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X-ray crystal and molecular structure of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/. 2PPh/sub 3/O thf: trichloro (eta/sup 5/cyclopentadienyl)bis(triphenylphosphine oxide) uranium(IV). thf

Abstract

Following reports of the preparation of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/.xL (x = 1, L = dimethoxyethane and x = 2, L = tetrahydrofuran (thf), a series of analogous oxygen-donor complexes were isolated. This paper describes the crystal and molecular structure of one of them, ((eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/.2PPh/sub 3/O)thf.
Authors:
Bombieri, G; De Paoli, G; [1]  Del Pra, A; Bagnall, K W
  1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
Publication Date:
Jan 01, 1978
Product Type:
Journal Article
Reference Number:
AIX-10-423003; EDB-79-069642
Resource Relation:
Journal Name: Inorg. Nucl. Chem. Lett.; (United Kingdom); Journal Volume: 14:10
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; URANIUM COMPLEXES; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; CHEMICAL PREPARATION; CYCLOPENTADIENE; FURANS; ORGANIC CHLORINE COMPOUNDS; TPO; URANIUM CHLORIDES; X-RAY DIFFRACTION; ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; ALKENES; CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; COMPLEXES; CYCLOALKENES; DIENES; DIFFRACTION; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; POLYENES; SCATTERING; SYNTHESIS; URANIUM COMPOUNDS; 400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
OSTI ID:
6141115
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: INUCA
Submitting Site:
INIS
Size:
Pages: 359-361
Announcement Date:
Mar 01, 1979

Citation Formats

Bombieri, G, De Paoli, G, Del Pra, A, and Bagnall, K W. X-ray crystal and molecular structure of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/. 2PPh/sub 3/O thf: trichloro (eta/sup 5/cyclopentadienyl)bis(triphenylphosphine oxide) uranium(IV). thf. United Kingdom: N. p., 1978. Web. doi:10.1016/0020-1650(78)80055-5.
Bombieri, G, De Paoli, G, Del Pra, A, & Bagnall, K W. X-ray crystal and molecular structure of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/. 2PPh/sub 3/O thf: trichloro (eta/sup 5/cyclopentadienyl)bis(triphenylphosphine oxide) uranium(IV). thf. United Kingdom. https://doi.org/10.1016/0020-1650(78)80055-5
Bombieri, G, De Paoli, G, Del Pra, A, and Bagnall, K W. 1978. "X-ray crystal and molecular structure of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/. 2PPh/sub 3/O thf: trichloro (eta/sup 5/cyclopentadienyl)bis(triphenylphosphine oxide) uranium(IV). thf." United Kingdom. https://doi.org/10.1016/0020-1650(78)80055-5.
@misc{etde_6141115,
title = {X-ray crystal and molecular structure of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/. 2PPh/sub 3/O thf: trichloro (eta/sup 5/cyclopentadienyl)bis(triphenylphosphine oxide) uranium(IV). thf}
author = {Bombieri, G, De Paoli, G, Del Pra, A, and Bagnall, K W}
abstractNote = {Following reports of the preparation of (eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/.xL (x = 1, L = dimethoxyethane and x = 2, L = tetrahydrofuran (thf), a series of analogous oxygen-donor complexes were isolated. This paper describes the crystal and molecular structure of one of them, ((eta/sup 5/C/sub 5/H/sub 5/)UCl/sub 3/.2PPh/sub 3/O)thf.}
doi = {10.1016/0020-1650(78)80055-5}
journal = []
volume = {14:10}
journal type = {AC}
place = {United Kingdom}
year = {1978}
month = {Jan}
}