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Unlimited mutual solubility in the system LaTiO/sub 3/-YTiO/sub 3/

Journal Article:

Abstract

Formation of unlimited series of solid solutions of substitution Lasub(1-x)Ysub(x)TiOsub(3) (1) with the structure of rhombic perovskite (sp. gr. Pbnm) is established using X-ray diffraction. With the increase of yttrium content in 1 a distortion of perovskite structure is intensified with the decrease of parameters a and c, increase of parameter b and decrease of unit cell volume V take place. Anomalies on the cirves, expressing the dependences b=f(x) and V=f(rsub(Lnsub(3+))sup(3)) in the limits 1 are connected with considerable distortion of oxygen octahedrons TiO/sub 6/ of LnTiO/sub 3/, where Ln-Sm, Gd and Y.
Authors:
Bazuev, G V; Shvejkin, G P [1] 
  1. AN SSSR, Sverdlovsk. Inst. Khimii
Publication Date:
Aug 01, 1982
Product Type:
Journal Article
Reference Number:
AIX-14-757793; EDB-83-123323
Resource Relation:
Journal Name: Zh. Neorg. Khim.; (USSR); Journal Volume: 27:8; Other Information: For English translation see the journal Russian Journal of Inorganic Chemistry (UK)
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; GADOLINIUM COMPOUNDS; LATTICE PARAMETERS; LANTHANUM COMPOUNDS; SOLUBILITY; SAMARIUM COMPOUNDS; TITANATES; YTTRIUM COMPOUNDS; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; DISSOCIATION; PEROVSKITES; QUANTITY RATIO; SOLID SOLUTIONS; SPACE GROUPS; X-RAY DIFFRACTION; COHERENT SCATTERING; DIFFRACTION; DISPERSIONS; MIXTURES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SCATTERING; SOLUTIONS; SYNTHESIS; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 400201* - Chemical & Physicochemical Properties
OSTI ID:
6108683
Country of Origin:
USSR
Language:
Russian
Other Identifying Numbers:
Journal ID: CODEN: ZNOKA
Submitting Site:
HEDB
Size:
Pages: 2080-2083
Announcement Date:

Journal Article:

Citation Formats

Bazuev, G V, and Shvejkin, G P. Unlimited mutual solubility in the system LaTiO/sub 3/-YTiO/sub 3/. USSR: N. p., 1982. Web.
Bazuev, G V, & Shvejkin, G P. Unlimited mutual solubility in the system LaTiO/sub 3/-YTiO/sub 3/. USSR.
Bazuev, G V, and Shvejkin, G P. 1982. "Unlimited mutual solubility in the system LaTiO/sub 3/-YTiO/sub 3/." USSR.
@misc{etde_6108683,
title = {Unlimited mutual solubility in the system LaTiO/sub 3/-YTiO/sub 3/}
author = {Bazuev, G V, and Shvejkin, G P}
abstractNote = {Formation of unlimited series of solid solutions of substitution Lasub(1-x)Ysub(x)TiOsub(3) (1) with the structure of rhombic perovskite (sp. gr. Pbnm) is established using X-ray diffraction. With the increase of yttrium content in 1 a distortion of perovskite structure is intensified with the decrease of parameters a and c, increase of parameter b and decrease of unit cell volume V take place. Anomalies on the cirves, expressing the dependences b=f(x) and V=f(rsub(Lnsub(3+))sup(3)) in the limits 1 are connected with considerable distortion of oxygen octahedrons TiO/sub 6/ of LnTiO/sub 3/, where Ln-Sm, Gd and Y.}
journal = {Zh. Neorg. Khim.; (USSR)}
volume = {27:8}
journal type = {AC}
place = {USSR}
year = {1982}
month = {Aug}
}