You need JavaScript to view this
ETDEWEB   /       /    /sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid

/sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid

Journal Article:

SAVE / SHARE

XML RIS EndNote CSV/Excel JSON

Abstract

A full pH range /sup 1/H and /sup 13/C nmr study was performed of the complexation of UO/sub 2//sup 2 +/ with malic acid, for variable concentrations and molar ratios. Spectral evidence for the existence of at least five complexes was found, and their stoichiometry and dependence on pH were investigated. Information on the bound ligand molecules was also obtained.
Authors:
Nunes, M T; [1]  Gil, V M.S.; [2]  Xavier, A V [3] 
  1. Junta de Energia Nuclear, Sacavem (Portugal). Lab. de Fisica e Engenharia Nucleares
  2. Aveiro Univ. (Portugal). Dept. of Chemistry
  3. Departamento de Quimica e Biotecnia, FCT, UNL, (Portugal)
Publication Date:
Apr 15, 1982
DOI:
https://doi.org/10.1139/v82-150
Product Type:
Journal Article
Reference Number:
AIX-14-760747; EDB-83-123666
Resource Relation:
Journal Name: Can. J. Chem.; (Canada); Journal Volume: 60:8
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MALIC ACID; CHEMICAL REACTIONS; URANYL COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; AQUEOUS SOLUTIONS; CARBON 13; EQUILIBRIUM; HYDROGEN; NMR SPECTRA; NUCLEAR MAGNETIC RESONANCE; PH VALUE; ACTINIDE COMPLEXES; CARBON ISOTOPES; CARBOXYLIC ACIDS; COMPLEXES; DISPERSIONS; ELEMENTS; EVEN-ODD NUCLEI; HYDROXY ACIDS; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; MIXTURES; NONMETALS; NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; RESONANCE; SOLUTIONS; SPECTRA; STABLE ISOTOPES; URANIUM COMPLEXES; 400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
OSTI ID:
6262540
Country of Origin:
Canada
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: CJCHA
Submitting Site:
HEDB
Size:
Pages: 1007-1018
Announcement Date:
May 01, 1983

Journal Article:

SAVE / SHARE

XML RIS EndNote CSV/Excel JSON

Citation Formats

Nunes, M T, Gil, V M.S., and Xavier, A V. /sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid. Canada: N. p., 1982. Web. doi:10.1139/v82-150.
Nunes, M T, Gil, V M.S., & Xavier, A V. /sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid. Canada. https://doi.org/10.1139/v82-150
Nunes, M T, Gil, V M.S., and Xavier, A V. 1982. "/sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid." Canada. https://doi.org/10.1139/v82-150.
@misc{etde_6262540,
title = {/sup 1/H and /sup 13/C nuclear magnetic resonance study of the complexation of uranyl ion with malic acid}
 author = {Nunes, M T, Gil, V M.S., and Xavier, A V}
 abstractNote = {A full pH range /sup 1/H and /sup 13/C nmr study was performed of the complexation of UO/sub 2//sup 2 +/ with malic acid, for variable concentrations and molar ratios. Spectral evidence for the existence of at least five complexes was found, and their stoichiometry and dependence on pH were investigated. Information on the bound ligand molecules was also obtained.}
 doi = {10.1139/v82-150}
 journal = []
 volume = {60:8}
 journal type = {AC}
 place = {Canada}
 year = {1982}
 month = {Apr}
 }