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Complexes of Sm(III) and Dy(III) with piperazines

Journal Article:

Abstract

Complexes of SmCl/sub 3/, DyCl/sub 3/, Sm(NO/sub 3/)/sub 3/ and Dy(NO/sub 3/) with piperazine, N-methylpiperazine, 2-methylpiperazine, N-phenyl-piperazine and N, N'-dimethyl-piperazine have been prepared and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate that the ligands are coordinated in the chair conformation giving polymeric bridged complexes and that the nitrate group is bidentate. Coordination numbers from 6 to 12 are proposed for the lanthanide ions.
Authors:
Manhas, B S; Trikha, A K; [1]  Singh, M [2] 
  1. Punjabi Univ., Patiala (India). Dept. of Chemistry
  2. Guru Nanak Dev Univ., Amritsar (India). Dept. of Chemistry
Publication Date:
Sep 01, 1981
Product Type:
Journal Article
Reference Number:
AIX-16-005235; EDB-85-047923
Resource Relation:
Journal Name: Indian J. Chem., Sect. A; (India); Journal Volume: 20:9
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DYSPROSIUM COMPLEXES; CHEMICAL COMPOSITION; STRUCTURAL CHEMICAL ANALYSIS; SAMARIUM COMPLEXES; CHEMICAL PREPARATION; CHLORIDES; COORDINATION NUMBER; ELECTRON SPECTRA; INFRARED SPECTRA; LIGANDS; MAGNETIC SUSCEPTIBILITY; NITRATES; PIPERAZINES; AZINES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; MAGNETIC PROPERTIES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; PYRAZINES; RARE EARTH COMPLEXES; SPECTRA; SYNTHESIS; 400201* - Chemical & Physicochemical Properties; 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
OSTI ID:
6103031
Country of Origin:
India
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: IJCAD
Submitting Site:
HEDB
Size:
Pages: 919-920
Announcement Date:

Journal Article:

Citation Formats

Manhas, B S, Trikha, A K, and Singh, M. Complexes of Sm(III) and Dy(III) with piperazines. India: N. p., 1981. Web.
Manhas, B S, Trikha, A K, & Singh, M. Complexes of Sm(III) and Dy(III) with piperazines. India.
Manhas, B S, Trikha, A K, and Singh, M. 1981. "Complexes of Sm(III) and Dy(III) with piperazines." India.
@misc{etde_6103031,
title = {Complexes of Sm(III) and Dy(III) with piperazines}
author = {Manhas, B S, Trikha, A K, and Singh, M}
abstractNote = {Complexes of SmCl/sub 3/, DyCl/sub 3/, Sm(NO/sub 3/)/sub 3/ and Dy(NO/sub 3/) with piperazine, N-methylpiperazine, 2-methylpiperazine, N-phenyl-piperazine and N, N'-dimethyl-piperazine have been prepared and characterized on the basis of elemental analyses, IR and electronic reflectance spectra and magnetic susceptibility measurements. IR data indicate that the ligands are coordinated in the chair conformation giving polymeric bridged complexes and that the nitrate group is bidentate. Coordination numbers from 6 to 12 are proposed for the lanthanide ions.}
journal = {Indian J. Chem., Sect. A; (India)}
volume = {20:9}
journal type = {AC}
place = {India}
year = {1981}
month = {Sep}
}