direct reaction of O/sub 2//sup -/ with catalase has also been observed.}
doi = {10.1080/09553008914550051}
journal = []
volume = {55:1}
journal type = {AC}
place = {United Kingdom}
year = {1989}
month = {Jan}
}
title = {Pulse radiolysis of catalase in solution: Pt. 1. Reactions of O/sub 2//sup -/ with catalase and its Compound I}
author = {Gebicka, Lidia, Metodiewa, Diana, and Gebicki, J L}
abstractNote = {The time-course of absorption changes of oxygen-saturated solutions of bovine-liver catalase after pulse radiolysis have been studied. The rate constant of formation of Compound I due to the reaction of catalase with hydrogen peroxide has been estimated to be 2.0 x 10/sup 7/ dm/sup 3/ mol/sup -1/s/sup -1/. Radiation generated super-oxide radicals reduce Compound I to Compound II with a rate constant of 5.0 x 10/sup 6/ dm/sup 3/ mol/sup -1/s/sup -1/. The formation of Compound III in the direct reaction of O/sub 2//sup -/ with catalase has also been observed.}
doi = {10.1080/09553008914550051}
journal = []
volume = {55:1}
journal type = {AC}
place = {United Kingdom}
year = {1989}
month = {Jan}
}