You need JavaScript to view this

Radiochemical studies on amorphous zirconium phosphate

Abstract

Amorphous zirconium phosphate (ZrP) is used in some hemodialysis machines for the regeneration of dialysate. Its function is to adsorb ammonium ions formed by the pretreatment of urea by urease. It also adsorbs Ca, Mg and K ions but leaches phosphate ions which are then removed (along with F/sup -/ ions) by a bed of hydrous zirconium oxide. The sodium form of ZrP is used although other forms have been suggested for use. The work reported here describes some preliminary radiochemical studies on the mechanism of release of phosphate ions and its possible relationship to sodium ion-exchange. /sup 32/P labelled material (HHZrP) was used for elution experiments with deionized water and buffer solutions having the pH's 4.2, 7.0 and 9.2. Buffer solutions used were as supplied by BDH. Elution was at four different temperatures in the range 293 to 363/sup 0/C. In the second series of experiments HHZrP was suspended in a NaCl solution labelled with /sup 22/Na. From this, /sup 22/Na labelled ZrP (NaHZrP) was prepared and eluted in the same way as the HHZrP. Results are given and discussed.
Authors:
Dyer, A; Moores, G E [1] 
  1. Salford Univ. (UK). Dept. of Chemistry and Applied Chemistry
Publication Date:
Jan 01, 1981
Product Type:
Journal Article
Reference Number:
AIX-12-624265; EDB-82-003602
Resource Relation:
Journal Name: J. Inorg. Nucl. Chem.; (United Kingdom); Journal Volume: 43:9
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; PHOSPHATES; LEACHING; PHOSPHORUS 32; ION EXCHANGE; RADIOCHEMISTRY; SODIUM 22; ZIRCONIUM PHOSPHATES; LABELLING; AMORPHOUS STATE; CHEMICAL REACTION KINETICS; LABELLED COMPOUNDS; PH VALUE; TEMPERATURE DEPENDENCE; TRACER TECHNIQUES; ALKALI METAL ISOTOPES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; CHEMISTRY; DAYS LIVING RADIOISOTOPES; DISSOLUTION; ISOTOPE APPLICATIONS; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHOSPHORUS ISOTOPES; RADIOISOTOPES; REACTION KINETICS; SEPARATION PROCESSES; SODIUM ISOTOPES; TRANSITION ELEMENT COMPOUNDS; YEARS LIVING RADIOISOTOPES; ZIRCONIUM COMPOUNDS; 400201* - Chemical & Physicochemical Properties; 400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
OSTI ID:
6243677
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JINCA
Submitting Site:
INIS
Size:
Pages: 2146-2148
Announcement Date:
Sep 01, 1981

Citation Formats

Dyer, A, and Moores, G E. Radiochemical studies on amorphous zirconium phosphate. United Kingdom: N. p., 1981. Web. doi:10.1016/0022-1902(81)80569-6.
Dyer, A, & Moores, G E. Radiochemical studies on amorphous zirconium phosphate. United Kingdom. https://doi.org/10.1016/0022-1902(81)80569-6
Dyer, A, and Moores, G E. 1981. "Radiochemical studies on amorphous zirconium phosphate." United Kingdom. https://doi.org/10.1016/0022-1902(81)80569-6.
@misc{etde_6243677,
title = {Radiochemical studies on amorphous zirconium phosphate}
author = {Dyer, A, and Moores, G E}
abstractNote = {Amorphous zirconium phosphate (ZrP) is used in some hemodialysis machines for the regeneration of dialysate. Its function is to adsorb ammonium ions formed by the pretreatment of urea by urease. It also adsorbs Ca, Mg and K ions but leaches phosphate ions which are then removed (along with F/sup -/ ions) by a bed of hydrous zirconium oxide. The sodium form of ZrP is used although other forms have been suggested for use. The work reported here describes some preliminary radiochemical studies on the mechanism of release of phosphate ions and its possible relationship to sodium ion-exchange. /sup 32/P labelled material (HHZrP) was used for elution experiments with deionized water and buffer solutions having the pH's 4.2, 7.0 and 9.2. Buffer solutions used were as supplied by BDH. Elution was at four different temperatures in the range 293 to 363/sup 0/C. In the second series of experiments HHZrP was suspended in a NaCl solution labelled with /sup 22/Na. From this, /sup 22/Na labelled ZrP (NaHZrP) was prepared and eluted in the same way as the HHZrP. Results are given and discussed.}
doi = {10.1016/0022-1902(81)80569-6}
journal = []
volume = {43:9}
journal type = {AC}
place = {United Kingdom}
year = {1981}
month = {Jan}
}