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Moessbauer study of iron-cobalt-rhodium spinels

Abstract

Moessbauer source and absorber studies have been carried out on the spinel system CoFesub(x)Rhsub(2-x)O/sub 4/ for x 0.005, 0.3, 0.5, 1.0, 1.2 and 1.5. For 0.005 =< x =< 1.2, the cation distribution is normal with Co/sup 2 +/ on A sites. At x = 1.5, the distribution is nearly inverse. In the cases x = 0.005 and 0.3, iron on the B sites does not produce a quadrupole doublet indicating that the B sites are cubic which is contrary to the usual case in spinels.
Authors:
Spencer, C D; Smith, P A; Karnes, C M; Shepard, W A [1] 
  1. Ithaca Coll., NY (USA). Dept. of Physics
Publication Date:
Jan 01, 1980
Product Type:
Journal Article
Reference Number:
AIX-12-576422; EDB-82-003214
Resource Relation:
Journal Name: J. Phys. Chem. Solids; (United Kingdom); Journal Volume: 41:10
Subject:
36 MATERIALS SCIENCE; COBALT OXIDES; MOESSBAUER EFFECT; IRON OXIDES; RHODIUM OXIDES; SPECTRA; CHALCOGENIDES; COBALT COMPOUNDS; IRON COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RHODIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 360202* - Ceramics, Cermets, & Refractories- Structure & Phase Studies
OSTI ID:
6089583
Country of Origin:
United Kingdom
Language:
English
Other Identifying Numbers:
Journal ID: CODEN: JPCSA
Submitting Site:
INIS
Size:
Pages: 1079-1082
Announcement Date:

Citation Formats

Spencer, C D, Smith, P A, Karnes, C M, and Shepard, W A. Moessbauer study of iron-cobalt-rhodium spinels. United Kingdom: N. p., 1980. Web. doi:10.1016/0022-3697(80)90062-1.
Spencer, C D, Smith, P A, Karnes, C M, & Shepard, W A. Moessbauer study of iron-cobalt-rhodium spinels. United Kingdom. doi:10.1016/0022-3697(80)90062-1.
Spencer, C D, Smith, P A, Karnes, C M, and Shepard, W A. 1980. "Moessbauer study of iron-cobalt-rhodium spinels." United Kingdom. doi:10.1016/0022-3697(80)90062-1. https://www.osti.gov/servlets/purl/10.1016/0022-3697(80)90062-1.
@misc{etde_6089583,
title = {Moessbauer study of iron-cobalt-rhodium spinels}
author = {Spencer, C D, Smith, P A, Karnes, C M, and Shepard, W A}
abstractNote = {Moessbauer source and absorber studies have been carried out on the spinel system CoFesub(x)Rhsub(2-x)O/sub 4/ for x 0.005, 0.3, 0.5, 1.0, 1.2 and 1.5. For 0.005 =< x =< 1.2, the cation distribution is normal with Co/sup 2 +/ on A sites. At x = 1.5, the distribution is nearly inverse. In the cases x = 0.005 and 0.3, iron on the B sites does not produce a quadrupole doublet indicating that the B sites are cubic which is contrary to the usual case in spinels.}
doi = {10.1016/0022-3697(80)90062-1}
journal = {J. Phys. Chem. Solids; (United Kingdom)}
volume = {41:10}
journal type = {AC}
place = {United Kingdom}
year = {1980}
month = {Jan}
}