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Tar bases in low-temperature coal tar

Abstract

Tar bases were extracted from three fractions, that boil below 260/sup 0/ at 260/sup 0/ to 280/sup 0/, and 280/sup 0/ to 330/sup 0/, respectively, of the low-temperature tar obtained by the carbonization of Ube coal in a Koppers' vertical retort at approximately 750/sup 0/. These were divided, respectively, into three groups, acetate-forming amine, HCl salt-forming bases (I), and CHCl/sub 3/-soluble bases (II), and further fractionally distilled. From the physical and chemical properties of the fractions thus obtained, it was concluded that low-temperature coal tar contained no low boiling pyridine homologues and that, besides higher homologues of pyridine, nonaromatic, more saturated, and less basic compounds of larger atomic weight and smaller refractive index, such as derivatives of pyrrole and indole, also existed as in crude petroleum.
Publication Date:
Jan 01, 1951
Product Type:
Journal Article
Reference Number:
EDB-81-119489
Resource Relation:
Journal Name: Koru Taru; (Japan); Journal Volume: 3
Subject:
01 COAL, LIGNITE, AND PEAT; COAL; CARBONIZATION; COAL TAR; FRACTIONATION; COAL TAR BASES; CHEMICAL PROPERTIES; DISTILLATION; PHYSICAL PROPERTIES; SOLVENT EXTRACTION; JAPAN; PROCESSING; PYRIDINES; ASIA; AZINES; BASES; CARBONACEOUS MATERIALS; CHEMICAL REACTIONS; DECOMPOSITION; ENERGY SOURCES; EXTRACTION; FOSSIL FUELS; FUELS; HETEROCYCLIC COMPOUNDS; MATERIALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OTHER ORGANIC COMPOUNDS; SEPARATION PROCESSES; TAR; 010500* - Coal, Lignite, & Peat- Products & By-Products; 010600 - Coal, Lignite, & Peat- Properties & Composition
OSTI ID:
6216675
Country of Origin:
Japan
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: KTARA
Submitting Site:
TIC
Size:
Pages: 292-298
Announcement Date:
Nov 01, 1981

Citation Formats

Sugiura, S, Ueno, H, and Yokoyama, H. Tar bases in low-temperature coal tar. Japan: N. p., 1951. Web.
Sugiura, S, Ueno, H, & Yokoyama, H. Tar bases in low-temperature coal tar. Japan.
Sugiura, S, Ueno, H, and Yokoyama, H. 1951. "Tar bases in low-temperature coal tar." Japan.
@misc{etde_6216675,
title = {Tar bases in low-temperature coal tar}
author = {Sugiura, S, Ueno, H, and Yokoyama, H}
abstractNote = {Tar bases were extracted from three fractions, that boil below 260/sup 0/ at 260/sup 0/ to 280/sup 0/, and 280/sup 0/ to 330/sup 0/, respectively, of the low-temperature tar obtained by the carbonization of Ube coal in a Koppers' vertical retort at approximately 750/sup 0/. These were divided, respectively, into three groups, acetate-forming amine, HCl salt-forming bases (I), and CHCl/sub 3/-soluble bases (II), and further fractionally distilled. From the physical and chemical properties of the fractions thus obtained, it was concluded that low-temperature coal tar contained no low boiling pyridine homologues and that, besides higher homologues of pyridine, nonaromatic, more saturated, and less basic compounds of larger atomic weight and smaller refractive index, such as derivatives of pyrrole and indole, also existed as in crude petroleum.}
journal = []
volume = {3}
journal type = {AC}
place = {Japan}
year = {1951}
month = {Jan}
}